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Partial - The Probability of Using Pulverized Mussel Shells
Partial - The Probability of Using Pulverized Mussel Shells
A Thesis in
Research 1
Presented to the Faculty of Industrial Technology Department
Cebu Technological University – Moalboal Campus
Moalboal, Cebu
In partial fulfillment
of the requirement for the degree
Bachelor of Science in Industrial Technology
Major in Drafting
December 2021
DEDICATION
To the workforces in the construction and masonry industry who devote their
time, efforts, and knowledge for the sake of improving infrastructures and civilization.
To the teachers, friends, and families of the researchers for giving the guidance,
Most importantly, to the Almighty Father for the knowledge and wisdom
The researchers have contributed the needed effort in this research, but it would
not have been possible without the generous and kind support of many.
The researchers would like to extend their sincerest gratitude primarily to the
The researchers would also like to express their heartfelt thanks to the parents for
The researchers express their gratitude also to their Research 1 professor, Sir
Resti Tito Villarino, for the opportunity to conduct this study and for the patience and
encouragement he portrayed. Sir Resti Villarino is, indeed generous and inspiring.
ABSTRACT
TABLE OF CONTENTS
CHAPTER I
INTRODUCTION
Brilliant discoveries continue to make life comfortable and more convenient through
latest inventions offering the best suitable services. In parallel to advancement and
modernization, the researchers intend to uncover studies that will do just that, a research
project concerning an essential material used in almost all infrastructures and building
Hollow blocks are rectangular bricks mostly used in the construction of multi-
blocks, cement blocks, and foundation blocks commonly used in compound walls. These
blocks are made from a mixture of cement, sand, and stone chips. Its presence reduces
There are many environmentalists, researchers, and students who have exerted
much needed efforts to study what mixture is suitable to increase the comprehensive
strength of hollow blocks. Some of these mixtures include soil, rice hull, plastics, broken
glass, and even coconut coir. Various related literature and studies, citing different factors
and considerations were collected, theoretically framed, and analyzed. The research study
results revealed that mussel shells contain 95%-99% calcium carbonate by weight with
fracture toughness of ~3000 times greater than that of the crystals themselves. This
application may help in fabricating new set of raw materials of producing hollow blocks
According to Varshney (2016) [1], “The first Concrete block as a replacement for
stone and wood in the building was used in the United States. The first concrete block
house built up in 1837 on Staten Island in New York. Harmon S. Palmer designed first
hollow concrete block in 1890. Palmer presented the design of hollow block in 1900 after
10 years of experimental research. Palmer’s blocks were 8-inch (20.3 cm) x 10-inch (25.4
cm) x 30-inch(76.2 cm) and they were heavy in weight. The early hollow blocks were
cast by hand and average output was about 10 blocks per hour. Now concrete blocks are
manufacturing by automated process that can make up to 2000 blocks per hour.” (p. 1)
Papadimitriou (2020) studied that [2] “The current trend in concrete engineering
is shifting towards the sustainability aspect due to the depletion of natural concrete –
making materials as well as the environmental impact arising from the utilization of these
concrete.”
and mussels have long been gathered for food by coastal communities in the Philippines,
and bivalve farming began in early 1900. The first farms were no more than a series of
bamboo poles inserted in the muddy bottom of Manila Bay in Bacoor Cavite. In May
1934, the Bureau of Fisheries and Aquatic Resources (BFAR) established a pilot oyster
farm in Binakayan, Cavite Province, Luzon, and a lucrative industry soon grew up. By
1950, about 200 ha of private farms existed in Bacoor Bay, but, in the late 1950s, mussels
appeared on the farms and threatened the industry. The response of BFAR was to initiate
farms for mussels, and the results prompted the establishment of a mussel industry that
communities. The recycling of mussel wastes in addition to hollow block mix will
contribute to the preservation of the environment by reducing the quantity of mussel shell
waste.
The utilization of pulverized mussel shells in concrete could restrain the problem
of excessive consumption of conventional materials and at the same time decrease the
amount of generated waste shells in the Asia-Pacific region. The probability of using
mussel shells as component in manufacturing hollow blocks was studied, and the results
show a great significance here in the Philippines, where increasing amounts of mussel
Natural resources of the world drastically dwindle due to the increasing demand
of natural aggregate for the construction industry. This has also degenerated the
environment and has given impetus to studies and research for sustainable development
from industrial waste such as fly ash, ground granulated blast furnace slag, bed ash has
led to sustainable materials but due to the lack of production techniques, many of the
developed and under-developed countries have not been able to use them to their
concrete, it favorably assists both the structural stability and economic viability, which
has been convincingly proved in developed countries. [3] (Prusty and Patro, 2014)
According to Reddy et al., (2014), [4] the consumption of the primary aggregate
was 110 million tonnes in the U.K. during 1960 and reached nearly 275 million tonnes in
the year 2006. Similarly, 2 billion ton-nes of aggregate are produced each year in the
United States and it is expected to increase to more than 2.5 billion tonnes by the year
2020.
