CHEMISTRY 333 (Sections 031-033, 035-036, 038) ‘Spring 2022 = Organic Chemistry | Dr. Mary Grace Hollenbeck Lecture:M/ WF 02:20 PM 03:10 PM Jones Physical Science Building Room 210, Recitation: Section 031 STB 210 T 10%05 am~ 10:55 am Section 032 ‘STB 210 T02:50 pm —03:40 pm Section 033 ‘STB 210 04:25 pm 05.15 pm Section 035 STB A17 T14:40 am — 12:30 pm ‘Section 036 ‘STB 210 M 03:30 pm — 04:20 pm Section 038 ‘STB 210 M05:50 pm - 06:40 pm Contact Information for Dr. Hollenbeck: OFFICE: TB 425 EMAIL: ‘maryah@mailbox.sc.edu (Emails will be answered within one business day) PHONE: 777-9521 (emails best) OFFICE HOURS: = M_ 12:55 PM~01:55 PM R 03:05 PM — 04:08 PM. F By Appointment Only Required Text Matera: ‘+ ‘Organic Chemistry” 9 Ealtion,L. G. Wade and J. W. Simek, Pearson, (ISBN: 978-0-32197137-1) © Achiove Essential anio Chemist Optional Materi “Organic Chemistry as a Second Language, 1% semester topics’ 4 Edition, David R. Klein (ISBN: 978-1-119-11066-8), (Highly recommended) + Molecular Model Set; (Highly recommended) Suggestions forkits see: yaw andruseducation com ($23.50 shipping included) ‘Amazon has a numberof options (Duluth Labs, ex.) Course Goals: The aim of this course is to expose students to the broad field of organic chemistry. The development of analytical and problem-solving skis will also be emphasized, Learning Outcome The following concepts should be mastered by the end of the semester and understood for continuation in the second semester of organic chemistry and advanced chemisties, as well as other related disciplines (biochemistry, biology, pre-med, pharmacy, chemical engineering, ee.) Name and recognize/classify basic organic functional groups and simple organic molecules. Develop a three-dimensional view of carbon compounds based on covalent and ionic bonding. Predict the properties and reactivity generally imparted to specific functional groups. Use arrow pushing to explain/define the mechanism of typical organic reactions, Predict aciitybasicity trends including estimating pka, Understand and interpret potential energy diagrams and reaction coordinate diagrams, Design single and mult-step synthetic schemes for organic compounds, Lecture: Regular class attendance is required. Some material covered in the lectures will not be found in the text. Furthermore, university Poli states that “Absence from more than 10% of the scheduled class sessions, whether excused or unexcused, is excessive and Instructors may exact a grade penalty for these absences.” Homework: Homework will be assigned and you can ask your TA to go over problems in recitation, but it will not be graded. | wil post the {answer keys in Blackboard. However, | cannot stress enough the importance of doing the homework. Do not think that you fully Understand the material because you have attended class and read the text, You need fo practice, Try to work through the problems first before looking at the answers,Quizzes: ‘Thoro willbe throe typos of quizzes: 1. Recitation quizzes, 2. Online quizzes, and 3. Pop quizzes (in clas), Recitation (60% of quiz grade): One quiz wll ba given each reckation period. You can dropimiss two recitation quizzes. Only two quizzes will be dropped. The recitation quizzes will typically be two to five questions, and they will be similar to the homework Or to a problem from the lecture, Online (20% of quiz arade): These are taken through the Achieve website, There will be approximately one per chapter. One quiz wll be dropped. Pop (20% of quiz arade): There vill be periodic ‘pop" quizzes given in lecture. Please bring paper and pen / pencil to class in case ‘there is a pop quiz, These will be factored into your quiz grad, but in-class pop quizzes cannot be dropped. Exams: Exams will be based on the homework, quizzes, matarial covered in the required text and material covered in lecture. There willbe no make-up exams. You are required to take the first exam. The lowest exam/cumulative quiz grade willbe dropped (Le. ether Exam |, Exam Il, Exam Il, Exam IV or the Quiz average