FIITJEE MOCK TEST-9

IIT – JEE, 2019 Paper Code

PAPER-I 100400.1
ANSWERS
Physics [PART-I]
1. C 2. A 3. B 4. C
5. C 6. B 7. B 8. A
9. A, B, D 10. A, B, C 11. A, B, C 12. C, D
13. B, C 14. C 15. B 16. B
17. C 18. B
1. 1 2. 6 3. 2 4. 2
5. 5 6. 4 7. 2 8. 4
9. 3 10. 8
Chemistry [PART-II]
1. D 2. A 3. C 4. A
5. A 6. A 7. B 8. D
9. B, C, D 10. B, C, D 11. A, B 12. A, B, C, D
13. A, C, D 14. B 15. A 16. C
17. B 18. D
1. 8 2. 8 3. 6 4. 3
5. 5 6. 5 7. 4 8. 8
9. 3 10. 6
Mathematics [PART-III]
1. D 2. B 3. A 4. C
5. C 6. A 7. C 8. A
9. A, C 10. A, B 11. A, C, D 12. A, B, C, D
13. A, C 14. A 15. A 16. B
17. A 18. A
1. 1 2. 6 3. 6 4. 0
5. 0 6. 3 7. 8 8. 6
9. 3 10. 1

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Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-2

Physics PART – I

SECTION – A
1. The rms voltage is found by parametrising the voltage
V t 0  t  1 sec .
V 0
V0 / 2 1  t  2 sec .
1/ 2 1/ 2
 1  2    1  1 V 2 2   7
Vrms =    V 2 (t)dt   =   V02  t 2 dt  0  dt   = V0
 2  0    2  0 4 1   24

2. Applying continuity equation at the top surface and at the hole

v1 a v
Av 1 = av2  =  1 < < 1 as a < < A
v2 A v2
where A and a are the cross-sectional areas and v 1 and v 2 are the velocities of the fluid at the top
surface and at the hole respectively.
Applying Bernoulli’s equation at these two cross-section
v12 v 22
P1 + gh1 + = P2 + gh2 +
2 2
v12
 P0 + g(h/2) + 2g (h/3) + 3g(h/4) +
2
3v 22
= P0 + 3g (h/6) +
2
17gh (3 v 2  v1 ) v 22 
2 2
v2 
 =   3  12 
12 2 2  v2 
17gh v 12 v 17gh
 v2 = 2
Neglecting 2
as 1 < < 1 We get v2 = .
 v 
1
v2 v2 18
6 3  
2
 v 
2

  
 ab
3. The median of the triangle between a and b is given
2
   
2 a  b a  b
 Location of centre of mass =  
3 2  3

4. Consider a small initial time interval dt. The vdt

120
change in velocity for the particle at A can be d 60
B
represented by the following velocity triangle. A
a
By sine law
a Vdt Vdt 
  v f

v
sin120 sin  
d
Vdt sin120 V 3 
 =  dt v
a 2a  
i

Now v = v vi  v f  v

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 Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-3

V2 3
 v = t
2a
v v2 3
 =
t 2a

5. F = ma
2
 v2 
 mg = m    a2t
 r 
2
 v2 
 at = 2 g2    = 4 m/s2
 r 

6. Consider the FBD of the bottle after shaping and beeping on the balance.
Now after shaping the suspended particles being heavier will again start
setfling down. Thus the centre of mass of the system must have a
downward acceleration.
Now: Mg  N = Ma
 N = Mg  Ma < Mg
Mg
Thus weight recorded is less than W.
N

I
7. Radiation pressure = P 
c
1 a 3
Area of Hexagon =  a  6 a
2 2 
F = pA cos 
3 3a2 I 3 9a2 3 9a2I
    =
2 c 2 4 2 4c

Power
8. I=
4 r 2
Power = 4r2.I= 4 (50)2  10-8 = 3.14  10-4 Watt
2
1 p0 B
also I= We know that v =
2 v 
2
B 1 p0 v
 = | I=
v2 2 B
2IB 2  10 8  1.6  10 5
 p0 =  = 3.07 10-3 N/m2
v 340

9. For ammeter
99 Ig = (I – Ig) 1 or I = 100 Ig . . . (i)
Ig is the full scale deflection current of the galvanometer and I is the range of ammeter

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Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-4

