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Mathematics Paper-1: Questions, Hints Solutions
Mathematics Paper-1: Questions, Hints Solutions
PART TEST-2(APT-2)
TARGET : JEE (MAIN+ADVANCED) 2021
DATE : 19-07-2020 SET/CODE-1 COURSE : VIJETA (JP) | BATCH : (JPA (STAR), IP, PA1)
QUESTIONS, HINTS & SOLUTIONS
MATHEMATICS
PAPER-1
SECTION – 1 : (Maximum Marks : 27)
This section contains TWELVE (12) questions.
Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four option is correct
There are 12 Questions & you have attempt any 9 Questions. If a student attempts more than 9
questions, then only first 9 questions which he has attempted will be checked.
Marking scheme :
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases
| x |
1. If y = logsin x , then the possible set of values of x and y are
x
| x |
;fn y = logsin x gks] rks x rFkk y ds ekuksa dk lEHkkfor leqPp; gS
x
(A) x (2n, 2n + ) and vkSj y {0}
nW
(Where W stands for the set of all the whole numbers) (tgk¡ W iw.kZ la[;kvksa ds leqPp;ksa dks crkrk gS½
|x|
Sol. logsin x sin x (0, 1) and x (0, )
x
x 2n, 2n 2n , (2n 1) and y {0}
nW 2 2
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2. Consider the following statements :
1
S1 : If x > 0, then x + 2.
x
S2 : Minimum value of 9 tan2 + 4cot2 is 12.
2000
{x r}
S3 : If [x] and {x} represent integral and fractional parts of x, then the expression [x] + = x.
r 1 2000
= [x] + {x} = x
Hindi S1: A.M. G.M. ls
x > 0 x + 2 lR; gS
9 tan 4cot 2
2
S2 : A.M. G.M. ls 6
2
9tan2 + 4cot2 = 12 dk U;wure eku
2000
{x r}
S3 : L.H.S = [x] +
r 1 2000
2000
{x}
= [x] +
r 1 2000
= [x] + {x} = x
3. Let f : R R satisfy relation f(x) f(y) – f(xy) = x + y x, y R and f(1) > 0. If h(x) = f(x) f –1(x), then
length of longest interval in which h(sinx+cosx) is strictly decreasing is.
ekuk f : R R lEcU/k f(x) f(y) – f(xy) = x + y x, y R rFkk f(1) > 0 dks larq"V djrk gSA ;fn h(x) = f(x) f
–1(x), rc vf/kdre vUrjky dh yEckbZ ftlesa h(sinx+cosx) fujUrj áleku gS&
(A) (B*) (C) (D)
2 4 6
Sol. f(x).f(y)–f(xy) = x + y ...(1)
put x = y = 1 j[kus ij
f ²(1)–f(1) = 2
f ²(1) –f(1) – 2 = 0
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f(1) = 2 or –1
f(1) = 2 ( f(1) > 0)
Now put y = 1 in eqn. (1) lehjd.k (1) esa y = 1 j[kus ij
f(1).f(x) – f(x) = x + 1
f(x) = x + 1
y = x+ 1
x=y–1
f–1(x) = x – 1
f(x). f–1(x) = x² – 1 = h(x)
h(sinx+ cosx) = (sinx + cosx)² – 1 = sin2x
Required interval length is vf/kdre vUrjky dh yEckbZ .
2
3
6. The solution set of the equation sin1 tan – sin1 – = 0 is
4
x 6
3
lehdj.k sin1 tan – sin1 – = 0 dk gy leqPp; gS&
4 x 6
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3
Sol. sin–1 tan –1
– sin – =0
4 x 6
3
sin–1 1 – sin–1 =
x 6
3 3
=
2 x
x =2 x=4
1
Thus cos–1 x > sin–1 x for x 1, and sin x > tan x for x (0,1]
–1 –1
2
1
vr% x 1, ds fy, cos–1 x > sin–1 x vkSj x (0,1] ds fy, sin–1 x > tan–1 x
2
1 1
cos–1 x > sin–1 x > tan–1 x for x 1, (0,1] 0,
2 2
1 1
x 1, (0,1] 0, ds fy, cos–1 x > sin–1 x > tan–1 x
2 2
(dy / dz)
8. If y = f(x3), z = g(x5), f '(x) = tanx and g '(x) = sec x. Then value of lim is
x 0 x
(dy / dz)
;fn y = f(x3), z = g(x5), f '(x) = tanx vkSj g '(x) = sec x rc lim dk eku gS &
x 0 x
2 3 4
(A) (B) 1 (C*) (D)
5 5 5
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dy f '(x3 )3x 2 tan x3 3 3 tan x 3 1 3
sol. . ; Hence vr% lim .
dz g'(x5 ).5x 4 sec x 5 5x 2 x 0 5x 2 .sec x 5 x 5
9 33 129
9. cot–1 + cot–1 + cot–1 ............ dk eku gS&
2
4 8
(A) (B) (C) (D*) buesa ls dksbZ ugha
4 2 4
1 9 1 2 1 4 2 1 1
Sol. cot tan tan tan 4 tan 2
2 9 1 4.2
33 4 84
cot 1 tan1 tan1 tan1 8 tan1 4
4 33 1 4.8
129 8 1 16 8
cot 1 tan1 tan tan1 16 tan1 8
8 129 1 16.8
1 n 1 1 n
blh izdkj Tn = tan 2 tan 2 dks tksMUks ij
1 n 1 1
;ksx = tan 2 tan 2
tc n , rc ;ksx = – tan–1 2 = cot–1 2.
