Sardar Patel University

Department of Applied and Interdisciplinary Sciences

M. Sc. Applied Chemistry Semester - IV
PT04CACH21- Applied Organic Chemistry
Assignment
UNIT – III

Short Questions

1. Give the name of the following heterocyclic compounds. (Any example)

2. Write the synthesis and reaction of pyrylium salts.
3. Write the synthesis and reaction of 2-pyrone/4-pyrone.
4. Give the synthsis of pyridinium and thiopyrylium slats.
5. Write the structures of diazine heterocyclic compounds.
6. Compare the structure of coumarins and chromones.
7. Complete the reaction. (any example)
Long Questions

8. Discuss the nomenclature of six membered heterocycles with one, two and more
heteroatoms.
9. Write a short note synthesis and reaction of diazines.
10. Give the synthesis and reaction of azepines.
11. Give the synthesis and reaction of oxepines.
12. Explain the Fisher-Indole synthesis with mechanism.
13. Write the synthesis and mechanism of Skarup and Combes synthesis.
14. Discuss the mechanism of Conard Limpach and its Knorr synthesis.
15. Identify and give the mechanism for following reaction.
1.

2.

1. CH3COCl,
NH2 2. P2O5, 210o C N
3. Pd,C
CH3
 Sardar Patel University
Department of Applied and Interdisciplinary Sciences
M. Sc. Applied Chemistry Semester - IV
PT04CACH21- Applied Organic Chemistry
Assignment
UNIT – IV
Short Questions
1. Define the term disconnection.
2. Define the term synthon and synthetic equivalent .
3. State the term FGI/FGA with suitable example.
4. Write the note on protection of alcohol.
5. Explain the protection and deprotection of ketone.
6. Explain logical and illogical synthon with suitable example.
7. Give the synthesis of 3 membered ring small compound.
8. Give the synthesis of 4 membered ring small compound.
9. Explain the disconnection of 1,2/1,3/1,4/1,5/1,6 dicarbonyl.
10. Explain the disconnection of alkene/alcohol/acid.

Long Questions

1. Give the retrosynthesis of following TMs and discuss their synthetic route. (Any example)