Question:

Describe the preparation of

(a) 500 mL of 0.0750 M AgNO3 from the solid reagent.

(b) 1.00 L of 0.285 M HCl, starting with a 6.00 M

solution of the reagent.

(c) 400 mL of a solution that is 0.0810 M in K+,

starting with solid K4Fe(CN)6.

(d) 600 mL of 3.00% (w/v) aqueous BaCl2 from a

0.400 M BaCl2 solution.

(e) 2.00 L of 0.120 M HClO4 from the commercial

reagent [71.0% HClO4 (w/w), sp gr 1.67].

(f) 9.00 L of a solution that is 60.0 ppm in Na+, starting

with solid Na2SO4.

Answer :

a) Given:

Molarity of

Volume of the

Molar mass of

Mass of in 500 mL of solution can be calculated as

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 Mass of

Therefore, 0.0750 M solution can be prepared by dissolving

of in water and diluting to 500 mL.

b) Given:

Molarity of the given

Molarity of the prepared

Volume of the prepared

Here, we have to calculate the volume of the concentrated and this can be
obtained by dividing the number of moles of required by the molarity of the
given solution:

Number of moles

Volume of concentrated reagent

Therefore, solution can be prepared by diluting of

concentrated to 1 L.

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 c) Molarity of

Molarity of

Volume of the prepared

Therefore, in can be prepared by dissolving of

in water and then diluting to 400 mL.

Mass of in 400 mL solution can be calculated as

Mass of

Therefore, 0.02025 M solution can be prepared by dissolving

of in water and diluting to 400 mL.

d) Given:

Molarity of the given

Volume of the prepared

Concentration of

To obtain the volume of concentrated , we have to first determined the

number of moles of and then divide it by the molarity of the concentrated
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 (given) solution.

Number of moles of

Volume of concentrated solution

Therefore, 3.00% (w/v) of can be prepared by diluting of the given

solution to 600 mL.

e)

Given:

Molarity of the prepared

Specific gravity of concentrated

Concentration of

Volume of the prepared

Calculation of molarity of concentrated

Now, to obtain the volume of the concentrated solution, we have to first calculate
the number of moles of and then divide it by the molarity of the
concentrated solution.
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 Number of moles of

Volume of the concentrated solution

Therefore, solution can be prepared by diluting of

concentrated solution to 2.00 L.

f) Given:

Concentration of

Volume of the prepared

Molar mass of

To determine the molar concentration of from the given ppm value, we have to
convert ppm into molarity.

For an aqueous solution 1ppm is given as

So,

Now, divide by the molar mass of in order to

determine the molar concentration of .
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 Molar concentration of

Thus, the molar concentration of

The mass of in 9.00 L solution can be calculated as

Mass of

Therefore, 60 ppm in solution can be prepared by dissolving of

in water and then diluting to 9.00 L.

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