(2018, CRC Press) CRC Handbook of Thermodynamic Data of Polymer Solutions, Three Volume Set

CRC HANDBOOK OF
THERMODYNAMIC
DATA of
AQUEOUS
POLYMER
SOLUTIONS
Christian Wohlfarth
CRC Press
Boca Raton London New York Washington, D.C.
CRC Press
Taylor & Francis Group
6000 Broken Sound Parkway NW, Suite 300
Boca Raton, FL 33487-2742
© 2004 by Taylor & Francis Group, LLC
CRC Press is an imprint of Taylor & Francis Group, an Informa business
No claim to original U.S. Government works

Version Date: 20130919
International Standard Book Number-13: 978-0-203-99820-5 (eBook - PDF)
This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been
made to publish reliable data and information, but the author and publisher cannot assume responsibility for the valid-
ity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright
holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this
form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may
rectify in any future reprint.
Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or uti-
lized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopy-
ing, microfilming, and recording, or in any information storage or retrieval system, without written permission from the
publishers.
For permission to photocopy or use material electronically from this work, please access www.copyright.com (http://
www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923,
978-750-8400. CCC is a not-for-profit organization that provides licenses and registration for a variety of users. For
organizations that have been granted a photocopy license by the CCC, a separate system of payment has been arranged.
Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for
identification and explanation without intent to infringe.
Visit the Taylor & Francis Web site at
http://www.taylorandfrancis.com
and the CRC Press Web site at
http://www.crcpress.com
Foreword
The knowledge of thermodynamic data of aqueous polymer solutions is important for basic and
applied chemistry and chemical engineering, computational modelling and thermodynamic research. It has
many applications in the fields of biotechnology, membrane science and membrane technology,
environmental and green chemistry, food chemistry and food industry.
Among the existing publications in this field are C. Wohlfarth’s own book Vapor-Liquid
Equilibria of Binary Polymer Solutions (Elsevier, 1994) and his recent CRC Handbook of Thermo-
dynamic Data of Copolymer Solutions (CRC Press, 2001). Liquid-liquid equilibrium data can be found in
Albertson’s book Partition of Cell Particles and Macromolecules (Wiley, 1986), and more recently in
Zaslavsky’s book Aqueous Two-Phase Partitioning. Physical Chemistry and Bioanalytical Applications
(Dekker, 1995). All these data are fairly old and cover a limited number of properties and chemical
systems that represent only a minor portion in comparison with this new book. Commercial electronic
databases do not provide such data. This Handbook offers a new and complete collection on
thermodynamic data of aqueous polymer solutions.
This new book contains low- and high-pressure equilibrium data, vapor-liquid equilibria, liquid-
liquid equilibria, enthalpic and volumetric data, as well as second virial coefficients. This covers all the
necessary areas for researchers and engineers who work in this field. It will help users to retrieve quickly
all the relevant information from the original literature and also help researchers to plan new
measurements where data are missing.
The structure and the contents of this book are organized in a similar way as in the CRC
Handbook of Thermodynamic Data of Copolymer Solutions and this will facilitate the extraction of the
desired new data.
Last but not least, author C. Wohlfarth has been known for his experience in thermodynamics of
polymer solutions for more than 20 years.
I am sure that readers interested in the field of thermodynamic properties of polymer solutions
will benefit from this Handbook and will identify the work that has to be done in the future.
Dr. Henry V. Kehiaian
IUPAC Representative on ICSU Committee on

Data for Science and Technology (CODATA)
PREFACE
Knowledge of thermodynamic data of polymer solutions is a necessity for industrial and

laboratory processes. Such data serve as essential tools for understanding the physical behavior of
polymer solutions, for studying intermolecular interactions, and for gaining insights into the molecular
nature of mixtures. They also provide the necessary basis for any developments of theoretical
thermodynamic models. Scientists and engineers in academic and industrial research need such data and
will benefit from a careful collection of existing data. The CRC Handbook of Thermodynamic Data of
Aqueous Polymer Solutions provides a reliable collection of such data for such polymer solutions from the
original literature.
The Handbook is divided into seven chapters: (1) Introduction, (2) Vapor-Liquid Equilibrium
(VLE) Data of Aqueous Polymer Solutions, (3) Liquid-Liquid Equilibrium (LLE) Data of Aqueous
Polymer Solutions, (4) High-Pressure Phase Equilibrium (HPPE) Data of Aqueous Polymer Solutions, (5)
Enthalpy Changes for Aqueous Polymer Solutions, (6) PVT Data of Polymers and Solutions, and (7)
Second Virial Coefficients (A2) of Aqueous Polymer Solutions. Finally, appendices quickly route the user
to the desired data sets. Thus, the book covers all the necessary areas for researchers and engineers who
work in this field.
In comparison with low-molecular systems, the amount of data for aqueous polymer solutions is
still rather small. About 800 literature sources were perused for the purpose of this handbook, including
some dissertations and diploma papers. About 1000 data sets, i.e., 165 vapor-pressure isotherms, a
number of Henry’s constants, 500 LLE and a small number of HPPE data sets, a number of volumetric
and enthalpic data and some second osmotic virial coefficients, are reported. Additionally, tables of
systems are provided where results were published only in graphical form in the original literature to lead
the reader to further sources. Data are included only if numerical values were published or authors
provided their numerical results by personal communication (and I wish to thank all those who did so). No
digitized data have been included in this data collection. The Handbook is the first complete overview
about this subject in the world’s literature. The closing day for the data collection was May 31, 2003. The
Handbook results from parts of a more general database, Thermodynamic Properties of Polymer Systems,
which is continuously updated by the author. Thus, the user who is in need of new additional data sets is
kindly invited to ask for new information beyond this book via e-mail at wohlfarth@chemie.uni-halle.de.
Additionally, the author will be grateful to users who call his attention to mistakes and make suggestions
for improvements.
The CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions will be useful to
researchers, specialists, and engineers working in the fields of polymer science, physical chemistry,
chemical engineering, material science, biological science and technology, and those developing
computerized predictive packages. The Handbook should also be of use as a data source to Ph.D. students
and faculty in Chemistry, Physics, Chemical Engineering, Biotechnology, and Materials Science
Departments at universities.
Christian Wohlfarth
Merseburg, August 2003
About the Author
Christian Wohlfarth is Associate Professor for Physical Chemistry at Martin Luther University
Halle-Wittenberg, Germany. He earned his degree in Chemistry in 1974 and wrote his Ph.D. thesis on
investigations on the second dielectric virial coefficient and the intermolecular pair potential in 1977, both
at Carl Schorlemmer Technical University Merseburg. In 1985, he wrote his habilitation thesis, Phase
Equilibria in Systems with Polymers and Copolymers, at Technical University Merseburg.
Since then, Dr. Wohlfarth’s main research has been related to polymer systems. Currently, his
research topics are molecular thermodynamics, continuous thermodynamics, phase equilibria in polymer
mixtures and solutions, polymers in supercritical fluids, PVT-behavior and equations of state, and sorption
properties of polymers, about which he has published approximately 100 original papers. He has also built
a database, Thermodynamic Properties of Polymer Systems, and has written the books Vapor-Liquid
Equilibria of Binary Polymer Solutions and CRC Handbook of Thermodynamic Data of Copolymer
Solutions.
He is working on the evaluation, correlation, and calculation of thermophysical properties of pure

compounds and binary mixtures resulting in six volumes of the Landolt-Börnstein New Series. He is a
respected contributor to the CRC Handbook of Chemistry and Physics.
CONTENTS
1. INTRODUCTION
1.1. Objectives of the handbook...............................................................................................1
1.2. Experimental methods involved........................................................................................2
1.3. Guide to the data tables...................................................................................................20
1.4. List of symbols................................................................................................................24
1.5. References.......................................................................................................................26
2. VAPOR-LIQUID EQUILIBRIUM (VLE) DATA

OF AQUEOUS POLYMER SOLUTIONS
2.1. Partial water vapor pressures or water activities
for binary polymer solutions..............................................................................................29
2.2. Partial solvent vapor pressures or solvent activities
for ternary aqueous polymer solutions...............................................................................58
2.3. Classical mass-fraction Henry’s constants of water vapor
in molten polymers............................................................................................................74
2.4. References.........................................................................................................................78
3. LIQUID-LIQUID EQUILIBRIUM (LLE) DATA

3.1. Cloud-point and/or coexistence curves of quasibinary solutions....................................... 81
3.2. Table of systems where binary LLE data were published only in
graphical form as phase diagrams or related figures..........................................................97
3.3. Cloud-point and/or coexistence curves of quasiternary solutions
containing water and at least one polymer.......................................................................105
3.3.1. Nonelectrolyte solutions............ .................................................................... 105
3.3.2. Electrolyte solutions....................................................................................... 167
3.4. Table of systems where ternary LLE data were published only in
graphical form as phase diagrams or related figures........................................................283
3.5. Cloud-point and/or coexistence curves of quasiquaternary solutions
containing water and at least one polymer.......................................................................301
3.5.1. Nonelectrolyte solutions........... ..................................................................... 301
3.5.2. Electrolyte solutions....................................................................................... 315
3.6. Table of systems where quaternary LLE data were published only in
graphical form as phase diagrams or related figures....................................................... 328
3.7. Lower critical (LCST) and/or upper critical (UCST) solution temperatures
of aqueous polymer solutions.......................................................................................... 331
3.8. References.......................................................................................................................339
4. HIGH-PRESSURE PHASE EQUILIBRIUM (HPPE) DATA
4.1. Experimental data of quasibinary polymer solutions.......................................................365
4.2. Table of systems where binary HPPE data were published only
in graphical form as phase diagrams or related figures....................................................369
4.3. Experimental data of quasiternary solutions containing water
and at least one polymer..................................................................................................370
4.4. Table of systems where ternary HPPE data were published only
4.5. References .......................................................................................................................375
5. ENTHALPY CHANGES FOR AQUEOUS POLYMER SOLUTIONS

5.1. Enthalpies of mixing or intermediary enthalpies of dilution,
and partial enthalpies of mixing (at infinite dilution),
or polymer (first) integral enthalpies of solution ............................................................377
5.2. Partial molar enthalpies of mixing at infinite dilution of water
and enthalpies of solution of water vapor in molten polymers
from inverse gas-liquid chromatography (IGC)...............................................................413
5.3. Table of systems where additional information on enthalpy effects
in aqueous polymer solutions can be found.....................................................................416
5.4. References.......................................................................................................................424
6. PVT DATA OF POLYMERS AND SOLUTIONS

6.1. PVT data of some polymers and their aqueous solutions................................................431
6.2. Excess volumes and/or densities of aqueous polymer solutions......................................448
6.3. Table of systems where additional information on volume effects
in aqueous polymer solutions can be found.....................................................................471
6.4. References.......................................................................................................................473
7. SECOND VIRIAL COEFFICIENTS (A2)

7.1. Experimental A2 data.......................................................................................................477
7.2. References.......................................................................................................................485
APPENDICES
Appendix 1 List of systems and properties in order of the polymers......................................487
Appendix 2 List of solvents in alphabetical order...................................................................505
Appendix 3 List of solvents in order of their molecular formulas...........................................507
INDEX.....................................................................................................................................................509
1. INTRODUCTION
1.1. Objectives of the handbook
Knowledge of thermodynamic data of aqueous polymer solutions is a necessity for industrial and
laboratory processes. Furthermore, such data serve as essential tools for understanding the physical
behavior of polymer solutions, for studying intermolecular interactions, and for gaining insights into the
molecular nature of mixtures. They also provide the necessary basis for any developments of theoretical
will benefit from a careful collection of existing data. However, the database for polymer solutions is still
modest in comparison with the enormous amount of data for low-molecular mixtures, and the specialized
database for aqueous polymer solutions is even smaller. On the other hand, aqueous polymer solutions are
gaining increasing commercial interest because of their unique physical properties, and thermodynamic
data are needed for optimizing applications, e.g., separations of complex mixtures of biomolecules,
recovery of antibiotics, precipitation and purification of proteins, separation of lignins from cellulose in
the paper pulping process, extraction of radioactive metal ions like strontium, cesium, actinides or
lanthanides from aqueous systems, formation of membranes, spinning fibers into aqueous media, or
thermoseparating polymers.
Basic information on polymers can be found in the Polymer Handbook (1999BRA). Some data
books on polymer solutions appeared in the early 1990s (1990BAR, 1992WEN, 1993DAN, and
1994WOH), but most data for polymer solutions have been compiled during the last decade. Older liquid-
liquid equilibrium data for aqueous polymer systems were collected in some books dedicated to the
separation of biomolecules by aqueous two-phase systems (1985WAL, 1986ALB, and 1995ZAS). A data
book with information on copolymer solutions appeared in 2001 (2001WOH). No databooks or databases
dedicated specially to aqueous polymer solutions presently exist. Thus, the intention of the Handbook is to
fill this gap and to provide scientists and engineers with an up-to-date compilation from the literature of
the available thermodynamic data on aqueous polymer solutions. The Handbook does not present theories
and models for polymer solution thermodynamics. Other publications (1971YAM, 1990FUJ, 1990KAM,
1999KLE, 1999PRA, and 2001KON) can serve as starting points for investigating those issues. Theories
for aqueous two-phase systems are reviewed by Cabezas (1996CAB). The state of the art for surfactants
and polymers in aqueous solutions is summarized by Holmberg et al. (2003HOL).
The data within this book are divided into six chapters:
• Vapor-liquid equilibrium (VLE) data of binary or ternary aqueous polymer solutions

• Liquid-liquid equilibrium (LLE) data of (quasi) binary, ternary, or quaternary
aqueous polymer solutions
• High-pressure phase equilibrium (HPPE) data of aqueous polymer solutions
• Enthalpy changes for aqueous polymer solutions
• PVT data of polymers and their aqueous solutions as well as excess volumes and
densities
• Second virial coefficients (A2) of aqueous polymer solutions
Data from investigations applying to more than one chapter are divided and appear in the relevant
chapters. Data are included only if numerical values were published or authors provided their results by
personal communication (and I wish to thank all those who did so). No digitized data have been included
in this data collection, but some tables include systems data published in graphical form.
2 CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions
____________________________________________________________________________________
1.2. Experimental methods involved

Vapor-liquid equilibrium (VLE) measurements
Investigations on vapor-liquid equilibrium of polymer solutions can be made by various methods:
1. Absolute vapor pressure measurement

2. Differential vapor pressure measurement
3. Isopiestic sorption/desorption methods, i.e., gravimetric sorption, piezoelectric sorption,
or isothermal distillation
4. Inverse gas-liquid chromatography (IGC) at infinite dilution, IGC at finite concentrations,
and headspace gas chromatography (HSGC)
5. Steady-state vapor-pressure osmometry (VPO)
Experimental techniques for vapor pressure measurements were reviewed in 1975BON and
2000WOH. Methods and results of the application of IGC to polymers and polymer solutions were
reviewed in 1976NES, 1988NES, 1989LLO, 1989VIL, and 1991MU1. Reviews on ebulliometry and/or
vapor-pressure osmometry can be found in 1974TOM, 1975GLO, 1987COO, 1991MAY, and 1999PET.
The measurement of vapor pressures for polymer solutions is generally more difficult and more
time-consuming than that of low-molecular mixtures. The main difficulties can be summarized as follows:
Polymer solutions exhibit strong negative deviations from Raoult’s law. These are mainly due to the large
entropic contributions caused by the difference between the molar volumes of solvents and polymers as
was explained by the classical Flory-Huggins theory about 60 years ago. However, because of this large
difference in molar mass, vapor pressures of dilute solutions do not differ markedly from the vapor
pressure of the pure solvent at the same temperature, even at polymer concentrations of 10-20 wt%. This
requires special techniques to measure very small differences in solvent activities. Concentrated polymer
solutions are characterized by rapidly increasing viscosities with increasing polymer concentration. This
leads to a strong increase in time required to obtain real thermodynamic equilibrium caused by slow
solvent diffusion effects (in or out of a non-equilibrium-state polymer solution). Furthermore, only the
solvent coexists in both phases because polymers do not evaporate. The experimental techniques used for
the measurement of vapor pressures of polymer solutions have to take into account all these effects.
Vapor pressures of polymer solutions are usually measured in the isothermal mode by static
methods. Dynamic methods are seldom applied, e.g., ebulliometry (1975GLO and 1987COO). At least,
one can consider measurements by VPO to be dynamic ones, where a dynamic (steady-state) balance is
obtained. Limits for the applicable ranges of polymer concentration and polymer molar mass, limits for
the solvent vapor pressure and the measuring temperature and some technical restrictions prevent its
broader application, however. Static techniques usually work at constant temperature. The three different
methods (1 through 3 above) were used to determine most of the vapor pressures of polymer solutions in
the literature. All three methods have to solve the problems of establishing real thermodynamic
equilibrium between liquid polymer solution and solvent vapor phase, long-time temperature constancy
during the experiment, determination of the final polymer concentration, and determination of pressure
and/or activity. Absolute vapor pressure measurement and differential vapor pressure methods were
mostly used by early workers. Most recent measurements were done with the isopiestic sorption methods.
Gas-liquid chromatography as IGC closes the gap at high polymer concentrations where vapor pressures
cannot be measured with sufficient accuracy. HSGC can be considered as some combination of absolute
vapor pressure measurement with GLC.
The following text (a short summary from the author’s own review, 2000WOH) explains briefly
the usual experimental equipment and the measuring procedures.
1. Introduction 3
____________________________________________________________________________________
Absolute vapor pressure measurement can be considered the classical technique for this purpose,
because one measures directly the vapor pressure above a solution of known polymer concentration. The
literature gives a variety of absolute vapor pressure apparatuses developed and used by different authors.
Vapor pressure measurement and solution equilibration were often made separately. A polymer sample is
prepared by weighing, the sample flask is evacuated, degassed solvent is introduced into a sample flask
that is sealed thereafter. Samples are equilibrated at elevated temperature in a thermostatted bath for some
weeks. The flask with the equilibrated polymer solution is then connected with the pressure-measuring
device at the measuring temperature. The vapor pressure is measured after reaching equilibrium and the
final polymer concentration is obtained after correcting for the amount of evaporated solvent. Modern
equipment applies electronic pressure sensors and digital technique to measure the vapor pressure. Data
processing can then be made online by computers. A number of problems have to be solved during the
experiment. The solution is usually of an amount of some cm3 and may contain about 1g of polymer or
even more. Degassing is absolutely necessary. All impurities in the pure solvent have to be eliminated.
Equilibration of all prepared solutions is very time consuming (liquid oligomers do not need so much
time, of course). Increasing viscosity makes the preparation of concentrated solutions more and more
difficult with further increasing the amount of polymer. Solutions above 50-60 wt% can hardly be
prepared (depending on the solvent/polymer pair under investigation).
The determination of the volume of solvent vaporized in the unoccupied space of the apparatus is
difficult and can cause serious errors in the determination of the final solvent concentration. To
circumvent the vapor phase correction, one can measure the concentration directly by means, for example,
of a differential refractometer. The contact of solvent vapor with the Hg surface in older equipment may
cause further errors. Complete thermostatting of the whole apparatus is necessary to avoid condensation of
solvent vapor at colder spots. Since it is disadvantageous to thermostat Hg manometers at higher
temperatures, null measurement instruments with pressure compensation were sometimes used. Modern
electronic pressure sensors can be thermostatted within certain temperature ranges. If pressure
measurement is made outside the thermostatted equilibrium cell, the connecting tubes must be heated
slightly above the equilibrium temperature to avoid condensation.
The measurement of polymer solutions with lower polymer concentrations requires very precise
pressure instruments, because the difference to the pure solvent vapor pressure becomes very small with
decreasing amount of polymer. A common consistency test on the basis of the integrated Gibbs-Duhem
equation does not work for vapor pressure data of binary polymer solutions because the vapor phase is
pure solvent vapor. Thus, absolute vapor pressure measurements need very careful handling, plenty of
time and an experienced experimentator. They are not the methods of choice for highly viscous polymer
solutions, and they were seldom applied to aqueous polymer solutions.
The differential method can be compared under some aspects with the absolute method, but it has
some advantages. The measuring principle is to obtain the vapor pressure difference between the pure
solvent and the polymer solution at the measuring temperature. Again, the polymer sample is filled, after
weighing, into a sample flask, the apparatus is evacuated, a desired amount of degassed solvent is distilled
into the sample flask to build the solution and the samples have to be equilibrated for a necessary duration
of time. The complete apparatus is kept at constant measuring temperature and, after reaching equilibrium,
the pressure difference is read from the manometer difference and the concentration is calculated after
correcting the amount of vaporized solvent in the unoccupied space of the equipment. The pure solvent
vapor pressure is usually precisely known from independent experiments.
____________________________________________________________________________________
Difference/differential manometers have some advantages in their construction: they are

comparatively smaller and their resolution is much higher (modern pressure transducers can resolve
differences of 0.1 Pa and less). However, there are the same disadvantages with sample/solution
preparation (solutions of grams of polymer in some cm3 volume, degassing, viscosity), long-time
thermostatting of the complete apparatus because of long equilibrium times (increasing with polymer
molar mass and concentration/viscosity of the solution), correction of unoccupied vapor space, impurities
of the solvent, connection to the Hg surface in older equipment, and the problem of obtaining real
thermodynamic equilibrium (or not) as explained above. Modern equipment uses electronic pressure
sensors instead of Hg manometers and digital technique to measure the vapor pressure. Also,
thermostatting is more precise in recent apparatuses. Problems caused by the determination of the
unoccupied vapor space could be avoided by measuring the absolute vapor pressure as well.
Again, the concentration can be determined independently by using a differential refractometer

and a normalized relation between concentration and refractive index. Degassing of the liquids remains a
necessity. Time for establishing thermodynamic equilibrium could somewhat be shortened by intensive
stirring. In comparison with absolute vapor pressure measurements, differential vapor pressure
measurements with a high resolution for the pressure difference can be applied even for dilute polymer
solutions where the solvent activity is very near to 1 or the vapor pressure of the solution is very close to
the value for the pure solvent (1989HAY). They need more time than VPO measurements, however.
3. Isopiestic sorption/desorption methods
Isopiestic measurements allow a direct determination of solvent activity or vapor pressure in

polymer solutions by using a reference system (a manometer may not have to be applied). There are two
general principles for lowering the solvent activity in the reference system: concentration lowering or
temperature lowering. Isopiestic measurements have to obey the condition that no polymer can vaporize
(as might be the case for lower-molecular oligomers at higher temperatures).
Concentration lowering under isothermal conditions is the classical isopiestic technique,

sometimes also called isothermal distillation. A number of solutions (two is the minimum) are in contact
with each other via their common solvent vapor phase, and solvent evaporates and condenses (this is the
isothermal distillation process) between them as long as the chemical potential of the solvent is equal in
all solutions. At least one solution serves as reference system, i.e., its solvent activity vs. solvent
concentration dependence is precisely known. After an exact determination of the solvent concentration in
all equilibrated solutions (usually by weighing), the solvent activity in all measured solutions is known
from and equal to the activity of the reference solution. This method is almost exclusively used for
aqueous polymer solutions, where salt solutions can be applied as reference systems (e.g., 1990OCH,
1995GRO, 1996LIN). It is a standard method for inorganic salt systems.
Temperature lowering at specified isobaric or isochoric conditions is the most often used
technique for the determination of solvent vapor pressures or activities in polymer solutions. The majority
of measurements for nonaqueous polymer solutions are made using this kind of an isopiestic procedure
where the pure solvent is used as the reference system (see 1994WOH). The equilibrium condition of
equal chemical potential of the solvent in the polymer solution as well as in the reference system is
realized by keeping the pure solvent at a lower temperature (T1) than the measuring temperature (T2) of the
solution. In equilibrium, the vapor pressure of the pure solvent at the lower temperature is then equal to
the partial pressure of the solvent in the polymer solution, i.e., P1s(T1) = P1(T2). Equilibrium is again
established via the common vapor phase for both subsystems.
1. Introduction 5
____________________________________________________________________________________
The vapor pressure of the pure solvent is either known from independent data or measured
additionally in connection with the apparatus. The composition of the polymer solution can be altered by
changing T1 and a wide range of compositions can be studied (between 30-40 wt% and 85-90 wt%
polymer, depending on the solvent). Measurements above 85-90 wt% polymer are subject to increasing
errors because of surface adsorption effects.
A broad variety of experimental equipment is based on this procedure. This isopiestic technique
is the recommended one for most polymer solutions since it is advantageous in nearly all aspects of
measurement. It covers the broadest concentration range. Only very small amounts of polymer are needed
(about 30-50 mg with the classical quartz spring balance, about 100 µg with piezoelectric sorption
detector or microbalance techniques, see below). It is much more rapid than all other methods explained
above, because equilibrium time decreases drastically for such small amounts of polymer and polymer
solution (about 12-24 hours for the quartz spring balance, about 3-4 hours for piezoelectric or
microbalance techniques). The complete isotherm can be measured using a single loading of the
apparatus. Equilibrium is easier to obtain since comparatively small amounts of solvent have to diffuse
into the bulk sample solution. Equilibrium can be tested better by measuring sorption and desorption runs
which must lead to equal results for thermodynamic absorption equilibrium.
The classical concept is the sorption method using a quartz spring balance that measures the
extension of the quartz spring according to Hook’s law (linear relationship, no hysteresis). In this method
a weighed quantity of the (non-volatile) polymer is placed on the pan of the quartz spring balance within a
measuring cell. The determination of spring extension vs. mass has to be made in advance as a calibration
procedure. Reading of the spring extension is usually made by means of a cathetometer. The cell is sealed,
evacuated and thermostatted to the measuring temperature (T2) and the solvent is then introduced into the
measuring cell as solvent vapor. The solvent vapor is absorbed by the polymer sample to form the
polymer solution until thermodynamic equilibrium is reached. The solvent vapor is provided from a
reservoir of either pure liquid solvent thermostatted at a lower temperature (T1) or a reference liquid
solution of known concentration/solvent partial pressure as in the case of the isothermal distillation
procedure as described above.
The following problems have to be solved during the experiment. The equilibrium cell has to be
sealed carefully to avoid any air leakage over the complete duration of the measurements (to measure one
isotherm takes about 14 days). Specially developed thin Teflon sealing rings are preferred to grease. The
polymer sample has to stand the temperature. Changes by thermal aging during the experiment must be
avoided. The temperatures provided by the thermostats must not fluctuate more than ± 0.1 K.
Condensation of solvent vapor at points that become colder than T2 has to be avoided. As was stated by
different experimentalists, additional measurement of the vapor pressure inside the isopiestic sorption
apparatus seems to be necessary if there is some doubt about the real pressure or if no reliable pure
solvent vapor pressure data exist for the investigated temperature range. This direct pressure measurement
has the advantage that absolute pressures can be obtained and pressure fluctuations can be observed. More
modern equipment applies electronic pressure sensors instead of Hg manometers to avoid the problems
caused by the contact of solvent vapor with the mercury surface and to get a better resolution of the
measuring pressure.
Isopiestic vapor sorption can be made using an electronic microbalance (for aqueous polymer
solutions, e.g., 1998HWA) instead of the quartz spring balance. Electronic microbalances are commer-
cially available from a number of producers. Their main advantages are their high resolution and their
ability to allow kinetic measurements. Additionally, experiments using electronic microbalances can be
automated easily and provide computing facilities.
____________________________________________________________________________________
The major disadvantage with some kinds of microbalances is that they cannot be used at high
solvent vapor pressures and so are limited to a relatively small concentration range. However, since thin
polymer films can be applied, this reduces both the time necessary to attain equilibrium (some hours) and
the amount of polymer required, and equilibrium solvent absorption can be obtained also at polymer mass
fractions approaching 1 (i.e., for small solvent concentrations). Depending on their construction, the
balance head is situated inside or outside the measuring apparatus. Problems may arise when it is inside
where the solvent vapor may come into contact with some electronic parts. Furthermore, all parts of the
balance that are inside the apparatus have to be thermostatted to the measuring temperature to enable the
correct equilibration of the polymer solution or even slightly above measuring temperature to avoid
condensation of solvent vapor in parts of the balance. The allowed temperature range of the balance and
its sensitivity to solvent corrosion determine the accessible measuring range of the complete apparatus. A
magnetic suspension balance can be applied instead of an electronic microbalance. The magnetic
suspension technique has the advantage that all sensitive parts of the balance are located outside the
measuring cell because the balance and the polymer solution measuring cell are in separate chambers and
connected by magnetic coupling only.
The most sensitive solvent vapor sorption method is the piezoelectric sorption detector. The
amount of solvent vapor absorbed by a polymer is detected by a corresponding change in frequency of a
piezoelectric quartz crystal coated with a thin film of the polymer because a frequency change is the
response of a mass change at the surface of such a crystal. The frequency of the crystal decreases as mass
increases when the crystal is placed in a gas or vapor medium. The frequency decrease is fairly linear. The
polymer must be coated onto the crystal from a solution with some care to obtain a fairly uniform film.
Measurements can be made at dynamic (vapor flow) or static conditions. With reasonable assumptions for
the stability of the crystal’s base frequency and the precision of the frequency counter employed, the
piezoelectric method allows the detection of as few as 10 ng of solvent using a 10-MHz crystal. This
greatly reduces both the time necessary to attain equilibrium (3-4 hours) and the amount of polymer
required. Because very thin films are applied, equilibrium solvent absorption can be obtained also at
polymer mass fractions approaching 1 (i.e., for small solvent concentrations). Sorption-desorption
hysteresis has never been observed when using piezoelectric detectors. This demonstrates the effect of
reducing the amount of polymer from about 50 mg for the quartz spring sorption technique by an order of
103 for the piezoelectric detector. However, measurements are limited to solvent concentrations well
below the region where solution drops would be formed. On the other hand, measurements can also be
made at higher temperatures and pressures. Limits are set by the stability of the electrical equipment and
the construction of the measuring cell.
4. Gas-liquid chromatography (GLC)
GLC can be used to determine the activity coefficient of a solute in a (molten) polymer at
essentially zero solute concentration. This type of activity coefficient is known as an infinite-dilution
activity coefficient. Because the liquid polymer in the stationary phase acts as a solvent for the very small
amount of an injected solute sample, this technique is often called inverse gas-liquid chromatography
(IGC). However, IGC is not widely used for water (vapor), being the low-molecular solute.
The equipment does not differ in principle very much from that used in analytical GLC. For
operating at infinite dilution, the carrier gas flows directly to the column that is inserted into a
thermostatted oil bath (to get a more precise temperature control than in a conventional GLC oven). The
output of the column is measured with a flame ionization detector or alternately with a thermal
conductivity detector. Helium is used today as the carrier gas (nitrogen was used in earlier work). From
the difference between the retention time of the injected solvent sample and the retention time of a non-
interacting gas (marker gas), thermodynamic equilibrium data can be obtained. Most experiments were
done up to now with packed columns, but capillary columns were used too.
1. Introduction 7
____________________________________________________________________________________
The experimental conditions must be chosen so that real thermodynamic data can be obtained,
i.e., equilibrium bulk absorption conditions. Errors caused by unsuitable gas flow rates, unsuitable
polymer loading percentages on the solid support material and support surface effects as well as any
interactions between the injected sample and the solid support in packed columns, unsuitable sample size
of the injected probes, carrier gas effects, and imprecise knowledge of the real amount of polymer in the
column, can be sources of problems, whether data are nominally measured under real thermodynamic
equilibrium conditions or not, and have to be eliminated. The sizeable pressure drop through the column
must be measured and accounted for. Column preparation is the most difficult and time-consuming task
within the IGC experiment. Two, three or even more columns must be prepared to test the reproducibility
of the experimental results and to check any dependence on polymer loading and sometimes to filter out
effects caused by the solid support. In addition, various tests regarding solvent sample size and carrier gas
flow rate have to be done to find out correct experimental conditions. There is an additional condition for
obtaining real thermodynamic equilibrium data that is caused by the nature of the polymer sample.
Synthetic polymers are usually amorphous or semicrystalline products. Thermodynamic equilibrium data
require the polymer to be in a molten state, however. This means that IGC measurements have to be
performed for our purpose well above the glass transition temperature of the amorphous polymer or even
above the melting temperature of the crystalline parts of a polymer sample. On the other hand, IGC can be
applied to determine these temperatures. Only data at temperatures well above the glass transition
temperature lead to real thermodynamic vapor-liquid equilibrium data. As a rule, the experimental
temperature must exceed the glass transition temperature by about 50 K.
GLC can also be used to determine the partial pressure of a solute in a polymer solution at
concentrations as great as 50 wt% solute. In this case of finite concentration IGC, a uniform background
concentration of the solute is established in the carrier gas. Finite concentration IGC can be extended to
multicomponent systems. Data reduction is somewhat complicated, however. Applications to aqueous
polymer systems are not known.
VLE measurements for polymer solutions can be done by so-called headspace gas chroma-
tography (HSGC), which is practically a combination of static vapor pressure measurement with gas
chromatographic detection (1997KOL). Again, polymer solutions have to be prepared in advance and
have to be equilibrated at the measuring temperature for some weeks before measurement. HSGC
experiments were carried out with an apparatus consisting of a headspace sampler and a normal gas
chromatograph. The thermostatted headspace sampler samples a constant amount of gas phase and injects
this mixture into the gas chromatograph. After separation of the components of the gaseous mixture in a
capillary column, they are detected individually by a thermal conductivity detector. The signals are sent to
an integrator which calculates the peak areas proportional to the amount of gas in the sample volume and
consequently to the vapor pressure. Calibration can be done by measuring the signal of the pure solvent in
dependence on temperature and comparing the data with the corresponding vapor pressure vs. temperature
data. Measurements can be done between about 25 wt% and 85 wt% polymer in the solution (again
depending on temperature, solvent and polymer investigated). In order to guarantee thermodynamic
equilibrium in the sampler, solutions have to be conditioned for at least 24 h at constant temperature in the
headspace sampler before measurement. Additional degassing is not necessary and solvents have to be
purified only to the extent that is necessary to prevent unfavorable interactions in the solution. The
experimental error in the vapor pressures is typically of the order of 1-3%. One great advantage of HSGC
is its capability to measure VLE data not only for binary polymer solutions but also for polymer solutions
in mixed solvents since it provides a complete analysis of the vapor phase in equilibrium. Examples for
aqueous polymer solutions are given by Barth and Wolf (2000BA1, 2000BA2).
The data reduction for infinite dilution IGC starts with the usually obtained parameters of
retention volume or net retention volume which have to be calculated from the measured retention times
and the flow rate of the carrier gas at column conditions.
____________________________________________________________________________________
Vnet = Vr − Vdead (1)
where:
Vnet net retention volume
Vr retention volume
Vdead retention volume of the inert marker gas, dead retention, gas holdup
These net retention volumes are reduced to specific retention volumes, Vg0, by division of
equation (1) with the mass of the liquid (here the liquid is the molten polymer). They are corrected for the
pressure difference between column inlet and outlet pressure, and reduced to a temperature T0 = 273.15 K.
0 V   T0  3( Pin / Pout ) 2 − 1
Vg =  net   3
(2)
 mB   T  2 ( Pin / Pout ) − 1
where:
Vg0 specific retention volume corrected to 0oC = 273.15 K
mB mass of the polymer in the liquid phase within the column
Pin column inlet pressure
Pout column outlet pressure
T measuring temperature
T0 reference temperature = 273.15 K
Theory of GLC provides the relation between Vg0 and thermodynamic data for the low-molecular
component (solvent A) at infinite dilution:
∞ ∞
 PA  RT0  PA  RT0
 L = 0 or  L = 0 (3)
 xA  Vg M B  wA  Vg M A
where:
MA molar mass of the solvent A
MB molar mass of the liquid (molten) polymer B
PA partial vapor pressure of the solvent A at temperature T
R gas constant
xAL mole fraction of solvent A in the liquid solution
wAL mass fraction of solvent A in the liquid solution
The activity coefficients at infinite dilution read, if we neglect interactions to and between carrier
gas molecules (which are normally helium):
 RT   ( B − V L )( P − PAs ) 
γ A∞ =  0 0 s  exp  AA A  (4)
V M P  RT
 g B A   
∞
 RT   ( B − VA L )( P − PA s ) 
Ω A =  0 0 s  exp  AA  (5)
V M P  RT
 g A A   
1. Introduction 9
____________________________________________________________________________________
where:
BAA second virial coefficient of the pure solvent A at temperature T
PAs saturation vapor pressure of the pure liquid solvent A at temperature T
VAL molar volume of the pure liquid solvent A at temperature T
γA activity coefficient of the solvent A in the liquid phase with activity aA = xAγA
ΩA mass fraction-based activity coefficient of the solvent A in the liquid phase with
aA = wAΩA
The standard state pressure P has to be specified. It is common practice by many authors to
define zero pressure as standard pressure since pressures are usually very low during GLC measurements.
Then, equations (4 and 5) change to:
 RT   P s A (VA L − BAA ) 
γ A∞ =  0 0 s  exp   (6)
V M P  RT
 g B A   
∞
 RT0   PA s (VA L − BAA ) 
ΩA = 0 exp 
 V M P s   (7)
 g A A   RT 
One should keep in mind that mole fraction-based activity coefficients γA become very small
values for common polymer solutions and reach a value of zero for MB →∞, which means a limited
applicability at least to oligomer solutions. Therefore, the common literature provides only mass fraction-
based activity coefficients for (high-molecular) polymer/(low-molecular) solvent pairs. The molar mass
MB of the polymeric liquid is an average value (Mn) according to the usual molar-mass distribution of
polymers. Additionally, it is a second average if mixed stationary liquid phases are applied.
Furthermore, thermodynamic VLE data from GLC measurements are provided in the literature as
values for (PA/wA)∞, see equation (3), i.e., classical mass fraction-based Henry’s constants (if assuming
ideal gas phase behavior):
∞
 P  RT
H A, B =  AL  = 0 0 (8)
 wA  Vg M A
Since Vnet = Vr − Vdead, the marker gas is assumed to not be retained by the polymer stationary
phase and will elute at a retention time that is usually very small in comparison with those of the samples
investigated. However, for small retention volumes, values for the mass fraction-based Henry’s constants
should be corrected for the solubility of the marker gas (1976LIU). The apparent Henry’s constant is
obtained from equation (8) above.
−1
app
 M A H Aapp
,B

H A, B = H A, B 1 +  (9)
 M ref H A,ref 
Mref is the molar mass of the marker gas. The Henry’s constant of the marker gas itself,
determined by an independent experiment, need not be known very accurately, as it is usually much larger
than the apparent Henry’s constant of the sample.
____________________________________________________________________________________
5. Vapor-pressure osmometry (VPO)
Vapor-pressure osmometry is, from its name, comparable to membrane osmometry by allowing
the vapor phase to act like a semipermeable membrane, but it is based on vapor pressure lowering or
boiling temperature elevation. Since the direct measure of vapor pressure lowering of dilute polymer
solutions is impractical because of the extreme sensitivity that is required, VPO is in widespread use for
low-molecular and oligomer solutions (i.e., Mn less than 20,000 g/mol) by employing the thermoelectric
method where two matched temperature-sensitive thermistors are placed in a chamber that is
thermostatted to the measuring temperature and where the atmosphere is saturated with solvent vapor. If
drops of pure solvent are placed on both thermistors, the thermistors will be at the same temperature (zero
point calibration). If a solution drop is placed on one thermistor, a temperature difference ∆T, which is
caused by condensation of solvent vapor onto the solution drop, occurs. The obtained temperature
difference is very small, about 10−5 K.
Because solvent transfer effects are measured, VPO is a dynamic method. This leads to a time-
dependent measurement of ∆T. Depending on technical details of the equipment, sensitivity of the
temperature detector, measuring temperature, solvent vapor pressure and polymer concentration in the
solution drop, a steady state for ∆T can be obtained after some minutes. The value of ∆T st is the basis for
thermodynamic data reduction; see below. If measuring conditions do not allow a steady state, an
extrapolation method to ∆T at zero measuring time can be employed for data reduction. Sometimes a
value is used that is obtained after a predetermined time. However, this may lead to some problems with
knowing the exact polymer concentration in the solution. The extrapolation method is somewhat more
complicated and needs experience of the experimenter but gives an exact value of polymer concentration.
Both methods are used within solvent activity measurements where polymer concentrations are higher and
condensation is faster than in common polymer characterization experiments.
Experience has shown that careful selection of solvent and temperature is critical to the success
of the VPO experiment. Nearly all common solvents, including water (e.g., 1999ELI), can be used with
VPO. Usually, there are different thermistor sensors for organic solvents and for water. The measuring
temperature should be chosen so that the vapor pressure of the solvent will be greater than 6,000 Pa, but
not so high as to lead to problems with evaporation from the chamber. Solvent purity is critical, and
volatile impurities and water must be avoided. Greater sensitivity can be achieved by using solvents with
low enthalpies of vaporization. This means that not all desirable polymer/solvent pairs and not all
temperature (pressure) ranges can be investigated by VPO. Additionally, VPO has some inherent sources
of error. These can be attributed to the possible existence of surface films, to differences in diffusion
coefficients in solutions, to appreciably different solution concentrations, to differences in heat
conductivity, to problems with drop size and shape, to the occurrence of reactions in the solution, and to
the presence of volatile solutes. Of course, most errors can be avoided to a good measure by careful
laboratory practice and/or technical improvements, but they must be taken into account when measuring
solvent activities.
The data reduction of vapor-pressure osmometry (VPO) uses the stationary temperature
difference as the starting point for determining solvent activities. There is an analogy to the boiling point
elevation in thermodynamic equilibrium. Therefore, in the steady-state period of the experiment, the
following relation can be applied if one assumes that the steady state is sufficiently near the vapor-liquid
equilibrium and linear non-equilibrium thermodynamics is valid:
RT 2
∆T st = − kVPO ln a A (10)
∆ LV H 0 A
1. Introduction 11
____________________________________________________________________________________
where:
aA activity of solvent A
kVPO VPO-specific constant (must be determined separately)
R gas constant
T measuring temperature (= temperature of the pure solvent drop)
∆T st temperature difference between solution and solvent drops in the steady state
∆LVH0A molar enthalpy of vaporization of the pure solvent A at temperature T
Liquid-liquid equilibrium (LLE) measurements
There are two different situations for the liquid-liquid equilibrium in polymer/solvent systems:
(i) the equilibrium between a dilute polymer solution (sol) and a polymer-rich solution (gel), and
(ii) the equilibrium between the pure solvent and a swollen polymer network (gel).
Only case (i) is considered here. To understand the results of LLE experiments in
polymer/solvent systems, one has to take into account the strong influence of distribution functions on
LLE, because fractionation occurs during demixing, with respect to molar mass distribution (and to
chemical distribution if copolymers are involved). Fractionation during demixing leads to some effects by
which the LLE phase behavior differs from that of an ordinary, strictly binary mixture, because a common
polymer solution is a multicomponent system. Cloud-point curves are measured instead of binodals; and
per each individual feed concentration of the mixture, two parts of a coexistence curve occur below (for
upper critical solution temperature, UCST, behavior) or above the cloud-point curve (for lower critical
solution temperature, LCST, behavior), i.e., produce an infinite number of coexistence data.
Distribution functions of the feed polymer belong only to cloud-point data. On the other hand,
each pair of coexistence points is characterized by two new and different distribution functions in each
coexisting phase. The critical concentration is the only feed concentration where both parts of the
coexistence curve meet each other on the cloud-point curve at the critical point that belongs to the feed
polymer distribution function. The threshold (maximum or minimum corresponding to UCST or LCST
behavior) temperature (or pressure) is not equal to the critical point, since the critical point is to be found
at a shoulder of the cloud-point curve. Details were discussed by Koningsveld (1968KON, 1972KON).
Thus, LLE data have to be specified in the tables as cloud-point or coexistence data, and coexistence data
make sense only if the feed concentration is given. This is not always the case, however.
Experimental methods can be divided into measurements of cloud-point curves, of real

coexistence data, and of critical points.
Due to distinct changes in a number of physical properties at the phase transition border, a
number of methods can be used to determine cloud-points. In many cases, the refractive index change is
determined because refractive indices depend on concentration (with the rare exception of isorefractive
phases) and the sample becomes cloudy when the highly dispersed droplets of the second phase appear at
the beginning of phase separation. Simple experiments observe cloud-points visually. More sophisticated
equipment applies laser techniques and light scattering, where changes in scattering pattern or intensity are
recorded as a function of decreasing/increasing temperature or pressure. The point where first deviations
from a basic line are detected is the cloud-point. Since demixing or phase homogenization requires some
time (especially for highly viscous solutions), special care is to be applied to obtain good data. Around the
critical point, large fluctuations occur (critical opalescence) and scattering data have to be measured at a
90o scattering angle. The determination of the critical point is to be made by independent methods; see
below. Various other physical properties have been applied for detecting liquid-liquid phase separation,
____________________________________________________________________________________
i.e., viscosity, ultrasonic absorption, thermal expansion, dielectric constant, differential thermal analysis
(DTA) or differential scanning calorimetry (DSC), UV- or IR-spectroscopy, and size exclusion chroma-
tography/gel permeation chromatography (SEC, GPC).
To measure real coexistence data is more difficult than to determine cloud-points. This is mainly
due to very long equilibrium times (sometimes weeks), which are necessary for obtaining
thermodynamically correct data in highly viscous solutions. On the other hand, aqueous two-phase
polymer solutions often contain some percent of polymer only and therefore have rather low viscosities
facilitating demixing. The common experimental method is to cool homogeneous solutions in ampoules
very slowly to the desired temperature in the LLE region, and equilibrium is reached after both phases are
sharply separated and clear. After separating both phases, concentrations and distribution functions are
measured. Highly viscous polymer solutions at higher concentrations can be investigated by a modified
ultracentrifuge where the equilibrium is quickly established during cooling by action of gravitational
forces. After some hours, concentrations, phase volume ratios and concentration differences can be
determined.
Special methods are necessary to measure the critical point. Only for solutions of monodisperse
polymers, the critical point is the maximum (or minimum) of the binodal. Binodals of polymer solutions
can be rather broad and flat. Then, the exact position of the critical point can be obtained by the method of
the rectilinear diameter:
I II
(ϕ B − ϕ B ) crit T
− ϕ B ∝ (1 − crit )1−α (11)
2 T
where:
ϕBI volume fraction of the polymer in coexisting phase I
ϕBII volume fraction of the polymer in coexisting phase II
ϕBcrit volume fraction of the polymer at the critical point
T crit critical temperature
α critical exponent
For solutions of polydisperse polymers, such a procedure cannot be used because the critical
concentration must be known in advance to measure its corresponding coexistence curve. Two different
methods were developed to solve this problem: the phase-volume-ratio method (1968KON) where one
uses the fact that this ratio is exactly equal to one only at the critical point, and the coexistence
concentration plot (1969WOL) where an isoplethal diagram of values of ϕBI and ϕBII vs. ϕ0B gives the
critical point as the intersection of cloud-point and shadow curves. Details will not be discussed here.
Treating polymer solutions with distribution functions by continuous thermodynamics is reviewed in
1989RAE, 1990RAE.
High-pressure phase equilibrium (HPPE) measurements
The experimental investigation of high-pressure fluid phase equilibria in polymer solutions is

confronted with the same problems discussed above insofar as the investigated phase equilibria
correspond with a VLE-, LLE-, or VLLE-type behavior, which are the only cases considered here. The
experimental equipment follows on the same techniques, however, extended to high pressure conditions,
using high-pressure cells and autoclaves for turbidimetry, light scattering, viscometry, and others.
1. Introduction 13
____________________________________________________________________________________
There are only a small number of investigations on high-pressure phase equilibria in aqueous
polymer systems. Recent experiments on aqueous systems were made by Rebelo et al. (2001GOM,
2002REB). Sometimes supercritical fluids are involved, i.e., gases/vapors above their critical temperature
and pressure (CO2 and some other fluids). There are some recent reviews on phase behavior of polymers
in systems involving supercritical fluids (1994MCH, 1997KIR, and 1999KIR) that summarize today’s
state of investigation. However, no dedicated reviews about aqueous polymer systems at high pressures
exist.
Measurement of enthalpy changes in polymer solutions
Experiments on enthalpy changes in binary polymer solutions can be made within common
microcalorimeters by applying one of the following three methods:
1. Measurement of the enthalpy change caused by solving a given amount of the solute
polymer in an (increasing) amount of solvent, i.e., the solution experiment
2. Measurement of the enthalpy change caused by mixing a given amount of a concentrated
polymer solution with an amount of pure solvent, i.e., the dilution experiment
3. Measurement of the enthalpy change caused by mixing a given amount of a
liquid/molten polymer with an amount of pure solvent, i.e., the mixing experiment
Care must be taken for polymer solutions with respect to the resolution of the instrument, which
has to be higher than for common solutions with larger enthalpic effects. Usually employed calorimeters
for such purposes are the Calvet-type calorimeters based on heat-flux principle. Details can be found in
1984HEM and 1994MAR.
In particular, one has to distinguish between the following effects for polymer solutions. The
(integral) enthalpy of mixing or the (integral) enthalpy of solution of a binary system is the amount of heat
that must be supplied when nA mole of pure solvent A and nB mole of pure polymer B are combined to
form a homogeneous mixture/solution in order to keep the total system at constant temperature and
pressure.
∆Mh = nAHA + nBHB − (nAH0A + nBH0B) (12a)

∆solh = nAHA + nBHB − (nAH0A + nBH0B) (12b)
where:
∆Mh, ∆solh (integral) enthalpy of mixing or solution
H A, H B partial molar enthalpy of solvent A or polymer B
H0A, H0B molar enthalpy of pure solvent A or pure polymer B
n A, n B amount of substance of solvent A or polymer B
The enthalpy effect might be positive (endothermic solution/mixture) or negative (exothermic

solution/mixture) depending on the ratio nA/nB, i.e., the concentration of the total system. Unfortunately, in
some of the older literature, the definition of the sign of the so-called (integral) heat of solution is
reversed, compared with the enthalpy, occasionally causing some confusion.
The value of the (integral) enthalpy of solution is dependent on the degree of crystallinity for
semicrystalline polymers and, usually to a lesser extent, on the thermal history of glassy polymers. The
(integral) enthalpy of mixing is independent of any crystalline or glassy aspects of the polymer. Thus, the
(integral) enthalpy of mixing can be obtained without difficulties only for liquid/molten polymers mixed
____________________________________________________________________________________
with a solvent. Otherwise, the melting enthalpy of the crystallites and/or the glass enthalpy have to be
determined additionally by independent measurements. As such a procedure is rather difficult and might
cause substantial errors, it is common to measure the (integral) intermediary enthalpy of dilution, i.e., the
enthalpy effect obtained if solvent A is added to an existing homogeneous polymer solution. The
intermediary enthalpy of dilution is the difference between two values of the enthalpy of mixing/solution
corresponding to the concentrations of the polymer solution at the beginning and at the end of the dilution
process. The term integral is often added to these enthalpy changes to describe changes where finite
amounts of substances are mixed. Especially, the integral enthalpy of solution/mixing for a polymer B is
given in a number of literature sources by applying the following two definitions:
• per mole polymer B:
int
∆solHB = ∆solh/nB = ∆solH/xB (13a)
int
∆MHB = ∆Mh/nB = ∆MH/xB (13b)
• per gram polymer B (where the intensive ∆Hs are the specific ones):
int
∆solHB = ∆solh/mB = ∆solH/wB (13c)
int
∆MHB = ∆Mh/mB = ∆MH/wB (13d)
where:
int
∆solHB integral enthalpy of solution of polymer B
int
∆ MH B integral enthalpy of mixing of polymer B
mB mass of polymer B
wB mass fraction of polymer B
xB mole fraction of polymer B
As stated above, the difference between int∆solHB and int∆MHB is determined by any enthalpic
effects caused from solid-liquid phase transition of the crystallites and/or from glass transition and is zero
for liquid/molten polymers.
The term differential is sometimes added to enthalpy changes where infinitesimal (i.e., very
small) amounts were added to a very large amount of either solution or pure component. These enthalpy
changes are usually called partial (molar or specific) enthalpies of solution/mixing:
∆solHB = (∂∆ sol h / ∂nB ) P ,T ,n j = HB − H0B (14a)

∆MHB = (∂∆ M h / ∂nB ) P ,T ,n j = HB − H0B (14b)
with a unit of J/mol. However, for polymer solutions, ∆solHB or ∆MHB is often expressed as the enthalpy
change per unit mass of polymer added which can be obtained from the following derivative:
∆solHB = (∂∆ sol h / ∂mB ) P ,T ,m j (14c)

∆MHB = (∂∆ M h / ∂mB ) P ,T ,m j (14d)
where:
∆solHB partial molar (or specific) enthalpy of solution of the polymer B
∆ MH B partial molar (or specific) enthalpy of mixing of the polymer B
1. Introduction 15
____________________________________________________________________________________
with a unit of J/g. Similar to these definitions one can find results related to one mole of monomers (or
base units). The derivative is then made by applying the base mole fraction of the polymer. The partial
(molar or specific) enthalpy of solution of the polymer B is equal to the so-called differential enthalpy of
solution at finite concentrations which is, for finite concentrations, different from the int∆solHB or int∆MHB
data as defined above. For example, in the case of a binary mixture, one obtains the relation:
∆MHB = ∆MH + (1 − xB)(∂∆MH/∂xB) (15)
which results in different values to int∆MHB. In the case of adding an infinitesimal amount of polymer to
the pure solvent, the partial (molar or specific) enthalpy of solution of the polymer B is properly identified
as the partial enthalpy of solution of the polymer at infinite dilution, ∆solHB∞, or the partial enthalpy of
mixing of the polymer at infinite dilution, ∆MHB∞. Its value at infinite dilution of the polymer is equal to
the so-called first integral enthalpy of solution (unfortunately, sometimes referred to more simply as the
enthalpy of solution of the polymer, but, as discussed above, identical values can only be obtained for
infinite dilution). In practice, the partial (molar or specific) enthalpy of solution of the polymer B is
measured by mixing isothermally a large excess of pure solvent and a certain amount of the polymer to
form a homogeneous solution.
The state of the polymer before dissolution can significantly affect the enthalpy of solution. An
amorphous polymer below its glass transition temperature Tg often dissolves with the release of heat. The
enthalpy of solution of a glassy polymer is usually dependent on temperature and, to some extent, on the
thermal history of the glass-forming process. An amorphous polymer above Tg can show endothermic or
exothermic dissolution behavior depending on the nature of the solvent and the interaction energies
involved as is the case for any enthalpy of mixing. The dissolving of a semicrystalline polymer requires an
additional amount of heat associated with the disordering of crystalline regions. Consequently, its
enthalpy of solution is usually positive and depends on the degree of crystallinity of the given polymer
sample.
The mathematical definition for the partial molar enthalpies of solution/mixing is given for the
solvent A by
∆solHA = (∂∆ sol h / ∂nA ) P ,T ,n j = HA − H0A (16a)

∆MHA = (∂∆ M h / ∂nA ) P ,T ,n j = HA − H0A (16b)
where:
∆solHA partial molar enthalpy of solution of the solvent A
∆ MH A partial molar enthalpy of mixing of the solvent A ( = differential enthalpy of dilution)
nA amount of substance of solvent A
again with a unit of J/mol. It is equal to the so-called differential enthalpy of dilution as a consequence of
adding an infinitesimal amount of solvent to the solution/mixture. The integral enthalpy of dilution for the
solvent is equivalent to the integral molar enthalpy of mixing for the solvent A as defined by:
int
∆MHA = ∆Mh/nA (17)
and, in the case of adding a very small amount of solvent to the pure polymer, the partial molar enthalpy
of solution at infinite dilution of the solvent is obtained. Partial molar enthalpies of mixing (or dilution) of
the solvent are included in this data collection only for cases where they were obtained from calorimetric
experiments.
____________________________________________________________________________________
Generally, it is known that such partial molar enthalpies of mixing (or dilution) of the solvent can
also be determined from the temperature dependence of the activity of the solvent:
∆MHA = R [∂ ln a A / ∂ (1/ T )]P (18)
However, agreement between enthalpy changes measured by calorimetry and results determined
from the temperature dependence of solvent activity data is often of limited quality. Therefore, such data
are not included here. From engineering and also from scientific aspects, the partial molar enthalpy of
mixing at infinite dilution of the solvent in the liquid/molten polymer ∆MHA∞ is of value. Therefore, data
for ∆MHA∞ determined by inverse gas-liquid chromatography (IGC) have been included here.
∞
∆MHA∞ = R [∂ ln Ω A / ∂ (1/ T )]P (19)
where:
∆ M H A∞ partial molar enthalpy of mixing at infinite dilution of the solvent A
ΩA∞ mass fraction-based activity coefficient of the solvent A at infinite dilution
Additionally, the enthalpies of solution at infinite dilution ∆solHA(vap)∞ of water vapor in molten
polymers determined by IGC have been included since IGC is the useful method for such data.
0
∆solHA(vap)∞ = − R [∂ ln Vg / ∂ (1/ T )]P (20)
where:
∆solHA(vap)∞ first integral enthalpy of solution of the vapor of solvent A
(with ∆solHA(vap)∞ = ∆MHA∞ − ∆LVH0A)
Vg0 specific retention volume corrected to 0oC
PVT/density measurement for polymer melt and solution
There are two widely practiced methods for the PVT measurement of polymers and polymer
solutions:
1. Piston-die technique
2. Confining fluid technique
which were described in detail by Zoller in papers and books (e.g., 1986ZOL, 1995ZOL). Thus, a short
summary is sufficient here.
In the piston-die technique, the material is confined in a rigid die or cylinder, which it has to fill
completely. A pressure is applied to the sample as a load on a piston, and the movement of the piston with
pressure and temperature changes is used to calculate the specific volume of the sample. Experimental
problems concerning solid samples need not be discussed here, since only data for the liquid/molten
(equilibrium) state are taken into consideration for this handbook. A typical practical complication is
leakage around the piston when low-viscosity melts or solutions are tested. Seals cause an amount of
friction leading to uncertainties in the real pressure applied. There are commercial devices as well as
laboratory-built machines which have been used in the literature.
1. Introduction 17
____________________________________________________________________________________
In the confining fluid technique, the material is surrounded at all times by a confining (inert)
fluid, often mercury, and the combined volume changes of sample and fluid are measured by a suitable
technique as a function of temperature and pressure. The volume change of the sample is determined by
subtracting the volume change of the confining fluid. A problem with this technique lies in potential
interactions between fluid and sample. Precise knowledge of the PVT properties of the confining fluid is
additionally required. The above-mentioned problems for the piston-die technique can be avoided.
For both techniques, the absolute specific volume of the sample must be known at a single
condition of pressure and temperature. Normally, these conditions are chosen to be 298.15 K and normal
pressure (101.325 kPa). There are a number of methods to determine specific volumes (or densities) under
these conditions. For polymeric samples, hydrostatic weighing or density gradient columns were often
used.
The tables in Chapter 6 provide specific volumes neither at or below the melting transition of
semicrystalline materials nor at or below the glass transition of amorphous samples, since PVT data of
solid polymer samples are non-equilibrium data and depend on sample history and experimental
procedure (which will not be discussed here).
Measurement of densities for aqueous polymer solutions at ordinary pressure is usually made
today by U-tube vibrating densimeters. Such instruments are commercially available. Calibration is made
with pure water when aqueous polymer solutions are investigated. Excess volumes are determined by
VEspez = Vspez − (wAV0A, spez + wBV0B, spez) (21a)

or
VE = (xAMA + xBMB)/ρ − (xAMA/ρA + xBMB/ρB) (21b)
where:
VE, VEspez molar or specific excess volume at temperature T
V0A, spez specific volume of pure solvent A at temperature T
V0B, spez specific volume of pure polymer B at temperature T
ρ density of the mixture at temperature T
ρA, ρB density of pure solvent A or pure polymer B at temperature T
Determination of second virial coefficients A2
There are a couple of methods for the experimental determination of the second virial coefficient:
colligative properties (vapor pressure depression, freezing point depression, boiling point increase,
membrane osmometry), scattering methods (classical light scattering, X-ray scattering, neutron scattering),
sedimentation velocity and sedimentation equilibrium. Details of the special experiments can be found in
textbooks (1972HUG, 1974TOM, 1975CAS, 1975FUJ, 1975GLO, 1987ADA, 1987BER, 1987COO,
1987KRA, 1987WIG, 1991CHU, 1991MAY, 1991MU2, 1992HAR, and 1999PET).
The vapor pressure depression of the solvent in a binary polymer solution, i.e., the difference
between the saturation vapor pressure of the pure solvent and the corresponding partial pressure in the
solution, ∆PA = PAs − PA, is expressed as:
∆PA  1 2 
= VAL cB  + A2 cB + A3cB + ... (22)
PA  Mn 
____________________________________________________________________________________
where:
A2, A3, ... second, third, ... osmotic virial coefficients at temperature T
cB (mass/volume) concentration at temperature T
Mn number-average relative molar mass of the polymer
∆P A PAs − PA, vapor pressure depression of the solvent A at temperature T
The freezing point depression, ∆SLTA, is:
 1 2 
∆ SLTA = ESL cB  + A2 cB + A3cB + ... (23)
 Mn 
and the boiling point increase, ∆LVTA, is:
 1 2 
∆ LV TA = ELV cB  + A2 cB + A3cB + ... (24)
 Mn 
where:
ELV ebullioscopic constant
ESL cryoscopic constant
∆SLTA freezing point temperature difference between pure solvent and solution, i.e., SLTA0 − SLTA
∆LVTA boiling point temperature difference between solution and pure solvent, i.e., LVTA − LVTA0
The osmotic pressure, π , can be described as:
π  1 2 
= RT  + A2cB + A3cB + ... (25)
cB  Mn 
In the dilute concentration region, the virial equation is usually truncated after the second virial
coefficient which leads to a linear relationship. A linearized relation over a wider concentration range can
be constructed if the Stockmayer-Casassa relation between A2 and A3 is applied:
2
AM 
A3 M n =  2 n  (26)
 2 
0.5 0.5
π  RT   A2 M n 
  =  1 + 2 c2  (27)
 c2   Mn 
Scattering methods enable the determination of A2 via the common relation:
KcB 1
= + 2 A2Q ( q )cB + ... (28)
R( q) M w Pz ( q)
1. Introduction 19
____________________________________________________________________________________
with
4π θ
q= sin (29)
λ 2
where:
K a constant that summarizes the optical parameters of a scattering experiment
Mw mass-average relative molar mass of the polymer
Pz(q) z-average of the scattering function
q scattering vector
Q(q) function for the q-dependence of A2
R(q) excess intensity of the scattered beam at the value q
λ wavelength
θ scattering angle
Depending on the chosen experiment (light, X-ray or neutron scattering), the constant K is to be
calculated from different relations. For details see the corresponding textbooks (1972HUG, 1975CAS,
1982GLA, 1986HIG, 1987BER, 1987KRA, 1987WIG, and 1991CHU).
Thermodynamic data from the ultracentrifuge experiment can be obtained either from the
sedimentation velocity (sedimentation coefficient) or from the sedimentation-diffusion equilibrium since
the centrifugal forces are balanced by the activity gradient. The determination of sedimentation and
diffusion coefficients yields the virial coefficients by:
D  1 
( )
  1 − υ B ,spez ρ A = RT 
 s
2
+ 2 A2cB + 3 A3cB + ...  (30)
 MB 
where:
D diffusion coefficient
s sedimentation coefficient
υ B , spez partial specific volume of the polymer
Sedimentation-diffusion equilibrium in an ultracentrifuge also gives a virial series:
(
ω 2 hD 1 − υB , spez ρ A )  ∂∂ lnhc B
  1
 = RT 
2 
+ 2 A2 cB + 3 A3cB + ...  (31)
 D   MB 
where:
hD distance from the center of rotation
ω angular velocity
Both equations are valid for monodisperse polymers only, i.e., for one definite single component
B. For all polydisperse polymers, different averages were obtained for the sedimentation and the diffusion
coefficients which depend on the applied measuring modes and the subsequent calculations. The averages
of MB correspond with averages of D and s and are mixed ones that have to be transformed into the
desired common averages. For details, please see reviews 1975FUJ, 1991MU2, and 1992HAR.
____________________________________________________________________________________
1.3. Guide to the data tables

Characterization of the polymers
Polymers vary by a number of characterization variables. The molar mass and their distribution
function are the most important variables. However, tacticity, sequence distribution, branching, and end
groups determine their thermodynamic behavior in solution too. Unfortunately, much less information is
provided with respect to the polymers that were applied in most of the thermodynamic investigations in
the original literature. For copolymers, the chemical distribution and the average chemical composition
are also to be given. In many cases, the samples are characterized only by one or two molar mass averages
and some additional information (e.g., Tg, ρ, or how and where it was synthesized). Sometimes even this
information is missed.
The molar mass averages are defined as follows:
number average Mn
∑n M Bi Bi ∑w Bi
Mn = i
= i
(32)
∑n i
Bi ∑w
i
Bi / M Bi
mass average Mw
∑n Bi M B2i ∑w M Bi Bi
Mw = i
= i
(33)
∑ni
Bi M Bi ∑w i
Bi
z-average Mz
∑n Bi M B3i ∑w Bi M B2i
Mz = i
= i
(34)
∑n
i
2
Bi M Bi ∑w i
Bi M Bi
viscosity average Mη
1/ a
 ∑ wBi M Bai 
M η =  i 
 (35)
 ∑ wBi 
 i 
where:
a exponent in the viscosity-molar mass relationship
MBi molar mass of the polymer species Bi
nBi amount of substance of polymer species Bi
wBi mass fraction of polymer species Bi
1. Introduction 21
____________________________________________________________________________________
Measures for the polymer concentration
The following concentration measures are used in the tables of this handbook (where B always
denotes the polymer, A denotes the solvent, and in ternary systems C denotes the third component):
mass/volume concentration:
cA = mA/V cB = mB/V (36)
mass fraction:
wA = mA/Σ mi wB = mB/Σ mi (37)
mole fraction:
xA = nA/Σ ni xB = nB/Σ ni with ni = mi/Mi and MB = Mn (38)
volume fraction:
ϕA = (mA/ρA)/Σ (mi/ρi) ϕB = (mB/ρB)/Σ (mi/ρi) (39)
segment fraction:
ψA = xArA/Σ xiri ψB = xBrB/Σ xiri usually with rA = 1 (40)
base mole fraction:
zA = xArA/Σ xiri zB = xBrB/Σ xiri with rB = MB/M0 and rA = 1 (41)
where:
cA (mass/volume) concentration of solvent A
cB (mass/volume) concentration of polymer B
mA mass of solvent A
MB molar mass of the polymer B
Mn number-average relative molar mass
M0 molar mass of a basic unit of the polymer B
nB amount of substance of polymer B
rA segment number of the solvent A, usually rA = 1
rB segment number of the polymer B
V volume of the liquid solution at temperature T
wA mass fraction of solvent A
xA mole fraction of solvent A
zA base mole fraction of solvent A
zB base mole fraction of polymer B
____________________________________________________________________________________
ϕA volume fraction of solvent A

ϕB volume fraction of polymer B
ρA density of solvent A
ρB density of polymer B
ψA segment fraction of solvent A
ψB segment fraction of polymer B
For high-molecular polymers, a mole fraction is not an appropriate unit to characterize

composition. However, for oligomeric products with rather low molar masses, mole fractions were
sometimes used. In the common case of a distribution function for the molar mass, MB = Mn is to be
chosen. Mass fraction and volume fraction can be considered as special cases of segment fractions
depending on the way by which the segment size is actually determined: ri/rA = Mi/MA or ri/rA = Vi/VA =
(Mi/ρi)/(MA/ρA), respectively. Classical segment fractions are calculated by applying ri/rA = VivdW/VAvdW
ratios where hard-core van der Waals volumes, VivdW, are taken into account. Their special values depend
on the chosen equation of state (or simply some group contribution schemes, e.g., 1968BON, 1990KRE)
and have to be specified.
Volume fractions imply a temperature dependence and, as they are defined in equation (39),
neglect excess volumes of mixing and, very often, the densities of the polymer in the state of the solution
are not known correctly. However, volume fractions can be calculated without the exact knowledge of the
polymer molar mass (or its averages). Base mole fractions are sometimes applied for polymer systems in
earlier literature. The value for M0 is the molar mass of a basic unit of the polymer. Sometimes it is chosen
arbitrarily, however, and has to be specified.
Experimental data tables
The data tables in each chapter are provided there in order of the names of the polymers. In this
data book, mostly source-based polymer names are applied. These names are more common in use, and
they are usually given in the original sources, too. Structure-based names, details about their nomenclature
can be found in the Polymer Handbook (1999BRA), are chosen in some single cases only. CAS index
names for polymers are not applied here. Finally, the list of systems and properties in order of the
polymers in Appendix 1 is made by using the names as given in the chapters of this book.
Within types of polymers the individual samples are ordered by their increasing average molar
mass, and, when necessary, systems are ordered by increasing temperature. In ternary systems, ordering is
additionally made subsequently according to the name of the third component in the system. Each data set
begins with the lines for the solution components, e.g., in binary systems
Polymer (B): methylcellulose 1972KAG

−1
Characterization: Mη/g.mol = 70000, degree of substitution about 26.5−32.0 wt%
Research Institute of Textiles, Yokohama, Japan
Solvent (A): water H2O 7732-18-5
where the polymer sample is given in the first line together with the reference. The second line provides
then the characterization available for the polymer sample. The following line gives the solvent’s chemical
name, molecular formula, and CAS-registry number. In this data book, the solvent (A) is always water.
1. Introduction 23
____________________________________________________________________________________
In ternary and quaternary systems, the following lines are either for a second solvent or a second
polymer or a salt or another chemical compound, e.g., in ternary systems with two solvents
Polymer (B): poly(N,N-diethylacrylamide) 2002MA2

Characterization: Mw/g.mol−1 = 19000, synthesized in the laboratory
Solvent (C): methanol CH4O 67-56-1
or, e.g., in ternary systems with a second polymer
Polymer (B): poly(ethylene glycol) 2000SIL

−1 −1
Characterization: Mn/g.mol = 10535, Mw/g.mol = 11589
Sigma Chemical Co., Inc., St. Louis, MO, USA
Polymer (C): maltodextrin
Characterization: Mn/g.mol−1 = 1540, Mw/g.mol−1 = 2017
Loremalt 2030, Companhia Lorenz, Blumenau, SC, Brazil
or, e.g., in quaternary (or higher) systems like
Polymer (B): poly(ethylene glycol) 2001MEL

−1 −1
Salt (C): dipotassium phosphate/monopotassium phosphate
K2HPO4/H2KPO4 7758-11-4/7778-77-0
Component (D): urea CH4N2O 57-13-6
There are some exceptions from this type of presentation within the tables for Henry’s constants, A2
values, UCST/LCST data, and PVT data of pure polymers. These tables are prepared in the forms as
chosen in 2001WOH.
The originally measured data for each single system are then listed together with some comment
lines if necessary. The data are usually given as published, but temperatures are always given in K.
Pressures are sometimes recalculated into kPa or MPa. Enthalpy data are always recalculated into J or kJ,
if necessary. Mass fraction-based Henry’s constants are calculated from published specific retention
volumes, if such data are not provided in the original source. They are always tabulated in MPa.
Because many investigations on liquid-liquid equilibrium in aqueous two-phase systems are

provided in the literature in figures only, Chapter 3 contains additional tables referring to types of systems,
included components, and references. To a smaller extent, such tables are given for Chapters 4 and 5, too.
Furthermore, subchapters 3.3 and 3.5 are divided with respect to systems that are nonelectrolyte
solutions and those containing electrolytes (which can be salts or polyelectrolytes as well).
Final day for including data into this Handbook was May, 31, 2003.
____________________________________________________________________________________
1.4. List of symbols

B, C parameters of the Tait equation
HE excess enthalpy = ∆MH = enthalpy of mixing
HA partial molar enthalpy of solvent A
HB partial molar (or specific) enthalpy of polymer B
H0A molar enthalpy of pure solvent A
H0B molar (or specific) enthalpy of pure polymer B
HA,B classical mass fraction Henry’s constant of solvent vapor A in molten polymer B
∆dilH12 (integral) intermediary enthalpy of dilution ( = ∆MH(2) − ∆MH(1))
∆ MH (integral) enthalpy of mixing
∆solH (integral) enthalpy of solution
int
∆ MH A integral enthalpy of mixing of solvent A ( = integral enthalpy of dilution)
∆MHA∞ partial molar enthalpy of mixing at infinite dilution of the solvent A
int
∆solHA integral enthalpy of solution of solvent A
∆solHA∞ first integral enthalpy of solution of solvent A (= ∆MHA∞ in the case of liquid/molten
polymers and a liquid solvent, i.e., it is different from the values for solutions of
solvent vapors or gases in a liquid/molten polymer ∆solHA(vap)∞ )
int
∆ MH B integral enthalpy of mixing of polymer B
∆ MH B partial molar (or specific) enthalpy of mixing of polymer B
∆MHB∞ partial molar (or specific) enthalpy of mixing at infinite dilution of polymer B
int
∆solHB integral enthalpy of solution of polymer B
∆solHB partial molar (or specific) enthalpy of solution of polymer B
∆solHB∞ first integral enthalpy of solution of polymer B (∆MHB∞ in the case of liquid/molten B)
kVPO VPO-specific constant
M relative molar mass
Mw mass-average relative molar mass
Mη viscosity-average relative molar mass
Mz z-average relative molar mass
MI melting index
1. Introduction 25
____________________________________________________________________________________
P pressure
Pin column inlet pressure in IGC
Pout column outlet pressure in IGC
q scattering vector
R gas constant
T (measuring) temperature
Tg glass transition temperature
T crit critical temperature
T0 reference temperature (= 273.15 K)
∆T st temperature difference between solution and solvent drops in VPO
V, Vspez volume or specific volume at temperature T
VE excess volume at temperature T
VBE partial molar (or specific) excess volume of the polymer B at temperature T
VBE ∞ partial molar (or specific) excess volume of the polymer B at infinite dilution
Vr, Vnet retention volume and net retention volume in IGC
Vdead retention volume of the (inert) marker gas, dead retention, gas holdup in IGC
Vg0 specific retention volume corrected to 0oC in IGC
λ wavelength
π osmotic pressure
θ scattering angle
ω angular velocity
activity aA = xAΩA
____________________________________________________________________________________
1.5. References
1968BON Bondi, A., Physical Properties of Molecular Crystals, Liquids and Glasses, J. Wiley &
Sons, New York, 1968.
1968KON Koningsveld, R. and Staverman, A.J., Liquid-liquid phase separation in multicomponent
polymer solutions I and II, J. Polym. Sci., Pt. A-2, 6, 305, 325, 1968.
1969WOL Wolf, B.A., Zur Bestimmung der kritischen Konzentration von Polymerlösungen,
Makromol. Chem., 128, 284, 1969.
1971YAM Yamakawa, H., Modern Theory of Polymer Solutions, Harper & Row, New York, 1971.
1972HUG Huglin, M.B., Ed., Light Scattering from Polymer Solutions, Academic Press, New York,
1972.
1972KON Koningsveld, R., Polymer solutions and fractionation, in Polymer Science, Jenkins, E.D.,
Ed., North-Holland, Amsterdam, 1972, 1047.
1974TOM Tombs, M.P. and Peacock, A.R., The Osmotic Pressure of Macromolecules, Oxford
University Press, London, 1974.
1975BON Bonner, D.C., Vapor-liquid equilibria in concentrated polymer solutions, Macromol. Sci.
Rev. Macromol. Chem., C13, 263, 1975.
1975CAS Casassa, E.F. and Berry, G.C., Light scattering from solutions of macromolecules, in
Polymer Molecular Weights, Marcel Dekker, New York, 1975, Pt. 1, 161.
1975FUJ Fujita, H., Foundations of Ultracentrifugal Analysis, J. Wiley & Sons, New York, 1975.
1975GLO Glover, C.A., Absolute colligative property methods, in Polymer Molecular Weights,
Marcel Dekker, New York, 1975, Pt. 1, 79.
1976LIU Liu, D.D. and Prausnitz, J.M, Solubilities of gases and volatile liquids in polyethylene and
in ethylene-vinyl acetate copolymers in the region 125-225 oC, Ind. Eng. Chem. Fundam.,
15, 330, 1976.
1976NES Nesterov, A.E. and Lipatov, Yu.S., Obrashchennaya Gasovaya Khromatografiya v Termo-
dinamike Polimerov, Naukova Dumka, Kiev, 1976.
1982GLA Glatter, O. and Kratky, O., Eds., Small-Angle X-Ray Scattering, Academic Press, London,
1982.
1984HEM Hemminger, W. and Höhne, G., Calorimetry: Fundamentals and Practice, Verlag Chemie,
Weinheim, 1984.
1985WAL Walter, H., Brooks, D.E., and Fischer, D., Partitioning in Aqueous Two-Phase Systems:
Theory, Methods, Uses, and Applications to Biotechnology, Academic Press, New York,
1985.
1986ALB Albertson, P.-A., Partition of Cell Particles and Macromolecules, 3rd ed., J. Wiley & Sons,
New York, 1986.
1986HIG Higgins, J.S. and Macconachie, A., Neutron scattering from macromolecules in solution, in
Polymer Solutions, Forsman, W.C., Ed., Plenum Press, New York, 1986, 183.
1986ZOL Zoller, P., Dilatometry, in Encyclopedia of Polymer Science and Engineering, Vol. 5, 2nd
ed., Mark, H. et al., Eds., J. Wiley & Sons, New York, 1986, 69.
1987ADA Adams, E.T., Osmometry, in Encyclopedia of Polymer Science and Engineering, Vol. 10,
2nd ed., Mark, H. et al., Eds., J. Wiley & Sons, New York, 1986, 636.
1987BER Berry, G.C., Light scattering, in Encyclopedia of Polymer Science and Engineering, Vol. 8,
1987COO Cooper, A.R., Molecular weight determination, in Encyclopedia of Polymer Science and
Engineering, Vol. 10, 2nd ed., Mark, H. et al., Eds., J. Wiley & Sons, New York, 1986, 1.
1987KRA Kratochvil, P., Classical Light Scattering from Polymer Solutions, Elsevier, Amsterdam,
1987.
1. Introduction 27
____________________________________________________________________________________
1989RAE Rätzsch, M.T. and Kehlen, H., Continuous thermodynamics of polymer systems, Prog.
Polym. Sci., 14, 1, 1989.
1987WIG Wignall, G.D., Neutron scattering, in Encyclopedia of Polymer Science and Engineering,
Vol. 10, 2nd ed., Mark, H. et al., Eds., J. Wiley & Sons, New York, 1986, 112.
1988NES Nesterov, A.E., Obrashchennaya Gasovaya Khromatografiya Polimerov, Naukova Dumka,
Kiev, 1988.
1989HAY Haynes, C.A., Beynon, R.A., King, R.S., Blanch, H.W., and Prausnitz, J.M., Thermody-
namic properties of aqueous polymer solutions. Poly(ethylene glycol)/dextran, J. Phys.
Chem., 93, 5612, 1989.
1989LLO Lloyd, D.R., Ward, T.C., Schreiber, H.P., and Pizana, C.C., Eds., Inverse Gas Chromato-
graphy, ACS Symposium Series 391, American Chemical Society, Washington, 1989.
1989VIL Vilcu, R. and Leca, M., Polymer Thermodynamics by Gas Chromatography, Elsevier,
Amsterdam, 1989.
1990BAR Barton, A.F.M., CRC Handbook of Polymer-Liquid Interaction Parameters and Solubility
Parameters, CRC Press, Boca Raton, 1990.
1990FUJ Fujita, H., Polymer Solutions, Elsevier, Amsterdam, 1990.
1990KAM Kamide, K., Thermodynamics of Polymer Solutions, Elsevier, Amsterdam, 1990.
1990KRE [Van] Krevelen, D.W., Properties of Polymers, 3rd ed., Elsevier, Amsterdam, 1990.
1990OCH Ochs, L.R., Kabri-Badr, M., and Cabezas, H., An improved isopiestic method to determine
activities in multicomponent mixtures, AIChE-J., 36, 1908, 1900.
1990RAE Rätzsch, M.T. and Wohlfarth, C., Continuous thermodynamics of copolymer systems, Adv.
Polym. Sci., 98, 49, 1990.
1991CHU Chu, B., Laser Light Scattering, Academic Press, New York, 1991.
1991MAY Mays, J.W. and Hadjichristidis, N., Measurement of molecular weight of polymers by
osmometry, in Modern Methods of Polymer Characterization, Barth, H.G. and Mays, J.W.,
Eds., J. Wiley & Sons, New York, 1991, 201.
1991MU1 Munk, P., Polymer characterization using inverse gas chromatography, in Modern Methods
of Polymer Characterization, Barth, H.G. and Mays, J.W., Eds., J. Wiley & Sons, New
York, 1991, 151.
1991MU2 Munk, P., Polymer characterization using the ultracentrifuge, in Modern Methods of
Polymer Characterization, Barth, H.G. and Mays, J.W., Eds., J. Wiley & Sons, New York,
1991, 271.
1992HAR Harding, S.E., Rowe, A.J., and Horton, J.C., Analytical Ultracentrifugation in Biochemistry
and Polymer Science, Royal Society of Chemistry, Cambridge, 1992.
1992WEN Wen, H., Elbro, H.S., and Alessi, P., Polymer Solution Data Collection. I. Vapor-liquid
equilibrium; II. Solvent activity coefficients at infinite dilution; III. Liquid-liquid
equlibrium, Chemistry Data Series, Vol. 15, DECHEMA, Frankfurt am Main, 1992.
1993DAN Danner, R.P. and High, M.S., Handbook of Polymer Solution Thermodynamics, American
Institute of Chemical Engineers, New York, 1993.
1994MAR Marsh, K.N., Ed., Experimental Thermodynamics, Volume 4, Solution Calorimetry,
Blackwell Science, Oxford, 1994.
1994MCH McHugh, M.A. and Krukonis, V.J., Supercritical Fluid Extraction: Principles and
Practice, 2nd ed., Butterworth Publishing, Stoneham, 1994.
1994WOH Wohlfarth, C., Vapour-Liquid Equilibrium Data of Binary Polymer Solutions: Physical
Science Data, 44, Elsevier, Amsterdam, 1994.
1995GRO Grossmann, C., Tintinger, R., Zhu, J., and Maurer, G., Aqueous two-phase systems of
poly(ethylene glycol) and dextran - experimental results and modeling of thermodynamic
properties, Fluid Phase Equil., 106, 111, 1995.
1995ZAS Zaslavsky, B.Y., Aqueous Two-Phase Partitioning. Physical Chemistry and Bioanalytical
Applications, Marcel Dekker Inc., New York, 1995.
1995ZOL Zoller, P. and Walsh, D.J., Standard Pressure-Volume-Temperature Data for Polymers,
Technomic Publishing, Lancaster, 1995.
____________________________________________________________________________________
1996CAB Cabezas, H., Jr., Theory of phase formation in aqueous two-phase systems, J. Chromatogr.
B, 680, 3, 1996.
1996LIN Lin, D.-Q., Mei, L.-H., Zhu, Z.-Q., and Han, Z.-X., An improved isopiestic method for
measurement of water activities in aqueous polymer and salt solutions, Fluid Phase Equil.,
118, 241, 1996.
1997KIR Kiran, E. and Zhuang, W., Miscibility and Phase Separation of Polymers in Near- and
Supercritical Fluids, ACS Symposium Series 670, 2, 1997.
1997KOL Kolb, B. and Ettre, L.S., Static Headspace Gas Chromatography: Theory and Practice,
Wiley-VCH, Weinheim, 1997.
1998HWA Hwang, S., Kim, J., and Yoo, K.-P., Vapor liquid equilibrium data of binary polymer
solutions by vacuum electromicrobalance, J. Chem. Eng. Data, 43, 614, 1998.
1999ELI Eliassi, A., Modarress, H., and Mansoori, G.A., Measurement of activity of water in
aqueous poly(ethylene glycol) solutions, J. Chem. Eng. Data, 44, 52, 1999.
1999BRA Brandrup, J., Immergut, E.H., and Grulke, E.A., Eds., Polymer Handbook, 4th ed., J. Wiley
& Sons, New York, 1999.
1999KIR Kirby, C.F. and McHugh, M.A., Phase behavior of polymers in supercritical fluid solvents,
Chem. Rev., 99, 565, 1999.
1999KLE Klenin, V.J., Thermodynamics of Systems Containing Flexible-Chain Polymers, Elsevier,
Amsterdam, 1999.
1999PET Pethrick, R.A. and Dawkins, J.V., Eds., Modern Techniques for Polymer Characterization,
J. Wiley & Sons, Chichester, 1999.
1999PRA Prausnitz, J.M., Lichtenthaler, R.N., and de Azevedo, E.G., Molecular Thermodynamics of
Fluid Phase Equilibria, 3rd ed., Prentice Hall, Upper Saddle River, NJ, 1999.
2000BA1 Barth, C. and Wolf, B.A., Preferential evaporation of precipitants from polymer solutions in
mixed solvents, Macromol. Rapid Commun., 21, 349, 2000.
2000BA2 Barth, C. and Wolf, B.A., Evidence of ternary interaction parameters for polymer solutions
in mixed solvents from headspace-gas chromatography, Polymer, 41, 8587, 2000.
2000WOH Wohlfarth, C., Methods for the measurement of solvent activity of polymer solutions, in
Handbook of Solvents, Wypych, G., Ed., ChemTec Publishing, Toronto, 2000, 146.
2001GOM Gomes de Azevedo, R., Rebelo, L.P.N., Ramos, A.M., Szydlowski, J., de Sousa, H.C., and
Klein, J., Phase behavior of (polyacrylamides + water) solutions: concentration, pressure
and isotope effects, Fluid Phase Equil., 185, 189, 2001.
2001KON Koningsveld, R., Stockmayer, W.H., and Nies, E., Polymer Phase Diagrams, Oxford
University Press, Oxford, 2001.
2001WOH Wohlfarth, C., CRC Handbook of Thermodynamic Data of Copolymer Solutions, CRC
Press, Boca Raton, 2001.
2002REB Rebelo, L.P.N., Visak, Z.P., de Sousa, H.C., Szydlowski, J., Gomes de Azevedo, R.,
Ramos, A.M., Najdanovic-Visak, V., Nunes da Ponte, M., and Klein, J., Double critical
phenomena in (water + polyacrylamides) solutions, Macromolecules, 35, 1887, 2002.
2003HOL Holmberg, K., Jönsson, B., Kronberg, B., and Lindman, B., Surfactants and Polymers in
Aqueous Solutions, 2nd Ed., J. Wiley & Sons, Ltd., New York, 2003.
2.1. Partial water vapor pressures or water activities for binary

polymer solutions
Polymer (B): dextran 1993GAU

Fluka AG, Buchs, Switzerland
T/K = 293.15
wB 0.0443 0.0974 0.1456 0.1923 0.2212
aA 0.99989 0.99949 0.99876 0.99756 0.99631
T/K = 313.15
wB 0.0417 0.0804 0.1503 0.2006
aA 0.99992 0.99971 0.99881 0.99752
T/K = 333.15
wB 0.0528 0.0872 0.1322 0.2033
aA 0.99989 0.99968 0.99928 0.99776
Polymer (B): dextran 1998KAN, 1999KAN

Lot 21072, Serva, Heidelberg, Germany
T/K = 293.15
wB 0.3546 0.3779 0.3986 0.3985 0.4306 0.4236
aA 0.9934 0.9927 0.9917 0.9912 0.9881 0.9880
Polymer (B): dextran 1998KAN

Pfeifer & Langen, Dormagen, Germany
T/K = 293.15
wB 0.3567 0.3730 0.3842 0.4088 0.4341 0.4436
aA 0.9937 0.9932 0.9908 0.9896 0.9878 0.9868
____________________________________________________________________________________
Polymer (B): dextran 1989HAY

T-70, Pharmacia Fine Chemicals, Piscataway, NJ, USA
T/K = 298.15
wB 0.095 0.121 0.123 0.130 0.132 0.142 0.165 0.180
PA/mmHg 23.753 23.750 23.749 23.747 23.746 23.741 23.736 23.734
wB 0.194 0.229 0.250 0.277 0.350 0.352
PA/mmHg 23.722 23.709 23.701 23.690 23.650 23.648

T/K = 293.15
wB 0.3442 0.3560 0.3867 0.4057 0.3970 0.4068 0.4163 0.4581 0.4440
aA 0.9948 0.9940 0.9912 0.9899 0.9897 0.9896 0.9875 0.9857 0.9849

T/K = 293.15
wB 0.0579 0.0923 0.1616 0.2029 0.2441
aA 0.99990 0.99973 0.99906 0.99823 0.99718
T/K = 313.15
wB 0.0412 0.0826 0.1419 0.1442 0.1866 0.2283 0.2632 0.2732 0.2925
aA 0.99996 0.99981 0.99936 0.99934 0.99881 0.99802 0.99706 0.99675 0.99613
T/K = 333.15
wB 0.0522 0.0884 0.1225 0.1284 0.1966 0.2131 0.2444
aA 0.99993 0.99981 0.99952 0.99963 0.99873 0.99873 0.99796

T/K = 293.15
wB 0.3599 0.3764 0.4069 0.3985 0.3974 0.4371 0.4197 0.4205 0.4468
aA 0.9934 0.9927 0.9912 0.9899 0.9897 0.9881 0.9880 0.9875 0.9868
2. Vapor-Liquid Equilibrium (VLE) Data 31
____________________________________________________________________________________

T/K = 293.15
wB 0.0453 0.0967 0.1049 0.1204 0.1242 0.1332 0.1676 0.1697 0.1760
aA 0.99994 0.99979 0.99973 0.99966 0.99964 0.99961 0.99933 0.99930 0.99923
wB 0.1959 0.2219 0.2250 0.2299 0.2577 0.2596 0.2799 0.2992 0.3003
aA 0.99896 0.99857 0.99854 0.99851 0.99782 0.99778 0.99724 0.99677 0.99673
T/K = 313.15
wB 0.0755 0.0983 0.0990 0.1049 0.1249 0.1295 0.1545 0.1853 0.2158
aA 0.99986 0.99978 0.99979 0.99974 0.99962 0.99959 0.99939 0.99908 0.99862
wB 0.2158 0.2158 0.2168 0.2697 0.2811 0.3356 0.3355
aA 0.99863 0.99861 0.99858 0.99750 0.99715 0.99536 0.99540
T/K = 333.15
wB 0.0886 0.1301 0.1426 0.1728 0.1922 0.2221 0.2636 0.2768 0.2893
aA 0.99990 0.99971 0.99966 0.99943 0.99920 0.99892 0.99812 0.99786 0.99761

T/K = 293.15
wB 0.0555 0.0971 0.1201 0.1532 0.2251 0.2333 0.2373 0.2566 0.3101
aA 0.99995 0.99981 0.99969 0.99949 0.99853 0.99843 0.99839 0.99798 0.99644
T/K = 313.15
wB 0.0806 0.0901 0.0952 0.1074 0.1087 0.1311 0.1596 0.1618 0.1791
aA 0.99990 0.99986 0.99985 0.99981 0.99979 0.99969 0.99950 0.99948 0.99931
wB 0.1970 0.2169 0.2521 0.2745 0.2912 0.3055
aA 0.99909 0.99884 0.99825 0.99779 0.99739 0.99700
T/K = 333.15
wB 0.0638 0.1237 0.1814 0.1936 0.2384
aA 0.99995 0.999795 0.99947 0.99938 0.99892
Polymer (B): dextran 1989HAY

T-500, Pharmacia Fine Chemicals, Piscataway, NJ, USA
T/K = 298.15
wB 0.112 0.130 0.139 0.152 0.161 0.199 0.219 0.225
PA/mmHg 23.756 23.755 23.755 23.753 23.751 23.742 23.737 23.733
continued
____________________________________________________________________________________
continued
wB 0.262 0.333 0.374 0.406
PA/mmHg 23.715 23.687 23.669 23.640
Polymer (B): dextran 1991ZHU, 1995GRO, 1995TIN

T-500, Lot PA08143, Pharmacia Fine Chemicals, Uppsala, Sweden
T/K = 293.15
wB 0.198 0.252 0.290 0.311 0.321 0.352 0.341 0.371 0.390
aA 0.9988 0.9981 0.9971 0.9966 0.9956 0.9939 0.9949 0.9933 0.9920
wB 0.439 0.467 0.476 0.489 0.505 0.521 0.514 0.538 0.552
aA 0.9891 0.9865 0.9852 0.9836 0.9803 0.9788 0.9794 0.9758 0.9749
T/K = 333.15
wB 0.387 0.406 0.419 0.462 0.501 0.608
aA 0.9947 0.9937 0.9906 0.9889 0.9839 0.9784
Polymer (B): N,N-diethylaminoethyl methacrylate/

methyl methacrylate copolymer 1996COR
Characterization: 30.0 mol% methyl methacrylate
T/K = 298.15
wB 0.725 0.826 0.870
aA 0.984 0.968 0.936
Polymer (B): N,N-diethylaminoethyl methacrylate/

methyl methacrylate copolymer 1996COR
T/K = 298.15
wB 0.860 0.885 0.920
aA 0.984 0.968 0.936
Polymer (B): ethylene oxide/propylene oxide copolymer 2000LIW

Characterization: Mn/g.mol−1 = 780, Mw/g.mol−1 = 865, 50.0 mol% ethylene oxide
Zhejiang Univ. Chem. Factory, PR China
T/K = 298.15
wB 0.0455 0.0817 0.1138 0.1453 0.2190 0.3040 0.3850 0.4073 0.5410
aA 0.9987 0.9975 0.9963 0.9952 0.9905 0.9825 0.9716 0.9675 0.9375
____________________________________________________________________________________

T/K = 298.15
wB 0.0715 0.0836 0.1414 0.1558 0.1637 0.1912 0.2677 0.4338 0.6113
aA 0.9987 0.9983 0.9975 0.9963 0.9962 0.9952 0.9905 0.9716 0.9375

−1 −1
Characterization: Mn/g.mol = 3640, Mw/g.mol = 4040, 50.0 mol% ethylene oxide
T/K = 298.15
wB 0.0970 0.1130 0.1522 0.1903 0.2213 0.3028 0.3771 0.4716 0.6612
aA 0.9987 0.9983 0.9975 0.9963 0.9952 0.9905 0.9840 0.9716 0.9375
Polymer (B): hydroxyethylcellulose 2000STR

Characterization: Mw/g.mol−1 = 90000-105000
Polysciences, Inc., Warrington, PA, USA
T/K = 367.65
wB 0.980 0.967 0.954 0.931 0.897 0.863 0.812 0.718
aA 0.149 0.243 0.328 0.442 0.558 0.652 0.751 0.847
Polymer (B): hydroxypropylcellulose 1979ASP

Characterization: Mw/g.mol−1 = 100000, MS = 4
Klucel L, Hercules Inc., Wilmington, DE, USA
T/K = 298.15
ϕB 0.5102 0.5638 0.6234 0.6642 0.7163 0.7969 0.8700 0.9077 0.9269
aA 0.960 0.951 0.934 0.920 0.885 0.847 0.758 0.668 0.606
ϕB 0.9374 0.9473 0.9604 0.9664 0.9725 0.9787 0.9909 0.9945 0.9983
aA 0.548 0.486 0.392 0.356 0.317 0.239 0.113 0.070 0.025
Polymer (B): hydroxypropyl starch 1994KOE

Characterization: Mn/g.mol−1 = 10800, Reppal 100
T/K = 293.15
wB 0.0460 0.0613 0.0949 0.1106 0.1496 0.1804 0.2208 0.3025
aA 0.99986 0.99980 0.99967 0.99958 0.99936 0.99919 0.99881 0.99743
____________________________________________________________________________________
Polymer (B): hydroxypropyl starch 1994KOE

Characterization: Mn/g.mol−1 = 17000, Reppal 200
T/K = 293.15
wB 0.0774 0.1003 0.1257 0.1510 0.1793 0.1920 0.2123 0.2693 0.2703
aA 0.99972 0.99964 0.99942 0.99925 0.99896 0.99885 0.99855 0.99789 0.99771
Polymer (B): hydroxypropyl starch 1999LIN

Characterization: Mw/g.mol−1 = 10000, Reppal 100, Carbamyl AB, Sweden
T/K = 298.15
wB 0.0572 0.1293 0.2055 0.3033 0.4276
aA 0.99973 0.99916 0.9985 0.9971 0.9930
Polymer (B): hydroxypropyl starch 1999LIN

T/K = 298.15
wB 0.0740 0.1468 0.2265 0.3137 0.4512
aA 0.99973 0.99916 0.9985 0.9971 0.9930
Polymer (B): maltopentaose 2002COO

Characterization: M/g.mol−1 = 828.7
T/K = 317.99
xB 0.00000 0.00347 0.01545 0.0216 0.0327 0.0462 0.0470 0.0696
PA/kPa 9.514 9.492 9.330 9.195 8.907 8.452 8.389 7.392
Polymer (B): maltotetraose 2002COO

T/K = 317.99
xB 0.00268 0.00778 0.01232 0.01857 0.0264 0.0369 0.0423 0.0554 0.0949
PA/kPa 9.465 9.426 9.380 9.279 9.154 8.971 8.863 8.561 7.541
Polymer (B): maltotriose 2002COO

T/K = 317.99
xB 0.00205 0.00528 0.00769 0.01015 0.01565 0.02559 0.0309 0.0420 0.0639
PA/kPa 9.487 9.461 9.422 9.399 9.332 9.194 9.135 8.967 8.579
____________________________________________________________________________________
Polymer (B): poly(acrylic acid) 1998HWA

Characterization: Mn/g.mol−1 = 1250000
Aldrich Chem. Co., Inc., Milwaukee, WI, USA
T/K = 303.15
wB 0.9738 0.9697 0.9574 0.9404 0.9157 0.8544 0.7994 0.7164 0.4521
PA/kPa 0.334 0.617 0.990 1.398 1.959 2.593 3.101 3.586 4.019
Polymer (B): polycarbonate-bisphenol-A 1998HWA

−1
Characterization: Mn/g.mol = 24000, Dow Chemical Co., Midland, MI, USA
T/K = 303.15
wB 0.9983 0.9973 0.9962 0.9951 0.9930 0.9904 0.9890 0.9836 0.9676
PA/kPa 0.293 0.526 0.913 1.266 1.934 2.375 2.811 3.654 4.311
Polymer (B): poly(N,N-diethylaminoethyl methacrylate) 1996COR

T/K = 298.15
wB 0.610 0.775 0.840
aA 0.984 0.968 0.936
Polymer (B): polyester (hyperbranched, aliphatic) 2003SEI

−1 −1
hydroxyl functional hyperbranched polyesters produced from poly-
alcohol cores and hydroxy acids, 16 OH groups per macromolecule,
hydroxyl no. = 490-520 mg KOH/g, acid no. = 5-9 mg KOH/g,
Boltorn H20, Perstorp Specialty Chemicals AB, Perstorp, Sweden
wB = 0.10 = constant
T/K 348.2 353.7 361.2 366.5 370.1 375.5 381.0 386.6 393.4
PA/MPa 0.045 0.052 0.069 0.083 0.095 0.113 0.135 0.163 0.203
T/K 398.3 405.4 411.4 415.4
PA/MPa 0.235 0.291 0.346 0.387

continued
____________________________________________________________________________________
continued
T/K 350.6 358.4 363.1 368.2 374.0 378.2 383.1 390.9 403.3
PA/MPa 0.046 0.062 0.073 0.087 0.107 0.123 0.145 0.185 0.271
T/K 408.8 413.2 418.2 423.2 428.7 433.4
PA/MPa 0.320 0.363 0.418 0.477 0.553 0.622

T/K = 393.15
wB 0.817 0.891 0.901 0.922 0.944 0.967 0.972 0.984 0.992
PA/kPa 144.340 125.640 119.650 105.200 87.080 60.560 51.270 36.310 22.350
Polymer (B): polyesteramide (hyperbranched) 2003SEI

Characterization: Mn/g.mol−1 = 1500, Mw/g.mol−1 = 7500, 8 OH groups per
macromolecule, Hybrane H1500, DSM Fine Chemicals,
Geleen, Netherlands
T/K = 393.15
wB 0.919 0.949 0.958 0.972 0.983 0.989 0.994
PA/kPa 105.770 84.500 74.535 61.025 49.210 38.420 30.400
Polymer (B): poly(ethylene glycol) 2002ZAF

Characterization: Mn/g.mol−1 = 190, Merck KGaA, Darmstadt, Germany
T/K = 298.15
wB 0.0796 0.0947 0.1131 0.1215 0.1418 0.1489 0.1877 0.2166 0.2216
aA 0.9762 0.9722 0.9644 0.9643 0.9575 0.9571 0.9435 0.9343 0.9326
wB 0.2641 0.2635 0.2788 0.2859 0.2872 0.3203 0.3365 0.3403 0.3578
aA 0.9188 0.9186 0.9153 0.9101 0.9093 0.9005 0.8942 0.8915 0.8830
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1993GAU

Characterization: Mn/g.mol−1 = 200, Huels AG, Marl, Germany
T/K = 293.15
wB 0.0289 0.0473 0.0908 0.1071 0.1871 0.2529 0.3659
aA 0.99727 0.99539 0.99060 0.98857 0.97632 0.96155 0.92908
T/K = 313.15
wB 0.0344 0.0664 0.0944 0.1473 0.2200 0.2900 0.3833
aA 0.99673 0.99337 0.99014 0.98323 0.97121 0.95683 0.93008
T/K = 333.15
wB 0.0229 0.0352 0.0564 0.0927 0.1418 0.2001 0.2723 0.3457
aA 0.99790 0.99675 0.99459 0.99069 0.98450 0.97563 0.96188 0.94403

T/K = 298.15
wB 0.0909 0.1667 0.2308 0.2857 0.3333 0.3750 0.4118 0.4444 0.5000
aA 0.9905 0.9796 0.9677 0.9554 0.9428 0.9305 0.9187 0.9080 0.8912
Polymer (B): poly(ethylene glycol) 1985HER

Characterization: Mn/g.mol−1 = 200, BDH
T/K = 293.10
wB 0.1493 0.2215 0.5135 0.5735 0.6912 0.8445 0.8932
aA 0.9849 0.9707 0.8654 0.8231 0.7294 0.5170 0.4106
T/K = 313.10
wB 0.1473 0.2220 0.4481 0.5197 0.5332 0.5815 0.6411 0.7120 0.8011
aA 0.9843 0.9706 0.9125 0.8790 0.8721 0.8415 0.7916 0.7422 0.6102
wB 0.8419 0.8670 0.8725 0.8991 0.9180
aA 0.5540 0.4915 0.4806 0.4404 0.3735
T/K = 333.10
wB 0.1493 0.2329 0.3828 0.5586 0.7328 0.7805 0.8375 0.9020 0.9370
aA 0.9849 0.9728 0.9350 0.8753 0.7508 0.6663 0.5937 0.4493 0.3215
Polymer (B): poly(ethylene glycol) 1999NIN

Characterization: Mn/g.mol−1 = 200, Sigma Chemical Co., Inc., St. Louis, MO, USA
T/K = 298.15
wB 0.0995 0.1882 0.2995 0.4016 0.4989 0.5988 0.6972 0.7983 0.8981
aA 0.991 0.976 0.954 0.921 0.874 0.805 0.717 0.587 0.393
____________________________________________________________________________________

T/K = 298.15
wB 0.0658 0.1231 0.1709 0.2019 0.2094 0.2200 0.2327 0.2525 0.2736
aA 0.9863 0.9740 0.9648 0.9574 0.9560 0.9543 0.9493 0.9449 0.9395
wB 0.3233 0.3458 0.3715 0.3761 0.3916 0.3908 0.4016 0.4117 0.4529
aA 0.9271 0.9232 0.9176 0.9162 0.9100 0.9098 0.9068 0.9038 0.8962
Polymer (B): poly(ethylene glycol) 1999ELI

wB 0.3926 0.2987 0.1998 0.1080
T/K = 308.15
aA 0.9410 0.9643 0.9815 0.9917
T/K = 318.15
aA 0.9458 0.9670 0.9821 0.9915
T/K = 328.15
aA 0.9499 0.9690 0.9829 0.9919
T/K = 338.15
aA 0.9533 0.9707 0.9837 0.9924
Polymer (B): poly(ethylene glycol) 1957MAL

Characterization: Mn/g.mol−1 = 300, Oxirane Ltd., Manchester, U.K.
T/K = 308.15
wB 0.000 0.298 0.488 0.659 0.800 0.899 0.950 0.988
PA/mmHg 31.82 30.41 28.65 25.10 20.61 14.88 9.81 3.95
T/K = 328.15
wB 0.000 0.298 0.488 0.660 0.800 0.899 0.950 0.988
PA/mmHg 92.51 89.39 84.77 75.58 63.11 46.07 30.31 12.12
T/K = 338.15
wB 0.000 0.299 0.489 0.662 0.801 0.900 0.951 0.988
PA/mmHg 187.54 181.89 173.54 156.12 132.31 97.13 63.95 24.97
Polymer (B): poly(ethylene glycol) 1968LAK

Characterization: Mn/g.mol−1 = 335, fractionated sample, Union Carbide Corp.
T/K = 297.75
continued
____________________________________________________________________________________
continued
wB 0.01399 0.01885 0.02994 0.03907 0.05416 0.07932 0.1205 0.1707 0.2406
aA 0.9990 0.9987 0.9979 0.9972 0.9958 0.9936 0.9899 0.9849 0.9764
wB 0.2747 0.3582 0.4108 0.5185 0.6505
aA 0.9713 0.9571 0.9417 0.9004 0.8011
T/K = 307.75
wB 0.01400 0.01885 0.02995 0.03910 0.05420 0.07933 0.1208 0.1711 0.2407
aA 0.9993 0.9989 0.9983 0.9977 0.9965 0.9948 0.9912 0.9860 0.9774
wB 0.2748 0.3543 0.4110 0.5188 0.6510
aA 0.9707 0.9614 0.9507 0.9081 0.8259
Polymer (B): poly(ethylene glycol) 1982MED

T/K = 298.15
wB 0.0000 0.5382 0.7102 0.8359 0.8956 0.9335 0.9526 0.9665 0.9809
PA/kPa 3.1631 2.8338 2.4295 1.9602 1.5786 1.2471 0.9824 0.7963 0.4982
wB 0.9924 0.9958 0.9987
PA/kPa 0.2305 0.1248 0.0762

T/K = 298.15
wB 0.0909 0.1667 0.2308 0.2857 0.3333 0.3750 0.4118 0.4737 0.5000
aA 0.9947 0.9879 0.9797 0.9704 0.9603 0.9494 0.9381 0.9265 0.9033

T/K = 298.15
wB 0.0499 0.1495 0.2993 0.4026 0.4989 0.5986 0.6970 0.7989 0.8980
aA 0.998 0.991 0.968 0.943 0.901 0.841 0.760 0.648 0.477
Polymer (B): poly(ethylene glycol) 1995GRO, 1995TIN

−1
Characterization: Mn/g.mol = 414.5, Polymer Standard Services, Mainz, Germany
T/K = 293.15
wB 0.266 0.548 0.563
aA 0.9744 0.8593 0.8567
____________________________________________________________________________________

T/K = 308.15
wB 0.3150 0.2451 0.1792 0.0623 0.0488 0.0305 0.0210 0.0120
aA 0.9691 0.9802 0.9878 0.9968 0.9974 0.9983 0.9991 0.9996
T/K = 318.15
wB 0.3150 0.2451 0.1792 0.0623 0.0488 0.0305 0.0210 0.0120
aA 0.9707 0.9820 0.9888 0.9972 0.9978 0.9987 0.9991 0.9996
T/K = 328.15
wB 0.3150 0.2451 0.1792 0.0623 0.0488 0.0305 0.0210 0.0120
aA 0.9720 0.9828 0.9890 0.9970 0.9976 0.9986 0.9990 0.9995
T/K = 338.15
wB 0.3150 0.2451 0.1792 0.0623 0.0488 0.0305 0.0210 0.0120
aA 0.9710 0.9828 0.9889 0.9971 0.9977 0.9987 0.9993 0.9997

T/K = 293.15
wB 0.0202 0.0442 0.0737 0.1183 0.2021 0.2945 0.3920
aA 0.99936 0.99850 0.99714 0.99457 0.98785 0.97537 0.95360
T/K = 313.15
wB 0.0138 0.0223 0.0516 0.0928 0.1446 0.1873 0.2509 0.2952 0.4196
aA 0.99959 0.99931 0.99823 0.99637 0.99348 0.99041 0.98377 0.97813 0.95246
T/K = 333.15
wB 0.0282 0.0507 0.0769 0.1001 0.1514 0.2234 0.3000
aA 0.99911 0.99831 0.99727 0.99632 0.99367 0.98864 0.98111

−1
Characterization: Mn/g.mol = 600, Sigma Chemical Co., Inc., St. Louis, MO, USA
T/K = 298.15
wB 0.0995 0.1994 0.2993 0.3985 0.4988 0.5984 0.6979 0.7976 0.8972
aA 0.997 0.990 0.976 0.953 0.913 0.855 0.777 0.692 0.423

T/K = 293.10
continued
____________________________________________________________________________________
continued
wB 0.4800 0.5021 0.5998 0.7065 0.7815 0.8082 0.8905 0.9011
aA 0.9182 0.9056 0.8462 0.7591 0.6851 0.6547 0.5280 0.4996
T/K = 313.10
wB 0.2310 0.3266 0.4734 0.5392 0.5395 0.6340 0.6905 0.7028 0.7245
aA 0.9868 0.9738 0.9367 0.9100 0.9089 0.8570 0.8130 0.8071 0.7908
wB 0.7470 0.8083 0.8368 0.8473
aA 0.7661 0.6938 0.6658 0.6518
T/K = 333.10
wB 0.2670 0.3662 0.4172 0.5672 0.6737 0.7644 0.8261
aA 0.9858 0.9729 0.9633 0.9186 0.8644 0.7953 0.7266

T/K = 297.75
wB 0.01342 0.01741 0.02474 0.03894 0.04939 0.06934 0.10640 0.1760 0.2157
aA 0.9996 0.9995 0.9992 0.9986 0.9982 0.9974 0.9958 0.9917 0.9885
wB 0.2593 0.3092 0.3982 0.5330 0.7241
aA 0.9840 0.9740 0.9439 0.8784 0.6817
T/K = 307.75
wB 0.01342 0.01741 0.02475 0.03897 0.04941 0.06939 0.10650 0.1761 0.2162
aA 0.9996 0.9995 0.9993 0.9988 0.9984 0.9978 0.9957 0.9927 0.9894
wB 0.2594 0.3094 0.3985 0.5334 0.7249
aA 0.9844 0.9767 0.9530 0.8938 0.7160

