March Attempt Online JEE Main 2021 01

17 MARCH SHIFT-II CHEMISTRY

1. (b) Fructose is an example of ketohexose is a class of sugars that [Co(NH 3 ) 6 ] [Cr(CN) 6 ] Û [Co(CN) 6 ] [Cr(NH 3 ) 6 ] (Coordinate
contains six-carbon atoms and a ketonic group. Fructose has a isomerism)
ketonic group with six carbon atoms.
B. Linkage isomerism occurs in coordination compounds that
It contains five hydroxyl group and one ketonic group. have the same composition but differ in the connectivity of the
The structure of fructose is ligand to the metal.
1 [Co(NH 3 ) 3 (NO2 ) 3 ] shows linkage isomerism. NO2 can connect
CH2OH through N and O donor sites.
2
C. Solvate isomerism is also known as ‘hydrate isomerism’ where
C==O Ketonic group water behaves as a ligand and water of crystallisation.
3 e.g., The complex  [Cr(H 2 O) 6 ]Cl3   (violet) contains water as a
HO H
4 ligand and its solvate isomer  [Cr(H 2 O)5 Cl] Cl2H 2 O  (grey- green)
H OH
5 contain water as a water of crystallisation.
H OH
D. Optical isomerism occurs mainly in compounds that are mirror
6 images of each other.
CH2OH
cis[CrCl2 (ox) 2 ]3+   is chiral compound, hence shows optical
2. (d) Li-Na pair is different from remaining three options as it do not isomerism.
shows diagonal relationship. Both Li-Na belongs to same group and
are not placed diagonally. 8. (a) Primary, secondary and tertiary amines can be separated using
Li-Mg, B- Si and Be- Al show diagonal relationship. para-toluene sulphonyl chloride. This test is known as Hinsberg test.
Reaction involved are as follows:
Li Be B (Diagonal
Na Mg Al Si relationship) Primary (1°) amine Primary amines react with para toluene sulphonyl
chloride to form a precipitate that is soluble in NaOH.
3. (a) The functional group responsible for the ion-exchange property
Me— —SO2Cl
of cation is ¾ SO3H and that of anion is ¾NH 2 .
R—NH2 RNHSO2 — —Me (ppt.)
Cation resins  attract positively charged ions and contain acidic –HCl
group like ¾ SO3H or ¾ COOH groups. While anion resins  attract Soluble in
negatively charged ions and contains basic groups like ¾NH 2 . NaOH (Base)

Secondary (2°) amine Secondary amines reacts with para toluene

4. (d) Correct matches are A-2, B-1, C-4, D-3.
sulphonyl chloride to give a precipitate that is insoluble in NaOH.
Ore Formula Me— —SO2Cl

Haematite Fe2 O3 R2—NH RNSO2 — —Me (ppt.)

–HCl
Not soluble in base
Bauxite Al2 O3 × xH 2 O
Tertiary (3°) amine Tertiary amines do not react with para toluene.
Magnetite Fe3 O4 Me— —SO2Cl
R3N No reaction
Malachite CuCO3 × Cu(OH) 2
9. (a) Common positive oxidation states for an element with atomic
5. (c)  The correct pair(s) of ambident nucleophile are (A) KCN and number 24, are + 2 to + 6.
AgCN and (C) AgNO2 and KNO2 . Chromium (Z = 24)
Ambident nucleophiles have the ability to bind the central atom via Electronic configuration: [Ar] 4s1 3d 5
the two different atoms. It has five electrons in 3d-subshell and one electron in 4s -subshell.
Structure are as follows: Thus, chromium metal has six valence electrons. Chromium can
- lose some or all of its valence electrons to form ions with different
CN can bind through C and N atoms.
oxidation states. Thus, chromium shows the oxidation states of + 1,
C N C N + 2, + 3, + 4, + 5 and + 6 respectively.
NO-2 can bind through N and O. The most common oxidation states of chromium are + 2, + 3 and
N N + 6.
–
10. (b) The correct matches are A-2, B-1, C-4, D-3.
6. (a) N 2 O and NO are neutral oxides of nitrogen, whereas NO2 and A. Sucralose ® Artificial sweetener
N 2 O3 are acidic oxides. Artificial sweetener is the sugar that is sweet like sugar but has
zero or low calories. Artificial sweeteners can be plant extract
Neutral oxides are neither acidic nor basic. These oxides neither
or chemical synthesised. Saccharin, aspartame, sodium
react with acids nor with bases.
cyclamate and sucralose are the examples of artificial
7. (a) (A)-3, (B)-1, (C)-2, (D)-4 sweeteners.
A. Coordination isomerisms occurs in coordination salts in which B. Glyceryl ester of stearic acid ® Synthetic detergent Esters of
there is an interchange of ligands between the metal in the stearic acid are used in synthesis of soaps and detergents.
cationic coordination spheres and the metal in the anionic C. Sodium benzoate ® Food preservative
coordination sphere.
02 Online JEE Main 2021 March Attempt

