Bài giảng DANGEROUS GOODS

7/29/2021
Vietnam Logistics Research and Development Institute

4th Fl, Vietnam Maritime Building, No.89, Pasteur Str., Ben Nghe Ward,
Dist.1, HCMC
Tel: (+84) 28 7301 8689 – Email: vli1@vli.edu.vn
Website: www.vli.edu.
MODULE
TRANSPORT OF
DANGEROUS GOODS
Facilitator: Nguyễn Trần Thanh Thuần
Module 12– Dangerous Goods 1

FIATA Diploma in International Freight Management © Copyright 2019 Vietnam Logistics Research
and Development Institute

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OBJECTIVES
Objectives
After learning this module, the learners will be able to:
1. Define dangerous goods and (DG)
2. Identify dangerous goods and classifications
3. Describe the role and responsibilities of the parties in the transit chain
4. Determine the training requirements of DG
5. Apply the Dangerous Goods Regulation (DGR) in all transport modes
6. Practice Dangerous goods Acceptance

CONTENTS
Contents
1. THE OVERVIEW OF DANGEROUS GOODS
2. THE SYSTEM OF REGULATIONS DANGEROUS GOODS IN

TRANSPORTATION
3. HANDLING OF DANGEROUS GOODS
4. VIETNAM’S REGULATIONS OF CARRIAGE OF DANGEROUS GOODS

HANDLING

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CHAPTER 1
OVERVIEW OF TRANSPORTATION OF
DANGEROUS GOODS

CHAPTER 1
OVERVIEW OF TRANSPORTATION
OF DANGEROUS GOODS
Learning Objectives:
After learning this part, the learners are able to:
- Distinguish the concept Safety/ security; accident/ incidents
- Recognize dangerous goods and its risk
- Practise the training requirement on DG
- Recognize the UN Model Regulations
- Training Requirements

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1.1 WHAT IS DANGEROUS GOODS ?
“Dangerous goods are articles or substances which are capable of

posing a risk to health, safety, property or the environment and which
are shown in the list of dangerous goods in these Regulations or
which are classified according to these Regulations.“

The difference between hazmat and DG????
Hazardous substances can be defined dangerous goods present an immediate

as: A product, material or substance that level of chemical and physical danger to
has the potential to be harmful to a the surrounding environment, including
person’s health, both short and long term. people and property.
The core difference that lies between
hazardous substances are substances dangerous goods and hazardous
that are dangerous to a person’s health. substances is that dangerous goods
Each state has its own legislative present an immediate danger to
requirements regarding hazardous people, property and the environment,
substances, generally in the form of a that may ultimately harm a person’s
code of practice that supports a health; on the other hand, hazardous
regulation and the occupational health substances are substances that
and safety acts. present a direct risk to a person’s
health both short and long-term.
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Ammonium nitrate - hóa chất gây ra thảm họa kinh hoàng ở Lebanon Ammonium
nitrate là chất oxy hóa. Nó khiến phản ứng nổ xảy ra mạnh hơn
?
và làm những chất hóa
học khác dễ cháy hơn. Tuy nhiên, bản thân chất hóa học này không dễ nổ. Chính vì vậy,
việc cất trữ ammonium nitrate luôn được quản lý chặt chẽ, cụ thể là để xa nhiên liệu
hoặc nguồn nhiệt. Nhiều thành viên Liên minh Châu Âu (EU) còn yêu cầu thêm calcium
carbonate (CaCO3) để tạo thành calcium ammonium nitrate (vôi nitro) để đảm bảo an
toàn và giảm rủi ro cháy nổ.

Tàu chở hóa chất này tiếp tục cháy ngày thứ 6 liên tiếp. Nhiều
hình ảnh được truyền thông đăng tải ngày 26-5 cho thấy khói đen
vẫn bốc lên từ con tàu.
Tàu chở tổng cộng 1.486 container, gồm 25 tấn axit nitrit cùng
nhiều hóa chất và mỹ phẩm khác. Số container này được đưa lên
tàu tại cảng Hazira ở Ấn Độ hôm 15-5. Con tàu đang trên đường
đi từ Ấn Độ tới Singapore, thông qua Colombo (Sri Lanka).
Hải quân Sri Lanka cho rằng đám cháy là do số hóa chất trên
tàu gây ra.

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1.2 GENERAL PHILOSOPHY

Training requirement
Packaging
Prohibitions
Classification
How to maintain
the safety Marking and Labeling
Documentation
Avoiding Hidden Hazards
Accident/ Incident Reporting
Notification to pilot-in-command

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1.3 SHIPPER’S RESPONSIBILITIES
− Recognize and identify

− Classify the item into 1 of 9 classes
− Packing/ Package
− Marking, labellings and placarding
− Complete the required documentation
− Ensure that all national and international regulations
have been complied with; and
− Ensure their shipment is made safe for transport

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1.4 FREIGHT FORWARDER ’S

RESPONSIBILITIES
− Select safe ways of transportation and handling of the
goods
− Advise the shipper on all implications and requirements
and verify that the regulations is followed
− Proper handling and storage

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1.4 FREIGHT FORWARDER ’S RESPONSIBILITIES
− Proper loading into trucks to transfer the items to the carrier

− Inspection of packages  to ensure the package is intact for transport and
handling
− Reporting of any accidents/incidents
− Following emergency procedures in the event of an accident/incident

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1.5 OPERATOR’S RESPONSIBILITIES

- Acceptance
− Storage
− Loading
− Inspection
− Provision of Information
− Emergency response
− Retention of records
− Training

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1.6 CARRIER’S LIABILITY

 Acceptance or verification that the shipment of dangerous goods has
been properly prepared;
 Provision of capable staff and appropriate equipment for transport and
handling of the goods;
 Provision of the appropriate marks, signs to the vehicles, and
documents;
 Storage, loading and unloading of the shipments;
 Inspection of the shipment during handling, for any leaks or damage;
 Reporting of any accidents/incidents, and corresponding emergency
procedures;
 Training of all employees that may come into contact with dangerous
goods;
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1. 7 THIRD PARTY’S LIABILITY
Provide capable staff for handling of dangerous goods;
− Provide appropriate and well maintained equipment for the storage and
handling of dangerous goods;
− Store and handle the dangerous goods in separated areas if needed.

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Chapter 2
THE SYSTEM OF DANGEROUS GOODS
REGULATIONS IN TRANSPORTATION

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Chapter 2

Learning Objectives:
- After learning this chapter , the
learners are able to:
- Recognize practical dangerous
goods Regulations
- Well- applied dangerous goods
regulations in accordance with
transport mode

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Chapter 2
2.1 UN- MODEL REGULATIONS

- The UN Model Regulations provide a uniform set of safety
procedures covering consignment and transport issues such as:
- classification, identification, packing, marking and labelling,
documentation, security and training.
- addressed to governments and to the international
organisations concerned with safety in the transport of dg.
- Aim: to present a basic scheme of provisions that will allow the
uniform development of national and international regulations
governing the various modes for transport

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- Transport of dangerous goods needs to be regulated in order to

prevent, as far as possible, accidents to persons or property and damage
to the environment, the means of transport employed or to other goods.
- different regulations in every country and for different modes of
transport, international trade in chemicals and dangerous products
would be seriously impeded, if not made impossible and unsafe.
- Dangerous goods are also subject to other kinds of regulations, e.g. work
safety regulations, consumer protection regulations, storage regulations,
environment protection regulations.

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- In order to ensure consistency between all these regulatory systems,

the United Nations has developed mechanisms for the harmonization
of hazard classification criteria and hazard communication tools
(GHS) as well as for transport conditions for all modes for transport
(TDG).
- In addition, the UNECE administers regional agreements that ensure the

effective implementation of these mechanisms as far as transport of
dangerous goods by road, rail and inland waterways is concerned

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-Developed by the United Nations Economic and Social Council's

Committee of Experts on the Transport of Dangerous Goods
- Prepared by the United Nations Economic and Social Council’s
(ECOSOC) Committee of Experts on the Transport of Dangerous
Goods (CETDG),
- “Orange book” published in 1956

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Scope
− The Model Regulations covers amongst other aspects:
− principles of classification and definition of classes;
− listing of the principal dangerous goods;
− identification of dangerous goods;
− general packing requirements;
− testing procedures;
− marking;
− labelling or placarding; and
− Transport documents.

