19. «© Given the following data at a certain temperature, 2N2(g) + Ox(g) —=2N,0() KK = 1.2 10° N30, —=2N0.(9) K=46x 107 3N.(g) + 0.) ==NO,Q) K=4.1X 10 calculate K for the reaction between one mole of dinitrogen oxide gas and ‘oxygen gas to give dinitrogen tetroxide gas. 20. Given the following data at 25°C, 2NO(g) = Nig) + Ong) K=1x10-? 2NO() + Bri(g)—=2NOBr(g) K= 8X 10! calculate K for the formation of one mole of NOBr from its elements in the gaseous state at 25°C. 13. mA buffer solution is prepared by adding 15.00 g of sodium acetate (NaC,H,0,) and 12.50 g of acetic acid to enough water to make 500 mL (three significant figures) of solution. (@) What is the pH of the buffer? (b) ‘Ihe buffer is diluted by adding enough water to make 1.50 L of so- lution, What is the pH of the diluted buffer? 14. A bulfer solution is prepared by adding 5.50 g of ammonium chloride and 0.0188 mol of ammonia to enough water to make 155 mL of solution. (@) What is the pH of the buffer? (b) If enough water is added to double the volume, what is the pH of the solution? 15. = A solution with a pH of 8.73 is prepared by adding water to 0.614 mol of NaX to make 2.50 L of solution. What is the pH of the solution after 0.219 mol of HX is added? 16. An aqueous solution of 0.043 M weak acid, HX, has a pH of 3.92. What is the pH of the solution if 0.021 mol of KX is dissolved in one liter of the weak acid? 17. Which of the following would form a buffer if added to 250.0 mL of 0.150 M SnF,? (@) 0.100 mol of HCL (b) 0.060 mol of HCI (© 0.040 mol of HCl (A) 0,040 mol of NAOH (©) 0.040 mol of HF 18. Which of the following would form a buffer if added to 650.0 mL of 0.40 MSr(OH),2 (a) 1.00 mol of HF (b) 0.75 mol of HF (© 030molofHF (A) 0.30 mol of NaF (©) 0.30 mol of HCI