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Resources, Conservation and Recycling
Resources, Conservation and Recycling
Novel approach for the treatment and recycle of wastewater from soya edible
oil refinery industry—An economic perspective
K. Rajkumar a,b,∗ , M. Muthukumar a , R. Sivakumar b
a
Department of Environmental Sciences, Bharathiar University, Coimbatore 641046, Tamilnadu, India
b
Sakthi Sugars Limited-Soya Division, Pollachi, 642103, Tamilnadu, India
a r t i c l e i n f o a b s t r a c t
Article history: The soya edible oil manufacturing industries with a capacity of 18,000 tones/annum, generate wastew-
Received 20 October 2008 aters and solid wastes. The streams of wastewater originate primarily after several processes viz. soap
Received in revised form splitting, floor washing, cooling tower and boiler. The wastewater from cooling tower, boiler sections and
12 November 2009
solid wastes can be recycled and reused after essential preliminary treatment. In this study, we observed
Accepted 16 December 2009
that wastewater from the site of study and other peripheral streams did not conform to the legislated
permissible limits prescribed for discharge, by the Central Pollution Control Board, Government of India.
Keywords:
Hence, we adopted certain novel measures to enhance the treatment efficacy of the effluent treatment
Cost estimated
Effluent treatment plant
plant (ETP). The overall percentage removal of COD, TDS, and O&G was 94–98, 92–97 and 97–99%, respec-
Edible oil refinery tively. Moreover the fixed capital cost of ETP was estimated 50 lakhs—Indian Rupees (Rs.) and annual
Reuse and recycle operation and maintenance cost was estimated Rs. 10.356 lakhs, the cost of treatment of 1 m3 wastewater
Soybean was Rs. 82.67 (U$ dollar = 1.79). Further recycle, recovery and reuse of water were adopted to achieve the
Solid wastes target of zero discharge for ecological and economical gains.
© 2010 Elsevier B.V. All rights reserved.
1. Introduction ular structures which make them more stable and difficult to be
biodegraded.
Saving water to save the planet earth and to ensure a safe future India has approximately 90 units of edible oil refineries located
for mankind is the ultimate need of the hour. With the growth of in different states. The sources of edible oil are soybean, ground-
mankind, society, science, and technology our world is reaching nut, rapeseed, sunflower, safflower, cotton, sesame, coconut, palm,
to new high horizons but the cost which we are paying or will mustard, rice bran, watermelon, neem, etc. This crude oil is then
pay in near future is surely going to be too high. Environmental refined in order to remove free fatty acids and other non-TAG (tri-
disorder with an increased pollution problem is one of the con- acylglyceride) components which contribute to undesirable flavor,
sequences of this rapid growth. Besides other needs, the demand odor and appearance (Anderson, 1953). Crude oil is refined using
for water (“Water for People Water for Life” United Nations World several processes to remove undesirable components before mak-
Water Development Report UNESCO) has increased tremendously ing it available for human consumption (Dumont and Narine, 2007).
with agricultural, industrial and domestic sectors consuming 70, The refinery process generates by-products produced after crude
22 and 8% of the available fresh water, respectively and this has oil refining. Fig. 1 summarizes the conventional processing steps
resulted in the generation of large amounts of wastewater contain- encountered from crude to refined rapeseed oil. The refining of
ing a number of ‘pollutants’ (Helmer and Hespanhol, 1997; Lehr et crude edible oils generates large amounts of wastewater. The neu-
al., 1980; Nemerrow, 1978). One of the important classes of the pol- tralization step, in particular, produces sodium salts of free fatty
lutants is edible oil refinery process, and once they are discharged acids (“soapstocks”) whose splitting through the use of H2 SO4 gen-
into enter the water bodies it is no longer good and sometimes erates highly acidic and oily wastewater. Its characteristics depend
difficult to treat as the oil refinery wastewater have complex molec- largely on the type of oil processed and on the process implemented
(Azbar and Yonar, 2004). Several successive physical processes are
involved in depollution of such effluents before a final biological
step in a waste treatment station. Oil and grease in oily wastewa-
ter may take various forms namely: free, dispersed and emulsified.
