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Terahertz Spectroscopy For Astronomy: From Comets To Cosmology
Terahertz Spectroscopy For Astronomy: From Comets To Cosmology
Terahertz Spectroscopy For Astronomy: From Comets To Cosmology
1, SEPTEMBER 2011
(Invited Paper)
Abstract—The terahertz portion of the electromagnetic spec- bolometer imaging cameras typically adopt wavelength units
trum is perhaps the last largely-unexplored wavelength frontier (micrometers), and the devotees of Fourier Transform Spec-
for astronomical observations. It is also one of the most diagnostic, trometers and laboratory astrochemistry inevitably speak in
harboring spectral signatures of ions, atoms, and molecules that
are central to our understanding of the composition and origin wavenumbers cm . New researchers in terahertz astronomy,
of the Solar System, the evolution of matter in our Galaxy, and particularly from radio or optical regimes, often find the lingual
the star formation history of galaxies over cosmic timescales. In partitioning of the field practically schizophrenic.
this brief overview, specific astronomical applications of terahertz Fortunately, the ions, atoms and molecules that permeate the
spectroscopy will be highlighted with examples of current hetero- Universe do not harbor preferences for dimensional units. How-
dyne capabilities, and projection of future astronomical demands
upon terahertz instrumentation. ever, it is clear many of the most diagnostic and luminous spec-
tral signatures of these elemental species lie at terahertz frequen-
Index Terms—Extragalactic astronomy, galactic astronomy, gas
cies. These spectral lines are signposts of star and planet forma-
spectroscopy, heterodyne instruments.
tion, the evolution of matter in galaxies, the rich astrochemistry
of interstellar clouds, even the prebiotic building blocks of life.
I. INTRODUCTION Furthermore, the reprocessing of visible and ultraviolet light by
dust grains in interstellar clouds makes the continuum emission
T ERAHERTz (THz) radiation, which we will loosely of star forming regions, circumstellar (pre-planetary) disks,and
consider 0.5–5 THz (600–60 micrometers wavelength), entire galaxies peak at terahertz frequencies. This continuum
is one of the last regions of the electromagnetic spectrum which emission is often comparable to, if not significantly larger than,
remains largely unexplored. This is partly due to the opacity of starlight directly generated at visible wavelengths. The spectro-
the Earth’s atmosphere at these frequencies and partly due to the scopic signatures of pivotal atoms and molecules, coupled with
difficulty constructing terahertz detectors, spectrometers, and bright continuum emission, leads to a rich spectrum of emission
telescopes. Nestled between traditional radio astronomy at cm- and absorption lines which is uniquely diagnostic of a wide va-
and mm-waves using heterodyne receivers, and the bolometer riety of astrophysical phenomena (Fig. 1).
and photoconductor detectors of infrared astronomy, the tera- Table I reflects a sample of important atomic and molecular
hertz regime is a technological hybrid; a confluence that often species at terahertz frequencies, along with their observability
necessarily inherits the most difficult aspects of both worlds. from the ground, airborne, and space platforms. They encom-
Thus, terahertz telescopes are often built in the style of radio pass the fine structure transitions of elemental ions and atoms,
telescopes but with optical figure requirements akin to infrared particularly those of carbon, nitrogen and oxygen; the ground
telescopes. The sensitivity of terahertz telescopes hinges deli- state transitions of pivotal light diatomic molecules, particularly
cately on the water vapor content of the atmosphere above the hydrides; and the low-frequency vibrational modes of heavy
telescope, as it does for the infrared. Heterodyne receivers are molecules.
used for high resolution spectroscopy as at radio wavelengths, While the breadth of terahertz spectroscopy encompasses
but the special challenges of fabricating submillimeter-scale both high resolution heterodyne measurements using coherent
quasioptical and waveguide structures, in addition to THz detectors and gratings, Fabry-Perot and Fourier Transform
local oscillator sources, are both extreme and unique.Even the spectrometers using incoherent detectors, this review will
units in which terahertz astronomers speak reflect this unusual tend to focus on heterodyne examples where they are most
conglomeration of overlapping instrumentation—while hetero- applicable.
dyne spectroscopists speak in units of frequency (GHz or THz),
II. SOLAR SYSTEM
A. Planetary Atmospheres
Manuscript received April 01, 2011; revised June 01, 2011; accepted June 01,
2011. Date of current version August 31, 2011. The remote sensing of planetary atmospheres such as Venus,
The author is with the Steward Observatory, University of Arizona, Tucson, Mars, and the Jovian planets probes and illuminates the per-
AZ 85721 USA (e-mail: ckulesa@email.arizona.edu).
tinent physical and chemical processes, just as passive THz
Color versions of one or more of the figures in this paper are available online
at http://ieeexplore.ieee.org. soundings on Earth are diagnostic of the telluric environment.
