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Chemistry 2 Week 3 4 2ND SEM
Chemistry 2 Week 3 4 2ND SEM
Introductory Message
To the Parents:
This learning material is made for your child to learn the needed skills in General
Chemistry 1. This is composed of discussions and activities where your child can learn. The
Introduction is all about the knowledge that your child already knows. This part connects
what is already known and what is about to be learned. The Development part provides the
needed information and skills to be learned. Engagement part has activities which will
strengthen the mastery of the lesson. The Assimilation part includes assessment to
determine if your child has acquired the needed skills and gives opportunity for your child to
reflect for their own learning/life skills.
As a guardian, you have a great role in helping your child to learn while at home. Your
guidance is needed so that he/she can understand the lessons and instructions better.
Nevertheless, you may let him/her work independently so he/she can develop his/her skills
fully.
If you have any question or if your child needs help about the lesson, please do not
hesitate to call or message us. We are ready to assist you.
When you return this to school, his/her teacher will check and record your child
responses and progress.
Thank you for always showing love to your child by continuously helping them to learn!
To the Learner:
Greetings!
This learning material is designed especially for you. This is composed of discussions
and activities to further develop your knowledge, understanding and skills in General
Chemistry 2. The lesson has four parts: Introduction, Development, Engagement and
Assimilation.
You are tasked to answer all the activities in this learning material using a clean sheet
of paper. Do not write anything on this learning material. You may ask the guidance of
your parents, guardian, brother and sisters while doing the activities. You are also expected
to attend the follow–up session on the schedule time provided for you. You have to finish
answering the activities before the date set by your teacher.
Your parents/guardian shall return this material together with your answers. Your
teacher shall check all your responses to the activities/exercises and shall inform you of your
progress.
Should you have any question about the lesson or you find difficulty in understanding
the lesson or activity, do not hesitate to contact or message your teacher who is always ready
to assist you.
Happy learning!
1
Grade Level: Grade 12
Quarter:
Week:
1st
3-4
Changes in Solutions
No of Days: 8
Introduction
https://whenyouriseup.com/courses/young-science-solids-liquids-gasses/
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Lesson 1 Phase Change
Start up
Pre-quiz
True or False.
Discussion
https://www.youtube.com/watch?v=29x7vArV2NI
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Our environment is mostly affected by the changes in temperature and pressure. Changes in
these tow environmental factors can result in phase changes. A phase change refers to the change of
a substance from one state to another. In the above example, moth balls, after being left inside the
cabinet will disappear without a trace as time passes by. The phase change that the moth balls
underwent is sublimation. A phase change is reversible since only the physical property of the
substance is change. There are six common phase changes of matter namely freezing, melting,
condensation, vaporization, sublimation and deposition.
(https://study.com/academy/lesson/phase-change-evaporation-condensation-freezing-
melting.html#:~:text=Learn%20the%20six%20changes%20of,%2C%20vaporization%2C%20sublimation%20and%20deposition)
http://www.chemistry.wustl.edu/~edudev/LabTutorials/CourseTutorials/bb/Thermochem/Phase.htm
Using the concept of phase changes, observations can be presented in two ways through the heating
curve or cooling curve and the phase diagram. The heating curve and the cooling curve are graphical
illustrations of the effects of heat when the pressure is held constant.
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https://www.worldwisetutoring.com/heating-and-cooling-curves/
Notice that heating curve and cooling curve are just the opposite of each other. In heating curve, the
temperature goes up as heat is added to the substance. In addition, when the curve becomes flat or
horizontal (called plateaus) phase change happens. During this stage, two phases happen. Solid and
liquid are in equilibrium during melting. However, liquid and gas phases are in equilibrium during boiling.
Super heating may occur when the temperature of the liquid exceeds the boiling point.
When heat is constantly added to a solid material, the following are expected to happen:
1. There will be constant rise in the temperature of the solid until it melting process begins.
2. Temperature stops rising once melting begins and remains constant until the solid material is
completely melted.
3. Temperature will begin to rise again at a constant rate until boiling begins.
4. Temperature stops rising once boiling starts. It remains constant until the liquid is completely
converted to gas.
5. The temperature of the gas rises at a steady rate.
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Phase Diagram
The phase diagram on the other hand, is a graphical illustration showing the effects of both pressure
and temperature. It shows the relationship among temperature, pressure and the three states of matter.