will be dropped). A missed exam will count as the exam that you can drop. Final Exam: The final exam willbe cumulative. The final is required. There will be no make-up exam offered forthe final exam. Grading: Exam! 100 pis Exam Il 100 pts Exam Ill 100 pis Exam IV 100 pis, Quizzes 100 pis. (Recitation (60%), online Achieve (20%), pop quizzes (20%) Final Exam 200 pis the finals required 700 pis 100 pts the lowest exanviquiz score will be dropped Total 600 pts Each exam and the final quiz average may be curved, whichis determined based on the class performance. ‘A540 ~ 600 pts B+ 510-539 pts B 480-509 pts (C+ 450-479 pts © 420-449 pis D+ 390-419 pis D 360-389 pts F ©360 pts Student Success Center Tutoring Program: “The Student Success Center Tutoring Program provides free academic assistanca to envolled USC students. They offer a variety ‘of academic support services on campus, including how to improve your study skis. ‘Thomas Cooper Library | Mezzanine Level 808-777-1000. SASSC@malboxse.cdu ww e.edueuccess Tutoring: Peer tutors are undergraduate students who have excolled in the course they tutor. They have been trained to facitate discussions on course content and to guise undergraduate stents atthe Universit of South Caroina as they improve thet academic habits. Options available: Virtual or Face-to-face — make an appointment. bitpsiivm sc.eduabouofices_and_divsionsistugent sucess. cenler'study-sra/Vtuorina/index.oho Supplemental instruction: These are peered study sessions, where trained undergracuate leaders alfend our lass then hold three weekly study sessions that can serve as “builtin study time.” You can attend S| Sessions to focus on the most diffu content being covered in class. Sessions are open to ll undergraduate students who’ are looking to enhance, thei Understanding ofthe material and improve tir grades, The schedules postad onthe SSC webste each week and wil also be Communicated by the I Leader. siisceduabouloffices_ and divsions/student_success_centerisupplementalinstruction/ndex.ph Study Skils: Success Consufants meet wit students one-on-one to sel goals. explore study and time management statecos create action plans, and make referals to campus resources. Appointments are made through Microsoft Teams hilpsi/scedulabouloices_and_ duisions/student success cenerstudy-smarvstudy-sklsindexhp Referrals: | may communicate with the SSC regarding your progress troughout the semester. I contacted by the SSC, please Schedule @ Success Consultant immediatly as this indicates lam concemed about your progress In this course. Referrals ae not punitive, and any information shared by mes confidential and subject to FERPA regulations.Policies: + Exam re-grades must be brought to my attention within one week of receiving the graded exam. (NOTE: do not write on the ‘exam question itself, this can lead to confusion. Simply note your objections on a separate piece of paper or on the exam cover sheet.) Exams are scanned for dacumentation before they are handed back, + Ringing and answering cell phones in class is considered “disruptive behavior" and appropriate action will be taken in accord with University policy for such disruptive behavior including ejaction from class, + Honor Code: It is the responsibilty of every student at the University of South Carolina Columbia to adhere steadfastly to truthfulness and to avoid dishonesty, fraud, or deceit of any type in connaction with any academic program. Any student who Violates this Honor Code or who knowingly assists another fo violate this Honor Code shall be subject to one or more of the following sanctions, 1. Educational Sanctions: These can include: 2. A workshop reviewing ethical dacision-making, integrity and the Honor Code: . Aresearch project or essay, «, Consultations withthe Writing Center or Student Success Center: 4. Additional sanctions may be imposed by the Office of Academic Integrity or the Carolina Judicial Council 2. Probation. A period of review and observation during which a student is under afcial notice that subsequent violations of the Honor Code are likely to result in more severe sanctions, including suspension or expulsion from the university. 