Geopolymer Ferrocement Panels Under Flexural Loading: Mohana Rajendran and Nagan Soundarapandian

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DOI 10.

1515/secm-2013-0012      Sci Eng Compos Mater 2015; 22(3): 331–341

Mohana Rajendran* and Nagan Soundarapandian

Geopolymer ferrocement panels under flexural


loading
Abstract: Efforts are needed to develop innovative and the atmosphere, which makes it the third largest man-
environmental friendly materials in order to reduce green- made source of CO2. The production of cement is respon-
house gas emissions. An experimental investigation on sible for the production of 1 ton of CO2 per ton of cement
the flexural behavior of thin cementless composite pan- produced, and the cement manufacturing industry is
els reinforced with welded rectangular wire mesh and causative to contribution of 7% of global CO2 emission,
chicken mesh with varying number of mesh layers as well which is one of the greenhouse gases that causes climate
as varying concentration of alkaline solution is presented. change due to global warming. Besides, production of
A total of 30 panels have been tested under flexural load- cement is energy intensive and is only succeeding to steel
ing. The size of the panel is 1000  mm (length) × 200  mm and aluminum production [1]. Meanwhile, the growth of
(width) × 25/35  mm (thickness). The parameters studied the coal-fired power plant industry produces flue gases
in this investigation include varying the concentration of from hydrocarbon combustion that generates extensive
NaOH (8, 10, 12, 14 m) and thickness of composite panels. particulate emissions such as fly ash and bottom ash as
In this work, cement is replaced by geopolymer mix to waste products. These solid waste ashes from coal-fired
bind the ferrocement skeletal framework and its flexural boilers have previously been dumped into landfills that
behavior is studied. It is concluded that the first crack and contribute to the subsequent environmental contami-
ultimate loads increase with the increase in the thickness nation. Hence, green demands are raised for alternative
of the element and the concentration of alkaline solution. ways to utilize the ashes to mitigate further environmen-
From the studies, it is observed that the load-carrying tal pollution by copious uncontrolled disposal of the coal
capacities, energy absorption, and deformation at ulti- ashes into the landfills [2].
mate load are high in the case of geopolymer ferrocement Although the use of portland cement is still unavoid-
element. Further, it is observed that there is reduction able in the foreseeable future, many efforts are being
in crack width, and increase in number of cracks in the made to reduce the use of portland cement in the concrete
case of geopolymer ferrocement indicates delay in crack industry. These efforts include the utilization of supple-
growth. mentary cementing materials such as fly ash, silica fume,
granulated furnace slag, rice husk ash, and metakaolin,
Keywords: crack width; ferrocement; geopolymer; load and finding alternative binders to portland cement. Efforts
deformation; molarity. have therefore been made to promote the use of pozzolans
by complete replacement of cement that can be achieved
using geopolymer technology. Recently, another form of
*Corresponding author: Mohana Rajendran, Department of
Civil Engineering, Thiagarajar College of Engineering, Madurai,
cementitious materials using silicon and aluminum acti-
Tamil Nadu 6250015, India, e-mail: rmohanaselvan@gmail.com vated in a high-alkali solution was developed. This mate-
Nagan Soundarapandian: Department of Civil Engineering, rial is usually based on fly ash as a source material and is
Thiagarajar College of Engineering, Madurai, Tamil Nadu 6250015, termed geopolymer or alkali-activated fly ash cement.
India The term geopolymer was first applied by Davidovits
[3] to alkali aluminosilicate binders formed by the alkali
silicate activation of aluminosilicate materials. Geopoly-
mers are amorphous to semicrystalline equivalents of
1 Introduction certain zeolitic materials with excellent properties such as
high fire and erosion resistance and high-strength mate-
Extensive consumption of natural sources, production of rials. The most used alkaline activators are a mixture of
massive amounts of industrial wastes, and environmen- sodium or potassium hydroxide (NaOH, KOH) with sodium
tal pollution require new solutions for a more sustainable water glass or potassium water glass. The activator solu-
development. The use of modern-day cement contributes tion used in this work is NaOH and sodium water glass,
to 2 billion tonnes of carbon dioxide (CO2) annually into and the concentration of NaOH solution that can be used is
332      M. Rajendran and N. Soundarapandian: Geopolymer ferrocement panels under flexural loading