Characterization: Mn/g.mol−1 = 943.1, Polymer Standard Services, Mainz, Germany
T/K = 293.15
wB 0.322 0.576 0.595
aA 0.9744 0.8593 0.8567
Polymer (B): poly(ethylene glycol) 1990OCH

Lot 19F-0037, Sigma Chemical Co., Inc., St. Louis, MO, USA
T/K = 298.15
wB 0.1547 0.1923 0.2243 0.2411 0.2998 0.3000 0.3270 0.3525 0.3711
aA 0.9944 0.9915 0.9893 0.9875 0.9801 0.9787 0.9748 0.9699 0.9660
____________________________________________________________________________________

T/K = 298.15
wB 0.1100 0.1444 0.2324 0.2454 0.2699 0.3243 0.3649 0.3921 0.4381
aA 0.9939 0.9922 0.9856 0.9842 0.9811 0.9767 0.9748 0.9721 0.9669
wB 0.4562 0.4652 0.4884 0.4889
aA 0.9639 0.9637 0.9593 0.9583
Polymer (B): poly(ethylene glycol) 1996LIN

Characterization: Mn/g.mol−1 = 990-1100
T/K = 298.15
wB 0.2146 0.2362 0.2748 0.3248 0.4357
aA 0.9895 0.9873 0.9824 0.9739 0.9431

T/K = 298.15
wB 0.0909 0.1667 0.2308 0.3333 0.3750 0.4118 0.4444 0.4737 0.5000
aA 0.9975 0.9936 0.9884 0.9742 0.9656 0.9560 0.9456 0.9344 0.9227

−1
Characterization: Mn/g.mol = 1000, Shanghai Chemical Reagent Factory, PR China
T/K = 298.15
wB 0.0205 0.0288 0.0394 0.0459 0.0750 0.1166 0.1240 0.1715
aA 0.99928 0.99905 0.9986 0.9985 0.9975 0.9960 0.9956 0.9933

T/K = 298.15
wB 0.0493 0.0986 0.1478 0.1971 0.2957 0.3943 0.4929
aA 0.999 0.998 0.995 0.993 0.978 0.961 0.921
____________________________________________________________________________________

Characterization: Mn/g.mol−1 = 1450, Mw/g.mol−1 = 1550, Huels AG, Marl, Germany
T/K = 293.15
wB 0.0200 0.0248 0.0347 0.0490 0.0501 0.0536 0.0729 0.0999 0.1077
aA 0.99972 0.99965 0.99947 0.99919 0.99918 0.99912 0.99864 0.99786 0.99757
wB 0.1183 0.1208 0.1251 0.1318 0.1458 0.1518 0.1997 0.2516 0.3191
aA 0.99719 0.99711 0.99689 0.99657 0.99600 0.99578 0.99270 0.98802 0.97905
T/K = 313.15
wB 0.0182 0.0268 0.0473 0.0665 0.0815 0.0861 0.0861 0.1170 0.1179
aA 0.99977 0.99964 0.99928 0.99890 0.99856 0.99841 0.99844 0.99751 0.99748
wB 0.1292 0.1484 0.1548 0.1622 0.1692 0.1881 0.2025 0.2540 0.3029
aA 0.99712 0.99637 0.99611 0.99585 0.99549 0.99453 0.99369 0.98998 0.98520
T/K = 333.15
wB 0.0420 0.0594 0.0736 0.0888 0.1332 0.1428 0.1502 0.2225 0.2987
aA 0.99944 0.99913 0.99881 0.99857 0.99747 0.99729 0.99699 0.99368 0.98886

T/K = 298.15
wB 0.0496 0.0993 0.1489 0.1985 0.2978 0.3975 0.4962 0.5985 0.6941
aA 0.998 0.997 0.996 0.994 0.983 0.962 0.925 0.870 0.795

−1
Characterization: Mn/g.mol = 1460, fractionated sample, Union Carbide Corp.
T/K = 297.75
wB 0.01152 0.01684 0.03381 0.05041 0.07580 0.1157 0.1565 0.1846 0.3018
aA 0.9998 0.9996 0.9992 0.9987 0.9977 0.9961 0.9940 0.9914 0.9801
wB 0.4002 0.5085 0.6221
aA 0.9522 0.9083 0.8520
T/K = 307.75
wB 0.01152 0.01685 0.03382 0.05047 0.07592 0.1159 0.1570 0.1846 0.3019
aA 0.9998 0.9996 0.9992 0.9987 0.9979 0.9964 0.9947 0.9929 0.9802
wB 0.4004 0.5089 0.6227
aA 0.9603 0.9251 0.8654
____________________________________________________________________________________

T/K = 293.10
wB 0.3454 0.4631 0.5437 0.5825 0.6378
aA 0.9714 0.9358 0.8964 0.8732 0.8346
T/K = 313.10
wB 0.5035 0.5995 0.6095 0.6259 0.7223 0.8175
aA 0.9392 0.8958 0.8903 0.8823 0.8178 0.7379
T/K = 333.10
wB 0.5746 0.6481 0.7071 0.7734
aA 0.9333 0.9037 0.8709 0.8284
Polymer (B): poly(ethylene glycol) 1994HAM

Huels AG, Marl, Germany
T/K = 293.15
wB 0.05002 0.09934 0.16634 0.23897
aA 0.99942 0.99846 0.99601 0.99064
T/K = 313.15
wB 0.04796 0.09947 0.16593 0.24510 0.33130
aA 0.99950 0.99874 0.99671 0.99270 0.98531

T/K = 293.15
wB 0.0253 0.0490 0.0571 0.0780 0.0871 0.0953 0.1070 0.1280 0.1521
aA 0.99978 0.99954 0.99941 0.99904 0.99886 0.99865 0.99837 0.99771 0.99668
T/K = 313.15
wB 0.0231 0.0299 0.0402 0.0571 0.0830 0.0935 0.1010 0.1037 0.1117
aA 0.99982 0.99976 0.99965 0.99945 0.99905 0.99886 0.99871 0.99866 0.99848
wB 0.1189 0.1213 0.1417 0.1537 0.1728 0.2145 0.2389
aA 0.99830 0.99821 0.99766 0.99726 0.99657 0.99461 0.99311
T/K = 333.15
wB 0.0463 0.0489 0.0788 0.0801 0.1144 0.1472 0.1748 0.2257 0.2993
aA 0.99965 0.99965 0.99930 0.99928 0.99874 0.99807 0.99733 0.99552 0.99157
____________________________________________________________________________________

T/K = 298.15
wB 0.0909 0.1667 0.2857 0.3333 0.3750 0.4118 0.4444 0.4737 0.5000
aA 0.9989 0.9961 0.9860 0.9789 0.9706 0.9613 0.9510 0.9400 0.9284

T/K = 328.15
wB 0.499 0.702 0.844 0.950 0.970
PA/mmHg 113.76 102.62 89.45 61.74 47.10
T/K = 338.15
wB 0.499 0.704 0.765 0.846 0.904 0.950 0.970 0.990
PA/mmHg 181.72 166.34 158.70 145.01 127.01 99.26 75.03 34.36

T/K = 298.15
wB 0.0993 0.1489 0.1988 0.2980 0.3972 0.4964
aA 0.998 0.997 0.993 0.985 0.965 0.930
Polymer (B): poly(ethylene glycol) 1989HAY

−1 −1
Carbowax 3350, Union Carbide Corp., New York, NY, USA
T/K = 298.15
wB 0.041 0.050 0.062 0.084 0.131 0.139 0.150 0.183
PA/mmHg 23.751 23.749 23.745 23.732 23.708 23.700 23.688 23.667
wB 0.190 0.216 0.220 0.247 0.282 0.305
PA/mmHg 23.656 23.623 23.622 23.587 23.523 23.512

T/K = 298.15
wB 0.2621 0.2819 0.3188 0.3674 0.4648
aA 0.9895 0.9873 0.9824 0.9739 0.9431
____________________________________________________________________________________

T/K = 297.75
wB 0.02814 0.09062 0.1736 0.2263 0.2654 0.3257 0.4227 0.5699 0.7304
aA 0.9998 0.9996 0.9952 0.9915 0.9897 0.9807 0.9633 0.9058 0.8278
T/K = 307.75
wB 0.02815 0.09075 0.1327 0.1736 0.2655 0.3259 0.4230 0.5703 0.7311
aA 0.9998 0.9988 0.9975 0.9958 0.9808 0.9830 0.9662 0.9052 0.8145

wB 0.3949 0.2940 0.1994 0.0490
T/K = 308.15
aA 0.9726 0.9878 0.9953 0.9996
T/K = 318.15
aA 0.9766 0.9897 0.9960 0.9997
T/K = 328.15
aA 0.9729 0.9920 0.9968 0.9995
T/K = 338.15
aA 0.9846 0.9935 0.9975 0.9997

T/K = 333.15
wB 0.000 0.735 0.835 0.902 0.950
PA/mmHg 149.38 130.91 118.70 104.22 81.50
T/K = 338.15
wB 0.496 0.662 0.764 0.839 0.900 0.949 0.970 0.990
PA/mmHg 182.79 171.30 160.58 150.33 133.11 103.24 78.92 35.71

T/K = 293.15
wB 0.0335 0.0502 0.0804 0.1267 0.1888 0.2523 0.3072
aA 0.99984 0.99970 0.99934 0.99833 0.99618 0.99202 0.98670
continued
____________________________________________________________________________________
continued
T/K = 313.15
wB 0.0159 0.0328 0.0644 0.0920 0.1212 0.1715 0.2022 0.3192
aA 0.99995 0.99988 0.99963 0.99928 0.99876 0.99741 0.99621 0.98825
T/K = 333.15
wB 0.0155 0.0399 0.0727 0.1224 0.1690 0.2044 0.2522
aA 0.99995 0.99985 0.99962 0.99908 0.99832 0.99739 0.99581

wB 0.3552 0.2931 0.1974 0.0982 0.0793 0.0601 0.0399
T/K = 308.15
aA 0.9961 0.9992 0.9994 0.9996 0.9998
T/K = 318.15
aA 0.9832 0.9900 0.9960 0.9986 0.9989 0.9993 0.9998
T/K = 328.15
aA 0.9872 0.9925 0.9973 0.9995 0.9997 0.9998 0.9999
T/K = 338.15
aA 0.9939 0.9977 0.9995 0.9996 0.9997 0.9998

T/K = 298.15
wB 0.0909 0.1667 0.2857 0.3333 0.3750 0.4118 0.4444 0.4737 0.5000
aA 0.9993 0.9969 0.9874 0.9805 0.9724 0.9632 0.9530 0.9419 0.9301

T/K = 313.10
wB 0.3292 0.4408 0.5341 0.6280
aA 0.9862 0.9624 0.9344 0.8892
T/K = 333.10
wB 0.3248 0.5068 0.5344 0.5800 0.6832 0.7852 0.8095
aA 0.9905 0.9595 0.9524 0.9376 0.8985 0.8411 0.8207
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1991ZHU

T/K = 293.15
wB 0.1136 0.1341 0.1628 0.1722 0.1933 0.1962 0.2212 0.2283 0.2528
aA 0.9988 0.9981 0.9971 0.9966 0.9956 0.9949 0.9933 0.9920 0.9891
wB 0.2745 0.2923 0.3006 0.3101 0.3188 0.3322 0.3510 0.3627 0.3843
aA 0.9865 0.9836 0.9821 0.9803 0.9788 0.9794 0.9758 0.9749 0.9687

T/K = 298.15
wB 0.0995 0.1489 0.1987 0.2980 0.3972 0.4970
aA 0.999 0.998 0.996 0.987 0.969 0.934

−1
T/K = 298.15
wB 0.0317 0.0426 0.0445 0.0587 0.0727 0.0862 0.1027 0.1056
aA 0.99952 0.99941 0.99938 0.99911 0.9989 0.9987 0.9984 0.9983

Lot 664762, Hoechst AG, Frankfurt, Germany
T/K = 293.10
wB 0.114 0.134 0.163 0.175 0.196 0.221 0.253 0.275 0.292
aA 0.9988 0.9981 0.9971 0.9956 0.9949 0.9933 0.9891 0.9865 0.9836
wB 0.310 0.332 0.351 0.401 0.423 0.432 0.495 0.510 0.520
aA 0.9803 0.9794 0.9758 0.9630 0.9559 0.9520 0.9279 0.9197 0.9124
T/K = 333.10
wB 0.306 0.321 0.427 0.478 0.471 0.485 0.518 0.541 0.675
aA 0.9914 0.9906 0.9772 0.9704 0.9697 0.9646 0.9592 0.9528 0.8919

−1 −1
continued
____________________________________________________________________________________
continued
T/K = 298.15
wB 0.1885 0.2170 0.2601 0.2667 0.2886 0.3103 0.3414 0.3594 0.3660
aA 0.9959 0.9946 0.9905 0.9903 0.9874 0.9850 0.9797 0.9769 0.9750

T/K = 298.15
wB 0.0499 0.0997 0.1495 0.1994 0.2990 0.3987 0.4984
aA 0.999 0.998 0.997 0.996 0.986 0.968 0.932
Polymer (B): poly(ethylene glycol) 1993BAE

T/K = 323.15
wB 0.416 0.645 0.811 0.897
PA/P0A 0.951 0.865 0.757 0.649
T/K = 333.15
wB 0.505 0.698 0.803
PA/P0A 0.937 0.870 0.770
T/K = 343.15
wB 0.550 0.710 0.803 0.890
PA/P0A 0.941 0.877 0.813 0.727
Polymer (B): poly(ethylene glycol) 1989HAY

−1 −1
T/K = 298.15
wB 0.059 0.078 0.085 0.125 0.133 0.167 0.214 0.225
PA/mmHg 23.749 23.743 23.740 23.722 23.717 23.686 23.657 23.649
wB 0.287 0.296 0.327 0.329 0.341 0.373
PA/mmHg 23.577 23.567 23.509 23.514 23.469 23.376

T/K = 298.15
wB 0.0497 0.0993 0.1490 0.1986 0.2980 0.3974 0.4967
aA 0.999 0.998 0.996 0.996 0.985 0.970 0.932
____________________________________________________________________________________

T/K = 298.15
wB 0.0909 0.1667 0.2857 0.3333 0.3750 0.4118 0.4444 0.4737 0.5000
aA 0.9994 0.9971 0.9881 0.9815 0.9735 0.9642 0.9536 0.9419 0.9290
Polymer (B): poly(ethylene glycol) 1998FEN

T/K = 333.15
wB 0.895 0.855 0.812 0.769 0.722 0.655 0.598 0.537
PA/P0A 0.414 0.538 0.617 0.720 0.792 0.867 0.941 0.985

T/K = 298.15
wB 0.0909 0.1667 0.2857 0.3333 0.3750 0.4118 0.4444 0.4737 0.5000
aA 0.9995 0.9973 0.9884 0.9818 0.9739 0.9646 0.9543 0.9427 0.9302

−1
T/K = 298.15
wB 0.0994 0.1491 0.1988 0.2983 0.3978 0.4971
aA 0.999 0.999 0.997 0.988 0.969 0.935
Polymer (B): poly(ethylene glycol) 1991ZHU

T/K = 293.15
wB 0.1123 0.1355 0.1567 0.1729 0.1959 0.1952 0.2177 0.2594 0.2794
aA 0.9988 0.9981 0.9971 0.9966 0.9956 0.9949 0.9933 0.9891 0.9865
wB 0.2873 0.2982 0.3070 0.3141 0.3247 0.3357 0.3599 0.3687 0.3934
aA 0.9852 0.9836 0.9821 0.9803 0.9788 0.9794 0.9758 0.9749 0.9687
____________________________________________________________________________________

Characterization: Mn/g.mol−1 = 39005, Hoechst AG, Frankfurt, Germany
T/K = 293.15
wB 0.112 0.136 0.157 0.173 0.196 0.218 0.259 0.279 0.287
aA 0.9988 0.9981 0.9971 0.9966 0.9956 0.9933 0.9891 0.9865 0.9852
wB 0.298 0.307 0.314 0.325 0.360 0.386 0.442 0.514 0.526
aA 0.9836 0.9821 0.9803 0.9788 0.9758 0.9687 0.9520 0.9197 0.9124
T/K = 333.15
wB 0.478 0.525 0.550 0.685
aA 0.9704 0.9592 0.9528 0.8919
Polymer (B): poly(ethylene oxide) 2000STR

Characterization: Mw/g.mol−1 = 100000, Tm/K = 338.2
T/K = 346.35
wB 0.990 0.982 0.969 0.962 0.951 0.930 0.904 0.868 0.834
aA 0.218 0.341 0.472 0.521 0.599 0.703 0.778 0.851 0.899
Polymer (B): poly(ethylene oxide) 2002JUN

Characterization: Mw/g.mol−1 = 600000
T/K = 303.15
wB 0.9886 0.9781 0.9687 0.9547 0.9431 0.9223 0.8886
aA 0.2057 0.3140 0.4349 0.5971 0.6953 0.8004 0.9609
Polymer (B): poly(ethylene oxide) 2000STR

Characterization: Mw/g.mol−1 = 4000000, Tm/K = 338.2
T/K = 367.65
wB 0.990 0.983 0.975 0.965 0.947 0.927 0.893 0.822
aA 0.150 0.243 0.328 0.442 0.558 0.652 0.751 0.847
Polymer (B): polyethylenimine 1998KAN

BASF AG, Ludwigshafen, Germany
continued
____________________________________________________________________________________
continued
T/K = 278.15
wB 0.1651 0.1954 0.2068 0.2476 0.2544 0.2935 0.2956
aA 0.9940 0.9906 0.9899 0.9803 0.9789 0.9670 0.9660
T/K = 293.15
wB 0.2347 0.2465 0.2515 0.2541 0.3122 0.3369
aA 0.9848 0.9828 0.9811 0.9808 0.9634 0.9526

T/K = 278.15
wB 0.1840 0.2115 0.2615 0.2738 0.3024 0.3305 0.3412
aA 0.9940 0.9906 0.9803 0.9776 0.9660 0.9550 0.9512
T/K = 293.15
wB 0.2474 0.2585 0.2635 0.2662 0.3344 0.3454
aA 0.9848 0.9828 0.9811 0.9808 0.9583 0.9526

T/K = 278.15
wB 0.1951 0.1993 0.2781 0.3132 0.3338
aA 0.9940 0.9906 0.9899 0.9789 0.9670 0.9550
T/K = 293.15
wB 0.2608 0.2709 0.2760 0.2781 0.2783 0.3374 0.3479
aA 0.9848 0.9828 0.9811 0.9809 0.9808 0.9583 0.9526
Polymer (B): polyethylenimine 2000STR

Characterization: Mw/g.mol−1 = 750000, Tg/K = 249.7, Tm/K = 331.7
T/K = 355.65
wB 0.981 0.945 0.907 0.874 0.826 0.780 0.719 0.630 0.597
aA 0.106 0.223 0.336 0.420 0.537 0.637 0.741 0.863 0.908
____________________________________________________________________________________
Polymer (B): polyglycerol 2002SEI

Characterization: Mn/g.mol−1 = 6000, 80 hydroxyl groups
hyperbranched, synthesized in the laboratory
T/K = 393.15
wB 0.855 0.887 0.923 0.934 0.947 0.958 0.977 0.985 0.999
P/kPa 148.470 130.810 101.380 90.380 79.240 67.730 47.960 33.570 4.400
Polymer (B): poly(N-isopropyl acrylamide) 1998KAN

T/K = 278.15
wB 0.2496 0.2668 0.2780 0.2841 0.2883
aA 0.9941 0.9925 0.9923 0.9917 0.9912
T/K = 293.15
wB 0.2576 0.2761 0.2794 0.3010 0.2892 0.3141 0.3505
aA 0.9963 0.9957 0.9953 0.9948 0.9947 0.9936 0.9919

T/K = 278.15
wB 0.2527 0.2620 0.2657 0.2758 0.2870 0.2804 0.2886
aA 0.9941 0.9925 0.9923 0.9923 0.9917 0.9912 0.9905
T/K = 293.15
wB 0.2725 0.2889 0.2933 0.3096 0.2987 0.3244
aA 0.9963 0.9957 0.9953 0.9948 0.9947 0.9936
Polymer (B): poly(propylene glycol) 2002JUN

T/K = 303.15
wB 0.9906 0.9863 0.9787 0.9696 0.9596 0.9451 0.9238
aA 0.1674 0.2315 0.3486 0.4183 0.5181 0.6138 0.7345
Polymer (B): poly(propylene glycol) 1957MAL

T/K = 303.15
continued
____________________________________________________________________________________
continued
wB 0.000 0.590 0.700 0.800 0.901 0.950 0.990
PA/mmHg 31.82 31.36 31.12 30.40 26.89 19.88 6.62
T/K = 323.15
wB 0.000 0.591 0.701 0.801 0.902 0.952 0.990
PA/mmHg 92.51 91.68 90.99 89.05 78.94 59.13 19.90
Polymer (B): poly(propylene glycol) 1982MED

T/K = 298.15
wB 0.0000 0.5715 0.7531 0.8555 0.8951 0.9187 0.9435 0.9532 0.9623
PA/kPa 3.1610 3.0968 3.0614 2.9508 2.7890 2.6021 2.2683 2.0878 1.8622
wB 0.9716 0.9819 0.9903 0.9920 0.9971
PA/kPa 1.5048 1.0291 0.5619 0.3339 0.2092
Polymer (B): poly(propylene glycol) 1972TAG

T/K = 298.15
wB 0.614 0.828 0.914 0.961 0.973 0.985 0.993 0.998
PA/mmHg 23.5 23.3 21.0 13.2 10.9 5.4 3.1 0.3
T/K = 312.65
wB 0.612 0.815 0.874 0.924 0.968 0.981 0.994 0.996
PA/mmHg 52.8 52.5 52.0 46.5 29.7 18.3 9.4 4.2
Polymer (B): poly(propylene oxide) 1999KIM

T/K = 303.15
wB 0.9945 0.9903 0.9858 0.9784 0.9704 0.9587
PA/kPa 0.8944 1.3197 1.8569 2.3581 2.8153 3.3925
Polymer (B): poly(tetramethylene glycol) 2002JUN

T/K = 303.15
wB 0.9977 0.9959 0.9928 0.9891 0.9852 0.9823 0.9746
aA 0.1523 0.2296 0.2921 0.4023 0.4726 0.5410 0.6605
____________________________________________________________________________________
Polymer (B): poly(vinyl alcohol) 1959SAK

T/K = 303.15
wB 0.543 0.682 0.823 0.923 0.952
PA/P0A 1.000 0.907 0.789 0.591 0.403
Polymer (B): poly(vinyl alcohol) 1959SAK

T/K = 303.15
wB 0.506 0.721 0.810 0.901 0.942
PA/P0A 1.000 0.901 0.818 0.620 0.498
Polymer (B): poly(vinyl alcohol) 2000NAG

Characterization: Mn/g.mol−1 = 70000, ρB (298 K) = 1.251 g/cm3
fractionated in the laboratory from Poval 420, Kuraray Co., Japan
T/K = 298.15
ϕB 0.0041 0.0075 0.0114 0.0123 0.0151 0.0169 0.0228 0.0247
aA 0.999999 0.999998 0.999996 0.999994 0.999990 0.999988 0.999986 0.999981
ϕB 0.0302 0.0326 0.0369 0.0404 0.0453 0.0490 0.0532 0.0576
aA 0.999977 0.999971 0.999962 0.999951 0.999946 0.999937 0.999926 0.999910
ϕB 0.0606 0.0658 0.0682 0.0741
aA 0.999898 0.999886 0.999878 0.999861
Comments: ϕB = (wB/1.251) (0.99705 + 0.255 wB).
Polymer (B): poly(vinyl alcohol) 1998HWA

T/K = 303.15
wB 0.9767 0.9659 0.9386 0.9217 0.8924 0.8148 0.6485
PA/kPa 0.968 1.164 1.803 2.371 2.919 3.643 4.188
Polymer (B): poly(vinyl alcohol) 1998KIM

T/K = 303.15
wB 0.9806 0.9497 0.9239 0.9053 0.8854 0.8319 0.8089 0.6659
aA 0.1601 0.3202 0.4849 0.5970 0.6967 0.8254 0.8574 0.9571
____________________________________________________________________________________
Polymer (B): poly(vinyl alcohol) 2000STR

Characterization: Mw/g.mol−1 = 124000-186000, Tg/K = 358.2, Tm/K = 503.2
T/K = 366.65
wB 0.993 0.984 0.974 0.963 0.951 0.936 0.916 0.894 0.788
aA 0.111 0.218 0.322 0.411 0.508 0.605 0.683 0.740 0.848
Polymer (B): poly(vinyl methyl ether) 2000STR

Characterization: Mw/g.mol−1 = 60000, Tg/K = 239.2
T/K = 355.65
wB 0.997 0.996 0.993 0.990 0.987 0.981 0.976 0.972 0.969
aA 0.225 0.340 0.420 0.537 0.634 0.754 0.838 0.902 0.908
Polymer (B): poly(1-vinyl-2-pyrrolidinone) 2000STR

T/K = 346.35
wB 0.977 0.958 0.939 0.908 0.898 0.876 0.811 0.782 0.751
aA 0.103 0.218 0.333 0.472 0.521 0.611 0.787 0.851 0.899
T/K = 367.65
wB 0.971 0.956 0.939 0.917 0.886 0.855 0.815 0.757
aA 0.150 0.243 0.328 0.442 0.556 0.652 0.751 0.847
Polymer (B): poly(1-vinyl-2-pyrrolidinone) 1998KAN, 2003KAN

T/K = 278.15
wB 0.3506 0.3736 0.3998 0.4000 0.4098 0.4202
aA 0.9825 0.9813 0.9789 0.9774 0.9735 0.9731
T/K = 293.15
wB 0.2489 0.3363 0.3500 0.3356 0.3526 0.3917
aA 0.9942 0.9888 0.9884 0.9883 0.9868 0.9823
T/K = 333.15
wB 0.4435 0.4934 0.5029 0.5398
aA 0.9829 0.9772 0.9753 0.9716
____________________________________________________________________________________
Polymer (B): poly(1-vinyl-2-pyrrolidinone) 1998KAN, 2003KAN

T/K = 278.15
wB 0.3826 0.3989 0.4017 0.4237 0.4146 0.4233
aA 0.9813 0.9789 0.9797 0.9769 0.9735 0.9731
T/K = 293.15
wB 0.2639 0.3464 0.3362 0.3466 0.3577 0.3579 0.3990 0.3874
aA 0.9942 0.9888 0.9883 0.9874 0.9868 0.9865 0.9823 0.9818
T/K = 333.15
wB 0.4498 0.4505 0.4607 0.4961 0.4931 0.5170
aA 0.9829 0.9811 0.9791 0.9783 0.9772 0.9751
Polymer (B): poly(1-vinyl-2-pyrrolidinone) 2000STR

T/K = 366.65
wB 0.982 0.962 0.940 0.915 0.884 0.851 0.817 0.779 0.715
aA 0.111 0.218 0.322 0.410 0.508 0.605 0.683 0.756 0.844
Polymer (B): vinyl acetate/vinyl alcohol copolymer 2000NAG

Characterization: Mn/g.mol−1 = 70000, 8.0 mol% vinyl acetate
ρB (298 K) = 1.241 g/cm3, synthesized in the laboratory
T/K = 298.15
ϕB 0.0039 0.0075 0.0113 0.0151 0.0206 0.0302 0.0360 0.0409
aA 0.999998 0.999996 0.999992 0.999990 0.999980 0.999968 0.999959 0.999945
ϕB 0.0505 0.0575 0.0635 0.0727 0.0747 0.0883 0.0910 0.1065
aA 0.999917 0.999896 0.999867 0.999839 0.999819 0.999746 0.999738 0.999627
Comments: ϕB = (wB/1.241) (0.99705 + 0.245 wB).
Polymer (B): vinyl acetate/vinyl alcohol copolymer 2000NAG

ρB (298 K) = 1.234 g/cm3, synthesized in the laboratory
T/K = 298.15
ϕB 0.0039 0.0150 0.0222 0.0305 0.0494 0.0626 0.0756 0.0878
aA 0.999999 0.999991 0.999983 0.999971 0.999928 0.999883 0.999832 0.999767
Comments: ϕB = (wB/1.234) (0.99705 + 0.237 wB).
____________________________________________________________________________________
2.2. Partial solvent vapor pressures or solvent activities for ternary

aqueous polymer solutions

Salt (C): ammonium sulfate (NH4)2SO4 7783-20-2
T/K = 298.15
wA 0.8965 0.9237 0.9417 0.9658 0.7882 0.8324 0.8639 0.9116 0.7331
wB 0.1011 0.0710 0.0510 0.0239 0.2068 0.1560 0.1191 0.0618 0.2606
wC 0.00244 0.00530 0.00728 0.0103 0.00498 0.0116 0.0170 0.0266 0.00628
aA 0.99567 0.99567 0.99567 0.99567 0.9882 0.9882 0.9882 0.9882 0.9825
wA 0.7828 0.8191 0.8774 0.6329 0.6874 0.7306 0.8014
wB 0.2021 0.1583 0.0859 0.3585 0.2909 0.2358 0.1388
wC 0.0151 0.0226 0.0367 0.00863 0.0217 0.0336 0.0598
aA 0.9825 0.9825 0.9825 0.9675 0.9675 0.9675 0.9675

T/K = 298.15
wA 0.8974 0.9222 0.9454 0.9703 0.8129 0.8491 0.8830 0.9263 0.7653
wB 0.1017 0.0758 0.0517 0.0259 0.1855 0.1471 0.1109 0.0643 0.2326
wC 0.000904 0.00196 0.00286 0.00379 0.00165 0.00381 0.00615 0.00938 0.00207
aA 0.99824 0.99824 0.99824 0.99824 0.99539 0.99539 0.99539 0.99539 0.99322
wA 0.8026 0.8416 0.8958 0.6520 0.6914 0.7358 0.8063
wB 0.1924 0.1501 0.0909 0.3449 0.3008 0.2503 0.1690
wC 0.00499 0.00832 0.0133 0.00306 0.00779 0.0139 0.0247
aA 0.99322 0.99322 0.99322 0.9840 0.9840 0.9840 0.9840
Polymer (B): poly(acrylamide) 1998HAI

Characterization: Mw/g.mol−1 = 5000000, 1.5 wt% acrylic acid
Component (C): sodium dodecyl sulfate C12H25NaO4S 151-21-3
T/K = 298.15 wB = 0.001 = constant
continued
____________________________________________________________________________________
continued
cC/(mmol/kg) 1.521 3.723 5.118 9.359 14.86 18.39 24.43 28.02 36.24 45.80
P/kPa 2.993 2.939 2.956 2.924 2.981 2.949 2.903 2.820 2.772 2.743
T/K = 308.15 wB = 0.001 = constant
cC/(mmol/kg) 1.521 3.723 5.118 9.359 14.86 18.39 24.43 28.02 36.24 45.80
P/kPa 5.504 5.499 5.533 5.399 5.483 5.427 5.326 5.311 5.388 5.330
T/K = 318.15 wB = 0.001 = constant
cC/(mmol/kg) 1.521 3.723 5.118 9.359 14.86 18.39 24.43 28.02 36.24 45.80
P/kPa 9.350 9.333 9.291 9.290 9.367 9.312 9.271 9.227 9.239 9.267
Comments: Additional data are given in the original source for sodium hydroxide added to the system.
Polymer (B): polyethersulfone 1999BAR, 2000BA1, 2000BA2

Characterization: Mw/g.mol−1 = 49000, ρB (298 K) = 1.37 g/cm3, Tg/K = 498
Ultrason E 6020 P, BASF AG, Ludwigshafen, Germany
Solvent (C): N,N-dimethylformamide C3H7NO 68-12-2
Comments: The mass fraction ratio of wC/wA in the solvent mixture was kept constant at a value of 97/3.
Additional data for wC/wA = 94/6 are given in the original sources.
T/K = 305.15
ϕA 0.020 0.018 0.016 0.014 0.013 0.010 0.009 0.006 0.004
ϕB 0.303 0.352 0.455 0.502 0.547 0.655 0.700 0.795 0.848
ϕC 0.677 0.629 0.529 0.484 0.441 0.335 0.291 0.199 0.148
PA/P0A 0.126 0.142 0.168 0.177 0.212 0.221 0.246 0.284 0.292
PC/P0C 0.779 0.761 0.721 0.684 0.608 0.525 0.456 0.206 0.086
T/K = 314.15
ϕA 0.021 0.018 0.017 0.014 0.011 0.010 0.009 0.007 0.004
ϕB 0.250 0.350 0.404 0.500 0.599 0.653 0.698 0.751 0.847
ϕC 0.729 0.631 0.580 0.486 0.389 0.337 0.293 0.242 0.149
PA/P0A 0.150 0.154 0.166 0.191 0.203 0.225 0.256 0.288 0.315
PC/P0C 0.860 0.802 0.797 0.718 0.598 0.542 0.491 0.416 0.155
T/K = 323.15
ϕA 0.021 0.018 0.017 0.014 0.011 0.010 0.009 0.007 0.004
ϕB 0.248 0.348 0.401 0.497 0.597 0.651 0.696 0.749 0.846
ϕC 0.730 0.634 0.582 0.488 0.391 0.339 0.295 0.244 0.150
PA/P0A 0.117 0.128 0.132 0.177 0.197 0.211 0.244 0.292 0.337
PC/P0C 0.858 0.849 0.835 0.711 0.604 0.546 0.504 0.436 0.234
____________________________________________________________________________________

T/K = 298.15
wA 0.9102 0.9340 0.9694 0.8613 0.8951 0.9311 0.7126 0.7643 0.8140
wB 0.0863 0.0604 0.0206 0.1329 0.0944 0.0519 0.2753 0.2111 0.1402
wC 0.0035 0.0056 0.0100 0.0058 0.0105 0.0170 0.0121 0.0246 0.0458
aA 0.9962 0.9962 0.9962 0.9924 0.9924 0.9924 0.9723 0.9723 0.9723
wA 0.6396 0.6819 0.7445
wB 0.3452 0.2863 0.1926
wC 0.0152 0.0318 0.0629
aA 0.9547 0.9547 0.9547

T/K = 298.15
wA 0.8766 0.9116 0.9497 0.8098 0.8511 0.9042 0.7356 0.7765 0.8395
wB 0.1207 0.0831 0.0421 0.1861 0.1399 0.0817 0.2587 0.2100 0.1343
wC 0.0027 0.0053 0.0082 0.0041 0.0090 0.0141 0.0057 0.0135 0.0262
aA 0.9965 0.9965 0.9965 0.9927 0.9927 0.9927 0.9850 0.9850 0.9850
wA 0.6307 0.6695 0.7371
wB 0.3613 0.3106 0.2200
wC 0.0080 0.0199 0.0429
aA 0.9660 0.9660 0.9660

Polymer (C): dextran
Characterization: Mw/g.mol−1 = 10000-12000
DX9300, Sigma Chemical Co., Inc., St. Louis, MO, USA
wA 0.9592 0.8886 0.8287 0.7488 0.7021
wB 0.0215 0.0928 0.1542 0.2262 0.2719
wC 0.0193 0.0186 0.0171 0.0250 0.0260
T/K = 308.15
aA 0.9989 0.9945 0.9895 0.9815 0.9745
T/K = 318.15
aA 0.9989 0.9947 0.9900 0.9824 0.9763
T/K = 328.15
aA 0.9989 0.9948 0.9899 0.9831 0.9772 continued
____________________________________________________________________________________
continued
T/K = 338.15
wA 0.9592 0.8886 0.8287 0.7488 0.7021
wB 0.0215 0.0928 0.1542 0.2262 0.2719
wC 0.0193 0.0186 0.0171 0.0250 0.0260
aA 0.9989 0.9949 0.9901 0.9837 0.9786
Polymer (B): poly(ethylene glycol) 1993STU

T/K = 293.15
wA 0.8637 0.8470 0.8255 0.8049 0.7837 0.7617 0.8466 0.8256 0.8043
wB 0.0292 0.0604 0.1006 0.1391 0.1787 0.2198 0.0410 0.0807 0.1209
wC 0.1071 0.0926 0.0739 0.0560 0.0376 0.0185 0.1124 0.0937 0.0748
aA 0.99715 0.99721 0.99725 0.99732 0.99740 0.99754 0.99659 0.99659 0.99661
wA 0.7839 0.7626 0.7418 0.7742 0.7642 0.7530 0.7429 0.7213
wB 0.1595 0.1997 0.2390 0.1605 0.1792 0.2004 0.2192 0.2599
wC 0.0566 0.0377 0.0192 0.0653 0.0566 0.0466 0.0379 0.0188
aA 0.99671 0.99678 0.99697 0.99629 0.99630 0.99635 0.99643 0.99656
T/K = 313.15
wA 0.9242 0.9138 0.9044 0.8948 0.8850 0.8803 0.8704 0.8561 0.8429
wB 0.0200 0.0422 0.0624 0.0829 0.1038 0.1140 0.0285 0.0631 0.0953
wC 0.0558 0.0440 0.0332 0.0223 0.0112 0.0057 0.1011 0.0808 0.0618
aA 0.99898 0.99909 0.99917 0.99931 0.99949 0.99958 0.99758 0.99769 0.99784
wA 0.8287 0.8152 0.8055 0.8505 0.8493 0.8478 0.7859 0.7815 0.7764
wB 0.1297 0.1623 0.1861 0.0024 0.0050 0.0081 0.1393 0.1486 0.1594
wC 0.0416 0.0225 0.0084 0.1471 0.1457 0.1441 0.0748 0.0699 0.0642
aA 0.99807 0.99832 0.99861 0.99638 0.99639 0.99640 0.99634 0.99634 0.99635
wA 0.7662 0.7586 0.7568 0.7480 0.7379 0.7296 0.6875 0.6869 0.6826
wB 0.1810 0.1971 0.2010 0.2197 0.2409 0.2586 0.2834 0.2847 0.2945
wC 0.0528 0.0443 0.0422 0.0323 0.0212 0.0118 0.0291 0.0284 0.0229
aA 0.99641 0.99649 0.99650 0.99663 0.99678 0.99694 0.99452 0.99456 0.99464
wA 0.6809 0.6801 0.6787 0.6761 0.6730 0.6697 0.6673
wB 0.2985 0.3002 0.3033 0.3092 0.3164 0.3238 0.3292
wC 0.0206 0.0197 0.0180 0.0147 0.0106 0.0065 0.0035
aA 0.99478 0.99478 0.99478 0.99485 0.99492 0.99507 0.99519
T/K = 333.15
wA 0.9251 0.9119 0.8981 0.8838 0.8936 0.8816 0.8657 0.8475 0.8418
wB 0.0286 0.0529 0.0783 0.1047 0.0363 0.0610 0.0937 0.1312 0.0506
wC 0.0463 0.0352 0.0236 0.0115 0.0701 0.0574 0.0406 0.0213 0.1076
aA 0.99919 0.99923 0.99943 0.99958 0.99868 0.99876 0.99892 0.99916 0.99744
continued
____________________________________________________________________________________
continued
wA 0.8252 0.7631 0.8032 0.7784 0.7479
wB 0.0841 0.2098 0.1021 0.1562 0.2229
wC 0.0907 0.0271 0.0947 0.0654 0.0292
aA 0.99745 0.99768 0.99695 0.99701 0.99724
Polymer (B): poly(ethylene glycol) 1993STU

T/K = 293.15
wA 0.9385 0.9274 0.9157 0.9039 0.8921 0.8774 0.8552 0.8332 0.8124
wB 0.0213 0.0400 0.0597 0.0796 0.0996 0.0409 0.0807 0.1203 0.1577
wC 0.0402 0.0326 0.0246 0.0165 0.0083 0.0817 0.0641 0.0465 0.0299
aA 0.99923 0.99923 0.99932 0.99942 0.99955 0.99784 0.99789 0.99800 0.99812
wA 0.8001 0.7901 0.7838 0.8703 0.8496 0.8278 0.8062 0.7845 0.8605
wB 0.1799 0.1978 0.2091 0.0405 0.0783 0.1183 0.1578 0.1975 0.0394
wC 0.0200 0.0121 0.0071 0.0892 0.0721 0.0539 0.0360 0.0180 0.1001
aA 0.99823 0.99834 0.99842 0.99757 0.99761 0.99768 0.99783 0.99804 0.99721
wA 0.8392 0.8176 0.8064 0.7753 0.7541 0.8997 0.8050 0.7912 0.7832
wB 0.0789 0.1191 0.1399 0.1975 0.2368 0.0003 0.1254 0.1501 0.1598
wC 0.0819 0.0633 0.0537 0.0272 0.0091 0.1000 0.0696 0.0587 0.0570
aA 0.99722 0.99728 0.99730 0.99747 0.99780 0.99691 0.99684 0.99685 0.99686
wA 0.7749 0.7634 0.7523 0.7407 0.7298 0.7377 0.7324 0.7227 0.7114
wB 0.1794 0.1999 0.2198 0.2407 0.2603 0.2201 0.2300 0.2484 0.2697
wC 0.0457 0.0367 0.0279 0.0186 0.0099 0.0422 0.0376 0.0289 0.0189
aA 0.99688 0.99695 0.99700 0.99710 0.99719 0.99588 0.99590 0.99597 0.99608
T/K = 313.15
wA 0.9047 0.8926 0.8828 0.8679 0.8592 0.8499 0.8651 0.7855 0.7712
wB 0.0284 0.0531 0.0732 0.1036 0.1213 0.1402 0.0109 0.1621 0.1891
wC 0.0669 0.0543 0.0440 0.0285 0.0195 0.0099 0.1240 0.0524 0.0397
aA 0.99862 0.99871 0.99882 0.99897 0.99911 0.99928 0.99712 0.99723 0.99728
wA 0.7632 0.7467 0.7350 0.7411 0.7396 0.7369 0.7314 0.7251 0.7176
wB 0.2044 0.2356 0.2578 0.2224 0.2256 0.2314 0.2430 0.2566 0.2725
wC 0.0324 0.0177 0.0072 0.0365 0.0348 0.0317 0.0256 0.0183 0.0099
aA 0.99735 0.99750 0.99759 0.99658 0.99661 0.99665 0.99672 0.99684 0.99697
wA 0.8372 0.8314 0.7602 0.7361 0.7294 0.7223 0.7159 0.7106 0.6988
wB 0.0013 0.0137 0.1656 0.2171 0.2312 0.2471 0.2600 0.2714 0.2964
wC 0.1615 0.1549 0.0742 0.0468 0.0394 0.0306 0.0241 0.0180 0.0048
aA 0.99584 0.99582 0.99586 0.99604 0.99610 0.99624 0.99631 0.99640 0.99669
continued
____________________________________________________________________________________
continued
T/K = 333.15
wA 0.9332 0.9273 0.9217 0.9111 0.8959 0.8772 0.8621 0.8448 0.8645
wB 0.0176 0.0332 0.0481 0.0762 0.0298 0.0693 0.1011 0.1376 0.0276
wC 0.0492 0.0395 0.0302 0.0127 0.0743 0.0535 0.0368 0.0176 0.1079
aA 0.99921 0.99937 0.99952 0.99972 0.99869 0.99884 0.99900 0.99920 0.99774
wA 0.8505 0.8339 0.8034 0.7906 0.7227 0.7182 0.7141 0.7087 0.7031
wB 0.0593 0.0967 0.1657 0.1946 0.2417 0.2529 0.2631 0.2767 0.2905
wC 0.0902 0.0694 0.0309 0.0148 0.0356 0.0289 0.0228 0.0146 0.0064
aA 0.99774 0.99789 0.99835 0.99872 0.99661 0.99677 0.99702 0.99735 0.99762
Polymer (B): poly(ethylene glycol) 1993GAU, 1993STU

T/K = 293.15
wA 0.9266 0.9143 0.9013 0.8912 0.9064 0.8887 0.8719 0.8558 0.8440
wB 0.0323 0.0237 0.0147 0.0078 0.0624 0.0474 0.0332 0.0197 0.0097
wC 0.0411 0.0620 0.0840 0.1010 0.0312 0.0639 0.0949 0.1245 0.1463
aA 0.99955 0.99957 0.99959 0.99962 0.99910 0.99911 0.99914 0.99920 0.99927
wA 0.8981 0.8823 0.8678 0.8538 0.8388 0.8894 0.8740 0.8591 0.8498
wB 0.0725 0.0571 0.0430 0.0292 0.0145 0.0808 0.0662 0.0522 0.0434
wC 0.0294 0.0606 0.0892 0.1170 0.1467 0.0298 0.0598 0.0887 0.1068
aA 0.99886 0.99887 0.99890 0.99896 0.99908 0.99866 0.99864 0.99865 0.99868
wA 0.8244 0.8037 0.7938 0.7865 0.7608 0.7571 0.7497 0.7094 0.7061
wB 0.0192 0.0261 0.0170 0.0105 0.0174 0.0139 0.0070 0.0086 0.0056
wC 0.1564 0.1702 0.1892 0.2030 0.2218 0.2290 0.2433 0.2820 0.2883
aA 0.99880 0.99833 0.99839 0.99842 0.99774 0.99775 0.99777 0.99669 0.99671
T/K = 313.15
wA 0.9053 0.9047 0.9042 0.9033 0.9021 0.8828 0.8708 0.8600 0.8437
wB 0.0742 0.0637 0.0544 0.0381 0.0185 0.0865 0.0713 0.0575 0.0368
wC 0.0205 0.0316 0.0414 0.0586 0.0794 0.0307 0.0579 0.0825 0.1195
aA 0.99900 0.99910 0.99919 0.99934 0.99959 0.99866 0.99868 0.99870 0.99877
wA 0.8371 0.8302 0.8213 0.8800 0.8789 0.8123 0.8076 0.8035 0.7972
wB 0.0284 0.0196 0.0085 0.1175 0.1161 0.0353 0.0296 0.0247 0.0169
wC 0.1345 0.1502 0.1702 0.0025 0.0050 0.1524 0.1628 0.1718 0.1859
aA 0.99881 0.99888 0.99895 0.99828 0.99826 0.99835 0.99838 0.99839 0.99844
wA 0.7937 0.7884 0.8451 0.7681 0.7633 0.7590 0.7577 0.7411 0.7376
wB 0.0127 0.0064 0.1520 0.0502 0.0436 0.0381 0.0363 0.0144 0.0097
wC 0.1936 0.2052 0.0029 0.1817 0.1931 0.2029 0.2060 0.2445 0.2527
aA 0.99848 0.99852 0.99725 0.99714 0.99717 0.99720 0.99721 0.99736 0.99742
continued
____________________________________________________________________________________
continued
T/K = 333.15
wA 0.9347 0.9258 0.9170 0.9074 0.8993 0.8837 0.8711 0.8288 0.8282
wB 0.0294 0.0190 0.0087 0.0640 0.0537 0.0337 0.0177 0.0460 0.0452
wC 0.0359 0.0552 0.0743 0.0286 0.0470 0.0826 0.1112 0.1252 0.1266
aA 0.99968 0.99973 0.99981 0.99929 0.99934 0.99940 0.99949 0.99875 0.99875
wA 0.8193 0.8136 0.8098 0.8040 0.7365 0.7335 0.7309 0.7278 0.7252
wB 0.0345 0.0276 0.0229 0.0158 0.0227 0.0177 0.0131 0.0078 0.0033
wC 0.1462 0.1588 0.1673 0.1802 0.2408 0.2488 0.2560 0.2644 0.2715
aA 0.99878 0.99879 0.99885 0.99892 0.99753 0.99757 0.99765 0.99774 0.99780
Polymer (B): poly(ethylene glycol) 1993GAU, 1993STU

T/K = 293.15
wA 0.9028 0.8891 0.8709 0.8610 0.8531 0.8393 0.8307 0.8682 0.8513
wB 0.0339 0.0579 0.0901 0.1074 0.1214 0.1456 0.1607 0.0307 0.0679
wC 0.0633 0.0530 0.0390 0.0316 0.0255 0.0151 0.0086 0.1011 0.0808
aA 0.99905 0.99905 0.99907 0.99908 0.99910 0.99913 0.99914 0.99796 0.99804
wA 0.8189 0.8030 0.7914 0.8851 0.8668 0.8493 0.8310 0.8162 0.8092
wB 0.1395 0.1745 0.2002 0.0378 0.0717 0.1040 0.1377 0.1650 0.1780
wC 0.0416 0.0225 0.0084 0.0771 0.0615 0.0467 0.0313 0.0188 0.0128
aA 0.99814 0.99837 0.99852 0.99865 0.99866 0.99867 0.99868 0.99869 0.99871
wA 0.8065 0.8015 0.7966 0.8811 0.7891 0.7831 0.7782 0.7732 0.7719
wB 0.1830 0.1922 0.2013 0.0031 0.1844 0.1956 0.2052 0.2151 0.2176
wC 0.0105 0.0063 0.0021 0.1158 0.0265 0.0213 0.0166 0.0117 0.0105
aA 0.99872 0.99875 0.99878 0.99808 0.99807 0.99808 0.99810 0.99815 0.99815
T/K = 313.15
wA 0.9319 0.9314 0.9214 0.9133 0.9031 0.8915 0.8739 0.8576 0.8434
wB 0.0251 0.0260 0.0466 0.0634 0.0846 0.0356 0.0732 0.1082 0.1387
wC 0.0430 0.0426 0.0320 0.0233 0.0123 0.0729 0.0529 0.0342 0.0179
aA 0.99949 0.99949 0.99952 0.99959 0.99967 0.99885 0.99888 0.99896 0.99912
wA 0.8968 0.8940 0.8337 0.8275 0.8175 0.8142 0.8869 0.8861 0.8058
wB 0.0046 0.0104 0.1341 0.1469 0.1674 0.1741 0.0031 0.0048 0.1702
wC 0.0986 0.0956 0.0322 0.0256 0.0151 0.0117 0.1100 0.1091 0.0240
aA 0.99871 0.99870 0.99878 0.99883 0.99892 0.99896 0.99847 0.99844 0.99857
wA 0.8025 0.8023 0.8018 0.7971 0.7933 0.7902 0.7882 0.7860
wB 0.1770 0.1775 0.1786 0.1881 0.1959 0.2023 0.2065 0.2110
wC 0.0205 0.0202 0.0196 0.0148 0.0108 0.0075 0.0053 0.0030
aA 0.99857 0.99858 0.99858 0.99863 0.99868 0.99869 0.99875 0.99880
continued
____________________________________________________________________________________
continued
T/K = 333.15
wA 0.9285 0.9155 0.9027 0.8914 0.9003 0.8753 0.8688 0.8528 0.8683
wB 0.0303 0.0544 0.0780 0.0989 0.0296 0.0614 0.0963 0.1301 0.0466
wC 0.0412 0.0301 0.0193 0.0097 0.0701 0.0633 0.0349 0.0171 0.0851
aA 0.99961 0.99965 0.99970 0.99976 0.99920 0.99925 0.99933 0.99942 0.99881
wA 0.8474 0.8305 0.8192 0.8029 0.7279 0.7237 0.7190
wB 0.0903 0.1256 0.1492 0.1833 0.2545 0.2637 0.2742
wC 0.0623 0.0439 0.0316 0.0138 0.0176 0.0126 0.0068
aA 0.99882 0.99889 0.99897 0.99905 0.99789 0.99793 0.99800

Characterization: Mn/g.mol−1 = 1000, Shanghai Chemical Reagent Factory, PR China
Polymer (C): hydroxypropyl starch
T/K = 298.15
wA 0.9428 0.9103 0.8772 0.8400 0.8954 0.8500 0.8083 0.7583 0.8416
wB 0.0332 0.0261 0.0176 0.0110 0.0607 0.0436 0.0274 0.0153 0.0919
wC 0.0240 0.0636 0.1052 0.1490 0.0439 0.1064 0.1643 0.2264 0.0665
aA 0.9986 0.9986 0.9986 0.9986 0.9975 0.9975 0.9975 0.9975 0.9956
wA 0.7923 0.7399 0.6941 0.7876 0.7343 0.6777 0.6274
wB 0.0604 0.0372 0.0194 0.1232 0.0772 0.0461 0.0236
wC 0.1473 0.2229 0.2865 0.0892 0.1885 0.2762 0.3490
aA 0.9956 0.9956 0.9956 0.9933 0.9933 0.9933 0.9933

T/K = 298.15
wA 0.9559 0.9272 0.9076 0.8879 0.9415 0.9058 0.8822 0.8579 0.9098
wB 0.0164 0.0121 0.0074 0.0034 0.0217 0.0156 0.0094 0.0043 0.0335
wC 0.0277 0.0607 0.0850 0.1087 0.0368 0.0786 0.1084 0.1378 0.0567
aA 0.99928 0.99928 0.99928 0.99928 0.99905 0.99905 0.99905 0.99905 0.9985
wA 0.8591 0.8281 0.7984 0.8167 0.7662 0.7263 0.6782
wB 0.0233 0.0138 0.0061 0.0680 0.0387 0.0219 0.0098
wC 0.1176 0.1581 0.1955 0.1153 0.1951 0.2518 0.3120
aA 0.9985 0.9985 0.9985 0.9960 0.9960 0.9960 0.9960
____________________________________________________________________________________

T/K = 298.15
wA 0.9391 0.9298 0.9166 0.9031 0.9243 0.9108 0.8966 0.8779 0.8923
wB 0.0371 0.0272 0.0173 0.0085 0.0461 0.0345 0.0215 0.0107 0.0656
wC 0.0238 0.0430 0.0661 0.0884 0.0296 0.0547 0.0819 0.1114 0.0421
aA 0.99938 0.99938 0.99938 0.99938 0.99911 0.99911 0.99911 0.99911 0.9987
wA 0.8762 0.8539 0.8312 0.8700 0.8525 0.8242 0.8068
wB 0.0479 0.0304 0.0147 0.0792 0.0571 0.0365 0.0169
wC 0.0759 0.1157 0.1541 0.0508 0.0904 0.1393 0.1763
aA 0.9987 0.9987 0.9987 0.9984 0.9984 0.9984 0.9984

−1
T/K = 298.15
wA 0.9535 0.9437 0.9311 0.9208 0.9388 0.9245 0.9078 0.8926 0.9086
wB 0.0249 0.0171 0.0115 0.0051 0.0328 0.0228 0.0154 0.0070 0.0556
wC 0.0216 0.0392 0.0574 0.0741 0.0284 0.0527 0.0768 0.1004 0.0358
aA 0.99952 0.99952 0.99952 0.99952 0.99941 0.99941 0.99941 0.99941 0.9989
wA 0.8930 0.8742 0.8463 0.8731 0.8486 0.8253 0.7967
wB 0.0414 0.0275 0.0125 0.0804 0.0593 0.0392 0.0191
wC 0.0656 0.0983 0.1412 0.0465 0.0921 0.1355 0.1842
aA 0.9989 0.9989 0.9989 0.9983 0.9983 0.9983 0.9983

Salt (C): magnesium sulfate MgSO4 7487-88-9
T/K = 298.15
wA 0.9110 0.8864 0.8635 0.8077 0.9245 0.8707 0.8322 0.7589 0.8846
wB 0.0553 0.0910 0.1221 0.1923 0.0000 0.0905 0.1469 0.2411 0.0000
wC 0.0337 0.0226 0.0144 0.0000 0.0755 0.0388 0.0209 0.0000 0.1154
aA 0.9915 0.9915 0.9915 0.9915 0.9875 0.9875 0.9875 0.9875 0.9793
wA 0.8629 0.8310 0.7738 0.6990 0.8554 0.8126 0.7762 0.7242 0.6418
wB 0.0483 0.1082 0.1977 0.3010 0.0000 0.0792 0.1486 0.2401 0.3582
wC 0.0888 0.0608 0.0285 0.0000 0.1446 0.1082 0.0752 0.0357 0.0000
aA 0.9793 0.9793 0.9793 0.9793 0.9686 0.9686 0.9686 0.9686 0.9686
____________________________________________________________________________________

T/K = 298.15
wA 0.9353 0.8950 0.8565 0.8115 0.9428 0.9085 0.8630 0.8112 0.7399
wB 0.0469 0.0938 0.1377 0.1885 0.0000 0.0485 0.1080 0.1735 0.2601
wC 0.0178 0.0112 0.0058 0.0000 0.0572 0.0430 0.0290 0.0153 0.0000
aA 0.9959 0.9959 0.9959 0.9959 0.9905 0.9905 0.9905 0.9905 0.9905
wA 0.9240 0.8827 0.8340 0.7819 0.7114 0.8684 0.8091 0.7626 0.6887
wB 0.0000 0.0621 0.1302 0.1996 0.2886 0.0656 0.1493 0.2163 0.3113
wC 0.0760 0.0552 0.0358 0.0185 0.0000 0.0660 0.0416 0.0211 0.0000
aA 0.9874 0.9874 0.9874 0.9874 0.9874 0.9845 0.9845 0.9845 0.9845

T/K = 298.15
wA 0.8718 0.8986 0.9295 0.8118 0.8416 0.8845 0.7213 0.7539 0.8086
wB 0.1165 0.0810 0.0355 0.1717 0.1292 0.0620 0.2543 0.2007 0.1028
wC 0.0117 0.0204 0.0350 0.0165 0.0292 0.0535 0.0244 0.0454 0.0886
aA 0.9925 0.9925 0.9925 0.9863 0.9863 0.9863 0.9711 0.9711 0.9711

T/K = 298.15
wA 0.8062 0.8569 0.9015 0.7686 0.8215 0.8670 0.7148 0.7702 0.8183
wB 0.1840 0.1201 0.0613 0.2197 0.1498 0.0828 0.2708 0.1929 0.1131
wC 0.0098 0.0230 0.0372 0.0117 0.0287 0.0502 0.0144 0.0369 0.0686
aA 0.9912 0.9912 0.9912 0.9872 0.9872 0.9872 0.9796 0.9796 0.9796

Polymer (C): poly(ethylene glycol)
continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.9000 0.7988 0.7022 0.6002 0.5010 0.3913 0.3014 0.2011
wB 0.0500 0.1004 0.1495 0.1997 0.2500 0.2996 0.3493 0.3992
wC 0.0500 0.1008 0.1483 0.2001 0.2490 0.3091 0.3493 0.3997
aA 0.993 0.981 0.964 0.935 0.892 0.822 0.745 0.628

−1
T/K = 298.15
wA 0.9003 0.7919 0.5999 0.5050 0.4028 0.3030
wB 0.0500 0.1066 0.2008 0.2482 0.2990 0.3492
wC 0.0497 0.1015 0.1993 0.2468 0.2982 0.3478
aA 0.993 0.982 0.939 0.901 0.837 0.754

−1
T/K = 298.15
wA 0.9003 0.8001 0.7022 0.6018 0.5021
wB 0.0499 0.1004 0.1490 0.1997 0.2496
wC 0.0498 0.0995 0.1488 0.1985 0.2483
aA 0.996 0.988 0.977 0.954 0.916

T/K = 298.15
wA 0.9010 0.7984 0.7028 0.6086 0.5196
wB 0.0495 0.0984 0.1501 0.1936 0.2373
wC 0.0495 0.1032 0.1471 0.1978 0.2431
aA 0.998 0.993 0.984 0.964 0.933
____________________________________________________________________________________

T/K = 298.15
wA 0.9013 0.8034 0.7059 0.6116 0.5315
wB 0.0490 0.0976 0.1461 0.1930 0.2265
wC 0.0497 0.0990 0.1480 0.1954 0.2420
aA 0.998 0.993 0.983 0.964 0.937

−1
T/K = 298.15
wA 0.9012 0.8027 0.7202 0.6060 0.5076
wB 0.0494 0.0986 0.1397 0.1970 0.2462
wC 0.0494 0.0987 0.1401 0.1970 0.2462
aA 0.999 0.996 0.988 0.965 0.933

Polymer (C): poly(propylene glycol)
wA 0.9715 0.9317 0.8875 0.8548 0.8239 0.7594
wB 0.0151 0.0327 0.0580 0.0724 0.0869 0.1281
wC 0.0134 0.0356 0.0545 0.0728 0.0892 0.1125
T/K = 308.15
aA 0.9982 0.9961 0.9935 0.9911 0.9887 0.9834
T/K = 318.15
aA 0.9865 0.9910 0.9928 0.9947 0.9968 0.9987
T/K = 328.15
aA 0.9885 0.9916 0.9932 0.9948 0.9968 0.9987
____________________________________________________________________________________

wA 0.9788 0.9428 0.9109 0.8775
wB 0.0114 0.0286 0.0446 0.0612
wC 0.0098 0.0286 0.0445 0.0613
T/K = 308.15
aA 0.9995 0.9986 0.9977 0.9965
T/K = 318.15
aA 0.9996 0.9988 0.9979 0.9969
T/K = 328.15
aA 0.9995 0.9987 0.9980 0.9970

Salt (C): sodium carbonate Na2CO3 497-19-8
T/K = 298.15
wA 0.9553 0.9274 0.8923 0.8453 0.9392 0.8952 0.8351 0.7757 0.9446
wB 0.0343 0.0661 0.1037 0.1547 0.0394 0.0904 0.1587 0.2243 0.0000
wC 0.0104 0.0065 0.0040 0.0000 0.0214 0.0144 0.0062 0.0000 0.0554
aA 0.9944 0.9944 0.9944 0.9944 0.9892 0.9892 0.9892 0.9892 0.9787
wA 0.8915 0.8386 0.7796 0.7000 0.9210 0.8598 0.8075 0.7461 0.6475
wB 0.0713 0.1375 0.2084 0.3000 0.0000 0.0909 0.1600 0.2373 0.3525
wC 0.0372 0.0239 0.0120 0.0000 0.0790 0.0493 0.0325 0.0166 0.0000
aA 0.9787 0.9787 0.9787 0.9787 0.9699 0.9699 0.9699 0.9699 0.9699

−1 −1
T/K = 298.15
wA 0.9577 0.9227 0.8773 0.8107 0.9265 0.8726 0.8210 0.7378 0.9616
wB 0.0345 0.0714 0.1189 0.1893 0.0559 0.1155 0.1721 0.2622 0.0000
wC 0.0078 0.0059 0.0038 0.0000 0.0176 0.0119 0.0069 0.0000 0.0384
aA 0.9960 0.9960 0.9960 0.9960 0.9908 0.9908 0.9908 0.9908 0.9850
continued
____________________________________________________________________________________
continued
wA 0.9246 0.8590 0.7963 0.6897 0.9395 0.8730 0.8194 0.7572 0.6406
wB 0.0445 0.1200 0.1915 0.3103 0.0000 0.0849 0.1513 0.2260 0.3594
wC 0.0309 0.0210 0.0122 0.0000 0.0605 0.0421 0.0293 0.0168 0.0000
aA 0.9850 0.9850 0.9850 0.9850 0.9769 0.9769 0.9769 0.9769 0.9769

−1 −1
Salt (C): sodium sulfate Na2SO4 7757-82-6
T/K = 298.15
wA 0.9241 0.8851 0.8292 0.7757 0.8917 0.8361 0.7706 0.7002 0.9090
wB 0.0490 0.0957 0.1631 0.2243 0.0551 0.1306 0.2150 0.2998 0.0000
wC 0.0269 0.0957 0.0077 0.0000 0.0532 0.0333 0.0144 0.0000 0.0910
aA 0.9893 0.9893 0.9893 0.9893 0.9801 0.9801 0.9801 0.9801 0.9748
wA 0.8708 0.8164 0.7527 0.6730 0.8772 0.8308 0.7842 0.7243 0.6289
wB 0.0639 0.1424 0.2274 0.3270 0.0000 0.0877 0.1627 0.2471 0.3711
wC 0.0653 0.0412 0.0199 0.0000 0.1228 0.0815 0.0531 0.0286 0.0000
aA 0.9748 0.9748 0.9748 0.9748 0.9660 0.9660 0.9660 0.9660 0.9660

T/K = 298.15
wA 0.9449 0.9019 0.8560 0.7830 0.9491 0.8862 0.8305 0.7333 0.9269
wB 0.0402 0.0875 0.1372 0.2170 0.0205 0.0928 0.1570 0.2667 0.0000
wC 0.0149 0.0106 0.0068 0.0000 0.0304 0.0210 0.0125 0.0000 0.0731
aA 0.9946 0.9946 0.9946 0.9946 0.9903 0.9903 0.9903 0.9903 0.9797
wA 0.8988 0.8298 0.7524 0.6586 0.9097 0.8704 0.8031 0.7369 0.6340
wB 0.0395 0.1311 0.2281 0.3414 0.0000 0.0578 0.8031 0.7369 0.6340
wC 0.0617 0.0391 0.0195 0.0000 0.0903 0.0718 0.0442 0.0247 0.0000
aA 0.9797 0.9797 0.9797 0.9797 0.9750 0.9750 0.9750 0.9750 0.9750

continued
____________________________________________________________________________________
continued
T/K = 293.15
wB 0.01016 0.02022 0.03025 0.03988 0.01996 0.03989 0.07955 0.03261 0.06551
wC 0.00226 0.00169 0.00112 0.00057 0.01118 0.00837 0.00278 0.05356 0.04038
aA 0.999109 0.999189 0.999269 0.999335 0.996119 0.996518 0.997661 0.982825 0.984789
wB 0.09895 0.13184 0.17102 0.18995 0.21433
wC 0.02699 0.01381 0.04578 0.03303 0.01660
aA 0.987290 0.990692 0.970701 0.974485 0.981077
T/K = 313.15
wB 0.00972 0.01950 0.02897 0.03850 0.02008 0.04011 0.05894 0.07987 0.03256
wC 0.00218 0.00162 0.00108 0.00054 0.01133 0.00847 0.00578 0.00279 0.05343
aA 0.999093 0.999198 0.999293 0.999390 0.996009 0.996576 0.997167 0.997901 0.982302
wB 0.06527 0.09868 0.13216 0.02640 0.06000 0.15080 0.20340 0.01810 0.26150
wC 0.04033 0.02694 0.01353 0.08020 0.06790 0.03460 0.01530 0.11090 0.02470
aA 0.984285 0.987217 0.991097 0.974551 0.974182 0.978684 0.984588 0.965922 0.969020

Characterization: Mn/g.mol−1 = 1400, Mw/g.mol−1 = 2100, 20 hydroxyl groups
Solvent (C): ethanol C2H6O 64-17-5
T/K = 363.15 wB = 0.20 = constant
xC 0.1001 0.2998 0.4996 0.7503 0.8510 0.9506
yC 0.4593 0.5817 0.6667 0.8042 0.8755 0.9531
T/K = 363.15 wB = 0.60 = constant
xC 0.1004 0.3012 0.4997 0.7487 0.8464 0.9476
yC 0.4451 0.6353 0.7448 0.8730 0.9162 0.9701
T/K = 363.15 wB = 0.70 = constant
xC 0.2988 0.6993 0.8473 0.9549
yC 0.7088 0.8724 0.9295 0.9746

Characterization: Mn/g.mol−1 = 4000, Mw/g.mol−1 = 8400, 53 hydroxyl groups
T/K = 363.15 wB = 0.40 = constant
xC 0.0200 0.0501 0.2001 0.3493 0.4914 0.6420 0.8014 0.8943 0.9503
yC 0.2177 0.3635 0.5510 0.6466 0.7000 0.7763 0.8614 0.9160 0.9588
T/K = 363.15 wB = 0.60 = constant
xC 0.2008 0.4998 0.7465 0.8914 0.9375
yC 0.5865 0.7511 0.8638 0.9315 0.9653
____________________________________________________________________________________
Polymer (B): polysulfone 1999BAR, 2000BA1, 2000BA2

Ultrason S 3010, BASF AG, Ludwigshafen, Germany
Comments: The mass fraction ratio of wC/wA in the solvent mixture was kept constant at a value of
98.5/1.5.
T/K = 305.15
ϕA 0.011 0.009 0.008 0.007 0.006 0.005 0.004 0.003 0.002
ϕB 0.254 0.356 0.455 0.505 0.601 0.654 0.703 0.754 0.851
ϕC 0.736 0.635 0.538 0.488 0.394 0.341 0.293 0.242 0.146
PA/P0A 0.118 0.146 0.145 0.144 0.156 0.158 0.167 0.200 0.209
PC/P0C 0.964 0.875 0.894 0.877 0.769 0.750 0.673 0.571 0.390
T/K = 314.15
ϕA 0.011 0.009 0.008 0.007 0.006 0.005 0.004 0.003 0.002
ϕB 0.252 0.354 0.452 0.502 0.599 0.652 0.701 0.799 0.850
ϕC 0.737 0.637 0.540 0.491 0.396 0.343 0.295 0.199 0.148
PA/P0A 0.093 0.109 0.115 0.117 0.132 0.145 0.168 0.199 0.194
PC/P0C 0.976 0.905 0.904 0.868 0.793 0.731 0.683 0.570 0.476
T/K = 323.15
ϕA 0.011 0.009 0.008 0.007 0.006 0.005 0.004 0.003 0.002
ϕB 0.250 0.352 0.450 0.500 0.596 0.650 0.699 0.797 0.849
ϕC 0.739 0.639 0.542 0.493 0.398 0.346 0.297 0.200 0.149
PA/P0A 0.087 0.088 0.097 0.095 0.104 0.119 0.127 0.157 0.173
PC/P0C 0.957 0.880 0.867 0.840 0.768 0.731 0.685 0.579 0.537
Polymer (B): poly(vinyl alcohol) 2002SEI

Characterization: Mw/g.mol−1 = 6000, 80 mol% hydrolyzed
T/K = 363.15 wB = 0.040 = constant
xC 0.1996 0.3998 0.5997 0.7997 0.8999
yC 0.5335 0.6093 0.6925 0.8211 0.8986
____________________________________________________________________________________
2.3. Classical mass-fraction Henry’s constants of water vapor in

molten polymers
Polymer (B): ethylene/vinyl acetate copolymer 1978DIN

Characterization: Mn/g.mol−1 = 43200, 29.0 wt% vinyl acetate,
MI = 15.0, sample DX-31034, Union Carbide Co., USA
_____________________________________
Solvent (A) T/ HA,B/
K MPa
_____________________________________
water 423.61 37.00
water 433.68 53.01
_____________________________________

____________________________________________________________________________________
Solvent (A) T/ HA,B/ Solvent (A) T/ HA,B/
K MPa K MPa
____________________________________________________________________________________
water 272.85 0.03136 water 327.95 0.2075
water 288.15 0.02166 water 332.75 0.3388
water 298.15 0.04631 water 338.05 0.4573
water 302.45 0.05946 water 342.15 0.5871
water 307.35 0.08189 water 347.85 0.7614
water 313.45 0.1094 water 352.65 0.9974
water 318.25 0.1492 water 357.65 1.206
water 323.05 0.2075
____________________________________________________________________________________
Polymer (B): polyetherimide 2001BAL

Characterization: Mw/g.mol−1 = 54000, Tg = 490 K
Ultem, General Electric Co., USA
____________________________________________________________________________________
K MPa K MPa
____________________________________________________________________________________
water 503.15 290.3 water 523.15 402.4
water 543.15 417.8
____________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1989BES

____________________________________________________________________________________
K MPa K MPa
____________________________________________________________________________________
water 333.15 0.218 water 368.15 1.228
water 343.15 0.378 water 373.15 1.504
water 348.15 0.490 water 378.15 1.817
water 353.15 0.627 water 383.15 2.187
water 358.15 0.808 water 393.15 3.198
water 363.15 0.997 water 403.15 4.578
____________________________________________________________________________________

____________________________________________________________________________________
K MPa K MPa
____________________________________________________________________________________
water 328.15 0.175 water 368.15 1.603
water 333.15 0.228 water 373.15 1.986
water 343.15 0.410 water 378.15 2.448
water 348.15 0.550 water 383.15 2.970
water 353.15 0.723 water 393.15 4.287
water 358.15 0.956 water 403.15 6.174
water 363.15 1.250 water 413.15 8.548
____________________________________________________________________________________

____________________________________________________________________________________
K MPa K MPa
____________________________________________________________________________________
water 323.15 0.174 water 363.15 1.461
water 333.15 0.316 water 368.15 1.836
water 338.15 0.430 water 373.15 2.375
water 343.15 0.561 water 383.15 3.867
water 348.15 0.713 water 393.15 5.921
water 353.15 0.921 water 403.15 8.896
water 358.15 1.166 water 413.15 13.023
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
K MPa K MPa
____________________________________________________________________________________
water 323.15 0.181 water 368.15 2.289
water 333.15 0.327 water 373.15 2.938
water 338.15 0.430 water 378.15 3.714
water 343.15 0.577 water 383.15 4.655
water 348.15 0.765 water 393.15 7.096
water 353.15 0.983 water 403.15 10.328
water 358.15 1.301 water 413.15 14.899
water 363.15 1.712
____________________________________________________________________________________

____________________________________________________________________________________
K MPa K MPa
____________________________________________________________________________________
water 353.15 0.849 water 378.15 3.674
water 358.15 1.156 water 383.15 4.834
water 363.15 1.519 water 393.15 8.435
water 368.15 2.078 water 403.15 13.951
water 373.15 2.744 water 413.15 23.327
____________________________________________________________________________________
Polymer (B): poly(ethylene oxide) 1983COU

Carbowax 1000, Union Carbide Co., USA
_____________________________________
K MPa
_____________________________________
water 343.15 0.5171
_____________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene oxide) 1983COU

Carbowax 20000, Union Carbide Co., USA
_____________________________________
K MPa
_____________________________________
water 343.15 0.7378
_____________________________________
Polymer (B): poly(ethylene oxide) 1975CHA

Characterization: Mw/g.mol−1 = about 4000000
Polyox WSR 301, Union Carbide Co., USA
____________________________________________________________________________________
K MPa K MPa
____________________________________________________________________________________
water 343.35 0.4444 water 375.05 0.1859
water 348.35 0.5744 water 398.85 4.007
water 361.35 0.9631 water 423.65 8.016
____________________________________________________________________________________
Polymer (B): polystyrene 1980GUN

Characterization: Mn/g.mol−1 = 20000 ± 5000
PS-K500, Petrokimya A.S., Yarimca, Turkey
____________________________________________________________________________________
K MPa K MPa
____________________________________________________________________________________
water 435.46 128.7 water 492.92 130.1
water 444.99 117.9 water 502.58 153.9
____________________________________________________________________________________
Polymer (B): polysulfone 2001BAL

Characterization: Mw/g.mol−1 = 78000-80000, Tg = 460 K, Udel
____________________________________________________________________________________
K MPa K MPa
____________________________________________________________________________________
water 473.15 90.99 water 523.15 142.0
water 493.15 113.8
____________________________________________________________________________________
____________________________________________________________________________________
2.4. References
1957MAL Malcolm, G.N. and Rowlinson, J.S., Thermodynamic properties of aqueous solutions of
polyethylene glycol, polypropylene glycol, and dioxane, Trans. Faraday Soc., 53, 921, 1957.
1959SAK Sakurada, I., Nakajima, A., and Fujiwara, H., Vapor pressures of polymer solutions. II.
Vapor pressure of poly(vinyl alcohol)-water system, J. Polym. Sci., 35, 497, 1959.
1968LAK Lakhanpal, M.L., Chhina, K.S., and Sharma, S.C., Thermodynamic properties of aqueous
solutions of polyoxyethleneglycols, Indian J. Chem., 6, 505, 1968.
1972TAG Tager, A.A., Adamova, L.V., Bessonov, Yu.S., Kuznetsov, V.N., Plyusnina, T.A., Soldatov,
V.V., and Tsilipotkina, M.V., Thermodynamic study of oligomeric poly(oxypropylene)diol
solutions in water and n-hexane in the precritical region (Russ.), Vysokomol. Soedin., Ser.
A, 14, 1991, 1972.
1975CHA Chang, Y.H. and Bonner, D.C., Sorption of solutes by poly(ethylene oxide). I. Infinite-
dilution studies, J. Appl. Polym. Sci., 19, 2439, 1975.
1976ADA Adamcova, Z., The solvent activity in aqueous solutions of poly(ethylene glycol) at 25 °C,
Sci. Pap. Prag. Inst. Chem. Technol., N2, 63, 1976.
1978DIN Dincer, S. and Bonner, D.C., Thermodynamic analysis of ethylene and vinylacetate
copolymer with various solvents by gas chromatography, Macromolecules, 11, 107, 1978.
1979ASP Aspler, J.S. and Gray, D.G., Gas chromatographic and static measurements of solute
activity for a polymeric liquid-crystalline phase, Macromolecules 12, 562, 1979.
1980GUN Gunduz, S. and Dincer, S., Solubility behaviour of polystyrene. Thermodynamic studies
using gas chromatography, Polymer, 21, 1041, 1980.
1982MED Medved, Z.N., Petrova,P.P., and Tarakanov, O.G., Comparative study of the thermodyna-
mics of mixing ethylene oxide and propylene oxide oligomers with water (Russ.),
Vysokomol. Soedin., Ser. B, 24, 674, 1982.
1983COU Courval, G.J. and Gray, D.G., Gas chromatographic evaluation of thermodynamic inter-
action parameters for the water-poly(ethylene oxide) systems, Polymer, 24, 323, 1983.
1985HER Herskowitz, M. and Gottlieb, M., Vapor-liquid equilibrium in aqueous solutions of various
glycols and poly(ethylene glycols) 3., J. Chem. Eng. Data, 30, 233, 1985.
1989BES Bestani, B. and Shing, K.S., Infinite-dilution activity coefficients of water in TEG, PEG,
glycerol and their mixtures in the temperature range 50 to 140°C, Fluid Phase Equil., 50,
209, 1989.
1989HAY Haynes, C.A., Beynon, R.A., King, R.S., Blanch, H. W., and Prausnitz, J.M., Thermody-
Chem., 93, 5612, 1989.
1990OCH Ochs, L.R., Kabri-Badr, M., and Cabezas, H., An improved isopiestic method to determine
activities in multicomponent mixtures, AIChE-J., 36, 1908, 1900.
1991ZHU Zhu, J., Flüssig-Flüssig-Gleichgewichte bei der Verteilung einiger Aminosäuren und
Peptide auf wäßrige Zwei-Phasen-Systeme, Dissertation, Universität Kaiserslautern, 1991.
1993BAE Bae,Y.C., Shim, J.J., Soane, D.S., and Prausnitz, J.M., Representation of vapor-liquid and
liquid-liquid equilibria for binary systems containing polymers: applicability of an extended
Flory-Huggins equation, J. Appl. Polym. Sci., 47, 1193, 1993.
1993GAU Gaube, J., Pfennig, A., and Stumpf, M., Vapor-liquid equilibrium in binary and ternary
aqueous solutions of poly(ethylene glycol) and dextran, J. Chem. Eng. Data, 38, 163, 1993.
1993STU Stumpf, M., Thermodynamische Untersuchungen zu wäßrigen PEG-Dextran-Zweiphasen-
systemen und Bestimmung des Salzeinflusses auf das Systemverhalten, Dissertation, TH
Darmstadt, 1993.
____________________________________________________________________________________
1994HAM Hammer, S., Pfennig, A., and Stumpf, M., Liquid-liquid and vapor-liquid equilibria in water
+ poly(ethylene glycol) + sodium sulfate, J. Chem. Eng. Data, 39, 409, 1994.
1994KOE Köster, M., Messung der Wasseraktivität in Polymerlösungen und Vergleich verschiedener
Modelle zur thermodynamischen Beschreibung von Polymerlösungen, Diploma Paper, TH
Darmstadt, 1994.
poly(ethylene glycol) and dextran - experimental results and modeling of thermodynamic
1995TIN Tintinger, R., Thermodynamische Eigenschaften ausgewählter wäßriger Zwei-Phasen
Systeme, Dissertation, Universität Kaiserslautern, 1995.
1996COR Cornejo-Bravo, J.M. and Siegel, R.A., Water vapour sorption behaviour of copolymers of
N,N-diethylaminoethyl methacrylate and methyl methacrylate, Biomaterials, 17, 1187, 1996.
1996LIN Lin, D.-Q., Mei, L.-H., Zhu, Z.-Q., and Han, Z.-X., An improved isopiestic method for
measurement of water activities in aqueous polymer and salt solutions, Fluid Phase Equil.,
118, 241, 1996.
1998FEN Feng, W., Wang, W., and Feng, Z., Measurements and correlation of vapor-liquid equilibria
for polymer solutions, J. Chem. Ind. Eng. (China), 49, 217, 1998.
1998HAI Hai, M., Han, B., Yan, H., and Han, G., Vapor pressure of aqueous solutions of
polyacrylamide + sodium dodecyl sulfate with and without NaOH, J. Chem. Eng. Data, 43,
1056, 1998.
1998HWA Hwang, S., Kim, J., and Yoo, K.-P., Vapor liquid equilibrium data of binary polymer
solutions by vacuum electromicrobalance, J. Chem. Eng. Data, 43, 614, 1998.
1998KAN Kany, H.-P., Thermodynamische Eigenschaften wäßriger Polymer-Lösungen, Dissertation,
Universität Kaiserslautern, 1998.
1998KIM Kim, J., Joung, K.C., Hwang, S., Huh, W., Lee, C.S., and Yoo, K.-P., Measurement of
vapor sorption equilibria of polymer solutions and comparative correlation by GE-models
and lattice equation of state, Korean J. Chem. Eng., 15, 199, 1998.
1999BAR Barth, C., Untersuchungen zum thermodynamischen Phasenverhalten membranbildender
Systeme, Dissertation, Johannes-Gutenberg-Universität Mainz, 1999.
1999ELI Eliassi, A., Modarress, H., and Mansoori, G.A., Measurement of activity of water in
aqueous poly(ethylene glycol) solutions, J. Chem. Eng. Data, 44, 52, 1999.
1999KAN Kany, H.-P., Hasse, H., and Maurer, G., Thermodynamic properties of aqueous dextran
solutions from laser-light scattering, membrane osmometry, and isopiestic measurements, J.
Chem. Eng. Data, 44, 230, 1999.
1999KIM Kim, J., Choi, E.-H., Yoo, K.-P., and Lee, C.S., Measurement of activities of solvents in
binary polymer solutions, Fluid Phase Equil., 161, 283, 1999.
1999LIN Lin, D.-Q., Wu, Y.-T., Zhu, Z.-Q., Mei, L.-H., and Yao, S.-J., Isopiestic determination of
the water activities and prediction of liquid-liquid equilibrium in polyethylene glycol +
hydroxypropyl starch + water systems, Fluid Phase Equil., 162, 159, 1999.
1999NIN Ninni, L., Camargo, M.S., and Meirelles, A.J.A., Water activity in poly(ethylene glycol)
aqueous solutions, Thermochim. Acta, 328, 169, 1999.
2000BA1 Barth, C. and Wolf, B.A., Preferential evaporation of precipitants from polymer solutions in
mixed solvents, Macromol. Rapid Commun., 21, 349, 2000.
2000BA2 Barth, C. and Wolf, B.A., Evidence of ternary interaction parameters for polymer solutions
in mixed solvents from headspace-gas chromatography, Polymer, 41, 8587, 2000.
2000FRI Friberg, S.E., Yin, Q., Barber, J.L., and Aikens, P.A., Vapor pressures of phenethyl alcohol
in the system water-phenethyl alcohol and the triblock copolymer EO4.5PO59EO4.5, J.
Dispersion Sci. Technol., 21, 65, 2000.
2000LIW Li, W., Lin, D.-Q., and Zhu, Z.-Q., Measurement of water activities and prediction of
liquid-liquid equilibria for water + ethylene oxide-propylene oxide random copolymer +
ammonium sulfate systems, Fluid Phase Equil., 175, 7, 2000.
____________________________________________________________________________________
2000NAG Nagy, M., A comparative and systematic thermodynamic study of aqueous solutions and
hydrogels of homo- and copolymers of poly(vinyl alcohol), Phys. Chem. Chem. Phys., 2,
2613, 2000.
2000STR Striolo, A. and Prausnitz, J.M., Vapor-liquid equilibria for some concentrated aqueous
polymer solutions, Polymer, 41, 1109, 2000.
2001BAL Balashova I.M., Danner, R.P., Puri, P.S., and Duda, J.L., Solubility and diffusivity of
solvents and nonsolvents in polysulfone and polyetherimide, Ind. Eng. Chem. Res., 40,
3058, 2001.
2001ELI Eliassi, A. and Modarress, H., Water activities in binary and ternary aqueous systems of
poly(ethylene glycol), poly(propylene glycol) and dextran, Eur. Polym. J., 37, 1487, 2001.
2002COO Cooke, S.A., Jonsdottir, S.O., and Westh, P., A thermodynamic study of glucose and related
oligomers in aqueous solution: vapor pressures and enthalpies of mixing, J. Chem. Eng.
Data, 47, 1185, 2002.
2002JUN Jung, J.K., Joung, S.N., Shin, H.Y., Kim, S.Y., Yoo, K.-P., Huh, W., and Lee, C.S.,
Measurements and correlation of hydrogen-bonding vapor sorption equilibrium data of
binary polymer solutions, Korean J. Chem. Eng., 19, 296, 2002.
2002SEI Seiler, M., Arlt, W., Kautz, H., and Frey, H., Experimental data and theoretical
considerations on vapor-liquid and liquid-liquid equilibria of hyperbranched polyglycerol
and PVA solutions, Fluid Phase Equil., 201, 359, 2002.
2002ZAF Zafarani-Moattar, M.T. and Yeganeh, N., Isopiestic determination of 2-propanol activity in
2-propanol + poly(ethylene glycol) solutions at 25 °C, J. Chem. Eng. Data, 47, 72, 2002.
2003KAN Kany, H.-P., Hasse, H., and Maurer, G., Thermodynamic properties of aqueous
poly(vinylpyrrolidone) solutions from laser-light-scattering, membrane osmometry, and
isopiestic measurements, J. Chem. Eng. Data, 48, 689, 2003.
2003SEI Seiler, M., Rolker, J., and Arlt, W., Phase behavior and thermodynamic phenomena of
hyperbranched polymer solutions, Macromolecules, 36, 2085, 2003.
3.1. Cloud-point and/or coexistence curves of quasibinary solutions
Polymer (B): N-cyclopropylacrylamide/vinylferrocene copolymer 1998KUR

Characterization: synthesized in the laboratory
Type of data: cloud points (LCST-behavior)
cB/(g/l) 1.0 T/K 314.85 for a copolymer of 1.0 mol% vinylferrocene
Polymer (B): N,N-diethylacrylamide/acrylic acid copolymer 2001CAI

Characterization: Mw/g.mol−1 = 319000, 5.98 mol% acrylic acid
wB 0.005 T/K 305.05
wB 0.005 T/K 301.25 (in a solution of 0.05 M NaCl)
Polymer (B): N,N-diethylacrylamide/vinylferrocene copolymer 1997KUR

Polymer (B): N-ethylacrylamide/vinylferrocene copolymer 1997KUR

82 CRC Handbook of Thermodynamic Data of Aqueous Solutions
____________________________________________________________________________________
Polymer (B): ethylene oxide/propylene oxide copolymer 2000LI2

Type of data: coexistence data (tie lines, LCST-behavior)
Comments: The total feed concentration of the polymer is wB = 0.2000.
T/K 341.35 345.25 350.65 357.95 364.65 373.15
wB (top phase) 0.1870 0.1087 0.0710 0.0424 0.0315 0.0216
wB (bottom phase) 0.6124 0.6592 0.6942 0.7173 0.7528 0.7654

Type of data: coexistence data (tie lines, LCST-behavior)
Comments: The total feed concentration of the polymer is wB = 0.2000.
T/K 328.85 332.55 339.05 343.30 347.20 352.15 363.35 373.15
wB (top phase) 0.1876 0.1275 0.0530 0.0320 0.0210 0.0140 0.0079 0.0084
wB (bottom phase) 0.6151 0.6531 0.6992 0.7394 0.7685 0.7881 0.8315 0.8461
Polymer (B): N-isopropylacrylamide/acrylic acid copolymer 2000YAM

5.4 mol% acrylic acid, synthesized in the laboratory
wB 0.001 0.001 0.001 0.001 0.001
pH 2.0 3.0 4.0 5.0 6.0
T/K 307.35 307.45 309.35 311.15 312.55
Comments: The pH of the solution was adjusted by adding the appropriate amount of NaOH solution.

wB 0.001 pH 5.0 T/K 315.25
3. Liquid-Liquid Equilibrium (LLE) Data 83
____________________________________________________________________________________

wB 0.001 pH 5.0 T/K 320.25
Polymer (B): N-isopropylacrylamide/1-deoxy-1-methacryl-

amido-D-glucitol 2002REB
−1 −1
Characterization: Mn/g.mol = 78000, Mw/g.mol = 170000, 12.9 mol% glucitol
synthesized in the laboratory by radical polymerization
wB 0.00500 0.01060 0.02062 0.03010 0.04010 0.05260 0.05440 0.06080 0.07080
T/K 320.1 316.1 314.3 313.6 313.7 312.7 312.8 313.1 313.1
wB 0.07790 0.08530 0.09720 0.18900
T/K 313.0 312.8 312.4 310.6

Characterization: Mn/g.mol−1 = 28600, Mw/g.mol−1 = 56000, 13.3 mol% glucitol
wB 0.0102 0.0174 0.0233 0.0263 0.0397 0.0550
T/K 413.2 384.8 368.5 358.1 353.0 366.0

wB 0.01001 0.03914 0.0400 0.08810
T/K 321.1 315.6 313.7 315.1
____________________________________________________________________________________

wB 0.0050 0.0100 0.0305 0.0432 0.0530 0.0983 0.1103 0.1294
T/K 313.1 311.3 310.1 309.8 309.3 308.6 308.0 307.3
Polymer (B): N-isopropylacrylamide/itaconic acid copolymer 1999ERB

Characterization: 9.8 mol% itaconic acid, synthesized in the laboratory
wB 0.005 0.005 0.005 0.005 0.005 0.005
pH 2.01 2.30 3.09 3.32 4.08 5.03
T/K 307.55 308.15 309.25 310.15 312.65 332.55
Polymer (B): N-isopropylacrylamide/itaconic acid copolymer 1999ERB

Characterization: 23.0 mol% itaconic acid, synthesized in the laboratory
wB 0.005 0.005 0.005
pH 1.00 2.02 3.14
T/K 310.35 310.65 315.55
Polymer (B): N-isopropylacrylamide/vinylferrocene copolymer 1998KUR

Polymer (B): N-isopropylacrylamide/1-vinylimidazole copolymer 2000PE1

wB 0.01 T/K 309.65 for a copolymer of 4.76 mol% 1-vinylimidazole
____________________________________________________________________________________

Characterization: Mη/g.mol−1 = 70000, degree of substitution about 26.5−32.0 wt%
ϕB 0.00199 0.00238 0.00265 0.00376 0.00462 0.00546 0.00546 0.00655 0.00684
T/K 339.35 337.85 334.05 330.55 328.55 328.55 330.15 327.35 326.65
ϕB 0.00783 0.00815 0.00892 0.01042 0.01150
T/K 324.55 325.05 324.75 324.05 324.35
Comments: Phase separation temperatures were determined by DTA and agree well with cloud points.
Critical point: ϕB = 0.00892 Tcrit/K = 324.75

−1
Characterization: Mη/g.mol = 150000, degree of substitution about 26.5−32.0 wt%
ϕB 0.00016 0.00071 0.00317 0.00386 0.00461 0.00536 0.00614 0.00764 0.01033
T/K 336.35 333.85 329.55 328.55 328.75 327.45 327.35 326.85 352.45

Characterization: Mη/g.mol−1 = 300000, degree of substitution about 26.5−32.0 wt%
ϕB 0.00016 0.00078 0.00264 0.00383 0.00463 0.00538 0.00708 0.00882 0.00997
T/K 335.65 333.15 331.25 328.75 328.95 328.75 329.45 331.85 348.45
Polymer (B): poly(N-cyclopropylacrylamide) 1998KUR

cB/(g/l) 1.0 T/K 320.25
____________________________________________________________________________________
Polymer (B): poly(N,N-diethylacrylamide) 1997KUR

cB/(g/l) 1.0 T/K 304.65

wB 0.001 0.005 0.05 0.10 0.20
T/K 307.45 306.55 305.15 305.35 306.05

Type of data: coexistence data (liquid-liquid-vapor three phase equilibrium)
wB 0.062 0.082 0.100 0.130 0.170 0.201 0.300 0.350 0.398
T/K 364.4 378.1 412.2 414.4 406.0 394.1 381.0 (*) 371.8 (*) 370.0 (*)
wB 0.300 0.350 0.398
T/K 377.5 (**) 358.8 (**) 331.6 (**) (*)
phase transition LLV to LV and (**) LV to LLV.
Polymer (B): poly(N-ethylacrylamide) 1997KUR

cB/(g/l) 1.0 T/K 317.85

Union Carbide Corp., New York, NY, USA
Type of data: cloud points (closed loop miscibility gap)
wB 0.049 0.070 0.100 0.150 0.200 0.297 0.399 0.443
T/K 513.65 518.05 518.55 519.55 517.75 512.95 501.65 496.35
wB 0.049 0.070 0.100 0.150 0.200 0.297 0.399 0.443
T/K 430.75 429.35 428.85 428.65 429.75 431.25 438.05 445.45
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1993SAR

Characterization: Mn/g.mol−1 = 2160, Mw/g.mol−1 = 2530, Mz/g.mol−1 = 2985
wB 0.0507 0.0638 0.0920 0.1805 0.2989 0.3788 0.4269
T/K 473.85 483.85 499.55 503.05 500.85 495.45 487.35
wB 0.0507 0.0638 0.0920 0.1805 0.2989 0.3788 0.4269
T/K 451.15 443.65 432.45 431.85 434.15 433.25 444.05

wB 0.0252 0.0487 0.1040 0.1906 0.2957 0.3636 0.4546
T/K 501.45 520.55 529.95 525.65 527.45 527.15 509.35
wB 0.0252 0.0487 0.1040 0.1906 0.2957 0.3636 0.4546
T/K 431.15 421.65 415.45 417.75 415.45 419.95 431.85

wB 0.012 0.020 0.030 0.049 0.100 0.300 0.400 0.550
T/K 548.65 552.15 554.05 555.05 555.65 552.05 544.35 503.15
wB 0.012 0.020 0.030 0.049 0.100 0.199 0.300 0.400 0.550
T/K 405.35 402.05 399.85 397.95 397.75 397.95 401.75 409.25 439.75
Polymer (B): poly(ethylene glycol) 1996FIS, 2001FIS

−1 −1 −1
Characterization: Mn/g.mol = 6096, Mw/g.mol = 6197, Mz/g.mol = 6293
Merck KGaA, Darmstadt, Germany
ϕB 0.0969 0.0840 0.0807 0.0771 0.0706 0.0659 0.0616 0.0583 0.0547
T/K 405.00 405.10 405.30 405.50 405.70 406.00 406.30 406.60 407.00
ϕB 0.0535 0.0502 0.0475 0.0461 0.0442 0.0418 0.0393 0.0392 0.0376
T/K 407.00 407.40 407.80 408.00 408.20 408.50 408.85 409.00 409.50
ϕB 0.0335 0.0316 0.0312 0.0282 0.0269 0.0254 0.0252 0.0230 0.0219
T/K 410.00 410.50 411.00 411.50 412.00 412.45 412.85 413.40 414.00
continued
____________________________________________________________________________________
continued
ϕB 0.0208 0.0198 0.0187 0.0187 0.0181 0.0152 0.0170 0.0157
T/K 414.50 415.00 415.50 416.00 416.45 416.65 417.00 417.90
ϕB 0.2031 0.2264 0.2209 0.2331 0.2368 0.2457 0.2538 0.2608 0.2690
T/K 405.00 405.10 405.30 405.50 405.70 406.00 406.30 406.60 407.00
ϕB 0.2751 0.2778 0.2846 0.2910 0.2921 0.2974 0.3111 0.3048 0.3094
T/K 407.00 407.40 407.80 408.00 408.20 408.50 408.85 409.00 409.50
ϕB 0.3181 0.3253 0.3299 0.3373 0.3488 0.3490 0.3527 0.3591 0.3650
T/K 410.00 410.50 411.00 411.50 412.00 412.45 412.85 413.40 414.00
ϕB 0.3699 0.3738 0.3792 0.3824 0.3859 0.4173 0.3907 0.3986
T/K 414.50 415.00 415.50 416.00 416.45 416.65 417.00 417.90

wB 0.0242 0.0511 0.1008 0.1607 0.2314 0.3921 0.4992
T/K 553.35 556.55 561.95 557.85 561.35 547.85 533.35
wB 0.0242 0.0511 0.1008 0.1607 0.2314 0.3921 0.4992
T/K 397.85 396.15 394.05 395.05 396.85 403.75 421.25
Polymer (B): poly(ethylene glycol) 2001FIS

−1 −1 −1
Characterization: Mn/g.mol = 10457, Mw/g.mol = 11615, Mz/g.mol = 12375
ϕB 0.0489 0.0477 0.0484 0.0480 0.0429 0.0242 0.0213 0.0241 0.0241
T/K 393.95 394.15 394.25 394.35 395.55 406.70 407.65 409.60 410.65
ϕB 0.2236 0.2280 0.2246 0.2239 0.2301 0.3411 0.3635 0.3931 0.4023
T/K 393.95 394.15 394.25 394.35 395.55 406.70 407.65 409.60 410.65

Characterization: Mn/g.mol−1 = 12000, Fluka AG, Buchs, Switzerland
ϕB 0.0278 0.0255 0.0230 0.0194 0.0202 0.0194 0.0182
T/K 391.14 391.98 393.14 394.97 397.03 398.02 398.97
ϕB 0.2045 0.2322 0.2446 0.2732 0.2917 0.3039 0.3145
T/K 391.14 391.98 393.14 394.97 397.03 398.02 398.97
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1994BOR, 2001FIS

trimodal distribution, Merck KGaA, Darmstadt, Germany
ϕB 0.0547 0.0469 0.0435 0.0416 0.0493 0.0315 0.0221 0.0225 0.0136
T/K 388.25 388.55 388.75 389.05 389.25 389.75 390.75 391.25 397.75
ϕB 0.1929 0.1879 0.1916 0.1900 0.1944 0.2095 0.2201 0.2443 0.3208
T/K 388.25 388.55 388.75 389.05 389.25 389.75 390.75 391.25 397.75

wB 0.002 0.005 0.007 0.010 0.021 0.050 0.071 0.101 0.202
T/K 543.15 550.75 553.35 557.75 560.65 568.25 569.25 569.05 568.85
wB 0.294 0.403 0.501 0.002 0.005 0.007 0.010 0.021 0.031
T/K 564.95 555.65 539.25 408.75 403.15 401.55 398.95 396.35 394.85
wB 0.050 0.071 0.101 0.202 0.294 0.403 0.501
T/K 393.35 392.95 392.65 393.35 397.35 406.05 419.45

ϕB 0.0316 0.0233 0.0174 0.0161 0.0140 0.0129 0.0115 0.0110 0.0090
T/K 382.00 382.24 382.35 382.75 383.55 383.67 384.04 384.51 384.83
ϕB 0.0084 0.0078 0.0065 0.0067 0.0054 0.0050 0.0040 0.0037 0.0025
T/K 385.27 386.44 387.47 387.94 388.95 389.97 391.93 392.87 397.86
ϕB 0.1200 0.1252 0.1372 0.1495 0.1579 0.1629 0.1697 0.1786 0.1871
T/K 382.00 382.24 382.35 382.75 383.55 383.67 384.04 384.51 384.83
ϕB 0.1937 0.2131 0.2288 0.2332 0.2500 0.2633 0.2883 0.3000 0.3518
T/K 385.27 386.44 387.47 387.94 388.95 389.97 391.93 392.87 397.86

WSR-10, Union Carbide Chemicals and Plastics, USA
ϕB 0.0076 0.0060 0.0050 0.0041 0.1675 0.1655 0.1997 0.2463 0.2659
T/K 379.95 380.85 385.95 387.95 379.95 380.85 380.95 385.95 387.95
____________________________________________________________________________________

Scientific Polymer Products, Inc., Ontario, NY, USA
wB 0.005 0.007 0.010 0.030 0.050 0.070 0.100
T/K 376.85 374.65 375.55 375.75 377.45 378.45 379.55
Polymer (B): poly(ethylene oxide)-b- poly(propylene fumarate)-b-

poly(ethylene oxide) dimethyl ether triblock copolymer 2002BEH
Characterization: Mn/g.mol−1 = 2730, about 40 mol% ethylene oxide in 1.9 blocks,
Mn/g.mol−1 = 570 PEG monomethyl ether block,
Mn/g.mol−1 = 1660 poly(propylene fumarate) block
wB 0.05 0.15 0.25
T/K 313.15 318.15 318.15
Polymer (B): poly(ethylene oxide)-b- poly(propylene fumarate)-b-

poly(ethylene oxide) dimethyl ether triblock copolymer 2002BEH
Characterization: Mn/g.mol−1 = 3120, about 50 mol% ethylene oxide in 1.8 blocks,
Mn/g.mol−1 = 800 PEG monomethyl ether block,
Mn/g.mol−1 = 1660 poly(propylene fumarate) block
wB 0.05 0.15 0.25
T/K 328.15 333.15 333.15
Polymer (B): poly(ethylene oxide)-b-poly(propylene oxide)-

b-poly(ethylene oxide) triblock copolymer 1995KIM
Characterization: Mn/g.mol−1 = 2500, 20.0 wt% propylene oxide
Pluronic L62, BASF Wyandotte Corp., Parsippany, NJ, USA
wB 0.005 0.010 0.025 0.050 0.075 0.100
T/K 308.15 305.15 301.15 299.15 297.15 296.15
____________________________________________________________________________________

hyperbranched, acetylated, synthesized in the laboratory
Type of data: coexistence data (tie lines)
T/K = 295.15
phase I wA 0.090 wB 0.910
phase II wA 0.997 wB 0.003
Polymer (B): poly(N-isopropylacrylamide) 2000AFR

synthesized in the laboratory
wB 0.0009 0.0010 0.0025 0.0049 0.0075 0.0100 0.0249 0.0499 0.1002
T/K 306.98 307.17 306.09 306.40 305.91 305.44 304.70 303.97 303.21
wB 0.2003 0.3017 0.3986 0.5001
T/K 301.97 301.01 300.55 300.32
Type of data: demixing temperatures (LCST behavior, measured by DSC)
wB 0.0100 0.0249 0.0499 0.1002 0.1495 0.2003 0.2462 0.3017 0.3505
T/K 306.20 305.63 304.86 304.03 302.70 302.50 302.23 301.36 300.99
wB 0.4000 0.4501 0.4942 0.5575 0.5984 0.6499 0.6992
T/K 300.89 300.89 300.55 300.80 300.85 302.23 302.86
Polymer (B): poly(N-isopropylacrylamide) 1992INO

wB 0.014 0.034
T/K 304.35 304.85

wB 0.0490 0.0998 0.1490 0.1999 0.2508 0.3006 0.3575 0.4496 0.4917
T/K 303.50 302.60 301.40 301.40 301.16 301.07 300.85 299.86 299.72
wB 0.5500 0.6008 0.6449 0.7072 0.7571 0.8016 0.8406 0.9089
T/K 301.01 301.22 301.22 302.87 304.82 311.12 316.82 338.62
____________________________________________________________________________________
Polymer (B): poly(N-isopropylacrylamide) 2002KUN

Type of data: cloud points (LCST-behavior, determined by DSC)
wB 0.00001 0.00005 0.00010 0.00020 0.00040
T/K 310.15 309.55 309.55 309.45 309.35

wB 0.0025 0.0049 0.0075 0.0099 0.0149 0.0198 0.0250 0.0299 0.0349
T/K 304.10 303.83 303.73 303.63 303.63 303.36 303.26 303.16 302.96
wB 0.0399 0.0453 0.0497 0.0749 0.1007 0.1503 0.1998 0.2487 0.3002
T/K 302.80 302.70 302.40 302.40 302.13 301.93 301.06 300.90 300.70
wB 0.3500 0.4096 0.4523 0.5161 0.5499 0.6338 0.7571
T/K 300.60 300.23 300.23 299.93 300.23 302.50 304.82
Polymer (B): poly(N-isopropylacrylamide) 2001GOM, 2002REB

wB 0.0103 0.0201 0.0250 0.0357 0.0370 0.0417 0.0453 0.0565 0.0640
T/K 307.2 306.7 306.6 306.5 305.6 305.5 306.3 306.1 306.2
wB 0.0677 0.0767 0.0884 0.1057 0.1146 0.1474 0.1757
T/K 306.4 306.3 306.5 305.9 306.2 305.8 305.7
Type of data: spinodal points (LCST-behavior)
wB 0.02011 0.03574 0.04167 0.04529 0.05646 0.06402 0.06774 0.07670 0.08839
T/K 321.6 312.1 309.2 310.7 308.9 307.8 308.7 309.1 308.7
wB 0.1146 0.1474 0.1757
T/K 309.1 308.7 310.9
Polymer (B): poly(N-isopropylacrylamide) 1990OTA

wB 0.059 0.044 0.030 0.015 0.0074 0.0037
T/K 303.05 305.45 306.15 306.95 307.45 308.25
____________________________________________________________________________________
Polymer (B): poly(N-isopropylacrylamide) 1998KUR

cB/(g/l) 1.0 T/K 306.45
Polymer (B): poly(N-isopropylacrylamide) 2000PE1

wB 0.01 T/K 307.15
Polymer (B): polyol (hyperbranched, 2nd generation) 1999JAN

wB 0.050 0.050 0.053 0.060 0.088 0.100 0.151 0.229 0.249
T/K 321.6 322.4 324.6 327.9 329.4 330.2 333.0 336.2 338.1
wB 0.276 0.290 0.299 0.327 0.375
T/K 341.6 341.4 341.5 341.6 341.0
Polymer (B): polyol (hyperbranched, 3rd generation) 1999JAN

wB 0.020 0.100 0.150 0.191 0.250 0.302 0.399 0.413 0.344
T/K 386.5 396.7 395.4 394.2 378.5 366.5 330.1 331.3 334.4
Polymer (B): polyol (hyperbranched, 4th generation) 1999JAN

wB 0.020 0.050 0.100 0.150 0.200 0.250 0.298 0.349
T/K 406.3 436.3 430.1 425.3 421.9 413.5 312.4 331.7
____________________________________________________________________________________
Polymer (B): poly(N-vinylcaprolactam) 2002MA1

wB 0.01 0.02 0.03 0.05 0.10 0.15 0.20 0.30 0.40
T/K 306.95 306.65 306.35 305.65 305.75 305.95 306.75 307.35 310.05
Polymer (B): poly(N-vinylcaprolactam) 2000PE1

wB 0.01 T/K 306.15
Polymer (B): poly(N-vinylisobutyramide) 2002KUN

synthesized and fractionated in the laboratory
wB 0.00001 0.00005 0.00010 0.00020 0.00040
T/K 318.15 316.25 315.65 315.15 314.85

wB 0.00001 0.00005 0.00010 0.00020 0.00040
T/K 314.85 314.65 314.25 314.05 313.95

wB 0.00001 0.00005 0.00010 0.00020 0.00040
T/K 313.35 313.05 312.85 312.75 312.55
____________________________________________________________________________________
Polymer (B): poly(vinyl methyl ether) 1990OTA

Characterization: Mw/g.mol−1 = 15000, Toyo Kasei Kogyo Co., Japan
wB 0.061 0.030
T/K 305.45 305.15

wB 0.060 0.0375
T/K 305.45 305.45
Polymer (B): tetra(ethylene glycol) monodecyl ether 1980LAN

Characterization: M/g.mol−1 = 334.5, C18H38O5, 5703-94-6
Type of data: coexistence data (I and II denote the coexisting phases)
T/K 571.65 569.65 568.15 567.65 557.65 551.15 492.65 407.65 362.05
wB(I) 0.2998 0.1999 0.0500
wB(II) 0.4001 0.5001 0.5980 0.7994 0.8497 0.8005
T/K 348.32 341.10 338.24 335.04 333.58 332.46 332.41 332.40 332.30
wB(I) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001
wB(II) 0.6997 0.6426 0.6001 0.5489 0.5249 0.5146 0.5092 0.5099 0.5128
T/K 318.67 317.83 317.79 316.97 315.52 302.68 297.35 294.772
wB(I) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001
wB(II) 0.4061 0.4000 0.4010 0.3860 0.3766 0.2424 0.1500 0.0696
T/K 294.584 294.543 294.474 294.342 294.237 294.101 294.086 293.946 293.892
wB(I) 0.0029 0.0008 0.0008 0.0028 0.0019 0.0033 0.0035 0.0062 0.0072
wB(II) 0.0612 0.0604 0.0596 0.0556 0.0521 0.0481 0.0493 0.0432 0.0415
T/K 293.811 293.788 293.757 293.738 293.722 293.716 293.711
wB(I) 0.0098 0.0099 0.0111 0.0136 0.0139 0.0159 0.0160
wB(II) 0.0372 0.0363 0.0337 0.0329 0.0288 0.0270 0.0261
Polymer (B): vinyl acetate/vinyl alcohol copolymer 1991EAG

wB 0.02 T/K 338.35 for a copolymer of 18.0 mol% vinyl acetate
____________________________________________________________________________________
Polymer (B): N-vinylcaprolactam/1-vinylimidazole copolymer 2000PE1

