March Attempt Online JEE Main 2021 01

16 MARCH SHIFT-II CHEMISTRY

1. (c) Greenhouse gases are carbon dioxide, methane, water vapours,

Mechanism
nitrous oxide, CFCs and ozone. The greenhouse effect is a natural
process that warms the Earth’s surface. When the Sun’s energy (I) Initiation : This involves formation of radicals.
reaches the Earth’s atmosphere, some of it is reflected back to space UV
Cl2 light 2Cl
and the rest is absorbed and re-radiated by greenhouse gases. The
absorbed energy warms the atmosphere and the surface of the Earth. (II) Propagation : Reactive free radicals react with stable
molecules to form new free radicals.
2. (c) In the given reaction, A is alkaline KMnO4 , H + .
Alkaline KMnO4 / H+ is a strong oxidising agent and oxidises alkyl Cl + + HCl (More stable allylic
benzene to benzoic acid. While NaBH 4 ,LiAlH 4 and Zn-Hg/HCl are free radical is formed)
reducing agent. Cl
CH3 COO–K+ COOH
+ Cl— Cl + Cl
Alkaline H+
KMnO4
Similarly second Cl atom is also attached at allylic position.
OCH3 OCH3 OCH3 Cl Cl
4-methoxy 4-methoxy 4-methoxy
toluene benzoate benzoic acid
+ Cl2
3. (a) Reduction of alumina (Al2O3) to Al cannot be achieved by carbon
reduction. As aluminium has greater reactivity with oxygen than
carbon and hence cannot be reduced by carbon. So, Cl
electrometallurgy (Hall-Heroult process) is used to get Al.
6. (c) In secondary structure of protein, hydrogen bond is formed
2Al2O3(l) + 3C ¾® 4 Al + 3CO2 O
Rest oxides can be reduced by coke as follows ½½
Fe2O3 + 3C ¾® 2Fe +3CO between ¾ C ¾ and ¾NH ¾ groups of the peptide bond.
Cu2O + C ¾® 2Cu + CO Peptide linkage is an amide formed between ¾ COOH group and
Coke, 1673 K
¾NH 2 group while connecting two amino acids.
ZnO + C ¾¾¾¾® Zn + CO The two monosaccharides are joined together by an oxide linkage
4. (a) Given data, formed by the loss of a water molecule is called glycosidic linkage.
IE1 IE2 7. (a) Fel3 does not exist because of I - . Being a very good reducing
X 495 4563 kJ/mol agent, I- reduces Fe3+ to Fe 2 + .
Y 731 1450 kJ/mol 2Fe3+ + 2I- ¾® 2Fe2+ + I2
X is Na (3s1) as it has very high second ionisation energy due to Reducing nature order I > Br > Cl > F
removal of electron from highly stable noble gas configuration.
IE
Fe3+ + e - ¾® Fe2+ E° = 0.77 V
Na ¾® 1
Na+ + e - ; IE1 = 495 kJ/mol
I 2 + 2 e - ¾® 2 I - E° = – 0.54 V
1s 22 s 22 p 63s1 1s 22 s 22 p 6 or [Ne]
IE
As standard reduction potential value of Fe3+ is more than I2, so it is
Na+ ¾®
2
Na 2+ + e - ; IE 2 = 4563 kJ/mol reduced to Fe2+ . Hence, except FeI3 , all other halogens can form
1s 22 s 22 p 6 1s 22 s 22 p5 iron halide compounds.
(Stable noble gas configuration).
8. (c) Urea-formaldehyde is used to manufacture unbreakable cups and
In case of Mg, noble gas configuration is achieved after removal of laminated sheets.
second electron. So, IE2 is comparatively less.
It is an example of condensation polymer in which water molecule
Mg ¾® Mg+ + e - ; IE1 = 731 kJ/mol is removed from urea and formaldehyde forming an amide linkage.
[Ne]3 s 2 [Ne]3 s1
(a) cis-poly isoprene is natural rubber.
Mg +
¾® Mg 2+ + e - ; IE2 = 1450 kJ/mol (b) Melamine - formaldehyde polymer used in the manufacture of
[Ne] 3 s1 [Ne]
unbreakable crockery.
5. (c) The reaction can be achieved by Cl2 /UV light (A). Given,
(d) Phenol-formaldehyde resin used as good wood adhesives for
reaction follows free radical substitution mechanism. plywood and particle board.
Cl
9. (c) NaH is not an oxidising agent as Na + and H - ions are formed. Na
Cl2 exists only in + 1 and hydrogen is present in minimum -1 state so,
UV light
cannot be reduced further. NaH is used as reducing agent.
Lone pair on nitrogen in pyridine is localised and does not take part
Cyclohexene
Cl in resonance. So, it can accept H + acting as a base.
1, 4-dichloro cyclohexene
02 Online JEE Main 2021 March Attempt