2
d2 x
2
dy
10. If a curve is represented parametrically by the equations x = 4t + 3 and y = 4 + 3t and
3 4
n
is
dx
dy
constant then value of n is
d2 x
2
;fn ,d oØ dh izkpfyd lehdj.ksa x = 4t3 + 3 vkSj y = 4 + 3t4 gS rFkk dy vpj gS rc n dk eku gS&
n
dx
dy
(A) 3 (B) 4 (C*) 5 (D) 6
dx
dx dt 12t 2 1
Sol.
dy dy 12t 3 t
dt
2
d x d dx d 1 dt 1 1 1
. .
dy 2 dy dy dt t dy t 2 12t 3 12t 5
1
5
So 12t n is constant n = 5
1
t
1
5
blfy, 12t n vpj gSA n = 5
1
t
11. Let f(x) be a polynomial in x. Then the second derivative of f(ex) w.r.t. x is
;fn f(x), x esa ,d cgqin gS rc f(ex) dk x ds lkis{k f}rh; vodyt gS &
(A) f (ex). ex + f (ex) (B*) f (ex). e2x + f (ex). ex
x
(C) f (e ) e 2x (D) f (ex). ex + f (ex). e2x
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d
Sol. (f(e x )) = f(ex).ex
dx
d2
(f(e x )) = ex f(ex) + e2x f(ex)
dx 2
d2 x
12. =
dy 2
3 1 1 3 2
d2 y dy d2 y d2 y dy d2 y dy
(A*) – 2 dx (B) 2 (C) – 2 dx (D) 2 dx
dx dx dx dx
dy 1 d2 y d 1 d 1 dy
Sol. 2
= .
dx dx dx dx dx / dy dy dx / dy dx
dy
d2 x d2 x
–
1 dy 2 dy 2
=– 2
. = 3
dx dx dx
dy
dy dy
3 sin x
13. If f(x) = tan–1 , then find the value of 7f .
4 5cos x 3
3 sin x
;fn f(x) = tan–1 gS] rks 7f dk eku Kkr dhft,A
4 5cos x 3
Ans. 03.00
1 3cos x(4 5 cos x) – 3 sin x(–5 sin x)
Sol. f (x) = 2
3 sin x (4 5 cos x)2
1
4 5 cos x
(4 5 cos x)2 12cos x 15 cos2 x 15 sin2 x
f (x) = 2
(4 5 cos x)2 3 sin x (4 5cos x)2
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3(4cos x 5)
f (x) =
16 40 cos x 25 cos2 x 9(1– cos2 x)
3(4cos x 5) 3 3
f (x) = = f =
(4cos x 5)2 4 cos x 5 3 7
x
14. If f(x) = max ,| sin x | , n N has maximum points of non-differentiability for x (0, 4) then what is
n
the least value of n.
x
;fn f(x) = max n ,| sin x | , n N, x (0, 4) ds fy, vodyuh;rk ugha gksus ds vf/kdre fcUnqvksa dks j[krk
gS] rc n dk U;wure eku gS&
Ans. (4)
Sol.
3.5
1 2 3 4
x
f(x) = max ,| sin x |
n
for max points vf/kdre fcUnq ds fy,
n > 3.5
nmin = 4
lim
sin1 x 22 sin1 2x 32 sin1 3x n2 sin1 nx
15. If x 0 ...... 2025 then find the value of 'n'
x x x x
(where [.] denotes the greatest integer function)
lim
sin1 x 22 sin1 2x 32 sin1 3x n2 sin1 nx
;fn x 0 ...... 2025 rc 'n' dk eku Kkr dhft,A
x x x x
(tgk¡ [.] egÙke iw.kkZad Qyu dks O;Dr djrk gSA)
Ans. 09.00
sin1 x
Sol. In vicinity of x 0, sin1 x | x | 1, in vicinity of x 0
x
sin1 x
x=0 ds fy, sin1 x | x | 1 vkSj x 0 ds fy,
x
l 13 23 33 ...................... n3 2025
sin1 x 23 sin1 2x 33 sin1 x n3 .sin1 nx
lim ............
x 0 x 2x 3x nx
2
n(n 1) 2 n(n 1)
2025 (45) 45
2 2
n2 n 90 0 (n 10)(n 9) 0 n 9
1
16. If f(x) = x2 – 3x + 1 ; x 2 and g(x) is inverse function of f(x), then find the value of .
g(1)
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1
;fn f(x) = x2 – 3x + 1 ; x 2 vkSj g(x), f(x) dk izfrykse Qyu gS] rc dk eku Kkr dhft,A
g(1)
Ans. 03.00
Sol. f(g(x)) = x
f (g(x)). g (x) = 1
1
g (x) =
f (g(x))
1
g (1) = [where tgk¡ f(x) = x2 – 3x + 1 = 1, x = 0, x = 3 but ijUrq x 2]
f (g(1))
1
=
f (3)
1 1
g (1) = 3
3 g(1)
2
1 sin x sin3x sin5x.sin7x k
lim 2
dk eku k gS rks cjkcj gS –
x
6
x
2
2
Ans. 07.00
Sol. x– =y
2
1 cos y cos 3y cos5y cos 7y
lim
y 0 y2
sin y cos3y cos5y cos7y 3cos y sin3y cos5y cos7y 5cos y cos3y sin5y cos7y 7cos y cos3y cos 5y sin7y
lim
y 0 2y
1 9 25 49
42
2 2 2 2
18. The domain of the function f(x) = 3 2x 21 x + sin1 x is [a, b], then find the value of a2 + b2 + ab.
Qyu f(x) = 3 2x 21 x + sin1 x dk izkUr [a, b] gS, rc a2 + b2 + ab dk eku Kkr dhft,A
Ans. 01.00
Sol. Letekuk (x) = 3 2x 21 x
1
andvkSj (x) = sin x
So vr% f(x) = (x) + (x)
Letekuk dom = D1 dom = D2 . Then rc dom f = D1 D2
Sovr%, D1 = {x R | 3 – 2x – 21 – x 0] and vkSj
D2 = {x R | sin–1 x 0}
Nowvc, 3 – 2x – 21 – x 0
2
or ;k 3 – 2x – x 0
2
or ;k 3 . 2x – (2x)2 – 2 0
or ;k (2x)2 – 3.2x + 2 0
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(2x – 2) (2x – 1) 0
By sign-scheme, fpUg ifjorZu fof/k ls
Let f(x)
sin1(1 {x}).cos1(1 {x}) , where {x} denotes the fractional part of x
2{x}.(1 {x})
1 1
ekukfd f(x) sin (1 {x}).cos (1 {x}) , tgk¡ {x}, x dk fHkUukRed Hkkx Qyu gSA
2{x}.(1 {x})
a
19. If lim f(x) is equal to (where a & b are co-prime to each other) then
x 0
b
;fn lim f(x) , a ds cjkcj gS& (tgk¡ a rFkk b ,d nwljs ds lgvHkkT; gS) rc
x 0 b
(A*) a = 1 (B) a = 2 (C*) b = 2 (D) b = 4
20.
then which of the following may be CORRECT ?
L lim f(x)
x 0 a b
rc fuEu esa ls dkSulk lR; gks ldrk gS ?
