2007, Comparison of Two Accelerated Corrosion Techniques For Concrete Structures

You might also like

Download as pdf or txt
Download as pdf or txt
You are on page 1of 4

ACI STRUCTURAL JOURNAL TECHNICAL PAPER

Title no. 104-S34

Comparison of Two Accelerated Corrosion Techniques for


Concrete Structures
by Yingshu Yuan, Yongsheng Ji, and Surendra P. Shah

Characterizing deterioration of reinforced concrete structures surface of the steel bar and different deterioration of the bond
caused by the corrosion of steel bars is a major problem in predicting behavior between the corroded bar and concrete and will lead
service life. Normally, the galvanostatic method is used for to different capacity and ductility behavior of the structure. The
accelerating steel bar corrosion in concrete. The surface corrosion process of the bar corroded under an artificial
characteristics of the corroded steel bar, however, are found to be
different when the corrosion is induced by galvanostatic method or
climate environment can be the same as under a natural envi-
by natural environment. Recently, an artificial climate environment ronment. Therefore, the durability test under artificial climate
has been used to accelerate reinforcing bar corrosion in concrete. This environment not only can achieve the purpose of accelerating
method is becoming important in assessing the durability of concrete steel corrosion and control the degree of the corrosion, but
structures because of the similarity in surface characteristics of the also result in the same corrosion characteristics on the bar
corroded steel bar under natural and artificial climate environments. surface. Researchers10-13 have begun to adopt the new accel-
In this study, two groups of reinforced concrete beams were erated corrosion technique for durability.
degraded as a result of the corrosion of steel bars. One group of In this research, the corrosion process and the differences
beams was subjected to the galvanostatic method, while the other of the structural behavior under the impressed current technique
group was corroded using the artificial climate environment. and artificial climate environment are studied. The purpose
Comparative studies including the corroded characteristics of is to verify if the artificial climate environment can be
steel bar surface, the mechanical behavior of the corroded bar, and
adopted as an accelerated technique for the durability test
the load-bearing capacity were conducted. The comparisons between
the two groups of beams were based on the identical width of corrosion instead of the galvanostatic method. Identical reinforced
cracking. Obvious differences were found from the comparisons. concrete beams were corroded under the two accelerated
corrosion techniques, and the comparisons of their structural
Keywords: acceleration; corrosion; deterioration; reinforcement. behavior are carried out based on the same crack width
caused by steel bar corrosion.
INTRODUCTION
Corrosion of steel reinforcement is one of the major causes RESEARCH SIGNIFICANCE
To study the influence of the reinforcing bar corrosion on
inducing deterioration of reinforced concrete structures. In
the response of the reinforced concrete beams, the galvanostatic
the past two decades, researchers have used the galvanostatic
method of inducing corrosion is commonly employed. The
method to study the effects of the degree of corrosion on
corrosion process, however, is known to be different with the
deterioration of the structural response. The method is an
impressed current technique as compared with the natural
impressed current technique for accelerating steel bar corrosion
environment. An alternative method of inducing corrosion
in concrete. Corrosion on the steel bar is induced by applying
using artificial climate environment is proposed in this study.
an electrical potential using the steel bar in concrete as the
To correctly predict the response of concrete structures subjected
anode and a stainless steel bar as the cathode. The corrosion
to steel bar corrosion, it is essential that an appropriate
degree can be controlled by varying the current density and/
method be used in the laboratory to accelerate corrosion. It is
or the time interval of the impressed current. The advantages
shown that the process of corrosion and the consequent
of adopting this method are achieving a high degree of
structural degradation are different when the two methods
corrosion within a short period of time and the easy control
were used to induce corrosion.
of the corrosion degree desired. Many studies have been
carried out using the galvanostatic method in the past two
decades, such as the mechanical behavior of corroded steel EXPERIMENTAL INVESTIGATION
Reinforced concrete beams for testing
bar;1-2 the bond behavior between corroded bar and The reinforced concrete beams employed for testing are
concrete;3-5 the structural behavior of corroded elements;6-7 divided into three groups. The first group (Group A) is
the behavior of marine concrete structure under fatigue corroded under an artificial climate environment, the second
loading;8 and the interaction between loading, corrosion, and group (Group B) is corroded using the galvanostatic method,
serviceability of reinforced concrete.9 It is of benefit to qual- and the third group (Group K) is in a non-corroded state. The
itatively study the effect of the corrosion degree on the dete- concrete composition, reinforcement, and dimension of the
rioration of the structural behavior. However, it can be very
difficult to quantitatively predict the corrosion degree-
dependent deterioration of the structural behavior.
ACI Structural Journal, V. 104, No. 3, May-June 2007.
From an electrochemical aspect, the corrosion process is MS No. S-2006-184.R3 received September 9, 2006, and reviewed under Institute
publication policies. Copyright © 2007, American Concrete Institute. All rights reserved,
different when the corrosion is induced using the galvanostatic including the making of copies unless permission is obtained from the copyright
method or under a natural environment. A different corrosion proprietors. Pertinent discussion including author’s closure, if any, will be published
in the March-April 2008 ACI Structural Journal if the discussion is received by
process will lead to different corrosion characteristics on the November 1, 2007.

