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MATERIAL 0

SAFETY DATA 3 1

SHEET NA

AES-A-350-RB
SECTION I : = = = = = = = = = = = = = = IDENTIFICATION = = = = = = = = = = = = = = = = = = = = = = = = = =

Name and Address: Tel: (813) 246 - 5448


Emergency Phone : CHEMTREC (800) 424-9300
AES ARABIA LTD.
P.O.Box-105689
SAUDI ARABIA.
Phone-966 11 4772398
Fax-966 11 4785456

Chemical Name : AES-A-350-RB


Synonyms: Proprietary Product Chemical Family :Proprietary
I.D.No: N/A
D.O.T: Hazard Class: 8
D.O.T: Shipping Name: Corrosive material

SECTION II : = = = = = = = = = = = = = =HAZARDOUS IDENTIFICATION = = = = = = = = = = = = = = = = = = = = = = = = = =

WHMIS Classification / Symbol: E: Corrosive


Warning! Causes eye, skin, and respiratory tract irritation and possible burns. Corrosive to metal in aqueous solution.
Primary Routes of Inhalation Skin Eyes
Entry:
Eye Contact: Dust is irritating to eyes resulting in stinging, reddening, tearing and swelling.
Skin Contact: Product is irritating to the skin resulting in reddening, stinging, and swelling.
Ingestion: No information
Inhalation: Dust may be irritating to nose, lungs and respiratory system

SECTION III : = = = = = = = = = = = = = INGREDIENTS == = = = = = = = = = = = = = = = = = = = = = = = == = = = = = =

Chemcial name Cas No %

Amidosulphuric acid & its salts , 5329-14-6 >5


Polymer Trade Secret <3
Water Balance

Information given above may be amended without notice.


Issue#: 1/1 Issue Date 5/23/2017
MATERIAL 0

SAFETY DATA 3 1

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AES-A-350-RB

SECTION IV: = = = = = = = = = = = = = PHYSICAL PROPERTIES = = = = = = = = = = = = = = = = = = = = = == = = = = = =

Boiling Point Above 100 deg C Specific Gravity (H2O = 1) 1.02 -1.09

Vapor Pressure (mm Hg.) NA Melting Point > 200 deg C

Vapor Density (AIR = 1) NA Evaporation Rate NA


(Butyl Acetate = 1)
Solubility in Water: Completely Soluble pH < 3.0

Appearance and Odor: Clear Colourless To Pale Yellow Liquid with slight odor.
(NA = Not Applicable)

SECTION V: = = = = = = = = = = = = = FIRST AID MEASURES = = = = = = = = = = = = = = = = = = = = = == = = = = = =

Description of first aid measures

Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If
symptoms persist, call a physician.

Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes.
Inhalation Move to fresh air.

Ingestion Clean mouth with water and afterwards drink plenty of water.

Protection of First-aiders Use personal protective equipment. Avoid contact with skin, eyes and clothing.

General Advice If symptoms persist, call a physician. Show this safety data sheet to the doctor in attendance. Use personal protective equipment.

Most important symptoms and affects, both acute and delayed

Eyes Irritating to eyes. Contact with eyes may cause mechanical irritation.

Skin According to GHS hazard classification criteria, the product is not considered as being a skin irritant. Product dust may cause mild, mechanical
irritation. Health injuries are not known or expected under normal use.

Inhalation May cause irritation of respiratory tract. Based on the low pH, would be expected to cause irritation to the
respiratory tract, resulting in a higher cough response as the inhalation exposure concentration was increased.

Ingestion Oral exposure is not anticipated under normal working conditions. Health injuries are not known or expected under
normal use.
Main Symptoms Itching. Redness. Burning sensation
Information given above may be amended without notice.
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AES-A-350-RB

Notes to Physician Treat symptomatically.

