Problem 1

c e

a d
b

Proton Shift Integration Multisplitas J Coupling

3
a 0.96 3 Triplet Jab = 7,4 Hz
3
b 2.21 2 Quartet of doublet of doublet Jab = 7,4 Hz
3
Jbd = 6,3 Hz
4
Jbc = 1,5 Hz
3
c 5.95 1 Doublet of doublet of triplet Jcd = 15,4 Hz
3
Jce = 7,7 Hz
4
Jbc = 1,5 Hz
3
d 6.78 1 Double of triplet Jcd = 15,4 Hz
3
Jbd = 6,3 Hz
3
e 9.35 1 Doublet Jce = 7,7 Hz

Tree Diagram :

Ha Hb Hc

Jab Jab
Jab Jab Jab Jcd

Jbd Jbd Jbd Jbd Jce Jce

Jbc Jbc Jbc Jbc Jbc Jbc Jbc Jbc

Jbc Jbc Jbc Jbc

Hd
He

Jcd
Jce

Jbd Jbd
Problem 2

a
c

b d

Proton Shift Integration Multisplitas J Coupling

a 2.80 3 Singlet -
3
b 5.98 1 Doublet Jbd = 9,9 Hz
2
Jbc = 0 Hz
3
c 6.23 1 Doublet Jcd = 16,6 Hz
2
Jbc = 0 Hz
3
d 6.62 1 Doublet of doublets Jcd = 16,6 Hz
3
Jbd = 9,9 Hz

Tree Diagram:

Hb Hc Hd

Jbd Jcd
Jcd

Jbd Jbd
Problem 3
b
a

d
c
Proton Shift Integration Multisplitas
a 3 Doublet of doublet
b 1 Singlet
c 1
d 1