Raclie

ha s iad
rEalueTur lari2s
TalkarLs ainy hgdn.
hydro chlen
klones
aldthurts 07
tdue
tduce This n Aeul ant,
a cd
acd an Zune amalam
Kulons ducion yomud m
eteetue anl- alkyl
Ihe r a c ' n
mone
heliiv
Friedul- C a acylaler
alyhale i w m.
cyclie Ktones ¥
r z
d rduuctiorn

znCH,
&, H

Aldel tondensaiun the prroence a diluth alkali

aldeheles and khores prooduce B-hucroryl aldehyoe(obl)
amd - hutreny kitome rtapuctuwrly The adol k Ketl
td tanbon
he
Ted rtadi lALL watr T we a,-unualuratid caskrl
compeundi, Such rtactions ore called adel aldsl tondurtsstiee

or examble, un h preaence ef dil. Na0H, ethanal rrduca

3-hydronybuenal (aldsd), " whueh radly lwsus walr
tPrduce bud -2-end
H
CH-C tH -c -c=o
CH- C-c -c =o
HH H H

2naalecudes acetaleluhupl
)Kesenmund Keduclo ohoyl hlerede hydvnyen aled fo
get reluerd to aldthyde amd halladum banue
ulphat wsd acatalst a rduclien
Ttac'nuhich mwplets acld1lien y hydngen

H, Pd Bau
tHC
R R H

ded chlemide 4Ldehyde

Hll Valhard-Zdraky Per Meal te rplace

the Carhanyde OH lh a bromd resulung
carbonyhi acid bpmud he acyk bromdecan
then tautnmunie e an antd ha md a tht
thi
moo p tactwrl B at the palen tmmn
a dbnm acd kromide:
BrP
R
oH

Cashouicacd BaDmo tabonyluc auid.

cCannuxar Reacluon dldhyds hawy no K hyelpg.t aloms

treatmerit
uMdergo cel onudalion Areduclon rach m

wh a Cemcentratd dkal Jn such nal'n, ne

MolLcule aldehyde ge c2dsed to form an aud

eth inole.cule of aldehyde quld rrducs ferm dch
th
Ex
HCHO t HCHo a0 Cna OH tHCOONa

Mthan Sod.frmak
Mulhanal
 Cros- Aldal Condensahion Reac'n wve dt kunds e aldehud.
aldahyd
Rutone molcules m breuna a shong bae he
the
hyoony
U aldehyde er- hyoloayeone an
uct
CHg CHD CH CH, HD C H - H =CCCH) HO + CH-H2~CHz
CHCAD
Sruclurts
H e 2- en-Aunec acid (b) 3 hudmouy butan ad

H - - c Fc -c = c -ë-oH C -C -C
HC
1
H OH

c) - Nito prepibphente ad) 3-BromD 1 phunylpentaneic add

HBH
oN i-cH,cH, C-CooH
H

d 3-Methuluehenan arbaldehyde
CHO

-
 n a mechanun

Sp Attack enuelaaphls an aeny arben

Sp T lakturt s pztn bytmudiak..

bSp Nu_cutack en Carhoul qmys.

kp T Prohnalén alkonid ougun
4. Dusumauwsh he alleung

APhunl 2 kanxove arid

h e diatinguishd by thut rtalion wth,
bucasbernat Lolution Runien aud wil zne &duun
wwth
NaHco NaHCO3
.

buk phenol wll nat rad. Jyrvbun

BFovmu Aud & Beiiu Aud
Pormu ud poducs J l r natrate oolulion. Healue auild
Fomwe acid also orms a whule preupttae wl
d
Hgh sol. t cue aud dos not repond non-thu
thu ttt

Benzaldhuyd md acitathinor
Mdhyl kutont are nidud
by sodum hyoibdte t g
ysllou Ppt wdotorm. deotpherone beung myl kur a

Tapond tust,ut benzeshunne does net rtupond

Benzalhyde and hanad
Et Ethonal rtacb wwth
Na OH |J, to tenm yelbv PpA
vwdedrrm whle benualdehyde du not u
whule hw tut,

5 Arm m wortey ordur

Di-ert buk Kebre Mthl tt -buta kitr Arulbnt Acutesud

HwoH< H,"cooH H(B1)0, ceoH HCBr)C

mathanybenysiud bunzout ud-nthuru <3,4-dunitnbena

au