Temperature is always plotted in the x-axis while pressure is plotted in the y-axis.
Melting curve – also called the solid-liquid equilibrium line, it shows the temperature and pressure that
a solid undergoes to become liquid and vice versa. This line points upward from the triple point.
Vapor curve – also called the liquid-gas equilibrium line, it shows the temperature and pressure that a
liquid undergoes to become a gas and vice versa. This line extends in a curved upward manner (due
to the compressibility of gases) and to the higher temperature side of the triple point. It ends at the
critical point or the maximum temperature at which any liquid can exist. The critical point occurs under
conditions at which no phase boundaries exist.
Sublimation curve – also called the solid-gas equilibrium line, it shows the temperature and pressure
that a solid undergoes to become a gas. This line extends in a downward curve manner (due to the
compressibility of gases) and to the lower temperature side of the triple point.
Triple point – the temperature and pressure where there is equilibrium between the three states of
matter.
http://www.sklogwiki.org/SklogWiki/index.php/Phase_diagrams:_Pressure-temperature_plane
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Fig. 2 phase diagram showing the different phases of the three states of matter
https://en.wikipedia.org/wiki/Phase_diagram#/media/File:Phase-diag2.svg
Engagement
What’s More?
Part I. Supply the missing words.
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Part II Copy and analyze the diagrams and answer the questions in your answer
sheet. Use graphing paper.
Assessment
Part I.
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https://www.ck12.org/book/ck-12-chemistry-second-edition/r18/section/16.6/
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Lesson 2 Gases, Solids and Liquids in Mixtures
Introduction
1. Use different ways of expressing concentration of solutions: percent by mass, mole
fraction, molarity, molality, percent by volume, ppm
2. Perform stoichiometric calculations for reactions in solutions.
3. Describe the effect of concentration on the colligative properties of solutions.
https://www.pinterest.ph/pin/270990102556387345/
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Start up
Pre-activity
Illustrate the molecular set up of solid, liquid and gas and describe each.
Discussion
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Solution
In a solution, components may be solid, liquid or gas. On this basis solutions can be divided
into following three types: https://10upon10.com/class12/12phychem/chemistry-solutions-1.html
• Gaseous solution
• Liquid solution
• Solid solution
1. Gaseous solutions.
Solutions in which solvent is present in gaseous state are called Gaseous solution. Gaseous
solutions can be divided into following three types on the basis of phases of solute and solvent.
https://10upon10.com/class12/12phychem/chemistry-solutions-1.html
a. Gas-gas solutions. Gaseous mixtures come in homogenous state just like the
earth’s atmosphere. The atmosphere is made up of the combination of different
gases (nitrogen, oxygen, helium, argon, etc.) which are vital to survival.
b. Liquid-gas solution. When the solute is in liquid state and solvent is in gaseous
state, are called Liquid-Gas Solution. For example - solution (mixture) of chloroform
in nitrogen gas.
c. Solid Gas Solution. The solute is in solid state and solvent is in gaseous state, are
called Solid-Gas Solutions. For example - Solution (mixture) of camphor in nitrogen
gas.
2. Liquid Solution:
These are solutions in which the solvent present is in liquid state. Liquid solutions can be
classified into following three types: Gas - Liquid Solution, Liquid - Liquid Solution, Solid
- Liquid Solution https://10upon10.com/class12/12phychem/chemistry-solutions-1.html
a. Gas - Liquid Solution. Solutions having solute in gaseous state and solvent in liquid
state, are called Gas - Liquid Solutions. For example - Solution (mixture) of oxygen in
water, mixture of carbon dioxide in water. Coca cola, a beverage, is an example of gas
- liquid solution, as it has carbon dioxide dissolved in water.
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b. Liquid - Liquid Solution. Solutions, in which solute and solvent both are present in liquid
state, are called liquid liquid solutions. For example - Vinegar solution, vinegar is the
mixture of ethanoic acid and water. Solution of ethanol in water, etc.
c. Solid - Liquid Solution. Solutions, in which solutes present in solid state and solvent is
in liquid state, are called solid liquid solutions. For example - Solution of salt in water,
solution of glucose in water, etc.