SECTION VI: = = = = = = = = = = FIRE FIGHTENING MEASURES= = = = = = = = = = = = = = = = = = = == = = = = = =

Flammable Properties
Fine dust dispersed in air may ignite. Risk of ignition followed by flame propagation or secondary explosions should be prevented
by avoiding accumulation of dust, e.g. on floors and ledges.
Extinguishing media
Suitable Extinguishing Media Dry chemical. Carbon dioxide (CO2). Water spray. Foam. Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Unsuitable Extinguishing Media No information available.
Hazardous Combustion Products Thermal decomposition can lead to release of irritating gases and vapors, Carbon monoxide (CO), Carbon dioxide
(CO2).
Specific Hazards Arising from the Chemical None known.
Sensitivity to mechanical impact No.
Sensitivity to static discharge Yes. (as dust).
Fine dust dispersed in air may ignite. Dust explosibility class = 1. Weak to moderately explosible.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus
pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION VII: = = = = = = = = = = ACCIDENTAL RELEASE MEASURES= = = = = = = = = = = = = = = = = = = == = = = = = =

Personal Precautions, Protective Equipment, and Emergency Procedures


Avoid contact with the skin and the eyes. Use personal protective equipment. For personal protection see section 8. Avoid dust
formation.
Environmental Precautions
Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
Methods and Materials for Containment and Cleaning Up
Pick up and transfer to properly labelled containers. Avoid dust formation. Keep in suitable, closed containers for disposal.
Aqueous spillage should be neutralized and treated prior to discharge.

SECTION VIII: = = = = = = = = = = HANDLING AND STORAGE= = = = = = = = = = = = = = = = = = = == = = = = = =

Handling
Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice.
Do not breathe vapours/dust. Use only in area provided with appropriate exhaust ventilation. Avoid dust formation in confined areas. Fine dust dispersed
in air may ignite. Ensure adequate ventilation. Refer to NFPA 61, "Standard for the Prevention of Fires and Dust Explosions in Agricultural and Food
Processing Facilities".
Storage
Keep containers tightly closed in a cool, well-ventilated place. Keep in properly labeled containers. Keep away from metals. Corrosive to metals (as
aqueous solution). Keep away from oxidizing agents. Keep away from strong bases. Keep away from amines.

Information given above may be amended without notice.


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AES-A-350-RB

SECTION IX: = = = = = = = = = = EXPOSURE CONTRLS / PERSONEL PROTECTION = = = = = = = = = = = = = = = = = = = ==

As an airborne dust, exposure limits pertaining to "particulates not otherwise regulated" have been provided below. Specific
exposure limits have not been identified for this product. However, as an irritant, it is advisable to limit worker exposure to the
greatest extent possible.
ACGIH TLV : TWA: 10 mg/m3 inhalable particles, recommended TWA: 3 mg/m3 respirable particles, recommended)
OSHA PEL : TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction

Appropriate Engineering Controls General Hygiene Considerations : Local exhaust ventilation. Ensure adequate ventilation, especially in
confined areas.When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing.
Personal Protective Equipment : Safety glasses with side-shields. If airborne dust concentrations are excessive, wear goggles
Impervious gloves. Long sleeved clothing. Boots.
Respirator with a dust filter. In case of insufficient ventilation wear suitable respiratory equipment.

SECTION X: = = = = = = = = = = STABILITY AND REACTIVITY = = = = = = = = = = = = = = = = = = = == = = =

Reactivity: Reactions with metal nitrates may be potentially explosive. Aqueous form is corrosive to copper, zinc, aluminum and their alloys.
Stability: Not applicable. Stable under normal conditions.
Possibility of Hazardous Reactions : None under normal processing.
Conditions to Avoid : Avoid dust formation. Heat, flames and sparks.
Incompatible Materials : Amines. Heavy metals. Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products: Thermal decomposition can lead to release of irritating gases and vapors. Carbon monoxide (CO). Carbon dioxide
(CO2).

