Table 1 Critical Properties and Acentric Factor - Organic Compounds

freeze point boiling point critical temp critical pres critical volume critical den crit com fac ac:ent rae

10 FORMULA NAME CAS No TF• K code TB, K code Tc, K code pc. bar code Ve, mVmol code rho e. glm I code Zc code omega
13 CBrCIF2 bromochlorodifluoromethane 353-59-3 113.65 1 269.14 1 426.15 1 42.54 1 246.0 1 0.6722 1 0.295 1 0.187
15 CBrCI2F bromodichlorotluoromethane 353-58-2 113.65 1 269.14 1 51290 2 45.30 2 266.0 2 0.6830 2 0.283 2 0.187
16 CBrCI3 bromotrichloromethane 75·62·7 252.15 1 378.05 1 606.00 2 49.70 2 284.0 2 0.6981 2 0.280 2 0.192
17 CBrF3 bromotritluoromethane 75-63-8 105.15 1 215.26 1 340.15 1 39.70 1 200.0 1 0.7446 1 0.281 1 0.170
23 CBr2F2 dibromodifluoromethane 75-61-6 163.05 1 295.94 1 478.00 2 40.70 2 249.0 2 0.8426 2 0.255 2 0.108
29 CBr4 carbon tetrabromide 558·13·4 364.15 1 462.65 1 724.91 2 96.31 2 328.5 2 1.0095 2 0.525 2 0.501
34 CCIF3 chlorotrifluoromethane 75-72-9 92.15 1 191.74 1 302.00 1 38.70 1 180.3 1 0.5794 1 0.278 1 0.172
39 CCIN cyanogen chloride 506·77·4 266.65 1 286.00 1 449.00 2 59.90 2 163.0 2 0.3771 2 0.262 2 0.320
42 CCI2F2 dichlorodifluoromethane 75-71-8 115.15 1 243.36 1 384.95 1 41.25 1 217.0 1 0.5572 1 0.280 1 0.180
44 CCI20 phosgene 75-44-5 145.37 1 280.71 1 455.00 1 56.74 1 190.2 1 0.5200 1 0.285 1 0.201
47 CCI3F trichlorofluoromethane 75-69-4 162.04 1 296.97 1 471.20 1 44.08 1 248.0 1 0.5539 1 0.279 1 0.189
50 CCI4 carbon tetrachloride 56-23-5 250.33 1 349.79 1 556.35 1 45.60 1 276.0 1 0.5573 1 0.272 1 0.193
68 CF20 carbonyl fluoride 353-50-4 161.89 1 188.58 1 297.00 2 57.60 2 141.0 2 0.4681 2 0.329 2 0.283
74 CF4 carbon tetrafluoride 75·73·0 89.56 1 145.09 1 227.50 1 37.40 1 140.0 1 0.6286 1 0.277 1 0.179
92 CHBrF2 bromodifluoromethane 1511-62-2 128.00 1 257.67 1 411.98 1 51.32 2 167.0 1 0.7840 1 0.250 1,2 0.205
96 CHBr3 bromoform 75·25·2 281.20 1 422.35 1 696.00 2 60.90 2 286.0 2 0.8837 2 0.301 2 0.156
97 CHCIF2 chlorodifluoromethane 75·45·6 115.73 1 232.32 1 369.30 1 49.71 1 166.0 1 0.5209 1 0.269 1 0.219
101 CHCI2F dichlorofluoromethane 75-43-4 138.15 1 282.05 1 451.58 1 51.84 1 196.0 1 0.5251 1 0.271 1 0.205
104 CHCI3 chloroform 67-66-3 209.63 1 334.33 1 536.40 1 54.72 1 239.0 1 0.4995 1 0.293 1 0.222
113 CHF3 f1uoroform 75·46-7 117.97 1 191.09 1 299.01 1 48.16 1 132.0 1 0.5304 1 0.256 1 0.264
117 CHI3 iodoform 75-47-8 396.16 1 491.16 1 794.55 2 53.12 2 349.5 2 1.1266 2 0.281 2 0.193
122 CHN hydrogen cyanide 74·90-8 259.91 1 298.85 1 456.65 1 53.90 1 139.0 1 0.1944 1 0.197 1 0.410
140 CH2BrCI bromochloromethane 74·97·5 185.20 1 341.20 1 557.00 2 64.70 2 204.0 2 0.6342 2 0.285 2 0.206
144 CH2Br2 dibromomethane 74-95-3 220.60 1 370.10 1 611.00 2 71.70 2 223.0 2 0.7795 2 0.315 2 0.210
145 CH2CIF chlorofluoromethane 593-70-4 138.00 1 264.06 1 427.00 2 56.20 2 154.0 2 0.4447 2 0.244 2 0.211
147 CH2CINO carbamic chloride 463-72-9 323.15 1 334.65 1 517.00 2 73.80 2 201.0 2 0.3955 2 0.345 2 0.445
