24th Chemistry Shift 1

JEE (Main)
PAPER-1 (B.E./B. TECH.)
2021
COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 24 February, 2021 (SHIFT-1) | TIME : (9.00 a.m. to 12.00 p.m)
Duration: 3 Hours | Max. Marks: 300
SUBJECT: CHEMISTRY
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| JEE MAIN-2021 | DATE : 24-02-2021 (SHIFT-1) | PAPER-1 | OFFICIAL | CHEMISTRY
PART : CHEMISTRY
Single Choice Type
This section contains 20 Single choice questions. Each question has 4 choices (1), (2), (3) and (4) for its answer,
out of which Only One is correct.
1. In Freundlich absorption isotherm, slope of AB line is :
B
A
log(x/m)
log P
Slope is :
1 1
with   0 to 1
1
(1) log with (n < 1) (2)
n n n 
(3) n with (n, 0.1 to 0.5) (4) log n with (n > 1)

Ans. (2)
x
Sol. = kP1/n
m
x 1
ln = ln K + ln P
m n
1
Slope =
n
Pressure Graph Relation
x
At low pressure straight line = kP
m
(x/m) = kp1/n
At intermediate pressure dependent on power of pressure 1
(0< <1)
n
x
At high pressure Independent of pressure =k
m

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CH3 CH
2. What is the major product formed by HI on reaction with C CH2 ?
CH3
CH3
CH3
CH3
(1) CH3–C—CH–CH2 (2) CH3–C—CH–CH3

CH3 H  CH3
CH3
(3) CH3–C—CH–CH3 (4) CH3–CH—CH–CH2–CH3

CH3  CH3 
Ans. (2)
CH3 CH3 
 
H+ 1,2-Me
CH3–C–CH–CH3 –
Sol. CH3–C–CH=CH2 CH3–C–CH–CH3 CH3–C–CH–CH3
shift
CH3 CH3 H3C CH3 H3C CH3
3. Which of the following reagent is used for the following reaction ?

?
CH3CH2CH3  CH3CH2CHO
(1) Potassium permanganate (2) Molybdenum oxide
(3) Copper at high temperature and pressure (4) Manganese acetate
Ans. (2)
Mo2O3
Sol. CH3–CH2–CH3 CHO
Controlled oxidation
4. Which of the following compound gives pink colour on reaction with phthalic anhydride in conc. H 2SO4
followed by treatment with NaOH ?
CH3 CH3
(1) (2)
OH HO
HO CH3 H3C CH3
(3) (4)
HO CH3 HO OH
Ans. (1)

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O
||
O O
|| OH
H2SO 4
Sol. O +  
NaOH
||
O HO OH
Pink colour
(derivative of phenolphthalein)
5. In the following reaction the reason why meta-nitro product also formed is :
NH2 NH2 NH2 NH2
NO2
Conc. HNO3 + +
Conc. H2SO4, 288 K
NO2
NO2
[A] [B] [C]
51% 47% 2%
(1) –NH2 group is highly meta-directive
(2) low temperature
(3) –NO2 substitution always takes place at meta-position
(4) Formation of anilinium ion
Ans. (4)

NH3
Sol. Due to strongly acidic medium, aniline convents into anilinium ion ( ) which is meta directing.
6. The gas released during anaerobic degradation of vegetation may lead to :

(1) Global warming and cancer (2) Corrosion of metals
(3) Acid rain (4) Ozone hole
Ans. (1)
Sol. During anaerobic degradation of vegetation CH4 gas is released which causes global warming & cancer.
7. Match List I with List II

List I List II
(Monomer Unit) (Polymer)
(A) Caprolactum (i) Natural rubber
(B) 2-Chloro-1,3-butadiene (ii) Buna-N
(C) Isoprene (iii) Nylon-6
(D) Acrylonitrile (iv) Neoprene
Choose the correct answer from the options given below :
(1) A – iii, B – iv, C – i, D – ii (2) A – i, B – ii, C – iii, D – iv
(3) A – ii, B – i, C – iv, D – iii (4) A – iv, B – iii, C – ii, D – i
Ans. (1)

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Sol. (a) Polymer of monomer caprolactum is Nylon-6

(b) Polymer of monomer 2-Chloro-1,3-butadiene (chloroprene) is Neoprene
(c) Polymer of monomer isoprene is natural rubber
(d) Polymer of monomer butadiene-acrylonitrile is Buna-N.
8. Identify products A and B,

