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Renewable Energy 149 (2020) 1339e1351

Contents lists available at ScienceDirect

Renewable Energy
journal homepage: www.elsevier.com/locate/renene

Oleaginous feedstocks for hydro-processed esters and fatty acids


(HEFA) biojet production in southeastern Brazil: A multi-criteria
decision analysis
Lorena Mendes de Souza a, c, *, Pietro A.S. Mendes b, Donato A.G. Aranda c
a
Centro de Pesquisas e Analises Tecnolo
gicas (CPT), Ag^
encia Nacional do Petroleo, Ga 
s Natural e Biocombustíveis (ANP), Setor de Grandes Areas Norte 603 -
Asa Norte, Brasília, DF, 70830-902, Brazil
b
Ag^encia Nacional do Petroleo, Gas Natural e Biocombustíveis (ANP), Av. Rio Branco, 65 - Centro, Rio de Janeiro, RJ, 20090-003, Brazil
c
Programa de Pos-Graduaça ~o em Engenharia de Processos Químicos e Bioquímicos (EPQB), Escola de Química (EQ), Universidade Federal do Rio de Janeiro
(UFRJ), Av. Athos da Silveira Ramos, 149, Cidade Universita ria, Rio de Janeiro, RJ, 21941-909, Brazil

a r t i c l e i n f o a b s t r a c t

Article history: This work establishes a ranking of the potential oleaginous feedstocks for HEFA biojet production in
Received 27 March 2019 southeast Brazil, and consolidates their advantages and limitations, in order to assist in prioritizing
Received in revised form strategic actions, such as research, R&D investment, and incentives for the most promising regional
28 August 2019
oilseeds. The oilseeds and the criteria considered were determined from a bibliographical review, using
Accepted 22 October 2019
Available online 24 October 2019
two multi-criteria tools in the evaluation: the analytic hierarchy process (AHP) and the Technique for
Order of Preference by Similarity to Ideal Solution (TOPSIS). The economic criterion and the oil cost sub-
criterion were considered the determining factors for the choice of oilseeds, which obtained the
Keywords:
Biojet
following ranking: soybean, jatropha, sunflower, castor bean, macauba palm, cotton, and peanut. Soy-
Hydro-processed Esters and Fatty Acids bean ranked first mainly because of the lower cost of its oil and high agricultural maturity. Hence,
(HEFA) soybean should be used first in HEFA biojet production. However, considering that soybean oil is the
Oleaginous feedstocks main feedstock for biodiesel production in the country, it is also important to evaluate other potential
Multi-criteria decision analysis crops. Thus, stimulating research aimed at reaching the technological domain of new local oleaginous
Analytic hierarchy process (AHP) plants is essential to increase the scale of production, reduce oil costs, and make HEFA production more
Technique for Order of Preference by competitive and sustainable.
Similarity to Ideal Solution (TOPSIS)
© 2019 Elsevier Ltd. All rights reserved.

1. Introduction total international civil aviation carbon emissions above 2020


levels. National emission reduction commitments were taken
The air transport sector accounts for approximately 2% of global through Nationally Determined Contributions (NDCs) under the
greenhouse gas (GHG) emissions [1]. To reduce this contribution, in Paris Agreement signed at the 21st Conference on Climate Change
2009, the International Civil Aviation Organization (ICAO) set the (COP 21). The commitment assumed by Brazil is to reduce its
goal of capping net emissions through carbon-neutral growth from emissions by 37% by 2025 and 43% by 2030, based on 2005 emis-
2020 and cutting net emissions in half by 2050, compared with sions [3]. To honor the commitment, one of the measures of the
2005 [1]. With this in mind, the ICAO, with the participation of Brazilian Government was the creation of the National Biofuels
almost 200 countries, approved the Carbon Offsetting and Reduc- Policy (RenovaBio), in December 2016 [4]. The program aims to
tion Scheme for International Aviation (CORSIA) [2]. The scheme promote the expansion of biofuels in the Brazilian national energy
provides for the limitation and offsetting of any annual increase in matrix [5] via the creation of the Biocarbon Decarbonation Credit
(CBIO), a kind of carbon market coin to price the contribution of
each agent into reduction targets.
The use of biojet produced from renewable feedstocks can
* Corresponding author. Centro de Pesquisas e An alises Tecnolo gicas (CPT),
^ncia Nacional do Petro
Age leo, G
as Natural e Biocombustíveis (ANP), Setor de contribute to achieving these ambitious targets [6e10] due to its

Grandes Areas Norte 603 - Asa Norte, Brasília, DF, 70830-902, Brazil. potential to reduce CO2 emissions by up to 80% throughout the life
E-mail addresses: lmsouza@anp.gov.br, enamendes@hotmail.com (L.M. de cycle of biojet production and use [1]. Nevertheless, the use of
Souza), pmendes@anp.gov.br (P.A.S. Mendes), donato@eq.ufrj.br (D.A.G. Aranda).

https://doi.org/10.1016/j.renene.2019.10.125
0960-1481/© 2019 Elsevier Ltd. All rights reserved.
1340 L.M. de Souza et al. / Renewable Energy 149 (2020) 1339e1351