It has been predicted that the demand for concrete is expected to grow to
approximately 18 billion tons a year by 2050. Such heavy demands draw attention and
preservation of natural aggregates, which are a matter of grave concern. Since aggregates
contribute about 60–80% of the volume of the concrete, effective and efficient use of
agricultural waste contributes to energy saving, conservation of natural resources and
aggregate for concrete production can be considered as one of the environmental benefits
and has shown better thermal property with the proven recognition by most of the
Giving emphasis on the above citations, the researchers decided to look for a
production. Mussel shells for a fact, embodies a good quality of concrete due to their
durable property, but still, it requires a mixture of more cement paste to make it feasible.
component in hollow blocks making, thus opening a new horizon in construction and
natural resources. In the past recent years, extreme efforts were initiated to introduce in
concrete mixing activities the by-products and wastes from various industrial,
agricultural, and other relative sources. Looking through at the fishery industry, seashell
wastes like mussel shells are available in certain regions in the Philippines and is usually
dumped in huge quantities without any reuse and proper waste regulation.
Papadimitriou et al. [2] investigated on mussel shells and its feasibility as an
aggregate replacement concrete. In their project study, the waste mussel shells were dried
and crushed into different aggregates ranging from coarse particulates to powder.
Specimens were prepared by using various types of cements (CEM I 52.5N, CEM
IV/B (P-W) 32.5N and CEM II/A-M (W-L) 42.5R) and mussel shells of different size.
Their 28-day compressive strength and elastic modulus was evaluated and compared with
the one of specimens made with compatible calcareous sand or gravel. Waste mussel
shells material showed characteristics, like limestone, that enable them to be an inert
material due to the high calcium oxide content. However, proper treatment such as
heating at high temperature and crushing to achieve appropriate fineness are desirable for
a better-quality material. It was shown that waste mussel shells could be utilized as a
partial aggregate for adequate workability and strength of concrete for non-structural
The test results also demonstrated that the aggregate fraction plays an important
role in the strength development of mussel concretes. The most impressive observation
was that mussel concretes (code named M1, M4 and M7) made with the coarser gravel
aggregate (4.76 – 12.7 mm fraction) showed strength values lower than the one of
reference concretes with much less cement content, for all types of cement. An
explanation for this result is the one proposed by Garcia et al. (2017), who stated that
the flat and flaky shape of the mussel aggregates, especially the one of the mussel
gravel, act as a barrier to the bleeding water which increases the water to cement ratio
in the downward face of the shell, resulting in a weaker bond between the two phases
obtained for the finer fraction (sand mussel concretes M3 and M6), which exhibited the
lower decrements in compressive strength and elastic modulus when cement types of
CEM I 52.5 N and CEM II/A-M (W-L) 42.5 R were used. [2] (Papadimitriou et al. 2014)
mussel concrete showed that their strength was lower than the natural aggregate
concretes. Their durability and strength are dependent on its amount in the mixture and
the cement type. Their conducted study shows that am adequate fraction of mussel shells
when mixed with a complex cement type containing pozzolan and ground limestone
one. Despite the reduction in the workability and strength, based on the studies
performed, it is suggested that mussel shells waste could still be utilized as a partial
concrete.
Another research study was conducted by a group of students which [8] aims to
develop stronger and tougher hollow blocks by using various shells. In their project
study, “The hollow block is mainly composed of shells and clay, wherein clay has been
researchers added cement to the mixture making the product more compact. Hollow
blocks from various shells and the commercial hollow blocks were set into trials to
compare each strength and ability to withstand weather. Both were stomped by different
people weighing 40kg, 50kg, and 80kg; and were poured with hot water (100 OC) and cold
water (16OC). After the trials, the researchers found out that commercial hollow block
was easily squashed into pieces unlike the study’s hollow block which is weaker in the
The student researchers proved that the hollow blocks with a mixture of 40% clay
and 60% sand seashells, from various shells, are stronger compared to the commercial
hollow blocks. The commercial hollow blocks were easily cracked into pieces unlike the
one with a mixture of different seashells. [8] “The results of the experiment show that the
hollow block is stronger when there are more crushed shells added. The mud clay and
cement react to produce alternative hollow blocks and much more when they are
combined. There is a difference in strength from the highest quantity of crushed shells in
study the effect of using mussel shells on the compressive strength and percentage of
water absorption of the bricks. The bricks were tested at the construction materials testing
center and it proved that the bricks could hold enough strength and can absorb much
water.