The food is oxidised or hydrolysed by several factors such as Reaction involved are as follows
air that is known as aerial oxidation, or by moisture, bacteria + –
and light. N2Cl OCH3
Sodium benzoate has an aromatic ring that can stabilise the
free radical which causes the oxidation of food. Sodium C2H5OH
benzoate is a food preservative. + N2 + CH3CHO + HCl
D. Bithionol ® Antiseptic Nitrogen Acetaldehyde Hydrochloric
Methoxy (X) acid
Bithionol is added to soap to impart antiseptic property. It OCH3 benzene (Y)
reduces odour produced by bacterial decomposition of organic (A)
matter on the skin. p-methoxy benzene
diazonium chloride
11. (c) Statement I is correct, whereas statement II is incorrect. Corrected
statement is as follows:
17. (b) To coagulate negative sol, Ba 2 + cation has highest coagulation
value.
Tertiary alkanes can be oxidised to alcohol by treating with KMnO4 .
For a negative sol, a positive ion is required for flocculation.
n-alkane are very less reactive and have no reaction with KMnO4 .
KMnO According to Hardy-Schulze law, greater the valence of the
n-alkanes ¾ ¾¾4 ® No reaction flocculating ion added, the greater is its power to cause
12. (b) Nitrogen can be estimated by Kjeldahl's method for the benzyl precipitation.
amine as in this compound nitrogen is not the part of ring and is free 18. (d) Statement (D) is incorrect.
to react.
As eutrophication is the  gradual increase in the concentration of
Because this method can be readily applied to the compound in phosphorus, nitrogen, and other plant nutrients  in an aging aquatic
which nitrogen is free to react with the reagent. The compounds ecosystem such as a lake. The productivity or fertility of such an
which have nitrogen in the ring (like pyridine), an azo compound, ecosystem naturally increases as the amount of organic material that
or in nitro compounds are not readily converted into the ammonium can be broken down into nutrients increases.
sulphate by the action of sulphuric acid.
19. (a)   Carbocation B is more stable due to more hyperconjugation and
13. (d) N -3 is linear species. formed relatively at faster rate compared to A.
–
– + – + HBr + Br
N O O N N N +
But-1-ene 2ºcarbocation
Cl Cl Linear
(B) –
Bent shape Bent shape Bent shape + Br
+
Hybridisation = Number of sigma bond + number of lone pairs + 1ºcarbocation
number of coordinate bonds. (A)
Hybridisation of N in NO = 1 + 1 + 1 = 3. So, hybridisation is sp 2 and Carbocation B is more stable as it is secondary carbocation having
structure is bent or V-shape. more number of  a-hydrogens, having a greater + I effect and formed
Hybridisation of O in OCl2 = 2 + 2 = 4. So, hybridisation is sp 3 and with faster rate due to low activation energy.
structure is bent or V-shape.
20. (a)   Entropy will decrease in A,B,C and D processes.
Hybridisation of O in O3 = 1 + 1 + 1 = 3. So, hybridisation is sp 2 and
A, B ® Freezing of water will decrease entropy as particles will
structure is bent or V-shape.
move closer and forces of attraction will increase. This leads to a
Hybridisation of N in N -3 = 2. So, hybridisation is sp and structure is decrease in randomness. So, entropy decreases.
linear.
(A) Water ¾ 0ºC
¾¾® ice; DS = - ve
14. (c) Invertase and zymase are enzyme A and enzyme B respectively. - 10ºC
(B) Water ¾ ¾ ¾
¾® ice; DS = - ve
Invertase  is the enzyme that catalyses the hydrolysis of sucrose with
(C) N 2 ( g ) + 3H 2 ( g ) ¾® 2NH 3 ( g ); DS = - ve
a resulting mixture of fructose and glucose, which is called inverted
sugar. It cleaves the O ¾ C bond. Number of moles are decreasing
n = 2 - (3 + 1)
C12H 22 O11 + H 2 O ¾Invertase
¾ ¾¾® C6H12 O6 + C6H12 O6
Sucrose Glucose Fructose n= -2
Zymase  is an enzyme that catalyses the fermentation of sugar into So, entropy decreases.
ethanol and carbon dioxide. (D) Adsorption; DS = - ve
Zymase
C6H12 O6 ¾ ¾ ¾
¾® 2C2H5 OH + 2CO2 Adsorption will lead to a decrease in the randomness of gaseous
Glucose Ethanol particles.
So, entropy decreases.
15. (c) CaCl2 is one of the by-products formed during the recovery of
(E) NaCl( s) ¾® Na + ( aq) + Cl- ( aq);DS > 0
NH 3   from Solvay process.
The number of species on product side is more than the number of
Ammonia required for the process can be prepared by heating species on reactant side. So, entropy increases on dissolution of
ammonium chloride with calcium hydroxide. NaCl in water.
2NH 4 Cl + Ca(OH) 2 ¾® 2NH 3 + CaCl2 + H 2 O
21. (57) Given,
Hence, the only by-product of the reaction is calcium chloride.
Conductivity of KCl solution kKCl = 0.14 Sm- 1
16. (a) The structural formula of (A), X and Y are p-methoxy benzene RKCl = 419
. ohm
diazonium chloride, acetaldehyde and hydrochloric acid
RHCl =1.03 ohm
respectively.
 March Attempt Online JEE Main 2021 03