Polymer (B): N-vinylisobutyramide/N-vinylamine copolymer 2000KUN

8.0 mol% N-vinylamine, synthesized in the laboratory
wB 0.001 0.001 0.001
pH 13 11 10
T/K 320.35 327.75 341.05

wB 0.001 pH 13 T/K 325.85

wB 0.001 pH 13 T/K 334.85

wB 0.001 pH 13 T/K 346.75
____________________________________________________________________________________
graphical form as phase diagrams or related figures
_____________________________________________________________________________
Polymer (B) Solvent (A) Ref.
_____________________________________________________________________________
Acrylamide/N,N-dimethylaminoethyl methacrylate
copolymer water 1997CHO
_____________________________________________________________________________
Acrylic acid/N-isopropylacrylamide copolymer water 2000BO1
_____________________________________________________________________________
Acrylic acid/methyl acrylate copolymer water 1993TA1
_____________________________________________________________________________
Acrylic acid/2-methyl-5-vinylpyridine copolymer water 1985VED
_____________________________________________________________________________
N-Acryloylpyrrolidine/vinylferrocene copolymer water 1994KUR
_____________________________________________________________________________
N,N-Diethylacrylamide/acrylic acid copolymer water 2001CAI
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-methoxyethyl acrylate
copolymer water 1996ELE
water 1997ELE
_____________________________________________________________________________
N,N-Dimethylacrylamide/N-phenylacrylamide copolymer water 1996MIY
_____________________________________________________________________________
Ethylene/vinyl alcohol copolymer water 1971SHI
_____________________________________________________________________________
Ethylene glycol/N-isopropylacrylamide copolymer water 1997TOP
_____________________________________________________________________________
Ethylene oxide/alkylglycidyl ether copolymer water 2001LIU
_____________________________________________________________________________
Ethylene oxide/1,2-butylene oxide copolymer water 2000SAH
_____________________________________________________________________________
Ethylene oxide/(dialkoxymethyl)propylglycidyl
ether copolymer water 2001LIU
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Ethylene oxide/dimethylsiloxane triblock copolymer water 1992YAN
_____________________________________________________________________________
Ethylene oxide/propylene oxide copolymer water 1981MED
water 1987ANA
water 1991LOU
water 1993JOH
water 1994ZH1
water 1999JOH
water 1999PER
water 2000PE2
_____________________________________________________________________________
Ethyl(hydroxyethyl)cellulose water 1985FUR
water 1991SA1
water 2000BAD
water 2000JOA
_____________________________________________________________________________
2-Ethyl-2-oxazoline/ε-caprolactone diblock copolymer water 2000KIM
_____________________________________________________________________________
2-Ethyl-2-oxazoline/ε-caprolactone triblock copolymer water 2000KIM
_____________________________________________________________________________
Gelatine water 1987PAN
_____________________________________________________________________________
Hepta(ethylene glycol) monododecyl ether water 1981HEU
water 2002ZHE
_____________________________________________________________________________
Hepta(ethylene glycol) monotetradecyl ether water 1984COR
water 1998KUB
_____________________________________________________________________________
Hexa(ethylene glycol) monododecyl ether water 1991SC3
water 2002ZHE
_____________________________________________________________________________
Hexa(ethylene glycol) monooctyl ether water 1991SC3
_____________________________________________________________________________
Hydroxypropylcellulose water 1971KAG
water 1983CON
water 1985FUR
water 1989FOR
water 1991ROB
water 1995GUI
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
N-Isopropylacrylamide/acrylamide copolymer water 1987PRI
_____________________________________________________________________________
N-Isopropylacrylamide/N-butylacrylamide copolymer water 1987PRI
_____________________________________________________________________________
N-Isopropylacrylamide/N-tert-butylacrylamide copolymer water 1987PRI
_____________________________________________________________________________
N-Isopropylacrylamide/butyl acrylate copolymer water 2003MAE
_____________________________________________________________________________
N-Isopropylacrylamide/butyl methacrylate copolymer water 1993FEI
_____________________________________________________________________________
N-Isopropylacrylamide/N,N-dimethylaminopropyl-
methacrylamide copolymer water 2000BO2
_____________________________________________________________________________
N-Isopropylacrylamide/N-ethylacrylamide copolymer water 1987PRI
_____________________________________________________________________________
N-Isopropylacrylamide/ethyl acrylate copolymer water 2003MAE
_____________________________________________________________________________
N-Isopropylacrylamide/N-methylacrylamide copolymer water 1987PRI
_____________________________________________________________________________
N-Isopropylacrylamide/methyl acrylate copolymer water 2003MAE
_____________________________________________________________________________
N-Isopropylacrylamide/vinyl acetate copolymer water 2003MAE
_____________________________________________________________________________
Methylcellulose water 1997CHE
water 2001TAK
water 2002LIL
_____________________________________________________________________________
Methyl(hydroxypropyl)cellulose water 1974BAB
water 1999KIT
water 2003SCH
_____________________________________________________________________________
Penta(ethylene glycol) monododecyl ether water 1985HAM
water 1991SC3
_____________________________________________________________________________
Penta(ethylene glycol) monooctyl ether water 1991SC3
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly[bis(2,3-dimethoxypropanoxy)phosphazene] water 1996ALL
_____________________________________________________________________________
Poly[bis(2-(2'-methoxyethoxy)ethoxy)phosphazene] water 1996ALL
_____________________________________________________________________________
Poly[bis(ethyl glycinat-N-yl)phosphazene]-
b-poly(ethylene oxide) diblock copolymer water 2002CH3
_____________________________________________________________________________
Poly[bis(2,3-bis(2-methoxyethoxy)propanoxy)phosphazene] water 1996ALL
_____________________________________________________________________________
Poly[bis(2,3-bis(2-(2'-methoxyethoxy)ethoxy)propanoxy)
phosphazene] water 1996ALL
_____________________________________________________________________________
Poly[bis(2,3-bis(2-(2'-(2''-dimethoxyethoxy)ethoxy)ethoxy)
propanoxy)phosphazene] water 1996ALL
_____________________________________________________________________________
Poly(N-cyclopropylacrylamide) water 2001MA1
_____________________________________________________________________________
Poly(N,N-diethylacrylamide) water 1990MAR
water 2002MA2
_____________________________________________________________________________
Poly[N,N-dimethyl-N-methacryloyloxyethyl-
N-(3-sulfopropyl) ammonium betaine] water 1986SCH
water 2000CH1
_____________________________________________________________________________
Poly(dimethylsiloxane)-b-poly(ethylene oxide)-
b-poly(dimethylsiloxane) triblock copolymer water 1990MAA
_____________________________________________________________________________
Poly(1,3-dioxolane) water 1992BEN
_____________________________________________________________________________
Poly(ethylene glycol) water 1957MAL
water 1970NAK
water 1976SAE
water 1977SAE
water 1980MED
water 1987KLE
water 1994BOR
water 1996FIS
_____________________________________________________________________________
Poly(ethylene glycol) diacetyl ether water 1980MED
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(ethylene glycol) dimethyl ether water 1980MED
_____________________________________________________________________________
Poly(ethylene glycol) didodecyl ether water 1996FRA
_____________________________________________________________________________
Poly(ethylene glycol) dioctadecyl ether water 1996FRA
_____________________________________________________________________________
Poly(ethylene glycol) monododecyl ether water 1980KUR
water 1981HEU
water 1988FUJ
_____________________________________________________________________________
Poly(ethylene glycol) mono(p-nonylphenyl) ether water 2003BAL
_____________________________________________________________________________
Poly(ethylene glycol) mono(p-octylphenyl) ether water 1969GOL
_____________________________________________________________________________
Poly(ethylene glycol) trisiloxanemethyl ether water 1993HEM
_____________________________________________________________________________
Poly(ethylene oxide) water 2002HAM
water 1959BAI
water 1974TAG
water 1978VSH
water 1994BOR
_____________________________________________________________________________
Poly(ethylene oxide) biscarboxymethyl water 2002RAC
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(1,2-butylene oxide) water 2001HAM
diblock copolymer water 2002CH1
water 2002SON
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(1,2-butylene oxide)-
b-poly(ethylene oxide) triblock copolymer water 2002SON
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(dimethylsiloxane)-
b-poly(ethylene oxide) triblock copolymer water 1990MAA
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(L-lactid)-
b-poly(ethylene oxide) triblock copolymer water 1999JEO
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene oxide) water 1990SAM
diblock copolymer water 1990SIM
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene oxide)- water 1990SAM
b-poly(ethylene oxide) triblock copolymer water 1992MAL
water 1995ZHA
water 2000LAM
_____________________________________________________________________________
Poly(ethyl oxazoline) water 1988LIN
_____________________________________________________________________________
Poly(N-isopropylacrylamide) water 1989FUJ
water 1989INO
water 1990INO
water 1990MAR
water 1997SU1
water 1998ZHE
water 2000AFR
water 2001MA1
water 2001YA2
water 2003BAD
water 2003MIL
_____________________________________________________________________________
Poly(N-isopropylmethacrylamide) water 1989FUJ
water 2001MA2
_____________________________________________________________________________
Poly(methacrylic acid) water 1974TAN
_____________________________________________________________________________
Poly(3,6,9,12,15,18,21,24-octaoxatriacontanyl acrylate) water 1987JAH
_____________________________________________________________________________
Polyol (hyperbranched) water 1979SIM
water 2001JAN
_____________________________________________________________________________
Poly(N-propylacrylamide) water 1990INO
water 2001MA1
_____________________________________________________________________________
Poly(propylene glycol) water 1957MAL
water 1969KUZ
water 1972TA1
water 1974BES
water 1974TAN
water 1975TA3
water 1975TA4
water 1977VSH
water 1979SIM
water 1980BIL
water 1986FIR
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(propylene glycol) water 1988ZGA
water 1996GAL
water 2001KIN
_____________________________________________________________________________
Poly(N-propylmethacrylamide) water 2001MA2
_____________________________________________________________________________
Poly(vinyl alcohol) water 1963REH
water 1969AND
water 1971TAG
water 1974AND
water 1978NIK
water 1985FUR
water 1997PAE
_____________________________________________________________________________
Poly(N-vinylcaprolactam) water 1990TAG
water 1991TAG
water 1993TA2
water 1994TAG
water 1999LAU
water 2000ME2
water 2002MA1
_____________________________________________________________________________
Poly(vinyl ethyl ether) water 1966NAG
_____________________________________________________________________________
Poly(N-vinylisobutyramide) water 1997SU1
_____________________________________________________________________________
Poly(vinyl methyl ether) water 1988TAN
water 1997SCH
water 1998MOE
water 2000ME1
water 2001MA3
water 2001YA1
water 2003SWI
_____________________________________________________________________________
Poly(N-vinyl-N-propylacetamide) water 1991TAG
water 1994TAG
_____________________________________________________________________________
Tetra(ethylene glycol) diethyl ether water 1972NAK
_____________________________________________________________________________
Tetra(ethylene glycol) monodecyl ether water 1991SC3
_____________________________________________________________________________
Tetra(ethylene glycol) monododecyl ether water 1991SC3
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Tetra(ethylene glycol) monohexyl ether water 1991SC3
_____________________________________________________________________________
Tetra(ethylene glycol) monooctyl ether water 1991SC3
water 1999SHI
_____________________________________________________________________________
Tri(ethylene glycol) monohexyl ether water 1984COR
water 1991SC3
_____________________________________________________________________________
Tri(ethylene glycol) monooctyl ether water 1991SC3
_____________________________________________________________________________
N-Vinylacetamide/N-vinylisobutyramide copolymer water 1997SU2
_____________________________________________________________________________
Vinyl acetate /vinyl alcohol copolymer water 1974AND
water 1978NIK
water 1997PAE
_____________________________________________________________________________
Vinyl acetate/N-vinylcaprolactam copolymer water 1993PAS
_____________________________________________________________________________
Vinyl acetate/1-vinyl-2-pyrrolidinone copolymer water 1974TAN
_____________________________________________________________________________
Vinyl alcohol/vinyl butyrate copolymer water 1974TAN
water 1984SHI
_____________________________________________________________________________
Vinyl amine/N-vinylcaprolactam copolymer water 1991TAG
water 1994TAG
_____________________________________________________________________________
N-Vinylcaprolactam/methacrylic acid copolymer water 2002MAK
_____________________________________________________________________________
N-Vinylcaprolactam/N-vinyl-N-methylacetamide copolymer water 1993PAS
_____________________________________________________________________________
N-Vinylisobutyramide/N-vinylvaleramide copolymer water 1997SU2
_____________________________________________________________________________
____________________________________________________________________________________

containing water and at least one polymer
3.3.1. Nonelectrolyte solutions
Polymer (B): casein 1987GRI

−1
Characterization: Mw/g.mol = 300000, Biokhimreaktiv, Moscow, Russia
Polymer (C): ficoll
Characterization: Mw/g.mol−1 = 400000, Pharmacia Fine Chemicals, Uppsala, Sweden
T/K = 293.15
___________________________________________________________________________________
Total system Phase I Phase II
wA wB wC wA wB wC wA wB wC
___________________________________________________________________________________
0.8882 0.0618 0.0500 0.84996 0.1445 0.00554 0.91347 0.00683 0.0797
0.9044 0.0529 0.0427 0.87794 0.1146 0.00746 0.9231 0.0109 0.0660
0.9181 0.0451 0.0368 0.9087 0.0805 0.0108 0.9286 0.0144 0.0570
0.9249 0.0414 0.0337 0.9177 0.0648 0.0175 0.9324 0.0254 0.0422
0.9289 0.0410 0.0301 0.9289 0.0410 0.0301 0.9289 0.0410 0.0301
___________________________________________________________________________________
Polymer (B): dextran 1998ZHA

−1
Characterization: Mw/g.mol = 74000, Sigma Chemical Co., Inc., St. Louis, MO, USA
Characterization: Mw/g.mol−1 = 74000, hydrophobically modified by esterification with
C2-C5 carboxylic acids, D.S. = 0.23 moles of fatty acids/mole of
anhydroglucose units
T/K = 296.15
___________________________________________________________________________________
Top phase Bottom phase
wA wB wC ρ/g cm−3 wA wB wC ρ/g cm−3
___________________________________________________________________________________
0.8816 0.1159 0.0025 1.0466 0.8018 0.0132 0.1850 1.0601
0.9121 0.0627 0.0252 1.0296 0.8958 0.0252 0.0790 1.0455
0.9054 0.0757 0.0189 1.0338 0.8684 0.0250 0.1066 1.0413
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 323.15
___________________________________________________________________________________
0.8900 0.1100 0.0000 1.0411 0.7688 0.0092 0.2220 1.0666
0.9151 0.0819 0.0030 1.0306 0.8153 0.0137 0.1710 1.0536
0.9200 0.0720 0.0080 1.0314 0.8337 0.0183 0.1480 1.0484
0.9201 0.0577 0.0222 1.0269 0.8754 0.0325 0.0921 1.0383
___________________________________________________________________________________
Polymer (B): dextran 1998ZHA

−1
Characterization: Mw/g.mol = 74000, Sigma Chemical Co., Inc., St. Louis, MO, USA
Characterization: Mw/g.mol−1 = 74000, hydrophobically modified by esterification with
C2-C5 carboxylic acids, D.S. = 0.37 moles of fatty acids/mole of
anhydroglucose units
T/K = 296.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8406 0.0416 0.1178 1.0492 0.8564 0.1281 0.0155 1.0519
0.7824 0.0187 0.1989 1.0645 0.8152 0.1684 0.0164 1.0685
0.7788 0.0168 0.2044 1.0743 0.7809 0.1954 0.0237 1.0834
0.8391 0.0378 0.1231 1.0563 0.8419 0.1428 0.0153 1.0587
___________________________________________________________________________________
Polymer (B): dextran 2002LAA

Characterization: Mw/g.mol−1 = 60000, Fluka AG, Buchs, Switzerland
Type of data: cloud points
T/K = 283.15
wA 0.477 0.496 0.527 0.540 0.563 0.578 0.600 0.614 0.624
wB 0.330 0.304 0.252 0.237 0.205 0.180 0.145 0.121 0.104
wC 0.193 0.200 0.221 0.223 0.232 0.242 0.255 0.264 0.271
wA 0.632 0.641 0.647 0.652 0.657 0.661
wB 0.091 0.077 0.067 0.059 0.051 0.045
wC 0.276 0.282 0.286 0.289 0.292 0.294
T/K = 298.15
continued
____________________________________________________________________________________
continued
wA 0.523 0.593 0.603 0.611 0.617 0.620 0.623 0.625 0.627
wB 0.244 0.115 0.090 0.075 0.064 0.055 0.049 0.044 0.040
wC 0.233 0.293 0.306 0.315 0.320 0.324 0.328 0.331 0.333
wA 0.628 0.629 0.445 0.479 0.504 0.537 0.558 0.572 0.581
wB 0.036 0.034 0.369 0.312 0.270 0.212 0.175 0.148 0.129
wC 0.335 0.337 0.185 0.209 0.226 0.251 0.267 0.280 0.290
wA 0.589 0.600 0.607 0.613 0.617 0.622 0.625
wB 0.114 0.092 0.077 0.067 0.059 0.050 0.043
wC 0.297 0.308 0.316 0.321 0.325 0.328 0.332
T/K = 343.15
wA 0.449 0.494 0.536 0.546 0.553 0.559 0.565 0.569 0.576
wB 0.386 0.300 0.205 0.176 0.154 0.137 0.124 0.113 0.096
wC 0.165 0.206 0.260 0.277 0.292 0.304 0.311 0.317 0.328
wA 0.580 0.584 0.587 0.593 0.595
wB 0.083 0.074 0.066 0.055 0.050
wC 0.337 0.342 0.347 0.353 0.355
Polymer (B): dextran 1993NEU

T/K = 293.15
___________________________________________________________________________________
Total system Top phase Bottom phase
___________________________________________________________________________________
0.358 0.144 0.498 0.362 0.119 0.519 0.313 0.440 0.247
0.310 0.134 0.556 0.322 0.056 0.622 0.246 0.571 0.183
0.240 0.103 0.657 0.247 0.019 0.734 0.212 0.636 0.152
0.209 0.090 0.701 0.215 0.011 0.774 0.175 0.712 0.113
0.178 0.075 0.747 0.182 0.006 0.812 0.158 0.746 0.096
0.141 0.059 0.800 0.143 0.001 0.856 0.108 0.788 0.104
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.540 0.060 0.400 0.561 0.027 0.412 0.407 0.394 0.199
0.497 0.055 0.448 0.517 0.008 0.475 0.351 0.482 0.167
0.452 0.050 0.498 0.468 0.002 0.530 0.292 0.544 0.164
0.405 0.045 0.550 0.418 0.001 0.581 0.260 0.603 0.137
0.361 0.040 0.599 0.371 0.000 0.629 0.235 0.646 0.119
0.313 0.035 0.652 0.320 0.000 0.680 0.218 0.695 0.087
___________________________________________________________________________________

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.592 0.066 0.342 0.619 0.018 0.363 0.471 0.316 0.213
0.567 0.063 0.370 0.593 0.007 0.400 0.413 0.388 0.199
0.540 0.060 0.400 0.559 0.002 0.439 0.377 0.454 0.169
0.496 0.055 0.449 0.516 0.001 0.483 0.351 0.496 0.153
0.450 0.050 0.500 0.465 0.000 0.535 0.311 0.551 0.138
0.426 0.051 0.523 0.439 0.000 0.561 0.279 0.593 0.128
0.359 0.040 0.601 0.372 0.000 0.628 0.245 0.644 0.111
___________________________________________________________________________________

T/K = 293.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.616 0.069 0.315 0.652 0.009 0.339 0.512 0.257 0.231
0.589 0.065 0.346 0.621 0.003 0.376 0.457 0.334 0.209
0.538 0.060 0.402 0.560 0.001 0.439 0.376 0.478 0.146
0.495 0.055 0.450 0.514 0.000 0.486 0.328 0.539 0.133
0.449 0.050 0.501 0.461 0.000 0.539 0.308 0.575 0.117
___________________________________________________________________________________

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.569 0.063 0.368 0.569 0.060 0.371 0.509 0.225 0.266
0.567 0.063 0.370 0.566 0.056 0.378 0.493 0.250 0.257
0.563 0.062 0.375 0.563 0.052 0.385 0.474 0.269 0.257
0.558 0.062 0.380 0.559 0.047 0.394 0.451 0.317 0.232
0.554 0.061 0.385 0.557 0.041 0.402 0.430 0.339 0.231
0.549 0.061 0.390 0.554 0.038 0.408 0.430 0.341 0.229
0.540 0.060 0.400 0.544 0.031 0.425 0.406 0.382 0.212
___________________________________________________________________________________
Fractionation of dextran (B) during demixing (the lines correspond with those above):
______________________________________________
Mn/ Mw/ M n/ Mw/
−1
g mol g mol−1 g mol −1
g mol−1
______________________________________________
7500 11100 12115 18900
7357 10300 11830 18100
7299 10000 11844 16700
6838 9300 11500 16100
6929 8800 11460 15700
6176 8400 10929 15300
5789 7700 10519 14200
______________________________________________
____________________________________________________________________________________

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.636 0.034 0.330 0.639 0.031 0.330 0.599 0.137 0.264
0.632 0.033 0.335 0.634 0.027 0.339 0.567 0.183 0.250
0.627 0.033 0.340 0.628 0.024 0.348 0.576 0.174 0.250
0.616 0.033 0.351 0.627 0.022 0.351 0.543 0.210 0.247
0.608 0.032 0.360 0.618 0.015 0.367 0.514 0.252 0.234
0.598 0.032 0.370 0.603 0.014 0.383 0.485 0.299 0.216
0.589 0.031 0.380 0.601 0.011 0.388 0.468 0.321 0.211
0.579 0.031 0.390 0.589 0.009 0.402 0.442 0.344 0.214
0.570 0.030 0.400 0.582 0.008 0.410 0.439 0.341 0.220
0.616 0.069 0.315 0.624 0.054 0.322 0.543 0.205 0.252
0.612 0.068 0.320 0.625 0.046 0.329 0.530 0.223 0.247
0.607 0.068 0.325 0.627 0.039 0.334 0.514 0.249 0.237
0.603 0.067 0.330 0.622 0.032 0.346 0.490 0.282 0.228
0.598 0.066 0.336 0.616 0.029 0.355 0.491 0.279 0.230
0.594 0.066 0.340 0.615 0.025 0.360 0.462 0.323 0.215
0.585 0.065 0.350 0.606 0.020 0.374 0.440 0.347 0.213
0.576 0.064 0.360 0.596 0.017 0.387 0.437 0.358 0.205
0.567 0.063 0.370 0.588 0.014 0.398 0.415 0.395 0.190
0.558 0.062 0.380 0.577 0.013 0.410 0.419 0.394 0.187
0.549 0.061 0.390 0.569 0.010 0.421 0.388 0.431 0.181
0.540 0.060 0.400 0.562 0.008 0.430 0.381 0.448 0.171
0.594 0.105 0.301 0.610 0.077 0.313 0.539 0.209 0.252
0.591 0.104 0.305 0.616 0.054 0.330 0.518 0.240 0.242
0.586 0.104 0.310 0.615 0.045 0.340 0.493 0.272 0.235
0.582 0.103 0.315 0.614 0.038 0.348 0.473 0.302 0.225
0.578 0.102 0.320 0.611 0.034 0.355 0.466 0.311 0.223
0.574 0.101 0.325 0.607 0.027 0.366 0.460 0.321 0.219
0.569 0.101 0.330 0.603 0.027 0.370 0.453 0.325 0.222
0.561 0.099 0.340 0.594 0.033 0.373 0.450 0.332 0.218
0.552 0.098 0.350 0.585 0.017 0.398 0.424 0.379 0.197
0.544 0.096 0.360 0.575 0.014 0.411 0.405 0.393 0.202
0.535 0.095 0.370 0.570 0.011 0.419 0.381 0.435 0.184
0.527 0.093 0.380 0.561 0.011 0.428 0.366 0.455 0.179
0.518 0.092 0.390 0.554 0.008 0.438 0.362 0.465 0.173
0.510 0.090 0.400 0.549 0.007 0.444 0.357 0.468 0.175
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
Fractionation of dextran (B) during demixing (the lines correspond with those above):
______________________________________________
Mn Mw Mn Mw
g mol−1 g mol−1 g mol−1 g mol−1
______________________________________________
17529 44700 45168 134600
16061 37100 44897 109100
15138 33000 43197 105400
14106 29200 43172 98000
11036 21300 43147 85000
10615 19000 41443 83300
9817 16100 38557 77500
8616 13700 37565 72500
8224 12500 35369 71800
16480 41200 33345 94700
15310 34600 36016 92200
13665 30200 30111 81300
12587 25300 34093 80800
11658 22500 34052 79000
10538 19600 33901 75600
10000 17000 33378 74100
8820 14200 32706 71300
8650 14100 30264 68700
7483 11300 30717 68500
7055 10300 29955 66500
6389 9200 28565 65700
16208 38900 28768 79400
12952 27200 30314 77300
11724 23800 30413 73600
10674 20600 29259 71100
10160 19000 30172 70300
9195 16000 29356 68400
9257 16200 28708 68900
9721 17400 28898 68200
7500 11700 28584 66600
6933 10400 27563 65600
6370 9300 27257 64600
6181 8900 26276 62800
6000 8400 25228 60800
5971 8300 25184 61700
______________________________________________
Polymer (B): dextran 1992ZAS

Lot 680480, Minmedprom, Moscow, Russia
continued
____________________________________________________________________________________
continued
Polymer (C): ficoll
Characterization: Mw/g.mol−1 = 400000, Lot HH-26371
Pharmacia Fine Chemicals, Uppsala, Sweden
T/K = 298.15
_____________________________________________________________________
wA wB wC wA wB wC
_____________________________________________________________________
0.6487 0.0343 0.3170 0.6766 0.2832 0.0402
0.6865 0.0425 0.2710 0.7089 0.2419 0.0492
0.7419 0.0528 0.2053 0.7564 0.1821 0.0615
0.7667 0.0622 0.1711 0.7766 0.1509 0.0725
0.7806 0.0780 0.1414 0.7862 0.1235 0.0908
_____________________________________________________________________
Dependence on pH, the total systems contain 0.01 mol/L universal buffer.
_____________________________________________________________________
wA wB wC pH wA wB wC pH
_____________________________________________________________________
0.7661 0.0228 0.2111 7.75 0.7917 0.1824 0.0259 7.74
0.7947 0.0278 0.1775 7.79 0.8079 0.1596 0.0325 7.78
0.7853 0.0210 0.1937 7.43 0.7749 0.1971 0.0280 7.42
0.8031 0.0267 0.1702 7.45 0.8018 0.1647 0.0335 7.46
0.8455 0.0412 0.1133 7.52 0.8445 0.1050 0.0505 7.54
_____________________________________________________________________
Polymer (A): dextran 1986ALB

Dextran 500, Pharmacia Fine Chemicals, Uppsala, Sweden
Polymer (C): ficoll
T/K = 296.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8500 0.0500 0.1000 0.8593 0.0817 0.0590 0.8367 0.0140 0.1493
0.8400 0.0600 0.1000 0.8509 0.0991 0.0500 0.8249 0.0100 0.1651
0.8300 0.0700 0.1000 0.8399 0.1148 0.0443 0.8125 0.0076 0.1799
0.8000 0.0800 0.1200 0.8146 0.1435 0.0419 0.7826 0.0041 0.2133
___________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): dextran 2001EDE

Characterization: Mw/g.mol−1 = 148000, Sigma Chemical Co., Inc., St. Louis, MO, USA
Polymer (C): gelatin
Characterization: Mw/g.mol−1 = 170000, IEP = 8.7, bloom 305 g
porcine skin gelatin, Degussa Biosystems, Baupte, France
Comments: The molar mass of gelatin depends somewhat on temperature caused by some extent of
dimerization on cooling (above the gelation temperature):
at T/K = 313.15, Mw/g.mol−1 = 177000
at T/K = 323.15, Mw/g.mol−1 = 184000
at T/K = 333.15, Mw/g.mol−1 = 175000
at T/K = 343.15, Mw/g.mol−1 = 167000
at T/K = 353.15, Mw/g.mol−1 = 147000
Comments: Solutions were prepared by using water with 0.1 M NaCl and 0.02% NaN3. Phase separation
changes when the salt concentration changes.
___________________________________________________________________________________
T/ Total system Dextran-rich phase Gelatin-rich phase
K wA wB wC wA wB wC wA wB wC
___________________________________________________________________________________
323.15 0.900 0.050 0.050 0.9049 0.0834 0.0117 0.8948 0.0100 0.0952
333.15 0.900 0.050 0.050 0.9071 0.0812 0.0117 0.8910 0.0132 0.0958
338.15 0.900 0.050 0.050 0.9030 0.0835 0.0135 0.8851 0.0112 0.1037
343.15 0.900 0.050 0.050 0.8986 0.0871 0.0143 0.8877 0.0156 0.0967
353.15 0.900 0.050 0.050 0.9028 0.0816 0.0156 0.8891 0.0170 0.0939
___________________________________________________________________________________

at T/K = 313.15, Mw/g.mol−1 = 177000
at T/K = 323.15, Mw/g.mol−1 = 184000
at T/K = 333.15, Mw/g.mol−1 = 175000
at T/K = 343.15, Mw/g.mol−1 = 167000
at T/K = 353.15, Mw/g.mol−1 = 147000
continued
____________________________________________________________________________________
continued
For determining the phase separation temperature, the polymer concentrations were fixed by
wB/wC = 50/50 = 1/1.
T/K 293.65 294.65 296.15 297.65 299.65 301.15 312.15 321.15 332.15
wA 0.9780 0.9730 0.9675 0.9627 0.9573 0.9525 0.9409 0.9402 0.9399
wB 0.0110 0.0135 0.01625 0.01865 0.02135 0.02375 0.02955 0.02990 0.03005
wC 0.0110 0.0135 0.01625 0.01865 0.02135 0.02375 0.02955 0.02990 0.03005
___________________________________________________________________________________
T/ Total system Dextran-rich phase Gelatin-rich phase
K wA wB wC wA wB wC wA wB wC
___________________________________________________________________________________
318.15 0.930 0.035 0.035 0.9359 0.0452 0.0189 0.9258 0.0201 0.0541
323.15 0.930 0.035 0.035 0.9318 0.0453 0.0229 0.9285 0.0232 0.0483
323.15 0.920 0.040 0.040 0.9303 0.0574 0.0123 0.9167 0.0160 0.0673
323.15 0.910 0.045 0.045 0.9198 0.0691 0.0111 0.9055 0.0143 0.0802
323.15 0.900 0.050 0.050 0.9121 0.0785 0.0094 0.9015 0.0111 0.0874
328.15 0.930 0.035 0.035 0.9314 0.0461 0.0225 0.9281 0.0206 0.0513
328.15 0.900 0.050 0.050 0.9161 0.0763 0.0076 0.8960 0.0122 0.0918
330.15 0.930 0.035 0.035 0.9304 0.0464 0.0232 0.9208 0.0240 0.0552
333.15 0.930 0.035 0.035 0.9354 0.0439 0.0207 0.9290 0.0211 0.0499
333.15 0.920 0.040 0.040 0.9290 0.0564 0.0146 0.9205 0.0148 0.0647
333.15 0.910 0.045 0.045 0.9136 0.0693 0.0171 0.9053 0.0146 0.0801
333.15 0.900 0.050 0.050 0.9120 0.0784 0.0096 0.8998 0.0109 0.0893
335.15 0.930 0.035 0.035 0.9352 0.0437 0.0211 0.9271 0.0234 0.0495
338.15 0.900 0.050 0.050 0.9166 0.0756 0.0078 0.9097 0.0069 0.0834
343.15 0.920 0.040 0.040 0.9279 0.0543 0.0178 0.9151 0.0193 0.0656
343.15 0.910 0.045 0.045 0.9116 0.0667 0.0217 0.9099 0.0144 0.0757
343.15 0.900 0.050 0.050 0.9074 0.0793 0.0133 0.8935 0.0150 0.0915
348.15 0.910 0.045 0.045 0.9238 0.0599 0.0163 0.9054 0.0170 0.0776
348.15 0.900 0.050 0.050 0.9121 0.0763 0.0116 0.9004 0.0129 0.0867
___________________________________________________________________________________

at T/K = 313.15, Mw/g.mol−1 = 177000
at T/K = 323.15, Mw/g.mol−1 = 184000
continued
____________________________________________________________________________________
continued
at T/K = 333.15, Mw/g.mol−1 = 175000
at T/K = 343.15, Mw/g.mol−1 = 167000
at T/K = 353.15, Mw/g.mol−1 = 147000
wB/wC = 50/50 = 1/1.
T/K 296.15 297.15 297.65 298.65 299.65 300.15 301.65 304.15 307.15
wA 0.9515 0.9445 0.9445 0.9375 0.9322 0.9323 0.9241 0.9164 0.9005
wB 0.02425 0.02775 0.02775 0.03125 0.03390 0.03385 0.03795 0.04180 0.04975
wC 0.02425 0.02775 0.02775 0.03125 0.03390 0.03385 0.03795 0.04180 0.04975
T/K 307.65 309.15 309.15 309.65 310.15 311.65 312.15 321.15 332.15
wA 0.9062 0.9075 0.9080 0.9094 0.9061 0.9069 0.9076 0.9058 0.9055
wB 0.04690 0.04625 0.04600 0.04530 0.04695 0.04655 0.04620 0.04710 0.04725
wC 0.04690 0.04625 0.04600 0.04530 0.04695 0.04655 0.04620 0.04710 0.04725

−1
Characterization: Mw/g.mol = 2000000, Sigma Chemical Co., Inc., St. Louis, MO
at T/K = 313.15, Mw/g.mol−1 = 177000
at T/K = 323.15, Mw/g.mol−1 = 184000
at T/K = 333.15, Mw/g.mol−1 = 175000
at T/K = 343.15, Mw/g.mol−1 = 167000
at T/K = 353.15, Mw/g.mol−1 = 147000
wB/wC = 50/50 = 1/1.
T/K 292.15 294.15 297.65 297.65 299.15 300.65 301.65 302.15 305.15
wA 0.9840 0.9805 0.9720 0.9758 0.9676 0.9575 0.9632 0.9612 0.9592
wB 0.0080 0.00975 0.0140 0.0121 0.0162 0.02125 0.0184 0.0194 0.0204
wC 0.0080 0.00975 0.0140 0.0121 0.0162 0.02125 0.0184 0.0194 0.0204
T/K 309.15 309.65 310.15 311.65 312.15 322.15 338.15
wA 0.9569 0.9567 0.9567 0.9564 0.9532 0.9531 0.9530
wB 0.02155 0.02165 0.02165 0.0218 0.0234 0.02345 0.0235
wC 0.02155 0.02165 0.02165 0.0218 0.0234 0.02345 0.0235
____________________________________________________________________________________

Polymer (C): hydroxypropyldextran
Characterization: Mw/g.mol−1 = 500000, D.S. = 0.39 per glucose unit, prepared from
T/K = 296.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8900 0.0600 0.0500 0.8938 0.0422 0.0640 0.8872 0.0824 0.0304
0.8800 0.0700 0.0500 0.8855 0.0371 0.0774 0.8770 0.0996 0.0230
0.8600 0.0800 0.0600 0.8678 0.0246 0.1076 0.8558 0.1208 0.0234
___________________________________________________________________________________

Polymer (C): hydroxypropyldextran
Characterization: Mn/g.mol−1 = 75000, D.S. = 1.0 per glucose unit, prepared from
T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9600 0.0200 0.0200 0.9616 0.0137 0.0247 0.9592 0.0256 0.0152
0.9500 0.0250 0.0250 0.9545 0.0077 0.0378 0.9485 0.0420 0.0095
0.9400 0.0300 0.0300 0.9425 0.0056 0.0519 0.9367 0.0551 0.0082
0.9200 0.0400 0.0400 0.9248 0.0039 0.0713 0.9153 0.0772 0.0075
0.9000 0.0500 0.0500 0.9075 0.0029 0.0896 0.8940 0.0988 0.0072
0.8800 0.0600 0.0600 0.8909 0.0024 0.1067 0.8711 0.1238 0.0051
___________________________________________________________________________________

−1 −1
continued
____________________________________________________________________________________
continued
Polymer (C): methylcellulose
Characterization: Mη/g.mol−1 = 30000, Methocel 10, Dow Chemical Company
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9688 0.0172 0.0140 0.9722 0.0100 0.0178 0.9673 0.0198 0.0129
0.9640 0.0200 0.0160 0.9707 0.0073 0.0220 0.9595 0.0285 0.0120
0.9600 0.0220 0.0180 0.9684 0.0055 0.0261 0.9533 0.0345 0.0122
___________________________________________________________________________________

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9840 0.0100 0.0060 0.9875 0.0047 0.0078 0.9791 0.0176 0.0033
0.9830 0.0100 0.0070 0.9867 0.0033 0.0100 0.9770 0.0201 0.0029
0.9800 0.0120 0.0080 0.9849 0.0028 0.0123 0.9732 0.0242 0.0026
0.9690 0.0200 0.0110 0.9774 0.0024 0.0202 0.9606 0.0374 0.0020
___________________________________________________________________________________

−1 −1
T/K = 277.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.9890 0.0080 0.0030 0.9906 0.0056 0.0038 0.9862 0.0121 0.0017
0.9896 0.0068 0.0036 0.9906 0.0051 0.0043 0.9849 0.0133 0.0018
0.9872 0.0080 0.0048 0.9899 0.0038 0.0063 0.9814 0.0172 0.0014
0.9810 0.0120 0.0070 0.9863 0.0025 0.0112 0.9735 0.0251 0.0014
0.9830 0.0050 0.0120 0.9845 0.0018 0.0137 0.9703 0.0288 0.0009
___________________________________________________________________________________
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9891 0.0079 0.0030 0.9907 0.0057 0.0036 0.9874 0.0109 0.0017
0.9896 0.0068 0.0036 0.9910 0.0047 0.0043 0.9865 0.0118 0.0017
0.9854 0.0110 0.0036 0.9896 0.0039 0.0065 0.9827 0.0158 0.0015
0.9788 0.0158 0.0054 0.9857 0.0028 0.0115 0.9746 0.0242 0.0012
0.9720 0.0200 0.0080 0.9799 0.0023 0.0178 0.9663 0.0327 0.0010
___________________________________________________________________________________
Polymer (B): dextran 1996MIS

Polymer (C): poly(ethylene glycol) monomethyl ether
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8729 0.0875 0.0396 0.9063 0.0000 0.0937 0.8518 0.1297 0.0185
0.8440 0.1072 0.0488 0.8967 0.0000 0.1033 0.8067 0.1787 0.0146
0.8135 0.1280 0.0585 0.8745 0.0000 0.1255 0.7556 0.2353 0.0091
0.7885 0.1421 0.0694 0.8530 0.0000 0.1470 0.7123 0.2817 0.0060
___________________________________________________________________________________
Polymer (B): dextran 1998KIS

−1
Characterization: Mw/g.mol = 170000-200000, Nacalai Tesque, Kyoto, Japan
continued
____________________________________________________________________________________
continued
Polymer (C): poly(N-vinylacetamide)
T/K = 277.15
___________________________________________________________________________________
cB/(mol/l) cC/(mol/l) wA wB wC wA wB wC
___________________________________________________________________________________
1.2 3.5 0.935 0.035 0.030 0.936 0.053 0.011
1.7 6.0 0.908 0.017 0.075 0.893 0.102 0.005
2.0 8.1 0.849 0.014 0.137 0.873 0.127 0.000
3.3 10.5 0.852 0.011 0.137 0.815 0.185 0.000
___________________________________________________________________________________
Polymer (B): ethylene oxide/propylene oxide copolymer 1995BE2

Characterization: Mn/g.mol−1 = 3200, 30 mol% ethylene oxide
Shearwater Polymers, Huntsville, AL, USA
Characterization: Mw/g.mol−1 = 200000, Reppe Glykos AB, Vaxjo, Sweden
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.850 0.090 0.060 0.865 0.101 0.034 0.775 0.030 0.195
0.830 0.090 0.080 0.859 0.115 0.026 0.760 0.028 0.212
0.790 0.100 0.110 0.832 0.148 0.020 0.722 0.019 0.259
0.780 0.100 0.120 0.829 0.153 0.018 0.714 0.020 0.266
___________________________________________________________________________________
Polymer (B): ethylene oxide/propylene oxide copolymer 1994MOD, 1995BE2

−1
Characterization: Mn/g.mol = 4000, 50 mol% ethylene oxide
Ucon 50-HB-5100, Union Carbide Corp., New York, NY, USA
continued
____________________________________________________________________________________
continued
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.856 0.075 0.069 0.873 0.088 0.039 0.797 0.015 0.188
0.845 0.080 0.075 0.866 0.101 0.033 0.786 0.017 0.197
0.820 0.080 0.100 0.857 0.115 0.028 0.750 0.006 0.244
0.808 0.100 0.092 0.840 0.139 0.021 0.734 0.008 0.258
0.759 0.125 0.116 0.803 0.185 0.012 0.676 0.005 0.319
___________________________________________________________________________________

Characterization: Mn/g.mol−1 = 10000, Reppe Glykos AB, Vaxjo, Sweden
T/K = 298.15
___________________________________________________________________________________
Total system Bottom phase Top phase
___________________________________________________________________________________
0.8500 0.1000 0.0500 0.7729 0.0250 0.2021 0.8571 0.1080 0.0349
0.8399 0.0999 0.0602 0.7618 0.0222 0.2160 0.8533 0.1139 0.0328
0.8300 0.1000 0.0700 0.7494 0.0204 0.2302 0.8498 0.1200 0.0302
0.8208 0.0995 0.0797 0.7405 0.0190 0.2405 0.8460 0.1260 0.0280
0.8099 0.0999 0.0902 0.7276 0.0172 0.2552 0.8420 0.1321 0.0259
0.8002 0.0999 0.0999 0.7169 0.0159 0.2672 0.8370 0.1380 0.0250
0.7901 0.1000 0.1099 0.7077 0.0152 0.2771 0.8320 0.1441 0.0239
0.7801 0.1000 0.1199 0.6950 0.0140 0.2909 0.8280 0.1489 0.0231
___________________________________________________________________________________
Plait-point composition: wA = 0.827 + wB = 0.063 + wC = 0.110

−1 −1
Characterization: Mn/g.mol = 3000, Mw/g.mol = 3300, 33.3 mol% ethylene oxide
continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8503 0.0999 0.0498 0.7872 0.0220 0.1908 0.8597 0.1118 0.0285
0.8401 0.1000 0.0599 0.7699 0.0171 0.2130 0.8561 0.1200 0.0239
0.8299 0.1001 0.0700 0.7567 0.0122 0.2311 0.8519 0.1271 0.0210
0.8201 0.1000 0.0799 0.7480 0.0100 0.2420 0.8469 0.1340 0.0190
0.8099 0.1000 0.0901 0.7336 0.0062 0.2602 0.8431 0.1390 0.0179
0.7998 0.1000 0.1002 0.7235 0.0050 0.2715 0.8361 0.1481 0.0158
0.7902 0.1000 0.1098 0.7145 0.0050 0.2805 0.8323 0.1529 0.0148
0.7796 0.1002 0.1202 0.7068 0.0050 0.2882 0.8260 0.1600 0.0140
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8498 0.1000 0.0502 0.7895 0.0303 0.1802 0.8549 0.1070 0.0381
0.8399 0.0999 0.0602 0.7767 0.0282 0.1951 0.8517 0.1141 0.0342
0.8296 0.1000 0.0704 0.7679 0.0251 0.2070 0.8476 0.1202 0.0322
0.8199 0.1001 0.0800 0.7516 0.0222 0.2262 0.8419 0.1281 0.0300
0.8099 0.1002 0.0899 0.7447 0.0212 0.2341 0.8378 0.1342 0.0280
0.8000 0.1000 0.1000 0.7326 0.0201 0.2473 0.8335 0.1403 0.0262
0.7901 0.1000 0.1099 0.7207 0.0201 0.2592 0.8299 0.1451 0.0250
0.7801 0.1000 0.1199 0.7090 0.0200 0.2710 0.8248 0.1511 0.0241
___________________________________________________________________________________
____________________________________________________________________________________

Characterization: Mn/g.mol−1 = 20000, Reppe Glykos AB, Sweden
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8403 0.0999 0.0598 0.7753 0.0241 0.2006 0.8627 0.1022 0.0351
0.8499 0.1001 0.0500 0.7620 0.0198 0.2182 0.8605 0.1090 0.0305
0.8403 0.0999 0.0704 0.7448 0.0142 0.2410 0.8570 0.1160 0.0270
0.8302 0.0999 0.0598 0.7290 0.0110 0.2600 0.8534 0.1230 0.0236
0.8201 0.1001 0.0699 0.7203 0.0092 0.2705 0.8495 0.1275 0.0230
0.8099 0.1001 0.0798 0.7089 0.0063 0.2848 0.8448 0.1322 0.0230
0.7996 0.1001 0.0899 0.6973 0.0052 0.2975 0.8410 0.1370 0.0220
0.7900 0.1001 0.1099 0.6892 0.0050 0.3058 0.8357 0.1423 0.0220
0.7802 0.0999 0.1199 0.6750 0.0050 0.3200 0.8320 0.1462 0.0218
___________________________________________________________________________________

wB 0.005 0.005 0.005 0.005 0.005 0.005
ϕC 0.00 0.10 0.20 0.30 0.40 0.50
T/K 305.25 306.25 306.95 309.95 320.05 338.35
Polymer (B): polyetherimide 1989ROE

Characterization: Mw/g.mol−1 = 32800, ρ = 1.27 g/cm3
Ultem 1000, General Electric, Bergen op Zoom, Netherlands
Solvent (C): 1-methyl-2-pyrrolidinone C5H9NO 872-50-4
T/K = 294
wA 0.055 0.050 0.050 0.049 0.048 0.049 0.046 0.044 0.037
wB 0.004 0.016 0.037 0.057 0.076 0.079 0.094 0.117 0.246
wC 0.941 0.931 0.913 0.894 0.876 0.872 0.860 0.839 0.717
____________________________________________________________________________________
Polymer (B): polyethersulfone 1999BAR, 2000BA1

Ultrason E 6020 P, BASF AG, Ludwigshafen, Germany
T/K = 293.15
wA 0.0696 0.0652 0.0639 0.0623 0.0610 0.0542
wB 0.0055 0.0099 0.0187 0.0244 0.0386 0.1185
wC 0.9249 0.9249 0.9174 0.9133 0.9004 0.8273
T/K = 303.15
wA 0.0720 0.0669 0.0658 0.0654 0.0638 0.0596 0.0562
wB 0.0055 0.0099 0.0187 0.0243 0.0380 0.0763 0.1174
wC 0.9225 0.9232 0.9155 0.9103 0.8982 0.8641 0.8264
T/K = 313.15
wA 0.0740 0.0688 0.0682 0.0690 0.0665 0.0620 0.0591
wB 0.0055 0.0099 0.0186 0.0242 0.0374 0.0753 0.1156
wC 0.9205 0.9213 0.9132 0.9068 0.8961 0.8627 0.8253
T/K = 323.15
wA 0.0787 0.0701 0.0706 0.0703 0.0693 0.0649 0.0614
wB 0.0054 0.0099 0.0186 0.0241 0.0369 0.0741 0.1142
wC 0.9159 0.9200 0.9108 0.9056 0.8938 0.8610 0.8244
T/K = 303.15
___________________________________________________________________________________
Total system Sol phase Gel phase
___________________________________________________________________________________
0.063 0.038 0.899 0.068 0.035 0.897 0.060 0.140 0.800
0.069 0.039 0.892 0.069 0.017 0.914 0.053 0.222 0.725
0.073 0.039 0.888 0.079 0.014 0.907 0.054 0.298 0.648
0.076 0.046 0.878 0.084 0.011 0.905 0.056 0.297 0.647
___________________________________________________________________________________
Polymer (B): polyethersulfone 1988ZEM

ρB (298 K) = 1.370 g/cm3, Victrex 4100, I.C.I. US, Inc., USA
continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.133 0.129 0.116 0.114 0.105 0.098 0.088 0.076
wB 0.009 0.026 0.049 0.089 0.134 0.180 0.228 0.370
wC 0.858 0.845 0.835 0.797 0.761 0.722 0.684 0.554
T/K = 298.15
____________________________________________________
Sol phase Gel phase
wA wB wC wA wB wC
____________________________________________________
0.1596 0.0139 0.8300 0.06 0.38 0.56
0.1875 0.0025 0.8100 0.11 0.50 0.39
____________________________________________________
Polymer (B): polyetherurethane 1987GER

Characterization: Mη/g.mol−1 = 95000, [poly(ethylene glycol adipinate), M = 2000] :
4,4'-diphenylmethanediisocyanate : 1,4-butanediol = 1:3:2
T/K = 295
ϕA 0.0567 0.0526 0.0445 0.0404 0.0363 0.0322 0.0282 0.0241 0.0200
ϕB 0.0239 0.0284 0.0404 0.0486 0.0592 0.0738 0.0957 0.1346 0.2250
ϕA 0.0646 0.0699 0.0831 0.0917 0.1028 0.1182 0.1417 0.1844 0.2827
ϕB 0.0174 0.0142 0.0088 0.0066 0.0048 0.0032 0.0020 0.0013 0.0019
Type of data: spinodal points
T/K = 295
ϕA 0.0584 0.0564 0.0531 0.0520 0.0512 0.0511 0.0523 0.0559 0.0657
ϕB 0.0226 0.0253 0.0333 0.0392 0.0470 0.0583 0.0758 0.1081 0.1862
ϕA 0.0631 0.0666 0.0766 0.0837 0.0934 0.1073 0.1291 0.1689 0.2564
ϕB 0.0187 0.0169 0.0142 0.0132 0.0125 0.0121 0.0124 0.0142 0.0243
Polymer (B): poly(ethylene glycol) 1995PAN

Characterization: Mw/g.mol−1 = 400, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
Component (C): deca(ethylene glycol) monocetyl ether
wA 0.98 0.96 0.94 0.92 0.90 0.88 0.84 0.78
wB 0.00 0.02 0.04 0.06 0.08 0.10 0.14 0.20
wC 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02
T/K 350.15 350.15 351.15 352.15 352.15 353.15 354.15 357.15
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1995PAN

Component (C): deca(ethylene glycol) monooleyl ether
wA 0.98 0.96 0.94 0.92 0.90 0.88 0.84 0.78
wB 0.00 0.02 0.04 0.06 0.08 0.10 0.14 0.20
wC 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02
T/K 336.15 335.15 335.15 336.15 336.15 336.15 338.15 340.15
Polymer (B): poly(ethylene glycol) 1993GA1

PL 500 VC, Pfeifer & Langen, Dormagen, Germany
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7443 0.1484 0.1073 0.7757 0.1909 0.0334 0.7158 0.1332 0.1510
0.7133 0.1684 0.1183 0.7641 0.2255 0.0104 0.6590 0.1106 0.2304
0.7015 0.1737 0.1248 0.7541 0.2384 0.0075 0.6349 0.1029 0.2622
0.6768 0.1879 0.1353 0.7364 0.2606 0.0030 0.5971 0.0862 0.3167
0.6563 0.1966 0.1471 0.7230 0.2764 0.0006 0.5709 0.0806 0.3485
0.6417 0.2029 0.1554 0.7072 0.2921 0.0007 0.5480 0.0775 0.3745
___________________________________________________________________________________
Fractionation of dextran during demixing (the lines correspond with those above):
_____________________________________
Mn/ Mw/ Mn/ Mw/
−1 −1
g.mol g.mol g.mol g.mol−1
−1
_____________________________________
67000 119748 113744 514158
45665 71326 107073 451683
38330 68395 101464 447542
31698 57808 102588 448402
30385 34539 100114 430362
22352 30570 100118 446267
_____________________________________
____________________________________________________________________________________

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8287 0.0905 0.0808 0.8567 0.1115 0.0318 0.8079 0.0728 0.1193
0.8245 0.0906 0.0849 0.8567 0.1169 0.0264 0.7977 0.0694 0.1329
0.8033 0.0958 0.1009 0.7526 0.1386 0.0088 0.7546 0.0520 0.1934
0.7835 0.0985 0.1180 0.8412 0.1547 0.0041 0.7252 0.0425 0.2323
0.7610 0.0895 0.1495 0.8350 0.1619 0.0031 0.7110 0.0380 0.2510
0.7493 0.1108 0.1399 0.8170 0.1816 0.0014 0.6745 0.0307 0.2948
___________________________________________________________________________________
_____________________________________
Mn/ Mw/ Mn/ Mw/
−1 −1
−1
_____________________________________
77794 138494 129136 486174
70185 115761 118567 462465
50536 70517 119028 441921
37870 49985 101766 393164
34212 42852 106709 399612
27860 34021 105530 400696
_____________________________________
Polymer (B): poly(ethylene glycol) 1995FUR

Wako Pure Chemical Ind., Ltd., Osaka, Japan
T40, Pharmacia Inc., Tokyo, Japan
continued
____________________________________________________________________________________
continued
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8501 0.0898 0.0601 0.8581 0.1003 0.0416 0.8001 0.0396 0.1603
0.8399 0.0950 0.0651 0.8583 0.1142 0.0275 0.7820 0.0298 0.1882
0.8298 0.1002 0.0700 0.8560 0.1245 0.0195 0.7608 0.0241 0.2151
0.8200 0.1050 0.0750 0.8498 0.1349 0.0153 0.7414 0.0220 0.2366
___________________________________________________________________________________
Fractionation during demixing (the lines correspond with those above):
___________________________________________________________________
PEG Dextran PEG Dextran
Mn/ Mw/ M n/ Mw/ Mn/ Mw/ Mn/ Mw/
−1 −1 −1 −1
g.mol g.mol g.mol g.mol g.mol g.mol g.mol g.mol−1
−1 −1 −1
___________________________________________________________________
3000 3100 14000 24400 3000 3100 23700 47800
3000 3100 12800 22900 3100 3200 24400 45100
3000 3100 10300 16700 3000 3100 22700 43800
3000 3100 9300 14500 3000 3100 21700 42000
___________________________________________________________________
Comments: The molecular weight distributions for the dextran sample and for the dextran fractions in the
coexisting phases are given in the appendix of the original source.

T70, Pharmacia Inc., Tokyo, Japan
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8598 0.0853 0.0549 0.8765 0.1016 0.0219 0.8105 0.0340 0.1555
0.8500 0.0900 0.0600 0.8718 0.1140 0.0142 0.7900 0.0278 0.1822
0.8399 0.0950 0.0651 0.8680 0.1224 0.0096 0.7683 0.0228 0.2089
0.8298 0.1002 0.0700 0.8617 0.1315 0.0068 0.7475 0.0194 0.2331
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
________________________________________________________________________________

g.mol−1 g.mol−1 g.mol−1 g.mol−1 g.mol−1 g.mol−1 g.mol−1 g.mol−1
________________________________________________________________________________
2900 3000 27500 44500 2900 3000 47800 78700
2900 3000 21600 34600 2900 3000 46600 75900
2900 3000 17700 28600 2900 3000 45400 73700
2900 3000 15400 24300 2900 3000 44400 72400
________________________________________________________________________________

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8697 0.0800 0.0503 0.8859 0.0932 0.0209 0.8218 0.0341 0.1431
0.8591 0.0857 0.0552 0.8815 0.1046 0.0139 0.7995 0.0281 0.1724
0.8500 0.0900 0.0600 0.8765 0.1129 0.0106 0.7824 0.0238 0.1938
0.8397 0.0951 0.0652 0.8687 0.1230 0.0083 0.7692 0.0203 0.2105
___________________________________________________________________________________
________________________________________________________________________________

Mn/ M w/ M n / M w/ M n / M w/ M n/ Mw/
−1 −1 −1 −1
−1 −1 −1
________________________________________________________________________________
3000 3100 24400 61000 3000 3100 58500 176700

2900 3100 19200 42500 3000 3100 57500 171100
2900 3100 17000 35400 3000 3100 60300 158800
3000 3100 14400 26600 3000 3100 56100 150300
________________________________________________________________________________
____________________________________________________________________________________

T-500, Lot PA08143, Pharmacia Inc., Tokyo, Japan
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8841 0.0731 0.0428 0.9002 0.0898 0.0100 0.8443 0.0381 0.1176
0.8800 0.0750 0.0450 0.8996 0.0929 0.0075 0.8376 0.0349 0.1275
0.8699 0.0800 0.0501 0.8921 0.1042 0.0037 0.8162 0.0281 0.1557
0.8499 0.0901 0.0600 0.8799 0.1189 0.0012 0.7823 0.0201 0.1976
___________________________________________________________________________________
___________________________________________________________________
___________________________________________________________________
3000 3100 118800 184100 2800 3000 222300 548100
2900 3100 101700 156900 2900 3100 197800 516200
2900 3000 78500 122400 2800 3000 211100 494500
2900 3000 55200 82700 2800 3000 199500 476700
___________________________________________________________________
Polymer (B): poly(ethylene glycol) 1991HAR

Characterization: Mn/g.mol−1 = 3000, Wako Pure Chemical Ind., Ltd., Osaka, Japan
Characterization: Mn/g.mol−1 = 24200, T40, Lot 003375, Pharmacia Inc., Tokyo, Japan
continued
____________________________________________________________________________________
continued
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7395 0.1718 0.0887 0.816 0.004 0.180 0.681 0.312 0.007
0.7586 0.1577 0.0837 0.829 0.006 0.165 0.702 0.286 0.012
0.7794 0.1503 0.0703 0.847 0.012 0.141 0.736 0.246 0.018
0.8134 0.0999 0.0867 0.857 0.017 0.126 0.756 0.222 0.022
0.8148 0.1025 0.0827 0.858 0.018 0.124 0.762 0.214 0.024
0.8226 0.0991 0.0783 0.862 0.024 0.114 0.778 0.191 0.028
0.7881 0.1099 0.1083 0.832 0.006 0.162 0.706 0.283 0.011
0.7901 0.1098 0.1001 0.838 0.008 0.154 0.720 0.266 0.014
0.7930 0.1081 0.0989 0.841 0.009 0.150 0.726 0.260 0.014
0.8003 0.1107 0.0890 0.849 0.012 0.139 0.743 0.240 0.017
0.8072 0.1060 0.0868 0.850 0.015 0.135 0.749 0.231 0.020
0.8139 0.1068 0.0793 0.853 0.019 0.128 0.765 0.211 0.024
0.8224 0.1031 0.0745 0.861 0.025 0.114 0.777 0.194 0.029
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1991CON

T/K = 273.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7932 0.0851 0.1217 0.8572 0.1416 0.0012 0.6995 0.0102 0.2903
0.8150 0.0768 0.1082 0.8742 0.1247 0.0011 0.7315 0.0121 0.2564
0.8339 0.0707 0.0954 0.8873 0.1105 0.0022 0.7609 0.0137 0.2254
0.8543 0.0638 0.0819 0.8992 0.0952 0.0056 0.7983 0.0205 0.1812
0.8697 0.0562 0.0741 0.9064 0.0799 0.0137 0.8319 0.0290 0.1391
0.8755 0.0543 0.0702 0.9064 0.0730 0.0206 0.8471 0.0335 0.1194
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
_____________________________________
Mn/ Mw/ Mn/ Mw/
g.mol−1 g.mol−1 g.mol−1 g.mol−1
_____________________________________
30758 51281 110148 439931
38251 62399 114351 435486
39384 60514 112625 432249
49206 70023 123445 460035
59550 89688 122235 458967
69080 114406 126831 490284
_____________________________________
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7726 0.0374 0.1900 0.8695 0.1274 0.0031 0.7567 0.0200 0.2233
0.7945 0.0847 0.1208 0.8514 0.1480 0.0006 0.7280 0.0132 0.2588
0.8161 0.0755 0.1084 0.8698 0.1288 0.0014 0.7629 0.0179 0.2192
0.8376 0.0709 0.0915 0.8810 0.1138 0.0052 0.7927 0.0251 0.1822
0.8546 0.0647 0.0807 0.8896 0.0968 0.0136 0.8210 0.0359 0.1431
0.8642 0.0593 0.0765 0.8861 0.0792 0.0347 0.8517 0.0497 0.0986
0.8557 0.1119 0.0324 0.8712 0.1272 0.0016 0.7615 0.0184 0.2201
___________________________________________________________________________________
_____________________________________
Mn/ Mw/ Mn/ Mw/
g.mol−1 g.mol−1 g.mol−1 g.mol−1
_____________________________________
35864 66822 109393 429826
38811 47384 108530 425680
44898 55977 108171 414886
47373 66825 114007 430083
58989 89369 119205 447505
78495 154137 117580 473681
43584 57271 120991 444618
_____________________________________
continued
____________________________________________________________________________________
continued
T/K = 313.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7946 0.0847 0.1207 0.8470 0.1522 0.0008 0.7396 0.0160 0.2444
0.8137 0.0754 0.1109 0.8642 0.1331 0.0027 0.7703 0.0203 0.2094
0.8356 0.0707 0.0937 0.8782 0.1153 0.0065 0.7990 0.0293 0.1717
0.8529 0.0644 0.0827 0.8856 0.0963 0.0181 0.8323 0.0403 0.1274
0.8598 0.0613 0.0789 0.8821 0.0829 0.0350 0.8526 0.0526 0.0948
0.8499 0.1167 0.0334 0.8647 0.1331 0.0022 0.7697 0.0199 0.2104
0.7878 0.0435 0.1687 0.8655 0.1318 0.0027 0.7693 0.0219 0.2088
___________________________________________________________________________________
_____________________________________
Mn/ Mw/ Mn/ Mw/
−1 −1
−1
_____________________________________
37473 50431 111950 433225
40139 62992 114965 432477
49976 71755 115741 438271
62026 110830 120856 457811
76350 154715 117566 459023
43369 62351 122336 448637
39799 53717 111907 419156
_____________________________________
Polymer (B): poly(ethylene glycol) 1989DIA

Pharmacia Fine Chemicals, Piscataway, NJ, USA
T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8470 0.0650 0.0880 0.8748 0.0882 0.0370 0.8089 0.0328 0.1583
0.8400 0.0670 0.0930 0.8752 0.0962 0.0286 0.7965 0.0277 0.1758
0.8310 0.0690 0.1000 0.8716 0.1071 0.0213 0.7804 0.0239 0.1957
0.8230 0.0710 0.1060 0.8705 0.1119 0.0176 0.7670 0.0209 0.2121
___________________________________________________________________________________
____________________________________________________________________________________

T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8640 0.0630 0.0730 0.8944 0.0824 0.0232 0.8232 0.0306 0.1462
0.8575 0.0645 0.0780 0.8922 0.0896 0.0182 0.8129 0.0282 0.1589
0.8505 0.0655 0.0840 0.8898 0.0954 0.0148 0.8005 0.0261 0.1734
0.8430 0.0670 0.0900 0.8875 0.1007 0.0118 0.7865 0.0242 0.1893
___________________________________________________________________________________

T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8930 0.0500 0.0570 0.9206 0.0643 0.0151 0.8735 0.0345 0.0920
0.8650 0.0650 0.0700 0.9049 0.0939 0.0012 0.8042 0.0210 0.1748
0.8500 0.0700 0.0800 0.8965 0.1028 0.0007 0.7790 0.0198 0.2012
0.8400 0.0800 0.0800 0.8845 0.1151 0.0004 0.7573 0.0150 0.2277
___________________________________________________________________________________

−1 −1
T-70, Lot 00356, Pharmacia Fine Chemicals, Piscataway, NJ, USA
continued
____________________________________________________________________________________
continued
T/K = 298.15
_____________________________________________________________________________________________________

_____________________________________________________________________________________________________
0.8631 0.0722 0.0647 0.8743 0.0787 0.0470 0.8361 0.0514 0.1125
0.8631 0.0722 0.0647 0.8768 0.0869 0.0363 0.8288 0.0339 0.1373
0.8579 0.0764 0.0657 0.8830 0.1023 0.0147 0.8159 0.0285 0.1556
0.8527 0.0915 0.0558 0.8799 0.1142 0.0059 0.7849 0.0201 0.1950
0.8311 0.0870 0.0819 0.8681 0.1240 0.0079 0.7643 0.0225 0.2132
0.8203 0.0976 0.0821 0.8579 0.1373 0.0048 0.7367 0.0214 0.2419
0.7883 0.1139 0.0978 0.8359 0.1622 0.0019 0.6919 0.0137 0.2944
_____________________________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1992ZAS

Characterization: Mn/g.mol−1 = 6000, Lot 463-80, Serva, Heidelberg, Germany
T/K = 298.15
_____________________________________________________________________________________

wA wB wC wA wB wC
_____________________________________________________________________________________
0.8475 0.1481 0.0044 0.7329 0.0057 0.2614
0.8609 0.1324 0.0069 0.7592 0.0066 0.2342
0.8845 0.1013 0.0142 0.8034 0.0120 0.1846
0.8923 0.0868 0.0209 0.8297 0.0165 0.1538
0.8970 0.0666 0.0364 0.8610 0.0228 0.1162
_____________________________________________________________________________________
Dependence on pH, the total systems contain 0.01 mol/L universal buffer.
_____________________________________________________________________________________

wA wB wC pH wA wB wC pH
_____________________________________________________________________________________
0.8440 0.1508 0.0052 4.32 0.7274 0.0066 0.2660 4.26
0.8786 0.1045 0.0169 4.23 0.8025 0.0105 0.1870 4.19
0.8873 0.0855 0.0272 4.17 0.8314 0.0163 0.1523 4.14
0.8440 0.1508 0.0052 7.89 0.7274 0.0066 0.2660 7.73
0.8786 0.1045 0.0169 7.88 0.8025 0.0105 0.1870 7.76
0.8873 0.0855 0.0272 7.87 0.8314 0.0163 0.1523 7.79
0.8440 0.1508 0.0052 8.22 0.7274 0.0066 0.2660 8.08
0.8786 0.1045 0.0169 8.24 0.8025 0.0105 0.1870 8.17
0.8873 0.0855 0.0272 8.26 0.8314 0.0163 0.1523 8.22
_____________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1995GR1, 1995TIN

T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9055 0.0425 0.0520 0.9315 0.0623 0.0062 0.8660 0.0179 0.1161
0.8815 0.0501 0.0684 0.9184 0.0800 0.0016 0.8263 0.0102 0.1635
0.8548 0.0651 0.0801 0.8968 0.1028 0.0004 0.7841 0.0056 0.2103
0.8324 0.0699 0.0977 0.8824 0.1173 0.0003 0.7595 0.0043 0.2362
___________________________________________________________________________________
T/K = 283.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9072 0.0426 0.0502 0.9302 0.0583 0.0115 0.8772 0.0219 0.1009
0.8901 0.0511 0.0588 0.9216 0.0756 0.0028 0.8378 0.0132 0.1490
0.8695 0.0599 0.0706 0.9087 0.0902 0.0011 0.8042 0.0084 0.1874
0.8395 0.0704 0.0901 0.8856 0.1139 0.0005 0.7653 0.0048 0.2299
___________________________________________________________________________________
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9076 0.0448 0.0476 0.9251 0.0626 0.0123 0.8845 0.0241 0.0914
0.8828 0.0489 0.0683 0.9191 0.0782 0.0027 0.8436 0.0134 0.1430
0.8824 0.0550 0.0626 0.9169 0.0808 0.0023 0.8318 0.0134 0.1548
0.8628 0.0633 0.0739 0.9007 0.0988 0.0005 0.8049 0.0080 0.1871
0.8541 0.0657 0.0802 0.8941 0.1053 0.0006 0.7913 0.0072 0.2015
0.8320 0.0699 0.0981 0.8799 0.1196 0.0005 0.7691 0.0046 0.2263
0.7696 0.1000 0.1304 0.8267 0.1730 0.0003 0.6808 0.0020 0.3172
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 313.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8816 0.0507 0.0677 0.9128 0.0842 0.0030 0.8424 0.0151 0.1425
0.8552 0.0648 0.0800 0.8913 0.1082 0.0005 0.8051 0.0093 0.1856
0.8321 0.0699 0.0980 0.8750 0.1247 0.0003 0.7784 0.0050 0.2166
0.8157 0.0756 0.1087 0.8621 0.1377 0.0002 0.7606 0.0024 0.2370
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1993MIS

Characterization: Mw/g.mol−1 = 7500, Wako Pure Chemical Ind., Ltd., Osaka, Japan
T500 VC, Pharmacia Inc., Tokyo, Japan
T/K = 298.15
wA 0.888 0.919 0.929 0.941 0.938 0.901 0.854 0.817 0.752
wB 0.112 0.081 0.070 0.056 0.038 0.020 0.011 0.006 0.002
wC 0.000 0.000 0.001 0.003 0.024 0.079 0.135 0.177 0.246
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8080 0.0622 0.1298 0.875 0.125 0.000 0.731 0.002 0.267
0.8312 0.0529 0.1159 0.887 0.113 0.000 0.768 0.003 0.229
0.8586 0.0438 0.0976 0.907 0.092 0.001 0.808 0.006 0.186
0.8729 0.0397 0.0874 0.917 0.081 0.002 0.832 0.008 0.160
0.8907 0.0325 0.0768 0.928 0.066 0.006 0.870 0.014 0.116
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8800 0.0500 0.0700 0.9140 0.0860 0.0000 0.8332 0.0038 0.1630
0.8800 0.0500 0.0700 0.9140 0.0860 0.0000 0.7945 0.0038 0.2017
0.8580 0.0580 0.0840 0.8940 0.1050 0.0010 0.8116 0.0014 0.1870
0.8430 0.0730 0.0840 0.8825 0.1175 0.0000 0.7735 0.0005 0.2260
0.8940 0.0440 0.0620 0.9286 0.0704 0.0010 0.8550 0.0049 0.1401
0.8790 0.0590 0.0620 0.9120 0.0880 0.0000 0.8174 0.0014 0.1812
0.9000 0.0500 0.0500 0.9219 0.0781 0.0000 0.8453 0.0057 0.1490
0.8850 0.0650 0.0500 0.9131 0.0869 0.0000 0.8148 0.0019 0.1833
0.9000 0.0600 0.0400 0.9286 0.0704 0.0010 0.8360 0.0040 0.1600
0.8850 0.0750 0.0400 0.9023 0.0970 0.0007 0.8047 0.0018 0.1935
___________________________________________________________________________________

T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8860 0.0390 0.0750 0.8958 0.0469 0.0573 0.8716 0.0280 0.1004
0.8760 0.0420 0.0820 0.9039 0.0672 0.0289 0.8515 0.0159 0.1326
0.8670 0.0460 0.0870 0.9012 0.0787 0.0201 0.8325 0.0117 0.1558
0.8590 0.0490 0.0920 0.8983 0.0855 0.0162 0.8186 0.0072 0.1742
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8905 0.0370 0.0725 0.9170 0.0595 0.0235 0.8653 0.0156 0.1191
0.8700 0.0500 0.0800 0.9083 0.0829 0.0088 0.8207 0.0076 0.1717
0.8590 0.0470 0.0940 0.9059 0.0864 0.0077 0.8123 0.0072 0.1805
0.8440 0.0510 0.1050 0.8974 0.0971 0.0055 0.7917 0.0058 0.2025
___________________________________________________________________________________

T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9189 0.0327 0.0484 0.9423 0.0491 0.0086 0.8954 0.0163 0.0883
0.8964 0.0450 0.0586 0.9286 0.0703 0.0011 0.8516 0.0073 0.1411
0.8674 0.0576 0.0750 0.9070 0.0927 0.0003 0.8084 0.0043 0.1873
0.8500 0.0700 0.0800 0.8916 0.1083 0.0001 0.7809 0.0030 0.2161
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1988SZL

−1
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8966 0.0457 0.0577 0.8670 0.1280 0.0050 0.8690 0.0110 0.1200
0.8244 0.0699 0.1057 0.8800 0.1180 0.0020 0.7580 0.0020 0.2400
0.7872 0.0850 0.1278 0.8500 0.1470 0.0030 0.6970 0.0030 0.3000
0.8180 0.0931 0.0889 0.8696 0.1300 0.0004 0.7390 0.0110 0.2500
___________________________________________________________________________________
____________________________________________________________________________________

T-500, Lot QC11346, Pharmacia Inc., Tokyo, Japan
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9200 0.0550 0.0250 0.9314 0.0641 0.0045 0.8723 0.0128 0.1149
0.9100 0.0600 0.0300 0.9249 0.0723 0.0028 0.8563 0.0096 0.1341
0.9000 0.0650 0.0350 0.9181 0.0802 0.0017 0.8410 0.0073 0.1517
0.8900 0.0700 0.0400 0.9107 0.0883 0.0010 0.8234 0.0054 0.1712
___________________________________________________________________________________
___________________________________________________________________
___________________________________________________________________
8300 8700 76200 176800 8100 8500 202500 520000
8400 8800 68500 171400 8400 8700 188100 492900
8600 8900 59700 147900 8300 8600 182200 487400
8500 8900 47900 78300 8000 8400 177800 467400
___________________________________________________________________

T-500, Lot 38624, Pharmacia Fine Chemicals, Piscataway, NJ, USA
T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.9166 0.0344 0.0490 0.9339 0.0498 0.0163 0.9082 0.0233 0.0685
0.9096 0.0410 0.0494 0.9341 0.0591 0.0068 0.8809 0.0160 0.1031
0.9071 0.0430 0.0499 0.9298 0.0668 0.0034 0.8655 0.0170 0.1175
0.8958 0.0449 0.0593 0.9259 0.0723 0.0018 0.8591 0.0142 0.1367
0.8930 0.0570 0.0500 0.9200 0.0790 0.0010 0.8390 0.0110 0.1500
0.8791 0.0507 0.0702 0.9169 0.0824 0.0007 0.8370 0.0100 0.1630
0.8675 0.0586 0.0739 0.9068 0.0929 0.0003 0.8288 0.0061 0.1757
0.8452 0.0716 0.0832 0.8885 0.1114 0.0001 0.7637 0.0058 0.2305
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1989SJ1

Characterization: Mw/g.mol−1 = 17000-20000, Serva, Heidelberg, Germany
T/K = 293.15
_____________________________________________________
wA wB wC wA wB wC
_____________________________________________________
0.9159 0.0545 0.0296 0.8794 0.0082 0.1124
0.9107 0.0735 0.0158 0.8503 0.0051 0.1446
0.8926 0.0995 0.0079 0.8160 0.0000 0.1840
0.8184 0.1806 0.0010 0.6916 0.0000 0.3084
_____________________________________________________
T/K = 323.15
_____________________________________________________
wA wB wC wA wB wC
_____________________________________________________
0.9135 0.0668 0.0197 0.8828 0.0110 0.1062
0.8959 0.0956 0.0085 0.8495 0.0050 0.1455
0.8753 0.1200 0.0047 0.8216 0.0019 0.1765
0.8553 0.1421 0.0026 0.7936 0.0007 0.2057
0.8221 0.1766 0.0013 0.7526 0.0011 0.2463
0.7949 0.2044 0.0007 0.7128 0.0010 0.2862
_____________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 353.15
_____________________________________________________
wA wB wC wA wB wC
_____________________________________________________
0.9048 0.0875 0.0077
0.8926 0.0070 0.1004
0.8855 0.1103 0.0042
0.8671 0.0029 0.1300
0.8386 0.0031 0.1583
0.8340 0.1646 0.0014 0.8166 0.0004 0.1830
0.7993 0.1998 0.0009 0.7770 0.0004 0.2236
0.7595 0.2400 0.0004 0.7374 0.0004 0.2622
_____________________________________________________
T/K = 373.15
_____________________________________________________
wA wB wC wA wB wC
_____________________________________________________
0.8925 0.1033 0.0042
0.9128 0.0086 0.0786
0.8743 0.1231 0.0026
0.8893 0.0051 0.1056
0.8498 0.1486 0.0016
0.8720 0.0030 0.1250
0.8127 0.1845 0.0028
0.8443 0.0027 0.1530
0.7925 0.0017 0.2058
_____________________________________________________

T-500, Pharmacia Inc., Tokyo, Japan
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9500 0.0350 0.0150 0.9553 0.0367 0.0080 0.9231 0.0088 0.0681
0.9400 0.0400 0.0200 0.9491 0.0467 0.0042 0.9043 0.0053 0.0904
0.9300 0.0500 0.0200 0.9389 0.0592 0.0018 0.8809 0.0049 0.1142
0.9200 0.0550 0.0250 0.9334 0.0656 0.0010 0.8637 0.0041 0.1322
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
__________________________________________________________________________
−1 −1 −1 −1
−1 −1 −1
__________________________________________________________________________
14800 18200 135800 238400 17400 18800 255400 725800
16000 18900 101800 154200 15000 16500 198200 558000
16100 19200 81200 112700 177300 503500
16100 19200 69500 89400 172200 479400
__________________________________________________________________________

Characterization: Mw/g.mol−1 = 20000, Carbowax 20M
T/K = 277.15
___________________________________________________________________________________________
___________________________________________________________________________________________
0.9160 0.0420 0.0420 0.9215 0.0472 0.0313 0.9134 0.0302 0.0564
0.9050 0.0450 0.0500 0.9156 0.0652 0.0192 0.8967 0.0234 0.0799
0.8850 0.0500 0.0650 0.9065 0.0793 0.0142 0.8602 0.0141 0.1257
0.8650 0.0550 0.0800 0.8973 0.0937 0.0090 0.8296 0.0082 0.1622
___________________________________________________________________________________________

T/K = 277.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________________
___________________________________________________________________________________________
0.9175 0.0415 0.0410 0.9279 0.0592 0.0129 0.9064 0.0233 0.0703
0.9020 0.0465 0.0515 0.9204 0.0701 0.0095 0.8796 0.0152 0.1052
0.8860 0.0510 0.0630 0.9125 0.0804 0.0071 0.8525 0.0107 0.1368
0.8650 0.0580 0.0770 0.8987 0.0965 0.0048 0.8225 0.0057 0.1718
___________________________________________________________________________________________

T/K = 277.15
___________________________________________________________________________________________
___________________________________________________________________________________________
0.9490 0.0310 0.0200 0.9557 0.0365 0.0078 0.9425 0.0187 0.0388
0.9347 0.0260 0.0393 0.9486 0.0486 0.0028 0.9272 0.0150 0.0578
0.9081 0.0335 0.0584 0.9360 0.0629 0.0011 0.8943 0.0104 0.0953
0.8891 0.0395 0.0714 0.9259 0.0737 0.0004 0.8563 0.0064 0.1373
___________________________________________________________________________________________

T/K = 277.15
___________________________________________________________________________________________
___________________________________________________________________________________________
0.9400 0.0249 0.0351 0.9563 0.0393 0.0044 0.9090 0.0034 0.0876
0.9190 0.0300 0.0510 0.9456 0.0527 0.0017 0.8823 0.0017 0.1160
0.8990 0.0400 0.0610 0.9307 0.0684 0.0009 0.8511 0.0012 0.1477
0.8800 0.0498 0.0702 0.9162 0.0829 0.0009 0.8210 0.0007 0.1783
___________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9403 0.0248 0.0349 0.9562 0.0382 0.0056 0.9175 0.0050 0.0775
0.9403 0.0264 0.0333 0.9555 0.0391 0.0054 0.9142 0.0040 0.0818
0.9202 0.0298 0.0500 0.9455 0.0524 0.0021 0.8905 0.0021 0.1074
0.9002 0.0402 0.0596 0.9300 0.0691 0.0009 0.8600 0.0011 0.1389
0.8984 0.0408 0.0608 0.9279 0.0714 0.0007 0.8582 0.0011 0.1407
0.8789 0.0507 0.0704 0.9124 0.0870 0.0006 0.8323 0.0009 0.1668
0.8793 0.0507 0.0700 0.9120 0.0875 0.0005 0.8322 0.0007 0.1671
0.8174 0.0801 0.1025 0.8673 0.1321 0.0006 0.7476 0.0008 0.2516
___________________________________________________________________________________
T/K = 313.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9203 0.0299 0.0498 0.9375 0.0599 0.0026 0.8965 0.0026 0.1009
0.9000 0.0400 0.0600 0.9249 0.0745 0.0006 0.8768 0.0013 0.1219
0.8798 0.0502 0.0700 0.9078 0.0920 0.0002 0.8461 0.0009 0.1530
0.8601 0.0600 0.0799 0.8911 0.1086 0.0003 0.8249 0.0008 0.1743
___________________________________________________________________________________
Additional data for the system poly(ethylene glycol) (B) + water (A) + dextran (C) can be
found in Refs. 1985WAL, 1986ALB, 1990FOR, 1991FO1, 1991FO2, and 1995ZAS.
Polymer (B): poly(ethylene glycol) 1987LOP

Solvent (C): 1,2-ethanediol C2H6O2 107-21-1
T/K 391 418 420 430
wA 0.990 0.980 0.955 0.894
wB 0.010 0.010 0.010 0.010
wC 0.000 0.010 0.035 0.096
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1989SJ2

Characterization: Mw/g.mol−1 = 17000-20000, Serva, Heidelberg, Germany
Component (C): D-glucose C6H12O6 50-99-7
T/K = 363.15
_____________________________________________________
wA wB wC wA wB wC
_____________________________________________________
0.314 0.522 0.164 0.470 0.000 0.530
0.389 0.414 0.197 0.516 0.000 0.484
0.466 0.295 0.239 0.545 0.026 0.429
0.504 0.258 0.238 0.580 0.032 0.388
_____________________________________________________
Polymer (B): poly(ethylene glycol) 1996LIM

−1
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7238 0.1097 0.1665 0.6285 0.0443 0.3272 0.7871 0.1669 0.0460
0.7336 0.0999 0.1665 0.6486 0.0465 0.3049 0.7912 0.1540 0.0548
0.7433 0.0898 0.1669 0.6760 0.0510 0.2730 0.7936 0.1345 0.0719
0.7510 0.0840 0.1650 0.7080 0.0570 0.2350 0.8000 0.1200 0.0800
0.7650 0.0840 0.1510 0.7240 0.0610 0.2150 0.8020 0.1040 0.0940
___________________________________________________________________________________

T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.7300 0.0899 0.1801 0.6568 0.0331 0.3101 0.8000 0.1470 0.0530
0.7400 0.0800 0.1800 0.6829 0.0359 0.2812 0.8090 0.1253 0.0657
0.7480 0.0720 0.1800 0.7100 0.0420 0.2480 0.8056 0.1144 0.0800
0.7524 0.0676 0.1800 0.7351 0.0531 0.2118 0.7991 0.0937 0.1072
0.7788 0.0682 0.1530 0.7500 0.0480 0.2020 0.8092 0.0900 0.1008
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7211 0.1100 0.1689 0.6155 0.0295 0.3550 0.7963 0.1645 0.0392
0.7331 0.1000 0.1669 0.6443 0.0317 0.3240 0.8036 0.1509 0.0455
0.7432 0.0899 0.1669 0.6616 0.0337 0.3047 0.7936 0.1368 0.0527
0.7532 0.0800 0.1666 0.6854 0.0348 0.2798 0.8105 0.1223 0.0652
0.7636 0.0699 0.1665 0.7121 0.0376 0.2503 0.8141 0.1044 0.0815
___________________________________________________________________________________

T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.7301 0.0899 0.1800 0.6389 0.0152 0.3459 0.8107 0.1564 0.0329
0.7401 0.0800 0.1799 0.6580 0.0152 0.3268 0.8201 0.1470 0.0329
0.7499 0.0700 0.1801 0.6746 0.0183 0.3071 0.8234 0.1334 0.0432
0.7602 0.0598 0.1800 0.7028 0.0151 0.2821 0.8359 0.1141 0.0500
0.7702 0.0498 0.1800 0.7269 0.0167 0.2564 0.8417 0.0986 0.0597
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1995BE2

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.800 0.070 0.130 0.830 0.097 0.073 0.737 0.032 0.231
0.795 0.080 0.125 0.828 0.115 0.057 0.722 0.028 0.250
0.793 0.092 0.115 0.827 0.130 0.043 0.702 0.024 0.274
0.780 0.095 0.125 0.823 0.137 0.040 0.690 0.023 0.287
___________________________________________________________________________________

−1
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7331 0.0999 0.1670 0.6360 0.0290 0.3350 0.8103 0.1563 0.0334
0.7432 0.0900 0.1668 0.6626 0.0285 0.3089 0.8188 0.1424 0.0388
0.7632 0.0701 0.1667 0.7051 0.0319 0.2630 0.8338 0.1150 0.0512
0.7790 0.0590 0.1620 0.7546 0.0404 0.2050 0.8384 0.1000 0.0616
___________________________________________________________________________________
____________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7295 0.0902 0.1803 0.6349 0.0137 0.3514 0.8112 0.1618 0.0270
0.7399 0.0800 0.1801 0.6536 0.0158 0.3306 0.8231 0.1471 0.0298
0.7499 0.0699 0.1802 0.6740 0.0158 0.3102 0.8315 0.1342 0.0343
0.7595 0.0599 0.1806 0.6959 0.0165 0.2876 0.8437 0.1175 0.0388
0.7713 0.0482 0.1805 0.7260 0.0200 0.2540 0.8553 0.1025 0.0422
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1988SZL

−1
Characterization: Mn/g.mol−1 = 1800, derived from corn starch
Grain Processing Corp., Muscatine, IA, USA
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7379 0.0375 0.2246 0.7560 0.0650 0.1790 0.7210 0.0290 0.2500
0.7112 0.0493 0.2395 0.7690 0.0970 0.1340 0.6900 0.0000 0.3100
0.7246 0.0375 0.2379 0.7650 0.0750 0.1600 0.7100 0.0000 0.2900
0.6303 0.0840 0.2857 0.7190 0.1810 0.1000 0.5800 0.0000 0.4200
___________________________________________________________________________________
Comments: Densities and viscosities are additionally given in the original source.

continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5397 0.1122 0.3480 0.5575 0.1559 0.2865 0.4875 0.0081 0.5042
0.5021 0.1297 0.3681 0.5423 0.1857 0.2719 0.4440 0.0060 0.5499
0.4615 0.1505 0.3878 0.5020 0.2542 0.2436 0.4025 0.0053 0.5921
0.4280 0.1669 0.4050 0.4764 0.2908 0.2327 0.3523 0.0089 0.6387
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5464 0.1072 0.3463 0.5784 0.1464 0.2750 0.4894 0.0045 0.5059
0.5184 0.1238 0.3577 0.5634 0.1804 0.2561 0.4427 0.0073 0.5499
0.4605 0.1515 0.3879 0.5042 0.2609 0.2347 0.3984 0.0091 0.5923
0.4291 0.1681 0.4026 0.4792 0.2960 0.2247 0.3817 0.0090 0.6091
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5521 0.1096 0.3382 0.5644 0.1268 0.3086 0.5059 0.0592 0.4348
0.5126 0.1254 0.3618 0.5504 0.1776 0.2718 0.4521 0.0431 0.5046
0.4305 0.1375 0.4318 0.4949 0.2459 0.2591 0.3628 0.0229 0.6142
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5399 0.1102 0.3498 0.6260 0.1884 0.1855 0.4645 0.0000 0.5354
0.5004 0.1323 0.3671 0.5913 0.2315 0.1770 0.4187 0.0000 0.5812
0.4600 0.1505 0.3893 0.5437 0.3019 0.1543 0.3984 0.0000 0.6015
0.4306 0.1681 0.4011 0.4849 0.3653 0.1497 0.3596 0.0012 0.6391
___________________________________________________________________________________

−1 −1
T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.5536 0.1061 0.3402 0.6308 0.1875 0.1815 0.4686 0.0000 0.5313
0.5169 0.1252 0.3577 0.5966 0.2302 0.1731 0.4239 0.0000 0.5760
0.4760 0.1455 0.3784 0.5468 0.3014 0.1517 0.4184 0.0004 0.5811
0.4370 0.1643 0.3986 0.5272 0.3270 0.1456 0.3608 0.0050 0.6340
___________________________________________________________________________________

Polymer (C): polysaccharide
Characterization: Mw/g.mol−1 = 110000, cashew-nut tree gum,
Anacardium occidentale L.
T/K = 303.15 pH = 6
___________________________________________________________________________________
___________________________________________________________________________________
0.73 0.09 0.18 0.8094 0.1354 0.0552 0.6128 0.0237 0.3635
0.69 0.11 0.20 0.7911 0.1923 0.0166 0.5615 0.0063 0.4322
0.65 0.13 0.22 0.7917 0.2024 0.0059 0.5048 0.0168 0.4784
___________________________________________________________________________________

Polymer (C): polysaccharide
Characterization: Mw/g.mol−1 = 110000, cashew-nut tree gum,
Anacardium occidentale L.
T/K = 303.15 pH = 6
___________________________________________________________________________________
___________________________________________________________________________________
0.75 0.09 0.16 0.8303 0.1333 0.0364 0.5999 0.0086 0.3915
0.71 0.11 0.18 0.7928 0.1939 0.0133 0.5527 0.0085 0.4388
0.67 0.13 0.20 0.7809 0.2156 0.0035 0.5164 0.0099 0.4737
___________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1987LOP

Solvent (C): 1,2,3-propanetriol C3H8O3 56-81-5
T/K 391 412 417 423
wA 0.990 0.980 0.940 0.891
wB 0.010 0.010 0.010 0.010
wC 0.000 0.010 0.050 0.099
Polymer (B): poly(ethylene oxide) 1993MAL

Polymer (C): poly(propylene oxide)
Type of data: cloud points (LCST behavior)
T/K = 298.15
wA 0.200 0.150 0.148 0.149 0.161 0.170 0.184 0.195 0.201
wB 0.080 0.130 0.208 0.253 0.293 0.330 0.368 0.400 0.440
wC 0.720 0.720 0.644 0.598 0.546 0.500 0.448 0.405 0.359
wA 0.213 0.224 0.230 0.250 0.305 0.362 0.434 0.470 0.489
wB 0.471 0.506 0.540 0.560 0.546 0.500 0.428 0.370 0.333
wC 0.316 0.270 0.230 0.190 0.149 0.138 0.138 0.160 0.178
wA 0.500 0.500 0.487 0.470 0.454 0.431 0.405 0.382 0.305
wB 0.299 0.276 0.256 0.240 0.218 0.201 0.175 0.155 0.103
wC 0.201 0.224 0.257 0.290 0.328 0.368 0.420 0.463 0.592
T/K = 326.15
wA 0.254 0.214 0.203 0.205 0.208 0.222 0.236 0.247 0.260
wB 0.038 0.083 0.123 0.162 0.242 0.277 0.310 0.339 0.370
wC 0.708 0.703 0.674 0.633 0.550 0.501 0.454 0.414 0.370
wA 0.270 0.282 0.290 0.304 0.374 0.456 0.560 0.606 0.649
wB 0.402 0.431 0.460 0.483 0.471 0.419 0.310 0.256 0.210
wC 0.328 0.287 0.250 0.213 0.155 0.125 0.130 0.138 0.141
wA 0.678 0.712 0.736 0.753 0.771 0.785 0.800 0.816 0.820
wB 0.178 0.144 0.118 0.098 0.080 0.066 0.050 0.029 0.013
wC 0.144 0.144 0.146 0.149 0.149 0.149 0.150 0.155 0.167
Polymer (B): poly(ethylene oxide) 1989BAS

Lot 45971, Polysciences, Inc., Warrington, PA, USA
Polymer (C): poly(vinyl methyl ether)
continued
____________________________________________________________________________________
continued
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.850 0.060 0.090 0.886 0.078 0.036 0.798 0.034 0.168
0.840 0.070 0.090 0.878 0.094 0.028 0.776 0.030 0.194
0.830 0.080 0.090 0.872 0.106 0.022 0.744 0.028 0.228
___________________________________________________________________________________

Lot 62891, Polysciences, Inc., Warrington, PA, USA
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.900 0.040 0.060 0.920 0.052 0.028 0.856 0.012 0.132
0.870 0.030 0.100 0.916 0.062 0.022 0.836 0.010 0.154
0.850 0.030 0.120 0.910 0.073 0.017 0.810 0.006 0.184
0.860 0.060 0.080 0.900 0.087 0.013 0.772 0.002 0.226
___________________________________________________________________________________

Fluka AG, Buchs, Switzerland
continued
____________________________________________________________________________________
continued
T/K = 293.15
_____________________________________________________________________________________________________

_____________________________________________________________________________________________________
0.910 0.020 0.070 0.939 0.049 0.012 0.890 0.002 0.108
0.890 0.020 0.090 0.930 0.060 0.010 0.869 0.001 0.130
0.870 0.020 0.110 0.921 0.072 0.007 0.850 0.001 0.149
_____________________________________________________________________________________________________
Polymer (B): poly(ethylene oxide)-b-poly(propylene oxide)

diblock copolymer 2002MON
Characterization: Mn/g.mol−1 = 1925, 10.0 mol% ethylene oxide
PE61, Oxiteno Brasil S/A, Sao Paulo, Brazil
T/K = 298.15
_____________________________________________________________________________________________________

_____________________________________________________________________________________________________
0.6213 0.3025 0.0762 0.1613 0.8303 0.0084 0.8553 0.0355 0.1092
0.4989 0.4007 0.1004 0.1229 0.8698 0.0073 0.7912 0.0351 0.1737
0.5353 0.3317 0.1330 0.1070 0.8863 0.0067 0.7654 0.0301 0.2045
0.3984 0.4006 0.2010 0.0782 0.9143 0.0075 0.6306 0.0125 0.3569
_____________________________________________________________________________________________________

diblock copolymer 2002MON
PE61, Oxiteno Brasil S/A, Sao Paulo, Brazil
Component (C): maltose C12H22O11 69-79-4
T/K = 298.15
_____________________________________________________________________________________________________

_____________________________________________________________________________________________________
0.5980 0.3503 0.0517 0.1865 0.8081 0.0054 0.8699 0.0504 0.0797

0.5500 0.3504 0.0996 0.1555 0.8373 0.0072 0.8115 0.0295 0.1590
0.4797 0.4002 0.1201 0.1356 0.8578 0.0066 0.7640 0.0221 0.2139
0.3342 0.4968 0.1690 0.0914 0.9045 0.0041 0.6217 0.0039 0.3744
_____________________________________________________________________________________________________
____________________________________________________________________________________

diblock copolymer 1991SA2
Solvent (C): N-methylacetamide C3H7NO 79-16-3
T/K = 298.15
_____________________________________________________________________
wA wB wC wA wB wC
_____________________________________________________________________
0.948 0.000 0.052 0.737 0.199 0.064
0.908 0.000 0.092 0.718 0.199 0.083
0.830 0.000 0.170 0.647 0.200 0.153
0.737 0.000 0.273 0.609 0.144 0.247
0.632 0.000 0.368 0.527 0.115 0.318
0.453 0.000 0.547 0.383 0.112 0.505
0.397 0.000 0.603 0.341 0.096 0.563
0.388 0.000 0.612 0.298 0.127 0.575
0.368 0.000 0.632 0.320 0.098 0.582
0.354 0.000 0.646 0.303 0.113 0.584
_____________________________________________________________________
Comments: The detection limit for the block copolymer in the top phase was 1 wt%.

hyperbranched, acetylated, synthesized in the laboratory
Solvent (C): tetrahydrofuran C4H8O 109-99-9
T/K = 295.15
wA 0.2954 0.3312 0.2515 0.2371 0.2402 0.3760 0.3822 0.3875 0.3996
wB 0.1018 0.0669 0.1497 0.1694 0.1668 0.0366 0.0315 0.0266 0.0184
wC 0.6028 0.6019 0.5988 0.5935 0.5930 0.5874 0.5863 0.5859 0.5820
wA 0.1705 0.1738 0.4366
wB 0.2489 0.2457 0.0123
wC 0.5806 0.5805 0.5511
continued
____________________________________________________________________________________
continued
T/K = 295.15
____________________________________________________
Phase I Phase II
wA wB wC wA wB wC
____________________________________________________
0.104 0.375 0.521 0.527 0.015 0.458
0.140 0.299 0.561 0.484 0.016 0.500
0.084 0.455 0.461 0.603 0.008 0.389
0.070 0.520 0.410 0.646 0.008 0.346
0.063 0.587 0.350 0.700 0.007 0.293
0.067 0.724 0.209 0.793 0.009 0.198
0.070 0.784 0.146 0.845 0.008 0.147
0.090 0.910 0.000 0.997 0.003 0.000
____________________________________________________

Solvent (C): 1-butanol C4H10O 71-36-3
wB 0.014 0.014
wC 0.0084 0.036
T/K 304.25 292.35

Solvent (C): dimethylsulfoxide C2H6OS 67-68-5
wB 0.066 0.061 0.058
wC 0.110 0.174 0.232
T/K 302.65 300.75 296.95

wB 0.014 0.014 0.014
wC 0.023 0.043 0.119
T/K 306.15 304.95 298.95
____________________________________________________________________________________

wB 0.014 0.014 0.014
wC 0.016 0.031 0.064
T/K 306.75 306.15 304.75

Solvent (C): 1,2,3-propanetriol C3H8O3 56-81-5
wB 0.014 0.014 0.014
wC 0.049 0.100 0.150
T/K 305.55 303.95 301.95

Solvent (C): 1-propanol C3H8O 71-23-8
wB 0.014 0.014
wC 0.029 0.068
T/K 302.85 296.25

Component (C): urea CH4N2O 57-13-6
wB 0.014 0.014 0.014
wC 0.020 0.060 0.200
T/K 306.95 306.25 305.15
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 2002MON

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.4585 0.4202 0.1213 0.3200 0.6282 0.0518 0.4972 0.3581 0.1447
0.4499 0.3503 0.1998 0.2058 0.7734 0.0208 0.5506 0.1588 0.2906
0.3395 0.4805 0.1800 0.1778 0.8032 0.0190 0.5051 0.1107 0.3842
0.3513 0.3992 0.2495 0.1458 0.8389 0.0153 0.4629 0.0833 0.4538
0.2999 0.5007 0.1994 0.1497 0.8348 0.0155 0.4732 0.0715 0.4553
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.4664 0.4000 0.1336 0.0583 0.9405 0.0012 0.7456 0.0209 0.2335
0.3992 0.4679 0.1329 0.0534 0.9459 0.0007 0.7139 0.0211 0.2650
0.3929 0.4338 0.1733 0.0498 0.9493 0.0009 0.6594 0.0143 0.3263
0.3321 0.4672 0.2007 0.0445 0.9544 0.0011 0.5790 0.0118 0.4092
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5308 0.3099 0.1593 0.3444 0.6281 0.0275 0.5719 0.2203 0.2078
0.4470 0.3534 0.1996 0.2637 0.7146 0.0217 0.5326 0.1770 0.2904
0.3694 0.4504 0.1802 0.2277 0.7578 0.0145 0.5172 0.1190 0.3638
0.3388 0.4815 0.1797 0.1887 0.8012 0.0101 0.4964 0.0936 0.4100
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5991 0.2869 0.1140 0.1093 0.8890 0.0017 0.7738 0.0712 0.1550
0.5127 0.3212 0.1661 0.1040 0.8957 0.0003 0.7112 0.0449 0.2439
0.4712 0.3346 0.1942 0.0998 0.8998 0.0004 0.6701 0.0242 0.3057
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.4024 0.4648 0.1328 0.0597 0.9394 0.0009 0.7271 0.0087 0.2642
0.4001 0.4338 0.1661 0.0510 0.9487 0.0003 0.6743 0.0133 0.3124
0.4126 0.3912 0.1962 0.0578 0.9414 0.0008 0.6494 0.0001 0.3505
0.3326 0.4674 0.2000 0.0502 0.9495 0.0003 0.5846 0.0051 0.4103
___________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 2001SIL

Characterization: Mn/g.mol−1 = 400, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.4402 0.3959 0.1639 0.3546 0.6282 0.0172 0.5095 0.1640 0.3265
0.4680 0.3070 0.2250 0.3558 0.6254 0.0188 0.5073 0.1554 0.3373
0.4350 0.2639 0.3011 0.3169 0.6711 0.0120 0.4536 0.1183 0.4278
0.3580 0.3361 0.3059 0.2372 0.7594 0.0034 0.4010 0.0720 0.5270
___________________________________________________________________________________

−1
Characterization: Mn/g.mol = 400, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5121 0.2210 0.2669 0.5138 0.3732 0.1130 0.5269 0.1388 0.3343
0.4693 0.2462 0.2845 0.4321 0.5204 0.0475 0.4652 0.1107 0.4241
0.4161 0.2845 0.2994 0.3408 0.6406 0.0186 0.4370 0.0913 0.4717
0.3640 0.3245 0.3115 0.2712 0.7193 0.0095 0.4096 0.0711 0.5193
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.4350 0.4007 0.1643 0.0341 0.9659 0.0000 0.7057 0.0174 0.2769
0.4681 0.3068 0.2251 0.0288 0.9712 0.0000 0.6535 0.0205 0.3260
0.4338 0.2666 0.2996 0.0373 0.9676 0.0000 0.5655 0.0247 0.4098
0.3852 0.2857 0.3291 0.0344 0.9784 0.0000 0.5086 0.0280 0.4676
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5125 0.2203 0.2672 0.0835 0.9159 0.0006 0.6404 0.0162 0.3434
0.4632 0.2497 0.2871 0.0647 0.9351 0.0002 0.5988 0.0164 0.3848
0.4154 0.2856 0.2990 0.0323 0.9676 0.0001 0.5582 0.0166 0.4252
0.3636 0.3257 0.3107 0.0215 0.9784 0.0001 0.5142 0.0182 0.4676
___________________________________________________________________________________
Polymer (B): polysulfone 1985WIJ

Solvent (C): N,N-dimethylacetamide C4H9NO 127-19-5
T/K = 298.15
ϕA 0.0645 0.0600 0.0570 0.0550 0.0530 0.0510
ϕB 0.000018 0.000060 0.000095 0.00015 0.00024 0.00042
ϕC 0.9355 0.9399 0.9429 0.9449 0.9468 0.9486
____________________________________________________________________________________
Polymer (B): polysulfone 1987LIS

Characterization: Type 3500, Union Carbide Corp., New York, NY, USA
T/K = 293.15
wA 0.0332 0.0363 0.0359 0.0374 0.0359 0.0385 0.0362 0.0400 0.0406
wB 0.201 0.170 0.148 0.141 0.126 0.120 0.110 0.0644 0.0334
wC 0.766 0.793 0.824 0.821 0.838 0.841 0.854 0.896 0.926
wA 0.0420 0.0421 0.0424 0.0426 0.0423 0.0429 0.0430 0.0431 0.0428
wB 0.0298 0.0266 0.0240 0.0225 0.0211 0.0197 0.0194 0.0180 0.0168
wC 0.928 0.931 0.934 0.935 0.937 0.937 0.938 0.939 0.940
wA 0.0432 0.0435 0.0440 0.0473 0.0499
wB 0.0139 0.0103 0.00750 0.00262 0.00050
wC 0.943 0.946 0.948 0.950 0.950
T/K = 303.15
wA 0.0363 0.0386 0.0370 0.0377 0.0402 0.0400 0.0412 0.0414 0.0410
wB 0.163 0.153 0.151 0.123 0.0939 0.0879 0.0810 0.0757 0.0547
wC 0.802 0.813 0.832 0.840 0.866 0.871 0.878 0.883 0.904
wA 0.0410 0.0427 0.0424 0.0463 0.0460 0.0462
wB 0.0511 0.0415 0.0387 0.0065 0.0062 0.0047
wC 0.908 0.916 0.919 0.947 0.948 0.949
T/K = 313.15
wA 0.0412 0.0412 0.0437 0.0423 0.0439 0.0437 0.0435 0.0440 0.0453
wB 0.0994 0.0931 0.0653 0.0611 0.0552 0.0516 0.0237 0.0334 0.0274
wC 0.859 0.866 0.891 0.896 0.901 0.905 0.922 0.925 0.927
wA 0.0449 0.0466 0.0462 0.0461 0.0468 0.0472 0.0477
wB 0.0216 0.0189 0.0159 0.0150 0.0105 0.0050 0.0045
wC 0.933 0.936 0.938 0.939 0.942 0.948 0.948
T/K = 323.15
wA 0.0367 0.0389 0.0401 0.0342 0.0435 0.0431 0.0448 0.0469 0.0489
wB 0.261 0.194 0.173 0.116 0.106 0.100 0.0947 0.0488 0.0422
wC 0.722 0.767 0.787 0.849 0.850 0.856 0.861 0.904 0.910
wA 0.0473 0.0466 0.0464 0.0468 0.0472 0.0476
wB 0.0371 0.0340 0.0331 0.0321 0.0318 0.0263
wC 0.916 0.919 0.920 0.921 0.921 0.926
T/K = 333.15
wA 0.0358 0.0411 0.0411 0.0416 0.0423 0.0376 0.0469 0.0455 0.0399
wB 0.300 0.192 0.183 0.178 0.174 0.169 0.122 0.0895 0.0684
wC 0.664 0.687 0.776 0.780 0.784 0.794 0.834 0.865 0.892
wA 0.0400 0.0483 0.0476 0.0483 0.0499 0.0497 0.0495 0.0502 0.0504
wB 0.0618 0.0627 0.0595 0.0225 0.0201 0.0181 0.0165 0.0151 0.0121
wC 0.895 0.889 0.893 0.929 0.931 0.932 0.934 0.935 0.937
____________________________________________________________________________________
Polymer (B): polysulfone 1990QIN

Characterization: Union Carbide Corp., New York, NY, USA
T/K = 293.15
ϕA 0.0344 0.0357 0.0365 0.0374 0.0383 0.0399 0.0399 0.0402 0.0404
ϕB 0.1536 0.1945 0.1107 0.0937 0.0496 0.0228 0.0203 0.0183 0.0172
ϕC 0.8121 0.8299 0.8528 0.8689 0.9121 0.9374 0.9378 0.9415 0.9425
ϕA 0.0401 0.0406 0.0407 0.0408 0.0405 0.0408 0.04l1 0.0415
ϕB 0.0161 0.0150 0.0148 0.0137 0.0128 0.0106 0.0078 0.0057
ϕC 0.9439 0.9444 0.9445 0.9455 0.9467 0.9486 0.9511 0.9528
Polymer (B): polysulfone 1999BAR, 2000BA1

Ultrason S 3010, BASF AG, Ludwigshafen, Germany
T/K = 293.15
wA 0.0212 0.0200 0.0191 0.0192 0.0183 0.0179
wB 0.0099 0.0262 0.0409 0.0803 0.1224 0.1614
wC 0.9689 0.9538 0.9400 0.9005 0.8593 0.8207
T/K = 303.15
wA 0.0228 0.0214 0.0202 0.0200 0.0196 0.0191
wB 0.0097 0.0257 0.0402 0.0794 0.1203 0.1588
wC 0.9675 0.9529 0.9396 0.9006 0.8601 0.8221
T/K = 313.15
wA 0.0245 0.0229 0.0219 0.0212 0.0208 0.0204
wB 0.0095 0.0251 0.0393 0.0780 0.1182 0.1558
wC 0.9660 0.9520 0.9388 0.9008 0.8610 0.8238
T/K = 323.15
wA 0.0267 0.0249 0.0235 0.0228 0.0223 0.0220
wB 0.0091 0.0244 0.0384 0.0763 0.1157 0.1524
wC 0.9642 0.9507 0.9381 0.9009 0.8620 0.8256
continued
____________________________________________________________________________________
continued
T/K = 303.15
___________________________________________________________________________________
Total system Sol phase Gel phase
___________________________________________________________________________________
0.021 0.076 0.903 0.024 0.049 0.927 0.025 0.177 0.798
0.023 0.083 0.894 0.019 0.037 0.944 0.023 0.234 0.743
0.027 0.082 0.891 0.034 0.024 0.942 0.021 0.292 0.687
___________________________________________________________________________________
Polymer (B): poly(vinyl alcohol) 2002YOU

Characterization: Mw/g.mol−1 = 74800, 99.2 mol% saponification, ρ = 1.26 g/cm3,
Tm/K = 499.9, Chang Chun Co., Ltd., Taiwan
T/K = 298.15
wA 0.65 0.68 0.72 0.75 0.77 0.79 0.80 0.11 0.10
wB 0.20 0.18 0.15 0.12 0.10 0.07 0.05 0.18 0.15
wC 0.15 0.14 0.13 0.13 0.13 0.14 0.15 0.71 0.75
wA 0.09 0.10 0.10 0.11
wB 0.12 0.10 0.07 0.05
wC 0.79 0.80 0.83 0.84
ϕA 0.6878 0.7157 0.7522 0.7785 0.7958 0.8121 0.8196 0.1225 0.1110
ϕB 0.1680 0.1504 0.1244 0.0989 0.0820 0.0571 0.0407 0.1590 0.1321
ϕC 0.1442 0.1339 0.1234 0.1226 0.1221 0.1308 0.1397 0.7185 0.7568
ϕA 0.0996 0.1109 0.1099 0.1204
ϕB 0.1054 0.0870 0.0610 0.0434
ϕC 0.7950 0.8021 0.8291 0.8361
Polymer (B): poly(vinyl alcohol) 1993MAT

−1 −1
Characterization: Mw/g.mol = 88000, Mw/g.mol = 281600, 98% hydrolysis
wB 0.01 0.05 0.10 0.01 0.05 0.10
ϕA/ϕC 50/50 50/50 50/50 30/70 30/70 30/70
T/K 296.55 304.35 309.95 293.85 303.15 307.75
____________________________________________________________________________________

Solvent (A): deuterium oxide D2O 7789-20-0
Solvent (C): methanol-d4 CD4O 811-98-3
wB 0.20 0.20 0.20 0.20 0.20 0.20 0.20
ϕC 0.0 0.10 0.20 0.30 0.40 0.45 0.50
T/K 305.85 307.05 306.75 306.85 308.45 317.45 317.45

wB 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005
ϕC 0.00 0.10 0.20 0.30 0.35 0.40 0.425 0.45
T/K 307.85 308.65 308.75 309.75 310.25 312.85 318.85 322.85

wB = 0.060
wC = 0.039
T/K = 305.95

wB = 0.060
wC = 0.024
T/K = 308.05
____________________________________________________________________________________

wB = 0.062
wC = 0.0165
T/K = 306.85

wB = 0.060
wC = 0.030
T/K = 307.35
____________________________________________________________________________________
3.3.2. Electrolyte solutions
Polymer (B): N,N-diallylammonioethanoic acid/

sulfur dioxide copolymer 2002ALM
Characterization: 50 mol% sulfur dioxide, synthesized in the laboratory
T/K = 296.15
Comments: The concentration of KCl in the feed system is given in mol/l, the concentration of HCl
is given in equivalents with respect to the copolymer.
_______________________________________________________________________________________________________

KCl HCl wA wB wC wA wB wC wA wB wC
_______________________________________________________________________________________________________
1.5 0.70 0.92083 0.05227 0.02690 0.94675 0.00135 0.0519 0.89686 0.0995 0.00364
1.0 0.70 0.92083 0.05227 0.02690 0.94541 0.00409 0.0505 0.89450 0.1040 0.00150
0.5 0.70 0.92095 0.05215 0.02690 0.94635 0.00425 0.0494 0.89242 0.1060 0.00158
0.1 0.70 0.92106 0.05204 0.02690 0.93820 0.01570 0.0461 0.90203 0.0915 0.00647
0.1 0.70 0.89064 0.05468 0.05468 0.91835 0.00175 0.0799 0.83228 0.1660 0.00172
0.1 0.70 0.90740 0.07676 0.01584 0.93700 0.01380 0.0492 0.89647 0.1000 0.00353
0.5 0.00 0.80580 0.11140 0.08280 0.78800 0.00000 0.2120 0.81688 0.1810 0.00212
0.5 0.00 0.83861 0.05934 0.10205 0.83100 0.00000 0.1690 0.84960 0.1480 0.00240
0.5 0.00 0.83440 0.06220 0.10340 0.84200 0.00000 0.1580 0.83920 0.1590 0.00180
_______________________________________________________________________________________________________