344 ACI Structural Journal/May-June 2007


Yingshu Yuan is a Professor of civil engineering at China University of Mining and
Technology, Xuzhou, Jiangsu, China. His research interests include durability test
methods, concrete durability, and durability assessment of concrete structures in service.

Yongsheng Ji is a Research Assistant and Lecturer of civil engineering at China


University of Mining and Technology.

Surendra P. Shah, FACI, is a Walter P. Murphy Professor of Civil Engineering at Fig. 2—Arrangement of reinforcement (all dimensions are
Northwestern University, Evanston, Ill., and the Director of the Center for Advanced
Cement-Based Materials. He is a member of ACI Committees E803, Faculty Network in mm; 1 mm = 0.0394 in.).
Coordinating Committee; 215, Fatigue of Concrete; 440, Fiber Reinforced Polymer
Reinforcement; 446, Fracture Mechanics; 544, Fiber Reinforced Concrete; 548, Polymers
in Concrete; and 549, Thin Reinforced Cementitious Products and Ferrocement. His
research interests include the development and behavior of cement-based materials,
high-performance concrete, fiber-reinforced composites, durability, nondestructive
testing, and fracture/failure behavior.

Fig. 3—Setup of galvanostatic method for accelerated


corrosion.
Fig. 1—Arrangement of loading on test beam (all dimensions Table 1—Comparison of capacity and ductility of
are in mm; 1 mm = 0.0394 in.). corroded beam
test beams are identical in the three groups. The structural Corrosion Average Capacity during Ultimate
behavior comparisons of the corroded beams are carried Beam crack width, corrosion bar yielding Py , capacity Pu, Ductility
no. mm (in.) degree, % kN (lbf × 103) kN (lbf × 103) fy /fu
out under the same corrosion crack width caused by steel
46.3 (10.41) 49.3 (11.08) 4.725
bar corrosion. K-1 0.0 (0.0) 0
[1.00] [1.00] [1.00]
The dimensions of the test beams are b x h x l = 100 x 160 x 47.8 (10.75) 50.4 (11.33) 3.367
1500 mm [3.937 x 6.299 x 59.055 in.], the concrete grade is A-1 0.2 (0.008) 1.1
[1.03] [1.02] [0.71]
C25, and the mixture proportions by weight are C:S:A:W = 47.0 (10.56) 49.8 (11.20) 1.916
B-1 0.2 (0.008) 1.4
1:1.75:2.98:0.55. Normal portland cement No. 32.5, river [1.02] [1.01] [0.41]
sand, and coarse aggregate of crushed basalt stone with a A-2 0.5 (0.020) 1.6
46.0 (10.34) 48.9 (10.99) 2.008
maximum aggregate size of 16 mm (0.630 in.) were used. [0.99] [0.99] [0.42]
The beam, shown in Fig. 1, was simply supported with a 45.5 (10.23) 46.2 (10.39) 1.360
B-2 0.5 (0.020) 3.0
[0.98] [0.94] [0.29]
span of 1.2 m (47.244 in.), and two concentration forces
45.6 (10.25) 46.3 (10.41) 1.650
were applied on the span. The arrangement of reinforcement A-3 0.8 (0.032) 2.4
[0.98] [0.94] [0.35]
in the test beam is shown in Fig. 2, and the thickness of the 44.4 (9.98)
concrete cover is 15 mm (0.591 in.). Three different corrosion- B-3 0.8 (0.032) 4.4 — —
[0.90]
cracking widths were selected for the corrosion control and Note: [ ] indicates ratio of value of corroded beam and value of no corrosion beam;
comparisons. The beams are loaded to failure after corrosion. Group A is corroded under artificial climate environment; Group B is corroded using
galvanostatic method; Group K is non-corroded beams; 1 mm = 0.0394 in.; 1 kN =
The grouping of the specimens is shown in Table 1. 224.82 lbf.

