Chemistry practical class x

1.Aim
To study the properties of acids (dil. HCl) and bases (dil. NaOH) by their reaction with

 Litmus solution (blue/red)

 Zinc metal
 Solid sodium carbonate

Materials Required
Test tubes, test tube stand, test tube holder, cork, droppers, boiling tube, match-box, burner, flat
bottom flask, thistle funnel, beaker, litmus solution/paper (red and blue), glass rod, zinc granules,
freshly prepared lime water, solid sodium carbonate and dil. HCl.

TheoryTheory
Acid
An acid is a substance which furnishes H+ ions when it is dissolved in water like HCl. Acids turn blue
litmus red and do not affect red litmus.
On reacting with zinc metal, HCl forms a salt, zinc chloride (ZnCl 2) and hydrogen gas (H2) is liberated.

Hydrogen gas burns in air with a blue flame and produces a pop sound.

HCl reacts with sodium carbonate (aqueous/solid) to liberate carbon dioxide (CO 2 ) which turns lime
water milky due to the formation of calcium carbonate. When excess of CO 2 is passed through the
solution, the milkiness disappears.

Procedure

1. Litmus Test

 Take two test tubes and mark them A and B and put them in a test tube stand. In test tube
A take 5 ml of blue litmus solution and in B, take 5mL of red litmus solution (as shown in
 Fig.1).

 Using a dropper, add few drops of HCl in each test tube. Stir each tube with separate
glass rods B. Note, if there is any colour change occurs in the solutions.
Observation In test tube A, blue litmus turns red and nothing happens to red litmus.
Hence, it can be concluded that acids (like HCl) turns blue litmus to red.

Reaction with Zinc (Zn) Metal

Take few zinc granules in a clean and dry test tube.

Add HCl to the test tube containing zinc granules, such that zinc granules are totally submerged
in the acid.
Place a cork having glass delivery tube.
A vigorous reaction will take place after 2-3 minutes, with the evolution of a colourless, odourless
gas.
On bringing a burning match-stick near the mouth of gas tube, the gas burns with a pale blue
flame producing pop sound (as shown in Fig. 2).

1.

 Reaction 2HCl(aq) + Zn(s) ——> ZnCl2 (aq) + H2↑

Observation Acids (like HCl) liberate hydrogen (H2) gas on reacting with active metals like
zinc (Zn) which burn with a pop sound when burning splinter brought near to it.
 Reaction with Solid Sodium Carbonate (Na2CO3)
 Take a small amount of solid sodium carbonate in a flat bottom flask and some distilled
water in it, shake it well.
 Take a double bore cork with a thistle funnel and a delivery tube fitted in it, fit it on the
open end of the flask.
 Now add HCl in the flask through thistle tube.
 Reaction taken place with the evolution of colourless and odourless gas. Then gas is
passed through freshly prepared lime water with the help of delivery tube (as shown in Fig.
3).
 The lime water turns milky.

1.

 Reaction
Na2CO3(aq)+2HCl(aq) ——–> 2NaCl(aq)+ CO2 ↑ + H2O(l)
Ca(OH)2 (aq) + CO2 ↑ ——–> CaCO3(s) + H2O (l)
CaCO3 (s) + H2O(l) + CO2 (g) ——–> Ca(HCO3)2 (aq)
Observation HCl on reacting with sodium carbonate (Na2CO3) liberates carbon dioxide
(CO2) gas which turns lime water milky. On passing the gas in excess of lime water, the
milkiness disappears.

Observation Table

S.No. Experiment Observation Inference

1. Litmus test Blue litmus solution turns HCl has……. character.

………….. in colour. HCl…….. affect red litmus solution.

Add few drops of dil. HCl to test

tube A containing blue litmus

solution. Add few drops of dil. HCl

 to test tube B containing red

litmus solution.

Reaction with Zn metal

 On adding dil. HCl  Zn reacts with dil.

to Zn metal and  ……. gas evolves. HCl and liberates

warming the  A pop sound is …….. gas.

contents. obtained.  Zn (s) + 2HCl(aq)

 On bringing a —->ZnCl2 + …

burning match-

stick near the jet.

A colourless, odourless
……. gas is liberated on
Reaction with Na2CO3 gas is evolved which turns
the reaction between dll.
Add a few drops of dil. lime water milky. On
3. HCl and Na2CO3.
HCI to Na2CO3. passing the gas in excess
2HCI + Na2CO3 ——–>
in lime water, the milkiness
2NaCl +……… + H2O
disappears.

 Result/Conclusion

1. Hydrochloric acid turns blue litmus solution/paper to red but it does not affect red litmus
solution/paper.

1. It reacts with zinc metal to liberate hydrogen gas and also forms zinc chloride as a product.
2. It reacts with sodium carbonate to liberate carbon dioxide.
Hence, we conclude that hydrochloric acid is acidic in nature.

