Professional Documents
Culture Documents
Experimental Analysis of Tribological Properties of Ultrasonically Dispersed Garnet Nanoparticles in SN500 Grade Lubricating Oil
Experimental Analysis of Tribological Properties of Ultrasonically Dispersed Garnet Nanoparticles in SN500 Grade Lubricating Oil
net/publication/308774938
CITATIONS READS
25 240
2 authors:
Some of the authors of this publication are also working on these related projects:
Numerical Analysis of Fractured Femur Bone with Prosthetic Bone Plates View project
All content following this page was uploaded by J. Sunil on 09 April 2018.
For Authors
If you would like to write for this, or any other Emerald publication, then please use our Emerald for Authors service
information about how to choose which publication to write for and submission guidelines are available for all. Please visit
www.emeraldinsight.com/authors for more information.
About Emerald www.emeraldinsight.com
Emerald is a global publisher linking research and practice to the benefit of society. The company manages a portfolio of
more than 290 journals and over 2,350 books and book series volumes, as well as providing an extensive range of online
products and additional customer resources and services.
Emerald is both COUNTER 4 and TRANSFER compliant. The organization is a partner of the Committee on Publication Ethics
(COPE) and also works with Portico and the LOCKSS initiative for digital archive preservation.
Abstract
Purpose – The optimal performance of the machinery is based on lubricants that require frequent monitoring and the analysis of characteristics
such as chemical content, contamination and viscosity. The application of nanoparticles dispersed lubricant in tribology has received remarkable
attention in recent years. This paper aims to investigate the tribological properties of SN500 grade lubricating oil containing garnet nanoparticles.
Design/methodology/approach – In this study, 45-nm-sized garnet particles are ultrasonically dispersed in SN500 grade base lubricant oil. The
effects of viscosity and additive concentration on tribological properties are investigated using a four-ball tester.
Findings – Rolling, reinforcing and film-forming behaviour of dispersed nano-sized garnet additives in the rubbing zone were investigated using
scanning electron microscopy equipped with energy dispersive spectroscopy. The results indicate that the garnet additives can improve the wear
Downloaded by 103.48.181.185 At 05:19 09 April 2018 (PT)
resistance and resistance to relative motion and decrease the friction coefficient of rubbing steel interface by surface polishing and formation of
tribo-film containing Si, C and Mn.
Originality/value – Because of the complex two-phase solid–liquid mixture, there are still limited physical understandings of the friction and wear
reduction mechanisms. Therefore, the present research was undertaken to interpret the possible phenomena.
Keywords Wear resistance, Nanofluids, Lubricant oil, Tribofilm
Paper type Research paper
250
Experimental analysis of tribological properties Industrial Lubrication and Tribology
Maheswaran R. and Sunil J. Volume 70 · Number 2 · 2018 · 250–255
viscosity on the tribological performances of SN500 grade base and density at 29.5°C is 0.877 g/cc. The measured weight
lubricant oil, and different concentrations of garnet–SN500 percentages of garnet particle are separately added with the
grade lubricant oil nanofluids, are evaluated using a four-ball lubricant oil. Further, the mixture is sonicated at 20 kHz for
wear tester. In addition, in situ investigations are performed at 15 minutes, and the nanofluids with different concentrations
the rubbing interfaces using scanning electron microscopy are prepared.
(SEM) equipped with energy dispersive spectroscopy (EDS) to
interpret the possible friction and wear-reduction mechanisms 2.2 Determination of density and kinematic viscosity
with and without nanoparticles dispersion in base lubricant oil. The density of the lubricant oil with and without nano garnet
particles suspension is measured using a pycnometer.
2. Materials and methods Furthermore, temperature and concentration-dependent
Today, different nanomaterials are used as an additive for kinematic viscosity of garnet–lubricant oil nanofluids are
improving the basic properties of lubricant oils. The obtained from the ratio between the dynamic viscosity of
tribological properties of the garnet–lubricant oil nanofluids are nanofluids with and without additive dispersion and its
determined by using four-ball wear testing, where the circular corresponding density values.
floating ball contact of lubricant oil is governed by the oil film
thickness. The film thickness depends upon the various factors 2.3 Friction and wear test
like the viscosity of lubricant, the concentration of additive, According to ASTMD 5183-2005, the tribological tests were
applied load and the coefficient of friction. In general, oxide performed in a four-ball friction and wear tester (Ducom
nanomaterials have good thermal stabilities. Therefore, the Instruments, USA) at ambient temperature (approximately
garnet, composed of different oxides, is chosen as a lubricant 27°C) under the lubrication of SN500 grade raw lubricating
Downloaded by 103.48.181.185 At 05:19 09 April 2018 (PT)
additive for the present work, and their tribological behaviour is oil and the lubricating oil containing garnet nanoparticles.
examined experimentally. Before and after each test, all the components in the test-
section were cleaned thoroughly using hexane solution, and
2.1 Materials and preparation of garnet–lubricant oil dried with hot air. The wear was evaluated according to the
nanofluids average wear scar diameter on the three stationary steel balls.