biofuels in Brazilian aviation is still negligible because they are different conclusions. Thus, in the search for better results, the
considered to have low competitiveness with fossil jet fuels [11,12]. authors [49] specify that it is essential to differentiate a good de-
This is because there are so many challenges to be overcome in the cision from a lucky decision. The first is based on a rational process,
biojet market [10e22]. One in particular relates to feedstock for this resulting from the analysis of different variables. However, the
form of biofuel production [7,13,23]. Connelly et al. [13] identified second is not necessarily made based on a rational and safe process,
the main actions necessary to promote the biojet market across the but is simply a decision that, luckily, brings a good result. According
world. Out of 37 actions ranked based on multi-criteria analysis, the to the authors, from a normative point of view, the first differs from
most important was ‘investing in research to reach more produc- the second because it is the result of a rationally elaborated process
tive feedstock’. that can be repeated and will bring the same results of analysis.
To address this challenge, several studies have been conducted Thus, it is important to create a framework for analysis that will
to solve the technical and economic challenges related to feed- provide decision-makers with guidance on the best way forward
stocks for hydro-processed esters and fatty acids (HEFA) biojet from the various variables involved. An interesting tool for this
production [24e32]. Although these studies seek to mitigate this judgment is multi-criteria decision analysis (MCDA), which can be
bottleneck, there are no studies comparing the raw materials for very useful in decision-making processes that involve prioritizing
biojet production from multiple aspects, that is, from multi-criteria one alternative over others in a situation in which decisions need to
evaluation. Studies of this nature have already been carried out be guided by objective and transparent technical criteria [50,51].
around the world for biodiesel production, a more mature market Decisions involving complex issues with high uncertainty, con-
than the biojet market [33e38], and for bioenergy production in flicting objectives, and multiple interests and perspectives are
Africa [39]. taken efficiently from MCDA [52e54].
For a multi-criteria evaluation of bioenergy feedstocks for biojet Several MCDA tools are available, and it is almost impossible to
production in Brazil, it is necessary to first define the production decide which one is the best method [55]. Løken [54] states that the
process, as different processes are associated with the use of ideal one must be easy to use and to understand. Two important
different feedstocks. In terms of process complexity, yield, market multi-criteria tools that satisfy this are the analytic hierarchy pro-
maturity, and economic viability, the most advantageous biojet cess (AHP) and the Technique for Order of Preference by Similarity
production process among all internationally approved processes is to Ideal Solution (TOPSIS) [56,57]. The AHP, one of the most recent
the HEFA [40e43], produced by hydrotreatment of oil such as and talked-about MCDA techniques, can efficiently handle tangible
vegetable oil. Brazil, although not yet producing biojet, already has as well as intangible criteria [55]. TOPSIS is more efficient in
great experience with hydrotreating. This technological process is handling tangible attributes, and there is no limit in terms of
already used in Petrobras’ Brazilian oil refineries to remove sulfur, number of criteria or alternatives [55]. Previous studies [56e63]
nitrogen, oxygen, and aromatics from mineral diesel. In addition, in have already used the combination of these tools in decisions
2006, Petrobras patented a renewable diesel production technol- involving renewable energy.
ogy (H-Bio), by adding up to 10% vegetable oil to the diesel-refining Against this background, this work aims to rank the potential
process in the hydrotreating units [44]. Petrobras is today the oleaginous feedstocks for biojet production in the Brazilian region
leading company with the expertise and infrastructure to start with the highest consumption of fossil jet fuel: southeast Brazil
biojet production in the country, and will certainly be the pioneer [48], and consolidates their advantages and limitations. The present
in the production of this biofuel in Brazil. The current context of work complements the study by Souza et al. [12], which reviewed
national and international pressure to reduce aviation emissions the current scenario of the Brazilian biojet market, as well as its
has created an opportunity for the company to include biofuel main uncertainties. The authors [12] made recommendations to
production in its investment plan. In December 2018, Petrobras’ mitigate these uncertainties, including a multi-criteria evaluation
Board of Directors approved the Business and Management Plan for to select feedstocks for biojet production. Besides contributing to
2019 to 2023, which signals Petrobras’ participation in biojet pro- the mitigation of the main bottleneck of this market, the study will
duction in plants integrated with oil refineries [45]. The evaluation allow decision-makers, stakeholders, and researchers to direct
of strategic feedstocks, in this case, may assist Petrobras in making policies, investment, and research to the most promising oleagi-
the biojet production project viable, based on the technical analysis nous feedstocks in a strategic way, based on technical criteria. The
of oilseeds, which represents about 70% of the total cost of biojet proposed study is one of the actions that aims to position Brazil as a
production. world leader in biojet production and use, contributing to the
To evaluate potential oleaginous feedstocks for HEFA biojet achievement of the national and international goals of GHG
production in Brazil, it is also important to consider the use of reduction and also to regional development, through the genera-
regional crops in specific production systems, as each region has a tion of employment, income, and development of the regional in-
soil and climate that favors a different type of feedstock cultivation dustry. Beyond that, this work may guide future studies of multi-
[46]. Diversification of production at the regional level should be criteria analysis which seek to select oleaginous feedstock for bio-
considered not only due to climatic, market, infrastructure, and jet production in other regions and countries.
regional development differences, but also due to logistic issues
[47]. Of the five Brazilian regions, the southeast of Brazil has the 2. Aspects of production, quality, and regulation of biojet in
largest concentration of consumption of fossil jet fuel, 64% in 2017 Brazil
[48]. The use of local feedstocks in this region can facilitate the
production of biojet around this large consumer center. Given the Biojet can be obtained through different production processes,
wide range of vegetable oil feedstocks available for biojet produc- including: 1. chemical processes, through the hydroprocessing of
tion in the southeast region, it is necessary to consider the advan- oils; 2. biochemical processes, from the use of genetically modified
tages and limitations of each one, based on efficient technical yeast or bacteria; and 3. thermochemical processes, from cracking,
criteria, to judge the best alternative. Furthermore, choosing the gasification, and catalytic synthesis [11]. However, not all biojet
best alternative from multiple technical criteria is critical in helping production processes are approved for production and use in
decision-makers direct efforts, resources, investment, and research. aircraft. To approve a new process, American Society for Testing and
Clemen [49] indicates that decision-making is a complex pro- Materials (ASTM) International approval is required based on tests
cess because it involves different perspectives that may lead to provided by ASTM D4054 [64]. Once approved, the specification is
L.M. de Souza et al. / Renewable Energy 149 (2020) 1339e1351 1341