(i) O3
H3C—C==C—CH3 2 CH3 — C==O
(ii) Zn/H2O
N CH3 CH3 CH3
Pyridine 2-3-dimethylbut-2-ene Ketone (acetone)
So, statement I is true but statement II is false. (b) Isopropylidiene undergoes ozonolysis reaction to give acetone
10. (d) along with cyclopropanone.
CH3 CH3
(i) O3
—
CH3—C — —O + O—
H3C—C — —
(ii) Zn/H2O
Acetone Cyclopropanone
Isopropylidiene

(c) Butyne reacts with O3 and Zn/H 2O to give 2-oxobutyraldehyde.

The aldehyde will give Tollen’s test to give silver mirror.
Note Tollen’s reagent contain silver nitrate ( AgNO3), ammonia
and sodium hydroxide (NaOH) which react with aldehydes to
give Ag (silver mirror).

O3
CH C—CH2 —CH3 HC—C—CH2 —CH3
Zn/H2O
Butyne 2-oxobutyraldehyde
C60 molecule has a shape like soccer ball and called Buckminster Tollen's
Silver mirror
fullerene. It is an allotrope of carbon. It contains twenty-six reagent
membered rings and twelve-five membered rings. A six membered
(d) But-2-yne undergoes ozonolysis to give butan-2, 3-dione.
ring is fused with six or five membered rings but a five membered
ring can only fuse with six membered rings.
O3
All the carbon atoms are equal and they undergo sp 2-hybridisation . CH3—C C—CH3 H3C—C—C—CH3
Zn/H2O
Each carbon atom forms three sigma bonds with other three carbon But-2-yne Butan-2, 3-dione
atoms. Only product of option (c) contains aldehyde group.
So, statement (d) is wrong.
14. (c) Basic nature is directly proportional to electron releasing
11 (b) H 2O2 act as both oxidising and reducing agent. tendency. If lone pair is delocalised, electron density decreases and
Oxygen is present in -1 oxidation state, so it can be oxidised to O2 basic strength decreases.
as well as reduced to water.
-1 -2
H 2O2 ¾® H 2O (Reduction) (a) CH3—C—NH—C2H5 CH3—C==NH—C2H5
Oxidising agent
-1 0
H 2O2 ¾® O2 (Oxidation)
Reducing agent (c) CH3—C—NH—C—C2H5 Delocalised with both
H 2O2 is miscible with water due to intermolecular H-bonding. carbonyl group
Due to open book like structure both ¾OH groups are not in same So, there is delocalisation of electron in both options (a) and (c).
plane and hence, H 2O2 is non-planar. But it option (c) there is delocalisation of electron with both
carbonyl group. Hence, it is weakest base.
There is a subtle interplay of the inductive effect, solvation effect
H H and steric hinderance of the alkyl group, which decides the basic
95.0 pm 98.08 pm strength of alkyl amines in the aqueous state. The order of basic
147.5 pm 111.5º 145.8 pm
O O O O 90.2º strength in case of ethyl substituted amines in aqueous solution is as
94.8° 101.9° follows
H H
(C2H5) 2NH > (C2H5) 3N > C2H5NH 2 > NH 3
(a) Gas phase ··
(b) Solid phase \ ( C2H5) 2 NH is strong base.
(a) H 2O2 structure in gas phase, dihedral angle is 111.5°. 15. (b) Atomic number 33 is for arsenic (As), 53 is for iodine (I) and 83
(b) H 2O2 structure in solid phase at 110 K, dihedral angle is 90.2°. is for bismuth (Bi).
H 2O2 used in treatment of effluents. X = As is metalloid, Y = I is non-metal and Z = Bi is metal.
12. (c) Ammonolysis of alkyl halides 16. (c) (A) Lassaigne test is used to detect N, S, P, X elements.
NH3 R—X R—X RX ⊕s
R–X R—NH2 R2NH R3N R4NX The elements present in the compound are converted from covalent
–HX –HX –HX form into the ionic form by fusing the compound with sodium
During the reaction HX (acid) is formed. Hence, we use NaOH to metal. Following reactions take place.
remove this acidic impurities. D
Na + C + N ¾® NaCN
13. (c) On ozonolysis, unsaturated hydrocarbon Xwill form carbonyl D
2Na + S ¾® Na 2S
compound, which gives positive Tollen’s test. So, it should be
aldehyde. D
Na + X ¾® NaX ( X = Cl, Br or I)
(a) 2, 3-dimethylbut-2-ene undergoes ozonolysis reaction to give 2
molecules of acetone.
 March Attempt Online JEE Main 2021 03