SECTION XI: = = = = = = = = = = TOXICOLOGICAL INFORMATION = = = = = = = = = = = = = = = = = = = == = =

LD50 oral 5400 mg/kg Mouse 11700 mg/kg Rat


LD50 dermal >2000 mg/kg bw Rat
Skin corrosion/irritation Based on available data, not, or only slightly irritating.
Serious eye damage/eye irritation Irritant, causes serious eye irritation.
Respiratory or skin sensitisation Based on available data, not expected to be a skin or respiratory sensitiser.
Germ cell mutagenicity Based on available data, negative to test/non-mutagenic.
Carcinogenicity Based on available data, no evidence of carcinogenicity.
Reproductive toxicity Based on available data, no evidence of reproductive toxicity
STOT - single exposure No evidence of toxicity.
STOT - repeated exposure Based on available data, no toxicity identified at highest exposure levels [NOAEL(rats)
4000mg/kg bw/d].
Aspiration hazard Based on available data, no known aspiration hazard.

Information given above may be amended without notice.


Issue#: 1/1 Issue Date 5/23/2017
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AES-A-350-RB
Eyes Irritating to eyes. Contact with eyes may cause mechanical irritation.
Skin According to GHS hazard classification criteria, the product is not considered as being a
skin irritant. Product dust may cause mild, mechanical irritation. Health injuries are not
known or expected under normal use.
Inhalation May cause irritation of respiratory tract. Based on the low pH, would be expected
to cause irritation to the respiratory tract, resulting in a higher cough response as the
inhalation exposure concentration was increased.
Ingestion Oral exposure is not anticipated under normal working conditions. Health injuries are not
known or expected under normal use.

Main Symptoms Itching. Redness. Burning sensation.

SECTION XII: = = = = = = = = = = ECOLOGICAL INFORMATION = = = = = = = = = = = = = = = = = = = == = = =


Ecotoxicity

Not classified for aquatic toxicity. Contains no substances known to be hazardous to the environment. Contains no substances
known to be not degradable in waste water treatment plants.
Fresh Water Algae NOEC(8d): 425mg/l (nominal)*
Acute Fish Toxicity LC50(48h):440mg/L (Leuciscus idus)(nominal)
Daphnia (Water flea) EC50(24h): 1535mg/L (Daphnia magna)(nominal)

Persistence/Degradability Readily biodegradable. Inherently biodegradable. 97% and 100% biodegradability in 28d and 19d, respectively (protocols
OECD 301E and OECD 301A, respectively).
Mobility Soluble in water
PBT and vPvB assessment This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).

SECTION XIII: = = = = = = = = = = DISPOSALCONSIDERATION = = = = = = = = = = = = = = = = = = = == = = =

Dispose of in compliance with the laws and regulations pertaining to this product in your jurisdiction. Rinse water resulting from cleanup should be
collected for treatment before disposal. Solutions with low pH-value should be neutralized before discharge. Empty containers should be decontaminated
and taken for local recycling, recovery or waste disposal

SECTION XIV: = = = = = = = = = = TRANSPORT INFORMATION = = = = = = = = = = = = = = = = = = = == = = =

Land Transport (ADR/RID/GGVSE)


Sea Transport (IMDG-Code/GGVSee) :
Air Transport (ICAO-IATA/DGR)

Class: 8 Corrosive material


Group: III
PIN Number: UN 2967
Information given above may be amended without notice.
Issue#: 1/1 Issue Date 5/23/2017
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AES-A-350-RB

SECTION XV: = = = = = = = = = = REGULATORY INFORMATION = = = = = = = = = = = = = = = = = = = == = = =

TSCA
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
acute.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not
contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
Information given above may be amended without notice.
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AES-A-350-RB
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.

SECTION XVI: = = = = = = = = = = OTHER INFORMATION = = = = = = = = = = = = = = = = = = = == = = =

The data contained in this Material Safety Data Sheet has been prepared based upon an evaluation of the ingredients contained in the
product, their concentration in the product and potential interactions. The information is offered in good faith and is believed to be
accurate. It is furnished to the customer who is urged to study it carefully to become aware of hazards, if any, in the storage, handling, use
and disposal of the product: and to insure his employees are properly informed and advised of all safety precautions required. The
information is furnished for compliance with the "Occupational Safety and Health Act" of 1970, the "Hazards Communication Act" of
1983 as well as various other Federal, State and Local regulations. Use or dissemination of all or part of this information for any other
purpose is illegal.

Information given above may be amended without notice.


Issue#: 1/1 Issue Date 5/23/2017

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