149 CH2CI2 dichloromethane 75-09-2 178.01 1 312.90 1 510.00 1 60.80 1 185.0 2 0.4591 2 0.265 1,2 0.199
158 CH2F2 difluoromethane 75·10·5 137.00 1 221.50 1 351.26 1 57.84 1 123.0 1 0.4230 1 0.244 1 0.277
161 CH212 diiodomethane 75-11-6 279.25 1 455.15 1 747.00 2 54.70 2 272.0 2 0.9847 2 0.240 2 0.141
175 CH20 formaldehyde 50-00-0 181.15 1 254.05 1 408.00 2 65.86 2 105.0 2 0.2860 2 0.204 2 0.282
176 CH202 formic acid 64-18-6 281.55 1 373.71 1 588.00 1 58.10 2 125.0 2 0.3682 2 0.149 1,2 0.317
191 CH3Br methyl bromide 74·83·9 179.55 1 276.71 1 467.00 1 80.00 2 156.0 1 0.6086 1 0.321 1,2 0.192
196 CH3CI methyl chloride 74-87-3 175.45 1 248.93 1 416.25 1 66.80 1 143.0 1 0.3531 1 0.276 1 0.153
201 CH3CI02S methanesulfonyl chloride 124-63-0 242.15 1 434.65 1 676.00 2 52.30 2 260.0 2 0.4406 2 0.242 2 0.300
210 CH3CI3Si methyl trichlorosilane 75-79-6 195.35 1 339.55 1 517.00 1 35.30 1 340.0 1 0.4396 1 0.279 1 0.263
214 CH3F methyl fluoride 593·53·3 131.35 1 194.82 1 317.42 1 58.75 1 113.0 1 0.3012 1 0.252 1 0.198
222 CH3t methyl iodide 74-88-4 206.70 1 315.58 1 528.00 2 73.70 2 185.0 2 0.7672 2 0.311 2 0.197
232 CH3NO formamide 75-12-7 275.70 1 493.00 1 771.00 2 78.00 2 163.0 2 0.2763 2 0.198 2 0.453
235 CH3N02 nitromethane 75-52·5 244.60 1 374.35 1 588.15 1 63.13 1 173.4 1 0.3520 1 0.224 1 0.348
251 CH4 methane 74·82-8 90.69 1 111.66 1 190.56 1 45.99 1 98.6 1 0.1627 1 0.286 1 0.012
254 CH4CI2Si methyl dichlorosilane 75-54-7 182.55 1 314.70 1 483.00 2 39.50 2 289.0 2 0.3980 2 0.284 2 0.276
259 CH4N20 N·hydroxymethanimidamide 624-82-8 405.85 1 465.00 1 705.00 2 90.50 2 218.0 2 0.2755 2 0.337 2 ---
265 CH4N2S ammonium thiocyanate 1762-95-4 454.15 1 536.00 1 854.00 2 82.30 2 248.0 2 0.3069 2 0.287 2 0.359
272 CH40 methyl alcohol 67·56·1 175.47 1 337.85 1 512.64 1 80.97 1 118.0 1 0.2715 1 0.224 1 0.564
275 CH403S methanesulfonic acid 75·75-2 292.81 1 561.00 1 --- --- --- --- 220.0 2 0.4368 2 --- --- ---
278 CH4S methyl mercaptan 74-93-1 150.18 1 279.11 1 469.95 1 72.30 1 145.0 1 0.3318 1 0.268 1 0.158
284 CH5CISi methyl chlorosilane 993·00-0 139.05 1 281.85 1 442.00 2 41.70 2 246.0 2 0.3276 2 0.279 2 0.225
286 CH5N methylamine 74-89-5 179.69 1 266.82 1 430.05 1 74.60 1 154.0 2 0.2017 2 0.321 1,2 0.281
322 CH6Si methyl silane 992-94-9 116.34 1 216.25 1 352.50 1 48.40 2 205.0 2 0.2251 2 0.339 1,2 0.139
337 CI4 carbon tetraiodide 507-25·5 444.15 1 591.61 2 961.09 2 52.28 2 432.5 2 1.2015 2 0.283 2 0.181
351 CNNa sodium cyanide 143·33-9 836.85 1 1769.15 1 2900.00 2 _.. --- --. --- ... ... ... ... .. .
363 CN408 tetranitromethane 509·14·8 287.05 1 398.85 1 540.00 2 26.80 2 439.0 2 0.4465 2 0.262 2 0.705
372 CO carbon monoxide 630-08-0 68.15 1 81.70 1 132.92 1 34.99 1 93.1 1 0.3009 1 0.295 1 0.066
373 COS carbonyl sulfide 463-58-1 134.35 1 223.00 1 378.80 1 63.49 1 135.1 1 0.4447 1 0.272 1 0.097