Precautions

1. As HCl is corrosive in nature, it should be handled with care.

2. Use small quantities of chemicals.
3. Use small quantities of Zn and HCl, otherwise large amounts of H 2 will be formed which may
cause explosion.
4. Use clean zinc metal, otherwise the reaction will occur very slowly.
5. Add HCI to Na2CO3, when the apparatus is airtight.
6. Observe the milkiness in the lime water soon.

2.Aim
To perform and observe the action of water on quicklime, action of heat on ferrous sulphate crystals,
reaction of iron nails kept in copper sulphate solution, reaction between sodium sulphate and barium
chloride solutions and classify the reaction.

Materials Required
Calcium oxide (quicklime), distilled water, borosil beaker, test tube, glass rod, dropper, red and blue
litmus paper strips.

Theory
When calcium oxide (quicklime) is dissolved in water, it forms calcium hydroxide (slaked lime). The
reaction is highly exothermic, i.e. a lot of heat is produced during the reaction.
This reaction may be represented in the form of a chemical reaction as follows:

Note Calcium hydroxide is basic in nature.

Therefore, it turns moist red litmus paper blue. If we pass CO 2 through clear calcium hydroxide
solution (lime water), it turns milky due to the formation of a white precipitate (insoluble calcium
carbonate).

In reaction (i), two compounds-quicklime and water combine to give a single product slaked lime. So,
this is an example of combination reaction. Hence, it may be stated that when two or more
substances react together to form a single product, is called a combination reaction.
Also, it has been observed that a large amount of heat is evolved alongwith the formation of products.
Such type of reactions which are accompanied by the evolution of heat, are called exothermic
reactions.

Procedure

1. Take a small amount of quicklime in a borosil beaker or hard glass beaker. Slowly add water to
it as shown in Fig. 1 (a).
2. Stir it well with a clean glass rod as shown in Fig. 1(b).

3. Observe what happens. Touch the beaker carefully.

4. Classify the reaction.
 5. Using a clean dropper, take a few drops of the solution formed in the beaker and place them on
red and blue litmus paper strip (as shown in Fig. 2). Make your observation.

Observation
The hissing sound is produced and solution becomes hot. The heat is evolved during the reaction
which raises the temperature of the reaction mixture. On putting a few drops of the solution on red
and blue litmus paper, it is observed that only red litmus paper turns blue, no changes occur in blue
litmus paper.

Inference
In this reaction, quicklime (CaO) and water (H2O) combine to give a single product slaked lime
[Ca(OH)2 ].
CaO(s) + H2O (l) ——–> Ca(OH)2 (aq) + Heat
It is a combination reaction and calcium hydroxide [Ca(OH) 2 ] is basic in nature.
As heat is evolved, the reaction is exothermic.

Result
The reaction between quicklime and water to form slaked lime is a combination reaction as well as
exothermic reaction.

Precautions

1. Always take small amount of quicklime.

2. The reaction is highly exothermic, so do not touch the reaction mixture directly.
3. Water is added slowly to a beaker containing quicklime.

3.Aim
To observe the action of Zn, Fe, Cu and Al metals on the following salt solutions:
ZnSO4 (aq), FeSO4 (aq), CuSO4 (aq), Al2(SO4)3 (aq)
To arrange Zn, Fe, Cu and Al metals in the decreasing order of reactivity based on the above results.

4. Materials Required
Aluminium foil, copper turnings, zinc granules, iron filings, ferrous sulphate solution, copper
sulphate solution, zinc sulphate solution, aluminium sulphate solution, test tubes, test tube
stand and four beakers of 50 ml

Theory
Different metals have different reactivities towards chemical reagents. Some metals are more
reactive than others. The metals, which can lose electron more readily to form positive ions
are more reactive.
According to the reactivity series (or activity series) of metals, a more reactive metal displaces
a less reactive metal from its aqueous salt solution. These reactions are called displacement
 reactions.
Displacement reactions can be used to find out the relative reactivities of metals

4.Aim
To observe the action of Zn, Fe, Cu and Al metals on the following salt solutions:
ZnSO4 (aq), FeSO4 (aq), CuSO4 (aq), Al2(SO4)3 (aq)
To arrange Zn, Fe, Cu and Al metals in the decreasing order of reactivity based on the above results.

Materials Required
Aluminium foil, copper turnings, zinc granules, iron filings, ferrous sulphate solution, copper sulphate
solution, zinc sulphate solution, aluminium sulphate solution, test tubes, test tube stand and four
beakers of 50 ml.