L lim f(x)
x 0 a b
(A*) (a, b) (2, 2) (B*) (a, b) (1, 8) (C) (a, b) (1, 4) (D) (a, b) (2, 4)
Sol. (5 to 6)
19.
sin1(1 {0 h}).cos1(1 {0 h})
lim
h 0
2{0 h}.(1 {0 h})
sin1(1 h) cos1(1 h)
lim .
h 0 (1 h) 2h
In second limit put 1 h cos
nwljh lhek 1 h cos j[kus ij
sin1(1 h) cos1 cos
lim limit
h 0 (1 h) 0 2(1 cos ) 2
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20. sin1(1 {0 h})cos 1(1 {0 h})
lim f(x) lim f(0 h) lim
x 0 h 0 h 0 2{0 h} (1 {0 h})
1 1
sin (1 h 1)cos (1 h 1) sin1 h cos1 h
lim lim .
h0 2{0 h} (1 h 1) h 0 h 2(1 h)
1. 2
2 2 2
n
x 4b
Consider two functions ekukfd Qyu f(x) = nlim cos & g(x) = –x
n
22. Number of solution(s) of equation f(x) + g(x) = 0 is two then can lies in the interval
lehdj.k f(x) + g(x) = 0 ds gyksa dh la[;k nks gS] rc dk vUrjky fLFkr gks ldrk gS&
(A) (–, –1) (B) (–7, –2) (C*) (0, ) (D*) (1, 5)
x
x2 sin x2
lim
2 2 n
e 2
Sol. f(x) = e n
x
2 n
x 1
b = xlim 2 2 = (rationalization ifjes;dj.k)
x x 1 x 1 2
x2
Hence vr% 2
x2
e
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ADVANCED PATTERN
PART TEST-2(APT-2)
TARGET : JEE (MAIN+ADVANCED) 2021
DATE : 19-07-2020 SET/CODE-1 COURSE : VIJETA (JP) | BATCH : (JPA (STAR), IP, PA1)
QUESTIONS, HINTS & SOLUTIONS
PHYSICS
PAPER-1
SECTION – 1 : (Maximum Marks : 27)
This section contains TWELVE (12) questions.
Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four option is correct
There are 12 Questions & you have attempt any 9 Questions. If a student attempts more than 9
questions, then only first 9 questions which he has attempted will be checked.
Marking scheme :
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases
[kaM 1 : (vf/kdre vad : 27)
bl [kaM esa ckjg (12) iz'u gSaA
izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls dsoy ,d fodYi lgh gSaA
bl [kaM esa 12 iz'u gaS ftuesa ls vkidks dsoy fdUgh 9 iz'uksa dk mÙkj nsuk gS ;fn vki 9 ls vf/kd iz'uksa dk mÙkj nsrs gS] rks mÙkj
fn;s x;s izFke 9 iz'uksa dh gh tk¡p dh tk;sxhA
vadu ;kstuk :
iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
_.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA
23. Maximum height reached by a rocket fired with a speed equal to 50% of the escape velocity from
earth’s surface is:
¶yk;u osx ds 50% pky ds cjkcj ls izTofyr jkWdsV }kjk i`Foh lrg ls izkIr egRRe Å¡pkbZ gS &
24. The plates S and T of an uncharged parallel plate capacitor are connected across a battery. The battery
is then disconnected and the charged plates are now connected in a system as shown in the figure.
The system shown is in equilibrium. All the strings and spring are insulating and massless. The
magnitude of charge on one of the capacitor plates is: [Area of plates = A]
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,d vukosf'kr lekUrj iê la/kkfj=k dh IysVsa S rFkk T dks cSVjh ls tksM+k tkrk gS fQj cSVjh dks gVk fn;k tkrk gS
rFkk vkosf'kr IysVksa dks ,d fudk; esa fp=kkuqlkj tksM+rs gSA fn[kk;k x;k fudk; lkE; esa gSA lHkh fLizax rFkk jfLl;k¡
dqpkyd rFkk nzO;eku jfgr gSA la/kkfj=k dh fdlh ,d IysV ij vkos'k dk ifjek.k gS% (IysVksa dks {ks=kQy = A)
4mgA 0 2mgA 0
(A*) 2mgA 0 (B) (C) mgA 0 (D)
k k
25. A wire of resistance 10 is bent to form a circle. P and Q are points on the circumference of the circle
dividing it into a quadrant of 3 V and internal resistance 1 as shown in the figure. The currents in the
two parts of the circle are
,d 10 izfrjks/k ds rkj dks eksM+ dj o`Ùk cuk;k x;k gSA P o Q o`Ùk dh ifjf/k ij fcUnq gSa] tksfd ,d 3 V vkSj
vkarfjd izfrjks/k 1 esa fp=kkuqlkj prqFkkZa'k esa foHkkftr djrh gSA o`Ùk ds nksuksa Hkkxksa esa /kkjk gS %
6 18 5 15 4 12 3 9
(*A) A and A (B) A and A (C) A and A (D) A and A
23 23 26 26 25 25 25 25
26. The resistance R1 is adjusted in such a way that whether the switch is in position 1 or in 2, the current
through the ammeter is I = 2 A. The value of emf of E2 = 6 V. The cells are ideal. The value of
resistance R2 is
izfrjks/k R1 dks bl izdkj lek;ksftr fd;k tkrk gS fd pkgs fLop fLFkfr 1 esa gks ;k 2 esa] vehVj ls izokfgr /kkjk
I = 2 A gS E2 ds foHkokUrj dk eku 6 V gSA lsy vkn'kZ gSA izfrjks/k R2 dk eku gSA
1
E1 R1 2 E R2
2
A
(A*) Equal to 3 (B) greater than 3 (C) Less than 3 (D) Dependent on E1
(A*) 3 ds cjkcj (B) 3 ls vf/kd (C) 3 ls de (D) E1 ij fuHkZj
E1 E1 E2 E2
Sol. = = R2 = 3
R1 R1 R 2 R2
27. In the figure initial status of capacitor and their connection is shown. Which of the following
is incorrect about this circuit :
fp=k esa la/kkfj=k rFkk la;kstu dh izkjfEHkd fLFkfr ds ckjs esa n'kkZ;k x;k gSA ifjiFk ds ckjs esa fuEu esa dkSu lk@ls