Artificial climate environment for The amount of corrosion is related to the electrical energy
accelerating corrosion consumed, which is a function of voltage, amperage, and
The corrosion process of the test beams under an artificial time interval. The amount of corrosion and the electric
climate environment can be accelerated by way of high current can be estimated by Faraday’s law based on the
temperature, high humidity, and repeated wetting-and- corrosion degree. The electric current I can be estimated by
drying cycles. Corrosion of the test beams in this group was surface area S of the steel bar to be corroded and using the
carried out in the artificial climate room controlled by a equation: I = S × 0.01 to 0.02 mA/mm2 [6.45 to 12.90 mA/in.2].
computer system. The artificial climate conditions in this A current of 1A (ampere) was applied in the corrosion
testing were temperature T = 40 °C (104 °F), relative process. During the corrosion process, the electric current
humidity (RH) = 80%, and salt water (5% NaCl solution) should be kept constant. The process was continued until the
spraying (1 hour) and infrared light shining (7 hours) for the crack width achieved the desired value as shown in Table 1.
wetting-and-drying cycle.
COMPARISONS OF STRUCTURAL
Galvanostatic method for accelerating corrosion BEHAVIOR OF CORRODED BEAM
At first, the test beam is immersed in a solution of 5% Capacity and ductility
NaCl for 7 days, then direct electric current is impressed on Figures 4 and 5 show the comparisons of the structural
the steel according to the setup shown in Fig. 3. The position behavior between non-corroded and corroded beams and
of the corroding steel bar in concrete is higher than the level of show the comparisons of the structural behavior between the
the solution for avoiding the dissolution of oxidation products. beams corroded under an artificial climate environment
The two bars (main tensile reinforcement in the beam) act (ACE) and using the galvanostatic method (G method) based
as the anode and the stainless bar in the centre of the beam on the corrosion crack width 0.5 or 0.8 mm (0.020 or 0.032 in.).
section acts as the cathode in the setup, as shown in Fig.3. The corresponding values of capacity and ductility are

ACI Structural Journal/May-June 2007 345


Fig. 7—Corrosion distributions under artificial climate
environment.
Fig. 4—Comparison of structural behavior (corrosion crack
width of 0.5 mm; 1 mm = 0.0394 in.).

Fig. 8—Corrosion distributions using galvanostatic method.

the surface of the steel bar under an artificial climate environment


and using the galvanostatic method, respectively. The corrosion
shows nearly uniform distribution around the steel bar
corroded using the galvanostatic method, but only under an
Fig. 5—Comparison of structural behavior (corrosion crack artificial climate environment was corrosion found at the
width of 0.8 mm; 1 mm = 0.0394 in.). surface of the steel bar facing the concrete cover.
The chemical compositions of corrosion products on the
bars corroded under an artificial climate environment and
using the galvanostatic method appear to be different. By
observation, the corrosion products show different colors
caused by different chemical compositions. The differences are
mainly due to the time intervals of the corrosion process. For the
beam under an artificial climate environment, the corrosion
Fig. 6—Brittle failure patterns—bond failure. process took more than 3 months for cracking. For the beam
corroded using the galvanostatic method, the corrosion process
took approximately 3 days. Fast corrosion reaction leads to
shown in Table 1. In this table, the average corrosion degree insufficient oxidation and different chemical compositions in the
is defined by weighing the bar before and after corrosion. corrosion products.