∗ Corresponding author at: Department of Environmental Sciences, Bharathiar
Decantation and skimming are effective in removing free oil
University, Coimbatore 641046, Tamilnadu, India. Tel.: +91 98653 10077.
E-mail addresses: rajkumar env@yahoo.co.in (K. Rajkumar),
(Cheryan and Rajagopalon, 1998). For decades, aerobic treatment
mmuthukumar@yahoo.com (M. Muthukumar), sivakumar@sakthisoyas.com has been used to remove biodegradable organic pollutants present
(R. Sivakumar). in the wastewater generated during various industrial processes.
0921-3449/$ – see front matter © 2010 Elsevier B.V. All rights reserved.
doi:10.1016/j.resconrec.2009.12.005
K. Rajkumar et al. / Resources, Conservation and Recycling 54 (2010) 752–758 753
and then discharged directly into soil or ground water. But, due
to the emergence of environmental consciousness, the Pollution
Control Boards have become stricter and impose very stringent
norms. The scarcity of water is also another incentive for recov-
ering pure water from effluents. For the treatment of an effluent
by conventional methods like aerobic or anaerobic digestion, the
ratio of BOD to COD should be >0.6 (Chian and Dewalle, 1977).
However, an effluent from the vegetable oil industry usually has
a BOD/COD ratio around 0.2, which could cause the destruction
of micro-organisms useful for the biodegradation. The combined
wastewater from these sections of the refined edible oil manufac-
turing industry is acidic and contaminated with oil and colloidal
particles. Generally, physico-chemical processes followed by bio-
logical processes are adopted for the treatment of such wastewater.
The physico-chemical processes include air flotation, skimming of
oil, flocculation and coagulation for colloidal pollutants followed
by biological processes for dissolved organics (Pathe et al., 2000;
Saha et al., 1998).
Flotation is a unit operation which is applied to separate solid or
liquid particles from a liquid phase, the dissolved air flotation (DAF)
for the removal of emulsified oils from oily wastewater. A dissolved
air flotation unit has been designed for this purpose and the ulti-
mate goal is to explore the technical viability of this technique. The
design and construction of the dissolved air flotation pilot plant
have been conducted to treat 1.0 m3 h−1 of oily wastewater. Sepa-
ration is achieved by introducing fine gas (with help of compressor
air) bubbles into the liquid phase. Being the bubble attached to the
(oil) particulate matter, and the buoyant force of the combined par-
Fig. 1. Simplified schematic diagram of soybean vegetable oil refining processes. ticle and gas bubbles are great enough to cause the particle to rise to
the surface. Particles that have a higher density than the liquid can
The refined edible oil manufacturing units generate solid waste be facilitated (e.g., oil suspension in water). Once the particles have
(spent earth) and wastewater which are of environmental con- been floated to the surface, they can be collected by a skimming
cern and need proper treatment prior to their disposal (Pandey et operation (Rajkumar, 2006).
al., 2003). In a vegetable oil industry, the effluent mainly comes The refinery uses chemical and physical methods for the
from the degumming, deacidification, neutralization, bleaching, refining of oils (soybean). The entire process involved is sum-
and deodorization steps, etc. (Kale et al., 1999). The blow-down marized in Fig. 1. On an average, the refinery and other process
of the boiler and wash water from de-oiling of the bleaching earth generate around 200 m3 of wastewater daily, which includes
also contribute to the effluent in small amounts. Previously, effluent acid wastewater (60–80 m3 /day) and technological wastewater
from a vegetable oil industry used to undergo primary treatment (90–120 m3 /day). In view of the present emphasis placed on envi-
Fig. 2. Simplified schematic diagram of the treatment system for the vegetable oil refinery wastewater.
754 K. Rajkumar et al. / Resources, Conservation and Recycling 54 (2010) 752–758
Table 2
Characteristics of the wastewater generated at soya edible oil refinery.
Parameter Influent Final Standard for treated effluent for inland water discharge (MoEF)
MoEF, Ministry of Environment and Forest, Government of India, New Delhi; ND, not detectable.
K. Rajkumar et al. / Resources, Conservation and Recycling 54 (2010) 752–758 755
Table 4
Cost estimation summary (2009).