included in ASTM D7566 [65], which sets out the minimum quality fractions, or steam reforming of light fractions and natural gas [70].
requirements of alternative jet fuel. In Brazil, ANP Resolution 778/ There is also the possibility of integrating non-petroleum hydro-
2019 [66], which is based on the ASTM approval process, provides carbon gasification processes, such as biomass, for combined-cycle
the quality regulation of this fuel. electricity generation (integrated gasification combined cycle, or
Currently, only five alternative jet fuels are approved by ASTM IGCC) producing hydrogen [70,71].
International, and consequently by Brazil [65,66]: FischereTropsch Finally, it is noteworthy that the HEFA biojet produced from the
Synthesized Paraffinic Kerosene (FT-SPK) and Aromatic process described above must meet the minimum quality re-
FischereTropsch (FT-SPK/A), produced by the thermochemical quirements of ASTM D7566 [65] and ANP Resolution 778/2019 [66],
method; Synthesized Iso-Paraffins (SIP) and Aviation Fuel Alcohol regardless of the oil used as feedstock. This is because ASTM defines
(ATJ-SPK), produced by the biochemical method; and Synthesized the HEFA biojet as paraffin kerosene obtained by the hydrogenation
Paraffinic Kerosene of Hydroprocessed Esters and Fatty Acids of free fatty acids and fatty acid esters that meet the expected
(HEFA), produced by the chemical method. All can be considered specification. Thus, any fatty acids from different oils can be used,
biojet if renewable raw material is used. Biojets produced by other requiring process adjustments, such as a more severe pretreatment
processes, such as hydrothermolysis, fast pyrolysis and hydro- of oil to remove acidity or a higher demand for hydrogen to saturate
deoxygenation, are under testing at ASTM and have not yet been the chain, so that the final product meets the stated specification.
approved [67].
As presented in section 1, of the five approved routes, the HEFA 3. Methodological procedures
biojet is the most advantageous in terms of process complexity,
yield, market maturity, and economic viability. Neuling and 3.1. Oleaginous feedstocks evaluated
Kaltschmitt [40] evaluated the complexity of the processes
involved in biojet production, and concluded that HEFA is the least In Brazil, several crops with high oil content and high energy
complex process because it is the only conversion pathway that density are being evaluated for HEFA biojet production. To choose
uses direct biosynthesis. The authors [40] also state that HEFA is the the oilseeds to be evaluated in this work, research was conducted
process that results in the best yields, also contributing to a more on studies published in peer-reviewed journals in the last 15 years
mature biojet in the global market. Vonortas and Papayannakos (January 2002 to January 2017) from the Scopus database that cite
[43], and Vasquez et al. [42], indicate that HEFA is the most widely oilseeds for biojet production in Brazil. To make the review more
used biojet production process because it can be used in existing efficient, an advanced search using the conjunctions “AND” and
refinery infrastructure. De Jong et al. [41] evaluated the short-term “OR” was considered. The term “biojet”, commonly used to refer to
economic viability of biojet production routes and concluded that aviation biofuels, is not a ubiquitous term in the literature. Different
the HEFA process is the best short-term option because the tech- studies use various terms such as “biokerosene”, “renewable avia-
nology has lower costs. tion fuel”, “alternative aviation fuel”, and others. In addition, the
The HEFA process involves triglyceride hydrogenation and terms “oilseed” and “vegetable oils” can be used to describe high-
deoxygenation reactions in the presence of catalysts to remove oil raw materials in their composition. Thus, the following key-
unsaturated carbon chains and oxygen from fatty acids. The words were considered: (biojet OR “aviation biofuel” OR “renew-
removal of unsaturated carbon chains considerably improves the able jet fuel” OR “aviation renewable fuel” OR “renewable aviation
stability of the final fuel. In turn, the removal of oxygen ensures low fuel” OR biokerosene OR “alternative aviation fuel” OR “alternative
reactivity with water and increased calorific power. These reactions jet fuel” OR “alternative kerosene”) AND (“oilseeds” OR “oilseed”
occur under temperature conditions ranging from 250 to 450  C OR “vegetable oils”) AND (brazil*). The asterisk (*) was used in
and hydrogen pressure of 10e300 bar, depending on the reactor “brazil*" because it allows searching for all variations of the term.
configuration and catalyst used [68]. Because lipids generally have Thus, the terms “brazil”, “brazilian”, and “brazilians” were included.
mostly aliphatic chains containing 16 to 20 carbon atoms, the From the search, 55 articles were found and 25 were selected for
deoxygenation process leads to the formation of long-chain hy- citing at least one oilseed for biojet production in Brazil. The
drocarbons that need to be broken down into smaller and more feedstocks available in the southeast region of Brazil that were
branched chains. The ramifications considerably favor the reduc- most cited in the selected works were: soybean (16 references),
tion of biojet freezing temperature, as required by aircraft subjected followed by jatropha (14 references), sunflower (11 references),
to high altitudes and low temperatures [69]. Thus, in addition to peanut (7 references), cotton (6 references), and castor bean (5
hydrogenation and deoxygenation, an additional or simultaneous references). In addition to the six most cited feedstocks, macauba
step involving cracking and isomerization reactions is required palm was included in the assessment due to the Pro-macauba Law
[68]. In the isomerization step, linear hydrocarbons are converted (Law No. 19,485, of January 13, 2011) [72], which established the
to branched species of the same molecular formula in the presence state policy to encourage cultivation, extraction, marketing, con-
of a catalyst. Several types of catalysts can be employed in both sumption and processing of macauba. The law aims to stimulate
cracking and isomerization, such as sulfonated metals, noble and make the macauba supply chain sustainable for biojet pro-
metals, bimetallic materials, and oxides [68]. Metal-based catalysts duction in the country.
are generally the most efficient for deoxygenation reactions. By Table 1 shows the oleaginous feedstocks evaluations, as well as
contrast, acid catalysts act mainly in cracking and isomerization the references consulted.
reactions [68].
For biojet HEFA production, it is ideal that vegetable oil has few 3.2. Setting the assessment criteria and sub-criteria
unsaturation. The more saturated the oil, the lower the hydrogen
consumption in the hydrogenation step. The hydrogen required in To select the criteria and sub-criteria, the authors searched
the HEFA biojet production steps can be generated by water elec- through the scientific articles of the Scopus database for the main
trolysis, catalytic reforming, or synthesis gas separation. Thus, for desirable parameters for the success of oleaginous feedstocks in
the short-term viability of HEFA biojet production in Brazil, it is HEFA biojet production. The search was based on studies published
essential to use the infrastructure of existing mineral oil-refining in peer-reviewed journals in the last 15 years (January 2002 to
units. This is because the refineries already have hydrogen pro- January 2017). The following keywords were used: (biojet OR
duction plants based on partial oxidation of heavy hydrocarbon “aviation biofuel” OR “renewable jet fuel” OR “aviation renewable
1342 L.M. de Souza et al. / Renewable Energy 149 (2020) 1339e1351

Table 1
Oleaginous feedstocks evaluated.