Digital Object Identifier 10.1109/TTHZ.2011.2159648 Terahertz observations play an especially important role in
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KULESA: TERAHERTZ SPECTROSCOPY FOR ASTRONOMY: FROM COMETS TO COSMOLOGY 233
TABLE I
SAMPLE OF IMPORTANT THz LINES
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234 IEEE TRANSACTIONS ON TERAHERTZ SCIENCE AND TECHNOLOGY, VOL. 1, NO. 1, SEPTEMBER 2011
Fig. 2. D/H ratios for objects in the Solar System. Enriched deuterium abundances are the result progressive isotopic exchange between deuterium rich interstellar
species and protosolar H . Figure from [3].
formation mechanisms for the outer planets with the chemical later with the Odin satellite [23]–[25]and both ortho- and para-
history of comets and chondrules remains a challenging goal. forms are now observed using the HIFI instrument on the
Herschel Space Observatory [3], [26].
B. Cometary Atmospheres The spatial distribution of cometary gas production, particu-
Comets spend the bulk of their existence in the cold outer larly water, is difficult to study from the ground, as cometary nu-
reaches of the Solar System, and therefore have not undergone clei are intrinsically small and generally unresolved. Terahertz
considerable thermal processing. As such, they represent our instruments are therefore deployed on spacecraft designed to ex-
best clue to the physical conditions and chemistry of the early plore comets during close flybys or extended orbital periods.
Solar System. Upon entering the inner Solar System, they re- One example is the Microwave Instrument for the Rosetta Or-
lease volatile species that yield direct measurements of their biter (MIRO) on board ESA’s Rosetta spacecraft, destined to in-
composition. In the absence of direct analysis of cometary mate- tercept and orbit Comet 67P/Churyumov-Gerasimenko in 2014.
rial, spectral line emission is the most useful technique to study With a microwave and terahertz spectrometer, it will diagnose
the physical and chemical conditions of cometary atmospheres, water production sites and evolution with kilometer-scale reso-
and their relation to other bodies in the Solar System. The rela- lution [27].
tive strengths of different lines from a given species can be used
to derive the gas temperature, whereas the shape of the spectral III. GALACTIC ECOLOGY
lines indicates the outgassing pattern, the line width indicates
the outgassing velocity. Knowledge of the molecular excitation A. The Life Cycle of Interstellar Matter
and radiative transfer yields an estimate of the total column den- The evolution of galaxies is determined to a large extent by
sity of the species, and hence an absolute outgassing rate. the life cycles of interstellar clouds, as shown in Fig. 3. The
About two dozen species have been detected in cometary at- interstellar medium in the Galaxy is a patchy, clumpy medium
mospheres, ranging from simple diatomics like CO, CS, C , hy- that encompasses extremes of temperature and a wide range of
drocarbons like CH , C H and C H , whose spectra lie in the densities [28].
infrared, and complex species such as formic acid, formamide, Interstellar clouds play a central role in cosmic evolution;
methyl formate and ethylene glycol [17], [18] and many other they are simultaneously the sites of formation of all stars and
spectral lines that are as yet unidentified. planets, and the reservoirs of material that has been processed
Among the most important and abundant of these species is through previous generations of stars. Interstellar clouds can
the water molecule H O . Water molecules in cometary atmo- be classified as either diffuse or dense. Diffuse clouds feature
spheres are excited via collisions with other molecules and ra- gas densities in the range of 10–1000 particles/cm and tem-
diative pumping of the fundamental vibrational levels by the peratures of 50–100 K. The gas is mainly comprised of atomic
solar infrared flux. However, because low-excitation water lines hydrogen, which is detectable via the 21 cm spin-flip transi-
are absorbed by water molecules in the Earth’s atmosphere, tion and provides the observational basis for current models of
water vapor production is often indirectly estimated through a multiphase Galactic interstellar medium (ISM). However, its
ground-based observations of its photodissociation product, the emission is insensitive to gas density and does not always dis-
OH radical [19], and water high vibrational bands [20]. criminate between atomic clouds and the warm, tenuous (
Direct measurement of the water production rate is there- K, cm ) neutral and ionized medium that is
fore advantageous. The ortho-water transition at thought to pervade the Galaxy [29].
557 GHz and the para-water transition at 1113 GHz Although molecular interstellar clouds are among the coldest,
are among the strongest lines in cometary comae, but generally least energetic objects in astronomy, they depend upon interac-
must be observed from space. The 557 GHz transition has tions with high energy photons and cosmic rays for much of
been observed directly using heterodyne techniques by the their internal heating and chemical activity. They are largely
Submillimeter Wave Astronomical Satellite (SWAS) [21], [22], comprised of molecular hydrogen and atomic helium, neither
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KULESA: TERAHERTZ SPECTROSCOPY FOR ASTRONOMY: FROM COMETS TO COSMOLOGY 235
Fig. 5. Color image of HI 21 cm emission from Deul & van der Hulst (1987)
with catalog sources overlaid. All molecular clouds lie in regions of H I over-
density. The area of the molecular cloud has been scaled to represent the relative
masses of the clouds. The coincidence of molecular clouds with HI overdensity
is evidence that clouds form out of the atomic gas. Caption and figure from [35].