(B) Carbon and hydrogen are detected by heating the compound H 3PO2 + NaOH ® NaH 2PO2 + H 2O
100 mL 1M
with copper (II) oxide. 2M V= ?
C + 2CuO ¾® 2Cu + CO2 Millimoles of H 3PO2 = M ´ V = 2 ´ 100 = 200
2H + CuO ¾® Cu + H 2O For 1 millimole of H 3PO2, we require 1 millimoles of NaOH.
(C) Halides are detected by silver nitrate. For 200 millimole of H 3PO2, we require 200 millimoles of NaOH.
They form precipitate of AgX except fluorine. So, volume of NaOH = 200 mL
Ag + ( aq) + X - ( aq) ¾® AgX( s )
20. (d) Cyanide undergoes nucleophilic addition with Grignard followed
(D) Sodium fusion extract gives black precipitate of PbS with acetic by hydrolysis to give carbonyl compound.
acid and lead acetate to confirm the presence of sulphur. Ph
Na 2S+ (CH 3COO) 2Pb ¾® PbS + 2CH 3 COONa – +
Black ppt. CN C6H5MgBr C NMgBr
(1.0 equivalent)/dry ether
17. (b) Statement (b) is incorrect whereas all other statements are correct.
(a) Colloidal solution exhibits colligative properties.
(b) An ordinary filter paper cannot stop the flow of colloidal OCH3 OCH3
particles as the pores are bigger as compared to size of
O
colloidal particles.
+
However, the pores of filter paper can be reduced in size by H3O /Hydrolysis Ph
impregnating with collodion solution to stop the flow of
colloidal particles. The usual collodion is a 4% solution of
nitrocellulose in a mixture of alcohol and ether. An ultra-filter OCH3
paper may be prepared by soaking the filter paper in a
collodion solution, hardening by formaldehyde and then finally Mechanism Carbon of cyanide is electrophilic and is attacked by
drying it. Thus, by using ultra-filter paper, the colloidal nucleophilic phenyl anion.
particles are separated from rest of the materials.
Ph
(c) The flocculating power of Al+3 is more than that of Na + . The
δ+ δ– –+
greater the valence of the flocculating ion added, the greater is C N C NMgBr
its power to cause precipitation. This is known as Hardy PhMgBr
schulze rule. In the coagulation of a negative sol, the Dry ether
flocculating power is in the order Al+3 > Ba+2 > Na+ .
+
(d) When colloidal solutions are viewed under a powerful OCH3 OCH3 H 3O
ultramicroscope, the colloidal particles appear to be in a state
of continuous zig-zag motion all over the field of view . This is Ph Ph
known as Brownian movement.
C O C NH
18. (d) H3O+ Br
+Mg
58 Ce ¾®
2 0 2 – NH3 OH
(A) [ Xe] 4 f 5d 6 s
In complex Ce +4 ¾® [ Xe] 4 f 0 5d 06 s 0
OCH3 OCH3
There is no unpaired electron, so m m = 0 BM
(B) 64 Gd ¾® [Xe]4 f 7 5d 16 s 2 21. (15) For HCP structure,
In complex, 2+
¾® [Xe]4 f 5d7 1 Effective number of atoms per unit cell ( Z ) = 6
64 Gd
Number of tetrahedral void = 2 Z = 12
There are 8 unpaired electrons.
Number of octahedral void = Z = 6
\ m m = 8(8 + 2) = 80 = 8.94 BM
Total number of voids per unit cell = 18
(C) 63Eu ¾® [ Xe]4 f 9 5d 06 s 0 Given mass 0.581
Moles of Ga = =
In complex 63Eu
+3
¾® [Xe]4 f 6 5d 06 s 0 Molar mass 70
0.581
contain six unpaired electrons. No. of atoms = ´ NA
70
So, m m = 6(6 + 2) = 48 BM = 6.93 BM
0.581 NA
Hence, order of spin only magnetic moment No. of unit cells = ´
70 6
B > C > A.
æ 0.581 6.02 ´ 1023 ö
19. (c) H 3PO3 +2NaOH ¾® Na 2HPO3 + 2H 2O No. of voids = ç ´ ÷ ´ 18 = 14.99 ´ 10 .
21