in the range of 8–14 m [4–6]. In recent years, geopolymers in the longitudinal and transverse directions and closely
have been extensively investigated due to their excellent spaced through the thickness of the section [16]. Because
characteristics including fire resistance, high compres- ferrocement lends itself to precasting, hence, precast fer-
sive strength, and immobilization of hazardous, toxic, rocement elements can be prepared to meet the strength
and radioactive wastes [1, 7–11]. Prefabricated floor is used and serviceability conditions. There is an ample scope
in the construction industry as an alternative system to for mass production and standardization together with
overcome the formwork problems (cost and delay in con- economy in construction.
struction) in addition to getting better quality control. The The objective of this work is to develop a novel low-
prefabricated elements made of reinforced concrete are cost composite material by geopolymer and ferrocement
very heavy and difficult to transport, to place in position, (FC) technology together and determine the strength of
and to construct. Alternatively, thin ferrocement panels the prefabricated geopolymer ferrocement (GF) elements
are being used in floor construction for low-cost housing by varying the alkaline concentration from 8 m to 14 m.
due to their low cost and good structural performance [12]. In the current scenario, new construction material and
Ferrocement is suitable for low-cost roofing, precast units. technology have to be developed to enhance easy fabri-
and manhole covers. It is used for the construction of cation, reducing the self-weight of material and eliminat-
domes, vaults, grid surfaces, and folded plates. It can be ing greenhouse gas production by the cement industry.
used for making water tanks, boats, and silos. Ferrocement Taking this into consideration, works are done on GF ele-
is the best alternative to concrete and steel. Generally, fer- ments for its strength, stability and applicability.
rocement shells range from 10 to 25 mm in thickness and
the reinforcement consists of layers of steel mesh, usually
with steel reinforcing bars sandwiched midway between.
The resulting shell or panel of mesh is impregnated with 2 Materials and methods
a very rich (high ratio of cement to sand) portland cement
mortar. The application of ferrocement panels/members
2.1 Materials used
has been found attractive due to these reasons: (i) Its basic
raw materials are available in most countries; (ii) it can be
The following materials are employed in this work: ordi-
fabricated into almost any shape; (iii) it is more durable
nary portland cement (53 grade), fine aggregate (sand),
than most woods and cheaper than imported steel; (iv) the
pozzolan (low-calcium fly ash), alkaline activator
skills for ferrocement construction can be easily acquired;
(NaOH+sodium silicate), chicken mesh with hexagonal
and (v) ferrocement construction is less capital-intensive
opening, and weld mesh with rectangular grid opening.
but more labor-intensive [13, 14].
Ordinary Portland cement was used to produce a
Ferrocement is a type of thin-wall reinforced concrete
control mix mortar in this paper. The physical properties
commonly constructed of hydraulic cement mortar rein-
of the cement obtained from the tests conducted as per rel-
forced with closely spaced layers of continuous and rela-
evant IS 4031 (Part 4 and 5)-1988 [17] are shown in Table 1.
tively small size wire mesh, which may be made of metallic
The fine aggregate used is ordinary river sand passed
or other suitable materials [15]. Because ferrocement pos-
through sieve no. 8 (2.36 mm) with a specific gravity of
sesses certain unique properties, such as high tensile
2.72, dry density of 1.6 g/cm3, and having a fineness
strength-to-weight ratio, superior cracking behavior, light
modulus of 2.56.
weight, moldability to any shape, and certain advantages
such as utilization of only locally available materials and
Table 1 Physical properties of cement.
semiskilled labor/workmanship, it has been considered to
be an attractive material and a material of good promise
SI no.  Physical property   Tested  Reference code
and potential by the construction industry, especially in values
developing countries. It has wide-ranging applications,
1  Specific gravity   3.15  Le-Chatelier flask IS
such as in the manufacture of boats and/barges; prefab-
1727-1967
ricated housing units; biogas structures; silos and tanks, 2  Standard consistency (%)  32  IS 4031-1988 part 4
and recently in the repair and strengthening of structures. 3  Setting time (min)    
Ferrocement is a highly versatile construction mate-    Initial   45  IS 4031-1988 part 5
rial and possesses high performance characteristic,    Final   255  IS 4031-1988 part 5
especially in cracking, strength, ductility, and impact 4  Compressive strength   54.5  –
(28 days) (MPa)
resistance, as its reinforcement is uniformly distributed
M. Rajendran and N. Soundarapandian: Geopolymer ferrocement panels under flexural loading      333

