The Leader In Chemistry NEET-2021-22 [XIIth Batch]

.....
Test-30 : Solutions

RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * *
Target Marks : 92 Date : 23/10/2021
Time : 30 min Sub. : Chemistry
1. Match the column I with column II and mark 6. What will be the degree of dissociation of 0.1
the appropriate choice M Mg(NO3)2 solution if van’t Hoff factor is
2.74?
1) 75% 2) 87%
3) 100% 4) 92%
7. The freezing point depression constant (Kf) of
benzene is 5.12 K kg mol–1. The freezing point
depression for the solution of molality
0.078 m containing a non-electrolyte solute in
benzene is (rounded off upto two decimal places)
1) 0.20 K 2) 0.80 K
3) 0.40 K 4) 0.60 K
1) A-i, B-iii, C-ii, D-iv
8. 200 mL of an aqueous solution of a protein
2) A-iii, B-i, C-iv, D-ii contains its 1.26 g. The osmotic pressure of this
3) A-ii, B-iii, C-iv, D-i soution at 300 K is found to be 2.57 × 10–3 bar.
4) A-iii, B-ii, C-i, D-iv The molar mass of protein will be (R = 0.083 L
2. Match the column I with column II and mark bar mol–1 K–1)
the appropriate choice 1) 51022 g mol–1 2) 122044 g mol–1
3) 31011 g mol–1 4) 61038 g mol–1
9. A solution of sucrose (molar mass=342 g mol–1)
has been prepared by dissolving 68.5 g of
sucrose in 1000 g of water. The freezing point
of the solution obtained will be
(Kf for water = 1.86 K kg mol–1)
1) – 0.372°C 2) – 0.520°C

1) A-i, B-ii, C-iii, D-iv 2) A-i, B-iii, C-ii, D-iv 3) + 0.372°C 4) – 0.570°C

3) A-iv, B-iii, C-ii, D-i 4) A-iii, B-ii, C-i, D-iv 10. 18 g glucose (C6H12O6) is added to 178.2 g water.
The vapour pressure of water (in torr) for this
3. What weight of glycerol should be added to
aqueous solution is :
600 g of water in order to lower its freezing
1) 7.6 2) 76.0
point by 10°C? (Kf = 1.86°C m–1)
1) 496 g 2) 297 g 3) 752.4 4) 759.0

3) 310 g 4) 426 g 11. The relative lowering of the vapoure pressure

is equal to the ratio between the number of
4. 10% solution of urea is isotopic with 6%
solution of a non-volatile solute X. What is 1) solute molecules to the solvent molecules
the molecular mass of solute X? 2) solute molecules to the total molecules in the
solution
1) 6 g mol–1 2) 60 g mol–1
3) 36 g mol–1 4) 32 g mol–1 3) solvent molecules to the total molecules in the
solution
5. Which of the following will have same value
of vant’ Hoff factor as that of K4[Fe(CN)6]? 4) solvent molecules to the total number of ions of
the solute
1) Al2 (SO4)3 2) AlCl3
3) Al(NO3)3 4) Al(OH)3

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 1

12. If 0.1 M solutions of each electrolyte are taken 18. One litre each of three solutions contain 20 g.
and if all electrolytes are completely dissociated, of fructose, 10 g. of urea and 34.2 g. of cane
then whose boiling point will be highest ? sugar. Their vapour pressure are P1, P2 and P3

RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * *
1) Glucose 2) KCl respectively. Then,
3) BaCl2 4) K4[Fe(CN)6] 1) P2 > P1 > P3 2) P2 > P3 > P1
13. True statement about non-ideal solutions is 3) P1 > P2 > P3 4) P3 > P1 > P2
1) do not obey Raoult’s law over the entire range 19. Assuming complete ionization, the depression
of concentration of freezing point of equimolar solutions of HCl,
CuSO4 and Na2SO4 are in the ratio of
2) A – A or B–B type interactions > A–B type
interactions 1) 1:2:3 2) 2:5:3
3) A –A or B–B type interactions < A–B type 3) 2:2:3 4) 1:1:1
interactions 20. The boiling point of C6H6, CH3OH, C6H5NH2
4) All of the above and C6H5NO2 are 80°C, 65°C, 184°C and 212°C
respectively. Which will show highest vapour
14. Which of the following solutions will have the
pressure at room temperature?
lowest vapour pressure ?
1) C6 H6 2) CH3 OH
1) 0.1 M Na3PO4 2) 0.1 M Na2SO4
3) C6H5NH2 4) C6 H5NO2
3) 0.1 M BaCl2 4) 0.1 M Urea
21. X3Y2 (i = 5) when reacted with A2B3(i = 5) in
15. Colligative properties depend on
aqueous solution gives brown colour. These
1) the nature of the solute particles dissolved in
are separated by a semipermeable membrane
solution
AB as shown. Due to osmosis there is
2) the number of solute particles in solution
3) the physical properties of the solute particles
dissolved in solution
4) the nature of solvent particles
16. Which of the following statements is/are true for the
diagram?

1) brown colour formation in side X

2) brown colour formation in side Y
3) formation in both of the sides X and Y
4) no brown colour formation
22. The vapour pressure at a given temperature
of an ideal solution containing 0.2 mol of a non-
vaolatile solute and 0.8 mol of solvent is 60 mm
1) The escaping tendency of molecule decreases for of Hg. The vapour pressure of the pure solvent
each component at the same temperatue is
2) Vapour pressure of the solution decreases 1) 150 mm of Hg 2) 60 mm of Hg
3) Solution shows negative deviation from Raoult’s 3) 75 mm of Hg 4) 120 mmm of Hg
law 23. Which one of the following pairs of the solution will
4) All of the above be same RLVP at the same temperature ?
17. A solution of 6 g. of a solute in 100 g. of water 1) 1.5 M AlCl3 and 2 M Na2SO4
boils at 100.52°C. The molar mass of the solute 2) 1 M NaCl and 2 M MgCl2
is (Given, Kb for water = 0.52 K kg mol–1) 3) 2.5 M KCl and 1.5 M Al2(SO4)3
–1
1) 600 g. mol 2) 6 4) 1.5 M KCl and 2.5 M urea
–1
3) 60 g. mol 4) 0.6

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 2