T/K = 298.15
_______________________________________________________________________________________________________

_______________________________________________________________________________________________________
0.6996 0.2005 0.0999 0.8007 0.0290 0.1703 0.5869 0.3839 0.0292
0.6894 0.2001 0.1105 0.7939 0.0193 0.1868 0.5553 0.4221 0.0226
0.6775 0.2017 0.1208 0.7847 0.0176 0.1977 0.5254 0.4576 0.0170
0.6587 0.2006 0.1407 0.7669 0.0103 0.2228 0.4774 0.5086 0.0140
0.6406 0.2003 0.1591 0.7479 0.0143 0.2378 0.4355 0.5570 0.0075
_______________________________________________________________________________________________________

____________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7670 0.1512 0.0818 0.8624 0.0221 0.1155 0.6510 0.3224 0.0266
0.7594 0.1505 0.0901 0.8566 0.0151 0.1283 0.6160 0.3630 0.0210
0.7502 0.1498 0.1000 0.8440 0.0119 0.1441 0.5832 0.4008 0.0160
0.7308 0.1495 0.1197 0.8264 0.0086 0.1650 0.5152 0.4749 0.0099
0.7095 0.1503 0.1402 0.8045 0.0049 0.1906 0.4590 0.5362 0.0048
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8090 0.1205 0.0705 0.8750 0.0247 0.1003 0.6631 0.3147 0.0222
0.8003 0.1196 0.0801 0.8667 0.0115 0.1218 0.6179 0.3642 0.0179
0.7743 0.1206 0.1051 0.8453 0.0077 0.1470 0.5386 0.4513 0.0101
0.7502 0.1197 0.1301 0.8251 0.0039 0.1710 0.4751 0.5190 0.0059
0.7319 0.1200 0.1481 0.8067 0.0041 0.1892 0.4213 0.5752 0.0036
___________________________________________________________________________________

Salt (C): dipotassium phosphate K2HPO4 7758-11-4
continued
____________________________________________________________________________________
continued
T/K = 275.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7147 0.1801 0.1052 0.8168 0.0010 0.1822 0.5958 0.3916 0.0141
0.7449 0.1652 0.0899 0.8408 0.0052 0.1540 0.6497 0.3298 0.0205
0.7653 0.1548 0.0799 0.8568 0.0096 0.1336 0.6744 0.3014 0.0242
0.7847 0.1453 0.0700 0.8631 0.0231 0.1138 0.7275 0.2395 0.0330
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7148 0.1800 0.1052 0.8350 0.0021 0.1629 0.5137 0.4793 0.0070
0.7252 0.1749 0.0999 0.8381 0.0031 0.1588 0.5420 0.4501 0.0079
0.7450 0.1651 0.0899 0.8534 0.0021 0.1445 0.5573 0.4341 0.0086
0.7652 0.1549 0.0799 0.8719 0.0028 0.1253 0.5855 0.4037 0.0108
0.7848 0.1452 0.0700 0.8835 0.0053 0.1112 0.6552 0.3300 0.0148
0.8050 0.1350 0.0600 0.8986 0.0103 0.0911 0.6773 0.3056 0.0171
___________________________________________________________________________________

Salt (C): potassium dihydrogen phosphate KH2PO4 7778-77-0
T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.7100 0.1950 0.0950 0.8382 0.0100 0.1518 0.5003 0.4850 0.0147
0.7250 0.1850 0.0900 0.8424 0.0097 0.1479 0.5818 0.3960 0.0222
0.7399 0.1751 0.0850 0.8477 0.0109 0.1414 0.6273 0.3435 0.0292
0.7700 0.1550 0.0750 0.8630 0.0216 0.1154 0.6721 0.2933 0.0346
0.7851 0.1450 0.0699 0.8610 0.0394 0.0996 0.6980 0.2653 0.0367
___________________________________________________________________________________
Polymer (B): ethylene oxide/propylene oxide copolymer 1997LIM

Characterization: Mn/g.mol−1 = 3000-3500, 33.3 mol% ethylene oxide
wB = 0.10 (was kept constant)
−1
cC/mol.l 0.0 0.1 0.2 0.3
T/K 340.15 324.15 316.15 309.15

cC/mol.l−1 0.0 0.1 0.2 0.3
T/K 343.15 327.15 321.15 313.15

T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.7750 0.1550 0.0700 0.8827 0.0041 0.1132 0.5800 0.4183 0.0017
0.7900 0.1450 0.0650 0.8973 0.0062 0.0965 0.6163 0.3770 0.0067
0.8049 0.1350 0.0601 0.9058 0.0094 0.0848 0.6309 0.3634 0.0057
0.8200 0.1252 0.0550 0.9082 0.0128 0.0790 0.6724 0.3165 0.0111
0.8350 0.1150 0.0500 0.9089 0.0223 0.0688 0.7160 0.2714 0.0126
___________________________________________________________________________________

−1
cC/mol.l 0.0 0.1 0.2 0.3
T/K 359.15 343.15 336.15 329.15
Polymer (B): ethyl(hydroxyethyl)cellulose 2000PE1

−1
Characterization: Mw/g.mol = 200000, EHEC 230G, Akzo Nobel, Sweden
−1
cC/mol.l 0.000 0.048 0.100 0.150 0.200 0.264 0.330
T/K 338.15 330.65 324.65 318.15 313.65 306.15 297.15
Polymer (B): methylcellulose 1986ALB

Polymer (C): sodium dextran sulfate
Characterization: Mw/g.mol−1 = 2200000, 16.8 % sulfur, prepared in the laboratory
from Dextran 2200, Pharmacia Fine Chemicals, Uppsala, Sweden
T/K = 277.15
continued
____________________________________________________________________________________
continued
_______________________________________________________________________________________________________

_______________________________________________________________________________________________________
Comments: Solutions were prepared by using 0.15 M NaCl in water.
0.9927 0.0051 0.0022 0.9933 0.0054 0.0013 0.9865 0.0020 0.0115
0.9890 0.0030 0.0080 0.9923 0.0059 0.0018 0.9868 0.0013 0.0119
0.9860 0.0040 0.0100 0.9901 0.0088 0.0011 0.9835 0.0010 0.0155
0.9780 0.0060 0.0160 0.9837 0.0152 0.0011 0.9749 0.0009 0.0242
Comments: Solutions were prepared by using 0.3 M NaCl in water.
0.9910 0.0030 0.0060 0.9935 0.0041 0.0024 0.9864 0.0011 0.0125
0.9870 0.0050 0.0080 0.9911 0.0075 0.0014 0.9795 0.0006 0.0199
0.9800 0.0080 0.0120 0.9861 0.0124 0.0015 0.9694 0.0006 0.0300
_______________________________________________________________________________________________________
Polymer (B): poly(acrylic acid) sodium salt 2002LAA

Characterization: Mw/g.mol−1 = 70000, Polysciences, Inc., Warrington, PA, USA
T/K = 283.15
wA 0.609 0.637 0.661 0.676 0.692 0.704 0.713 0.722 0.729
wB 0.359 0.325 0.297 0.272 0.252 0.234 0.218 0.204 0.192
wC 0.033 0.038 0.042 0.052 0.056 0.062 0.069 0.074 0.079
wA 0.733 0.742 0.750 0.756 0.761 0.762 0.768 0.770 0.771
wB 0.181 0.162 0.147 0.134 0.124 0.114 0.106 0.100 0.093
wC 0.087 0.096 0.103 0.110 0.115 0.124 0.126 0.131 0.136
wA 0.771 0.771 0.776 0.776 0.774 0.774 0.771
wB 0.083 0.074 0.068 0.062 0.057 0.053 0.048
wC 0.147 0.155 0.156 0.162 0.169 0.173 0.181
T/K = 298.15
wA 0.723 0.733 0.739 0.741 0.745 0.751 0.755 0.748 0.747
wB 0.025 0.027 0.032 0.034 0.040 0.051 0.065 0.072 0.080
wC 0.253 0.240 0.229 0.226 0.215 0.198 0.180 0.180 0.173
wA 0.755 0.752 0.753 0.750 0.752 0.750 0.748 0.745 0.745
wB 0.088 0.091 0.095 0.099 0.100 0.107 0.114 0.115 0.122
wC 0.157 0.158 0.152 0.151 0.147 0.143 0.138 0.140 0.132
wA 0.742 0.738 0.736 0.733 0.726 0.716 0.705 0.679 0.622
wB 0.132 0.136 0.145 0.157 0.167 0.192 0.215 0.265 0.335
wC 0.126 0.126 0.119 0.110 0.107 0.092 0.080 0.056 0.042
T/K = 343.15
wA 0.616 0.681 0.696 0.699 0.697 0.695 0.689 0.684 0.683
wB 0.332 0.193 0.121 0.087 0.068 0.058 0.049 0.040 0.039
wC 0.053 0.126 0.183 0.213 0.235 0.247 0.263 0.275 0.278
continued
____________________________________________________________________________________
continued
T/K = 298.15
_________________________________________________________________
Phase I Phase II
wA wB wC wA wB wC
_________________________________________________________________
0.751 0.025 0.224 0.627 0.347 0.026

0.684 0.009 0.307 0.553 0.429 0.018
0.630 0.004 0.365 0.544 0.436 0.019
_________________________________________________________________
Polymer (B): poly(acrylic acid) sodium salt 1995TON

50 mol% neutralized with NaOH, SEPC, Genay, France
T/K = 303.15
_______________________________________________________________________________________________________

_______________________________________________________________________________________________________
0.562 0.218 0.220 0.575 0.1410 0.284 0.318 0.548 0.1340
0.542 0.208 0.250 0.553 0.0710 0.376 0.348 0.520 0.1320
0.511 0.198 0.291 0.521 0.0374 0.442 0.418 0.495 0.0829
0.491 0.189 0.320 0.491 0.0284 0.481 0.436 0.478 0.0866
0.469 0.181 0.350 0.480 0.0206 0.500 0.454 0.457 0.0891
0.424 0.227 0.350 0.428 0.0123 0.560 0.485 0.446 0.0684
_______________________________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1998BER, 2000BER

Salt (C): ammonium carbamate CH6N2O2 1111-78-0
T/K = 298.15
_______________________________________________________________________________________________________

wA wB wC ρ/g cm−3 pH wA wB wC ρ/g cm−3 pH
_______________________________________________________________________________________________________
0.6395 0.1823 0.1782 1.0976 9.57 0.6942 0.0766 0.2292 1.1033 9.59
0.5597 0.3033 0.1370 1.1027 9.62 0.6918 0.0370 0.2712 1.1141 9.57
0.5216 0.3520 0.1264 1.1073 9.63 0.6758 0.0244 0.2998 1.1230 9.58
0.4759 0.4088 0.1153 1.1131 9.68 0.6447 0.0225 0.3328 1.1353 9.58
0.4308 0.4563 0.1129 1.1188 9.65 0.6177 0.0202 0.3621 1.1471 9.57
_______________________________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1998BER, 2000BER

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6702 0.1997 0.1301 1.0849 9.61 0.7621 0.0447 0.1932 1.0868 9.58
0.6474 0.2300 0.1226 1.0861 9.70 0.7614 0.0355 0.2031 1.0883 9.67
0.6272 0.2572 0.1156 1.0902 9.68 0.7582 0.0219 0.2199 1.0944 9.66
0.5840 0.3062 0.1098 1.0953 9.71 0.7342 0.0178 0.2480 1.1021 9.70
0.5315 0.3644 0.1041 1.1025 9.62 0.7172 0.0135 0.2693 1.1148 9.58
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1998BER

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7540 0.1243 0.1217 1.0695 9.49 0.8031 0.0450 0.1519 1070.5 9.49
0.6852 0.2083 0.1065 1.0755 9.55 0.8022 0.0166 0.1812 1076.6 9.53
0.6388 0.2620 0.0992 1.0828 9.54 0.7863 0.0150 0.1987 1084.1 9.52
0.5965 0.3091 0.0944 1.0919 9.57 0.7554 0.0133 0.2313 1096.1 9.58
0.5528 0.3611 0.0861 1.0981 9.60 0.7325 0.0141 0.2534 1106.1 9.51
___________________________________________________________________________________

Salt (C): ammonium carbamate/ammonium bicarbonate
CH6N2O2/CH5NO3 1111-78-0/1066-33-7
T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
Comments: The ratio of NH3/CO2 in the salt mixture was fixed to 1.79 ± 0.01.
0.6005 0.2301 0.1694 1.1086 9.33 0.6871 0.0719 0.2410 1.1154 9.32
0.4308 0.4563 0.1129 1.1082 9.36 0.6937 0.0617 0.2446 1.1147 9.36
0.5492 0.2631 0.1867 1.0931 10.05 0.6487 0.0587 0.2926 1.0992 10.03
0.5139 0.3286 0.1575 1.0972 10.06 0.6449 0.0290 0.3261 1.1079 10.04
0.4454 0.4275 0.1271 1.1061 10.16 0.5875 0.0127 0.3998 1.1255 10.12
___________________________________________________________________________________

Salt (C): ammonium carbamate/ammonium bicarbonate
CH6N2O2/CH5NO3 1111-78-0/1066-33-7
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6698 0.1823 0.1479 1.0924 9.30 0.7415 0.0614 0.1971 1.0945 9.29
0.6074 0.2617 0.1309 1.0954 9.31 0.7516 0.0264 0.2220 1.1001 9.31
0.5974 0.2821 0.1205 1.0987 9.31 0.7455 0.0166 0.2379 1.1053 9.28
0.5793 0.3090 0.1117 1.1027 9.34 0.7321 0.0105 0.2574 1.1120 9.30
0.6618 0.1695 0.1687 1.0772 9.99 0.7277 0.0713 0.2010 1.0777 9.99
0.6024 0.2516 0.1460 1.0813 9.98 0.7091 0.0272 0.2637 1.0833 9.96
0.5752 0.2942 0.1306 1.0858 10.06 0.7069 0.0145 0.2786 1.0899 10.04
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 2002ZA1

Characterization: Mw/g.mol−1 = 6000, Merck KGaA, Darmstadt, Germany
Salt (C): ammonium dihydrogen phosphate (NH4)H2PO4 7722-76-1
continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.5983 0.6216 0.6337 0.6485 0.6629 0.6770 0.6898 0.7001 0.7105
wB 0.3372 0.3064 0.2886 0.2672 0.2455 0.2245 0.2046 0.1869 0.1698
wC 0.0645 0.0720 0.0777 0.0843 0.0916 0.0985 0.1056 0.1130 0.1197
wA 0.7239 0.7301 0.7407 0.7510 0.7609 0.7665 0.7735 0.7729 0.7723
wB 0.1434 0.1323 0.1122 0.0910 0.0706 0.0503 0.0221 0.0141 0.0067
wC 0.1327 0.1376 0.1471 0.1580 0.1685 0.1832 0.2044 0.2130 0.2210
T/K = 308.15
wA 0.6083 0.6136 0.6295 0.6481 0.6664 0.6843 0.6986 0.7120 0.7235
wB 0.3329 0.3231 0.3014 0.2761 0.2506 0.2249 0.2023 0.1812 0.1623
wC 0.0588 0.0633 0.0691 0.0758 0.0830 0.0908 0.0991 0.1068 0.1142
wA 0.7323 0.7396 0.7452 0.7655 0.7732 0.7812 0.7891 0.7908 0.7918
wB 0.1473 0.1338 0.1227 0.0838 0.0670 0.0509 0.0259 0.0183 0.0119
wC 0.1204 0.1266 0.1321 0.1507 0.1598 0.1679 0.1850 0.1909 0.1963
T/K = 318.15
wA 0.6114 0.6219 0.6441 0.6679 0.6918 0.7113 0.7257 0.7374 0.7468
wB 0.3310 0.3165 0.2878 0.2565 0.2240 0.1953 0.1747 0.1565 0.1404
wC 0.0576 0.0616 0.0681 0.0756 0.0842 0.0934 0.0996 0.1061 0.1128
wA 0.7578 0.7645 0.7834 0.7927 0.8005 0.8070 0.8088 0.8049 0.8036
wB 0.1225 0.1099 0.0787 0.0615 0.0461 0.0318 0.0210 0.0125 0.0065
wC 0.1197 0.1256 0.1379 0.1458 0.1534 0.1612 0.1702 0.1826 0.1899
T/K = 298.15
_________________________________________________________________

wA wB wC wA wB wC
_________________________________________________________________
0.59608 0.33940 0.06452 0.72635 0.00859 0.26506
0.60687 0.32620 0.06693 0.73461 0.00882 0.25657
0.62400 0.30357 0.07243 0.74307 0.00955 0.24738
0.63627 0.28506 0.07867 0.75271 0.00871 0.23858
0.65963 0.25032 0.09005 0.76324 0.00797 0.22879
0.69864 0.18934 0.11202 0.77397 0.01853 0.20750
_________________________________________________________________

T/K = 308.15
_________________________________________________________________

wA wB wC wA wB wC
_________________________________________________________________
0.59557 0.34606 0.05837 0.75375 0.01134 0.23491
0.60825 0.33003 0.06172 0.75991 0.01192 0.22817
0.62619 0.30586 0.06795 0.76816 0.01063 0.22121
_________________________________________________________________
continued
____________________________________________________________________________________
continued
_________________________________________________________________

wA wB wC wA wB wC
_________________________________________________________________
0.63886 0.28904 0.07210 0.77742 0.00713 0.21545
0.65514 0.26670 0.07816 0.78273 0.00900 0.20827
0.67597 0.23722 0.08681 0.78900 0.01111 0.19989
0.70304 0.19532 0.10164 0.78929 0.02632 0.18439
_________________________________________________________________

T/K = 318.15
_________________________________________________________________

wA wB wC wA wB wC
_________________________________________________________________
0.60012 0.34361 0.05627 0.78751 0.00556 0.20693
0.61508 0.32586 0.05906 0.79458 0.00563 0.19979
0.62867 0.30873 0.06260 0.79912 0.00724 0.19364
0.64981 0.28056 0.06963 0.80324 0.01167 0.18509
0.67096 0.25246 0.07658 0.80664 0.01600 0.17736
0.69619 0.21816 0.08565 0.80696 0.02452 0.16852
0.71579 0.18988 0.09433 0.80695 0.03069 0.16236
_________________________________________________________________
Polymer (B): poly(ethylene glycol) 1993VOR

T/K = 288.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5699 0.2399 0.1902 0.4779 0.4970 0.0251 0.6756 0.0000 0.3244
0.5960 0.2241 0.1799 0.5069 0.4629 0.0302 0.6858 0.0000 0.3142
0.6245 0.2074 0.1681 0.5395 0.4247 0.0358 0.7091 0.0033 0.2876
0.6538 0.1877 0.1585 0.5764 0.3799 0.0437 0.7340 0.0046 0.2614
0.6803 0.1727 0.1470 0.6146 0.3302 0.0552 0.7487 0.0179 0.2334
0.7001 0.1598 0.1401 0.6470 0.2830 0.0700 0.7590 0.0292 0.2118
0.7148 0.1502 0.1350 0.6827 0.2282 0.0891 0.7591 0.0544 0.1865
0.7214 0.1449 0.1337 0.7108 0.1755 0.1137 0.7456 0.0933 0.1611
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5675 0.2394 0.1931 0.4596 0.5187 0.0217 0.6813 0.0000 0.3187
0.5944 0.2268 0.1788 0.4874 0.4865 0.0261 0.6918 0.0000 0.3082
0.6234 0.2075 0.1691 0.5213 0.4467 0.0320 0.7139 0.0035 0.2826
0.6527 0.1877 0.1596 0.5574 0.4033 0.0393 0.7365 0.0070 0.2565
0.6791 0.1725 0.1484 0.5974 0.3532 0.0494 0.7551 0.0154 0.2295
0.6984 0.1611 0.1405 0.6287 0.3108 0.0605 0.7638 0.0284 0.2078
0.7127 0.1522 0.1351 0.6625 0.2614 0.0761 0.7686 0.0439 0.1875
0.7196 0.1465 0.1339 0.6808 0.2322 0.0870 0.7619 0.0639 0.1742
___________________________________________________________________________________
T/K = 308.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5647 0.2392 0.1961 0.4387 0.5402 0.0211 0.6752 0.0000 0.3248
0.5938 0.2254 0.1808 0.4727 0.5045 0.0228 0.6994 0.0000 0.3006
0.6221 0.2071 0.1708 0.5025 0.4699 0.0276 0.7224 0.0027 0.2749
0.6528 0.1857 0.1615 0.5393 0.4282 0.0325 0.7423 0.0074 0.2503
0.6792 0.1715 0.1493 0.5791 0.3778 0.0431 0.7597 0.0141 0.2262
0.6968 0.1619 0.1413 0.6081 0.3395 0.0524 0.7730 0.0231 0.2039
0.7121 0.1521 0.1358 0.6410 0.2965 0.0625 0.7732 0.0404 0.1864
0.7179 0.1471 0.1350 0.6539 0.2766 0.0695 0.7719 0.0498 0.1783
___________________________________________________________________________________
T/K = 318.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5621 0.2386 0.1993 0.4182 0.5666 0.0152 0.6850 0.0000 0.3150
0.5940 0.2235 0.1825 0.4456 0.5356 0.0188 0.7047 0.0000 0.2953
0.6231 0.2023 0.1746 0.4842 0.4931 0.0227 0.7273 0.0027 0.2700
0.6537 0.1818 0.1645 0.5149 0.4567 0.0284 0.7478 0.0048 0.2474
0.6797 0.1683 0.1520 0.5548 0.4097 0.0355 0.7661 0.0126 0.2213
0.6961 0.1609 0.1430 0.5874 0.3689 0.0437 0.7805 0.0168 0.2027
0.7125 0.1502 0.1373 0.6141 0.3354 0.0505 0.7828 0.0282 0.1890
0.7181 0.1455 0.1364 0.6248 0.3206 0.0546 0.7847 0.0335 0.1818
___________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1991GAO

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.69581 0.15938 0.14481 0.62124 0.31720 0.06156 0.75914 0.02716 0.21370
0.71109 0.15001 0.13890 0.65398 0.26900 0.07702 0.76174 0.04636 0.19190
0.70421 0.15428 0.14151 0.63619 0.29660 0.06721 0.76179 0.03551 0.20270
0.71935 0.14452 0.13613 0.67472 0.23590 0.08938 0.75764 0.06806 0.17430
0.69600 0.16206 0.14194 0.62309 0.31560 0.06131 0.76044 0.02876 0.21080
0.72163 0.14331 0.13506 0.68339 0.22040 0.09621 0.75434 0.07836 0.16730
0.72386 0.13996 0.13618 0.68754 0.21250 0.09996 0.75104 0.08436 0.16460
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1992SNY

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.710 0.150 0.140 0.632 0.296 0.072 0.771 0.031 0.198
0.655 0.185 0.160 0.537 0.417 0.046 0.744 0.005 0.250
0.590 0.210 0.200 0.436 0.536 0.029 0.658 0.001 0.341
0.520 0.240 0.240 0.371 0.612 0.017 0.594 0.000 0.405
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1989NIF

T/K = 293.15
continued
____________________________________________________________________________________
continued
_____________________________________________________________
_____________________________________________________________
0.683 0.238 0.079 1.087 0.804 0.000 0.196 1.091
0.608 0.342 0.050 1.086 0.790 0.000 0.210 1.116
0.569 0.392 0.039 1.084 0.769 0.000 0.231 1.129
0.496 0.482 0.022 1.057 0.725 0.000 0.275 1.161
0.471 0.509 0.020 1.046 0.100 0.000 0.300 1.176
_____________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.74243 0.13085 0.12672 0.66795 0.26990 0.06215 0.79508 0.03552 0.16940
0.75504 0.11102 0.13394 0.67227 0.26380 0.06393 0.79628 0.03782 0.16590
0.76195 0.10944 0.12861 0.69506 0.23110 0.07384 0.80357 0.04353 0.15290
0.77182 0.10835 0.11983 0.71240 0.20290 0.08470 0.79144 0.06326 0.14530
0.72332 0.13453 0.14215 0.62380 0.32680 0.04940 0.78631 0.01759 0.19610
0.72159 0.14632 0.13209 0.63567 0.31170 0.05263 0.78905 0.02075 0.19020
0.73237 0.12627 0.14136 0.63395 0.31470 0.05135 0.78968 0.02052 0.18980
0.77548 0.09282 0.13170 0.70833 0.20330 0.08837 0.78930 0.06820 0.14250
0.75786 0.12213 0.12001 0.71335 0.18950 0.09715 0.78289 0.07811 0.13900
0.73159 0.13520 0.13321 0.63576 0.31240 0.05184 0.79179 0.02411 0.18410
0.76687 0.10901 0.12412 0.72100 0.17880 0.10020 0.78285 0.08245 0.13470
___________________________________________________________________________________

T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.72000 0.15162 0.12838 0.63065 0.32200 0.04735 0.79559 0.00661 0.19780
0.72739 0.14757 0.12504 0.63749 0.31350 0.04901 0.80138 0.01262 0.18600
0.73545 0.14168 0.12287 0.65202 0.29480 0.05318 0.80462 0.01468 0.18070
0.74952 0.13166 0.11882 0.67875 0.25950 0.06175 0.80954 0.02356 0.16690
0.75413 0.13088 0.11499 0.69148 0.24200 0.06652 0.80858 0.03462 0.15680
0.75951 0.12925 0.11124 0.72911 0.18570 0.08519 0.79795 0.06565 0.13640
___________________________________________________________________________________

T/K = 288.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6838 0.1656 0.1506 0.5830 0.3841 0.0329 0.7680 0.0000 0.2320
0.6986 0.1603 0.1411 0.6052 0.3574 0.0374 0.7881 0.0000 0.2119
0.7060 0.1643 0.1297 0.6219 0.3377 0.0404 0.7923 0.0000 0.2077
0.7245 0.1532 0.1223 0.6562 0.2952 0.0486 0.8050 0.0071 0.1879
0.7491 0.1282 0.1227 0.6868 0.2563 0.0569 0.8134 0.0108 0.1758
0.7666 0.1201 0.1133 0.7266 0.2001 0.0733 0.8163 0.0319 0.1518
0.7699 0.1202 0.1099 0.7589 0.1456 0.0955 0.8005 0.0682 0.1313
___________________________________________________________________________________
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6842 0.1637 0.1521 0.5636 0.4078 0.0286 0.7725 0.0000 0.2275
0.6977 0.1602 0.1421 0.5841 0.3831 0.0328 0.7845 0.0000 0.2155
0.7058 0.1652 0.1290 0.6040 0.3601 0.0359 0.7962 0.0000 0.2038
0.7299 0.1503 0.1198 0.6413 0.3148 0.0439 0.8140 0.0015 0.1845
0.7485 0.1287 0.1228 0.6607 0.2908 0.0485 0.8217 0.0037 0.1746
0.7693 0.1210 0.1097 0.7204 0.2116 0.0680 0.8218 0.0332 0.1450
0.7784 0.1100 0.1116 0.7266 0.2034 0.0700 0.8201 0.0398 0.1401
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 308.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6854 0.1604 0.1542 0.5382 0.4381 0.0237 0.7746 0.0000 0.2254
0.6983 0.1584 0.1433 0.5627 0.4099 0.0274 0.7895 0.0000 0.2105
0.7046 0.1648 0.1306 0.5812 0.3888 0.0300 0.8012 0.0000 0.1988
0.7230 0.1598 0.1172 0.6155 0.3484 0.0361 0.8162 0.0030 0.1808
0.7475 0.1286 0.1239 0.6481 0.3084 0.0435 0.8235 0.0048 0.1717
0.7647 0.1199 0.1154 0.6651 0.2860 0.0489 0.8327 0.0123 0.1550
0.7784 0.1089 0.1127 0.6886 0.2582 0.0532 0.8331 0.0217 0.1452
___________________________________________________________________________________
T/K = 318.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6880 0.1549 0.1571 0.5087 0.4720 0.0193 0.7788 0.0000 0.2212
0.7001 0.1544 0.1455 0.5332 0.4450 0.0218 0.7940 0.0000 0.2060
0.7040 0.1632 0.1328 0.5492 0.4268 0.0240 0.8050 0.0000 0.1950
0.7193 0.1622 0.1185 0.5797 0.3925 0.0278 0.8188 0.0017 0.1795
0.7471 0.1270 0.1259 0.5963 0.3731 0.0306 0.8272 0.0026 0.1702
0.7644 0.1185 0.1171 0.6281 0.3358 0.0361 0.8378 0.0068 0.1554
0.7790 0.1069 0.1141 0.6474 0.3129 0.0397 0.8419 0.0147 0.1434
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.76229 0.13585 0.10186 0.66916 0.28030 0.05054 0.82969 0.01141 0.15890
0.77290 0.12384 0.10326 0.69031 0.25590 0.05379 0.83528 0.01552 0.14920
0.76298 0.14113 0.09589 0.69255 0.25360 0.05385 0.83537 0.01643 0.14820
0.79420 0.09008 0.11572 0.69891 0.24570 0.05539 0.83543 0.01697 0.14760
0.79092 0.09527 0.11381 0.70148 0.24180 0.05672 0.83557 0.01713 0.14730
0.78636 0.11110 0.10254 0.75043 0.17910 0.07047 0.83583 0.03807 0.12610
0.80476 0.10037 0.09487 0.76379 0.16020 0.07601 0.82926 0.05384 0.11690
___________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 2001SAL

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.784 0.127 0.089 0.725 0.220 0.055 0.833 0.048 0.119
0.756 0.142 0.102 0.656 0.299 0.045 0.825 0.030 0.145
0.715 0.173 0.112 0.611 0.352 0.037 0.799 0.025 0.176
0.693 0.188 0.119 0.579 0.392 0.029 0.790 0.015 0.195
0.665 0.206 0.129 0.544 0.433 0.023 0.768 0.010 0.222
0.635 0.227 0.138 0.523 0.460 0.017 0.738 0.006 0.256
0.611 0.242 0.147 0.501 0.486 0.013 0.721 0.003 0.276
0.600 0.245 0.155 0.482 0.508 0.010 0.710 0.000 0.290
___________________________________________________________________________________

T/K = 298.15
wA 0.540 0.637 0.691 0.728 0.755 0.774 0.788 0.799 0.808
wB 0.432 0.325 0.262 0.217 0.183 0.158 0.139 0.123 0.111
wC 0.028 0.038 0.047 0.055 0.062 0.068 0.073 0.078 0.081
wA 0.830 0.855 0.866 0.814 0.750
wB 0.078 0.036 0.002 0.002 0.002
wC 0.092 0.109 0.132 0.184 0.248
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6622 0.1513 0.1865 0.479 0.502 0.019 0.742 0.00001 0.258
0.6924 0.1537 0.l539 0.530 0.446 0.024 0.777 0.00002 0.223
0.7219 0.1561 0.1220 0.582 0.387 0.031 0.818 0.00005 0.182
0.7514 0.1456 0.1030 0.641 0.321 0.038 0.644 0.00034 0.156
0.7712 0.1380 0.0908 0.698 0.255 0.047 0.859 0.00294 0.138
___________________________________________________________________________________
____________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.760 0.100 0.140 0.600 0.364 0.036 0.813 0.000 0.186
0.720 0.120 0.160 0.552 0.419 0.029 0.782 0.000 0.218
0.660 0.140 0.200 0.454 0.525 0.021 0.723 0.000 0.277
0.600 0.160 0.240 0.434 0.552 0.014 0.674 0.000 0.326
___________________________________________________________________________________

Salt (C): diammonium hydrogen phosphate (NH4)2HPO4 7783-28-0
T/K = 298.15
wA 0.6431 0.6695 0.7092 0.7400 0.7905 0.8059 0.8161 0.8247 0.8411
wB 0.3357 0.3016 0.2530 0.2125 0.1425 0.1190 0.1040 0.0901 0.0624
wC 0.0212 0.0289 0.0378 0.0475 0.0670 0.0751 0.0799 0.0852 0.0965
wA 0.8478 0.8537 0.8587 0.8624 0.8647 0.8633
wB 0.0508 0.0397 0.0297 0.0211 0.0134 0.0047
wC 0.1014 0.1066 0.1116 0.1165 0.1219 0.1320
T/K = 308.15
wA 0.5845 0.7076 0.7478 0.7807 0.8054 0.8233 0.8360 0.8517 0.8589
wB 0.3992 0.2581 0.2076 0.1657 0.1321 0.1072 0.0899 0.0663 0.0552
wC 0.0163 0.0343 0.0446 0.0536 0.0625 0.0695 0.0741 0.0820 0.0859
wA 0.8652 0.8706 0.8783 0.8800 0.8807
wB 0.0451 0.0359 0.0210 0.0160 0.0128
wC 0.0897 0.0935 0.1007 0.1040 0.1065
T/K = 318.15
wA 0.6180 0.6936 0.7395 0.7701 0.7955 0.8079 0.8141 0.8377 0.8475
wB 0.3644 0.2770 0.2220 0.1840 0.1514 0.1348 0.1264 0.0937 0.0798
wC 0.0176 0.0294 0.0385 0.0459 0.0531 0.0573 0.0595 0.0686 0.0727
wA 0.8578 0.8645 0.8740 0.8798
wB 0.0651 0.0553 0.0400 0.0298
wC 0.0771 0.0802 0.0860 0.0904
continued
____________________________________________________________________________________
continued
T/K = 298.15
____________________________________________________
wA wB wC wA wB wC
____________________________________________________
0.67604 0.29399 0.02997 0.83780 0.00516 0.15704
0.68221 0.28636 0.03143 0.83956 0.00506 0.15538
0.70147 0.26274 0.03579 0.84639 0.00526 0.14835
0.70437 0.25951 0.03612 0.84884 0.00469 0.14647
0.71099 0.25062 0.03839 0.84982 0.00530 0.14488
0.72684 0.23000 0.04316 0.85843 0.00473 0.13684
0.73422 0.22060 0.04518 0.86220 0.00508 0.13272
0.74346 0.20804 0.04850 0.86432 0.00637 0.12931
____________________________________________________
T/K = 308.15
____________________________________________________
wA wB wC wA wB wC
____________________________________________________
0.62628 0.35310 0.02062 0.84322 0.00884 0.14794
0.64027 0.33752 0.02221 0.84767 0.01009 0.14224
0.67994 0.29110 0.02896 0.85621 0.01093 0.13286
0.69799 0.26988 0.03213 0.86191 0.01186 0.12623
0.71335 0.25068 0.03597 0.86607 0.01198 0.12195
0.72772 0.23264 0.03964 0.86994 0.01232 0.11774
0.74464 0.21205 0.04331 0.87371 0.01268 0.11361
____________________________________________________
T/K = 318.15
____________________________________________________
wA wB wC wA wB wC
____________________________________________________
0.64591 0.33200 0.02209 0.85854 0.01516 0.12630
0.67158 0.30232 0.02610 0.86738 0.01639 0.11623
0.68501 0.28696 0.02803 0.86994 0.01651 0.11355
0.70369 0.26509 0.03122 0.87409 0.01692 0.10899
0.71816 0.24763 0.03421 0.87656 0.01942 0.10402
0.74551 0.21461 0.03988 0.88037 0.02497 0.09466
0.76423 0.19171 0.04406 0.87866 0.03083 0.09051
____________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1994PE1

T/K = 298.15 pH = 9.43
____________________________________________________
wA wB wC wA wB wC
____________________________________________________
0.6300 0.3452 0.0248 0.7583 0.0019 0.2398
0.6312 0.3433 0.0255 0.7592 0.0022 0.2386
0.6311 0.3404 0.0285 0.7752 0.0039 0.2209
0.6351 0.3356 0.0293 0.7763 0.0042 0.2195
0.6375 0.3307 0.0318 0.7893 0.0069 0.2038
0.6373 0.3305 0.0322 0.7927 0.0092 0.1981
0.6468 0.3117 0.0415 0.8025 0.0143 0.1832
0.6894 0.2508 0.0598 0.8084 0.0274 0.1642
0.6985 0.2367 0.0648 0.8092 0.0321 0.1587
0.7055 0.2257 0.0688 0.8076 0.0389 0.1535
____________________________________________________

Characterization: Mn/g.mol−1 = 2000, Asahi-Kasei, Japan
T/K = 298.15 pH = 9.43
____________________________________________________
wA wB wC wA wB wC
____________________________________________________
0.6647 0.3049 0.0304 0.8237 0.0081 0.1682
0.6781 0.2861 0.0358 0.8273 0.0112 0.1615
0.6810 0.2817 0.0373 0.8278 0.0114 0.1608
0.6872 0.2726 0.0402 0.8302 0.0142 0.1556
0.7079 0.2434 0.0487 0.8315 0.0233 0.1452
0.7278 0.2175 0.0547 0.8332 0.0289 0.1379
0.7692 0.1601 0.0707 0.8309 0.0474 0.1217
0.7724 0.1549 0.0727 0.8279 0.0544 0.1177
0.7893 0.1303 0.0804 0.8197 0.0718 0.1085
____________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1990LEI

T/K = 277.15 pH = 9.2
___________________________________________________________________________________
___________________________________________________________________________________
0.7700 0.1380 0.0920 0.7165 0.2395 0.0440 0.8311 0.0226 0.1463
0.7490 0.1480 0.1030 0.6834 0.2791 0.0375 0.8174 0.0073 0.1753
0.7300 0.1600 0.1100 0.6596 0.3082 0.0322 0.8012 0.0039 0.1904
0.7100 0.1700 0.1200 0.6330 0.3391 0.0279 0.7831 0.0021 0.2148
___________________________________________________________________________________

T/K = 298.15 pH = 9.43
____________________________________________________
wA wB wC wA wB wC
____________________________________________________
0.6678 0.3114 0.0208 0.8229 0.0004 0.1767
0.6848 0.2904 0.0248 0.8498 0.0007 0.1495
0.7023 0.2649 0.0328 0.8456 0.0049 0.1495
0.7215 0.2357 0.0428 0.8480 0.0171 0.1349
0.7336 0.2195 0.0469 0.8469 0.0272 0.1259
0.7613 0.1814 0.0573 0.8415 0.0453 0.1132
0.7646 0.1769 0.0585 0.8413 0.0461 0.1126
0.7832 0.1503 0.0665 0.8348 0.0609 0.1043
0.7859 0.1464 0.0677 0.8338 0.0623 0.1039
0.7908 0.1388 0.0704 0.8334 0.0644 0.1022
____________________________________________________
Polymer (B): poly(ethylene glycol) 2002SER

continued
____________________________________________________________________________________
continued
T/K = 283.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7920 0.0809 0.1271 0.8207 0.1406 0.0387 0.7634 0.0211 0.2155
0.7783 0.0995 0.1222 0.7992 0.1712 0.0296 0.7574 0.0278 0.2148
0.7713 0.1067 0.1220 0.7877 0.1837 0.0286 0.7550 0.0297 0.2153
0.7614 0.1171 0.1215 0.7712 0.2017 0.0271 0.7517 0.0324 0.2159
0.7588 0.1198 0.1214 0.7668 0.2065 0.0267 0.7509 0.0331 0.2160
0.7571 0.1215 0.1214 0.7640 0.2095 0.0265 0.7502 0.0336 0.2162
0.7548 0.1240 0.1212 0.7601 0.2137 0.0262 0.7495 0.0342 0.2163
0.7546 0.1242 0.1212 0.7597 0.2141 0.0262 0.7494 0.0343 0.2163
0.7522 0.1267 0.1211 0.7557 0.2185 0.0258 0.7486 0.0349 0.2165
0.7519 0.1270 0.1211 0.7552 0.2190 0.0258 0.7485 0.0350 0.2165
0.7387 0.1355 0.1258 0.7316 0.2337 0.0347 0.7458 0.0372 0.2170
0.7435 0.1357 0.1208 0.7413 0.2341 0.0246 0.7457 0.0373 0.2170
0.7383 0.1410 0.1207 0.7327 0.2433 0.0240 0.7439 0.0387 0.2174
0.7289 0.1508 0.1203 0.7170 0.2603 0.0227 0.7408 0.0412 0.2180
0.7057 0.1746 0.1197 0.6785 0.3017 0.0198 0.7330 0.0475 0.2195
0.7029 0.1790 0.1181 0.6722 0.3122 0.0156 0.7335 0.0459 0.2206
0.6965 0.1840 0.1195 0.6631 0.3181 0.0188 0.7298 0.0500 0.2202
0.6638 0.2173 0.1189 0.6090 0.3758 0.0152 0.7186 0.0588 0.2226
0.6592 0.2220 0.1188 0.6013 0.3840 0.0147 0.7171 0.0600 0.2229
0.6380 0.2433 0.1187 0.5664 0.4209 0.0127 0.7096 0.0658 0.2246
0.6305 0.2509 0.1186 0.5541 0.4339 0.0120 0.7069 0.0679 0.2252
0.5996 0.2818 0.1186 0.5037 0.4869 0.0094 0.6955 0.0767 0.2278
0.5977 0.2833 0.1190 0.5004 0.4896 0.0100 0.6949 0.0771 0.2280
0.5969 0.2850 0.1181 0.4963 0.4953 0.0084 0.6975 0.0747 0.2278
0.5772 0.3040 0.1188 0.4675 0.5248 0.0077 0.6869 0.0832 0.2299
0.5236 0.3563 0.1201 0.3830 0.6125 0.0045 0.6643 0.1000 0.2357
0.5117 0.3678 0.1205 0.3645 0.6316 0.0039 0.6589 0.1040 0.2371
0.4738 0.4039 0.1223 0.3076 0.6900 0.0024 0.6400 0.1177 0.2423
0.4394 0.4325 0.1281 0.2589 0.7398 0.0013 0.6200 0.1251 0.2549
___________________________________________________________________________________
T/K = 288.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8137 0.0904 0.0959 0.7876 0.1724 0.0400 0.8399 0.0083 0.1518
0.8050 0.0968 0.0982 0.7726 0.1887 0.0387 0.8374 0.0048 0.1578
0.7918 0.1057 0.1025 0.7573 0.2068 0.0359 0.8262 0.0046 0.1692
0.7688 0.1254 0.1058 0.7237 0.2441 0.0322 0.8139 0.0066 0.1795
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.7670 0.1267 0.1063 0.7211 0.2469 0.0320 0.8129 0.0065 0.1806
0.7529 0.1376 0.1095 0.7011 0.2688 0.0301 0.8048 0.0063 0.1889
0.7508 0.1392 0.1100 0.6980 0.2721 0.0299 0.8036 0.0063 0.1901
0.7462 0.1427 0.1111 0.6914 0.2792 0.0294 0.8010 0.0062 0.1928
0.7310 0.1542 0.1148 0.6698 0.3024 0.0278 0.7922 0.0061 0.2017
0.6718 0.1957 0.1325 0.5890 0.3865 0.0245 0.7546 0.0049 0.2405
0.6552 0.2080 0.1368 0.5668 0.4108 0.0224 0.7437 0.0052 0.2511
0.6576 0.2098 0.1326 0.5645 0.4128 0.0227 0.7506 0.0068 0.2426
0.6028 0.2470 0.1502 0.4948 0.4841 0.0211 0.7108 0.0099 0.2793
___________________________________________________________________________________
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8141 0.0934 0.0925 0.7775 0.1855 0.0370 0.8507 0.0013 0.1480
0.8063 0.0955 0.0982 0.7726 0.1887 0.0387 0.8399 0.0023 0.1578
0.7934 0.1041 0.1025 0.7573 0.2068 0.0359 0.8295 0.0013 0.1692
0.7859 0.1090 0.1051 0.7487 0.2169 0.0344 0.8232 0.0010 0.1758
0.7730 0.1173 0.1097 0.7339 0.2339 0.0322 0.8122 0.0006 0.1872
0.7714 0.1183 0.1103 0.7320 0.2360 0.0320 0.8108 0.0006 0.1886
0.7691 0.1198 0.1111 0.7294 0.2390 0.0316 0.8088 0.0005 0.1907
0.7518 0.1255 0.1227 0.7200 0.2502 0.0298 0.7836 0.0008 0.2156
0.7548 0.1290 0.1162 0.7184 0.2530 0.0286 0.7913 0.0050 0.2037
0.7585 0.1282 0.1150 0.7173 0.2560 0.0301 0.7997 0.0003 0.2000
0.7523 0.1304 0.1173 0.7103 0.2604 0.0293 0.7943 0.0003 0.2054
0.7437 0.1344 0.1219 0.7012 0.2685 0.0303 0.7862 0.0003 0.2135
0.7385 0.1386 0.1226 0.6948 0.2770 0.0276 0.7822 0.0002 0.2176
0.7096 0.1568 0.1336 0.6625 0.3128 0.0247 0.7566 0.0008 0.2426
0.6961 0.1609 0.1430 0.6577 0.3178 0.0245 0.7344 0.0041 0.2615
0.7022 0.1613 0.1365 0.6543 0.3216 0.0241 0.7500 0.0010 0.2490
0.6781 0.1760 0.1459 0.6275 0.3501 0.0224 0.7287 0.0019 0.2694
0.6622 0.1852 0.1526 0.6083 0.3703 0.0214 0.7161 0.0001 0.2838
0.6380 0.1999 0.1621 0.5813 0.3986 0.0201 0.6947 0.0012 0.3041
0.6344 0.2019 0.1637 0.5767 0.4034 0.0199 0.6920 0.0005 0.3075
0.6195 0.2080 0.1725 0.5684 0.4106 0.0210 0.6706 0.0054 0.3240
0.5834 0.2293 0.1873 0.5239 0.4563 0.0198 0.6429 0.0024 0.3547
0.5633 0.2412 0.1955 0.4996 0.4811 0.0193 0.6271 0.0012 0.3717
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 303.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7811 0.1169 0.1020 0.7374 0.2181 0.0445 0.8247 0.0158 0.1595
0.7753 0.1256 0.0991 0.7228 0.2371 0.0401 0.8277 0.0142 0.1581
0.7688 0.1271 0.1041 0.7189 0.2415 0.0396 0.8186 0.0127 0.1687
0.7648 0.1307 0.1045 0.7134 0.2497 0.0369 0.8161 0.0117 0.1722
0.7615 0.1333 0.1052 0.7079 0.2565 0.0356 0.8151 0.0101 0.1748
0.7276 0.1585 0.1139 0.6579 0.3091 0.0330 0.7973 0.0079 0.1948
0.7282 0.1606 0.1112 0.6568 0.3137 0.0295 0.7996 0.0076 0.1928
0.7253 0.1616 0.1131 0.6550 0.3166 0.0284 0.7955 0.0067 0.1978
0.7076 0.1758 0.1166 0.6248 0.3451 0.0301 0.7903 0.0065 0.2032
0.6992 0.1811 0.1197 0.6174 0.3562 0.0264 0.7809 0.0061 0.2130
0.6766 0.1971 0.1263 0.5841 0.3890 0.0269 0.7690 0.0052 0.2258
0.6555 0.2135 0.1310 0.5553 0.4224 0.0230 0.7562 0.0047 0.2391
0.6473 0.2188 0.1339 0.5424 0.4333 0.0243 0.7521 0.0043 0.2436
0.6454 0.2213 0.1333 0.5406 0.4383 0.0211 0.7502 0.0043 0.2455
0.6384 0.2254 0.1362 0.5298 0.4468 0.0234 0.7469 0.0041 0.2490
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1991PAT

Characterization: Mw/g.mol−1 = 4000, M/s S.D. Fine Chemicals Pvt. Ltd., India
T/K = 303.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7941 0.0955 0.1104 0.6728 0.2965 0.0307 0.8494 0.0084 0.1422
0.7884 0.0919 0.1197 0.6438 0.3275 0.0287 0.8466 0.0034 0.1500
0.7797 0.0867 0.1336 0.6042 0.3734 0.0210 0.8348 0.0022 0.1630
0.7677 0.0793 0.1530 0.5700 0.4161 0.0140 0.8174 0.0014 0.1812
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.8701 0.8641 0.8591 0.8570 0.8514 0.8479 0.8369 0.8360 0.9219
wB 0.1027 0.0991 0.0956 0.0941 0.0906 0.0884 0.0819 0.0817 0.0742
wC 0.0272 0.0368 0.0453 0.0489 0.0580 0.0637 0.0812 0.0823 0.0039
wA 0.9142 0.8039 0.7864 0.7849 0.7475 0.6845 0.6218
wB 0.0717 0.0660 0.0590 0.0587 0.0469 0.0324 0.0232
wC 0.0141 0.1301 0.1546 0.1564 0.2056 0.2831 0.3550

Characterization: Mn/g.mol−1 = 6000, Asahi-Kasei, Japan
T/K = 298.15
Comments: pH = 9.43
____________________________________________________
wA wB wC wA wB wC
____________________________________________________
0.7234 0.2494 0.0272 0.8555 0.0011 0.1434
0.7320 0.2363 0.0317 0.8620 0.0049 0.1331
0.7372 0.2289 0.0339 0.8637 0.0069 0.1294
0.7485 0.2144 0.0371 0.8643 0.0152 0.1205
0.7592 0.2007 0.0401 0.8642 0.0214 0.1144
0.7779 0.1735 0.0486 0.8635 0.0273 0.1092
0.7970 0.1486 0.0544 0.8635 0.0342 0.1023
0.8094 0.1318 0.0588 0.8592 0.0443 0.0965
0.8145 0.1249 0.0606 0.8564 0.0514 0.0922
0.8277 0.1077 0.0646 0.8566 0.0559 0.0875
____________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 277.15
___________________________________________________________________________________
wA wB wC wA wB wC pH wA wB wC pH
___________________________________________________________________________________
0.8087 0.0954 0.0959 0.7317 0.2277 0.0406 9.57 0.8652 0.0000 0.1348 9.45
0.7685 0.1163 0.1152 0.6765 0.2906 0.0329 9.72 0.8294 0.0000 0.1706 9.49
0.7238 0.1348 0.1414 0.6225 0.3523 0.0252 9.89 0.7871 0.0000 0.2129 9.56
0.6853 0.1736 0.1411 0.5890 0.3902 0.0208 9.89 0.7602 0.0000 0.2398 9.60
0.7721 0.1145 0.1134 0.6902 0.2733 0.0365 9.26 0.8320 0.0000 0.1675 9.31
0.7250 0.1338 0.1412 0.6322 0.3415 0.0263 9.33 0.7897 0.0000 0.2102 9.39
___________________________________________________________________________________
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8292 0.0857 0.0851 0.7983 0.1357 0.0660 9.23 0.8647 0.0289 0.1064 9.27
0.8226 0.0777 0.0997 0.7389 0.2134 0.0477 9.37 0.8649 0.0075 0.1276 9.26
0.8055 0.0869 0.1076 0.7086 0.2517 0.0397 9.12 0.8561 0.0029 0.1410 9.20
0.7980 0.0805 0.1215 0.6763 0.2903 0.0334 9.03 0.8438 0.0012 0.1550 9.04
0.7786 0.1079 0.1135 0.6698 0.2982 0.0320 9.09 0.8412 0.0008 0.1580 9.26
0.7834 0.0771 0.1395 0.6392 0.3332 0.0276 9.07 0.8241 0.0003 0.1756 9.10
0.7407 0.1315 0.1278 0.6252 0.3505 0.0243 9.09 0.8139 0.0001 0.1860 9.29
0.6990 0.1505 0.1505 0.5798 0.4003 0.0199 9.55 0.7735 0.0000 0.2265 9.44
___________________________________________________________________________________
T/K = 313.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8300 0.0852 0.0848 0.7281 0.2357 0.0362 9.22 0.8838 0.0054 0.1108 9.27
0.7699 0.1150 0.1151 0.6130 0.3660 0.0210 9.71 0.8380 0.0030 0.1590 9.31
0.7262 0.1338 0.1400 0.5599 0.4241 0.0160 9.81 0.8016 0.0000 0.1984 9.40
0.6900 0.1699 0.1401 0.5424 0.4438 0.0138 9.78 0.7828 0.0000 0.2172 9.44
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.657 0.675 0.692 0.710 0.721 0.758 0.782 0.799 0.812
wB 0.316 0.295 0.276 0.255 0.240 0.194 0.162 0.140 0.122
wC 0.027 0.030 0.032 0.035 0.039 0.048 0.056 0.061 0.066
wA 0.822 0.836 0.844 0.859 0.867 0.871 0.876 0.869 0.798
wB 0.108 0.088 0.075 0.053 0.040 0.034 0.008 0.002 0.002
wC 0.070 0.076 0.081 0.088 0.093 0.095 0.116 0.129 0.200
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7462 0.1535 0.1003 0.641 0.335 0.024 0.830 0.00039 0.170
0.7587 0.1488 0.0925 0.663 0.310 0.027 0.845 0.00058 0.154
0.7712 0.1420 0.0868 0.681 0.289 0.030 0.856 0.00130 0.143
0.7822 0.1358 0.0820 0.708 0.259 0.033 0.865 0.00157 0.133
0.8144 0.0958 0.0898 0.727 0.235 0.038 0.875 0.00310 0.122
0.8246 0.0916 0.0838 0.757 0.195 0.048 0.878 0.00935 0.113
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1995MI2

T/K = 288.15
wA 0.6635 0.7249 0.7820 0.8132 0.8677 0.8681 0.8605 0.8487
wB 0.3045 0.2344 0.1556 0.1106 0.0212 0.0066 0.0021 0.0015
wC 0.0320 0.0407 0.0624 0.0762 0.1111 0.1253 0.1374 0.1498
T/K = 308.15
wA 0.6593 0.7422 0.7928 0.7932 0.8150 0.8299 0.8406 0.8487 0.8926
wB 0.3159 0.2197 0.1571 0.1566 0.1268 0.1064 0.0922 0.0809 0.0114
wC 0.0248 0.0381 0.0501 0.0502 0.0582 0.0637 0.0672 0.0704 0.0960
wA 0.8899 0.8826
wB 0.0045 0.0022
wC 0.1056 0.1152
T/K = 318.15
wA 0.6374 0.6728 0.7014 0.7250 0.7449 0.7620 0.7764 0.7888 0.7993
wB 0.3422 0.3028 0.2707 0.2441 0.2210 0.2006 0.1833 0.1682 0.1550
wC 0.0204 0.0244 0.0279 0.0309 0.0341 0.0374 0.0403 0.0430 0.0457
continued
____________________________________________________________________________________
continued
wA 0.8083 0.8163 0.8166 0.8321 0.8437 0.8527 0.8596
wB 0.1439 0.1337 0.1329 0.1132 0.0980 0.0866 0.0766
wC 0.0478 0.0500 0.0505 0.0547 0.0583 0.0607 0.0638
T/K = 288.15
___________________________________________________________________________________
___________________________________________________________________________________
0.824 0.092 0.084 0.785 0.149 0.066 0.865 0.023 0.112
0.782 0.136 0.082 0.719 0.241 0.040 0.864 0.002 0.134
0.771 0.142 0.087 0.705 0.258 0.037 0.856 0.001 0.143
0.759 0.149 0.092 0.681 0.287 0.032 0.841 0.0003 0.159
0.746 0.154 0.100 0.664 0.306 0.030 0.834 0.0001 0.166
___________________________________________________________________________________
T/K = 308.15
___________________________________________________________________________________
___________________________________________________________________________________
0.824 0.092 0.084 0.730 0.234 0.036 0.883 0.006 0.111
0.782 0.136 0.082 0.691 0.279 0.030 0.868 0.002 0.130
0.771 0.142 0.087 0.661 0.313 0.026 0.857 0.004 0.139
0.759 0.149 0.092 0.635 0.342 0.023 0.853 0.001 0.146
0.746 0.154 0.100 0.610 0.370 0.020 0.844 0.001 0.155
___________________________________________________________________________________
T/K = 318.15
___________________________________________________________________________________
___________________________________________________________________________________
0.824 0.092 0.084 0.697 0.274 0.029 0.887 0.005 0.108
0.782 0.136 0.082 0.667 0.310 0.023 0.872 0.004 0.124
0.771 0.142 0.087 0.645 0.335 0.020 0.866 0.002 0.132
0.759 0.149 0.092 0.623 0.358 0.019 0.856 0.001 0.143
0.746 0.154 0.100 0.590 0.392 0.018 0.845 0.001 0.154
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8447 0.0755 0.0798 0.8064 0.1420 0.0516 9.43 0.8869 0.0145 0.0986 9.42
0.7768 0.1251 0.0981 0.7085 0.2563 0.0352 9.57 0.8521 0.0000 0.1479 9.45
0.7418 0.1609 0.0973 0.6740 0.2943 0.0317 9.69 0.8239 0.0000 0.1761 9.51
0.6936 0.1702 0.1362 0.6056 0.3718 0.0226 9.82 0.7681 0.0000 0.2319 9.54
___________________________________________________________________________________
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8490 0.0757 0.0753 0.8021 0.1453 0.0526 9.16 0.8958 0.0068 0.0974 9.23
0.8508 0.0715 0.0777 0.7968 0.1497 0.0535 9.16 0.8949 0.0063 0.0988 9.23
0.8228 0.0996 0.0776 0.7568 0.1968 0.0464 8.94 0.8871 0.0015 0.1114 9.20
0.7993 0.1203 0.0804 0.7359 0.2250 0.0391 9.00 0.8774 0.0009 0.1217 9.00
0.7841 0.1183 0.0976 0.6777 0.2903 0.0320 9.53 0.8517 0.0008 0.1475 9.21
0.7569 0.1388 0.1043 0.6514 0.3211 0.0275 9.03 0.8334 0.0002 0.1664 9.07
0.7023 0.1595 0.1382 0.5682 0.4059 0.0259 9.67 0.7862 0.0000 0.2138 9.37
0.6999 0.1502 0.1499 0.5706 0.4056 0.0238 9.97 0.7779 0.0000 0.2221 9.60
___________________________________________________________________________________
T/K = 313.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8514 0.0703 0.0783 0.7568 0.2070 0.0362 9.48 0.8962 0.0030 0.1008 9.44
0.8202 0.0793 0.1005 0.6763 0.2987 0.0250 9.59 0.8724 0.0032 0.1244 9.55
0.7779 0.1264 0.0957 0.6464 0.3288 0.0248 9.71 0.8600 0.0000 0.1400 9.64
0.6951 0.1691 0.1358 0.5370 0.4491 0.0139 9.80 0.7884 0.0000 0.2116 9.71
___________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
continued
____________________________________________________________________________________
continued
T/K = 277.15
Comments: pH = 7, prepared by weight ratio of dibasic to monobasic potassium phosphate = 1.82.
___________________________________________________________________________________
___________________________________________________________________________________
0.6460 0.1940 0.1600 0.6440 0.2875 0.0685 0.6550 0.0305 0.3145
0.6260 0.2060 0.1680 0.6220 0.3202 0.0578 0.6395 0.0254 0.3351
0.5940 0.2320 0.1740 0.5852 0.3679 0.0469 0.6015 0.0224 0.3761
0.5700 0.2510 0.1790 0.5632 0.3973 0.0395 0.5815 0.0212 0.3973
___________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7050 0.1400 0.1550 0.6795 0.2301 0.0904 0.7253 0.0541 0.2206
0.6806 0.1551 0.1643 0.6484 0.2873 0.0643 0.7048 0.0347 0.2605
0.6610 0.1700 0.1690 0.6274 0.3188 0.0538 0.6905 0.0266 0.2829
0.6430 0.1830 0.1740 0.6074 0.3448 0.0478 0.6741 0.0200 0.3059
___________________________________________________________________________________

−1
Characterization: Mw/g.mol = 1000, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 277.15
continued
____________________________________________________________________________________
continued
_______________________________________________________________________________________________________

_______________________________________________________________________________________________________
0.7200 0.1300 0.1500 0.6834 0.2502 0.0664 0.7536 0.0308 0.2156
0.6930 0.1500 0.1570 0.6545 0.2902 0.0553 0.7336 0.0108 0.2556
0.6680 0.1700 0.1620 0.6284 0.3256 0.0460 0.7121 0.0071 0.2808
0.6400 0.1900 0.1700 0.5993 0.3637 0.0370 0.6863 0.0056 0.3081
_______________________________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 277.15
Comments: pH = 7, prepared by weight ratio of dibasic to monobasic potassium phosphate.
_______________________________________________________________________________________________________

_______________________________________________________________________________________________________
0.7160 0.1790 0.1050 0.6893 0.2609 0.0408 0.7160 0.0746 0.1947
0.6862 0.1999 0.1139 0.6475 0.3200 0.0325 0.6938 0.0686 0.2274
0.6572 0.2199 0.1229 0.6096 0.3601 0.0203 0.6759 0.0499 0.2542
_______________________________________________________________________________________________________

_______________________________________________________________________________________________________

_______________________________________________________________________________________________________
0.7162 0.1789 0.1049 0.6830 0.2686 0.0484 0.7532 0.0519 0.1949
0.6860 0.2000 0.1140 0.6397 0.3273 0.0330 0.7396 0.0376 0.2228
0.6570 0.2200 0.1230 0.5991 0.3710 0.0290 0.7244 0.0291 0.2465
_______________________________________________________________________________________________________
T/K = 298.15
_______________________________________________________________________________________________________

_______________________________________________________________________________________________________
0.7243 0.1738 0.1019 0.7015 0.2514 0.0471 0.7606 0.0465 0.1930
0.6864 0.1997 0.1138 0.6391 0.3278 0.0331 0.7458 0.0332 0.2210
0.6570 0.2200 0.1230 0.5963 0.3737 0.0300 0.7091 0.0491 0.2418
_______________________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.7161 0.1789 0.1050 0.6579 0.2919 0.0502 0.7809 0.0362 0.1829
0.6860 0.2000 0.1140 0.6085 0.3568 0.0347 0.7606 0.0227 0.2167
0.6570 0.2200 0.1230 0.5717 0.3970 0.0313 0.7575 0.0233 0.2292
___________________________________________________________________________________
T/K = 313.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7034 0.1790 0.1050 0.6622 0.2770 0.0401 0.7758 0.0350 0.1892
0.6862 0.1998 0.1050 0.6500 0.3177 0.0323 0.7534 0.0275 0.2186
0.6570 0.2200 0.1230 0.5883 0.3841 0.0306 0.7191 0.0326 0.2483
___________________________________________________________________________________
___________________________________________________________________________________
___________________________________________________________________________________
0.7161 0.1789 0.1050 0.6398 0.3086 0.0516 0.7829 0.0296 0.1875
0.6861 0.1999 0.1140 0.5973 0.3673 0.0354 0.6997 0.0647 0.2355
0.6572 0.2199 0.1229 0.5615 0.4066 0.0319 0.7542 0.0091 0.2367
___________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 298.15
Comments: pH = 8, prepared by weight ratio of dibasic to monobasic potassium phosphate = 15.
continued
____________________________________________________________________________________
continued
_______________________________________________________________________________________________________

_______________________________________________________________________________________________________
0.739 0.161 0.100 0.705 0.227 0.068 0.790 0.050 0.160
0.716 0.179 0.105 0.661 0.289 0.050 0.785 0.028 0.187
0.686 0.200 0.114 0.604 0.361 0.035 0.763 0.021 0.216
0.657 0.220 0.123 0.578 0.391 0.031 0.744 0.016 0.240
_______________________________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 277.15
_______________________________________________________________________________________________________

_______________________________________________________________________________________________________
0.7477 0.1240 0.1283 0.7114 0.2222 0.0664 0.7788 0.0379 0.1833
0.7322 0.1368 0.1312 0.6901 0.2530 0.0569 0.7713 0.0250 0.2037
0.7036 0.1574 0.1390 0.6561 0.2995 0.0444 0.7518 0.0134 0.2348
0.6619 0.1864 0.1517 0.6141 0.3513 0.0346 0.7131 0.0098 0.277l
_______________________________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 277.15
_______________________________________________________________________________________________________

_______________________________________________________________________________________________________
0.7700 0.1050 0.1250 0.7385 0.1811 0.0804 0.8001 0.0249 0.1750
0.7600 0.1100 0.1300 0.7209 0.2081 0.0710 0.7944 0.0188 0.1868
0.7400 0.1200 0.1400 0.6931 0.2454 0.0615 0.7821 0.0100 0.2070
0.7200 0.1300 0.1500 0.6721 0.2714 0.0565 0.7613 0.0060 0.2327
_______________________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.7900 0.1010 0.1090 0.7485 0.1855 0.0660 0.8244 0.0276 0.1480
0.7760 0.1100 0.1140 0.7235 0.2214 0.0551 0.8191 0.0161 0.1648
0.7600 0.1220 0.1180 0.7054 0.2458 0.0488 0.8107 0.0101 0.1792
0.7400 0.1370 0.1230 0.6813 0.2766 0.04Z1 0.7937 0.0078 0.1985
___________________________________________________________________________________
___________________________________________________________________________________
___________________________________________________________________________________
0.7700 0.1380 0.0920 0.7230 0.2311 0.0459 0.8321 0.0204 0.1475
0.7490 0.1480 0.1030 0.6893 0.2733 0.0374 0.8175 0.0078 0.1747
0.7300 0.1600 0.1100 0.6667 0.3003 0.0330 0.8032 0.0064 0.1904
0.7100 0.1700 0.1200 0.6418 0.3289 0.0293 0.7830 0.0052 0.2118
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1994PE1, 1994PE2, 1995PEN

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 298.15
Comments: pH = 6.01, prepared by mole ratio of dibasic to monobasic potassium phosphate = 0.3528.
____________________________________________________
wA wB wC wA wB wC
____________________________________________________
0.7076 0.2308 0.0616 0.7994 0.0104 0.1902
0.7083 0.2298 0.0619 0.8006 0.0131 0.1863
0.7125 0.2237 0.0638 0.8016 0.0152 0.1832
0.7197 0.2124 0.0679 0.7829 0.0232 0.1939
0.7323 0.1932 0.0745 0.8032 0.0323 0.1645
0.7373 0.1866 0.0761 0.8047 0.0344 0.1609
0.7504 0.1643 0.0853 0.8026 0.0468 0.1506
0.7574 0.1524 0.0902 0.7996 0.0567 0.1437
0.7609 0.1464 0.0927 0.7979 0.0622 0.1399
____________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________
wA wB wC wA wB wC
____________________________________________________
0.6598 0.3034 0.0368 0.8049 0.0049 0.1902
0.6857 0.2721 0.0422 0.8165 0.0112 0.1723
0.6877 0.2697 0.0426 0.8170 0.0123 0.1707
0.6996 0.2538 0.0466 0.8196 0.0203 0.1601
0.7071 0.2436 0.0493 0.8213 0.0211 0.1576
0.7211 0.2258 0.0531 0.8237 0.0262 0.1501
0.7334 0.2067 0.0599 0.8242 0.0283 0.1475
0.7455 0.1922 0.0623 0.8238 0.0393 0.1369
0.7563 0.1754 0.0683 0.8192 0.0534 0.1274
0.7756 0.1463 0.0781 0.8169 0.0629 0.1202
____________________________________________________
____________________________________________________
wA wB wC wA wB wC
____________________________________________________
0.6553 0.3194 0.0253 0.8038 0.0004 0.1958
0.6783 0.2896 0.0321 0.8218 0.0023 0.1759
0.6844 0.2819 0.0337 0.8282 0.0049 0.1669
0.7003 0.2615 0.0382 0.8326 0.0058 0.1616
0.7103 0.2488 0.0409 0.8342 0.0059 0.1599
0.7240 0.2296 0.0464 0.8385 0.0114 0.1501
0.7320 0.2194 0.0486 0.8402 0.0145 0.1453
0.7375 0.2113 0.0512 0.8407 0.0158 0.1435
0.7376 0.2105 0.0519 0.8406 0.0163 0.1431
0.7517 0.1934 0.0549 0.8436 0.0195 0.1369
0.7595 0.1826 0.0579 0.8399 0.0334 0.1267
0.7749 0.1582 0.0669 0.8352 0.0454 0.1194
____________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
continued
____________________________________________________________________________________
continued
T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7810 0.1220 0.0970 0.7313 0.2219 0.0468 0.8323 0.0200 0.1477
0.7650 0.1320 0.1030 0.7102 0.2485 0.0413 0.8197 0.0160 0.1643
0.7480 0.1430 0.1090 0.6902 0.2714 0.0384 0.8067 0.0135 0.1798
0.7280 0.1550 0.1170 0.6884 0.2982 0.0334 0.7885 0.0119 0.1996
___________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7841 0.1389 0.0770 0.7545 0.2087 0.0368 0.8268 0.0443 0.1289
0.7392 0.1609 0.0999 0.6821 0.2957 0.0222 0.8045 0.0292 0.1663
0.7133 0.1788 0.1079 0.6493 0.3306 0.0201 0.7706 0.0410 0.1884
0.6582 0.2189 0.1229 0.5994 0.3828 0.0178 0.7081 0.0483 0.2436
___________________________________________________________________________________
___________________________________________________________________________________
___________________________________________________________________________________
0.7840 0.1390 0.0770 0.7537 0.2092 0.0371 0.8465 0.0274 0.1261
0.7391 0.1610 0.0999 0.6649 0.3106 0.0245 0.8132 0.0223 0.1645
0.7135 0.1787 0.1078 0.6440 0.3358 0.0202 0.7917 0.0248 0.1835
0.6581 0.2189 0.1230 0.5728 0.4122 0.0150 0.7274 0.0349 0.2377
___________________________________________________________________________________
T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.7458 0.1603 0.0939 0.6816 0.2684 0.0331 0.8058 0.0282 0.1660
0.7156 0.1792 0.1052 0.6384 0.3166 0.0242 0.7874 0.0283 0.1843
0.6840 0.2000 0.1160 0.6053 0.3547 0.0197 0.7656 0.0288 0.2056
___________________________________________________________________________________
___________________________________________________________________________________
___________________________________________________________________________________
0.7845 0.1387 0.0768 0.7005 0.2597 0.0398 0.8567 0.0188 0.1245
0.7380 0.1607 0.1013 0.6167 0.3568 0.0265 0.8122 0.0231 0.1647
0.7133 0.1788 0.1079 0.5919 0.3859 0.0222 0.8052 0.0144 0.1804
0.6588 0.2185 0.1227 0.5439 0.4402 0.0159 0.7667 0.0098 0.2235
___________________________________________________________________________________
___________________________________________________________________________________
___________________________________________________________________________________
0.7842 0.1389 0.0769 0.7378 0.2245 0.0377 0.8572 0.0161 0.1267
0.7391 0.1610 0.0999 0.6547 0.3204 0.0249 0.8212 0.0158 0.1630
0.7132 0.1789 0.1079 0.6005 0.3776 0.0219 0.7995 0.0162 0.1843
0.6581 0.2189 0.1230 0.5394 0.4446 0.0160 0.7488 0.0212 0.2300
___________________________________________________________________________________
T/K = 313.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7392 0.1609 0.0999 0.6669 0.2989 0.0342 0.8094 0.0256 0.1650
0.7130 0.1789 0.1081 0.6233 0.3475 0.0292 0.7921 0.0296 0.1783
0.6841 0.2000 0.1160 0.5906 0.3792 0.0302 0.7751 0.0362 0.1887
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.7840 0.1390 0.0770 0.6992 0.2670 0.0338 0.8609 0.0150 0.1241
0.7391 0.1610 0.0999 0.6202 0.3534 0.0264 0.8233 0.0142 0.1625
0.7146 0.1780 0.1074 0.5916 0.3862 0.0222 0.8099 0.0108 0.1793
0.6581 0.2189 0.1230 0.5243 0.4593 0.0164 0.7545 0.0162 0.2293
___________________________________________________________________________________
___________________________________________________________________________________
___________________________________________________________________________________
0.7650 0.1512 0.0838 0.6792 0.2865 0.0343 0.8300 0.0387 0.1313
0.7390 0.1610 0.1000 0.6051 0.3707 0.0242 0.8064 0.0317 0.1619
0.7131 0.1789 0.1079 0.5606 0.4192 0.0202 0.7805 0.0334 0.1861
0.6581 0.2189 0.1230 0.5171 0.4679 0.0150 0.7539 0.0205 0.2256
___________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.802 0.121 0.077 0.739 0.217 0.044 0.867 0.019 0.115
0.784 0.139 0.077 0.715 0.246 0.039 0.861 0.016 0.124
0.739 0.161 0.100 0.629 0.346 0.026 0.821 0.016 0.163
0.713 0.179 0.108 0.597 0.381 0.022 0.794 0.023 0.183
0.684 0.200 0.116 0.570 0.412 0.018 0.764 0.030 0.206
0.658 0.219 0.123 0.540 0.444 0.016 0.749 0.020 0.231
___________________________________________________________________________________
____________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8200 0.0900 0.0900 0.7709 0.1755 0.0536 0.8591 0.0210 0.1199
0.8040 0.1000 0.0960 0.7524 0.2006 0.0470 0.8624 0.0120 0.1356
0.7870 0.1140 0.0990 0.7260 0.2339 0.0401 0.8411 0.0090 0.1499
0.7660 0.1300 0.1040 0.7010 0.2621 0.0369 0.8276 0.0088 0.1636
___________________________________________________________________________________
Additional data for the system poly(ethylene glycol) (B) + water (A) + dipotassium phosphate/
monopotassium phosphate (C) can be found in Ref. 1986ALB.

Salt (C): disodium hydrogen phosphate Na2HPO4 7558-79-4
T/K = 298.15
wA 0.8347 0.8306 0.8238 0.8154 0.8077 0.7916 0.7747 0.7339 0.7293
wB 0.0444 0.0593 0.0772 0.0926 0.1080 0.1344 0.1620 0.2230 0.2293
wC 0.1209 0.1101 0.0990 0.0920 0.0843 0.0740 0.0633 0.0431 0.0414
wA 0.7130 0.6944 0.6724 0.6544 0.6418 0.6322 0.6229 0.5633 0.4970
wB 0.2517 0.2760 0.3039 0.3250 0.3399 0.3511 0.3625 0.4296 0.5004
wC 0.0353 0.0296 0.0237 0.0206 0.0183 0.0167 0.0146 0.0071 0.0026
T/K = 308.15
wA 0.8390 0.8425 0.8382 0.8305 0.8233 0.8210 0.8108 0.8069 0.7980
wB 0.0176 0.0310 0.0461 0.0634 0.0757 0.0814 0.1009 0.1096 0.1240
wC 0.1434 0.1265 0.1157 0.1061 0.1010 0.0976 0.0883 0.0835 0.0780
wA 0.7844 0.7622 0.7348 0.7031 0.6534 0.6023 0.5689 0.5238 0.4704
wB 0.1471 0.1817 0.2203 0.2648 0.3266 0.3853 0.4220 0.4701 0.5251
wC 0.0685 0.0561 0.0449 0.0321 0.0200 0.0124 0.0091 0.0061 0.0045
continued
____________________________________________________________________________________
continued
T/K = 318.15
wA 0.5026 0.5557 0.6105 0.6335 0.6610 0.6935 0.7218 0.7436 0.7581
wB 0.4911 0.4337 0.3727 0.3461 0.3135 0.2729 0.2354 0.2051 0.1844
wC 0.0063 0.0106 0.0168 0.0204 0.0255 0.0336 0.0428 0.0513 0.0575
wA 0.7743 0.7895 0.8096 0.8266 0.8401 0.8464 0.8473 0.8356
wB 0.1612 0.1370 0.1034 0.0742 0.0484 0.0290 0.0180 0.0054
wC 0.0645 0.0735 0.0870 0.0992 0.1115 0.1246 0.1347 0.1590
T/K = 298.15
_____________________________________________________________________

wA wB wC wA wB wC
_____________________________________________________________________
0.4013 0.3966 0.0096 0.7647 0.0103 0.2250
0.6284 0.3555 0.0161 0.7814 0.0157 0.2029
0.6339 0.3501 0.0160 0.7846 0.0157 0.1997
0.6496 0.3308 0.0196 0.7973 0.0157 0.1870
0.6741 0.3029 0.0230 0.8110 0.0157 0.1733
0.7092 0.2578 0.0330 0.8298 0.0257 0.1445
_____________________________________________________________________

T/K = 308.15
_____________________________________________________________________

wA wB wC wA wB wC
_____________________________________________________________________
0.5942 0.3940 0.0118 0.7748 0.0030 0.2222
0.6239 0.3610 0.0151 0.7922 0.0034 0.2044
0.6485 0.3319 0.0196 0.8015 0.0040 0.1945
0.6733 0.3020 0.0247 0.8135 0.0040 0.1825
0.6925 0.2777 0.0298 0.8199 0.0042 0.1759
0.7115 0.2533 0.0352 0.8387 0.0203 0.1410
_____________________________________________________________________

T/K = 318.15
_____________________________________________________________________

wA wB wC wA wB wC
_____________________________________________________________________
0.5345 0.4535 0.0120 0.7700 0.0000 0.2300
0.5571 0.4315 0.0114 0.7853 0.0000 0.2147
0.5798 0.4062 0.0140 0.7994 0.0000 0.2006
0.5952 0.3900 0.0148 0.8128 0.0000 0.1872
0.6246 0.3570 0.0184 0.8290 0.0000 0.1710
_____________________________________________________________________

____________________________________________________________________________________

T/K = 298.15
wA 0.9032 0.8976 0.8878 0.8774 0.8669 0.8502 0.8311 0.8046 0.7833
wB 0.0076 0.0213 0.0371 0.0529 0.0685 0.0921 0.1189 0.1539 0.1814
wC 0.0892 0.0811 0.0751 0.0697 0.0646 0.0577 0.0500 0.0415 0.0353
wA 0.7511 0.7410 0.7271 0.7069 0.6822 0.5994
wB 0.2204 0.2326 0.2489 0.2723 0.3009 0.3923
wC 0.0285 0.0264 0.0240 0.0208 0.0169 0.0083
T/K = 308.15
wA 0.9088 0.9032 0.8951 0.8810 0.8621 0.8377 0.8173 0.8001 0.7950
wB 0.0051 0.0215 0.0352 0.0551 0.0812 0.1137 0.1402 0.1617 0.1682
wC 0.0861 0.0753 0.0697 0.0639 0.0567 0.0486 0.0425 0.0382 0.0368
wA 0.7837 0.7581 0.7334 0.7084 0.6853 0.6586 0.6403 0.6257 0.5964
wB 0.1819 0.2128 0.2416 0.2703 0.2966 0.3263 0.3465 0.3627 0.3943
wC 0.0344 0.0291 0.0250 0.0213 0.0181 0.0151 0.0132 0.0116 0.0093
T/K = 318.15
wA 0.9168 0.9138 0.9051 0.8855 0.8673 0.8320 0.8156 0.7858 0.7585
wB 0.0099 0.0170 0.0312 0.0584 0.0826 0.1268 0.1468 0.1819 0.2140
wC 0.0733 0.0692 0.0637 0.0561 0.0501 0.0412 0.0376 0.0323 0.0275
wA 0.7267 0.7199 0.7010 0.6985 0.6821 0.6792 0.6562 0.6355 0.6024
wB 0.2505 0.2581 0.2797 0.2823 0.3003 0.3038 0.3289 0.3517 0.3870
wC 0.0228 0.0220 0.0193 0.0192 0.0176 0.0170 0.0149 0.0128 0.0106
T/K = 298.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.6643 0.3194 0.0163 0.8570 0.0030 0.1400
0.6857 0.2973 0.0170 0.8619 0.0071 0.1310
0.6952 0.2857 0.0191 0.8624 0.0096 0.1280
0.7230 0.2536 0.0234 0.8727 0.0101 0.1172
0.7429 0.2300 0.0271 0.8813 0.0107 0.1080
0.7626 0.2069 0.0305 0.8888 0.0091 0.1021
0.8003 0.1572 0.0425 0.8986 0.0154 0.0860
________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 308.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.6216 0.3657 0.0127 0.8570 0.0000 0.1430
0.6362 0.3495 0.0143 0.8600 0.0000 0.1400
0.6840 0.2972 0.0188 0.8781 0.0007 0.1212
0.7049 0.2746 0.0205 0.8849 0.0000 0.1151
0.7192 0.2590 0.0218 0.8914 0.0016 0.1070
0.7470 0.2260 0.0270 0.9025 0.0000 0.0975
0.7777 0.1892 0.0331 0.9065 0.0066 0.0869
________________________________________________________
T/K = 318.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.6027 0.3853 0.0120 0.8608 0.0000 0.1392
0.6281 0.3589 0.0130 0.8707 0.0000 0.1293
0.6661 0.3196 0.0143 0.8874 0.0000 0.1126
0.6839 0.2991 0.0170 0.8907 0.0064 0.1029
0.6995 0.2819 0.0186 0.8929 0.0071 0.1000
0.7123 0.2675 0.0202 0.8944 0.0096 0.0960
0.7412 0.2342 0.0246 0.9051 0.0062 0.0887
________________________________________________________

Salt (C): ferrous sulfate FeSO4 7720-78-7
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6600 0.1800 0.1600 0.6755 0.2547 0.0698 0.6198 0.0086 0.3716
0.5805 0.2200 0.1995 0.6140 0.3536 0.0324 0.5666 0.0082 0.4252
0.5400 0.2400 0.2200 0.5786 0.4044 0.0170 0.5027 0.0029 0.4944
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 303.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6600 0.2000 0.1400 0.6558 0.2933 0.0509 0.6403 0.0131 0.3466
0.6100 0.2100 0.1800 0.6202 0.3482 0.0316 0.5954 0.0085 0.3961
0.7000 0.1100 0.1900 0.7120 0.1860 0.1020 0.6739 0.0161 0.3100
0.5604 0.2398 0.1998 0.5833 0.3942 0.0225 0.5384 0.0041 0.4575
___________________________________________________________________________________
T/K = 313.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6800 0.1600 0.1600 0.6907 0.2739 0.0354 0.6764 0.0086 0.3150
0.6000 0.2211 0.1789 0.5902 0.4050 0.0048 0.6161 0.0020 0.3819
0.6401 0.1800 0.1799 0.6371 0.3421 0.0208 0.6507 0.0039 0.3454
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.765 0.140 0.095 0.661 0.306 0.033 0.805 0.063 0.132
0.755 0.145 0.100 0.634 0.335 0.031 0.816 0.038 0.146
0.745 0.150 0.105 0.608 0.361 0.031 0.817 0.026 0.157
0.735 0.155 0.110 0.591 0.378 0.031 0.815 0.020 0.165
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.799 0.123 0.079 0.715 0.254 0.031 0.831 0.048 0.122
0.779 0.131 0.089 0.682 0.292 0.026 0.817 0.045 0.139
0.762 0.140 0.098 0.647 0.328 0.025 0.807 0.051 0.142
0.748 0.147 0.105 0.632 0.344 0.024 0.804 0.044 0.152
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.809 0.121 0.070 0.750 0.212 0.038 0.846 0.059 0.095
0.796 0.127 0.077 0.701 0.279 0.020 0.843 0.045 0.112
0.769 0.140 0.091 0.642 0.345 0.013 0.836 0.026 0.138
0.752 0.150 0.098 0.617 0.375 0.008 0.831 0.021 0.148
0.730 0.165 0.105 0.588 0.405 0.007 0.815 0.015 0.170
0.708 0.180 0.112 0.558 0.437 0.005 0.810 0.012 0.178
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 2001BLA

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7534 0.1266 0.1200 0.7347 0.1954 0.0699 0.7829 0.0047 0.2124
0.7100 0.1700 0.1200 0.6801 0.2781 0.0418 0.7550 0.0000 0.2450
0.6488 0.2312 0.1200 0.5981 0.3780 0.0239 0.7049 0.0000 0.2951
0.6050 0.2750 0.1200 0.5766 0.4094 0.0140 0.6725 0.0000 0.3275
0.5610 0.3190 0.1200 0.5329 0.4563 0.0108 0.6212 0.0000 0.3788
___________________________________________________________________________________
____________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.800 0.120 0.080 0.710 0.252 0.038 0.837 0.038 0.125
0.765 0.140 0.095 0.651 0.323 0.026 0.847 0.008 0.145
0.755 0.145 0.100 0.642 0.335 0.023 0.843 0.007 0.151
0.745 0.150 0.105 0.626 0.352 0.022 0.833 0.008 0.159
0.735 0.155 0.110 0.601 0.382 0.017 0.822 0.012 0.167
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1996GON

Salt (C): magnesium sulfate heptahydrate MgSO4.7H2O 10034-99-8
T/K = 298.15
wA 0.4911 0.5461 0.6174 0.6633 0.6673 0.6707 0.6461 0.6432 0.6297
wB 0.5012 0.4334 0.3314 0.2192 0.1691 0.0912 0.0300 0.0287 0.0197
wC 0.0077 0.0205 0.0512 0.1175 0.1636 0.2381 0.3239 0.3281 0.3506
wA 0.6026 0.5700
wB 0.0106 0.0059
wC 0.3868 0.4241

T/K = 298.15
wA 0.5308 0.6945 0.7397 0.7563 0.7631 0.7565 0.7492 0.7409 0.7255
wB 0.4617 0.2446 0.1467 0.0698 0.0277 0.0319 0.0158 0.0095 0.0041
wC 0.0075 0.0609 0.1136 0.1739 0.2092 0.2116 0.2350 0.2496 0.2704
____________________________________________________________________________________

T/K = 298.15
wA 0.4739 0.5808 0.7046 0.7371 0.7650 0.7837 0.7956 0.8017 0.7996
wB 0.5206 0.4066 0.2477 0.1946 0.1461 0.0969 0.0563 0.0240 0.0242
wC 0.0055 0.0126 0.0477 0.0683 0.0889 0.1194 0.1481 0.1743 0.1762
wA 0.7961 0.7798 0.7798 0.7715 0.7686 0.7604 0.7480 0.7401
wB 0.0109 0.0044 0.0038 0.0020 0.0016 0.0008 0.0006 0.0005
wC 0.1930 0.2158 0.2164 0.2265 0.2298 0.2388 0.2514 0.2594
Polymer (B): poly(ethylene glycol) 2001GRU

Polyglycol 6000S, Hoechst AG, Frankfurt, Germany
Polymer (C): poly(acrylic acid) ammonium salt
Characterization: M/g.mol−1 = 5000, unspecified average molar mass
Rohagit SL135, Roehm GmbH, Darmstadt, Germany
T/K = 298.15
wA 0.527 0.520 0.462 0.544 0.602 0.598 0.533 0.568 0.593
wB 0.406 0.386 0.518 0.093 0.148 0.253 0.408 0.289 0.220
wC 0.067 0.094 0.020 0.363 0.250 0.149 0.059 0.143 0.187
wA 0.593 0.538 0.541 0.575 0.599 0.486 0.416 0.626 0.546
wB 0.108 0.416 0.384 0.320 0.232 0.473 0.574 0.143 0.271
wC 0.299 0.046 0.075 0.105 0.169 0.041 0.010 0.231 0.183
T/K = 323.15
wA 0.601 0.702 0.799 0.499 0.598 0.769 0.845 0.802 0.834
wB 0.002 0.002 0.002 0.487 0.387 0.182 0.011 0.117 0.047
wC 0.397 0.296 0.199 0.014 0.015 0.049 0.144 0.081 0.119

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.592 0.691 0.708 0.780 0.505 0.377 0.677 0.756 0.805
wB 0.013 0.012 0.114 0.133 0.482 0.383 0.223 0.169 0.079
wC 0.395 0.297 0.178 0.087 0.013 0.240 0.100 0.075 0.116
wA 0.679 0.731 0.642 0.688 0.698 0.708 0.790 0.707 0.422
wB 0.182 0.025 0.309 0.183 0.166 0.081 0.071 0.137 0.578
wC 0.139 0.244 0.049 0.129 0.136 0.211 0.139 0.156 0.000

T/K = 298.15
wA 0.544 0.650 0.730 0.717 0.658 0.469 0.581 0.691 0.726
wB 0.430 0.300 0.087 0.158 0.268 0.520 0.395 0.211 0.114
wC 0.026 0.050 0.183 0.125 0.074 0.011 0.024 0.098 0.160
T/K = 323.15
wA 0.526 0.609 0.712 0.800 0.857 0.799 0.848 0.870 0.753
wB 0.460 0.383 0.264 0.142 0.057 0.003 0.004 0.016 0.212
wC 0.014 0.008 0.024 0.058 0.086 0.198 0.148 0.114 0.035

T/K = 298.15
wA 0.552 0.688 0.763 0.825 0.797 0.736 0.702 0.672 0.602
wB 0.378 0.248 0.157 0.075 0.006 0.019 0.004 0.013 0.008
wC 0.070 0.064 0.080 0.100 0.197 0.245 0.294 0.315 0.390
T/K = 323.15
wA 0.699 0.803 0.604 0.687 0.776 0.873 0.877 0.880 0.857
wB 0.005 0.002 0.379 0.288 0.185 0.039 0.005 0.021 0.055
wC 0.296 0.195 0.017 0.025 0.039 0.088 0.118 0.099 0.088
____________________________________________________________________________________

T/K = 298.15
wA 0.771 0.845 0.769 0.713 0.802 0.854 0.761 0.719 0.671
wB 0.036 0.006 0.190 0.259 0.143 0.062 0.049 0.252 0.303
wC 0.193 0.149 0.041 0.028 0.055 0.084 0.190 0.029 0.026
T/K = 323.15
wA 0.799 0.900 0.708 0.877 0.896 0.613
wB 0.002 0.004 0.275 0.084 0.026 0.381
wC 0.199 0.096 0.017 0.039 0.078 0.006

Polymer (C): poly(acrylic acid) sodium salt
T/K = 298.15
wA 0.592 0.685 0.780 0.817 0.453 0.503 0.597 0.692 0.770
wB 0.014 0.022 0.025 0.037 0.530 0.460 0.373 0.276 0.173
wC 0.394 0.293 0.195 0.146 0.017 0.037 0.030 0.032 0.057
T/K = 323.15
wA 0.596 0.694 0.839 0.502 0.600 0.696 0.837 0.863 0.825
wB 0.007 0.008 0.068 0.485 0.388 0.285 0.080 0.008 0.006
wC 0.397 0.298 0.093 0.013 0.012 0.019 0.083 0.129 0.169
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.743 0.129 0.128 0.684 0.286 0.030 0.781 0.028 0.191
0.700 0.150 0.150 0.633 0.331 0.036 0.745 0.023 0.232
0.637 0.196 0.167 0.560 0.406 0.034 0.690 0.018 0.292
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.820 0.060 0.120 0.753 0.212 0.035 0.841 0.007 0.152
0.770 0.100 0.130 0.682 0.297 0.021 0.805 0.008 0.187
0.680 0.170 0.150 0.592 0.396 0.012 0.731 0.008 0.261
0.600 0.220 0.180 0.502 0.485 0.013 0.673 0.008 0.319
___________________________________________________________________________________

Sokolan SA 40, BASF AG, Ludwigshafen, Germany
T/K = 298.15
wA 0.491 0.586 0.834 0.591 0.775 0.741 0.840 0.849 0.421
wB 0.496 0.391 0.094 0.017 0.190 0.012 0.011 0.024 0.579
wC 0.013 0.023 0.072 0.392 0.035 0.247 0.149 0.127 0.000
T/K = 323.15
wA 0.595 0.693 0.795 0.496 0.693 0.799 0.876 0.791 0.886
wB 0.005 0.011 0.005 0.496 0.300 0.002 0.006 0.182 0.032
wC 0.400 0.296 0.200 0.008 0.007 0.199 0.118 0.027 0.082

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.750 0.150 0.100 0.788 0.174 0.038 0.838 0.016 0.146
0.752 0.150 0.098 0.720 0.248 0.032 0.789 0.011 0.200
0.709 0.150 0.141 0.664 0.309 0.027 0.740 0.011 0.249
0.649 0.181 0.170 0.595 0.390 0.015 0.690 0.011 0.299
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.840 0.050 0.110 0.779 0.200 0.021 0.854 0.004 0.142
0.770 0.120 0.110 0.713 0.277 0.010 0.810 0.004 0.186
0.649 0.201 0.150 0.579 0.411 0.010 0.701 0.004 0.295
0.530 0.270 0.200 0.438 0.556 0.006 0.609 0.003 0.388
___________________________________________________________________________________

T/K = 298.15
wA 0.709 0.775 0.831 0.873 0.631 0.719 0.810 0.839 0.864
wB 0.264 0.184 0.108 0.025 0.005 0.004 0.003 0.103 0.056
wC 0.027 0.041 0.061 0.102 0.364 0.277 0.187 0.058 0.080
T/K = 323.15
wA 0.501 0.600 0.698 0.786 0.898 0.799 0.700 0.601 0.875
wB 0.496 0.395 0.291 0.188 0.003 0.003 0.002 0.002 0.066
wC 0.003 0.005 0.011 0.026 0.099 0.198 0.298 0.397 0.059
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.847 0.080 0.073 0.827 0.125 0.048 0.873 0.011 0.116
0.800 0.100 0.100 0.748 0.221 0.031 0.833 0.003 0.164
0.736 0.151 0.113 0.687 0.284 0.029 0.783 0.003 0.214
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.860 0.050 0.090 0.785 0.191 0.024 0.881 0.004 0.115
0.790 0.100 0.110 0.699 0.289 0.012 0.830 0.004 0.166
0.700 0.150 0.150 0.592 0.401 0.007 0.751 0.003 0.246
0.600 0.200 0.200 0.466 0.530 0.004 0.665 0.003 0.332
___________________________________________________________________________________

T/K = 298.15
wA 0.684 0.498 0.599 0.697 0.794 0.887 0.777 0.850 0.877
wB 0.298 0.005 0.007 0.006 0.007 0.015 0.194 0.095 0.045
wC 0.018 0.497 0.394 0.297 0.199 0.098 0.029 0.055 0.078
T/K = 323.15
wA 0.504 0.594 0.693 0.699 0.784 0.868 0.898 0.918 0.897
wB 0.489 0.399 0.297 0.293 0.196 0.096 0.046 0.004 0.002
wC 0.007 0.007 0.010 0.008 0.020 0.036 0.056 0.078 0.101
wA 0.890 0.796 0.693 0.594 0.598
wB 0.010 0.004 0.010 0.008 0.003
wC 0.100 0.200 0.297 0.398 0.399
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.850 0.050 0.100 0.805 0.154 0.041 0.863 0.011 0.126
0.799 0.101 0.100 0.756 0.219 0.025 0.829 0.010 0.161
0.747 0.153 0.100 0.708 0.276 0.016 0.791 0.010 0.199
0.700 0.150 0.150 0.648 0.336 0.016 0.737 0.008 0.255
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.870 0.050 0.080 0.806 0.175 0.019 0.888 0.004 0.108
0.700 0.150 0.150 0.622 0.370 0.008 0.744 0.004 0.252
0.589 0.231 0.180 0.506 0.487 0.007 0.652 0.004 0.344
0.739 0.151 0.110 0.670 0.320 0.010 0.787 0.004 0.209
0.610 0.190 0.200 0.508 0.485 0.007 0.658 0.004 0.338
___________________________________________________________________________________

Polymer (C): poly(diallyldimethylammonium chloride)
Characterization: low Mn, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
T/K = 298.15
wA 0.778 0.752 0.624 0.645 0.467 0.578 0.530 0.610 0.772
wB 0.027 0.115 0.299 0.321 0.524 0.407 0.450 0.372 0.093
wC 0.195 0.133 0.077 0.034 0.009 0.015 0.020 0.018 0.135
T/K = 323.15
wA 0.793 0.509 0.614 0.748 0.792 0.779
wB 0.021 0.483 0.361 0.161 0.042 0.106
wC 0.186 0.008 0.025 0.091 0.166 0.115

Characterization: high Mn, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
T/K = 298.15
wA 0.805 0.519 0.657 0.467 0.594 0.421
wB 0.005 0.470 0.285 0.526 0.375 0.579
wC 0.190 0.011 0.058 0.007 0.031 0.000
T/K = 323.15
wA 0.798 0.712 0.667 0.805
wB 0.005 0.218 0.280 0.018
wC 0.197 0.070 0.053 0.177
____________________________________________________________________________________

Characterization: high Mn, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
T/K = 298.15
wA 0.795 0.758 0.634 0.805
wB 0.006 0.108 0.333 0.019
wC 0.199 0.134 0.033 0.176

Polymer (C): poly(ethylene sulfonic acid) sodium salt
T/K = 298.15
wA 0.489 0.469 0.441 0.457 0.471 0.471 0.480 0.431 0.421
wB 0.349 0.414 0.533 0.488 0.445 0.414 0.364 0.559 0.579
wC 0.162 0.117 0.026 0.055 0.084 0.115 0.156 0.010 0.000
T/K = 323.15
wA 0.800 0.750 0.606 0.703 0.794 0.853 0.509 0.847 0.867
wB 0.002 0.002 0.385 0.284 0.176 0.068 0.480 0.006 0.023
wC 0.198 0.248 0.009 0.013 0.030 0.079 0.011 0.147 0.110
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.786 0.060 0.154 0.765 0.209 0.026 0.795 0.002 0.203
0.718 0.100 0.182 0.683 0.306 0.011 0.738 0.001 0.261
0.668 0.150 0.182 0.632 0.356 0.012 0.698 0.001 0.301
0.575 0.201 0.224 0.534 0.456 0.010 0.614 0.001 0.385
___________________________________________________________________________________
____________________________________________________________________________________

Natriumapolat PIPU 005, Hoechst AG, Frankfurt, Germany
T/K = 298.15
wA 0.598 0.691 0.787 0.512 0.597 0.692 0.766 0.799 0.808
wB 0.009 0.013 0.017 0.481 0.395 0.293 0.189 0.111 0.095
wC 0.393 0.296 0.196 0.007 0.008 0.015 0.045 0.090 0.097
T/K = 323.15
wA 0.692 0.796 0.589 0.762 0.798 0.595 0.814 0.682 0.790
wB 0.011 0.005 0.394 0.190 0.090 0.399 0.042 0.286 0.148
wC 0.297 0.199 0.017 0.048 0.112 0.006 0.144 0.032 0.062
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.744 0.111 0.145 0.755 0.212 0.033 0.725 0.005 0.270
0.703 0.145 0.152 0.720 0.259 0.021 0.680 0.005 0.315
0.602 0.200 0.198 0.620 0.370 0.010 0.575 0.005 0.420
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.780 0.100 0.120 0.768 0.183 0.049 0.784 0.004 0.212
0.716 0.145 0.139 0.700 0.277 0.023 0.718 0.004 0.278
0.669 0.180 0.151 0.661 0.316 0.023 0.674 0.004 0.322
0.609 0.201 0.190 0.598 0.388 0.014 0.607 0.004 0.389
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.793 0.845 0.876 0.603 0.702 0.791 0.859 0.870
wB 0.009 0.006 0.027 0.392 0.283 0.162 0.073 0.006
wC 0.198 0.149 0.097 0.005 0.015 0.047 0.068 0.124
T/K = 323.15
wA 0.507 0.603 0.702 0.795 0.895 0.906 0.899 0.799 0.749
wB 0.486 0.392 0.290 0.184 0.045 0.019 0.002 0.002 0.003
wC 0.007 0.005 0.008 0.021 0.060 0.075 0.099 0.199 0.248
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.810 0.050 0.140 0.798 0.122 0.080 0.814 0.008 0.178
0.755 0.091 0.154 0.742 0.184 0.074 0.764 0.006 0.230
0.682 0.150 0.168 0.670 0.315 0.015 0.690 0.006 0.304
0.590 0.200 0.210 0.573 0.419 0.008 0.602 0.004 0.394
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.838 0.050 0.112 0.809 0.167 0.024 0.852 0.004 0.144
0.770 0.090 0.140 0.727 0.265 0.008 0.788 0.004 0.208
0.716 0.130 0.154 0.671 0.322 0.007 0.750 0.004 0.246
0.638 0.180 0.182 0.604 0.389 0.007 0.668 0.003 0.329
0.710 0.140 0.150 0.663 0.330 0.007 0.754 0.003 0.243
0.789 0.101 0.110 0.752 0.236 0.012 0.819 0.004 0.177
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.496 0.595 0.699 0.796 0.598 0.694 0.770 0.817 0.827
wB 0.006 0.006 0.005 0.005 0.399 0.295 0.193 0.090 0.025
wC 0.498 0.399 0.296 0.199 0.003 0.011 0.037 0.093 0.148
T/K = 323.15
wA 0.690 0.782 0.818 0.837 0.841 0.846 0.845 0.866 0.846
wB 0.294 0.196 0.133 0.101 0.093 0.068 0.060 0.016 0.005
wC 0.016 0.022 0.049 0.062 0.066 0.086 0.095 0.118 0.149
wA 0.848 0.794 0.696 0.595 0.600
wB 0.002 0.006 0.007 0.008 0.002
wC 0.150 0.200 0.297 0.397 0.398
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.800 0.050 0.150 0.800 0.130 0.070 0.795 0.005 0.200
0.750 0.100 0.150 0.760 0.210 0.030 0.740 0.005 0.255
0.700 0.150 0.150 0.705 0.285 0.010 0.680 0.005 0.315
0.700 0.200 0.100 0.705 0.285 0.010 0.683 0.005 0.312
0.724 0.135 0.141 0.735 0.242 0.023 0.712 0.003 0.285
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.829 0.070 0.101 0.791 0.184 0.025 0.830 0.003 0.167
0.750 0.110 0.140 0.725 0.254 0.021 0.756 0.003 0.241
0.680 0.180 0.140 0.665 0.321 0.014 0.686 0.003 0.311
0.620 0.200 0.180 0.611 0.374 0.015 0.622 0.003 0.375
0.709 0.151 0.140 0.694 0.293 0.013 0.715 0.003 0.282
___________________________________________________________________________________

Polymer (C): poly(methacrylic acid) sodium salt
continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.422 0.695 0.746 0.796 0.843 0.862 0.454 0.603 0.700
wB 0.578 0.007 0.006 0.004 0.008 0.042 0.540 0.381 0.285
wC 0.000 0.298 0.248 0.200 0.149 0.096 0.006 0.016 0.015
wA 0.788 0.820 0.747 0.858 0.836
wB 0.174 0.122 0.226 0.025 0.091
wC 0.038 0.058 0.027 0.117 0.073
T/K = 323.15
wA 0.603 0.700 0.787 0.852 0.873 0.876 0.875 0.795 0.694
wB 0.380 0.284 0.179 0.076 0.043 0.026 0.008 0.006 0.009
wC 0.017 0.016 0.034 0.072 0.084 0.098 0.117 0.199 0.297
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.817 0.070 0.113 0.784 0.191 0.025 0.826 0.006 0.168
0.767 0.120 0.113 0.729 0.254 0.017 0.790 0.006 0.204
0.706 0.171 0.123 0.665 0.318 0.017 0.737 0.008 0.255
0.616 0.220 0.164 0.558 0.436 0.006 0.659 0.006 0.335
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.847 0.050 0.103 0.793 0.172 0.035 0.861 0.007 0.132
0.787 0.100 0.113 0.732 0.243 0.025 0.821 0.006 0.173
0.696 0.150 0.154 0.616 0.374 0.010 0.743 0.006 0.251
0.646 0.200 0.154 0.571 0.413 0.016 0.706 0.007 0.287
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.686 0.787 0.866 0.453 0.511 0.602 0.783 0.818 0.422
wB 0.020 0.017 0.038 0.543 0.478 0.388 0.181 0.124 0.578
wC 0.294 0.196 0.096 0.004 0.011 0.010 0.036 0.058 0.000
T/K = 323.15
wA 0.605 0.701 0.789 0.856 0.885 0.876 0.792 0.800
wB 0.378 0.286 0.178 0.079 0.016 0.005 0.010 0.002
wC 0.017 0.013 0.033 0.065 0.099 0.119 0.198 0.198
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.820 0.080 0.100 0.780 0.179 0.041 0.829 0.019 0.152
0.755 0.130 0.115 0.716 0.273 0.011 0.783 0.017 0.200
0.714 0.151 0.135 0.667 0.318 0.015 0.742 0.018 0.240
0.644 0.200 0.156 0.587 0.409 0.004 0.684 0.016 0.300
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.846 0.050 0.104 0.782 0.200 0.018 0.858 0.005 0.137
0.774 0.101 0.125 0.699 0.289 0.012 0.806 0.005 0.189
0.694 0.150 0.156 0.609 0.381 0.010 0.738 0.005 0.257
0.603 0.220 0.177 0.512 0.479 0.009 0.671 0.005 0.324
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.696 0.797 0.882 0.599 0.704 0.781 0.844 0.882 0.865
wB 0.005 0.003 0.020 0.396 0.271 0.176 0.096 0.045 0.006
wC 0.299 0.200 0.098 0.005 0.025 0.043 0.060 0.073 0.129
T/K = 323.15
wA 0.797 0.896 0.516 0.606 0.699 0.868 0.910 0.748 0.833
wB 0.004 0.004 0.474 0.383 0.288 0.083 0.011 0.236 0.133
wC 0.199 0.100 0.010 0.011 0.013 0.049 0.079 0.016 0.034
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.849 0.051 0.100 0.807 0.147 0.046 0.871 0.009 0.120
0.802 0.140 0.058 0.781 0.197 0.022 0.846 0.004 0.150
0.780 0.100 0.120 0.733 0.239 0.028 0.811 0.003 0.186
0.710 0.140 0.150 0.655 0.327 0.018 0.752 0.002 0.246
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.868 0.050 0.082 0.809 0.170 0.021 0.892 0.007 0.101
0.816 0.081 0.103 0.741 0.245 0.014 0.849 0.004 0.147
0.747 0.130 0.123 0.664 0.326 0.010 0.792 0.005 0.203
0.646 0.200 0.154 0.561 0.435 0.004 0.666 0.050 0.284
___________________________________________________________________________________

T/K = 298.15
wA 0.694 0.795 0.844 0.605 0.694 0.779 0.833 0.857 0.844
wB 0.008 0.008 0.063 0.390 0.277 0.167 0.068 0.033 0.007
wC 0.298 0.197 0.093 0.005 0.029 0.054 0.099 0.110 0.149
continued
____________________________________________________________________________________
continued
T/K = 323.15
wA 0.605 0.700 0.790 0.869 0.908 0.917 0.894 0.800 0.691
wB 0.383 0.288 0.182 0.085 0.026 0.004 0.006 0.002 0.008
wC 0.012 0.012 0.028 0.046 0.066 0.079 0.100 0.198 0.301
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.718 0.200 0.082 0.692 0.281 0.027 0.764 0.008 0.228
0.750 0.110 0.140 0.698 0.277 0.025 0.780 0.007 0.213
0.800 0.060 0.140 0.745 0.204 0.051 0.814 0.008 0.178
0.690 0.140 0.170 0.627 0.366 0.007 0.728 0.007 0.265
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.749 0.101 0.150 0.635 0.357 0.008 0.792 0.008 0.200
0.680 0.170 0.150 0.570 0.416 0.014 0.746 0.008 0.246
0.850 0.075 0.075 0.789 0.194 0.017 0.872 0.008 0.120
___________________________________________________________________________________

Polymer (C): poly(styrene sulfonic acid) sodium salt
T/K = 298.15
wA 0.421 0.463 0.474 0.492 0.499 0.404 0.504 0.426 0.405
wB 0.579 0.458 0.434 0.389 0.349 0.576 0.322 0.504 0.548
wC 0.000 0.079 0.092 0.119 0.152 0.020 0.174 0.070 0.047
wA 0.498 0.521 0.409 0.504 0.455 0.459 0.489 0.483 0.484
wB 0.284 0.161 0.534 0.255 0.233 0.298 0.322 0.368 0.401
wC 0.218 0.318 0.057 0.241 0.312 0.243 0.189 0.149 0.115
wA 0.406 0.448 0.494 0.500 0.420 0.408 0.415
wB 0.513 0.469 0.355 0.318 0.579 0.551 0.569
wC 0.081 0.083 0.151 0.182 0.001 0.041 0.016
continued
____________________________________________________________________________________
continued
T/K = 323.15
wA 0.383 0.418 0.459 0.479 0.506 0.542 0.545 0.517
wB 0.569 0.525 0.449 0.398 0.337 0.232 0.180 0.126
wC 0.048 0.057 0.092 0.123 0.157 0.226 0.275 0.357

T/K = 323.15
wA 0.460 0.519 0.456 0.493 0.552 0.584 0.479 0.515
wB 0.459 0.346 0.457 0.401 0.273 0.189 0.429 0.345
wC 0.081 0.135 0.087 0.106 0.175 0.227 0.092 0.140

Salt (C): potassium citrate C6H8O7K3 866-84-2
T/K = 298.15
wA 0.5371 0.5986 0.6138 0.6289 0.6481 0.6645 0.6853 0.6996 0.7140
wB 0.4230 0.3515 0.3339 0.3146 0.2914 0.2698 0.2420 0.2221 0.2014
wC 0.0399 0.0499 0.0523 0.0565 0.0605 0.0657 0.0727 0.0783 0.0846
wA 0.7253 0.7356 0.7470 0.7573 0.7682 0.7760 0.7855 0.7894 0.7931
wB 0.1854 0.1693 0.1516 0.1343 0.1151 0.1010 0.0837 0.0760 0.0688
wC 0.0893 0.0951 0.1014 0.1084 0.1167 0.1230 0.1308 0.1346 0.1381
wA 0.7956 0.8022 0.8077 0.8108 0.8131 0.8136 0.8155
wB 0.0642 0.0515 0.0385 0.0301 0.0235 0.0179 0.0086
wC 0.1402 0.1463 0.1538 0.1591 0.1634 0.1685 0.1759
T/K = 308.15
wA 0.5581 0.5844 0.6206 0.6576 0.6869 0.7113 0.7315 0.7536 0.7655
wB 0.4039 0.3743 0.3324 0.2874 0.2510 0.2192 0.1916 0.1575 0.1387
wC 0.0380 0.0413 0.0470 0.0550 0.0621 0.0695 0.0769 0.0889 0.0958
wA 0.7755 0.7859 0.7956 0.8031 0.8089 0.8124 0.8203 0.8264 0.8315
wB 0.1227 0.1049 0.0884 0.0753 0.0653 0.0594 0.0454 0.0340 0.0203
wC 0.1018 0.1092 0.1160 0.1216 0.1258 0.1282 0.1343 0.1396 0.1482
continued
____________________________________________________________________________________
continued
T/K = 318.15
wA 0.6091 0.6508 0.6586 0.6676 0.6774 0.6909 0.7079 0.7248 0.7413
wB 0.3530 0.3025 0.2932 0.2826 0.2702 0.2538 0.2327 0.2109 0.1886
wC 0.0379 0.0467 0.0482 0.0498 0.0524 0.0553 0.0594 0.0643 0.0701
wA 0.7565 0.7695 0.7827 0.7922 0.8004 0.8069 0.8116 0.8202 0.8322
wB 0.1676 0.1487 0.1299 0.1148 0.1016 0.0910 0.0833 0.0713 0.0515
wC 0.0759 0.0818 0.0874 0.0930 0.0980 0.1021 0.1051 0.1085 0.1163
wA 0.8390 0.8428 0.8449 0.8466
wB 0.0393 0.0303 0.0232 0.0191
wC 0.1217 0.1269 0.1319 0.1343
T/K = 298.15
________________________________________________________
Polymer-rich phase Salt-rich phase
wA wB wC wA wB wC
________________________________________________________
0.5423 0.4197 0.0380 0.7233 0.0007 0.2760
0.5662 0.3924 0.0414 0.7441 0.0059 0.2500
0.5954 0.3572 0.0474 0.7694 0.0054 0.2252
0.6571 0.2799 0.0630 0.8009 0.0094 0.1897
0.6876 0.2434 0.0690 0.8072 0.0230 0.1698
________________________________________________________
T/K = 308.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.5510 0.4120 0.0370 0.7348 0.0141 0.2511
0.5843 0.3757 0.0400 0.7641 0.0203 0.2156
0.6245 0.3279 0.0476 0.7914 0.0207 0.1879
0.6558 0.2917 0.0525 0.8126 0.0132 0.1742
________________________________________________________
T/K = 318.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.5207 0.4553 0.0240 0.7291 0.0213 0.2496
0.5500 0.4200 0.0300 0.7724 0.0142 0.2134
0.6433 0.3101 0.0466 0.8288 0.0029 0.1683
0.6694 0.2786 0.0520 0.8368 0.0122 0.1510
________________________________________________________
____________________________________________________________________________________