Table 2 Chemical composition of fly ash.

Composition   SiO2   Al2O3   Fe2O3   CaO   Na2O  K2O  TiO2   SO3   MgO

Mass (%)   65.43  20.67  6.18   1.26   –   –   –   Trace  0.82

The pozzolan used here is the low-calcium fly ash of 2.2 Volume fraction of reinforcement
class F obtained from the Tuticorin thermal power plant.
The chemical composition of the fly ash, as determined by When the same square or rectangular wire mesh is used
X-ray fluorescence analysis is given in Table 2. throughout the depth of an FC element then the volume
Geopolymer is a combination of the following com- fraction of reinforcement can be calculated from Eq. (1)
pounds: pozzolan (fly ash), activator solution (silicates [19]:
of sodium), alkali powder (hydroxides of sodium), a high-
N πdw2  1 1 
range water-reducing lignosulfonated normal super plas- Vr =  +  (1)
ticizer, and distilled water. 4h  Dl Dt 

In this research, analytical grade NaOH in pellet
form (NaOH with 98% purity) and sodium silicate solu- where Vr is the volume fraction of reinforcement, N is
tions (14.7% Na2O, 29.4% SiO2, and 55.9% water by mass) the number of layers of mesh, π = 3.14, dw is the diameter
were used as the alkaline activators. In order to avoid the of mesh wire, h is the thickness of FC element, Dl is the
effect of unknown contaminants in the mixing water, the
NaOH pellets were dissolved in distilled water. The activa-
tor solution was prepared at least 1 day prior to its use.
To improve the workability of fresh mortar, commercially
available naphthalene-based super plasticizer was used.
The constituents of geopolymer mortar are shown in
Figure 1.
Wire woven chicken meshes (Figure 2) with a hexago-
nal opening of size 12 mm and wire thickness of 0.72 mm
(20 gauge) are used. Machine-welded weld mesh (Figure 3)
having a rectangular grid opening of size 76.2 mm × 38.1 mm,
with a thickness of 2.45 mm in the transverse direction and
3.45  mm in the longitudinal direction are used. Ultimate
strength values of weld mesh and chicken mesh are 440
and 270 N/mm2 as per ASTM A 185 [18].

Figure 2 Chicken mesh.

Figure 1 Composition of geopolymer mortar. Figure 3 Weld mesh.