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Structure
The UN Model Regulations consists of seven parts, two

appendices and an alphabetical index of substances and articles
in two volumes. Each part is subdivided into chapters, sections and
subsections. The layout is as follows:

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Volume I Volume II
1. General provisions, definitions, 4. Packing and tank provisions
training and security 5. Consignment procedures
2. Classification 6. Requirements for the construction
3. Dangerous goods list and limited and testing of packaging, intermediate
quantities exceptions bulk containers (IBCs), large
Appendix A – List of generic and N.O.S. packaging, portable tanks, multiple-
proper shipping names element gas containers
Appendix B – Glossary of terms (MEGCs) and bulk containers
Alphabetical index of substances and 7. Provisions concerning transport
articles operations

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2.1 UN MODEL REGULATION

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2.2 DANGEROUS GOODS

TRANSPOSTED BY AIR

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2.2.1 BASIC OF IATA DANGEROUS GOODS REGULATIONS
Recommendations of the UN Regulations for the Safe

Committee of Experts on the Transport Transport of Radioactive Material
Of Dangerous Goods by IAEA
Technical Instructions for the Safe

of Dangerous Goods by Air
by ICAO
IATA
Module 12– Dangerous Goods
Dangerous Goods Regulations 30
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2.2.1 BASIC OF IATA DANGEROUS GOODS

REGULATIONS
Annex 18 (Chicago Convention)

Technical instructions for Safe Transport ICAO
of DG by air
MORE RESTRICTIVE
IATA DGR are recognized by ICAO as the IATA
field document for the transport of DG by
air. STATES
Some States and Operators use their DGR 2.8.1
right to be more restrictive than the ICAO
OPERATOR
Technical Instructions. The variations are
DGR 2.8.3
files with ICAO and IATA
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2.2.2 TYPE OF DANGEROUS GOODS
2.2.2
TYPE OF DG
FORBIDDEN TO BE SENT ACCEPTABLE

AS CARGO
Forbidden Totally In Pax ‘s PAX’S

unless forbidden OPbaggage
CREW COMAT
BAGGAGE
exempted by air
CAO PAX a/c

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2.2 3 TRAINING REQUIREMENTS
− Training is mandated
− Recurrent training must be taken
− The training is required in accordance with table
1.5 A
− There are 3 elements of the training:
– General familiarization of training
– Function or job specific training
– Safety training

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2.2.3 TRAINING REQUIREMENTS

− WHO TO BE TRAINED?
a) the contents of dangerous goods requirements commensurate with
their responsibilities.
− Employees shall be trained in accordance with b) before has not yet
been provided, under the direct supervision of a trained person.
b) Individual such as those who classify dangerous good, pack; mark
and label; prepare transport documents for dangerous goods; offer or
accept for transport; carry or handle dangerous goods in transport;
− mark or placard or load or unload packages of dangerous goods into or
from transport vehicles,
− but packaging or freight containers; or are otherwise directly involved
in the transport of dangerous goods as determined by the competent
authority; shall be trained in the following 1.3.2.
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− WHAT TO BE TRAINED? (Con’t)

− General awareness/ familiarization training:
a) Each person shall be trained in order to be familiar with the general
provisions of dangerous goods transport requirements;
b) Such training shall include a description of the classes of dangerous
goods; labelling, marking, placarding and packaging, segregation and
compatibility requirements;
a description of the purpose and content of the dangerous goods transport
document;
and a description of available emergency response documents.
c) Function – specific training:
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Safety training:
Commensurate with the risk of exposure in the event of a release and
the function performed, each person shall be trained in:
a) Methods and procedures for accidents avoidance,
b) Available emergency response information and how to use it;
c) Classes of dangerous goods and how to prevent exposure to
those hazards,
d) Immediate procedures
− required by 1.3.2 shall be provided or verified upon employment in
a position involving dangerous goods transport
− periodically supplemented with retraining as deemed appropriate by
the competent authority.
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TABLE 1.5 A- IATA DGR 2020

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TABLE 1.5 C
Designated Postal Operators
Aspect of DG by air with which they should be familiar, as a minimum a: Staff of
a b c Designated Postal
1. General philosophy x x x Operators involved in
2.Limitations x x x accepting mail
3.General requirements for shippers x containing
4. Classifications x dangerous goods
5. List of dangerous goods x x b: Staff of
6. General packing requirements x Designated Postal
7. Packing instructions x Operators involved in
8. Labelling and marking x x x
processing mail
9. Shippers’ declaration and other relevant documentation x x
(other than
10. Acceptance of dangerous goods listed in 2.4 x
dangerous goods)
11. Recognition of Undeclared dangerous goods x x x
c: Staff of
12. Storage and loading procedures
Designated Postal
x
13. Provisions for passenger and crew

Operators involved in
x x x
14 Emergency procedure
handling, storage
x x x
FIATA Diploma in International Freight Management
and loading of mail 39
© Copyright 2019 Vietnam Logistics Research
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2.2.4 CLASSIFICATION

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DGR CAT 6 41 Research
© Copyright 2019 Vietnam Logistics
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CLASS 1 EXPLOSIVE
6 divisions: 1.1; 1.2; 1.3; 1.4; 1.5 and 1.6
13 compatibility groups:
A,B,C,D,E,F,G,H, J,K, L,N, and S
1.4 S is permitted on passenger aircraft.
classes 1 is normally forbidden for carried by air.

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CLASS 2 GAS
DIV 2.1 (RFG) DIV 2.2 (RNG) DIV 2.3 (RPG)
Most toxic gases are forbidden for carriage by air; some are permitted

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Class 3 has no divisions DGR-Table 3.3A
Class 3 Packing Group Assignment
Packing Flash Point Initial

Group (Closed cup) boiling point
I - ≤ 350C
II < 230C
III ≥ 230C but ≤ 600C > 350C

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CLASS 4: FLAMMABLE SOLIDS
Div 4.1 (RFS) Matches, Sulfur

Div 4.2 (RSC) White or yellow phosphorus
Div 4.3 (RFW) Sodium
Note: Some are self- reactive

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CLASS 5: OXIDIZING SUBSTANCES & ORGANIC PEROXIDE
Div 5.1: Oxidizing substances ( ROX)
The catastrophic explosion at Beirut port on
Tuesday evening (August 4) caused by over
2,700 tonnes of ammonium nitrate kept in
storage for over six years.
Ammonium nitrate, the substance
In its pure form, ammonium nitrate (NH4NO3) is a
white, crystalline chemical which is soluble in
water. It is the main ingredient in the manufacture
of commercial explosives used in mining and
construction.
At least 135 people are dead and 5,000 are
wounded.
DGR CAT 6
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FIATA Diploma in International Freight Management © Copyright 2019 Vietnam Logistics
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Div 5.2: Organic peroxide (ROP)

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Div 6.1 Toxic ( RPX)
Liquids or solids,
which are
Dangerous if
inhaled, swallowed
or absorbed
through the skin.
Ex: Arsenic,
nicotine, cyanide,
pesticides.