According to ASTM c1088 standard specification for thin veneer brick units
made from clay or shale, the compressive strength of the thin veneer bricks is not
necessary because its strength cannot be measured accurately due its thickness. But we
can conclude that the bricks with 100% mussel shell (sample 2) can have more
compressive strength than combining the mussel shell to the sand (sample 3) and bricks
with no mussel shell at all (sample 4). Therefore, using 100% and 50% mussel shell can
increase the compressive strength by 65.29% and 57.56% respectively. [6] (Manao, A.
n.d.)
Based on the studies performed, the brick with mussel shells mixture could be
concrete. Pulverized mussel shells when used as an additive in making hollow blocks can
be used both as a cement substitute and as a filler material for the formulation of non-
structural concrete. This newly formulated mixture can be applied in structures with low
strength concrete requirement. Indeed, this type of hollow blocks or concrete blocks can
be used as strengthening and infill material for confined beams. Another conceivable
service life.
Theoretical Framework
Fig. 01 is a sample framework showing the structure that can hold and support
this research study. This theoretical framework describes why there is a need for the
researchers to study the probability of using mussel shells as component in hollow blocks
making.
Fig. 01 Theoretical Framework showing the structure showing the need to study the
probability of using mussel shells in making hollow blocks.
Statement of the Problem
shells in making hollow blocks. Specifically, this study is made to answer the following
problems:
1. What would be the best feasible mussel shells mixture in making the hollow
blocks:
shells and the commercial ones that has been used for years?
Formulation of Hypothesis
The hollow blocks out from a mixture with mussel shells would be the improved
version of the commercial hollow blocks commonly used for years. It has great
comprehensive strength compared to the ordinary and commercialized ones that we have
The study entitled, “The Probability of Using Pulverized Mussel Shells (Perna
This study is significant not just for the students and the campus but also to the society.
This chosen study also helps the society provide an efficient idea on how to deal
agricultural wastes like mussel shells as a composite material in making hollow blocks
instead of simply disposing them. Empty mussel shells cannot be easily decomposed and
would take for up to 20 years. This would certainly harm the atmosphere, environment,
and the people when burned. Thus, there is a great need to make a move on how to
This research also helps the construction industry to produce products with very
good comprehensive strength. Hollow blocks with improved quality play an important
bridges, etc. Even more, this research study also intends to gather a thorough data
analysis that may serve as reference point of information for material’s appropriateness.
Furthermore, this study can be used as basis in building houses for pets, fences,
The study was conducted to determine the feasibility of using mussel shells as a
composite material in making hollow blocks and would either produce a product with
comprehensive strength or one with weaker properties. The researchers limit the results
on having only four experimental set-ups: three hollow blocks with varying composition
of mussel shells (40-60, 50-50, and 60-40) respectively, and one commercial hollow
block. Justifying why these percentage was used is not part of its scope.
The researchers will not conduct the experiment inside the school premises, but
rather done outside the school grounds due to the present pandemic situation. The results
only limit to home-made hollow blocks, with the help of professionals in hollow blocks
making industry.
Definition of Terms
These are some of the terminologies used by the researchers in this study:
Biorefinery -
Cement –
Compressive Strength -
Hollow blocks - are rectangular bricks mostly used in the construction of multi-
Mussel Shells – are wedge shaped or asymmetrical shells usually longer than the
wide. These wide shells come into two halves that are close and inside contain the
mussel meat.
Waste Valorization -
CHAPTER II
This chapter is all about the concept, research studies, and literatures regarding
with this research study. The concepts are arranged revolving major topics explained in
this study.