CH3
dil. KMnO4 CrO3
A B
273K
CH3 CH3
(1) A : B:
OH O
CH3 CH3
(2) A : OH B: OH
OH O
O
(3) A : B : HOOC–CH2CH2CH2–C–CH3
CH3 CH3
(4) A : OH B:
OH O
Ans. (2)
Sol. CH3
–
KMnO4/OH OH CrO3 OH
H2O H+
Syn hydroxylation OH O
9. The product formed in the first step of the reaction of with excess
Mg/Et2O(Et=C2H5) is :
MgBr
CH3–CH2–CH–CH2–CH–CH3
(1) (2) CH3CH2–CH–CH2–CH–CH3
CH3–CH2–CH–CH2–CH–CH3
MgBr
CH3–CH2–CH–CH2–CH–CH3 CH2
(3) (4) CH3–CH
CH3–CH–CH2–CH–CH2–CH3 CH–CH3
Ans. (2)
Sol. It is 1,3-dihalide, in this case internal Wurtz reaction takes place & form cyclopropane ring.

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10. Al2O3 was leached with alkali to get X. The solution of X on passing of gas Y, forms Z. X, Y and Z
respectively are :
(1) X = Al(OH)3, Y = SO2, Z = Al2O3.xH2O (2) X = Na[Al(OH)4], Y = CO2, Z = Al2O3.xH2O
(3) X = Al(OH)3, Y = CO2, Z = Al2O3 (4) X = Na[Al(OH)4], Y = SO2, Z = Al2O3
Ans. (2)
NaOH heat
Sol. Al2O3   Na[Al(OH)4]   Al(OH)3 
CO2 ( gas )
  Al2O3.xH2O
Acidic oxide
Amphoteric Soluble Reprecipitated
Nature Complex
[Soluble in NaOH]
11. What is the final product (major) ‘A’ in the given reaction ?
CH3 OH
CH HCl ‘A’
CH3 (major Product)
CH3 Cl CH3
CH Cl
CH3
(1) (2) CH2–CH3
CH3 CH3
CH=CH2 CH
(3) (4) CH3
Ans. (2)

OH OH2
+
Sol. H+ –H2O 1,2-H– +
shift
Cl–
Cl
12. Consider the elements Mg, Al, S, P and Si, the correct increasing order of their first ionization enthalpy
is:
(1) Al < Mg < Si < S < P (2) Mg < Al < Si < S < P
(3) Al < Mg < S < Si < P (4) Mg < Al < Si < P < S
Ans. (1)

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Sol. Mg12 = 1s22s22p63s2

Al13 = 1s22s22p63s23p1
Si14 = 1s22s22p63s23p2
P15 = 1s22s22p63s23p3
S16 = 1s22s22p63s23p4
13. Which of the following are isostructural pairs ?

2– 2– –
(A) SO4 and CrO4 (B) SiCl4 and TiCl4 (C) NH3 and NO3 (D) BCl3 and BrCl3
(1) B and C only (2) C and D only (3) A and B only (4) A and C only
Ans. (3)
Sol. SiCl4  sp3 hybridisation  Tetrahedral
TiCl4  sp3 hybridisation  Tetrahedral
 H
N  sp3 hybridisation (p = 1)  Pyramidal
3
NO3–  sp2 hybridisation (p = 0)  Trigonal planar

SO42–  sp3 hybridisation  Tetrahedral
CrO42–  d3s hybridisation  Tetrahedral
14. (A) HOCl + H2O2  H3O+ + Cl– + O2

(B) 2 + H2O2 + 2OH–  2– + 2H2O + O2
Choose the correct option.
(1) H2O2 act as oxidizing and reducing agent respectively in equations (A) and (B)
(2) H2O2 acts are reducing agent in equations (A) and (B)
(3) H2O2 acts are oxidising agent in equations (A) and (B)
(4) H2O2 acts reducing and oxidising agent respectively in equations (A) and (B)
Ans. (2)
Sol. In both Case H2O2 act as reducing agent.
15. ‘A’ and ‘B’ in the following reactions are :

NH2
SnCl / HCl / H O 
NaNO 2 / HCl
  (A) 2 
3
 (B)
KCN
+ –
CN Cl N2Cl Cl
(1) (A) : (B) : (2) (A) : (B) :
+ –
N2Cl CHO CN CHO
(3) (A) : (B) : (4) (A) : (B) :
Ans. (4)

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NH2 CN CHO
NaNO/HCl SnCl2 / HCl / H3O+

Sol.
KCN
[A] [B]
16. Out of the following, which type of interaction is responsible for the stabilisation of -helix structure of
proteins ?
(1) Ionic bonding (2) Hydrogen bonding
(3) Vander Waals forces (4) Covalent bonding
Ans. (2)
O
Sol. -Helix structure arise due to H-bonding between —C— and —NH— group of peptide bond.
17. The major components in “Gun Metal” are :