dFku vlR; gS@gSaA
(A) Final charge on each capacitor will be zero izR;sd la/kkfj=k ij vfUre vkos'k 'kwU; gSA
(B) Final total electrical energy of the capacitors will be zero
izR;sd la/kkfj=k dh vfUre dqy fo|qr ÅtkZ 'kwU; gSA
(C) Total charge flown from A to D is 30µC
A ls D dh rjQ cgus okyk dqy vkos'k 30µC gSA
(D*) Total charge flown from A to D is – 30µC
A ls D dh rjQ cgus okyk dqy vkos'k – 30µC gSA
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Q1 Q2
Sol. (C) V = =0
C1 C2
28. A wire has resistance per unit length and is arranged as shown. If side of the bigger square is then
equivalent resistance between points A and B will be
,d rkj dk izfr bdkbZ yEckbZ izfrjks/k gS] vkSj ;g n'kkZ;s vuqlkj O;ofLFkr gSA ;fn cM+s oxZ dh Hkqtk gS rks fcUnq
A o B ds e/; rqY; izfrjks/k gksxk -
/2
A B
(A*) (B) 2 (C) 2 (D)
2
2
2
1+ 2
1+ 2
2
2 2 2
Sol. A
2
B A B A B
2
2 2
1+ 2
1 1 2 1 1 2
= = =
1 2 2 1 2 2 2 2
29. A cubical box is used to keep drinks cold in a bus. Surface area of each face is 0.80 m2 and each wall
has thickness 2.00 cm. It is filled with ice and water which remains at 0ºC. Temperature outside each
wall is 30ºC then : (Thermal conductivity of material of box=1×10–2w/m–k) (Latent heat of fusion of
ice=3.2×105 J/kg)
cl esa is; dks B.Mk j[kus ds fy, ?ku ckWDl ç;qDr gSA çR;sd i`"B dk i`"Bh; {ks=k 0.80 m2 rFkk eksVkbZ 2.00 cm gSA
bls cQZ rFkk ty ls Hkjk x;k gS tks 0ºC ij jgrk gSA çR;sd nhokj ds ckgj rkieku 30ºC gS rks : (ckWDl ds inkFkZ
dh Å"eh; pkydrk = 1 × 10–2 w/m–k) (cQZ dh xyu dh xqIr Å"ek = 3.2 × 105 J/kg)
(A) Total heat current in the box is 60 J/s (B) Total heat current in the box is 52 J/s
(C*) Mass of ice melted in 1 hour is 810 gm (D) Mass of ice melted in 1 hour is 690 gm
(A) ckWDl esa dqy Å"eh; /kkjk 60 J/s gSA (B) ckWDl esa dqy Å"eh; /kkjk 72 J/s gSA
(C*) 1 ?k.Vs esa fi?kyh cQZ dk nzO;eku 810 gm gSA (D) 1 ?k.Vs esa fi?kyh cQZ dk nzO;eku 690 gm gSA
T TC
Sol. H = KA H
L
30º 0º
= (0.01) (0.80).
0.020
H = 12w = 12 J/s
So, through all faces = 12 × 6
vr% lHkh i`"Bksa ls = 12 × 6
Htotal = 72 J/sec.
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= Ht = 72 × 3600 J
72 3600
m= = = 810 gms.
Lf 3.2 105
30. A ring consisting of two parts ADB and ACB of same conductivity K carries an amount of heat at rate H.
The ADB part is now replaced with another metal keeping the temperature T1 and T2 constant. The rate
ACB
of heat carried increases to 2H. What should be the conductivity of the new ADB part ? 3
ADB
,d oy; tksfd leku pkydrk okys nks fgLlksa ADB rFkk ACB ls cus gS dqy Å"ek H dh nj ls çofkgr djrs gSA
ADB fgLlk vc ,d nwljs /krq ls cny fn;k tkrk gS ysfdu rkieku T1 rFkk T2 fu;r j[krs gSA vc dqy Å"ek çokg
ACB
nj 2H gks tkrh gSA u, ADB fgLls dh pkydrk D;k gksuh pkfg,?
3
ADB
C
A B
T1 D T2
7 5
(A*) K (B) 2K (C) K (D) 3K
3 2
Sol. In first case çFke fLFkfr esa :
KA(T1 T2 ) KA(T1 T2 ) 4 KA(T1 T2 )
H = H1 + H2 = + =
3 3
In 2nd case f}r :
H1 + H2 = 2H
H2 = 2H – H1 [H1 = H1]
8 KA KA KA(T1 T2 )
H2 = 2H – H1 = (T1 T2 ) – (T1 T2 ) =
3
7
K = K
3
31. A black body emits radiation at the rate P when its temperature is T. At this temperature the wavelength
at which the radiation has maximum intensity is 0. If at another temperature T the power radiated is P
and wavelength at maximum intensity is 0 then
2
rkiØe 'T' ij ,d vkn'kZ d`f".kdk P 'kfä nj ls fofdj.k mRlftZr djrh gSA bl rki ij egRre rhozrk ds
fofdj.k dh rjaxnS/;Z 0 gSA ;fn vU; rki T ij mRlftZr 'kfä P gS rFkk egRre rhozrk dh rjaxnS/;Z 0 gS rc &
2
(A*) P T = 32PT (B) P T = 16PT (C) P T = 8PT (D) P T = 4PT
Sol. For a block body, wavelength for maximum intensity :
,d Ñf".kdk oLrq ds fy,] vf/kdre rhozrk ds fy, rjaxnS/;Z
1
& P T4
T
1
P 4
P = 16 P. P T = 32PT
32. A sphere and a cube of same material and same total surface area are placed in same evacuated
space after they are heated to same temperature. The ratio of their initial rate of cooling in space is :
,d xksyk o ,d ?ku] ,d gh inkFkZ ls cus gS rFkk buds dqy i`"Bh; {ks=k Hkh leku gSA leku rki rd xeZ dj bUgsa
leku fuokZfrr LFkku ij j[kk x;k gSA buds çkjfEHkd 'khryu dh nj dk vuqikr gksxk
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1
(A) 1 (B) (C*) (D)
6 6
Sol. For sphere : xksys ds fy,
d
T4 S = m1C.
dt sphere
For cube : ?ku ds fy,
d
T4. S = m2.C
dt cube
d
dt
sphere m V
= 2 = 2 [S = 6a2 = (4r2)]
d m1 V1
dt
cube
=
6
33. A solid cube of side R and solid sphere of radius R of same material inside room of temperature T0.
If temperature of cube 4T0 and sphere 2T0 then find out ratio of their rates of cooling.
