All India Test Series: JEE (Advanced) - 2022 Open Test - I

ALL INDIA TEST SERIES
JEE (Advanced)-2022
OPEN TEST – I
PAPER –2
TEST DATE: 23-01-2022
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:
 The test consists of total 57 questions.
 Each subject (PCM) has 19 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Three Sections: Section-A, Section-B & Section-C.
Section – A (01 –06, 20 – 25, 39 – 44): This section contains EIGHTEEN (18) questions. Each question has
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – A (07 –10, 26 – 29, 45 – 48): This section contains SIX (06) paragraphs. Based on each
paragraph, there are TWO (02) questions. Each question has FOUR options (A), (B), (C) and (D). ONLY ONE
of these four options is the correct answer.
Section – B (11 – 13, 30 – 32, 49 – 51): This section contains NINE (09) questions. The answer to each
question is a NON-NEGATIVE INTEGER.
Section – C (14 – 19, 33 – 38, 52 – 57): This section contains NINE (09) question stems. There are TWO
(02) questions corresponding to each question stem. The answer to each question is a NUMERICAL
VALUE. If the numerical value has more than two decimal places, truncate/round-off the value to TWO
decimal places.
MARKING SCHEME
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both of which
are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
Section – C: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-OT-I (Paper-2)-PCM-JEE(Advanced)/22 2
Physics PART – I
Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MOER THAN ONE of these four option(s) is (are) correct answer(s).
1. 1025 atoms of helium in a container of volume 27 liter are in random motion. Assume speed of
atoms is same and equal to 2  103 m/s. Mass of He atom is 6.65  1027 kg and each collision is
elastic.
(A) Pressure of the gas is 3.3  106 N/m2
(B) Pressure of the gas is 6.6  106 N/m2
(C) Number of atoms hitting wall of 1 m2 area in a second is 1.23  1029
(D) Number of atoms hitting wall of 1 m2 area in a second is 6.17  1028
Ans. A, C
10251028
Sol. no. of atoms per m3  
27  103 27
Assuming a cube of 1 m volume frequency of collisiion is n
3
 No. of atoms colliding 1 m2 in one second

 1028  1
n=   2000  1.23  1029
 27  6
 
Pressure P = 2mvn
= 2  6.65  1027  2000  1.23  1029 = 3.3  106 N/m2
2. Two balls A and B of mass 1 kg and 4 kg respectively are connected A

by an ideal string and placed on a smooth horizontal surface. A and B 1 kg
are given velocity perpendicular to the string connecting them as 2 m/s
shown in the figure. Motion of balls are in horizontal plane.
 = 1m
4 kg
5 m/s
B
(A) Acceleration of ball A is 39.2 m/s2
(B) Acceleration of ball B is 9.8 m/s2
(C) Tension in the string is 39.2 N
(D) Tension in the string is 4 N
Ans. A, B, C
Sol. Let accelertion of B is a towards A

Motion of A with respect to B
3 AITS-OT-I (Paper-2)-PCM-JEE(Advanced)/22
72
T  1  a  1
1
  
a A,g  a A,B  aB,g
72
 a 
= 1
 (49  a) 
Motion of B with respect to A
72
T  4(49  a)  4 
1
Solving we get T = 39.2 N and a = 9.8 m/s2
3. Interferecne pattern experiment is done on the screen

surface of water by using a slit S in an opaque plate A
AB and screen is placed at 50 cm from slit. Slit is 1
cm above water surfce and light of wavelength  =
6000 Å is falling over it. The plate is oscillating S 5 cm
according to equation X = A sint along the line BO,
where A = 1 cm,  = 100 rad/s. Point O is just above B
the water surface and another point P is 5 cm above water
the water surface. Plate AB is just above the water
surface. x
(A) Intensity at point O is minimum
(B) Intensity at point O is maximum
(C) Maximum speed of fringe at point P is 10 cm/s
(D) Maximum speed of fringe at point P is 5 cm/s
Ans. A, C
Sol. Reflection will take place from water surface which will introduce /2 path difference.
At distance y above point O, path difference
dy 
x  
D 2

for y = 0, x =  at point O, I is minimum.
2
dy 
x = n = 
D 2
D  1
 y  n 
d  2
dy   1  dD y
 n    A cos t
dt d  2  dt D
 dy  Ay 1 cm  100  5 cm
 dt     10 cm/s
 max D 50 cm
4. Two particles of equal mass m interact with each other by a force for which potential energy
 1 2
function U  U0  12  6 
r r 
Where U0 is a constant, r is separation between the particles. Equilibrium separation between
them is r0. When their separation slightly changes from equilibrium separation they start
oscillating with angular frequency . Then choose the correct option(s).
(A) r0 = 1
r0   2 
1/6
(B)
144U0
(C) 
m
72U0
(D) 
m
Ans. A, C
dU  12 12 
Sol. F  U0   13  7 
dr  r r 
F = 0  r0 = 1
If slightly displaced by r then
r = r0 + r
= 1 + r
 12 12 
F  U0  13
   72U0 r
 (1  r) (1  r)7 
F  144U0  144U0
a  a    r   
(m / 2)  m  m
5. -particle collides elastically with a nucleus of gas which is filled in a chamber. After collision
-particle deviates at 60 and nucleus at 30 with the direction of motion of incident -particle.
Then choose the correct option(s).
(A) Mass number of gas filled in chamber is 4
(B) Mass number of gas filled in chamber is 2
1
(C) Ratio of the speed of struck nucleus to the speed of incident -particle is
3
3
(D) Ratio of the speed of struck nucleus to the speed of incident -particle is
2
Ans. A, D
Sol. mass of -particle is 4 v1

