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Dimension Stone
Dimension Stone
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Ten-thin section observations of samples collected from both lithotypes were carried
out under polarizing microscope according to EN12407 recommendations [14].
Modal analysis were performed following point counting method (thousand points
of minerals were analyzed per each thin section). The lithotype A + B has around
34–40% carbonates and 30–32% quartz, whereas the lithotype C + M has about
20–25% carbonates and 45–51% quartz. Both lithotypes have the same classification
according to Folk [15], i.e., they are classified as lithic arkose with carbonate cement
[16,17].
In this chapter, only the results of variety M will be considered. Lineations were not
macroscopically detected on the variety M, but in thin sections under a polarizing
microscope, two preferred orientations of mica minerals were present. All these vari-
eties have about 4–6% mica minerals. The average size of quartz and feldspar grains
in the sandstone varieties A and B ranges between 0.1 and 0.13 mm (Figure 10.3),
whereas in variety M, the average size is about 0.24 mm (Figure 10.4). Sandstones
A and B are generally fine grained and variety M sandstones are medium to fine
grained [16].
Figure 10.3. Thin section observation of lithotype A + B (variety B) carried out under
polarizing microscope (magnification 40 ×).
Figure 10.4. Thin section observation of lithotype C + M (variety M) carried out under
polarizing microscope (magnification 40 ×).
Sandstone specimens of variety M were randomly cut in prismatic and cubic spec-
imens of 50 × 50 mm2 cross section, corresponding to a height-to-length ratio of,
respectively, 2 and 1. These samples were used to carry out physical and mechanical
tests.
As far as Italy is concerned, this use dates back at least to the times of the Greek
colonization of the southern part of the peninsula (about 2700 years ago). The Greek
colonizers used tuff as building blocks for constructing various masonry structures,
houses, and burial chambers. In Naples, remains of potent fortifications belonging
to the walls of the old city (viz., Neapolis) are still preserved (see Figure 1), but most
of these works were destroyed, because the Roman city was built over the ruins of
the Greek city. The Romans used the tuff blocks for all kinds of construction and
to meet both architectural and structural requirements [82]. Hundreds of ruins of
buildings made with zeolitic tuff are spread over the Neapolitan area. Remarkable
examples are present also in the old cities of Pompeii, Herculaneum, Stabiae, and
Oplonti, buried by thick beds of volcanic ash during the Vesuvius eruption of 79 AD
and therefore mostly preserved.
The building techniques developed by the Romans, including the practice to cover
tuff walls by plaster or more valuable stones (e.g. marble), were utilized almost
unchanged during the first millennium and beyond. More recently, beginning in the
Middle Ages, frequent use was made of tuff as a facing stone, also outside Italy, in
recognition of its architectural value. Examples of this use are numerous in Naples
and its surroundings, including some castles (Figure 8, left) and churches, made
with bare blocks of phillipsite-rich Neapolitan yellow tuff, dated from the 12th–16th
centuries [2], and the two hundreds and more monumental buildings constructed
in Germany since the Middle Ages. The greatest concentration is in Cologne, where
some 30 monuments and churches (Figure 8, right), made of Rhenish trass, a local
chabazite-rich material, are located [83]. Relevant examples of more recent use
of this material are the impressive bridges of the Acquedotto Carolino (Charles III
Bourbon Aqueduct) in Valle di Maddaloni, near Caserta (south Italy) (Figure 9), built
in the second half of the 18th century, in opus mixtum (tuff blocks intercalated with
clay brick lines) by Luigi Vanvitelli, the famous architect of Caserta Royal Palace.
Figure 8. (left) Naples (Italy): Castel dell'Ovo (12th century), a historical monument
made with Neapolitan yellow tuff; (right) Cologne (Germany): Gross-Martin Church,
a historical monument (12th–13th century) made with Rhenish trass.
The use of zeolitic tuff was very extensive also in the popular constructions. In Italy
entire villages were traditionally (and are still being) constructed using this stone,
e.g. all the houses in the villages of Pitigliano, Sovana, and Bagnoregio and in the
city of Orvieto (central Italy) are made of chabazite-rich tuffs [84].