Fig. 3. Cost breakdown in term of percentage for the (a) total fixed capital cost, (b) annual operation and maintenance and (c) treatment cost per cubic meter of wastewater.
tem, and power required to achieve an arbitrarily selected 98% COD 3.6.2. Soap stock
removal level for the pollutants studied in this work are shown in The degumming step is not always necessary prior to chemical
Table 4. The nature of the pollutant strongly influences the power refining. The best known and the most widely used chemical refin-
requirements, with the ratio between the aeration and the power ing process is the caustic soda process. Phosphoric acid is added to
required to be in the range 2.5 kg equivalent O2 /kWh. On the basis the crude oil in order to precipitate the phospholipids; this is fol-
of this information, an average operational cost in the range Rs. lowed by the addition of an alkaline solution. The alkaline solution
44.74 kg−1 ($—0.97) equivalent O2 was assumed (Rajkumar and neutralizes the free fatty acids Eq. (2) and any excess phosphoric
Muthukumar, 2009). acid Eq. (3). Reaction of the alkaline solution with fatty acids leads to
the formation of soap. The soap stock created is then continuously
separated from crude oil by centrifugation (O’Brien, 2004):
3.6. Recovery, recycle and reuse of the wastes treatment
RCOOH + NaOH → RCOONa (2)
Generally, the soya edible oil manufacturing units practice
recovery of lecithin, soap stock and spent earth as by-products for H3 PO + 3NaOH → Na3 PO4 (3)
reuse.
Soap stock is defined as a by-product, which results from the
alkali-refining of the edible oil, otherwise treated as waste. The
3.6.1. Lecithin basic reaction in alkali-refining is given in Eq. (4) below:
Lecithin is derived from the degummed edible oil and it is one
of the important ingredients of phosphatides. Soy lecithin con- C3 H5 (O2 CR)3 + 3NaOH → 3RCO2 Na + C3 H5 (OH)3 (4)
fat alkali sodium soap glycerol
sists of three types of phospholipids; phosphatidylcholine (PC),
phosphatidylethanolamine (PE) and phosphatidylinositol (PI). It The soap stock is produced during the refining of edible oil. The
is extracted from soybean oil and is generally used as a natu- soap stock contains 50% total fatty matter and, therefore, it has a
ral emulsifier or stabilizer in various food applications. Lecithin commercial value. The soap stock produced in the industry is sold
is a combination of naturally occurring phospholipids, which are directly to the soap manufacturers (Pandey et al., 2003).
extracted during the processing of soybean oil. Soybean oil is
extracted from the flakes through a distillation process and lecithin 3.6.3. Spent earth
is separated from the oil by the addition of water and centrifugation Spent bleaching earth (SBE) is an industrial waste generated at
or steam precipitation. the vegetable oil refining industry after the colouration (bleaching)
Soy lecithin offers a multifunctional, flexible and versatile tool. of crude oil. The annual world generation of SBE is between 1.5 and
It is probably best known for its emulsifying properties, which help 2.0 million tones based on the world edible oil production of 128.2
promote solidity in margarine and give consistent texture to dress- million metric tones in 2007 (Soystats, 2007) and 1.2–1.6 kg of SBE
ings and other creamy products. Lecithin is also used in chocolates generation per metric ton of edible oil production. SBE contains
and coatings to counteract spattering during frying. Additionally, 20–40% by weight of oil, fat and coloured pigments (Werner, 1994)
its unique lipid molecular structure makes lecithin useful for phar- and may present a fire hazard, if it is not stored or disposed properly
maceutical and cosmetic applications and various industrial uses (Taylor and Jenkins, 1999). Waste minimisation is an umbrella term
such as paints, textiles, lubricants and waxes. used to denote any process which results in a reduction of the waste
K. Rajkumar et al. / Resources, Conservation and Recycling 54 (2010) 752–758 757
stream prior to treatment or disposal (Patterson, 1989). Source of applying a range of onsite wastewater treatment techniques to
reduction, waste recovery, reuse, and recycling are examples of meet legislative standards and discharge into inland surface water.
