Test - 4A (Paper-1) (Code-A)_(Answers) All India Aakash Test Series for JEE (Advanced)-2023

All India Aakash Test Series for JEE (Advanced)-2023

TEST - 4A (Paper-1) - Code-A
Test Date : 03/04/2022

ANSWERS
PHYSICS CHEMISTRY MATHEMATICS

1. (C) 20. (B) 39. (D)

2. (A) 21. (B) 40. (B)

3. (C) 22. (B) 41. (A)

4. (D) 23. (D) 42. (B)

5. (21.00) 24. (05.00) 43. (07.00)

6. (50.20) 25. (00.00) 44. (29.00)

7. (00.33) 26. (12.00) 45. (33.00)

8. (01.50) 27. (03.00) 46. (09.00)

9. (08.00) 28. (09.00) 47. (07.00)

10. (04.00) 29. (02.00) 48. (06.00)

11. (A, B) 30. (A, B) 49. (A, B)

12. (C, D) 31. (A, B, D) 50. (A, B, D)

13. (B, D) 32. (B, C) 51. (A, C, D)

14. (A, B, C) 33. (A, C, D) 52. (B, C, D)

15. (A, C) 34. (A, B) 53. (A, C, D)

16. (C, D) 35. (A, C, D) 54. (A, B, D)

17. (50) 36. (19) 55. (08)

18. (04) 37. (07) 56. (16)

19. (03) 38. (75) 57. (04)

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All India Aakash Test Series for JEE (Advanced)-2023 Test - 4A (Paper-1) (Code-A)_(Hints & Solutions)

HINTS & SOLUTIONS

PART - I (PHYSICS) 4. Answer (D)

Hint : Heat gained = Heat lost
1. Answer (C)
1
Sol. : Q1 = S   20 + 5  80 = 450 cal
Hint : Q = U + W 2

Sol. : QB→A = (UA – UB) + W = 0 Q2 = 10 × 1 × 30 = 300 cal

 Final temperature = 0°C
 (UA – UB) + (–30) = 0
5. Answer (21.00)
 UA – UB = 30 J …(i) 6. Answer (50.20)

QA→B = (UB – UA) + WA→B = 20 Solution for Q. Nos. 5 and 6

– 30 + WA→B = 20 1
Wgas = P   V + Kx 2
2
 WA→B = 50 J

2. Answer (A)
( )
= 105  20  10  10−6 +
1
2
 200  (0.1)2

a
Hint : tan  = = 20 + 1
g
(12 − 8) 4 1 = 21 joules
Sol. : tan  = = =
(12 + 8) 20 5 PiVi = nRTi
a 1
 = 2  R  300
g 5 Vi = m3
105
g
 a= = 2 m/s2
5 25
2  300
3. Answer (C) Vi = 3  106 cm3
5
Hint : Use Doppler effect 10
Sol. :
= 50000 cm3

V = 20 × 10 cm3

= 200 cm3

Vf = Vi + V = 50200 cm3

= 50.2 × 103 cm3

v
n' =  n0
v − v 0 cos  7. Answer (00.33)

SD cos  SD v
8. Answer (01.50)
and, =  cos  = 0
v0 v v Solution for Q. Nos. 7 and 8

v2 mv 2
n = n0 Hint : F =
v 2 – v 02 r
T (r )
3402 Sol. : dl =
 n' =  1200  YA 
3402 − 1702  dx 
 
= 1600 Hz
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Test - 4A (Paper-1) (Code-A)_(Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2023

  dl = 
(
1  L − r dr
2 2 2
) 13. Answer (B, D)

