Solutions

(1+1+5=7)
For: PU Boards

(1 MARKS)
1. Define the term ‘molarity’. (2014)
2. Mention the enthalpy of mixing (∆mixH) value to form an ideal solution. (2014)
3. What is Binary solution? (2014s)
4. Define Molarity. (2014s)
5. At a given temperature and pressure nitrogen gas is more soluble in water than Helium gas.
Which one of them has higher value of KH? (2015)
6. On mixing equal volumes of acetone and ethanol, what type of deviation from Raoult’s law is
expected? (2015)
7. Give an example for liquid solution in which solute is gas. (2015s)
8. On what factor the value the colligative property depends? (2015s)
9. Name the law behind the dissolution of CO2 gas in soda under high pressure? (2016)
10. Ornamental gold containing copper is an example for what type of solution? (2016)
11. What are ideal solution? (2016s)
12. What is the effect of rise in temperature on the solubility of gases in liquids? (2016s)
13. How does molarity vary with temperature? (2017,2021m)
14. 10ml of liquid ‘A’ is mixed with 10ml of liquid ‘B’ the volume of the resultant solution is
19.9 ml. what type of deviation expected from Raoult’s law? (2017,2020)
15. State Raoult’s law of a binary solution of two volatile liquid components. (2017s)
16. Vant’s Hoff factor for a solution is more than one. What is the conclusion drawn from it?
(2017s)
17. State Henry’s law. (2018, 2018s)
18. Van’t Hoff,s factor for a solution is less than one, what is the conclusion drawn from it. (2018)
19. In a binary solution, mole fraction of one component is 0.068. What is the mole fraction of
another component? (2018s)
20. How does the size of blood cells change when placed in an aqueous solution containing more
than 0.9% (m/v) sodium chloride? (2019,2021m)
21. How does the volume change on mixing two volatile liquids to form an ideal solution? (2019)
22. Write the unit of molality of a solution? (2019s)
23. At a given temperature, oxygen gas is more soluble in water than Nitrogen gas. Which one
of them has higher value of KH ? (2019s)
24. What is the value of Van’t Hoff factor (i) for K2SO4? (2020)
25. What is osmotic pressure? (2021m)
26. Solubility of a gas in liquid decreases as the temperature increases. Why? (2021m)

(5 MARKS)
1. a) On dissolving 2.34 g of solute in 40g of benzene, the boiling point of solution was higher
than that of benzene by 0.81 K. Kb value of benzene is 2.53 K kg mol-1. Calculate the molar
mass of the solute.
b) State Henry’s law. Write its mathematical form. (2014)
2. a) The vapour pressure of pure benzene at certain temperature is 0.850 bar a non-volatile, non-
electrolyte solid weighing 0.5 grams when added to 39 grams of benzene (molar mass 78
grams), vapour pressure of the solution then is 0.845 bars. What is the molar mass of the solid
substance? (2014s)
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 Solutions
(1+1+5=7)
For: PU Boards

b) What happens to the solubility of a gas in a liquid with increase in temperature? Give reason
3. a) A solution containing 18g of non-volatile non-electrolyte solute is dissolved in 200g of water
freezes at 272.07K. Calculate the molecular mass of solute. Given: Kf =1.86 Kgmol-1. Freezing
point of water = 273K. (2015)
b) Define isotonic solution. What happens when the blood cell is dipped in a solution
containing more than normal saline concentration? (2015)
4. a) The boiling point of benzene is 353.23 K when 1.80 g of a non-volatile, non-ionizing solute
was dissolved in 90 g of benzene, the boiling point is raised to 354.11K. Calculate the molar
mass of the solute.
b) Write two differences between ideal and non-ideal solutions. (2015s)
5. a) 5.8g of a non-volatile solute was dissolved in 100g carbon disulphide (CS2) The vapour
pressure of the solution was found to be 190mm of Hg calculate the molar mass of the solute
given the vapour pressure of pure CS2 is 195mm of Hg [Molar mass of CS2 = 76gmol-1]
b) Mention any two differences between Ideal and non-ideal solutions. (2016, 2018s)
6. a) 300cm3 of an aqueous solution of a protein contains 2.12g of the protein, the osmotic
pressure of such a solution at 300K is found to be 3.89*10-3 bar. Calculate the molar mass of
the protein. (R=0.0823 L bar mol-1 K-1)
b) i) State Henry’s law.
ii) Soda water bottles are sealed under high pressure. Give reason. (2016s)
7. a) 1.0 g of non-electrolyte solute dissolved in 50 g of benzene lowered the freezing point of
benzene by 0.4 K. find the molar mass of the solute. [Given: Freezing point depression constant
of benzene = 5.12 K. kg mol-1]
b) How solubility of a gas in liquid varies with i) Temperature and ii) Pressure (2017)
8. a) The vapour pressure of pure benzene at certain temperature is 0.850 bar a non-volatile, non-
electrolyte solid weighing 0.5 grams when added to 39 grams of benzene (molar mass 78
grams), vapour pressure of the solution then is 0.845 bars. What is the molar mass of the solid
substance?
b) What is Reverse Osmosis? Mention its one practical utility. (2017s)
9. a) The boiling point of benzene is 353.23 K when 1.80 g of a non-volatile, non-ionizing solute
was dissolved in 90 g of benzene, the boiling point is raised to 354.11K. Calculate the molar
mass of the solute. [Kb for benzene = 2.53 Kkg mol-1
b) Define:
i. Molality of solution
ii. Isotonic solutions. (2018)
10. a) 31g of an unknown molecular material is dissolved in 500 g of water. The resulting solution
freezes at 271.14 K. Calculate the molar mass of the material. [Given : Kf for water = 243 K].
b) What is reverse osmosis? Mention its use. (2019)
11. a) On dissolving 2.34 g of non-electrolyte solute in 40g of benzene, the building point of
solution was higher than benzene by 0.81 K. Kb value for benzene is 2.53 K kgmol-1.
Calculate the molar mass of solute. [Molar mass of benzene is 2.53 K kgmol-1. Calculate the
molar mass of solute. [Molar mass of benzene is 78 g mol-1]
b) i) State Henry’s law.
ii) How solubility of a gas in liquid changes with increase in temperature? (2019s)

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 Solutions
(1+1+5=7)
For: PU Boards

12. a) Vapour pressure of benzene is 200 mm of Hg. When 2 grams of a non-volatile solute
dissolved in 78 gram benzene. Benzene has vapour pressure of 195 mm of Hg. Calculate the
molar mass of the solute. [molar mass of benzene is 78 gram mol-1] [3]
b) What are azeotropes? Give an example for binary solutions showing minimum boiling
azeotrope. [2] (2020)
13. a) Addition of 0.643g of a compound to 50mL of a liquid (density=0.879g/mL) lowers the
freezing point from 5.510C to 5.030C. Calculate the molar mass of the compound. (Kf for
benzene = 5.12KKgmol-1)
b) Give any two differences between ideal and non-ideal solutions. (2021m)
14. a) The boiling point of benzene is 353.23 K when 1.80 g of a non-volatile, non-ionizing solute
was dissolved in 90 g of benzene, the boiling point is raised to 354.11K. Calculate the molar
mass of the solute. (Given Kb for benzene is 2.53 Kkg mol–1).
b) Define mole fraction of a solute in a binary solution and how is it related to relative lowering
of vapour pressure. (2021m)

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