24th Chemistry Shift 2

JEE (Main)
PAPER-1 (B.E./B. TECH.)
2021
COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 24 February, 2021 (SHIFT-2) | TIME : (3.00 p.m. to 6.00 p.m)
Duration: 3 Hours | Max. Marks: 300
SUBJECT: CHEMISTRY
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| JEE MAIN-2021 | DATE : 24-02-2021 (SHIFT-2) | PAPER-1 | OFFICIAL | CHEMISTRY
PART : CHEMISTRY
Single Choice Type

This section contains 20 Single choice questions. Each question has 4 choices (1), (2), (3) and (4) for its answer,
out of which Only One is correct.
1. Given below are two statements :

Statement I : The value of the parameter “Biochemical Oxygen Demand (BOD)” is important for survival
of aquatic life.
Statement-II : The optimum value of BOD is 6.5 ppm.
In the light of the above statements, choose the most appropriate answer from the options given below :
(1) Both Statement I and Statement II are false (2) Statement I is true but Statement II is false
(3) Both Statement I and Statement II are true (4) Statement I is false but Statement II is true
Ans. (2)
Sol. Factual
2. What is the correct sequence of reagents used for converting nitrobenzene into m-dibromobenzene ?
NO2 Br
   

Br
Br2 / Fe Sn / HCl NaNO / HCl CuBr / HBr
(1)    /   / 2 /   
H
 / 

Sn / HCl KBr Br2
(2)   /  / 
Sn / HCl Br2 NaNO 2 NaBr
(3)   /  /   /  
H
 / 

NaNO 2 HCl KBr
(4)   /  / 
Ans. (1)
NO2 NO2 NH2 N2Cl

Br2/Fe Sn/HCl
Sol. NaNO2/HCl
Br Br Br
CuBr/HBr
Br
Br

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3. The correct shape and ––bond angles respectively in 3– ion are :
(1) T-shaped; 180º and 90º (2) Trigonal planar; 120º
(3) Distorted trigonal planar; 135º and 90º (4) Linear; 180º
Ans. (4)
·· I –
I ··
Sol.
·· I
4. The correct set from the following in which both pairs are in correct order of melting point is :
(1) LiCl > LiF ; MgO > NaCl (2) LiCl > LiF ; NaCl > MgO
(3) LiF > LiCl ; MgO > NaCl (4) LiF > LiCl ; NaCl > MgO
Ans. (3)
Sol. Lattice energy  |Z+| |Z–|
1

r  r
Lattice energy  melting point

Lattice energy: LiF > LiCl
Lattice energy: MgO > NaCl
M.Pt. of LiF = 845ºC
M.Pt. of LiCl = 605ºC
M.Pt. of NaCl = 801ºC
M.Pt. of MgO = 2852ºC
5. In polymer Buna-S : ‘S’ stands for :

(1) Sulphonation (2) Sulphur (3) Styrene (4) Strength
Ans. (3)
Sol. Buna-S is an addition polymer of 1,3-Butadiene and styrene. So ‘S’ stands for styrene (Ph–CH=CH2).

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6. The correct order of the following compounds showing increasing tendency towards nucleophilic
substitution reaction is :
Cl Cl Cl
Cl NO2
NO2 O2N
NO2 NO2 NO2

   V
(1) (i) < (ii) < (iii) < (iv) (2) (iv) < (iii) < (ii) < (i) (3) (iv) < (i) < (ii) < (iii) (4) (iv) < (i) < (iii) < (ii)
Ans. (1)
Sol. Electron withdrawing group increases rate of aromatic nucleophilic substitution reaction.
7. What is the correct order of the following elements with respect to their density ?
(1) Zn < Cu < Co < Fe < Cr (2) Zn < Cr < Fe < Co < Cu
(3) Cr < Zn < Co < Cu < Fe (4) Cr < Fe < Co < Cu < Zn
Ans. (2)
Sol. Fe = 7.8 gram/cm3
Co = 8.7 gram/cm3
Cu = 8.9 gram/cm3
Zn = 7.1 gram/cm3
8. Match List-I with List-II.