The garnet–lubricant oil nanofluids are prepared by suspending The balls used for this study were made of chrome alloy steel
natural garnet mineral powders (V.V. Minerals, India) with (AISI standard steel no. E-52100) with a diameter of
SN500 grade base lubricant oil. Nano garnet powders were 12.7 mm; the Rockwell C hardness is 64–66 HRC, and its
prepared by high energy ball-milling at room temperature. The chemical composition is given in Table II. The morphology
SEM morphology of the ball-milled particles show that the of the rubbed surfaces was investigated using a scanning
average particle size is about 45 nm and is dispersed in SN500
electron microscope, and the chemical content of selected
grade lubricant oil by ultrasonic agitation (Sonics & Materials,
friction spots were examined using EDS.
USA), which is shown in Figure 1. The chemical constitutions
of the garnet powder are given in Table I.
The base fluid used in this research is SN500 grade mineral- 3. Results and discussions
based lubricant oil with a kinematic viscosity at 40°C is 78.2 cP Figure 2 shows the temperature-dependent density of the
lubricant oil with and without garnet nanoparticles dispersion.
Figure 1 SEM image of garnet particles after ball-milling The results show that the density of the lubricant oil increases
when additive concentration is increased, and decreases with
an increase in temperature. Furthermore, the suspended garnet
additives in the lubricant oil increased its kinematic viscosity
over the measured temperature range, while decreasing it with
an increase in temperature, as shown in Figure 3. However, the
effect of increased temperature decreased the kinematic
viscosity of garnet–lubricant oil nanofluids, which is higher
than the kinematic viscosity of base lubricant oil at the
measured temperature range. The failure of lubricant oil
between the rubbing surfaces is because of the drop of
kinematic viscosity during extreme pressure conditions.
Furthermore, the drop of the viscosity of garnet–lubricant oil
nanofluids owing to temperature variation is less than that of
additive free lubricant oil, which may provide comparably
better lubricity.
251
Experimental analysis of tribological properties Industrial Lubrication and Tribology
Maheswaran R. and Sunil J. Volume 70 · Number 2 · 2018 · 250–255
Table II Chemical composition of a ball used in four-ball wear test lubricant oil is loaded to 98 N, 294 N and 588 N the average
wear scar diameters are 0.46 mm, 0.85 mm and 1.09 mm,
Chemical constitution Cr C Mn Si P S
respectively. The raw lubricant oil containing 0.25 wt. per cent
Percentage 1.488 1.053 0.44 0.186 0.011 0.006 of garnet nanoparticles reduced the average wear scar
diameters to 0.40 mm, 0.79 mm and 0.97 mm, respectively, for
the unaltered loadings. The reduction percentage of average
Figure 2 Density of lubricant oil with and without additives wear scar diameters of raw lubricant oil dispersed with 0.50 wt.
per cent of nano garnet particles is 39.13, 12.94 and 24.77
per cent, respectively, as compared to that of base lubricant oil.
This shows that the garnet additive significantly reduced the
friction and enhanced the wear resistance property of SN500
grade lubricant oil.
The friction coefficients of four-ball wear test samples
lubricated with raw lubricant oil with and without garnet
nanoparticle dispersions are compared to and exhibited in
Figure 5. The results showed that the friction coefficient of the
raw lubricant oil with nano garnet particles dispersion steadily
decreased when compared to the oil without garnet
nanoparticles dispersion. The coefficient of friction between
the rubbing interfaces at 588 N loading show smaller frictional
coefficient value than that of 294 N loading conditions. At
Downloaded by 103.48.181.185 At 05:19 09 April 2018 (PT)
Figure 3 Effect of temperature on the kinematic viscosity of garnet– 588 N loading condition the active garnet nanoparticles
lubricant oil nanofluids between the rubbing pair may absorb a part of the frictional
force owing to metal–additive interaction, which contributes
the development of tribochemical reaction, and thus, the
frictional coefficient is reduced.