 From COM
4v = 4v1 cos 60 + mv2 cos 30 60
v
And 0 = 4v1 sin60 mv2 sin 30
Conservation of energy  m 30
m
1 1 1 v2
 4v 2   4v12  mv 22
2 2 2
Solving m = 4
v 3
and 2 
v 2
6. A particle of charge q and mass m is dropped from rest. It falls under the effect of uniform gravity
where acceleration due to gravity is g. There exists a uniform horizontal magnetic field B. Choose
the correct statement(s).
(A) After falling through certain distance the particle starts climbing up
2mg
(B) Speed of particle when it starts climbing is
qB
2m2 g
(C) Depth after which particle starts climbing is
q2B2
mg
(D) Speed of particle when it starts climbing is
qB
Ans. A, B, C
 dv dv y  z
Sol. m  x ˆi  ˆj   mgjˆ  q(v ˆi  v ˆj)  Bkˆ
 dt dt 
x y

dv x qB dv y qB
  v y and  g vx x
dt m dt m
mg mg
Solving v x  (1  cos t) and v y  sin t vx y
qB qB
qB B
Where  
m
v y  0  t   v
vy
2mg
 vx 
qB
Conservation of energy
2
1  2gm 
mghmax  m 
2  qB 
2m2 g
 hmax 
q2B2

This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
Paragraph for Question Nos. 07 and 08
One mole of an ideal monoatomic gas is taken through cyclic process P

ABCA as shown in the figure. Temperature in state A and B are euqal to A
400 K. 4P0
B
P0
C
V0 4V0 V
7. What is the maximum temperature achieved in cyclic process?
(A) 400 K
(B) 625 K
(C) 450 K
(D) 550 K
Ans. B
PV
Sol. T
nR
For Tmax product of PV must be maximum Tc is minimum.
TA = TB = 400 K
4P0 V0 PV
  400  0 0  100
R R
A  B process
P
P   0 V  5P0
V0
RT P0 2 5P0
PT V  V
V RV0 R
2
dT 5 P 5  5P  5 
 0  V  V0 and Tmax   0  V0   0  V0 
dV 2 RV0  2  R 2 
25 P0 V0
Tmax   625 K
4 R
8. The cyclic process is best represented by T-P diagram
(A) T (B) T
B
B
A A
C C
P P
(C) T (D) T
A
B
B
A
C C
P P
Ans. C
Sol. Use the relation from the given graph, and make the required graph
Experiments are going on to produce large scale energy by using Deuterium 1H2    
and Tritium 1H3 .
They are using laser beams to compress the material. Fuel pallets are made by mixing equal number of
atoms of 1H3 and 1H2 . Such fuel pallets are spheres of radius r = 200 m and its density is 200 kg/m3.
When laser beams hit the pallet, it gets compressed and its density is increased by 1000 times. Assume
that only 10% of the atoms take part in fusion reaction
2 3 4 1
1H 1 H  2He  0 n  Q
mass of 1H2 = 2.0141 u

mass of 1H3  3.0160 u
mass of 2 He4  4.0026 u
mass of 0 n1  1.0087 u
(Take, 1 amu = 931 MeV/c2)
9. The Q-value of this nuclear reaction is
(A) 3.27 MeV
(B) 4.03 MeV
(C) 956 MeV
(D) 17.5 MeV
Ans. D
10. The energy produced in laser action of a pallet is
(A) 108 J
(B) 105 J
(C) 103 J
(D) 106 J
Ans. B
Sol. (for Q. 9-10)

Q m  1H
2 m
1H
3 m
2 He
4 m
0n
1   931 MeV  17.5 MeV
Let n is number of atoms per unit volume then
n n nM M 
200  103  md  mT   d  T 
2 2 2  NA NA 
2NA (2  105 ) 2  6.02  1023  2  105
n   4.8  1031 /m3
Md  MT (2  10 3  3  10 3 )
4
Volume of pallet = (20  10 6 )3
3
4
Number of atoms in a pallet = 4.8  1031   3.14  (20  10 6 )3  1.61 1018
3
Energy produced in one laser action on a pallet is
1.61 1017
 17.5  106  1.6  10 19  2.2  105 J
2
Section – B (Maximum Marks: 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.
11. A block of mass 30 kg and an empty and light Box of