Oleaginous Feedstocks Name References

Cotton (Gossypium sp.) F1 [19,20,73e76]


Peanut (Arachis hypogaea L.) F2 [19,20,73,75e78]
Sunflower (Helianthus annuus L.) F3 [10,16,19,73e80]
Macauba palm (Acrocomia aculeata.) F4 [76,81]
Castor bean (Ricinus communis L.) F5 [20,73,76,82,83]
Jatropha (Jatropha curcas L.) F6 [19e21,40,75e78,83e88]
Soybean (Glycine max L.) F7 [10,16,19e22,40,73e77,80,83,87,89]

fuel” OR “renewable aviation fuel” OR biokerosene OR “alternative principle, and (d) synthesizing priorities. The hierarchical struc-
aviation fuel”) AND (hydroprocessed OR hydroprocessing OR turing step consists of the problem formulation, that is, the defi-
hydrotreatment OR hydrogenated OR hydrogenation) AND (“oil- nition of the overall objective and decomposition of the system into
seeds” OR “oilseed” OR 00 vegetable oils”). From the search, 78 pa- levels of hierarchy [121]. In the problem in question, the objective
pers were found and 21 were selected for containing at least one of the AHP problem is to define the weight of each sub-criterion,
desirable parameter for the selection of oilseeds for the HEFA biojet which is used in the subsequent application of the TOPSIS method.
production process. Beyond that, desirable parameters for this In pairwise comparison, Saaty [120] recommends the use of a
purpose were searched in publications in Brazilian government numerical scale ranging from 1 to 9. The value 1 means no differ-
institutions: the Ministry of Mines and Energy (MME), Ministry of ence in importance of one criterion over the other. The value 9
Agriculture, Livestock and Supply (MAPA), and Brazilian Agricul- means the extreme importance of one criterion over another. The
tural Research Corporation (Embrapa). Criteria and principles of numbers 2, 4, 6, and 8, in turn, represent the intermediate stages of
international sustainability standards such as the Roundtable on importance between levels. The assessment indicates how one
Sustainable Biomaterials (RSB), Global Bioenergy Partnership criterion is more important than another, or at the level of sub-
(GBEP), and International Sustainability and Carbon Certification criteria, how one sub-criterion is more important than another. It
(ISCC) were also considered. Table 2 presents the criteria and sub- should be noted that Saaty [120] also proposes an evaluation of the
criteria chosen, the references consulted, as well as the desired consistency of the judgments, considering 0.10 as the maximum
solution (i.e. whether it is desirable to minimize or maximize the inconsistency recommended in the judgments of the decision-
value of the sub-criterion). makers.
In this study, 42 biojet specialists from different areas (business
3.3. Criteria and sub-criteria weighting sector, government, research institutions, and non-profit in-
stitutions) were invited to respond to the form containing pairwise
The multi-criteria AHP, proposed by Saaty [118], was chosen to comparison. Initially, many experts were invited so that at least one
weight the defined criteria and sub-criteria. This method was representative from each area could respond to the form, making
chosen because it is based on mathematics and psychology [119], the research unbiased. Of the 42 invited, 18 answered, of whom 6
which allows the comparison of qualitative criteria, also consid- were from the business sector, 6 from the government, 3 from
ering the subjective aspects of the decision-making. Saaty [118] research institutions, and 3 from non-profit institutions. It is
introduced the idea that a decision-maker can use a pairwise noteworthy that the non-participation of some of the 42 invited
comparison mechanism to give weight to the criteria and sub- experts did not compromise the research, as there were re-
criteria as they do not necessarily have the same importance. spondents from across all areas. In surveys involving AHP, there is
The problem in AHP analysis is divided into a hierarchy of no minimum or maximum requirement for responses from experts.
descending levels, each of which can be decomposed into new For example, in previous AHP assessments involving bioenergy, the
levels [120]. Al-Harbi [121] summarizes the process in four basic study by Aras [122] and Majumdar [55] was conducted with only
steps: (a) hierarchical structuring, (b) applying the parity compar- one expert for pairwise comparison of criteria, Karahalios’s work
ison of elements at each level of the system, (c) prioritization [57] was conducted with 10 experts, Khang [34] with 18 experts,

Table 2
Criteria and sub-criteria evaluated.

Criteria Name Ref. Sub-criteria Name Ideal Solution References

Economic C1 [90e92] Oil Cost SC1 Minimize [7,14,93e97]


Oilseed Cost SC2 Minimize [7,14,93,94,96,98]
Environment C2 [90e92] Land use: oilseed productivity SC3 Maximize [7,46,94,96,97,99e105]
Land use: oil yield SC4 Maximize [7,14,94,96,97,100,103,104]
Water requirements SC5 Minimize [14,91,92,98,102,106e108]
Social C3 [90e92] Extractivism dependence SC6 Minimize [102,107,108]
Oil food dependence SC7 Minimize [14,92,95,99,106,108]
Production Scale C4 [7,101] Annual agricultural production SC8 Maximize [92,93,97,101,109]
Planted area SC9 Maximize [7,94,96,98,101,102,110,111]
Oil content SC10 Maximize [46,93,94,96e99,102e105,109,112]
Harvest period (seasonality) SC11 Maximize [46,93,94,97,102]
Registered cultivars SC12 Maximize [94,101,102,111]
Oil and oilseed quality C5 [113,116] Oil Net Calorific Value SC13 Maximize [7,19,93,100,113e115]
Oil acidity SC14 Minimize [103,113,117,129]
Oil moisture SC15 Minimize [100,103,113,129]
Saturated fatty acids content in oil SC16 Maximize [19,102,103,117]
Oilseed moisture SC17 Minimize [92,104]
L.M. de Souza et al. / Renewable Energy 149 (2020) 1339e1351 1343