99 
i Ig
G

1
For the circuit in figure-1
12 V
= 3 A  r = 1.01 .
99  1
2r 
99  1
For voltmeter, range
V = Ig (99 + 101) V = 200 Ig . . . (2)
Also resistance of the voltmeter = 99 + 101 = 200 
200  2
In figure –2 resistance across the terminals of the battery R1 = r + = 2.99 
202
99  101 
G
Ig

V
12
 Current drawn from the battery, I1 = = 4.01 A
2.99
4
 Voltmeter reading V = 12 – I1 r = 12 – 4.01  1.01
5
5
V = 7.96  = 9.95 V
4
9.95
Using (2), Ig = = 0.05 A
200
Using (1), range of the ammeter
I = 100 Ig

10. (a) The power loss in the circuit is:

Ploss = Vrms  Irms cos= 200 V  10 A  cos = 1000 W
1
cos =  = /3 (since the circuit element is an inductor)
2
The inductance in the circuit is calculated as follows:
200  10 3 3
XL =  sin = 10 3  L=  H
10 3 2  50 10
L 
(b)  tan  1
R 4
3 1 50
2f    1 or, f= Hz.
10 10 3
P 1 L 25
(c) reactive   tan    f= Hz, which is half of the previous value.
Ploss 2 R 3

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 Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-5

11. Initially the charges on the plates will be distributed as shown. P.d across the plates is given by
Q1  Q2
and is independent of the charge on the outer surfaces. Thus, when capacitor is
2C
discharged, the charges on the outer surface do not change. Charge on the inner surface decreases
according to
Q1+Q2 Q1+Q2
2 2

Q1-Q2 Q2-Q1
2 2

t
 Q1  Q 2   RC
the equation q =  e
 2 
t
Q1  Q 2  Q1  Q 2   RC
Total charge on the left plate q =  e
2  2 
t
Q1  Q 2  Q1  Q 2   RC
And total charge of the right plate q2 =  e .
2  2 

12. Applying work energy theorem:

1
Wgas  Watm  KE   mu2
4
1 2
 WGAS   mu  Watm  uGAS
4
Since the gas is compressed
 Watm  0
1
 WGAS   mu2
4
1
and UGAS  mu2
4

7
13.  y2 = (5 )2  x 2 = (3 2)2  (7  x)2 x 7x

3
 x = 4   y = 3   T  2 5
y
g 32

14. y
 ydA , choosing a horizontal strip at a height y of thickness dy, dA = dy   a  y
 evaluating
 b 
 dA 
3
the integrals, we get y  b . (since here a = 1)
10

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Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-6

Similarly x
 xdA . For this we choose a vertical strip at a distance x from the origin of thickness dx.
 dA
3
dA = kx2dx. Now evaluating the integrals, we get x  .
4

15. Volume = Generating area  length of the path traced by centeriod

b 3 b
  2  
3 4 2

GMm GMh
16. h '  h  = h  2
R CR
 GM 
 h '  h  1  2 
 C R
' GM
or,  1 2
 cR

' GM
17.  1 2
 cR
GM '
  1
c 2R 
   ' 
  GRS
 

GMm
18. Total energy h 
R
GMh
= h 
Rc 2
Now from black hole this must be negative
 GM 
 h 1  2 
0
 Rc 
GM
 1
Rc 2

SECTION –C

T v v 1 T
1. v= ; w =  
m    m
v 3v 5 nd
For organ pipe: op =  ;  pipe  (2 overtone)  = 2m ;  = 
 2 4
p RT RT
where, v S =   = 360 m/s
 M M

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 Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-7

3  360
op = = 270 Hz
4
w - op = 5 w = 275 Hz
1 302.5
275 = 
2 m  = 3/2 ;  = 2/3
m = 10-3 kg/m

2. The ray will suffer TIR on face BC and will then hit B
face AC normally.

60°

60°

A C

fe ( a  g  1) a  
3. 
fa a g a 

 20 (1.5  1) a  

10 1 .5
3 = 1.5 a    t = 10 sec.

2  1 1 
4.
 