252
Experimental analysis of tribological properties Industrial Lubrication and Tribology
Maheswaran R. and Sunil J. Volume 70 · Number 2 · 2018 · 250–255
Figure 6 SEM macromorphology of wear scar diameter lubricated with base lubricant oil (a-c) and base lubricant oil dispersed with 0.50 wt. per cent
garnet nanoparticles (d-f) under different loads
Downloaded by 103.48.181.185 At 05:19 09 April 2018 (PT)
lubricant oil [Figure 7(a-c)] and the base lubricant oil with nanoparticles [Figures 8(d-f)] under different loading
0.50 wt. per cent garnet nanoparticles [Figure 7(d-f)] under conditions. The EDS spectrum of the samples loaded to
different loading conditions. In situ observation of Figure 7(a-c) 98 N does not indicate any new emerged elements, which is
shows that the worn surface of the steel balls lubricated by shown in Figures 8(a) and 8(d). Nevertheless, dispersed
SN500 grade lubricant oil is abraded and have many sharp ball garnet additives strengthened the C, Cr and Fe constitutions
processing traces in sliding direction owing to the lack of by filling the micropores of rubbing surfaces. Figures 8(d-f)
lubricant oil between the rubbing surfaces. The in situ show that the addition of garnet additives enhances the
observation of Figure 7(d-f) shows that the friction surface of surface strengthening process. Further, Figure 8(e) shows
the steel balls lubricated by SN500 grade lubricant oil with the chemisorption of garnet additive during 294 N loading
garnet additives has comparably fewer furrows and sharp forms a tribo-film containing Si. When the rubbing surfaces
are loaded to 588 N, the dispersed with nano garnet
edges than that of the base lubricant oil, and that the area
additives in the lubricant oil decomposes and reacts with the
between its blunted edges are polished. This demonstrates
surfaces because of shearing, resulting in the formation of
that the spherical nature of the dispersed garnet additives
boundary lubricating tribo-film containing C and Mn,
rolls – as well as embeds – in the micropores of rubbing
which is shown in Figure 8(f).
surfaces. It makes the rubbing surface smooth, which leads to The durability of friction and wear reduction mainly
the decrease in frictional force. The blunted edges and the depends upon the number of additives entered between the
nano polished area due to metal–additive interaction are rubbing zones. According to the concentration and
found on steel surfaces lubricated with garnet nanoparticles, the chemical constitutions of suspended additives in the
showing the direct influences of dispersed additives on the lubricant oil, the friction and wear reduction mechanism
reduction of friction. varies in the rubbing zone. As provided in Table I, the
major chemical constitutions of nano garnet particles are
3.3 Tribochemical reaction oxides, which roll and reinforce at micropores of rubbing
Figure 8 shows the elemental analysis of the specimens zone. These reinforcement actions convert the micropore
lubricated with the base lubricant oil [Figures 8(a-c)], and surface into smooth, and the rolling action involves in the
the lubricant oil contains 0.50 wt. per cent garnet nano polishing. The transformed smooth rubbing spots
253
Experimental analysis of tribological properties Industrial Lubrication and Tribology
Maheswaran R. and Sunil J. Volume 70 · Number 2 · 2018 · 250–255
Figure 7 SEM macromorphology of the worn surface of specimens lubricated with base lubricant oil (a-c) and base lubricant oil dispersed with 0.50 wt.
per cent garnet particles (d-f) under different loads
Downloaded by 103.48.181.185 At 05:19 09 April 2018 (PT)
254
Experimental analysis of tribological properties Industrial Lubrication and Tribology
Maheswaran R. and Sunil J. Volume 70 · Number 2 · 2018 · 250–255
On the basis of the present study, it was confirmed that the Liu, R., Wei, X., Tao, D. and Zhao, Y. (2010), “Study of
garnet additives improved the lubricant properties of SN500 preparation and tribological properties of rare earth
grade base lubricant oil, not only in terms of their anti-wear nanoparticles in lubricating oil”, Tribology International,
properties, but also their ability to reduce friction. Vol. 43 Nos 5/6, pp. 1082-1086.
Olomolehin, Y.K. and Spikes, H. (2009), “Antagonistic
interaction of antiwear additives and carbon black”, Tribology
References Letters, Vol. 37 No. 1, pp. 49-58.
Antusch, S., Dienwiebel, M., Nold, E., Albers, P., Spicher, U. Padgurskas, J., Rukuiza, R., Prosycevas, I. and Kreivaitis, R.
and Scherge, M. (2010), “On the tribochemical action of (2013), “Tribological properties of lubricant additives of Fe,
engine soot”, Wear, Vol. 269 Nos 1/2, pp. 1-12. Cu and Co nanoparticles”, Tribology International, Vol. 60,
Chinas-Castillo, F. and Spikes, H.A. (2003), “Mechanism of pp. 224-232.
action of colloidal solid dispersions”, Journal of Tribology, Qi, X., Jia, Z., Yang, Y. and Fan, B. (2011), “Characterization
Vol. 125 No. 3, pp. 552-557. and auto-restoration mechanism of nanoscale serpentine
Chu, H.Y., Hsu, W.C. and Lin, J.F. (2010), “The anti-scuffing powder as lubricating oil additive under high temperature”,
performance of diamond nano-particles as an oil additive”, Tribology International, Vol. 44 Nos 7/8, pp. 805-810.