T0 rkieku ds dejs ds vUnj j[ks leku inkFkZ ds ,d Bksl ?ku dh Hkqtk R ,oa Bksl xksys dh f=kT;k R gSA ;fn ?ku
dk rki 4T0 ,oa xksys dk rki 2T0 gSA rc muds 'khryu dh nj dk vuqikr Kkr dhft,A
(1*) 34 (2) 32 (3) 12 (4) 28
27
(5)
8
dT eA 4
Sol. C (T T04 )
dt ms
4 4
C1 A1 m2 T1 T0
C2 A 2 m1 T24 T 4
0
4 3
R
C1 6R2 3 256T0 T0
2 3
C2 4R .R 16T0 T0
C1
34
C2
x2
34. A rod of uniform cross–section but non–uniform thermal conductivity which vary as k = k0 (1 x
L2
L) (as shown in figure) is kept between fixed temperature difference for a long time. Select the correct
option(s) :
,d le:i vuqçLFk dkV {ks=kQy dh ,d NM+ ysfdu vle:i rkih; pkydrk dh ,d NM+ ftldh pkydrk k = k0
x2
(1 x L) ds vuqlkj ifjofrZr gksrh gSA fp=k eas n'kkZ;s vuqlkj fuf'pr rkikUrj ds e/; yEcs le; ds fy,
L2
j[kh tkrh gSA lgh fodYi@fodYiksa dk p;u dhft, &
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(A*) (B) (C) (D) None of these
2 T 2 x
k0 x dT i L dx
Sol. i= A T dT k 0 A 1 x 2
L2 dx H
x
i L2 1
T – TH = x
k0 A 1
1 35.35
The acceleration due to gravity at surface of planet is same as a depth ‘R’. The ratio of is
2 n
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4 4 4
R3 1 + (8R3 – R3)2 = 4 .R3 .1
3 3 3
1 + 72 = 41
1 7
=
2 3
36. A man does work W on a ball to throw it vertically upto a height h on earth, if man does work kW on
1
same ball to throw it vertically upto height 2h on another planet having its radius of radius of earth
4
51
and planet has same density as that of earth. Find k ?
2
,d O;fDr ,d xsan dks i`Foh ij h Å¡pkbZ rd Å/okZ/kj Qsadus esa] xsan ij W dk;Z djrk gSA ;fn O;fDr mlh xsan dks
1
vU; xzg ij ftldh f=kT;k] i`Foh dh f=kT;k dh gS rFkk ?kuRo] i`Foh ds ?kuRo ds leku gS] 2h Å¡pkbZ rd
4
51
Å/okZ/kj Qsadus esa kW dk;Z djrk gS rks k Kkr djks ?
2
Ans. 12.75
Sol. W earth = mgeh
4
= m GdR.h
3
4 R
W planet = m. Gd. 2h
3 4
Wearth
=2
Wplanet
W
W planet = .
2
37. 300 nos. of identical galvanic cells, each of internal resistance 9 are arranged as several in–series
groups of cells connected in parallel. The arrangement has been laid out so that power output in an
externally connected resistance of value 16 is maximum. If n number of cells are connected in every
n
series group that form parallel combination, then find value of .
4
300 ,d leku xsYosfud lsy] çR;sd dk vkUrfjd çfrjks/k 9 bl çdkj O;ofLFkr gS fd Js.khØe esa tqM+s lsyksa ds
lewg lekUrj esa tqM+s gSA bl O;oLFkk esa 16 ds ckº; çfrjks/k esa fuxZr 'kfDr vf/kdre gSA ;fn Js.khØe esa tqM+s
n
lsyksa ds çR;sd lewg esa n lsy gS rks dk eku Kkr djksA
4
E1 E2 En
R = 16
Ans. 06.25
Sol. Power developed in it is maximum when req = R
nr
= R (N – total nos. of cells)(n - cell in one series group)
N/n
RN
n=
r
using values R = 16 , N = 300, r = 9
40
n= = 23.1
3
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As n has to be integer and cofactor of 300, then nearest possible values are 25 and 25.
29Power is maximum when current through it is maximum
nE
I=
n2 r
R
N
using n = 25 and n = 20 and solving we get
300E 300E
25 , 20
417 420
It is obvious that when n = 25, I is greater than when n = 20.
Therefore n = 25 nos.
Sol. tc mRiUu 'kfDr vf/kdre gS req = R
nr
=R (N – dqy lSyksa dh la[;k)
N/n
(n - ,d Js.kh lewg esa lSyksa dh la[;k)
RN
n=
r
ekuksa dk iz;ksx djus ij R = 16 W, N = 300, r = 9 W
40
n= = 23.1
3
pwafd n iw.kk±d gS rFkk;g 300 dk xq.kdgS rks laHkkfor lehire eku 20 rFkk 25 gS
'kfDr vf/kdre gksxh tc izokfgr /kkjk vf/kdre gksA
nE
I=
n2 r
R
N
n = 25 o n = 20 j[kus ij ,oa gy djus ij
300E 300E
25 , 20
417 420
vFkkZr~ tc n = 25 gS rks , n = 20 dh vis{kk vf/kdre gS
vr% n = 25 gksxk
38. A cell of emf 1.5 V and internal resistance 0.5 is connected to a non-linear conductor in which current
varies with voltage as V2 = . If the current drawn from cell is 'I', then find 12.75×I(in ampere). [EASY]
1.5 V fo-ok-cy rFkk 0.5 vkUrfjd çfrjks/k ds lsy dks vjs[kh; pkyd ls tksM+k x;k gS] ftlesa /kkjk, oksYVst ds
lkFk V2 = vuqlkj ifjorhZ gSA ;fn lsy ls yh xbZ /kkjk 'I' gS, rks 12.75×I (,sfEi;j ek=kd esa) Kkr dhft,A
Ans. 12.75
Sol.