30 kg
equal volume are attached by an ideal spring of force
constant k = 400 N/m. The whole system is floating in
water of density (w) = 103 kg/m3. The upper block is
half submerged into water. Take the value of
acceleration due to gravity g = 10 m/s2. If the
compression in spring is 10k cm. Then find the value
of k.
Light box
Ans. 5
V
Sol. 30g = kx  w g
2
And
kx  Vw g
Solving, x = 50 cm
12. A tuning fork produces 3 beats with a sonometer wire of length 80

cm. When separation between the bridges is increased by 1cm,
tuning fork resonates with sonometer wire. If frequency of tuning
fork is 80P Hz. Find the value of P.
Ans. 3
v
Sol.  fT  3
2  80
v
fT   3  80 Hz
2  81
13. A bead of charge q and mass m is free to move on a smooth fixed y

insulating wire, which is in the shape of parabola y = (2  x2) located

in a vertical plane. Uniform gravity g  10(  ˆj) m/s2 is present in the
space. The bead is pushed slightly on the wire from (0, 2)m, it y = 2  x2
reaches on the ground (y = 0) with speed v. Electric field

ˆ N/C is present in space and q  2 (in SI unit). Find
E  (xiˆ  yj)
m
the speed v (in m/s). x
Ans. 6
Sol. Work energy theorem

 
ˆ  1 mv 2  0

(mg  qE)  (dxiˆ  dyj)
2
1
 mg(ˆj)  q(xiˆ  yj)ˆ (dxiˆ  dyj)ˆ  2 mv
2
0 2 0
1
  xdx  q ydy  2 mv
2
mg dy  q
2 0 2
 v = 6 m/s
Section – C (Maximum Marks: 12)

This section contains THREE (03) question stems. There are TWO (02) questions corresponding to each
question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.
Question Stem for Question Nos. 14 and 15

Question Stem
A sphere of radius R = 5 cm is rolling without slipping with a velocity 10
m/s on two parallel, horizontal fixed rods as shown in the figure. The
separation between the rods is   2 24 cm. There is friction between
the rods and sphere and coefficient of friction  = 0.3. The sphere
collides with a smooth vertical wall elastically. It returns back and again
collides with a velocity v2. Similarly it collides with the wall again with a
velocity v3.
14. The value of v2 (in m/s) is ……………….
Ans. 8.18
15. The value of v3 (in m/s) is ……………….
Ans. 6.69
Sol. (for Q. 14-15)

After 1st collision its linear velocity becomes opposite but angular velocity remains same.
2
v0 0
r v2
Just after collision When it returns back due to

friction
Condition of rolling on rods v0 = r0
r = 1  v 0 = 0
and v2 = 2
Applying COAM about mid point in the plane of rods
2 2
mv 0r  mR2 0  mv 2r  mR2 2
5 5
9
 v2  v0
11
3
v2 2
v3
Just after collision When it returns back due to

friction
Conservation of angular momentum provides
9 9 9
v3  v2   v0
11 11 11
By putting the values
v2 = 8.18 m/s
v3 = 6.69 m/s
Question Stem
A metal sphere with its centre at origin has radius R = Y P(2R, 2R, 0)
1m. It has three spherical cavities each of radius R/4 and
 R   R   R 
their centres are at  0, , 0  ,   , 0, 0  and  0,  ,0 
 2   2   2 
A
respectively. Initially cavity A and B have some non zero
charges and cavity C is empty. The electric field at point R=1m
P is zero. x
B
C
kV
16. When charge from cavity A is removed, electric field at point P(2R, 2R, 0) is found to be 1 .
m
The magnitude of charge present in the cavity A (in C) was …………
Ans. 0.89
17. By keeping the charges same in the cavities A and B and the charge of 2 C is placed at the
kV
centre of cavity C. The electric field at point P (in ) is …………….
m
Ans. 2.25
Sol. (for Q. 16-17)

kQ
E = 0  net charge on sphere is zero. If one is removed, field E 
r2
9  109  q  10 6
1 103 
8R2
R = 1  q = 0.89 C
Now field is due to charge induced on surface due to charge present in cavity C
k qC 9  109  2  10 6
E 2 
r 8R2
kV
R = 1  E = 2.25
m

Question Stem
A uniform time varying magnetic field B = B0t is present in a      R   

cylindrical region. A fixed wire frame PQR of equilateral triangular         
shape has slight curve at its corners. Side length of frame is         
  2 3 m and it is made of insulating material. A charged bead of         
charge q and mass m can move on the wire frame without friction         
is released from rest at mid point of PQ. It is assumed that bead         
moves through corners of frame without any loss of kinetic energy.         
The bead moves on the frame and again comes at initial position         
qB0 P q,m Q
        
in time t0 and with a speed v0. It is given that  3 (in SI
m         
unit).
18. The value of time t0(in sec) is ………………….
Ans. 4.90
19. The value of speed v0(in m/s) is ………
Ans. 4.24
Sol. (for Q. 18-19)

dB
E2r  r 2
dt 
r
B0 r D
 E
2
qE qB0D
a  cos   30
m 2m P  Q
1 qB0D 2
3  t
2 2m
E
12
t …(i)
 qB0 
 m D
 