Natural stone has a low EE and carbon footprint (Tables 12.3 and 12.4). However,
objective comparison between materials of different build contexts is difficult:
Masonry materials tend to be used in heavy constructions, whilst the materials
associated with higher EE/EC footprints tend to be lighter. This difficulty is resolved
by the LCA for the structures respectively, although a feel for comparative purposes
can be gained by comparing constructions in the BRE's Green Guide (Anderson et al.,
2009). The context of use issue is well represented in slate; whilst there are exceptions
in which it is used in structural walling, its predominant application is as a roofing
material. Therefore, a unit area assessment of the EE/EC footprint would be in order.
Table 12.3. Embodied carbon footprint of selected natural stones available in pub-
lished literature
Table 12.4. Embodied energy footprint of selected natural stones available in pub-
lished literature
a NB: Processing data was unavailable from the University of Tennessee; how-
ever, the quarrying cost was lower than limestone, and processing/dressing
techniques to produce dimension stone are quite comparable between sand-
stone and limestone.
The data pool for the EE and carbon environmental impact of natural dimension
stone was noted by the source authors to be small, leading to the relatively high
deviation observed. The figures quoted in Tables 12.3 and 12.4 are largely composed
of the energy (and related CO2 impact) in the processing of the quarried stone. The
EE figures do not appear to accord well with the EC figures, across the few sources
available. The figures indicated consider the ‘waste’ associated with the final product
(dimension stone), which is very high for slate. However, Crishna et al. (2011) observe
that, owing to the zero waste in practice arising from stone quarries, considering
the environmental footprint of stone on the total material produced (including
secondary products of rubble and hardcore, etc.), slate can be demonstrated to have
lesser carbon impact than the other building stones.
Interpreting the data generally, taking average values across the different sources,
it is clear that natural stone exhibits a low environmental footprint when compared
with other typical building materials (Table 12.5).
The mortar with which the stone is laid represents a major constituent in the bulk of a
stonework wall, particularly where the masonry units are small (demanding a higher
frequency of joints, as in brickwork). Traditionally, stone masonry was laid with lime
mortar. As with natural stone, the data pool for lime mortars is correspondingly
small, and some contention is to be found in the literature as to its environmental
footprint relative to cement mortar (eg, Hammond and Jones, 2008; De Vekey, 2005;
Reddy and Jagadish, 2003).
The lower burning temperature of lime does not necessarily or directly constitute
an environmental saving, owing to the typically longer burning durations. However,
lime mortars feature a carbonation set, which reabsorbs an extent of the CO2 driven
off when the limestone is burned. This is especially so for putty limes, which
set entirely by carbonation and fully reabsorb the displaced CO2; the low end of
the natural hydraulic lime (NHL) (eg, NHL 2) similarly exhibit a high degree of
carbonation. Little difference is observed between NHL 3.5 and NHL 5 mortars in
terms of their respective proportion of carbonation set (Hughes and Swann, 1998).
The formation of the compound which demands the carbonation set (portlandite)
is strongly influenced by the phase chemistry, but in general terms the lower the
burning temperature, the higher the proportion of portlandite formed and available
for carbonation. For the more hydraulic mortars (NHL 3.5, NHL 5 and cements),
the mineralogy and higher burning temperatures lead to smaller proportion of
portlandite formed, and consequent carbonation is small if at all. Carbonation is a
complex process related to available portlandite, diffusivity of the pore matrix and
environmental conditions.
Given the foregoing, support is made for the use of the weaker, high-carbonation
limes. Reddy and Jagadish (2003) observe that lime:pozzolana mortars have the
lowest environmental impact of all the building mortars they studied, including
cementitious. Table 12.6 abstracts from Hammond & Jones Inventory of Carbon
and Energy (ICE) the data for cement mortar, and the closest available mixture to
represent a lime mortar.
Data from Crishna, N., Banfill, P., Goodsir, S., 2011. Embodied energy and CO2 in
UK dimension stone. Resour. Conserv. Recycl. 55, 1265–1273.
The environmental footprint of stone increases many times over the further away the
source is located. Clear suppport for the use of indigenous stone is demonstrated
in EE and carbon terms, aside from the less-quantifiable sustainability benefits of
promoting local rural employment, and safeguarding local distinctiveness.