and Ziolkouwska [33] and Mendes [123] with 20 experts. criterion considered most important was the economic one, with a
The 18 expert responses to the paired comparison form allowed level of importance of 28.16%. The oil and oilseed quality and the
the application of the AHP method to determine the relative production scale reached second and third place in the prioritiza-
importance of each criterion and sub-criterion. tion of the criteria, reaching 25.42% and 21.85%, respectively. The
least important criterion according to the specialists consulted was
3.4. Evaluation of alternatives social, with 8.97%.
The assessment by groups shows that the specialists are aligned
The multi-criteria method Technique for Order of Preference by in their preference for the main sub-criterion. All sectors under-
Similarity to Ideal Solution (TOPSIS) was used to establish the stand that the cost of oil is the most important attribute for crop
oleaginous feedstock ranking. The TOPSIS algorithm, developed by selection for HEFA biojet. The group of specialists from non-profit
Hwang and Yoon [124], is a technique for evaluating performance institutions was the most dissociated from the other groups, giv-
of alternatives through similarity with an ideal solution. According ing high weight to the planted area and annual agricultural
to this technique, the best alternative is the one closest to the ideal production.
solution and furthest away from the non-ideal solution [125,126]. To evaluate the consistency of the responses, consistency tests
TOPSIS assumes that the positive ideal solution (PIS) is the one that were applied to the groups of specialists. The results obtained
maximizes the benefit criteria (the ideal solution is the one with geometrically indicate that the groups of specialists were consis-
the highest possible value, such as “oil content”) and minimizes the tent, demonstrating the following average consistency levels:
criteria for losses (the ideal solution is the one that has the lowest business sector: 0.05, government: 0.06, research institutions: 0.09,
possible value, such as “oil cost”). The negative ideal solution (NIS), non-profit institutions: 0.08. As such, according to Saaty’s method,
in turn, maximizes the criteria for losses and minimizes those for the results were deemed valid (with average consistency of less
benefits [124]. than 0.10) [120].
According to the basic concept of this tool, the best oleaginous
feedstock will be the one closest to the PIS and furthest away from 4.2. Evaluation of alternatives: TOPSIS application
the NIS [127]. This premise defines the similarity coefficient, ob-
tained by combining the Euclidean distances in relation to the ideal Regarding the economic criterion, the best performance in
positive and negative solutions, which was used to establish the terms of oil cost was obtained by soybean. The cost of soybean oil in
feedstock ranking. For the method’s application it is necessary to the southeast is US$691.1 per ton, five times lower than the cost of
know the performance of each sub-criterion in relation to each peanut oil, for example. The oilseed cost, in turn, performed better
alternative (oleaginous feedstocks), initially constructing a perfor- than that of the macauba palm, which costs US$61.9 per ton of the
mance matrix. crop. The castor bean, whose oil costs US$ 283.15 per ton, per-
The data collection for the performance matrix was initially formed worst on this issue.
based on the research carried out to identify oilseeds in Brazil, For the environmental criterion, the macauba palm was distin-
which included peer-reviewed articles published in the last 15 guished by its efficiency in use of land, characterized by produc-
years (January 2002 to January 2017) from the Scopus database. The tivity of oilseed and yield in oil. The productivity of this oilseed can
following keywords were considered: (biojet OR “aviation biofuel” reach 24,000 kg/ha and its oil yield can reach 4 tons/ha, much
OR “renewable jet fuel” OR “aviation renewable fuel” OR “renew- higher than the other feedstocks evaluated. Second position in
able aviation fuel” OR biokerosene OR “alternative aviation fuel” OR terms of productivity and yield was occupied by jatropha. It has a
“alternative jet fuel” OR “alternative kerosene”) AND (“oilseeds” OR maximum productivity four times lower than that of macauba, and
“oilseed” OR “vegetable oils”) AND (brazil*). The search identified its oil yield is three times smaller. On the other hand, the water
78 papers, which were minimally evaluated to collect the data requirement of the macauba palm is the highest among all. Cotton,
needed to construct the performance matrix of the feedstocks for peanut, sunflower, castor bean, jatropha, and soybean all require an
each sub-criterion. As this is a developing area of research, with few average of 600 mm of rainfall per crop cycle, while macauba palm
works exclusively focused on biojet production in Brazil, the pub- requires 1750 mm.
lished and peer-reviewed scientific papers were not enough to fill For the social criterion, high dependence on the extractivism of
the entire performance matrix. Thus, the research was redone, also the macauba palm and jatropha assured low performance of these
including publications by Brazilian government institutions, mas- oleaginous feedstocks, as it is expected that the use of cultures for
ter’s dissertations, and doctoral theses. energetic purposes could negatively affect families that depend on
Table 3 presents the performance matrix (rating value) of the extractivism for survival. Castor bean and jatropha showed better
feedstocks for each sub-criterion, and the consulted references. performance in terms of oil food dependence as they are non-edible
Fig. 1 summarizes the multi-criteria problem evaluated. crops.
Regarding the “scale of production”, soybean stands out in the
4. Results sub-criteria of annual agricultural production, planted area, and
registered cultivars. Annual soybean production in the region is
4.1. Weighting of the criteria: AHP application 7375 thousand tons per year and the planted area is 2300 thousand
hectares. Other crops, however, have negligible annual yield and
Tables 4 and 5 show the weights of the criteria and sub-criteria planted area. In terms of technological domain, soybean stands out
obtained from the AHP evaluation by expert groups and the overall with 1674 cultivars registered. Cultivars are species of cultures
preferences, considering the AHP evaluation from the responses of improved by man, possessing characteristics that the original did
the 18 biojet specialists. not possess [88]. The second-largest crop in terms of registered
For the group of experts from the business sector, government cultivars is sunflower, with 265 registered cultivars. Macauba palm
and research institutions, the criterion considered of greatest and jatropha presented the worst performance in this sub-
importance was the economic one. For the specialists from non- criterion, with only one cultivar recorded for each species. Soy-
profit institutions, the scale of production was considered the bean did not perform better in terms of oil content or seasonality.
most important criterion. All the respondent groups considered the The average oil content in peanut, sunflower, macauba palm, and
social criterion of least importance. From the overall evaluation, the castor bean is 43% m/m, higher than the average of 20% in cotton
1344 L.M. de Souza et al. / Renewable Energy 149 (2020) 1339e1351

Table 3
Oleaginous feedstocks performance matrix (raiting value).

