CY1101 (Autumn-2021-2022) - Class Test (Organic Section) 11.03.2022 (Preview) Microsoft Forms

11/03/2022, 16:11 CY1101 (Autumn-2021-2022)-Class Test (Organic Section) 11.03.
2022 (Preview) Microsoft Forms
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CY1101 (Autumn-2021-2022)-Class
Test (Organic Section) 11.03.2022
Examination Date: 11-03-2022
Start Time: 4.15 PM
End Time: 5.15 PM
Question
(0.5 Points)
-79°
+79°
+118.5°
-118.5°
Question
(1 Point)
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11/03/2022, 16:11 CY1101 (Autumn-2021-2022)-Class Test (Organic Section) 11.03.2022 (Preview) Microsoft Forms
(±) cis-1,2-cyclohexanediol
Cyclohexanol
(±) cis-1,2-epoxycyclohexanol
(±) trans-1,2-cyclohexanediol
Question
(0.5 Points)
Question
(1 Point)
III
IV
II
More than one of these
Question
(0.5 Points)
II and III
I and III
III
Question
(0.5 Points)
Functional
Tautomer
Positional
Linkage
Question
(1 Point)
(1R, 3R)-1-chloro-3-methylcyclohexane
(1S, 3S)-1-chloro-3-methylcyclohexane
(1R, 3S)-1-chloro-3-methylcyclohexane
(1S,3 R)-1-chloro-3-methylcyclohexane
Question
(1 Point)
I, II, IV and V
I, IV and V
I, III, IV and V
I and III
III and V
Question
(0.5 Points)
(I) is achiral and (II) and (III) are chiral
(I) and (II) are achiral and (III) is chiral
(I) is chiral and (II) and (III) are achiral

(I) and (II) are chiral and (III) is achiral
10
Question
(0.5 Points)
R, S
S, R
R, R
S, S
11
Question
(0.5 Points)
II, III, IV
I, III, IV
I, II, III
All compounds
I, III, V
12
Question
(0.5 Points)
I, IV
IV
II, III
I, III
13
Question
(1 Point)
1R,2R,3R,4S,5S
1S,2S,3R,4R,5S
1R,2R,3S,4S,5R
1R,2R,3S,4S,5S
14
Question
(0.5 Points)
III
IV
II
15
What is the necessary (minimum) condition for a molecule to show optical

activity?
(0.5 Points)
Devoid of three element of symmetry (Sigma, Inversion center, Alternating axis of symmetry)
A stereogenic Center
Devoid of plane of symmetry
Devoid of all four element of symmetry
16
Question
(1 Point)
Rate of elimination is faster in trans-1-bromo-2-methylcyclohexane compared to cis-1-bromo-2-

methylcyclohexane
trans-1-bromo-2-methylcyclohexane produces 1-methylcyclohex-1-ene as major product.
Both b and c are correct
cis-1-bromo-2-methylcyclohexane produces 3-methylcyclohex-1-ene as major product.
None of the above
17
Chair conformation is the most stable conformation for cyclohexane because

of –
(0.5 Points)
All of the above
no torsional strain
no valence angle strain
no flagpole interaction
18
Among the following, which one is incorrect for (R,R) tartaric acid and (S,S)
tartaric acid?
(0.5 Points)
They rotate the plane-polarized light at same magnitude and in same direction
They have identical NMR and IR spectra
They have identical melting point
They rotate the plane-polarized light at same magnitude but in opposite direction
19
Question
(0.5 Points)
IV
III
II
20
Question
(1 Point)
III
II, III
III, IV
I, III, IV
21
Question
(0.5 Points)
22
Question
(0.5 Points)
The compound is not a meso form.
The compound has an optical purity of less than 100%.
The compound possesses only one stereogenic center.
The compound has the (R) configuration.
The compound has the (S) configuration.
23
Question
(1 Point)
II
None of the above
III
24
Question
(0.5 Points)
diastereomers
a single compound.
enantiomers
conformational isomers
meso forms
25
Question
(0.5 Points)
Z-2-Butene gives meso-1,2-dibromobutane as the only product.
Bromination of alkenes is stereospecific process.
Bromination of cycloalkenes affords trans-1,2-dibromo product.
The reaction proceeds through a positively charged intermediate.
26
Question
(0.5 Points)
1R,2R-1-methyl-2-ethylcyclohexanol and 1S,2S-1-methyl-2-ethylcyclohexanol
1R,2R-1-ethyl-2-methylcyclohexanol and1S,2S-1-ethyl-2-methylcyclohexanol
1S,2R-1-ethyl-2-methylcyclohexanol and 1R,2S-1-ethyl-2-methylcyclohexanol
1S,2R-1-methyl-2-ethylcyclohexanol and 1R,2S-1-methyl-2-ethylcyclohexanol
27
Question
(0.5 Points)
IV
III
II
28
Question
(1 Point)
Identical
Diastereomers
Enantiomers
Conformational isomers
29
Question
(1 Point)
II
I and III
III
30
Question
(0.5 Points)
1,3-Diaxial
Flagpole-Flagpole
Angle strain
1,3-Diequitorial
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11/03/2022, 16:11 CY1101 (Autumn-2021-2022)-Class Test (Organic Section) 11.03.

2022 (Preview) Microsoft Forms

Duplicate this form to use as your own. Duplica

Examination Date: 11-03-2022

Start Time: 4.15 PM

End Time: 5.15 PM

More than one of these

(I) is achiral and (II) and (III) are chiral

(I) and (II) are achiral and (III) is chiral

(I) is chiral and (II) and (III) are achiral

(I) and (II) are chiral and (III) is achiral

What is the necessary (minimum) condition for a molecule to show optical

Devoid of plane of symmetry

Devoid of all four element of symmetry

Rate of elimination is faster in trans-1-bromo-2-methylcyclohexane compared to cis-1-bromo-2-

trans-1-bromo-2-methylcyclohexane produces 1-methylcyclohex-1-ene as major product.

Both b and c are correct

cis-1-bromo-2-methylcyclohexane produces 3-methylcyclohex-1-ene as major product.

None of the above

Chair conformation is the most stable conformation for cyclohexane because

All of the above

no valence angle strain

They have identical NMR and IR spectra

They have identical melting point

The compound is not a meso form.

The compound has an optical purity of less than 100%.

The compound possesses only one stereogenic center.

The compound has the (R) configuration.

The compound has the (S) configuration.

None of the above

Z-2-Butene gives meso-1,2-dibromobutane as the only product.

Bromination of alkenes is stereospecific process.

Bromination of cycloalkenes affords trans-1,2-dibromo product.

The reaction proceeds through a positively charged intermediate.

1R,2R-1-methyl-2-ethylcyclohexanol and 1S,2S-1-methyl-2-ethylcyclohexanol

1S,2R-1-ethyl-2-methylcyclohexanol and 1R,2S-1-ethyl-2-methylcyclohexanol

1S,2R-1-methyl-2-ethylcyclohexanol and 1R,2S-1-methyl-2-ethylcyclohexanol

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