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39. A body of mass 4 kg is suspended from a spring of spring constant 400 N/m. Another body of mass 4
1 3
kg moving vertically upward with 2 m/s hits it & gets embedded in it. If amptitude is m. find
x 4
'5.05x'.
nzO;eku 4 kg dh ,d oLrq 400 N/m fLçax fu;rkad ds ,d fLçax ls yVdh gSA 4 kg nzO;eku dh ,d vU; oLrq 2
1 3
m/s ls Åij dh xfr'khy gS ,oa blls Vdjkdj blesa ?kql tkrh gSA ;fn vk;ke m gS rks '5.05x' Kkr
x 4
dhft,A
Ans. 25.25
K 400
Sol. = = 50
m 8
2 = 50
V = A 2 – x2
V2 = 2(A2 – x2)
1
1 = 50 A 2 –
100
1 1
A2 =
50 100
3
A2 =
100
1 3
A= x=5
5 4
40. A pendulum has period 51s for small oscillations. An obstacle is placed directly beneath the pivot, so
that only the lowest one quarter of the string can follow the pendulum bob when it swings to the left of
its resting position as shown in the figure. The pendulum is released from rest at a certain point A. The
time taken by it to return to that point is X s. Find the minimum value of X ?
,d yksyd ds fy;s vYi nksyuksa dk vkorZdky 51s gSA ,d vojks/kd dks dhyd ds Bhd uhps yxk fn;k tkrk gS
rkfd fojkekoLFkk ls NksM+us ij tc yksyd dk xksyd viuh ek/; fLFkfr ls xqtjs rks blds ckn og ewy yEckbZ dh
,d pkSFkkbZ yEckbZ ls gh fp=kkuqlkj cka;h vksj nksyu djsA yksyd dks fcUnq A ls fojkekoLFkk ls NksM+k tkrk gSA bls
okil blh fcUnq rd iqu% ykSVus esa yxk le; Xs gSA X dk U;wure~ eku Kkr djks ?
Ans. 38.75
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T
Sol. T length free length becomes So time period becomes T1 =
4 2
T
T yEckbZ eqDr yEckbZ gks tk;sxhA vr% vkorZdky T1 = gksxk
4 2
Half oscillation is with free length and half with free length
4
vk/ks nksyu esa Mksjh dh yEckbZ gS rFkk 'ks"k vk/kk nksyu ds lkFk gSA
4
T T 3T
Total time dqy le; = + 1 =
2 2 4
A point source of sound 'S' generating sound of 875 Hz is moving along straight line with speed 50 m/s
as shown in figure. A stationary observer 'O' is situated at a perpendicular distance 300 m from CD as
shown. Speed of sound is 300 m/s. Based on given information answer the following :
,d fcUnqor~ /ofu L=kksr 'S' ljy js[kk ds vufn'k 50 m/s pky ls xfr djrs le; fp=kkuqlkj 875 Hz vko`fÙk dh
/ofu mRiUu djrk gSA fp=kkuqlkj CD js[kk ls 300 m yEcor~ nwjh ij ,d fLFkj çs{kd 'O' fLFkr gSA /ofu dh pky
300 m/s gSA mijksDr lwpuk ds vk/kkj ij fuEu dk mÙkj nhft, :
c2 3002
f' = f = 875 = 900 Hz.
c 2 u2 3002 502
42. Distance between observer and source when observer hears original frequency :
tc çs{kd okLrfod vko`fÙk lwurk gS rc L=kksr rFkk çs{kd ds e/; nwjh Kkr djks &
(A) 300 m (B) 305 m (C*) 50 37 m (D) None of these buesa ls dksbZ ugha
Sol.
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Paragraph for Question Nos. 43 to 44
ç'u 43 ls 44 ds fy, vuqPNsn
A string fixed at both the ends of length 2 m, vibrating in its 7th overtone. Equation of the standing wave
is given by y = A sin kx cos (t + /3), All the symbols have their usual meaning. Mass per unit length of
the string is 0.5 gm/cm. Given that A = 1 cm and = 100 rad/sec. Answer the following 2 questions
based on information given (Use 2 = 10)
2 m yEckbZ dh jLlh nksuksa fljksa ij tM+or~ cU/kh gqbZ gS, ;g 7 osa vf/kLojd esa dEiUu dj jgh gSA blesa
mRiUu vizxkeh rjax dh lehdj.k y = A sin kx cos (t + /3) }kjk nh tkrh gSA ;gk¡ lHkh izrhdksa ds
lkekU; vFkZ gSA jLlh dh bdkbZ yEckbZ dk nzO;eku 0.5 gm/cm gSA fn;k gS A = 1 cm rFkk = 100
rad/secA nh xbZ lqpuk ij vk/kkfjr fuEu nks iz'uksa ds mÙkj nhft,A (2 = 10)
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ADVANCED PATTERN
PART TEST-2(APT-2)
TARGET : JEE (MAIN+ADVANCED) 2021
DATE : 19-07-2020 SET/CODE-1 COURSE : VIJETA (JP) | BATCH : (JPA*,IP, PA1)
QUESTIONS, HINTS & SOLUTIONS
PAPER-1
PART : III CHEMISTRY
SECTION – 1 : (Maximum Marks : 27)
This section contains TWELVE (12) questions.
Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four option is correct
There are 12 Questions & you have attempt any 9 Questions. If a student attempts more than 9
questions, then only first 9 questions which he has attempted will be checked.
Marking scheme :
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases
45. In which of the following electrolysis in aqueous medium, mass of anode and pH of solution both
remains unchanged?
(A) Electrolysis of aqueous AgNO3 using silver anode and copper cathode.
(B) Electrolysis of aqueous CuSO4 using pure copper anode and impure copper cathode.
(C) Electrolysis of aqueous CuSO4 using silver anode and platinum cathode.
(D*) Electrolysis of aqueous AgNO3 using gold anode and silver cathode.
tyh; ek/;e esa fuEu esa ls dkSulk oS|qr vi?kVu esa ,uksM dk æO;eku rFkk foy;u dh pH nksuksa vifjofrZr jgrh
gS ?