T/K = 288.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6858 0.2188 0.0954 0.5751 0.4136 0.0113 0.8126 0.0000 0.1874
0.7040 0.2056 0.0904 0.5988 0.3877 0.0135 0.8273 0.0000 0.1727
0.7156 0.1996 0.0848 0.6173 0.3666 0.0161 0.8349 0.0009 0.1642
0.7395 0.1807 0.0798 0.6524 0.3274 0.0202 0.8479 0.0048 0.1473
0.7649 0.1601 0.0750 0.6925 0.2797 0.0278 0.8583 0.0106 0.1311
0.7790 0.1509 0.0701 0.7271 0.2361 0.0368 0.8588 0.0274 0.1138
0.7887 0.1383 0.0730 0.7350 0.2248 0.0402 0.8551 0.0321 0.1128
___________________________________________________________________________________
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6836 0.2211 0.0953 0.5588 0.4305 0.0107 0.8184 0.0000 0.1816
0.7049 0.2051 0.0900 0.5819 0.4058 0.0123 0.8323 0.0000 0.1677
0.7133 0.2022 0.0845 0.6017 0.3842 0.0141 0.8413 0.0000 0.1587
0.7409 0.1793 0.0798 0.6340 0.3468 0.0192 0.8529 0.0040 0.1431
0.7625 0.1627 0.0748 0.6769 0.2980 0.0251 0.8611 0.0139 0.1250
0.7766 0.1537 0.0697 0.7147 0.2518 0.0335 0.8580 0.0274 0.1146
0.7882 0.1393 0.0725 0.7219 0.2425 0.0356 0.8584 0.0334 0.1082
___________________________________________________________________________________
T/K = 308.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6818 0.2227 0.0955 0.5396 0.4503 0.0101 0.8253 0.0000 0.1747
0.7013 0.2086 0.0901 0.5644 0.4244 0.0112 0.8374 0.0000 0.1626
0.7114 0.2045 0.0841 0.5851 0.4007 0.0142 0.8460 0.0017 0.1523
0.7377 0.1831 0.0792 0.6209 0.3600 0.0191 0.8565 0.0067 0.1368
0.7621 0.1627 0.0752 0.6550 0.3228 0.0222 0.8635 0.0146 0.1219
0.7739 0.1570 0.0691 0.6933 0.2760 0.0307 0.8615 0.0302 0.1083
0.7877 0.1391 0.0732 0.7014 0.2679 0.0307 0.8627 0.0307 0.1066
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 318.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6810 0.2221 0.0969 0.5202 0.4705 0.0093 0.8304 0.0000 0.1696
0.6995 0.2099 0.0906 0.5451 0.4447 0.0102 0.8429 0.0000 0.1571
0.7083 0.2084 0.0833 0.5652 0.4230 0.0118 0.8507 0.0009 0.1484
0.7364 0.1847 0.0789 0.6020 0.3833 0.0147 0.8611 0.0062 0.1327
0.7628 0.1614 0.0758 0.6354 0.3455 0.0191 0.8689 0.0134 0.1177
0.7872 0.1388 0.0740 0.6753 0.2980 0.0267 0.8676 0.0268 0.1056
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.803 0.127 0.070 0.763 0.179 0.058 0.823 0.076 0.101
0.792 0.099 0.109 0.637 0.342 0.021 0.842 0.020 0.137
0.759 0.136 0.105 0.602 0.385 0.013 0.840 0.015 0.145
0.763 0.119 0.119 0.588 0.394 0.018 0.826 0.011 0.163
0.721 0.149 0.129 0.531 0.459 0.010 0.803 0.019 0.178
___________________________________________________________________________________

T/K = 288.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6299 0.2600 0.1101 0.4985 0.4958 0.0057 0.7734 0.0000 0.2266
0.6499 0.2501 0.1000 0.5251 0.4682 0.0067 0.7942 0.0000 0.2058
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.6654 0.2396 0.0950 0.5409 0.4513 0.0078 0.8123 0.0000 0.1877
0.7048 0.2048 0.0904 0.5823 0.4079 0.0098 0.8300 0.0000 0.1700
0.7411 0.1786 0.0803 0.6280 0.3592 0.0128 0.8601 0.0000 0.1399
0.7652 0.1599 0.0749 0.6616 0.3201 0.0183 0.8713 0.0000 0.1287
0.7792 0.1501 0.0707 0.6841 0.2942 0.0217 0.8770 0.0021 0.1209
0.7953 0.1398 0.0649 0.7185 0.2532 0.0283 0.8819 0.0099 0.1082
___________________________________________________________________________________
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6278 0.2627 0.1095 0.4836 0.5115 0.0049 0.7845 0.0000 0.2155
0.6469 0.2542 0.0989 0.5073 0.4862 0.0065 0.8014 0.0000 0.1986
0.6630 0.2421 0.0949 0.5272 0.4657 0.0071 0.8131 0.0000 0.1869
0.7052 0.2048 0.0900 0.5633 0.4274 0.0093 0.8372 0.0000 0.1628
0.7400 0.1800 0.0800 0.6079 0.3780 0.0141 0.8552 0.0000 0.1448
0.7777 0.1517 0.0706 0.6653 0.3151 0.0196 0.8817 0.0017 0.1166
0.7943 0.1410 0.0647 0.7031 0.2719 0.0250 0.8873 0.0089 0.1038
___________________________________________________________________________________
T/K = 308.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6252 0.2661 0.1087 0.4593 0.5363 0.0044 0.7917 0.0000 0.2083
0.6441 0.2576 0.0983 0.4879 0.5067 0.0054 0.8096 0.0000 0.1904
0.6616 0.2430 0.0954 0.5051 0.4889 0.0060 0.8195 0.0000 0.1805
0.7030 0.2072 0.0898 0.5430 0.4487 0.0083 0.8434 0.0000 0.1566
0.7397 0.1798 0.0805 0.5871 0.4020 0.0109 0.8655 0.0000 0.1345
0.7768 0.1524 0.0708 0.6446 0.3387 0.0167 0.8859 0.0018 0.1123
0.7933 0.1416 0.0651 0.6813 0.2975 0.0212 0.8908 0.0090 0.1002
___________________________________________________________________________________
T/K = 318.15
___________________________________________________________________________________
___________________________________________________________________________________
0.6222 0.2693 0.1085 0.4414 0.5547 0.0039 0.7984 0.0000 0.2016
0.6424 0.2590 0.0986 0.4648 0.5304 0.0048 0.8137 0.0000 0.1863
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.6606 0.2440 0.0954 0.4822 0.5123 0.0055 0.8257 0.0000 0.1743
0.7055 0.2029 0.0916 0.5190 0.4734 0.0076 0.8478 0.0000 0.1522
0.7408 0.1774 0.0818 0.5671 0.4231 0.0098 0.8710 0.0000 0.1290
0.7772 0.1512 0.0716 0.6202 0.3658 0.0140 0.8895 0.0010 0.1095
0.7934 0.1409 0.0657 0.6549 0.3277 0.0174 0.8949 0.0065 0.0986
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.751 0.140 0.109 0.580 0.375 0.045 0.848 0.008 0.144
0.720 0.161 0.119 0.525 0.432 0.043 0.830 0.005 0.165
0.660 0.200 0.140 0.462 0.505 0.034 0.782 0.015 0.203
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 2001TA1

T/K = 298.15
____________________________________________________________________________________
wA wB wC wA wB wC ρ/g cm−3 wA wB wC ρ/g cm−3
____________________________________________________________________________________
0.7700 0.1500 0.0800 0.5016 0.3678 0.1306 1.0756 0.9880 0.0000 0.0120 1.1289
0.7196 0.2001 0.0803 0.4378 0.4195 0.1427 1.0802 0.9911 0.0000 0.0089 1.1491
0.6699 0.2499 0.0802 0.3747 0.4563 0.1690 1.0851 0.9933 0.0000 0.0067 1.1761
0.6500 0.2000 0.1500 0.2674 0.5191 0.2135 1.0935 0.9959 0.0000 0.0041 1.2240
0.6374 0.2501 0.1125 0.2119 0.5516 0.2365 1.0976 0.9966 0.0000 0.0034 1.2482
0.5017 0.3976 0.1007 0.1085 0.6235 0.2680 1.1052 0.9980 0.0000 0.0020 1.2972
____________________________________________________________________________________
____________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.827 0.117 0.056 0.719 0.259 0.022 0.911 0.005 0.085
0.750 0.190 0.060 0.630 0.349 0.021 0.878 0.005 0.117
0.791 0.088 0.121 0.563 0.429 0.008 0.845 0.005 0.150
0.755 0.103 0.143 0.518 0.480 0.001 0.816 0.003 0.181
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1986ALB

−1
Characterization: Mn/g.mol = 6000-7500
T/K = 277.15
Comments: Solutions were prepared by using water with 0.3 M NaCl.
___________________________________________________________________________________
___________________________________________________________________________________
0.9191 0.0238 0.0571 0.9496 0.0380 0.0124 0.8960 0.0000 0.1040
0.9053 0.0284 0.0663 0.9481 0.0479 0.0040 0.8554 0.0000 0.1446
0.8898 0.0348 0.0754 0.9397 0.0588 0.0015 0.8193 0.0000 0.1807
0.8754 0.0403 0.0843 0.9313 0.0678 0.0009 0.7919 0.0000 0.2081
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1986ALB

continued
____________________________________________________________________________________
continued
T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9044 0.0287 0.0669 0.9478 0.0491 0.0031 0.8712 0.0100 0.1188
0.8952 0.0381 0.0667 0.9390 0.0602 0.0008 0.8361 0.0080 0.1559
0.9335 0.0645 0.0020 0.9349 0.0650 0.0001 0.8219 0.0080 0.1701
0.8857 0.0476 0.0667 0.9294 0.0703 0.0003 0.8121 0.0100 0.1779
___________________________________________________________________________________

Salt (C): sodium dihydrogen phosphate NaH2PO4 7558-80-7
T/K = 298.15
wA 0.6875 0.7043 0.7244 0.7252 0.7286 0.7273 0.7216 0.7125 0.7047
wB 0.0039 0.0070 0.0161 0.0259 0.0394 0.0570 0.0798 0.1075 0.1324
wC 0.3086 0.2887 0.2595 0.2489 0.2320 0.2157 0.1986 0.1800 0.1629
wA 0.6833 0.6645 0.6450 0.6206 0.6016 0.5787 0.5406 0.5237 0.5019
wB 0.1879 0.2303 0.2686 0.3072 0.3388 0.3727 0.4265 0.4500 0.4773
wC 0.1288 0.1052 0.0864 0.0722 0.0596 0.0486 0.0329 0.0263 0.0208
T/K = 308.15
wA 0.7222 0.7284 0.7343 0.7363 0.7363 0.7359 0.7350 0.7329 0.7306
wB 0.0115 0.0187 0.0288 0.0405 0.0430 0.0471 0.0536 0.0640 0.0721
wC 0.2663 0.2529 0.2369 0.2232 0.2207 0.2170 0.2114 0.2031 0.1973
wA 0.7280 0.7233 0.7175 0.7109 0.6980 0.6848 0.6787 0.6676 0.6549
wB 0.0806 0.0939 0.1091 0.1250 0.1557 0.1841 0.1976 0.2206 0.2453
wC 0.1914 0.1828 0.1734 0.1641 0.1463 0.1311 0.1237 0.1118 0.0998
wA 0.6398 0.6166 0.5936 0.5639 0.5324 0.5066 0.4837 0.4611
wB 0.2726 0.3112 0.3465 0.3886 0.4331 0.4676 0.4961 0.5250
wC 0.0876 0.0722 0.0599 0.0475 0.0345 0.0258 0.0202 0.0139
T/K = 318.15
wA 0.7230 0.7305 0.7411 0.7449 0.7467 0.7422 0.7358 0.7250 0.7153
wB 0.0078 0.0131 0.0213 0.0307 0.0432 0.0623 0.0825 0.1121 0.1375
wC 0.2692 0.2564 0.2376 0.2244 0.2101 0.1955 0.1817 0.1629 0.1472
wA 0.7068 0.6770 0.6653 0.6478 0.6275 0.6087 0.5851 0.5683
wB 0.1562 0.2109 0.2337 0.2636 0.2977 0.3270 0.3607 0.3842
wC 0.1370 0.1121 0.1010 0.0886 0.0748 0.0643 0.0542 0.0475
continued
____________________________________________________________________________________
continued
T/K = 298.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.4709 0.5151 0.0140 0.6340 0.0000 0.3660
0.5251 0.4443 0.0306 0.6699 0.0001 0.3300
0.5623 0.3950 0.0427 0.7098 0.0002 0.2900
0.6024 0.3385 0.0591 0.7241 0.0231 0.2528
________________________________________________________
T/K = 308.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.5009 0.4736 0.0255 0.6453 0.0000 0.3547
0.5260 0.4421 0.0319 0.6622 0.0000 0.3378
0.5495 0.4100 0.0405 0.6832 0.0000 0.3168
0.5768 0.3717 0.0515 0.7000 0.0000 0.3000
________________________________________________________
T/K = 318.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.4515 0.5255 0.0230 0.6400 0.0000 0.3600
0.4664 0.5087 0.0249 0.6553 0.0000 0.3447
0.4906 0.4828 0.0266 0.6675 0.0000 0.3325
0.5146 0.4584 0.0270 0.6798 0.0000 0.3202
0.5590 0.3945 0.0465 0.7233 0.0000 0.2767
________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.8133 0.8219 0.8194 0.8113 0.8069 0.7981 0.7871 0.7738 0.7590
wB 0.0021 0.0150 0.0283 0.0468 0.0562 0.0720 0.0926 0.1163 0.1417
wC 0.1846 0.1631 0.1523 0.1419 0.1369 0.1299 0.1203 0.1099 0.0993
wA 0.7445 0.7287 0.7128 0.6835 0.6477 0.6200 0.5898 0.5657 0.5395
wB 0.1651 0.1894 0.2126 0.2550 0.3022 0.3386 0.3761 0.4057 0.4378
wC 0.0904 0.0819 0.0746 0.0615 0.0501 0.0414 0.0341 0.0286 0.0227
T/K = 308.15
wA 0.8390 0.8380 0.8344 0.8280 0.8169 0.8013 0.7854 0.7681 0.7513
wB 0.0095 0.0159 0.0280 0.0423 0.0628 0.0886 0.1142 0.1414 0.1664
wC 0.1515 0.1461 0.1376 0.1297 0.1203 0.1101 0.1004 0.0905 0.0823
wA 0.7337 0.7184 0.6878 0.6528 0.6181 0.5801 0.5521 0.5372
wB 0.1915 0.2129 0.2545 0.2992 0.3422 0.3882 0.4214 0.4391
wC 0.0748 0.0687 0.0577 0.0480 0.0397 0.0317 0.0265 0.0237
T/K = 318.15
wA 0.8474 0.8512 0.8533 0.8494 0.8390 0.8260 0.8113 0.7954 0.7747
wB 0.0027 0.0052 0.0135 0.0255 0.0456 0.0665 0.0894 0.1131 0.1434
wC 0.1499 0.1436 0.1332 0.1251 0.1154 0.1075 0.0993 0.0915 0.0819
wA 0.7490 0.7304 0.7099 0.6843 0.6619 0.6293 0.5961 0.5590 0.5335
wB 0.1792 0.2028 0.2295 0.2618 0.2902 0.3297 0.3695 0.4123 0.4412
wC 0.0718 0.0668 0.0606 0.0539 0.0479 0.0410 0.0344 0.0287 0.0253
T/K = 298.15
_____________________________________________________________________

wA wB wC wA wB wC
_____________________________________________________________________
0.5700 0.4044 0.0256 0.7400 0.0050 0.2550
0.6096 0.3555 0.0349 0.7609 0.0081 0.2310
0.6565 0.2914 0.0521 0.7920 0.0080 0.2000
0.6830 0.2550 0.0620 0.8072 0.0080 0.1848
_____________________________________________________________________

T/K = 308.15
_____________________________________________________________________

wA wB wC wA wB wC
_____________________________________________________________________
0.4431 0.5360 0.0209 0.7000 0.0000 0.3000
0.5538 0.4214 0.0248 0.7503 0.0024 0.2473
0.5987 0.3630 0.0383 0.7660 0.0070 0.2270
0.6764 0.2678 0.0558 0.8085 0.0146 0.1769
_____________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 318.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.5151 0.4607 0.0242 0.7555 0.0000 0.2445
0.5595 0.4125 0.0280 0.7722 0.0000 0.2278
0.5780 0.3890 0.0330 0.7790 0.0000 0.2210
0.6113 0.3517 0.0370 0.8046 0.0000 0.1954
0.6750 0.2750 0.0500 0.8289 0.0004 0.1707
________________________________________________________

Salt (C): sodium hydrogen sulfate NaHSO4 7681-38-1
T/K = 298.15
wA 0.5325 0.5498 0.5657 0.5792 0.5882 0.5955 0.6016 0.6061 0.6098
wB 0.0091 0.0135 0.0193 0.0277 0.0360 0.0453 0.0590 0.0720 0.0900
wC 0.4584 0.4367 0.4150 0.3931 0.3758 0.3592 0.3394 0.3219 0.3002
wA 0.6125 0.6149 0.6165 0.6179 0.6188 0.6182 0.6164 0.6140 0.6102
wB 0.1056 0.1240 0.1454 0.1588 0.1742 0.2034 0.2199 0.2344 0.2506
wC 0.2819 0.2611 0.2381 0.2233 0.2070 0.1784 0.1637 0.1516 0.1392
wA 0.6027 0.5898 0.5812 0.5722 0.5545 0.5367 0.5214 0.5029 0.4826
wB 0.2763 0.3088 0.3269 0.3439 0.3746 0.4029 0.4237 0.4483 0.4750
wC 0.1210 0.1014 0.0919 0.0839 0.0709 0.0604 0.0549 0.0488 0.0424
T/K = 308.15
wA 0.5462 0.5675 0.5742 0.5792 0.5859 0.5930 0.5964 0.5976 0.5990
wB 0.0197 0.0293 0.0351 0.0412 0.0527 0.0711 0.0826 0.0920 0.1019
wC 0.4341 0.4032 0.3907 0.3796 0.3614 0.3359 0.3210 0.3104 0.2991
wA 0.6014 0.6036 0.6055 0.6070 0.6072 0.6058 0.6037 0.6010 0.5896
wB 0.1155 0.1339 0.1536 0.1743 0.1935 0.2159 0.2332 0.2486 0.2824
wC 0.2831 0.2625 0.2409 0.2187 0.1993 0.1783 0.1631 0.1504 0.1280
wA 0.5866 0.5738 0.5596 0.5370 0.5153 0.4946
wB 0.2952 0.3272 0.3526 0.3916 0.4249 0.4536
wC 0.1182 0.0990 0.0878 0.0714 0.0598 0.0518
T/K = 318.15
wA 0.5474 0.5550 0.5636 0.5679 0.5757 0.5797 0.5817 0.5854 0.5885
wB 0.0226 0.0262 0.0349 0.0397 0.0519 0.0592 0.0696 0.0831 0.1011
wC 0.4300 0.4188 0.4015 0.3924 0.3724 0.3611 0.3487 0.3315 0.3104
continued
____________________________________________________________________________________
continued
wA 0.5907 0.5921 0.5936 0.5943 0.5938 0.5919 0.5858 0.5809 0.5760
wB 0.1231 0.1476 0.1709 0.1904 0.2094 0.2285 0.2602 0.2772 0.2920
wC 0.2862 0.2603 0.2355 0.2153 0.1968 0.1796 0.1540 0.1419 0.1320
wA 0.5699 0.5624 0.5503 0.5428 0.5325 0.5160 0.4979 0.4856 0.4786
wB 0.3091 0.3276 0.3521 0.3670 0.3843 0.4128 0.4388 0.4558 0.4663
wC 0.1210 0.1100 0.0976 0.0902 0.0832 0.0712 0.0633 0.0586 0.0551
Polymer (B): poly(ethylene glycol) 2001GRA

Salt (C): sodium nitrate NaNO3 7631-99-4
T/K = 298.15
wA 0.3689 0.4008 0.4071 0.4167 0.4312 0.4430 0.4543 0.4702 0.4810
wB 0.3788 0.3407 0.3330 0.3199 0.3004 0.2835 0.2653 0.2409 0.2233
wC 0.2523 0.2585 0.2599 0.2634 0.2684 0.2735 0.2804 0.2889 0.2957
wA 0.4888 0.4955 0.4988 0.5168 0.5192 0.5229 0.5287 0.5349 0.5379
wB 0.2096 0.1964 0.1708 0.1532 0.1492 0.1407 0.1295 0.1164 0.1087
wC 0.3016 0.3081 0.3204 0.3300 0.3316 0.3364 0.3418 0.3487 0.3534
wA 0.5440 0.5502 0.5546 0.5582 0.5615 0.5633 0.5520 0.5444 0.5186
wB 0.0963 0.0794 0.0670 0.0562 0.0466 0.0298 0.0137 0.0098 0.0043
wC 0.3597 0.3704 0.3784 0.3856 0.3919 0.4069 0.4343 0.4458 0.4771
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5216 0.1194 0.3590 0.5754 0.0314 0.4032 0.4330 0.2835 0.2735
0.4930 0.1504 0.3566 0.5504 0.0145 0.4351 0.4226 0.3104 0.2670
0.4646 0.1813 0.3541 0.5404 0.0073 0.4523 0.3927 0.3506 0.2567
0.4529 0.1905 0.3566 0.5259 0.0066 0.4675 0.3834 0.3603 0.2563
0.4412 0.1997 0.3591 0.5219 0.0000 0.4781 0.3722 0.3727 0.2551
___________________________________________________________________________________
Comments: Densities and refractive indices are additionally given in the original source.

−1
Characterization: Mw/g.mol = 3500-4500, Merck KGaA, Darmstadt, Germany
continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.3690 0.4015 0.4299 0.4588 0.4745 0.4892 0.5070 0.5229 0.5357
wB 0.3950 0.3630 0.3330 0.3000 0.2790 0.2580 0.2360 0.2130 0.1940
wC 0.2360 0.2355 0.2371 0.2412 0.2465 0.2528 0.2570 0.2641 0.2703
wA 0.5527 0.5665 0.5848 0.5945 0.6082 0.6080 0.6097 0.6129 0.6087
wB 0.1620 0.1410 0.1080 0.0780 0.0550 0.0390 0.0370 0.0230 0.0210
wC 0.2853 0.2925 0.3072 0.3275 0.3368 0.3530 0.3533 0.3641 0.3703
wA 0.6090 0.6111 0.6009 0.5953 0.5868
wB 0.0200 0.0130 0.0080 0.0060 0.0040
wC 0.3710 0.3759 0.3911 0.3987 0.4092
T/K = 298.15
____________________________________________________________________________________
wA wB wC wA wB wC ρ/g cm−3 wA wB wC ρ/g cm−3
____________________________________________________________________________________
0.5507 0.0995 0.3498 0.4660 0.2920 0.2420 1.2288 0.6030 0.0160 0.3810 1.3131
0.5008 0.1990 0.3002 0.4548 0.3060 0.2392 1.2291 0.5911 0.0120 0.3969 1.3186
0.4918 0.1750 0.3332 0.4257 0.3370 0.2373 1.2320 0.5617 0.0050 0.4333 1.3414
0.4587 0.1952 0.3461 0.3822 0.3790 0.2388 1.2381 0.5328 0.0040 0.4632 1.3728
0.4436 0.1874 0.3690 0.3643 0.3950 0.2407 1.2410 0.5229 0.0040 0.4731 1.3850
0.3800 0.2500 0.3700 0.3636 0.3960 0.2404 1.2413 0.5219 0.0020 0.4761 1.3895
____________________________________________________________________________________

T/K = 298.15
wA 0.3534 0.3600 0.3812 0.4279 0.4764 0.5199 0.5445 0.5631 0.5881
wB 0.4161 0.3998 0.3876 0.3383 0.2811 0.2295 0.1916 0.1613 0.1194
wC 0.2305 0.2302 0.2312 0.2338 0.2425 0.2506 0.2639 0.2756 0.2925
wA 0.6138 0.6186 0.6289 0.6288 0.6215 0.6220 0.5912 0.5453 0.5206
wB 0.0718 0.0597 0.0249 0.0205 0.0100 0.0093 0.0028 0.0027 0.0014
wC 0.3144 0.3217 0.3462 0.3507 0.3685 0.3687 0.4060 0.4520 0.4780

T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.5488 0.1359 0.3153 0.6069 0.0038 0.3893 0.4767 0.2815 0.2418
0.5053 0.1663 0.3284 0.5825 0.0007 0.4168 0.4368 0.3306 0.2326
0.4638 0.1959 0.3403 0.5468 0.0004 0.4528 0.3840 0.3859 0.2301
0.4236 0.2221 0.3543 0.5189 0.0000 0.4811 0.3407 0.4288 0.2305
___________________________________________________________________________________

T/K = 298.15
wA 0.3496 0.3962 0.4639 0.4909 0.5126 0.5374 0.5660 0.5872 0.6022
wB 0.4258 0.3764 0.3041 0.2742 0.2477 0.2148 0.1793 0.1492 0.1193
wC 0.2246 0.2274 0.2320 0.2349 0.2397 0.2478 0.2547 0.2636 0.2785
wA 0.6189 0.6354 0.6399 0.6479 0.6509 0.6477 0.6434 0.6354 0.5213
wB 0.0928 0.0651 0.0525 0.0356 0.0188 0.0089 0.0040 0.0020 0.0004
wC 0.2883 0.2995 0.3076 0.3165 0.3303 0.3434 0.3526 0.3626 0.4783
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.5799 0.1200 0.3001 0.6379 0.0042 0.3579 0.5112 0.2507 0.2371
0.5295 0.1599 0.3106 0.6038 0.0011 0.3951 0.4561 0.3173 0.2266
0.4977 0.1794 0.3229 0.5728 0.0000 0.4272 0.4202 0.3563 0.2235
0.4550 0.2094 0.3356 0.5401 0.0000 0.4599 0.3650 0.4108 0.2242
0.4287 0.2218 0.3495 0.5199 0.0000 0.4801 0.3490 0.4251 0.2259
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.776 0.128 0.096 0.689 0.266 0.045 0.811 0.052 0.137
0.770 0.100 0.130 0.633 0.344 0.023 0.815 0.023 0.162
0.750 0.110 0.140 0.625 0.352 0.023 0.803 0.014 0.183
0.730 0.125 0.145 0.613 0.369 0.019 0.789 0.008 0.203
0.710 0.140 0.150 0.567 0.415 0.018 0.778 0.006 0.216
___________________________________________________________________________________

Characterization: Mw/g.mol−1 = 1500, Huels AG, Marl, Germany
T/K = 293.15
___________________________________________________________________________________
wA wB wC pH wA wB wC pH wA wB wC pH
___________________________________________________________________________________
0.6943 0.1976 0.1081 5.8 0.5710 0.4101 0.0189 0.8089 0.0000 0.1911
0.7157 0.1835 0.1008 5.8 0.5967 0.3834 0.0199 5.95 0.8196 0.0000 0.1804 5.75
0.7439 0.1601 0.0960 5.8 0.6425 0.3316 0.0259 0.8349 0.0020 0.1631
0.7601 0.1498 0.0901 5.8 0.6784 0.2889 0.0327 0.8370 0.0178 0.1452
0.7819 0.1312 0.0869 5.8 0.7372 0.2064 0.0564 0.8338 0.0401 0.1261
___________________________________________________________________________________

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7148 0.1830 0.1022 5.2 0.5942 0.3943 0.0115 5.35 0.8189 0.0007 0.1804 5.15
0.7489 0.1611 0.0900 5.2 0.6403 0.3482 0.0115 5.30 0.8378 0.0011 0.1611 5.05
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.7848 0.1354 0.0798 5.2 0.6958 0.2743 0.0299 5.20 0.8485 0.0161 0.1354 5.05
0.8046 0.1180 0.0774 5.2 0.7275 0.2357 0.0368 5.15 0.8424 0.0396 0.1180 5.00
0.6339 0.3246 0.0415 5.8 0.5893 0.4007 0.0100 6.05 0.8152 0.0057 0.1791 5.75
0.7119 0.2034 0.0847 5.8 0.6099 0.3764 0.0137 5.95 0.8296 0.0000 0.1704 5.75
0.7087 0.2084 0.0829 5.8 0.6096 0.3770 0.0134 5.95 0.8309 0.0000 0.1691 5.80
0.7130 0.2016 0.0854 5.8 0.6090 0.3778 0.0132 5.95 0.8149 0.0162 0.1689 5.75
0.7781 0.1004 0.1215 5.8 0.6269 0.3578 0.0153 6.00 0.8144 0.0239 0.1617 5.75
0.7234 0.2002 0.0764 5.8 0.6397 0.3420 0.0183 5.90 0.8244 0.0170 0.1586 5.75
0.7432 0.1832 0.0736 5.8 0.6745 0.3007 0.0248 5.85 0.8460 0.0082 0.1458 5.70
0.7613 0.1653 0.0734 5.8 0.7083 0.2624 0.0293 5.85 0.8428 0.0218 0.1354 5.75
0.7689 0.1660 0.0651 5.8 0.7274 0.2357 0.0369 5.85 0.8446 0.0380 0.1174 5.70
0.7845 0.1538 0.0617 5.8 0.7628 0.1890 0.0482 5.80 0.8226 0.0899 0.0875 5.70
0.7985 0.1424 0.0591 5.8 0.7985 0.1424 0.0591 0.7985 0.1424 0.0591
0.7171 0.1724 0.1105 8.1 0.5835 0.4057 0.0108 7.80 0.8156 0.0011 0.1833 7.95
0.7464 0.1603 0.0933 8.1 0.6388 0.3424 0.0188 7.90 0.8377 0.0041 0.1582 8.05
0.7714 0.1447 0.0839 8.1 0.6920 0.2782 0.0298 8.10 0.8497 0.0108 0.1395 8.15
0.7848 0.1378 0.0774 8.1 0.7257 0.2368 0.0375 8.15 0.8469 0.0335 0.1196 8.20
___________________________________________________________________________________
T/K = 303.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7196 0.1929 0.0875 5.8 0.5990 0.3912 0.0098 0.8377 0.0000 0.1623
0.7435 0.1746 0.0819 5.8 0.6310 0.3552 0.0138 0.8481 0.0079 0.1440
0.7693 0.1543 0.0764 5.8 0.6728 0.3073 0.0199 0.8516 0.0230 0.1254
0.7860 0.1446 0.0694 5.8 0.7233 0.2438 0.0329 0.8459 0.0501 0.1040
0.8001 0.1339 0.0660 5.8 0.7633 0.1903 0.0464 0.8350 0.0796 0.0854
___________________________________________________________________________________
T/K = 313.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7257 0.1832 0.0911 5.8 0.5801 0.4136 0.0063 0.8427 0.0006 0.1567
0.7400 0.1725 0.0875 5.8 0.5926 0.4004 0.0070 5.90 0.8483 0.0030 0.1487 5.75
0.7599 0.1554 0.0847 5.8 0.6192 0.3716 0.0092 0.8561 0.0063 0.1376
0.7715 0.1501 0.0784 5.8 0.6546 0.3335 0.0119 0.8606 0.0117 0.1277
0.7896 0.1382 0.0722 5.8 0.6941 0.2843 0.0216 0.8660 0.0226 0.1114
0.8077 0.1242 0.0681 5.8 0.7401 0.2212 0.0387 0.8589 0.0474 0.0937
___________________________________________________________________________________
____________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.828 0.076 0.097 0.715 0.236 0.049 0.867 0.013 0.121
0.792 0.099 0.109 0.659 0.308 0.033 0.849 0.006 0.146
0.753 0.140 0.108 0.617 0.349 0.034 0.832 0.004 0.164
0.693 0.179 0.129 0.535 0.451 0.014 0.783 0.003 0.215
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 2001TA2

T/K = 298.15
wA 0.7587 0.7773 0.8167 0.8452 0.8740 0.8760 0.8639 0.8606 0.8540
wB 0.0029 0.0038 0.0038 0.0055 0.0068 0.0115 0.0399 0.0516 0.0625
wC 0.2384 0.2189 0.1795 0.1493 0.1192 0.1125 0.0962 0.0878 0.0835
wA 0.8287 0.8234 0.7721 0.7687 0.7182 0.6908 0.6032 0.5763 0.5697
wB 0.1004 0.1083 0.1771 0.1840 0.2479 0.2801 0.3800 0.4098 0.4174
wC 0.0709 0.0683 0.0508 0.0473 0.0339 0.0291 0.0168 0.0139 0.0129
wA 0.5619 0.5584 0.5398 0.4987 0.4912
wB 0.4253 0.4298 0.4491 0.4931 0.5016
wC 0.0128 0.0118 0.0111 0.0082 0.0072
T/K = 298.15
____________________________________________________________________________________
−3
wA wB wC wA wB wC ρ/g cm wA wB wC ρ/g cm−3
___________________________________________________________________________________
0.5844 0.2746 0.1410 0.49166 0.50148 0.00686 1.0937 0.69581 0.00620 0.29799 1.2662
0.6093 0.2923 0.0984 0.53069 0.46044 0.00887 1.0892 0.74784 0.00612 0.24605 1.2293
0.6350 0.2710 0.0940 0.56267 0.42558 0.01178 1.0853 0.78413 0.00588 0.20999 1.2042
0.6736 0.2380 0.0884 0.59496 0.39081 0.01423 1.0816 0.80689 0.00560 0.18751 1.1762
0.7243 0.1940 0.0817 0.64572 0.33378 0.02051 1.0764 0.84054 0.00473 0.15473 1.1436
0.7694 0.1538 0.0768 0.70322 0.26712 0.02966 1.0723 0.86841 0.00348 0.12811 1.1172
____________________________________________________________________________________
____________________________________________________________________________________

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8250 0.1000 0.0750 0.8046 0.1534 0.0420 0.8748 0.0330 0.0922
0.7700 0.1500 0.0800 0.7069 0.2623 0.0308 0.8567 0.0220 0.1213
0.7000 0.2000 0.1000 0.5828 0.3928 0.0244 0.8204 0.0103 0.1693
0.7990 0.0710 0.1300 0.6342 0.3378 0.0280 0.8496 0.0137 0.1367
0.7000 0.1000 0.2000 0.4791 0.5017 0.0192 0.7614 0.0075 0.2311
0.6600 0.1400 0.2000 0.4104 0.5763 0.0133 0.7490 0.0062 0.2448
___________________________________________________________________________________
T/K = 303.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8250 0.1000 0.0750 0.7434 0.2176 0.0390 0.8848 0.0180 0.0972
0.7700 0.1500 0.0800 0.6683 0.3037 0.0280 0.8596 0.0150 0.1254
0.7000 0.2000 0.1000 0.5636 0.4178 0.0186 0.8206 0.0054 0.1740
0.7990 0.0710 0.1300 0.6110 0.3617 0.0240 0.8631 0.0078 0.1391
0.7000 0.1000 0.2000 0.4650 0.5203 0.0147 0.7595 0.0043 0.2362
0.6600 0.1400 0.2000 0.4086 0.5819 0.0098 0.7489 0.0027 0.2484
0.6323 0.1488 0.2189 0.3654 0.6216 0.0130 0.7095 0.0011 0.2894
___________________________________________________________________________________
T/K = 313.15
___________________________________________________________________________________
___________________________________________________________________________________
0.8250 0.1000 0.0750 0.7388 0.2400 0.0212 0.8803 0.0152 0.0972
0.7700 0.1500 0.0800 0.6683 0.3037 0.0280 0.8596 0.0150 0.1554
0.7000 0.2000 0.1000 0.5511 0.4362 0.0127 0.8201 0.0036 0.1763
0.7990 0.0710 0.1300 0.6050 0.3817 0.0132 0.8512 0.0051 0.1437
0.7000 0.1000 0.2000 0.4459 0.5433 0.0108 0.7525 0.0033 0.2444
0.6600 0.1400 0.2000 0.3914 0.6023 0.0063 0.7469 0.0012 0.2519
___________________________________________________________________________________
____________________________________________________________________________________

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7353 0.1779 0.0868 5.8 0.6152 0.3730 0.0118 5.95 0.8452 0.0013 0.1535 5.70
0.7353 0.1832 0.0815 5.8 0.6239 0.3640 0.0121 0.8480 0.0000 0.1520
0.7623 0.1575 0.0802 5.8 0.6602 0.3221 0.0177 0.8597 0.0022 0.1381
0.7787 0.1492 0.0721 5.8 0.6915 0.2853 0.0232 0.8689 0.0067 0.1244
0.8097 0.1160 0.0743 5.8 0.7247 0.2455 0.0298 0.8787 0.0112 0.1101
0.8149 0.1157 0.0694 5.8 0.7518 0.2120 0.0362 0.8783 0.0184 0.1033
0.8207 0.1148 0.0645 5.8 0.7895 0.1613 0.0492 0.8721 0.0372 0.0907
___________________________________________________________________________________

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.803 0.122 0.075 0.761 0.194 0.045 0.858 0.030 0.112
0.789 0.134 0.077 0.729 0.239 0.032 0.863 0.011 0.126
0.761 0.157 0.082 0.678 0.301 0.021 0.848 0.011 0.141
0.740 0.174 0.086 0.647 0.335 0.018 0.832 0.008 0.160
0.715 0.192 0.093 0.624 0.360 0.016 0.819 0.007 0.174
0.690 0.210 0.100 0.584 0.401 0.015 0.808 0.006 0.186
0.677 0.223 0.106 0.528 0.461 0.011 0.800 0.005 0.195
___________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1995SAV

Characterization: Mw/g.mol−1 = 6000, Rukma Chemicals, Bombay, India
continued
____________________________________________________________________________________
continued
T/K = 298.15
______________________________________________________________________________________________________

______________________________________________________________________________________________________
0.8250 0.1000 0.0750 0.7434 0.2176 0.0390 0.8848 0.0180 0.0972
0.7700 0.1500 0.0800 0.6683 0.3037 0.0280 0.8596 0.0150 0.1254
0.7000 0.2000 0.1000 0.5636 0.4178 0.0186 0.8206 0.0054 0.1740
0.7000 0.1000 0.2000 0.4650 0.5203 0.0147 0.7595 0.0043 0.2362
0.6600 0.1400 0.2000 0.4086 0.5819 0.0098 0.7489 0.0027 0.2484
______________________________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1999RAE, 2000RAE

−1 −1
Characterization: Mn/g.mol = 7000, Mw/g.mol = 8400, Clariant, Gendorf, Germany
T/K = 298.15
Comments: pH = 7, prepared by addition of potassium phosphate buffer (10 mmol/l in the feed).
______________________________________________________________________________

wB wC wB wC wB wC
______________________________________________________________________________
0.1446 0.1097 0.4077 0.0165 0.0000 0.1608
0.1268 0.1016 0.3644 0.0191 0.0000 0.1459
0.1085 0.0903 0.3096 0.0238 0.0000 0.1272
0.0906 0.0785 0.2345 0.0317 0.0017 0.1071
0.0900 0.0707 0.1697 0.0456 0.0212 0.0942
______________________________________________________________________________

T/K = 298.15
______________________________________________________________________________________________________

______________________________________________________________________________________________________
0.790 0.130 0.080 0.699 0.258 0.043 0.876 0.005 0.119
0.770 0.100 0.130 0.604 0.365 0.032 0.825 0.014 0.160
0.750 0.110 0.140 0.581 0.387 0.031 0.812 0.011 0.177
0.730 0.125 0.145 0.567 0.404 0.029 0.799 0.011 0.190
0.710 0.140 0.150 0.551 0.417 0.032 0.785 0.012 0.203
______________________________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene oxide) 1984FLO

Characterization: Mw/g.mol−1 = 4000000, Polyox WSR-301, Union Carbide Corp., USA
Salt (C): cesium chloride CsCl 7647-17-8
wB 0.0100 (was kept constant)
cC/mol.kg water−1 0.00 0.10 0.20 0.40 0.60 0.80 1.00 2.00
T/K 369.39 366.74 363.58 358.59 354.15 350.18 346.67 331.24

Salt (C): lithium chloride LiCl 7447-41-8
−1
cC/mol.kg water 0.00 0.40 0.80 1.00 1.20 2.00
T/K 369.39 361.88 356.88 354.83 353.13 347.78
Polymer (B): poly(ethylene oxide) 2001GRU

Polymer Standard Services GmbH, Mainz, Germany
T/K = 298.15
wA 0.603 0.702 0.799 0.779 0.843 0.868 0.875 0.878
wB 0.003 0.002 0.003 0.180 0.081 0.003 0.012 0.031
wC 0.394 0.296 0.198 0.041 0.076 0.129 0.113 0.091
T/K = 323.15
wA 0.611 0.707 0.800 0.899 0.858 0.783 0.904 0.824 0.900
wB 0.011 0.007 0.003 0.003 0.086 0.189 0.031 0.135 0.001
wC 0.378 0.286 0.197 0.098 0.056 0.028 0.065 0.041 0.099
wA 0.800 0.701 0.604 0.890 0.858 0.825 0.898
wB 0.001 0.001 0.002 0.042 0.088 0.133 0.019
wC 0.199 0.298 0.394 0.068 0.054 0.042 0.083
continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.849 0.051 0.100 0.800 0.156 0.044 0.861 0.002 0.137
0.810 0.080 0.110 0.750 0.219 0.031 0.831 0.002 0.167
0.749 0.101 0.150 0.671 0.313 0.016 0.774 0.002 0.224
0.680 0.150 0.170 0.596 0.400 0.004 0.716 0.002 0.282
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.859 0.051 0.090 0.780 0.192 0.028 0.872 0.003 0.125
0.790 0.100 0.110 0.708 0.271 0.021 0.825 0.002 0.173
0.699 0.150 0.151 0.596 0.400 0.004 0.745 0.002 0.253
0.599 0.202 0.199 0.474 0.522 0.004 0.653 0.002 0.345
___________________________________________________________________________________

T/K = 298.15
wA 0.608 0.700 0.800 0.889 0.789 0.867 0.889 0.897 0.836
wB 0.008 0.006 0.008 0.016 0.188 0.083 0.045 0.028 0.128
wC 0.384 0.294 0.192 0.095 0.023 0.050 0.066 0.075 0.036
T/K = 323.15
wA 0.899 0.801 0.702 0.599 0.906 0.879 0.842 0.914 0.914
wB 0.001 0.001 0.001 0.001 0.035 0.078 0.127 0.018 0.002
wC 0.100 0.198 0.297 0.400 0.059 0.043 0.031 0.068 0.084
continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.850 0.050 0.100 0.800 0.176 0.024 0.860 0.009 0.131
0.800 0.080 0.120 0.746 0.238 0.016 0.818 0.008 0.174
0.730 0.120 0.150 0.671 0.323 0.006 0.755 0.006 0.239
0.650 0.150 0.200 0.573 0.420 0.007 0.680 0.006 0.314
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.870 0.050 0.080 0.802 0.174 0.024 0.888 0.002 0.110
0.800 0.100 0.100 0.723 0.264 0.013 0.838 0.002 0.160
0.700 0.150 0.150 0.616 0.378 0.006 0.742 0.002 0.256
0.590 0.230 0.180 0.496 0.501 0.003 0.649 0.002 0.349
___________________________________________________________________________________

T/K = 298.15
wA 0.602 0.703 0.800 0.850 0.849 0.878 0.895 0.868 0.899
wB 0.003 0.003 0.003 0.086 0.002 0.003 0.019 0.057 0.005
wC 0.395 0.294 0.197 0.064 0.149 0.119 0.086 0.075 0.096
T/K = 323.15
wA 0.608 0.706 0.800 0.899 0.863 0.836 0.894 0.914 0.896
wB 0.007 0.007 0.004 0.002 0.091 0.130 0.054 0.022 0.042
wC 0.385 0.287 0.196 0.099 0.046 0.034 0.052 0.064 0.062
continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.850 0.050 0.100 0.825 0.120 0.055 0.866 0.002 0.132
0.750 0.100 0.150 0.677 0.312 0.011 0.779 0.002 0.219
0.680 0.150 0.170 0.597 0.398 0.005 0.719 0.002 0.279
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.860 0.050 0.090 0.788 0.192 0.020 0.879 0.002 0.119
0.790 0.100 0.110 0.703 0.282 0.015 0.829 0.003 0.168
0.699 0.151 0.150 0.575 0.419 0.006 0.754 0.004 0.242
0.739 0.101 0.160 0.627 0.365 0.008 0.778 0.004 0.218
___________________________________________________________________________________

T/K = 298.15
wA 0.607 0.704 0.800 0.862 0.896 0.898 0.905 0.883
wB 0.009 0.009 0.003 0.101 0.041 0.003 0.021 0.080
wC 0.384 0.287 0.197 0.037 0.063 0.099 0.074 0.037
T/K = 323.15
wA 0.593 0.693 0.801 0.891 0.834 0.873 0.612 0.881 0.912
wB 0.004 0.006 0.002 0.003 0.139 0.092 0.002 0.084 0.035
wC 0.403 0.301 0.197 0.106 0.027 0.035 0.386 0.035 0.053
continued
____________________________________________________________________________________
continued
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.849 0.050 0.101 0.800 0.178 0.022 0.860 0.003 0.137
0.800 0.080 0.120 0.746 0.244 0.010 0.820 0.003 0.177
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.870 0.050 0.080 0.807 0.174 0.019 0.889 0.003 0.108
0.800 0.100 0.100 0.729 0.263 0.008 0.835 0.003 0.162
___________________________________________________________________________________

T/K = 298.15
wA 0.751 0.800 0.848 0.794 0.861 0.885 0.873 0.835
wB 0.005 0.006 0.006 0.179 0.076 0.018 0.053 0.112
wC 0.244 0.194 0.146 0.027 0.063 0.097 0.074 0.053
T/K = 323.15
wA 0.750 0.800 0.900 0.838 0.873 0.899 0.909
wB 0.001 0.001 0.001 0.130 0.079 0.038 0.019
wC 0.249 0.199 0.099 0.032 0.048 0.063 0.072
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.810 0.050 0.140 0.797 0.123 0.080 0.809 0.006 0.185
0.756 0.090 0.154 0.744 0.179 0.078 0.757 0.005 0.238
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.838 0.050 0.112 0.799 0.145 0.056 0.854 0.003 0.143
0.770 0.090 0.140 0.723 0.208 0.069 0.794 0.003 0.203
0.716 0.130 0.154 0.671 0.321 0.008 0.746 0.004 0.250
0.637 0.181 0.182 0.588 0.411 0.001 0.679 0.005 0.316
___________________________________________________________________________________

T/K = 298.15
wA 0.595 0.700 0.799 0.801 0.831 0.825 0.803 0.807 0.811
wB 0.002 0.001 0.003 0.155 0.065 0.026 0.011 0.111 0.132
wC 0.403 0.299 0.198 0.044 0.104 0.149 0.186 0.082 0.057
T/K = 323.15
wA 0.601 0.700 0.800 0.817 0.848 0.870 0.877 0.869
wB 0.001 0.001 0.001 0.130 0.083 0.038 0.009 0.002
wC 0.398 0.299 0.199 0.053 0.069 0.092 0.114 0.129
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.800 0.050 0.150 0.794 0.155 0.051 0.793 0.002 0.205
0.750 0.100 0.150 0.754 0.212 0.034 0.739 0.002 0.259
0.680 0.150 0.170 0.691 0.298 0.011 0.659 0.002 0.339
0.600 0.200 0.200 0.613 0.384 0.003 0.569 0.001 0.430
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.820 0.070 0.110 0.825 0.126 0.049 0.845 0.002 0.153
0.666 0.147 0.187 0.675 0.308 0.017 0.674 0.001 0.325
___________________________________________________________________________________
____________________________________________________________________________________

T/K = 298.15
wA 0.752 0.800 0.849 0.890 0.878 0.900 0.877
wB 0.006 0.005 0.005 0.020 0.091 0.040 0.005
wC 0.242 0.195 0.146 0.090 0.031 0.060 0.118
T/K = 323.15
wA 0.802 0.900 0.845 0.876 0.902 0.917
wB 0.001 0.001 0.131 0.081 0.043 0.009
wC 0.197 0.099 0.024 0.043 0.055 0.074
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.810 0.050 0.140 0.793 0.200 0.007 0.809 0.004 0.187
0.757 0.090 0.153 0.741 0.258 0.001 0.762 0.004 0.234
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.838 0.050 0.112 0.811 0.175 0.014 0.850 0.001 0.149
0.800 0.060 0.140 0.753 0.242 0.005 0.818 0.001 0.181
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.599 0.702 0.793 0.866 0.848 0.860 0.870 0.852 0.867
wB 0.001 0.001 0.003 0.034 0.007 0.021 0.044 0.089 0.065
wC 0.400 0.297 0.204 0.100 0.145 0.119 0.086 0.059 0.068
T/K = 323.15
wA 0.610 0.709 0.798 0.822 0.852 0.875 0.887 0.870
wB 0.003 0.005 0.002 0.134 0.083 0.045 0.019 0.001
wC 0.387 0.286 0.200 0.044 0.065 0.080 0.094 0.129
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.800 0.050 0.150 0.794 0.160 0.046 0.792 0.008 0.200
0.770 0.080 0.150 0.775 0.191 0.034 0.762 0.008 0.230
0.829 0.051 0.120 0.826 0.128 0.046 0.826 0.008 0.166
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.819 0.071 0.110 0.794 0.166 0.040 0.830 0.002 0.168
0.680 0.180 0.140 0.652 0.343 0.005 0.696 0.002 0.302
___________________________________________________________________________________

Salt (C): potassium bromide KBr 7758-02-3
−1
cC/mol.kg water 0.00 0.50 1.00 1.50 2.00
T/K 369.39 363.40 357.66 352.35 346.53

Salt (C): potassium chloride KCl 7447-40-7
continued
____________________________________________________________________________________
continued
−1
cC/mol.kg water 0.00 0.10 0.20 0.40 0.60 0.80 1.00 2.00
T/K 369.39 366.07 363.03 357.69 353.06 348.85 345.00 328.70

Salt (C): potassium fluoride KF 7789-23-3
cC/mol.kg water−1 0.00 0.50 1.00 1.50 1.93
T/K 369.39 337.08 312.30 291.53 276.59

−1
Characterization: Mw/g.mol = 4000000, Polyox WSR-301, Union Carbide Corp., USA
Salt (C): potassium iodide KI 7681-11-0
−1
cC/mol.kg water 0.00 0.50 1.00 1.50 2.00
T/K 369.39 370.73 368.90 365.98 360.93

Salt (C): rubidium chloride RbCl 7791-11-9
−1
cC/mol.kg water 0.00 0.10 0.20 0.40 0.60 0.80 1.00 2.00
T/K 369.39 366.07 363.04 357.74 353.14 348.93 345.13 328.79

Salt (C): sodium chloride NaCl 7647-14-5
−1
cC/mol.kg water 0.00 0.10 0.20 0.40 0.60 0.80 1.00 2.00
T/K 369.39 366.45 363.39 358.40 353.95 350.10 346.53 332.09
____________________________________________________________________________________

b-poly(ethylene oxide) triblock copolymer 1997MAT
Characterization: Mw/g.mol−1 = 13000 (2000 PPO block), 80.0 wt% ethylene oxide
Epan 785, Lot 69K004, Daiichi Kogyo Seiyaku Co., Ltd., Japan
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.825 0.091 0.084 0.622 0.359 0.019 0.897 0.0004 0.103
0.783 0.135 0.082 0.610 0.373 0.017 0.881 0.0006 0.118
0.772 0.141 0.087 0.600 0.385 0.015 0.869 0.001 0.130
0.766 0.141 0.093 0.588 0.398 0.014 0.856 0.002 0.142
0.746 0.153 0.101 0.569 0.419 0.012 0.841 0.003 0.156
___________________________________________________________________________________

Salt (C): ammonium bromide NH4Br 12124-97-9
cB/(base mol/g solution) 0.000299 0.000300 0.000300
cC/(mol/g solution) 0.0000532 0.0000994 0.000199
T/K 304.65 304.45 304.15

Salt (C): potassium bromide KBr 7758-02-3
cC/(mol/g solution) 0.000300 0.000498 0.000998
T/K 302.35 300.45 295.55

cC/(mol/g solution) 0.000301 0.000504 0.000997
T/K 300.25 297.45 291.15
____________________________________________________________________________________

Salt (C): potassium iodide KI 7681-11-0
cC/(mol/g solution) 0.000302 0.000506 0.000988
T/K 304.45 303.75 300.65

Salt (C): sodium bromide NaBr 7647-15-6
cC/(mol/g solution) 0.000293 0.000506 0.000983
T/K 302.15 300.45 296.05

cC/(mol/g solution) 0.000301 0.000499 0.001000
T/K 300.25 297.75 290.85
Polymer (B): poly(N-isopropylacrylamide) 2002KUN

Type of data: cloud points (determined by DSC, LCST-behavior)
wB 0.0001 0.0001 0.0001 0.0001 0.0001
wC 0.0000 0.00005 0.0002 0.0005 0.0010
T/K 309.55 309.65 309.65 313.85 324.45

Salt (C): sodium iodide NaI 7681-82-5
cB/(base mol/g solution) 0.000124 0.000125 0.000127 0.000124
cC/(mol/g solution) 0.000151 0.000295 0.000492 0.001000
T/K 304.55 304.55 304.05 301.15
____________________________________________________________________________________

Salt (C): tetrabutylammonium bromide C16H36BrN 1643-19-2
cC/(mol/g solution) 0.0000489 0.0000983 0.000201
T/K 304.85 304.95 304.85

Salt (C): tetraethylammonium bromide C8H20BrN 71-91-0
cC/(mol/g solution) 0.0000571 0.0000962 0.000202
T/K 304.95 305.25 305.75

Salt (C): tetramethylammonium bromide C4H12BrN 64-20-0
cC/(mol/g solution) 0.0000482 0.0000980 0.000201
T/K 304.65 304.65 304.55

Salt (C): tetrapentylammonium bromide C20H44BrN 866-97-7
cB/(base mol/g solution) 0.000299 0.000301
cC/(mol/g solution) 0.0000494 0.0000992
T/K 303.15 300.95

Salt (C): tetrapropylammonium bromide C12H28BrN 1941-30-6
cC/(mol/g solution) 0.0000508 0.0000987 0.000199
T/K 305.05 305.45 305.95
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 1998ZAF

T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.7276 0.2269 0.0455 0.6829 0.2886 0.0285 0.7839 0.1488 0.0673
0.7175 0.2347 0.0478 0.6351 0.3484 0.0165 0.7965 0.1275 0.0760
0.6995 0.2463 0.0542 0.5809 0.4077 0.0114 0.8075 0.1004 0.0921
0.6734 0.2638 0.0628 0.5228 0.4692 0.0080 0.8152 0.0710 0.1138
0.6501 0.2813 0.0686 0.4826 0.5121 0.0053 0.8185 0.0504 0.1311
0.6105 0.3123 0.0772 0.3989 0.5991 0.0020 0.8145 0.0359 0.1496
0.5879 0.3297 0.0824 0.3609 0.6382 0.0009 0.8074 0.0324 0.1602
0.5389 0.3666 0.0945 0.2942 0.7050 0.0008 0.7894 0.0211 0.1895
0.4807 0.4093 0.1100 0.1977 0.8017 0.0006 0.7615 0.0210 0.2175
0.4244 0.4500 0.1256 0.1432 0.8562 0.0006 0.7284 0.0121 0.2595
___________________________________________________________________________________
Polymer (B): poly(propylene glycol) 1994CH1

T/K = 278.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.2320 0.7530 0.0150 0.7500 0.1640 0.0860
0.1900 0.7950 0.0150 0.7640 0.1270 0.1090
0.1660 0.8260 0.0080 0.7730 0.1040 0.1230
0.1540 0.8380 0.0080 0.7710 0.0700 0.1590
0.1520 0.8390 0.0090 0.7660 0.0490 0.1850
0.1460 0.8460 0.0080 0.7550 0.0290 0.2160
0.1290 0.8620 0.0090 0.7390 0.0140 0.2470
________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 298.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.3400 0.6510 0.0090 0.5610 0.4120 0.0270
0.3060 0.6870 0.0070 0.6220 0.3400 0.0380
0.2860 0.7090 0.0050 0.6610 0.2910 0.0480
0.2520 0.7430 0.0050 0.7020 0.2340 0.0640
0.2350 0.7610 0.0040 0.7170 0.2150 0.0680
0.2080 0.7880 0.0040 0.7480 0.1680 0.0840
0.1910 0.8050 0.0040 0.7650 0.1370 0.0980
0.1810 0.8160 0.0030 0.7830 0.1020 0.1150
0.1690 0.8280 0.0030 0.7900 0.0850 0.1250
0.1610 0.8360 0.0030 0.7910 0.0480 0.1610
0.1520 0.8450 0.0030 0.7880 0.0400 0.1720
0.1470 0.8500 0.0030 0.7810 0.0300 0.1890
0.1360 0.8610 0.0030 0.7750 0.0280 0.1970
0.1240 0.8730 0.0030 0.7490 0.0190 0.2320
________________________________________________________
T/K = 333.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.1887 0.8107 0.0006 0.8821 0.0653 0.0526
0.1805 0.8190 0.0005 0.8864 0.0661 0.0475
0.1723 0.8270 0.0007 0.8722 0.0416 0.0862
0.1637 0.8355 0.0008 0.8538 0.0330 0.1132
0.1563 0.8430 0.0007 0.8883 0.0430 0.0687
0.1537 0.8455 0.0008 0.8734 0.0236 0.1030
0.1390 0.8601 0.0009 0.8430 0.0181 0.1389
0.1341 0.8648 0.0011 0.8352 0.0028 0.1620
0.1170 0.8818 0.0012 0.7661 0.0079 0.2260
0.1046 0.8941 0.0013 0.7546 0.0063 0.2391
0.0807 0.9179 0.0014 0.7391 0.0001 0.2608
________________________________________________________
Polymer (B): poly(propylene glycol) 1994CH1

continued
____________________________________________________________________________________
continued
T/K = 278.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.1180 0.8729 0.0091 0.7647 0.2155 0.0198
0.0959 0.8910 0.0131 0.8339 0.1132 0.0529
0.0863 0.9033 0.0104 0.8733 0.0341 0.0926
0.0750 0.9166 0.0084 0.8558 0.0159 0.1283
0.0604 0.9314 0.0082 0.8196 0.0122 0.1682
0.0535 0.9393 0.0072 0.7654 0.0116 0.2230
0.0537 0.9399 0.0064 0.7346 0.0136 0.2518
________________________________________________________
T/K = 298.15
________________________________________________________
wA wB wC wA wB wC
________________________________________________________
0.1234 0.8753 0.0013 0.7994 0.1931 0.0075
0.1225 0.8757 0.0018 0.8117 0.1775 0.0108
0.1149 0.8828 0.0023 0.8577 0.1131 0.0292
0.1150 0.8837 0.0013 0.8457 0.1304 0.0239
0.0829 0.9127 0.0044 0.8938 0.0443 0.0619
0.0738 0.9204 0.0058 0.8805 0.0284 0.0911
0.0575 0.9344 0.0081 0.7503 0.0024 0.2473
________________________________________________________
Polymer (B): poly(styrene sulfonic acid) sodium salt 2002LAA

Characterization: degree of sulfonation DS = 0.85, Mw/g.mol−1 = 70000
T/K = 283.15
wA 0.453 0.458 0.462 0.464 0.466 0.468 0.472 0.472 0.473
wB 0.287 0.267 0.249 0.233 0.219 0.206 0.181 0.159 0.143
wC 0.261 0.275 0.289 0.303 0.314 0.326 0.347 0.368 0.385
wA 0.473 0.471 0.466 0.460 0.450
wB 0.118 0.100 0.076 0.061 0.043
wC 0.410 0.429 0.458 0.479 0.507
continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.435 0.445 0.449 0.452 0.458 0.460 0.457 0.456 0.448
wB 0.291 0.264 0.238 0.217 0.177 0.149 0.112 0.089 0.063
wC 0.274 0.291 0.313 0.330 0.365 0.391 0.431 0.455 0.489
wA 0.438 0.341 0.430 0.461 0.470 0.437
wB 0.048 0.004 0.035 0.084 0.150 0.268
wC 0.514 0.655 0.535 0.455 0.380 0.295
T/K = 343.15
wA 0.449 0.459 0.462 0.466 0.465 0.464 0.463 0.462 0.459
wB 0.297 0.280 0.261 0.245 0.229 0.215 0.186 0.164 0.145
wC 0.254 0.261 0.277 0.289 0.306 0.321 0.351 0.375 0.396
wA 0.456 0.453 0.448 0.440 0.418
wB 0.119 0.101 0.077 0.062 0.043
wC 0.425 0.446 0.475 0.498 0.539
T/K = 298.15
____________________________________________________
Phase I Phase II
wA wB wC wA wB wC
____________________________________________________
0.434 0.027 0.540 0.416 0.335 0.249
0.403 0.011 0.586 0.386 0.350 0.264
0.376 0.007 0.617 0.397 0.377 0.226
0.308 0.004 0.688 0.347 0.442 0.211
0.248 0.002 0.750 0.261 0.525 0.214
____________________________________________________
Polymer (B): poly(styrene sulfonic acid) sodium salt 2002LAA

Characterization: degree of sulfonation DS = 0.85, Mw/g.mol−1 = 70000
T/K = 298.15
wA 0.498 0.517 0.530 0.542 0.547 0.558 0.559 0.556 0.553
wB 0.314 0.288 0.266 0.246 0.227 0.190 0.162 0.140 0.123
wC 0.189 0.195 0.204 0.211 0.225 0.252 0.279 0.305 0.324
wA 0.546 0.539 0.534 0.524 0.506
wB 0.098 0.082 0.070 0.054 0.036
wC 0.355 0.380 0.396 0.422 0.458
____________________________________________________________________________________
Polymer (B): poly(N-vinylacetamide) 1996HON

cC/mol.kg water−1 0.71 0.82
T/K 358.15 307.15
wB = 0.01 and cC/mol.kg water−1 = 0.71
___________________________________________________________________________________
T/ cB/ cC / cB/ cC /
K base mol/kg water mol/kg water base mol/kg water mol/kg water
___________________________________________________________________________________
303.15 0.61 0.56 0.074 0.86
308.15 0.90 0.58 0.071 0.90
313.15 1.02 0.54 0.044 0.90
313.15 1.15 0.56 0.036 0.87
___________________________________________________________________________________
Polymer (B): poly(vinyl alcohol) 1986ALB

Characterization: Polyviol 28/20, Wacker Chemie GmbH, Munich, Germany
T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9722 0.0144 0.0134 0.9730 0.0159 0.0111 0.9716 0.0119 0.0165
0.9619 0.0190 0.0191 0.9656 0.0313 0.0031 0.9582 0.0069 0.0349
0.9523 0.0238 0.0239 0.9566 0.0416 0.0018 0.9479 0.0061 0.0460
0.9428 0.0285 0.0287 0.9473 0.0511 0.0016 0.0381 0.0055 0.0564
0.9238 0.0380 0.0382 0.9282 0.0706 0.0012 0.9187 0.0053 0.0760
___________________________________________________________________________________
____________________________________________________________________________________

T/K = 293.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9754 0.0116 0.0130 0.9753 0.0156 0.0091 0.9727 0.0092 0.0181
0.9698 0.0142 0.0160 0.9727 0.0223 0.0050 0.9671 0.0068 0.0261
0.9622 0.0178 0.0200 0.9647 0.0325 0.0028 0.9573 0.0053 0.0374
0.9546 0.0214 0.0240 0.9580 0.0399 0.0021 0.9497 0.0048 0.0455
0.9471 0.0249 0.0280 0.9511 0.0469 0.0020 0.9430 0.0047 0.0523
___________________________________________________________________________________

T/K = 277.15
___________________________________________________________________________________
___________________________________________________________________________________
0.9789 0.0111 0.0100 0.9808 0.0147 0.0045 0.9779 0.0090 0.0131
0.9703 0.0147 0.0150 0.9719 0.0271 0.0010 0.9692 0.0057 0.0251
0.9604 0.0196 0.0200 0.9617 0.0375 0.0008 0.9593 0.0054 0.0353
0.9506 0.0244 0.0250 0.9519 0.0473 0.0008 0.9494 0.0057 0.0449
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
wB 0.20 0.20 0.20
cC/(mol/l) 0.0 0.5 1.0
T/K 306.75 301.45 296.35

wB 0.005 0.005 0.005 0.005 0.005
cC/(mol/l) 0.0 0.25 0.5 0.75 1.0
T/K 307.85 305.55 303.55 300.85 299.15

Salt (C): see table
wB = 0.005 cC/(mol/l) = 0.5 T/K = 308.95 for salt (C) = KBr (7758-02-3)
wB = 0.005 cC/(mol/l) = 0.5 T/K = 294.55 for salt (C) = KF (7789-23-3)
wB = 0.005 cC/(mol/l) = 0.5 T/K = 318.15 for salt (C) = KI (7681-11-0)
wB = 0.005 cC/(mol/l) = 0.5 T/K = 309.55 for salt (C) = NaBr (7647-15-6)
wB = 0.005 cC/(mol/l) = 0.5 T/K = 304.05 for salt (C) = NaCl (7647-14-5)
wB = 0.005 cC/(mol/l) = 0.5 T/K = 293.45 for salt (C) = NaF (7681-49-4)
wB = 0.005 cC/(mol/l) = 0.5 T/K = 318.55 for salt (C) = NaI (7681-82-5)

wB 0.00010 0.00010 0.00010 0.00010 0.00010
wC 0.00000 0.00005 0.00020 0.00050 0.00100
T/K 315.65 315.25 316.65 323.85 333.65
Comments: The cloud points were determined by DSC.
____________________________________________________________________________________

wB 0.00010 0.00010 0.00010 0.00010 0.00010
wC 0.00000 0.00005 0.00020 0.00050 0.00100
T/K 314.25 313.95 315.05 317.25 323.65

wB 0.00010 0.00010 0.00010 0.00010 0.00010
wC 0.00000 0.00005 0.00020 0.00050 0.00100
T/K 312.85 311.75 311.65 313.35 318.75
Polymer (B): poly(1-vinyl-2-pyrrolidinone) 2001GRU

Kollidon 17 PF, BASF AG, Ludwigshafen, Germany
T/K = 298.15
wA 0.598 0.699 0.799 0.598 0.683 0.745 0.798 0.830 0.775
wB 0.003 0.002 0.001 0.365 0.248 0.145 0.064 0.030 0.101
wC 0.399 0.299 0.200 0.037 0.069 0.110 0.138 0.140 0.124
wA 0.823 0.714 0.773 0.745 0.684 0.796
wB 0.009 0.195 0.100 0.146 0.249 0.066
wC 0.168 0.091 0.127 0.109 0.067 0.138
T/K = 323.15
wA 0.601 0.701 0.800 0.519 0.631 0.799 0.849 0.743 0.699
wB 0.001 0.002 0.002 0.468 0.336 0.086 0.050 0.167 0.243
wC 0.398 0.297 0.198 0.013 0.033 0.115 0.101 0.090 0.058
____________________________________________________________________________________

T/K = 298.15
wA 0.798 0.846 0.731 0.801 0.843 0.571 0.685 0.769 0.627
wB 0.003 0.005 0.207 0.101 0.041 0.415 0.271 0.149 0.347
wC 0.199 0.149 0.062 0.098 0.116 0.014 0.044 0.082 0.026
T/K = 323.15
wA 0.509 0.613 0.727 0.798 0.845 0.851 0.867 0.870 0.825
wB 0.486 0.370 0.222 0.118 0.054 0.001 0.005 0.020 0.084
wC 0.005 0.017 0.051 0.084 0.101 0.148 0.128 0.110 0.091

K30, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
T/K = 298.15
wA 0.598 0.699 0.796 0.599 0.685 0.753 0.808 0.848
wB 0.003 0.002 0.005 0.371 0.258 0.159 0.071 0.002
wC 0.399 0.299 0.199 0.030 0.057 0.088 0.121 0.150
T/K = 323.15
wA 0.623 0.724 0.841 0.604 0.704 0.801 0.792 0.849 0.864
wB 0.352 0.222 0.051 0.003 0.003 0.003 0.125 0.001 0.019
wC 0.025 0.054 0.108 0.393 0.293 0.196 0.083 0.150 0.117

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.596 0.695 0.793 0.811 0.599 0.689 0.753 0.830 0.837
wB 0.007 0.008 0.008 0.098 0.376 0.260 0.162 0.076 0.015
wC 0.397 0.297 0.199 0.091 0.025 0.051 0.085 0.094 0.148

T/K = 298.15
wA 0.797 0.859 0.614 0.720 0.798 0.852 0.845 0.877 0.878
wB 0.004 0.046 0.368 0.236 0.130 0.054 0.006 0.004 0.003
wC 0.199 0.095 0.018 0.044 0.072 0.094 0.149 0.119 0.119

T/K = 298.15
wA 0.596 0.697 0.797 0.502 0.595 0.689 0.762 0.813 0.842
wB 0.007 0.005 0.005 0.491 0.393 0.278 0.165 0.075 0.010
wC 0.397 0.298 0.198 0.007 0.012 0.033 0.073 0.112 0.148
T/K = 323.15
wA 0.501 0.600 0.692 0.766 0.601 0.700 0.800 0.825 0.847
wB 0.494 0.387 0.272 0.166 0.003 0.002 0.002 0.076 0.039
wC 0.005 0.013 0.036 0.068 0.396 0.298 0.198 0.099 0.114

T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.594 0.202 0.204 0.497 0.498 0.005 0.669 0.004 0.327
0.757 0.130 0.113 0.690 0.279 0.031 0.803 0.006 0.191
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.776 0.101 0.123 0.683 0.281 0.036 0.805 0.006 0.189
0.734 0.136 0.130 0.639 0.332 0.029 0.780 0.008 0.212
0.696 0.160 0.144 0.596 0.382 0.022 0.754 0.006 0.240
___________________________________________________________________________________

T/K = 298.15
wA 0.596 0.697 0.799 0.685 0.593 0.760 0.862 0.864 0.846
wB 0.002 0.001 0.002 0.295 0.395 0.190 0.041 0.018 0.004
wC 0.402 0.302 0.199 0.020 0.012 0.050 0.097 0.118 0.150
T/K = 323.15
wA 0.495 0.598 0.705 0.797 0.497 0.598 0.879 0.843 0.683
wB 0.012 0.004 0.005 0.004 0.495 0.399 0.022 0.009 0.293
wC 0.493 0.398 0.290 0.199 0.008 0.003 0.099 0.148 0.024
wA 0.798 0.860 0.825 0.760 0.866 0.876
wB 0.144 0.049 0.102 0.196 0.041 0.006
wC 0.058 0.091 0.073 0.044 0.093 0.118

T/K = 298.15
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________
___________________________________________________________________________________
0.700 0.170 0.130 0.639 0.351 0.010 0.762 0.001 0.237
0.746 0.154 0.100 0.736 0.231 0.033 0.804 0.002 0.194
0.790 0.100 0.110 0.759 0.200 0.041 0.821 0.001 0.178
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.790 0.080 0.130 0.678 0.302 0.020 0.810 0.003 0.187
0.749 0.120 0.131 0.651 0.337 0.012 0.780 0.003 0.217
0.710 0.140 0.150 0.607 0.391 0.002 0.747 0.003 0.250
___________________________________________________________________________________

T/K = 298.15
wA 0.789 0.602 0.761 0.833 0.868 0.603 0.705 0.802 0.852
wB 0.140 0.377 0.179 0.091 0.014 0.001 0.001 0.002 0.002
wC 0.071 0.021 0.060 0.076 0.118 0.396 0.294 0.196 0.146
T/K = 323.15
wA 0.500 0.688 0.776 0.843 0.603 0.702 0.752 0.802 0.870
wB 0.490 0.284 0.176 0.084 0.001 0.001 0.001 0.001 0.001
wC 0.010 0.028 0.048 0.073 0.396 0.297 0.247 0.197 0.129
wA 0.883 0.894 0.599 0.861 0.812 0.735
wB 0.029 0.007 0.395 0.057 0.121 0.224
wC 0.088 0.099 0.006 0.082 0.067 0.041
continued
____________________________________________________________________________________
continued
T/K = 298.15
______________________________________________________________________________________________________

______________________________________________________________________________________________________
0.817 0.090 0.093 0.778 0.163 0.059 0.852 0.001 0.147
0.675 0.171 0.154 0.579 0.409 0.012 0.745 0.002 0.253
______________________________________________________________________________________________________
T/K = 323.15
______________________________________________________________________________________________________

______________________________________________________________________________________________________
0.818 0.080 0.102 0.708 0.260 0.032 0.860 0.002 0.138
0.756 0.121 0.123 0.623 0.354 0.023 0.820 0.002 0.178
______________________________________________________________________________________________________

T/K = 298.15
wA 0.596 0.696 0.800 0.895 0.591 0.687 0.767 0.869 0.862
wB 0.006 0.006 0.000 0.004 0.398 0.295 0.193 0.048 0.064
wC 0.398 0.298 0.200 0.101 0.011 0.018 0.040 0.083 0.074
T/K = 323.15
wA 0.598 0.701 0.793 0.496 0.597 0.775 0.851 0.699 0.912
wB 0.004 0.003 0.006 0.497 0.396 0.191 0.097 0.280 0.008
wC 0.398 0.296 0.201 0.007 0.007 0.034 0.052 0.021 0.080
T/K = 298.15
______________________________________________________________________________________________________

______________________________________________________________________________________________________
0.846 0.051 0.103 0.762 0.200 0.038 0.859 0.002 0.139
0.795 0.095 0.110 0.717 0.260 0.023 0.830 0.001 0.169
0.731 0.149 0.120 0.656 0.328 0.016 0.784 0.002 0.214
0.679 0.150 0.171 0.590 0.395 0.015 0.728 0.001 0.271
______________________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 323.15
______________________________________________________________________________________________________

______________________________________________________________________________________________________
0.869 0.040 0.091 0.796 0.168 0.036 0.877 0.002 0.121
0.840 0.070 0.090 0.767 0.202 0.031 0.860 0.001 0.139
0.800 0.100 0.100 0.708 0.273 0.019 0.836 0.001 0.163
0.750 0.130 0.120 0.654 0.333 0.013 0.795 0.001 0.204
______________________________________________________________________________________________________

T/K = 298.15
wA 0.749 0.602 0.704 0.787 0.825 0.797 0.836 0.803 0.749
wB 0.002 0.392 0.274 0.150 0.050 0.004 0.016 0.100 0.214
wC 0.249 0.006 0.022 0.063 0.125 0.199 0.148 0.097 0.037
T/K = 323.15
wA 0.505 0.606 0.704 0.786 0.834 0.751 0.802 0.849 0.758
wB 0.489 0.385 0.273 0.148 0.057 0.001 0.001 0.026 0.197
wC 0.006 0.009 0.023 0.066 0.109 0.248 0.197 0.125 0.045
T/K = 298.15
______________________________________________________________________________________________________

______________________________________________________________________________________________________
0.749 0.070 0.181 0.737 0.236 0.027 0.754 0.004 0.242
0.633 0.172 0.195 0.625 0.370 0.005 0.657 0.005 0.338
0.559 0.206 0.235 0.544 0.455 0.001 0.588 0.006 0.406
______________________________________________________________________________________________________
T/K = 323.15
______________________________________________________________________________________________________

______________________________________________________________________________________________________
0.762 0.070 0.168 0.725 0.247 0.028 0.762 0.004 0.234
0.732 0.100 0.168 0.691 0.291 0.018 0.740 0.004 0.256
0.702 0.130 0.168 0.659 0.328 0.013 0.716 0.004 0.280
______________________________________________________________________________________________________
____________________________________________________________________________________

T/K = 298.15
wA 0.598 0.698 0.594 0.676 0.738 0.793 0.760 0.803 0.789
wB 0.004 0.003 0.395 0.290 0.185 0.008 0.134 0.018 0.059
wC 0.398 0.299 0.011 0.034 0.077 0.199 0.106 0.179 0.152
T/K = 323.15
wA 0.675 0.742 0.797 0.810 0.817 0.797 0.699 0.597 0.600
wB 0.290 0.185 0.086 0.046 0.016 0.003 0.003 0.005 0.003
wC 0.035 0.073 0.117 0.144 0.167 0.200 0.298 0.398 0.397
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.690 0.140 0.170 0.686 0.284 0.030 0.688 0.004 0.308
0.768 0.081 0.151 0.757 0.140 0.103 0.768 0.006 0.226
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.660 0.161 0.179 0.614 0.375 0.011 0.695 0.002 0.303
0.701 0.120 0.179 0.647 0.311 0.042 0.717 0.002 0.281
0.757 0.101 0.142 0.705 0.254 0.041 0.771 0.002 0.227
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 323.15
wA 0.751 0.800 0.856 0.506 0.607 0.704 0.786 0.831 0.751
wB 0.001 0.001 0.001 0.488 0.381 0.273 0.146 0.056 0.210
wC 0.248 0.199 0.143 0.006 0.012 0.023 0.068 0.113 0.039
T/K = 323.15
______________________________________________________________________________________________________

______________________________________________________________________________________________________
0.748 0.070 0.182 0.685 0.290 0.025 0.757 0.008 0.235
0.717 0.101 0.182 0.650 0.329 0.021 0.730 0.008 0.262
0.668 0.150 0.182 0.618 0.366 0.016 0.698 0.008 0.294
______________________________________________________________________________________________________

T/K = 298.15
wA 0.599 0.697 0.796 0.591 0.679 0.747 0.799 0.837
wB 0.001 0.005 0.002 0.397 0.293 0.187 0.089 0.016
wC 0.400 0.298 0.202 0.012 0.028 0.066 0.112 0.147
T/K = 323.15
wA 0.596 0.799 0.590 0.681 0.750 0.805 0.840 0.831
wB 0.006 0.002 0.395 0.290 0.188 0.101 0.012 0.049
wC 0.398 0.199 0.015 0.029 0.062 0.094 0.148 0.120
T/K = 298.15
______________________________________________________________________________________________________

______________________________________________________________________________________________________
0.787 0.070 0.143 0.765 0.149 0.086 0.793 0.004 0.203
0.728 0.131 0.141 0.711 0.254 0.035 0.748 0.004 0.248
0.640 0.190 0.170 0.630 0.351 0.018 0.653 0.004 0.343
0.567 0.231 0.202 0.562 0.426 0.012 0.578 0.003 0.419
______________________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.810 0.050 0.140 0.761 0.174 0.065 0.811 0.002 0.187
0.780 0.080 0.140 0.735 0.195 0.070 0.788 0.004 0.208
0.747 0.103 0.150 0.704 0.257 0.039 0.759 0.004 0.237
0.720 0.120 0.160 0.679 0.288 0.033 0.735 0.003 0.262
___________________________________________________________________________________

T/K = 298.15
wA 0.694 0.847 0.830 0.503 0.699 0.780 0.837 0.852 0.798
wB 0.008 0.003 0.078 0.490 0.274 0.158 0.069 0.042 0.003
wC 0.298 0.150 0.092 0.007 0.027 0.062 0.094 0.106 0.199
T/K = 323.15
wA 0.694 0.745 0.513 0.604 0.700 0.779 0.844 0.869 0.843
wB 0.009 0.007 0.476 0.379 0.270 0.161 0.072 0.034 0.007
wC 0.297 0.248 0.011 0.017 0.030 0.060 0.084 0.097 0.150
wA 0.861 0.875 0.795 0.815 0.793 0.505 0.602 0.698 0.780
wB 0.032 0.005 0.006 0.107 0.009 0.489 0.387 0.270 0.162
wC 0.107 0.120 0.199 0.078 0.198 0.006 0.011 0.032 0.058
wA 0.842 0.696 0.876 0.873 0.809 0.743 0.813 0.751 0.850
wB 0.071 0.006 0.026 0.008 0.117 0.219 0.114 0.001 0.001
wC 0.087 0.298 0.098 0.119 0.074 0.038 0.073 0.248 0.149
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.696 0.150 0.154 0.622 0.362 0.016 0.744 0.007 0.249
0.645 0.181 0.174 0.567 0.418 0.015 0.707 0.006 0.287
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.796 0.080 0.124 0.702 0.273 0.025 0.822 0.006 0.172
0.746 0.110 0.144 0.650 0.330 0.020 0.789 0.007 0.204
0.706 0.130 0.164 0.610 0.372 0.018 0.759 0.007 0.234
___________________________________________________________________________________

T/K = 298.15
wA 0.695 0.747 0.794 0.845 0.603 0.700 0.780 0.840 0.862
wB 0.007 0.004 0.007 0.006 0.386 0.272 0.160 0.071 0.035
wC 0.298 0.249 0.199 0.149 0.011 0.028 0.060 0.089 0.103
T/K = 323.15
wA 0.502 0.603 0.699 0.847 0.800 0.729 0.870 0.849 0.882
wB 0.493 0.388 0.273 0.073 0.001 0.001 0.037 0.001 0.001
wC 0.005 0.009 0.028 0.080 0.199 0.270 0.093 0.150 0.117
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.744 0.100 0.126 0.700 0.285 0.015 0.798 0.010 0.192
0.717 0.148 0.135 0.644 0.343 0.013 0.757 0.010 0.233
0.642 0.201 0.157 0.566 0.425 0.009 0.697 0.010 0.293
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.785 0.100 0.115 0.689 0.298 0.013 0.803 0.005 0.192
0.746 0.130 0.124 0.654 0.326 0.020 0.773 0.005 0.222
___________________________________________________________________________________
____________________________________________________________________________________

T/K = 298.15
wA 0.762 0.875 0.895 0.869 0.851 0.785 0.697 0.602
wB 0.009 0.004 0.006 0.045 0.075 0.167 0.278 0.387
wC 0.229 0.121 0.099 0.086 0.074 0.048 0.025 0.011
T/K = 323.15
wA 0.790 0.842 0.892 0.604 0.700 0.785 0.855 0.886 0.557
wB 0.011 0.009 0.008 0.379 0.276 0.171 0.078 0.037 0.432
wC 0.199 0.149 0.100 0.017 0.024 0.044 0.067 0.077 0.011
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.795 0.103 0.102 0.724 0.255 0.021 0.843 0.004 0.153
0.655 0.181 0.164 0.575 0.410 0.015 0.720 0.004 0.276
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.856 0.030 0.114 0.729 0.245 0.026 0.868 0.005 0.127
0.827 0.050 0.123 0.709 0.269 0.021 0.849 0.003 0.148
0.797 0.080 0.123 0.682 0.298 0.020 0.820 0.004 0.176
0.767 0.110 0.123 0.658 0.324 0.018 0.800 0.004 0.196
___________________________________________________________________________________

continued
____________________________________________________________________________________
continued
T/K = 298.15
wA 0.696 0.745 0.788 0.843 0.892 0.600 0.697 0.783 0.852
wB 0.006 0.007 0.015 0.009 0.009 0.397 0.287 0.169 0.080
wC 0.298 0.248 0.197 0.148 0.099 0.003 0.016 0.048 0.068
T/K = 323.15
wA 0.699 0.801 0.507 0.602 0.699 0.797 0.865 0.849 0.893
wB 0.001 0.001 0.487 0.389 0.280 0.160 0.069 0.001 0.008
wC 0.300 0.198 0.006 0.009 0.021 0.043 0.066 0.150 0.099
T/K = 298.15
___________________________________________________________________________________
___________________________________________________________________________________
0.775 0.100 0.125 0.688 0.297 0.015 0.803 0.008 0.189
0.696 0.169 0.135 0.616 0.372 0.012 0.742 0.006 0.252
0.613 0.220 0.167 0.529 0.461 0.010 0.672 0.005 0.323
___________________________________________________________________________________
T/K = 323.15
___________________________________________________________________________________
___________________________________________________________________________________
0.814 0.100 0.086 0.730 0.244 0.026 0.848 0.005 0.147
0.774 0.130 0.096 0.687 0.298 0.015 0.818 0.006 0.176
___________________________________________________________________________________

T/K = 323.15
wA 0.698 0.801 0.900 0.866 0.816 0.795 0.849 0.926 0.850
wB 0.001 0.001 0.002 0.027 0.034 0.032 0.004 0.003 0.031
wC 0.301 0.198 0.098 0.107 0.150 0.173 0.147 0.071 0.119
wA 0.786 0.838 0.918 0.883 0.782 0.899
wB 0.032 0.031 0.016 0.023 0.024 0.018
wC 0.182 0.131 0.066 0.094 0.194 0.083
____________________________________________________________________________________
Polymer (B): poly(1-vinyl-2-pyrrolidinone) 2002ZA2

T/K = 293.15
wA 0.5556 0.5936 0.6139 0.6385 0.6525 0.6718 0.6853 0.7030 0.7236
wB 0.3869 0.3300 0.2980 0.2574 0.2358 0.2076 0.1859 0.1588 0.1282
wC 0.0575 0.0764 0.0881 0.1041 0.1117 0.1206 0.1288 0.1382 0.1482
T/K = 298.15
wA 0.5543 0.5715 0.5860 0.6180 0.6270 0.6428 0.6575 0.6733 0.6861
wB 0.3863 0.3609 0.3396 0.2932 0.2785 0.2536 0.2306 0.2068 0.1874
wC 0.0594 0.0676 0.0744 0.0888 0.0945 0.1036 0.1119 0.1199 0.1265
wA 0.6936 0.7043 0.7119 0.7238
wB 0.1758 0.1597 0.1489 0.1317
wC 0.1306 0.1360 0.1392 0.1445
T/K = 303.15
wA 0.5534 0.5678 0.5922 0.6172 0.6410 0.6620 0.7034 0.7160 0.7307
wB 0.3832 0.3631 0.3309 0.2947 0.2592 0.2259 0.1640 0.1461 0.1257
wC 0.0634 0.0691 0.0769 0.0881 0.0998 0.1121 0.1326 0.1379 0.1436
T/K = 293.15
_____________________________________________________________
wA wB wC wA wB wC
_____________________________________________________________
0.4410 0.5260 0.0330 0.6686 0.0447 0.2867
0.4616 0.5002 0.0382 0.6803 0.0432 0.2765
0.4854 0.4696 0.0450 0.6896 0.0447 0.2657
0.5053 0.4452 0.0495 0.7008 0.0464 0.2528
0.5248 0.4222 0.0530 0.7127 0.0449 0.2424
0.5492 0.3890 0.0618 0.7210 0.0468 0.2322
_____________________________________________________________
T/K = 298.15
_____________________________________________________________
wA wB wC wA wB wC
_____________________________________________________________
0.4258 0.5361 0.0381 0.6765 0.0390 0.2845
0.4557 0.5005 0.0438 0.6852 0.0412 0.2736
0.4819 0.4681 0.0500 0.6970 0.0391 0.2639
0.5025 0.4430 0.0545 0.7079 0.0412 0.2509
0.5187 0.4232 0.0581 0.7190 0.0430 0.2380
_____________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 303.15
_____________________________________________________________
wA wB wC wA wB wC
_____________________________________________________________
0.4171 0.5391 0.0438 0.6821 0.0349 0.2830
0.4434 0.5080 0.0486 0.6915 0.0387 0.2698
0.4634 0.4866 0.0500 0.6985 0.0405 0.2610
0.4922 0.4539 0.0539 0.7146 0.0387 0.2467
0.5247 0.4175 0.0578 0.7283 0.0366 0.2351
0.5500 0.3870 0.0630 0.7390 0.0450 0.2160
_____________________________________________________________

Salt (C): cesium chloride CsCl 7647-17-8
wB 0.02 cC/mol.l−1 0.15
T/K 329.85 for a copolymer of 18.0 mol% vinyl acetate

Salt (C): lithium chloride LiCl 7447-41-8
wB 0.02 cC/mol.l−1 0.15

wB 0.02 cC/mol.l−1 0.15
continued
____________________________________________________________________________________
continued

Salt (C): sodium bromide NaBr 7647-15-6
wB 0.02 cC/mol.l−1 0.15

wB 0.02 cC/mol.l−1 0.15

Salt (C): sodium fluoride NaF 7681-49-4
wB 0.02 cC/mol.l−1 0.15
____________________________________________________________________________________

Salt (C): sodium iodide NaI 7681-82-5
wB 0.02 cC/mol.l−1 0.15

wB 0.02 cC/mol.l−1 0.15

Salt (C): sodium thiocyanate NaCNS 540-72-7
wB 0.02 cC/mol.l−1 0.15
____________________________________________________________________________________
3.4. Table of systems where ternary LLE data were published only
in graphical form as phase diagrams or related figures
_____________________________________________________________________________
Polymer (B) Second and third component Ref.
_____________________________________________________________________________
Acrylamide/acrylic acid copolymer calcium chloride and water 1994AXE
_____________________________________________________________________________
Acrylamide/N,N-dihexylacrylamide
copolymer polyacrylamide and water 2000JIM
_____________________________________________________________________________
Alginate calcium chloride and water 1994AXE
copper chloride and water 1994AXE
sodium chloride and water 1994AXE
_____________________________________________________________________________
Agarose dextran and water 1993MED
poly(ethylene glycol) and water 1993MED
_____________________________________________________________________________
Amylopectin amylose and water 1987KAL
dextran and water 1993DUR
_____________________________________________________________________________
Amylose amylopectin and water 1987KAL
dextran and water 1986KAL
_____________________________________________________________________________
Benzoyl dextran dextran and water 1995LUM
poly(ethylene glycol) and water 1994LUM
valeryl dextran and water 1994LUM
_____________________________________________________________________________
Casein gliadin and water 1986POL
globulin and water 1986POL
ovalbumin and water 1986POL
_____________________________________________________________________________
Cellulose dextran and water 2002EDG
_____________________________________________________________________________
Cellulose acetate acetic acid and water 1986AN2
1,4-dioxane and water 1980BRO
1,4-dioxane and water 1986REU
1,4-dioxane and water 1989RON
1,4-dioxane and water 1990BOO
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Cellulose acetate 2-propanone and water 1980LEM
2-propanone and water 1986AN2
2-propanone and water 1986REU
2-propanone and water 1986VSH
2-propanone and water 1987REU
2-propanone and water 1989VSH
2-propanone and water 1990BOO
2-propanone and water 1999BAT
tetrahydrofuran and water 1986REU
tetrahydrofuran and water 1990BOO
_____________________________________________________________________________
Dextran agarose and water 1993MED
amylose and water 1986KAL
benzoyl dextran and water 1995LUM
cellulose and water 2002EDG
ethanol and water 2002LAA
ethylene oxide/propylene oxide copolymer and water 1986ALB
ethylene oxide/propylene oxide copolymer and water 1994ALR
ethylene oxide/propylene oxide copolymer and water 1997PLA
ethylene oxide/propylene oxide copolymer and water 1998PLA
ethylene oxide/propylene oxide copolymer and water 1999BER
ethyl(hydroxyethyl)cellulose and water 1958ALB
ficoll and water 1980ZAS
ficoll and water 1987ZA3
gelatin and water 1970GRI
gelatin and water 1991TOL
gelatin and water 1997VIN
gelatin and water 2001AND
gelatin and water 2001EDE
guar and water 2002SIM
methylcellulose and water 1958ALB
methylcellulose and water 1980POL
methyl(hydroxypropyl)cellulose and water 1984HEF
octa(ethylene oxide) dodecyl ether and water 1996PIC
octyl-β-D-glucopyranoside and water 1996PIC
penta(ethylene oxide) dodecyl ether and water 1996BER
penta(ethylene oxide) dodecyl ether and water 1996PIC
penta(ethylene oxide) dodecyl ether and water 1996SIV
poly(ethylene glycol) and water 1958ALB
poly(ethylene glycol) and water 1968EDM
poly(ethylene glycol) and water 1981SHI
poly(ethylene glycol) and water 1984BAM
poly(ethylene glycol) and water 1984HEF
poly(ethylene glycol) and water 1986GUS
poly(ethylene glycol) and water 1986ZAS
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Dextran poly(ethylene glycol) and water 1987ANA
poly(ethylene glycol) and water 1987BAS
poly(ethylene glycol) and water 1987KAN
poly(ethylene glycol) and water 1987SJO
poly(ethylene glycol) and water 1987ZA3
poly(ethylene glycol) and water 1988ABB
poly(ethylene glycol) and water 1988KAN
poly(ethylene glycol) and water 1988MAK
poly(ethylene glycol) and water 1989HA1
poly(ethylene glycol) and water 1989HA2
poly(ethylene glycol) and water 1990CAB
poly(ethylene glycol) and water 1990RAG
poly(ethylene glycol) and water 1993GA2
poly(ethylene glycol) and water 1993HAR
poly(ethylene glycol) and water 1993HAY
poly(ethylene glycol) and water 1994HAR
poly(ethylene glycol) and water 1995DOE
poly(ethylene glycol) and water 1996CES
poly(ethylene glycol) and water 1997NIL
poly(ethylene glycol) and water 1997SAR
poly(ethylene glycol) and water 2002ZA2
poly(ethylene glycol) monododecyl ether and water 2000SIV
poly(oxyethylene) sorbitan-monolaurate and water 2000SIV
poly(oxyethylene) sorbitan-monooleate and water 2000SIV
poly(N-isopropylacrylamide) and water 1999KIS
poly(vinyl alcohol) and water 1958ALB
poly(vinyl alcohol) and water 1986ZAS
poly(vinyl alcohol) and water 1989ZAS
poly(N-vinylisobutyramide) and water 1999KIS
poly(vinyl methyl ether) and water 1984HEF
poly(1-vinyl-2-pyrrolidinone) and water 1958ALB
poly(1-vinyl-2-pyrrolidinone) and water 1984HEF
poly(1-vinyl-2-pyrrolidinone) and water 1986ZAS
poly(1-vinyl-2-pyrrolidinone) and water 1987ZA3
N-vinylcaprolactam/1-vinylimidazole copolymer and water 1997FRA
_____________________________________________________________________________
Dextran sulfate penta(ethylene oxide) dodecyl ether and water 1996BER
penta(ethylene oxide) dodecyl ether and water 1996SIV
polystyrene sulfonate and water 1991PIC
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-hydro-
xyethyl methacrylate copolymer β-cyclodextrin and water 1998GOS
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Ethylene/vinyl alcohol copolymer dimethylsulfoxide and water 1997YOU
dimethylsulfoxide and water 1999YOU
dimethylsulfoxide and water 2001CHE
2-propanol and water 1998YOU
____________________________________________________________________________________
Ethylene oxide/propylene oxide copolymer acetic acid and water 1993JOH
ammonium acetate and water 1997JO2
ammonium phosphate and water 1987ANA
ammonium sulfate and water 2000LI1
butanoic acid and water 1993JOH
dextran and water 1986ALB
dextran and water 1994ALR
dextran and water 1997PLA
dextran and water 1998PLA
dextran and water 1999BER
dipotassium phosphate and water 1997CUN
ethylene oxide/propylene oxide copolymer
and water 1999PER
glycine and water 1997JO2
hydroxypropyl starch and water 1994MOD
hydroxypropyl starch and water 1997CUN
hydroxypropyl starch and water 2000PE2
octa(ethylene glycol) dodecyl ether and water 1992ZHA
octa(ethylene glycol) dodecyl ether and water 1994ZH1
octa(ethylene glycol) dodecyl ether and water 1994ZH2
phenol and water 1997JO2
poly(ethylene glycol) and water 1994ZH1
poly(propylene glycol) and water 1994ZH1
propanoic acid and water 1993JOH
sodium acetate and water 1997JO2
sodium butyrate and water 1997JO2
sodium chloride and water 2002HUA
sodium perchlorate and water 1997JO1
sodium propionate and water 1997JO2
sodium sulfate and water 1997JO1
tetra(ethylene glycol) dodecyl ether and water 1992ZHA
tetra(ethylene glycol) dodecyl ether and water 1994ZH1
____________________________________________________________________________________
Ethyl(hydroxyethyl)cellulose 1-butanol and water 1990KAR
butanoic acid and water 1997JO2
cetyltrimethylammonium bromide and water 1996GOL
ethanol and water 1990KAR
1-heptanol and water 1990KAR
1-hexanol and water 1990KAR
____________________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Ethyl(hydroxyethyl)cellulose methanol and water 1990KAR
octa(ethylene glycol) dodecyl ether and water 1990KAR
octa(ethylene glycol) dodecyl ether and water 1992ZHA
penta(ethylene glycol) dodecyl ether and water 1990KAR
1-pentanol and water 1990KAR
phenol and water 1997JO2
1-propanol and water 1990KAR
propionic acid and water 1997JO2
salts and water 1986CAR
salts and water 1990KAR
sodium acetate and water 1997JO2
sodium butyrate and water 1997JO2
sodium dodecyl sulfate and water 1990KAR
sodium dodecyl sulfate and water 1997HO1
sodium pentanote and water 1997JO2
sodium propionate and water 1997JO2
tetra(ethylene glycol) dodecyl ether and water 1992ZHA
tetramethylammonium dodecyl sulfate and water 1990KAR
_____________________________________________________________________________
Ficoll dextran and water 1980ZAS
dextran and water 1986ZAS
dextran and water 1987ZA3
_____________________________________________________________________________
Gelatin amylopectin and water 1993DUR
dextran and water 1970GRI
dextran and water 1972GRI
dextran and water 1991TOL
dextran and water 1997VIN
dextran and water 2001AND
dextran and water 2001EDE
maltodextrin and water 2001BUT
maltodextrin and water 2001LOR
methylcellulose and water 1984GRI
methylcellulose and water 1991TOL
pectin and water 1991TOL
_____________________________________________________________________________
Hydroxyethylcellulose poly(ethyleneimine) and water 1993DIS
poly(ethyleneimine) and water 1994DIS
sodium sulfate and water 1982MEE
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Hydroxypropylcellulose hyaluronic acid and water 1995DAV
poly(acrylic acid) and water 2002LUS
1,2,3-propanetriol and water 2001FUJ
1,2,3-propanetriol and water 2002FUJ
_____________________________________________________________________________
Hydroxypropyl starch ethylene oxide/propylene oxide copolymer and water 1994MOD
ethylene oxide/propylene oxide copolymer and water 1997CUN
ethylene oxide/propylene oxide copolymer and water 2000PE2
poly(ethylene glycol) and water 1986MAT
poly(ethylene glycol) and water 1986TJE
poly(ethylene glycol) and water 1989LIN
poly(ethylene glycol) and water 1996CES
poly(ethylene glycol) and water 1998ALM
poly(ethylene glycol) and water 1998BEL
_____________________________________________________________________________
N-Isopropylacrylamide/
1-vinylimidazole copolymer ethylene oxide/propylene oxide copolymer and water 2000PE1
_____________________________________________________________________________
Maltodextrin dextran and water 2001BUT
gelatin and water 2001LOR
poly(ethylene glycol) and water 1988SZL
poly(ethylene glycol) and water 1991RAG
poly(ethylene glycol) and water 1994ATK
poly(ethylene glycol) and water 2000SR1
_____________________________________________________________________________
Methyl(hydroxypropyl)cellulose dextran and water 1984HEF
poly(vinyl alcohol) and water 1993SAK
sodium sulfate and water 1982MEE
_____________________________________________________________________________
Methylcellulose cetyltrimethylammonium bromide and water 1996GOL
dextran and water 1980POL
gelatin and water 1991TOL
_____________________________________________________________________________
Nylon-4,6 formic acid and water 1996BUL
_____________________________________________________________________________
Nylon-4,6/nylon-6 copolymer formic acid and water 1996BUL
_____________________________________________________________________________
Nylon-6 formic acid and water 1994CH2
formic acid and water 1996BUL
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Nylon-6,6 formic acid and water 1994CH2
formic acid and water 1995CH1
_____________________________________________________________________________
Nylon-6,10 formic acid and water 1994CH2
_____________________________________________________________________________
Nylon-6/nylon-6,6/nylon-6,10 formic acid and water 1994CH2
_____________________________________________________________________________
Pectin calcium chloride and water 1994AXE
copper chloride and water 1994AXE
manganese chloride and water 1994AXE
_____________________________________________________________________________
Poly(acrylamide) acrylamide/N,N-dihexylacrylamide copolymer and water 2000JIM
poly(ethylene glycol) and water 1989PER
poly(vinyl alcohol) and water 1982MIN
poly(1-vinyl-2-pyrrolidinone) and water 1989PER
vinyl acetate/vinyl alcohol copolymer and water 1984HEF
_____________________________________________________________________________
Poly(acrylic acid) hydroxypropylcellulose and water 2002LUS
poly(ethylene glycol) and water 2002GUP
sodium chloride and water 1982BUS
_____________________________________________________________________________
Poly(acrylic acid) sodium salt ethanol and water 2002LAA
poly(ethylene glycol) and water 1989PER
poly(styrene sulfonate) and water 1995BE1
poly(vinyl alcohol) and water 1983MIN
poly(1-vinyl-2-pyrrolidinone) and water 1989PER
sodium chloride and water 1982BUS
tetradecyltrimethlyammonium bromide and water 2002NIL
_____________________________________________________________________________
Polyamic acid 1,4-dioxane and water 1985ZHU
tetrahydrofuran and water 1985ZHU
_____________________________________________________________________________
Poly(γ-benzyl-L-glutamate) 1,4-dioxane and water 1990JAC
_____________________________________________________________________________
Poly(N-cyclopropylacrylamide) potassium bromide and water 2001MA1
potassium chloride and water 2001MA1
potassium fluoride and water 2001MA1
potassium iodide and water 2001MA1
sodium chloride and water 2001MA1
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(diallyldimethylammonium)
chloride tetradecyltrimethlyammonium bromide and water 2002NIL
_____________________________________________________________________________
Poly(N,N-diethylacrylamide) ammonium sulfate and water 1999BAL
methanol and water 2002MA2
sodium chloride and water 1999BAL
_____________________________________________________________________________
Polyetherimide N,N-dimethylacetamide and water 1999WAN
N,N-dimethylacetamide and water 2003SHE
N,N-dimethylformamide and water 1999WAN
N,N-dimethylformamide and water 2001ALB
1-methyl-2-pyrrolidinone and water 1991HOU
1-methyl-2-pyrrolidinone and water 1992VIA
1-methyl-2-pyrrolidinone and water 1994BO2
1-methyl-2-pyrrolidinone and water 1999WAN
1-methyl-2-pyrrolidinone and water 2001ALB
1-methyl-2-pyrrolidinone and water 2001FER
_____________________________________________________________________________
Polyethersulfone N,N-dimethylacetamide and water 1988SWI
N,N-dimethylacetamide and water 1991LA1
N,N-dimethylformamide and water 1991LA1
N,N-dimethylformamide and water 2000BA2
dimethylpropyleneurea and water 1991LA1
dimethylsulfoxide and water 1988SWI
dimethylsulfoxide and water 1991LA1
dimethylsulfoxide and water 1999BAT
1-methyl-2-pyrrolidinone and water 1988SWI
1-methyl-2-pyrrolidinone and water 1991LA1
1-methyl-2-pyrrolidinone and water 1994BO2
1-methyl-2-pyrrolidinone and water 1999BAI
tetramethylurea and water 1991LA1
_____________________________________________________________________________
Polyetherurethane N,N-dimethylformamide and water 2001LEE
_____________________________________________________________________________
Poly(ethylene glycol) agarose and water 1993MED
ammonium sulfate and water 1985SHK
ammonium sulfate and water 1988MOL
ammonium sulfate and water 1994EI1
ammonium sulfate and water 1995ROG
ammonium sulfate and water 2000WIL
ammonium sulfate and water 2001LIM
ammonium sulfate and water 2002WIL
2-butoxy-ethanol and water 1980DON
cellobiose and water 1989SJ2
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(ethylene glycol) dextran and water 1958ALB
dextran and water 1968EDM
dextran and water 1981SHI
dextran and water 1984BAM
dextran and water 1984HEF
dextran and water 1986GUS
dextran and water 1987ANA
dextran and water 1987BAS
dextran and water 1987KAN
dextran and water 1987SJO
dextran and water 1988ABB
dextran and water 1988KAN
dextran and water 1988MAK
dextran and water 1989HA1
dextran and water 1989HA2
dextran and water 1990CAB
dextran and water 1990RAG
dextran and water 1993GA2
dextran and water 1993HAR
dextran and water 1993HAY
dextran and water 1994HAR
dextran and water 1995DOE
dextran and water 1996CES
dextran and water 1996PIC
dextran and water 1997SAR
dipotassium phosphate and water 2000MIS
dipotassium phosphate and water 2000RIT
1,2-ethanediol and water 1987LOP
ethylene oxide/propylene oxide copolymer and water 1994ZH1
glucose and water 1989SJ2
hydroxypropyl starch and water 1986MAT
hydroxypropyl starch and water 1986TJE
hydroxypropyl starch and water 1989LIN
hydroxypropyl starch and water 1996CES
hydroxypropyl starch and water 1998ALM
hydroxypropyl starch and water 1998BEL
isomaltose and water 1989SJ2
isomaltotriose and water 1989SJ2
lithium sulfate and water 2002WIL
magnesium sulfate and water 2002WIL
magnesium sulfate heptahydrate and water 1990EIT
maltodextrin and water 1988SZL
maltodextrin and water 1991RAG
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(ethylene glycol) maltodextrin and water 1994ATK
maltodextrin and water 2000SR1
maltose and water 1989SJ2
maltotriose and water 1989SJ2
monosodium phosphate and water 1988MOL
octa(ethylene oxide) dodecyl ether and water 1996PIC
octyl-β-D-glucopyranoside and water 1996PIC
phosphates and water 1995KAU
poly(acrylamide) and water 1984HEF
poly(acrylamide) and water 1989PER
poly(acrylic acid) and water 2002GUP
poly(acrylic acid) sodium salt and water 1989PER
poly(ethylene glycol) monoalkyl ether and water 1995PAN
poly(ethyleneimine) and water 1993DIS
poly(ethyleneimine) and water 2002GUP
poly(propylene glycol) and water 1993MAL
polysaccharides and water 1998CHR
polysaccharides and water 2002OLI
poly(vinyl alcohol) and water 1984INA
poly(vinyl alcohol) and water 1986INA
potassium carbonate and water 1988MOL
potassium carbonate and water 1995ROG
potassium carbonate and water 2002WIL
potassium hydroxide and water 1995ROG
potassium phosphate and water 1958ALB
potassium phosphate and water 1992MOO
potassium phosphate and water 1993KIT
potassium phosphate and water 1995SEB
potassium phosphate and water 1998BEL
potassium phosphate and water 2002WIL
1,2,3-propanetriol and water 1987LOP
1,2,3-propanetriol and water 1988VSH
rubidium hydroxide and water 1995ROG
sodium carbonate and water 1995ROG
sodium chloride and water 1977SAE
sodium hydroxide and water 1995ROG
sodium phosphate and water 1998MER
sodium sulfate and water 1995ROG
sodium sulfate and water 2000SR1
sodium thiosulfate and water 1996JOH
starch and water 1988LAR
starch-graft-polyacrylamide copolymer and water 2000PIE
vinyl acetate/vinyl alcohol copolymer and water 1984HEF
zinc sulfate and water 2002WIL
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(ethylene glycol)
mono(p-nonylphenyl) ether n-hexane and water 2003BAL
_____________________________________________________________________________
Poly(ethyleneimine) hydroxyethylcellulose and water 1993DIS
hydroxyethylcellulose and water 1994DIS
poly(ethylene glycol) and water 1993DIS
poly(ethylene glycol) and water 2002GUP
_____________________________________________________________________________
Poly(ethylene oxide) ammonium chloride and water 1976BOU
ammonium nitrate and water 1976BOU
ammonium sulfate and water 1976BOU
2-butoxyethanol and water 1991WOR
calcium chloride and water 1976BOU
chlorobenzene and water 2002SP1
dichloromethane and water 2002SP1
different salts and water 1959BAI
2,6-dimethylpyridine and water 2002SHR
disodium phosphate and water 1987ATA
isobutyric acid and water 1995TOK
isobutyric acid and water 2002SHR
lithium chloride and water 1976BOU
magnesium chloride and water 1976BOU
magnesium sulfate and water 1976BOU
magnesium thiosulfate and water 1987ATA
potassium carbonate and water 1976BOU
potassium chloride and water 1976BOU
potassium fluoride and water 1982ATA
potassium nitrate and water 1976BOU
potassium phosphate and water 1982ATA
potassium thiosulfate and water 1976BOU
potassium sulfate and water 1976BOU
sodium acetate and water 1982ATA
sodium carbonate and water 1976BOU
sodium chloride and water 1976BOU
sodium dodecyl sulfate and water 1990KAR
sodium nitrate and water 1976BOU
sodium perchlorate and water 1987ATA
sodium thiosulfate and water 1982ATA
strontium chloride and water 1976BOU
tetra(ethylene glycol) octyl ether and water 1991WOR
tetrahydrofuran and water 2001SCH
trichloromethane and water 2002SP1
zinc sulfate and water 1976BOU
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene fumarate)-
b-poly(ethylene oxide) triblock copolymer sodium chloride and water 2002BEH
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene oxide)
diblock copolymer N-methylacetamide and water 1991SA2
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene oxide)-
b-poly(ethylene oxide) triblock copolymer 1-butanol and water 1997HO2
1-butanol and water 2001KWO
dextran and water 1995SVE
ethanol and water 2001KWO
2-phenylethanol and water 2000FRI
potassium phosphate and water 1993KIT
sodium acetate and water 2000LAM
sodium bromide and water 2000LAM
sodium perchlorate and water 2000LAM
sodium sulfate and water 2000LAM
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(tetrahydrofuran)-
b-poly(ethylene oxide) triblock copolymer 1-butanol and water 1997HO2
_____________________________________________________________________________
Poly(ethylene oxide) polyblock copolymer
grafted with alkyl chains sodium chloride and water 2002THU
_____________________________________________________________________________
Poly(ethyl oxazoline) 1,4-dioxane and water 1988LIN
sodium chloride and water 1988LIN
tetrabutylammonium bromide and water 1988LIN
_____________________________________________________________________________
Poly(hydroxystearic acid)-b-poly(ethylene oxide)-
b-poly(hydroxystearic acid) triblock copolymer isopropyl myristate and water 2002PLA
_____________________________________________________________________________
Polyimide N,N-dimethylacetamide and water 2000CHU
N,N-dimethylacetamide and water 2002SHI
N,N-dimethylformamide and water 2001LEB
N,N-dimethylformamide and water 2002SHI
dimethylsulfoxide and water 2001KI2
dimethylsulfoxide and water 2002SHI
1-methyl-2-pyrrolidinone and water 2002SHI
2-propanone and water 2002SHI
tetrahydrofuran and water 2002SHI
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(N-isopropylacrylamide) ammonium sulfate and water 1999BAL
cesium chloride and water 2002FRE
cesium hydroxide and water 2002FRE
dextran and water 1999KIS
N,N-dimethylformamide and water 2002COS
dimethylsulfoxide and water 2002COS
1,4-dioxane and water 1991SC1
ethanol and water 2002COS
lithium chloride and water 2002FRE
lithium hydroxide and water 2002FRE
methanol and water 1990WIN
methanol and water 1991SC1
methanol and water 2002COS
potassium bromide and water 2001MA1
potassium bromide and water 2002FRE
potassium chloride and water 2002FRE
potassium fluoride and water 2002FRE
potassium hydroxide and water 2002FRE
potassium iodide and water 2002FRE
potassium sulfate and water 2002FRE
1-propanol and water 2002COS
2-propanol and water 2002COS
2-propanone and water 2002COS
rubidium chloride and water 2002FRE
rubidium hydroxide and water 2002FRE
sodium bromide and water 2001YA2
sodium butyl sulfate and water 1991SC2
sodium chloride and water 1993PAR
sodium chloride and water 1999BAL
sodium chloride and water 2000MAE
sodium chloride and water 2001YA2
sodium chloride and water 2002FRE
sodium chloride and water 2003BAD
sodium decyl sulfate and water 1991SC2
sodium dodecyl sulfate and water 1991SC2
sodium ethyl sulfate and water 1991SC2
sodium heptyl sulfate and water 1991SC2
sodium hexyl sulfate and water 1991SC2
sodium hydroxide and water 2002FRE
sodium iodide and water 2001YA2
sodium methyl sulfate and water 1991SC2
sodium octyl sulfate and water 1991SC2
sodium pentyl sulfate and water 1991SC2
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(N-isopropylacrylamide) sodium sulfate and water 1991SC2
tetrahydrofuran and water 1991SC1
_____________________________________________________________________________
Poly(DL-lactide) 1,4-dioxane and water 1996WIT
1-methyl-2-pyrrolidone and water 1996WIT
_____________________________________________________________________________
Poly(L-lactide) 1,4-dioxane and water 1996WIT
1,4-dioxane and water 2001HUA
1-methyl-2-pyrrolidone and water 1996WIT
_____________________________________________________________________________
Poly(maleic acid) salts and water 1993KAW
_____________________________________________________________________________
Poly(methacrylic acid) methacrylic acid and water 2002SAX
_____________________________________________________________________________
Poly(methyl methacrylate) 1-butanol and water 1987COW
cyclohexanol and water 2002MAT
ethanol and water 1987COW
methanol and water 1987COW
1-methyl-2-pyrrolidinone and water 2002LIN
1-propanol and water 1987COW
2-propanol and water 1987COW
2-propanol and water 2000CH2
2-propanone and water 1998LAI
tetrahydrofuran and water 2001SCH
_____________________________________________________________________________
Poly(2-methyl-5-vinyltetrazole) perchloric acid and water 2002KIZ
sulfuric acid and water 2002KIZ
_____________________________________________________________________________
Poly(N-propylacrylamide) potassium bromide and water 2001MA1
_____________________________________________________________________________
Poly(propylene glycol) n-alkylpolyglycolether and water 1986FIR
cyclohexane and water 1986FIR
1,3-diethylurea and water 1967SAI
1,3-dimethylurea and water 1967SAI
formamide and water 1967SAI
guanidine hydrochloride and water 1967SAI
n-octane and water 1986FIR
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(propylene glycol) 1-phenylbutane and water 1986FIR
1-phenylheptane and water 1986FIR
1-phenylhexane and water 1986FIR
1-phenyloctane and water 1986FIR
1-phenylpentane and water 1986FIR
poly(ethylene glycol) and water 1993MAL
triton X-100 and water 1996GAL
urea and water 1967SAI
_____________________________________________________________________________
Polysaccharide milk protein and water 1986ZHU
poly(ethylene glycol) and water 1998CHR
poly(ethylene glycol) and water 2002OLI
gelatin and water 1997VIN
decyltrimethlyammonium bromide and water 1991TH1
dodecyltrimethlyammonium bromide and water 1991TH1
octyltrimethlyammonium bromide and water 1991TH1
tetradecyltrimethlyammonium bromide and water 1991TH1
_____________________________________________________________________________
Poly(styrene sulfonate) ethanol and water 2002LAA
dextran sulfate and water 1991PIC
poly(acrylic acid) and water 1995BE1
poly(vinyl sulfuric acid) sodium salt and water 2001NIS
1-propanol and water 2002LAA
sodium dodecyl sulfate and water 1998NIL
tetradecyltrimethlyammonium bromide and water 2002NIL
_____________________________________________________________________________
Polysulfone N,N-dimethylacetamide and water 1985WIJ
N,N-dimethylacetamide and water 1989GAI
N,N-dimethylacetamide and water 1991LA1
N,N-dimethylacetamide and water 1993BOO
N,N-dimethylformamide and water 1980BRO
N,N-dimethylformamide and water 1988SWI
N,N-dimethylformamide and water 2000BA2
1-methyl-2-pyrrolidone and water 1988SWI
1-methyl-2-pyrrolidone and water 1991LA1
1-methyl-2-pyrrolidone and water 1997KIM
1-methyl-2-pyrrolidone and water 1999BAI
tetrahydrofuran and water 1997KIM
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Polysulfone (carboxylated) N,N-dimethylacetamide and water 1991LA2
1-methyl-2-pyrrolidone and water 1991LA2
_____________________________________________________________________________
Polyurethane N,N-dimethylformamide and water 1977KOE
N,N-dimethylformamide and water 1999KIM
_____________________________________________________________________________
Poly(N-vinylacetamide) ammonium sulfate and water 1996HON
cesium sulfate and water 1996HON
lithium sulfate and water 1996HON
sodium sulfate and water 1996HON
_____________________________________________________________________________
Poly(vinyl alcohol) dextran and water 1958ALB
methyl(hydroxypropyl)cellulose and water 1993SAK
poly(acrylamide) and water 1982MIN
poly(acrylic acid) sodium salt and water 1983MIN
poly(ethylene glycol) and water 1984INA
poly(ethylene glycol) and water 1986INA
sodium thiocyanate and water 1996JOH
vinyl acetate/vinyl alcohol copolymer and water 1997PAE
_____________________________________________________________________________
Poly(N-vinylcaprolactam) methanol and water 2002MA1
_____________________________________________________________________________
Poly(vinylidene fluoride) N,N-dimethylacetamide and water 1991BOT
N,N-dimethylformamide and water 1991BOT
N,N-dimethylformamide and water 1999CH1
N,N-dimethylformamide and water 1999CH2
N,N-dimethylformamide and water 1999MAT
dimethylsulfoxide and water 1991BOT
hexamethylphosphotriamide and water 1991BOT
1-methyl-2-pyrrolidone and water 1991BOT
tetramethylurea and water 1991BOT
triethyl phosphate and water 1991BOT
trimethyl phosphate and water 1991BOT
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(N-vinylisobutyramide) dextran and water 1999KIS
_____________________________________________________________________________
Poly(vinyl methyl ether) dextran and water 1984HEF
methanol and water 1991SC1
_____________________________________________________________________________
Poly(1-vinyl-5-aminotetrazole) sulfuric acid and water 2002KIZ
_____________________________________________________________________________
Poly(1-vinyl-5-methyltetrazole) sulfuric acid and water 2002KIZ
_____________________________________________________________________________
Poly(1-vinyl-2-pyrrolidinone) dextran and water 1958ALB
dextran and water 1984HEF
poly(acrylamide) and water 1989PER
poly(acrylic acid) sodium salt and water 1989PER
poly(ethylene glycol) monoalkyl ether and water 1996PAN
poly(ethylene oxide) and water 1998NIL
sodium caprylate and water 2001GAS
_____________________________________________________________________________
Poly(vinyl sulfonic acid) salts potassium bromide and water 1962EIS
potassium chloride and water 1959EIS
potassium chloride and water 1962EIS
rubidium chloride and water 1959EIS
sodium chloride and water 1959EIS
_____________________________________________________________________________
Poly(vinyl sulfuric acid) salt poly(styrene sulfonate) and water 2001NIS
_____________________________________________________________________________
Sulfobetaine polymer lithium chloride and water 1986SCH
poly(2-acrylamido-2-methylpropylsulfonic acid) and water 2000CH1
poly(2-acrylamido-2-methylpropylsulfonic acid) and water 2002CHE
potassium chloride and water 1986SCH
silver nitrate and water 1986SCH
sodium bromide and water 1986SCH
sodium chloride and water 1986SCH
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Sulfobetaine polymer sodium chloride and water 2000CH1
sodium thiocyanate and water 1986SCH
poly(ethylene glycol) and water 2003ASR
tetrabutyl ammonium chloride and water 1986SCH
_____________________________________________________________________________
Tetra(ethylene glycol) ethylene oxide/propylene oxide copolymer and water 1992ZHA
dodecyl ether ethylene oxide/propylene oxide copolymer and water 1994ZH1
ethyl(hydroxyethyl)cellulose and water 1992ZHA
ethyl(hydroxyethyl)cellulose and water 1994ZH1
_____________________________________________________________________________
Tetra(ethylene glycol) poly(ethylene oxide) and water 1991WOR
octyl ether urea and water 1999SHI
_____________________________________________________________________________
Valeryl dextran benzoyl dextran and water 1994LUM
dextran and water 1995LUM
poly(ethylene glycol) and water 1994LUM
_____________________________________________________________________________
Vinyl acetate/vinyl alcohol ammonium salts and water 1969SAI
copolymer ammonium salts and water 1971SAI
1,3-diethylurea and water 1967SAI
1,3-dimethylurea and water 1967SAI
formamide and water 1967SAI
guanidine hydrochloride and water 1967SAI
poly(vinyl alcohol) and water 1997PAE
_____________________________________________________________________________
Vinyl acetate/1-vinyl-2-
pyrrolidone copolymer 1,3-dimethylurea and water 1967SAI
_____________________________________________________________________________
N-Vinylcaprolactam/1-vinyl-
imidazole copolymer dextran and water 1997FRA
starch-graft-polyacrylamide copolymer and water 2000PIE
_____________________________________________________________________________
Xanthan perfluoro copolymer and water 2003KOE
_____________________________________________________________________________
____________________________________________________________________________________
3.5. Cloud-point and/or coexistence curves of quasiquaternary

solutions containing water and at least one polymer
3.5.1. Nonelectrolyte solutions
Polymer (B): polyetherimide 2001ALB