have been living in settled communities, solid waste, or garbage, has been an issue, and
modern societies generate far more solid waste than early humans ever did. Daily life in
industrialized nations can generate several pounds of solid waste per consumer, not only
directly in the home, but indirectly in factories that manufacture goods purchased by
Arroyo et al. (2005) [10] conducted a study on the feasibility of a mollusk shell–
based adhesive as a substitute for mortar. The mollusks shell-based adhesive was made
from combining powdered mollusks shells and tackifier in an elastomer and toluene
mixture. (DOST Report, Bicutan, 2005) [11]. In southern coast of Korea, enormous
amount of oyster-shell waste has been illegally disposed at oyster farm sites along the
Mussel Shells
In the present project the waste mussel shells were dried and crushed into
prepared by using various types of cements (CEM I 52.5N, CEM IV/B (P-W) 32.5N and
CEM II/A-M (W-L) 42.5R) and shells of different size. Their 28-day compressive
strength and elastic modulus was evaluated and compared with the one of specimens
made with compatible calcareous sand or gravel. Waste mussel shells material showed
characteristics, like limestone, that enable them to be an inert material due to the high
calcium oxide content. However, proper treatment such as heating at high temperature
and crushing to achieve appropriate fineness are desirable for a better-quality material. It
was shown that waste mussel shells could be utilized as a partial aggregate for adequate
workability and strength of concrete for non-structural purposes. [2] (Papadimitriou et al.
2014)
[16] A mussel is any bivalve mollusk, especially and edible marine bivalve of the
family Mytiliadae and a freshwater clam of the family Unionidae. The byssal threads of
the mussel are so adhesive that they even cling to Teflon; scientists are now trying to
develop a mussel-based adhesive for use in eye surgery. The oyster creates its own
carbonate. The remainder of the shell is made up of organic material and trace amounts of
manganese, iron, aluminum, sulfate and magnesium. The structure or the shell of a
mussel consists or four distinct layers: periostracum, a tissue of organic material called
conchiolin, secreted by the cells located near the edge of the mantle. The periostracum is
poorly developed in crassostrea virginica and it is not round in old shells, prismatic layer,
which is made up of bricklike prism units. Each prism consists or calcite crystals laid in a
foliated sheets or calcite laid between thin membranes of conchiolin. This layer is
interrupted by 6 soft chalky deposits which consist of amorphous material. This layer
makes up the major part of the shell, hypostracum layer is made or shell material under
the abductor muscle. In the crassostrea virginica the layer is pigmented and consists of
aragonite. As the oyster grows the adductor muscle increases in size and the new areas or
Shells grow by the accretion of material secreted at their edges. The rings on the
outer surfaces or a bivalve shell represent the contours of the shell at different ages. Rings
are common to all bivalves’ shells. Depending on the shape of the shell, the rings are
either circular or oval with a common point or origin at the extreme dorsal side near the
umbo. The rate of growth along the edge of the shell is not uniform and may actually
change direction in response to environmental factors The mantle of the mussel; the
animal inside the shell is covered by a mantle. The principal function of the mantle is the
formation or the shell and its calcification. It is made up of soft and freshly tissue. The
structure of the mantle consists of a sheet of connective tissue containing muscles, blood
vessels, nerves and it is covered on both sides by epithelium. The mantle receives sensory
stimuli and conveys them to the nervous system and aid in the shedding and dispersal of
eggs. It also participates in respiration, stores reserve materials, secretes large quantities
of mucous and aids in excretion. The most obvious components of the mantle are the
radial muscles, blood vessels and nerves. The radial muscles are large bands of fibers
which extend almost the entire width of the mantle. The radial muscle contracts and pulls
the entire mantle inside and throws its surface into ridges. The mantle’s blood vessel is
the circumpallial artery which sends out many branches; the common pallial artery, and a
large pulsating vessel in the anteriorventral part of 7 the mantle called the accessory
heart. The nerve provides communication. Close nerve contact is maintained between the
muscles and the organs of the mantle through a fine nerve network.
Calcium Carbonate
[17] An important use of calcium carbonate is in the building industry. Due to its
wide abundance and properties, it has been used as a building substance since ancient
times. For example, the Egyptians used limestone for building their pyramids. Another
notable monument made up of white marble is the Taj Mahal in India. Today, calcium
Besides construction, calcium carbonate is also used in other industries like paint, plastic,
rubber, ceramic, cement, glass, steel, oil refining, iron ore purification and bio rock
correcting compound in swimming pools. As per statistics, about 200 tons of chalk is
used every year. Calcium carbonate is the most preferred mineral in the paper industry,
used for filling and coating paper. It helps in production of the best quality printing
papers. Since calcium is essential for healthy bones and teeth, calcium carbonate is used
ailments related to calcium deficiency, for example, osteoporosis and acidity problems.