Wear, Vol. 268 Nos 7/8, pp. 960-967. Rapport, L., Bilik, Y., Feldman, Y., Homyonfer, M., Cohen,
Dwyer-Joyce, R.S., Sayles, R.S. and Ioannides, E. (1994), “An S.R. and Tenne, R. (1997), “Hollow nanoparticles of WS2
investigation into the mechanisms of closed three-body as potential solid-state lubricants”, Nature, Vol. 387,
abrasive wear”, Wear, Vol. 175 Nos 1/2, pp. 133-142. pp. 791-793.
GU, C., LI, Q., GU, Z. and ZHU, G. (2008), “Study on Song, X., Zheng, S., Zhang, J., Li, W., Chen, Q. and Cao, B.
application of CeO2 and CaCO3 nanoparticles in lubricating (2012), “Synthesis of monodispersed ZnAl2O4
Downloaded by 103.48.181.185 At 05:19 09 April 2018 (PT)
oils”, Journal of Rare Earths, Vol. 26 No. 2, pp. 163-169. nanoparticles and their tribology properties as lubricant
Hernández, B.A., Gonzalez, R., Felgueroso, D., Fernández, additives”, Materials Research Bulletin, Vol. 47 No. 12,
J.E., Fernández, M., R.F., Garcíam, M.A. and Penuelas, I. pp. 4305-4310.
(2007), “Wear prevention behaviour of nanoparticle Tajik, B., Abbassi, A., Avval, M.S. and Najafabadi, M.A.
suspension under extreme pressure conditions”, Wear, (2012), “Ultrasonic properties of suspensions of TiO2 and
Vol. 263 Nos 7/12, pp. 1568-1574. Al2O3 nanoparticles in water”, Powder Technol, Vol. 217,
Hu, Z.S., Dong, J.X., Chen, G.X. and He, J.Z. (2000), pp. 171-176.
“Preparation and tribological properties of nanoparticle Tarasov, S., Kolubaev, A., Belyaev, S., Lerner, M. and Tepper,
lanthanum borate”, Wear, Vol. 243 Nos 1/2, pp. 43-47. F. (2002), “Study of friction reduction by nanocopper
Hu, Z.S., Lai, R., Lou, F., Wang, L.G., Chen, Z.L., Chen, additives to motor oil”, Wear, Vol. 252, pp. 63-69.
G.X. and Dong, J.X. (2002), “Preparation and tribological Xue, Q., Liu, W. and Zhang, Z. (1997), “Friction and wear
properties of nanometer magnesium borate as lubricating oil properties of a surface modified TiO2 nanoparticle as an
additive”, Wear, Vol. 252 Nos 5/6, pp. 370-374. additive in liquid paraffin”, Wear, Vol. 213 Nos 1/2,
Huq, M.Z., Aswath, P.B. and Elsenbaumer, R.L. (2007), pp. 29-32.
“TEM studies of anti-wear films/wear particles generated Yu, L.G., Lian, Y.F. and Xue, Q.J. (1998), “The tribological
under boundary conditions lubrication”, Tribology behaviors of some rare earth complexes as lubricating
International, Vol. 40 No. 1, pp. 111-116. additives”, Wear, Vol. 214 No. 2, pp. 151-155.
Kalin, M., Kogovsek, J. and Remskar, M. (2012), Yu, Y., Gu, J.L., Kang, F.Y. and Kong, X.Q. (2007), “Surface
“Mechanisms and improvements in the friction and wear restoration induced by lubricant additive of natural
behaviour using MoS2 nanotubes as potential oil additives”, minerals”, Applied Surface Science, Vol. 253 No. 18,
Wear, Vols 280/281, pp. 36-45. pp. 7549-7553.
Liu, R.D., Tao, D.H. and Zhao, Y. (2008), “Tribological
performance of rare earth alkylsalicylate as lubrication additive”, Corresponding author
Industrial Lubrication and Tribology, Vol. 60 No. 1, pp. 9-13. Sunil J. can be contacted at: sunil@vvcoe.org
For instructions on how to order reprints of this article, please visit our website:
www.emeraldgrouppublishing.com/licensing/reprints.htm
Or contact us for further details: permissions@emeraldinsight.com
255