3. Solid Solution
Solutions having solvent in solid state, are called solid solutions. Solid solution can be divided
into following three categories: Gas - Solid Solution Liquid, Solid Solution Solid, Solid
Solution https://10upon10.com/class12/12phychem/chemistry-solutions-1.html
a. Gas - Solid Solution. Solutions having solvent in solid state and solute in gaseous state
are called gas-solid solutions. Example - solution of hydrogen in palladium.
b. Liquid - Solid Solution. Solutions having solvent in solid state and solute in liquid state
are called liquid - solid solutions. Example amalgum of mercury with sodium.
c. Solid - solid solution. Solutions having solvent and solute both in solid state are called
solid – solid solutions. Example - Solution of gold and copper.
Based on the whether the solvent is water or not, solutions are of two types.
✓ Aqueous solutions: These solutions have water as the solvent. Examples of such
solutions are sugar in water, carbon dioxide in water, etc.
✓ Non-Aqueous Solutions: These solutions have a solvent that is not water. It could be
ether, benzene, petrol, carbon tetrachloride etc. Common examples include sulfur in
carbon disulphide, naphthalene in benzene, etc.
✓ Unsaturated Solution: An unsaturated is one that can dissolve more solute at a definite
temperature. It means that we can still add more solute to the solvent.
✓ Saturated Solution: A solution is said to be saturated when we can’t add any more
solute to the solvent. This means that the solution can’t dissolve any more solute at a
definite temperature.
✓ Supersaturated Solution: A supersaturated solution is one where the solute is present
in an excess amount. This solute is dissolved forcefully by raising the temperature or
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pressure of the solution. These generally crystal out in the bottom by the method called
crystallization.
✓ Dissolution- the process by which a solid or liquid, forms a homogenous mixture with
a solvent to form a solution.
✓ Solubility – a measure of how much solute can be dissolved in a specific solvent.
Solutions Stoichiometry
In the first quarter, you learned about stoichiometry and other calculations. Now you will
learn how to apply the concepts of stoichiometry in dealing with solutions.
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It must be remembered that the objective of stoichiometry is to get data from balanced
chemical equation. The following data can be calculated depending on the type of problem:
2. Molar mass
3. volume of gas
4. mole ratio
• Mole
• Molar mass
• Molarity
• molality
• Empirical formula
• Percent composition
• Equivalent weights
• Limiting reagent
1. Molarity - the most common unit of concentration. Defined as the number of moles
of solute dissolved in 1 liter of solution.
𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒 𝑚
Molarity (M) = or
𝑙𝑖𝑡𝑒𝑟𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 𝑛
Step 1: Find the moles of HCl by dividing the amount in grams by its molar mass.
H=1x1 = 1 Cl = 35 x 1 = 35
35+ 1 = 36
1 𝑚𝑜𝑙 𝑜𝑓 𝐻𝐶𝑙
2.6 g of HCl x = 0.072 mol of HCl
36 𝑔 𝑜𝑓 𝐻𝐶𝑙
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2. Molality - the number of moles of solute per kilogram of solvent
𝑚𝑜𝑙
m=
𝑘𝑔
Example:
Suppose that 0.15 mole of table salt is dissolved in 1.26 kg of water. What is the
molal concentration of this solution?
0.15 𝑚𝑜𝑙
mol = = 0.12 molal (m) or 0.12 mol/kg
1.26 𝑘𝑔
Example:
What is the concentration of a solution made by dissolving 2.1 grams of salt in 8.3 g
of water?
Solution:
Mass of solution = 2.1 g + 8.3 g = 10.4 g
2.1 𝑔
% mass = ( ) x 100% = 20%
10.4 𝑔
5. Percentage by volume - the volume of the solute per unit volume of the solution.
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
% volume = ( ) x 100%
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
Example:
A solution is prepared by dissolving 90 milliliters of pure hydrogen peroxide in
enough water to make 3000 milliliters of solution. What is the concentration of the
hydrogen peroxide solution?
Given data:
Volume of solute = 90 mL
Volume of solution = 3000 mL
90 𝑚𝑙
% volume = ( ) x 100% = 3%
3000 𝑚𝑙
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6. Parts per million and parts per billion
Parts per million and parts per billion is similar to the concentration by percentage by
mass or volume, only the multiplier must be changed into 106 and 109 respectively.
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
Parts per million (ppm) = ( ) x 1,000,000
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
Parts per billion (ppb) = ( ) x 1,000,000,000
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
Cross multiply.