(A) flYoj ,uksM rFkk dkWij dSFkksM+ dk iz;ksx djrs gq, tyh; AgNO3 dk oS|qr vi?kVu
(B) 'kq) dkWij ,uksM rFkk v'kq) dkWij dSFkksM+ dk iz;ksx djrs gq, tyh; CuSO4 dk oS|qr vi?kVu
(C) flYoj ,uksM rFkk IysfVue dSFkksM+ dk iz;ksx djrs gq, tyh; CuSO4 dk oS|qr vi?kVu
(D*) xksYM ,uksM rFkk flYoj dSFkksM dk iz;ksx djrs gq, tyh; AgNO3 dk oS|qr vi?kVu
Sol. Anode Cathode
(A) Ag Ag+ + e– Ag+ + e– Ag
(B) Cu Cu2+ + 2e– Cu2+ + 2e– Cu
(C) Ag Ag+ + e– Ag+ + e– Ag
(D) 2H2O O2 + 4H + 4e+ – Ag+ + e– Ag
Sol. ,uksM dSFkksM
(A) Ag Ag+ + e– Ag+ + e– Ag
(B) Cu Cu2+ + 2e– Cu2+ + 2e– Cu
(C) Ag Ag+ + e– Ag+ + e– Ag
(D) 2H2O O2 + 4H+ + 4e– Ag+ + e– Ag
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h
46. Orbital angular momentum of an electron is 3 , then the number of possible orientations of this
orbital in space is:
h
,d bysDVªkWu dk d{kd dks.kh; laosx 3 gS rks vUrfj{k esa bl d{kd ds laHko foU;klksa dh la[;k gksxh &
(A) 3 (B) 5 (C*) 7 (D) 9
Sol. Orbital angular momentum of electron
h h
= l(l 1). 3.
2
l=3
number of orientation = 2l + 1 = 2 × 3 + 1 = 7
Sol. bysDVªkWu dk d{kd dks.kh; laosx
h h
= l(l 1). 3.
2
l=3
foU;kl dh la[;k = 2l + 1 = 2 × 3 + 1 = 7
47. Which of the following will not produce a precipitate with Ba(OH)2?
(A) Chromyl chloride (B) CO2 (C) SO2 (D*) NaNO2
fuEu es ls dkSulk Ba(OH)2 ds lkFk vo{ksi mRikfnr ugha djsxk\
(A) Øksfey DyksjkbM (B) CO2 (C) SO2 (D*) NaNO2
49. Which of the following aq. solution turn 'milky' with CO2?
fuEu es ls dkSulk tyh; foy;u] CO2 ds lkFk nwf/k;k gks tkrk gS\
(A) CaCl2 (B) NaOH (C) AgNO3 (D*) Ba(OH)2
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Sol. okWYÝsekbV ykSgpqEcdh; izd`fr dk gS blfy, dSlhVsjkbV v;Ld ¼vpqEcdh;½ ls bldk i`FkDdj.k oS|qrpqEcdh;
i`FkDdj.k fof/k }kjk fd;k tkrk gSA
51. Using the data given below find the incorrect statement regarding for the given species :
EoCr O2– / Cr 3 = 1.33 V E oCl / Cl– = 1.36 V
2 7 2
o
EMnO – 2 = 1.51 V EoCr 3 / Cr = – 0.74 V
4 / Mn
(C*) HCCH is more acidic than NH3 (D) is more stable than
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Sol. Four chiral carbon atoms (pkj fdjSy dkcZu ijek.kq)
55. Give the decreasing order of nucleophilic addition reaction of the following :
(i) HCHO (ii) PhCHO (iii) Chloral (Cl3C–CH=O) (iv) Acetophenone
fuEu ;kSfxdksa esa ukfHkdLusgh ;ksxkRed vfHkfØ;k ds fy, ?kVrh gqbZ nj dk Øe gS %
(i) HCHO (ii) PhCHO (iii) Dyksjy (Cl3C–CH=O) (iv) ,lhVksfQuksu
(A) iii > i > ii > iv (B) iv > ii > i > iii (C*) i > iii > ii > iv (D) iii > i > iv > ii
Sol. Reactivity of Neucleophilic addition reaction EWG.
Sol. ukfHkdLusgh ;ksxkRed vfHkfØ;k dh nj EWG ds lekuqikrh gksrh gSA
mRikn
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57. How many of following metals can be extracted by self reduction method?
fuEu es ls dqy fdrus /kkrqvksa dks Lor% vip;u fof/k }kjk fu"df"kZr fd;k tk ldrk gSA
Ca, Sn, Sb, Hg, Cu, Zn, Pb, Al , Na
Ans. 04.00
Sol. Sb, Hg, Cu & Pb can be extracted by self reduction method
Sb, Hg, Cu o Pb dks Lor% vip;u fof/k }kjk fu"df"kZr fd;k tk ldrk gSA
58. Consider the following molecules: O2, Cl2, Li2, H2, B2, C2 and N2
Let a = number of molecules having (bond order = 1)
b = number of molecules having (bond order = 2)
c = number of molecules having (bond order = 3)
d = number of paramagnetic molecules.
Find the value of (a × b × c × d × 4.2).
fuEu v.kqvks ij fopkj dhft, : O2, Cl2, Li2, H2, B2, C2 rFkk N2
ekuk
a = (ca/k Øe = 1) j[kus okys v.kqvks dh la[;k
b = (ca/k Øe = 2) j[kus okys v.kqvks dh la[;k
c = (ca/k Øe = 3) j[kus okys v.kqvks dh la[;k
d = vuqpqEcdh; v.kqvks dh la[;k]
(a × b × c × d × 4.2) Kkr dhft,A
Ans. 67.20
Sol. a = Cl2, Li2, H2, B2 = 4
b = O2, C2 = 2
c = N2 = 1
d = O2, B2 = 2
59. Evolution of a gas or acid vapours on addition of concentrated H2SO4 to an aqueous solution may
indicate presence of how many of the following acidic radicals in the solution?
Chloride, Carbonate, Bromide, Nitrite, Nitrate, Sulphite, Sulphide, Sulphate, Acetate, Phosphate
,d tyh; foy;u esa lkafnzr H2SO4 feykus ij xSl ;k vEy ok"iksa dk fu"dklu foy;u esa fuEu esa ls fdrus
vEyh; ewydksa dh mifLFkfr dks bafaxr dj ldrk gS\
DyksjkbM, dkcksZusV, czksekbM, ukbVªkbV, ukbVªsV, lYQkbV, lYQkbM, lYQsV, ,lhVsV, QkWLQsV
Ans. 08.00
Sol. Acidic radical which evolve gases on treatment with dilute HCl also show evolution of gas with
concentrated sulphuric acid. Except sulphate and phosphate all the given radicals show evolution of
gas or acid vapours on treatment with conc. H2SO4.