List-I List-II
(Metal) (Ores)
(a) Aluminium (i) Siderite
(b) Iron (ii) Calamine
(c) Copper (iii) Kaolinite
(d) Zinc (iv) Malachite
Choose the correct answer from the options given below :
(1) (a) – (ii) ; (b) – (iv) ; (c) – (i) ; (d) – (iii) (2) (a) – (iii) ; (b) – (i) ; (c) – (iv) ; (d) – (ii)
(3) (a) – (i) ; (b) – (ii) ; (c) – (iii) ; (d) – (iv) (4) (a) – (iv) ; (b) – (iii) ; (c) – (ii) ; (d) – (i)
Ans. (2)
Sol. Siderite = Fe2O3.
Malachite = CuCO3. Cu(OH)2 s
Calamine = ZnCO3
Kaolinite = Al2O3

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9. The incorrect statement among the following is :

(1) Cr2O3 is an amphoteric oxide
(2) VOSO4 is a reducing agent
(3) Red colour of ruby is due to the presence of Co3+
(4) RuO4 is an oxidizing agent
Ans. (3)
Sol. Red Colour of Ruby is due to Cr3+ not due to Co3+
10. According to Bohr’s atomic theory :
Z2
(A) Kinetic energy of electron is 
n2
(B) The product of velocity (v) of electron and principal quantum number (n), ‘vn’  Z2.
Z3
(C) Frequency of revolution of electron in an orbit is 
n3
Z3
(D) Coulombic force of attraction on the electron is 
n4
Choose the most appropriate answer from the options given below :
(1) (A), (C) and (D) only (2) (A) and (D) only
(3) (A) only (4) (C) only
Ans. (2)
Z2
Sol. (i) KE = –TE = 13.6 × eV
n2
Z2
So, KE 
n2
Z
(ii) V = 2.188 × 106 × m/sec
n
So, Vn  Z
v
(iii) Frequency =
2 r
Z2
So, (F) 
n3
kq1 q2
(iv) Force (F) =
r2
 Z3 
So, F   4 

n 
Note : Reso Ans. is (2) but NTA Ans. is (1)

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11. Match List – I and List – II

List – I List – II
(a) Valium (i) Antifertility drug
(b) Morphine (ii) Pernicious anaemia
(c) Norethindrone (iii) Analgesic
(d) Vitamin B12 (iv) Transquilizer
(1) (a) – (i) ; (b) – (iii) ; (c) – (iv) ; (d) – (ii) (2) (a) – (iv) ; (b) – (iii) ; (c) – (ii) ; (d) – (i)
(3) (a) – (ii) ; (b) – (iv) ; (c) – (iii) ; (d) – (i) (4) (a) – (iv) ; (b) – (iii) ; (c) – (i) ; (d) – (ii)
Ans. (4)
Sol. From NCERT
12. Given below are two statements : One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : Hydrogen is the most abundant element in the Universe, but it is not the most abundant
gas in the troposphere.
Reason R : Hydrogen is the lightest element.
In the light of the above statements, choose the correct answer from the options given below :
(1) A is true but R is false
(2) Both A and R are true but R is NOT the correct explanation of A
(3) A is false but R is true
(4) Both A and R are true and R is the correct explanation of A
Ans. (4)
Sol. From NCERT
13. The calculated magnetic moments (spin only value) for species [FeCl4]2–, [Co(C2O4)3]3– and MnO42–
respectively are :
(1) 4.90, 0 and 2.83 BM (2) 4.90, 0 and 1.73 BM
(3) 5.82, 0 and 0 BM (4) 5.92, 4.90 and 0 BM
Ans. (2)
Sol. Complex
(i) [FeCl4]2– = Fe2+ = 3d6, eg2, 1 t2g1,1,1,  = 4.9 BM
(ii) [Co(C2O4)3]3– = Co3+ = 3d6 t2g2,2,2, eg0, 0  = 0 BM
(iii) MnO42– = Mn+6 = 3d1, eg1, 0 t2g0,0,0,  = 1.73 BM