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DGR-Table 3.6A
Division 6.1 Packing Group Criteria
Inhalation Toxicity
Packing Oral Toxicity LD50 Dermal Toxicity
Group
by dust & mists
(mg/kg) LD50 (mg/kg)
LC50 (mg/l)
I ≤ 5.0 ≤ 50 ≤ 0.2
II > 5.0 but ≤ 50 > 50 but ≤ 200 > 0.2 but ≤ 2.0
III
Module 12– Dangerous Goods > 50 but ≤ 300
> 200 but ≤ 1000
DGR CAT 6
> 2.0 but ≤ 4.0 49
49 Research
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Division 6.2: Infectious substances (RIS)

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Div 6.2 INFECTIOUS SUBSTANCES

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Class 7 RADIOACTIVE MATERIAL has no divisions

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Class 8: CORROSIVE

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DGR-Table 3.8A
Class 8 Packing Group Assignment
Packing Corrosion rate on

Exposure Time Observation Time
Group steel/ aluminium
I ≤ 3min ≤ 60 min -
II > 3min ≤ 60min ≤ 14d -
> 6.25 mm a year at a

III
> 60min ≤ 4h ≤ 14d
DGR CAT 6
test temperature of 54
54 Research
550C
FIATA Diploma in International Freight Management © Copyright 2019 Vietnam Logistics
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Class 9 MISCELLANEOUS (RMD)
Polymeric beads (RSB) Carbon dioxide (ICE) Magnetized material (RMG)

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Packing Group – PG indicates the level of danger

Packing Group I – High danger
Packing Group II – Medium danger
Packing group III – Low danger
Packing groups do not apply to Classes 1. 2. 7
Module 12– Dangerous Goods DGR CAT 6 56 56

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Exercise on classification Characteristics of Class/

IMP code
the articles div
RFL (ref
1 Liquid with a flash point of 55oC
B2.2.4)
2 Solid substances, which can cause fire through friction
3 Substance which is infectious to human or animals
4 Substances which yields oxygen
Liquid, when in contact with the skin, causes full thickness
5
destruction of skin.
6 Pyrotechnic substance which present no significant hazards.
Solid substance giving off a flammable gas when in contact
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with water.
8 Substance which is toxic to human is very small quantities.
9 Aerosol dispenser (no further hazards).

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2.2.6 IDENTIFICATION
IDENTIFICATION OF DANGEROUS GOODS
There are two primary tools that can be used to help identify the presence of
dangerous goods:
- Marking on the packaging of the proper shipping name, the class number or
numbers and/or a unique four-digit United Nations number (e.g. Gasoline,
Class 3, UN 1203).
Proper Shipping Name ( PSN)  4.2 DGR ( LIST OF DG)  UN number
UN NUMBER  4.3 DGR  PAGE NUMBER  PSN

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The following components
of the PSN have been ignored:
numerals Ex: 2-
Bromopentane
the single letters a-,b-, N-,…
Ex: N- Butylaniline, n-
Butylamine
the prefix alpha-, beta-, meta-
Ex: 5-tert- Butyl-2,4,6-
trinitro-m-xylene
the term n.o.s,
ex Alcohols, n.o.s
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4.3 DGR

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REVIEW
CLASS/
CHARACTERISTICS CLASS/ DIVNAME
DIV NR
1 EXPOSURE TIME
2 LD50 and/ or LC50
3. TRANSPORT INDEX
4. INITIAL BOILING POINT
LIST ALL CLASSES HAS NO

5.
DIV
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2.2.6 PACKING REQUIREMENTS
- Packaging manufactures: must apply design and 1. Requirements

testing requirements on packaging of
- Shipper/ consignee: make sure of proper package dangerous goods is
and marks for transport one of the most
- Freight forwarder and carrier: verify that correct important
packaging is used preventive safety
- The cargo agent or the operator’s DG staff must measures within the
ensure that the shipper has used the appropriate regulations for safety
packing instructions and packaging. transport of DG
-Package
2. Packing is
-Packaging
-Packing
shipper’s
- Overpack
responsibilities 64
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- Requirements on packaging
- Types of packing
- Construction and testing of Packaging
- UN test and test report
- UN packaging mark
- Sub-paragraph 5.0.1.2
- Any external contamination on
packagings must be removed prior to
packages being placed in transport

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General requirements (5.0.2)

1. Packing group
2. Packaging quality
3. Packaging test requirements
4. Material
5. Ullage
6. Internal pressure standards
7. Minimum size

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When packing the article(s) or

substances, the shipper has to
ensure that:
– DGR 5.0.2 are met;
– PPR are applied;
- Column H,J , L
– The quantity limit of inner
packaging
– More restrictive packing group is
required
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A PACKAGE
Inner packaging
Outer
packaging

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Single packaging
Combination packaging

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UN specification
Packaging

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LIMITED QUANTITY (DGR 2.7)
– Single packaging are not permitted.

– Packing group I is not permitted.
– The gross weight of limited quantity not
exceed 30 kgs
– Note any special provisions which may
apply to the packing of item
– Note to the maximum net quantity or
maximum gross mass for each package;

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Packing Instruction Y 340
Inner Packaging Net qty per inner Packaging Total net quantity per package
Glass 0.5 L 0.5 L

Metal 0.5 L
Plastic 0.5 L
Type Drums Jerrican Boxes
Des. Steel Aluminu Ply- Fibre Plastic Other Steel Alumin Plastic Steel Aluminu wood Ply fibrebo
m wood metal um m wood ard

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Glass 1.0L
Metal 1.0L
1.0 L
Plastic 1.0 L

Des. Steel Aluminum Ply-wood Fibre Plastic Other metal Steel Aluminum Plastic Steel Aluminum wood Ply wood Fibre
board
Spec. 1A2 1B2 1D 1G 1H2 1N2 3A2 3B2 3H2 4A 4B 4C1 4D 4G

4C2

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Packing Instruction 363
Glass 2.5 L
Metal 5.0L
5.0 L
Plastic 2.5 L

Des. Steel Aluminu Ply- Fibre Plastic Other Steel Alumin Plastic Steel Aluminu wood Ply Fibre
m wood metal um m wood board
Spec. 1A2 1B2 1D

Module 12– Dangerous Goods 1G 1H2 1N2 3A2 3B2 3H2 4A 4B 4C1 4D 4G 75
4C2 and Development Institute
75

Packing Instruction 363 (Cont’d)

Fibre
Des. Steel Alumin Ply- Fibre Plasti Other Steel Alumi Plastic Steel Alumin wood Ply board
um wood c metal num um wood
Spec. 1A2 1B2 1D 1G 1H2 1N2 3A2 3B2 3H2 4A 4B 4C1 4D 4G
4C2
Type Drums Jerrican composite cylinder

Des. Steel Aluminum Plastic Other Steel Aluminu Plastic Plastic
metal m
Spec. 1A1 1B1 1H1 1N1 3A1 3B1 3H1 All As permitted in
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FIATA Diploma in International Freight Management 5.0.6.6
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EXERCISE
1. What is the Proper Shipping Name (PSN) for UN 1104?

2. What is the UN number for Anisole?

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What is the UN number for n- Amylene?

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EXERCISE
1. What PI are used for AMYLAMINE on passenger aircraft?
2. What PI are used for AMYLAMINE on CAO- Cargo aircraft Only?
3. What is the maximum net quantity per package on passenger aircraft for
AMYLAMINE?

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2.2.7 MARKING AND LABELING
The purpose of marking & labeling :

- Indicate the contents;
- Indicate that the packaging
- Provide safe handling and stowage information;
- Indicate the nature of hazard(s)
The cargo agent, freight forwarder and operators’ acceptance staff must check
and make sure the corrections

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IDENTIFICATION OF DG SHIPMENT
There are two primary tools that can be used to help identify the presence of
dangerous goods:
 Marking on the packaging of the proper shipping name, the class number
or numbers and/or a unique four-digit United Nations number (e.g.
Gasoline, Class 3, UN 1203).
 Labels designed to correspond to the classes and divisions of dangerous
goods. (See Attachment B.)

