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Q1. Determine the enthalpy of reaction of

2H2S(g) + SO2(g)  3S(s) + 2H2O(l)
using the following standard enthalpies of formation:
H2S(g) ∆H°f = -20.63 kJ/mol
SO2(g) ∆H°f = -296.83 kJ/mol
H2O(g) ∆H°f = -241.82 kJ/mol
H2O(l) ∆H°f = -285.83 kJ/mol

Q2. For the reaction: CH4(k) + CO2(k) 2CO(k) + 2H2(k) , Kp = 5.8 × 102 at 900K.
Calculate the ∆ G0 of the above reaction:

Q3. The conventional equilibrium constant expression (Kc) for the system as described by the
below equation is:
2SO3(g) ↔ 2SO2(g) + O2(g)

Q4. If the equilibrium constant for the reaction

A + 2B ↔ C + 5/2 D
has a value of 4.0, what is the value of the equilibrium constant for the reaction
2C + 5D ↔ 2A + 4B
at the same temperature?

Q5. The half-life for a first-order reaction is 50 s. What was the original concentration if,
after 2.0 minutes, the reactant concentration is 0.05 M?

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Q6. What is the reduction potential for the half-reaction at 25o C:
Al3+ + 3e- → Al, if [Al3+] = 0.10 M and Eo = -1.66 V ?

Q7. Calculate the freezing point of a solution containing 10% glycerol C3H8O3 in water,
known that the freezing point depression constant of water is 1.86 ºC. Kg/mol and water
freezs at 0 celcius degree.

Q8. Calculate the molality of a solution that contains 51.2 g of naphthalene, C 10H8, in 500
mL of carbon tetrachloride. The density of CCl4 is 1.60 g/mL.

Q9. A 250 mL solution containing 21.4 g of a polymer in toluene had an osmotic pressure of
0.055 atm at 27 oC. What is the apparent formula weight of the polymer?

Q10. Find the Kp3 of the reaction : 2CO2(k)  2CO(k) + O2(k)

Given that: CO2(k) + H2  CO(k) + H2O(k) Kp1
2H2O(k)  O2(k) + 2H2 Kp2