Characterization: Ultem 1000, General Electric, USA
Solvent (D): N,N-dimethylformamide C3H7NO 68-12-2
T/K = 295-297
wA 0.03021 0.02600 0.02404 0.02339 0.02209 0.01738 0.01570 0.01440 0.01205
wB 0.010 0.019 0.039 0.059 0.078 0.010 0.020 0.039 0.059
wC 0.4799 0.4775 0.4685 0.4588 0.4500 0.2432 0.2411 0.2367 0.2322
wD 0.4799 0.4775 0.4685 0.4588 0.4500 0.7295 0.7232 0.7100 0.6967
wA 0.01110 0.01040 0.01295 0.01187 0.01025 0.01099 0.00929 0.00502 0.00420
wB 0.079 0.099 0.010 0.020 0.040 0.059 0.079 0.020 0.040
wC 0.2275 0.2227 0.1954 0.1936 0.1900 0.1860 0.1823 0.1706 0.1673
wD 0.6824 0.6680 0.7816 0.7745 0.7598 0.7440 0.7294 0.8044 0.7885
wA 0.00296 0.00458 0.00413 0.00320 0.00687 0.00569 0.00426 0.00545
wB 0.080 0.020 0.060 0.080 0.010 0.020 0.040 0.060
wC 0.1605 0.1463 0.1404 0.1375 0.0983 0.0974 0.0956 0.0935
wD 0.7566 0.8291 0.7955 0.7793 0.8848 0.8769 0.8602 0.8411
Polymer (B): polyetherimide 1989ROE

−1 3
Characterization: Mw/g.mol = 32800, ρ = 1.27 g/cm
Ultem 1000, General Electric, Bergen op Zoom, Netherlands
Polymer (D): poly(1-vinyl-2-pyrrolidinone)
Characterization: Mw/g.mol−1 = 423000, ρ = 1.22 g/cm3
K-90, Janssen Chimica, Belgium
T/K = 294
wA 0.055 0.053 0.052 0.052 0.048 0.046 0.039 0.035 0.033
wB 0.006 0.009 0.011 0.013 0.019 0.022 0.029 0.035 0.038
wC 0.931 0.929 0.926 0.922 0.914 0.910 0.903 0.895 0.891
wD 0.006 0.009 0.011 0.013 0.019 0.022 0.029 0.035 0.038
continued
____________________________________________________________________________________
continued
wA 0.029 0.028 0.025 0.021 0.016
wB 0.044 0.048 0.056 0.071 0.174
wC 0.883 0.876 0.863 0.837 0.636
wD 0.044 0.048 0.056 0.071 0.174
Polymer (B): poly(ethylene glycol) 1995TIN, 1997TIN

−1 −1
Component (D): L-glutamic acid C5H9NO4 56-86-0
T/K = 293.15
Comments: K2HPO4/KH2PO4 (equimolar) was added as buffer with 0.05 mol/kg (pH scatters around 6.5).
____________________________________________________________________________________
wA wB wC wD wA wB wC wD wA wB wC wD
____________________________________________________________________________________
0.8705 0.0494 0.0705 0.00100 0.9068 0.0788 0.0027 0.00093 0.8198 0.0130 0.1524 0.00099
0.8449 0.0603 0.0853 0.00101 0.8871 0.1015 0.0001 0.00093 0.7826 0.0075 0.1958 0.00104
0.8252 0.0700 0.0953 0.00100 0.8701 0.1190 0.0003 0.00091 0.7581 0.0030 0.2238 0.00100
0.8053 0.0800 0.1052 0.00101 0.8541 0.1360 0.0002 0.00089 0.7297 0.0020 0.2522 0.00102
0.8911 0.0468 0.0563 0.00102 0.9192 0.0675 0.0075 0.00099 0.8582 0.0205 0.1160 0.00105
0.8708 0.0504 0.0731 0.00100 0.9085 0.0825 0.0040 0.00094 0.8244 0.0150 0.1550 0.00103
0.8474 0.0627 0.0824 0.00097 0.8903 0.1020 0.0010 0.00091 0.7861 0.0075 0.1970 0.00102
0.8297 0.0698 0.0947 0.00100 0.8752 0.1190 0.0005 0.00091 0.7649 0.0040 0.2245 0.00100
0.8109 0.0783 0.1048 0.00101 0.8619 0.1325 <0.0001 0.00089 0.7409 0.0025 0.2490 0.00104
____________________________________________________________________________________

−1 −1
Lot E06373013, Hoechst AG, Frankfurt, Germany
T/K = 293.15
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
____________________________________________________________________________________
0.9139 0.0309 0.0450 0.00099 0.9385 0.0500 0.0020 0.00089 0.8851 0.0030 0.1010 0.00093
0.8888 0.0406 0.0597 0.00100 0.9203 0.0690 0.0010 0.00090 0.8481 0.0010 0.1390 0.00086
0.8304 0.0594 0.0998 0.00100 0.8796 0.1120 <0.0001 0.00081 0.7719 <0.0001 0.2160 0.00074
0.7752 0.0854 0.1293 0.00100 0.8405 0.1520 <0.0001 0.00071 0.6950 <0.0001 0.2920 0.00069
0.8899 0.0452 0.0554 0.00100 0.9154 0.0740 0.0005 0.00095 0.8452 0.0002 0.1443
0.8700 0.0503 0.0704 0.00100 0.9032 0.0870 0.0002 0.00092 0.8202 0.0001 0.1667 0.00103
0.8453 0.0601 0.0849 0.00102 0.8847 0.1060 0.0001 0.00091 0.7892 <0.0001 0.1979 0.00103
0.8256 0.0700 0.0949 0.00100 0.8701 0.1220 0.0001 0.00087 0.7660 <0.0001 0.2237 0.00099
0.8059 0.0798 0.1048 0.00100 0.8560 0.1355 0.0005 0.00084 0.7353 <0.0001 0.2509 0.00090
____________________________________________________________________________________

Component (D): glycine C2H5NO2 56-40-6
T/K = 293.15
____________________________________________________________________________________
____________________________________________________________________________________
0.8841 0.0488 0.0571 0.00104 0.9115 0.0710 0.0060 0.00101 0.8449 0.0195 0.1220 0.00111
0.8673 0.0518 0.0706 0.00106 0.9058 0.0808 0.0023 0.00105 0.8183 0.0134 0.1548 0.00117
0.8409 0.0621 0.0873 0.00105 0.8862 0.1035 0.0005 0.00101 0.7812 0.0078 0.1980 0.00117
0.8280 0.0689 0.0937 0.00096 0.8755 0.1163 0.0001 0.00091 0.7761 0.0055 0.2075 0.00109
0.8060 0.0802 0.1038 0.00099 0.8560 0.1354 <0.0001 0.00092 0.7339 0.0020 0.2512 0.00114
____________________________________________________________________________________

−1 −1
continued
____________________________________________________________________________________
continued
T/K = 293.15
____________________________________________________________________________________
____________________________________________________________________________________
0.9301 0.0252 0.0330 0.00100 0.9453 0.0383 0.0051 0.00099 0.9106 0.0039 0.0732 0.00104
0.9181 0.0300 0.0402 0.00100 0.9404 0.0464 0.0023 0.00099 0.8870 0.0024 0.0981 0.00105
0.8733 0.0530 0.0621 0.00100 0.9064 0.0832 0.0004 0.00095 0.8154 0.0006 0.1702 0.00106
0.8274 0.0703 0.0906 0.00100 0.8742 0.1158 0.0003 0.00090 0.7354 0.0003 0.2504 0.00105
____________________________________________________________________________________

Component (D): L-lysine C6H14N2O2 56-87-1
T/K = 293.15
____________________________________________________________________________________
____________________________________________________________________________________
0.8724 0.0497 0.0693 0.00100 0.9134 0.0756 0.0034 0.00090 0.8365 0.0098 0.1447 0.00112
0.8273 0.0697 0.0944 0.00100 0.8689 0.1235 0.0005 0.00081 0.7656 0.0028 0.2213 0.00127
0.8061 0.0808 0.1046 0.00100 0.8564 0.1365 0.0003 0.00077 0.7329 0.0012 0.2562 0.00134
0.8893 0.0455 0.0557 0.00100 0.9078 0.0768 0.0077 0.00089 0.8657 0.0223 0.1026 0.00111
0.8704 0.0497 0.0701 0.00099 0.8846 0.1044 0.0027 0.00085 0.8321 0.0100 0.1468 0.00117
0.8448 0.0599 0.0858 0.00100 0.8898 0.1016 0.0004 0.00081 0.7955 0.0057 0.1884 0.00127
0.8288 0.0691 0.0927 0.00098 0.8531 0.1381 0.0005 0.00076 0.7673 0.0043 0.2177 0.00117
0.8054 0.0793 0.1058 0.00100 0.8296 0.1618 <0.0001 0.00073 0.7395 0.0036 0.2467 0.00122
____________________________________________________________________________________
____________________________________________________________________________________

T/K = 293.15
____________________________________________________________________________________
____________________________________________________________________________________
0.9321 0.0250 0.0334 0.00089 0.9490 0.0367 0.0062 0.00089 0.9191 0.0050 0.0756 0.00101
0.9199 0.0303 0.0403 0.00089 0.9415 0.0475 0.0026 0.00086 0.8908 0.0021 0.0971 0.00101
0.8986 0.0410 0.0510 0.00089 0.9251 0.0659 0.0008 0.00083 0.8625 0.0009 0.1256 0.00105
0.8750 0.0530 0.0625 0.00089 0.9083 0.0831 0.0004 0.00079 0.8276 0.0003 0.1605 0.00110
0.8303 0.0699 0.0904 0.00089 0.8769 0.1153 0.0004 0.00070 0.7746 0.0003 0.2130 0.00118
0.9279 0.0253 0.0328 0.00100 0.9434 0.0390 0.0048 0.00096 0.8907 0.0042 0.0906 0.00109
0.9168 0.0298 0.0397 0.00100 0.9336 0.0515 0.0025 0.00096 0.8892 0.0018 0.0942 0.00111
0.8947 0.0412 0.0505 0.00100 0.9194 0.0675 0.0007 0.00093 0.8510 0.0010 0.1331 0.00117
0.8705 0.0529 0.0629 0.00100 0.9117 0.0757 0.0004 0.00088 0.8225 0.0006 0.1611 0.00125
0.8252 0.0707 0.0903 0.00100 0.8686 0.1195 0.0006 0.00080 0.7670 0.0005 0.2150 0.00137
____________________________________________________________________________________

Component (D): L-phenylalanine C9H11NO2 63-91-2
T/K = 293.15
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
____________________________________________________________________________________
0.8963 0.0440 0.0570 0.00124 0.9224 0.0670 0.0080 0.00121 0.8787 0.0245 0.0940 0.00120
0.8960 0.0451 0.0561 0.00128 0.9193 0.0690 0.0090 0.00128 0.8761 0.0240 0.0970 0.00126
0.8837 0.0478 0.0657 0.00130 0.9135 0.0790 0.0048 0.00132 0.8541 0.0160 0.1270 0.00128
0.8708 0.0552 0.0713 0.00124 0.9036 0.0915 0.0021 0.00130 0.8287 0.0095 0.1590 0.00122
0.8518 0.0670 0.0784 0.00125 0.8904 0.1066 0.0003 0.00130 0.7930 0.0066 0.1976 0.00123
0.8484 0.0697 0.0791 0.00127 0.8853 0.1115 0.0005 0.00130 0.7927 0.0055 0.1990 0.00120
____________________________________________________________________________________

T/K = 293.15
____________________________________________________________________________________
____________________________________________________________________________________
0.9392 0.0249 0.0331 0.00125 0.9522 0.0370 0.0080 0.00129 0.9207 0.0069 0.0696 0.00127
0.9185 0.0311 0.0477 0.00116 0.9443 0.0510 0.0020 0.00118 0.8823 0.0020 0.1130 0.00113
0.8949 0.0430 0.0592 0.00131 0.9266 0.0700 0.0005 0.00136 0.8555 0.0012 0.1405 0.00129
0.8897 0.0445 0.0646 0.00119 0.9217 0.0755 <0.0001 0.00127 0.8398 0.0005 0.1570 0.00118
____________________________________________________________________________________
More data can be found in Refs. 1995TIN and 1997TIN for liquid-liquid equilibrium and
partitioning of amino acids and low molecular peptides in PEG/dextran aqueous two-phase
systems.

continued
____________________________________________________________________________________
continued
Polymer (D): poly(ethylene glycol)
T/K = 293.15
_______________________________________________________________________________________________________

wB wC wD wB wC wD wB wC wD
_______________________________________________________________________________________________________
0.0203 0.0631 0.0675 0.0885 0.0101 0.0237 0.0261 0.1606 0.0161
0.0220 0.0738 0.0732 0.1028 0.0058 0.0272 0.0191 0.1977 0.0155
0.0236 0.0893 0.0785 0.1160 0.0018 0.0290 0.0132 0.2343 0.0154
0.0250 0.1038 0.0831 0.1293 0.0005 0.0321 0.0107 0.2637 0.0156
0.0261 0.1175 0.0869 0.1412 0.0010 0.0352 0.0084 0.2881 0.0157
0.0270 0.1324 0.0898 0.1527 0.0008 0.0369 0.0069 0.3102 0.0153
_______________________________________________________________________________________________________
0.0370 0.1492 0.0110 0.0173 0.0067 0.0969 0.0114 0.1766 0.0234
0.0306 0.1777 0.0091 0.0160 0.0038 0.1058 0.0101 0.1980 0.0191
0.0265 0.2228 0.0079 0.0170 0.0011 0.1282 0.0078 0.2463 0.0117
0.0252 0.2518 0.0075 0.0173 0.0025 0.1470 0.0079 0.2791 0.0084
_______________________________________________________________________________________________________
0.0818 0.0220 0.0244 0.0271 0.0068 0.0858 0.0189 0.1567 0.0251
0.0940 0.0191 0.0281 0.0301 0.0031 0.0996 0.0184 0.1894 0.0207
0.1133 0.0160 0.0338 0.0355 0.0013 0.1180 0.0192 0.2471 0.0103
0.1184 0.0133 0.0354 0.0368 0.0009 0.1222 0.0192 0.2509 0.0105
0.1291 0.0121 0.0386 0.0398 0.0003 0.1323 0.0200 0.2667 0.0089
_______________________________________________________________________________________________________
0.0416 0.0781 0.0488 0.0551 0.0334 0.0574 0.0460 0.1016 0.0333
0.0438 0.0908 0.0515 0.0635 0.0125 0.0716 0.0373 0.1549 0.0270
0.0516 0.1053 0.0605 0.0785 0.0036 0.0885 0.0296 0.2189 0.0214
0.0360 0.1065 0.0423 0.0747 0.0009 0.1169 0.0241 0.2803 0.0174
_______________________________________________________________________________________________________

___________________________________________________________________________________

PEG dextran PEG dextran
___________________________________________________________________________________
1549 2411 59841 115909 1090 1955 123630 511782
1369 2372 50205 134610 937 1775 115613 471896
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
___________________________________________________________________________________

PEG dextran PEG dextran
−1 −1 −1
−1 −1 −1
___________________________________________________________________________________
1469 2414 34081 139665 826 1550 112915 477048
1487 2414 34189 39976 774 1440 111116 480602
1460 2409 37775 68868 667 1309 109415 468984
1502 2423 66268 123180 683 1228 108017 460696
___________________________________________________________________________________
1797 2561 47576 67225 1183 2063 109187 471143

1901 2609 41064 57452 1214 2072 110979 478258
1977 2630 37856 59561 1089 1906 110594 473940
2063 2694 23308 32140 984 1756 110429 478511
___________________________________________________________________________________
1487 2350 62046 91881 1057 1880 156789 619956

1482 2354 47534 67142 991 1782 138075 542165
1503 2379 38062 56423 783 1351 122639 484896
1490 2364 41095 55018 764 1351 122098 503323
1484 2356 35051 39940 794 1273 117152 492948
___________________________________________________________________________________
906 1653 71440 140824 809 1463 111000 479326

936 1712 49253 75268 733 1267 105901 441200
935 1703 35478 41990 640 993 101988 416771
1068 1886 28927 36634 621 953 99362 428621
___________________________________________________________________________________
Comments: The mixture of PEG600 + PEG3000 was made to get Mn = 1480 g/mol and Mw = 2365 g/mol
for subsystems 1-3, and Mn = 862 g/mol and Mw = 1560 g/mol for subsystem 4.

T/K = 298.15
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
____________________________________________________________________________________
0.8650 0.0500 0.0700 0.0150 0.8943 0.0860 0.0000 0.0197 0.8065 0.0038 0.1780 0.0117
0.8650 0.0500 0.0700 0.0150 0.8955 0.0860 0.0005 0.0180 0.8418 0.0038 0.1430 0.0114
0.8430 0.0580 0.0840 0.0150 0.8939 0.0987 0.0004 0.0070 0.7834 0.0007 0.2077 0.0082
0.8580 0.0430 0.0840 0.0150 0.9017 0.0807 0.0000 0.0176 0.8088 0.0015 0.1799 0.0098
0.8790 0.0440 0.0620 0.0150 0.9133 0.0696 0.0004 0.0167 0.8242 0.0028 0.1648 0.0082
0.8940 0.0290 0.0620 0.0150 0.9297 0.0520 0.0000 0.0183 0.8763 0.0070 0.1044 0.0123
0.8640 0.0440 0.0620 0.0300 0.9000 0.0650 0.00001 0.0350 0.8109 0.0023 0.1650 0.0218
0.8850 0.0500 0.0500 0.0150 0.9141 0.0700 0.0000 0.0159 0.8249 0.0031 0.1620 0.0100
0.9000 0.0350 0.0500 0.0150 0.9251 0.0560 0.0015 0.0174 0.8622 0.0076 0.1188 0.0114
0.8850 0.0600 0.0400 0.0150 0.9066 0.0780 0.0000 0.0154 0.8252 0.0035 0.1630 0.0083
0.9000 0.0450 0.0400 0.0150 0.9215 0.0627 0.0010 0.0148 0.8471 0.0067 0.1366 0.0096
0.8700 0.0600 0.0400 0.0300 0.8832 0.0782 0.0000 0.0386 0.7968 0.0015 0.1830 0.0187
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1989KAN

Polymer (E): poly(ethylene glycol)
T/K = 293.15
Comments: The ratio of PEG/dextran in the total system was kept constant at 4.2 wt% : 4.2 wt% = 1:1.
____________________________________________________________________________________
wB wC wD wE wB wC wD wE wB wC wD wE
____________________________________________________________________________________
0.0126 0.0420 0.0084 0.0210 0.0144 0.0080 0.0132 0.0341 0.0112 0.0800 0.0072 0.0039
0.0000 0.0420 0.0084 0.0336 0.0000 0.0017 0.0140 0.0504 0.0000 0.1080 0.0060 0.0040
0.0063 0.0420 0.0063 0.0294 0.0069 0.00313 0.0097 0.0457 0.0051 0.1020 0.0043 0.0000
0.0000 0.0420 0.0063 0.0357 0.0000 0.0000 0.0100 0.0543 0.0000 0.1183 0.0037 0.0000
____________________________________________________________________________________
____________________________________________________________________________________

Characterization: Mn/g.mol−1 = 1100, Mw/g.mol−1 = 1320, Clariant, Gendorf, Germany
Dextran T-500, Pharmacia-Biotech, Freiburg, Germany
T/K = 298.15
Comments: pH = 7, prepared by addition of potassium phosphate buffer (10 mmol/L in the feed).
The urea partition coefficient scattered around 1.
_____________________________________________________________________________
wB wC wD wB wC wB wC
_____________________________________________________________________________
0.1906 0.1241 0.200 0.2731 0.0000 0.0606 0.3340
0.1702 0.1236 0.199 0.2504 0.0005 0.0884 0.2480
0.1812 0.1083 0.199 0.2490 0.0002 0.0766 0.2859
0.1619 0.1134 0.199 0.2305 0.0035 0.1044 0.2152
0.1703 0.0927 0.201 0.2296 0.0038 0.0996 0.2231
0.1602 0.1027 0.199 0.2137 0.0081 0.1151 0.1859
0.1589 0.0919 0.200 0.1960 0.0182 0.1276 0.1474
0.1512 0.1030 0.200 0.1889 0.0243 0.1314 0.1329
_____________________________________________________________________________

T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.0989 0.1177 0.200 0.1652 0.0000 0.0198 0.2576
0.1022 0.0972 0.201 0.1541 0.0000 0.0220 0.2398
_____________________________________________________________________________
continued
____________________________________________________________________________________
continued
_____________________________________________________________________________
_____________________________________________________________________________
0.0988 0.0904 0.200 0.1498 0.0000 0.0244 0.2280
0.0991 0.0801 0.200 0.1418 0.0003 0.0267 0.2115
0.0990 0.0612 0.201 0.1326 0.0010 0.0325 0.1860
0.0812 0.0783 0.201 0.1215 0.0041 0.0400 0.1538
0.0701 0.0905 0.199 0.1151 0.0074 0.0467 0.1324
0.0813 0.0590 0.200 0.1060 0.0140 0.0529 0.1129
0.1085 0.1376 0.300 0.1891 0.0000 0.0199 0.2877
0.0993 0.1298 0.300 0.1753 0.0000 0.0247 0.2548
0.1004 0.1174 0.301 0.1692 0.0007 0.0270 0.2390
0.0955 0.1079 0.300 0.1552 0.0002 0.0314 0.2193
0.0895 0.1095 0.299 0.1498 0.0005 0.0345 0.1993
0.0902 0.0977 0.302 0.1435 0.0005 0.0379 0.1885
0.0902 0.0783 0.300 0.1318 0.0049 0.0477 0.1544
0.0792 0.0897 0.299 0.1216 0.0092 0.0525 0.1338
0.0799 0.0792 0.301 0.1090 0.0229 0.0643 0.1044
0.0993 0.0991 0.349 0.1545 0.0006 0.0375 0.2063
0.1002 0.0886 0.350 0.1491 0.0012 0.0407 0.1926
0.0989 0.0791 0.351 0.1409 0.0036 0.0444 0.1719
0.0814 0.0982 0.350 0.1330 0.0063 0.0554 0.1428
0.0796 0.0883 0.351 0.1186 0.0159 0.0670 0.1106
_____________________________________________________________________________

T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.0870 0.1420 0.202 0.1551 0.0000 0.0060 0.2928
0.0967 0.1526 0.201 0.1800 0.0000 0.0053 0.3065
0.0775 0.1340 0.200 0.1464 0.0000 0.0082 0.2747
_____________________________________________________________________________
continued
____________________________________________________________________________________
continued
_____________________________________________________________________________
_____________________________________________________________________________
0.0722 0.1212 0.208 0.1317 0.0000 0.0087 0.2470
0.0676 0.1127 0.201 0.1245 0.0000 0.0086 0.2260
0.0593 0.0819 0.199 0.1002 0.0005 0.0143 0.1715
0.0533 0.0718 0.200 0.0917 0.0033 0.0201 0.1456
0.0499 0.0612 0.198 0.0767 0.0097 0.0241 0.1147
0.0479 0.0661 0.202 0.0783 0.0168 0.0314 0.0938
0.0793 0.1599 0.301 0.1707 0.0007 0.0072 0.3044
0.0768 0.1347 0.301 0.1418 0.0014 0.0119 0.2560
0.0697 0.1391 0.300 0.1411 0.0007 0.0093 0.2692
0.0668 0.1185 0.302 0.1246 0.0008 0.0115 0.2308
0.0575 0.0969 0.300 0.1092 0.0022 0.0186 0.1733
0.0482 0.0878 0.299 0.0846 0.0079 0.0330 0.1251
0.0500 0.0753 0.300 0.0790 0.0159 0.0395 0.0983
0.0797 0.1374 0.353 0.1621 0.0007 0.0088 0.2683
0.0819 0.1200 0.352 0.1491 0.0007 0.0103 0.2511
0.0699 0.1093 0.352 0.1316 0.0007 0.0132 0.2187
0.0703 0.0937 0.350 0.1193 0.0010 0.0192 0.1989
0.0666 0.0997 0.350 0.1178 0.0010 0.0175 0.1978
0.0607 0.0920 0.352 0.1097 0.0027 0.0259 0.1696
0.0574 0.0809 0.353 0.0916 0.0057 0.0342 0.1372
0.0582 0.0720 0.351 0.0866 0.0094 0.0379 0.1213
_____________________________________________________________________________

Cat. No. 807490-1000, Merck KGaA, Darmstadt, Germany
Cat. No. 20,245-2, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
Comments: The composition of the PEG mixture is kept constant at wB/wC/wD = 0.389/0.513/0.098.
The corresponding molar mass distribution averages are given by Mn = 5000 g/mol,
Mw = 6000 g/mol, and Mz = 7080 g/mol.
wB+ wC+ wD 0.0105 0.0249 0.0531 0.1077 0.1489 0.2198 0.3012 0.3402
T/K 410.45 407.55 405.35 403.55 402.55 404.85 410.65 416.95
T/K 524.65 543.45 546.65 544.45 544.15 539.45 536.55 534.15
wB+ wC+ wD 0.3914
T/K 408.35
T/K 528.15
____________________________________________________________________________________

Comments: The composition of the PEG mixture is kept constant at wB/wC/wD = 0.524/0.197/0.279.
The corresponding molar mass distribution averages are given by Mn = 3750 g/mol,
Mw = 6000 g/mol, and Mz = 9960 g/mol.
wB+ wC+ wD 0.0106 0.0246 0.0528 0.0986 0.1440 0.1909 0.2954 0.3405
T/K 402.65 401.05 399.85 401.05 402.05 404.35 409.05 414.55
T/K 536.35 549.45 557.35 552.65 545.55 541.85 531.55 528.85
wB+ wC+ wD 0.3825
T/K 418.55
T/K 523.15

Polymer (E): poly(ethylene glycol)
Comments: The composition of the PEG mixture is kept constant at wB/wC/wD/wE = 0.245/0.331/
0.264/0.160. The corresponding molar mass distribution averages are given by
Mn = 4285 g/mol, Mw = 6000 g/mol, and Mz = 8580 g/mol.
wB+ wC+ wD+ wE 0.0101 0.0251 0.0511 0.0972 0.1320 0.2025 0.3011 0.3361
T/K 406.65 401.45 400.95 402.85 405.25 406.15 409.15 411.15
T/K 533.45 549.15 551.85 549.35 544.65 541.15 533.85 532.65
continued
____________________________________________________________________________________
continued
wB+ wC+ wD+ wE 0.3818
T/K 417.05
T/K 527.15
Comments: The composition of the PEG mixture is kept constant at wB/wC/wD/wE = 0.158/0.584/
0.058/0.200. The corresponding molar mass distribution averages are given by
Mn = 4285 g/mol, Mw = 6000 g/mol, and Mz = 8880 g/mol.
wB+ wC+ wD+ wE 0.0114 0.0245 0.0492 0.0965 0.1487 0.2468 0.2985 0.3485
T/K 407.75 403.15 400.45 401.65 403.55 406.35 408.25 414.75
T/K 531.55 537.45 553.05 550.15 545.15 538.35 534.75 531.05
wB+ wC+ wD+ wE 0.4067
T/K 421.65
T/K 523.55
Polymer (B): polysulfone 2002HAN

−1
Characterization: Mw/g.mol = 30000, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
Polymer (D): poly(1-vinyl-2-pyrrolidinone)

T/K = 298.15
wA 0.000 0.048 0.097
wB 0.141 0.144 0.145
wC 0.798 0.771 0.726
wD 0.061 0.037 0.032
____________________________________________________________________________________
3.5.2. Electrolyte solutions
Polymer (B): poly(ethylene glycol) 1989NIF

Salt (D): ammonium thiocyanate NH4SCN 1762-95-4
Component (E): sulfuric acid H2SO4 7664-93-9
T/K = 293.15
____________________________________________________________________________________
−3
wA wB wC wD wE ρ/g cm wA wB wC wD wE ρ/g cm−3
____________________________________________________________________________________
0.525 0.332 0.117 0.004 0.022 1.120 0.751 0.000 0.051 0.098 0.100 1.142
0.389 0.471 0.113 0.008 0.019 1.121 0.720 0.000 0.076 0.112 0.092 1.152
0.373 0.488 0.109 0.012 0.018 1.122 0.700 0.000 0.090 0.125 0.085 1.161
0.348 0.515 0.106 0.016 0.017 1.131 0.667 0.000 0.108 0.146 0.079 1.171
0.320 0.530 0.113 0.020 0.016 1.131 0.630 0.000 0.124 0.173 0.073 1.171
0.314 0.547 0.103 0.020 0.016 1.133 0.621 0.000 0.133 0.172 0.014 1.178
0.310 0.540 0.113 0.023 0.014 1.134 0.605 0.000 0.139 0.185 0.071 1.183
0.288 0.571 0.101 0.028 0.014 1.135 0.582 0.000 0.159 0.193 0.066 1.198
0.282 0.588 0.085 0.032 0.014 0.525 0.000 0.195 0.219 0.060 1.203
0.275 0.593 0.083 0.037 0.012 0.477 0.000 0.223 0.245 0.055 1.225
____________________________________________________________________________________

Salt (D): potassium chloride KCl 7447-40-7
T/K = 296-298
Comments: The feed system without salt consists of 12.8 wt% dextran, 8.0 wt% poly(ethylene glycol), and
79.8 wt% water.
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
cD/mol.kg−1 wA wB wC wD wA wB wC wD
____________________________________________________________________________________
0.00 0.8461 0.1495 0.0044 0.0000 0.7349 0.0057 0.2594 0.0000
0.10 0.8397 0.1511 0.0044 0.0048 0.7281 0.0013 0.2604 0.0102
0.50 0.8062 0.1583 0.0034 0.0321 0.7086 0.0011 0.2506 0.0397
1.00 0.7728 0.1663 0.0029 0.0580 0.6818 0.0006 0.2376 0.0800
____________________________________________________________________________________

−1
Characterization: Mn/g.mol = 6000, Lot 419-80, Serva, Heidelberg, Germany
Salt (D): potassium sulfate K2SO4 7778-01-9
T/K = 296-298
79.8 wt% water.
____________________________________________________________________________________
____________________________________________________________________________________
0.00 0.8461 0.1495 0.0044 0.0000 0.7349 0.0057 0.2594 0.0000
0.10 0.8372 0.1530 0.0042 0.0056 0.7302 0.0062 0.2518 0.0118
0.50 0.8284 0.1537 0.0030 0.0149 0.7307 0.0028 0.2466 0.0199
1.00 0.7877 0.1770 0.0003 0.0350 0.7085 0.0010 0.2405 0.0500
____________________________________________________________________________________

Salt (D): potassium thiocyanate KSCN 333-20-0
T/K = 296-298
continued
____________________________________________________________________________________
continued
79.8 wt% water.
____________________________________________________________________________________
____________________________________________________________________________________
0.00 0.8461 0.1495 0.0044 0.0000 0.7349 0.0057 0.2594 0.0000
0.10 0.8324 0.1523 0.0053 0.0100 0.7310 0.0039 0.2557 0.0094
0.50 0.7842 0.1614 0.0037 0.0507 0.7008 0.0024 0.2410 0.0558
1.00 0.7143 0.1785 0.0018 0.1054 0.6776 0.0016 0.2230 0.0978
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1995MI1

T500 VC, Pharmacia Inc., Tokyo, Japan
Salt (D): silver nitrate AgNO3 7761-88-8
T/K = 293.15
Comments: The feed phase contains about 0.38 wt% polyunsaturated fatty acid ethyl ester that is
partitioned between both phases after phase separation.
____________________________________________________________________________________
____________________________________________________________________________________
0.8539 0.0326 0.0768 0.0329 0.8830 0.0610 0.0230 0.0330 0.8200 0.0050 0.1420 0.0330
0.8364 0.0397 0.0874 0.0327 0.8930 0.0720 0.0020 0.0330 0.8080 0.0020 0.1570 0.0330
0.8222 0.0438 0.0976 0.0326 0.8720 0.0940 0.0010 0.0330 0.7650 0.0006 0.2010 0.0330
0.7951 0.0530 0.1159 0.0323 0.8580 0.1080 0.0020 0.0320 0.7420 0.0002 0.2260 0.0320
0.7722 0.0622 0.1298 0.0321 0.8430 0.1220 0.0020 0.0330 0.7050 0.00001 0.2630 0.0320
____________________________________________________________________________________

Salt (D): sodium chloride NaCl 7647-14-5
continued
____________________________________________________________________________________
continued
T/K = 296-298
____________________________________________________________________________________
____________________________________________________________________________________
0.7619 0.0874 0.1409 0.0098 0.8161 0.1732 0.0025 0.0082 0.7058 0.0035 0.2793 0.0114
0.7810 0.0816 0.1276 0.0098 0.8299 0.1571 0.0037 0.0093 0.7270 0.0035 0.2581 0.0114
0.7997 0.0728 0.1177 0.0098 0.8458 0.1391 0.0061 0.0090 0.7524 0.0036 0.2334 0.0106
0.8352 0.0594 0.0956 0.0098 0.8719 0.1060 0.0123 0.0098 0.7949 0.0092 0.1861 0.0098
0.8700 0.0462 0.0740 0.0098 0.8884 0.0720 0.0295 0.0101 0.8497 0.0170 0.1242 0.0091
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1997GRO

T/K = 293.15
Comments: pH is about 8.5 in the top phase and in the bottom phase.
____________________________________________________________________________________
____________________________________________________________________________________
0.81940 0.0987 0.0806 0.00132 0.86960 0.0203 0.1084 0.00166 0.79150 0.1468 0.0606 0.00113
0.81960 0.0764 0.1021 0.00193 0.86510 0.0052 0.1274 0.00227 0.77250 0.2263 0.0447 0.00118
0.80360 0.0703 0.1239 0.00221 0.84600 0.0011 0.1503 0.00260 0.66970 0.2958 0.0334 0.00108
0.77180 0.1053 0.1212 0.00169 0.83240 0.0002 0.1653 0.00214 0.65430 0.3153 0.0296 0.00082
____________________________________________________________________________________

Hoechst AG, Frankfurt, Germany
continued
____________________________________________________________________________________
continued
T/K = 293.15
Comments: pH is about 8.3 in the top phase and 8.5 in the bottom phase.
____________________________________________________________________________________
____________________________________________________________________________________
0.8282 0.1001 0.0701 0.00157 0.8925 0.0044 0.1011 0.00203 0.8073 0.1369 0.0545 0.00129
0.8333 0.0825 0.0825 0.00169 0.8864 0.0015 0.1100 0.00212 0.7688 0.1850 0.0450 0.00118
0.7826 0.1294 0.0861 0.00195 0.8613 0.0000 0.1360 0.00269 0.7118 0.2510 0.0360 0.00118
0.7553 0.1454 0.0977 0.00162 0.8357 0.0000 0.1620 0.00233 0.6671 0.3000 0.0320 0.00088
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1995GR2

T/K = 293.15
____________________________________________________________________________________
____________________________________________________________________________________
0.82577 0.0782 0.0944 0.00163 0.75694 0.1921 0.0500 0.00097 0.86804 0.0113 0.1188 0.00186
0.79823 0.1159 0.0839 0.00197 0.73602 0.2184 0.0445 0.00108 0.86529 0.0070 0.1251 0.00262
0.76541 0.1441 0.0882 0.00229 0.69062 0.2734 0.0349 0.00108 0.84893 0.0013 0.1464 0.00338
0.74087 0.1601 0.0965 0.00253 0.64830 0.3222 0.0285 0.00100 0.83173 0.0003 0.1640 0.00397
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1995TIN, 1997GRO

T/K = 293.15
Comments: pH is from 8.9 to 9.3 in the top phase and 8.9 to 9.8 in the bottom phase.
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
____________________________________________________________________________________
0.8168 0.1017 0.0802 0.00134 0.8829 0.0010 0.1144 0.00174 0.7357 0.2244 0.0390 0.00089
0.7781 0.1353 0.0850 0.00157 0.8614 0.0003 0.1360 0.00229 0.6916 0.2752 0.0323 0.00093
0.7345 0.1655 0.0981 0.00187 0.8283 0.0008 0.1685 0.00239 0.6314 0.3429 0.0249 0.00077
0.7133 0.1803 0.1050 0.00137 0.8180 0.0000 0.1800 0.00201 0.6114 0.3630 0.0250 0.00061
0.8331 0.0836 0.0823 0.00101 0.8874 0.0010 0.1100 0.00158 0.7524 0.2040 0.0430 0.00059
0.8142 0.0987 0.0861 0.00101 0.8775 0.0010 0.1200 0.00151 0.7285 0.2310 0.0400 0.00051
0.7477 0.1521 0.0992 0.00101 0.8354 <0.0001 0.1630 0.00163 0.6555 0.3150 0.0290 0.00049
0.6954 0.1867 0.1170 0.00099 0.7962 <0.0001 0.2020 0.00175 0.5886 0.3850 0.0260 0.00039
____________________________________________________________________________________

T/K = 293.15
____________________________________________________________________________________
____________________________________________________________________________________
0.80830 0.0999 0.0908 0.00097 0.86460 0.0080 0.1260 0.00136 0.74060 0.2120 0.0470 0.00042
0.76240 0.1415 0.0951 0.00097 0.84150 0.0010 0.1560 0.00152 0.68470 0.2820 0.0330 0.00026
0.72840 0.1705 0.1001 0.00096 0.82330 0.0000 0.1750 0.00166 0.63380 0.3400 0.0260 0.00020
0.71460 0.1741 0.1104 0.00092 0.80850 0.0000 0.1900 0.00154 0.61280 0.3640 0.0230 0.00017
____________________________________________________________________________________

T/K = 293.15
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
____________________________________________________________________________________
0.8325 0.0862 0.0802 0.00100 0.8887 0.0020 0.1080 0.00135 0.7605 0.1950 0.0440 0.00049
0.8141 0.0997 0.0852 0.00101 0.8765 0.0010 0.1210 0.00146 0.7246 0.2370 0.0380 0.00044
0.7463 0.1528 0.0999 0.00100 0.8323 <0.0001 0.1660 0.00169 0.6507 0.3210 0.0280 0.00027
0.7164 0.1755 0.1071 0.00100 0.8133 <0.0001 0.1850 0.00168 0.6188 0.3540 0.0270 0.00023
____________________________________________________________________________________

Component (D): lysozyme chloride 55219-07-5
T/K = 293.15
____________________________________________________________________________________
____________________________________________________________________________________
0.80258 0.1033 0.0931 0.00102 0.72449 0.2300 0.0450 0.00051 0.85558 0.0150 0.1280 0.00142
0.76437 0.1353 0.0995 0.00083 0.67567 0.2920 0.0320 0.00033 0.84066 0.0010 0.1570 0.00134
0.69892 0.1894 0.1107 0.00095 0.59983 0.3800 0.0200 0.00017 0.79811 0.0000 0.2000 0.00189
0.76990 0.1330 0.0961 0.00100 0.69666 0.2630 0.0400 0.00034 0.84837 0.0020 0.1480 0.00163
0.78507 0.0998 0.1143 0.00083 0.68075 0.2800 0.0390 0.00025 0.84535 0.0015 0.1520 0.00115
0.78124 0.1043 0.1134 0.00106 0.67765 0.2850 0.0370 0.00035 0.84251 0.0010 0.1550 0.00150
0.80053 0.1218 0.0767 0.00097 0.77942 0.1600 0.0600 0.00058 0.86351 0.0200 0.1150 0.00149
0.80322 0.1003 0.0955 0.00098 0.72451 0.2300 0.0450 0.00049 0.85564 0.0150 0.1280 0.00136
0.80312 0.1005 0.0954 0.00098 0.72466 0.2300 0.0450 0.00034 0.85561 0.0150 0.1280 0.00139
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1995GR2

continued
____________________________________________________________________________________
continued
T/K = 293.15
____________________________________________________________________________________
____________________________________________________________________________________
0.82754 0.0812 0.0900 0.00126 0.77184 0.1648 0.0620 0.00136 0.86330 0.0225 0.1131 0.00110
0.80342 0.1108 0.0845 0.00128 0.72582 0.2237 0.0490 0.00148 0.86434 0.0099 0.1247 0.00106
0.76375 0.1451 0.0899 0.00125 0.68801 0.2737 0.0368 0.00149 0.85289 0.0012 0.1450 0.00091
0.74714 0.1567 0.0949 0.00126 0.65359 0 .3118 0.0331 0.00151 0.83652 0.0005 0.1621 0.00088
____________________________________________________________________________________

T/K = 293.15
____________________________________________________________________________________
____________________________________________________________________________________
0.79690 0.1066 0.0865 0.01004 0.85200 0.0115 0.1269 0.00956 0.74500 0.1866 0.0580 0.01045
0.76890 0.1301 0.0906 0.01042 0.84160 0.0026 0.1461 0.00965 0.68730 0.2568 0.0439 0.01195
0.73320 0.1600 0.0966 0.01017 0.82570 0.0009 0.1647 0.00873 0.64750 0.3031 0.0369 0.01247
0.71550 0.1732 0.1014 0.00995 0.81210 0.0005 0.1792 0.00815 0.62390 0.3302 0.0326 0.01325
____________________________________________________________________________________

T/K = 293.15
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
____________________________________________________________________________________
0.8504 0.0717 0.0763 0.00162 0.8916 0.0058 0.1011 0.00146 0.8041 0.1375 0.0566 0.00177
0.7991 0.1302 0.0691 0.00160 0.8807 0.0013 0.1167 0.00133 0.7516 0.2050 0.0416 0.00177
0.7852 0.1257 0.0876 0.00154 0.8609 0.0004 0.1375 0.00124 0.6982 0.2642 0.0357 0.00190
0.7562 0.1313 0.1110 0.00151 0.8296 0.0001 0.1692 0.00109 0.6389 0.3292 0.0296 0.00228
____________________________________________________________________________________
More data can be found in Refs. 1995TIN, 1995GR2, and 1997GRO for liquid-liquid
equilibrium as well as partitioning of amino acids and low molecular peptides in
PEG/dipotassium phosphate aqueous two-phase systems.

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 298.15
____________________________________________________________________________________
wA wB wC wD wA wB wC wD pH wA wB wC wD pH
____________________________________________________________________________________
0.6251 0.2009 0.1147 0.0593 0.5771 0.3185 0.0579 0.0465 6.7 0.6673 0.1060 0.1660 0.0607 6.7
0.5932 0.2226 0.1243 0.0599 0.5296 0.3911 0.0354 0.0439 6.6 0.6364 0.1048 0.1845 0.0743 6.9
0.5698 0.2339 0.1361 0.0602 0.5050 0.4298 0.0270 0.0382 6.5 0.6137 0.1012 0.2075 0.0776 6.9
0.5478 0.2459 0.1461 0.0602 0.4797 0.4578 0.0247 0.0378 6.5 0.5719 0.0995 0.2371 0.0915 6.7
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 298.15
____________________________________________________________________________________
____________________________________________________________________________________
0.6347 0.1995 0.1062 0.0596 0.5867 0.3171 0.0494 0.0468 8.5 0.6763 0.1046 0.1575 0.0616 8.9
0.5950 0.2199 0.1249 0.0602 0.5317 0.3884 0.0360 0.0439 8.5 0.6382 0.1021 0.1851 0.0746 8.9
0.5682 0.2346 0.1367 0.0605 0.5034 0.4305 0.0276 0.0385 8.5 0.6121 0.1019 0.2081 0.0779 8.7
0.5482 0.2459 0.1459 0.0600 0.4807 0.4572 0.0245 0.0376 8.3 0.5761 0.0999 0.2327 0.0913 8.8
____________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 298.15
____________________________________________________________________________________
____________________________________________________________________________________
0.6812 0.1587 0.0997 0.0604 0.6309 0.2295 0.0577 0.0819 6.9 0.7264 0.0809 0.1394 0.0533 7.0
0.6590 0.1798 0.1008 0.0604 0.5912 0.2741 0.0507 0.0840 6.8 0.7063 0.0798 0.1552 0.0587 6.9
0.6311 0.1936 0.1152 0.0601 0.5758 0.3356 0.0404 0.0482 6.8 0.6860 0.0764 0.1758 0.0618 6.9
0.5968 0.2209 0.1216 0.0607 0.5446 0.3747 0.0349 0.0458 6.7 0.6274 0.0753 0.2016 0.0957 6.9
____________________________________________________________________________________
T/K = 298.15
____________________________________________________________________________________
____________________________________________________________________________________
0.6850 0.1563 0.0987 0.0600 0.6072 0.2670 0.0461 0.0797 8.9 0.7206 0.1039 0.1263 0.0492 9.0
0.6564 0.1788 0.1033 0.0615 0.5611 0.3226 0.0359 0.0804 8.6 0.7082 0.0833 0.1511 0.0574 9.0
0.6303 0.1958 0.1131 0.0608 0.5568 0.3604 0.0331 0.0497 8.4 0.6881 0.0691 0.1806 0.0622 9.0
0.5968 0.2187 0.1233 0.0612 0.5044 0.4350 0.0267 0.0339 8.3 0.6270 0.0625 0.1999 0.1106 9.0
____________________________________________________________________________________
____________________________________________________________________________________

K2HPO4/H2KPO4 7758-11-4/7778-77-0
T/K = 298.15
____________________________________________________________________________________
____________________________________________________________________________________
0.6804 0.1588 0.1001 0.0607 0.5782 0.2873 0.0507 0.0838 6.8 0.7378 0.0720 0.1348 0.0554 6.9
0.6570 0.1791 0.1036 0.0603 0.5407 0.3304 0.0432 0.0857 6.8 0.7228 0.0708 0.1483 0.0581 6.9
0.6271 0.1980 0.1156 0.0593 0.5363 0.3779 0.0373 0.0485 6.7 0.6966 0.0695 0.1703 0.0636 6.9
0.5934 0.2199 0.1253 0.0614 0.5200 0.4147 0.0325 0.0328 6.7 0.6208 0.0607 0.1984 0.1201 6.9
____________________________________________________________________________________
T/K = 298.15
____________________________________________________________________________________
____________________________________________________________________________________
0.6780 0.1595 0.1001 0.0624 0.5769 0.3069 0.0363 0.0799 8.7 0.7247 0.0863 0.1414 0.0476 9.0
0.6596 0.1780 0.1026 0.0598 0.5409 0.3444 0.0324 0.0823 8.7 0.7140 0.0729 0.1554 0.0577 9.0
0.6292 0.1975 0.1139 0.0594 0.5354 0.3873 0.0274 0.0499 8.5 0.6905 0.0716 0.1764 0.0615 9.0
0.6014 0.2169 0.1218 0.0599 0.4995 0.4230 0.0233 0.0542 8.6 0.6366 0.0705 0.1978 0.0951 9.2
____________________________________________________________________________________

T/K = 298.15
continued
____________________________________________________________________________________
continued
_____________________________________________________________________________
_____________________________________________________________________________
0.1110 0.1206 0.1006 0.3509 0.0230 0.0000 0.1627
0.1097 0.1131 0.1007 0.3179 0.0277 0.0000 0.1564
0.1330 0.1057 0.0999 0.3187 0.0286 0.0000 0.1585
0.1019 0.1051 0.1008 0.2928 0.0327 0.0003 0.1432
0.1106 0.0948 0.1011 0.2572 0.0384 0.0050 0.1308
0.0923 0.0964 0.0999 0.2387 0.0425 0.0091 0.1241
0.1007 0.0894 0.1038 0.2078 0.0480 0.0115 0.1236
0.0953 0.0856 0.1003 0.1600 0.0609 0.0225 0.1132
0.1387 0.1342 0.2011 0.3374 0.0252 0.0000 0.2132
0.1094 0.1211 0.1998 0.3030 0.0298 0.0002 0.1721
0.1200 0.1100 0.2009 0.2816 0.0344 0.0006 0.1658
0.1001 0.1099 0.2008 0.2631 0.0371 0.0043 0.1520
0.1103 0.1022 0.2000 0.2440 0.0412 0.0056 0.1462
0.0898 0.1028 0.2004 0.2163 0.0463 0.0115 0.1394
0.1006 0.0992 0.2026 0.2073 0.0485 0.0118 0.1403
0.0903 0.0992 0.2006 0.1806 0.0572 0.0198 0.1292
0.1196 0.1101 0.3054 0.2515 0.0438 0.0037 0.1677
0.1193 0.1084 0.2999 0.2439 0.0452 0.0047 0.1649
0.1106 0.1096 0.2996 0.2341 0.0480 0.0056 0.1607
0.1059 0.1004 0.3004 0.1891 0.0609 0.0l58 0.1423
0.0998 0.1008 0.3004 0.1845 0.0624 0.0l94 0.1377
0.1000 0.0959 0.3010 0.1507 0.0720 0.0368 0.1258
_____________________________________________________________________________

T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.1209 0.1097 0.0997 0.3396 0.0230 0.0005 0.1596
0.1143 0.0997 0.1001 0.3013 0.0271 0.0006 0.1418
_____________________________________________________________________________
continued
____________________________________________________________________________________
continued
_____________________________________________________________________________
_____________________________________________________________________________
0.1091 0.0995 0.0995 0.3013 0.0274 0.0005 0.1410
0.1043 0.0949 0.1004 0.2795 0.0306 0.0013 0.1337
0.1095 0.0939 0.0996 0.2763 0.0310 0.0006 0.1381
0.0998 0.0903 0.0997 0.2497 0.0345 0.0018 0.1283
0.0946 0.0891 0.1000 0.2401 0.0374 0.0028 0.1215
0.0903 0.0852 0.1007 0.2082 0.0426 0.0056 0.1152
0.0848 0.0844 0.1000 0.1965 0.0435 0.0122 0.1125
0.0845 0.0842 0.1000 0.1905 0.0447 0.0141 0.1106
0.0845 0.0796 0.0996 0.1706 0.0509 0.0219 0.1001
0.0823 0.0794 0.0999 0.1590 0.0523 0.0241 0.1015
0.1656 0.1173 0.1982 0.3624 0.0224 0.0002 0.1981
0.1570 0.1147 0.1994 0.3532 0.0237 0.0006 0.1884
0.1411 0.1103 0.1975 0.3257 0.0263 0.0005 0.1711
0.1313 0.1099 0.1983 0.3205 0.0278 0.0006 0.1661
0.1367 0.0973 0.1995 0.2938 0.0311 0.0006 0.1499
0.1151 0.0995 0.2003 0.2743 0.0340 0.0006 0.1446
0.1055 0.0956 0.1996 0.2443 0.0385 0.0015 0.1357
0.1089 0.0906 0.1991 0.2363 0.0402 0.0018 0.1308
0.0993 0.0892 0.1990 0.2117 0.0448 0.0050 0.1226
0.0887 0.0852 0.2007 0.1585 0.0557 0.0200 0.1106
0.0851 0.0842 0.2006 0.1532 0.0558 0.0187 0.1086
0.0872 0.0841 0.1994 0.1531 0.0588 0.0289 0.1056
0.1087 0.1042 0.2993 0.2537 0.0414 0.0014 0.1503
0.1090 0.0995 0.2998 0.2420 0.0431 0.0022 0.1443
0.0990 0.0990 0.2996 0.2245 0.0470 0.0036 0.1371
0.0888 0.0944 0.2995 0.1817 0.0553 0.0144 0.1241
0.0907 0.0889 0.2997 0.1600 0.0602 0.0224 0.1166
0.0813 0.0885 0.2988 0.1249 0.0719 0.0402 0.1038
_____________________________________________________________________________
____________________________________________________________________________________
3.6. Table of systems where quaternary LLE data were published only
_____________________________________________________________________________
Polymer (B) Second/third and fourth component Ref.
_____________________________________________________________________________
Cellulose N,N-dimethylacetamide/lithium chloride and water 2003CHR
_____________________________________________________________________________
Dextran α-amylase//poly(ethylene glycol) and water 1990FUR
bovine serum albumin/sodium chloride and water 1996HOS
bovine serum albumin/poly(ethylene glycol) and water 2001NER
γ-globulin/sodium chloride and water 1996HOS
β-lactoglobulin/sodium chloride and water 2001WAN
poly(ethylene glycol)/benzene derivatives and water 1993MIS
poly(ethylene glycol)/potassium phosphate and water 1993HAY
poly(ethylene glycol)/potassium sulfate and water 1993HAY
poly(ethylene glycol)/salts and water 1989HA2
poly(ethylene glycol)/salts and water 1994HAR
poly(ethylene glycol)/sodium phosphate and water 1984BAM
poly(ethylene glycol)/sodium chloride and water 1984BAM
_____________________________________________________________________________
Dextran sulfate polystyrene sulfonate/sodium chloride and water 1991PIC
_____________________________________________________________________________
Ethyl(hydroxyethyl)cellulose bovine serum albumin/sodium chloride and water 1996HOS
γ-globulin/sodium chloride and water 1996HOS
alkyl(dimethylamino)propanesulfonates/NaCl and water 1990KAR
alkyltrimethylammonium halides/NaCl and water 1990KAR
cetyltrimethylammonium bromide/NaCl and formamide 1991SA1
potassium alkanoates/NaCl and water 1990KAR
sodium alkyl sulfates/NaCl and water 1990KAR
sodium dodecyl sulfate/NaCl and formamide 1991SA1
_____________________________________________________________________________
Gelatin gum Arabic/maltodextrin and water 2001BUT
_____________________________________________________________________________
Methylcellulose sodium alkyl sulfates/NaCl and water 1990KAR
_____________________________________________________________________________
Poly(acrylic acid) n-octane/tetradecyltrimethlyammonium bromide
and water 2002NIL
1-octanol/tetradecyltrimethlyammonium bromide
and water 2002NIL
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(diallyldimethylammonium) n-octane/tetradecyltrimethlyammonium bromide
chloride and water 2002NIL
and water 2002NIL
_____________________________________________________________________________
Polyetherimide N,N-dimethylacetamide/acetic acid and water 2003SHE
N,N-dimethylformamide/1-methyl-2-pyrrolidinone
and water 2001ALB
1-methyl-2-pyrrolidinone/poly(1-vinyl-2-pyrrolidinone)
and water 1994BO2
_____________________________________________________________________________
Polyethersulfone 1-methyl-2-pyrrolidinone/polysulfone and water 1999BAI
1-methyl-2-pyrrolidinone/ poly(1-vinyl-2-pyrrolidinone)
and water 1994BO1
1-methyl-2-pyrrolidinone/ poly(1-vinyl-2-pyrrolidinone)
and water 1994BO2
_____________________________________________________________________________
Poly(ethylene glycol) acetylspiromycin/potassium phosphate and water 1994GUA
α-amylase/dextran and water 1990FUR
ammonium sulfate/benzene derivatives and water 1993MIS
benzenedimethanol/potassium phosphate and water 1994EI2
bovine serum albumin/dextran and water 2001NER
bovine serum albumin/sodium chloride and water 1968EDM
2,3-butanediol/potassium phosphate and water 1991EIT
1-butanol/potassium phosphate and water 1991EIT
dextran/benzene derivatives and water 1993MIS
dextran/potassium chloride and water 1993HAY
dextran/potassium phosphate and water 1993HAY
dextran/potassium sulfate and water 1993HAY
dextran/salts and water 1989HA2
dextran/salts and water 1994HAR
dextran/sodium phosphate and water 1984BAM
dextran/sodium chloride and water 1984BAM
dipotassium phosphate/benzene derivatives and water 1993MIS
dipotassium/monopotassium phosphate and water 1958ALB
dipotassium/monopotassium phosphate and water 1997MEL
dipotassium/monopotassium phosphate and water 2000SR2
dipotassium/monopotassium phosphate and water 2002ASE
ethanol/potassium phosphate and water 1991EIT
1-hexanol/potassium phosphate and water 1991EIT
1-pentanol/potassium phosphate and water 1991EIT
3-phenyl-1-propanol/potassium phosphate and water 1991EIT
1-propanol/potassium phosphate and water 1991EIT
potassium phosphate/terephthalic acid and water 1994EI2
potassium phosphate/1,4-xylylene diamine and water 1994EI2
sodium hydroxide/-sulfide/-carbonate and water 2002GUO
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(ethylene oxide) sodium dodecyl sulfate/NaCl and water 1990KAR
_____________________________________________________________________________
Poly(hydroxystearic acid)-b-poly-
(ethylene oxide)-b-poly(hydroxy- isopropyl myristate/1,2-hexanediol and water 2002PLA
stearic acid) triblock copolymer isopropyl myristate/1,2-octanediol and water 2002PLA
_____________________________________________________________________________
Polyimide N,N-dimethylformamide/poly(1-vinyl-2-pyrrolidinone)
and water 2001KI1
1-methyl-2-pyrrolidinone/poly(1-vinyl-2-pyrrolidinone)
and water 2001KI1
_____________________________________________________________________________
Poly(N-isopropylacrylamide) potassium fluoride/sodium chloride and water 2002FRE
_____________________________________________________________________________
Poly(L-lactide) 1,4-dioxane/sodium chloride and water 2001HUA
_____________________________________________________________________________
Polysaccharide sodium bromide/tetradecyltrimethlyammonium
bromide and water 1991TH2
two fractions of schizophyllan and water 1984ITO
_____________________________________________________________________________
Poly(styrene sulfonate) dextran sulfate/sodium chloride and water 1991PIC
n-octane/tetradecyltrimethlyammonium bromide
and water 2002NIL
and water 2002NIL
_____________________________________________________________________________
Polysulfone 1-methyl-2-pyrrolidinone/polyethersulfone and water 1999BAI
_____________________________________________________________________________
Poly(1-vinyl-2-pyrrolidinone) dipotassium/monopotassium phosphate and water 1958ALB
N,N-dimethylformamide/polyimide and water 2001KI1
1-methyl-2-pyrrolidinone/polyimide and water 2001KI1
_____________________________________________________________________________
____________________________________________________________________________________
3.7. Lower critical (LCST) and/or upper critical (UCST) solution

temperatures of aqueous polymer solutions
_____________________________________________________________________________
Polymer (B) Mn/ Mw / UCST/ LCST/ Ref.
g/mol g/mol K K
_____________________________________________________________________________
N,N-Dimethylacrylamide/butyl acrylate copolymer
(15 wt% butyl acrylate) 346.2 1992MUE
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-butoxyethyl acrylate copolymer
(50 wt% 2-butoxyethyl acrylate) <273.2 1992MUE
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-ethoxyethyl acrylate copolymer
(50 wt% 2-ethoxyethyl acrylate) 319.2 1992MUE
(75 wt% 2-ethoxyethyl acrylate) 285.2 1992MUE
_____________________________________________________________________________
N,N-Dimethylacrylamide/ethyl acrylate copolymer
(25 wt% ethyl acrylate) 347.2 1992MUE
(55 wt% ethyl acrylate) <273.2 1992MUE
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-methoxyethyl acrylate copolymer
(38 mol% 2-methoxyethyl acrylate) 353.2 1996ELE
(50 wt% 2-methoxyethyl acrylate) 343.2 1992MUE
_____________________________________________________________________________
____________________________________________________________________________________

g/mol g/mol K K
_____________________________________________________________________________
N,N-Dimethylacrylamide/methyl acrylate copolymer
(30 wt% methyl acrylate) 371.2 1992MUE
(70 wt% methyl acrylate) <273.2 1992MUE
_____________________________________________________________________________
N,N-Dimethylacrylamide/propyl acrylate copolymer
(20 wt% propyl acrylate) 353.2 1992MUE
_____________________________________________________________________________
Ethylene/vinyl alcohol copolymer
(87.2 mol% vinyl alcohol) ∞ ∞ 463.55 285.65 1971SHI
_____________________________________________________________________________
Ethylene oxide/propylene oxide copolymer
(20.0 mol% ethylene oxide) 3400 303 2000PE2
(33.3 mol% ethylene oxide) 3000-3500 340 1997LIM
(50.0 mol% ethylene oxide) 2340 2480 338.25 2000LI2
3640 4040 324.85 2000LI2
3900 323 2000PE2
3000-3500 343 1997LIM
(58.8 mol% ethylene oxide) 3000 326.65 2000PE1
(66.7 mol% ethylene oxide) 3000-3500 359 1997LIM
(72.4 mol% ethylene oxide) 36000 333 1991LOU
(79.5 mol% ethylene oxide) 30800 345 1991LOU
32500 345 1991LOU
(86.6 mol% ethylene oxide) 30100 355.5 1991LOU
_____________________________________________________________________________
Ethyl(hydroxyethyl)cellulose
200000 338 2000PE1
_____________________________________________________________________________
Hepta(ethylene glycol) monotetradecyl ether
690 331.75 1984COR
690 332.68 1998KUB
_____________________________________________________________________________
____________________________________________________________________________________

g/mol g/mol K K
_____________________________________________________________________________
Hexa(ethylene glycol) monododecyl ether
452 323.55 1984COR
452 324.45 1991SC3
_____________________________________________________________________________
Hexa(ethylene glycol) monooctyl ether
396 347.55 1991SC3
_____________________________________________________________________________
Hydroxypropylcellulose
75000 318.45 1971KAG
100000 319.15 1990SCH
150000 324.45 1971KAG
300000 331.25 1971KAG
300000 316.05 1990SCH
1000000 315.05 1990SCH
∞ 343.85 1971KAG
_____________________________________________________________________________
N-Isopropylacrylamide/acrylamide copolymer
(15 mol% acrylamide) 3100000 315.15 1994MUM
_____________________________________________________________________________
N-Isopropylacrylamide/1-deoxy-1-methacrylamido-D-glucitol
(12.9 mol% glucitol) 78000 170000 311.3 2002REB
(13.3 mol% glucitol) 28600 56000 359.6 2002REB
(13.7 mol% glucitol) 51600 110000 314.9 2002REB
(14.0 mol% glucitol) 145000 432000 307.5 2002REB
_____________________________________________________________________________
N-Isopropylacrylamide/N-isopropylmethacrylamide copolymer
(10.56 mol% N-isopropylmethacrylamide)
55300 177000 307.15 2001DJO
42800 137000 308.45 2001DJO
28800 92000 309.75 2001DJO
23100 74000 311.05 2001DJO
18800 60000 312.95 2001DJO
23100 74000 314.65 2001DJO
17500 56000 315.55 2001DJO
_____________________________________________________________________________
____________________________________________________________________________________
Polymer (B) Mn/ Mw / Mη / UCST/ LCST/ Ref.

g/mol g/mol g/mol K K
_____________________________________________________________________________
N-Isopropylacrylamide/N-isopropylmethacrylamide copolymer
16600 53000 317.35 2001DJO
14700 47000 318.75 2001DJO
_____________________________________________________________________________
Methylcellulose
14000 323.15 2000PE1
(about 30 mol% methyl substitution) 70000 324.75 1972KAG
150000 326.35 1972KAG
300000 328.75 1972KAG
∞ 332.65 1972KAG
_____________________________________________________________________________
Methyl(hydroxypropyl)cellulose
(25 mol% methyl, 8 mol% hydroxypropyl substitution)
80000 340.15 1974BAB
160000 337.15 1974BAB
260000 333.15 1974BAB
(28 mol% methyl, 6.5 mol% hydroxypropyl substitution)
40000 337.65 1974BAB
100000 333.15 1974BAB
200000 338.65 1974BAB
(29 mol% methyl, 10 mol% hydroxypropyl substitution)
45000 345.15 1974BAB
130000 339.15 1974BAB
260000 333.65 1974BAB
_____________________________________________________________________________
Octa(ethylene glycol) monododecyl ether
538 348.65 1984COR
_____________________________________________________________________________
Penta(ethylene glycol) monodecyl ether
378 568 317 1980LAN
_____________________________________________________________________________
Penta(ethylene glycol) monododecyl ether
406 305.06 1985HAM
406 305.15 1991SC3
_____________________________________________________________________________
Penta(ethylene glycol) monooctyl ether
350 334.85 1991SC3
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly[bis(2-(2'-methoxyethoxy)ethoxy)phosphazene]
667000 1000000 338.15 1996ALL
_____________________________________________________________________________
Poly[bis(2,3-bis(2-methoxyethoxy)propanoxy)phosphazene]
714000 1000000 311.15 1996ALL
_____________________________________________________________________________
Poly[bis(2,3-bis(2-(2'-methoxyethoxy)ethoxy)propanoxy)phosphazene]
1420000 1700000 322.65 1996ALL
_____________________________________________________________________________
Poly[bis(2,3-bis(2-(2'-(2''-dimethoxyethoxy)ethoxy)ethoxy)propanoxy)phosphazene]
857000 1200000 334.65 1996ALL
_____________________________________________________________________________
Poly(N,N-diethylacrylamide)
19000 305.15 2002MA2
412000 303.65 2001CAI
412000 303.65 2001GAN
_____________________________________________________________________________
2180 489.7 448.7 1976SAE
2270 505.2 437.2 1976SAE
2290 507.7 435.7 1976SAE
6096 6197 404.77 2000FIS
14000 399 1970NAK
10457 11615 394.33 2000FIS
8000 389.4 1976SAE
12161 15481 388.47 2000FIS
15767 18887 385.95 2000FIS
33700 382.00 2000FIS
14400 380.7 1976SAE
40800 151000 378.25 2000FIS
21200 376.8 1976SAE
208200 832700 372.86 2000FIS
719000 372.3 1976SAE
1020000 371.8 1976SAE
4000000 369.39 1984FLO
∞ 366.04 2000FIS
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly[bis(methoxyethoxyethoxy)-phosphazene] block copolymer
(about 67 mol% ethylene oxide)
22000 31500 338 2003CHA
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) triblock copolymer
(about 30 mol% ethylene oxide)
4400 286.65 2000LAM
_____________________________________________________________________________
Poly(N-isopropylacrylamide)
2300 2700 305.85 2002FRE
5400 14000 307.45 1990SCH
11000 76000 307.25 1990SCH
49000 160000 307.05 1990SCH
70000 144000 306.4 2002REB
70000 224000 305.95 2001DJO
73000 400000 306.35 1990SCH
160000 440000 306.35 1990SCH
146000 530000 305.85 1990SCH
1550000 305.65 1990WIN
300000 304.95 2001KUJ
7800000 304.55 2002BER
_____________________________________________________________________________
Poly(N-isopropylmethacrylamide)
6250 20000 319.95 2001DJO
_____________________________________________________________________________
Poly(N-isopropylmethacrylamide)-poly[(N-acetylimino)ethylene] block copolymer
(80 wt% N-isopropylacrylamide)
5500 306.2 2003DAV
_____________________________________________________________________________
Poly(N-isopropylmethacrylamide)-poly[(N-acetylimino)ethylene] graft copolymer
6030 306.2 2003DAV
41400 308.7 2003DAV
16000 308.7 2003DAV
_____________________________________________________________________________
Poly(propylene glycol)
500 318.2 1975TA4
575 318.2 1974BES
_____________________________________________________________________________
Poly(vinyl alcohol)
40000 514 1971TAG
46000 515 1969AND
84000 504 1969AND
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
Poly(N-vinylcaprolactam)
150000 306.45 2002MA1
high 304.55 1999LAU
470000 304.0 1994TAG
_____________________________________________________________________________
Poly(N-vinylisobutyramide)
66000 105600 313.25 2000KUN
_____________________________________________________________________________
Poly(vinyl methyl ether)
60000 305.65 2000PE1
83000 155000 306.95 1990SCH
_____________________________________________________________________________
Poly(N-vinyl-N-propylacetamide)
30000 313.5 1994TAG
_____________________________________________________________________________
Tetra(ethylene glycol) diethyl ether
250 363 1972NAK
_____________________________________________________________________________
Tetra(ethylene glycol) monodecyl ether
334 573 294 1980LAN
334 293.65 1991SC3
_____________________________________________________________________________
Tetra(ethylene glycol) monododecyl ether
362 279.75 1991SC3
_____________________________________________________________________________
Tetra(ethylene glycol) monohexyl ether
278 339.25 1991SC3
_____________________________________________________________________________
Tetra(ethylene glycol) monooctyl ether
306 313.45 1984COR
306 313.95 1991SC3
306 314.11 1999SHI
_____________________________________________________________________________
Tri(ethylene glycol) monohexyl ether
234 317.85 1984COR
234 319.15 1991SC3
_____________________________________________________________________________
Tri(ethylene glycol) monooctyl ether
262 289.15 1991SC3
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
N-Vinylacetamide/vinyl acetate copolymer
(58 mol% vinyl acetate) 30000 57000 340.15 2003YAM
_____________________________________________________________________________
Vinyl alcohol/vinyl butyrate copolymer
(7.5 mol% butyralized PVA)
∞ ∞ 408.0 298.25 1984SHI
∞ ∞ 296.45 1984SHI
∞ ∞ 287.55 1984SHI
_____________________________________________________________________________
Vinylamine/N-vinylcaprolactam copolymer
(3.8 mol% vinylamine) 160000 308.8 1994TAG
_____________________________________________________________________________
N-Vinylformamide/vinyl acetate copolymer
____________________________________________________________________________
____________________________________________________________________________________
3.8. References
1957MAL Malcolm, G.N. and Rowlinson, J.S., Thermodynamic properties of aqueous solutions of
polyethylene glycol, polypropylene glycol, and dioxane, Trans. Faraday Soc., 53, 921, 1957.
1958ALB Albertson, P.-A., Particle fractionation in liquid two-phase systems, Biochim. Biophys.
Acta, 27, 378, 1958.
1959BAI Bailey, F.E. and Callard, R.W., Some properties of poly(ethylene oxide) in aqueous
solution, J. Appl. Polym. Sci., 1, 56, 1959.
1959EIS Eisenberg, H. and Mohan, G.R., Aqueous solutions of polyvinylsulfonic acid: phase
separation and specific interaction with ions, viscosity, conductance and potentiometry, J.
Phys. Chem.. 63, 671, 1959.
1962EIS Eisenberg, H. and Woodside, D., Multicomponent polyelectrolyte solutions. Part II.
Excluded volume study of polyvinylsulfonate alkali halide systems, J. Chem. Phys., 36,
1844, 1962.
1963REH Rehage, G., Quellung, Gelierung und Diffusion bei Kunststoffen, Kunststoffe, 53, 605,
1963.
1966NAG Nagasawa, M., Asai, Y., and Sugiura, I., Determination of molecular weight distribution of
linear polymers by measuring specific heat of solution (Jap.), Kogyo Kagaku Zasshi, 69,
1759, 1966.
1967SAI Saito, S. and Otsuka, T., Dissolution of some polymers in aqueous solutions of urea, of its
related compounds and tetraalkylammonium salts, J. Colloid Interface Sci., 25, 531, 1967.
1968EDM Edmond, E. and Ogston, A.G., An approach to the study of phase separation in ternary
aqueous systems, Biochem. J., 109, 569, 1968.
1969AND Andreeva, V.M., Tager, A.A., Anikeeva, A.A., and Kuz'mina, T.A., Lower critical tempera-
ture of the dissolution of poly(vinyl alcohol) in water (Russ.), Vysokomol. Soedin., Ser. B,
11, 555, 1969.
1969GOL Goldfarb, J. and Sepulveda, L., Application of a theory of polymer solutions to the cloud
points of nonionic detergents, J. Colloid Interface Sci., 31, 454, 1969.
1969KUZ Kuznetsov, V.I., Kogan, V.B., and Vilesova, M.S., Investigation of mutual solubility of
polyoxypropylene polyoles and water (Russ.), Vysokomol. Soedin., Ser. A, 11, 1330, 1969.
1969SAI Saito, S. and Yukawa, M., Interaction of polymers and cationic surfactants with thiocyanate
as counterions, J. Colloid Interface Sci., 30, 211, 1969.
1970GRI Grinberg, V.Ya., Shvenke, K.D., and Tolstoguzov, V.E., On phase states in the system
gelatin-dextran-water (Russ.), Izv. Akad. Nauk SSSR, Ser. Khim., -,1430, 1970.
1970NAK Nakayama, H., Temperature dependence of the heat of solution of poly(ethylene glycol) and
of related compounds, Bull. Chem. Soc. Japan, 43, 1683, 1970.
1971KAG Kagemoto, A. and Baba, Y., Phase diagrams of polymer solutions (Jap.), Kobunshi Kagaku,
28, 784, 1971.
1971SAI Saito, S. and Kitamura, K., Counterion effect of tetraalkylammonium and long chain alkyl-
ammonium salts in the interaction with nonionic polymers, J. Colloid Interface Sci., 35,
346, 1971.
1971SHI Shibatani, K. and Oyanagi, Y., Solution properties of vinyl alcohol-ethylene copolymers in
water, Kobunshi Kagaku, 28, 361, 1971.
1971TAG Tager, A.A., Anikeeva, A.A., Adamova, L.V., Andreeva, V.M., Kuz'mina, T.A., and
Tsilipotkina, M.V., Effect of temperature on the solubility of poly(vinyl alcohol) in water
(Russ.), Vysokomol. Soedin., Ser. A, 13, 659, 1971.
1972GRI Grinberg, V.Ya. and Tolstoguzov, V.B., Thermodynamic compatibility of gelatin with some
D-glucans in aqueous media, Carbohydr. Res., 25, 313, 1972.
____________________________________________________________________________________
1972KAG Kagemoto, A., Baba, Y., and Fujishiro, R., Phase equilibrium of the cellulose derivatives
determined by differential thermal analysis. 1. Methylcellulose/water, Makromol. Chem.,
154, 105, 1972.
1972NAK Nakayama, H., Thermodynamic properties of an aqueous solution of tetraethylene glycol
diethyl ether, Bull. Chem. Soc. Japan, 45, 1371, 1972.
1972TA1 Tager, A.A., Adamova, L.V., Bessonov, Yu.S., Kuznetsov, V.N., Plyusnina, T.A., Soldatov,
A, 14, 1991, 1972.
1972TA2 Tager, A.A., Anikeeva, A.A., Andreeva, V.M., and Vshivkov, S.A., Poly(vinyl acetate)
solutions having upper and lower critical mixing temperatures (Russ.), Vysokomol. Soedin.,
Ser. B, 14, 231, 1972.
1974AND Andreeva, V.M., Anikeeva, A.A., Tager, A.A., Kosareva, L.P., Phase equilibrium of
aqueous solutions of poly(vinyl alcohol) and products of its acetylation (Russ.), Vysokomol.
Soedin., Ser. B, 16, 277, 1974.
1974BAB Baba, Y. and Kagemoto, A., Phase diagrams of aqueous solutions of cellulose derivatives
(Jap.), Kobunshi Ronbunshu, 31, 446, 1974.
1974BES Bessonov, Yu.S. and Tager, A.A., Thermodynamic investigation of oligomeric polyoxy-
propylenediol-water system in the demixing region, Tr. Khim. Khim. Tekhnol., 1, 150, 1974.
1974TAG Tager, A.A., Vshivkov, S.A., Andreeva, V.M., and Sekacheva, T.V., Structural study of
solutions of poly(oxyethylene) with lower critical temperatures of mixing (Russ.),
Vysokomol. Soedin., Ser. A, 16, 9, 1974.
1974TAN Taniguchi, Y., Suzuki, K., and Enomoto, T., The effect of pressure on the cloud point of
aqueous polymer solutions, J. Colloid Interface Sci., 46, 511, 1974.
1975TA3 Tager, A.A. and Bessonov, Yu.S., Thermochemistry of solutions of polymers and polymer
compositions in the phase separation region, Vysokomol. Soedin., Ser. A, 17, 2383, 1975.
1975TA4 Tager, A.A., Lirova, B.I., Smolyanskii, A.L., and Plomadil, L.A., Phase equilibriums in
systems with a lower critical temperature of mixing studied by an IR spectroscopic method,
1976BOU Boucher, E.A. and Hines, P.M., Effects of inorganic salts on the properties of aqueous
poly(ethylene oxide) solutions, J. Polym. Sci. Polym. Phys. Ed., 14, 2241, 1976.
1976SAE Saeki, S., Kuwahara, N., Nakata, M., and Kaneko, M., Upper and lower critical solution
temperatures in poly(ethylene glycol) solutions, Polymer, 17, 685, 1976.
1977KOE Koehnen, D.M., Mulder, M.H.V., and Smolders, C.A., Phase separation phenomena during
the formation of asymmetric membranes, J. Appl. Polym. Sci., 21, 199, 1977.
1977SAE Saeki, S., Kuwahara, N., Nakata, M., and Kaneko, M., Phase separation of poly(ethylene
glycol)-water-salt systems, Polymer, 18, 1027, 1977.
1977VSH Vshivkov, S.A., Tager, A.A., Lantseva, N.V., and Loginova, L., Phase equilibrium and
structure of solutions of oligomeric poly(oxypropylene)diols with upper and lower critical
solution temperatures (Russ.), Protsessy Studneobras. Polimern. Sistem., (2), 3, 1977.
1978NIK Nikolaeva, N.D., Stankevich, R.P., and Vilesova, M.S., Nekotorye zakonomernosti zhid-
kofaznogo razdeleniya rastvorov polivinilovogo spirta, Termodinam. Kinet. Khim.
Protsess., Leningrad, 1, 87, 1978.
1978VSH Vshivkov, S.A., Tager, A.A., and Benkovskii, A.D., Phase equilibrium of polymer solutions
in a hydrodynamic field (Russ.), Vysokomol. Soedin., Ser. B, 20, 603, 1978.
1979SIM Simenido, A.V., Medved, Z.N., Denisova, L.L., Tarakanov, O.G., Starikova, N.A., Some
physicochemical properties of the mixtures of polypropylene polyols with water (Russ.),
1980BIL Bilimova, E.S., Gladkovskii, G.A., Golubev, V.M., and Medved, Z.N., Study of phase
equilibriums in mixtures of poly(propylene oxide) with water (Russ.), Vysokomol. Soedin.,
Ser. A, 22, 2240, 1980.
____________________________________________________________________________________
1980BRO Broens, L., Altena, F.W., Smolders, C.A., and Koennen, D.M., Asymmetric membrane
structures as a result of phase separation phenomena, Desalination, 32, 33, 1980.
1980DON Dondos, A. and Izumi, Y., Study on polymer solutions in solvent mixtures in the vicinity of
the critical point of the solvents, 2., Makromol. Chem., 181, 701, 1980.
1980KUR Kuroiwa, S., Matsuda, H., and Fujimatsu, H., Temperature dependence of solution
properties of nonionic surface active agent, Nippon Kagaku Kaishi, (3), 362, 1980.
1980LAN Lang, J.C. and Morgan, R.D., Nonionic surfactant mixtures. I. Phase equilibria in C10E4-
H2O and closed-loop coexistence, J Chem. Phys., 73, 5849, 1980.
1980LEM Lemoyne, C., Friedrich, C., Halary, J.L., Noel, C., and Monnerie, L., Physicochemical
processes occurring during the formation of cellulose diacetate membranes. V., J. Appl.
Polym. Sci., 25, 1883, 1980.
1980MED Medved, Z.N. and Bulgakova, M.V., Phase equilibrium in aqueous solutions of
poly(ethylene oxide) derivatives possessing eng groups of different hydrophilic character
(Russ.), Zh. Prikl. Khim., 53, 1669, 1980.
1980POL Polyakov, V.I., Grinberg, V.Ya., and Tolstoguzov, V.B., Application of phase-volume-ratio
method for determining the phase diagram of water-casein-soybean globulins system,
Polym. Bull., 2, 757, 1980.
1980ZAS Zaslavsky, B.Yu., Miheeva, L.M., Mestechkina, N.M., Shchyukina, L.G., Chlenov, M.A.,
Kudryashov, L.I., and Rogozhin, S.V., Use of solute partition for comparative characte-
rization of several aqueous biphasic polymeric systems, J. Chromatogr., 202, 63, 1980.
1981HEU Heusch, R., Formation of crystalline, liquid-crystalline, and liquid phases during the
formation of hydrates of poly(glycol ethers) with different lengths of poly(glycol ether)
chains (Ger.), Makromol. Chem., 182, 589, 1981.
1981MED Medved, Z.N., Penzel, U., Denosiva, T.A., and Lebedev, V.S., Study of phase equilibrium
in mixtures of water and ethylene oxide-propylene oxide cooligomers (Russ.), Vysokomol.
Soedin., Ser. B, 23, 276, 1981.
1981SHI Shishov, A.K., Krivobokov, V.V., Chubarova, E.V., and Frenkel, S.Ya., Phase separation in
aqueous solutions of polyethylene glycol and dextran (Russ.), Vysokomol. Soedin., Ser. A,
23, 1197, 1981.
1982BUS Buscall, R. and Corner, T., The phase separation behavior of aqueous solutions of
polyacrylic acid and its partial sodium salts in the presence of sodium chloride, Eur. Polym.
J., 18, 967, 1982.
1982MEE Meerson, S.I., Shakhova, E.M., Prokof'eva, M.V., and Khin, N.N., Distribution of
electrolytes and phase equilibria in cellulose ethers-water-electrolyte systems (Russ.),
1982MIN Minh, L. V., Ohtsuka, T., Soyama, H., and Nose, T., Phase equilibrium of poly(acryl
amide)-poly(vinyl alcohol)-water system, Polym. J., 14, 575, 1982.
1983CON Conio, G., Bianchi, E., Ciferri, A., Tealdi, A., and Aden, M.A., Mesophase formation and
chain rigidity in cellulose and derivatives. 1. (Hydroxypropyl)cellulose in dimethylacet-
amide, Macromolecules, 16, 1264, 1983.
1983MIN Minh, L.V. and Nose, T., Phase equilibrium of poly(acrylic acid) partially neutralized by
NaOH-poly(vinyl alcohol)-water system, Polym. J., 15, 145, 1983.
1984BAM Bamberger, S., Seaman, G.V.F., Brown, J.A., and Brooks, D.E., The partition of sodium
phosphate and sodium chloride in aqueous dextran poly(ethylene glycol) two-phase
systems, J. Colloid Interface Sci., 99, 187, 1984.
1984COR Corti, M., Minero, C., and Degiorgio, V., Cloud point transition in nonionic micellar
solutions, J. Phys. Chem., 88, 309, 1984.
1984FLO Florin, E., Kjellander, R., and Eriksson, J.C., Salt effects on the cloud point of the
poly(ethylene oxide) + water system, J. Chem. Soc., Faraday Trans. I, 80. 2889, 1984.
1984GRI Grishchenkova, E.V., Antonov, Yu.A., Braudo, E.E., and Tolstoguzov, V.B., A study of
gelatine-methylcellulose compatibility in aqueous media, Nahrung, 28, 15, 1984.
1984HEF Hefford, R.J., Polymer mixing in aqueous solution, Polymer, 25, 979, 1984.
____________________________________________________________________________________
1984INA Inamura, I., Toki, K., Tamae, T., and Araki, T., Effects of molecular weight on the phase
equilibrium of a poly(vinyl alcohol)-poly(ethylene glycol)-water system, Polym. J., 16, 657,
1984.
1984ITO Itou, T. and Teramoto, A., Triphase equilibria in aqueous solutions of the rodlike polysac-
charide schizophyllan, Macromolecules, 17, 1419, 1984.
1984SHI Shiomi, T., Imai, K., Watanabe, C., and Miya, M., Thermodynamic and conformational
properties of partially butyralized poly(vinyl alcohol) in aqueous solution, J. Polym. Sci.
Polym. Phys. Ed., 22, 1305, 1984.
1985FUR Furusawa, K. and Tagawa, T., Adsorption behavior of water soluble polymers with lower
critical solution temperature, Colloid Polym. Sci., 263, 353, 1985.
1985HAM Hamano, K., Kuwahara, N., Koyama, T., and Harada, S., Critical behaviors in the two-
phase region of a micellar solution, Phys. Rev. A, 32, 3168, 1985.
1985SHK Shkinev, V.M., Molochnikova, N.P., Zvarova, T.I., Spivakov, B.Ya., Myasoedov, B.F., and
Zolotov, Yu.A., Extraction of complexes of lanthanides and actinides with arsenazo III in
an ammonium sulfate-poly(ethylene glycol)-water two-phase system, J. Radioanal. Nucl.
Chem., 88, 115, 1985.
1985VED Vedikhina, L.I., Kurmaeva, A.I., and Barabanov, V.P., Phase separation in solutions of
polyampholytes of acrylic acid-2-methyl-5-vinylpyridine copolymers (Russ.), Vysokomol.
Soedin., Ser. A, 27, 2131, 1985.
1985WAL Walter, H., Brooks, D.E., and Fischer, D., Partitioning in Aqueous Two-Phase Systems:
Theory, Methods, Uses, and Applications to Biotechnology, Academic Press, New York,
1985.
1985WIJ Wijmans, J. G., Kant, J., Mulder, M.H.V., and Smolders, C.A., Phase separation pheno-
mena in solutions of polysulfone in mixtures of a solvent and a nonsolvent. Relationship
with membrane formation, Polymer, 26, 1539, 1985.
1985ZHU Zhubanov, B.A., Solomin, V.A., Lyakh, E.A., and Cherdabaev, A.S., Phase behavior of
polyamic acid solutions in cyclic ethers (Russ.), Vestn. Akad. Nauk Kaz. SSR, (9) 19, 1985.
New York, 1986.
1986AN1 Andreeva, V.M., Budnitskii, G.A., Tager, A.A., Shil'nikova, N.I., Bakunov, V.A., and
Maiboroda, L.F., Phase separation and structure of cellulose acetate solutions used for
formation of hollow selective fibers (Russ.), Vysokomol. Soedin., Ser. B, 28, 606, 1986.
1986AN2 Andreeva, V.M., Tsilipotkina, M.V., Tager, A.A., Safronova, V.A., and Shil'nikova, N.I.,
Effect of phase separation of cellulose acetate and polyarylate solutions on the porous
structure and strength of films cast from them (Russ.), Vysokomol. Soedin., Ser. A ,28,
2147, 1986.
1986CAR Carlson, A., Karlström, G., and Lindmann, B., Synergistic surfactant-electrolyte effect in
polymer solutions, Langmuir, 2, 536, 1986.
1986FIR Firman, P. and Kahlweit, M., Phase behavior of the ternary system H2O-oil-polypropylene
glycol (PPG), Colloid Polym. Sci., 264, 936, 1986.
1986GUS Gustafsson, A. and Wennerström, H., Aqueous polymer two-phase systems in biotechno-
logy, Fluid Phase Equil., 29, 365, 1986.
1986INA Inamura, I., Liquid-liquid phase separation and gelation in the poly(vinyl alcohol)-poly
(ethylene glycol)-water-system. Dependence on molecular weight of poly(ethylene glycol),
Polym. J., 18, 269, 1986.
1986KAL Kalichevsky, M.T., Oorford P.D., and Ring, S.G., The incompatibility of concentrated
aqueous solutions of dextran and amylose and its effect on amylose gelation, Carbohydr.
Polym., 6, 145, 1986.
1986MAT Mattiasson, B. and Ling, T.G.I., Efforts to integrate affinity interactions with conventional
separation technologies. Affinity partition using biospecific chromatographic particles in
aqueous two-phase systems, J. Chromatogr., 376, 235, 1986.
____________________________________________________________________________________
1986POL Polyakov, V.I., Popello, I.A., Grinberg, V.Ya., and Tolstoguzov, V.B., Thermodynamic
compatibility of proteins in aqueous medium, Nahrung, 30, 365, 1986.
1986REU Reuvers, A.J., Altena, F.W., and Smolders, C.A., Demixing and gelation behavior of ternary
cellulose acetate solutions, J. Polym. Sci.: Part B: Polym. Phys., 24, 793, 1986.
1986SCH Schulz, D.N., Peiffer, D.G., Agarwal, P.K., Larabee, J, Kaladas, J.J., Soni, L., Handwerker,
B., and Garner, R.T., Phase behavior and solution properties of sulfobetaine polymers,
Polymer, 27, 1764, 1986.
1986TJE Tjerneld, F., Berner, S., Cajarville, A., and Johansson, G., New aqueous two-phase system
based on hydroxypropyl starch useful in enzyme purification, Enzyme Microb. Technol., 8,
417, 1986.
1986VSH Vshivkov, S.A. and Safronov, A.P., Fasovoe ravnovesie rastvorov polimerov v
staticheskikh usloviyakh i v rezhime techeniya, Vysokomol. Soedin., Ser. A, 28, 2516, 1986.
1986ZAS Zaslavskii, B.Yu., Bagirov, T.O., Borovskaya, A.A., Gasanova, G.Z., Gulaeva, N.D., Levin,
V.Yu., and Rogozhin, S.V., Aqueous biphasic systems formed by nonionic polymers. I.,
Colloid Polym. Sci., 264, 1066, 1986.
1986ZHU Zhuravskaya, N.A., Kiknadze, E.V., Antonov, Yu.A., and Tolstoguzov, V.B., Concentration
of proteins as a result of the phase separation of water-protein-polysaccharide systems. 1.
Phase equilibria in water-milk proteins-polysaccharide systems, Nahrung, 30, 591, 1986.
1987ANA Ananthapadmanabhan, K.P. and Goddard, E.D., The relationship between clouding and
aqueous biphase formation in polymer solutions, Coll. Surfaces, 25, 393, 1987.
1987ATA Ataman, M., Properties of aqueous salt solutions of poly(ethylene oxide). Cloud points, θ-
temperatures, Colloid Polym. Sci., 265, 19, 1987.
1987BAS Baskir, J.N., Hatton, T.A., and Suter, U.W., Thermodynamics of the separation of
biomaterials in two-phase aqueous polymer systems: effect of the phase-forming polymers,
Macromolecules, 20, 1300, 1987.
1987COW Cowie, J.M.G., Mohain, M.A., and McEwen, I.J., Alcohol-water cosolvent systems for
poly(methyl methacrylate), Polymer, 28, 1569, 1987.
1987GER Gerasimov, V.K. and Chalykh, A.E., Diagramma fazovogo sostoyaniya sistemy
poliefiruretan-dimetilformamid-voda, Vysokomol. Soedin., Ser. B, 29, 234, 1987.
1987GRI Grinberg, V.Ya., Dotdaev, S.Kh., Borisov, Yu.A., and Tolstoguzov, V.B., Possibility of the
determination of Flory-Huggins interaction parameters for the polymer-polymer-solvent
system from its binodal (Russ.), Vysokomol. Soedin., Ser. B, 29, 145, 1987.
1987JAH Jahns, E. and Finkelmann, H., Lyotropic liquid crystalline phase behavior of a polymeric
amphiphile polymerized via their hydrophilic ends, Colloid Polym. Sci., 265, 304, 1987.
1987KAL Kalichevsky, M.T. and Ring, S.G., Incompatibility of amylose and amylopectin in aqueous
solution, Carbohydr. Res., 162, 323, 1987.
1987KAN Kang, C.H., Sandler, S.I., Phase behavior of aqueous two-polymer systems, Fluid Phase
Equil., 38, 245, 1987.
1987KLE Klenin, V.I., Kolnibolotchuk, N.K., Solonina, N.A., Ivanyuta, Yu.F., and Panina, N.I.,
Phase analysis of the polyethylene glycol-water system (Russ.), Vysokomol. Soedin., Ser. A,
29, 636, 1987.
1987LIS Li, S., Jiang, C., and Zhang, Y., The investigation of solution thermodynamics for the
polysulfone-DMAC-water system, Desalination, 62, 79, 1987.
1987LOP Lopyrev, V.A., Shaglaeva, N.S., Tager, A.A., Kogan, B.R., and Gelman, A.S., Phase
equilibrium of polyethylene glycol solutions in water-glycerol and water-ethylene glycol
binary mixtures (Russ.), Vysokomol. Soedin., Ser. B, 29, 503, 1987.
1987PAN Panina, N.I., Lojev, A.M., Averjanova, V.M., and Zelenev, V.M., Vyzkum fazovych
rovnvoah v polymernich systemech, Plasty Kauch., 24(2), 36, 1987.
1987PRI Priest, J.H., Murray, S.L., Nelson, R.J., and Hoffman, A.S., Lower critical solution
temperatures of aqueous copolymers of N-isopropylacrylamide and other N-substituted
acrylamides, ACS Symp. Ser., 350, 255, 1987.
____________________________________________________________________________________
1987REU Reuvers, A.J. and Smolders, C.A., Formation of membranes by means of immersion
precipitation. Part II. The mechanism of formation of membranes prepared from the system
cellulose acetate-acetone-water, J. Membrane Sci., 34, 67, 1987.
1987SJO Sjöberg, A., Karlström, G., Wennerström, H., and Tjerneld, F., Compatibility of aqueous
poly(ethylene glycol) and dextran at elevated temperatures, Polym. Commun., 28, 263, 1987.
1987ZA1 Zaslavsky, B.Yu., Miheeva, L.M., Gasanova, G.Z., and Mahmudov, A.U., Influence of
inorganic electrolytes on partitioning of non-ionic solutes in an aqueous dextran-
poly(ethylene glycol) biphasic system, J. Chromatogr., 392, 95, 1987.
1987ZA2 Zaslavsky, B.Yu., Miheeva, L.M., Gasanova, G.Z., and Mahmudov, A.U., Effect of
polymer composition on the relative hydrophobicity of the phases of the biphasic system
aqueous dextran-poly(ethylene glycol), J. Chromatogr., 403, 123, 1987.
1987ZA3 Zaslavskii, B.Yu., Mahmudov, A.U., Bagirov, T.O., Borovskaya, A.A., Gasanova, G.Z.,
Gulaeva, N.D., Levin, V.Yu., Mestechkina, N.M., Miheeva, L.M., and Rogozhin, S.V.,
Aqueous biphasic systems formed by nonionic polymers. II. Concentration effects of
inorganic salts on phase separation, Colloid Polym. Sci., 265, 548, 1987.
1988ABB Abbott, N.L. and Hatton, T.A., Liquid-liquid extraction for protein separations, Chem. Eng.
Progr., (8), 31, 1988.
1988FUJ Fujimatsu, H., Ogasawara, S., and Kuroiwa, S., Lower critical solution temperature (LCST)
and theta temperature of aqueous solutions of nonionic surface active agents of various
polyoxyethylene chain lengths, Colloid Polym. Sci., 266, 594, 1988.
1988KAN Kang, C.H. and Sandler, S.I., Effects of polydispersivity on the phase behavior of aqueous
two-phase polymer systems, Macromolecules, 21, 3088, 1988.
1988KIN King, R.S., Blanch, H.W., and Prausnitz, J.M., Molecular thermodynamics of aqueous two-
phase systems for bioseparations, AIChE-J., 34, 1585, 1988.
1988LAR Larsson, M. and Mattiasson, B., Characterization of aqueous two-phase systems based on
polydisperse phase forming polymers: enzymatic hydrolysis of starch in a PEG-starch
aqueous two-phase system, Biotechnol. Bioeng., 31, 979, 1988.
1988LIN Lin, P., Clash, C., Pearce, E.M., Kwei, T.K., and Aponte, M.A., Solubility and miscibility
of poly(ethyl oxazoline), J. Polym. Sci.: Part B: Polym. Phys., 26, 603, 1988.
1988MAK Makhmudov, A.U., Gasanova, G.Z., Zaslavskii, B.Yu., and Mikheeva, L.M., Effect of the
polymeric composition on relative water repellency of phases of the dextran-polyethylene
glycol aqueous two-phase system (Russ.), in Fiz. Elementar. Chastits, Atomov i Molekul,
Baku, 1988, 90.
1988MOL Molochnikova, N.P., Shkinev, V.M., Spivakov, V.Ya., Zolotov, Yu.A., and Myasoedov,
V.F., Extraction of complexes of actinides and lanthanides by the aqueous two-phase
system potassium carbonate-poly(ethylene glycol)-water (Russ.), Radiokhim., 30, 60, 1988.
1988SZL Szlag, D.C. and Giuliano, K.A., A low-cost aqueous two phase system for enzyme
extraction, Biotechnol. Techn., 2, 277, 1988.
1988SWI Swinyard, B.T. and Barrie, J.A., Phase separation in non-solvent/dimethylformamide/poly-
ethersulphone and non-solvent/dimethylformamide/polysulphone systems, Brit. Polym. J.,
20, 317, 1988.
1988TAN Tanaka, H. and Nishi, T., Anomalous phase separation behavior in a binary mixture of
poly(vinyl methyl ether) and water under deep quench condition, Jap. J. Appl. Phys., 27,
L1787, 1988.
1988VSH Vshivkov, S.A. and Balashova, M.I., Phase equilibrium of the polyethylene glycol-glycerol-
water system in a mechanical field (Russ.), Vysokomol. Soedin., Ser. B, 30, 689, 1988.
1988ZAS Zaslavsky, B.Yu., Miheeva, L.M., Aleschko-Ozhevskii, Yu.P., Mahmudov, A.U., Bagirov,
T.O., and Garaev, E.S., Distribution of inorganic salts between the coexisting phases of
aqueous polymer two-phase systems. Interrelationship between the ionic and polymer
composition of the phases, J. Chromatogr., 439, 267, 1988.
1988ZEM Zeman, L. and Tkacik, G., Thermodynamic analysis of a membrane-forming system water/
N-methyl-2-pyrrolidone/polyethersulfone, J. Mebrane Sci., 36, 119, 1988.
____________________________________________________________________________________
1988ZGA Zgadzai, O.E., Maklakov, A.E., Skirda, V.D., and Chalykh, A.E., Self-diffusion and phase
separation in aqueous solutions of polyoxypropylenediol (Russ.), Vysokomol. Soedin., Ser.
A, 30, 104, 1988.
1989BAS Baskir, J.N., Hatton, T.A., and Suter, U.W., Thermodynamics of the partitioning of
biomaterials in two-phase aqueous polymer systems: comparison of lattice model to
experimental data, J. Phys. Chem., 93, 2111, 1989.
1989DIA Diamond, A.D. and Hsu, J.T., Fundamental studies of biomolecule partitioning in aqueous
two-phase systems, Biotechnol. Bioeng., 34, 1000, 1989.
1989FOR Fortin, S. and Charlet, G., Phase diagram of aqueous solutions of (hydroxypropyl)cellulose,
1989FUJ Fujishige, S., Kubota, K., and Ando, I., Phase transition of aqueous solutions of poly(N-iso-
propylacrylamide) and poly(N-isopropylmethacrylamide), J. Phys. Chem., 93, 3311, 1989.
1989GAI Gaides, G.E. and McHugh, A.J., Gelation in an amorphous polymer. A discussion of its
relation to membrane formation, Polymer, 30, 2118, 1989.
1989HA1 Haynes, C.A., Beynon, R.A., King, R.S., Blanch, H.W., and Prausnitz, J.M., Thermody-
Chem., 93, 5612, 1989.
1989HA2 Haynes, C.A., Blanch, H.W., and Praunsitz, J.M., Separation of protein mixtures by
extraction: thermodynamic properties of aqueous two-phase polymer systems containing
salts and proteins, Fluid Phase Equil., 53, 463, 1989.
1989INO Inomata, H., Yagi, Y., Otake, K., Konno, M., and Saito, S., Spinodal decomposition of an
aqueous solution of poly(N-isopropylacrylamide), Macromolecules, 22, 3494, 1989.
1989KAN Kang, C.-H., Lee, C.-K., and Sandler, S.I., Polydispersity effects on the behavior of aqueous
two-phase two-polymer systems, Ind. Eng. Chem. Res., 28, 1537, 1989.
1989LIN Ling, T.G.I., Nilsson, H., and Mattiasson, B., Reppal PES − a starch derivative for aqueous
two-phase systems, Carbohydr. Polym., 11, 43, 1989.
1989NIF Nifant'eva, T.I., Matoushova, V., Adamtsova, Z., and Shkinev, V.M., Two-phase aqueous
systems on the basis of polyethylene glycol and inorganic salts (Russ.), Vysokomol. Soedin.,
Ser. A, 31, 2131, 1989.
1989PER Perrau, M.B., Iliopoulos, I., and Audebert, R., Phase separation of polyelectrolyte/nonionic
polymer systems in aqueous solution: effects of salt and charge density, Polymer, 30, 2112,
1989.
1989ROE Rösink, H.D.W., Microfiltration membrane development and module design, Proefschrift,
Universiteit Twente, 1989.
1989RON Ronner, J.A., Wassink, S.G., and Smolders, C.A., Investigation of liquid-liquid demixing
and aggregate formation in a membrane-forming system by means of pulse-induced critical
scattering (PICS), J. Membrane Sci., 42, 27, 1989.
1989SJ1 Sjöberg, A. and Karlström, G., Temperature dependence of phase equilibria for the system
poly(ethylene glycol)/dextran/water. A theoretical and experimental study, Macromolecules,
22, 1325, 1989.
1989SJ2 Sjöberg, A., Karlström, G., and Tjerneld, F., Effects on the cloud point of aqueous
poly(ethylene glycol) solutions upon addition of low molecular weight saccharides,
1989VSH Vshivkov, S.A., Pastukhnova, L.A., and Titov, R.V., Influence of the mechanical field on
the phase equilibrium of polyether mixtures and the cellulose diacetate-acetone-water
system (Russ.), Vysokomol. Soedin., Ser. A, 31, 1404, 1989.
1989ZAS Zaslavsky, B.Yu., Bagirov, T.O., Borovskaya, A.A., Gulaeva, N.D., Miheeva, L.H.,
Mahmudov, A.U., and Rodnikova, M.N., Structure of water as a key factor of phase
separation in aqueous mixtures of two nonionic polymers, Polymer, 30, 2104, 1989.
____________________________________________________________________________________
1990BOO Boomgaard, Th. van den, Boom, R.M., and Smolders, C.A., Diffusion and phase separation
in polymer solution during asymmetric membrane formation, Makromol. Chem., Macromol.
Symp., 39, 271, 1990.
1990CAB Cabezas, H., Kabiri-Badr, M., and Szlag, F.C., Statistical thermodynamics of phase
separation and ion partitioning in aqueous two-phase systems, Bioseparation, 1, 227, 1990.
1990EIT Eiteman, M.A. and Gainer, J.L., Peptide hydrophobicity and partitioning in poly(ethylene
glycol)/magnesium sulfate aqueous two-phase systems, Biotechnol. Progr., 6, 479, 1990.
1990FOR Forciniti, D., Hall, C.K., and Kula, M.R., Interfacial tension of poly(ethylene glycol)-
dextran-water systems: influence of temperature and polymer molecular weight, J.
Biotechnol., 16, 279, 1990.
1990FUR Furuya, T., Iwai, Y., Shimizu, T., and Arai, Y., Partition coefficients of α-amylase in the
aqueous two-phase system containing dextran and polyethylene glycol, Kagaku Kogaku
Ronbunshu, 16, 830, 1990.
1990INO Inomata, H., Goto, S., and Saito, S., Phase transition of N-substituted acrylamide gels,
1990JAC Jackson, C.L. and Shaw, M.T., The phase behaviour and gelation of a rod-like polymer in
solution and implications for microcellular foam morphology, Polymer, 31, 1070, 1990.
1990KAR Karlström, G., Carlsson, A., and Lindman, B., Phase diagrams of nonionic polymer-water
systems. Experimental and theoretical studies of the effects of surfactants and other
cosolutes, J. Phys. Chem., 94, 5005, 1990.
1990LEI Lei, X., Diamond, A.D., and Hsu, J.T., Equilibrium phase behavior of the poly(ethylene
glycol)/potassium phosphate/water two-phase system at 4°C, J. Chem. Eng. Data, 35, 420,
1990.
1990MAA Maasen, H.-P., Yang, J.L., and Wegner, G., The structure of poly(ethylene oxide)-poly
(dimethyl siloxane) triblock copolymers in solution, Makromol. Chem., Macromol. Symp.,
39, 215, 1990.
1990MAR Marchetti, M., Prager, S., and Cussler, E.L., Thermodynamic predictions of volume changes
in temperature-sensitive gels. I. Theory, II. Experiments, Macromolecules, 23, 1760, 3445,
1990.
1990OTA Otake, K., Inomata, H., Konno, M., and Saito, S., Thermal analysis of the volume phase
transition with N-isopropylacrylamide gels, Macromolecules, 23, 283, 1990.
1990QIN Qin, J. and Jiang, C., Investigation of phase diagrams of polysulfone membrane forming
systems (Chin.), Membrane Sci. Technol., Lanzhou, 10(3), 13, 1990.
1990RAG Raghava Rao, K.S.M.S., Stewart, R.M., and Todd, P., Electrokinetic demixing of two-phase
aqueous polymer systems. I., Sep. Sci. Technol., 25, 985, 1990.
1990SAM Samii, A.A., Lindman, B., and Karström, G., Phase behavior of some nonionic polymers in
non-aqueous solvents, Prog. Coll. Polym. Sci., 82, 280, 1990.
1990SCH Schild, H.G. and Tirrell, D.A., Microcalorimetric detection of lower critical solution
temperatures in aqueous polymer solutions, J. Phys. Chem., 94, 4352, 1990.
1990SIM Simek, L., Petrik, S., Hadobas, F., and Bohdanecky, M., Solubility in water of triblock
(PEP) copolymers of ethylene and propylene oxides, Eur. Polym. J., 26, 375, 1990.
1990TAG Tager, A.A., Safronov, A.P., Sharina, S.V., and Galaev, I.Yu., Thermodynamics of aqueous
solutions of polyvinylcaprolactam (Russ.), Vysokomol. Soedin., Ser. A, 32, 529, 1990.
1990WIN Winnik, F.M., Fluorescence studies of aqueous solutions of poly(N-isopropylacylamides)
below and above their LCST, Macromolecules, 23, 233, 1990.
1991BAE Bae, Y.C., Lambert, S.M., Soane, D.S., and Prausnitz, J.M., Cloud-point curves of polymer
solutions from thermooptical measurements, Macromolecules, 24, 4403, 1991.
1991BOT Bottino, A., Camera-Roda, G., Capanelli, G., and Munari, S., The formation of microporous
polyvinylidene fluoride membranes by phase separation, J. Membrane Sci., 57, 1, 1991.
1991CON Connemann, M., Gaube, J., Leffrang, U., Müller, S., and Pfennig, A., Phase equilibria in the
system poly(ethylene glycol) + dextran + water, J. Chem. Eng. Data, 36, 446, 1991.
____________________________________________________________________________________
1991EAG Eagland, D. and Crowther, N.J., Influence of composition and segment distribution upon
lower critical demixing of aqueous poly(vinyl alcohol-stat-vinyl acetate) solutions, Eur.
Polym. J., 27, 299, 1991.
1991EIT Eiteman, M.A. and Gainer, J.L., Predicting partition coefficients in polyethylene glycol-
potassium phosphate aqueous two-phase systems, J. Chromatogr., 586, 341, 1991.
1991FO1 Forciniti, D., Hall, C.K., and Kula, M.R., Influence of polymer molecular weight and
temperature on phase composition in aqueous two-phase systems, Fluid Phase Equil., 61,
243, 1991.
1991FO2 Forciniti, D., Hall, C.K., and Kula, M.R., Analysis of polymer molecular weight
distributions in aqueous two-phase systems, J. Biotechnol., 20, 151, 1991.
1991GAO Gao, Y.-L., Peng, Q.-H., Li, Z.-C., Li, Y.-G., Thermodynamics of ammonium sulfate-
polyethylene glycol aqueous two-phase systems. Part 1. Experiment and correlation using
extended UNIQUAC equation, Fluid Phase Equil., 63, 157, 1991.
1991HAR Hartounian, H., and Sandler, S.I., Polymer fractionation in aqueous two-phase polymer
systems, Biotechnol. Progr., 7, 279, 1991.
1991HOU Hourdet, D., Muller, G., Vincent, J.C., Avrillon, R., and Robert, E., Characterization of
polyimides in solution. Relation with the preparation of asymmetric membranes, in Poly-
imides and other High-Temperature Polymers, Elsevier Sci. Publ., Amsterdam, 1991, 507.
1991LA1 Lau, W.W.Y., Guiver, M.D., and Matsuura, T., Phase separation in polysulfone/
solvent/water and polyethersulfone/solvent/water systems, J. Membrane Sci., 59, 219, 1991.
1991LA2 Lau, W.W.Y., Guiver, M.D., and Matsuura, T., Phase separation in carboxylated
polysulfone/solvent/water systems, J. Appl. Polym. Sci., 42, 3215, 1991.
1991LOU Louai, A., Sarazin, D., Pollet, G., Francois, J., and Moreaux, F., Properties of ethylene
oxide-propylene oxide statistical copolymers in aqueous solution, Polymer, 32, 703, 1991.
1991PAT Pathak, S.P., Sudha, S., Sawant, S.B., and Joshi, J.B., New salt-polyethylene glycol systems
for two-phase aqueous extraction, Chem. Eng. J., 46, B31, 1991.
1991PIC Piculell, L., Nilsson, S., Falck, L., and Tjerneld, F., Phase separation in aqueous mixtures of
similarly charged polyelectrolytes, Polym. Commun., 32, 158, 1991.
1991RAG Raghava Rao, K.S.M.S., Stewart, R., and Todd, P., Electrokinetic demixing of two-phase
aqueous polymer systems. II., Sep. Sci. Technol., 26, 257, 1991.
1991ROB Robitaille, L., Turcotte, N., Fortin, S., and Charlet, G., Calorimetric study of aqueous
solutions of (hydroxypropyl)cellulose, Macromolecules, 24, 2413, 1991.
1991SA1 Samii, A.A., Karlström, G., and Lindman, B., Phase behavior of a nonionic cellulose ether
in nonaqueous solution, Langmuir, 7, 653, 1991.
1991SA2 Samii, A.A., Karlström, G., and Lindman, B., Phase behavior of nonionic block copolymer
in a mixed-solvent system, J. Phys. Chem., 95, 7887, 1991.
1991SC1 Schild, H.G., Muthukumar, M., and Tirrell, D.A., Cononsolvency in mixed aqueous
solutions of poly(N-isopropylacrylamide), Macromolecules, 24, 948, 1991.
1991SC2 Schild, H.G. and Tirrell, D.A., Interaction of poly(N-isopropylacrylamide) with sodium n-
alkyl sulfates in aqueous solution, Langmuir, 7, 665, 1991.
1991SC3 Schubert, K.-V., Strey, R., and Kahlweit, M., A new purification technique for alkyl poly-
glycol ethers and miscibility gaps for water CiEj, J. Colloid Interface Sci., 141, 21, 1991.
1991TAG Tager, A.A., Safronov, A.P., Berezyuk, E.A., and Galaev, I.Yu., Hydrophobic interactions
and lower critical solution temperatures of aqueous polymer solutions (Russ.), Vysokomol.
Soedin., Ser. B, 33, 572, 1991.
1991TH1 Thalberg, K., Lindmann, B., and Karlström, G., Phase behavior of systems of cationic
surfactant and anionic polyelectrolyte: influence of surfactant chain length and
polyelectrolyte molecular weight, J. Phys. Chem., 95, 3370, 1991.
1991TH2 Thalberg, K., Lindmann, B., and Karlström, G., Phase diagram of a system of cationic
surfactant and anionic polyelectrolyte: the effect of salt, J. Phys. Chem., 95, 6004, 1991.
____________________________________________________________________________________
1991TOL Tolstoguzov, V. B., Functional properties of food proteins and role of protein-
polysaccharide interaction, Food Hydrocolloids, 4, 429, 1991.
1991WOR Wormuth, K.R., Patterns of phase behavior in polymer and amphiphile mixtures, Langmuir,
7, 1622, 1991.
1992BEN Benkhira, A., Franta, E., and Francois, J., Polydioxolane in aqueous solutions. 1. Phase
diagram, Macromolecules, 25, 5697, 1992.
1992INO Inomata, H., Goto, S., Otake, K., and Saito, S., Effect of additives on phase transition of N-
isopropylacrylamide gels, Langmuir, 8, 687, 1992.
1992MAL Malmsten, M. and Lindman, B., Self-assambly of aqueous block copolymer solutions,
1992MOO Moore, I.P.T., Gilchrist, A., Hawtin, J., Nienow, A., Kuboi, R., and Komasawa, I., Phase
inversion behavior of aqueous two-phase systems, Process Metall., 7B, 1869, 1992.
1992MUE Müller, K.F, Thermotropic aqueous gels and solutions of N,N-dimethylacrylamide-acrylate
copolymers, Polymer, 33, 3470, 1992.
1992SNY Snyder, S.M., Cole, K.D., and Szlag, D.C., Phase compositions, viscosities, and densities
for aqueous two-phase systems composed of polyethylene glycol and various salts at 25°C,
J. Chem. Eng. Data, 37, 268, 1992.
1992VIA Viallat, A., Cohen Addad, J.P., Bom, R.P., and Perez, S., Transient phase diagram of
ternary polyetherimide solutions: effect of polymer association, Polymer, 33, 2784, 1992.
1992YAN Yang, J., Wegner, G., and Koningsveld, R., Phase behavior of ethylene oxide-dimethyl-
siloxane PEO-PDMS-PEO triblock copolymers with water, Colloid Polym. Sci., 270, 1080,
1992.
1992ZAS Zaslavskii, B.Yu., Borovskaya, A.A., Gulaeva, N.D., and Miheeva, L.M., Physicochemical
features of solvent media in the phases of aqueous polymer two-phase systems, Biotechnol.
Bioeng., 40, 1, 1992.
1992ZHA Zhang, K.-W., Karlström, G., and Lindman, B., Phase behaviour of systems of a non-ionic
surfactant and a non-ionic polymer in aqueous solution, Colloids Surfaces, 67, 147, 1992.
1993BAE Bae,Y.C., Shim, J.J., Soane, D.S., and Prausnitz, J.M., Representation of vapor-liquid and
liquid-liquid equilibria for binary systems containing polymers: applicability of an extended
Flory-Huggins equation, J. Appl. Polym. Sci., 47, 1193, 1993.
1993BOO Boom, R.M., van den Boomgard, Th., van den Berg, J.W.A., and Smolders, C.A.,
Linearized cloudpoint curve correlation for ternary systems consisting of one polymer, one
solvent and one non-solvent, Polymer, 34, 2348, 1993.
1993DIS Dissing, U. and Mattiasson, B., Poly(ethyleneimine) as a phase-forming polymer in aqueous
two-phase systems, Biotechnol. Appl. Biochem., 17, 15, 1993.
1993DUR Durrani, C.M., Prystupa, D.A., Donald, A.M., and Clark, A.H., Phase diagram of mixtures
of polymers in aqueous solution using Fourier transform spectroscopy, Macromolecules, 26,
981, 1993.
1993FEI Feil, H., Bae, Y.H., Feifen, J., and Kim, S.W., Effect of comonomer hydrophobicity and
ionization on the lower critical solution temperature of N-isopropylacrylamide copolymers,
1993GA1 Gaube, J., Höchemer, R., Keil, B., and Pfennig, A., Polydispersity effects in the system
poly(ethylene glycol) + dextran + water, J. Chem. Eng. Data, 38, 207, 1993.
1993GA2 Gaube, J., Pfennig, A., and Stumpf, M., Thermodynamics of aqueous poly(ethylene glycol)-
dextran two-phase systems using the consistent osmotic virial equation, Fluid Phase Equil.,
83, 365, 1993.
1993HAR Hartounian, H., Flöter, E., Kaler, E.W., and Sandler, S.I., Effect of temperature on the
phase equilibrium of aqueous two-phase polymer systems, AIChE-J., 39, 1976, 1993.
1993HAY Haynes, C.A., Benitez, F.J., Blanch, H.W., and Prausnitz, J.M., Application of integral-
equation theory to aqueous two-phase partitioning systems, AIChE-J., 39, 1593, 1993.
____________________________________________________________________________________
1993HEM He, M., Hill, R. M., Lin, Z., Scriven, L.E., and Davis, H.T., Phase behavior and micro-
structure of polyoxyethylene trisiloxane surfactants in aqueous solution, J. Phys. Chem., 97,
8820, 1993.
1993JOH Johansson, H.O., Karlström, G., and Tjerneld, F., Experimental and theoretical study of
phase separation in aqueous solutions of clouding polymers and carboxylic acids,
1993KAW Kawaguchi, S., Toui, S., Onodera, M., Ito, K., and Minakata, A., Phase separation behavior
in neutralized poly(maleic acid) aqueous solutions, Macromolecules, 26, 3081, 1993.
1993KIT Kitahara, T., Kamihara, M., and Takeuchi, H., Application of Pluronic F68 for aqueous
two-phase extraction of proteins, J. Chem. Eng. Japan, 26, 183, 1993.
1993MAL Malmsten, M., Linse, P., and Zhang, K.W., Phase behavior of aqueous poly(ethylene oxide)/
poly(propylene oxide) solutions (exp. data by P. Linse), Macromolecules, 26, 2905, 1993.
1993MAT Matsuo, M., Kawase, M., Sugiura, Y., Takematsu, S., and Hara, C., Phase separation
behavior of poly(vinyl alcohol) solutions in relation to the drawability of films prepared
from the solutions, Macromolecules, 26, 4461, 1993.
1993MED Medin, A.S. and Janson, J.-C., Studies on aqueous polymer two-phase systems containing
agarose, Carbohydr. Polym., 22, 127, 1993.
1993MIS Mishima, K., Mori, S., Nagayusa, S., Eya, H., and Nagatani, M., Partition coefficient of
benzene derivatives in aqueous two-phase systems containing polyethylene glycol, Kagaku
Kogaku Ronbunshu, 19, 1171, 1993.
1993NEU Neuchl, C. and Mersmann, A., Phase equilibria of narrowly distributed dextranes in the
ternary system dextran-water-ethanol, Fluid Phase Equil., 90, 389, 1993.
1993PAR Park, T.G. and Hoffman, A.S., Sodium chloride-induced phase transition in nonionic
poly(N-isopropylacrylamide) gel, Macromolecules, 26, 5045, 1993.
1993PAS Pashkin, I.I., Kirsh, Yu.E., Zubov, V.P., Anisimova, T.V., Kuzkina, I.F., Voloshina, Ya.P.,
and Krylov, A.V., Synthesis of water-soluble N-vinylcaprolactam-based copolymers and
physicochemical properties of their aqueous solutions (Russ.), Vysokomol. Soedin., Ser. A,
35, 481, 1993.
1993SAK Sakellariou, P., Hassan, A., and Rowe, R.C., Phase separation and polymer interactions in
aqueous poly(vinyl alcohol)/hydroxypropylmethylcellulose blend, Polymer, 34, 1240, 1993.
1993SAR Saraiva, A., Persson, O., and Fredenslund, A., An experimental investigation of cloud-point
curves for the poly(ethylene glycol)/water system at varying molecular weight distributions,
Fluid Phase Equil., 91, 291, 1993.
1993TA1 Tager, A.A., Klyuzhin, E.S., Adamova, L.V., and Safronov, A.P., Thermodynamics of
dissolution of acrylic acid-methyl acrylate copolymers in water (Russ.), Vysokomol. Soedin.,
Ser. B, 35, 1357, 1993.
1993TA2 Tager, A.A., Safronov, A.P., Sharina, S.V., and Galaev, I.Yu., Thermodynamic study of
poly(N-vinyl caprolactam) hydration at temperatures close to lower critical solution
temperature, Colloid Polym. Sci., 271, 868, 1993.
1993VOR Voros, N., Proust, P., and Fredenslund, A., Liquid-liquid phase equilibria of aqueous two-
phase systems containing salts and polyethylene glycol, Fluid Phase Equil., 90, 333, 1993.
1994ALR Alred, P.A., Kozlowski, A., Harris, J.M., and Tjerneld, F., Application of temperature-
induced phase partitioning at ambient temperature for enzyme purification, J. Chromatogr.
A, 659, 289, 1994.
1994ATK Atkinson, L. and Johns, M.R., Trypsin and α-chymotrypsin partitioning in polyethylene
glycol/maltodextrin aqueous-two-phase systems, Trans. Inst. Chem. Eng., Part C, Food
Biopolym. Process., 72 (C2), 106, 1994.
1994AXE Axelos, M.A.V., Mestdagh, M.M., and Francois, J., Phase diagrams of aqueous solutions of
polycarboxylates in the presence of divalent cations, Macromolecules, 27, 6594, 1994.
1994BO1 Boom, R.M., Van den Boomgard, Th., and Smolders, C.A., Mass transfer and thermody-
namics during immersion precipitation for a two-polymer system. Evaluation with the
system PES-PVP-NMP-water, J. Membrane Sci., 90, 213, 1994.
____________________________________________________________________________________
1994BO2 Boom, R.M., Reinders, H.W., Rolevink, H.H.W., Van den Boomgard, Th., and Smolders,
C.A., Equilibrium thermodynamics of a quaternary mambrane-forming system with two
polymers. 2. Experiments, Macromolecules, 27, 2041, 1994.
1994BOR Borchard, W., Frahn, S., and Fischer, V., Determination of cloud-point, shadow and other
coexistence curves in multicomponent systems from measurements of phase volume ratios,
Macromol. Chem. Phys., 195, 3311, 1994.
1994CH1 Cheluget, E.L., Gelinas, S., Vera, J.H., and Weber, M.E., Liquid-liquid equilibrium of
aqueous mixtures of poly(propylene glycol) with NaCl, J. Chem. Eng. Data, 39, 127, 1994.
1994CH2 Cheng, L.-P., Dwan, A.-H., and Gryte, C.C., Isothermal phase behavior of nylon-6, -66, and
-610 polyamides in formic acid-water systems, J. Polym. Sci.: Part B: Polym. Phys., 32,
1183, 1994.
1994DIS Dissing, U. and Mattiasson, B., Partition of proteins in polyelectrolyte-neutral polymer
aqueous two-phase systems, Bioseparation, 4, 335, 1994.
1994EI1 Eiteman, M.A., Temperature-dependent phase inversion and its effect on partitioning in the
poly(ethylene glycol)-ammonium sulfate aqueous two-phase system, J. Chromatogr. A, 668,
13, 1994.
1994EI2 Eiteman, M.A., Predicting partition coefficients of multi-charged solutes in aqueous two-
phase systems, J. Chromatogr. A, 668, 21, 1994.
1994GUA Guan, Y., Mei, L., and Zhu, Z., Recovery of antibiotics by aqueous two-phase partition:
partitioning behavior of pure acetylspiramycin solution in polyethylene glycol/potassium
phosphate aqueous two-phase system, Biotechnol. Techn., 8, 491, 1994.
1994HAM Hammer, S., Pfennig, A., and Stumpf, M., Liquid-liquid and vapor-liquid equilibria in water
+ poly(ethylene glycol) + sodium sulfate, J. Chem. Eng. Data, 39, 409, 1994.
1994HAR Hartounian, H., Sandler, S.I., and Kaler, E.W., Aqueous two-phase systems. 1. Salt
partitioning, Ind. Eng. Chem. Res., 33, 2288, 1994.
1994KUR Kuramoto, N., Shishida, Y., and Nagai, K., Preparation of thermally responsive electroactive
poly(N-acryloylpyrrolidine-co-vinylferrocene), Macromol. Rapid Commun., 15, 441, 1994.
1994LUM Lu, M., Albertsson, P.-A., Johansson, G., and Tjerneld, F., Partitioning of proteins and
membrane vesicles in aqueous two-phase systems with hydrophobically modified dextran, J.
Chromatogr. A, 668, 215, 1994.
1994MOD Modlin, R.F., Alred, P. A., and Tjerneld, F., Utilization of temperature-induced phase
separation for the purification of ecdysone and 20-hydroxyecdysone from spinach, J.
Chromatogr. A, 668, 229, 1994.
1994MUM Mumick, P.S. and McCormick, C.L., Water soluble copolymers. 54: N-isopropyl-
acrylamide-co-acrylamide copolymers in drag reduction: synthesis, characterization, and
dilute solution behavior, Polym. Eng. Sci., 34, 1419, 1994.
1994PE1 Peng, Q., Li, Z., and Li, Y., Thermodynamics of potassium hydrogen phosphate-potassium
dihydrogen phosphate-polyethylene glycol aqueous two-phase systems, Fluid Phase Equil.,
95, 341, 1994.
1994PE2 Peng, Q., Li, Z., and Li, Y., Thermodynamics of protein-K2HPO4-KH2PO4-PEG aqueous
two-phase systems (Chin.), J. Chem. Ind. Eng. (China), 45, 515, 1994.
1994TAG Tager, A.A., Safronov, A.P., Berezyuk, E.A., and Galaev, I.Yu., Lower critical solution
temperature and hydrophobic hydration in aqueous polymer solutions, Colloid Polym. Sci.,
272, 1234, 1994.
1994ZH1 Zhang, K., Carlsson, M., Linse, P., and Lindman, B., Phase behavior of copolymer-
homopolymer mixtures in aqueous solution, J. Phys. Chem., 98, 2452, 1994.
1994ZH2 Zhang, K., Karlström, G., and Lindman, B., Ternary aqueous mixtures of a nonionic
polymer with a surfactant or a second polymer, J. Phys. Chem., 98, 4411, 1994.
1995BE1 Bergfeldt, K., Piculell, L., and Tjerneld, F., Phase separation phenomena and viscosity
enthancements in aqueous mixtures of poly(styrenesulfonate) with poly(acrylic acid) at
different degrees of neutralization, Macromolecules, 28, 3360, 1995.
____________________________________________________________________________________
1995BE2 Berggren, K., Johansson, H.-O., and Tjerneld, F., Effects of salts and the surface
hydrophobicity of proteins on partitioning in aqueous two-phase systems containing thermo-
separating ethylene oxide-propylene oxide copolymers, J. Chromatogr. A, 718, 67, 1995.
1995DAV Dave, V., Tamagno, M., Focher, B., and Marsano, E., Hyaluronic acid-(hydroxypropyl)
cellulose blends: a solution and solid state study, Macromolecules, 28, 3531, 1995.
1995DOE Döbert, F., Pfennig, A., and Stumpf, M., Derivation of the consistent osmotic virial equation
and its application to aqueous poly(ethylene glycol)-dextran two-phase system,
1995FUR Furuya, T., Iwai, Y., Tanaka, Y., Uchida, H., Yamada, S., and Arai, Y., Measurement and
correlation of liquid-liquid equilibria for dextran-poly(ethylene glycol)-water aqueous two-
phase systems at 20°C, Fluid Phase Equil., 103, 119, 1995.
1995GR1 Grossmann, C., Tintinger, R., Zhu, J., and Maurer, G., Aqueous two-phase systems of
poly(ethylene glycol) and dextran − experimental results and modeling of thermodynamic
1995GR2 Grossmann, C., Tintinger, R., Zhu, J., and Maurer, G., Aqueous two-phase systems of
poly(ethylene glycol) and dipotassium hydrogen phosphate with and without partitioning
biomolecules − experimental results and modeling of thermodynamic properties, Ber.
Bunsenges. Phys. Chem., 99, 700, 1995.
1995GUI Guido, S., Phase behavior of aqueous solutions of hydroxypropylcellulose,
1995KAU Kaul, A., Pereira, R.A.M., Asenjo, J.A., and Merchuk, J.C., Kinetics of phase separation for
polyethylene glycol-phosphate two-phase systems, Biotechnol. Bioeng., 48, 246, 1995.
1995KIM Kim, Y.-H., Kwon, C., Bae, Y.H., and Kim, S.W., Saccharide effect on the lower critical
solution temperature of thermosensitive polymers, Macromolecules, 28, 939, 1995.
1995LUM Lu, M., Johansson, G., Albertson, P.-A., and Tjerneld, F., Partitioning of proteins in
dextran/hydrophobically modified dextran aqueous two-phase systems, Bioseparation, 5,
351, 1995.
1995MI1 Mishima, K., Ueno, M., Totoki, M., Nomiyama, T., Sugino, J., and Nagatani, M., Recovery
of eicosapentaenoic acid ethyl ester and docoshexaenoic acid ethyl ester from an aqueous
two-phase system using supercritical fluid extraction, Solvent Extraction Res. Developm.,
Japan, 2, 204, 1995.
1995MI2 Mishima, K., Nakatani, K., Nomiyama, T., Matsuyama, K., Nagatani, M., and Nishikawa,
H., Liquid-liquid equilibria of aqueous two-phase systems containing polyethylene glycol
and dipotassium hydrogen phosphate, Fluid Phase Equil., 107, 269, 1995.
1995NEU Neuchl, C. and Mersmann, A., Fractionation of polydisperse dextran using ethanol, Chem.
Eng. Sci., 50, 951, 1995.
1995PAN Pandit, N.K., Kanjia, J., Patel, K., and Pontikes, D.G., Phase behavior of aqueous solutions
containing nonionic surfactant-polyethylene glycol mixtures, Int. J. Pharm., 122, 27, 1995.
1995PEN Peng, Q., Li, Z., and Li, Y., Experiments, correlation and prediction of protein partition
coefficients in aqueous two-phase systems containing PEG and K2HPO4-KH2PO4, Fluid
Phase Equil., 107, 303, 1995.
1995ROG Rogers, R.D., Bauer, C.B., and Bond, A.H., Novel polyethylene glycol-based aqueous
biphasic systems for the extraction of strontium and cesium, Sep. Sci. Technol., 30, 1203,
1995.
1995SAV Save, S.V. and Pangarkar, V.G., Behaviour of surfactants in aqueous two-phase systems,
Bioseparation, 5, 27, 1995.
1995SEB Sebastiao, M.J., Cabral, J.M.S., and Aires-Barros, M.R., Simultaneous quantification of
polymer and salt in polyethylene glycol/phosphate aqueous two-phase systems by HPLC,
Biotechnol. Techn., 9, 503, 1995.
1995SVE Svensson, M., Linse, P., and Tjerneld, F., Phase behavior in aqueous two-phase systems
containing micelle-forming block copolymers, Macromolecules, 28, 3597, 1995.
____________________________________________________________________________________
1995TIN Tintinger, R., Thermodynamische Eigenschaften ausgewählter wäßriger Zwei-Phasen