To find conductivity of HCl solution kHCl 26. (49) Electronic configuration of Fe : 1s 2 2 s 2 2 p 6 3s 2

We know that, In 3d 6 , number of unpaired electrons (n) = 4
k = 1 /R × G * Spin only magnetic moment = n(n + 2) BM
where k is the conductivity, R is the resistance and G * is the cell = 4( 4 + 2) = 24 = 4.9 = 49 ´ 10- 1
constant.
Nearest integer value will be 49.
As k is constant. Therefore, k and G * constant
\ kKCl × RKCl = kHCl × RHCl 27. (1) The number of chlorine atoms in 20 mL of chlorine gas at STP is
1 ´ 1021
. ´ 419
Therefore, 014 . = k ´ 103 .
. ´ 419
014 . Given values are : At STP, pressure of gas, p = 1 atm
or, k of HCl solution = Temperature of gas, T = 273 K
103
.
Volume of gas, V = 20 mL = 20/1000 L
= 0.5695 S m- 1 = 56.95 ´ 10- 2 Sm- 1
Gas constant, R = 0.083 L atm/K mol
= 57 ´ 10- 2 Sm- 1 Ideal gas equation: pV = nRT …(i)
22. (6) Secondary valency is equal to coordination number of central On putting given values of p, V and T in Eq. (i)
metal ion. In this reaction, central metal atom iron is attached with 20 N
3-oxalato ligand, and oxlaic acid it is a bidentate ligand i.e. have 1.0 ´ = ´ 0.083 ´ 273
1000 6.023 ´ 1023
two donor sites. So, coordination number or secondary valency
=3´2 =6 n = number of molecules,
FeCl3 + 3H 2 C2 O4 + 6KOH ¾® K 3 [Fe(C2 O4 ) 3 ] + 3KCl + 6H 2 O Avogadro’s constant, NA = 6.023 ´ 1023
(A) Number of Cl 2 molecules, N = 53. ´ 1020
Hence, product A have iron with secondary Number of Cl atoms in 1 molecule of chlorine gas = 2
valency = 6 Number of Cl atoms in 53. ´ 1020 molecules = 53
. ´ 1020 ´ 2 =1 ´ 1021
23. (27) Given, the reaction 2A + B2 ¾® 2 AB is an elementary 28. (5) The number of cationic vacancies in 1 g of KBr crystal is 5 ´ 1014 .
reaction.
For every Sr 2+   ion, 1 cationic vacancy is created. Hence, number of
So, rate of reaction = k[ A ]2 [B2 ] Sr 2+   ion = number of cationic vacancies
Initial rate = k ( a / V ) 2 ( b / V )1 Since, the mole percentage of SrBr2   dopped is10-5   to that of total
where, a and b are the number of moles of A and B and V is the moles of KBr.
volume. 10- 5 1
Hence, number of cationic vacancy = ´ ´ NA