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2.2.7.1 MARKING
THE SHIPPER MUST:

– Check that the required marking in correct locations ; meet the quality
and specification requirements of the regulations
– Ensure the specification markings are as specified.
– Remove or obliterate any irrelevant marking
– Ensure all required marking have been applied when presenting to the
operator

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2.2.7.1 MARKING (DGR 7.1)

TYPES OF MARKING
SPECIFICATION PACKAGING MARKING
UN
specification
Packaging

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2.2.7. 1 MARKING

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2.2.7.1 MARKING

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2.2.7. 1 MARKING

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2.2.7. 1 MARKING
LIMITED
QUANTITY
PCKG

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2.2.7. 1 MARKING
TYPES OF MARKING
GENERAL MARKING
1. UN number
2. Proper Shipping Name
3. Full name and address of
SHIPPER and CONSIGNEE
4. Net quantity in each package

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2.2.7. 1 MARKING
 Class 2: “Do not drop- handle

with care”
 UN 3373: “BIOLOGICAL
SUBSTANCE, CATEGORY B”
 UN 3077, UN 3082:
Environmentally hazardous
substance mark

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2.2.7. 1 MARKING

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2.2.7. 1
MARKING
An overpack is an enclosure
used by a single shipper to
contain one or more packages
and to form one handling unit for
convenience of handling and
stowage.
Dangerous goods packages
contained in the overpack must
be properly packed, marked,
labelled and in proper condition
as required by the Regulations..

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2.2.7. 1 MARKING
OVERPACK
 An identification mark is required on

each overpack when the
consignment contains two or more
overpacks
 Where an overpack contains of

more than one UN number, the total
quantity of DG should be shown by
the UN number.

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2.2.7.1 MARKING FOR OVERPACK
In case all markings required by

7.1.5.1 for all DG in the overpack are
not clearly visible, the overpack
must be marked with:
 The word “overpack”
 Required marking of 7.1.5.1
 Handling instructions

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2. 2. 7. 2 LABELLING
(DGR 7.2)
The operator is responsible only for

replacing labels which become detached
or unidentifiable during transport
 The shipper is responsible for labeling
a package or overpack containing
dangerous goods (DGR 7.2.1)
 There are 2 types of labels :
Hazard labels & Handling labels

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(DGR 7.2)
HAZARD LABELS Required for

most of the DG in all classes
 Some articles and
substances required subsidiary
risk label as well as primary
hazard label

97
(DGR 7.2)
Handling Labels
The labels in
various
rectangular
shapes give
information
relating to
handling and
stowage of DG
Cryogenic Lithium battery Label
Environmental
Hazardous mark

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(DGR 7.2)

99
2.2.6. MARKING & LABELLING

(DGR 7)

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MARKING & LABELLING

101

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EXCEPTED QUANTITY PACKAGE

103
Revision
What markings and labels are required for

1. Methanol, PI 352
2. Methanol PI Y341
3. UN 1237, PI 364
c. Is UN 1239 accepted on CAO?
d. What is the proper shipping name of UN 1336?

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2.2.8 DOCUMENTATION
1. SHIPPER’S DANGEROUS GOODS DECLARATION

105
DGR
2.2.8 DOCUMENTATION
AIR WAYBILL

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2.2.8 DOCUMENTATION
AIR WAYBILL

107
DGR
2.2.8 DOCUMENTATION
AIR WAYBILL

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DGR
2.2.8 DOCUMENTATION
AIR WAYBILL

109
DGR
2.2.8 DOCUMENTATION
If a Shipper’s Declaration is not required for dangerous goods, the Nature and
Quantity of Goods box of the Air Waybill MUST show the following Information.
UN Number Or ID Number (Not Required for Magnetized Material)
Proper Shipping Name
Number of Packages (unless these are the only packages within the consignment)
Net Quantity Per Package (Only Required for UN1845 Carbon Dioxide Solid)

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2.3 THE IMDG CODE

111
2.3 THE IMDG CODE
2.3.1 INTRODUCTION
This provides a brief overview of the provisions for shipping dangerous
goods by sea, as contained in the International Maritime Dangerous
Goods (IMDG) Code.
The IMDG Code, 2018 Edition (inc. Amendment 39-18) comes into
force on 1 January 2020 for two years and may be applied voluntarily
as from 1 January 2019.

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2.3 IMDG CODE
2.3.1 INTRODUCTION
The International Maritime Organization (IMO)
- The IMDG Code is produced by the International Maritime Organization
(IMO)
- These are published in the UN ‘Recommendations on the Transport of
Dangerous Goods’, known as the ‘Model Regulations’ because the document
provides a framework of rules for the safe transport of dangerous goods by all
modes – air, road and rail as well as sea.

113
2.3 IMDG CODE
2.3.1 INTRODUCTION
The International Maritime Organization (IMO)
The IMO is a United Nations specialised agency which has developed
international legislation dealing with two key issues for the maritime
industry:
− The safety of life at sea
− Prevention of pollution from ships
- The key objectives are to:
facilitate the free movement of dangerous goods

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2.3 IMDG CODE
2.3.1 INTRODUCTION
The IMO has developed two international conventions to address these issues:
− The SOLAS Convention (covering safety of life at sea)
− The MARPOL Convention (covering pollution prevention)
− The IMDG code contains detailed technical specifications to enable dangerous
goods to be transported safely by sea.
− The IMDG Code became mandatory for adoption by SOLAS signatory states
from 1st January 2004.

115
2.3 IMDG CODE

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2.3 IMDG CODE
The supplement contains the following texts related to

the Code:
- Emergency Response Procedures for Ships Carrying
Dangerous Goods
- Medical First Aid Guide
- Reporting Procedures
- IMO/ILO/ECE Guidelines for Packing Cargo Transport
Units
- Safe Use of Pesticides in Ships, Cargo Holds and CTUs
(Cargo Transport Units)
- International Code for the Carriage of Packaged
Module 12– Dangerous Goods Irradiated Nuclear Fuel, Plutonium and High-Level 117
Radioactive Wastes on Board Ships and Development Institute
117
2.3 IMDG CODE
2.3.2 APPLICATION OF THE IMDG CODE

The IMDG Code amplifies the relevant safety and pollution prevention
provisions of these Conventions.
Most of the requirements in the IMDG Code apply on a mandatory basis but
there are a few provisions which are recommendatory.
The IMDG Code is applied automatically by the governments of all the States
which are members of SOLAS, and has a worldwide application to the
movement of dangerous goods by sea.
While some SOLAS Member Governments incorporate the requirements of the
IMDG Code without amendment into their national legislation, others apply
some different and/or additional (usually more stringent) national requirements.

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2.3 IMDG CODE
2.3.2 APPLICATION OF THE IMDG CODE

− The IMDG Code is updated every two years to take account of:
− New dangerous goods.
− New technology and methods of working
− Safety concerns which arise as a result of experience.
−Each version of the Code is given an Amendment number to signify
how many times it has been updated. This number appears at the
bottom of each page together with the year of the Amendment.

119
2.3 IMDG CODE
2.3.2 APPLICABLE OF THE IMDG CODE

The IMDG Code is based on an internationally agreed system:
− classification.
− Packaging.
− hazard warning labels and other identifying marks
− standard documentation.
− Segregation.
− ensure safe transport.
− emergency response advice for dangerous goods involved in a fire or
spillage on board ship.

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2.3 IMDG CODE

2.3.3 TRAINING REQUIREMENT
− In the 2002 edition of the IMDG Code, training was introduced for the
first time.
− The IMO Member Governments recognised that the safe transport of
dangerous goods by sea is dependent upon the appreciation, by all persons
involved, of the risks involved and on a detailed understanding of the IMDG
Code requirements.
− The training requirements became mandatory with Amendment 34-08.