The easiest application of these materials for building is directly as dimension stones
[263], and their use in this form is possible on account of the high compressive
strength of natural zeolites, which can reach 17.5 MPa and has average values of
3–5 MPa [264]. At present around 3 million tons of zeolitic tuff is produced each
year for building materials in Italy alone [263].
The use of zeolitic tuffs for the preparation of blended cements is a common
industrial practice [32, 265–268]. In recent times the use of blended cements has
increased for energy saving reasons, and currently large quantities of blended
cements are produced with a significant decrease in energy consumption. That is
not, however, the only reason for the production of blended cements. The addition
of zeolite increases their mechanical strength and their resistance to chemical attack,
and decreases the amount and rate of heat evolution and the alkali level in the
mortars prepared with these cements [266].
Further applications of natural zeolites in the building industry are the preparation
of lightweight brick [45] and lightweight aggregates in high-strength mortar and
concrete [269].
The identification of the minerals or the minerals, main chemical groups or ions
(e.g., sulfates) and their extent on samples by chemical analysis can also be obtained
using atomic absorption spectroscopy (AAS), energy dispersive X-ray fluorescence
(EDXRF), laser Raman spectroscopy (LRS), Fourier transform infrared spectroscopy
(FTIR), and laser-induced breakdown spectroscopy (LIBS). According to Bitossi et al.
[207] the XRF (X-ray fluorescence spectroscopy) and EDXRF are among the most
important techniques for qualitative and semiquantitative analysis of elements in a
sample. For this purpose, portable XRF systems have been widely used for in situ
nondestructive analyses.
Listed here are the 67 volumes, divided among their 16 sections, published by the
ASTM:
A typical American Standard for Testing Materials covers, among many things, the
following;
• Scope.
• Referenced documents.
• Ordering information.
• Chemical composition.
• Heat treatment.
These standards guarantee that, if the base material used is manufactured to a set of
well defined rules, then the various characteristics of that material will be predictable
and the materials of construction can be specified with confidence.
The following is an example of the detail that an ASTM specification goes into:
2.6 Sandstone
Crishna et al. [56] carried out a process based on LCA of the dimension stone
production in the UK. From a survey of eight production operations, the calculated
carbon footprint of sandstone was 77 kg CO2e/tonne, of granite 107 kg CO2e/tonne,
and of slate 251 kg CO2e/tonne. These values would be considerably higher for stone
imported from abroad due to the impact of transport. Authors stated that reducing
the use of imported stone would contribute to emissions reduction targets.
According to Reddy [32,57] a mixture of lime, fly ash and stone crusher dust can be
compacted in a high-density block. Lime reacts with fly ash minerals forming water
insoluble blonds imparting strength to the block.
According to the Government's Vision 2030 (Republic of Zambia, 2006), the people
of Zambia look forward to seeing a strong and stable middle-income industrialized
country by 2030. This means hard work through investment and diversification
of the economy by not only depending on mining but also on agriculture and
manufacturing industries. The notion of achieving a middle-income nation by 2030
is based on the implementation of policies and framework under the Sustainable
Development Goals3 (SDGs). The African Union's (AU) agenda 2063 and the Seventh
National Development Plan (7th NDP) set from 2017 to 2021 (Ministry of National
Development and Planning, 2017) have also been aligned to the aforementioned
notion predicting an average of 5% in economic growth. Zambia has potential
for investment in mining and other natural resource sectors but the problem is
mainly inadequate to poor infrastructure and social amenities including health and
education centres (ZDA, 2016).
Despite some of the industrial mineral resources not being quantified or evaluated,
they have the capacity to develop Zambia without even focusing on base metal and
precious mineral mining. It has been estimated that over $520 million worth of
industrial minerals and related products were imported in 2017. On the other hand,
over $5 million of the same goods were exported resulting in a trade deficit of around
$515 million.4 This is a negative impact on the economy of the nation since such
imported goods can easily be extracted locally. Beneficiation of the same minerals
and products could even fetch a higher value on local and international markets.
This study gives an insight of industry minerals for the entire country specifically
highlighting their impact on the local economy and livelihoods of the local people.
Generally, the industrial mineral sector has been neglected for decades by relevant
stake-holders. This calls for more research, exploration and funding towards the
project through the Geological Survey Department (GSD) which falls under Ministry
of Mines and Minerals Development (MMMD).