Sol. vEyh; ewyd tks ruq HCl ds lkFk mipkj.k ij xSl fu"dkflr djrk gS] lkafnzr lY¶;wfjd vEy ds lkFk Hkh xSl dk
fu"dklu n'kkZrk gSA lYQsV rFkk QkWLQsV dks NksM+dj fn;s x;s lHkh ewyd lkanz H2SO4 ds lkFk mipkfjr djus ij
xSl ;k vEy ok"i dk fu"dklu n'kkZrs gSaA
60. Calculate acid dissociation constant for 0.1 M HCOOH if its solution shows a resistance of 50 when
filled in a cell having separation between parallel electrodes 4 cm and cross section area of electrode
10 cm2
Given, m [Ca(HCOO)2 ] = 230 Scm2 mol–1
m [CaCl2 ] 280 Scm2 mol–1
m [HCl] = 425 Scm2 mol–1
(Fill your answer by multiplying the answer with 103)
0.1 M HCOOH ds fy, vEy fo;kstu fLFkjkad ifjdfyr dhft;s ;fn bldk foy;u 50 dk izfrjks/k n'kkZrk gS
tc lekUrj bysDVªkWMks ds e/; 4 cm nwjh j[kus okys ,d lsy esa bls Hkjk tkrk gS rFkk bysDVªkWM dk vuqizLFk dkV
{ks=kQy 10 cm2 gSA
fn;k gS m [Ca(HCOO)2 ] = 230 Scm2 mol–1
m [CaCl2 ] 280 Scm2 mol–1
m [HCl] = 425 Scm2 mol–1
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(viuk mÙkj 103 ls xq.kk djus ds i'pkr~ nhft;s)
Ans. 05.00
1 1 4
Sol. K= = 8 × 10–3 Scm–1
R a 50 10
K 1000
m = 80 S cm2 mol–1
0.1
1 1
m (HCOOH) = m (HCl) Ca(HCOO)2 (CaCl2 )
2 2
= 425 + 115 – 140 = 400 S cm2 mol–1
m 0.2
m
0 .1 2 0.1 0.04
Ka = = = 5 × 10–3 M
1 0.8
61. What is the maximum number of moles of CH3MgCl that can be consumed by one mole of phosgene ?
CH3MgCl ds eksykss dh vf/kdre la[;k D;k gSa tks 1 eksy QksLthu ls vfHkfØ;k djrs gSa \
Ans. 03.00
Sol.
62. How many of the following substituents present on benzene ring can cause aromatic electrophilic
substitution faster than benzene?
fuEu çfrLFkkfi;ksa esa ls fdrus csUthu dh rqyuk esa ,sjksesfVd bysDVªkWu Lusgh izfrLFkkiu vfHkfØ;k csUthu ij rhoz
nsrk gSA
(a) –NH2 (b) –NR2 (c) –NO2 (d) – NH3
O O O O
|| || || ||
(e) –O – C – R (f) –NH – C – R (g) –C – Cl (h) –C – H
(i) –SO3H (j) –CH3 (k) –CH = CR2
Sol. 06.00 (a , b , e, f , j , k)
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[kaM 3 : (vf/kdre vad : 16)
bl [kaM esa nks (02) vuqPNsn gSaA izR;sd vuqPNsn ij nks iz'u gaSA
izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqus gq, fodYi lgh fodYi gSaA
vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj
pquk gqvk fodYi lgh fodYi gSA
'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
_.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
dsoy fodYi (A) pquus ij +1 vad feysaxs ’
dsoy fodYi (B) pquus ij +1 vad feysaxs ’
dsoy fodYi (D) pquus ij +1 vad feysaxs ’
dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs
63. Which of the following contain at least one non-metal in its highest possible oxidation state?
fuEu es ls fdles de ls de ,d v/kkrq] bldh mPpre lEHko vkWDlhdj.k voLFkk es mifLFkr gS\
(A) A (B) B (C*) C (D) D
64. Solution (C) will not give a precipitate with excess of which of the following?
(A) Borax (B*) NH3 (C) dil. HCl (D) KOH
foy;u (C) fuEu es ls fdlds vkf/kD; ds lkFk vo{ksi ugha nsxk\
(A) cksjsDl (B*) NH3 (C) ruq HCl (D) KOH
Nucleophilic aliphatic substitution reaction is given by those compounds which have electron rich
groups as leaving groups. Less is the basicity of the leaving group, more is its leaving power.
R – L + Nu R – Nu + L
In the given reaction, L is the leaving group which leaves as nucleophile. Nu is the incoming group
which is always nucleophilic in character. The reaction is nucleophilic substitution reaction which can be
unimolecular or bimolecular reaction.
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ukfHkdLusgh ,yhQsfVd izfrLFkkiu vfHkfØ;k mu ;kSfxd }kjk nh tkrh gS ftuesa bysDVªkWu /kuh lewg fu"dkflr lewg
ds :i esa gksA fu"dkflr lewg dh {kkjdrk ftruh de gksrh gS mruh gh vf/kd fu"dklu 'kfDr gksrh gSA
R – L + Nu R – Nu + L
bl vfHkfØ;k esa] L ,d fu"dkflr lewg gS tks fd ukfHkdLusgh ds :i esa”fu"dkflr gksrk gSA Nu ,d vkus okyk lewg
gS tks fd lnSo UkkfHkdLusgh gksrk gSA vfHkfØ;k ,d ukfHkdLusgh izfrLFkkiu vfHkfØ;k gS tks fd ,dk.kwd ;k f}v.kwd
vfHkfØ;k gks ldrh gSA
65. Leaving power of which group is maximum ?
fuEu esa ls fdldh fu"dklu lewg lkEFk;Z lokZf/kd gSA
(A) ” (B*) (C) (D) –Cl
Sol. Leaving group in which the negative charge or lone pair of electrons is stabilized, is a good leaving
group.
og fu"dklu lewg vPNk gksrk gS] ftldk _.kkos'k ;k ,dkdh bySDVªkWu ;qXe LFkkuhd`r gksA
66. Which one of the following is strong base but poor nucleophile ?
fuEu esa dkSu izcy {kkj gS fdUrq nqcZy ukfHkdLusgh gSA
(A) CH3 (B) HO (C) (D*)
Sol. (CH3)3 CO is strong base due to +I effect of three –CH3 group but poor Nu due to steric hinderance.
(CH3)3 CO ,d izcy {kkj gS] rhu –CH3 lewg ds +I izHkko ds dkj.k ijUrq mudh f=kfoe ck/kk ds dkj.k nqcZy
ukfHkdLusgh gSA
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