121
2.3 IMDG CODE

2.3.3 TRAINING REQUIREMENT
These training requirements highlight the need for all shore-based personnel involved in the
shipment of dangerous goods to receive training commensurate with their
responsibilities. The IMDG Code defines shore-based personnel as those who:
1. Classify dangerous goods and identify 7. Accept dangerous goods for transport
PSNs 8. Handle dangerous goods in transport
2. Pack dangerous goods 9. Prepare dangerous goods loading/stowage plans
3. Mark, label or placard dangerous goods 10. Load/unload dangerous goods into/ from ships
4. Load/ unload CTUs (Cgo Transport Unit) 11.Carry dangerous goods in transport
5. Prepare transport documents for 12.Enforce, survey or inspect for compliance with
dangerous goods applicable rules and regulations
6. Offer dangerous goods for transport

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2.3 IMDG CODE
2.3.4 IMDG CODE REQUIREMENT

− The IMDG Code requires certain provisions to be followed whenever dangerous
goods are shipped by sea.
− These provisions require that dangerous goods are correctly and safely:
− Classified and identified
− Packed
− Marked, labelled and placarded
− Documented
− Stowed on board the vessel
− Segregated from other goods with which they may react dangerously
− Appropriate emergency response
123
2.3.5 IMDG CODE CLASSIFICATION SYSTEM
There are 3 types of shippers and 3 types of dangerous goods
SHIPPER DANGEROUS GOODS

Compliant with IMDG Code  Compliant to the code
Ignorant, lesser compliant hence  Misdeclared dangerous
may offer some goods as non- goods
dangerous or mis-declared  Undeclared dangerous goods
Fraudulent Willfully falsify
information and offer dangerous
goods as non-dangerous

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2.3 IMDG CODE
2.3.5 IMDG CODE CLASSIFICATION SYSTEM
The purpose of the IMDG Code’s classification system is:

- To distinguish
- To identify the dangers
- To ensure that these goods to be transported safely without risk to
persons or property.
The International Maritime Dangerous Goods (IMDG) Code relates to the
safe carriage of dangerous goods by sea,

125
2.3 IMDG CODE
2.3.5
IMDG
CODE
CLAS
SIFIC
ATIO
N
SYST
EM

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2.3 6 IDENTIFICATION- DANGEROUS GOODS LIST
UN No. Proper Shipping Name Class or Subsidiary risk(s) Packing group Special Limited quantities Packing IBC
division provision
Instructions Provisions Instructions Provisions
(1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11)
AMMONIUM PICRATE dry or wetted with less than

0004 1.1D 0 - - None P112 (a), (b) or (c ) PP26 - -
10% water, by mass
CARTRIDGES FOR WEAPONS with

0005 1.1F - - - None P130 - - -
bursting charge
CARTRIDGES FOR WEAPONS with

0006 1.1E - - - None P130 LP101 PP67L1 - -
bursting charge
0007 CARTRIDGES FOR WEAPONS with bursting charge 1.2F - - - None P130 - - -
AMMUNITION, INCENDIARY with or without burster,

0009 1.2G - - - None P130 LP101 PP67L1 - -
expelling charge or propelling charge
AMMUNITION, INCENDIARY with or without burster,

0010 1.3G - - - None P130 LP101 PP67L1 - -
expelling Module
charge 12–
or propelling charge
Dangerous Goods 127
127
IMDG CODE

Portable tanks and bulk containers
IMO tank UN Provisions EMS Stowage and segregation Properties and observations UN
instructions tank instructions No.
(12) (13) (14) (15) (16) (17) (18)

Category 10. "Away from"
explosives containing
- - - F-B, S-Y chlorates or perchlorates. Substance. 0004
"Away from" lead and its
compounds.
See glossary of terms in appendix B for "CARTRIDGES FOR

- - - F-B, S-X Category 08 0005
WEAPONS with bursting charge (1 )".

- - - F-B, S-X Category 03 0006
WEAPONS with bursting charge (2)".

- - - F-B, S-X Category 08 0007
WEAPONS with bursting charge (1 )".
See glossary of terms in appendix B for "AMMUNITION,

- - - F-B, S-X Category 03 INCENDIARY with or without burster, expelling charge or propelling 0009
charge".
See glossary of terms in appendix B for "AMMUNITION,

128
- - Module 12– Dangerous Goods
- F-B, S-X Category 03 IINCENDIARY with or without burster, expelling charge or 0010
propelling charge".
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UN Proper Shipping Name Class Subsidiar Packing Special Limited Packing IBC Portable tanks and bulk containers
No. or y risk(s) group provisio quantities Instructions Provisions Instruction Provisio EMS Stowage and segregation Properties and observations UN
divisio n s ns IMO UN Provision No.
n tank tank s
instructions instructions
(1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11)
(12) (13) (14) (15) (16) (17) (18)
AMMONIUM PICRATE dry or Category 10. "Away from"
P112 (a), (b) explosives containing
0004 wetted with less than 10% 1.1D 0 - - None PP26 - -
or (c ) - - - F-B, S-Y chlorates or perchlorates. Substance. 0004
water, by mass
"Away from" lead and its
compounds.
CARTRIDGES FOR
0005 WEAPONS with 1.1F - - - None P130 - - - See glossary of terms in appendix
bursting charge B for "CARTRIDGES FOR
- - - F-B, S-X Category 08 0005
WEAPONS with bursting charge
CARTRIDGES FOR (1 )".
0006 WEAPONS with 1.1E - - - None P130 LP101 PP67L1 - - See glossary of terms in appendix
bursting charge B for "CARTRIDGES FOR
- - - F-B, S-X Category 03 0006
CARTRIDGES FOR (2)".
0007 WEAPONS with bursting 1.2F - - - None P130 - - -
See glossary of terms in appendix
charge
B for "CARTRIDGES FOR
- - - F-B, S-X Category 08 0007
AMMUNITION, INCENDIARY (1 )".
with or without burster, See glossary of terms in appendix
0009 1.2G - - - None P130 LP101 PP67L1 - -
expelling charge or propelling B for "AMMUNITION,
charge - - - F-B, S-X Category 03 INCENDIARY with or without 0009
burster, expelling charge or
propelling charge".
AMMUNITION, INCENDIARY See glossary of terms in appendix
with or without burster, B for "AMMUNITION,
0010 1.3G - - - None P130 LP101 PP67L1 - - 129
expelling charge or propellingModule 12– Dangerous Goods - - - F-B, S-X Category 03 IINCENDIARY with or without 0010
charge FIATA Diploma in International Freight Management © Copyright 2019 Vietnam
burster, expelling Logistics
charge or Research
propelling charge".
129
2.3 .7 MARKING AND LABELING

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2.3 .7 MARKING AND LABELING

131
2.3.8 DOCUMENTATION

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2.4 ADR
THE INTERNATIONAL CARRIAGE OF
DANGEROUS GOODS BY ROAD

133
STATISTIC EXAMPLES OF DG TRANSPORT BY ROAD
Source: Thailand - 2017 Source: EU - 2017

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ACCIDENTS WITH DG TRANSPORT BY ROAD
Source: Internet
135
2.4 ADR
THE EUROPEAN AGREEMENT CONCERNING
THE INTERNATIONAL CARRIAGE OF DG BY ROAD
2. 4.1 Introduction of ADR

2. 4.2 Identification
2. 4.3 Plates/ Placarding of vehicles/
2. 4.4 Handling Procedures
2. 4.5 Training

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ADR
2.4.1 INTRODUCTION
− The European Agreement concerning the International Carriage of

Dangerous Goods by Road (ADR) was done at Geneva on 30 September
1957
− it entered into force on 29 January 1968.
− The Agreement itself was amended by the Protocol amending article
14 (3) done at New York on 21 August 1975, which entered into force on
19 April 1985.

137
ADR
2.4.1 INTRODUCTION
The Agreement itself is short and simple.

− Other dangerous goods may be carried internationally in road vehicles
subject to compliance with:
− The conditions laid down in Annex A for the goods in question, their
packaging and labelling; and
− The conditions laid down in Annex B for the construction, equipment and
operation of the vehicle carrying the goods in question.

