9/22/2020 CH-351: Spectroscopic Methods in Structure Determination

CH-351: Spectroscopic Methods in

Structure Determination
Dr. Anil Gokul Beldar
Department of Chemistry,
PSGVPM's ASC college Shahada
Mock Test for M.Sc.-II Organic Chemistry Students
(CH-351: Spectroscopic Methods in Structure Determination)
*Required

1. Email address *

2. Enter your Name *

3. Enter your Mobile Number *

4. Enter your College Name *

Time- 11:00 AM to 01:00PM

Online Practice Test for CH: 351

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9/22/2020 CH-351: Spectroscopic Methods in Structure Determination

5. 1. Chemical shift unit is…… ? * 1 point

Mark only one oval.

A. Mm

B. Cm

C. PPM

D. None

6. 2. Due to increase hydrogen bonding in NMR proton …. * 1 point

Mark only one oval.

A. Deshielded

B. Shielded

C. Increase chemical shift

D. A and C

7. 3. Due to steric effects in NMR, protons …. * 1 point

Mark only one oval.

A. chemical shift value increase

B. chemical shift value decrease

C. A and B value

D. None of this

8. 4. Boltzmann distribution indicates * 1 point

Mark only one oval.

A. The relative no. of protons present in the excited state and ground state

B. Relative no. of neutrons present in the excited state and ground state

C. Relative no. of nucleus present in the excited state and ground state

D. All of the above

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9. 5. In NMR spectrum the nuclei in up field resonate at ….. * 1 point

Mark only one oval.

A. High frequency

B. Low frequency

C. It is constant throughout the spectrum

D. It doesn’t depends on chemical shift

10. 6. The nuclei that doesn’t give NMR signal is * 1 point

Mark only one oval.

A. 15N

B. 12C

C. 19F

D. 31P

11. 7. Signal splitting in NMR arises from * 1 point

Mark only one oval.

A. Shielding effect

B. Spin-spin decoupling

C. Spin-spin coupling

D. Deshielding effect

12. 8. Nuclei with odd number of protons and odd number of neutrons will 1 point

have spin quantum number as... *

Mark only one oval.

A. 1/2

B. 3/2

C. 0

D. 1

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13. 9. The possible spin states of a nucleus with spin quantum number 1/2 1 point

are.... *

Mark only one oval.

A. 0

B.1

C. 2

D. 4

14. 10. Enantiotropic protons are...... * 1 point

Mark only one oval.

A. Chemically equivalent

B. Magnetically equivalent

C Both A and B

D. Does not give NMR signal

15. 11.Which of the following solvent is not used in NMR? * 1 point

Mark only one oval.

A. D2O

B. CHCl3

C. CCl4

D. CDCl3

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16. 12. Which of the following environmental effect is influenced by magnetic 1 point

field strength? *

Mark only one oval.

A. Chemical shift

B. Spin splitting

C. Both are influenced

D. Both are not influenced

17. 13. Chemical shift has the units of.... * 1 point

Mark only one oval.

A. Parts per million

B. Parts per billion

C. Tesla

D. No units

18. 14. Equivalent protons in a molecules will have.... * 1 point

Mark only one oval.

A. Same environment

B. Same chemical shift

C. Same shielding effect

D. All of the above

19. 15. Coupling constant of two nuclei is defined as.... * 1 point

Mark only one oval.

A. Ratio of chemical shifts

B. Distance between splitted peaks in Hz

C. Difference of chemical shifts

D. Ratio of absorption frequencies

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20. 16. Which of the following produces magnetic anisotropic effect? * 1 point

Mark only one oval.

A. Hydrogen bonding

B. Aromatic ring system

C. Electronegativity

D. Electropositive

21. 17. Which of the following statement is CORRECT * 1 point

Mark only one oval.

A. More the electro negativity lesser the chemical shift

B. More the electro negativity more the chemical shift

C. More the size of the atom lesser the chemical shift

D. More the size of the atom more the chemical shift

22. 18. Which of the following proton has more chemical shift * 1 point

Mark only one oval.

A. Methylene

B. Methine

C. Methyl

D. All above

23. 19. Which technique is used to study keto enol tautomerism ? * 1 point

Mark only one oval.

A. NMR

B. UV

C. IR

D. All of the

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24. 20. How many signals does the aldehyde (CH3)3CCH2CHO have in 1H 1 point

NMR and 13C NMR spectra? *

Mark only one oval.

a) five 1H signals and six 13C signals

b) three 1H signals and four 13C signals

c) five 1H signals and four 13C signals

d) three 1H signals and six 13C signals

25. 21. How many signals does the unsaturated 1 point

ketone(CH3)2CHCH2C(O)CH=CH2 have in 1H NMR and 13C NMR spectra?

