ANNUAL EXAMINATION (2021-22)

CHEMISTRY–(043)
CLASS - XI
Time : 2 Hours M.M. : 35
General Instructions:
1. There are 12 questions in the question paper. All questions are compulsory.
2. Question 1 to 3 carry 2 marks each.
3. Question 4 to 11 are carry 3 marks each.
4. Question 12 are carry 5 marks.
5. There is no overall choice. However, internal choices have been provided in
some questions. Students have to attempt only one of the alternatives in such
questions.
SECTION A
Q.1. The enthalpy of formation of carbon monoxide and steam are – 1105 and –
243.0 kJ respectively. Calculate the heat of the reaction when steam is passed
over coke as

C(s) + H2O (g)  CO(g) + H2 (g) (2)

Q.2. At 473K, equilibrium constant K c for decomposition of phosphorus

pentachloride, PCI5 is 8.3 × 10–3. If decomposition is depiced as, (2)

PCI5 (g) PCI3 (g) + Cl2 (g); H° = 124.0 kJ mol–1

(i) Write an expression for Kc for the reaction.

(ii) What is the value of Kc for the reverse reaction at the same temperature?

Q.3. (i) Alkali metals react with water vigorously to form hydroxides and
dihydrogen. Name alkali metals reacts with water least vigorously?

(ii) When sodium is dissolved in liquid ammonia, a solution of deep blue

colour is obtained. Why it is deep blue in colour. (2)

Q.4. Use the information and data given below to answer the question (a) to (c),
Stronger intermolecular forces result in higher boiling point.
 Strength of London forces increase with the number of electrons in the molecules.

Boiling point of HF, HCl, HBr and HI are 293 K, 189 K, 206 K and 238 K
respectively.

(i) Which type of intermolecular forces are present in the molecules HF,
HCl, HBr and HI?

(ii) Looking at the trend of boiling points of HCl, HBr and HI, explain out
of dipole-dipole interaction and London interaction, which one is
predominant here.

(iii) Why is boiling point of hydrogen fluoride highest while that of hydrogen
chloride lowest? (3)

Q.5. (i) 100 mL of a liquid is contained in an insulated container at a pressure of

1 bar. The pressure is steeply increased to 100 bar. The volume of the
liquid is decreased by 1 mL at this constant pressure. Find H and U.

(ii) One mole of acetone requires less heat to vaporise than 1 mole of water.
Which of the two liquids has higher enthalpy of vaporisation?

(iii) At 1 atm will the fH° be zero for Cl2 (g) and Br2 (g). Explain.

OR

(i) For the same increase in volume, why work done is more if the gas is
allowed to expand reversibly at higher temperature?

(ii) Predict the change in internal energy for an isolated system at constant
volume.

(iii) If the combustion of 1g of graphic produces 20.7 kJ of heat, what will

be molar enthalpy chnage? Give the significance of sign also.