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ADR
2.4.1 INTRODUCTION
− Annexes A and B have been regularly amended and updated since

the entry into force of ADR. Consequently to the amendments for
entry into force on 1 January 2011, a revised consolidated version
has been published as document ECE/TRANS/215, Vol. I and II

139
ADR
2.4.1 INTRODUCTION
2.4.1 INTRODUCTION
Annex A includes the following chapters.
Part 1. Introduction
Part 2. Classification
Part 3. The dangerous goods list (including special provisions and
exemptions related to limited quantities.
Part 4. Packing and tank provisions
Part 5. Consignment procedures, including documentation and
vehicle marking
Part 6. Construction and testing of packagings, intermediate bulk
containers (IBC), large packagings and tanks
Part 7. Carriage, loading, unloading and handling

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ADR
2.4.1 INTRODUCTION
2.4.1 INTRODUCTION
Annex B: Provisions concerning transport equipment and
transport operations
Part 8
Requirements for vehicle crews, equipment, operation and
documentation
Part 9
Requirements concerning the construction and approval of vehicles

141
ADR
2.4.2 SAFETY OBLIGATIONS OF THE PERSONS INVOLVED
The carrier holding license to operate
Article Description
Use a vehicle with the equipment and accessories and components as prescribed by
1 relevant regulations
Provide necessary equipment, tools, and appliances used to prevent hazards, the
2 equipment and tools have to be in accordance with the Notification announced by the
Director General.
Provide transport documents as prescribed by the Director General and the documents
3 must be carried in the driver’s cab of the vehicle throughout the transport
To affix the danger placard and mark on the vehicle carrying dangerous as prescribed by
4 relevant notification

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ADR
The carrier holding license to operate
Article Description
Check receptacles in accordance with relevant legal standards and passed the
5 periodic inspections*
Check if the receptacles affixed by relevant labels and marks to display the hazards of
6 the dangerous goods
Ensure that the loading, unloading, lashing, handling, stowing, and carriage of
dangerous goods are in line with the required notification issued by the Director
7
General

143
ADR
2.4.2 SAFETY OBLIGATIONS OF THE PERSONS
INVOLVED
Article Description
Not giving or permitting the following persons to perform driving duties:

(A) A person who does not have a driving license type 4 or is suspended or the license
is revoked or expired.
(B) A person who does not hold the driver training certificate according to the
8 curriculum prescribed by the Director General.
(C) A driver who performs driving exceeding driving prescribed by regulations.
(D) A driver who is incapable of driving.

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Article Description
Must not load exceeding maximum permissible weight prescribed by relevant

9. regulations
Control the driver at a speed not exceeding the speed limit prescribed by law
10.
Prepare and report information on dangerous goods transported. Or other reports as

11. prescribed by the Director General
Control the driver to comply with the safety requirements for the Safety in Transport of
Dangerous Goods by Road under (2), (3), (4), (6), and (7)
12.

145
ADR

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ADR
2.4.4 INTERNATIONAL KEMLER CODE

147
ADR
2.4.4 INTERNATIONAL KEMLER CODE
22 refrigerated liquefied gas, asphyxiant 462 toxic solid which reacts with water, emitting flammable gases
323 flammable liquid which reacts with water, emitting flammable gases X462 solid, which reacts dangerously with water, emitting toxic gases
X323 flammable liquid which reacts dangerously with water, emitting flammable gases
482 corrosive solid, which reacts with water, emitting flammable gases
333 spontaneously combustible liquid X482 solid, which reacts dangerously with water, emitting corrosive
X333 spontaneously combustible liquid which reacts dangerously with water gases
362 flammable liquid, toxic, which reacts with water, emitting flammable gases 539 flammable organic peroxide
X362 flammable liquid toxic, which reacts with water, emitting flammable gases
606 infectious substances
382 flammable liquid, corrosive, which reacts with water, emitting flammable gases
623 toxic liquid, which reacts with water, emitting flammable gases
X382 flammable liquid, corrosive, reacts with water, emitting flammable gases 642 toxic solid, which reacts with water, emitting flammable gases
423 solid which reacts with water, emitting flammable gases 823 corrosive liquid which reacts with water, emitting flammable gases
X423 flammable solid which reacts dangerously with water, emitting flammable gases
842 corrosive solid which reacts with water, emitting flammable gases
44 flammable solid, in the molten state at an elevated temperature 90 environmentally hazardous substance; miscellaneous dangerous
446 flammable solid, toxic, in the molten state, at an elevated temperature substances

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ADR
2.4.5 LABELS AND PLACARD

149
ADR

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ADR

151
3.3 ADR
VEHICLE MARKING AND METHOD OF PACKAGING (HANDLING,
STOWING, AND LASHING)

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153
Placarding

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ADR

155
ADR

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ADR

PLACARDS 157
157
IMPLEMENTATION OF ADR IN ONE PAGE

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GHS uses 9 red diamond-shaped pictograms to represent

various kinds of chemical hazards

159
• Size
• Many countries have set GHS label requirements on sizes for chemical packages
with different packaging capacities. Some countries have even set additional
requirements on GHS label pictogram size and even font size.
• Under TDG regulations, there are also requirements on the minimum dimension of
hazard labels. (i.e, 100mm x100mm for >25kg packages). This size is usually much
bigger than the size of a GHS pictogram.
• Where to Place GHS Labels and Dangerous Goods Labels
• Dangerous labels are usually placed on the outer packagings. A hazardous chemical
product may be packaged in multi-layer packages in which case inner packages
need to be labelled according to GHS while the outer packaging shall meet the
labelling provisions of TDG. Outer packages may also be labelled according to GHS
(This is mandatory for single packagings such as drum).

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161
2.5 REGULATIONS CONCERNING THE INTERNATIONAL

CARRIAGE OF DANGEROUS GOODS BY RAIL (RID)

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2.5 REGULATIONS CONCERNING THE INTERNATIONAL

CARRIAGE OF DANGEROUS GOODS BY RAIL (RID

163
2.5.1 RID
RID consists of 7 parts
1. General provisions 5. Consignment

procedures
2. Classification
6. Requirements for the
3. Dangerous goods construction and testing
list, special of packing, intermediate
provisions and bulk container (IBCs),
exemptions related large packaging, tanks,
bulk containers
to DG packed in
limited quantities 7. Provisions
concerning the
4. Packing and tank conditions of carriage of
provisions loading, unloading and
handling
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2.6 INLAND WATERWAY TRANSPORT

ADN
Objective
The learner should understand what the

European agreement governing
dangerous goods in Inland waterway
transport is, its effective status and its
application in general

165
2.6 ADN
- The
ECE Inland Transport Committee produces the European Provisions
Concerning the International Carriage of Dangerous Goods by Inland
Waterway (ADN) and the Central Rhine Commission produces the
Regulations for the Carriage of Dangerous Substances on the Rhine
(ADNR).
- The ADN entered force in 2001. The European Commission has proposed an
ADN framework Directive to enter force after AND was adopted. It is unlikely
that this will apply to UK waterways as we have no waterways carrying
commercial traffic linked to the inland waterway networks of another member
state.

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ADN STRUCTURE
2.6.1 ADN CONSTRUCTIONS

: consists of main legal text and regulations annexed thereto contains 9 parts
Part 1-7 is in line with the UN regulations:
- Part 1: General provisions
- Part 2: Classification
- Part 3: The dangerous goods list, special provisions and exemptions related
to Dangerous goods packed and limited quantities.

167
ADN STRUCTURE
– Part 4: Packing and tank provisions
– Part 5: Consignment procedures
– Part 6: Requirements for the Construction and testing of packagings, intermediate bulk
containers (IBC), large packagings, tanks and bulkcontainers
– Part 7: Provision concerning the Conditions of carriage, loading, unloading and handling
Part 8 and 9 contain specifics provisions affecting transport by inland waterway only
(ADN)
– Part 8. Requirement for crews, equipment, operation and documentation
– Part 9. Requirement concerning the construction and approval of ships

168
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Inland waterway
in the Rhine River
Continent Europe
Countries it flows Switzerland, Principality of

through or borders Liechtenstein, Austria, Germany,
France and the Netherlands
Length 1,232 km (766 mi)
Number of tributaries 2
Source Swiss Alps
Mouth Rotterdam into the North Sea

169
CHAPTER 3
HANDLING DANGEROUS GOODS

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CHAPTER 3
3.1 ACCEPTANCE:
using checklist top be sure the package / containers are properly packed,
marked and labelled

171
CHAPTER 3
3.2 EMERGENCY RESPONSE
 Emergency procedures must be available wherever DG are handled.
 ICAO Annex 14- Aerodromes, chapter 9- Emergency and other
services, requires that procedures must be established by the airport
authorities to deal with emergencies involving dangerous goods.
 . Emergency response training is required for all categories of
personnel as specified in table 1.5. A and 1.5.B
 4. It is important that the student is familiar with local requirements and
is aware of all emergency contacts.