2 Y Hint : V AB = V A − V B
3V 3
2L3 Sol. : Urel = V + V cos60° = =  10
 L = 2 2
3Y
= 15 m/s
1 10  ( 400 )  ( 0.5 )
4 2 3
=  = 0.33 mm 30
3 2  1011  t = =2s
15
32 l 2  s = 10 × 2 = 20 m
Stress = = 1.5 × 108 Pa
8 14. Answer (A, B, C)
9. Answer (08.00) Hint : Use constraint relation
10. Answer (04.00) Sol. : T1 – mg = maA
Sol. of Q. 9 and Q. 10 m  2m
T1 = 4   ( g − aA )
1 3m
Hint : dK = (dm )  v y2
2 mg – T2 = maB and T1 = 2T2
Sol. : y = (A sinKx) (sint) 5g 16mg 8mg
 aA = , T1 = , T2 =
2 11 11 11
1  dy 
 dK =  (dm)   
2  dt  3g
aB =
11
 Kv =
 K ( x )  dx = m2 A2 15. Answer (A, C)
l 8
Fext
Hint : acm =
N=8 mass
m2 A2 Sol. : Block moves downward and rightward.
Total energy is always constant = . Friction acts rightward on the wedge.
4
16. Answer (C, D)
11. Answer (A, B)
Hint : At pure rolling slipping stops.
Hint : Use principle of homogeneity
2 v 7 v
Sol. : [a] = [PV2] = ML5T–2 Sol. : mv 0R + mR 2  0 = mR 2 
5 2R 5 R
[b] = [V] = L3
6v 0 7v 6v
 =  v= 0
PV  = ML2T–2K–1
R  = 5 5 7
T   6v 0 
 v0 − 7 
12. Answer (C, D)   =t v0
 0  t0 =
1 2 g 7g
Hint : v = u + at, s = ut + at
2 17. Answer (50)
8−0 Hint : KE = Wext
Sol. : a1 = = 0.8 m/s2
10
( )
2
Sol. : l1 = 32 + 3 3 =6m
1
s1 =  0.8  (10 ) = 40 m
2
2 l 2 = 32 + 42 = 5 m
82 − 0  KE = F S = 50 × 1 = 50 J
a3 = = 0.5 m/s2
2  64

s3 = 64 m  s2 = 584 – 40 – 64 = 480 m 18. Answer (04)

 t = 10 + 60 + 16 = 86 s dv
Hint : F = A
dz
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All India Aakash Test Series for JEE (Advanced)-2023 Test - 4A (Paper-1) (Code-A)_(Hints & Solutions)

dv 22. Answer (B)

Sol. : F = mg sin = A
dz Hint : Acidic buffer
1  10 
 20  10  = 10−2  22    [Salt]
2  h  pH = pK a + log
[Acid]
104 1
 =
10  4 h Sol : Initial mmol of C6H5COOH = 14
 h = 4 × 10–3 m = 4 mm Initial mmol of C6H5COONa = 7
19. Answer (03)
dT 7
Hint : =0 pH1 = pKa + log = pKa − log 2
dx 14
ml 2 After adding 2 mmol NaOH, the mmol of
Sol. : I = + my 2 , y = − x
12 2 C6H5COOH = 12 mmol and C6H5COONa = 9
I
 T = 2 9
mg y pH2 = pKa + log
12
dT
and =0 y = =
dy 12 2 3 3
= pK a + log
4
 x= −y = –
2 2 2 3 23. Answer (D)
 3 – 1 Hint : Be2+ < Mg2+ < Ca2+ < Sr2+ < Ba2+
=  
2 3 
[Ionic radius M2+]
Be > Mg > Ca > Sr > Ba (IE1)
PART - II (CHEMISTRY)
Sol : Melting point: Be > Ca > Sr > Ba > Mg
20. Answer (B)
Hint : An ideal gas undergoing reversible 24. Answer (05.00)
adiabatic expansion follows the following
25. Answer (00.00)
equation.
TV–1 = constant Hint and Sol. for Q.Nos. 24 and 25
–1
Sol : TV = constant
−1 Hint : is most acidic among the
500(10) = T2 (40)−1
−1 products.
 1 500
T2 = 500   = = 200 K
4 (4)2/3
q = 0 = E – w Sol. :
w = E = nCvm(T2 – T1)
3
= R (200 − 500)
2
= –3 × 150R
= –3735 J
21. Answer (B)
S H
Hint : ln K = − , where K is equilibrium
R RT
constant.

S H
Sol : lnK = −
R RT
H
= 2062.65  H = 17.12 kJ
R

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Test - 4A (Paper-1) (Code-A)_(Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2023
26. Answer (12.00) 31. Answer (A, B, D)
27. Answer (03.00)
Hint : As, ng = 0  KP = KC
Hint and Sol. for Q.Nos. 24 and 25
Hint : Sol. : 2XY(g) X2 (g) + Y2 (g)

t=0 2 – –

x x
t = eq. 2–x
2 2

(x/2)2
= 0.16
Sol. :  Energy of stabilisation by (2 − x)2
12
1C–H= = 3 kJ/mole x 2
4 =
2(2 − x) 5
28. Answer (09.00)
29. Answer (02.00) 8
 x=
Hint and Sol. for Q.Nos. 28 and 29 9

Hint: The possible benzenoid compounds are : 32. Answer (B, C)

[H+ ]2 [S2− ]
Hint : K1K 2 = = 10−21
[H2S]

Sol. : Saturated solution of H2S = 0.1 M H2S

(0.2)2 [S2− ]
Sol. : I. = 10−21
0.1

 [S2–] = 2.5 × 10–21

Ksp = [Fe2+][S2–] = 3.7 × 10–19
Since (0.1) × (2.5 × 10–21) < 3.7 × 10–19
FeS will not precipitate.