1995TOK To, K., Chan, C.K., and Choi, H.J., Phase equilibrium and conformation of a polymer in a
binary solvent, Physica A, 221, 223, 1995.
1995TON Tong, Z., Meissner, K., and Wolf, B.A., Phase equilibria and interfacial tension between
coexisting phases for the system water/2-propanol/poly(acrylic acid), Macromol. Chem.
Phys., 196, 521, 1995.
1995ZAS Zaslavsky, B.Y., Aqueous Two-Phase Partitioning. Physical Chemistry and Bioanalytical
Applications, Marcel Dekker Inc., New York, 1995.
1995ZHA Zhang, K. and Kahn, A., Phase behavior of poly(ethylene oxide)-poly(propylene oxide)-
poly(ethylene oxide) triblock copolymers in water, Macromolecules, 28, 3807, 1995.
1996ALL Allcock, H.R. and Dudley, G.K., Lower critical solubility temperature study of alkyl ether
based polyphosphazenes, Macromolecules, 29, 1313, 1996.
1996BER Bergfeldt, K. and Piculell, L., Phase behavior of weakly charged polymer/surfactant/water
mixtures, J. Phys. Chem., 100, 5935, 1996.
1996BUL Bulte, A.M.W., Naafs, E.M., van Eeten, F., Mulder, M.H.V., Smolders, C.A., and
Strathmann, H., Equilibrium thermodynamics of the ternary membrane-forming system
nylon, formic acid, and water, Polymer, 37, 1647, 1996.
1996CES Cesi, V., Katzbauer, B., Narodoslawsky, M., and Moser, A., Thermophysical properties of
polymers in aqueous two-phase systems, Int. J. Thermophys., 17, 127, 1996.
1995CH1 Cheng, L.-P., Dwan, A.-H., and Gryte, C.C., Membrane formation by isothermal
precipitation in polyamide-formic acid-water systems I. Description of membrane
morphology, J. Polym. Sci.: Part B: Polym. Phys., 33, 211, 1995.
1995CH2 Cheng, L.-P., Dwan, A.-H., and Gryte, C.C., Membrane formation by isothermal
precipitation in polyamide-formic acid-water systems II. Precipitation dynamics, J. Polym.
Sci.: Part B: Polym. Phys., 33, 223, 1995.
1996ELE El-Ejmi, A.A.S. and Huglin, M.B., Characterization of N,N-dimethylacrylamide/2-methoxy-
ethylacrylate copolymers and phase behaviour of their thermotropic aqueous solutions,
Polym. Int., 39, 113, 1996.
1996FIS Fischer, V., Borchard, W., and Karas, M., Thermodynamic properties of poly(ethylene
glycol)/water systems. 1. A polymer sample with a narrow molar mass distribution, J. Phys.
Chem., 100, 15992, 1996.
1996FRA Francois, J., Maitre, S., Rawiso, M., Sarazin, D., Beinert, G., and Isel, F., Neutron and X-
ray scattering studies of model hydrophobically end-capped poly(ethylene oxide) aqueous
solutions at rest and under shear, Coll. Surfaces A, 112, 251, 1996.
1996FUR Furuya, T., Yamada, S., Zhu, J., Yamaguchi, Y., Iwai, Y., and Arai, Y., Measurement and
correlation of liquid-liquid equilibria and partition coefficients of hydrolytic enzymes for
DEX T500 + PEG20000 + water aqueous two-phase system at 20°C, Fluid Phase Equil.,
125, 89, 1996.
1996GAL Galera-Gomez, P.A. and Gu, T., Cloud point of mixtures of polypropylene glycol and
Triton X-100 in aqueous solutions, Langmuir, 12, 2602, 1996.
1996GOL Goldszal, A., Costeux, S., and Djabourov, M., Phase separation of aqueous solutions of
cellulose derivatives: influence of surfactants, Coll. Surfaces A, 112, 141, 1996.
1996GON Gonzalez-Tello, P., Camacho, F., Blazquez, G., and Alarcon, F.J., Liquid-liquid equilib-
rium in the system poly(ethylene glycol) + MgSO4 + H2O at 298 K, J. Chem. Eng. Data, 41,
1333, 1996.
1996HON Hong, J.S., Nakahara, T., Maeda, H., Kikunaga, Y., Kishida, A., and Akashi, M., Cloud
points and phase separation of aqueous poly(N-vinylacetamide) solutions in the presence of
salts, Colloid Polym. Sci., 274, 1013, 1996.
1996HOS Hoskins, R., Robb, I.D., Williams, P.A., and Warren, P., Phase separation in mixtures of
polysaccharides and proteins, J. Chem. Soc., Faraday Trans., 92, 4515, 1996.
____________________________________________________________________________________
1996JOH Johansson, G., Aqueous two-phase systems with a liquid protein (bovine serum albumin)
phase for partitioning of enzymes, J. Chromatogr. B, 680, 123, 1996.
1996LIM Li, M., Zhu, Z. Q., and Mei, L. H., Liquid-liquid equilibria for hydroxypropyl starch +
poly(ethylene glycol) + water at 25°C, J. Chem. Eng. Data, 41, 500, 1996.
1996LUM Lu, M., Albertson, P.-A., Johansson, G., and Tjerneld, F., Ucon-benzoyl dextran aqueous
two-phase systems: protein purification with phase component recycling, J. Chromatogr. B,
680, 65, 1996.
1996MIS Mishima, K., Wada, N., Sigematsu, Y., Oka, S., and Nagatani, M., Measurement and
correlation of liquid-liquid phase equilibrium compositions of aqueous solutions containing
methoxypolyethylene glycol and dextran, Fukuoka Daigaku Kogaku Shuho, 57, 141, 1996.
1996MIY Miyazaki, H. and Kataoka, K., Preparation of polyacrylamide derivatives showing thermo-
reversible coacervate formation and their potential application to two-phase separation
processes, Polymer, 37, 681, 1996.
1996PAN Pandit, N.K. and Kanjia, J., Phase behavior of nonionic surfactant solutions in the presence
of polyvinylpyrrolidone, Int. J. Pharm., 141, 197, 1996
1996PIC Piculell, L., Bergfeldt, K., and Gerdes, S., Segregation in aqueous mixtures of nonionic
polymers and surfactant micelles. Effects of micelle size and surfactant headgroup/polymer
interactions, J. Phys. Chem., 100, 3675, 1996.
1996SIV Sivars, U., Bergfeldt, K., Piculell, L., and Tjerneld, F., Protein partitioning in weakly
charged polymer-surfactant aqueous two-phase systems, J. Chromatogr. B, 680, 43, 1996.
1996WIT Witte, P. van de, Dijkstra, P.J., Van den Berg, J.W.A., and Feijen, J., Phase behavior of
polylactides in solvent-nonsolvent mixtures, J. Polym. Sci.: Part B: Polym. Phys., 34, 2553,
1996.
1997CHE Chevillard, C. and Axelos, M.A.V., Phase separation of aqueous solution of methyl-
cellulose, Colloid Polym. Sci., 275, 537, 1997.
1997CHO Cho, S.H., Jhon, M.S., Yuk, S.H., and Lee, H.B., Temperature-induced phase transition of
poly(N,N-dimethylaminoethyl methacrylate-co-acrylamide), J. Polym. Sci.: Part B: Polym.
Phys., 35, 595, 1997.
1997CUN Cunha, M.T., Cabral, J.M.S., and Aires-Barros, M.R., Quantification of phase composition
in aqueous two-phase systems of Breox/phosphate and Breox/Reppal PES 100 by isocratic
HPLC, Biotechnol. Techn., 11, 351, 1997.
1997ELE El-Ejmi, A.A.S. and Huglin, M.B., Behaviour of poly(N,N-dimethylacrylamide-co-2-
methoxyethylacrylate) in non-aqueous solution and LCST behaviour in water, Eur. Polym.
J., 33, 1281, 1997.
1997FRA Franco, T.T., Galaev, I.Yu., Hatti-Kaul, R., Holmberg, N., Bülow, L., and Mattiasson, B.,
Aqueous two-phase system formed by thermoreactive vinyl imidazole/vinyl caprolactam
copolymer and dextran for partitioning of a protein with a polyhistidine tail, Biotechnol.
Techn., 11, 231, 1997.
1997GRO Grossmann, C., Tintinger, R., Zhu, J., and Maurer, G., Partitioning of some amino acids and
low molecular peptides in aqueous two-phase systems of poly(ethylene glycol) and
dipotassium hydrogen phosphate, Fluid Phase Equil., 137, 209, 1997.
1997HO1 Holmberg, C., Nilsson, S., and Sundelöf, L.-O., Thermodynamic properties of surfactant/
polymer/water systems with respect to clustering adsorption and intermolecular interactions
as a function of temperature and polymer concentration, Langmuir, 13, 1392, 1997.
1997HO2 Holmqvist, P., Alexandridis, P., and Lindman, B., Phase behavior and structure of ternary
amphiphilic block copolymer-alkanol-water systems: comparison of poly(ethylene
oxide)/poly(propylene oxide) to poly(ethylene oxide)/poly(tetrahydrofuran) copolymers,
Langmuir, 13, 2471, 1997.
1997JO1 Johansson, H.-O., Karlström, G., and Tjerneld, F., Temperature-induced phase partitioning
of peptides in water solutions of ethylene oxide and propylene oxide random copolymers,
Biochim. Biophys. Acta, 1335, 315, 1997.
____________________________________________________________________________________
1997JO2 Johansson, H.-O., Karlström, G., and Tjerneld, F., Effect of solute hydrophobicity on phase
behaviour in solutions of thermoseparating polymers, Colloid Polym. Sci., 275, 458, 1997.
1997KIM Kim, J.Y., Lee, H.K., Baik, K.J., and Kim, S.C., Liquid-liquid phase separation in
polysulfone/solvent/water systems, J. Appl. Polym. Sci., 65, 2643, 1997.
1997KUR Kuramoto, N., Shishido, Y., and Nagai, K., Thermosensitive and redox-active polymers:
preparation and properties of poly(N-ethylacrylamide-co-vinylferrocene) and poly(N,N-di-
ethylacrylamide-co-vinylferrocene), J. Polym. Sci.: Part A: Polym. Chem., 35, 1967, 1997.
1997LIM Li, M., Zhu, Z.-Q., and Mei, L.-H., Partitioning of amino acids by aqueous two-phase
systems combined with temperature-induced phase formation, Biotechnol. Progr., 13, 105,
1997.
1997MAT Matsuyama, K., Enjoji, T., Mishima, K., Oka, S., Uchiyama, H., Ide, M., and Nagatani, M.,
Partition coefficients of amylase, maltose, and starch in aqueous two-phase systems
containing polyoxyethylene-polyoxypropylene block copolymer, Solvent Extraction Res.
Developm., Japan, 4, 80, 1997.
1997MEL Meller da Silva, L.H., Coimbra, J.S.R., and Meirelles, A.J.de A., Equilibrium phase
behavior of poly(ethylene glycol) + potassium phosphate + water two-phase systems at
various pH and temperatures, J. Chem. Eng. Data, 42, 398, 1997.
1997PAE Pae, B.J., Moon, T.J., Lee, C.H., Ko, M.B., Park, M., Lim S., Kim, J., and Choe, C.R.,
Phase behavior in PVA/water solution, Korean Polym. J., 5, 126, 1997.
1997PLA Planas, J., Lefebvre, D., Tjerneld, F., and Hahn-Haegerdal, B., Analysis of phase compo-
sition in aqueous two-phase systems using a two-column chromatographic method:
application to lactic acid production by extractive fermentation, Biotechnol. Bioeng., 54,
303, 1997.
1997SAR Sargantanis, I.G. and Karim, M.N., Prediction of aqueous two-phase equilibrium using the
Flory-Huggins model, Ind. Eng. Chem. Res., 36, 204, 1997.
1997SCH Schäfer-Sönen, H., Mörkerke, R., Berghmans, H., Koningsveld, R., and Solc, K., Zero and
off-zero critical concentrations in systems containing polydisperse polymers with very high
molar masses. 2., Macromolecules, 30, 410, 1997.
1997SU1 Suwa, K., Wada, Y., Kikunaga, Y., Morishita, K., Kishida, A., and Akashi, M., Synthesis
and functionalities of poly(N-vinylalkylamide). IV., J. Polym. Sci.: Part A: Polym. Chem.,
35, 1763, 1997.
1997SU2 Suwa, K., Morishita, K., Kishida, A., and Akashi, M., Synthesis and functionalities of
poly(N-vinylalkylamide). V., J. Polym. Sci.: Part A: Polym. Chem., 35, 3087, 1997.
1997TIN Tintinger, R., Zhu, J., Grossmann, C., and Maurer, G., Partitioning of some amino acids and
low molecular mass peptides in aqueous two-phase systems of poly(ethylene glycol) and
dextran in the presence of small amounts of K2HPO4/KH2PO4-buffer at 293 K: experimental
results and correlation, J. Chem. Eng. Data, 42, 975, 1997.
1997TOP Topp, M.D.C., Dijkstra, P.J., Talsma, H., and Feijen, J., Thermosensitive micelle-forming
block copolymers of poly(ethylene glycol) and poly(N-isopropylacrylamide),
1997VIN Vinches, C., Parker, A., and Reed, W.F., Phase behavior of aqueous gelatin/oligo-
saccharide mixtures, Biopolymers, 41, 607, 1997.
1997YOU Young, T.-H., Lai, J.-Y., You, W.-M., and Cheng, L.-P., Equilibrium phase behavior of the
membrane forming water-DMSO-EVAL copolymer system, J. Membrane Sci., 128, 55,
1997.
1998ALM Almeida, M.C., Venancio, A., Teixeira, J.A., and Aires-Barros, M.R., Cutinase purification
on poly(ethylene glycol)-hydroxypropyl starch aqueous two-phase systems, J. Chromatogr.
B, 711, 151, 1998.
1998BEL Belval, S. de, Breton, B. le, Huddleston, J., and Lyddiatt, A., Influence of temperature upon
protein partitioning in poly(ethylene glycol)-salt aqueous two-phase systems close to the
critical point with some observations relevant to the partitioning of particles, J.
Chromatogr. B, 711, 19, 1998.
____________________________________________________________________________________
1998BER Berlo, M. van, Luyben, K.Ch.A.M., and Wilen, L.A.M. van der, Poly(ethylene glycol)-salt
aqueous two-phase systems with easily recyclable volatile salts, J. Chromatogr. B, 711, 61,
1998.
1998CHR Christian, T.J., Manley-Harris, M., and Richards, G.N., A preliminary study of the use of
larch arabinogalactan in aqueous two-phase systems, Carbohydr. Polym., 35, 7, 1998.
1998KIS Kishida, A., Nakano, S., Kikunaga, Y., and Akashi, M., Synthesis and functionalities of
poly(N-vinylalkylamide). VII. A novel aqueous two-phase system based on poly(N-vinyl
acetamide) and dextran, J. Appl. Polym. Sci., 67, 255, 1998.
1998KUB Kubota, K., Kita, R., and Dobashi, T., Renormalized Ising behavior of critical nonionic
surfactant solution, J. Chem.,Phys., 109, 711, 1998.
1998KUR Kuramoto, N. and Shishido, Y., Property of thermo-sensitive and redox-active poly(N-
cyclopropylacrylamide-co-vinylferrocene) and poly(N-isopropylacrylamide-co-vinylferro-
cene), Polymer, 39, 669, 1998.
1998LAI Lai, J.-Y., Lin, S.-F., Lin, F.-C., and Wang, D.-M., Construction of ternary phase diagrams
in nonsolvent/solvent/PMMA systems, J. Polym. Sci.: Part B: Polym. Phys., 36, 607, 1998.
1998LI1 Li, M., Zhu, Z.-Q., Wu, Y.-T., and Lin, D.-Q., Measurement of phase diagrams for new
aqueous two-phase systems and prediction by a generalized multicomponent osmotic virial
equation, Chem. Eng. Sci., 53, 2577, 1998.
1998LI2 Li, M., Wang, Y.-X., and Zhu, Z.-Q., Liquid-liquid equilibria for random copolymer of
ethylene oxide + propylene oxide + salt + water, J. Chem. Eng. Data, 43, 93, 1998.
1998MER Merchuk, J.C., Andrews, B.A., and Asenjo, J.A., Aqueous two-phase systems for protein
separation. Studies on phase inversion, J. Chromatogr. B, 711, 285, 1998.
1998MOE Mörkerke, R., Meeussen, F., Koningsveld, R., Berghmans, H., Mondelaers, W., Schacht, E.,
Dusek, K., and Solc, K., Phase transitions in swollen networks. 3. Swelling behavior of
radiation cross-linked poly(vinyl methyl ether) in water, Macromolecules, 31, 2223, 1998.
1998NIL Nilsson, S., Blokhus, A.M., and Saure, A., Influence of hydrophobic cosolutes on aqueous
two-phase polymer-surfactant systems, Langmuir, 14, 6082, 1998.
1998PLA Planas, J., Varelas, V., Tjerneld, F., and Hahn-Hägerdal, B., Amine-based aqueous
polymers for the simultaneous titration and extraction of lactic acid in aqueous two-phase
systems, J. Chromatogr. B, 711, 256, 1998.
1998YOU Young, T.-H., Cheng, L.-P., Hsieh, C.-C., and Chen, L.-W., Phase behavior of EVAL
polymers in water-2-propanol cosolvent, Macromolecules, 31, 1229, 1998.
1998ZAF Zafarani-Moattar, M.T. and Salabat, A., Thermodynamics of magnesium sulfate-
polypropylene glycol aqueous two-phase system. Experiment and correlation, Fluid Phase
Equil., 152, 57, 1998.
1998ZHA Zhang, J., Pelton, R., and Wagberg, L., Aqueous biphase formation by mixtures of dextran
and hydrophobically modified dextran, Colloid Polym. Sci., 276, 476, 1998.
1998ZHE Zheng, X., Tong, Z., Xie, X., and Zeng, F., Phase separation in poly(N-isopropyl acryl-
amide)/water solutions. I. Cloud point curves and microgelation, Polym. J., 30, 284, 1998.
1999BAL Baltes, T., Garret-Flaudy, F., and Freitag, R., Investigation of the LCST of polyacrylamides
as a function of molecular parameters and the solvent composition, J. Polym. Sci.: Part A:
Polym. Chem., 37, 2977, 1999.
1999BAI Baik, K.-J., Kim, J. Y., Lee, H. K., and Kim, S. C., Liquid-liquid phase separation in poly-
sulfone/polyethersulfone/N-methyl-2-pyrrolidone/water quarternary system, J. Appl. Polym.
Sci., 74, 2113, 1999.
1999BAT Baton, B.F. and McHugh, A.J., Kinetics of thermally induced phase separation in ternary
polymer solutions. I., J. Polym. Sci.: Part B: Polym. Phys., 37, 1449, 1999.
1999BER Berggren, K., Veide, A., Nygren, P.-A., and Tjerneld, F., Genetic engineering of protein-
peptide fusions for control of protein partitioning in thermoseparating aqueous two-phase
systems, Biotechnol. Bioeng., 62, 135, 1999.
____________________________________________________________________________________
1999CH1 Cheng, L.-P., Effect of temperature on the formation of microporous PVDF membranes by
precipitation from 1-octanol/DMF/PVDF and water/DMF/PVDF systems, Macromolecules,
32, 6668, 1999.
1999CH2 Cheng, L.-P., Lin, D.-J., Shih, C.-H., Dwan, A.-H., and Gryte, C.C., PVDF membrane
formation by diffusion-induced phase separation-morphology based on phase behavior and
mass transfer modeling, J. Polym. Sci.: Part B: Polym. Phys., 37, 2079, 1999.
1999ERB Erbil, C., Akpinar, F.D., and Uyanik, N., Investigation of the thermal aggregations in
aqueous poly(N-isopropylacrylamide-co-itaconic acid) solutions, Macromol. Chem. Phys.,
200, 2448, 1999.
1999JAN Jang, J.G. and Bae, Y.C., Phase behaviors of hyperbranched polymer solutions, Polymer,
40, 6761, 1999.
1999JEO Jeong, B., Lee, D.S., Shon, J.-I., Bae, Y.H., and Kim, S.W., Thermoreversible gelation of
poly(ethylene oxide) biodegradable polyester block copolymers, J. Polym. Sci.: Part B:
Polym. Phys., 37, 751, 1999.
1999JOH Johansson, H.-O., Persson, J., and Tjerneld, F., Thermoseparating water/polymer system: a
novel one-polymer aqueous two-phase system for protein purification, Biotechnol. Bioeng.,
66, 247, 1999.
1999KIM Kim, Y.D., Kim, J.Y., Lee, H.K., Kim, S.C., Formation of polyurethane membranes by
immersion precipitation. I. Liquid-liquid phase separation in a polyurethane/DMF/water
system, J. Appl. Polym. Sci., 73, 2377, 1999.
1999KIS Kishida, A., Kikunaga, Y., and Akashi, M., Synthesis and functionality of poly(N-
vinylalkylamide). X. A novel aqueous two-phase system based on thermosensitive polymers
and dextran, J. Appl. Polym. Sci.,73, 2545, 1999.
1999KIT Kita, R., Kaku, T., Kubota, K., and Dobashi, T., Pinning of phase separation of aqueous
solution of hydroxypropylmethylcellulose by gelation, Phys. Lett. A, 259, 302, 1999.
1999LAU Lau, A.C.W. and Wu, C., Thermally sensitive and biocompatible poly(N-vinylcaprolactam):
synthesis and characterization of high molar mass linear chains, Macromolecules, 32, 581,
1999.
1999LIW Li, W., Zhu, Z.-Q., and Lin, D.-Q., Liquid-liquid equilibria of aqueous two-phase systems
containing ethylene oxide-propylene oxide random copolymer and ammonium sulfate, J.
Chem. Eng. Data, 44, 921, 1999.
1999MAT Matsuyama, H., Teramoto, M., Nakatani, R., and Maki, T., Membrane formation via phase
separation induced by penetration of nonsolvent from vapor phase. I. Phase diagram and
mass transfer process, J. Appl. Polym. Sci., 74, 159, 1999.
1999PER Persson, J., Johansson, H.-O., and Tjerneld, F., Purification of protein and recycling of
polymers in a new aqueous two-phase system using two thermoseparating polymers, J.
Chromatogr. A, 864, 31, 1999.
1999RAE Rämsch, C., Kleinelanghorst, L.B., Knieps, E.A., Thömmes, J., and Kula, M.-R., Aqueous
two-phase systems containing urea: influence on phase separation and stabilization of
protein conformation by phase components, Biotechnol. Progr., 15, 493, 1999.
1999SHI Shimofure, S., Kubota, K., Kita, R., and Dobashi, T., Coexistence curve and turbidity of
aqueous solutions of oligooxyethylene alkyl ether with the addition of urea near the critical
point, J. Chem. Phys., 111, 4199, 1999.
1999SVE Svensson, M., Berggren, K., Veide, A., and Tjerneld, F., Aqueous two-phase systems
containing self-associating block copolymers. Partitioning of hydrophilic and hydrophobic
biomolecules, J. Chromatogr. A, 839, 71, 1999.
1999WAN Wang, D., Li, K., and Teo, W.K., Phase separation in polyetherimide/solvent/nonsolvent
systems and membrane formation, J. Appl. Polym. Sci., 71, 1789, 1999.
1999YOU Young, T.-H., Cheng, L.-P., You, W.-M., and Chen, L.-Y., Prediction of EVAL membrane
morphologies using the phase diagram of water-DMSO-EVAL at different temperatures,
Polymer, 40, 2189, 1999.
____________________________________________________________________________________
2000AFR Afroze, F., Nies, E., and Berghmans, H., Phase transitions in the system poly(N-isopropyl-
acrylamide)/water and swelling behaviour of the corresponding networks (experimental data
by H. Berghmans), J. Mol. Struct., 554, 55, 2000.
2000BAD Badiger, M.V., Lutz, A., and Wolf, B.A., Interrelation between the thermodynamic and
viscometric behaviour of aqueous solutions of hydrophobically modified ethyl hydroxyethyl
cellulose, Polymer, 41, 1377, 2000.
2000BA1 Barth, C. and Wolf, B.A., Quick and reliable routes to phase diagrams for polyethersulfone
and polysulfone membrane formation, Macromol. Chem. Phys., 201, 365, 2000.
2000BA2 Barth, C., Goncalves, M.C., Pires, A.T.N., Röder, J., and Wolf, B.A., Asymmetric
polysulfone and polyethersulfone membranes: effects of thermodynamic conditions during
formation on their performance, J. Membrane Sci., 169, 287, 2000.
2000BER Berlo, M. van, Ottens, M., Luyben, K.Ch.A.M., and Van der Wilen, L.A.M., Feasible
boundaries of aqueous two-phase systems with NH3 and COS as recyclable volatile salts,
Biotechnol. Bioeng., 70, 65, 2000.
2000BO1 Bokias, G., Staikos, G., and Iliopoulos, I., Solution properties and phase behaviour of
copolymers of acrylic acid with N-isopropylacrylamide, Polymer, 41, 7399, 2000.
2000BO2 Bokias, G., Vasilevskaya, V.V., Iliopoulos, I., Hourdet, D., and Khokhlov, A.R., Influence
of migrating ionic groups on the solubility pf polyelectrolytes: phase behavior of ionic
poly(N-isopropylacrylamide) copolymers in water, Macromolecules, 33, 9757, 2000.
2000CH1 Chen, L., Honma, Y., Mizutani, T., Liaw, D.-J., Gong, J.P., and Osada, Y., Effects of poly-
electrolyte complexation on the UCST of zwitterionic polymer, Polymer, 41, 141, 2000.
2000CH2 Cheng, L.-P. and Shaw, H.-Y., Phase behavior of a water/2-propanol/poly(methyl
methacrylate) cosolvent system, J. Polym. Sci.: Part B: Polym. Phys., 38, 747, 2000.
2000CHU Chun, K.-Y., Jang, S.-H., Kim, H.-S., Kim, Y.-W., and Joe, Y.-I., Effects of solvent on the
pore formation in asymmetric 6FDA-4,4'ODA polyimide membrane: terms of thermodyna-
mics, precipitation kinetics, and physical factors, J. Membrane Sci., 169, 197, 2000.
2000FIS Fischer, V. and Borchard, W., Thermodynamic properties of poly(ethylene glycol)/water
systems. 2. Critical point data, J. Phys. Chem. B, 104, 4463, 2000.
2000FRI Friberg, S.E., Yin, Q., Barber, J.L., and Aikens, P.A., Vapor pressures of phenethyl alcohol
in the system water-phenethyl alcohol and the triblock copolymer EO4.5PO59EO4.5, J.
Dispersion Sci. Technol., 21, 65, 2000.
2000GRA Graber, T.A., Taboada, M.E., Carton, A., and Bolado, S., Liquid-liquid equilibrium of the
poly(ethylene glycol) + sodium nitrate + water system at 298.15 K, J. Chem. Eng. Data, 45,
182, 2000.
2000JIM Jimenez-Regalado, E., Selb, J., and Candau, F., Phase behavior and rheological properties
of aqueous solutions containing mixtures of associating polymers, Macromolecules, 33,
8720, 2000.
2000JOA Joabsson, F., Nyden, M., and Thuresson, K., Temperature-induced fractionation of a quasi-
binary self-associating polymer solution. A phase behavior and polymer self-diffusion
investigation, Macromolecules, 33, 6772, 2000.
2000KIM Kim, C., Lee, S.C., Kang, S.W., Kwon, I.C., and Jeong, S.Y., Phase-transition charac-
teristics of amphiphilic poly(2-ethyl-2-oxazoline)/poly(ε-caprolactone) block copolymers in
aqueous solutions J. Polym. Sci.: Part B: Polym. Phys., 38, 2400, 2000.
2000KUN Kunugi, S., Tada, T., Yamazaki, Y., Yamamoto, K., and Akashi, M., Thermodynamic
studies on coil-globule transitions of poly(N-vinylisobutyramide-co-vinylamine) in aqueous
solutions, Langmuir, 16, 2042, 2000.
2000LAM LaMesa, C., Phase equilibria in a water-block copolymer system, J. Therm. Anal. Calorim.,
61, 493, 2000.
2000LI1 Li, W., Lin, D.-Q., and Zhu, Z.-Q., Measurement of water activities and prediction of
liquid-liquid equilibria for water + ethylene oxide-propylene oxide random copolymer +
ammonium sulfate systems, Fluid Phase Equil., 175, 7, 2000.
____________________________________________________________________________________
2000LI2 Li, W., Zhu, Z.-Q., Li, M., Measurement and calculation of liquid-liquid equilibria of binary
aqueous polymer solutions, Chem. Eng. J., 78, 179, 2000.
2000MAE Maeda, Y., Higuchi, T., and Ikeda, I., Changes in hydration states of during the coil-globule
transition of aqueous solutions of poly(N-isopropylacrylamide) as evidenced by FTIR
spectroscopy, Langmuir, 16, 7503, 2000.
2000ME1 Meeussen, F., Bauwens, Y., Mörkerke, R., Nies, E., and Berghmans, H., Molecular
complex formation in the system poly(vinyl methyl ether)/water, Polymer, 41, 3737, 2000.
2000ME2 Meeusen, F., Nies, E., Berghmans, H., Verbrugghe, S., Göthals, E., and DuPrez, F., Phase
behaviour of poly(N-vinyl caprolactam) in water, Polymer, 41, 8597, 2000.
2000MIS Mishima, K., Matsuyama, K., Yamauchi, S., Baba, B., Hirabaru, T., and Ogino, K., Measu-
rement and correlation of liquid-liquid equilibrium compositions of aqueous two-phase
systems containing polyethylene glycol by UNIQUAC model, Fukuoka Daigaku Kogaku
Shuho, 65, 31, 2000.
2000PE1 Persson, J., Johansson, H.-O., Galaev, I., Mattiasson, B., and Tjerneld, F., Aqueous polymer
two-phase systems formed by new thermoseparating polymers, Bioseparation, 9, 105, 2000.
2000PE2 Persson, J., Kaul, A., and Tjerneld, F., Polymer recycling in aqueous two-phase extractions
using thermoseparating ethylene oxide-propylene oxide copolymers, J. Chromatogr. B, 743,
115, 2000.
2000PIE Pietruszka, N., Galaev, I.Yu., Kumar, A., Brzozowski, Z.K., and Mattiasson, B., New
polymers forming aqueous two-phase polymer systems, Biotechnol. Progr., 16, 408, 2000.
2000RAE Rämsch, C., Untersuchungen zur Verteilung von nativen und entfalteten Enzymen in
wäßrigen Zweiphasensystemen, Dissertation, RWTH Aachen, 2000.
2000RIT Rito-Palomares, M. and Cueto, L., Effect of biological suspensions on the position of the
binodal curve in aqueous two-phase systems, J. Chromatogr. B, 743, 5, 2000.
2000SAH Sahakaro, K., Chaibundit, C., Kaligradaki, Z., Mai, S.-M., Heatley, F., Booth, C., Padget, J.
C., and Shirley, I.M., Clouding of aqueous solutions of difunctional tapered statistical
copolymers of ethylene oxide and 1,2-butylene oxide, Eur. Polym. J., 36, 1835, 2000.
2000SAR Sarubbo, L.A., Oliveira, L.A., Porto, A.L.F., Duarte, H.S., Carneiro-Leao, A.M.A., and
Lima-Filho, J.L., New aqueous two-phase system based on cashew-nut tree gum and
poly(ethylene glycol), J. Chromatogr. B, 743, 79, 2000.
2000SIL Silva, L.H.M. da and Meirelles, A.J.A., Phase equilibrium in polyethylene glycol/
maltodextrin aqueous two-phase systems, Carbohydr. Polym., 42, 273, 2000.
2000SIV Sivars, U. and Tjerneld, F., Mechanism of phase behaviour and protein partitioning in
detergent/polymer aqueous two-phase systems for purification of integral membrane
proteins, Biochim. Biophys. Acta, 1474, 133, 2000.
2000SR1 Srinivas, N.D., Barbate, R.S., Raghavarao, K.S.M.S., and Todd, P., Acoustic demixing of
aqueous two-phase systems, Appl. Microbiol. Biotechnol., 53, 650, 2000.
2000SR2 Srinivas, N.D., Barbate, R.S., Raghavarao, K.S.M.S. and Todd, P., Acoustic field assisted
demixing of aqueous two-phase systems, Biochim. Biophys. Acta, 1524, 38, 2000.
2000WIL Willauer, H.D., Huddleston, J.G., Li, M., and Rogers, R.D., Investigation of aqueous two-
phase systems for the separation of lignins from cellulose in the paper pulping process, J.
Chromatogr. B, 743, 127, 2000.
2000YAM Yamazaki, Y., Tada, T., and Kunugi, S., Effect of acrylic acid incorporation on the
pressure-temperature behavior and the calorimetric properties of poly(N-isopropyl-
acrylamide) in aqueous solutions, Colloid Polym. Sci., 278, 80, 2000.
2001ALB Albrecht, W., Weigel, Th., Schossig-Tiedemann, M., Kneifel, K., Peinemann, K.-V., and
Paul, D., Formation of hollow fiber membranes from poly(ether imide) at wet phase
inversion using binary mixtures of solvents for the preparation of the dope (experimental
data by W. Albrecht), J. Membrane Sci., 192, 217, 2001.
2001AND Anderson, V.J. and Jones, R.A.L., The influence of gelation on the mechanism of phase
separation of a biopolymer mixture, Polymer, 42, 9601, 2001.
____________________________________________________________________________________
2001BLA Blazquez, G., Camacho, F., Calero, M., and Alarcon, F.-J., Interaction probabilities in a
four-component aqueous two-phase system: polymer + salt + water + protein, Chem. Eng.
Sci., 56, 4451, 2001.
2001BUT Butler, M.F. and Heppenstall-Butler, M., Phase separation in gelatin/maltodextrin and
gelatin/maltodextrin/gum Arabic mixtures studied using small-angle light scattering,
turbidity, and microscopy, Biomacromolecules, 2, 812, 2001.
2001CAI Cai, W.S., Gan, L.H., and Tam, K.C., Phase transition of aqueous solutions of poly(N,N-
diethylacrylamide-co-acrylic acid) by differential scanning calorimetric and spectrophoto-
metric methods, Colloid Polym. Sci., 279, 793, 2001.
2001CHE Cheng, L.-P., Young, T.-H., Chuang, W.-Y., Chen, L.-Y., and Chen, L.-W., The formation
mechanism of membranes prepared from the nonsolvent-solvent-crystalline polymer
systems, Polymer, 42, 443, 2001.
2001DJO Djokpe, E. and Vogt, W., N-Isopropylacrylamide and N-isopropylmethacrylamide: cloud
points of mixtures and copolymers, Macromol. Chem. Phys., 202, 750, 2001.
2001EDE Edelman, M.W., Van der Linden, E., DeHoog, E., and Tromp, R.H., Compatibility of
gelatin and dextran in aqueous solution (experimental data by M.W. Edelman),
Biomacromolecules, 2, 1148, 2001.
2001FER Fernandes, G.R., Pinto, J.C., and Nobrega, R., Modeling and simulation of the phase-
inversion process during membrane preparation, J. Appl. Polym. Sci., 82, 3036, 2001.
2001FIS Fischer, V., Bestimmung und Beschreibung der thermodynamischen Eigenschaften entmi-
schender, wäßriger Polymerlösungen am Beispiel des Systems Polyethylenglykol/Wasser in
einem weiten Konzentrations- und Temperaturbereich, Dissertation, Gerhard-Mercator-
Universität-GH Duisburg 2001.
2001FUJ Fujii, S., Sasaki, N., and Nakata, M., Rheological studies on the phase separation of hydro-
xypropylcellulose solution systems, J. Polym. Sci.: Part B: Polym. Phys., 39, 1976, 2001.
2001GAN Gan, L.-H., Cai, W., and Tam, K.C., Studies of phase transition of aqueous solutions of
poly(N,N-diethylacrylamide-co-acrylic acid) by differential scanning calorimetry and
spectrophotometry, Eur. Polym. J., 37, 1773, 2001.
2001GAS Gasbarrone, P. and LaMesa, C., Interaction of short-chain surfactants with a nonionic
polymer, Colloid Polym. Sci., 279, 1192, 2001.
2001GRA Graber, T.A., Taboada, M.E., Asenjo, J.A., and Andrews, B.A., Influence of molecular
weight of the polymer on the liquid-liquid equilibrium of the poly(ethylene glycol) + NaNO3
+ H2O system at 298.15 K, J. Chem. Eng. Data, 46, 765, 2001.
2001GRU Grünfelder, T., Experimentelle und theoretische Untersuchungen zum Flüssig-Flüssig-
Gleichgewicht in ternären Systemen Polyelektrolyt/ungeladenes Polymer/Wasser,
Dissertation, Universität Kaiserslautern, 2001.
2001HAM Hamley, I.W., Mai, S.-M., Ryan, A.J., Fairclough, J.P.A., and Booth, C., Aqueous meso-
phases of block copolymers of ethylene oxide and 1,2-butylene oxide, Phys. Chem. Chem.
Phys., 3, 2972, 2001.
2001HUA Hua, F.J., DoNam, J., and Lee, D.S., Preparation of a macroporous poly(L-lactide) scaffold
by liquid-liquid phase separation of a PLLA/1,4-dioxane/water ternary system in the
presence of NaCl, Macromol. Rapid Commun., 22, 1053, 2001.
2001JAN Jang, J.G. and Bae, Y.C., Phase behavior of hyperbranched polymer solutions with specific
interactions, J. Chem. Phys., 114, 5034, 2001.
2001KI1 Kim, J.H., Min, B.R., Park, H.C., Won, J., and Kang, Y.S., Phase behavior and morpho-
logical studies of polyimide/PVP/solvent/water systems by phase inversion, J. Appl. Polym.
Sci., 81, 3481, 2001.
____________________________________________________________________________________
2001KI2 Kim, J.H., Min, B.R., Won, J., Park, H.C., and Kang, Y.S., Phase behavior and mechanism
of membrane formation for polyimide/DMSO/water system, J. Membrane Sci., 187, 47,
2001.
2001KIN King, A.D., The solubility of gases in aqueous solutions of poly(propylene glycol), J.
Colloid Interface Sci., 243, 457, 2001.
2001KUJ Kujawa, P. and Winnik, F. M., Volumetric studies of aqueous polymer solutions using
pressure perturbation calorimetry: a new look at the temperature-induced phase transition of
poly(N-isopropylacrylamide) in water and D2O, Macromolecules, 34, 4130, 2001.
2001KWO Kwon, K.W., Park, M.J., Hwang, J., and Char, K., Effects of alcohol addition on gelation in
aqueous solution of poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide)
triblock copolymer, Polym. J., 33, 404, 2001.
2001LEB Leblanc, N., LeCerf, D., Chappey, C., Langevin, D., Metayer, M., and Muller, G., Influence
of solvent and non-solvent on polyimide asymmetric membranes formation in relation to gas
permeation, Separation Purification Technol., 22-23, 277, 2001.
2001LEE Lee, H.K., Kim, J.Y., Kim, Y.D., Shin, J.Y., and Kim, S.C., Liquid-liquid phase separation
in a ternary system of segmented polyetherurethane/dimethylformamide/water: effect of
hard segment content, Polymer, 42, 3893, 2001.
2001LIU Liu, F., Frere, Y., and Francois, J., Association properties of poly(ethylene oxide) modified
by pendant aliphatic groups, Polymer, 42, 2969, 2001.
2001LIM Li, M., Willauer, H.D., Huddleston, J.G., and Rogers, R.D., Temperature effects on
polymer based aqueous biphasic extraction technology in the paper pulping process, Sep.
Sci. Technol., 36, 835, 2001.
2001LOR Loren, N., Altskaer, A., and Hermansson, A.-M., Structure evolution during gelation at later
stages of spinodal decomposition in gelatin/maltodextrin mixtures, Macromolecules, 34,
8117, 2001.
2001MA1 Maeda, Y., Nakamura, T., and Ikeda, I., Change in the hydration states of poly(N-alkyl-
acrylamide)s during their phase transitions in water observed by FTIR spectroscopy,
2001MA2 Maeda, Y., Nakamura, T., and Ikeda, I., Change in the hydration states of poly(N-n-
propylmethacrylamide) and poly(N-isopropylmethacrylamide) during their phase transitions
in water observed by FTIR spectroscopy, Macromolecules, 34, 8246, 2001.
2001MA3 Maeda, Y., IR spectroscopic study on the hydration and the phase transition of poly(vinyl
methyl ether) in water, Langmuir, 17, 1737, 2001.
2001MEL Meller da Silva, L.H. and Meirelles, A.J.A., PEG + potassium phosphate + urea aqueous
two-phase systems. Phase equilibrium and protein partitioning, J. Chem. Eng. Data, 46,
251, 2001.
2001NER Nerli, B.B., Espariz, M., and Pico, G.G., Thermodynamic study of forces involved in
bovine serum albumin and ovalbumin partitioning in aqueous two-phase systems,
Biotechnol. Bioeng., 72, 468, 2001.
2001NIS Nishida, K., Shibata, M., Kanaya, T., and Kaji, K., Incompatibility of polyelectrolyte
solutions − mixed solutions of PSSNa and PVSNa, Polymer, 42, 1501, 2001.
2001SAL Salabat, A., The influence of salts on the phase composition in aqueous two-phase systems:
experiments and predictions, Fluid Phase Equil., 187-188, 489, 2001.
2001SCH Schuhmacher, E., Soldi, V., and Nunes Pires, A.T., PMMA or PEO in THF/H2O mixture:
phase diagram, separation mechanism and application, J. Membrane Sci., 184, 187, 2001.
2001SIL Silva, L.H.M. and Meirelles, A.J.A., Phase equilibrium and protein partitioning in aqueous
mixtures of maltodextrin with polypropylene glycol, Carbohydr.Polym., 46, 267, 2001.
2001TA1 Taboada, M.E., Asenjo, J.A., and Andrews, B.A., Liquid-liquid and liquid-liquid-solid
equilibrium in Na2CO3-PEG-H2O, Fluid Phase Equil., 180, 273, 2001.
____________________________________________________________________________________
2001TA2 Taboada, M.E., Rocha, O.A., Graber, T.A. and Andrews, B.A., Liquid-liquid and solid-
liquid equilibria of the poly(ethylene glycol) + sodium sulfate + water system at 298.15 K,
J. Chem. Eng. Data, 46, 308, 2001.
2001TAK Takahashi, M., Shimazaki, M., and Yamamoto, J., Thermoreversible gelation and phase
separation in aqueous methyl cellulose solutions, J. Polym. Sci.: Part B: Polym. Phys., 39,
91, 2001.
2001WAN Wang, S., Van Dijk, J.A.P.P., Odijk, T., and Smit, J.A.M., Depletion-induced demixing in
aqueous protein-polysaccharide solutions, Biomacromolecules, 2, 1080, 2001.
2001YA1 Yang, Y., Zeng, F., Xie, X., Tong, Z., and Liu, X., Phase separation and network formation
in poly(vinyl methyl ether)/water solutions, Polym. J., 33, 399, 2001.
2001YA2 Yang, Y., Zeng, F., Tong, Z., Liu, X., and Wu, S., Phase separation in poly(N-isopropyl
acrylamide)/water dolutions. II. Salt effects on cloud-point curves and gelation, J. Polym.
2001ZAF Zafarani-Moattar, M.T. and Sadeghi, R., Liquid-liquid equilibria of aqueous two-phase
systems containing polyethylene glycol and sodium dihydrogen phosphate or disodium
hydrogen phosphate. Experiment and correlation, Fluid Phase Equil., 181, 95, 2001.
2002ALM Al-Muallem, H.A., Wazeer, M.I.M., and Ali, Sk.A., Synthesis and solution properties of a
new ionic polymer and its behavior in aqueous two-phase polymer systems, Polymer, 43,
1041, 2002.
2002ASE Asenjo, J.A., Mistry, S.L., Andrews, B.A., and Merchuk, J.C., Phase separation rates of
aqueous two-phase systems: correlation with system properties, Biotechnol. Bioeng., 79,
217, 2002.
2002BEH Behravesh, E., Shung, A.K., Jo, S., and Mikos, A.G., Synthesis and characterization of
triblock copolymers of methoxy poly(ethylene glycol) and poly(propylene fumarate),
Biomacromolecules, 3, 153, 2002.
2002BER Berlinova, I.V., Nedelcheva, A.N., Samchikov, V., and Ivanov, Ya., Thermally induced
hydrogel formation in aqueous solutions of poly(N-isopropylacryalamide) and fluoro-
carbon-modified poly(oxyethylene)s, Polymer, 43, 7243, 2002.
2002CH1 Chaibundit, C., Ricardo, N.M.P.S., Crothers, M., and Booth, C., Micellization of diblock
(oxyethylene/oxybutylene) copolymer E11B8 in aqueous solution. Micelle size and shape.
Drug solubilization, Langmuir, 18, 4277, 2002.
2002CH3 Chang, Y., Bender, J.D., Phelps, M.V.B., and Allcock, H.R., Synthesis and self-association
behavior of biodegradable amphiphilic poly[bis(ethyl glycinat-N-yl)phosphazene]-poly
(ethylene oxide) block copolymers, Biomacromolecules, 3, 1364, 2002.
2002CHE Chen, L., Gong, J., and Osada, Y., Novel thermosensitive IPN hydrogel having a phase
transition without volume change, Macromol. Rapid Commun., 23, 171, 2002.
2002COS Costa, R.O.R. and Freitas, R.F.S., Phase behavior of poly(N-isopropylacrylamide) in binary
aqueous solutions, Polymer, 43, 5879, 2002.
2002EDG Edgar, C.D. and Gray, D.G., Influence of dextran on the phase behavior of suspensions of
cellulose nanocrystals, Macromolecules, 35, 7400, 2002.
2002FRE Freitag, R. and Garret-Flaudy, F., Salt effects on the thermoprecipitation of poly(N-
isopropylacrylamide) oligomers from aqueous solution, Langmuir, 18, 3434, 2002.
2002FUJ Fujii, S., Sasaki, N., and Nakata, M., Elongational flow studies on the phase separation of
hydroxypropylcellulose solution, J. Appl. Polym. Sci., 86, 2984, 2002.
2002GUO Guo, Z., Li, M., Willauer, H.D., Huddleston, J.G., April, G.C., and Rogers, R.D.,
Evaluation of polymer-based aqueous biphasic systems as improvement for the hardwood
alkaline pulping process, Ind. Eng. Chem. Res., 41, 2535, 2002.
2002GUP Gupta, V., Nath, S., and Chand, S., Role of water structure on phase separation in polyelec-
trolyte-polyethylene glycol based aqueous two-phase systems, Polymer, 43, 3387, 2002.
2002HAM Hammouda, B., Ho, D., and Kline, S., SANS from poly(ethylene oxide)/water systems,
____________________________________________________________________________________
2002HAN Han, M.-J. and Nam, S.-T., Thermodynamic and rheological variation in polysulfone
solution by PVP and its effect in the preparation of phase inversion membrane, J.
Membrane Sci., 202, 55, 2002.
2002HUA Huang, Y. and Forciniti, D., Ethylene oxide and propylene oxide random copolymer/sodium
chloride aqueous two-phase systems: wetting and adsorption on dodecyl-agarose and
polystyrene, Biotechnol. Bioeng., 77, 786, 2002.
2002KIZ Kizhnyaev, V.N., Gorkovenko-Spirina, O.P., and Smirnov, A.I., Solubility of tetrazole-
containing polymers in acids (Russ.), Vysokomol. Soedin., Ser. B, 44, 1079, 2002.
2002KUN Kunugi, S., Tada, T., Tanaka, N., Yamamoto, K., and Akashi, M., Microcalorimetric study
of aqueous solution of a thermoresponsive polymer, poly(N-vinylisobutyramide)
(PNVIBA), Polym. J., 34, 383, 2002.
2002LAA Laatikainen, M., Markkanen, I., Tiihonen, J., and Paatero, E., Liquid-liquid equilibria in
ternary systems of linear and cross-linked water-soluble polymers (experimental data by M.
Laatikainen), Fluid Phase Equil., 201, 381, 2002.
2002LIL Li, L., Shan, H., Yue, C.Y., Lam, Y.C., Tam, K.C., and Hu, X., Thermally induced associa-
tion and dissociation of methylcellulose in aqueous solutions, Langmuir, 18, 7291, 2002.
2002LIN Lin, K.-Y., Wang, D.-M., and Lai, J.-Y., Nonsolvent-induced gelation and its effect on
membrane morphology, Macromolecules, 35, 6697, 2002.
2002LUS Lu, S., Hu, Z., and Schwartz, J., Phase transition behavior of hydroxypropylcellulose under
interpolymer complexation with poly(acrylic acid), Macromolecules, 35, 9164, 2002.
2002MA1 Maeda, Y., Nakamura, T., and Ikeda, I., Hydration and phase behavior of poly(N-vinyl
caprolactam) and poly(N-vinylpyrrolidone) in water (experimental data by Y. Maeda),
2002MA2 Maeda, Y., Nakamura, T., and Ikeda, I., Change in solvation of poly(N,N-diethylacryl
amide) during phase transition in aqueous solutions as observed by IR spectroscopy
(experimental data by Y. Maeda), Macromolecules, 35, 10172, 2002.
2002MAK Makhaeva, E.E., Tenhu, H., and Khokhlov, A.R., Behavior of poly(N-vinylcaprolactam-co-
methacrylic acid) macromolecules in aqueous solution: interplay between coulombic and
hydrophobic interaction, Macromolecules, 35, 1870, 2002.
2002MAT Matsuyama, H., Takida, Y., Maki, T., and Teramoto, M., Preparation of porous membrane
by combined use of thermally induced phase separation and immersion precipitation,
Polymer, 43, 5243, 2002.
2002MON Monteiro-Filho, E.S., Coimbra, J.S.R., Minim, L.A., Silva, L.H.M., and Meirelles, A.J.A.,
Liquid-liquid equilibrium for ternary systems containing a sugar + a synthetic polymer +
water, J. Chem. Eng. Data, 47, 1346, 2002.
2002NIL Nilsson, S., Blokhus, A.M., Hellebust, S., and Glomm, W.R., Influence of hydrophobic
cosolutes on the associative/segregative phase separation of aqueous cationic surfactant-
polymer systems, Langmuir, 18, 6504, 2002.
2002OLI Oliveira, L.A., Sarubbo, L.A., Porto, A.L.F., Lima-Filho, J.L., Campos-Takaki, G.M., and
Tambourgi, E.B., Physical and rheological characterization of polyethylene glycol-cashew
nut tree gum aqueous two-phase systems, J. Chromatogr. B, 766, 27, 2002.
2002PLA Plaza, M., Pons, R., Tadros, Th. F., and Solans, C., Phase behavior and formation of micro-
emulsions in water/A-B-A block copolymer (polyhydroxystearic acid-polyethylene oxide-
polyhydroxystearic acid)/1,2-alkanediol/isopropyl myristate systems, Langmuir, 18, 1077,
2002.
2002RAC Rackaitis, M., Strawhecker, K., and Manias, E., Water-soluble polymers with tunable temp-
erature sensitivity. Solution behavior, J. Polym. Sci.: Part B: Polym. Phys., 40, 2339, 2002.
____________________________________________________________________________________
2002SAX Saxena, R. and Caneba, G.T., Studies of spinodal decomposition in a ternary polymer-
solvent-nonsolvent system, Polym. Eng. Sci., 42, 1019, 2002.
2002SEI Seiler, M., Arlt, W., Kautz, H., and Frey, H., Experimental data and theoretical
considerations on vapor-liquid and liquid-liquid equilibria of hyperbranched polyglycerol
and PVA solutions, Fluid Phase Equil., 201, 359, 2002.
2002SER Se, R.A.G. and Aznar, M., Liquid-liquid equilibrium of the aqueous two-phase system water
+ PEG 4000 + potassium phosphate at four temperatures: experimental determination and
thermodynamic modeling, J. Chem. Eng. Data, 47, 1401, 2002.
2002SHI Shimizu, H., Kawakami, H., and Nagaoka, S., Membrane formation mechanism and perme-
ation properties of a novel porous polyimide membrane, Polym. Adv. Techn., 13, 370, 2002.
2002SHR Shresth, R.S., McDonald, R.C., and Greer, S.C., Molecular weight distributions of
polydisperse polymers in coexisting liquid phases, J. Chem. Phys., 117, 9037, 2002.
2002SIM Simonet, F., Garnier, C., and Doublier, J.-L., Description of the thermodynamic incompa-
tibility of the guar-dextran aqueous two-phase system by light scattering, Carbohydr.
Polym., 47, 313, 2002.
2002SON Soni, S.S., Sastry, N.V., Patra, A.K., Joshi, J.V., and Goyal, P.S., Surface activity, SANS,
and viscosity studies in aqueous solutions of oxyethylene and oxybutylene di- and triblock
copolymers, J. Phys. Chem. B, 106, 13069, 2002.
2002SP1 Spitzer, M., Sabadini, E., and Loh, W., Entropically driven partitioning of ethylene oxide
oligomers and polymers in aqueous/organic biphasic systems, J. Phys. Chem. B, 106,
12448, 2002.
2002SP2 Spitzer, M., Sabadini, E., and Loh, W., Poly(ethylene glycol) or poly(ethylene oxide)?
Magnitude of end-group contribution to the partitioning of ethylene oxide oligomers and
polymers between water and organic phases, J. Braz. Chem. Soc., 13, 7, 2002.
2002THU Thuresson, K., Karlson, L., and Lindman, B., Clouding of a cationic hydrophobically
associating comb polymer, Coll. Surfaces A, 201, 9, 2002.
2002WIL Willauer, H.D., Huddleston, J.G., and Rogers, R.D., Solute partitioning in aqueous biphasic
systems composed of polyethylene glycol and salt: the partitioning of small neutral organic
species, Ind. Eng. Chem. Res., 41, 1892, 2002.
2002YOU Young, T.-H. and Chuang, W.-Y., Thermodynamic analysis on the cononsolvency of
poly(vinyl alcohol) in water–DMSO mixtures through the ternary interaction parameter
(experimental data by T.-H. Young), J. Membrane Sci., 210, 349, 2002.
2002ZA1 Zafarani-Moattar, M.T. and Gasemi, J., Liquid-liquid equilibria of aqueous two-phase
systems containing polyethylene glycol and ammonium dihydrogen phosphate or diammo-
nium hydrogen phosphate. Experiment and correlation, Fluid Phase Equil., 198, 281, 2002.
2002ZA2 Zafarani-Moattar, M.T. and Sadeghi, R., Measurement and correlation of liquid-liquid
equilibria of the aqueous two-phase system polyvinylpyrrolidone-sodium dihydrogen
phosphate, Fluid Phase Equil., 203, 177, 2002.
2002ZAV Zavarzina, A.G., Demin, V.V., Nifant'eva, T.I., Shkinev, V.M., Danilova, T.V., and
Spivakov, B.Ya., Extraction of humic acids and their fractions in poly(ethylene glycol)-
based aqueous biphasic systems, Anal. Chim. Acta, 452 (2002) 95-103
2002ZHE Zheng, L., Suzuki, M., Inoue, T., and Lindman, B., Aqueous phase behavior of
hexaethylene glycol dodecyl ether studied by differential scanning calorimetry, Fourier
transform infrared spectroscopy, and 13C NMR spectroscopy, Langmuir, 18, 9204, 2002.
2003ASR Asrof Ali, Sk., Al-Muallem, H.A., and Mazumder, M.A.J., Synthesis and solution proper-
ties of a new sulfobetaine/sulfur dioxide copolymer and its use in aqueous two-phase
polymer systems, Polymer, 44, 1671, 2003.
2003BAD Badiger, M. V. and Wolf, B.A., Shear induced demixing and rheological behavior of aque-
ous solutions of poly(N-isopropylacrylamide), Macromol. Chem. Phys., 204, 600, 2003.
2003BAL Balcan, M., Anghel, D.-F., and Raicu, V., Phase behavior of water/oil/nonionic surfactants
with normal distribution of the poly(ethylene oxide) chain length, Colloid Polym. Sci., 281,
143, 2003.
____________________________________________________________________________________
2003CHA Chang, Y., Powell, E.S., Allcock, H.R., Park, S.M., and Kim, C., Thermosensitive behavior
of poly(ethylene oxide)-poly[bis(methoxyethoxyethoxy)-phosphazene] block copolymers,
2003CHR Chrapava, S., Touraud, D., Rosenau, T., Potthast, A., and Kunz, W., The investigation of
the influence of water and temperature on the LiCl/DMAc/cellulose system, Phys. Chem.
Chem. Phys., 5, 1842, 2003.
2003DAV David, G., Alupei, V., Simionescu, B. C., Dincer, S., and Piskin, E., Poly(N-isopropylacryl
amide)/poly[(N-acetylimino)ethylene] thermosensitive block and graft copolymers, Eur.
Polym. J., 39, 1209, 2003.
2003KOE Könderink, G.H., Aarts, D.G.A.L., DeVilleneuve, V.W.A., Philipse, A.P., Tuinier, R., and
Lekkerkerker, H.N.W., Morphology and kinetics of phase separating transparent xanthan-
colloid mixtures, Biomacromolecules, 4, 129, 2003.
2003MAE Maeda, Y., Tsubota, M., and Ikeda, I., Fourier transform IR spectroscopic study on phase
transitions of copolymers of N-isopropylacrylamide and alkyl acrylates in water, Colloid
Polym. Sci., 281, 79, 2003.
2003MIL Milewska, A., Szydlowski, J., and Rebelo, L.P.N., Viscosity and ultrasonic studies of
poly(N-isopropylacrylamide)-water solutions, J. Polym. Sci.: Part B: Polym. Phys., 41,
1219, 2003.
2003SCH Schmidt, J., Burchard, W., and Richtering, W., Shear-induced mixing and demixing in
aqueous methyl hydroxypropyl cellulose solutions, Biomacromolecules, 4, 453, 2003.
2003SHE Shen, L.-Q., Xu, Z.-K., and Xu, Y.-Y., Phase separation behavior of poly(ether imide)/N,N-
dimethylacetamide/nonsolvent systems, J. Appl. Polym. Sci., 89, 875, 2003.
2003SWI Swier, S., Van Durme, K., Van Mele, B., Modulated-temperature differential scanning
calorimetry study of temperature-induced mixing and demixing in poly(vinyl methyl ether)/
water, J. Polym. Sci.: Part B: Polym. Phys., 41, 1824, 2003.
2003YAM Yamamoto, K., Serizawa, T., and Akashi, M., Synthesis and thermosensitive properties of
poly[(N-vinylamide)-co-(vinyl acetate)]s and their hydrogels, Macromol. Chem. Phys., 204,
1027, 2003.
2003ZAF Zafarani-Moattar, M.T. and Hamidi, A.A., Liquid-liquid equilibria of aqueous two-phase
poly(ethylene glycol)-potassium citrate system, J. Chem. Eng. Data, 48, 262, 2003.
4.1. Experimental data of quasibinary polymer solutions

amido-D-glucitol copolymer 2002REB
−1 −1

wB 0.0102 0.0174 0.0233 0.0263 0.0397 0.0550 0.0102 0.0102 0.0102
T/K 413.2 384.8 368.5 358.1 353.0 366.0 428.6 450.3 465.0
P/bar 1.00 1.00 1.00 1.00 1.00 1.00 2.90 3.87 4.48
wB 0.0174 0.0174 0.0233 0.0233 0.0233 0.0233 0.0233 0.0397 0.0397
T/K 401.6 432.5 391.3 395.0 419.0 433.5 453.0 377.8 400.0
P/bar 2.27 3.87 2.10 2.27 3.58 5.71 8.57 2.57 3.65
wB 0.0550 0.0550 0.0550 0.0550 0.0550 0.0550 0.0550 0.0550
T/K 373.0 388.5 392.2 403.8 411.5 421.6 440.2 451.6
P/bar 1.62 2.26 2.45 2.90 3.58 4.70 7.43 8.84

−1 −1

wB 0.01001 0.03914 0.0400 0.08810 0.0070 0.0070 0.0070 0.0070 0.0070
T/K 321.1 315.6 313.7 315.1 320.9 321.8 322.7 323.4 323.8
P/bar 1.0 1.0 1.0 1.0 20.0 100.0 200.0 300.0 500.0
wB 0.0070 0.0230 0.0230 0.0230 0.0230 0.0230 0.0230
T/K 324.0 317.6 319.0 320.3 320.7 321.9 322.4
P/bar 600.0 20.0 200.0 300.0 400.0 600.0 700.0

−1 −1
continued
_____________________________________________________________________________
continued
Type of data: cloud-points (LCST-behavior)

wB 0.0050 0.0100 0.0305 0.0432 0.0530 0.0983 0.1103 0.1294 0.0038
T/K 313.1 311.3 310.1 309.8 309.3 308.6 308.0 307.3 311.7
P/bar 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 3.5
wB 0.0038 0.0038 0.0038 0.0038 0.0038 0.0038 0.0038 0.0038 0.0432
T/K 312.0 312.4 313.3 313.6 313.7 314.3 314.3 314.0 310.0
P/bar 62.0 110.0 200.0 300.0 400.0 500.0 600.0 700.0 10.0
wB 0.0432 0.0432 0.0432 0.0432 0.0432 0.0432 0.0432 0.0432 0.0432
T/K 310.1 310.3 310.5 310.8 311.1 311.4 311.8 311.8 312.0
P/bar 40.0 70.0 100.0 150.0 200.0 250.0 300.0 350.0 400.0
wB 0.0432 0.0432 0.0432 0.0432
T/K 312.1 312.3 312.3 312.0
P/bar 450.0 550.0 600.0 700.0
Polymer (B): penta(ethylene glycol) monoheptyl ether 1992SAS

−1
Characterization: Mn/g.mol = 336, surfactant C7E5, Bachem, purity > 98 wt%

wB 0.0100 0.0100 0.0100 0.0100 0.0100 0.0302 0.0302 0.0302 0.0302
T/K 341.74 342.82 343.92 345.93 348.12 341.34 342.28 343.02 345.04
P/MPa 6.35 15.34 25.65 46.20 71.60 8.35 15.45 21.45 39.35
wB 0.0302 0.0302 0.0302 0.0799 0.0799 0.0799 0.0799 0.0799 0.0799
T/K 346.98 347.88 349.98 339.94 340.96 341.91 343.15 344.14 345.06
P/MPa 59.25 70.15 96.15 1.88 9.85 17.55 28.65 38.15 47.45
wB 0.0799 0.0799 0.0987 0.0987 0.0987 0.0987 0.0987 0.0987 0.0987
T/K 347.03 348.93 340.88 341.93 342.97 345.08 346.89 347.77 348.75
P/MPa 70.25 95.95 7.95 16.55 25.75 46.15 66.75 77.65 91.15
wB 0.1595 0.1595 0.1595 0.1595 0.1595 0.1595 0.1595 0.1862 0.1862
T/K 340.81 341.84 342.85 344.87 346.94 348.05 349.40 340.56 342.65
P/MPa 6.65 15.05 23.85 43.15 66.15 80.05 99.15 2.83 19.65
wB 0.1862 0.1862 0.1862 0.2488 0.2488 0.2488 0.2488 0.2488 0.2488
T/K 344.78 346.67 348.65 340.79 341.91 342.89 344.06 345.84 347.81
P/MPa 39.45 59.75 84.75 1.03 9.75 17.95 28.55 46.25 68.65
wB 0.2488 0.2488 0.3489 0.3489 0.3489 0.3489 0.3489 0.3489 0.3489
T/K 348.80 349.79 343.87 345.05 345.92 347.86 349.80 350.75 351.88
P/MPa 81.45 95.35 10.55 20.65 28.55 47.95 70.55 83.05 99.35
wB 0.4006 0.4006 0.4006 0.4006 0.4006 0.4006 0.4006 0.5029 0.5029
T/K 345.04 346.19 347.36 347.88 350.71 351.73 353.05 349.77 350.70
P/MPa 5.95 15.45 25.35 30.05 58.45 70.35 87.45 7.15 14.45
continued
4. High-Pressure Phase Equilibrium (HPPE) Data 367
_____________________________________________________________________________
continued
wB 0.5029 0.5029 0.5029 0.5029 0.5029 0.5029
T/K 351.74 352.61 354.53 356.43 357.44 358.37
P/MPa 23.15 30.85 49.35 69.55 81.55 93.15
Polymer (B): poly(ethylene oxide) 1992COO

Pressure Chemical Company, Pittsburgh, PA, USA

cB/g.dl−1 1.0 20.0
T/K 295.65 295.65
P/MPa 557 539
Comments: The complete phase behavior is given in the original source in graphs.

American Polymer Standards, USA

cB/g.dl−1 0.3 1.0
T/K 295.65 295.65
P/MPa 430 435
Polymer (B): poly(N-isopropylacrylamide) 2001GOM


wB 0.04167 0.04167 0.04167 0.04167 0.04167 0.04167 0.04167 0.04167 0.04167
T/K 305.60 305.70 305.73 305.86 305.90 308.12 308.27 308.32
P/MPa 1.0 2.5 3.0 4.0 5.0 20.0 30.0 40.0
Type of data: spinodal points (LCST-behavior)

wB 0.04167 0.04167 0.04167 0.04167 0.04167
T/K 308.5 309.2 308.2 307.6 307.4
P/MPa 1.0 2.5 3.0 4.0 5.0
_____________________________________________________________________________
Polymer (B): poly(N-isopropylacrylamide) 2002REB


wB 0.0035 0.0035 0.0035 0.0035 0.0035 0.0035 0.0035 0.0035 0.0307
T/K 313.0 313.7 314.2 314.9 315.1 315.6 315.8 315.4 310.2
P/bar 100.0 202.0 354.5 507.5 558.5 609.5 660.5 711.5 20.5
wB 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307
T/K 311.2 311.7 312.5 313.1 313.2 313.4 313.4 313.3 313.0
P/bar 148.5 262.5 365.0 426.0 477.0 507.5 538.5 558.5 609.5


wB 0.0039 0.0039 0.0039 0.0039 0.0039 0.0039 0.0039 0.0039 0.0295
T/K 307.2 307.5 308.1 308.4 308.4 308.4 308.2 308.0 306.6
P/bar 20.55 50.00 148.50 252.50 354.50 426.00 507.50 609.50 20.55
wB 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295
T/K 307.0 307.7 308.1 308.1 308.0 307.9 307.9
P/bar 50.00 148.50 283.50 354.50 426.00 507.50 609.50


wB 0.0417 0.0417 0.0417 0.0417 0.0417 0.0417 0.0417 0.0417 0.0417
T/K 305.6 305.7 305.7 305.9 305.9 306.7 308.0 308.0 308.0
P/bar 10.0 25.0 30.0 40.0 50.0 100.0 200.0 300.0 400.0
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Hydroxypropylcellulose water 2001KUN
_____________________________________________________________________________
N-Isopropylacrylamide/acrylic acid copolymer water 1993OTA
water 2000YAM
_____________________________________________________________________________
N-Isopropylacrylamide/1-deoxy-1-methacryl-
amide-D-glucitol copolymer water 2001GOM
_____________________________________________________________________________
N-Isopropylacrylamide/4-pentenoic acid copolymer water 1999KUN
_____________________________________________________________________________
Poly(butylene terephthalate) water 1991SCH
_____________________________________________________________________________
Poly(ethylene glycol) water 1976SAE
_____________________________________________________________________________
Poly(ethylene oxide) water 1992COO
_____________________________________________________________________________
Poly(N-isopropylacrylamide) water 1993OTA
water 1997KUN
water 1999KUN
_____________________________________________________________________________
Poly(methacrylic acid) water 1974TAN
_____________________________________________________________________________
Poly(propylene glycol) water 1974TAN
_____________________________________________________________________________
Poly(N-vinylisobutyramide) water 1997KUN
water 1999KUN
_____________________________________________________________________________
N-Vinylacetylamide/vinyl acetate copolymer water 2003SET
_____________________________________________________________________________
N-Vinylformamide/vinyl acetate copolymer water 2003SET
_____________________________________________________________________________
_____________________________________________________________________________
4.3. Experimental data of quasiternary solutions containing water

and at least one polymer

Solvent (C): carbon dioxide CO2 124-38-9
Type of data: cloud points (UCST-behavior)

wA 0.90 0.90 0.90 0.90 0.864 0.864 0.864 0.864
wB 0.10 0.10 0.10 0.10 0.096 0.096 0.096 0.096
wC 0.00 0.00 0.00 0.00 0.04 0.04 0.04 0.04
T/K 369.9 370.2 369.8 369.9 356.7 355.7 355.5 355.1
P/MPa 1.10 3.10 6.10 8.10 12.10 13.60 15.10 17.10

Type of data: cloud points (UCST-behavior)

wA 0.90 0.90 0.90 0.90 0.90 0.90 0.882 0.882 0.882
wB 0.10 0.10 0.10 0.10 0.10 0.10 0.098 0.098 0.098
wC 0.00 0.00 0.00 0.00 0.00 0.00 0.02 0.02 0.02
T/K 414.7 415.0 414.0 413.8 412.8 414.7 407.1 405.0 405.3
P/MPa 1.10 3.10 7.10 10.10 12.10 16.10 4.40 10.10 13.10
wA 0.098 0.096 0.096 0.096
wB 0.098 0.096 0.096 0.096
wC 0.02 0.04 0.04 0.04
T/K 405.2 395.6 394.7 393.9
P/MPa 15.90 11.93 14.10 16.60
_____________________________________________________________________________
Polymer (B): poly(ethylene glycol) dimethyl ether 1995GAI

Characterization: PEGDM-mixture used for the Selexol process
diethylene glycol dimethylether 2.07 Ma%
diethylene glycol monomethylether 0.16 Ma%
triethylene glycol dimethylether 21.01 Ma%
triethylene glycol monomethylether 0.72 Ma%
tetraethylene glycol dimethylether 33.68 Ma%
tetraethylene glycol monomethylether 0.67 Ma%
pentaethylene glycol dimethylether 26.39 Ma%
pentaethylene glycol monomethylether 0.38 Ma%
hexaethylene glycol dimethylether 12.78 Ma%
hexaethylene glycol monomethylether 0.10 Ma%
heptaethylene glycol dimethylether 1.87 Ma%
Solvent (A): carbon dioxide CO2 124-38-9
Solvent (C): diisopropanolamine C6H15NO2 110-97-4
Solvent (D): water H2O 7732-18-5
Comments: The feed liquid mixture is given by wB = 0.85 + wC = 0.10 + wD = 0.05.
Type of data: gas solubility
T/K = 298.15
P/MPa 0.385 0.730 1.327 1.753 2.077 2.533 3.030 3.587 4.053
xA 0.0798 0.1386 0.2100 0.2584 0.2856 0.3224 0.3650 0.4139 0.4600
T/K = 313.15
P/MPa 0.517 0.963 1.317 1.814 2.148 2.614 2.908 3.567 4.063
xA 0.0753 0.1374 0.1748 0.2211 0.2474 0.2772 0.2976 0.3366 0.3716
T/K = 333.15
P/MPa 0.547 0.922 1.327 1.854 2.290 2.553 2.928 3.526 4.083
xA 0.0558 0.0879 0.1215 0.1557 0.1814 0.1958 0.2188 0.2562 0.2996

see data set above
Solvent (A): hydrogen H2 1333-74-0
T/K = 298.15
P/MPa 1.023 1.510 1.672 2.057 2.361 2.634 3.009 3.405 3.769
xA 0.0022 0.0031 0.0035 0.0042 0.0049 0.0055 0.0062 0.0070 0.0078
continued
_____________________________________________________________________________
continued
T/K = 313.15
P/MPa 1.013 1.398 1.601 2.097 2.341 2.564 2.999 3.263 3.587
xA 0.0023 0.0032 0.0036 0.0048 0.0054 0.0058 0.0068 0.0074 0.0081
T/K = 333.15
P/MPa 1.023 1.419 1.702 1.935 2.280 2.564 2.979 3.212 3.840
xA 0.0027 0.0038 0.0045 0.0052 0.0060 0.0068 0.0079 0.0086 0.0102

see data set above
Solvent (A): nitrogen N2 7727-37-9
T/K = 298.15
P/MPa 1.034 1.439 1.925 2.239 2.564 2.817 3.081 3.405 3.699
xA 0.0031 0.0043 0.0058 0.0067 0.0077 0.0085 0.0092 0.0103 0.0111
T/K = 313.15
P/MPa 1.023 1.419 1.672 1.935 2.219 2.604 2.717 3.091 3.526
xA 0.0035 0.0049 0.0057 0.0067 0.0076 0.0089 0.0096 0.0106 0.0121
T/K = 333.15
P/MPa 1.013 1.409 1.804 1.996 2.169 2.462 2.888 3.101 3.506
xA 0.0037 0.0053 0.0067 0.0074 0.0080 0.0091 0.0106 0.0115 0.0129
Polymer (B): poly(vinyl chloride) 1985GEE

fractionated in the laboratory
Solvent (A): tetrahydrofuran C4H8O 109-99-9
Solvent (C): water H2O 7732-18-5
wA 0.8145 0.8145 0.8145 0.8094 0.8094 0.8094 0.8065 0.8065 0.8065
wB 0.0795 0.0795 0.0795 0.0790 0.0790 0.0790 0.0787 0.0787 0.0787
wC 0.1060 0.1060 0.1060 0.1116 0.1116 0.1116 0.1148 0.1148 0.1148
T/K 283.85 286.85 290.25 295.85 299.05 303.45 303.55 306.75 311.55
P/bar 1 500 1000 1 500 1000 1 500 1000
_____________________________________________________________________________

wA 0.8194 0.8194 0.8194 0.8151 0.8151 0.8151 0.8097 0.8097 0.8097
wB 0.0800 0.0800 0.0800 0.0796 0.0796 0.0796 0.0789 0.0789 0.0789
wC 0.1006 0.1006 0.1006 0.1053 0.1053 0.1053 0.1114 0.1114 0.1114
T/K 282.85 286.95 291.35 293.25 298.25 302.55 307.15 310.25 315.65
P/bar 1 500 1000 1 500 1000 1 500 1000

wA 0.8546 0.8546 0.8546 0.8498 0.8498 0.8498 0.8547 0.8547 0.8547
wB 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0199 0.0199 0.0199
wC 0.1254 0.1254 0.1254 0.1302 0.1302 0.1302 0.1254 0.1254 0.1254
T/K 279.65 283.95 292.65 293.65 302.05 309.65 309.65 319.15 327.15
P/bar 1 500 1000 1 500 1000 1 500 1000
wA 0.8439 0.8439 0.8439 0.8389 0.8389 0.8389 0.8334 0.8334 0.8334
wB 0.0407 0.0407 0.0407 0.0405 0.0405 0.0405 0.0403 0.0403 0.0403
wC 0.1154 0.1154 0.1154 0.1206 0.1206 0.1206 0.1263 0.1263 0.1263
T/K 284.05 289.25 296.05 299.25 305.25 311.55 310.95 319.75 326.15
P/bar 1 500 1000 1 500 1000 1 500 1000
wA 0.8338 0.8338 0.8338 0.8292 0.8292 0.8292 0.8245 0.8245 0.8245
wB 0.0613 0.0613 0.0613 0.0609 0.0609 0.0609 0.0607 0.0607 0.0607
wC 0.1049 0.1049 0.1049 0.1099 0.1099 0.1099 0.1148 0.1148 0.1148
T/K 285.25 287.85 293.15 296.75 301.65 306.05 308.75 314.35 320.45
P/bar 1 500 1000 1 500 1000 1 500 1000
wA 0.8244 0.8244 0.8244 0.8200 0.8200 0.8200 0.8150 0.8150 0.8150
wB 0.0952 0.0952 0.0952 0.0999 0.0999 0.0999 0.1056 0.1056 0.1056
wC 0.0952 0.0952 0.0952 0.0999 0.0999 0.0999 0.1056 0.1056 0.1056
T/K 275.45 277.55 280.35 287.95 290.15 294.45 299.85 304.65 308.45
P/bar 1 500 1000 1 500 1000 1 500 1000
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
water and different salts 2001KUN
_____________________________________________________________________________
Penta(ethylene glycol) monoheptyl ether
n-dodecane and water 1992SAS
_____________________________________________________________________________
water and different salts 1998SUW
_____________________________________________________________________________
Poly(methyl methacrylate)
carbon dioxide and water 1997VIN
carbon dioxide and water 1998KAZ
_____________________________________________________________________________
Poly(perfluoropropylene oxide) acid
sorbitol ester
carbon dioxide and water 1997SIN
_____________________________________________________________________________
Polystyrene
cyclohexane and water 1991DEE
_____________________________________________________________________________
water and different salts 1998SUW
_____________________________________________________________________________
N-Vinylformamide/vinyl acetate
copolymer
water and different salts 2003SET
_____________________________________________________________________________
_____________________________________________________________________________
4.5. References
1976SAE Saeki, S., Kuwahara, N., Nakata, M., and Kaneko, M., Upper and lower critical solution
1985GEE Geerissen, H., Roos, J., and Wolf, B.A., Continuous fractionation and solution properties of
PVC 4. Pressure dependence of the solubility in a mixed solvent, Makromol. Chem., 186,
777, 1985.
1991DEE Dee, G.T., The application of equation-of-state theories to polar-nonpolar liquid mixtures,
J. Supercrit. Fluids, 4, 152, 1991.
1991SCH Schultze, J.D., Zhou, Z., and Springer, J., Gas sorption in poly(butylene terephthalate). A
critical test of the influence of gas data, Angew. Makromol. Chem., 185-186, 265, 1991.
1992COO Cook, R.L., King, H.E., and Peiffer, D.G., Pressure-induced crossover from good to poor
solvent behavior for polyethylene oxide in water, Phys. Rev. Lett., 69, 3072, 1992.
1992SAS Sassen, C.L., Gonzales Casielles, A., de Loos, Th.W., de Swaan Arons, J., The influence of
pressure and temperature on the phase behaviour of the system H2O + C12 + C7E5 and
relevant binary subsystems, Fluid Phase Equil., 72, 173, 1992.
1993OTA Otake, K., Karaki, R., Ebina, T., Yokoyama, C., and Takahashi, S., Pressure effects on the
aggregation of poly(N-isopropylacrylamide) and poly(N-isopropylacrylamide-co-acrylic
acid) in aqueous solutions, Macromolecules, 26, 2194, 1993.
1995GAI Gainar, I. and Anitescu, G., The solubility of CO2, N2, and H2 in a mixture of dimethylether
polyethylene glycols at high pressures, Fluid Phase Equil., 109, 281, 1995.
1997KUN Kunugi, S., Takano, K., Tanaka, N., Suwa, K., and Akashi, M., Effects of pressure on the
behavior of the thermoresponsive polymer poly(N-vinylisobutyramide) (PNVIBA),
1997SIN Singley, E.J., Liu, W., and Beckman, E.J., Phase behavior and emulsion formation of novel
fluoroether amphiphiles in CO2, Fluid Phase Equil., 128, 199, 1997.
1997VIN Vincent, M.F., Kazarian, S.G., and Eckert, C.A., Tunable diffusion of D2O in CO2-swollen
poly(methyl methacrylate) films, AIChE-J., 43, 1838, 1997.
1998KAZ Kazarian, S.G., Vincent, M.F., and Eckert, C.A., Partitioning of solutes and cosolvents
between supercritical CO2 and polymer phases, J. Supercrit. Fluids, 13, 107, 1998.
1998SUW Suwa, K., Yamamoto, K., Akhashi, M., Takano, K., Tanaka, N., and Kunugi, S., Effects of
salt on the temperature and pressure responsive properties of poly(N-vinylisobutyramide)
aqueous solutions, Colloid Polym. Sci., 276, 529, 1998.
1999KUN Kunugi, S., Yamazaki, Y., Takano, K., and Tanaka, N., Effects of ionic additives and ionic
comonomers on the temperature and pressure responsive behavior of thermoresponsive
polymers in aqueous solutions, Langmuir, 15, 4056, 1999.
2001KUN Kunugi, S., Yoshida, D., and Kiminami, H., Effects of pressure on the behavior of
(hydroxypropyl)cellulose in aqueous solution, Colloid Polym. Sci., 279, 1139, 2001.
_____________________________________________________________________________
2003SET Seto, Y., Kameyama, K., Tanaka, N., Kunugi, S., Yamamoto, K., and Akashi, M., High-
pressure studies on the coacervation of copoly(N-vinylformamide-vinylacetate) and
copoly(N-vinylacetylamide-vinylacetate), Colloid Polym. Sci., 281, 690, 2003.
5. ENTHALPY CHANGES FOR AQUEOUS POLYMER
SOLUTIONS

and polymer partial enthalpies of mixing (at infinite dilution),
or polymer (first) integral enthalpies of solution
Polymer (B): dextran 1980BAS

T/K = 298.15 ϕB(1) = 0.25 ϕB(2) = 0.01 ∆dilh12/(J/g polymer) −0.68
Comments: ϕB(1) and ϕB(2) denote the volume fractions of the polymer in the solution before and after
the dilution process. Additional data were given by a figure in the original source.
T/K = 298.15 ∆solHB∞ = −140 J/(g polymer)
Polymer (B): dextran 1979BAS

(1) (2) 12
T/K = 298.15 wB = 0.12 wB = 0.04 ∆dilh /(J/g polymer) −0.07
(1) (2)
Comments: wB and wB denote the mass fractions of the polymer in the solution before and after the
dilution process. Additional data were given by a figure in the original source.
Polymer (B): dextran 1995GRO, 1995TIN

T-500, Pharmacia Fine Chemicals, Uppsala, Sweden
T/K = 298.15
mA'/g 39.54 30.30 39.54 39.41 39.33 39.45 39.55 29.91 39.19
mB'/g 0.0 12.98 0.0 0.0 0.0 0.0 0.0 12.81 0.0
mA"/g 6.820 8.588 4.706 4.930 5.126 4.561 4.267 8.730 6.849
mB"/g 2.293 0.0 3.136 3.287 5.124 5.147 5.216 0.0 2.935
∆dilh12/J −1.6 −1.8 −3.3 −4.0 −9.4 −10.4 −13.6 −1.7 −2.0
mA'/g 39.47 39.39 39.36 39.18 39.05
mB'/g 0.0 0.0 0.0 0.0 0.0
mA"/g 6.050 5.369 5.128 4.831 4.510
mB"/g 4.032 3.579 5.126 5.452 5.515
∆dilh12/J −3.6 −5.1 −9.9 −10.5 −15.2
continued
_____________________________________________________________________________
continued
T/K = 333.15
mA'/g 38.82 39.03 38.50 38.81
mB'/g 0.0 0.0 0.0 0.0
mA"/g 5.271 4.884 5.874 4.648
mB"/g 3.568 4.884 3.976 4.647
∆dilh12/J −4.8 −13.4 −5.4 −14.8
Comments: ∆dilh12 is the extensive enthalpy change in the result of the mixing process obtained for the
given masses in the table, where the superscripts ' and " designate the two solutions placed
in the two parts of a mixing cell, respectively.
Polymer (B): dextran 1976KIS

Characterization: ρ = 1.303 g/cm3, completely amorphous sample
∞
T/K = 298.15 ∆solHB = −123.4 J/(g polymer)
Polymer (B): gelatine 1958MEE

Characterization: −
T/K = 293.15 ∆solHB∞ = −92.0 J/(g polymer)
Comments: Additional data were given by a figure in the original source, also for solutions containing
urea.
Polymer (B): maltopentaose 2002COO

T/K = 318.15
xB 0.00084 0.00113 0.00159 0.00229
∆MHA/J.mol−1 0.05 −0.02 −0.10 −0.14
Polymer (B): maltotetraose 2002COO

T/K = 318.15
xB 0.00123 0.00171 0.00250
∆MHA/J.mol−1 −0.01 −0.10 −0.22
5. Enthalpy Data 379
_____________________________________________________________________________
Polymer (B): maltotriose 2002COO

T/K = 318.15
xB 0.00128 0.00195 0.00303 0.00345 0.00482 0.00541 0.01259
∆MH/J.mol−1 −25 −39 −61 −69 −96 −109 −249
∆MHA/J.mol−1 0.02 0.01 −0.18 −0.54 −0.64 −1.77 −5.07
Polymer (B): oxyethylcellulose 1982MEE

Characterization: 3 mole ethylene oxide per 1 mole cellulosic units
∞
Comments: The final concentration is 0.13 polymer/20 g solution.
Polymer (B): penta(ethylene glycol) 1998OHT

∞
T/K = 283.15 ∆MHB = −41.31 ± 0.041 kJ/mol
T/K = 288.15 ∆MHB∞ = −40.67 ± 0.033 kJ/mol
T/K = 293.15 ∆MHB∞ = −39.73 ± 0.030 kJ/mol
T/K = 298.15 ∆MHB∞ = −38.77 ± 0.024 kJ/mol
T/K = 303.15 ∆MHB∞ = −37.61 ± 0.024 kJ/mol
T/K = 308.15 ∆MHB∞ = −36.51 ± 0.016 kJ/mol
T/K = 313.15 ∆MHB∞ = −35.32 ± 0.026 kJ/mol
Polymer (B): poly(acrylic acid) 1988AZU

T/K = 298.15
ϕB(1) 0.0273 0.0273 0.0273 0.0273 0.0559 0.0559 0.0559 0.0559
ϕB(2) 0.0191 0.0164 0.0136 0.0109 0.0336 0.0280 0.0224 0.0168
∆dilh12/J.mol−1 0.227 0.199 0.514 0.129 0.671 0.568 0.468 0.361
ϕB(1) 0.0559 0.0856 0.0856 0.0856 0.0856 0.0856
ϕB(2) 0.0112 0.0559 0.0514 0.0428 0.0342 0.0257
∆dilh12/J.mol−1 0.250 1.450 1.270 1.100 0.913 0.729
Comments: ∆dilh12 is the enthalpy change caused by diluting the primary solution by 1 mol solvent,
where ϕB(1) and ϕB(2) denote the volume fractions of the polymer in the solution before and
after the dilution process.
_____________________________________________________________________________

T/K = 298.15
ϕB(1) 0.0346 0.0346 0.0346 0.0346 0.0346 0.0346 0.0739 0.0739
ϕB(2) 0.0277 0.0242 0.0173 0.0138 0.0104 0.0069 0.0665 0.0591
∆dilh12/J.mol−1 0.324 0.258 0.205 0.164 0.131 0.085 1.480 1.270
ϕB(1) 0.0739 0.0739 0.0739 0.0739 0.0739 0.107 0.107 0.107
ϕB(2) 0.0444 0.0370 0.0296 0.0222 0.0148 0.0748 0.0534 0.320
∆dilh12/J.mol−1 0.942 0.803 0.658 0.519 0.367 2.190 1.590 1.040

T/K = 298.15
ϕB(1) 0.0334 0.0334 0.0334 0.0334 0.0334 0.0609 0.0609 0.0609
ϕB(2) 0.0234 0.0200 0.0167 0.0134 0.0100 0.0426 0.0366 0.0305
∆dilh12/J.mol−1 0.234 0.200 0.170 0.140 0.109 0.761 0.642 0.542
ϕB(1) 0.0609 0.0886 0.0886 0.0886 0.0886
ϕB(2) 0.0244 0.0532 0.0443 0.0355 0.0266
∆dilh12/J.mol−1 0.443 1.330 1.090 0.882 0.660

T/K = 298.15
ϕB(1) 0.0210 0.0210 0.0210 0.0281 0.0281 0.0281 0.0281 0.0281
ϕB(2) 0.0168 0.0084 0.0063 0.0225 0.0197 0.0169 0.0141 0.0112
∆dilh12/J.mol−1 0.068 0.034 0.023 0.128 0.104 0.081 0.064 0.052
ϕB(1) 0.0281 0.0353 0.0353 0.0353 0.0353 0.0353 0.0353 0.0353
ϕB(2) 0.0084 0.0282 0.0247 0.0247 0.0212 0.0177 0.0141 0.0106
∆dilh12/J.mol−1 0.037 0.264 0.198 0.198 0.148 0.127 0.089 0.070
ϕB(1) 0.0353 0.0426 0.0426 0.0426 0.0647 0.0647 0.0647 0.0647
ϕB(2) 0.0071 0.0383 0.170 0.085 0.453 0.388 0.324 0.259
∆dilh12/J.mol−1 0.043 0.434 0.127 0.062 0.977 0.770 0.577 0.447
continued
_____________________________________________________________________________
continued
ϕB(1) 0.0647 0.0647 0.0647 0.0721 0.0721 0.0721 0.0721 0.0721
ϕB(2) 0.194 0.129 0.065 0.0361 0.0288 0.0216 0.0144 0.0072
∆dilh12/J.mol−1 0.310 0.206 0.094 0.843 0.626 0.430 0.279 0.129
Polymer (B): poly(acrylic acid) 1971CAR

Characterization: Mη/g.mol−1 = 300000
T/K = 298.15
ϕB(1) 0.0888 0.0609 0.0433 0.0301 0.0216 0.0150 0.0108 0.0076
ϕB(2) 0.0664 0.0460 0.0325 0.0227 0.0161 0.0113 0.0081 0.0057
∆dilh12/(J/g polymer) 0.3808 0.2323 0.1919 0.1159 0.0901 0.0622 0.0306 0.0333
the dilution process.
Polymer (B): poly(ethylene glycol) 1967KAG

T/K = 298.15
V (1)/cm3 14.05 19.38 6.85 11.12 15.39 35.66 45.72 6.25 6.25
ϕB(1) 1.000 1.000 1.000 0.616 0.445 0.191 0.148 1.000 1.000
V (2)/cm3 19.07 28.89 11.12 15.39 25.50 45.72 55.91 16.38 26.38
ϕB(2) 0.713 0.670 0.616 0.445 0.268 0.148 0.121 0.381 0.236
∆dilh12/J −463.1 −781.3 −321.4 −135.1 −133.1 −33.1 −21.9 −456.6 −549.8
Comments: ∆dilh12 is the extensive quantity obtained for a given total volume change from V (1) to V (2),

T/K = 321.35
wB 0.00356 0.0108 0.0227 0.0489 0.0733 0.0932 0.193 0.285
∆MH/J.mol−1 −5.48 −26.6 −53.6 −116 −172 −255 −527 −862
wB 0.356 0.412 0.529 0.601 0.686 0.786 0.888 0.979
∆MH/J.mol−1 −1090 −1260 −1840 −2060 −2290 −2430 −2120 −849
_____________________________________________________________________________

T/K = 353.45
wB 0.287 0.475 0.630 0.719 0.820 0.897 0.948
∆MH/J.g−1 −26.32 −33.68 −31.13 −27.57 −22.01 −12.97 −5.94
Polymer (B): poly(ethylene glycol) 1961CUN

T/K = 300.05
wB 0.130 0.209 0.296 0.323 0.392 0.411 0.478 0.520 0.636
∆MH/J.g−1 −18.83 −30.79 −40.42 −41.63 −49.37 −49.79 −53.14 −53.97 −53.56
wB 0.722 0.816 0.886
∆MH/J.g−1 −43.93 −32.01 −23.22

T/K = 300.05
wB 0.02147 0.03852 0.07416 0.1190 0.1670 0.2310 0.3337 0.4022
∆MH/J.mol−1 −57.90 −110.5 −204.0 −335.6 −434.2 −693.3 −1078 −1311
Polymer (B): poly(ethylene glycol) 1979KOL, 1981KOL

Comments: The final concentration is 0.13 polymer/100 cm3 solvent.