D 
 tan30  D  1
( / 2) 2 3
t  24  4.90 s
qB0D
v 2  2a (3 )  2   3  2 3  4.24 m/s
2m
Chemistry PART – II

20. Compound (X), C4H8 O decolorizes Baeyer’s reagent. It undergoes hydrolysis on reaction with
dil. H2SO 4 and produces (Y) and (Z). Both (Y) and (Z) give iodoform test positive. Only (Y) gives
Tollen’s silver mirror test positive
(A)  Y  
 i aq. NaOH10% 
 ii  CH3  CH  CH  CHO
(B)  Z  
PCC
CH Cl
2
Y
2
Br
(C)  X  
Br2
CCl4
H2C CH O CH2 CH3
Br
(D)  X  1. O 3
2. Zn/H O
  Y   other product
2
Ans. A, B, C
Sol.  X   CH2  CH  O  CH2  CH3

 Y   CH3 CHO
 Z   CH3CH2OH
21. O
1. LiAlH4  ether
 2. H2 O
 U 
HCHO
dry HCl g Z
O
PCC / DMF
 V  

W 
(Where DMF = N,N - dimethyl formamide)
Identify the correct statement (s) among the following:
(A) ‘U’ is optically active.
(B) ‘V’ gives effervascence with NaHCO3 .
(C) Molecular formula of ‘Z’ C6H12O 2 .
(D) ‘W’ gives iodoform test.
Ans. A, B, C, D
Sol. O OH
O O
1. LiAlH4  ether
 2. H2 O
 
HCHO
dry HCl g
O OH
U
 chiral   Z
PCC / DMF
O O
COOH  
 CH3
 CO2
H3C
W 
V
22. Consider the following reaction sequence:
M2   aq 
H2 S
HCl dilute 
Black precipitate 
conc. HNO3

 White precipitate
Which of the following metal ion(s) can be M2 ?
(A) Hg2 
(B) Ni2 
(C) Cu2 
(D) Pb2 
Ans. C, D
Sol. Only IInd group cations form ppt. of sulphide with H2S in presence of dil. HCl.
So, Ni2  cannot be M2  as it belongs to IVth group. Also, HgS does not dissolve in nitric acid. So,
Hg2  is also not possible. CuS and PbS are black precipitates which dissolve in nitric acid form
colloidal sulphur, a white ppt.
23. An ideal gas is subjected to three different type of adiabatic processes from same initial state to
same final volume as given below:
Expansion Work Final temperature Internal energy Enthalpy
change change
Reversible W T2 U H
Irreversible W T2 U H
Free W  T2 U H
Which of the following relation(s) is/are correct?
(A) T2  T2  T2
(B) W  W   W  and W  W   W 
(C) U  U  U
(D) H  H  H
Ans. A, B, C, D
Sol. (i) Free expansion of an ideal gas is isothermal as well as adiabatic irreversible process. So,
q  0,W   0, U  0, H  0 .
(ii) For the same change of volume, magnitude of work done in reversible expansion is more
than irreversible expansion.
So, W  W  or W  W   with sign 
U  W  for adiabatic 
U  U
Also, H  H
nRTf
Pfinal 
Vf
So, T2  T2  T2
24. The nitrogen containing product obtained by heating lead nitrate:
(A) can also be obtained by reacting white phosphorus with conc. HNO3 .
(B) is diamagnetic.
(C) contains sp2 hybridized nitrogen atom.
(D) liberates a paramagnetic gas when reacted with water.
Ans. A, C, D
Sol. 2Pb NO3 2  s  


 2PbO  s   4NO2  g   O2  g 
Paramagnetic 
P4  20HNO3  conc.  4H3PO 4  20NO2  4H2 O
NO2  g  H2 O  HNO3  HNO2 
HNO2   HNO3  NO  g 
Paramagnetic 
25. B3N3H6  solution of hydrochloric acid  ?
Select ‘INCORRECT’ statement(s) about the above reaction:
(A) No reaction
(B) B3N3H6 shows substitution reaction and forms B3N3 Cl6
(C) B3N3H6 show addition reaction and produces B3N3H9 Cl3 in which ‘Cl’-atoms are bonded
to boron atoms.
(D) B3N3H6 shows addition reaction and produces B3N3H9 Cl3 in which ‘Cl’-atoms are bonded
to nitrogen atoms.
Ans. A, B, D
Sol. H H Cl
H B H
B N N
H N N H 3HCl H H
 
Cl H
H B B H B B
N N Cl
H
H H
H

answer.
Consider the stereoisomer of iso-leucine labelled as below:

CH3 O
CH3 O
OH (P);
OH (Q);
NH2
NH2
CH3 O CH3 O
OH (R); OH (S)
NH2 NH2
Consider the following data to answer the questions posted:
o
(i) Set molar Gibb’s free energy of ‘P’, Gm  0 kJ mol1.
(ii) The equilibrium constant K eq   for epimerization of (P) has the value of 1.38 (at 374 K).
(iii) Epimerization of (R) into (Q) follows first order kinetics with rate constant ‘k’ (at 374 K) =
9.02  10 5 hr 1 and considered to be irreversible.
RQ
(iv) Diastereomeric excess is defined as De   100 .
RQ
Where, [R] and [Q] represents the concentrations of R and Q forms in their mixture.
o
26. What is the Gm of ‘Q’? [Given ln1.38 = 0.322]
(A) 0 kJ
(B) 1.00  103 kJ mol1
(C) 1.00  103 kJ mol1
(D) 1.38 kJ mol1
Ans. A
Sol. Enantiomers have same molar free energy.
27. If ‘R’ is boiled for 1943 hours at 374 K, then it undergoes epimerization to form (Q). What is the
value of Diastereomeric excess (De) after 1943 hours? e0.175  1.19  
(A) 83.5%
(B) 12.5%
(C) 68.2%
(D) 19.6%
Ans. C
Sol. order 1
R  Q
at t  0 1 0
after time ' t ' 1    
1 1
9.02  10 5   n
1943 1   
1
n  1943  9.02  10 5  0.175
1   
1
 e0.175  1.19
1   
   0.159
So, (R) = 1 – 0.159 = 0.841, (Q) = 0.159
So, Diastereomeric excess (De) 

R  Q  100
R  Q
 0.841  9.159 
De   100
 0.841  0.159 
0.682
De   100  68.2%
1
Rust indicator containing potassium hexacyano ferrate (II) solution was poured into the following glass
dishes to cover the iron nails which were wrapped with different metal strips. The dishes were allowed to
stand in air for some time.
Zinc strip Copper strip Magnesium strip

Silver strip
(Dish - 2) (Dish - 3) (Dish - 4)
(Dish - 1)
28. If the iron nail rusts, what would the colour of rust indicator be around the nail?
(A) Yellow
(B) Brown
(C) Red
(D) Blue
Ans. D
Sol. In the rust, iron is present in +3 oxidation state and form blue solution with K 4 Fe  CN6  .
29. In which of the dishes would the iron nail rust?
(A) Dish – 1 only
(B) Dish – 2 only
(C) Dishes – 1 and 3 only
(D) Dishes – 2 and 4 only
Ans. C
Sol. Since Zn and Mg are more electropositive than iron. So, iron will not rust. But Cu and Ag are less
electropositive than iron, so, can not reduce the rust.

INTEGER.
30. A sample of camphor used in a method for determining of molar mass had melting point of 450 K.
The melting point of a solution containing 0.5 gm camphor and 0.04 gm of an unknown non-
volatile non-electrolyte compound was 430 K. The molar mass of camphor is 152 and its
Hfusion  1.52 Kcal mol1. The molar mass of unknown compound in gm/mole is………
R  2 cal mol 1

K 1 .
Ans. 162
 
2
R Tfo 2  152   450 
2
 M2
Sol. K f  of camphor     40.5
1000  Hof 1000  1.52  1000
Tf  i  K f  M
0.04  1000
450  430  1 40.5 
Msolute  0.5
0.04  1000  40.5
Msolute   162
0.5  20
31. The sum of total numbers of isomers possible for the complexes
Co  ox PMe3   NH3  Cl   and K 4Fe  CN  is……….
 2  6
Ans. 16
Sol. Total isomers of Co  ox PMe3 NH3  Cl   are 6 and total isomers of K 4Fe  CN6 are 10.
32. 2-methyl butane on photochemical monochlorination gives ‘x’ number of isomeric products of the
formula C4H9 Cl . The number of product(s) obtained when major structural isomer of C4H9 Cl
produced in the reaction is heated with KOH in presence of C2H5 OH is y. What is the value of
(x + y)?
Ans. 8
Sol. Cl

Cl2
h
  Cl  Cl

Cl
Major 

alc. KOH
 

Cl
Major 
Question Stem
An acid ‘A’ which is an important constituent of vinegar; on reaction with red phosphorous and Br 2, gives
a monobromo derivative (B) which on reaction with NH3 gives white solid (C). However, ethanal on
reaction with a mixture of ammonium chloride and sodium cyanide undergoes strecker synthesis to give a
product which on acidic hydrolysis gives another high melting solid (D). The sum of total optical isomers
of (C) and (D) are ‘x’ while ‘y’ is the total number of dipeptides (excluding stereoisomers) that a mixture of
(C) and (D) can form.
33. The value of x is________
Ans. 2.00
Sol. A  CH3 COOH; B  H2C COOH ; C  H2C COOH ; D  H3C CH COOH
Br NH2 NH2
34. The value of y is_________
Ans. 4.00
Sol. Possible dipeptides are:

C–C;D–D
C–D;D–C
Question Stem
Scheme 1: A person takes 6.1 gm of an antacid tablet comprising bicarbonate ion at 20.8% by mass.
 
