spectroscopy) 7 *E

Ei Tua f 7 I
1
rotational
spectrum) quf Z 4 - OG

(ROTATIONAL SPECTRUM]

active) 37' TEÀ EI

inactive) 37 5
T a I À 3q3i ' H T T 37f57 (microwave
, à qur

TEer aui T (Energy Levels of a Rigid Rotator)

m2 (bond length) r 3YtATTY 3s

m
-r= +2

fHT 3 TEeT* (rigid

C rotator) R ZA AR* m, 3R m,

-2-
01 Tar (centre of gravity)C

74Ti t a T gà (bond distance) 3fierita sir ffrTa (fixed) H

 zrfut-I | 93

T fsvTATys 3
(intensity) 7 7 4 TA ¥RH (rotational transition) feT ar f
*51 fAeTTUI
(selection rule)

(moments) KR EN
m m/2 .5)
fRT m, T T 5 5 3TUi (moment ofinertia) TA T

m,+ m,r, 6)

(6) stt (5) ,

I =m r t m 2
(m)r + (m,r2)r2

m,rri tmi"T2
r +m) (7)
fa 3.9 ,
rrt2 8)
r2r- .9)
FHTTT (5) 3R (9) R,
m mr2 m,r-r) .(10)
mtmaim
rm, tm,) mar
m
(m +m,) 1)

2 (m, +m,) (12)

m, m,r
I = X

+m,)"(m, +m,
ma 13)
(m+m,)
TA TEVRATTT m,m,
ST 1 FHTAA ZOAHTA (reduced mass) 4=,+mErI E
TI
(14)

e v, 3t v, zeq4A m, att m,
E-m?+ 5my2 15)
THT: Tua 7
(linear velocity) E1
 E-m,a+mor
rtm my:5)
16
of inertia) t1
TEI u 3a8 U vfa À aT 7 T5 T (moment
cum)
L = lo

h
L2 18)

L J+1) (19)
FHTR (19) f yAR frai i Hodl :

.20)
0+1)4
iT HHT (17) 4,
L lo
1 (1 21)
FHTTI (20) a (21) 4,

Fo JJ+ 1) .22)

H E5l[zttTm(16) ]
.23)
HHT7 (23) À o* 1 4 HHTU (22) Ta
h
J(J + 1) A
J +1)TT .(24)

ET J= 0, 1, 2, 3... 3G, h
=
i 6 fRT5, I =
T$ ATui aem J =
qu e

AI
p FATA qU FRI (allowed rotational energy levels) 51 fTETA

E B.J. U+ 1) T (25)
 f r - 1 |95
nfa aT (wave number) 7 u j f TCT
Eho h = hc

hc .(26)

h Ich+1)A-I
8n
hc

h
8 2 I + 1) A 27)

hc
FHiTI(27) ÄJ=0, 1,2, 3.... Af UTts,c =TTRI =3 x 10-10 ET/$TUE;

m, +m,

& BJ(J + 1) AT-I (28)

BJ(J + 1) ÀA-I
B
I5R (25) 3R (28) Ha TEI fearm
6 42 B

5 30 B

HT f5 J =0 3, 74 208
Ey-o BJ (J + 1) FHT-
B x O(0+ 1) 3 12 B
= 0 AT-1
29)
6B
2B
HTP J= 1, Ta
-BJ(+ 1) àAt-
Bx 1(1 +1) fa 3-10. T furaTua 3T
2B HT 30)
 at
THTYT feia (4tfa% THTY-)-Jaia
96I t 1 S
t i yenk J
=
3, 4, 5.. Hfë yute Ta}
6B RHt-|
(J+ 1) B 2(2 1)
=
+
l EH3-10 qvT TR
= x

E- BJ TrN
541: 12B, 20B, 30B 337fe qufa zÍ
TT A EI T

J
6 42 B
12 B

E = E =02B
-0 =2BH- .31)
5 30 B

10 B

4 20 B = - J-0 2B 0 2B H
8B

- 12 B
3
6B fa M:
2 6B E-2-E= 6 B -2B 4B T(32)
4B 2B -2j= = 6B 2B 4B ÀHT
0 26
12 B Cm-
4 B B
0

68 10 B 4195 (in general) zf 3y 1 HHTJ

2B
TFTÀJ+1 3541 EIEtUT (28) HTHK,
fa 3-11. PRi terN
E or D-J+1
=
B(U + 1)(0+2) -BJ(J + 1)
=B[J+3J +2 -(+ J)]
2B(J+ 1) ÈHT-1

3 f : 2B, 4B, 6B... T IT ë, ST À T If a a (3-10)

3R (3-11) À f¢ERI
TT