(1) Cu, Zn and Ni (2) Cu, Ni and Fe
(3) Cu, Sn and Zn (4) Al, Cu, Mg and Mn
Ans. (3)
Sol. (Cu + Zn + Sn) (87 : 3 : 10) Gun metal
18. Given below are two statements :

Statement I : Colourless cupric metaborate is reduced to cuprous metaborate in a luminous flame.
Statement II : Cuprous metaborate is obtained by heating boric anhydride and copper sulphate in a non-
luminous flame.
In the light of the above statements, choose the most appropriate answer from the options given below.
(1) Statement I is false but Statement II is true
(2) Both Statement I and Statement II are false
(3) Statement I is true but Statement II is false
(4) Both Statement I and Statement II are true
Ans. (2)
Sol. Na2B4O7.10H2O  Na2B4O7  2NaBO2 + B2O3
Oxidising flame [Non-luminous flame]
CuSO4  CuO + SO3
2
CuO + B2O3  Cu(BO2 )2
Blue bead
Reducing flame [luminous flame]
1
Cu(BO2)2 + C  2 CuBO2 + CO + B2O3
0
2CuBO2 + C  2 Cu(s) + B2O3 + CO(g)

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19. The electrode potential of M2+ /M of 3d-series elements shows positive value for :
(1) Zn (2) Cu (3) Co (4) Fe
Ans. (2)
Sol. Copper is placed below the Hydrogen in electrochemical series.
20. Which of the following ore is concentrated using group I cyanide salt ?
(1) Sphalerite (2) Siderite (3) Malachite (4) Calamine
Ans. (1)
Sol. NaCN reacts with ZnS and forms a layer of Na2[Zn(CN)4] complex on the surface of ZnS and thus
prevents it from the formation of froth.
ZnS + CN–  [Zn(CN)4]2–
Numerical Value Type

This section contains 10 Numerical value type questions.
21. The reaction of sulphur in alkaline medium is given below :

–
S8(s) + aOH (aq)  b S2–(aq) + cS2O3 (aq) + dH2O()
2–
the values of ‘a’ is …………. (Integer answer)

Ans. (12)
Sol. S8 + a OH–  b S2– + c S2O32– + d H2O
(1) Reduction Half reaction :
16e– + S8  8S2–
(2) Oxidation Half reaction :
24OH– + S8  4S2O32– + 12H2O + 16e–
On adding (1) & (2)
Net redox reaction is
2S8 + 24OH–  8S2– + 4S2O32– + 12H2O
S8 + 12OH–  4S2– + 2S2O32– + 6H2O
Ans. a = 12
22. At 1990 K and 1 atm pressure, there are equal number of Cl 2 molecules and Cl atoms in the reaction
mixture. The value of Kp for the reaction Cl2(g) = 2Cl(g) under the above conditions is x × 10–1. The value
of x is ………. (Rounded off to the nearest integer)
Ans. (5)
Sol. Cl2(g) 2Cl (g)
½atm ½atm
(1 / 2) 2
Kp =
(1 / 2 )
1
Kp = = 0.5 Kp = 5 × 10–1
2

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23. For the reaction A(g)  B(g), the value of the equilibrium constant at 300 K and 1 atm is equal to 100.0.
The value of rG for the reaction at 300 K and 1 atm in J mol–1 is –xR. Where x is
[R = 8.31 J mol–1 K–1 and in 10 = 2.3]
Ans. (1380)
Sol. For chemical reaction at equilibrium
Gº = –RT ln Keq
Gº = –R × 300 × ln 100
Gº = –R × 300 × ln (10)2
Gº = –R × 300 × 2 × 2.3
Gº = –1380 R So, x = 1380
24. Gaseous cyclobutene isomerizes to butadiene in a first order process which has a ‘k’ value of 3.3 × 10–
4s–1 at 153ºC. The time in minutes it takes for the isomerization to proceed 40% to completion at this
temperature is …………. (Rounded off to the nearest integer)

Ans. (26)
2.303 100
Sol. tx% = log
K 100  x
2.303 100
= 4
log
3.33  10 100  40
3  2.303  104 100
= log
10 60
3  2.303  104 5
= log
10 3
= 1532 sec. = 25.5 minute  26 min.
25. When 9.15 g of ClCH2COOH is added to 500 mL of water, its freezing point drops by 0.5ºC. The
dissociation constant of ClCH2COOH is x × 10–3. The value of x is………
(Rounded off to the nearest integer)
[ K f (H2O ) = 1.86 K kg mol–1]
Ans. (34)
Sol. ClCH2COOH  ClCH2COO– + H+ [n = 2]
i = 1 + (n – 1) = (1 – )
TF = i [KF × m]
 9.45  1000 
0.5 = i 1.86 
 94.5  500 
0 .5  5
i= = 1.344
1.86
i = (1 + (n – 1)
n=2
i = 1 + 
 = i – 1 = 1.344 – 1
 = 0.344