(0.001)2 [S2− ]
II. = 10−21 [S2− ] = 10 −16
0.1

Since (0.01)(10–16) > 3.7 × 10–19

FeS will precipitate.
33. Answer (A, C, D)
→ compound having highest dipole Hint : U = q + w
Sol. :
moment (it has 2 benzylic hydrogens)
30. Answer (A, B) I. H2O(l) H2O(s)
Hint : Total number of nodes = n – l – 1
Sol. : The correct plots for 2s and 3p are It is at equilibrium at 273 K and 1 atm.
So, Ssystem is negative

G = 0
II. Mixing of two ideal gas at constant T
q = 0, U = 0, w = 0

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All India Aakash Test Series for JEE (Advanced)-2023 Test - 4A (Paper-1) (Code-A)_(Hints & Solutions)

34. Answer (A, B) 37. Answer (07)

Hint : Tetranuclear unit [B4O5(OH)4]2–
Hint : Generally thermal stability increases down
Sol. :
the group.

Sol. : BeCO3 > MgCO3 > CaCO3 > SrCO3 >

BaCO3 (Solubility order)

Be(OH)2 < Mg(OH)2 < Ca(OH)2 < Sr(OH)2 <

Ba(OH)2 (Thermal stability order)

35. Answer (A, C, D) 38. Answer (75)

Hint : Hint : 2NaN3 ⎯⎯→ 2Na + 3N2

600 −800 K
BeO + C + Cl2 BeCl2 + CO 10Na + 2KNO3 ⎯⎯→ K2O + 5Na2O + N2
(P) (Q)
Sol. : Assume reaction initially starts with ‘a’
2BeCl2 + LiAlH4 ⎯⎯→ 2BeH2 + LiCl+ AlCl3 moles of NaN3
(R) (S) (T)
 Moles of Na formed = a
Sol. : Polymeric structure of (BeCl2)n 3a
Moles of N2 formed =
2
Moles of KNO3 required for ‘a’
a
moles of Na =
5
a
Polymeric BeH2  Be is sp3 hybridised Moles of N2 formed in 2nd reaction =
10
36. Answer (19) 3a a 8  18.45
 + = =6
2 10 0.082  300
Hint : HA + NaOH ⎯⎯→ H2O + NaA
10  6
Sol. : Millimoles of salt of NaA or A– = 40 × 0.1  a= = 3.75 moles
=4 16
 Mass of KNO3 required =
A – + H+ ⎯⎯→ HA
a
Initial millimoles 4 2  101 = 75.75 g
5
Final millimoles 2 – 2

Acidic buffer solution is formed and PART - III (MATHEMATICS)

[A–] = [HA]
39. Answer (D)
[A − ]
pH = pKa + log  pK a = 6 Hint : If A + B + C =  then tan A + tan B + tan C
[HA]
= tan A  tan B  tan C
Now, HA + NaOH ⎯⎯→ NaA + H2O
Sol. :  50° + 60° + 70° = 180°
Hydrolysis of A– will take place.
Millimoles of acid 20  0.2 tan 50° + tan 60° + tan 70°
[NaA] = = = 0.1
Total volume 40 = tan 50°  tan 60°  tan 70°
1 = 3  tan(60 − 10)  tan(60 + 10)
pH = (pK w + pKa + log C)
2
sin(60 − 10)  sin(60 + 10)
=
1
(14 + 6 − 1) = 9.5
= 3
2 cos(60 − 10)  cos(60 + 10)

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Test - 4A (Paper-1) (Code-A)_(Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2023

sin2 60 − sin2 10 On replacing y = 0 we get

= 3
cos2 60 − sin2 10 49
  f (r ) = f (1) + f (2) + ... + f (49)
3 − 4sin 10
2
3 − 4sin 10
2 r =1
= 3 = 3
1 − 4sin 10
2
4cos 10 − 3
2 = 2 + 3 + 4 + … + 50
50  51
3sin10 − 4sin3 10 cos10 = − 1 = 1274
= 3  2
4cos3 10 − 3cos10 sin10
42. Answer (B)
1
= 3  tan30  cot10 = 3  .tan80 Hint : Property of ellipse
3
= tan80 Sol. : (S1M1)(S2M2) = b2 = 4
43. Answer (07.00)
40. Answer (B)
Hint : Convert the given equation in quadratic in
Hint : For maximum value of MPN a circle with
x and y respectively to get range of y and x.
centre at perpendicular bisector of MN and
Sol. : 9x2 + 2xy + y2 – 92x – 20y + 244 = 0
touches the x axis at P
 9x2 + (2y – 92)x + (y2 – 20y + 244) = 0
Sol. : Equation of perpendicular bisector of MN is
y – 3 = –1 (x – 0)  x = (92 − 2y )  (2y − 92) − 4.9( y − 20y + 244)
2 2