The volume of CO2  g  evolved at 1 atm, 25o C in the stomach be ‘x’ litres.
R  0.0821 L atm mol K  . 1 1

 
Scheme 2: The standard cell potential of the following cell:
Pt | H2  g  | HBr  aq  | AgBr  s  | Ag  s 
was measured over a range of temperatures, and the data was fitted as:
Eocell  volts   0.01  1 104  T  298   2  10 6  T  298 
2
Where ‘T’ is the absolute temperature. The standard enthalpy change of the cell reaction
at 298 K is – ‘y’ kJ mol-1 corresponding to 1 Faraday charge [1 F = 96500 C].
35. The value of ‘x’ is________
Ans. Range (0.50 – 0.52)
Sol. HCO3  H  CO2  H2O

6.1 20.8
Moles of HCO3  moles of CO2    0.0208
61 100
PV = nRT
0.0208  0.0821 298
V  0.5088 L  0.51 L
1
36. Value of ‘y’ is_________
Ans. Range (3.80 – 3.85)
 o

Sol.  S   nF  ET 
o
298
 P, 298
 1 96500  10 4 
 9.65 J / K
Go298  nFEcell
o
Go298  Ho  TSo

Ho  Go  TSo

 0.965  298 9.65  10 3 
 0.965  2.8757
Ho298  3.8407kJmol1
Question Stem
Three isomers of molecular formula  C6H12O3  is shown below. On complete acidic hydrolysis P, Q, R
and S are formed as organic products:
H3C O CH3
H O

3
 P 
O O
CH3
O CH3
H3C
H O

3
Q  R  P
O O
O
H O

3
R  S
O O
CH2 CH3
H3C
Let, the ratio of the number of products (P, Q, R, S) which gives haloform reaction to the co-ordination
number of an atom in the top most layer of cubic close packed (ccp) structure be ‘x’ and let the ratio of
packing fraction of diamond to the number of organic products (P, Q, R, S) which gives Tollen’s test

positive be ‘y’,   3.14, 2  1.414, 3  1.732 
37. Value of ‘x’ is________
Ans. 0.25
Sol. P  CH3  CH  O; Q  CH3  CH2  CHO;

O
||
R  HCHO; S  CH3  CH2  C  CH3
2
So, x   0.25
8
38. Value of ‘y’ is__________
Ans. Range (0.10 – 0.12)
0.34
Sol. y  0.11
3
Mathematics PART – III

39. Curves A, B, C and D are defined in the plane as follows;

 x   y 
A   x, y  ; x 2  y 2  2 2
; B   x, y  ; 2xy  2 2
 3 ;
 x  y   x y 
C  x, y ; 
x 3  3xy 2  3y  1 ; D   x, y ; 
3x 2 y  3x  y 3  0 , then
(A)  A  B  C  D
(B)  A  B  C  D
n  A  B
(C) 1
n C  D
n A  B
(D) 4
n C  D
Ans. A, C
Sol. Let z = x + iy
A and B are real and imaginary part of z2 = z–1 + 3i
Similarly C and D are real and imaginary part of z3 – 3iz = 1
 (x, y)  A  B  (x, y)  C  D  A  B = C  D
40. Let x0 > 0 – {3} and xn be defined recursively by xn  6  x n1 where n  1, then lim xn is
n 
(A) 6
(B) 6  x0
(C) does not exist

(D) none of these
Ans. D
Sol. xn  6  x n1 ; xn2  xn21    xn 1  3  xn 1  2 

Case-I : Case-II :
x0 < 3, then xn < 3 x0 > 3, then x2 > 3
Bounded by above Bounded below
Also, xn2  xn21  0 So, xn2  xn21  0
xn > xn – 1 increasing sequence  xn  xn 1 decreasing sequence
x2 y2
41. If ABC be a triangle inscribed in an ellipse   1 , then
4 2
2
(A) area of ABC is maximum when the eccentric angles of the vertices differ by
3
5
(B) area of ABC is maximum when the eccentric angles of the vertices differ by
9
3
(C) maximum area of ABC = 3
2
(D) if area of ABC is maximum, then normals at A, B and C are concurrent
Ans. A, C
ar  A BC 
Sol. ar  ABC  
2
Hence, two areas are maximum simultaneously thus ABC is equilateral
2 3
So, | – | = | – | = | – | = ;   ABC   3
3 2
Hence, let  <  <  ; sin       sin       sin     
 2   4 
= sin   2   sin  2  2   sin   2 
 3   3 

= 2 sin    2  cos  sin 2  0
3
42. If ABCD is a regular tetrahedron with length of any edge be 7, then
343
(A) volume of tetrahedron is
6 2
243
(B) volume to tetrahedron is
2
2
(C) minimum distance of any vertex from the opposite face is 7
3
3
(D) minimum distance of any vertex from the opposite face is 7
2
Ans. A, C
     
aa ab ac
   2              
Sol. a b c   b  a b b b  c ; a  a  72  b  b  c  c ; a  b  72  cos 60
     
c a c b c c
1 2
v  base area   height ; h  7
3 3
  1n 1 c 
43. If  3n  1  a  lnb   , then
n 0  a
a + b divides  222    888 