Failure mode of corroded beam Mechanical behavior of corroded steel bars


The failure modes of the corroded Beams A-1 and B-1 and The mechanical behavior comparison of the corroded bars
Beams A-2 and B-2 at the low corrosion degree show similar was carried out on the beams with the same corrosion crack
failure mode with non-corroded Beam K-1. The mode shows width. Table 2 shows the comparison results. In the table, the
that the tensile bar yielded first in the tension zone, and then corrosion degree is defined by the weight of the bar before and
underwent obvious plastic deformations of the bar. Finally, after corrosion. The nominal yield and ultimate strength are the
the concrete crushed in the compression zone of the beam. measured tension force by the nominal section area of the steel
This failure mode shows ductile characteristics. bar. The toughness is the deformation near tension failure in the
When the corrosion crack width reaches 0.8 mm (0.032 in.), 100 mm (3.937 in.) zone divided by 100 mm (3.937 in.).
the comparison of failure modes between Beams A-3 and B-3 The test results show that nominal yield and ultimate
show a clear difference. Beam A-3 corroded under the artificial strength and toughness values in Group B are lower than the
climate environment still showed ductile failure characteristics. strength and toughness values in Group A. In Table 1, the
Beam B-3, however, corroded using the galvanostatic corrosion degree in Group B is higher than the corrosion
method showed brittle failure mode. This sudden failure is degree in Group A based on the same corrosion crack width.
caused by bond failure of the main tension corroded bar; the Therefore, the effective section area in the beam of Group B
failure pattern is shown in Fig. 6. is less than in the beam of Group A.

Corrosion characteristics on surface of ANALYSES OF RESULTS


steel bar in concrete Electrochemical corrosion process
After the structural behavior testing, the beams were Carbonation and chloride diffusion under a natural or artificial
broken and the steel bars were cut and removed for observation environment are gradual processes proceeding from the
analyses. Figures 7 and 8 show corrosion distribution along concrete surface to the inside. The passivity of the steel bar

346 ACI Structural Journal/May-June 2007


Fig. 9—Corrosion process under natural or artificial climate
environment. Fig. 10—Corrosion process using galvanostatic method.