334      M. Rajendran and N. Soundarapandian: Geopolymer ferrocement panels under flexural loading

distance center to center between longitudinal wires, markings were made on the inside of the formwork and on
and Dt is the distance center to center between transverse all its sides to indicate levels of different volume fractions
wires. and different molar concentrations during casting.
For other types of mesh (hexagonal or chicken wire, Ordinary portland cement and river sand passing
expandable metal, fiber-reinforced plastic, or irregular through No. 8 (2.38 mm) sieve and having a fineness
meshes) Eq. (2) [19] is recommended to be used. modulus of 2.72 were used for casting. The geopolymer
mortar used in this study is composed of low-calcium fly
Nwr
Vr = (2) ash and alkaline solution composed of NaOH and sodium
hδr
 silicate combinations. NaOH is mixed with deionized
water at a required concentration and kept for at least
where Vr is the volume fraction of reinforcement, N is the 24  h prior to casting. All geopolymer mortar specimens
number of layers of mesh, wr is the unit weight of reinforc- were made with sand-to-geopolymer ratio in equal pro-
ing mesh, h is the thickness of FC element, and δr is the portion. The hydroxide-to-silicate ratio is kept constant
density of reinforcement material. as 1:1 Table 3. The fly ash and fine aggregate were dry
mixed together in a mixer machine for 5 min, followed
by the addition of activator solution containing hydrox-
2.3 Method of specimen preparation ide and silicate to the mixture, and mixed for another 10
min. The mixing was carried out at a room temperature of
Thirty FC panels (10 series, three in each series), each approximately 25–30°C (Figure 5).
of size 1000 mm × 200 mm × 25  mm and 35-mm thickness Ordinary mesh obtained from the market was cut
(Figure 4), were cast in steel molds with cement mortar (8, to obtain the required number of layers of desired size
10, 12, and 14 m), geopolymer mortar reinforced with four and orientation. The reinforcement was provided with a
layers of chicken mesh and one layer of weld mesh, which combination of chicken mesh and weld mesh. Chicken
were tied firmly together for volume fractions of 1.8% and mesh with 12-mm hexagonal opening and gauge 20
1.3%. were used. Weld mesh of rectangular opening of size
The molds were made in a form such that each of the
four side walls and the base of the formwork were detach-
Table 3 Mortar mix details.
able so that the mold could be easily separated from the
cast element after its initial setting. The contact surfaces of Specimen   Cement   8 m   10 m   12 m   14 m
the steel molds to the mortar were greased before casting
No. of specimens   3   3   3   3   3
the specimens to ease the demolding process. A minimum
Cement (kg)   18.94   –   –   –   –
cover of 5 mm on all sides was maintained when placing Sand (kg)   18.94   18.94   18.94   18.94   18.94
the reinforcement inside the mold, and a cover block was Fly ash (kg)   –   14.15   14.15   14.15   14.15
used to maintain a 5-mm cover at the base. Indelible ink NaOH (kg)   –   2.29   2.29   2.29   2.29
Sodium silicate (kg)   –   2.29   2.29   2.29   2.29
Water (kg)   5.682   –   –   0.14   0.283
Super plasticizer (kg)  0.37   0.14   0.283   0.35   0.42

Figure 4 Rectangular panel mold, 25/35-mm thickness. Figure 5 Mixing of mortar.


M. Rajendran and N. Soundarapandian: Geopolymer ferrocement panels under flexural loading      335

Figure 6 Specimen under table vibration.

76.2  mm × 38.1  mm was placed in such a way that the


longer dimension was placed in the lengthwise direc-
tion of the panels. The reinforcements were tied firmly
Figure 8 Heat-curing chamber under operation mode.
together in specified layers for various volume fractions.
The geopolymer mortar was spread at the base of the
mold, and on this base layer the mesh layers were laid.
mixed dry in a mixer and then the required quantity of
The molds were placed on the vibrating table and the
water and super plasticizer were added gradually while
mortar was spread evenly until the thickness of the panels
the mix was continuously stirred.
was completely filled without voids (Figure 6). In each
Similarly, FC panels were prepared by using cement
casting, three GF panels along with three mortar cubes of
mortar instead of geopolymer mortar in the mold. The
size 70.6 mm × 70.6 mm × 70.6 mm were cast to test the char-
specimens were air-dried for 24  h for initial setting and
acteristic strength of the mortar mix (Figure 7). All these
then immersed in water for curing. The specimens were
geopolymer mortars and GF specimens were heat cured
removed from water after 28 days and were air-dried until
for 48 h at 75°C in a heat curing chamber (Figure 8).
the test was performed.
For all the FC specimens, the water-to-cement ratio
of 0.3 and equal proportion of sand and cement (in order
to compare with the geopolymer specimen) were taken
2.4 Testing of specimens
by weight. The required amount of sand and cement was

