AIR POLLUTION
AND CONTROL SEMINAR ON:
PHOTOCHEMICAL
SMOG
DONE BY; MAHASWARI JOGIAWHAT IS A PHOTOCHEMICAL SMOG?
Pea merce mC ME CUM ICOUM HOMO MELT one
hit molecules of different kinds of pollutants in the atmosphere.
Ree ee ew Oe RECUR emit
it is detected in many metropolitan cities in the world.
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PLUNGE eMC MeO Meri e TMT M Lema mike (oc
OR TUR UTE Mel Ge MOC Tee Me Role rece CMC TC come Commis
formation of photochemical smog.
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the interaction of hydro carbon and nitrogen oxide released by exhausts of
automobiles and some stationery sources.
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secondary pollutants such as ozone, aldehyde, ketones, peroxyacyl nitrates.
Pen MACRO REReMn In Chem ml hMIT eC ene
Beeler ct} aFORMATION OF PHOTOCHEMICAL SMOG
When fossil fuels are burnt, a variety of pollutants are emitted into the earth’s
troposphere. Two of the pollutants that are emitted are hydrocarbons (unburnt
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sufficient, a chain reaction occurs from the interaction with sunlight in which
NO is converted into nitrogen dioxide (NO,). This NO, in turn absorbs energy
PROM Ce RLM eC tC ecm Q eto
NO,(g) + Av Aas Raed ®
Oxygen atoms are very reactive and combine with the O, in air to produce
ozone,
O(g) +O, (6) > 03 (g) (i)
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formed in the reaction (i) to regenerate NO,. NO, is a brown gas and at
sufficiently high levels can contribute to haze.
NO (g) + 0, (g) ——~> NO, (g) + O, (9) (i)
Ozone is a toxic gas and both NO, and O, are strong oxidizing agents and can
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such as formaldehyde, acrolein and peroxyacetyl nitrate (PAN).
SCH, + 20, +3CH,=O +3H,O
Formaldehyde
CH,=CHCH=0 CH,COONO,
Acrolein
oO
Peroxyacetyl nitrate (PAN)
BeieL prc} 5SOURCES FOR PHOTOCHEMICAL SMOG
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