RayatShikshan Sanstha’s

Karmaveer Bhaurao Patil, College, Vashi

(Autonomous)
Analytical chemistry Semester VI 2021-22
Class: T.Y.B.Sc Course code: UGCH604 Total Marks: 60 Time: 2Hours
N.B. i) All questions are compulsory
ii) Figures to the right indicate full marks
____________________________________________________________________
Q.1-A Answer the following (Any two) ( 08 M) CO
1 Explain the principle of polarography with particular reference to CO2
advantage of dropping mercury electrode.
2 State the IlKovic equation and explain terms involved in it. CO1
3 Summarize what meant by half wave potential and diffusion current? CO2
4 Compile construction and working of dropping mercury electrode and CO4
give its limitations.
Q.1-B Answer the following ( 07M)
1 Indentify the electrode In polarography, of large surface area which do CO2
not change its own potential is called ________.
a)Polarisable electrode b)Non-polarisable electrode c)None of these
d)Both (a) and (b)
2 ----------- is used as supporting electrolyte in polarography CO2
a)NaCl b)KCl c)KBr d)HCl
3 Dissolved oxygen is removed by passing _________ gas through the CO3
experimental solution in polarographic analysis.
a)Nitrogen b)Carbon dioxide c)Oxygen d)Helium
4 In amperometric titrations, __________ is measured as a function of CO4
volume of titrant.
a)Diffusion current b)pH c)Potential d)Temperature

5 When both titrant and reactant are reducible in amperometric titration, CO3
________ shape curve is obtained.
a)S-shaped b)peak c)V-shaped d)Hump

6  The dissolved oxygen present in experimental solution in acidic medium CO1

gets easily reduced at DME to form _________, in the first step.
a)Hydrogen peroxide b)Gelatin c)Triton X 100 d)Nitrogen

7 The Half wave potential is defined as potential at which current flowing CO1
through the cell is half of _________.
a)Residual Current b)Limiting Current c)Diffusion Current d)None of
these

Q.2-A Answer the following (Any two) ( 08 M)

1. Explain the fundamental principle of gas liquid chromatography CO2
2 Define ion-exchange capacity. How is it determined? CO1
 3 Describe in detail any one detector used in gas chromatography. CO2
4 Discriminate the following applications of ion-exchange CO4
Chromatography i) Separation of metal ions ii) preparation of deionised
water

Q.2-B Answer the following ( 07M)

1 When larger the number of theoretical plates, more --------is the column. CO2
a)Efficient b) Heavy c) Costly d)Popular

2 ---------detector is very sensitive for analysis halogenated hydrocarbons. CO1

a)TCD b)ECD c) FID d)PMT
3 Gas chromatography is a useful method for separation of mixtures CO1
containing _________ components.
a)Solid b)Ionic c)Non-volatile d)Volatile
4 Which of the following is an example of a natural ion exchanger? CO1
a)Clay b)Alum c)Rock salt d)Neoprene
5 The total ion-exchange capacity of resin is expressed in terms of ---- CO2
a)millivolt per meter b)miliequivalent per gram c)meter per secondd) mile
per hour

6 ---------------can be separated using ion exchange chromatography? CO3

a)Lanthanides b)Amino acids c)ionic mixtures d)All of these
7 The principle of separation in GSC is __________. CO1
a)Selective diffusion b)Ion exchange c)Different boiling points
d)Selective adsorption
Q.3-A Answer the following (Any two) ( 08 M)
1 Explain the need of food preservation. CO2
2 Describe the Process of pasteurization? Explain its objectives. CO1
3 Summarize different types of tea. CO4
4 Generalise the term cosmetics? Explain its functions. CO5
Q. 3-B Answer the following ( 07M)
1 Food processing improves the ______ of food. CO1
a)Nutritional value b)Shelf-life c)Both (a) and (b)
d)None of these
2 Which of the following is a physical method of food preservation? CO2
a) Fermentationb) Pasteurization c) Irradiation
d) Both (b) and (c)
3 Identify which can be used as food preservative. CO1
a)Acetic acid in vinegar b)Carbon dioxide c)Benzoic acid and sodium
benzoate d)All of these
4 Zinc oxide is added to face powder to increase its_____________. CO2
a)Fluffiness b)Weight c) Cost d)Opacity
5 Which of the following prevents / controls body odour? CO2
a)Lipstick b)Deodorant c)Sanitizer d)Face powder
6 Identify which is the major pharmacologically active compound is found CO1
 in coffee.
a)Inuline b)Caffeine c)Chicory d)Nicotine
7 Raw honey contains the enzyme _________. CO2
a) Glucose oxidase b)Lipase c)Alkaline phosphate d)Lysase

Q. 4-A Answer the following (Any two) ( 08 M)

1 Draw a schematic diagram of thermobalance & give the requirements of CO1
good theromobalance .
2 Distinguish between DTA and TGA CO2
3 Explain in detail construction and working of the theromobalance. CO1
4 What is meant by the validation in the analytical Chemistry? CO4
Q.4-B Answer the following ( 07M)
1) In thermometric titrations the property measured is ___ CO1
a) heat evolved or absorbed b) change in weight c)change in temperature
d)fluorescence
2) Enumerate TGA, involves measurement of change in ________ of a CO3
substance
a) weight b)temperature c)enthalpy d) colour
3) Fusion of the sample during DTA is indicated by ________Peak. CO1
a) exothermic b) endotherm c) no change d)sudden fall

4) Which is effect of the differential thermogram for the dehydration shows CO2
_________ peaks
a) exothermic b) endothermic c)multiple d) non-uniform

5)  Report in DTA, _______ is mostly used as reference material. CO2

a) MgO b) SiC c) Ca(OH)2 d) NaCl
6)  List Thermometric titrations can also be performed using _________ CO1
solvents.
a)Non-aqueous b)Organic c)Inorganic d)volatile
7)  Analysis of the sample with two different methods is used to validate CO3
_________ of the method
a)Precision b)Linearity c)Accuracy d)Experience