Two-point loading was used to conduct flexure tests. The


bed of the testing machine is provided with two steel
rollers on which the specimen is to be supported, and
these rollers are mounted in such a way that the distance
from center to center is 600 mm. The load is applied
through two similar rollers mounted at the third point of
the supporting span that is 200 mm center to center. The
load is divided equally between the two loading rollers,
and all rollers are mounted in such a manner that the load
is applied axially and without subjecting the specimen
to any torsional stress or restraints. For this experiment,
the manual operating system was used and the readings
were taken at an interval of 0.1 kN. The deflections were
measured with the dial gauges having at least a count of
0.01 mm at the midsection of the element. Figure 9 shows
the typical flexural test setup of GF panel. Before testing,
all the elements were painted white so that the cracks
could be easily observed and clearly photographed. The
load was applied in a vertically upward direction by
means of an electric jack. The load application was contin-
Figure 7 Cube mold. ued until the deflection became excessive (not exceeding
336      M. Rajendran and N. Soundarapandian: Geopolymer ferrocement panels under flexural loading

Figure 9 Flexure test setup.

30 mm). The deflections were measured for each interval


Figure 10 Typical failure of the specimen.
of load increment. On each day of testing, 70.6-mm mortar
cubes of the respective mortar mix were also tested on
the Universal testing machine to record the characteristic
compressive strength of the specimen. The crack patterns
3 Results and discussion
were monitored and crack width was measured by using
The results obtained from the experimental investigations
a microscope. The load at first crack, the maximum load,
are tabulated in tables and the comparisons are presented
and corresponding deflections were also recorded. Table 4
in the form of graphs.
shows the test results of all the tested specimens and
Figure 10 shows a typical failure of a test specimen. After
testing, the panels were removed from the test setup and
3.1 C
 ompressive strength of different
both top and bottom sides were examined to investigate
the sustained damage, such as yielding of reinforcement specimens
and cracking pattern at the bottom face.
The testing of 70.6-mm mortar cubes of the respective
mortar mix to record the characteristic compressive
Table 4 Flexural test results of GF panels.
strength of the specimen is shown in Table 5 and Figure 11.
Specimen ID   Vr (%)   Ductility   Stiffness   Energy absorption Figure 11 illustrates the effect of NaOH concentration on
factor μ (N /mm) ( × 106 J)

FC25   1.8   1.5   617.28   9.48 Table 5 Compressive strength.


8 m GF25     1.52   628.75   9.88
10 m GF25     1.53   704.08   12.19
Sample no.   Specimen   Compressive
12 m GF25     1.57   709.09   14.58
strength (MPa)
14 m GF25     1.58   724.19   16.39
FC35   1.3   1.32   683.33   14.89 1   Cement   32.72
8 m GF35     1.36   712.24   15.76 2   8m   35.67
10 m GF35     1.38   718.51   17.48 3   10 m   44.53
12 m GF35     1.40   780.00   19.67 4   12 m   52.01
14 mGF35     1.45   791.26   22.29 5   14 m   60.02
M. Rajendran and N. Soundarapandian: Geopolymer ferrocement panels under flexural loading      337