*

Mark only one oval.

a) five 1H signals and six 13C signals

b) six 1H signals and six 13C signals

c) six 1H signals and seven 13C signals

d) five 1H signals and seven 13C signals

26. 22. The 1H NMR spectrum of CH3OCHCICH2Cl will exhibit ________ * 1 point

Mark only one oval.

a) A three proton doublet. One proton singlet and a two proton doublet

b) A three proton singlet. One proton singlet and a two proton doublet

c) A three proton singlet. One proton triplet and a two proton doublet

d) A three proton triplet. One proton triplet and a two proton triple

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27. 23. Which of the following 1H-NMR spectrum of compound with molecular 1 point

formula C4H9NO2 shows delta 5.30 (broad, IH), 4.10(q, 2H), 2.80 (d, 3H),
1.20 (t, 3H) ppm? *

Mark only one oval.

a) CH3NHCOOCH2CH3

b) CH3CH2NHCOOCH3

c) CH3OCH2CONHCH3

d) CH3CH2OCH2CONH2

28. 24. How many Hertz does 1 ppm correspond to for an PMR spectrometer 1 point

operating at a radio frequency of 60 MHz and 100 MHz? *

Mark only one oval.

a) 6 Hz, 10 Hz

b) 60 Hz, 100 Hz

c) 100 Hz, 60 Hz

d) 10Hz, 100Hz

29. 25. The 1H NMR spectrum of a dilute solution of a mixture of acetone and 1 point

dichloromethane in CDCl3 exhibits two singlets of 1:1 intensity. What will

be the molar ratio of acetone to dichloromethane in the solution? *

Mark only one oval.

a) 3:1

b) 1:3

c) 1:1

d) 1:2

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30. 26. Who discovered the mass spectrometer? * 1 point

Mark only one oval.

a) Francis Aston

b) J. J Thomson

c) Ernest O. Lawrence

d) Walter Kaufmann

31. 27. What is use of mass spectroscopy ? * 1 point

Mark only one oval.

A.Determination of molecule weight

B. Determine the structures of molecules

C. A and B

D.None of the above

32. 28. Highest intense m/z peak in mass spectrum is called as * 1 point

Mark only one oval.

A. Base peak

B.Fragment peak

C.Isotopic peak

D.Parent peak

33. 29. Which of the following is not one of the types of mass analyser? * 1 point

Mark only one oval.

A. Magnetic sector analyser

B. Double focussing spectrometer

C. Frequency sweep analyser

D. Time of flight analyser

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34. 30. Propene reacts with hydrogen bromide to form a mixture of saturated 1 point

organic products. The proton n.m.r. spectrum of the major organic

product has .... *

Mark only one oval.

A. 3 peaks with relative intensities 3 : 2 : 2

B. 2 peaks with relative intensities 3 : 4

C. 3 peaks with relative intensities 3 : 1 : 3

D. 2 peaks with relative intensities 6 : 1

35. 31. Which one of the following has a singlet peak in its proton n.m.r. 1 point

spectrum? *

Mark only one oval.

A. ethyl propanoate

B. propyl methanoate

C. hexan-3-one

D. 2-chlorobutane

36. 32. When number of nitrogen atoms in a compound or ion is zero, the 1 point

molecular weight will be _____ numbered. *

Mark only one oval.

A. Odd

B. Zero

C. Even

D. All of these

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37. 33. Compound containing chlorine and bromine have _____ peak. * 1 point

Mark only one oval.

A. M+2

B. M+1

C. M+

D. All of these

38. 34. In a magnetic analyser ions are separated on the basis of____ values. * 1 point

Mark only one oval.

A. Atomic Number

B. m/z

C. Atomic mass

D. None of these

39. 35. An anisotropic effect causes shielding in the following molecule_____ * 1 point

Mark only one oval.

A. Alkynes

B. Alkene

C. Benzene

D. Aldehyde

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40. 36. What will be the strength of coupling between geminal protons in the 1 point

following molecules? *

Mark only one oval.

a) Decrease as the size of ring increase

b) Increase as the size of ring increase

c) Remains same

d) No relation between the size of the ring & coupling

41. 37. At room temperature, what is the number of singlet resonances 1 point
observed in the 1H NMR spectrum of HCC(O)NMe2 (N, N-
Dimethylformamide)? *

Mark only one oval.

a) 3

b) 4

c) 5

d) 2

42. 38. An organic compound (MF; C8H10O) exhibited the following 1H NMR 1 point
special data: 62.5 (3H, s), 3.8 (314, s), 6.8 (2H, d, J 8 Hz), 7.2 (2H, d, J 8 Hz)
ppm. What will be the compound among the choices? *

Mark only one oval.

a) 4-ethylphenol

b) 2-ethylphenol

c) 4-methylanisole

d) 4-methylbenzyl alcohol

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43. 39. How many signals appeared in 1H NMR Spectrum of the given 1 point

compounds? *

Mark only one oval.

a) One & Two

b) One & Three

c) Two & Three

d) Two & One

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44. 40. MF: C9H13N IR:1625, 1580 cm-1 PMR: 2.20 δ (s, 6H), 3.40 δ (s, 2H), 7.30 δ 1 point
(m, 5H), *

Mark only one oval.

