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MANZIL
Coordination Compound DPP-01

1. The correct IUPAC name of the complex two moles of AgCl as a precipitate. The
is: formula of this complex would be
H3C OH (A) [Co(NH3)4(NO2)Cl] [(NH3)Cl]
(B) [Co(NH3)5Cl] [Cl NO2]
C=N (C) [Co(NH3)5(NO2)]Cl2
CoCl2 (D) [Co (NH3)5] [(NO2)2Cl2]
C=N
H3C OH 5. From the stability constant (hypothetical
(A) Dichloridodimethylglyoximecobalt values), given below, predict which is the
(II) most stable complex?
(B) Bis(dimethyglyoxime) (A) Cu2+ + 4NH3 [Cu(NH3)4]2+, K = 4.5×
dichloridocobalt (II) 1011
(C) Dimethylglyoximecobalt(II) chloride (B) Cu2+ 4CN– [Cu(CN)4]3–, K = 2.0 ×
(D) Dichlorido(dimethylglyoximato) 1027
cobalt(II) (C) Cu2+ + 2en [Cu(en)2]2+, K = 3.0 ×
1015
2. A co-ordination complex has the formula (D) Cu2+ + 4H2O [Cu(H2O)4]2+,K = 9.5 ×
PtCl4.2KCl. Electrical conductance 108
measurements indicate the presence of
three ion in one formula unit. Treatment 6. Which is not a p-bonded complex?
with AgNO3 produces no precipitate of (A) Zeise's salt (B) Ferrocene
AgCl. What is the co-ordination number (C) bis(benzene) chromium
of Pt in this complex? (D) Tetraethyl
(A) 5 (B) 6
(C) 4 (D) 3 7. What is wrong about the compound K [Pt
(h2 – C2H4) Cl3]?
3. Which of the following complexes (A) It is called Zeise's salt
produces three moles of silver chloride (B) It is p bonded complex
when its one mole is treated with excess (C) Oxidation number of Pt is +4
of silver nitrate? (D) Four ligands surround the platinum
(A) [Cr(H2O)3Cl3] atom
(B) [Cr(H2O)4Cl2]Cl
(C) [Cr(H2O)5Cl]Cl2 8. Crystal field stabilization energy for high
(D) [Cr(H2O)6]Cl3 spin d4 octahedral complex is:
(A) – 0.6 D0 (B) – 1.8 D0
4. A coordination compound of cobalt has (C) – 1.6 D0 (D) – 1.2 D0
the molecular formula containing five
ammonia molecules, one nitro group and 9. [(NH3)5Co–O–O–Co(NH3)5]+4
two chlorine atoms for one cobalt atom. Brown
One mole of this compound produces [(NH3)5Co–O–O–Co(NH3)5]+5
three moles of ions in an aqueous Green

solution. The aqueous solution on The magnetic moment of green complex

treatment with an excess of AgNO3 gives is 1.7 BM & for brown complexes
magnetic moment is zero. (O–O) is same
in all respect in both the complexes. The

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O.S. of Coin brown complex & green (A) it is a low spin complex
complex respectively are- (B) it is diamagnetic
(A) III III
𝑏𝑟𝑜𝑤𝑛
& IV III
𝑔𝑟𝑒𝑒𝑛
(C) it shows geometrical isomerism
III II (D) (A) and (B) both
(B) 𝑏𝑟𝑜𝑤𝑛
& III III
𝑔𝑟𝑒𝑒𝑛
III III
(C) 𝑏𝑟𝑜𝑤𝑛
& III
𝑔𝑟𝑒𝑒𝑛
II
17. Which of the following pairs will show
III IV
(D) 𝑏𝑟𝑜𝑤𝑛
& III III
𝑔𝑟𝑒𝑒𝑛 the same magnetic moment (‘spin only’)?
(A) [Cr(H2O)6]3+ and [Fe(H2O)5NO]2+
10. Which one of the following will be able to (B) [Mn(CN)6]4– and [Fe(CN)6]3–
show cis-trans isomerism? (C) [Ni(CO)4] and [Zn(NH3)4]2+
(A) Ma3b (B) M(AA)2 (D) All of these
(C) M(AB)(CD) (D) Ma4
18. Which of the following complex ion is not
11. Which of the following compounds show expected to absorb visible light?
optical isomerism? (A) [Ni(H2O)6]2+ (B) [Zn (NH3)4]2+
1. trans - [Co(NH3)4 Cl2]+ (C) [Cr(NH3)6]3+ (D) [Fe(H2O)6]2+
2. trans - [Co(en)2Cl2]+
3. cis - [Co(en)2Cl2]+ 19. Which of the following statements is not
4. [Co(en)3]3+ true?
Select the correct answer using the codes (A) MnCl ion has tetrahedral geometry
given below: and is paramagnetic.
(A) 1 and 2 (B) 2 and 3 (B) [Mn(CN)6]2– ion has octahedral
(C) 3 and 4 (D) 1, 3 and 4 geometry and is paramagnetic.
(C) [Cu(CN)4]3– has square planar
12. The complex that exhibits Co-ordination geometry and is diamagnetic.
isomerism is (D) [Ni(Ph3P)2Br3] has trigonal
(A) [Cr(NCS)(H2O)5]2+ bipyramidal geometry and is
(B) [Cr(NH3)6]Cl3 paramagnetic.
(C) [Cr(NH3)6][Co(CN)6]
(D) [CoCI2(NH3)4]Cl.H2O 20. The complexes given below show:
Cl Cl Cl
13. The strong field ligand is: Pt and
Pt
(A) SCN– (B) NO2
–
(C) I (D) S2– (C2H5)3P Cl P(C2H5)3

