West Visayas State University

Luna St., La Paz, Iloilo City

College of Education

Unit Test 4

in CHEM 209A

Xzylle Pearl C. Jerez

Name: ______________________ 1-D
Section: _________ Score: _________

1. Calculate the molar H+ ion concentration of the solution that has a pH of 7.50.
Given: pH = 7.50

Asked: [H+]

Solution:

[H+] = antilog (-pH)

[H+] = 10-7.50 = 3.16 x 10-8 M

Answer: = 3.16 x 10-8 M

2. Calculate the p-functions for each ion in a solution of 0.200 M barium bromide.
Given: 0.200 M Ba+ and 0.200 M Br-

Asked: p- functions of Ba+ and Br-

Solution:

pBa+ = -log [Ba+] pBr- = -log [Br-]

pBa+ = -log [0.200] = 0.699 pBr- = -log [0.200] = 0.699

Answer: 0.699
3. Sea water contains an average of 1.08 x 103 ppm of Na+ and 270 ppm of SO42- .
Calculate

a. the molar concentrations of Na+ and SO42- given that the average density of sea
water is 1.02 g/mL.

Given: density of sea water = 1.02g/ml

1.08 x 103 ppm of Na+ and 270 ppm of SO42-.

Find: M Na+ and SO42-

Solution:
1 g Na
Mol Na+ =1080 mg Na x x 1 mol Na = 0.04695652174 g Na+
1000 mg Na 23 g Na
m 1000 g
Volume of sea water = = = 980 mL or 0.980 L
d 1.02 g/mL
0.0469565214 g Na
M Na+= = 0.0479 M
0.980 L

1 g SO42-
x 1 mol SO2-4 = 0.0028125 g SO42-
2-
Mol SO42- = 270 mg SO42- x
1000 mg SO4 2-
96 g SO4
m 1000 g
Volume of sea water = = 1.02 g/mL = 980 mL or 0.980 L
d
0.0028125 g SO42-
M SO42- = = 0.0029 M
0.980 L

b. the molal concentrations of Na+ and SO42-.

Given:

1.08 x 103 ppm of Na+ and 270 ppm of SO42-.

Mol of Na+ = 0.04695652174 g Na+

Mol of Mol SO42- = 0.0028125 g SO42-

Find: the molal concentrations of Na+ and SO42-

Solution:
0.04695652174 g Na+
m Na+ = = 0.047 m
1 kg
(1.02 g /mL) (980 mL) ( )
1000 g

0.0028125 g SO42-
m SO42- = = 0.0028 m
1 kg
(1.02 g /mL) (980 mL) ( 1000 g
)

c. the pNa and pSO4 for sea water

Given: molar concentration of Na+ = 0.0479 M

molar concentration of SO42- = 0.0029 M

Find: the pNa and pSO42- for sea water

Solution:

pNa+ = -log [Na+] pSO42- = -log [SO42- ]

pNa+ = -log [ 0.0479] = 1.32 pSO42- = -log [0.0029 M] = 2.54

4. A solution was prepared by dissolving 8.90 g of KCl • MgCl2 • 6H2O in sufficient

water to give 1500 mL. Calculate

a. the molar concentration of KCl • MgCl2 • 6H2O in this solution.

Given:

m of KCl • MgCl2 • 6H2O = 8.90 g

v = 1500 ml

Find: molar concentration of KCl • MgCl2 • 6H2O in this solution.

Solution:

1 mol KCl · MgCl2 · 6H2O 1

M = 8.90 g of KCl • MgCl2 • 6H2O x x
277.85 g KCl · MgCl2 · 6H2O 1.5 mL x 1L
1000 mL
= 21.354 M

b. the molar concentration of Cl-.

Given:

molar mass = 35.45 g/mol

v = 1.5 mL

Find: the molar concentration of Cl−.

Solution:
35.45 mol Cl
3 moles Cl
1 mol Cl
M Cl- = =70.90 M
1
1.5 mL x 1L
1000 mL

c.the ( m
v ) percentage of KCl • MgCl2 • 6H2O.

Given:

m = 8.90 g KCl • MgCl2 • 6H2O

V = 1500 mL

m
Find: the ( v ) percentage of KCl • MgCl2 • 6H2O

Solution:

m 8.90 g KCl • MgCl2 • 6H2O

% ( v ) KCl • MgCl2 • 6H2O= x 100 = 0.59%
1 500 mL sol’n
d. the number of millimoles of Cl− in 50.0 mL of this solution.

Given: V = 50.0 mL

M Cl- = 1.60 M

Find: mmol of Cl-

Solution:

n
M= v

Millimoles of Cl- = Mv

Millimoles of Cl- = 1.60 x 103 mmol x 50 mL

mL

Millimoles of Cl- = 8.0 x 104 mmol

e. ppm K+

Given:

M = 2.135 M of KCl • MgCl2 • 6H2O

Molar mass K+ = 39.10g/mol

Find: ppm K+

Solution:

1 mol K+
[ K+ ] = KCl • MgCl2 • 6H2O x
1 mol KCl • MgCl2 • 6H2O
1 mol K+
= 2.135 M of KCl • MgCl2 • 6H2O x
1 mol KCl • MgCl2 • 6H2O

= 2.135 M K+

2.135 mol K+ 39.10 g K+ 1000 mg

ppm K+ = x x = 83.48 x 104 ppm K+
L K+ 1 mol K+ 1g