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CHAPTER 3
3.2.1 PROCEDURES FOR GROUND STAFF
Airport authorities and operators must have

established emergency procedures that incorporate
provisions for the handling of spills of dangerous goods or other
unidentified substances.
The general emergency procedures to be followed comprise the following
 Advise immediate supervisor first.
 Identify the substances involved by reference the documentation
(DGD) or package markings
 Isolate the package by removing the other packages or property.
 Isolate the area and advise emergency services as per local
procedures.
173
CHAPTER 3
3.2.1 PROCEDURES FOR GROUND STAFF
 Avoid contact with the content of package.
 If content come in contact with body or clothes:
thoroughly wash off body with plenty of water;
remove the contaminated clothes;
do not eat or smoke;
keep hands away from eyes, mouth and nose;
apply for medical assistance.
 Staff involved in such incidents should stay on the site
until their names are noted.

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CHAPTER 3
3.2.2 CONTAMINATED CARGO OR BAGGAGE HANDLING
1. If baggage or cargo not identified as containing dangerous goods has

been contaminated and it is suspected that dangerous goods may be
the cause of the contamination, the operator must take reasonable
steps to identify the nature and source of contamination before
proceeding with the loading of the contamination baggage or cargo.
2. . If the contaminating substance is found or suspected to be a
substance classified as dangerous goods by the regulations, the
operator must isolate the baggage or cargo and take the appropriate
steps to nullify any identified hazard before the baggage or cargo is
transported further by air.
175
CHAPTER 3
3.3 REPORT
 Serious incidents and accidents
 Undeclared and Mis- declared dangerous goods must be reported
without delay to the appropriate authorities of the State of operator
or of the State where this occurred. emergency services.

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Immediate
3.4 DANGEROUS GOOD action
Hazard Emergency Response Charts Minimize
Dangerous goods
class/ div Hazard description leakage &
class
contact with
other cargo.
Fire and minor blast hazard
1.3 C
and/ or minor propulsive
1.3 G
hazard
1.4B Explosives (accept on
1.4C Cargo aircraft only) Notify deparment
Fire but no other significant
1.4D Guard against fire
hazards
1.4E
1.4G
1.4 S Explosive (safety)

Small fire hazard 177
177
Hazar Immediate action

d 3.4 DANGEROUS GOOD Minimize leakage
class/
div
Emergency
Dangerous goods Response
class Hazard Charts
description & contact with
other cargo.
2.1 Flammable gas Ignite when leaking -Notify deparment
2.2 Non- flammable gas High pressure cyclinder busting Guard against fire
Cryogenic liquid Sub -cooling - Evacuate goods-
2.2 ventilate area
Toxic gas (acceptable on High pressure cyclinder busting -Keep away ≥ 25 m
2.3 CAO only ) and toxic inhalation
3 Flammable liquid Give off flammable vapour - Notify department

4.1 Flammable solid Combustible contribute to fire Guard against fire
4.2 Spontaneously Ignite in contact with air Do NOT use water
combustible under any
4.3 Dangerous when wet Ignite in contact with water circumstances
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3.4 DG EMERGENCY RESPONSE CHART

Hazard Immediate action
class/ Dangerous goods Hazard description
Minimize leakage &
div class contact with other
cargo.
Ignites combustible on contact Notify deparment
5.1 Oxidizer
React violently with other Guard against fire
5.2 Organic peroxide
substance Do NOT use water
Harmful if swallowed, inhaled Isolate area
6.1 Toxic substances
or in contact with skin Obtain qualified
Causes disease in human and assistance
6.2 Infectious subs.
animals Do NOT touch
7- cat 1 Radioactive- white Radiation hazards and harm Keep away minimum 25
179
Radiaoactive - ful to health m

7- cat 2 yellow
179 Hazardous to skin and metal -Notify deparment
3.4 DG EMERGENCY RESPONSE CHART

Immediate action
Hazard
Minimize leakage &
class/ Dangerous goods
Hazard description contact with other
div class
cargo.
 Polimeric beads Evolves small quantities of

 Magnetized flammable gas Avoid contact with skin
material Affect the navigation system
 Carbon dioxide
solid (Dry ice) Causes sub-cooling/ suffocation No
180 immediate action
9
Miscellaneous required
dangerous goods
Hazard not cover by other class 180
180
90
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CHAPTER 3
3.5 ACCIDENT PREVENTION
1 Obey all safety rules and regulations
2 No smoking
3 Do not eat or drink when handling DG
4 Take particular care when handling DG
5 Check DG is storage
6 Keep the DG information system up to date

181
CHAPTER 3
EMERGENCY PLAN
1. Initial response system

2 Lines of responsibility and command
3 Emergency equipment
4 Liaison with local emergency services
5 Action specification
6 Reporting system
7 Publication and distribution of plan
182
91
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CHAPTER 3
DEALING WITH EMERGENCIES

1 Accident prevention
2 emergency plan
3 Procedure practice
4 Equipment checking
5 Following the plan
6 Reporting system

183
5L 2kg 20kg UN 2940 in 5L UN 1719,

UN 2285 on pax UN 0278 on single pkg PGIII in combi
Packagings acft CAO pkg
Not permitted Not permitted Not permitted Not permitted
Not permitted acceptable Not permitted

Not permitted
Not permitted Not permitted Acceptable Not permitted
acceptable Not permitted Not permitted acceptable
acceptable acceptable acceptable acceptable

184
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EMERGENCY RESPONSE GUIDE 2016/ 2020

185
Chapter 4
LOCAL REGULATIONS

186
93
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CHAPTER 4 DANGEROUS GOODS

TRANSPORT REGULATIONS IN VIETNAM
Learning Objective
- After learning this part, the learner are able to:
- Understand classifications of dangerous goods
transported by road/rail
- Identify dangerous goods by labels and placards
- Understand training requirements for all those who
relating to transporting dangerous goods by road/rail

187
DANGEROUS GOODS TRANSPORT

REGULATIONS IN VIETNAM
 List of Dangerous Goods
 Dangerous Goods Regulations in Vietnam
 Some of Degree/Circular

188
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4. LOCAL REGULATIONS
• Requirements for transportation service provider
• Assign responsible person to accompany during transport
• Obtain knowledge of characteristics of chemicals which are being transported e.g
chemical class, UN number…
• Obtain safe handling procedures: loading/unloading, incident reporting, first aid,
emergency response, emergency contacts, response and recovery measures…

189
104/2009/NĐ-CP
updated by Decree 42/2020/ND-CP
Chương V
GIẤY PHÉP VẬN CHUYỂN HÀNG NGUY HIỂM
Điều 18. Thẩm quyền cấp Giấy phép vận chuyển hàng nguy hiểm
1. Bộ Công an cấp Giấy phép vận chuyển hàng nguy hiểm loại 1, loại 2, loại 3,
loại 4 và loại 9 quy định tại khoản 1 Điều 4 Nghị định này.
2. Bộ Khoa học và Công nghệ cấp Giấy phép vận chuyển hàng nguy hiểm loại 5,
loại 7, loại 8 quy định tại khoản 1 Điều 4 Nghị định này.
3. Bộ Y tế cấp Giấy phép vận chuyển hàng nguy hiểm đối với các hóa chất độc
dùng trong lĩnh vực y tế và hóa chất diệt côn trùng, diệt khuẩn dùng trong lĩnh vực
gia dụng.