Theory
Different metals have different reactivities towards chemical reagents. Some metals are more reactive
than others. The metals, which can lose electron more readily to form positive ions are more reactive.
According to the reactivity series (or activity series) of metals, a more reactive metal displaces a less
reactive metal from its aqueous salt solution. These reactions are called displacement reactions.
Displacement reactions can be used to find out the relative reactivities of metals.
Example If a piece of zinc metal is dipped in a solution of copper sulphate, zinc will displace copper
from copper sulphate. The blue colour of copper sulphate solution will gradually fade and finally
colourless solution of zinc sulphate will be obtained.

It means that zinc has displaced copper from copper sulphate solution, i.e. zinc is more reactive than
copper.

 Al can displace Zn, Fe, Cu from their salt solutions, therefore it is more reactive than Zn, Fe and
Cu.

 2Al(s) + 3ZnSO4(aq) ——> Al2(SO4)3 +3Zn (s)

 2Al(s)+ 3FeSO4(aq) ——-> Al2(SO4)3 + 3Fe(s)
 2Al(s)+ 3CuSO4(aq) ——–> Al2(SO4)3 +3Cu(s)
Zn can displace Fe and Cu from their salt solutions, therefore zinc is more reactive than Fe and Cu.
 Zn(s) + CuSO4 (aq) ——> ZnSO4(aq)+Cu(s)
 Zn(s) + FeSO4(aq) ——–> ZnSO4(aq) + Fe(s)
 Zn(s) + Al2 (SO4)3(aq) ——-> No reaction
 Zn(s) + ZnSO4(aq) ———-> No reaction
Fe can displace copper from copper sulphate solution, therefore it is more reactive than copper.
 Fe(s) + CuSO4(aq) ——–> FeSO4(aq) + Cu(s)
 Fe(s) + ZnSO4 (aq) ——–> No reaction
 Fe(s) + FeSO4(aq) ——–> No reaction
 Fe(s) + Al2(SO4)3(aq) ——–> No reaction
Cu cannot displace any of the given metals from their salt solutions, therefore it is least reactive than
the other given metals.
No reaction takes place when any of the metals copper, iron, zinc and aluminium are placed in
aqueous aluminium sulphate solution. From this, it can be concluded that aluminium is the most
reactive and copper is the least reactive among the given four metals (Fe,Zn,Cuand Al). Thus,
the decreasing order of reactivity of metals is
Al > Zn > Fe > Cu

Metals and their aqueous salt solutions exhibit colours as follows:

 S. No. Name and formula Colour

1. Zinc sulphate (ZnS0 ) 4 Colourless

2. Ferrous sulphate (FeS0 ) 4 Light green

3. Copper sulphate (CuS0 ) 4 Blue

4. Aluminium sulphate AI (S0 )

2 4 3 Colourless

5. Aluminium (Al) White

6. Iron (Fe) Blackish grey

7. Copper (Cu) Reddish brown

8. Zinc (Zn) Silvery white (greyish)

Procedure

1. Prepare 50 ml solutions of 5% concentration (by volume) of zinc sulphate, iron(II) sulphate,

copper(II) sulphate and aluminium sulphate in distilled water in four different beakers. Label
 these beakers as P, Q, R and S (as shown in Fig.1).

2. Take about 10 mL of saturated solution of zinc sulphate (ZnSO 4), ferrous sulphate (FeSO4),
copper sulphate (CuSO4) and aluminium sulphate [Al2(SO4)3] in the respective test tubes (as
shown in Fig. 2). Observe the colour of the solutions.

3. Take zinc, copper, iron and aluminium metal strips and clean their surfaces.
4. Put zinc metal strip in all the four test tubes A, B, C and D and observe the change that
follows.
5. Repeat the above experiment with other metal strips by dipping them in fresh salt solutions of
metal and observe for displacement reactions.
Observation Table

Result

1. The action of metals on respective salt solutions are given below:

 Al metal is able to displace Zn, Fe and Cu from their salt solutions, therefore Al is most
reactive.
 Zn metal is able to displace Fe and Cu from their salt solutions therefore, Zn is more
reactive than Fe and Cu.
 Fe metal is able to displace Cu from its salt solution, therefore Fe is more reactive than
copper.
 Cu is unable to displace any metal (among Al, Fe and Zn) from their salt solutions,
therefore Cu is least reactive.
The decreasing order of reactivity, based on the above results, follows the order:
Al > Zn > Fe > Cu

Precautions

1. All the apparatus should be clean and dry.

2. Handle the chemicals carefully.
3. Some reactions may occur slowly, so observe the changes carefully.
4. Do not touch or taste the chemicals.
5. clean the metals by rubbing them with a piece of sand paper before dipping them in the salt
solutions.
6. Wash the test tubes after every set of observations of interaction of a particular metal with the
four salt solutions.
7. For the preparation of solutions use only distilled water and add small quantity of sulphuric
acid.
8. Clean your hands properly after the experiment because the salt solutions are poisonous.