waste minimisation strategies. The reuse of SBE and the concomi- The optimal design and operation, in terms of installation and
tant recovery of residual oil has been a recurrent focus of research operation cost, of ETP from our numerical experiences, we may con-
within the edible oil industry for nearly 50 years. Clay regenera- clude that the efficiency of the treatment influences directly and the
tion has been attempted by steam (Penninger, 1979). However, the estimate way the resulting cost of the effluent treatment plant. The
industry was suggested to reuse spent earth as substitute of coal in economic evaluation for 200 m3 /day treatment plant concluded
the boiler plant. that the fixed capital cost was Rs. 50 lakhs (U$ dollar = 108,695.65),
operation and maintenance cost was estimated Rs. 10.356 lakhs (U$
3.6.4. Wastewater dollar = 22,513.04), and the cost of treatment of 1 m3 wastewater
It was suggested, and also practiced to reuse and recycle the was Rs. 82.67 (U$ dollar = 1.79) (1 U$ dollar = Rs. 46). However, the
acidic wastewater from soap splitting tank for soap splitting. Recy- most effective approach to pollution control is one that emphasizes
cling of the cleaning water through collection tank was adopted process development to minimise losses at the source, reuse and
for reusing in the manufacturing process. The recycling of process recycle.
cooling water was adopted in bleaching, deodourizer, and green
development. Acknowledgements
3.6.5. Lime sludge The authors are thankful to Dr. N. Mahalingam, Chairman of
Lime sludge generated during the process after dewatering of Sakthi Group of Companies, Sri M. Manickam, Vice Chairman and
producing wastewater is a product that has beneficial reuses. Lime Managing Director, Sakthi Sugars Limited and Mr. M. Ponnuswami,
sludge has beneficial reuse via agricultural land application, mixing Senior President of Sakthi Sugars Limited, Tamilnadu, India.
with compost, or other application. If it is demonstrated that these
reuses are economically impractical, other methods of lime sludge References
disposal that may be considered include placement in lagoons,
Almato M, Espuna A, Puigjaner L. Optimization of water use in batch process indus-
quarries, or landfills. These reuses must be considered and demon- tries. Comput Chem Eng 1999;23:1427–37.
strated to be economically impractical before other options will be American Public Health Association (APHA), American Water Works Associ-
considered. ation (AWWA), Water Environment Federation (WEF). Standard methods
for the examination of water and wastewater. 20th ed. Washington, D.C.:
APHA/AWWA/WEF; 1995.
3.6.6. Biological sludge from aeration basins Anderson AJC. Refining of oils and fats for edible purposes. London/New York: Aca-
demic Press; 1953. pp. 204.
Excess sludge in an inevitable by-product of wastewater treat-
Azbar N, Yonar T. Comparative evaluation of a laboratory and full-scale treatment
ment. Sludge production is clearly located in the aeration basin alternatives for the vegetable oil refining industry wastewater (VORW). Process
and sludge is composed of minerals (10–30%), biomass (20–50%) Biochem 2004;39:869–75.
and non-biomass organics (20–40%) along with garbage was sug- Bruggen BV, Braeken L. The challenge of zero discharge from water balance to regen-
eration. Desalination 2006;188:177–83.
gested to be composted and reused for vegetation. The suggestions Cheryan M, Rajagopalon N. Membrane processing of oily streams. Wastewater treat-
were adopted by the industry and produced composted sludge is ment and waste reduction. J Memb Sci 1998;151:13–28.
now being taken up from the pit and distributed to the farmers for Chian ESK, Dewalle FB. Treatment of high strength acidic wastewater with com-
pletely mixed anaerobic filter. Water Res 1977;11:295.
agricultural usage. Dumont MJ, Narine SS. Soapstock and deodorizer distillates from North American
vegetable oils: review on their characterization, extraction and utilization. Rev
Food Res Int 2007;40:957–74.
4. Economic study Dunn RF, Wenzel H. Process integration design methods for water conservation and
wastewater reduction in industry. Part 1. Design for single contaminants. Clean
Based on the above results, effluent treatment plant economic Prod Processes 2001;3:307–18.
El-Halwagi MM. Pollution prevention through process integration: systematic
study for 200 m3 /day wastewater treatment plant for the soya oil design tools. San Diego, CA, USA: Academic Press; 1997.
refinery industry was conducted. Maximum design parameters of Hallale N, Fraser DM. Capital cost targets for mass exchange networks. A special
wastewater samples for soya oil refinery industry are illustrated case: water minimization. Chem Eng Sci 1998;53:293–313.