A. B

C D

45. 41. How many signals appeared in 13C NMR Spectrum of given 1 point
compound? *

Mark only one oval.

a) Four & Four

b) Three & One

c) Three & Two

d) Four & Two

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46. 42. In following ketones, which ketone can undergo Mclafferty 1 point

Rearrangement. *

Mark only one oval.

A B

C D

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47. 43. Which compound can gives following fragment ions after genesis? * 1 point

Mark only one oval.

A B

C D

48. 44. How many lines appeared in CMR spectrum of Deutarated DMSO? * 1 point

Mark only one oval.

a) Seven

b) Three

c) Five

d) Four

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49. 45. MF: C6H10O3 IR: 1740, 1710, 1150 cm-1 PMR: 1.28 δ (t, J=7Hz, 30mm), 2.01 1 point
δ (s, 30mm), 3.24 δ (s, 20mm), 4.20 δ (q, J=7Hz, 20mm) *

Mark only one oval.

A B

C D

50. 46. Which of the following statements is true concerning infrared 1 point

spectroscopy? *

Mark only one oval.

A. IR spectroscopy is useful in determining the size and shape of a compound's

carbon skeleton.

B. An IR spectrometer shines infrared light on a compound and records the

positions where the light is blocked by the compound. This results in the spectrum's
peaks.

C. When the infrared light frequency matches the frequency of bond vibration in a
molecule, a peak is recorded on the spectrum.

D. Functional groups can be identified by looking in the fingerprint region of the

spectrum.

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51. 47. Which of the following functional groups exhibits the highest 1 point
frequency in an infrared (IR) spectrum? *

Mark only one oval.

A. Ketone

B. Alcohol

C. Aldehyde

D. Ester

52. 48. An alcohol group in a compound would result in a broad dip around 1 point

what part of the infrared (IR) spectrum? *

Mark only one oval.

A. 1700cm-1

B.1200cm-1

C. 3400cm-1

D. 2800cm-1

53. 49. An unknown compound is analyzed using infrared spectroscopy. A 1 point

strong, sharp peak is observed at a frequency of 1750cm-1. What

functional group is present? *

Mark only one oval.

A. Alcohol

B. Unsaturated ketone

C. Ester

D.Nitrile

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54. 50. An IR spectrum reading is taken before and after treating acetone with 1 point

the reducing agent NaBH4. What IR peak readings would be seen for the
reactant acetone and for the predicted product? *

Mark only one oval.

A. Acetone: 3300cm−1, Product: 1750cm−1

B. Acetone: 1000cm−1, Product: 3300cm−1

C. Acetone: 1720cm−1, Product: 3300cm−1

D. Acetone: 3300cm−1, Product: 3300cm−1

55. 51. Which of the following finger print region found in IR spectroscopy? * 1 point

Mark only one oval.

A. 4000 to 1000 cm

B. 1500 to 400 cm

C. 200 to 1400cm

D. 2999 to 1200 cm

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56. 52. MF: C9H12 IR: 3030, 2950, 1600, 1550 cm-1 CMR: 21.2 δ (q), 127.2 δ (d), 1 point
137.5 δ (s) *

Mark only one oval.

A B

C D

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57. 53. MF: C4H8O IR: 1200 cm-1 CMR: 33 δ (t), 65 δ (t) * 1 point

Mark only one oval.

A B

C D

58. 54. The correct order of IR frequencies of carbonyl group- * 1 point

Mark only one oval.

A. II< IV< III< I

B. IV< II< I< III

C. II< IV< I< III

D. III< II< IV< I

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59. 55. 3-J H-H coupling constants may have a value of * 1 point

Mark only one oval.

a. 140 Hz

b. 35 Hz

c. 8 Hz

d. 70 Hz

60. 56. 1-J C-H coupling constants may have a value of * 1 point

Mark only one oval.

a. 140 Hz

b. 35 Hz

c. 8 Hz

d. 70 Hz

61. 57. 3-J H-H coupling constants are dependent on * 1 point

Mark only one oval.

a. magnetic field strength

b. relative orientation of the coupled protons

c. sample concentration

d. 90◦ pulse width

62. 58. The natural abundance of 13C is about * 1 point

Mark only one oval.

a. four times less than 1H

b. 0.11% of total carbon

c. 1.1% of total carbon

d. 99% of total carbon

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63. 59. Chemical shifts originate from * 1 point

Mark only one oval.

a. magnetic momentum

b. electron shielding

c. free induction decay

d. scalar coupling (J -coupling)

64. 60. Deuterated solvent in an NMR sample is used to * 1 point

Mark only one oval.

a. stabilize the magnetic field

b. set the chemical shift reference

c. obtain good field homogeneity across the sample

d. both (a) and (c)

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