3. Transcript Notation: This inicates that an Honor Code violation has occurred in @ specific course. 4. Suspension: Derial of enrollment, attendance, and other privileges at the university for no less than one semester. 5. Expulsion: Expulsion results in permanent dismissal from the university ‘What constitutes an honor code violation? 1. Plagiarism: Use of work or ideas without proper acknowledgment of source. 2. Cheating: improper collaboration or unauthorized assistance in connection with any academic work, (This includes helping others during online quizzeslexams, or looking up material during an eniine quizlexam,) 3. Falsification: Misrepresenting or misteading others with respect to academic work 4. Complicity: Assisting or attempting to assist another in any violation of the Honor Code (This includes taking pictures of uizlexam problems to share with others or helping others with the answers to those questions.) Faculty members are requited to report potential violation fice of Academic Integr Your enroliment inthis class signifies your wilingness fo accept these responsibillies and uphold the Honor Code of the University of ‘South Carolina. Please review the Honor Code via www.sc.edulacedemicintegrity. Any deviation from this expectation can result in @ referral tothe Otfice of Academic integrity and iffound responsible a grade penalty will be applied. + Email Etiquette Emailis a great way to communicate with me, however, there are afew policies I woul like to go over. 1.1 generally answer emails quickly, however, you can expect that it will take up to 24 hours to respond, 2.lF you email after 5pm do not expect a response until the next business day. Generally, | ry to email before then but do ot expect it 3, Please be professional in your emails and make sure to include wich lecture you are attending, 4-Review the syllabus/olackboard announcements prior to asking a question as many things are covered in it Disabilities: Reasonable accommodations are available for students with a documented disabiliy. If you have a disabilty and may need accommodations to fully participate in this class, contact the Office of Student Disabilly Services: 803-777-6142, omail ‘sadro@mailbox.sc.edu, oF stop by Close-Hipp Room 102. All accommodations must be approved through the Office of Student Disability Services. Hazardous Weather Emergency closures are announced on the university Carolina alert website hip//carolinaalerso.edul. In case of emergency closure, assignments or lectures may be posted on Blackboard, Topical Outin Chapter 1: Structure and Bonding Chapter 2: Acids and Bases: Functional Groups Chapter 3: Structure and Stereochemisiry of Alkanes Chapter 4: The Study of Chemical Reactions Chapter 5: Stereochemistry Chapter 8: Alkyl Halides, Nucleophilic Substitution Chapter 7: Structure and Synthesis of Alkenes; Elimination Chapter 8: Reactions of Alkenes Chapter 9: Alkynes Shapter 10: Structure and Synthesis of Alcohols Chapter 11: Reactions of Alcohols Chapter 14: Ethers, Epoxides and ThicethersImportant Dates, "Tuesday, January 18" Last day to change a course schedule or drop a course without a grade of "W" ‘Monday, March 28" Last day to drop a course or witdraw without a grade of WF" being recorded Monday, April 25° Last day of classes Friday, April 29 Final Exam = 12:30 3:00 pm COVID-19 Information The university guidelines regarding COVID-19 can be found at the weblink below. Please check frequently for updates regarding policies and procedures. hitpsiisc.edulsafety/coronavrusisafety_quidelines/index.php ‘Students must attend all classes in the format they are offered (For exampla, students are expected to attend in-person classes in person). Students who miss classes due to COVID quarantine, a diagnosed health condition or registered disabiity should contact the Underaraduate Student Ombudsman or Student Disablity Resource Services to document the