14. The electronic spectrum of [Ni(H2O)6]++ (C2H5)3P Cl Cl

shows a band at 8500 cm–1 due to d-d
transition. [Ph4As]2[NiCl4] will have such Pt Pt
a transition in cm–1 at Cl Cl P(C2H5)3
(A) 3778 (B) 8500 (A) optical isomerism
(C) 4250 (D) 850 (B) co-ordination isomerism
(C) geometrical isomerism
15. The metal carbonyl which is paramagnetic (D) bridged isomerism
is
(A) Ni(CO)4 (B) V(CO)6 21. Which one of the following high-spin
(C) Cr(CO)6 (D) Fe(CO)5 complexes has the largest CFSE (Crystal
field stabilization energy)?
16. [Fe(en)2(H2O)2]2+ + en ® complex(X). (A) [Mn(H2O)6]2+ (B) [Cr(H2O6)]2+
The correct statement about the complex (C) [Mn(H2O)6]3+ (D) [Cr(H2O)6]3+
(X) is:

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22. Which kind of isomerism is shown by the (A) sp3, sp3 (B) sp3, dsp2
complex [Co(NH3)5(ONO)]SO4? (C) dsp2, sp3 (D) dsp2, sp2
1. Ionisation isomerism
2. Linkage isomerism 26. The geometry and magnetic moment of
3. Geometrical isomerism the complexes [NiCl4]2– and [PdCl4]2–
4. Optical isomerism respectively are:
(A) 1, 2, 3 and 4 are correct (A) tetrahederal, square planar; 2.83, 0
(B) 1, 3 and 4 are correct only (B) tetrahedral, tetrahedral; 2.83, 2.83
(C) 1 and 2 are correct only (C) square planar, tetrahedral; 0, 2.83
(D) 2, 3 and 4 are correct only (D) square planar, square planar : 0, 0

23. The correct structure of 27. An excess of AgNO3 is added to 100 mL

ethylenediaminetetraacetic acid (EDTA) of a 0.01M solution of
is: dichlorotetraaquachromium (III) chloride.
The number of moles of AgCl precipitated
HOOC–CH2 CH2–COOH
would be:
N–CH=CH–N (A) 0.002 (B) 0.003
(A)
HOOC–CH2 CH2–COOH (C) 0.01 (D) 0.001
HOOC COOH
28. The value of 'spin only' magnetic moment
(B) N–CH2–CH2–N for one of the following configurations is
HOOC COOH 2.84 BM. The correct one is:
HOOC–CH2 CH2–COOH (A) d4 (in strong field ligand)
(B) d4 (in weak field ligand)
(C) N–CH2–CH2–N
(C) d3 (in weak as well as strong field
HOOC–CH2 CH2–COOH
ligand)
(D) (D) d5 (in strong field ligand)
COOH
HOOC – CH2 CH2 H 29. Which one of the following has a square
N–CH–CH–N planar geometry?
(A) [NiCl4]2– (B) [PtCl4]2–
H CH2 CH2 – COOH 2–
(C) [CoCl4] (D) [FeCl4]2–
HOOC (At. no. Co = 27, Ni = 28, Fe = 26, Pt =
78)
24. The spin only magnetic moment value (in
Bohr magneton units) of Cr(CO)6 is: 30. In which of the following octahedral
(A) 0 (B) 2.84 complexes of Co (at no. 27), will the
(C) 4.90 (D) 5.92 magnitude of 0 be the highest?
(A) [Co(C2O4)3]3– (B) [Co(H2O)6]3+
25. Both [Ni(CO)4] and [Ni(CN)4]2– are (C) [Co(NH3)6]3+ (D) [Co(CN)6]3–
diamagnetic. The hybridisation of nickel
in these complexes, respectively, are:

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ANSWERS KEY
1. (A) 9. (A) 17. (D) 25. (B)
2. (B) 10. (C) 18. (B) 26. (A)
3. (D) 11. (C) 19. (C) 27. (D)
4. (C) 12. (C) 20. (C) 28. (A)
5. (B) 13. (B) 21. (D) 29. (B)
6. (D) 14. (A) 22. (C) 30. (D)
7. (C) 15. (B) 23. (C)
8. (A) 16. (D) 24. (A)

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