70 are elastic and the load-deflection curve is linear with


60 the applied load. In this stage, the load is carried by the
Compressive strength (MPa)

geopolymer matrix. Cracking load can be predicted by


50
using the linear elastic theory. Stage II can be designated
40 as multiple cracking of the specimen wherein more cracks
30 occur after cracking of the geopolymer matrix. During
this stage, a transfer of load from mortar to the wire mesh
20
takes place. The wire mesh elongates under additional
10 load, transferring the load back to the mortar matrix,
0 forming new cracks. The final stage is named as failure of
Cement 8-molarity 10-molarity 12-molarity 14-molarity the specimen wherein there is widening of existing cracks
with the increase of load. In this stage, the load is pre-
Figure 11 Compressive strength relationships.
dominantly carried by the mesh. The specimen undergoes
more deflection, and cracks can extend deep through the
the compressive strength of mortar and demonstrates that depth of the geopolymer matrix, reaching the top surface
the compressive strength of geopolymer mortar increases of the specimen.
with the increase in the concentration of NaOH. The com-
pressive strength of geopolymer specimens increases as
NaOH concentration in the aqueous phase increases from 3.2.1 Displacement ductility
8 m to 14 m. The NaOH concentration in the aqueous phase
of the geopolymeric system acts on the dissolution process The ability of a member to deform without a signifi-
as well as on the bonding of solid particles in the final cant loss of its strength is known as ductility. One of the
structure. The use of high concentration of NaOH leads methods of quantifying ductility is by using the ductility
to greater dissolution of the initial solid materials and factor (displacement ductility index) as defined by the
increases geopolymerization reaction, and hence, higher ratio of ultimate deflection to the deflection at yielding of
compressive strength is achieved [20, 21]. The increment tensile reinforcement. The percentage increase in ductil-
of sample strength is believed to be mainly due to the ity factor compared to control specimen for 25-mm thick-
increase in Na ions and water molecules, which are the ness, 8, 10, 12, and 14 m GF specimens is 1.3%, 2%, 4.67%,
basic ingredients for geopolymerization that enhances the 5.33% and 3.03%, 4.5%, 6.06%, 9.8% for 35-mm thick 8,
dissolution and reaction of the geopolymer mortars that 10, 12, and 14 GF specimens, respectively. The ductility of
eventually increases the final compressive strength. The GF specimen increases with increase in thickness of the
percentage increase in compressive strength compared specimens and molarity of NaOH.
to the control specimen for 8, 10, 12, and 14 m geopoly-
mer mortars is 9.015%, 36.09%, 58.95%, and 83.43%,
respectively. 3.2.2 Energy absorption capacity

The percentage increase in energy absorption compared


3.2 Load-deflection characteristics to control specimen for 25-mm thickness 8, 10, 12, and
14 m GF specimens is 4.22%, 28.58%, 53.79%, 72.89% and
Deflection characteristics have been considered as essen- 6.83%, 28.80%, 41.55%, 64.80% for 35-mm thickness 8,
tial criteria in the design of FC structures by practitioners. 10, 12, and 14 m GF specimens, respectively.
Deflection in FC is normally caused by the magnitude of
loading it carries and also due to time-dependent factors
such as shrinkage and creep [22]. One of the main advan- 3.2.3 Stiffness
tages of having meshed reinforcement in FC is that the
deflections due to shrinkage are significantly reduced The percentage increase in stiffness compared to control
by the presence of uniformly distributed mesh. From specimen for 25-mm thickness 8, 10, 12, and 14 m GF
Figure  12A–E, the behavior of GF panels can be charac- specimens is 1.85%, 14.06%, 14.7%, 17.28% and 4.23%,
terized by three distinct stages. Stage I can be designated 5.14%,14.14%, 15.79% for 35-mm thickness 8, 10, 12, and
as precracking of the specimen, wherein all the materials 14 m GF specimens, respectively.
338      M. Rajendran and N. Soundarapandian: Geopolymer ferrocement panels under flexural loading

A 10 10
8.95
8 8.29 8
Load (kN)

Load (kN)
6.54 6.82
6 6 6.15
4.21 5 4.64 5.2
4 4.6 4
2 2.38 2 2.56

0 0
0 5 10 0 5 10
Deflection (mm) Deflection (mm)
FC25 5 layers FC35 5 layers FC25 6 layers FC35 6 layers

B 10 10
8.92 9.01
8 8
Load (kN)

