THE RAJAS INTERNATIONAL SCHOOL

OZHUGINASERY. NAGERCOIL.
CHEMISTRY
Grade : 12 Cyclic Test - 1 Marks :
35

Section - A

1. For the reaction H2+ Br2 —--> 2HBr

The experimental data suggests that,
Rate = k[H2] [Br2]^½.
The molecularity and order for the reaction is ________

2. In a reaction 2A —---> Products, concentration of A decreases from

0.5 mol/L to 0.4 mol / L in 10 minutes. Calculate the rate during this
interval.
3. The conversion of X to Y follows second order kinetics. If
concentration of X is increased three times, how will it affect the rate
of formation of Y.
4. Time required to decompose SO2Cl2 to half of its initial amount is 60
minutes.If the decomposition is a first order reaction, calculate the
rate constant of the reaction.
5. Determine the order of the reaction and the dimensions of the rate
constant for C2H5Cl —----> C2H4 + HCl ; Rate = k[C2H5Cl]

Section - B
1. Define (i) Half life of a reaction.
(ii) Rate constant
2. (i) What are pseudo first order reactions? Give examples.
(ii) Write the rate expression of half life for zero order reaction.
3. A first order reaction takes 40 min for 30% decomposition. Calculate
t1/2 for this reaction.( log 1.428 = 0.1548)
4. Differentiate order and molecularity of a reaction.
5. The rate constant for a first order reaction is 60s^-1. How much time
will it take to reduce the initial concentration of the reactant to reduce
to its 1/10th value.
Section - C
1.(i) Derive the integrated rate equation for a first order reaction.
(ii) A reaction is 1st order w.r.t. A and 2nd order w.r.t. B. Write the
differential rate equation. How is the rate affected when the
concentrations of both A and B are doubled.

2. The decomposition of a compound is found to follow first order rate

law. If it takes 15 min for 20% of original material to react, calculate
(i) the rate constant
(ii) the time at which 10% of the original material remains unreacted.