STD : XII PRELIMINARY EXAMINATION MARKS: 70

DATE : __/___/_____ CHEMISTRY DURATION : 3 HR

General Instructions :
The question paper is divided into FOUR sections.
1. Section A : Q. No.1 contains Ten multiple choice type of questions carrying One mark each.
. Q. No. 2 contains Eight very short answer type of questions carrying One mark each.
2. Section B : Q. No.3 to Q. No. 14 are Twelve short answer type of questions carrying Two marks
each. (Attempt any Eight).
3. Section C : Q. No. 15 to Q. No.26 contain Twelve short answer type of questions carrying Three
marks each. (Attempt any Eight)
4. Section D : Q. No. 27 to Q. No. 31 are Five long answer type of questions carrying Four marks
each. (Attempt any Three)
5. Use of log table is allowed. Use of calculator is not allowed.
6. Figures to the right indicate full marks.

Q.1 Select and write correct answer of the following 10M

i Which among the following hydrides is not reducing agent
(a) H2O (b) H2S (c) H2Te (d) H2Se

ii Name the reagent which on reaction with glucose confirm the presence of
fivo hydroxyl in glucose.
(a)Hydroxyl amine (b) Bromine Water
(c) Dilute nitric acid (d)Acetic Anhydride.

iii Identity antibiotic drug amongst the following.

(a) Codein (b) Equanil (c) Penicilin (d) valium

iv In Crystal Lattice formed by bcc unit cell the void volume is

(a) 68% (b) 74% (c)32% (d) 26%

v Solubility of N2 gas in water at 250C & 1 bar is

(a) 6.85 × 10-4 Mol L-1 bar-1 (b) 1.66 × 10-4 Mol L-1 bar-1
(C) 2.22 × 10-3 Mol L-1 bar-1 (b) 6.85 × 10-6 Mol L-1 bar-1

vi The Enthalpy formation for all elements in their standard state is

(a) Unity (b) Zero (c) Less than zero (d) different elements

vii Among the known interhalogen compound the maximum number of atom is
(a) 3 (b) 6 (c) 7 (d) 8

viii The sum of co ordination number and oxidation number of M in

[ M (en)2C2O4] Cl
(a) 6 (b) 7 (c) 9 (d) -8
 ix Butanenitrile may be prepared by heating
(a) Propanol with KCN (c) Butanol with KCN
(b) N- butyl chloride with KCN (d) n- propyl chloride with KCN

X Which of the following is naturally accruing polymer

(a) Telfon (b) polyethylene (c) PVC (d) protein

Q.2 Answer the following questions 8M

i Write a reaction to convert acetic acid into methyl amine.
ii What are the aromatic ketone.
iii Write any two function of salt bridge.
iv Write name of electrophile used in kolbe’s reactions.
v What are the rate determining step.
vi In a particular reaction 2KJ of heat is released by the system & 6 KJ of work
is done on the system determine ΔU.
vii Why cation are lewis acids.
viii What is osmotic pressure.

Section B

Attempt any eight of following questions 16M

Q.3 State & explain Hess law of constant summations.
Q.4 Write two uses of Helium & Neon.
Q.5 What are the paramagnetic substance? Give example?
Q.6 The Henry’s law constant of methyl bromide CH3Br is 0.159 mol L-1 at 25 0C
What is the solubility of methyl bromide in water at 250C & at a pressure of
130 mmHg.
Q.7 Derive the relation between PH & POH.
Q.8 Write a electrode reaction during electrolysis of molten KCl.
Q.9 Give reason haloarenes are less reactive than haloalkanes.
Q.10 Explain why phenol is more acidic than ethyl alcohol.
Q.11 State Williamsons synthesis & explain it.
Q.12 Draw a neat diagram for Hawarth formula of glucopyranose.
Q.13 Classify the following solid into different types
a) Silver b) P4 c) Diamond d) NaCl
Q.14 Define
a) Molarity b) Osmotic pressure

Section C

Attempt any eight of following questions 24M

Q.15 Define instantaneous rate of reaction ? explain pseudo first order reaction
with example.
Q.16 What are the monosaccharides ? explain denaturation of proteins.
Q.17 Niobium forms bcc structure the density of niobium is 8.55 g/cm3 & length
of unit cell edge is 330.6 pm How many atoms & unit cells are present in 0.5
g of niobium.
Q.18 Define degree of dissociation? Derive ostwarld dilution law for acetic acid.
Q.19 Explain the trend in following atomic properties of group 16 elements.
1. Atomic radii 2. Ionization enthalpy 3. electronegativity
Q.20 What is ligands ? Give two example.
Q.21 What is lanthanide construction explain its causes.
Q.22 Convert the following
Propene to propan-1-01
 Benzyl alcohol to benzene cyanide
 Ethanol to propene nitrile
Q.23 Give the preparation of phenol from.
 Chlorobenzene
 From cumene
Q.24 What are amines explain basic nature of amines with suitable example.
Q.25 Write reaction of formation of
a) Nylon 6 b) Terylene
Q.26 Define green chemistry explain the role of green chemistry.

Section D
Attempt any Three of following questions 12M
Q.27 Explain the mechanism of aldol addition reaction mention two uses of
aldehydes.
Q.28 2 mole of an ideal gas are expands isothermally and reversibly from 20L to
30L at 300k. calculate the work done (R = 8.314JK-1mol-1 ).
Q.29 Derive the mathematical expression between molar mass of a non volatile
solute and elevation of boiling point.
State & explain Roults law.
Q.30 What is kohrausch law of independent migration of ion? How is it use full on
obtaining molar conductivity at zero concentration of weak electrolyte.
Explain with example.
Q.31 Write the names and structure formulae of oxoacids of chlorine.