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14. The diazonium salt of which of the following compounds will form a coloured dye on reaction with -
Naphthol in NaOH ?
CH3
NH2 CH2NH2 N–CH3 NH–CH3

(1) (2) (3) (4)
Ans. (1)
Sol. Only aromatic primary amines will give Azo dye test.
15. Which one of the following, carbonyl compounds cannot be prepared by addition of water on an alkyne
in the presence of HgSO4 and H2SO4 ?
O O O O
(1) CH3–C–CH2CH3 (2) CH3–CH2–C–H (3) CH3–C–H (4) C–CH3
Ans. (2)
Sol. HgSO4/H2SO4/H2O gives Markovnikov’s addition product with any alkyne which will gives ketone as a
product. Hence CH3–CH2–CHO will not be produced.
16. Match List – I with List – II.

(Salt) (Flame colour wavelength)
(a) LiCl (i) 455.5 nm
(b) NaCl (ii) 670.8 nm
(c) RbCl (iii) 780.0 nm
(d) CsCl (iv) 589.2 nm
(1) (a) – (ii) ; (b) – (iv) ; (c) – (iii) ; (d) – (i) (2) (a) – (i) ; (b) – (iv) ; (c) – (ii) ; (d) – (iii)
(3) (a) – (iv) ; (b) – (ii) ; (c) – (iii) ; (d) – (i) (4) (a) – (ii) ; (b) – (i) ; (c) – (iv) ; (d) – (iii)
Ans. (1)
Sol. The alkali metals and their salts impart characteristic colour to an oxidizing flame. This is because the
heat from the flame excites the outermost orbital electron to a higher energy level. When the excited
electron comes back to the ground state, there is emission of radiation in the visible region as given below
Metal Li Na K Rb Cs
Colour Crimson red Yellow Violet Red violet Blue
λ/nm 670.8 589.2 766.5 780.0 455.5

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17. Most suitable salt which can be used for efficient clotting of blood will be :
(1) NaHCO3 (2) Mg(HCO3)2 (3) FeCl3 (4) FeSO4
Ans. (3)
Sol. Blood is a negative sol. According to Hardy-Schulz’s rule the cation with high charge has high coagulation
power. Hence FeCl3 can be used for clotting blood.
?
18.
O
Which of the following reagent is suitable for the preparation of the product in the above reaction ?
– 
(1) NH2–NH2/ C2H5 O Na (2) NaBH4
(3) Red P + Cl2 (4) Ni/H2

Ans. (1)
Sol. Wolff Kishner reagent NH2–NH2/C2H5O–K is suitable reagent for the conversion since it is a basic
O
reagent and does not affect alkene. It will reduce C to –CH2–.
19. Match List – I and List – II

O
(a) R–C–ClR–CHO (i) Br2/naOH
(b) R–CH2–COOHR–CH–COOH (ii) H2/Pd-BaSO4

Cl
O
(c) R–C–NH2R–NH2 (iii) Zn(Hg)/Conc. HCl
O
(d) R–C–CH3R–CH2–CH3 (iv) Cl2/Red P, H2O

(1) (a) – (iii) ; (b) – (i) ; (c) – (iv) ; (d) – (ii) (2) (a) – (iii) ; (b) – (iv) ; (c) – (i) ; (d) – (ii)
(3) (a) – (ii) ; (b) – (iv) ; (c) – (i) ; (d) – (iii) (4) (a) – (ii) ; (b) – (i) ; (c) – (iv) ; (d) – (iii)
Ans. (3)

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O
Sol. (A) R–C–Cl H2/Pd R–CHO Rosenmund reaction
BaSO4
O
Zn-Hg/HCl
(B) R–C–R R–CH2–R Clemmensen reduction
Red P + Cl2
(C) RCH2COOH R–CH–COOH HVZ reaction
Cl
O
Br2 + KOH
(D) R–C–NH2 R–NH2 Hoffmann bromamide reaction
20. Which one of the following compounds is non-aromatic ?