Sub-Criteria Oleaginous Feedstocks

F1 F2 F3 F4 F5 F6 F7
a
SC1 Value (US$/ton) 1592.9 3493.2 1746.6 928.3 1967.6 774.9 691.1
Reference [128] [128] [128] Adapted from Ref. [129] [128] [130] [128]
SC2 Value (US$/ton) 233.1 184.8 283.1 62.0 604.9 113.2 243.9
Reference [128] [131] [128] [132] [132] [130] [132]
SC3 Value (kg/ha) 2069 3030 1041 24000 1151 6000 3224
Reference [133] [134] [134] [135] [134] [136] [134]
SC4 Value (t/ha) 0.361 0.78 0.66 4 0.75 1.5 0.56
Reference [133] [133] [133] [137] [136] [138] [133]
SC5b Value (mm) 575 648 600 1750 700 600 650
Reference [139] [140] [141] [137] [110] [142] [139]
SC6c Value (Dimensionless) 0 0 0 1 0 1 0
Reference [143] [143] [143] [144,145] [143] [146] [143]
SC7d Value (Dimensionless) 0 0 0 0 1 1 0
Reference [147] [147] [147] [148] [149] [149] [147]
SC8 Value (103t/ano) 58.1 418.37 8.49 0 0.24 0 7375.33
Reference [133] [134] [134] [150] [134] [150] [134]
SC9 Value (103ha) 28.1 118.78 8.15 0 0.23 0 2300.73
Reference [133] [134] [134] [150] [134] [150] [134]
SC10e Value (%m/m) 19 45 43 43.45 45 35.5 20
Reference [133] [133] [133] Adapted from Refs. [151,152] [133] [153] [133]
SC11 Value (months) 3 3 3 4 3 12 3
Reference [154] [137] [137] [155] [137] [138] [137]
SC12 Value (Dimensionless) 176 29 265 1 39 1 1674
Reference [156] [156] [156] [156] [156] [156] [156]
SC13 Value (Kcal/l) 8050 8000 7950 8529 8000 8021 8125
Reference [157] [157] [100] [158] [100] Adapted from Ref. [159] [157]
SC14f Value (mg de KOH/g) 6.11 2.0 0.18 57.45 12.33 15.12 1.71
Reference [160] [161] [120] Adapted from Refs. [151,152] [162] [163] [164]
SC15f Value (% m/m) 0.20 0.06 0.04 0.80 0.41 0.37 0.27
Reference [165] [166] [16] Adapted from Refs. [151,152] [162] [163] [167]
SC16f Value (%m/m) 29 20 11 20.35 2.95 20.3 14.3
Reference [168] [168] [169] Adapted from Refs. [151,152] [170] [171] [172]
SC17 Value (%m/m) 10.45 7 5.8 34.75 6.47 6.8 9.5
Reference [173] [174] [175] [152] [176] [177] [178]
a
The cost of vegetable oil refers to refined oil due to the lack of quotation of some oils in nature (crude). This consideration does not compromise the analysis of the sub-
criterion, since standardization was done for the quotation of refined oil in all crops analyzed.
b
The water demand for crop was evaluated in terms of rainfall, since the greater demand for rainfall increases the demand of crop for irrigation. Thus, the water demand per
cycle of the crop was considered as indicative of the need for additional irrigation.
c
To make this quantitative criterion, value 1 was assigned to crops with a high dependency on extractivism, 0.5 for crops with some type of dependence on extractivism, but
the crop is also destined to agroindustry, and 0 for commercial crops with low or no dependence on extractivism.
d
To make this quantitative criterion, value 1 was assigned to crops producing edible oil, which is therefore used in the food industry, and value 0 for crops whose oil is not
edible, i.e. unfit for human consumption.
e
The oil content was established on a dry basis.
f
To determine the acidity, moisture content and saturated fatty acids in the oil, the crude oil (in nature) of the oleaginous was considered.

and soybean, and 35.5% in jatropha. In terms of seasonality, jatro- 5. Discussion


pha stands out as a perennial crop, which can be harvested
throughout the year once planted. The economic criterion and the oil cost sub-criterion, chosen as
Regarding oil and oilseed quality, all raw materials evaluated, the most important in the general evaluation of the experts, agrees
with the exception of macauba palm, presented similar behavior. with Anderson et al. [15], who stated that the viability of HEFA will
The macauba palm had the lowest performance in oil acidity, and in be set by vegetable oil price. The economic viability of HEFA biojet
oil and oilseed moisture. In relation to the content of saturated fatty is linked to the production cost of this fuel [17,87]. Of the total cost,
acids, the castor bean presented the worst behavior, as it has a high about 70% is represented by feedstock cost [7,15,179]. The greater
content of unsaturated fatty acids in its oil, requiring a greater weight attributed by non-profit organizations to scale of produc-
amount of hydrogen in the hydrogenation stage of the HEFA tion can be explained by the profile of these institutions. In Brazil,
process. most of the NPOs related to biojet are formed by representatives of
Based on the performance matrix (Table 3) and the final weight the production chain of the raw material, that is, representatives
(across all specialists) established for each criterion (Table 4) and who are concerned with the production scale gain of feedstocks.
sub-criterion (Table 5), the TOPSIS method was applied, establish- The TOPSIS tool provided the following ranking of oleaginous
ing the following final ranking: soybean (F7), jatropha (F6), sun- feedstocks in southeast Brazil, in descending order: soybean,
flower (F3), castor bean (F5), macauba palm (F4), cotton (F1), and jatropha, sunflower, castor bean, macauba palm, cotton, and pea-
peanut (F2), as shown in Table 6. nut. Soybean was ranked highest due to its high performance in oil
From Table 6 it is possible to observe the rank similarity ob- cost, water requirements, extractivism dependence, registered
tained from the evaluation of each group. Soybean and jatropha cultivars, planted area, annual agricultural production, and good oil
occupied the first and second rank in all groups. Peanut, by contrast, and oilseed quality. Although the groups of specialists assigned
took the last position in all evaluations. different weights to the sub-criteria, similarity in the rankings of
feedstocks per group was evidenced. Soybean and jatropha
L.M. de Souza et al. / Renewable Energy 149 (2020) 1339e1351 1345