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Cross multiply.
Answer: 2.78 moles of H2
4. Volume to Volume
- Volume to volume relationship is applicable only to gases. according to
Avogadro’s Law, one mole of gas at standard temperature and pressure (STP)
is equal to 22.4 L volume which is called the molar volume of a gas.
- Example: What volume of oxygen gas would react with 25.0 L of hydrogen
has at STP?
2 H2(g) + O2(g) → 2 H2O(g)
25.0 L X
44.8 L 22.4 L
To solve for H2, multiply 22.4 by 2. Thus, the answer is 44.8 L.
Cross multiply.
X= 12.5 L of O2
Normality - Normality (N) of a solution is the number of equivalents of solute per liter of
solution. It is another way of expressing concentration of solution. However, the term is not
used in the SI system. Slowly normality is being replaced by molarity.
𝑔
No. of equivalent solute = ( )
𝑒𝑞 𝑤𝑡
Based on Arrhenius’ concept, an acid is a substance that yields H+ ions in water solution,
while a base is a substance that yields OH- ions in water solution. Salt on the other hand, is
one of the products of neutralization reactions. Svante August Arrhenius, a Swedish physicist
and chemist and a Nobel prize winner for chemistry was the one who espoused this concept.
The equivalent weight of an acid is the weight in grams that will furnish 1 mole of H+ ions.
Example:
1. HCl + NaOH → NaCl + H2O
1 mole of HCl (36.5 g) furnishes 1 mole of H+; therefore, 1 equivalent weight of HCl weighs
36.5 g.
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2. H2SO4 + Mg(OH)2 → MgSO4 + 2H2O
1 mole of H2SO4 (98 g) furnishes 2 moles of H+; therefore, 1 equivalent weight of H 2SO4
weighs 49 g.
Example:
98
1. H3PO4 = ( ) = 32.66
3
Engagement
• Water • sugar
• Vinegar • 6 disposable glasses
• Oil • a spoon
Procedure:
1. Obtain 6 clean disposable glasses and prepare the following set-up.
Set-up 1: 1 cup water + 4 tablespoons vinegar
Set-up 2: 1 cup water + 4 tablespoons oil
Set-up 3: 1 cup water + 4 tablespoons sugar
Set-up 4: 1 cup vinegar + 4 tablespoons oil
Set-up 5: 1 cup vinegar + 4 tablespoons sugar
Set-up 6: 5 tablespoon oil + 4 tablespoons alcohol
2. Thoroughly stir each mixture and observe carefully.
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Note: •Do not forget to wash and dry the spoon after each use.
• Properly label each set-up.
• Samples with oil should first be mixed with dishwashing liquid before disposing down the
sink
Guide Question:
a. Which of the following set-ups mixed well? Which did not?
b. What can you infer from the result of this activity?
1. A saline solution with a mass of 355 g has 36.5 g NaCl dissolved in it. What is the
mass/mass percent concentration of the solution?
2. What is the percent by mass concentration of 12.5 grams NaCl dissolved in 20 g of
water?
Assessment
Generalization
✓ Solution is a homogenous mixture of two or more substances
✓ Three types of solutions are:
• Gaseous solution
• Liquid solution
• Solid solution
✓ Factors affecting dissolution and solubility are temperature, particle size, stirring,
pressure and molarity
Assessment
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Part 2. Compute for the equivalent weights. Show your solutions.
1. HNO3
2. HNO2
3. H3PO4
4. NaOH
5. Mg(OH)2
6. NH4OH
7. Al(OH)3
8. KOH
9. HF
10. HBr
11. HI
12. H2S
Reflection:
References:
https://studylib.net/doc/17618107/chemistry--name--__________________-heating-curve-
workshe...
https://www.sophia.org/tutorials/labeling-a-phase-change-diagram
https://studylib.net/doc/8562750/heating-curves-and-phase-change-diagrams
https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Map
s/Supplemental_Modules_(Physical_and_Theoretical_Chemistry)/Physical_Properties_of_Ma
tter/States_of_Matter/Phase_Transitions/Phase_Diagrams
https://www.studocu.com/en-us/document/university-of-houston-downtown/introductory-
chemistry/tutorial-work/ws-f-phase-change-problems-worksheet/7012135/view
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