7.2
6
6.8 Load (kN) 6
6.98

4.5 5 4.65 5.6


4 4
4.65
2 2.43 2 2.48
0 0
0 5 10 0 5 10
Deflection (mm) Deflection (mm)
F25 5 layers F35 5 layers F25 6 layers F35 6 layers

C 15 15
9.8 10.3
Load (kN)

10 7.6 7.9
Load (kN)

10
4.98 5.58 7.76
6.9
5 5 6.2
5.62 3.87
3.12
0 0
0 5 10 15 0 5 10 15
Deflection (mm) Deflection (mm)
F25 5 layers F35 5 layers F25 6 layers F35 6 layers

D 15 15 11.7
10.7
8.4 8.4
Load (kN)

Load (kN)

10 10 6.94
5.92 8.97
7.8
5 6.7 6.8
5
3.98 4.05

0 0
0 5 10 15 0 5 10 15
Deflection (mm) Deflection (mm)
F25 5 layers F35 5 layers F25 6 layers F35 6 layers

E 15
11.6 15 13.4
9.8 9.8
Load (kN)

10
Load (kN)

10 7.86 9.97
6.69 8.98
7.9
5 7.4
4.5 5 4.97

0 0
0 5 10 15 0 5 10 15
Deflection (mm) Deflection (mm)
F25 5 layers F35 5 layers F25 6 layers F35 6 layers

Figure 12 Load vs. mid-span deflection curve of (A) FC panels, (B) 8 m GF panels, (C) 10 m GF panels, (D) 12 m GF panels, and (E) 14 m GF
panels.
M. Rajendran and N. Soundarapandian: Geopolymer ferrocement panels under flexural loading      339

3.3 Cracking behavior 3.3.2 Crack spacing

The failure of specimens results from the yielding of wire The highest number of cracks developed at failure was
mesh reinforcement followed by the crushing of mortar. observed for 14 m GF panels followed by 12 m GF, 10 m GF,
Initially, fine flexural cracks appeared at the bottom of 8 m GF, and FC. Due to the large number of cracks devel-
the specimen. With further increase in the load, regu- oped, GF panels of 14 m GF exhibited the lowest magni-
larly spaced vertical cracks were observed, and they tude of average crack spacing followed by a test panel 12
extended from the bottom of the specimen toward the m GF, 10 m GF, 8 m GF, and FC (Table 6). This indicated that
top. The load was increased up to the ultimate stage and the bond strength and the degree of interaction between
cracking pattern is observed. It was observed that the the steel reinforcements and the mortar matrix are the
number of cracks formed in all specimens depended highest for test panel 14 m GF followed by 12 m GF, 10 m
on the volume fraction of reinforcement. Also from the GF, 8 m GF, and FC. The high bond strength of 14 m GF,
observations it is understood that a higher volume frac- 12 m GF, 10 m GF, and 8 m GF as compared to control FC
tion of reinforcement provides a better crack control panels can be attributed to the high compressive strength
mechanism by the formation of a large number of and flexural strength of the mortar mixes. The high bond
well-distributed cracks. Table  6 presents the details of strength of steel reinforcements in mortar matrices 14,
measured average crack width, number of cracks, and 12, 10, and 8 m enabled the transfer of the tensile stress
average crack spacing.

A
3.3.1 Crack width

The variation of average crack width with various molar


concentrations and thickness of the specimens is shown
in Table 6. Average crack width is primarily a function
of tensile strain in the extreme layer of mesh and it is
found to decrease with an increase in the molar concen-
tration of NaOH and thickness of the specimens. Lowest
maximum crack width is observed in the case of 14 m GF
panels. The above phenomenon is due to the role of the
mesh in holding the matrix together and offering resist-
ance for widening of the crack in the matrix. In the GF
panels, spacing of tensile cracks was observed to be closer
and crack width smaller, which indicates that the crack- B
arresting mechanism is better and distributed through the
entire thickness than the FC panels.

Table 6 Cracking behavior.