cost of this oil (due to its high required quality for the food in-
dustry) compromises its use for energy purposes [182]. The
development of new pest-resistant cultivars is a way to reduce oil
costs, making it more attractive for biojet production. Regarding
the oil cost of jatropha, although there is still no commercial pro-
duction in the southeast of Brazil, the low cost of oil can be
explained by the low cost of this feedstock production, and high
availability in its native form. Jatropha is a native crop that is easy to
grow, with high resistance to drought, and it adapts to various
fertile soils [183].
Regarding soybean, the large market of this oilseed in Brazil
allows the cost of oil to be lower than the other oleaginous feed-
stocks evaluated. Since the early 1970s, soybeans have boosted
Brazil’s agricultural development, and became the most exported
product in the country [184]. Unlike traditional agriculture, soy-
bean agribusiness is loaded with modernity, capital-intensive, and
has a high level of technology integrated into its production process
[185], as can be verified by its number of registered cultivars (1674).
This number shows that this oilseed has a technological dominance
when compared to any of the other crops evaluated.
Cantarella et al. [7] reviewed the main feedstocks for biojet
production in Brazil, based on an evaluation focused on the costs
involved and technical efforts required. Among the evaluated
Fig. 1. Multi-criteria structure to rank oleaginous feedstocks for HEFA biojet produc-
feedstocks (lignocellulosic, oilseeds, waste, sugar, and starches), the
tion in Southeastern Brazil.
authors concluded that the production of biojet from oleaginous
feedstocks (HEFA process) would be the first to reach commercial
occupied the first and second position in the rankings obtained scale. The authors also concluded that among the oil crops, soy-
from all the groups. Peanut occupied the last position unanimously. beans would remain the most viable option of feedstock for biojet
This similarity is explained by the high weight attributed by all in the short term. However, considering that soybean is currently
groups to the cost of the oil. Soybean oil and jatropha cost US$691.1 the main feedstock for biodiesel production, it is important to
and US$774.9 per ton, respectively. Peanut oil, by contrast, is five consider additional oleaginous feedstocks for biojet production, as
times more expensive, costing US$3493.2 per ton. it is not strategic for the country to rely on only one source, because
The high cost of peanut oil is explained by the high production the two sectors would compete with each other [112]. In addition to
cost of the crop [180], of which 25% corresponds to the expense of soybean, other crops already have a relatively high level of pro-
the application of agricultural pesticides [181]. Besides, the high duction scale, such as sunflower, castor bean, peanut and cotton.

Table 4
Weight (%) of the criteria based on the evaluation of each specialists group.

Criteria Business sector Government Research institutions Non-profit institutions Overall specialists

C1 32.18 31.49 29.24 18.54 28.16


C2 17.78 17.57 15.45 12.43 15.60
C3 8.09 8.22 7.42 11.76 8.97
C4 16.63 21.80 18.57 31.23 21.85
C5 25.32 20.93 29.33 26.04 25.42

Table 5
Weight (%) of the sub-criteria based on the evaluation of each specialists group.

Sub-criteria Business sector Government Research institutions Non-profit institutions Overall specialists

SC1 24.96 24.35 23.36 15.93 22.65


SC2 7.21 7.14 5.87 2.62 5.51
SC3 3.66 3.88 3.73 2.59 3.47
SC4 6.51 7.32 3.52 5.63 5.63
SC5 7.61 6.36 8.20 4.21 6.49
SC6 5.59 2.14 1.89 4.50 3.50
SC7 2.50 6.08 5.53 7.26 5.47
SC8 1.52 3.76 4.66 10.36 4.60
SC9 1.54 4.54 3.37 10.20 4.45
SC10 6.61 7.88 6.30 2.85 6.25
SC11 2.64 3.55 2.98 3.83 3.62
SC12 4.32 2.07 1.26 3.98 2.92
SC13 5.39 3.88 7.35 6.52 5.79
SC14 4.35 3.71 5.8 7.08 4.67
SC15 4.64 4.18 3.84 4.95 4.40
SC16 6.54 4.65 8.57 4.75 5.73
SC17 4.39 3.76 4.33 3.29 4.03
1346 L.M. de Souza et al. / Renewable Energy 149 (2020) 1339e1351

Table 6
Ranking of oleaginous feedstocks for HEFA biojet production in Southeastern Brazil.

Feedstock Business sector Government Research Non-profit Overall specialists


institutions institutions

Ciþ Rank Ciþ Rank Ciþ Rank Ciþ Rank Ciþ Rank

Cotton (F1) 0.525 5 0.434 6 0498 5 0.343 5 0.474 6


Peanut (F2) 0.371 7 0.354 7 0.400 7 0.277 7 0.363 7
Sunflower (F3) 0.577 3 0.509 3 0.499 4 0.347 4 0.518 3
Macauba (F4) 0.538 4 0.472 5 0.493 6 0.309 6 0.489 5
Castor bean (F5) 0.510 6 0.474 4 0.505 3 0.378 3 0.492 4
Jatropha (F6) 0.627 2 0.565 2 0.612 2 0.404 2 0.590 2
Soybean (F7) 0.662 1 0.608 1 0.627 1 0.697 1 0.635 1