+
(1) (2)
+
(3) (4)
O
Ans. (3)
Sol.  contains sp3–C atom. So it is non planar & hence non aromatic.
* 3
sp
 All other options follow Huckel’s rule i.e. (4n + 2) electrons. So all are aromatic compounds.
Numerical Value Type

This section contains 10 Numerical value type questions.
21. The magnitude of the change in oxidising power of MnO 4–/Mn2+ couple is x × 10–4 V, if the H+
concentration is decreased from 1 M to 10 –4 M at 25ºC. (Assume concentration of MnO4– and Mn2+ to be
same on change in H+ concentration). The value of x is……………..
(Rounded off to the nearest integer)
 2.303 RT 
Given :  0.059
 F 
Ans. (3776)

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Sol. MnO4– + 8H+ + 5e–  Mn2+ + 4H2O

1M 1M
0.059 [Mn 2 ]
E = Eº – log
5 [MnO 4 ][H ]8
0.059
E1 = Eº – log 1 = Eº
5
0.059 1
E2 = Eº – log
5 (10  4 )8
0.059
= Eº – log 1032
5
0.059
= Eº – × 32
5
So, magnitude of change in electrode potential
0.059  32
|(E2 – E1)| = – = 0.3776 = 3776 × 10–4
5
22. The solubility product of Pb2 is 8.0 × 10–9. The solubility of lead iodine in 0.1 molar solution of lead nitrate
is x × 10–6 mol/L. The value of x is……… (Rounded off to the nearest integer).
[Given : 2 = 1.41]
Ans. (141)
 –
Sol. Pb(NO3 )2  Pb 2  2NO3
0.1 M 0.1 M 0.2 M
Pb(2)(s) Pb2 (aq)  2 –

( S0.1) 2S
_ 0.1
~
KsP(Pb2) = [Pb2+] [–]2 = 8 × 10–9

= 0.1 (2S)2 = 8 × 10–9
= 4S2 = 8 × 10–8
S2 = 2 × 10–8
S= 2 × 10–4
S = 1.414 × 10–4  141.4 × 10–6
Ans. 141
23. 1.86 g of aniline completely reacts to form acetanilide. 10% of the product is lost during purification.
Amount of acetanilide obtained after purification (in g) is…………… × 10–2.
Ans. (243)

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O
NH2 Ac 2O or CH3COCl NH–C–CH3
Sol.     
Pyridine
Aniline Acetanilide
C6H7N C8H9NO
Molar mass = 93 Molar mass = 135

93 g aniline produce 135 g acetanilide
135 1.86
1.86 g aniline produces = 2.70 g
93
2.70  90
At 90% yield of reaction it produces = = 2.43 g  243 × 10–2 g
100
24. C6H6 freezes at 5.5ºC. The temperature at which a solution of 10 g of C 4H10 in 200 g of C6H6 freeze
is………… ºC. (The molal freezing point depression constant of C6H6 is 5.12ºC/m.)
Ans. (1)
Sol. Tƒ = kƒ × m
 10  1000 
= 5.12 ×  
 58  200 
Tƒ – (Tƒ)soln = 4.41
5.5 – (Tƒ)soln = 4.41
(Tƒ)soln = 1.09ºC
25. The formula of a gaseous hydrocarbon which requires 6 times of its own volume of O 2 for complete
oxidation and produces 4 times its own volume of CO 2 is CxHy. The value of y is…………….
Ans. (8)
Sol. C4H8 + 6O2  4CO2 + 4H2O
26. The volume occupied by 4.75 g of acetylene gas at 50ºC and 740 mmHg pressure is ………….L.
(Rounded off to the nearest integer) [Given R = 0.0826 L atm K–1 mol–1]
Ans. (5)
Sol. PV = nRT
740 4.75
×V= × 0.082 × 323
760 26
V = 4.98 lit
so Ans. = 5