50 mL 1M è 70 6 ø
1M V= ?
Nearest integer = 15 ´ 1021
Millimoles of H 3PO3 = M ´ V = 1 ´ 50 = 50
For 1 millimole of H 3PO3, we require 2 millimoles of NaOH. So, correct answer is 15.
For 50 millimole of H 3PO3, we require (2 ´ 50) =`100 millimoles of 22. (14) Given, concentration of KCl
NaOH. (C ) = 5 m mol / L = 5 ´ 10-3mol/L
Millimoles of NaOH = M × V = 100 Conductance ( G) = 0.55 mS
1 ´ V = 100 l
Cell constant = 1.3 cm-1
V = 100 mL A
04 Online JEE Main 2021 March Attempt

k l = 1, ml = - 1, 0, 1
Lm =
1000 ´ C l = 2, ml = - 2 , - 1, 0, 1, 2
where, L m = molar conductivity l = 3, ml = - 3, - 2 , - 1, 0, 1, 2 , 3
k = conductivity, C = molarity l = 4, ml = - 4 , - 3, - 2 , - 1, 0, 1, 2 , 3, 4
l Possible value of ml for a given value of l
Conductivity ( k) = G = 0.55 ´ (1.3 ´ 100)
A = 0, ± 1, ± 2 , ± 3 .... ± l
= 55 ´ 1.3 So, number of orbitals having n = 5 and ml = ±2 are 3.
55 ´ 1.3
Lm = 26. (19) From Raoult’s law,
1000 ´ 5 ´ 10-3
L m = 14.3 pT = p° A c A + pB° cB …(i)
Closest integer, where, pT = total pressure of solution
L m = 14 pB° , p°A = vapour pressure of pure liquid B and A respectively.
23. (108) Given, (t 1/ 2)1 = 54 min c A , cB = mole fraction of A and B in solution phase.
(t 1/ 2) 2 = 18 min Given, p°A = 21kPa, pB° = 18 kPa
A B nA = 1, nB = 2
t = 0, ‘ x’ M t = 0, ‘ x’ M nA 1
To calculate, [ A t ] = 16 ´ [Bt ] …(i) cA = =
nA + nB 3
time = ?
2
A cB = 1 - c A =
For Ist order reaction, [ A t ] = 0n 3
(2)
Putting the values in equation (i),
n = number of half-lives
pT = æç21 ´ ö÷ + æç18 ´ ö÷ = 7 + 12 = 19 kPa
1 2
From Eq. (i), [ A t ] = 16 ´ [Bt ]
è 3ø è 3ø
x x
= ´ 16
(2) n1 (2) n2 27. (1) For H 2SO3 , Ka 1 >> Ka2
(2) n2
= (2) n1
´ (2) 4
So, we mainly consider 1st ionisation
Þ n2 = n1 + 4 H 2SO3 H+ + HSO3- ; Ka1 = 17
- . ´ 10-2
+ 4 Þ t æç
t t 1 1 ö
= - ÷=4 t=0 0.558 0 0
(t 1/ 2) 2 (t 1/ 2)1 è18 54 ø
t = t eq 0.558-0.558a 0.558a 0.558a
4 ´ 18 ´ 54
Þ t = = 108 min [H + ][HSO-3 ] ( 0.558 a)( 0.558 a) 0.558 a2
36 Ka 1 = = =
[H 2SO3 ] 0.558(1 - a) 1- a
24. (19) Given, mass of organic compound 0.1840 g a << 1 for weak acid