18
y=3–x
Here (y – 46)2 – 9 (y2 – 20y + 244) ≥ 0
Let centre of circle be (x1, 3 – x1)
Then equation of circle passing though points M  –8y2 + 88y – 80 ≥ 0

and N is  y2 – 11y + 10 ≤ 0

( x − x1)2 + (y − 3 + x1)2 = ( x1 − 1)2 + (3 − x1 − 4)2  y  [1, 10]

 minimum value of y = 1
 ( x − x1)2 + ( y − 3 + x1)2 = 2( x12 + 1) …(1)
And again
If this circle touches the x axis then
y2 + (2x – 20)y + (9x2 – 92x + 244) = 0
| 3 − x1 | =
2
2( x12 + 1)
 y = (20 − 2x )  4( x −10) − 4(9 x − 92 x + 244)
2 2

 x12 + 6x1 − 7 = 0 18

 x1 = −7 or 1.  (x – 10)2 – (9x2 – 92x + 244) ≥ 0

For maximum angle radius must be minimum.  x2 – 9x + 18 ≤ 0

 x1 = 1 and point of contact P = (1, 0).  x  [3, 6]

41. Answer (A)  Maximum value of x = 6

Hint : Interchange the x and y in given equation  Required sum = 6 + 1 = 7

to get function. 44. Answer (29.00)
Sol. :  f(xy + 1) = f(x)  f(y) – f(y) – x + 2 …(1) Hint : For two linear factors the discriminant must
be equal to zero.
On interchanging x and y we get
Sol. : The expression
f(xy + 1) = f(y)  f(x) – f(x) – y + 2 …(2)
–3x2 – 8xy + 3y2 – kx + 3y – 18 is compared with
From. eq (1) and eq. (2) :
ax2 + 2hxy + by2 + 2gx + 2fy + c we get
f(x)  f(y) – f(y) – x + 2 = f(y)  f(x) – f(x) – y – 2
k 3
 f(x) + y = f(y) + x a = −3, h = −4, b = 3, g = − , f = , c = −18
2 2
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All India Aakash Test Series for JEE (Advanced)-2023 Test - 4A (Paper-1) (Code-A)_(Hints & Solutions)

For linear factors : Sol. :

abc + 2fgh – af2 – bg2 – ch2 = 0
2
3  k 3
 ( −3)  3  ( −18) + 2    −   ( −4) − ( −3)   
2  2 2
2
 k
−3   −  − (−18)  (−4)2 = 0
 2

27 3k 2
162 + 6k + − + 288 = 0
4 4

 k2 – 8k – 609 = 0

 k = 29 as k  N.
45. Answer (33.00)
Hint : Use of Multinomial theorem 49. Answer (A, B)
Sol. : Number of permutations = Coefficients of x2 y2
Hint : Equation of normal to ellipse + =1
 x2  a 2
b2
x3 in 3! (1 + x )  1 + x +
3

 2!  a2 x b2 y

at point (x1, y1) is − = a2 − b2
x1 y1
= coefficients of x3 in
Sol. : Equation of normal to ellipse at point with
 x2  eccentric angle  is :
3!(1+ 3 x + 3 x 2 + x 3 )  1+ x + 
 2 
 ax by
− = a2 − b2 …(1)
cos  sin 
3 
= 6  + 3 + 1 = 33 And normal at point (–a sin , b cos ) is
2 
ax by
46. Answer (09.00) + = b2 − a2 ...(2)
sin  cos 
Hint : Use of coefficients in multinomial theorem a
Slope of normal (1) = m1 = tan 
Sol. :   = Coefficient of x4 in b
a