Specimen ID  Vr (%)   Average crack   Average crack   Number


width (mm) spacing (mm) of cracks

FC25   1.8   0.33   41.45   3


8 m GF25     0.31   39.89   3
10 m GF25     0.30   28.32   4
12 m GF25     0.28   25.6   4
14 m GF25     0.25   22.87   6
FC35   1.3   0.28   22.0   5
8 m GF35     0.25   20.8   4
10 m GF35     0.23   19.2   6
12 m GF35     0.2   18.17   8 Figure 13 Cracking behavior of (A) 35-mm-thick 12 m GF panels and
14 m GF35     0.18   16.93   9 (B) 35-mm-thick FC panels with five layers of wire mesh.
340      M. Rajendran and N. Soundarapandian: Geopolymer ferrocement panels under flexural loading

induced at the mid-span to a larger extent of the adjacent less in the geopolymer specimens and large number
mortar matrices. Therefore, a higher number of cracks of cracks compared with the control specimens.
with smaller widths and crack spacing were formed on 3. Compared with the control specimen, the compressive
the test panels [23]. strength of the geopolymer specimens also increases
with increase in the molarity of the NaOH solution.
4. The percentage increase in compressive strength
3.3.3 Crack pattern of GF panels and failure mode compared to control cement mortar specimen for
8, 10, 12, and 14 m geopolymer mortars is 9.015%,
Failures of tested GF panels were observed to occur when 36.09%, 58.95%, and 83.43%, respectively.
the extreme layer of steel mesh failed under tensile stress. 5. Increase in the thickness and molarity concentration
No spalling of the mortar matrix was observed for any in the GF panels increased the load-carrying capacity,
tested GF panels. A major continuous crack joining the ductility, energy absorption, and stiffness of the
bottom and top fibers was observed to be present on all element and decreased the crack width and crack
tested panels. From Figure 13A, large numbers of closely spacing.
spaced cracks were observed to be developed on test 6. All the tested panels failed in pure bending.
panels 12 m GF. Meanwhile, the relatively smaller number 7. The percentage increase in stiffness compared to
of cracks with larger intercrack spacings were detected on control specimen for 25-mm thickness 8, 10, 12, and
FC panels (Figure 13B). Only flexural cracks were observed 14  m GF specimens are 1.85%,14.06%,14.7%,17.28%
on all tested GF and FC panels at ultimate failure. Hence, it and 4.23%, 5.14%, 14.14%, 15.79% for 35-mm thickness
can be concluded that all the tested panels failed in pure 8, 10, 12, and 14 m GF specimens, respectively.
bending. 8. The percentage increase in ductility factor compared
to control specimen for 25-mm thickness 8, 10, 12, and
14 m GF specimens is 1.3%, 2%, 4.67%, 5.33% and
3.03%, 4.5%, 6.06%, 9.8% for 35-mm thickness 8, 10,
4 Conclusions 12, and 14 m GF specimens, respectively.
9. The percentage increase in energy absorption
This work represents the results of a research study on compared to control specimen for 25-mm thickness
the effect of using geopolymer as a substitute for ordinary 8, 10, 12, and 14 m GF specimens is 4.22%, 28.58%,
portland cement in FC panels. Geopolymer specimens 53.79%, 72.89% and 6.83%, 28.80%, 41.55%, 64.80%
are tested for compressive strength, load deflection, for 35-mm thickness 8, 10, 12, and 14 m GF specimens,
cracking behavior for different molar concentrations, respectively.
and different thicknesses, and the following conclusions
are arrived at. Acknowledgments: The authors express their gratitude
1. The initial cracking load and ultimate load of the to the management of Thiagarajar College of Engineering
specimens in flexural testing increase with increasing and to the department for facilitating this work.
molarity.
2. The cracking behavior of the various specimen shows Received January 9, 2013; accepted October 26, 2013; previously
that the cracking region and the cracking space are published online December 9, 2013

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