On reducing the volume by a factor of 3, the concentrations of A 100 119
1
and B2 will become 3 times = ´ 10- 7 ´ 6.022 ´ 1023 (Mass of KBr = 119)
Final rate = k(3 a / V ) 2 (3b / V )1 119
2 1 = 5 ´ 10- 2 ´ 10- 7 ´ 1023 = 5 ´ 1014
a æbö
32 ´ 3k æç ö÷ ç ÷ = 27 ´ initial rate 29. (354) The temperature at which KC = 20.4 and Kp = 6001
. , is 354 K.
èV ø èV ø
Hence, the rate becomes 3 ´ 3 = 27 times of initial rate.
2 Given reaction is, N 2 O4 ( g )
Given values are : Kp = 6001
.
- 2 NO2 ( g )
24. (5) The structural formula with C ¾ C sigma bond(s) in mesityl oxide
is as follows: KC = 20.4
σ
H3C—C= σ σ σ
=CH—C—CH Dng = number of moles of product - number of moles of reactant
3
σ Using relation between Kp and KC = 2 - 1 = 1
CH3 Dn
Kp = KC (RT ) g
Therefore, number of C ¾ C sigma bonds in mesityl oxide = 5. where R is the gas constant = 0.083 L atm/K mol
25. (85) K 4 Fe(CN) 6 - 4K + + [Fe(CN) 6 ]4 - Dng = 1 (for given reaction)
Initial conc. 1m 0 0 On putting given values, we will get
Final conc. (1 - 0.4) m 4 ´ 0.4 0.4 m . = 20.4 (RT )1 Þ T » 354 K
6001
= 0.6 m = 16
. m
Effective molality = 06 . + 16
. + 0.4 = 2.6 m
30. (77)
As elevation in boiling point is a colligative property which depends
on the amount of solute. So, to have same boiling point, the molality C Cl C—N(C6H5)2
of two solutions should be same. + C6H5NHC6H5 + HCl
Molality of non-electrolyte solution = molality of
K 4 [Fe(CN) 6 ] = 2.6 m Given mass = 0.140 g 0.388 g 0.210 g
Now, 18.1 weight per cent solution means 18.1 g solute is present Molar mass = 140.5 g/mol 169 g/mol 273 g/mol
in 100 g solution and hence, (100 - 181 . =) 819
. g water. No. of moles = 0.001 mol 0.0023 mol 0.00077 mol
(Mass of solute / Molar mass of solute)
Molality = ´ 1000 Limiting reagent is benzoyl chloride as amount of benzoyl chloride
Mass of solvent(g) is less than amount of amine.
18.1 / M Theoretical of amide formed = moles of benzoyl chloride = 0.001 mol
Now, 2.6 =
81.9 /1000 Given amount of amide formed
% yield = ´ 100
where, M is the molar mass of non-electrolyte solute Theoretical amount of amide
Molar mass of solute, M = 85 0.00077
= ´ 100 = 77%
0.001