reason for ther absence, Students with ‘documented absences may be offered the opportunity to reschedule exams or quizzes at the instructor's discretion; fist utliing any syllabus statement regarding missed class, quizzes, or exams. EXAMPLE: Our syllabus has a policy on dropping a low or missed ‘exam, therefore that policy will be used for the fist missed exam, If @ student misses more than one exam with proper official ‘documentation then the second missed exam may be rescheduled. ALL excused absences and accommodations for disabilities ‘MUST have proper official documentation. Face Coverings: Face coverings protect you and your classmates in case that the wearer is unknowingly infected but does not have ‘symptoms. Faculty, students, and staff are encouraged fo wear an appropriate face covering in all classrooms and in other designated ‘areas on campus. Face coverings should cover your nose and mouth in a community setting. In alignment with the tenets of the Carolinian Creed ~ including integrity, honesty, and respect for others — and in an effort to keep our campus safe, faculty, staff, and sludents are expected to follow this recommendation. | can encourage but nat requia face coverings in the classroom. Student Well-Being If you feel unsafe on campus at any time in any place, please contact Police Dispatch at 803-777-4215 (in an emergency, please call 911) and reach out tothe Division of Student Affairs and Academic Support. ‘Students may experience situations or challenges that can interfere with leaming and interpersonal functioning including stress, anxiety, depression, substance use, concer for a femiylriend, or feelings of hopelessness. Pay attention to what is happening in the classroom and in the lives of your fellow students. There are numerous campus resources available to students including University Counseling & Psychiatry Service and University Student Health Services. Help is available 24/7. Students who need immediate help should call 603-777-5223, An outside resource isthe National Suicide Prevention Lifeline (800-273-8255).Tentative Course Outline: he topics covered on each date and exam dates are subject to change. January ‘Monday Tuesday ‘Wednesday Thursday Friday 10 7 a we m Syllabus, Chapter 1-2 Chapter 1-2 ‘Chapter 1 17 8 @ 2 a MLK Service Day (No | Lastdayto add / drop | Chapter 1-2 Chapter 1-2 Classes) | 4 B 6 7 28 Chapter 1-2 Chapter 23 Chapter 2-3 a - Chapter 23 ‘ebruary ‘Monday Tuosda Wednesday Thursday Friday 7 z a a Chapter 23, Exam 1 7 8 9 Ty TT Chapter 23 | Chapter2-3 Chapter 3-6 oy 6 6 7 e Chapter 36 Chapter 36 Chapter 3-6 a 2 3 2 5 Chapter 3-6 Chapter 3.6 Chapter 3-6 aa Exam? March ‘Monday Tuesday Wednesday Thursday Friday 7 z 3 a Chapter 3-6 Chapter 346 7 8 3 0 7 ‘Spring Break (No Spring Break (No Spring Break (No Spring Break (No Spring Break (No Classes Classes) Classes) Classes) Classes) 4 15 6 7 1 Chapter 3.6 Chapter 36 Chapter 4-6 a 2 3 me ry Chapter 4-6 ‘Chapter 7-9 Exam 3 oy 2B 30 a Chapter 7-9 ‘Chapter 7-9 Last day to drop without WE April Monday Tuesday Wednesday Thursday Frida) 7 Chapter 7-9 + 3 6 7 8 Chapter 7-9 Chapter 10, 11, 14 Chapter 10, 11, 14 TT a B 1 6 ‘Chapter 10, 11, 14 Chapter 10, 11, 14 Exam 4 w 8 20 emai @ Chapter 10, 11, 14 Chapter 10, 11, 14 Chapter 10, 11, 14 NS e 26 a Fy Fc Shapler 10, 11, 14 Reading day i 12:30 (Last day of classes, 3:00 pm)Wades Ch L Class | ~ Problems? 2la-c,!33) ; Sla-e)s Vfrof22 5 bet) 4 Vlaeds 124 255 urzta-e, 9,h) 5454 5y je Rangquad é 7 Cha cei © ao proven? ry) cleus % a urrons (0) ~ ne e7 = electrens E\ectrons do Not move freel — move in Shells or principle En levels Lienergy —~ each shell conrains Zu? electrons N= Shell 4b Shell 2? 2 electrons Jower in EN (closer +o nuc) srei) 2 —> & electrons Stell 3 — > 1% electrons J shell YU —> 32 etectrens higher!" én Char ther from nuc) K Jower in fu — mort stable Se Ape oe Oe a Phe stable 0(prorens Stabilize electrons) 15 broken into SUbShell Se aq — Each shell s ire where we Hive e art orbit als3 regien of space —— > thes s tem sha conhain \a| x Lf a