01/03/2022

POTENSIOMETRI

POTENSIOMETRI

A potentiometric device has three parts:

1) a reference electrode
2) an indicator/working electrode (selective for the analyte of interest)
3) a device to measure the potential difference

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Liquid junction potential

1. El. Jenis pertama 1. El selektif ion

2. El. Jenis kedua 2. El. Selektif molekul
1. EHS 3. El. redoks
2. Elektroda kalomel
3. Elektroda Ag/AgCl

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SCE: Reference electrode based on the

reduction of Hg2Cl2 to Hg in an aqueous solution
saturated with KCl.

Reference electrode based on the reduction of AgCl to Ag

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(Electrode of the first kind)

Indicator electrode should respond

rapidly, reversibly, and reproducibly
and specifically to analyte of
interest.

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Misal, elektroda indicator jenis pertama logam Cu

digunakan dalam suatu sel potensiometri yg
menggunakan elektroda reference SCE (T 25°C).

Elektroda jenis kedua (Electrode of the second kind)

A metallic electrode whose potential is a function of the

concentration of X in an MXn/M redox half-reaction.

Misal, elektroda Ag dalam larutan jenuh AgI

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Redox electrode
An inert electrode that serves as a source or sink for electrons for a redox half reaction
Example: electrode Pt

Elektroda jenis ke-2 Elektroda redoks

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Hitung potensial teoritis dari sel berikut (dengan asumsi a sama dengan
konsentrasi molar dan T 25oC):
a. SCE || Fe3+ (0,0150 M), Fe2+ (0,0222 M) | Pt
b. Ag/AgCl jenuh || I3- (0,00562 M), I- (0,00313 M) | Pt

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Elektroda indicator membran

Potensial membran: terjadi krn adanya interaksi antara analit dengan membrane dg
adanya perbedaan aktivitas (konsentrasi) diantara 2 sisi membran.

Elektroda selektif ion: suatu elektroda yang potensial membrannya merupakan

fungsi dari konsentrasi ion tertentu dalam larutan.

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Selektivitas membran

KA,I is a selectivity coefficient accounting for the relative response of the interferent

(aA)e and (aI)e are the activities of analyte and interferent yielding identical cell potentials. When the selectivity
coefficient is 1.00 the membrane responds equally to the analyte and the interferent. A membrane shows good
selectivity for the analyte when KA,I is significantly less than 1.00.

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Glass electrode: An ion-selective electrode based on a glass

membrane in which the potential develops from an ion-exchange
reaction on the membrane’s surface.

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Elektroda gelas untuk mengukur pH (pH-meter)

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Solid-state ion-selective electrode: An ion-selective

electrode based on a sparingly soluble inorganic
crystalline material.

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Solid-state ion-selective electrode: An ion-selective

electrode based on a sparingly soluble inorganic
crystalline material.

Liquid-based ion-selective electrode: An ion-selective

electrode in which a chelating agent is incorporated
into a hydrophobic membrane.

For Ca2+ selective ion:

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Solid-state ion-selective electrode: An ion-selective

electrode based on a sparingly soluble inorganic
crystalline material.

Liquid-based ion-selective electrode: An ion-selective

electrode in which a chelating agent is incorporated
into a hydrophobic membrane.

Gas-Sensing Electrode: A membrane electrodes that respond

to the concentration of dissolved gases. Or example CO2
electrode:

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