:Eiy-§-¥

"
"
Q2 ) done .

a 3) done
.
HOycH=0
an) done .
¥

as ) done
no ¥
c.
66)

§-}o
"
a
° *
-

}
as ) *
( bond
here is
no
9-1
✗
Aiff cleavage
chime
between

chili P
1. G.
OH
" then retenhi
.y•"k°
it

¥
. .

choli
•
+

cD1A)_11%7
-

2 Potts
9) done

Clio) done
oxidising angst
.

€37s
a
"
If
1µ=cYBg meta chloro
perbentoic
acid .

c- o
-
o H
- -
[ 0] nascent

t-Peroxyhningeoxjgento.tl }

clh=iy 1K¥ -

(epoxide)
uts

"

"
it
HBO

↳ NaOH
'

Inhrareaehi
b) done .
i} -0
OCI
my -4
-
at
}
base
b) c)
'
Cnnreaetivej ↳ 1 shy
,µ=Ec↳
r-I-dt-E.ru
( vinyl system)
'

as
Allyl system
.

f. icy vinyl system

meitner undying
a

# OCI } SNL nor SNL

reaehii .

) done
(Pyridinwm
in
it}
.

chloro
is ) done CH CH -_
Caz chromate)
City
-
. -

I Hglorte ) + 1h0
-

RZCH -
OH + Habits

fdAHCR.tt I ) 44 ( 2. Alcohol
CH CH el
) -

}
}C
-
-

"
RzC=0 OH

9-1 converts ⇐ fpcc ( oxidising

reagent)
}e_ÉH↳_ g-
2. Alcohol
a
→ ketone I } ,
 4) Li D- 11th is
) Na B Ith

Li Allt ( Ot Bn), 4) TPH

3)
Ph GH
,
- I

(5) Bzltg : (diborane)

Sarney It -0 (reducing agent

electrophilic ( e- dethicienej

reducing agent
.

RCIKOH (1 Alcohol)
'

Rat
-
= o

R2 CHOH 12 ketone
'

R
R
Cy
- - -

R Rcltzolt ( 2020)
g-
-
OH -

yield is
very hgi
.

1) sing 13, Hg .

R-G.jo/2'-RC1hoHtR'oH
 RIH=Élh-É¥)RgH -
cha

( nu)
(
1131021-1 ☒
Bzltg 4310<1-1
É Reid
4h
-

Cllzcozt .

I
BZDG
Cl
}L0zT .

R-CE.CH
'¥É put __ our

113211-6/43102-4
Limitations Balto R4{- Cltg
reduce
It cannot
explanation
.

is ,z_ñt e- deficient .

dthioe .

is RANK
e- deficient .

c- I )→ "

7
' "

R -
X -

( Itself édelticions
)
Balto
no
reaction .
 CHROH The best
02¥
regmrtr
,

the
maximum field g pdr
a) LAH

ftp.gy-ce £1321b
it b) SBH
d) lblnij

'
citron
Fat

13¥
.lt#ymJIU
✓
SBH

=E÷
→ "

E.
-
her
Its ton LAH
ko SBE
→
Redone all Ine system except
repealing
"
( IIT
"

- Coz It's Ester

given)

Nilpdlptml.nl
I Hzlcatalyst)
provide surface
.

→ Reiko H
RCH -_ o

R -
122 CHOW
R
g-
-

ce → RCIKOH
R
Cy
-
-

→ Rub-141k
MHz
R g-
-

→ RUSH 12
R -
CEN
→
RAIL
121402
Ñ=i RAH Clb -

R → .

-
:
 Chemisorption
r
>
Adsorption :( surface)

RClt-CHR-y.RCIE-cltr.TL
( HydrogenationA-)It =
- ne .

exothermic
Ruiz cltrr
-

R
.

RC :c -

Hs)
less ihre
alkene,
More stable

hydrogenation
.

hearty

By .im#i--i?gciE--i?g
icy
15/(12×11) ¥1921T) ( bait)

CG < 44=42
< c1h= CH -

Exit
↳ < HI
 Limitation Hz ( cat
g
reduce -

coz it
It cannot

RCOZH ",
or
☒ no

reaction .

Hrcpd)

FEE-i-EH.I.L.fi#R-jbntinI --
; always it
pn

given ÷ehi
is
.
121
Rh

4¥
is
R or yield Ra
g-
.
-

very rent Rn
negligible ; RI ✗ xx
 * Catalyst is poisoned , catalyst
decreases Alkene is
reactivity .

the final poll .

VI ) Hz ( Pd Bas -
g) *

or (IIT)
Lind lar (Pd - Caco}
) Leroy yrs
catalyst poisoned with Quinoline .

Cis alkene
Alkyne
.

REC R -

Same
-

side
¥c=i?④
attack [syn addition)

% -
E- c- #←É
cltg
reagents
%)
-
Another
=L
which is also
-
µ

some conversion
now for
 µ ;,⑤÷%zKd or

¥
a- ⇐ c-

* *
ey¥dÉ%É?u
p-2-m.lt
' '
H

Its (Niz B)

01ns uses (nickel

beside)

ighindlari-NCER-DR-q.ee#s
Hz ( Pd - Bason)
Rc
Pepanli
Quinoline
+ ⑤ great -
- o

ñros÷.¥¥¥
 "
H2O Reif
-
-4

nulgemdihahidej )
"
RCH -
Heo

É RCH
Hep aahig
R-

Goiu
'
= 0
Aldehyde

R
Éi
g
- -
ee
-

78°C .

Frans Alkene
Alkyne
→

R E- - R'
c-

or
!¥=E"R
,

Li in big 1-1113
. .

:BirchRedLIIa
sin

,
ÉY ,

Flat Hst
/
- cis hex . > ene
P
.

{+ ⇐ c- qy

'c=cs
Et

3
hexgne in liq .
NH 3 '
¥72 ene .
 chiral centre Chiral centre
single is lost

@sµnpr
" i§FÉ 113C

F.
"
E-
*

optically ?
inactive poets

fÉa±§÷f
"
's

( does nor ,

catalyst
¥4.gl
reduce
it }
= band
12 converts
triplets d
-
-1€ ,
( optically
active

{
to big 14113
(
. poet,
Cis alkene -
cannot (chirality is
reduce maintained
double bond
Tong
alkyne
→

but converts
alkene .

I
}C•µ chirality is
Optically (
inactive .
µ÷y, lost )
 discussed
iLiA1Hy ✓

in )NaBHy r

m
) Li AIHCOTBN) } r

in
phzsnlt
or

✓
✓
I Bzltg

vis Hglni / Pd / Pt ) ✓
HYDROGENATION
✓

in ] Hg Kindler) ROSENMVND
REDUCTION

my Hy - P-2 catalyst ✓

BIRCH
'¥
) Na/m'hg Li
MY
v. RE DUE
-110N

! A. RV
d) D- 1- Isopropoxide zedrrehi
•

.
 R
M.p.ir rednehi
Merwin
-
Pmdoof
-

c¥} ,

Reduction .

# sopnpyy
-

Verley
RCIKOH
Rut -_o
Aluminium f Alcohol
Aldehyde Isopropoxide .

1221=0*-4%-134-104
( ) 2. Alcohol

ketone .

p.fi?j#A' ¥
d-
.

"
[ a

3(Redoing
Isopnpo
✗ ide
]

Jus agone ,
membered
A- donor .
Al -

¥0
6
cyclic
-1 S -
.

= o

Comets
piii HI ,
is
-

C. Alcohol)) ↳ '
(organo
-

in .
.

newbie
'_ epd)
Rclholt ¥ Rely OJAI >
-