Calcium supplements, made from calcium carbonate, are prescribed in various doses as
per the requirement of the patients. Calcium carbonate is used in homeopathy, production
component of garden lime, also known as agricultural lime, which is used for neutralizing
soil. Acidic soils can be treated with garden lime to enhance 8 the soil quality. Garden
lime when added in soil acts as a calcium source for plants as well as increases the pH
and water retaining capacity of acidic soils. Calcium carbonate sources such as limestone
and chalk, along with other chemical compounds are used in preparation of garden lime.
drinking water, desulphurisation of flue gas and wastewater treatments. Water bodies
affected by acid rain can be neutralized by using calcium carbonate. However, care must
common substance found in rocks in all parts of the world and is the main component of
shells of marine organisms, snails, coal balls, pearls, and eggshells. Calcium carbonate is
the active ingredient in agricultural lime and is usually the principal cause of hard water.
AlJabri K. S. et al., (2009) [13] makes the block with waste materials: vermiculite
and polystyrene which were used as light weight aggregates and cement kiln dust (CKD)
which was the partial replacement for cement. The result shows that the lightweight
concrete blocks manufactured from polystyrene had low thermal conductivity than
vermiculite and ordinary concrete blocks and the addition of up to 15% CKD as cement
Kaosol T. (2010) [14] has made study on the reuse of concrete waste as crushed
stone for hollow concrete masonry units. The main objective was to increase the value of
the concrete waste, to make a sustainable and profitable disposal alternative for the
concrete waste. Attempts were made to utilize the concrete waste as crushed stones in the
concrete mix to make hollow concrete blocks. Various percentages of crusted stones have
been tried the amount (i.e. 0%, 10%, 20%, 50% and 100%). From the results they found
concrete waste can used to produce hallow concrete block masonry units.
Maroliya M. K. (2012) [15] found that the crack patterns developed in the
structural elements such as wall and the strength of wall constructed with hollow concrete
block gives the less strength as compared to brick masonry, but cost of construction is
very less.
The construction sector requires the use of vast quantities of raw/virgin materials
derived from natural resources. However, in the last decade intensive efforts have been
made to introduce in concrete mixture activities, by products and wastes from various
industrial, agricultural, or other alternative sources. Originating from the fishery industry,
seashell waste, such as oyster shells, mussel shells, and scallop shells, among others, is
without any reuse value. The characteristics of different types of seashell waste, as well
as the effects of incorporating the seashells on the fresh and hardened properties of
concrete, are discussed. The material characteristics suggest that, like limestone, seashell
waste could be an inert material due to the high calcium oxide content. However, proper
fineness are desirable for a better-quality material. It is shown in past research that while
seashell waste has been used as a replacement for both cement and aggregate, there is still
a lack of investigation concerning its durability, as well as the actual influence of seashell
powder as a cement replacement material. Despite the reduction in the workability and
strength, based on the review, it is suggested that seashell waste could still be utilized as a
strength of concrete for nonstructural purposes. The current trend in concrete engineering
is shifting towards the sustainability aspect due to the depletion of natural concrete-
making materials as well as the environmental impact arising from the utilization of these
concrete. For this purpose, several studies have been carried out to utilize wastes
originating from different sources, such as construction and demolition waste [3,4], and
from a variety of industries including steel [5], agricultural [6–8], glass [9], and rubber
[10], among others. These wastes are available in huge volume in certain countries, and,
hence, have the potential to be reused in large-scale concrete production. The utilization
of waste materials in concrete could moderate the problem of excessive consumption of
conventional materials as well as reduce the amount of waste shells generated. In the
present project the feasibility of using mussel shells as aggregates in the production of
concrete was investigated, the results of the study are of particular importance for Greece
and especially the area of Thessaloniki, where vast amounts of mussel shells are disposed
under no regulation near RAMSAR and NATURA 2000 protected site of Axios. The
investigation of reuse or utilization of waste shells can attribute to the decision making
upon the sustainable management practices in the specific area. [2] (Papadimitriou et al.
2014)
CHAPTER III
METHODOLOGIES
Research Method
component in hollow blocks making, the experimental method was used in this study.
conclusions and can be conducted based on some of the findings from previous related
forms of research. In this kind of research, the investigations manipulate the experimental
variables.
Research Design
To expound the purpose of this study, the researchers gathered several reviews of
related studies involving mussel shells, shell waste management, hollow blocks mixed
Aside from related literatures, books, and other written materials, the researchers
used a survey questionnaire for the study which in Google form. Google forms provide a
fast way to create online survey, and the responses are collected in an online spreadsheet.
The survey questions will be answered from almost any web browser – including mobile
smartphone and tablet browsers using their email addresses. Their responses will be
automatically recorded. The researchers can access the survey questionnaire through the
Research Procedures
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