E = (13.6 eV) Z  Z  2 2  Z 2 
 
 Z 2  ( Z  2) 2  4Z  1  13.6
 
= 13.6  Z  2 2
 =
  Z  22 eV
h2  h 
Now energy of electron is k = ;  we have    Or, k = 6eV
22m  2mk 
4Z  1  13.6
So, = 10.2 eV
Z  22
Or,
Z  1  3  (Z2) (3Z+2) = 0
Z  22 16
So, the value of Z = 2 (neglecting the negative/ fractional value)

hc
5. Energy of photon corresponding ot wavelength  E =

hc ( 6.6  10 34 )  (3  10 8 ) 1
Emax =  7
 = 3.1 eV
 min 4  10 
1.6  10 19
From Einstein's equation for photoelectric effect
Emax =  + (Ek) max
(Ek)max = Emax -  = 3.1  2.1 = 1 eV
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Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-8

The photoelectron with charge e mass m and maximum velocity bends in a circle of radius r
mv 2
BeV =
r
mv 2mE k
r= 
Be Be
For ammeter reading to be zero, no electron should reach the collector plate.
For which r  d

2mEk
d
Be
2mE k -5
B  Bmin = 2.25  10 Tesla.
ed

1 1 1
6. sin  = [x  (2  1)] = (n  (2  1)]= 6
[n  500  109  20  106 ]
d d 10  10
  n  
 n 
sin  = 2   1 Hence  = sin1 2  40  1 
 40 
| sin  |  1
 n 
12   1  1
 40 
20  [ n – 40]  20
20  n  60 Hence number of maxima = 41

nRT
7. U 
   1
nRT
W  Where  is a constant
1  
W nRT / 1  
  2 / 3 where   5 / 3 ,   2
U nRT /    1

8. The wavelength of the sound wave in air is,

340
= 3
m = 25103m s 1
13.6  10
d
the separation between the sources, d = 1m = 40 s 2

n interference pattern is produced on the circumference of the

circular track,
here, d sin = n, representing the position of the nth
maximum as shown in the figure i.e.
0 sin = n or, sin = n/40,
1
since, sin lies between 0 & 1, there are 40 maxima in th of the circumference or 160 maxima on
4
the entire circle.
72  103
The (observer) train travels at 72 km/hr or, m / s i.e. 20 m/s
3600
and observes 4 beats / seconds.
160
160 beats are observed in = 40 sec, when the observer travels along the entire circle.
4
The length of the track = 4020m = 800m
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 Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-9

800
 The radius of the track = m
2

9. Let us calculate the equivalent resistance of circuit:

solving the shown circuit
 15
we get  R = 15 
i 11
2
so maximum current in the given circuit = A
3

Mg
10. Buoyant force =
2
Apply work energy theorem
1  ML2  2 MgL Mg 2  L MgL Mg  L MgL
       
2 3  2 2 2 4 4
3g
 
2L
L 3gL
So, vcm =  
2 8

Chemistry PART – II

SECTION – A
1. D
pKa for the compound A, B, C and D are respectively 9.98, 9.48, 8.81 and 8.48.

2. A
PCl2  PCl  1 atm
P
rate 
m
PCl2 PCl 1.2  1
1/ 2
 1/2
 1
 71  35.5   64  2
PCl2
 PCl  0.9
2
PCl2  0.34
PCl = 0.66
2

Kp 
 0.66   1.28 atm
0.34 
3. C

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Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-10

7 7
4 4
2 2 
5 5 1 HOAc
1 3 OTs   3 OTs  
6 2 6 OAc  AcO
H H H H
50% 50%
4 5
3 7
6
2 1
The solvolysis of exo-isomers (option C) is 350 times faster than that of endo-isomers (option D).
Both the compound (C and D) give only exo acetate. The C6 – C1 bond is situated to the rear of the
ionizable group this facilating the ionization. This leads to non-classical carbonium ion that react with
acetic acid to yield the racemic mixture of acetate. No such anchimeric assistance available to the
endo-isomer which undergoes slow acetolysis through classical carbonium ions.

4. A
NH3 act as strong field ligand for Co2+ and Co3+ in the presence of strong field ligand Co+2 act as a
very good oxidizing agent.
2 3
Co  NH3 5 H2 O   Co  NH3 6   e   H2 O
 NH3 
Hence sp3 d2 LS  d2 sp3 LS 
d7 Co II d6 Co III

5. A

6. A

7. B
t 75% 34.65
t1/2   hour
2 2
0.693
K  4  102 hour
34.65 / 2

8. D
Compound P  BeO
Compound Q  BeCl2
Compound R  Be(OH)2

9. B, C, D
I2Cl6 XeF4 K 2 Ni(CN)4  and Al2Br6
sp3 d2 sp3d2 dsp2 sp3

Cl Cl Cl
I I
Cl Cl
Cl

Planar molecule
Both the I atom are square planar due to lone pair repulsion.