Fig. 3. Sketch of the various stages in the life cycle of interstellar clouds.
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236 IEEE TRANSACTIONS ON TERAHERTZ SCIENCE AND TECHNOLOGY, VOL. 1, NO. 1, SEPTEMBER 2011
Fig. 7. Spectrum of the Orion KL hot core from the Herschel HEXOS key program. The strongest lines are labeled. Figure from [45].
of diffuse clouds in a sample characterized by C and HI emis- toward the Orion KL hot core as observed by the HEXOS key
sion but without CO demonstrates the presence of a dignificant program is shown in Fig. 7.
diffuse warm, dark H component [39]–[41] that had been sug- 1) Light Hydrides: The simplest components of interstellar
gested by previous work [42], [43]. The diversity of clouds that chemistry, diatomic hydrides and their ions ( H and H with
may be disentangled along even a single line of sight is nothing C, N, O) have received remarkably little observational
short of spectacular. While “GOT C+” now demonstrates what study, since their rotational ground state lines generally lie at
can be accomplished by combining C emission with CO and THz frequencies and frequently outside the atmospheric win-
HI maps, it is limited to 900 individual lines of sight through the dows observable from the ground. Nevertheless, their impor-
Galaxy, summing to less than 0.1 square degree of sky. Fully tance to chemistry is profound, and major puzzles remain for
sampled two-dimensional maps in C and C must await dedi- even simple chemical pathways. For example, the molecular
cated survey facilities at THz frequencies. Two such telescopes ion CH is only formed by the highly endothermic reaction
to begin operations in the next year from Antarctica are the 80 C H K CH H. At the cold temperatures of
centimeter aperture Stratospheric Terahertz Observatory (STO) interstellar clouds, one would expect very little CH to form,
[44] and the 60 centimeter aperture High Elevation Antarctic but it remains one of the more abundant ions. The superthermal
Terahertz (HEAT) telescope. These surveys will connect the distribution of energy required for achieve the observed abun-
molecular cloud component with the atomic diffuse interstellar dance can perhaps be explained by invoking the dissipation of
medium, illuminating the origin of molecular clouds and the turbulent energy in molecular clouds [46]. Nevertheless the high
origin of turbulence in the cold ISM. abundance of CH is unsettling; is the puzzle related to un-
known chemistry, or undiscovered physics of the structure of
B. Astrochemistry of Star Forming Regions interstellar clouds, perhaps between the macroscopic and mi-
croscopic scales?
Astrochemistry is the interdisciplinary application of atomic Similarly, the OH molecule is extremely pervasive; it is a
and molecular physics to the quantitiative study of astronomical chemical tracer of disturbed molecular gas, and the terahertz
objects. It is fundamentally driven by a synergistic interplay be- portion of the spectrum in which its ground state may be probed
tween modeling, observation, and laboratory work. While the demonstrates a rich mixture of absorption and emission spectra.
origins of astrochemistry took root in the detections of the first Other molecules such as CH and reactive molecular ions such as
molecules in diffuse interstellar clouds, much of the recent im- CH and CO have been detected in photon-dominated regions
petus has been on dark clouds, star forming regions, and circum- (PDRs) and may provide important insight into the interactions
stellar disks. In dark clouds alone, over 140 distinct interstellar of UV radiation with gas, dust and large molecules like poly-
molecules have been discovered to date ranging from simple di- cyclic aromatic hydrocarbons (PAHs).
atomic molecules such as H , CO and OH, to complex carbon A new renaissance in the study of light hydrides is being pro-
chain molecules like HC N. The richest spectra are usually vided by the Herschel Space Observatory, whose heterodyne
observed towards warm dense clouds where intricate species spectrometer (HIFI) provides complete coverage of the tera-
such as acetone CH CO , ethylene glycol CH OH , hertz bands from 0.5 THz to 2 THz. An example of the study of
and ethyl formate C H OCHO have been observed. To illus- numerous hydrides and their ions is depicted toward the massive
trate, a small portion of the terahertz spectrum (1.6–1.9 THz) star forming region AFGL 2591, in which CH, CH , NH, OH ,
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KULESA: TERAHERTZ SPECTROSCOPY FOR ASTRONOMY: FROM COMETS TO COSMOLOGY 237
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238 IEEE TRANSACTIONS ON TERAHERTZ SCIENCE AND TECHNOLOGY, VOL. 1, NO. 1, SEPTEMBER 2011
V. CONCLUSION: ASTRONOMICAL DRIVERS FOR FUTURE the broad range of astrophysical studies, from Solar System as-
TERAHERTZ INSTRUMENTS tronomy to the formation of stars and galaxies at high redshift.
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KULESA: TERAHERTZ SPECTROSCOPY FOR ASTRONOMY: FROM COMETS TO COSMOLOGY 239
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