facing the concrete cover is at first broken. Figure 9 is a Table 2—Comparison of mechanical behavior of
sketch of the corrosion process under natural or artificial corroded bar
environment and shows that the anodes of electrochemical Nominal
corrosion reaction is mainly located on the bar surface facing Corrosion Average Nominal yield ultimate
the concrete cover. Therefore, the corrosion distribution Beam crack width, corrosion strength MPa, strength MPa, Toughness,
no. mm (in.) degree, % (psi × 103) (psi × 103) %
shown in Fig. 7 mainly occurred on the surface of the steel
bar facing the concrete cover under a natural or an artificial A-2 0.5 (0.020) 1.6 349.4 (50.67) 535.2 (77.62) 23.3
climate environment. B-2 0.5 (0.020) 3.0 331.7 (48.11) 517.5 (75.05) 15.0
Figure 10 shows the electrochemical process using the A-3 0.8 (0.032) 2.4 340.6 (49.40) 521.9 (75.69) 16.7
galvanostatic method. In the reaction, the whole surface of the B-3 0.8 (0.032) 4.4 256.5 (37.20) 362.7 (52.60) 11.7
steel bar in concrete is the anode; the corrosion occurred almost Note: 1 mm = 0.0394 in.; 1 MPa = 145.03 psi.
entirely around the whole surface of steel. The corrosion
characteristics shown in Fig. 8 are almost uniform in
distribution on the surface of the steel bar facing and at the back
of the concrete cover. ACKNOWLEDGMENTS
The authors would like to express their appreciation to the National Science
Foundation of China (NSFC). The research works belong to one part of the
Deterioration of bond strength between corroded projects (50478100 and 50538070), which are supported by the NSFC.
bar and concrete
The deterioration degree of the bond strength based on the REFERENCES
same corrosion crack width is different between the two 1. Almusallam, A. A., “Effect of Degree of Corrosion on the Properties
accelerated corrosion techniques due to the different corrosion of Reinforcing Steel Bars,” Construction and Building Materials, V. 15,
distribution on the bar surface. When the structural behavior 2001, pp. 361-368.
of Beams A-3 and B-3 were compared, the bond strength of the 2. El Maaddawy, T. A., and Soudki, K. A., “Effectiveness of Impressed
Current Technique to Simulate Corrosion of Steel Reinforcement in Concrete,”
main tension bars in Beam A-3 was higher than that in Beam B-3 Journal of Materials in Civil Engineering, ASCE, V. 15, No. 1, Jan.-Feb.
due to a smaller corroded area on the bar surface of Beam A-3. 2003, pp. 41-47.
This results in different failure modes of the two beams. 3. Lee, H.-S.; Noguchi, T.; and Tomosawa, F., “Evaluation of the Bond
Properties between Concrete and Reinforcement as a Function of the
Degree of Reinforcement Corrosion,” Cement and Concrete Research, V. 32,
CONCLUSIONS 2002, pp. 1313-1318.
Based on the results of the experimental investigation 4. Auyeung, Y.; Balaguru, P.; and Chung, L., “Bond Behavior of Corroded
using an artificial climate environment and using the Reinforcement Bars,” ACI Materials Journal, V. 97, No. 2, Mar.-Apr. 2000,
galvanostatic method, the following conclusions are drawn: pp. 214-220.
1. The steel bar in concrete can be corroded using the 5. Congqi, F.; Lundgren, K.; Chen, L.; and Zhu, C.; “Corrosion Influence on
Bond on Reinforced Concrete,” Cement and Concrete Research, V. 34,
galvanostatic method, but its electrochemical corrosion 2004, pp. 2159-2167.
process is different from the corrosion process under the 6. Uomoto, T., and Misra, S., “Deterioration of Concrete Beams and
artificial climate and natural environment. The differences Columns Caused by Corrosion of Reinforcing Steel Bars,” 4th Interna-
lead to different corrosion distribution on the surface of the tional Conference on Durability of Building Materials and Components,
Singapore, 1987.
steel bar. The corrosion mainly occurs on the surface of the 7. Ballim, Y., and Rei, J. C., “Reinforcement Corrosion and the Deflection
steel bar on the side facing the concrete cover under an of RC Beams––An Experimental Critique of Current Test Methods,”
artificial climate and natural environment; however, the Cement & Concrete Composites, V. 25, 2003, pp. 625-632.
steel bar is corroded on the whole surface of the steel bar 8. Ahn, W., and Reddy, D. V., “Galvanostatic Testing for the Durability
when using the galvanostatic method; of Marine Concrete under Fatigue Loading,” Cement and Concrete
Research, V. 31, 2001, pp. 343-349.
2. The corrosion of the main steel bar in the beam can 9. Yoon, S.; Wang, K.; Weiss, W. J.; and Shah, S. P., “Interaction
reduce the loading capacity and ductile characteristic and between Loading, Corrosion, and Serviceability of Reinforced Concrete,”
can transfer the failure mode from ductile to brittle mode. ACI Material Journal, V. 97, No. 6, Nov.-Dec. 2000, pp. 637-644.
Different corrosion characteristics on the surface of the steel 10. Li, C. Q., “Initiation of Chloride-Induced Reinforcement Corrosion
in Concrete Structural Members-Experimentation,” ACI Structural Journal,
bar are the main reasons that cause the different structural V. 98, No. 4, July-Aug. 2001, pp. 502-510.
behavior of the concrete beams corroded by two different 11. Li, C. Q., and Melchers, R. E., “Time-Dependent Risk Assessment
methods of inducing corrosion; and of Structural Deterioration Caused by Reinforcement Corrosion,” ACI
3. The corrosion process and corrosion characteristics of Structural Journal, V. 102, No. 5, Sept.-Oct. 2005, pp. 754-762.
the steel bar under artificial climate environment are similar 12. Nounu, G., and Chaudhary, Z., “Reinforced Concrete Repairs in
Beams,” Construction and Building Materials, V. 13, 1999, pp. 195-212.
to that of corrosion under natural environment. Artificial 13. Yuan; Y.; Li, G.; and Jiang, D., “Corrosion Rate of Rebar in Concrete,”
climate environment as an accelerated laboratory test method is International Conference on Advances in Concrete and Structures
more representative than the galvanostatic method. (ICACS), Sept. 17-19, 2003, Xuzhou, China, pp. 388-373.

ACI Structural Journal/May-June 2007 347

You might also like