888 222
(A)
(B) a + b is a prime number
(C) c is an irrational number
(D) [2c] = 6
(where [.] denotes greatest integer function)
Ans. A, B, C, D
x 2 x3 x 4
Sol. ln 1  x   x     ..... ….. (1)
2 3 4
x 2 2 x 3
2 ln 1  x   x   ..... ….. (2)
2 3
2 x 2 x 3 x 4
 ln 1  2 x   x     ..... ….. (3)
2 3 4
1  
Adding equation (1) + (2) + (3), we get S  ln2 
3  
3
44. Which of the following are INCORRECT?
19991999   2000 
1998
(A)
(B) e1/e  e1/   2e1/3
(C) log2 3  log3 5
1  1  3   2n  1  1
(D)      .....  
4n  2   4   2n  2n
Ans. A, B, C
Sol. (A) Let f(x) = (1999 – x) ln(1999 + x)

f(x) < 0  0  x  1
 f(0) > f(1)
(B) f  x   e1/ x , f < 0, f > 0
f is dec and convex
(C) x = log2 3, y = log3 5
2x = 3, 3y = 5
27 = 33 = (2x)3 = 8x and 25 = s2 = (3y)2 = 9y
 8x > ay but 8 < 9  x > y
 1 3   2n  1 
(D) Let P      .....  
 2  4   2n 
2 4 2n  2 1
Q   ..... ; PQ 
3 5 2n  1 2n
1 2 3 4 2n  1
     ..... 
2 3 4 5 2n
So, 2P  Q ; 2P2  PQ (where n  I+)

answer.
1 1
 f  x  dx  1 and L   x f  x  dx , then
2 2021
If f(x) be a continuous function over [0, 1]  R+ such that
0 0
45. Maximum value of L is
1
(A)
4041
2
(B)
4041
1
(C)
4043
3
(D)
4043
Ans. C
46. If maximum value of L is achieved for f(x) = g(x), then number of points of non-differentiability of
1
  x  1  x  2   2023
   g x   x  (0, 1) is/are
 2  3  
(A) 0
(B) 1
(C) 2
(D) none of these
Ans. C
Sol. (for Q. 45-46)

2
 n
  n
 n

 nlim  xi2021 f  x i  x    lim  f 2  xi  x   lim  xi4042 x 
  i 1   n 
i 1   n i 1 
1 1
1
= f
2  x  dx  x 4042 dx 
0 0
4043
Let A and B be points on the same branch of the hyperbola xy = 1. Suppose that P is a point lying
between A and B on this hyperbola, such that the area of the triangle APB is maximum
 1
47. Let A  (1, 1) and B   4,  , then abscissa of P is equal to
 4
(A) 2
(B) 3
(C) 2
(D) 3
Ans. C
Area of the region bounded by the hyperbola and chord AP

48. is equal to
Area of the region bounded by the hyperbola and chord PB
1
(A)
2
(B) 1
(C) 2
(D) 3
Ans. B
 a  b  a  t  b  t   1
Sol. A t  A  a, 
2abt  a
 a  b   t 2  ab 
A  t  
2abt 2
So, t  ab is point of maxima moreover P(t)  1
B  b, 
ab b  b
 1 1 1 1  1 1 1 1
   x     dx =
 at a t x    x     dx
 bt b t x
a ab

INTEGER.
 1  2   n 
49. lim sin  2   sin  2   .....  sin  2  is t, then 2t is equal to
n  n  n  n 
Ans. 1
 1  2   n 
Sol. Let sin  2   sin  2   .....  sin  2  be Sn
n  n  n 
1 1 n3 1 2 n
So,  n2  
6 n 6
 Sn  2  2  .....  2
n n n
50. If A is a 2  2 matrix such that trace(A) = det(A) = 3, then trace(A–1) is
Ans. 1
a b
Sol. Let A    , a + d = 3 = ad – bc
 c d
51. To each positive integer with n2 decimal digits we associate the determinant of the matrix
obtained by writing the digits in order across the rows. For example, for n = 2, to the integer 8617
8 6
we associate det    50 . If the sum of all the determinants associated with n -digit integers
2
 1 7 
be S, then
S
is equal to
451 45
(Leading digits are assumed to be nonzero; for example, for n = 2, there are 9000 determinants)
Ans. 1
Sol. n = 1 ; 1 + 2 + 3 + ….. + 9 = 45
1 0 1 0 9 9
n=2;   ..... 
0 0 0 1 9 9
i j
=  k 
   i  jk  = 100  i  90  jk
1 i  9 1 i  9 1  j, k  9
0  j, k,   9 09
= 100.452 – 90.452

Question Stem
Let  be the equation of the line which intersect each of the two lines x + 2y – 2 = 0 = 2x – 2y + z
and 3x – 2y + z –1 = 0 = x + 4y + z – 3 and is parallel to the line x + 2y – 3z = 0 = 2x + y + z + 3.
If line  meets the plane x + y + z = 0 at the point (, , ), then
52.    is equal to
Ans. 0.80
 
53.    is equal to (where [.] denotes greatest integer function)
 
Ans. 1.00
Sol. (for Q. 52-53)