Helmer R, Hespanhol I. Water pollution control—a guide to the use of water quality
in Table 3. Fig. 2 shows the schematic block flow diagram of the
management principles. London, Great Britain: E & FN Spon; 1997.
effluent treatment system, which consists of: equalization tank, Jodicke G, Fischer U, Hungerbuhler K. Wastewater reuse: a new approach to screen
flocculate, D.A.F. clarifier, oil separator, aeration tank, and sec- for designs with minimal total costs. Comput Chem Eng 2001;25:203–15.
ondary clarification. The economies of the plant were computed Kale V, Katikaneni SSP, Cheryan M. Deacidification of ricebran oil by solvent extrac-
tion and membrane technology. JAOCS 1999;76(6):723.
with the estimated cost data shown in Table 4, Fig. 3. The fixed cap- Koppol APR, Bagajewicz MJ, Dericks BJ, Savelski MJ. On zero water discharge solu-
ital cost was Rs. 50 lakhs. The cost of treatment of 1 m3 wastewater tions in the process industry. Adv Environ Res 2003;8:151–71.
was Rs. 82.67 ($—1.79). Kuo WCJ, Smith R. Designing for the interactions between water-use and effluent
treatment. Trans IChemE Part A: Chem Eng Res Des 1998;76:287–301.
Lehr JH, Gass TE, Pettyjohn DeMarre J. Domestic water treatment. New York:
5. Conclusions McGraw-Hill Book Company; 1980.
Nemerrow NL. Industrial water pollution: origins, characteristics, and treatment.
Massachusetts: Addison-Wesley Publishing Company; 1978.
The waste from soya edible oil refinery included solid wastes O’Brien RD. Fats and oils formulating and processing for applications. 2nd ed. Boca
viz. spent earth, chemical and biological sludge and wastewater Raton, FL: CRC Press; 2004. pp. 68–69.
Pandey RA, Sanyal PB, Chattopadhyay N, Kaul SN. Treatment and reuse of wastes of
from solvent extraction, soap splitting unit, floor washing, and
a vegetable oil refinery. Res Conserv Recycl 2003;37:101–17.
cooling and boiler sections. The combined wastewater from soap Parthasarathy G. Minimization of cost of recycling in chemical processes. Chem Eng
splitting and floor washing had high concentration of oil and COD. J 2001;81:137–51.
Pathe PP, Nandy T, Kaul SN. Wastewater management in vegetable oil industries.
The wastewaters produced are amenable to physical, chemical, and
Indian J Environ Protect 2000;27:481–92.
biological treatment. It is clear that the degree and type of treat- Patterson JW. Industrial wastes reduction. Environ Sci Technol 1989;23:1032–8.
ment are influenced by local circumstances. The industry under Penninger JML. Extraction of oily matter from spent bleaching earth with water at
investigation recycled and reused most of the solid wastes, while elevated temperature and pressure. J Chem Tech Biotechnol 1979;29:154–7.
Rajkumar K. Industrial pollution and control—pollution control audits, air, noise,
wastewater from cooling and boiler section was recycled in the pro- wastewater treatment and solid waste management. Sakthi Sugars Limited -
cess (Pandey et al., 2003). The remaining wastewater has a history Soya Division, Pollachi, Tamilnadu, India; 2006.
758 K. Rajkumar et al. / Resources, Conservation and Recycling 54 (2010) 752–758
Rajkumar K, Muthukumar M. Operation and maintenance manual for effluent treat- Soystats. World vegetable oil consumption 2007. St. Louis, MO: American Soybean
ment plant. Sakthi Sugars Limited - Soya Division, Pollachi, Tamilnadu, India; Association; 2007.
2006. Taylor DR, Jenkins DB. Factors affecting the pyrophorisity of spent bleaching clay. J
Saha K, Pathe PP, Kaul SN. Environmental management in vegetable oil and vanas- Am Oil Chem Soc 1999;67:678.
pati industries, national seminar and exposition. Lucknow, U.P., India: World Wang YP, Smith R. Wastewater minimization. Chem Eng Sci 1994;49:981–1006.
Scenario Oleochemicals and Surfactants Industries; 1998. Werner Z. Spent bleaching earth-practical solutions. Inform 1994;5:1375.