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 Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-11

10. B, C, D
(A) Work done by the gas is P1V1 
 25P1V1 
(B) The maximum temperature attained by the gas during cycle  
 8R 
(C) The heat absorbed by path PQ is (3P1V1)
5
(D) The net heat rejected by gas in path RP is P1V1
2

11. A, B
German silver – Cu, Zn, Ni
Dutch metal – Cu, Zn
Bronze – Cu, Sn
Kaolin – Al2O3.2SiO2.2H2O

12. A, B, C, D
O

H O P O H

H
P4 O6  H2O  4H3PO3
PCl3  3H2 O  H3PO3  3HCl

4H3PO3 
200o C
3H3PO4  PH3
H3PO3 with Co(NO3)2 gives violet blue ppt. while HPO3 can’t.

13. A, C, D
BeO is metal oxide and amphoteric in nature. OF2 is not an oxide rather oxyfluoride and neutral in
nature.

14. B

15. A
Solution for the Q. No. 14 to 15
H5C2 H O H O H
H5C2 H5C2
C C C Step I
 C  Step II
 C
Faster epoxidation due to 
 
H3C C4H9 Me C4H9 
 high reactivity of C C 
 Me O C4H9
P  Q R 

O
||
 3 i H O
C4H9 COOH  C2H5  C Me  CO2  
 ii KMnO /H / 

4
 T  S
H2 /Pt
C4H9 COOH 
 CH3 CH2 CH2 CH2  CH2  OH
 Amyl alcohol
Compound (R) is optically active, it does not contains plane of symmetry and C2 – axis of symmetry. And also
it does not give neutral FeCl3 test.

16. C
Na2CO3 is thermally stable and cannot be decomposed at N.T.P.

17. B
Moles of NaOH is more as compare to NaHCO3 (a > b).
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Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-12

18. D
b = moles of NaHCO3 = 2 × CO2 = 0.02 mole
a = moles of NaOH = moles of NaHCO3 + moles of NaOH reacted with HCl at the end point.
= 0.02 + 0.05
= 0.07
Moles of Na2CO3 = c + moles of Na2CO3 formed from NaHCO3 and NaOH reaction.
Moles of BaCrO4 = c + moles of NaHCO3
c = 0.50 – 0.02
= 0.48
a + b + c = 0.02 + 0.07 + 0.48 = 0.57

SECTION – C
1. 8
1


 K  2
H    w  K a2  K a1 
 K b  
1
 10 14  2
H    5  10 15   107 


 10  
1
H   109  10 7  10 15  10 7  2
1
H   1016  10 22  2
1
H   1016  2  10 8
pH = 8

2. 8

Cl Cl
Br

Br /h alc KOH NCS BH

2

1eq.
    3

1eq. CH COOH
3

Cl
MgCl
Mg / Ether

Ether

F 
Number of chiral center in compound (F) are 4.

3. 6
 a
E1  0.0591pKa  log 
 b
  b 
E 2  0.0591 pKa  log  
  a 
E1 = 0.0591 (pH) E2 = 0.0591(pH)for (SHE)
E1 + E2 = 0.0591[2 × pKa]
E1  E 2
pKa   pH  6.0
2  0.0591

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4. 3
Acidic  CrO3, Mn2O7, SiO2
Basic  MnO, CrO
Amphoteric  SnO2, Ga2O3, MnO2, Cr2O3, BeO.

5. 5
+ N
N N
N N N
N
C C
N N
C
N
+
N
N

6. 5
Tf  iK f m
i = 1.0215


NH3  H2 O  
 NH4  OH


0.1  2
Kb   4.72  10 5
1   
As    i  1

7. 4
A 


 B  C
0
P x xy xy
C 


 B  D
xy yx y
 0
Peq.  P  x  y  2P  0

0
x  y  P
Ceq.  x  y 
 2
 A eq.  P0  x 
(x = 3y)
2
K P1 K C1 x  y 4
  0 
K P2 K C2 P  x  .y 1
8. 8
O

R O R NH
C
Acetals O R , sucrose (C H O ), Caprolactum do not give any ppt. or
R 12 22 11

colour change with (AgNO3 + NH4OH).

9. 3
Ssurr  0, for ideal solution, and non ideal solution.

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Mock Test-9–Paper-1 (100400.1)-PCM-IITJEE-14

 S mix  0 for ideal solution and non ideal solution.

 S univ  0 for ideal solution and non ideal solution.
 G mix  0 for ideal solution and non ideal solution.
 V mix  0 for non ideal minimum boiling azeotropes.
 a, b and c are minimum boiling azeotropes.
 e is maximum boiling azeotropes.
 d and f are ideal solution.
Hence there are only three solution are satisfying the above given set of conditions.