Equation of a line which is coplanar to the lines x + 2y – 2 + (2x – 2y + z) = 0
(1 + 2)x + (2 – 2)y + z – 2 = 0 ….. (1)
(3x – 2y + z – 1) + (x + 4y + z – 3) = 0
(3 + )x + (–2 + 4)y + (1 + )z + (–1 – 3) = 0 ….. (2)
(1) dot pd with (5, –7, –3)
5 + 10 – 14 + 14 – 3 = 0
3
21 = 9   
7
 6  6 3
(1) becomes,  1   x   2   y  z  2  0
 7  7 7
13 8 3
x  y  z  2  0 ; 13x + 8y + 3z – 14 = 0 …..(3)
7 7 7
y = 1 ; 4x + 2y + 2z – 4 = 0
2x + y + z – 2 = 0 ….. (4)
2 2
x y
3 3 z
So, line l is  
5 7 3
2 2 4 4
Hence, 5t   7t   3t  0  5t    t 
3 3 3 15
 6 4
Point  2,  ,  
 5 5
Question Stem
Suppose 20 distinct objects are placed along a circle at equal distances. Let n1 be the number of ways of
selecting 3 objects so that no two of them are adjacent and n2 be the number of ways of selecting 3
objects so that neither of them are adjacent nor diametrically opposite, then
n1
54. The value of is
400
Ans. 2.00
n2
55. The value of is
75
Ans. 8.80
Sol. (for Q. 54-55)

n1  20 C3  20  20  16
n2  n1   10 C1  14 
Question Stem
The system of equations 2x – 3y + 5z = 12, 3x + y + z = , x – 7y + 8z = 17 has
56. Will have a unique solution if   k, then k is equal to
Ans. 2.00
57. Will have infinite number of solutions if  +  is equal to
Ans. 9.00
Sol. (for Q. 56-57)

2 3 5
  3 1   0 , c1  c1 – c2, then new  can be 0 if  = 2
1 7 8
Now if  = 2
Then 2x – 3y + 5z = 12, 3x + y + 2z = , x – 7y + 8z = 17 will have infinite solution if  = 7

All India Test Series: JEE (Advanced) - 2022 Open Test - I

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ALL INDIA TEST SERIES

Section – A (Maximum Marks: 24)

(A) Pressure of the gas is 3.3  106 N/m2

(B) Pressure of the gas is 6.6  106 N/m2

(C) Number of atoms hitting wall of 1 m2 area in a second is 1.23  1029

(D) Number of atoms hitting wall of 1 m2 area in a second is 6.17  1028

 No. of atoms colliding 1 m2 in one second

2. Two balls A and B of mass 1 kg and 4 kg respectively are connected A

(A) Acceleration of ball A is 39.2 m/s2

(B) Acceleration of ball B is 9.8 m/s2

(C) Tension in the string is 39.2 N

(D) Tension in the string is 4 N

Sol. Let accelertion of B is a towards A

3. Interferecne pattern experiment is done on the screen

(A) Intensity at point O is minimum

(B) Intensity at point O is maximum

(C) Maximum speed of fringe at point P is 10 cm/s

(D) Maximum speed of fringe at point P is 5 cm/s

(A) Mass number of gas filled in chamber is 4

(B) Mass number of gas filled in chamber is 2

Sol. mass of -particle is 4 v1

Section – A (Maximum Marks: 12)

Paragraph for Question Nos. 07 and 08

One mole of an ideal monoatomic gas is taken through cyclic process P

7. What is the maximum temperature achieved in cyclic process?

8. The cyclic process is best represented by T-P diagram

Paragraph for Question Nos. 09 and 10

mass of 1H2 = 2.0141 u

9. The Q-value of this nuclear reaction is

(A) 3.27 MeV

(B) 4.03 MeV

(C) 956 MeV

(D) 17.5 MeV

10. The energy produced in laser action of a pallet is

Sol. (for Q. 9-10)

Section – B (Maximum Marks: 12)

11. A block of mass 30 kg and an empty and light Box of

12. A tuning fork produces 3 beats with a sonometer wire of length 80

13. A bead of charge q and mass m is free to move on a smooth fixed y

Sol. Work energy theorem

Section – C (Maximum Marks: 12)

Question Stem for Question Nos. 14 and 15

14. The value of v2 (in m/s) is ……………….

15. The value of v3 (in m/s) is ……………….

Sol. (for Q. 14-15)

Just after collision When it returns back due to

Just after collision When it returns back due to

Question Stem for Question Nos. 16 and 17

Sol. (for Q. 16-17)

Question Stem for Question Nos. 18 and 19

A uniform time varying magnetic field B = B0t is present in a      R   

18. The value of time t0(in sec) is ………………….

19. The value of speed v0(in m/s) is ………

Sol. (for Q. 18-19)

Section – A (Maximum Marks: 24)

Sol.  X   CH2  CH  O  CH2  CH3

(A) ‘U’ is optically active.

(B) ‘V’ gives effervascence with NaHCO3 .

(C) Molecular formula of ‘Z’ C6H12O 2 .

(D) ‘W’ gives iodoform test.

(A) T2  T2  T2

(C) U  U  U