055 CHEM 402 Assignment#1 Fall 2020

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Kesignment No. 1 Gubmilted By Nowra flower {WHS 1-055 Gunitied To Br. Gajjad Soo Course Code CHEM - Uo Covse Title Lnorgee Chanishs- Date of Sisorission 18" Ockoler .2020 L0G Errectrve Asoisae! Nlowsen: ~~ Tn a gen Comp len SPecien , the som af, eledtronn — prerert_ in Ake corsa eraial adem , ov ion and there doraked ba Ye ligands called EAN gy he control onsial dons | ion. Caledation of EAN of the Central Metal Mom ov Ton ‘In a Complen Species. EAN the contual mtn adem ov ton OO Gren conPlex specien Gen ot EAN ob the Codizal muial atom = Monie toler Oy the méiad alom - onidakion undoes of He melo atom 4 No. of decrvorms doraked by ligands . = Z~ (ON) + 2x ON EAN Roles Aecoreiog to thy we , a stable conflen species i permed th the EAN oh te tertral enelal Oen—Prerenk «i empl speci ‘se equal fo Yhe homic — qumber say the noble. which flee the cevah = metal alm me Yhe e (ericd of the fericdi table. Ths We is AN si: wc Bai ob eatin ty aso called = alomie qomber «Ue oY noble J ide, When GAN Of te relal ab BOC IKr), 54 (xe) or B6(Rn) , the se & satd qo be typlowed . Examples Mononuclear Carbonyl Having the Metalic Atom with Even Atomic umber. @ Fe(cors Atomic number Of Fee Zs 26 Neo of € donoled by CO meal s He SK2=10 EAN 2 Zen = Wrtlo 2 36 Gi, NCO), torrie nunmloes of Nis 28 Gy Cartons Species. a) Mn(co), = an Species ov anionic Menic 00: oh Mos Zs 2S A 4 ‘ a u e%e Sxlo slo EAN 2 24% = 2S +o oe cs (Mo ceo} eS 41) 4 24g 2 3% Wy NCO), Ronis ao. 4, Ve 222 4 a a 4 4 es WeGKD 212 EQN = 24a 22s = 3S (yeoxy + QB eoKLe % & Contant tyin single nd aie on Odom. a) Malo). c{ Kf Mn 2 Ze 2S 4 4 4 Vaeeu tS OK ow SKID slo Eletron Of = A on 4 CAN 2 Ze 2 UAlosh 2 S44 = 3b by Ho (Oy Brom somber of Eo 24 4 4 a 4 o 2 WX228 Eleekon S Wydegen 2 4 EQN 2 24,844 2 36 Gy Cartoons Med — dimeyise 40 give dinuclens Conrlrona ts. YQ Maz(od. Onwic noe y Mo, = 25%1— So Elector boom 4cCO mekulen = lox2= 20 Elethenn benno Ma-Ma bore) 2 4%22 2 EAN bie tke Man hos . Sy 420422 12 EAN psem ore Mn dem 2 7%/a2 36 by Co, COD, Phonic to» 44 Qo, . Ke SY Elechenn — sere ACD rreleulns BK 2216 Klethom fom one CoCo bond 2 1kK2 22 TAN forte Co ems 2 SU HIGH 2 212 Een YSN Cectom : 72/5 2 %& > C) Pdyrudasw Cartrong ts 6G Mrz) to Elechon feem MQ loan + 2SKr 2 Sw 4 u ILD moles 2 [ox 2220 4 4 one. Mo-Ma bend 2 IX222 EAny os due Mn clemy s So FRO +2 2 12 Ns cr Pye 26 Gh) Co,coys Elechom fem 20D atone p22 TH SH 4 4 RUD utectlen 2 2XB= IG 4 4 one Coty bend 2 [X22 2 Ens Cy, Awe Co cdomy , SWelotr zal 4 one Cotten 2 12, 2 36 4 ian Shee wap Daal ve hyve Gy * Bod ok te e: dorloer “Ay MM val Cok iQ me Fuen! ootet Coleen . a can be cities toy chakerniny * The Somber ene By Matt bank tn Fea Cloya 9 Fes(Cbyn Coad, canons «i Fe, (Coy, Elechons [tom te alm 2 26x22 Sd n w GUO mdlenken = XQ 2 18 EAN Ye ee Fe cdo, in Fex(coy 42 SHB = 10 Na ene Fe coe god > lz 238 Sine EAN Len an “ one Oy Here on. «Fake bord in Fes (to), BY Loy(CO> lechon lyse UConttors + 2X2 2 lod H “ (20D spapss (2 %2 224 EAN A ew adorn = 122 a w ene Ca olen: 8275 aaa EAN) A Cored fos ten 3b bY abvee ey cadh (ohm tH Con(Ouamnlewde Gavech wir otter «three, Co -cdoms Question No.2 Comparison between Cendant coed and Metal carloonyls. Similavities : o he Ugand pest in beth Coarchinalion pod ad vated coveonls \none. pais wld —& doreded fo eral wade atom te yer complex. + Bol kee Mase. luidged ov non-bridged chudue Urchrered comptes — dont attack westene \ bidacbron curs) aererabl jacob tn waler — onlom ay couleat Megas OH gy NM Hed can He bond fo Wales Undeged corpcer dak contain dpa, Mypde cre SHALL on pilot Cobad. Same Ga, dd carbons. ave aho Soluble + aw Be a ot eet A ty Lanes ling de Differences + A coordination comple is Te one inthis contsad alm oy ion ts — Svrmnded by elechon sich — oleate. cy ion row ay ‘tigend. While metal caabor's ove. toordinalion complexes Fy Femition eka wt, castor monouidle gard . A caodinakion Conflsen ave ot matal cotloonss bk ol metal cathenyls ove ceordination — Lomploxen . + Coordiralisn compound contain coordinahe — covallast bond feelers matali Jigen or fi While metal caiterys contain wolal caken bond. So metal Satvont\ | de Me doration a, Alethom by Abe Coban) moles to He vacank ovitel 9 ae wale) carken © bond by yrd ond de po A elechoa —_ bybom pail, a Jo He dovabion % a a bylled A eb malal te vacant anki bordig GT onild ga carbon! Migand » waded eaten TF bond & termed. + Back — bending don't} occer 1 @orclinalion bons be oar in mead tbony ls. + Mout alt the cawvelinahion enpoudy le ve war ii douly\ Laredo Re onieleion State, oy te corked molal dom = wsle mattal Caleon ls we not emeatially colour bd They Cve toltlan fete yellow in Glow, Cwrordinabion conpourl colar rth clomy ev jons ee — Aechon — vich Yipedl Wee motel ebony coven motel odony end an crasee potion i re ° LonPlus a Coovdin akion companohs ore (CocnmaysBrJsoy , [evo Js » Fe cnt), TTete. ond exomples mete eattlonjis Ove (uiCcoyn), Fer Ca, Coy (Wn » Car(cDs eke. © ERAN Adenine The ea in Loorinakion Lompoud pie (BE We dalerning the, sehiiny in nated eodvon'e

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