The production of these oleaginous feedstocks in southeast Brazil, oil. The current extractivist form of obtaining this crop compro-
although small, makes these crops promising alternatives for biojet. mises the quality of its oil [190]. Macauba and jatropha should be
Sunflower, after soybean, is the oilseed among the evaluated ones considered in studies of genetic improvement, so they can also
which has the second-highest number of cultivars registered by become viable for biojet production.
MAPA, and it has a high oil content of 43%. However, the cost of its Castor bean, another non-edible plant, also has the advantage of
oil is still high (US$1746.6 per ton). not competing with food production. Moreover, it is an unde-
In addition to crops commercially produced in Brazil, the native manding oilseed that grows very well in tropical conditions and
plants jatropha and macauba palm (still without planted area in the provides high oil yields [191]. Castor bean is the plant with the
country) have potential for biojet mainly due to their high pro- highest oil content among the evaluated oleaginous feedstocks,
ductivity, oil yield, and oil content. The oil content of macauba palm reaching 45% m/m. However, the high cost of its oil makes it un-
reaches 43.45% m/m, and 35.5% m/m in jatropha, compared to only feasible for biojet production purposes.
20% m/m in soybean. Further, these oleaginous plants have high Each oleaginous feedstock has some advantage over the others,
productivity and yield, which guarantees them high efficiency in as observed in the performance distribution shown in Table 3.
land use. The productivity of macauba palm reaches 24000 kg/ha, There is no perfect isolated feedstock to produce an aviation biofuel
and 6000 kg/ha in jatropha, compared to only 3224 kg/ha in soy- in Brazil. All have advantages and limitations, and the ideal scenario
bean. The oil yield reaches 4 tons of oil per hectare in macauba palm is that biojet production can take place from different raw materials
and 1.5 in jatropha, against only 0.56 tons of soybean oil per hectare to ensure greater availability and large-scale production. However,
planted. That is, when planting the same area of soybean, macauba the study shows that the advantages of cotton, peanut, sunflower,
palm, and jatropha, we could extract 7.5 times more oil from the macauba palm, castor bean and jatropha are still lower than the
plantation of macauba palm and 2.7 times more oil from the advantages of soybean. This means that in the short term, for Brazil
plantation of jatropha than from that of soybean. to start producing sustainable aviation fuels, and to meet aviation’s
Besides having the advantage of efficient land use, jatropha, as a ambitious GHG emission reduction targets, soybean must be
perennial crop, covers the soil with dry matter, and can be used in treated as the immediate feedstock for hydroprocessing.
soil conservation, reducing erosion and flooding, and enriching the
soil with decomposed organic matter [186]. Furthermore, jatropha
6. Final remarks and conclusion
and castor bean deserve recognition in relation to oil food
competition. The oil extracted from these oleaginous feedstocks is
The use of biojet can contribute to the achievement of the
highly toxic. Therefore, these oils cannot be used as human and
ambitious goals of reducing GHG emissions proposed by the ICAO
animal food. This means their production can be dedicated fully to
and Brazilian NDC. In addition to the targets, the new market could
energy purposes, rather than competing with food production
contribute to environmental development, considering the eco-
[187]. However, despite the advantages presented, the commercial
nomics of carbon emissions; economic development, from the
cultivation of jatropha and macauba palm faces many obstacles,
generation of wealth and economically viable production; and so-
with the lack of genetic improvement being the most limiting. The
cial development, from the generation of employment, income and
high toxicity of jatropha may be a positive factor for non-
opportunities. However, for biojet usage to become a reality in
competition with food use, but it could also be a challenge. Due
Brazil and in the world, it is necessary to make it economically
to the presence of toxic components in the seeds, an efficient
competitive with fossil jet fuel.
detoxification system is necessary for it to be used as an animal
In southeast Brazil, soybean is the most promising crop for HEFA
feed, the main market for oilseed [188]. Seed toxicity does not
biojet production. Thus, considering the need for a timely imple-
minimize the potential of its oil in HEFA biojet production, as there
mentation of biojet production in Brazil to achieve the ambitious
is no change in seed processing cost. However, the co-product
emission reduction targets of GHG, soybean is initially suggested as
generated will become unviable for its current main destination
the feedstock for production of HEFA biojet in this region. At the
of oilseed extraction residues, which necessitates a detailed
same time, seeking the best solutions for the future of sustainable
assessment of the best destination for waste generated from oil
aviation, it is necessary to reduce the bottlenecks related to alter-
extraction of the different oilseeds. An alternative for jatropha solid
native soybean crops in Brazil. Therefore, it is necessary to invest in
waste is, for example, use as fuel in boilers for power generation, as
research that seeks the technological domain of crops that have
fertilizer, or for biogas production [189]. Therefore, it is also
high productivity, yield and oil content, seeking the desirable
important to consider studies of the co-products and residues
qualities of these oils for hydrotreating. Domestication of potential
generated by the extraction of oil from the various evaluated crops.
crops should be considered in public policymaking and govern-
The height of the plant is also a problem in jatropha cultivation,
ment agroenergy programs, considering the opportunity for local,
which hampers harvesting on a large scale [188]. Regarding the
regional and national development. It is also important to consider
macauba palm, one of the biggest hurdles is the high acidity of its
studies that focus on co-products and residues generated by oil
L.M. de Souza et al. / Renewable Energy 149 (2020) 1339e1351 1347

extraction from the various evaluated crops. It is expected that, in reducing greenhouse gas emissions.
with the advancement of technology in oilseed crops, new options Thus, researchers are encouraged to study these gaps for future
for protein concentrates will favor animal production, also stimu- inclusion in the assessment. Knowing the performance of the
lating the biojet market. feedstock in relation to a greater number of criteria and sub-criteria
Another important aspect to consider is the concept of local would make the evaluation more complete and efficient. It is also
production arrangements around biojet industrial plants. At pre- encouraged, in future research with the use of multi-criteria tools,
sent, as there are no specific biojet plants yet, production ar- to determine the prioritization of oleaginous feedstocks in other
rangements around existing oil refining units should be considered. regions of Brazil, and the prioritization of locations for HEFA biojet
These arrangements are important because in many cases the facilities, as has already been done for biodiesel [195e197], biogas
feedstock supply center is far from the transformation center, [51], and biorefinery [198,199]. The mapping of strategic locations
which raises costs and increases sustainability risks. Local pro- for the implantation of HEFA biojet refining centers should consider
duction arrangements should be organized to enhance logistics and smaller distances to the supplier of feedstocks and to the great
supply, ensuring that biojet production from these sources is sus- consumers, the airports.
tainable from an economic, social and environmental point of view. Finally, decision-makers, stakeholders, and researchers are
It is also necessary to consider the concept of biorefinery to enable encouraged to make investment-related decisions, policies, and
HEFA biojet. All the oils mentioned in this work can be used, for research regarding HEFA biojet production based on the results of
example, in the pharmaceutical, cosmetics, and lubricant in- this study. Thus, efforts are expected to be carried out strategically
dustries, among others. The development of biojet production to optimize biojet production.
processes that can simultaneously generate other products and
integrate processes, such as the use of existing hydrogen generation Declaration of competing interest
infrastructure in oil refineries, has the potential to enable biojet
production at more competitive prices. The authors declare no conflict of interest.
As a limitation of this work, it is highlighted that some impor-
tant sub-criteria were not included in the research. This is because Acknowledgments
there is a lack of information in the literature regarding the per-
formance of some oleaginous feedstocks in relation to desirable The authors would like to thank the National Agency of Oil,
characteristics. For the TOPSIS application, it is fundamental to Natural Gas and Biofuels (ANP), INCT Midas, and the Post-Graduate
know the performance of all alternatives in relation to all criteria Program on Engineering of Chemical and Biochemical Process
and sub-criteria evaluated. The main sub-criteria not considered in (EPQB) - Chemical School (EQ) of Federal University of Rio de
relation to the economic criteria were: 1. the production cost of Janeiro (UFRJ) for making this study viable.
HEFA, considering the use of each oilseed, 2. oilseed participation in
the GDP, and 3. cost of all co-products generated, such as peel, bran, References
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