Total pressure = 758 mm of Hg
(1 - a) » 1
Aqueous tension = 14 mm of Hg
Ka1 . ´ 10-2
17
Partial pressure of dry N 2 = 758 - 14 a =` =
0.558 0.558
= 744 mm of Hg
. ´ 10-1 = 017
a = 17 .
For N 2,
V = 30 mL = 0.03 L [H] + = 0.558 a = 9.9 ´ 10-2
T = 287 K pH = - log[ H + ] = - log(9.9 ´ 10-2) [Q log 9.9 » 1]
744
p = 744 mm of Hg = atm = 2 - log 9.9 = 2 - 1
760
pH = 1
pV 744 0.03
So, moles of N 2 (n) = = ´
RT 760 0.0821 ´ 287 28. (525) 3Pb(NO3) 2 + Cr2(SO4 ) 3 ¾® 3PbSO4 + 2Cr(NO3) 3
. ´ 10-3 moles of N 2
n = 125 35 mL 20 mL
0.15 M 0.12 M
Weight of N 2 = Moles × Molar mass
M ´V 20 ´ 0.12
= 1.25 ´ 10-3 ´ 28
35 ´ 015
. = 2.4 0 0
= 35 ´ 10-3 g = 5.25
% composition of N 2 For 3 moles of Pb(NO3) 2, we require 1 mole of Cr2(SO4 ) 3
1
=
Mass of N 2
´ 100 For 5.25 moles of Pb(NO3) 2 , we require ´ 525 . mole of
Mass of organic compound 3
Cr2(SO4 ) 3 = 175
. moles
35 ´ 10-3
= ´ 100 But we have 2.4 moles. So, Cr2(SO4 ) 3 is excess reagent and
01840
. Pb(NO3) 2 is limiting reagent, (LR)
= 19.02% 3Pb(NO3 )2 + Cr2(SO4 )3 ¾® 3PbSO4 + 2Cr(NO3 )3
25. (3) Given, n = 5, ml = + 2 t = 0 5.25 m mol 2.4 0 0
t = t 5.25 - 5.25 2.4 - 1.7 = 07
. 5.25
For n = 5, possible value of l = 0, 1, 2,3, 4
=0
For l = 0, ml = 0
 March Attempt Online JEE Main 2021 05

Moles of PbSO4 formed = moles of Pb(NO3 )2 consumed 30. (4) [Ti(H 2O)6] 3+ is an octahedral complex.
= 525
. m mol
= 525 ´ 10-5 eg
29. (2218) ∆o
Fe( s) + HCl( aq) ¾® FeCl 2( aq) + H 2( g ) d-orbital
t2g
50 g (Moles of Fe = Moles of H 2)
50
moles = 0.8952 mol 0.8952 mol For transition of electron from t 2g to eg orbital, D o amount of energy
55.85
is required.
= 0.8952 mol
Given, l = 498 nm = 498 ´ 10-9 m
Work done can be given by
D o = hc / l
W = - p ext DV
where, h = Planck’s constant
W = - Dng RT
c = speed of light
where, Dng = {gaseous moles on product side } -
l = wavelength of radiation
{gaseous mole on reactant side}
6.6 ´ 10-34 ´ 3 ´ 108
= 08952
. -0 So, D o =
498 ´ 10-9
W = - 08952
. ´ 8.314 ´ 298
. ´ 10-19 J = 4 ´ 10-19 J
= 398
= - 2217.92 J
Closest integer = 2218