GUIDED REVISION ENTHUSIAST & LEADER

Target : JEE(Main + Advanced) - 2019 COURSE

ORGANIC CHEMISTRY
GUIDED REVISION PLAN-SCORE ADVANCED
Question Bank # 03

Only one correct :

1. The final product of the given reaction sequence
NO2

 NH 
4 2 S
NaNO 2 H2 O,Cu 2 O
  
HCl
 
Cu  NO3 

NO2 0  5 C
2

is :
OH OH OH

(A) (B) (C) (D)

NO2 OH

NO2

(i)NaOI SOCl2 C 6H 5NH2 conc.HNO3

2. A 
(ii)H 
 B   C 
NaOH

 D 
conc.H SO
 E (Major).
2 4
(1equivalent)
E can be :
NO2
O O
NH NH
(A) (B)

NO2

O
H
NH
(C) NO2 (D) O 2N NH 2

Cl

3. Select reactions from the following showing incorrect product formations-

OH Cl
Cl
PCl3
Red P
(A) CH3–COOH CH2–COOH (B)
Cl2
Me Me
Me Me
PCl5 PCl5 Cl
(C) (D) Me–CHO Me – CH
O
H H Cl
4. Compound which can consume more than one mole of Ph–NHNH2 per mol is-
OH OH
O
(A) (B) (C) (D)
HO O
O O
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 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE
5. Carbonyl compound with highest percentage of its hydrate is -
O O
(A) (B)
O O O O

O O O O
(C) (D)
O

6. Which is reduced during cannizaro's reaction of HCHO & PhCHO with 50% conc. NaOH

(A) H–C–H (B) Ph–C–H (C) Both H–C–H & Ph–C–H (D) NaOH
O O O O

Br KMnO
7. A 2 4  B
 

Compound A and B respectively are:

(A) o-Bromostyrene, benzoic acid (B) p-Bromostyrene, benzaldehyde
(C) m-Bromostyrene, benzaldehyde (D) Styrene dibromide, benzoic acid
8. Which chloroderivative of benzene among the following would undergo-hydrolysis most readily with
aq.NaOH to furnish the corresponding hydroxy derivative.

(A) O2N (B) O2N Cl

(C) Me2N Cl (D) Cl

More than one correct :

9. The monomer that undergo radical polymerisation most easily is
(A) CH2=CH2 (B) C6H5CH=CH2
Me
(C) CH2=C (D) CH3 –CH=CH2
Me
10. Select the correct statement :
(A) Glycosides do not undergo mutarotation
(B) All OH groups of a cyclic monosaccharides are converted to ethers by treatment with base and
an alkyl halide
(C) -D glucose reacts with Ag2O and excess CH3I to form tetramethyl ether
(D) D-glucose upon treatment with warm HNO3 forms D-glucaric acid

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 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE

11. Amino acids are synthesised from

(A) -Halo acids by reaction with NH3
(B) Aldehydes by reaction with NH3 and cyanide ion followed by hydrolysis
(C) Alkyl halides by reaction with the enolate anion derived from diethyl acetamidomalonate
& hydrolysis.
(D) Alcohols by reaction with NH3 and CN¯ ion followed by hydroysis.
12. Select the correct statement
(A) High density polythene is a linear polymer.
(B) Low density polythene is a branched chain polymer.
(C) Chain growth polymers are also known as addition polymer.
(D) Step growth polymer is also known condensation polymer.
Matrix Match Type :
13. Match the reactions in Column-I with appropriate types of step/reactive intermediate involved in these
reactions as given in Column-II
Column-I Column-II
H3C O O
O
(A) aq NaOH
  (P) Nucleophilic substitution

O O
CH 3MgI
(B) CH2CH2CH2Cl    CH3 (Q)Electrophilic substitution

18 O
O
18 H SO
(C) CH2CH2CH2OH 
2 4
 (R) Dehydration

CH2CH2CH2C(CH3)2 H 2SO 4
(D)   (S) Nucleophilic addition
OH
H3C CH3
(R) Carbanion
Integer type :
14. Number of reagents which converts CH3–CHO into carboxylic acid or its salt :
(1) Cu/573 K (2) Fehlling’s reagent (3) Na/LiqNH3 (4) Tollen’s reagent

(5) NaOH/I2 (6) Bayer’s reagent (7) H/KMnO4/ (8) H2/Pd

(9) H/K2Cr2O7/ (10) OH¯/

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 GUIDED REVISION ENTHUSIAST & LEADER
Target : JEE(Main + Advanced) - 2019 COURSE
15. The compound among following which can give 2,4-DNP test (2,4-dinitrophenylhydrazine test)
O
(i) (ii) (iii) (iv)
O NH
NH2 O
H
(v) (vi) (vii) (viii) HCHO
O
O
O–H

(ix) (x)

ANSWERS
ORGANIC CHEMISTRY
Guided Revision Plan-Score Advance-Question Bank (03)Only one correct :
1. Ans. (B) 2. Ans. (B) 3. Ans (C) 4. Ans. (D) 5. Ans. (C)
6. Ans. (B) 7. Ans. (D) 8. Ans. (A)
More than one correct :
9. Ans. (B) 10. Ans. (A,B,D) 11. Ans. (A,B,C) 12. Ans. (A,B,C,D)
Matrix Match Type :
13. Ans. (A)R,S,T ; (B)P,S ; (C)R,S ; (D)Q,R
Integer type :
14. Ans. (5) 15. Ans. (5)

4 E