10. 6
O Br Br

Br
HBr
  Br Na / ether

O
O Br Br

Mathematics PART – III

SECTION – A

1. We have to find non negative integral solution of equation 2x + y + z = 21

Note that x can take a maximum value of 10 and a minimum value of 0.
We rearrange equation so that we get an integer equation with y and z as variables, x as a constant
y + z = 21 – 2x
The number of non negative integer solution is 21 – 2x + 2 – 1C1 = 22 – 2x C1 = 22 – 2x
We now add the number of solutions so obtained for all the possible values of x.
10
The total number of solution is therefore   22  2x   132
x 0

n 1
 1 1 
  1  x  x 8  .....   x 2  x 6  x10  .....  dx
4
2. lim
n

r 0
   =
 4r  1 4r  3 
0
1 2 1
 1 x  1 1 
=   1  x 4
  dx =
4  1 x 2
dx  tan1 x 0 
1 x  4
0 0

 2x  y  1    x  2y  3z   0
3. 
 3x  y  z  2     4x  5y  2z  3   0
x y z
Line is parallel to  
1 2 3
So, (2 + )  1 + (1 – 2)  2 + 3  3 = 0
2

3
(3 + 4)  1 + (–1 + 5)  2 + (1 – 2)  3 = 0
1

2

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/4 /4
sec x sec x
4. I e tan x sec x  sec x  tan x  1 dx  e sec 2 xdx
0 0

2 2
5. Let AG = 2x, GD = x and DF = y then xy = 4 and 2x(3x + y) = 36 and 2(9x + 4) = 36 + AC

7. Put 3x = t
 2t 
2 tan1 t  sin1  
 1 t2 
   2 tan1 t t  1
 2t  
sin1  2 
  2 tan1 t 1  t  1
 1 t   1
   2 tan t t 1
–1  3x  1
1 1
 x
3 3

8. TA and CA are angle bisector of asymptotes

9. (x2 – 1) + y(y – 2) = 0 A
y = –x
(x2 – 1) + x(x + 2) = 0  3  1 1 2 
2x2 + 2x – 1 = 0 
 2
,
2 

S
(1, 2)
2  4  8
x
4 A P  1 1
 , 
1  3  2 2
x
2 (–1, 0)
 1  3 1  3 
 , 
 2 2 

2 x
10. e x f  x    x  (0, 1)
e

2 1 1
13. m 
1  1 2
1 1
 
2 5   5 2
m1   
 1 1   2 5 1 
1    
 2 5
1 1
 
2 5
m2 
 1 1 
1    
 2 5

14.–15. |a| = |b| and |c| = 1

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SECTION – C

 2sin  sin x  cos x 2  1  cos x  sin x 

1. lim  
3
x  sin x  cos x 
4

lim  2sin x  sin x  cos x   1 = –1

3
x
4

2. Orthocentre is foot of perpendicular drawn from origin on the plane

6 6
  y 2  4y  8  
3. A   xP  xL  dy =
     2y  7   dy
 4  
0 0

4. Equation of chord will be x cos  + y sin  = 1

Combined equation of OA and OB will be
y2 – 16x(x cos  + y sin ) – 64(x cos  + y sin )2 = 0
Coefficient of x2 + coefficient of y2 = 0
–16 cos  – 64 cos2  + 1 – 64 sin2  = 0
–16 cos  – 63 = 0
63
cos   
16

1 1 1
6. 1 4 1  1 8  1  1 3   11  4  = 9 – 3 – 3 = 3
1 1 2

7. 7 3
C3   4    4 C1  6 3
C2   3   4C2  5 C1  23  4
C3 
= 2240 – {1620 – 240 + 4} = 856
= 856 – all 4 red balls goes to one
= 856 – 24 = 832

4 2
8. Focus is  , 
5 5

10. Let t = tan x


x ,t
2
  1 t  
lim 1  t  1  t  ln    1
t   2t 
  1     1 1  
 lim 1  t  1  t  ln  1    1 = lim 1  t  1  t    2
 .....  1
t    2  t   t    2  t 2  t  
   
  2  
 1  t 1  t 2    1 2 1  t   
= lim 1  t     2
 .....   1 = lim 1  t   1   2
.....   1
t    2  t  2  t    t   2  t 2  t   
= 1 – 2 = –1

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