190
95
7/29/2021
104/2009/NĐ-CP
updated by Decree 42/2020/ND-CP
Chương V
GIẤY PHÉP VẬN CHUYỂN HÀNG NGUY HIỂM
Điều 18. Thẩm quyền cấp Giấy phép vận chuyển hàng nguy hiểm (TT)
4. Bộ Nông nghiệp và Phát triển nông thôn cấp Giấy phép vận chuyển hàng nguy hiểm
là các chất bảo vệ thực vật.
5. Bộ Tài nguyên và Môi trường cấp Giấy phép vận chuyển hàng nguy hiểm đối
với các hóa chất độc nguy hiểm còn lại trong các loại, nhóm hàng nguy hiểm.
6. Các Bộ có thẩm quyền cấp Giấy phép vận chuyển hàng nguy hiểm nêu tại các
khoản: 1, 2, 3, 4 và 5 Điều này quy định cụ thể về trình tự, thủ tục cấp Giấy phép vận
chuyển hàng nguy hiểm.

191
Decree 42/2020/ND-CP

192
96
7/29/2021

193

194
97
7/29/2021
• Nghị định sửa đổi Nghị định điều kiện kinh doanh tài nguyên môi trường
• Điều 8. Sửa đổi, bãi bỏ một số điểm, khoản tại các điều của Nghị định
số 104/2009/NĐ-CP ngày 09 tháng 11 năm 2009 của Chính phủ quy định Danh
mục hàng nguy hiểm và vận chuyển hàng nguy hiểm bằng phương tiện giao
thông cơ giới đường bộ
• 1. Sửa đổi điểm c khoản 2 Điều 10 như sau:
• “Bộ Công Thương xây dựng, bổ sung các quy định về các loại xăng dầu, khí
đốt; các hóa chất nguy hiểm và các hóa chất độc nguy hiểm;”.
• 2. Bãi bỏ điểm đ khoản 2 Điều 10 và khoản 5 Điều 18.
• Nghị định 91/2016/NÐ-CP quản lý hóa chất chế phẩm diệt côn trùng diệt khuẩn
dùng gia dụng y tế
• Khoản 3 Điều 18 Nghị định số 104/2009/NĐ-CP ngày 09 tháng 11 năm 2009 của
Chính phủ quy định Danh Mục hàng nguy hiểm và vận chuyển hàng nguy hiểm bằng
phương tiện giao thông cơ giới đường bộ hết hiệu lực kể từ ngày Nghị định này có
hiệu lực thi hành.
195
REVIEW
1. What is the maximum net quantity per package on CAO
for Pyrrolidine?
2. What is the Proper Shipping Name (PSN) for UN 1942?
3. What is the PSN for UN 1760?

196
98
7/29/2021
REVIEW
What hazards labels are required for:

a) Ferric arsenite?
b) Sulphur dioxide
c) Piperidine
d) Phosphorous, amorphous

197
REVIEW

198
99
7/29/2021
REVIEW
-
5. Marking & labelling
Marking Labelling
- UN number and PSN, net qty - Hazard label
- Full name and add of shipper & - Handling label
consignee
- UN spec. packaging or LTD QTY

199

200
100
7/29/2021
REVIEW 6. DOCUMENTATION
SHIPPING DOCUMENTS (PAPERS)
Shipping Documents (Papers) are
synonymous and can be found as follows:
 Road – kept in the cab of a motor vehicle
 Rail – kept in possession of a crew
member
 Aviation – kept in possession of the
aircraft pilot
 Marine – kept in a holder on the bridge
of a vessel
Shipping Documents (Papers) provide vital
information regarding the hazardous
materials/dangerous goods to initiate
protective actions* 201
201
REVIEW
The commodity to be transported by air is:

Proper shipping name:Propyleneimine, stabilized
Net quantity: 20L in one outer packaging
a) What is the applicabe UN number?

b) Can this shipment be transported on a pax aircraft?
c) What is the applicable PI?
d) Which single packaging can the shipper use for this item?

202
101
7/29/2021
REVIEW
1. List the markings and labels for the shipment of Fuzes detonating, UN 0367

203
REVIEW
A shipment consists of 14 litres of Propyl Acohol normal PG II , packed

in IP 1 glass bottle of 1000ml capacity each in UN combination
packages. The shipment will be transported by pax aircraft.
a) What PI is involved
b) What stipulated with reference to the marking and labelling of the

upright position of the package?
c) How many different types of outer packagings are permitted?

204
102
7/29/2021
REVIEW
1. List the markings and labels for the shipment of

Neon refregerated liquid, UN 1913

205
REVIEW
What are the meaning of marking of packaging below:
1) 1H2/X40/S/18/ZA/TE7576
2) 1A1/Y1.5/100/18/ZA/TE7576
3) 4G/Y 5/S/19/A/PA-03/3050
4) 1A1/X1.4/300/17/ D/BAM/7929 KHV

206
103
7/29/2021
Sub- PAX/
Proper Shipping Name Net qty UN/ ID Class/ Packing
sidiary CAO EQ
per Pkg number div. Ins
risk A/C
PG III
1 Kerosene
60 L
PG I UN
2
1L 2407
10 kg
Isosorbide dinitrate
3 solid,
mixture
PG II
PG II UN
4
1L 1802
Diphenylchloroarsine,
PG I
5 solid
1 Kg
207
Thank you

208
104

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Vietnam Logistics Research and Development Institute

Module 12– Dangerous Goods 1

Module 12– Dangerous Goods 2

Module 12– Dangerous Goods 3

2. THE SYSTEM OF REGULATIONS DANGEROUS GOODS IN

3. HANDLING OF DANGEROUS GOODS

4. VIETNAM’S REGULATIONS OF CARRIAGE OF DANGEROUS GOODS

Module 12– Dangerous Goods 4

Module 12– Dangerous Goods 5

Module 12– Dangerous Goods 6

1.1 WHAT IS DANGEROUS GOODS ?

“Dangerous goods are articles or substances which are capable of

Module 12– Dangerous Goods 7

The difference between hazmat and DG????

Hazardous substances can be defined dangerous goods present an immediate

Module 12– Dangerous Goods 9

Module 12– Dangerous Goods 10

1.2 GENERAL PHILOSOPHY

Module 12– Dangerous Goods 11

1.3 SHIPPER’S RESPONSIBILITIES

− Recognize and identify

Module 12– Dangerous Goods 12

1.4 FREIGHT FORWARDER ’S

Module 12– Dangerous Goods 13

1.4 FREIGHT FORWARDER ’S RESPONSIBILITIES

− Proper loading into trucks to transfer the items to the carrier

Module 12– Dangerous Goods 14

1.5 OPERATOR’S RESPONSIBILITIES

Module 12– Dangerous Goods 15

1.6 CARRIER’S LIABILITY

1. 7 THIRD PARTY’S LIABILITY

Provide capable staff for handling of dangerous goods;

− Store and handle the dangerous goods in separated areas if needed.

Module 12– Dangerous Goods 17

Module 12– Dangerous Goods 18

THE SYSTEM OF DANGEROUS GOODS

Module 12– Dangerous Goods 19

2.1 UN- MODEL REGULATIONS

Module 12– Dangerous Goods 20

2.1 UN- MODEL REGULATIONS

- Transport of dangerous goods needs to be regulated in order to

Module 12– Dangerous Goods 21

2.1 UN- MODEL REGULATIONS

- In order to ensure consistency between all these regulatory systems,

- In addition, the UNECE administers regional agreements that ensure the

Module 12– Dangerous Goods 22

2.1 UN- MODEL REGULATIONS

-Developed by the United Nations Economic and Social Council's

Module 12– Dangerous Goods 23

2.1 UN- MODEL REGULATIONS

Module 12– Dangerous Goods 24

2.1 UN- MODEL REGULATIONS

The UN Model Regulations consists of seven parts, two

Module 12– Dangerous Goods 25

2.1 UN- MODEL REGULATIONS

Module 12– Dangerous Goods 26

2.1 UN MODEL REGULATION

Module 12– Dangerous Goods 27