2 Slope of normal (2) = m2 = − cot 
x2   x2 x3  b
4! (1 + x )  1 + x +
4
  1 + x + + 
 2   2! 3! 
 m1 − m2
 tan  =
= Coefficient of x4 in 4! (1 + 4x + 6x2 + 4x3 + x4) 1 + m1m2

 x4  x2 x3  a a
 1 + 2 x +
2
+ 2x + x 3  1 + x + +  tan  + cot 
4  2 6 b b
    tan  =
a2
= 1422 1− 2
b
 Sum of digits of  = 9.
1 1

47. Answer (07.00) 1 − e2 sin   cos 
 tan  =
48. Answer (06.00) 1
1−
1 − e2
Hint and Sol. for Q.Nos. 47 and 48
Hint : Sketch graphs and count number of prints 2cot  e2 1 − e2 −e2 e2
 = = or
of intersection. sin2 e2 − 1 1 − e2 1 − e2
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Test - 4A (Paper-1) (Code-A)_(Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2023
50. Answer (A, B, D) 7!
Sol. : The words start with T is .
Hint : Let common ratio of G.P. be r then a = a, b 2!
= ar and c = ar2.  Probability that words start with T
Sol. :  a + b + c = 70 7!
1
 a (1 + r + r2) = 70 …(i) = 2! =
8! 4
and 10b = 4a + 4c 2!  2!
5ar = 2a + 2ar2 Probability that word start with vowel
 2r2 – 5r + 2 = 0 7! 7!
+
1 2! 2!  2! 3
 r = 2 or …(ii) = =
2 8! 8
2!  2!
1
From (i) and (ii) : r = 2 then a = 10 and r = then
2 Probability that word start and end with I
a = 40. 6!
 (a, b, c) = (10, 20, 40) or (40, 20, 10) 1
= 2! =
8! 28
51. Answer (A, C, D)
2!  2!
Hint : L.H.L. = lim f ( x ) = lim f (a − h)
− x→0
x→a Probability that word start with K and end with C
and R.H.L. = lim f ( x ) = lim f (a + h) is
+ h→ 0
x→a
6!
Sol. : lim f ( x ) = lim f (1 − h) = lim (1 − h)2 − 2 = −1
− h→ 0 h→ 0 2!  2! 1 1
x →1
= = =
8! 8  7 56
and lim f ( x ) = lim f (1+ h) = lim (1+ h) +1 = 2
+
x →1 h→ 0 h→ 0 2!  2!

lim f ( x ) = lim f (4 − h) = lim 4 − h + 1 = 5 54. Answer (A, B, D)

x → 4− h→ 0 h→ 0
 4 
and lim f ( x ) = lim f (4 + h) = lim 6 − (4 + h) = 2 Hint : f ( x ) = log2  
+
x→ 4 h→ 0 h→ 0  x +2 + 2− x 
52. Answer (B, C, D) = 2 − log2 ( x + 2 + 2 − x )
Hint : z1 lies on circle and z2 lies on elliptical
region. Sol. : For domain of f(x),

Sol. : | z − 3 |2 + | z − 7 |2 = 40 then replace x + 2 ≥ 0 and 2 – x ≥ 0

z = x + iy then  x  [ −2, 2]
(x – 3)2 + y2 + (x – 7)2 + y2 = 40
For range of f(x) we have to get range of
 x2 + y2 – 10x + 9 = 0
Centre of circle is (5, 0) and radius 4 units. y = x +2 + 2− x

| z − 12 | + | z − 16 |  6 is elliptical region with y 2 = 4 + 2 4 − x2

centre at (14, 0)
 y 2  [4, 8]  y  [2, 2 2]
The max | z1 − z2 | = 16 units
1 
min | z1 − z2 | = 2 units.  Range of f ( x ) =  , 1
2 
53. Answer (A, C, D)
55. Answer (08)
Hint : Total number of words formed by
Hint : For shortest chord it must be perpendicular
8!
‘TIKTANIC’ is equal to = 10080 to x axis.
2!  2!

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All India Aakash Test Series for JEE (Advanced)-2023 Test - 4A (Paper-1) (Code-A)_(Hints & Solutions)

Sol. :  Required equation of chord is x = 2 Sol. :

When x = 2 then y = ±4
56. Answer (16)
Hint : Differentiate f(x) w.r.t. x and replace x by
zero.
Sol. : f(0) = 5 – 7 = –2

and f ( x ) = 12x3 + 5 + 2ex + 2xex

In OMB
+ 7sec2 x − 5sin x
 2
 f (0) = 7 + 7 = 14 sin =
6 r
 f (0) − f (0) = 16 2
 r = =4
57. Answer (04) 
sin
6
Hint : Length of chord is 4 units.
Radius of circle be 4 units.

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