SETH ANANDRAM JAIPURIA SCHOOL

REVISION TEST(2021-22) , CLASS-XII

(Topic -Amines)

Time:. 45 min Min Max. Marks-20

OBJECTIVE TYPE QUESTIONS (1 x 5=5)

1. Which of the following reagents would not be a good choice for reducing an aryl nitro compound to an amine?
(a) H2 (excess)/Pt
(b) LiAlH4 in ether
(c) Fe and HCl
(d) Sn and HCl

2. The correct decreasing order of boiling points among amines and their corresponding acids and alcohols is
(a) R – CH2 NH2 > RCOOH > RCH2OH
(b) RCH2NH2 > RCH2OH > RCOOH
(c) R – CH2OH > R – CH2NH2 > RCOOH
(d) R – COOH > R – CH2OH > R – CH2NH2

3. Aniline is less basic than ethylamine. This is due to

(a) Conjugation of lone pair of nitrogen with the ring
(b) The insoluble nature of aniline
(c) More Kb value of aniline
(d) Hydrogen bonding
4. Choose the amide which on reduction with LiAlH4 gives secondary amine.
(a) Ethanamide
(b) N-Methyl ethanamide
(c) N, N-diethyl ethanamide
(d) Benzamide

5. 4-Nitrotoluene is treated with bromine to get P. ‘P’ is reduced with Sn/HCl to get compound ‘Q\ ‘Q’ is diazotised
and the product is treated with phosphinic acid to get compound ‘R’. ‘R’ is oxidised with alkaline KMnO4 to get
‘S’. Compound ‘S’ is
(a) 2-Bromo-4-hydroxy benzoic acid
(b) 2-Bromo benzoic acid
(c) 3-Bromo benzoic acid
(d) 4-Bromo benzoic acid

6. What is the product obtained when C6H5CH2NH2 reacts with HNO2 ? [1]
7. What is the structure and IUPAC name of the compound, allyl amine ? [1]
8. Why are carboxylic acids more acidic than alcohols and phenols although all of them have hydrogen linked to a
oxygen atom? [1]
9. Write the structure of the amide which gives propanamine by Hofmann bromamide reaction. [1]
10. How will you distinguish between the following pairs of compounds- [2]
(a) N-Ethylethanamine and benzylamine
(b) Ethylamine and Aniline
11. Arrange the following in the order mentioned below and justify - [3]
(a) C6H5NH2 , C6H5N(CH3)2 , (C6H5)2NH , CH3NH2 ( increasing basic strength)
(c) CH3NH2 ,(CH3)2NH , (CH3)3N , C6H5NH2, C6H5CH2NH2 (increasing order of basic strength)
(d) (C2H5)2NH, C6H5 NH2 C2H5NH2 (decreasing order of solubility in water)
1
12. Predict the products of the following reaction: [3]

(i)HNO3
(i) C6H5NH2 (CH3CO)2O ‘ A’ ‘ B’
(ii) H+

NH3 NaOBr
(iii) CH3COOH A B

13. Give reasons for the following- [3]

(a) ) Reactivity of –NH2 group gets reduced in acetanilide.
(b)MeNH2 is stronger base than MeOH.
(c)Aniline does not undergo Friedal-Crafts reaction.