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27. Sucrose hydrolyses in acid solution into glucose and fructose following first order rate law with a half-life
 1
of 3.33 h at 25ºC. After 9 h, the fraction of sucrose remaining is f. The value of log10   is………×10–2.
f
(Rounded off to the nearest integer)
[Assume : In 10 = 2.303, ln 2 = 0.693]
Ans. (81)
tim e given 9
Sol. n= = = 2.7
(T1/ 2 ) 3.33
C0 C  1 1
Cn = n
& F =  n  =
 n
=
( 2)  C0  ( 2) ( 2 ) 2 .7
 1
log   = log(2)2.7
F
= 2.7 × log 2
= 0.81  81 × 10–2
Ans. 81
28. The total number of amines among the following which can be synthesized by Gabriel synthesis is……..
CH3
(A) CH–CH2–NH2 (B) CH3CH2NH2
CH3
CH2–NH2 NH2
(C) (D)
Ans. (3)
Sol. Only primary aliphatic amines can be formed by Gabriel-phthalimide reaction.
29. Among the following allotropic forms of sulphur, the number of allotropic forms, which will show
paramagnetism is…………. [IOC, XII, PBC(16), E]
(1) -sulphur (2) -sulphur (3) S2-form
Ans. (1)
Sol. In S2 molecule have 2 unpaired electrons similar to O2. According to MOT.
30. Assuming ideal behaviour, the magnitude of log K for the following reaction at 25ºC is x × 10–1. The value
of x is……… (integer answer) [PC, XI, TDS, M]
3HC  CH(g) C6H6()
[Given : fGº(HCCH)] = –2.04 × 105 J mol–1; fGº(C6H6) = –1.24 × 105 J mol–1; R = 8.314 JK–1mol–1]
Ans. (855)

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Sol. Gºrxn. = Gºƒ(C6H6) – 3Gºƒ(C2H2)

Gºrxn. = – 1.24 × 105 – 3 × –(2.4 × 105)
Gºrxn. = 4.88 × 105 J/mol
– 2.303 RT log K = 4.88 × 105 J
|log K| = |–85.5| = |–855 × 10–1|
= 855 × 10–1
so Ans. 855

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24th Chemistry Shift 2

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JEE (Main)

PAPER-1 (B.E./B. TECH.)

Resonance Eduventures Ltd.

Single Choice Type

1. Given below are two statements :

   

NO2 NO2 NH2 N2Cl

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Lattice energy  melting point

5. In polymer Buna-S : ‘S’ stands for :

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NO2 NO2 NO2

8. Match List-I with List-II.

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9. The incorrect statement among the following is :

10. According to Bohr’s atomic theory :

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11. Match List – I and List – II

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NH2 CH2NH2 N–CH3 NH–CH3

16. Match List – I with List – II.

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(3) Red P + Cl2 (4) Ni/H2

19. Match List – I and List – II

(b) R–CH2–COOHR–CH–COOH (ii) H2/Pd-BaSO4

Choose the correct answer from the options given below :

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20. Which one of the following compounds is non-aromatic ?

Numerical Value Type

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Sol. MnO4– + 8H+ + 5e–  Mn2+ + 4H2O

Pb(2)(s) Pb2 (aq)  2 –

KsP(Pb2) = [Pb2+] [–]2 = 8 × 10–9

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Molar mass = 93 Molar mass = 135

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Sol. Gºrxn. = Gºƒ(C6H6) – 3Gºƒ(C2H2)

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