375 CO2 carbon dioxide 124-38-9 216.58 1 194.67 1 304.19 1 73.82 1 94.0 1 0.4682 1 0.274 1 0.228
382 CS2 carbon disulfide 75-15-0 161.58 1 319.37 1 552.00 1 79.00 1 160.0 1 0.4759 1 0.275 1 0.111
404 C2BrF3 bromotrifluoroethylene 598-73-2 --- --- 270.65 1 432.00 2 44.80 2 239.0 2 0.6733 2 0.298 2 0.175
413 C2Br2F4 1,2·dibromotetrafluoroethane 124-73-2 163.00 1 320.31 1 487.80 1 33.93 1 341.0 1 0.7619 1 0.285 1 0.243
423 C2CIF3 chlorotrifluoroethylene 79-38-9 115.00 1 244.80 1 379.15 1 40.53 1 212.0 1 0.5494 1 0.273 1 0.244
427 C2CIF5 chloropentafluoroethane 76-15-3 173.71 1 234.04 1 353.15 1 31.57 1 252.0 1 0.6130 1 0.271 1 0.251
441 C2CI2F4 1,2-dichloro-l,I,2,2-tetrafluoroethane 76-14-2 180.62 1 276.92 1 418.85 1 32.60 1 294.0 1 0.5814 1 0.275 1 0.252
442 C2CI2F4 1,I'dichloro-l,2,2,2-tetrafluoroethane 374-07-2 216.58 1 276.17 1 418.55 1 33.00 1 294.0 1 0.5814 1 0.279 1 0.253
449 C2CI3F3 1,I,2-trichloro-l,2,2-trifluoroethane 76-13-1 236.92 1 320.75 1 487.25 1 34.10 1 325.0 1 0.5765 1 0.274 1 0.252
450 C2CI3F3 1,I,I-trichloro-2,2,2-trifluoroethane 354-58-5 287.52 1 319.20 1 483.00 2 33.20 2 321.0 2 0.5837 2 0.265 2 0.267
455 C2CI4 tetrachloroethylene 127'18-4 250.80 1 394.40 1 620.00 2 44.90 2 248.0 2 0.6687 2 0.216 2 0.214
456 C2CI4F2 1,1,2,2-tetrachloro-l,2-difluoroethane 76·12·0 297.91 1 366.00 1 551.00 2 33.40 2 351.0 2 0.5807 2 0.256 2 0.279
457 C2CI4F2 1,1,1,2-tetrachloro-2,2-difluoroethane 76·11·9 313.75 1 364.65 1 552.00 2 33.40 2 351.0 2 0.5807 2 0.255 2 0.257
459 C2CI40 trichloroacetyl chloride 76-02-8 216.20 1 391.15 1 590.00 2 41.00 2 332.0 2 0.5477 2 0.277 2 0.350
462 C2CI5F pentachlorofluoroethane 354·56-3 373.15 1 411.05 1 624.00 2 33.40 2 382.0 2 0.5767 2 0.246 2 0.245
463 C2CI6 hexachloroethane 67-72-1 459.95 1 458.00 1 695.00 2 33.40 2 412.0 2 0.5746 2 0.238 2 0.239
488 C2F4 tetrafluoroethylene 116-14-3 142.00 1 197.51 1 306.45 1 39.44 1 172.0 1 0.5815 1 0.266 1 0.227
494 C2F6 hexafluoroethane 76-16-4 173.10 1 194.95 1 292.80 1 29.80 1 224.0 1 0.6161 1 0.274 1 0.249
511 C2HBrCIF3 haiothane 151-67-7 157.40 1 323.35 1 496.00 2 39.20 2 296.0 2 0.6668 2 0.281 2 0.275
525 C2HCIF2 2-chloro·l,l·difluoroethylene 359-10-4 134.65 1 254.55 1 400.55 1 44.58 1 197.0 1 0.4999 1 0.264 1 0.212
528 C2HCIF4 1·chloro·l,I,2,2-tetrafluoroethane 354-25-6 156.15 1 261.41 1 400.00 1 37.60 1 252.0 1 0.5416 1 0.285 1 0.274
529 C2HCIF4 2·chloro·l ,1,1 ,2·tetrafluoroethane 2837-89-0 74.00 1 261.05 1 395.65 1 36.60 1 243.8 1 0.5598 1 0.271 1 0.288
534 C2HCI2F3 1, l-dichloro-l ,2,2-trifluoroethane 812-04-4 255.51 2 303.00 2 481.32 2 39.46 2 282.5 2 0.5413 2 0.279 2 0.287
535 C2HCI2F3 l,2-dichloro·l,I,2-trifluoroethane 354-23-4 195.15 1 301.15 1 461.60 1 36.10 2 278.0 2 0.5501 2 0.262 1,2 0.241
536 C2HCI2F3 2,2·dichloro·l ,1, l·trifluoroethane 306-83-2 166.00 1 301.05 1 456.94 1 36.76 1 278.0 1 0.5501 1 0.269 1 0.282
539 C2HCI3 trichloroethylene 79-01-6 188.40 1 360.10 1 571.00 2 49.10 2 256.0 2 0.5132 2 0.265 2 0.217