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c 2
Ka =
1 
0.2  0.34  0.34 –3
= = 0.035  35 × 10
1  0.34
so Ans. is 35
26. the stepwise formation of [Cu(NH3)4]2+ is given below :

K1
Cu2+ + NH3 [Cu(NH3)]2+
K2
[Cu(NH3)]2+ + NH3 [Cu(NH3)2]2+
K3
[Cu(NH3)2]2+ + NH3 [Cu(NH3)3]2+
K4
[Cu(NH3)3]2+ + NH3 [Cu(NH3)4]2+
The value of stability constants K1, K2, K3 and K4 are 104, 1.58 × 103, 5 × 102 and 102 respectively. The
overall equilibrium constants for dissociation of [Cu(NH 3)4]2+ is x × 10–12. The value of x is………
Ans. (1)
Sol. Cu2+ + 4NH3 [Cu(NH3)4]2+
kƒ = k1 × k2 × k3 × k4
kƒ = 104 × 1.58 × 103 × 5 × 102 × 102 = 7.9 × 1012
1
so, dissociation constant for [Cu(NH3)4]2+ is kd = = 1.26 × 10–12
kƒ
So, x = 1
27. Number of amphoteric compounds among, the following is……….

(A) BeO (B) BaO (C) Be(OH)2 (D) Sr(OH)2
Ans. (2)
Sol. BeO, Be(OH)2 are amphoteric.
28. The coordination number of an atom in a body-centered cubic structure is…….

[Assume that the lattice is made up of atoms]
Ans. (8)
Sol. A body-centred cubic (bcc) unit cell has an atom at each of its corners and also one atom at its body
centre. Fig. depicts (a) open structure (b) space filling model and (c) the unit cell with portions of atoms
actually belonging to it. It can be seen that the atom at the filling structure (c) actual portions of atoms
belonging to one unit cell.

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29. A proton and a Li3+ nucleus are accelerated by the same potential. If Li and p denote the de Broglie
 Li
wavelengths of Li3+ and proton respectively, then the value of is x × 10–1.
P
The value of x is…………. (Rounded off to the nearest integer)
[Mass of Li3+ = 8.3 mass of proton]
Ans. (2)
h
Sol. =
2m (qV )
 Li 3  m P qP 1 1 1 1
= =  = = = 0.2 = 2 × 10–1
P m Li 3  qLi 3  8 .3 3 24.9 5
so x = 2
30. 4.5 g of compound A (MW = 90) was used to make 250 mL of its aqueous solution. The molarity of the
solution in M is x × 5 10–1. The value of x is………….
Ans. (2)
W
Sol. molarity = × 1000
M  Vml
4.5
= × 1000
90  250
1
= = 0.2
5
= 2 × 10–1 Ans. x=2

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JEE (Main)

PAPER-1 (B.E./B. TECH.)

Resonance Eduventures Ltd.

1. In Freundlich absorption isotherm, slope of AB line is :

(3) n with (n, 0.1 to 0.5) (4) log n with (n > 1)

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(1) CH3–C—CH–CH2 (2) CH3–C—CH–CH3

(3) CH3–C—CH–CH3 (4) CH3–CH—CH–CH2–CH3

3. Which of the following reagent is used for the following reaction ?

HO CH3 H3C CH3

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6. The gas released during anaerobic degradation of vegetation may lead to :

7. Match List I with List II

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Sol. (a) Polymer of monomer caprolactum is Nylon-6

8. Identify products A and B,

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Sol. Mg12 = 1s22s22p63s2

13. Which of the following are isostructural pairs ?

NO3–  sp2 hybridisation (p = 0)  Trigonal planar

14. (A) HOCl + H2O2  H3O+ + Cl– + O2

15. ‘A’ and ‘B’ in the following reactions are :

(1) (A) : (B) : (2) (A) : (B) :

(3) (A) : (B) : (4) (A) : (B) :

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NaNO/HCl SnCl2 / HCl / H3O+

17. The major components in “Gun Metal” are :

18. Given below are two statements :

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Numerical Value Type

21. The reaction of sulphur in alkaline medium is given below :

the values of ‘a’ is …………. (Integer answer)

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temperature is …………. (Rounded off to the nearest integer)

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26. the stepwise formation of [Cu(NH3)4]2+ is given below :

27. Number of amphoteric compounds among, the following is……….

28. The coordination number of an atom in a body-centered cubic structure is…….

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