T/K = 321.35
wB 0.00505 0.00948 0.0139 0.0232 0.0476 0.0723 0.0997 0.143
∆MH/J.mol−1 −12.8 −22.1 −41.7 −58.6 −134 −228 −287 −477
wB 0.221 0.295 0.362 0.424 0.476 0.556 0.662 0.807
∆MH/J.mol−1 −770 −1080 −1360 −1640 −1790 −2150 −2590 −2900
wB 0.846 0.877 0.976 0.981
∆MH/J.mol−1 −3000 −2710 −1590 −1270
_____________________________________________________________________________

T/K = 321.35 ∆solHB∞ = −60 kJ/mol polymer
Polymer (B): poly(ethylene glycol) 1989AND

Characterization: M/g.mol−1 = 400
T/K = 278.15
wB 0.0241 0.0589 0.1750 0.3805 0.6188 0.7850 0.9060 0.9540
∆MHA/(J/g solvent) −9 −6 −53 −412 −1529 −2638 −3726 −4383
T/K = 298.15
wB 0.0000 0.0241 0.0589 0.1750 0.3805 0.6188 0.7850 0.9060
∆MHA/(J/g solvent) +0.3 −0.3 −12 −52 −373 −1462 −2507 −3452
wB 0.9540 0.9763 0.9917 1.0000
∆MHA/(J/g solvent) −3724 −4215 −4561 −4753
T/K = 317.15
wB 0.0000 0.0241 0.0589 0.1750 0.3805 0.6188 0.7850 0.9060
∆MHA/(J/g solvent) +4 −0.6 −5 −48 −379 −1353 −2288 −2963
wB 0.9540 0.9763 0.9917 1.0000
∆MHA/(J/g solvent) −3286 −3826 −4299 −4583

Characterization: Mn/g.mol−1 = 414.5, Polymer Standard Services, Mainz, Germany
T/K = 298.15
mA'/g 28.17 3.371 22.17 28.25 20.74 6.353 9.333 28.04 12.42
mB'/g 0.0 27.34 7.390 0.0 8.901 25.24 21.90 0.0 18.24
mA"/g 16.62 0.0 19.63 14.75 20.19 0.0 0.0 11.07 0.0
mB"/g 4.158 22.34 0.0 6.302 0.0 22.65 22.52 10.95 22.63
∆dilh12/J −42.2 −59.8 −71.8 −112 −115 −136 −277 −416 −528
mA'/g 28.52 15.28 28.14 27.92 28.86 18.05 39.63 28.02 0.0
mB'/g 0.0 15.28 0.0 0.0 0.0 12.03 0.0 0.0 44.43
mA"/g 8.913 0.0 6.671 6.713 6.757 0.0 0.0 4.557 8.458
mB"/g 13.37 22.92 15.63 15.69 15.77 22.63 9.667 18.25 0.0
∆dilh12/J −705 −865 −1081 −1091 −1106 −1240 −1472 −1585 −1646
mA'/g 0.0 0.0 23.31 28.23 25.83 28.01 0.0 27.92 0.0
mB'/g 44.43 44.27 5.810 0.0 2.867 0.0 31.90 0.0 31.70
mA"/g 8.458 8.423 0.0 2.247 0.0 0.0 19.94 0.0 20.03
mB"/g 0.0 0.0 22.44 20.47 22.71 22.70 0.0 22.60 0.0
∆dilh12/J −1664 −1698 −2065 −2137 −2441 −2745 −2763 −2720 −2793
continued
_____________________________________________________________________________
continued
mA'/g 28.23 3.496 22.03 20.68 6.366 9.387 27.92 12.48 27.92
mB'/g 0.0 28.36 7.342 8.874 25.29 21.90 0.0 18.71 0.0
mA"/g 16.95 0.0 19.96 20.12 0.0 0.0 11.23 0.0 8.912
mB"/g 4.239 22.36 0.0 0.0 22.72 22.60 11.12 22.46 13.37
∆dilh12/J −42.7 −61.6 −72.5 −114 −134 −277 −413 −518 −700
mA'/g 15.22 28.25 28.61 28.16 18.16 39.54 28.11 0.0 20.75
mB'/g 15.22 0.0 0.0 0.0 12.10 0.0 0.0 44.27 8.900
mA"/g 0.0 6.619 6.718 6.626 0.0 0.0 4.585 8.423 0.0
mB"/g 22.69 15.50 15.68 15.52 22.20 9.574 18.36 0.0 22.56
∆dilh12/J −859 −1050 −1085 −1094 −1229 −1380 −1585 −1638 −1649
mA'/g 20.58 23.30 28.31 25.68
mB'/g 8.827 5.817 0.0 2.851
mA"/g 0.0 0.0 2.240 0.0
mB"/g 22.66 22.50 20.41 22.73
∆dilh12/J −1668 −2058 −2119 −2423
T/K = 333.15
mA'/g 39.03 13.05 38.93 0.0 39.02 12.87 39.05 0.0
mB'/g 0.0 30.44 0.0 43.24 0.0 30.01 0.0 43.54
mA"/g 2.735 8.085 0.0 8.150 2.835 8.245 0.0 8.342
mB"/g 6.376 0.0 8.993 0.0 6.608 0.0 8.862 0.0
∆dilh12/J −447 −588 −1096 −1273 −468 −608 −1101 −1281
Comments: Explanations for ∆dilh12 and superscripts ' and " appear on page 378.

T/K = 303.15
cB(1)/(g.cm−3) 0.1 0.02 0.010 0.020 0.031 0.051 0.101 0.200
cB(2)/(g.cm−3) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005
∆dilh12/(J/g polymer) −7.3 −1.16 −0.5 −1.1 −2.1 −3.0 −7.3 −14.7
cB(1)/(g.cm−3) 0.404 0.450 0.564 1.12
cB(2)/(g.cm−3) 0.005 0.005 0.005 0.005
∆dilh12/(J/g polymer) −31.6 −32.3 −43.0 −83.3
Comments: cB(1) and cB(2) denote the concentrations of the polymer in the solution before and after the
dilution process.

continued
_____________________________________________________________________________
continued
T/K = 298.15
V (1)/cm3 5.0 10.0 25.0 40.0 5.0 5.0 5.0 25.0 30.0
ϕB(1) 1.000 0.500 0.200 0.125 1.000 1.000 1.000 0.200 0.167
V (2)/cm3 10.0 15.0 30.0 45.0 25.0 35.0 45.0 30.0 35.0
ϕB(2) 0.500 0.333 0.167 0.111 0.200 0.143 0.111 0.167 0.143
∆dilh12/J −235.4 −70.75 −14.39 − 5.90 −358.6 −383.8 −399.0 −14.39 −9.96

T/K = 300.05
wB 0.01907 0.03857 0.07766 0.1075 0.1668 0.2310 0.3395 0.4131
∆MH/J.mol−1 −60.71 −119.7 −240.6 −333.9 −530.08 −775.7 −1184 −1444

T/K = 300.05
wB 0.01320 0.02658 0.05175 0.07574 0.1205 0.1399 0.2543 0.3236
∆MH/J.mol−1 −28.87 −68.03 −194.3 −189.5 −302.4 −372.2 −616.7 −737.6

−1
Characterization: Mn/g.mol = 943.1, Polymer Standard Services, Mainz, Germany
T/K = 298.15
mA'/g 28.27 28.19 12.29 28.19 23.35 23.34 27.76 12.42 28.22
mB'/g 0.0 0.0 18.43 0.0 5.838 5.836 0.0 18.62 0.0
mA"/g 16.91 8.760 19.81 4.515 19.90 20.40 8.793 19.88 4.615
mB"/g 4.226 13.13 0.0 17.88 0.0 0.0 13.18 0.0 18.28
∆dilh12/J −37.9 −715 −769 −1686 −37.0 −38.9 −732 −783 −1755
T/K = 333.15
mA'/g 38.85 12.92 0.0 38.98 38.84 12.82 0.0 38.88
mB'/g 0.0 30.11 43.60 0.0 0.0 29.905 43.12 0.0
mA"/g 2.826 8.056 8.191 0.0 2.846 8.052 8.167 0.0
mB"/g 6.584 0.0 0.0 9.169 6.630 0.0 0.0 9.421
∆dilh12/J −491 −647 −1099 −1157 −503 −667 −1104 −1161
Comments: Explanations for ∆dilh12 and superscripts ' and " appear on page 378.
_____________________________________________________________________________


T/K = 321.35
wB 0.00364 0.0140 0.0243 0.0357 0.0481 0.0618 0.0817 0.135
∆MH/J.mol−1 −6.44 −26.4 −51.9 −105 −126 −165 −227 −416
wB 0.221 0.300 0.371 0.486 0.576 0.694 0.878 0.972
∆MH/J.mol−1 −703 −992 −1240 −1820 −2260 −2670 −3080 −2260

T/K = 298.15
V (1)/cm3 26.6 46.6 15.3 25.3 50.3 10.5 30.3 36.6 36.6
ϕB(1) 0.230 0.131 0.341 0.206 0.103 0.096 0.172 0.167 0.167
V (2)/cm3 36.6 66.6 25.3 30.3 60.3 20.5 50.3 66.6 76.6
ϕB(2) 0.167 0.092 0.206 0.172 0.086 0.046 0.103 0.092 0.080
∆dilh12/J −26.13 −15.43 −49.73 −11.53 −5.548 −2.853 −22.66 −30.34 −35.65

T/K = 303.15
cB(1)/(g.cm−3) 0.1 0.02
cB(2)/(g.cm−3) 0.005 0.005
∆dilh12/(J/g polymer) −6.1 −0.98
dilution process.
_____________________________________________________________________________

T/K = 300.05
wB 0.03192 0.05559 0.1054 0.1501 0.2275 0.3062 0.4120 0.5130
∆MH/J.mol−1 −23.43 −45.44 −79.29 −115.9 −187.0 −200.4 −322.5 −263.3


T/K = 321.35
wB 0.00232 0.00678 0.0145 0.0283 0.0376 0.0600 0.0647 0.0826
∆MH/J.mol−1 −4.94 −14.7 −36.9 −76.6 −107 −175 −187 −223
wB 0.120 0.143 0.184 0.272 0.345 0.418 0.557 0.661
∆MH/J.mol−1 −366 −435 −548 −866 −1120 −1460 −2330 −2780
wB 0.771 0.917 0.976
∆MH/J.mol−1 −3060 −2960 −2080

T/K = 303.15
cB(1)/(g.cm−3) 0.1 0.02
cB(2)/(g.cm−3) 0.005 0.005
dilution process.

T/K = 303.15 ∆solHB∞ = 57 J/(g polymer)
_____________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1979MON

T/K = 298.31
ϕB(1) 0.0747 0.0721 0.0675 0.0634 0.0617 0.567 0.535
ϕB(2) 0.0721 0.0675 0.0634 0.0617 0.0567 0.0535 0.0497
12
∆dilh /(J/g polymer) −0.219 −0.461 −0.394 −0.015 −0.472 −0.297 −0.355
Polymer (B): poly(ethylene glycol) 1980SCH

T/K = 298.31
wB(1) 0.1088 0.1052 0.0987 0.0929 0.0905 0.0834
wB(2) 0.1052 0.0987 0.0929 0.0905 0.0834 0.0788
∆dilh12/J −0.693 −1.391 −1.245 −0.465 −1.493 −0.940
Comments: ∆dilh12 is here an extensive quantity obtained for a given total mass change of 1 g. wB(1) and
wB(2) are the mass fractions of the polymer in the solution before and after dilution.

T/K = 298.31
ϕB(1) 0.0606 0.0584 0.0408 0.0390 0.0367 0.0346 0.0269 0.0458
ϕB(2) 0.0584 0.0563 0.0394 0.0367 0.0346 0.0327 0.0261 0.0442
∆dilh12/(J/g polymer) −0.192 −0.175 −0.129 −0.192 −0.157 −0.163 −0.060 −0.146
ϕB(1) 0.1529 0.1482 0.1438 0.1397 0.1266 0.1234 0.1028 0.0958
ϕB(2) 0.1482 0.1438 0.1397 0.1358 0.1234 0.1203 0.0922 0.0917
∆dilh12/(J/g polymer) −0.412 −0.405 −0.391 −0.368 −0.306 −0.296 −0.351 −0.420
ϕB(1) 0.0526 0.0473 0.0364 0.0338 0.0473 0.0313 0.1214 0.1214
ϕB(2) 0.0473 0.0430 0.0338 0.0313 0.0430 0.0289 0.0529 0.0531
∆dilh12/(J/g polymer) −0.402 −0.336 −0.212 −0.173 −0.334 −0.167 −6.49 −6.57
T/K = 304.80
ϕB(1) 0.1353 0.1221 0.1188 0.1127 0.1098 0.0964 0.0943 0.0923
(2)
ϕB 0.1333 0.1188 0.1156 0.1098 0.1032 0.0943 0.0923 0.0904
∆dilh12/(J/g polymer) −0.153 −0.246 −0.250 −0.222 −0.578 −0.188 −0.161 −0.165
ϕB(1) 0.0904 0.0877 0.0812 0.0783 0.0683 0.0638 0.0590 0.0453
ϕB(2) 0.0877 0.0860 0.0797 0.0769 0.0638 0.0590 0.0549 0.0423
∆dilh12/(J/g polymer) −0.250 −0.153 −0.122 −0.126 −0.424 −0.431 −0.384 −0.252
continued
_____________________________________________________________________________
continued
T/K = 330.48
ϕB(1) 0.0718 0.0694 0.0374 0.0345 0.1629 0.1609 0.1588 0.1380
ϕB(2) 0.0636 0.0670 0.0345 0.0321 0.1609 0.1588 0.1569 0.1366
∆dilh12/(J/g polymer) −0.266 −0.197 −0.219 −0.193 −0.211 −0.208 −0.203 −0.153
ϕB(1) 0.1049 0.1032 0.1015
ϕB(2) 0.1032 0.1015 0.0999
∆dilh12/(J/g polymer) −0.160 −0.164 −0.153
Polymer (B): poly(ethylene glycol) 1980SCH

T/K = 298.31
wB(1) 0.0897 0.0858 0.0605 0.0579 0.0545 0.0514 0.0402 0.0678 0.0654
wB(2) 0.0859 0.0829 0.0585 0.0546 0.0515 0.0487 0.0390 0.0655 0.0611
∆dilh12/J −0.935 −0.847 −0.352 −0.525 −0.430 −0.446 −0.156 −0.541 −0.973
wB(1) 0.2145 0.2085 0.2027 0.1973 0.1799 0.1756 0.1478 0.1383 0.1273
wB(2) 0.2086 0.2028 0.1974 0.1925 0.1758 0.1716 0.1429 0.1326 0.1192
∆dilh12/J −3.028 −2.977 −2.870 −2.703 −2.244 −2.169 −2.255 −2.701 −3.700
wB(1) 0.0775 0.0699 0.0541 0.0503 0.0699 0.0466 0.0775 0.0637 0.0637
wB(2) 0.0699 0.0637 0.0503 0.0467 0.0637 0.0431 0.0699 0.0585 0.0585
∆dilh12/J −1.150 −0.959 −0.605 −0.493 −0.955 −0.477 −1.190 −0.819 −0.850
T/K = 304.80
wB(1) 0.1915 0.1739 0.1695 0.1612 0.1574 0.1391 0.1362 0.1334 0.1308
wB(2) 0.1889 0.1696 0.1653 0.1574 0.1484 0.1362 0.1334 0.1308 0.1271
∆dilh12/J −1.011 −1.327 −1.653 −1.468 −3.814 −1.239 −1.060 −1.091 −1.652
wB(1) 0.1271 0.1180 0.1139 0.1035 0.0936 0.0867 0.0670
wB(2) 0.1247 0.1160 0.1121 0.0966 0.0867 0.0809 0.0627
∆dilh12/J −1.009 −0.803 −0.834 −1.246 −1.265 −1.127 −0.741
T/K = 330.48
wB(1) 0.1014 0.0555 0.0514 0.2276 0.2249 0.2223 0.1951 0.1506 0.1486
wB(2) 0.0981 0.0514 0.0478 0.2251 0.2224 0.2199 0.1933 0.1484 0.1461
∆dilh12/J −1.148 −0.448 −0.395 −2.011 −1.986 −1.938 −1.457 −1.530 −1.564
Comments: ∆dilh12 is here an extensive quantity obtained for a given total mass change of 1 g. wB(1) and
wB(2) denote the mass fractions of the polymer in the solution before and after the dilution
process.
_____________________________________________________________________________

T/K = 300.05
wB 0.01965 0.03855 0.1075 0.1669 0.2384 0.2929 0.3854 0.4142
∆MH/J.mol−1 1.63 5.40 28.24 60.0 130.2 204.3 325.0 518.0

T/K = 353.45
wB 0.102 0.303 0.517 0.719 0.780 0.847 0.904
∆MH/J.g−1 −9.71 −27.57 −34.06 −24.77 −19.50 −12.01 −5.56
Comments: These data include the enthalpy change caused by melting the crystalline parts of the
polymer when mixing the polymer and the solvent to form the solution.

T/K = 303.15
cB(1)/(g.cm−3) 0.1 0.02
cB(2)/(g.cm−3) 0.005 0.005
dilution process.

T/K = 298.15
V (1)/cm3 30.4 35.5 51.9 20.1 20.1 20.1 20.1 61.9 60.5
ϕB(1) 0.177 0.152 0.244 0.270 0.270 0.270 0.270 0.205 0.060
V (2)/cm3 35.5 40.5 61.9 30.3 35.4 40.5 45.6 71.9 70.5
ϕB(2) 0.152 0.133 0.205 0.177 0.152 0.133 0.166 0.174 0.051
∆dilh12/J −4.703 −3.757 −20.10 −18.95 −23.66 −27.41 −30.13 −12.54 −1.079
_____________________________________________________________________________

T/K = 321.35
wB 0.00333 0.0108 0.0229 0.0504 0.0768 0.112 0.123 0.221
∆MH/J.mol−1 4.52 12.1 21.8 94.1 64.9 109 84.9 169
wB 0.296 0.360 0.412 0.458
∆MH/J.mol−1 257 481 690 921

∞
T/K = 303.15 ∆solHB = 28 J/(g polymer)

T/K = 303.15
cB(1)/(g.cm−3) 0.1 0.01 0.02 0.03 0.101 0.200 0.302 0.404
(2) −3
cB /(g.cm ) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005
∆dilh12/(J/g polymer) −4.6 −0.40 −0.60 −0.94 −4.55 −10.0 −17.7 −23.1
dilution process.

T/K = 298.15
mA'/g 26.99 39.61 36.37 28.01 25.59 24.34 39.70 32.97 32.81
mB'/g 1.438 0.0 4.040 0.0 2.843 4.297 0.0 8.241 8.202
mA"/g 20.35 7.743 8.319 18.39 19.74 20.21 6.963 8.477 8.690
mB"/g 0.0 0.861 0.0 2.043 0.0 0.0 1.741 0.0 0.0
∆dilh12/J −1.1 −2.6 −3.8 −5.3 −5.9 −16.1 −17.1 −21.4 −22.0
continued
_____________________________________________________________________________
continued
mA'/g 23.36 28.09 23.81 22.98 39.67 21.92 29.45 29.02 20.46
mB'/g 5.436 0.0 5.970 6.269 0.0 7.274 12.62 12.43 8.312
mA"/g 20.29 16.78 19.83 20.36 6.186 20.02 8.323 8.693 20.05
mB"/g 0.0 4.195 0.0 0.0 2.652 0.0 0.0 0.0 0.0
∆dilh12/J −29.2 −32.4 −33.5 −41.1 −50.5 −60.2 −63.8 −67.3 −88.6
mA'/g 25.42 27.96 20.94 20.49 39.78 25.96 25.56 19.67 18.30
mB'/g 16.95 0.0 8.988 8.794 0.0 17.30 17.04 10.63 12.00
mA"/g 3.755 14.96 19.84 20.26 5.376 8.388 8.405 20.20 19.91
mB"/g 5.633 6.411 0.0 0.0 3.586 0.0 0.0 0.0 0.0
∆dilh12/J −92.8 −95.5 −100 −100 −112 −151 −154 −156 −205
mA'/g 28.00 39.60 39.66 18.50 18.20 16.52 21.74 21.94 17.13
mB'/g 0.0 0.0 0.0 12.22 12.13 28.12 21.73 21.93 13.94
mA"/g 13.07 4.666 4.610 20.54 20.09 6.569 8.292 9.597 20.18
mB"/g 8.708 4.663 4.607 0.0 0.0 2.814 0.0 0.0 0.0
∆dilh12/J −217 −219 −222 −229 −231 −268 −309 −316 −323
mA'/g 16.63 39.65 19.98 28.26 15.41 15.28 15.64 14.55 27.80
mB'/g 13.67 0.0 24.42 0.0 15.37 15.11 15.64 16.00 0.0
mA"/g 20.56 3.700 8.377 11.00 19.58 20.15 19.63 20.08 10.16
mB"/g 0.0 5.554 0.0 10.98 0.0 0.0 0.0 0.0 12.24
∆dilh12/J −328 −384 −423 −425 −441 −446 −456 −521 −557
mA'/g 17.45 14.21 13.90 16.28 28.99 28.17 12.56 28.07 11.68
mB'/g 26.17 17.18 16.98 27.72 0.0 0.0 18.83 0.0 19.88
mA"/g 8.550 19.99 19.99 8.498 8.954 9.033 19.95 8.362 20.11
mB"/g 0.0 0.0 0.0 0.0 13.42 13.56 0.0 14.24 0.0
∆dilh12/J −570 −606 −620 −683 −746 −766 −839 −899 −988
mA'/g 26.93 39.60 36.08 25.17 24.28 39.96 32.91 32.82 23.55
mB'/g 1.435 0.0 4.008 2.797 4.286 0.0 8.226 8.205 5.480
mA"/g 20.05 7.785 8.642 20.45 20.06 6.888 8.419 8.507 19.96
mB"/g 0.0 0.865 0.0 0.0 0.0 1.722 0.0 0.0 0.0
∆dilh12/J −1.4 −3.1 −3.8 −5.9 −16.0 −16.9 −21.1 −21.7 −28.7
mA'/g 28.19 23.71 22.58 39.80 22.38 29.42 29.22 20.63 25.44
mB'/g 0.0 5.946 6.159 0.0 7.426 12.60 12.53 8.379 16.96
mA"/g 16.67 19.99 20.27 6.069 19.98 8.216 8.537 20.06 3.738
mB"/g 4.167 0.0 0.0 2.602 0.0 0.0 0.0 0.0 5.608
∆dilh12/J −31.9 −33.4 −40.0 −49.3 −59.8 −63.8 −65.3 −88.0 −90.3
mA'/g 28.14 20.48 20.84 39.77 26.00 25.53 19.57 18.00 28.22
mB'/g 0.0 .903 8.947 0.0 17.33 17.02 10.57 11.80 0.0
mA"/g 14.77 19.94 19.98 5.362 8.491 8.481 20.57 19.84 13.10
mB"/g 6.332 0.0 0.0 3.576 0.0 0.0 0.0 0.0 8.729
∆dilh12/J −94.6 −97.4 −100 −109 −151 −153 −155 −203 −217
mA'/g 24.12 18.22 23.95 18.15 16.60 22.05 21.65 16.55 17.13
mB'/g 19.74 12.03 19.59 12.10 28.26 22.04 21.64 13.61 13.94
mA"/g 8.716 19.89 8.687 20.05 6.543 8.359 8.312 19.97 20.03
mB"/g 0.0 0.0 0.0 0.0 2.803 0.0 0.0 0.0 0.0
∆dilh12/J −219 −221 −223 −231 −265 −308 −311 −322 −327
continued
_____________________________________________________________________________
continued
mA'/g 39.71 28.17 19.97 39.74 40.01 15.57 15.58 14.55 27.97
mB'/g 0.0 0.0 24.44 0.0 0.0 15.56 15.59 16.00 0.0
mA"/g 3.754 10.80 8.561 3.462 3.407 19.88 20.03 20.08 10.02
mB"/g 5.634 10.79 0.0 5.898 5.805 0.0 0.0 0.0 12.07
∆dilh12/J −382 −414 −425 −440 −443 −454 −458 −525 −560
mA'/g 17.44 14.14 16.34 12.96 28.20 21.60 28.19 11.56
mB'/g 26.16 17.10 27.82 17.90 0.0 18.89 0.0 19.68
mA"/g 8.506 19.97 8.366 20.07 8.845 19.93 8.230 20.13
mB"/g 0.0 0.0 0.0 0.0 13.28 0.0 14.02 0.0
∆dilh12/J −576 −611 −637 −727 −746 −831 −881 −975
T/K = 333.15
mA'/g 25.00 38.80 19.01 39.22 39.06 12.80 39.22 39.11 8.812
mB'/g 16.66 0.0 23.23 0.0 0.0 29.84 0.0 0.0 35.19
mA"/g 8.200 3.995 6.762 3.804 1.848 8.202 1.834 0.882 8.284
mB"/g 0.0 4.876 0.0 5.682 7.447 0.0 7.389 7.938 0.0
∆dilh12/J −120 −236 −288 −324 −693 −708 −727 −945 −963
mA'/g 8.630 2.128 25.01 39.03 39.07 18.87 39.40 12.84 38.72
mB'/g 34.47 40.44 16.67 0.0 0.0 23.06 0.0 29.92 0.0
mA"/g 8.268 8.443 8.325 4.037 3.778 8.314 1.814 8.510 0.907
mB"/g 0.0 0.0 0.0 4.928 5.643 0.0 7.237 0.0 8.163
∆dilh12/J −980 −1130 −120 −240 −319 −339 −701 −718 −934
mA'/g 39.14 38.74 2.151
mB'/g 0.0 0.0 40.87
mA"/g 0.916 0.918 8.462
mB"/g 8.231 8.248 0.0
∆dilh12/J −948 −968 −1045

T/K = 353.45
wB 0.206 0.336 0.480 0.548 0.675 0.755 0.825 0.887 0.953
∆MH/J.g−1 −20.04 −29.41 −34.31 −33.10 −25.86 −20.46 13.60 −5.82 −1.26

T/K = 303.15
continued
_____________________________________________________________________________
continued
cB(1)/(g.cm−3) 0.1 0.02
cB(2)/(g.cm−3) 0.005 0.005
dilution process.
Polymer (B): poly(ethylene glycol) 1970NAK

Characterization: Mη/g.mol−1 = 14000, Wako Pure Chemicals Company, Japan
T/K = 303.15 ∆solHB∞ = 293 J/(mol polymer)
T/K = 313.15 ∆solHB∞ = 1213 J/(mol polymer)
Comments: Experimental data for mixtures of water and low-molecular glycols can be found in the
original source.

T/K = 298.15
V (1)/cm3 25.6 35.6 45.6 55.6 15.6 15.6 25.3 10.0 10.0
ϕB(1) 0.211 0.152 0.119 0.096 0.346 0.346 0.190 0.301 0.325
V (2)/cm3 35.6 45.6 55.6 65.6 35.6 45.6 35.3 25.0 25.0
ϕB(2) 0.152 0.119 0.096 0.081 0.152 0.119 0.136 0.120 0.130
∆dilh12/J −4.368 −2.954 −1.397 −1.058 −19.29 −22.25 −4.222 −8.309 −10.05

T/K = 303.15
cB(1)/(g.cm−3) 0.1 0.02
cB(2)/(g.cm−3) 0.005 0.005
dilution process.
_____________________________________________________________________________

T/K = 298.31
ϕB(1) 0.0661 0.0579 0.0507 0.0457 0.0411
ϕB(2) 0.0623 0.0507 0.0457 0.0411 0.0373
12
∆dilh /(J/g polymer) −0.133 −0.246 −0.219 −0.183 −0.016

T/K = 303.15
cB(1)/(g.cm−3) 0.1 0.02
cB(2)/(g.cm−3) 0.005 0.005
dilution process.

−1
Characterization: Mn/g.mol = 39005, Hoechst AG, Frankfurt, Germany
T/K = 298.15
mA'/g 26.70 39.68 36.38 28.31 26.21 39.71 92.91 28.02 23.00
mB'/g 1.471 0.0 4.042 0.0 2.975 0.0 8.227 0.0 5.835
mA"/g 20.00 7.799 8.732 18.43 20.06 6.892 8.405 16.78 20.29
mB"/g 0.0 0.867 0.0 2.048 0.0 1.721 0.0 4.200 0.0
∆dilh12/J −0.7 −2.3 −3.4 −5.3 −5.9 −16.5 −20.9 −31.9 −33.7
mA'/g 39.92 21.85 29.40 29.29 28.21 20.53 39.67 19.23 25.43
mB'/g 0.0 6.971 12.60 12.55 0.0 8.601 0.0 10.17 16.95
mA"/g 6.186 20.09 8.285 4.550 14.94 20.55 5.395 20.16 8.436
mB"/g 2.652 0.0 0.0 5.130 6.397 0.0 3.597 0.0 0.0
∆dilh12/J −48.6 −59.3 −62.5 −92.5 −94.0 −94.6 −109 −146 −150
mA'/g 25.64 18.44 27.97 39.46 39.68 44.35 16.70 21.94 16.84
mB'/g 17.09 11.04 0.0 0.0 0.0 0.0 13.33 21.94 14.33
mA"/g 8.619 20.68 13.04 4.725 4.342 4.384 20.22 8.198 20.20
mB"/g 0.0 0.0 8.683 4.729 4.894 4.943 0.0 0.0 0.0
∆dilh12/J −155 −185 −215 −220 −256 −274 −303 −305 −336
continued
_____________________________________________________________________________
continued
mA'/g 20.58 16.60 26.72 39.77 36.38 28.13 25.60 39.74 32.67
mB'/g 23.21 15.19 1.473 0.0 4.043 0.0 2.907 0.0 8.166
mA"/g 8.634 19.85 20.22 7.693 8.390 18.49 19.89 6.894 8.525
mB"/g 0.0 0.0 0.0 0.855 0.0 2.054 0.0 1.721 0.0
∆dilh12/J −380. −399. −1.1 −2.8 −3.9 −5.7 −6.3 −16.6 −21.1
mA'/g 28.17 23.06 39.66 22.24 29.16 27.99 20.51 29.36 39.38
mB'/g 0.0 5.851 0.0 7.094 12.50 0.0 8.594 12.58 0.0
mA"/g 16.68 20.04 6.262 20.78 8.570 14.84 20.47 4.369 5.617
mB"/g 4.174 0.0 2.684 0.0 0.0 6.356 0.0 4.927 3.746
∆dilh12/J −32.0 −34.3 −49.3 −60.5 −64.2 −93.4 −94.1 −96.5 −114
mA'/g 19.18 28.21 18.36 28.19 39.65 44.52 39.64 16.92 21.75
mB'/g 10.15 0.0 10.99 0.0 0.0 0.0 0.0 13.29 21.74
mA"/g 20.20 10.97 21.07 12.96 4.645 4.485 4.341 20.48 8.240
mB"/g 0.0 10.97 0.0 8.636 4.649 5.057 5.893 0.0 0.0
∆dilh12/J −146 −411 −184 −210 −217 −253 −260 −300 −303
mA'/g 16.74 20.48 15.98
mB'/g 13.97 23.09 14.62
mA"/g 19.99 8.324 20.14
mB"/g 0.0 0.0 0.0
∆dilh12/J −334 −379 −390
T/K = 333.15
mA'/g 18.90 18.67 38.84 39.28 38.45 12.10 12.81 8.554 18.56
mB'/g 23.09 22.82 0.0 0.0 0.0 28.22 29.88 34.22 22.67
mA"/g 8.688 8.177 2.165 3.089 1.436 8.990 8.268 8.382 8.748
mB"/g 0.0 0.0 5.050 7.159 5.744 0.0 0.0 0.0 0.0
∆dilh12/J −352 −363 −426 −535 −609 −656 −699 −1064 −359
mA'/g 39.03 39.06 39.40 38.99 38.43 8.239
mB'/g 0.0 0.0 0.0 0.0 0.0 32.96
mA"/g 2.412 2.326 1.604 1.576 1.629 8.699
mB"/g 5.627 5.391 6.406 6.305 6.507 0.0
∆dilh12/J −402 −428 −562 −614 −670 −852

∞
T/K = 303.15 ∆solHB = 40 J/(g polymer)
(1) −3
cB /(g.cm ) 0.10 0.010 0.030 0.051 0.101 0.198 0.300 0.416
cB(2)/(g.cm−3) 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005
∆dilh12/(J/g polymer) −3.9 −0.22 −0.90 −1.7 −3.9 −10.0 −18.1 −21.4
dilution process.
_____________________________________________________________________________

T/K = 298.15
V (1)/cm3 15.0 45.0 50.0 70.0 30.0 20.0 30.0 20.0 10.0
ϕB(1) 0.127 0.172 0.154 0.110 0.156 0.186 0.154 0.186 0.101
V (2)/cm3 25.0 50.0 60.0 80.0 50.0 30.0 70.0 50.0 30.0
ϕB(2) 0.076 0.154 0.130 0.097 0.093 0.124 0.066 0.074 0.050
∆dilh12/J −0.397 −0.891 −1.515 −0.661 −2.477 −1.874 −3.322 −3.138 −0.791

T/K = 298.15
V (1)/cm3 30.5 40.5 50.0 60.0 50.1 55.1 60.1 65.1 30.3
ϕB(1) 0.085 0.064 0.051 0.043 0.065 0.059 0.054 0.050 0.070
V (2)/cm3 40.5 50.5 60.5 70.5 55.1 60.1 65.1 70.1 40.3
ϕB(2) 0.064 0.051 0.043 0.037 0.059 0.054 0.050 0.046 0.055
∆dilh12/J −0.372 −0.213 −0.134 −0.096 −0.134 −0.100 −0.092 −0.079 −0.264
V (1)/cm3 40.3 50.3 30.5 30.5 30.5 50.1 50.1 50.1 30.3
ϕB(1) 0.053 0.040 0.085 0.085 0.085 0.065 0.065 0.065 0.070
V (2)/cm3 50.3 60.3 50.5 60.5 70.5 60.1 65.1 70.1 50.3
ϕB(2) 0.040 0.033 0.051 0.043 0.037 0.054 0.050 0.046 0.040
∆dilh12/J −0.130 −0.084 −0.590 −0.724 −0.820 −0.230 −0.322 −0.289 −0.393
Polymer (B): poly(ethylene glycol) monododecyl ether 1980KUR

T/K 303.15 308.15 313.15 318.15 323.15 328.15 333.15 338.15
ϕB 0.0522 0.0521 0.0519 0.0517 0.0513 0.0509 0.0503 0.0495
∆MH/(J/mol polym.) −74.94 −73.97 −72.26 −68.49 −63.14 −58.58 −53.51 −51.46
T/K 343.15 348.15 353.15
ϕB 0.0484 0.0476 0.0469
∆MH/(J/mol polym.) −48.28 −47.66 −46.15
_____________________________________________________________________________
Polymer (B): poly(ethylene oxide) 1975IKE

T/K = 293.15 ∆MHB∞ = 403.1 J/(base mol polymer) quenched sample
T/K = 293.15 ∆MHB∞ = 392.2 J/(base mol polymer) annealed sample
Polymer (B): poly(ethylene oxide) 1972MAR

T/K = 303.15
ϕB(1) 0.0179 0.0346 0.0474 0.0474 0.0474 0.0619 0.0995 0.1133
ϕB(2) 0.0149 0.0289 0.0090 0.0406 0.0068 0.0530 0.0911 0.0283
∆dilh12/(J/g polymer) −2.075 −2.284 −48.11 −1.833 −74.48 −1.862 −0.753 −35.77
T/K = 303.15 ∆MHB∞ = −50.6 J/(g polymer)
Comments: ∆MHB∞ is the value corrected for enthalpic contributions arising from destructing glassy and
crystalline portions of the polymer.

∞
T/K = 293.15 ∆MHB = 28.0 J/(base mol polymer) quenched sample

_____________________________________________________________________________
Polymer (B): poly(N-isopropylacrylamide) 1968HES

Characterization: intrinsic viscosity = 2.6 dl/g in trichloromethane at 298 K
T/K = 293.15 ∆solHB∞ = 0.213 J/(g solution)
Comments: The final concentration is 0.03 %.
Polymer (B): poly(propylene glycol) 1968LA2

T/K = 300.05
wB 0.01483 0.03418 0.04643 0.08906 0.1425 0.2211 0.4113 0.7867
∆MH/J.mol−1 −34.6 −95.8 −129 −242 −395 −615 −1152 −242
Polymer (B): poly(propylene glycol) 1988PAR

∞
T/K = 321.35 ∆MHB = −13.7 J/(mol polymer)
wB 0.003250 0.01104 0.02217 0.05288 0.08175 0.1543 0.2663 0.3511
∆MH/J.mol−1 −5.424 −24.12 −61.04 −132.5 −197.1 −377.0 −631.8 −820.5
wB 0.4784 0.5503 0.6373 0.7558 0.8890 0.9755
∆MH/J.mol−1 −1020 −1112 −1205 −1242 −998.7 −0.500
Polymer (B): poly(propylene glycol) 1961CUN

T/K = 300.05
wB 0.109 0.198 0.314 0.393 0.477 0.609 0.701 0.791 0.908
∆MH/J.g−1 −16.32 −26.48 −34.31 −36.94 −37.66 −33.89 −28.74 −22.01 −11.13
Polymer (B): poly(propylene glycol) 1995CAR

T/K = 298.15 ∆MHB∞ = −163.9 J/(g polymer)
wB 0.02496 0.05003 0.1701 0.2494 0.3801 0.5899 0.7486 0.8949 0.9997
∆MH/J.g−1 −4.12 −8.03 −24.5 −32.6 −38.7 −34.9 −25.8 −12.6 −0.041
∆MHA/J.g−1 −0.094 −0.365 −5.19 −12.30 −32.08 −60.6 −83.4 −103.6 −136.4
continued
_____________________________________________________________________________
continued
T/K = 321.15
wB 0.1699 0.3791 0.5881 0.7494
∆MH/J.g−1 −18.9 −26.5 −26.0 −20.2

T/K = 300.05
wB 0.00885 0.03336 0.06077 0.1070 0.1352 0.1499 0.2623 0.7372
∆MH/J mol−1 −27.8 −92.9 −172 −297 −351 −415 −692 −1557
Polymer (B): poly(propylene glycol) 1988PAR

T/K = 321.35
wB 0.005353 0.01405 0.02872 0.06428 0.1060 0.1369 0.1832 0.2885
∆MH/J.mol−1 −9.082 −27.74 −57.74 −150.2 −248.1 −313.4 −430.1 −599.2
wB 0.3715 0.4399 0.4963 0.5784 0.7016 0.8879 0.9700
∆MH/J.mol−1 −709.6 −794.5 −950.6 −1084 −1296 −1217 −755.6
T/K = 321.35 ∆MHB∞ = −19.9 J/(mol polymer)

T/K = 300.05
wB 0.04045 0.08389 0.1162 0.1399 0.1868 0.2719 0.3613 0.6545
∆MH/J.mol−1 −5.31 −8.79 −6.44 −7.49 −10.2 −7.20 −4.90 +14.3
Comments: These data include the enthalpy change caused by melting the crystalline parts of the
polymer when mixing the polymer and the solvent to form the solution.
Polymer (B): poly(styrenesulfonic acid) 1995PER

T/K = 298.15
cB(1)/(base mol/l) = 0.12 cB(2)/(base mol/l) = 0.02 ∆dilh12/(J/base mol polymer) = −369
dilution process.
_____________________________________________________________________________
Polymer (B): poly(styrenesulfonic acid) 1967SK1

Characterization: Mη/g.mol−1 = 200000, degree of sulfonation = 1.0
T/K = 298.15
cB(1)/(base mol/kg water) 0.381 0.181 0.127 0.0876 0.0611 0.0424 0.0297
∆dilh12/(J/base mol polymer) −214.6 −182.0 −179.1 −172.0 −168.2 −164.8 −162.3
∆dilh12/(J/base mol polymer) −1757 −1544 −1456 −1364 −1276 −1188 −1109
dilution process.
Polymer (B): poly(styrenesulfonic acid) calcium salt 1973SKE

Characterization: Mw/g.mol−1 = 100000, degree of sulfonation = 1.0
T/K = 298.15
∆dilh12/(J/base mol polymer) +11.7 −11.3 −17.2 −18.0 −20.1 −22.6 −28.0
dilution process.
Polymer (B): poly(styrenesulfonic acid) cesium salt 1970SKE

T/K = 298.15
dilution process.
_____________________________________________________________________________
Polymer (B): poly(styrenesulfonic acid) cupric salt 1995PER

T/K 298.15 308.15 318.15
cB(1)/(base mol/l) 0.12 0.12 0.12
cB(2)/(base mol/l) 0.02 0.02 0.02
∆dilh12/(J/base mol polymer) −106 −113 −124
Polymer (B): poly(styrenesulfonic acid) lead salt 1995PER

T/K = 298.15
cB(1)/(base mol/l) = 0.08 cB(2)/(base mol/l) = 0.02 ∆dilh12/(J/base mol polymer) = 164
dilution process.
Polymer (B): poly(styrenesulfonic acid) lithium salt 1970SKE

T/K = 298.15
∆dilh12/(J/base mol polymer) −193.3 −160.7 −139.3 −123.0 −144.8 −136.4 143.9
∆dilh12/(J/base mol polymer) −113.4 −119.2 −1276 −1079 −920.5 −782.4 −656.9
cB(1)/(base mol/kg water) 0.00951 0.00467 0.00231 0.00112
∆dilh12/(J/base mol polymer) −514.6 −376.6 −234.3 −121.3
dilution process.
Polymer (B): poly(styrenesulfonic acid) magnesium salt 1973SKE

T/K = 298.15
continued
_____________________________________________________________________________
continued
dilution process.
Polymer (B): poly(styrenesulfonic acid) potassium salt 1970SKE

T/K = 298.15
∆dilh12/(J/base mol polymer) −117.2 −108.8 −619.2 −665.3 636.0 −585.8 −527.2
∆dilh12/(J/base mol polymer) −443.5 −334.7 −225.9 −108.8
dilution process.
Polymer (B): poly(styrenesulfonic acid) silver salt 1995PER

T/K = 298.15
cB(1)/(base mol/l) = 0.13 cB(2)/(base mol/l) = 0.02 ∆dilh12/(J/base mol polymer) = −374
Polymer (B): poly(styrenesulfonic acid) sodium salt 1967SK1

T/K = 298.15
∆dilh12/(J/base mol polymer) −124.3 −144.3 −167.4 −138.1 −121.3 −970.6 −1004
continued
_____________________________________________________________________________
continued
dilution process.
Polymer (B): poly(styrenesulfonic acid) strontium salt 1973SKE

T/K = 298.15
∆dilh12/(J/base mol polymer) +41.8 +10.0 −3.85 −8.8 −8.8 −10.0 −10.9
dilution process.
Polymer (B): poly(vinyl alcohol) 1955OYA

Polymer (B): poly(vinyl alcohol) 1958TAG

∞
Polymer (B): poly(vinyl alcohol) 1956AMA1

Characterization: Mn/g.mol−1 = 26400, < 0.3 mol% vinyl acetate
T/K = 303.15
V (1)/cm3 15.0 20.0 25.0 30.0 20.0 20.0 25.0 30.0 40.0
ϕB(1) 0.0997 0.0740 0.0589 0.0489 0.1429 0.0933 0.0740 0.0613 0.0453
V (2)/cm3 20.0 25.0 30.0 35.0 25.0 25.0 30.0 35.0 40.0
ϕB(2) 0.0740 0.0589 0.0489 0.0418 0.1129 0.0740 0.0614 0.0453 0.0365
∆dilh12/J −0.469 −0.310 −0.192 −0.042 −0.803 −0.289 −0.209 −0.264 −0.184
continued
_____________________________________________________________________________
continued
T/K = 343.15
V (1)/cm3 15.0 20.0 25.0 30.0
ϕB(1) 0.100 0.075 0.059 0.049
V (2)/cm3 20.0 25.0 30.0 35.0
ϕB(2) 0.075 0.059 0.049 0.042
∆dilh12/J −0.469 −0.310 −0.192 −0.042
T/K = 373.15
V (1)/cm3 20.0 25.0 20.0 25.0 30.0 40.0 25.0 30.0 35.0
ϕB(1) 0.143 0.114 0.094 0.075 0.062 0.046 0.114 0.094 0.081
V (2)/cm3 25.0 30.0 25.0 30.0 40.0 50.0 30.0 35.0 40.0
ϕB(2) 0.114 0.094 0.075 0.062 0.046 0.037 0.094 0.081 0.071
∆dilh12/J −0.192 −0.119 −0.069 −0.050 −0.063 −0.044 −0.120 −0.090 −0.078
Polymer (B): poly(vinyl alcohol) 1955OYA

∞
Comments: The final concentration is < 2 g polymer/200 cm3 solvent.
Polymer (B): poly(vinyl alcohol) 1952TAG

Comments: The final concentration is about 1%.
Polymer (B): poly(vinylbenzyltrimethylammonium) bromide 1995PER

T/K 298.15 308.15 318.15
cB(1)/(base mol/l) 0.17 0.17 0.17
cB(2)/(base mol/l) 0.02 0.02 0.02
∆dilh12/(J/base mol polymer) 950 640 470
dilution process.
_____________________________________________________________________________
Polymer (B): poly(vinylbenzyltrimethylammonium) chloride 1995PER

T/K 298.15 308.15 318.15
cB(1)/(base mol/l) 0.18 0.18 0.18
cB(2)/(base mol/l) 0.02 0.02 0.02
dilution process.
Polymer (B): poly(vinylbenzyltrimethylammonium) hydroxide 1995PER

T/K 298.15 308.15 318.15
cB(1)/(base mol/l) 0.19 0.19 0.19
cB(2)/(base mol/l) 0.02 0.02 0.02
dilution process.
Polymer (B): poly(vinylbenzyltrimethylammonium) iodide 1995PER

T/K 298.15 308.15 318.15
cB(1)/(base mol/l) 0.12 0.12 0.12
cB(2)/(base mol/l) 0.02 0.02 0.02
dilution process.
Polymer (B): −vinyl-N−

poly(1− −butylpyridinium bromide) 1954SCH
T/K = 298.15 cB(2)/(base mol/l) = 0.00000246 for all measurements
cB(1)/(base mol/l) 0.00488 0.02500 0.04928 0.19796 1.07912 2.00435 4.07555
∆dilh12/(J/base mol polymer) −1485 −3749 −5268 −5933 −6749 −6293 −6180
dilution process.
_____________________________________________________________________________
Polymer (B): −vinyl−

poly(1− −3,5−
−dimethyl−
−1,2,4−
−triazole) 1991TA1
T/K = 298.15 ∆MHB∞ = −139 J/(g polymer)
Polymer (B): −vinylimidazole)

poly(1− 1988TAG, 1989SAF, 1991TA1
∞
T/K = 298.15 ∆MHB = −119 J/(g polymer) = −11200 J/base mol polymer
T/K = 298.15 ∆MHA∞ = −13500 J/mol solvent

poly(1− −2−
−pyrrolidinone) 1968GOL
−1
Characterization: Mη/g.mol = 32000
T/K = 298.15 ∆solHB∞ = −149.6 J/(g polymer) = −16610 J/base mol polymer

poly(1− −1,2,4−
−triazole) 1988TAG, 1989SAF, 1991TA1
∞
T/K = 298.15 ∆solHB = −68.9 J/(g polymer) = −6550 J/base mol polymer
T/K = 298.15 ∆MHA∞ = −14300 J/mol solvent
Polymer (B): tetra(ethylene glycol) 1987BIR

T/K = 298.15
wA 0.0146 0.0348 0.0542 0.0728 0.0994 0.1482 0.1962 0.2403 0.2764
∆MH/J.g−1 −3.982 −9.298 −13.74 −17.69 −22.80 −30.72 −37.21 −42.44 −45.60
wA 0.3084 0.3467 0.3849 0.4185 0.4418 0.4466 0.4683 0.5000 0.5343
∆MH/J.g−1 −48.00 −50.00 −51.87 −52.72 −53.19 −53.01 −53.09 −52.63 −51.68
wA 0.5737 0.6195 0.6705 0.7250 0.7800 0.8429 0.8912 0.9313 0.9758
−1
∆MH/J.g −49.91 −47.10 −43.14 −37.91 −31.84 −23.70 −16.79 −10.65 −3.842
Comments: Experimental data for mixtures of water and 1,2-ethanediol, di(ethylene glycol) and
tri(ethylene glycol) can be found in the original source.
_____________________________________________________________________________
Polymer (B): tetra(ethylene glycol) 1998OHT

T/K = 283.15 ∆MHB∞ = −32.70 ± 0.033 kJ/mol
T/K = 288.15 ∆MHB∞ = −32.10 ± 0.028 kJ/mol
T/K = 293.15 ∆MHB∞ = −31.33 ± 0.014 kJ/mol
T/K = 298.15 ∆MHB∞ = −30.47 ± 0.016 kJ/mol
T/K = 303.15 ∆MHB∞ = −29.51 ± 0.040 kJ/mol
T/K = 308.15 ∆MHB∞ = −28.80 ± 0.029 kJ/mol
T/K = 313.15 ∆MHB∞ = −27.73 ± 0.034 kJ/mol
Polymer (B): tetra(ethylene glycol) diethyl ether 1972NAK

T/K = 298.15
xA 0.0106 0.0346 0.0662 0.0973 0.1456 0.1962 0.2964 0.3708
∆MH/J.mol−1 −531.4 −1323 −1708 −1813 −1772 −1662 −1236 −941.4
xA 0.4383 0.4829 0.5168 0.5954 0.6881 0.7880 0.8865
∆MH/J.mol−1 −682.4 −577.0 −463.2 −242.7 −53.1 +48.5 +67.8
Polymer (B): tetra(ethylene glycol) dimethyl ether 1987BIR

T/K = 298.15
wA 0.0125 0.0247 0.0366 0.0383 0.0596 0.0739 0.0919 0.1225 0.1319
−1
∆MH/J.g 0.2490 −0.0430 −0.787 −0.804 −3.142 −4.828 −7.536 −11.89 −13.80
wA 0.1663 0.1684 0.2051 0.2059 0.2421 0.2750 0.3108 0.3424 0.3713
∆MH/J.g−1 −19.10 −19.82 −25.93 −25.82 −31.63 −36.75 −42.16 −46.39 −49.84
wA 0.4014 0.4286 0.4535 0.4764 0.4884 0.4949 0.5128 0.5398 0.5697
−1
∆MH/J.g −53.00 −55.30 −56.97 −58.06 −58.89 −58.57 −59.51 −59.74 −59.38
wA 0.6032 0.6409 0.6836 0.7324 0.7872 0.8369 0.8914 0.9556
∆MH/J.g−1 −58.21 −56.00 −52.47 −47.08 −39.58 −31.56 −21.58 −8.925
Comments: Experimental data for mixtures of water and the dimethyl ethers of 1,2-ethanediol,
di(ethylene glycol) and tri(ethylene glycol) can be found in the original source.
Polymer (B): tetra(ethylene glycol) dimethyl ether 1987CIF

T/K = 298.15 ∆solHB∞ = −42.60 kJ/mol polymer
_____________________________________________________________________________
Polymer (B): tetra(ethylene glycol) monooctyl ether 1989AND

T/K = 283.15
wB 0.0164 0.0943 0.2600 0.5020 0.7820 0.9000 0.9800 0.9900
∆MHA/(J/g solvent) −5.0 −29 −76 −357 −1457 −2340 −3509 −3958
T/K = 298.15
wB 0.0000 0.0216 0.0520 0.1053 0.2600 0.5020 0.7820 0.9000
∆MHA/(J/g solvent) −3.6 −3.6 −3.9 −10 −30 −282 −1362 −2225
wB 0.9700 0.9800 0.9900 1.0000
∆MHA/(J/g solvent) −2950 −3240 −3704 −4179
T/K = 313.15
wB 0.0323 0.0992 0.2600 0.5020 0.7820 0.9000 0.9700 1.0000
∆MHA/(J/g solvent) −2.3. −4 −23 −129 −1106 −1929 −2368 −2885
Polymer (B): vinyl acetate/vinyl alcohol copolymer 1956AMA2

T/K = 343.15
V (1)/cm3 9.00 9.51
ϕB(1) 0.099 0.109
V (2)/cm3 19.00 19.51
ϕB(2) 0.047 0.053
∆dilh12/J −0.607 −0.741
Polymer (B): vinyl acetate/vinyl alcohol copolymer 1956AMA1

T/K = 303.15
V (1)/cm3 15.0 20.0 25.0
ϕB(1) 0.155 0.115 0.092
V (2)/cm3 20.0 25.0 30.0
ϕB(2) 0.115 0.092 0.077
∆dilh12/J −1.305 −1.054 −0.720
_____________________________________________________________________________
Polymer (B): vinyl acetate/vinyl alcohol copolymer 1955OYA

Comments: The final concentration is < 2 g copolymer/200 cm3 solvent.

Comments: The final concentration is < 2 g copolymer/200 cm3 solvent.
Polymer (B): vinyl acetate/vinyl alcohol copolymer 1956AM2

T/K = 343.15
V (1)/cm3 9.57 8.57
ϕB(1) 0.077 0.077
V (2)/cm3 19.57 18.57
ϕB(2) 0.038 0.0355
∆dilh12/J −0.699 −0.632


_____________________________________________________________________________



T/K = 343.15
V (1)/cm3 9.91 9.94
ϕB(1) 0.052 0.052
V (2)/cm3 19.91 19.94
ϕB(2) 0.026 0.026
∆dilh12/J −0.167 −0.172

T/K = 343.15
V (1)/cm3 9.86 9.94
ϕB(1) 0.038 0.038
V (2)/cm3 19.86 19.94
ϕB(2) 0.019 0.019
12
∆dilh /J −0.071 −0.063
_____________________________________________________________________________



∞

∞

∞

_____________________________________________________________________________
5.2. Partial molar enthalpies of mixing at infinite dilution of water

and enthalpies of solution of water vapor in molten polymers
from inverse gas-liquid chromatography (IGC)
Polymer (B): cellulose acetate 1983ASP

Characterization: D.S. = 2.45, Eastman Kodak Company, USA
______________________________________________
Solvent (A) T-range/ ∆MHA∞/
K kJ/mol
______________________________________________
water 333.15-358.15 −9.5
______________________________________________
Polymer (B): cellulose monoacetate 1983ASP

Characterization: D.S. = 0.89, prepared in the laboratory by partial
saponification of cellulose triacetate
______________________________________________
K kJ/mol
______________________________________________
water 333.15-358.15 −16.0
______________________________________________
Polymer (B): cellulose triacetate 1983ASP

Characterization: D.S. = 3.0 , Eastman Kodak Company, USA
______________________________________________
K kJ/mol
______________________________________________
water 333.15-358.15 −5.0
______________________________________________
_____________________________________________________________________________
Polymer (B): ethylcellulose 1983ASP

Characterization: D.S. = 1.4, Dow Ethocel
______________________________________________
K kJ/mol
______________________________________________
water 333.15-358.15 −12.0
______________________________________________
Polymer (B): ethylene/vinyl acetate copolymer 1978DIN

Characterization: Mn/g.mol−1 = 43200, 29.0 wt% vinyl acetate
MI = 15.0, Union Carbide, DX-31034
______________________________________________
Solvent (A) T-range/ ∆solHA(vap)∞/
K kJ/mol
______________________________________________
water 423.61-433.68 −28.00
______________________________________________

______________________________________________
Solvent (A) T/ ∆MHA∞/
K kJ/mol
______________________________________________
water 288.15 −2.6
water 292.85 −3.2
water 298.15 −3.8
water 302.45 −4.3
water 307.35 −4.9
water 313.45 −5.6
water 318.25 −6.1
water 323.05 −6.6
water 327.95 −7.2
water 332.75 −7.7
water 338.05 −8.2
water 342.15 −8.6
water 347.85 −9.2
water 352.65 −9.7
water 357.65 −10.2
______________________________________________
_____________________________________________________________________________
Polymer (B): hydroxypropylcellulose 1982ASP, 1983ASP

______________________________________________
K kJ/mol
______________________________________________
water 288.15-358.15 −5.7
______________________________________________
Polymer (B): methylcellulose 1983ASP

Characterization: D.S. = 1.9, Dow Methocel
______________________________________________
K kJ/mol
______________________________________________
water 333.15-358.15 −18.5
______________________________________________
Polymer (B): polystyrene 1980GUN

Characterization: Mn/g.mol−1 = 20000 ± 5000
PS-K500, Petrokimya A.S., Yarimca, Turkey
______________________________________________
K kJ/mol
______________________________________________
water 435.46-502.58 −18.9
______________________________________________
Polymer (B): poly(vinyl chloride) 1992KAL

−1
Characterization: Mw/g.mol = 100000, Polysciences, Inc., Warrington, PA, USA
______________________________________________
K kJ/mol
______________________________________________
water 298.15-323.15 −43.66
______________________________________________
_____________________________________________________________________________
5.3. Table of systems where additional information on enthalpy

effects in aqueous polymer solutions can be found
_____________________________________________________________________________
Polymer (B) Solvent (A) Enthalpy T-range Ref.
_____________________________________________________________________________
Acrylic acid/methyl acrylate copolymer
water ∆MH 298 K 1993ADA
water ∆MH 298 K 1993TA1
_____________________________________________________________________________
Acrylic acid/methyl methacrylate
copolymer
_____________________________________________________________________________
Acrylonitrile/styrene copolymer
water ∆solHB∞ 298 K 1991ZVE
_____________________________________________________________________________
Acrylonitrile/styrenesulfonate copolymer
_____________________________________________________________________________
Acrylonitrile/vinyl chloride copolymer
_____________________________________________________________________________
Carboxymethylcellulose sodium salt
water ∆dilH12 298-313 K 1974MIT
water ∆solHB∞ 298 K 2000SUV
water ∆solHB∞ 298, 353 K 2002SUV
_____________________________________________________________________________
Cellulose
water ∆MHA 323 K 1940MEY
water ∆MH 298 K 1985IOE
water ∆solHA 298 K 1994KHA
water/NaOH ∆solHB 298 K 1966KAR
_____________________________________________________________________________
Cellulose acetate
water ∆solHA 298 K 1994KHA
_____________________________________________________________________________
Cellulose xanthogenate
water/NaOH ∆dilH12 298 K 1949LAU
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Chitosan
water/acetic acid ∆dilH12 298 K 2002SAF
_____________________________________________________________________________
Cyclopentene/maleic acid copolymer
water ∆dilH12 298 K 1981PAO
_____________________________________________________________________________
Dextran
water ∆dilH12 279-306 K 1978COM
water ∆MH 298 K 1980BAS
_____________________________________________________________________________
Epoxy resin
water ∆solHA 310-333K 1982GAR
_____________________________________________________________________________
Ethylene/maleic acid copolymer
_____________________________________________________________________________
Hemoglobin
water ∆dilH12 298 K 1981FUJ
_____________________________________________________________________________
Hexa(ethylene glycol) monododecyl ether
water ∆MH 298 K 1967CLU
_____________________________________________________________________________
water ∆MHA 298 K 1981ASP
_____________________________________________________________________________
Isobutylene/maleic acid copolymer
_____________________________________________________________________________
N-Isopropylacrylamide/N-octadecyl-
acrylamide copolymer
water ∆dilH12 303 K 1996FAE
_____________________________________________________________________________
Methylcellulose
water ∆solHB 298 K 1997RAS
water ∆solHB 298 K 2000SUV
water/NaOH ∆solHB 298 K 1959TSU
_____________________________________________________________________________
4-Methyl-1-pentene/maleic acid
copolymer
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
N-Methacryloyl-L-alanine/N-phenyl-
methacrylamide copolymer
water ∆dilH12 298 K 1982MOR
_____________________________________________________________________________
Octa(ethylene glycol) monododecyl ether
_____________________________________________________________________________
water ∆MH, ∆MHB 283-313K 2001OHT
_____________________________________________________________________________
Poly(acrylamide)
water ∆MHA∞ 305-315 K 1957SIL
water ∆solHB, 303 K 1970GRO
water ∆solHB, ∆dilH12 298 K 1978SCH
water ∆dilH12 298 K 1981DAY
_____________________________________________________________________________
Poly(2-acrylamido-2-methyl-
propanesulfonic acid)
water ∆dilH12 298 K 1993KEL
_____________________________________________________________________________
Poly(acrylic acid)
water ∆dilH12 298 K 1972CRE
water ∆dilH12 298 K 1974SKE
water ∆solHB, ∆dilH12 298 K 1978SCH
water ∆solHB 298 K 1979KLE
water ∆MH 298 K 1983TAG
water ∆dilH12 273-313 K 1986SKE
water ∆dilH12 298 K 1990DAO
water ∆dilH12 298 K 1993SAF
water ∆MH 290-313 K 1996SAF
_____________________________________________________________________________
Poly(acrylic acid) salts
water ∆dilH12 298 K 1973ISE
water ∆dilH12 298-313 K 1974MIT
water ∆dilH12 273-313 K 1986SKE
_____________________________________________________________________________
Poly(acrylonitrile)
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Poly(N,N-dimethylacrylamide)
_____________________________________________________________________________
Poly(ethacrylic acid) salts
_____________________________________________________________________________
water ∆MHA∞ 324 K 1965SAT
water ∆MHA 298-308 K 1968LA1
water ∆MH 328 K 1976LAK
water ∆MH 298 K 1981MED
water ∆MH, ∆solHB 278-317 K 1989AND
water ∆dilH12 298 K 1993AUC
water ∆dilH12 298 K 1994AUC
water ∆MHA 278-308 K 1994NAG
water ∆solHB 298 K 1995GRO
water ∆solHB 298 K 2002SP1
_____________________________________________________________________________
Poly(ethylene glycol) didodecyl ether
water ∆dilH12 293 K 1994PER
_____________________________________________________________________________
Poly(ethylene imine) hydrochloride
water ∆dilH12 298 K 1975MIT
_____________________________________________________________________________
Poly(ethylene oxide)
water ∆MH, ∆dilH12 298 K 1984DAO
water ∆MH 263 K 1987BOG
water ∆MH 264 K 1991HEY
water ∆dilH12 288-293 K 1993EAG
water ∆MH, ∆dilH12 298 K 1999SAF
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene
oxide)-b-poly(ethylene oxide) triblock
copolymer
water ∆MH 298 K 2002THU
_____________________________________________________________________________
Poly(ethylenesulfonic acid) sodium salt
water ∆dilH12 298 K 1976BO1
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Poly(2-(2-hydroxyethoxy)ethyl
methacrylate)
water ∆MH 298 K 1982POU
_____________________________________________________________________________
Polyionene
water ∆solHB, ∆dilH12 286-343 K 1991BUR
_____________________________________________________________________________
Poly(5-isopropenyltetrazole)
water ∆solHB, ∆dilH12 298 K 1997KIZ
_____________________________________________________________________________
_____________________________________________________________________________
Poly(L-lysine)
water ∆dilH12 298 K 1982TAN
_____________________________________________________________________________
Poly(methacrylic acid)
water ∆dilH12 298 K 1972CRE
water ∆MH 294 K 1981HOR
water ∆MH 298-313 K 1996SAF
_____________________________________________________________________________
Poly(methacrylic acid) salts
_____________________________________________________________________________
Poly(N-methacryloyl-L-alanine)
_____________________________________________________________________________
Poly(3-methacryloyloxypropane-
1-sulfonic acid) sodium salt
_____________________________________________________________________________
Poly(N-methylacrylamide)
_____________________________________________________________________________
Poly(2-methyl-1-vinylimidazole chloride)
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Poly(2-methyl-5-vinyltetrazole)
water ∆solHB 298 K 1995KIZ
_____________________________________________________________________________
water ∆MH 298-313 K 1972TAG
water ∆MH 298-329 K 1974BES
water ∆MH 298 K 1979SIM
water ∆solHA∞, ∆solHB∞ 298 K 1980BIL
water ∆MH 298 K 1983ME1
water ∆MH 298 K 1983ME2
_____________________________________________________________________________
Poly(styrenesulfonic acid)
water ∆dilH12 298 K 1974DOL
water ∆dilH12 298 K 1984VE2
_____________________________________________________________________________
Poly(styrenesulfonic acid) salts
water ∆dilH12 298 K 1967SK2
water ∆dilH12 298 K 1974DOL
water ∆MH 298 K 1976BO2
water ∆dilH12 298 K 1976MIT
water ∆dilH12 273-313 K 1984VE1
water ∆dilH12 298 K 1984VE2
water ∆dilH12 273-313 K 1987VES
_____________________________________________________________________________
Poly(vinyl alcohol)
water ∆solHB 313-353 K 1963ME1
water ∆MHA 298 K 1969NAP
water ∆MH 294 K 1981HOR
water ∆dilH12 298 K 1987SCH
_____________________________________________________________________________
Poly(vinylbenzyltrimethylammonium)
halides
water ∆dilH12 298-318 K 1993PER
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
water ∆MH, ∆dilH12 298 K 1990TAG
water ∆MHA, ∆solHB 298 K 1990TAG
water ∆dilH12 298 K 1993TA2
_____________________________________________________________________________
Poly(vinyl ethyl ether)
water ∆solHB 288-313 K 1966NAG
_____________________________________________________________________________
Poly(1-vinylimidazole)
water ∆MHB∞ 298 K 1989SAF
_____________________________________________________________________________
Poly(N-vinyl-N-propyl-acetamide)
water ∆MH 298-308 K 1991TA2
_____________________________________________________________________________
Poly(1-vinyl-2-pyrrolidinone)
water ∆dilH12 298 K 1975MUR
water/methanol ∆dilH12 298 K 1975MUR
water ∆dilH12 298 K 1979GAR
water ∆dilH12 298 K 1985SAR
water ∆solHB 298 K 1997RAS
_____________________________________________________________________________
Poly(1-vinyltetrazole)
water ∆solHB 298 K 1995KIZ
_____________________________________________________________________________
Poly(5-vinyltetrazole)
water ∆solHB, ∆dilH12 298 K 1997KIZ
_____________________________________________________________________________
Poly(1-vinyl-1,2,4-triazole)
water ∆MHB∞ 298 K 1989SAF
_____________________________________________________________________________
Propylene/maleic acid copolymer
_____________________________________________________________________________
Starch
water ∆solHB 298 K 2000SUV
water ∆solHB 298, 353 K 2002SUV
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
water ∆MH 283-308 K 1997ARA
water ∆MH, ∆MHB 283-313 K 2001OHT
_____________________________________________________________________________
water ∆MH, ∆MHB 283-313 K 2001OHT
_____________________________________________________________________________
Trimethyl-1-pentene/maleic acid
copolymer
_____________________________________________________________________________
Vinyl amine/vinyl caprolactam
copolymer
_____________________________________________________________________________
5-Vinyltetrazole/2-methyl-5-vinyl-
tetrazole copolymer
water ∆solHB∞, ∆dilH12 298 K 1997KIZ
water ∆MH 298 K 1997KIZ
_____________________________________________________________________________
_____________________________________________________________________________
5.4. References
1940MEY Meyer, K.H. and Van der Wyk, A.J.A., Proprietes de polymeres en solution. Resume de
propriete thermodynamique de systeme binaires liquides, Helv. Chim. Acta, 23, 488, 1940.
1949LAU Lauer, K., Wilde, O., and Dobberstein, O., Zur Kenntnis des Lösungszustandes des Zellu-
losexanthogenats in Viskosen, Kolloid Z. Z. Polymere, 112, 16, 1949.
1952TAG Tager, A.A. and Kargin, V.A., Thermodynamic studies of systems of polymer-hydrated
monomer (Russ.), Kolloidn. Zh., 14, 367, 1952.
1954SCH Schulze, W., Verdünnungswärmen eines Polyelektrolyten in Wasser bei kleinen Konzen-
trationen, Z. Elektrochem., 58, 165, 1954.
1955OYA Oya, S., Heat of solution of synthetic high polymers. III. Heat of solution of partially
acetylated poly(vinyl alcohol), Chem. High Polym. Japan, 12, 122, 1955.
1956AM1 Amaya, K. and Fujishiro, R., Heats of dilution of polyvinylalcohol solutions I, Bull. Chem.
Soc. Japan, 29, 361, 1956.
1956AM2 Amaya, K. and Fujishiro, R., Heats of dilution of polyvinylalcohol solutions II, Bull. Chem.
Soc. Japan, 29, 830, 1956.
1957MAL Malcolm, G.N. and Rowlinson, J.S., The thermodynamic properties of aqueous solutions of
polyethylene glycol, polypropylene glycol, and dioxane, Trans. Faraday Soc., 53, 921,
1957.
1957SIL Silberberg, A., Eliassaf, J., and Katchalsky, A., Temperature-dependence of light scattering
and intrinsic viscosity of hydrogen bonding polymers, J. Polym. Sci., 23, 259, 1957.
1958MEE Meerson, S.I. and Lipatov, S.M., Melting of gelatin gels (Russ.), Kolloidn. Zh., 20, 353,
1958.
1958TAG Tager, A.A. and Kargin, V.A., The heat of solution of polymers and their hydrated
monomers in the same liquid (Russ.), Zh. Fiz. Khim., 32, 2694, 1958.
1959TSU Tsuda, Y., Heat of solution of methanolized cellulose, Bull. Chem. Soc. Japan, 32, 372,
1959.
1961CUN Cunninghame, R.G. and Malcolm, G.N., The heats of mixing of aqueous solutions of
polypropylene glycol and polyethylene glycol, J. Phys. Chem., 65, 1454, 1961.
1965SAT Sato, H. and Nakamura, R., Thermodynamic properties of solutions of poly(ethylene
glycol), Nippon Kagaku Zasshi, 86, 168, 1965.
1966KAR Karasev, N.E., Dymarchuk, N.P., and Mishchenko, K.P., Determination of integral heat of
interaction between cellulose and sodium hydroxide from heat of dilution (Russ.), Zh. Prikl.
Khim., 39, 2301, 1966.
1966LAK Lakhanpal, M.L., Kapoor, V., Sharma, R.K., and Sharma, S.C., Studies on polyoxyethylene
glycols. Part III - Heats of mixing of polyoxyethylene glycols-water systems, Indian J.
Chem., 4, 59, 1966.
1966NAG Nagasawa, M., Asai, Y., and Sugiura, I., Determination of molecular weight distribution of
linear polymers by measuring specific heat of solution (Jap.), Kogyo Kagaku Zasshi, 69,
1759, 1966.
1967CLU Clunie, J.S., Corkill, J.M., Goodman, J.F., and Symons, P.C., Thermodynamics of nonionic
surface-active agent + water systems, Trans. Faraday Soc., 63, 2839, 1967.
1967KAG Kagemoto, A., Murakami, S., and Fujishiro, R., The heats of dilution of the poly(ethylene
oxide)/water solutions, Makromol. Chem., 105, 154, 1967.
1967SK1 Skerjanc, J., Dolar, D., and Leskovsek, D., Heats of dilution of polyelectrolyte solutions. I.
Polystyrenesulphonic acid and its sodium salt, Z. Phys. Chem., N. F., 56, 207, 1967.
1967SK2 Skerjanc, J., Dolar, D., and Leskovsek, D., Heats of dilution of polyelectrolyte solutions. II.
Zinc polystyrenesulphonate, Z. Phys. Chem., N. F., 56, 218, 1967.
____________________________________________________________________________________
1968GOL Goldfarb, J. and Rodriguez, S., Aqueous solutions of polyvinylpyrrolidone, Makromol.

Chem., 116, 96, 1968.
1968HES Heskins, M. and Guillet, J.E., Solution properties of poly(N-isopropylacrylamide), J.
Macromol. Sci.-Chem. A, 2, 1441, 1968.
1968LA1 Lakhanpal, M.L., Chhina, K.S., and Sharma, S.C., Thermodynamic properties of aqueous
solutions of polyoxethyleneglycols, Indian J. Chem., 6, 505, 1968.
1968LA2 Lakhanpal, M.L., Singh, H.G., Singh, H., and Sharma, S.C., A comparative study of heats
of mixing of polyoxypropylene glycol-water and polyoxypropylene glycol-water systems,
Indian J. Chem., 6, 95, 1968.
1969CLU Clunie, J.S., Goodman, J.F., and Symons, P.C., Phase equilibria of dodecylhexaoxyethy-
lene glycol monoether in water, Trans. Faraday Soc., 65, 287, 1969.
1969NAP Napper, D.H., A reversible transformation from enthalpic to entropic stabilization, Kolloid
Z. Z. Polym., 234, 1149, 1969.
1970GRO Gromov, V.F., Khomikovskii, P.M., and Abkin, A.D., Medium influence on radical
polymerization of acrylamide (Russ.), Vysokomol. Soedin., Ser. B, 12, 767, 1970.
1970NAK Nakayama, H., Temperature dependence of the heat of solution of poly(ethylene glycol) and
of related compounds, Bull. Chem. Soc. Japan, 43, 1683, 1970.
1970SKE Skerjanc, J., Dolar, D., and Leskovsek, D., Heats of dilution of polyelectrolyte solutions
III., Z. Phys. Chem., N. F., 70, 31, 1970.
1971CAR Cartier, J.-P. and Daoust, H., Chaleur de dilution de solutions aqueuses d'acide poly-
acrylique, de son sel de sodium et de l'acide propionique, Can. J. Chem., 49, 3935, 1971.
1972CRE Crescenzi, V., Quadrifolio, F., and Delben, F., Calorimetric investigation of poly(methacry-
lic acid) and poly(acrylic acid) in aqueous solution, J. Polym. Sci.: Part A-2, 10, 357, 1972.
1972MAR Maron, S.H. and Filisko, F.E., Heats of solution and dilution for polyethylene oxide in
several solvents, J. Macromol. Sci.-Phys. B, 6, 79, 1972.
1972NAK Nakayama, H., Thermodynamic properties of an aqueous solution of tetraethylene glycol
diethyl ether, Bull. Chem. Soc. Japan, 45, 1371, 1972.
A, 14, 1991, 1972.
1973ISE Ise, N., Mita, K., and Okubo, T., Heat of dilution of aqueous solutions of polyacrylates, J.
Chem. Soc., Faraday Trans. I, 69, 106, 1973.
1973SKE Skerjanc, J., Hocevar, S., and Dolar, D., Heats of dilution of polyelectrolyte solutions. IV.
Alkaline-earth polystyrenesulphonates, Z. Phys. Chem., N. F., 86, 311, 1973.
1974BES Bessonov, Yu.S. and Tager, A.A., Thermodynamic investigation of oligomeric
polyoxypropylenediol-water system in the demixing region (Russ.), Tr. Khim. Khim.
Tekhnol., (1), 150, 1974.
1974DOL Dolar, D. and Skerjanc, J., Studies of polyelectrolyte solutions containing mixtures of
mono- and divalent counterions. II. Heat of dilution, J. Phys. Chem., 61, 4106, 1974.
1974MIT Mita, K. and Okubo, T., Heat of dilution of aqueous solutions of sodium carboxymethyl-
cellulose and sodium poylacrylate, J. Chem. Soc., Faraday Trans. I, 70, 1546, 1974.
1975IKE Ikeda, M., Suga, H., and Seki, S., Thermodynamic studies of solid polyethers: 5.
Crystalline-amorphous interfacial thermal properties, Polymer, 16, 634, 1975.
1975MIT Mita, K., Okubo, T., and Ise, N., Heats of dilution of aqueous solutions of
polyethyleneimine hydrochloride and sodium polyphosphate and their low molecular weight
analogues, J. Chem. Soc., Faraday Trans. I, 71, 1932, 1975.
1975MUR Murakami, S., Kimura, F., and Fujishiro, R., Enthalpies of dilution of poly(1-vinyl-2-
pyrrolidone) + aqueous methanol solution, Makromol. Chem., 176, 3425, 1975.
1975TAG Tager, A.A. and Bessonov, Yu.S., Thermochemistry of solutions of polymers and polymer
compositions in the phase separation region (Russ.), Vysokomol. Soedin., Ser. A, 17, 2383,
1975.
_____________________________________________________________________________
1976BO1 Boyd, G.E. and Wilson, D.P., Enthalpies of dilution of strong polyelectrolyte solutions.
Comparisons with the cell and line charge theories, J. Phys. Chem., 80, 805, 1976.
1976BO2 Boyd, G.E., Wilson, D.P., and Mannig, G.S., Enthalpies of mixing of polyelectrolytes with
simple aqueous electrolyte solutions, J. Phys. Chem., 80, 808, 1976.
1976DA1 Daoust, H. and Hade, A., Effect of cation size on heats of dilution of aqueous solutions of
alkaline poly(styrenesulfonates), Macromolecules, 9, 608, 1976.
1976DA2 Daoust, H. and Lajoie, A., Chaleurs de dilution de solutions aqueuses d'acide polymeth-
acrylique et de ses sels de sodium et de rubidium, Can. J. Chem., 54, 1853, 1976.
1976KIS Kiselev, V.P., Shakhova, E.M., Fainberg, E.Z., Virnik, A.D, and Rogovin, Z.A., Measure-
ment of density and heat of solution of various dextran samples (Russ.), Vysokomol.
Soedin., Ser. B, 18, 847, 1976.
1976LAK Lakhanpal, M.L., Chaturvedi, L.K., Puri, T., and Sharma, S.C., Thermochemical studies on
ternary systems. Part I - Enthalpies of mixing of polyoxyethylene glycols in aqueous
dioxane and ethyl alcohol, Indian J. Chem., 14A, 645, 1976.
1976MIT Mita, K., Okubo, T., and Ise, N., Heat of dilution of aqueous solutions of sodium salts of
partially sulphonated polystyrenes, J. Chem. Soc., Faraday Trans. I, 72, 504, 1976.
1978COM Comper, W.D. and Laurent, T.C., An estimate of the enthalpic contribution to the
interaction between dextran and albumin, Biochem. J., 175, 703, 1978.
1978DIN Dincer, S. and Bonner, D.C., Thermodynamic analysis of ethylene and vinyl acetate
1978SCH Scholz, W., Kalorimetrische Untersuchungen zum Lösungsverhalten von Polyacrylsäure
und Polyacrylamid in Wasser, Formamid und Ethylenglykol, Dissertation, TU Braun-
schweig, 1978.
1979ASP Aspler, J.S. and Gray, D.G., Gas chromatographic and static measurements of solute
activity for a polymeric liquid-crystalline phase, Macromolecules, 12, 562, 1979.
1979BAB Baba, Y., Kagemoto, A., and Fujishiro, R., Calorimetric studies in the helix-coil transition
of poly(amino acid)s in methanol-water solvent mixtures, Makromol. Chem., 180, 2221,
1979.
1979BAS Basedow, A.M. and Ebert, K.H., Production, characterization, and solution properties of
dextran fractions of narrow molecular weight distributions, J. Polym. Sci. Polym. Symp., 66,
101, 1979.
1979GAR Garvey, M.J. and Robb, I.D., Effect of electrolytes on solution behavior of water soluble
macromolecules, J. Chem. Soc., Faraday Trans. I, 75, 993, 1979.
1979KLE Klein, J. and Scholz, W., Kalorimetrische Untersuchungen zum Lösungsverhalten von
Polyacrylsäure und Poly(natrium acrylat) in Wasser, Formamid und Ethylenglycol,
Makromol. Chem., 180, 1477, 1979.
1979KOL Koller, J., Kalorimetrische Untersuchungen der inter- und intramolekularen
Wechselwirkungen von Polyethylenglycolen in wässriger und benzolischer Lösung,
Dissertation, TU München, 1979.
1979MON Monshausen, F.W., Kalorimetrische Messungen am System Wasser – Polyethylenoxid,
Dissertation, RWTH Aachen, 1979.
1979SIM Simenido, A.V., Medved, Z.N., Denisova, L.L., Tarakanov, O.G., and Starikova, N.A.,
Some physicochemical properties of the mixtures of polypropylene polyols with water
1980BAS Basedow, A.M., Ebert, K.H., Feigenbutz, W., Polymer-solvent interactions. Dextrans in
water and DMSO, Makromol. Chem., 181, 1071, 1980.
1980BIL Bilimova, E.S., Gladkovskii, G.A., Golubev, V.M., and Medved, Z.N., Study of phase
equilibriums in mixtures of poly(propylene oxide) with water (Russ.), Vysokomol. Soedin.,
Ser. A, 22, 2240, 1980.
1980DAO Daoust, H. and Chabot, M.-A., Effect of cation size and of the presence of hydrophobic
groups on heats of dilution of aqueous solutions of alkali metal and tetramethylammonium
salts of the polyacrylic series, Macromolecules, 13, 616, 1980.
____________________________________________________________________________________
1980KUR Kuroiwa, S., Matsuda, H., and Fujimatsu, H., Temperature dependence of solution
properties of nonionic surface active agent, Nippon Kagaku Kaishi, (3), 362, 1980.
1980SCH Schönert, H. and Monshausen, F., Calorimetric measurements on dilute solutions of
polyethylene oxide in water, Colloid Polym. Sci., 258, 578, 1980.
1980SKE Skerjanc, J., Vesnaver, G., and Dolar, D., Heats of dilution of polystyrene sulfonates in
dioxane-water mixtures, Eur. Polym. J., 16, 179, 1980.
1980GUN Gunduz, S. and Dincer, S., Solubility behaviour of polystyrene. Thermodynamic studies
using gas chromatography, Polymer, 21, 1041, 1980.
1981ASP Aspler, J.S. and Gray, D.G., Mixing of water with (hydroxypropyl)cellulose liquid
crystalline mesophases, Macromolecules, 14, 1546, 1981.
1981DAY Day, J.C. and Robb, I.D., Thermodynamic parameters of polyacrylamides in water,
Polymer, 22, 1530, 1981.
1981FUJ Fujioka, K., Nakajima, K., Baba, Y., Kagemoto, A., and Fujishiro, R., Enthalpy changes of
dissociation of hemoglobin solution, Netsusokutei 8(3), 91, 1981.
1981HOR Horiuchi, H. and Ohshita, T., Heat of mixing of poly(vinyl alcohol) and poly(methacrylic
acid) in aqueous solution, Kobunshi Ronbunshu, 38, 407, 1981.
1981KOL Koller, J. and Killmann, E., Lösungs- und Verdünnungswärmen von Polyethylenglykolen in
Wasser und Benzol, 1. Experimentelle Ergebnisse, Makromol. Chem., 182, 3579, 1981.
1981MED Medved, Z.N. and Starikova, N.A., Enthalpies of mixing of oligomers of ethylene oxide or
propylene oxide with water (Russ.), Zh. Fiz. Khim., 55, 2438, 1981.
1981PAO Paoletti, S., Delben, F., and Crescenzi, V., Enthalpies of dilution of partially neutralized
maleic acid copolymers in water. Correlation of experiments with theories, J. Phys. Chem.,
85, 1413, 1981.
1982ASP Aspler, J.S. and Gray, D.G., Interaction of organic vapours with hydroxypropyl cellulose,
Polymer, 23, 43, 1982.
1982GAR Garcia-Fierro, J.L. and Aleman, J.V., Sorption of water by epoxide prepolymers,
1982MED Medved, Z.N., Petrova, N.I., and Tarakanov, O.G., Comparison of thermodynamics of
mixtures of oligomers of ethylene oxide or propylene oxide with water (Russ.), Vysokomol.
Soedin., Ser. B, 24, 674, 1982.
1982MEE Meerson, S.I., Shakhova, E.M., Prokof'eva, M.V., and Khin, N.N., Distribution of electro-
lytes and phase equilibria in cellulose ethers-water-electrolyte systems (Russ.), Vysokomol.
Soedin., Ser. A, 24, 634, 1982.
1982MOR Morcellet, M., Loucheux, C., and Daoust, H., Poly(methacrylic acid) derivatives 5.
Microcalorimetric study of poly(N-methacryloyl-L-alanine) and poly(N-methacryloyl-L-
alanine-co-N-phenylmethacrylamide) in aqueous solutions, Macromolecules, 15, 890, 1982.
1982POU Pouchly, J., Benes, S., Masa, Z., and Biros, J., Sorption of water in hydrophilic polymers, 2.
Thermodynamics of mixing of water with poly(2-hydroxyethyl methacrylate) and with
poly[2-(2-hydroxyethoxy)ethyl methacrylate], Makromol. Chem., 183, 1565, 1982.
1982TAN Tanaka, S., Fukagawa, O., Baba, Y., Kagemoto, A., and Fujishiro, R., Calorimetric studies
on the coil-helix transition of poly(L-lysine) in water-organic solvent mixtures,
Netsusokutei, 9(1), 2, 1982.
1983ASP Aspler, J.S. and Gray, D.G., An inverse gas-chromatography study of the interactions of
water with some cellulose derivatives, J. Polym. Sci. Polym. Phys. Ed. 21, 1675, 1983.
1983LAK Lakhanpal, M.L. and Parashar, R.N., Enthalpies of mixing for aqueous solutions of
polyoxyethylene glycols, Indian J. Chem., 22A, 48, 1983.
1983ME1 Medved, Z.N. and Starikova, N.A., Enthalpies of mixing of oligomeric propylene oxides
and water (Russ.), Zh. Fiz. Khim., 57, 2590, 1983.
1983ME2 Medved, Z.N., Petrova, N.I., and Tarakanov, O.G., Thermodynamics of mixing of
oligomeric polypropylene glycol polyols with water (Russ.), Vysokomol. Soedin., Ser. B, 25,
764, 1983.
_____________________________________________________________________________
1983TAG Tager, A.A., Adamova, L.V., and Morkvina, L.I., Thermodynamics of the formation of
polycomplexes of poly(acrylic acid) with poly(vinyl alcohol) and poly(ethylene oxide)
1984DAO Daoust, H. and St-Cyr, D., Microcalorimetric study of poly(ethylene oxide) in water and in
water-ethanol mixed solvent, Macromolecules, 17, 596, 1984.
1984VE1 Vesnaver, G., Rudez, M., Pohar, C., and Skerjanc, J., Effect of temperature on the enthalpy
of dilution of strong polyelectrolyte solutions, J. Phys. Chem., 88, 2411, 1984.
1984VE2 Vesnaver, G. and Skerjanc, J., Structural contributions of the counterion solvent interactions
to the enthalpies of dilution of the aqueous polystyrenesulfonate solutions, Vestn. Slov.
Kem. Drus., 31, 325, 1984.
1985IOE Ioelovich, M.Ya., Thermodynamics of the system amorphous regions of cellulose-water
(Russ.), Khim. Drev., (5), 3, 1985.
1985SAR Sardharwalla, I. and Lawton, J.B., Calorimetric determination of the enthalpy change for the
binding of methyl orange to poly(vinylpyrrolidone) in aqueous solution, Polymer, 26, 751,
1985.
1986SKE Skerjanc, J. and Fele, M., Effect of temperature on the enthalpy of dilution of weak
polyelectrolyte solutions, J. Calorim. Anal. Therm. Thermodyn. Chim., 17, 453, 1986.
1987BIR Biros, J., Pouchly, J., and Zivny, A., A calorimetric investigation of interactions in aqueous
solutions of poly(oxyethylene) 1. Heats of mixing of oligomeric models, Makromol.Chem.,
188, 379, 1987.
1987BOG Bogdanov, B. and Mikhailov, M., Calorimetric inverstigation of water/polyoxyethylene
systems, J. Thermal Anal., 32, 161, 1987.
1987CIF Cifra, P. and Romanov, A., Enthalpies of solution of methoxy and ethoxy end group
oligomers of poly(ethylene glycol) in binary solvent water-dimethylformamide. Study of
hydrophobic hydration, Chem. Pap., 41, 395, 1987.
1987SCH Schneider, P. and Heintz, A., Enthalpies of solution of polyvinylalcohol in water and
polyvinylacetate in dioxane, Thermochim. Acta, 119, 47, 1987.
1987TAG Tager, A.A., Safronov, A.P., Lopyrev, V.A., Ermakova, T.G., Tatarova, L.A., Kashik, T.N.,
Thermodynamics of aqueous solutions of poly(1-vinylimadazole) and poly(1-vinyl-1,2,4-
triazole) (Russ.), Vysokomol. Soedin., Ser. A, 29, 2421, 1987.
1987VES Vesnaver, G., Kranjc, Z., Pohar, C., and Skerjanc, J., Free enthalpies, enthalpies and
entropies of dilution of aqueous solutions of alkaline earth poly(styrenesulfonates) at
different temperatures, J. Phys. Chem., 91, 3845, 1987.
1988AZU Azuma, H., Hanada, K., Yoshikawa, Y., Baba, Y., and Kagemoto, A., Heats of dilution of
water-soluble polymer solutions, Thermochim. Acta, 123, 271, 1988.
1988PAR Parashar, R. and Sharma, S.C., Enthalpies of mixing of polyoxypropyleneglycols with
benzene, ethanol and water, Indian J. Chem., 27A, 1092, 1988.
1988TAG Tager, A.A., Safronov, A.P., Voit, V.V., Lopyrev, V.A., Ermakova, T.G., Tatarova, L.A.,
and Shagelaeva, N.S., Heats of solution of poly(1-vinylpyrazole), poly(1-vinylimid-azole),
and poly(1-vinyl-1,2,4-triazole) in organic donor solvents (Russ.), Vysokomol. Soedin., Ser.
A, 30, 2360, 1988.
1989AND Andersson, B. and Olofsson, G., Calorimetric study of binary systems of tetraethyleneglycol
octylether and polyethyleneglycol with water, J. Solution Chem., 18, 1019, 1989.
1989SAF Safronov, A.P., Tager, A.A., Sharina, S.V., Lopyrev, V.A., Ermakova, T.G., Tatarova,
L.A., and Kashik, T.N., Nature of hydration in aqueous solutions of poly(1-vinylazoles)
1990DAO Daoust, H., Darveau, R., and Laberge, F., Microcalorimetric investigation on interaction
between poly(acrylic acid) and oxyethylene oligomers in water, Polymer, 31, 1946, 1990.
1990TAG Tager, A.A., Safronov, A.P., Sharina, S.V., and Galaev, I.Yu., Thermodynamics of aqueous
solutions of polyvinylcaprolactam, Vysokomol. Soedin., Ser. A, 32, 529, 1990.
1991BUR Burmistr, M.V., Privalko, V.P., and Lipatov, Yu.S., Energetics of dissolution of alkyl-
aromatic polyionenes in water (Russ.), Dokl. Akad. Nauk Ukr. SSR, 10, 135, 1991.
____________________________________________________________________________________
1991HEY Hey, M.J. and Ilett, S.M., Poly(ethylene oxide) hydration studied by differential scanning
calorimetry, J. Chem. Soc., Faraday Trans., 87, 3671, 1991.
1991TA1 Tager, A.A. and Safronov, A.P., Complex formation in aqueous and nonaqueous solutions
of poly(vinylazoles) (Russ.), Vysokomol. Soedin., Ser. A, 33, 67, 1991.
1991TA2 Tager, A.A., Safronov, A.P., Berezyuk, E.A., and Galaev, I.Yu., Hydrophobic interactions
Soedin., Ser. B, 33, 572, 1991.
1991ZVE Zverev, M.P., Zenkov, I.D., Zakharova, N.N., Zashchenkina, E.S., and Bondarenko, O.A.,
Properties of polyacrylonitrile and its fibers containing chemically active groups (Russ.),
Khim. Volokna, (5), 32, 1991.
1992KAL Kalaouzis, P.J. and Demertzis, P.G., Water sorption and water vapour diffusion in food-
grade plastics packaging materials: effect of a polymeric plasticizer, Packag. Technol. Sci.,
5, 133, 1992.
1992TAG Tager, A.A., Adamova, L.V., Safronov, A.P., Klyuzhin, E.S., and Zhigalova, E.P., Thermo-
dynamics of poly(acrylic acid) solutions in water (Russ.), Vysokomol. Soedin., Ser. B, 34,
10, 1992.
1993ADA Adamova, L.V., Klyuzhin, E.S., Safronov, A.P., Nerush, N.T., and Tager, A.A., Thermo-
dynamics of interactions between water and copolymers of acrylate and acrylic acid (Russ.),
1993AUC Aucouturier, C. and Roux, A.H., Thermodynamic study of polyethylene glycol in micellar
aqueous solutions of sodium dodecylsulfate, Calorim. Anal. Therm., 24, 9, 1993.
1993EAG Eagland, D., Crowther, N.J., and Butler, C.J., Interaction of poly(oxyethylene) with water as
a function of molar mass, Polymer, 34, 2804, 1993.
1993KEL Keller, M., Heintz, A., and Lichtenthaler, R., Enthalpies of dilution of polyelectrolyte
solutions and exchange enthalpies of polyelectrolyte counterions, Thermochim. Acta, 229,
243, 1993.
1993PER Peregudov, Yu.S., Amelin, A.N., Perelygin, V.M., Calorimetric study of the dilution of
solutions of poly(vinylbenzyltrimethylammonium) and its salts (Russ.), Vysokomol. Soedin.,
Ser. B, 35, 127, 1993.
1993SAF Safronov, A.P., Tager, A.A., Adamova, L.V., and Klyuzhin, E.S., Thermodynamics of the
interaction of polyacrylic acid with water, Vysokomol. Soedin., Ser. A, 35, 702, 1993.
1993TA1 Tager, A.A., Klyuzhin, E.S., Adamova, L.V., and Safronov, A.P., Thermodynamics of
Ser. B, 35, 1357, 1993.
1993TA2 Tager, A.A., Safronov, A.P., Sharina, S.V., and Galaev, I.Yu., Thermodynamic study of
poly(N-vinyl caprolactam) hydration at temperatures close to lower critical solution
temperature, Colloid Polym. Sci., 271, 868, 1993.
1994AUC Aucouturier, C., Rous-Desgranges, G., and Roux, A.H., Thermodynamic study of poly-
ethyleneglycols in micellar solutions of water + sodium dodecylsulfate, J. Therm. Anal., 41,
1295, 1994.
1994KHA Khamrakulov, G., Myagkova, N.V., and Budtov, V.P., Water sorption and diffusion in
cellulose and cellulose acetates (Russ.), Vysokomol. Soedin., Ser. B, 36, 845, 1994.
1994NAG Nagahama, K., Inomata, H., and Saito, S., Measurement of osmotic pressure in aqueous
solutions of poly(ethylene glycol) and poly(N-isopropylacrylamide), Fluid Phase Equil., 96,
203, 1994.
1994PER Persson, K., Wang, G., and Olofsson, G., Self-diffusion, thermal effects and viscosity of a
monodisperse associative polymer: self-association and interaction with surfactants, J.
Chem. Soc., Faraday Trans., 90, 3555, 1994.
272, 1234, 1994.
_____________________________________________________________________________
1995CAR Carlsson, M., Hallen, D., Linse, P., Mixing enthalpy and phase separation in a
poly(propylene oxide)-water system, J. Chem. Soc., Faraday Trans., 91, 2081, 1995.
poly(ethylene glycol) and dextran − experimental results and modeling of thermodynamic
1995KIZ Kizhnyaev, V.N., Gorkovenko, O.P., Bazhenov, D.N., and Smirnov, A.I., Interrelation
between hydrodynamic and thermodynamic characteristics of solutions of
poly(vinyltetrazoles) in mixed solvents (Russ.), Vysokomol. Soedin., Ser. B, 37, 1948, 1995.
1995PER Peregudov, Yu.S., Amelin, A.N., Perelygin, V.M., Thermodynamic characteristics of inter-
actions between poly(styrenesulfonic acid), poly(vinylbenzyltrimethylammonium) hydro-
xide, and their salt forms with water (Russ.), Vysokomol. Soedin., Ser. B, 37, 302, 1995.
1995TIN Tintinger, R., Thermodynamische Eigenschaften ausgewählter wässriger Zwei-Phasen
1996FAE Faes, H., De Schryver, F.C., Sein, A., Bijma, K., Kevelam, J., and Engberts, J.B.F., Study
of self-associating amphiphilic copolymers and their interaction with surfactants,
1996KEL Keller, M., Lichtenthaler, R., and Heintz, A., Enthalpies of dilution of polycation solutions
and exchange enthalpies of polycations, Ber. Bunsenges. Phys. Chem., 100, 776, 1996.
1996NAK Nakamoto, C., Kitada, T., and Kato, E., Pressure dependence on the Flory-Huggins inter-
action parameter of poly(N-isopropylacrylamide) gels, Polym. Gels Networks, 4, 17, 1996.
1996SAF Safronov, A.P., Tager, A.A., and Koroleva, E.B., Thermodynamics of dissolution of
polyacrylic acid in donor and acceptor solvents, Vysokomol. Soedin., Ser. B, 38, 900, 1996.
1997ARA Aratono, M., Ohta, A., Ikeda, N., Matsubara, A., Motomura, K., and Takiue, T.,
Calorimetry of surfactant solutions. Measurement of the enthalpy of mixing of tetraethylene
glycol monooctyl ether and water, J. Phys. Chem. B, 101, 3535, 1997.
1997KIZ Kizhnyaev, V.N., Gorkovenko, O.P., Safronov, A.P., and Adamova, L.V., Thermodynamics
of the interaction between tetrazole-containing polyelectrolytes and water (Russ.),
1997RAS Rashidova, S.Sh., Voropaeva, N.L., Kalantarova, T.D., and Yushkova, S.M., Calorimetric
studies of the heats of interaction between methylcellulose and poly(vinylpyrrolidone)
(Russ.), Vysokomol. Soedin., Ser. B, 39, 556, 1997.
1998OHT Ohta, A., Takiue, T., Ikeda, N., and Aratono, M., Calorimetric study of dilute aqueous
solutions of ethylene glycol oligomers, J. Phys. Chem. B, 102, 4809, 1998.
1999SAF Safronov, A.P. and Kovalev, A.A., Enthalpy of interaction of crystalline polyethyleneoxide
with water, toluene, and chloroform (Russ.), Vysokomol. Soedin., Ser. A, 41, 1008, 1999.
2000SUV Suvorova, A.I., Safronov, A.P., and Mel'nikova, O.A., Enthalpies of interaction of cellulose
derivatives with starch (Russ.), Vysokomol. Soedin., Ser. A, 42, 822, 2000.
2001OHT Ohta, A., Takiue, T., Ikeda, N., and Aratono, M., Calorimetric study of micelle formation in
polyethylene glycol monooctyl ether solutions, J. Solution Chem., 30, 335, 2001.
2002COO Cooke, S.A., Jonsdottir, S.O., and Westh, P., A thermodynamic study of glucose and related
oligomers in aqueous solution: vapor pressures and enthalpies of mixing, J. Chem. Eng.
Data, 47, 1185, 2002.
2002SAF Safronov, A.P. and Zubarev, A.Yu., Flory-Huggins parameter of interaction in
polyelectrolyte solutions of chitosan and its alkylated derivative, Polymer, 43, 743, 2002.
2002SUV Suvorova, A.I., Safronov, A.P., and Mel'nikova, O.A., Thermodynamic compatibility of
starch and carboxymethyl cellulose sodium (Russ.), Vysokomol.,Soedin., Ser. A, 44, 98,
2002.
2002THU Thurn, T., Couderc, S., Sidhu, J., Bloor, D.M., Penfold, J., Holzwarth, J.F., and Wyn Jones,
E., Study of mixed micelles and interaction parameters for triblock copolymers of the type
EOm-POn-EOm and ionic surfactants: equilibrium and structure, Langmuir, 18, 9267, 2002.
6.1. PVT data of some polymers and their aqueous solutions
Polymer (B): ethylene/vinyl alcohol copolymer 1995ZOL

Characterization: 56 wt% vinyl alcohol
____________________________________________________________________________________
P/MPa T/K
468.35 476.85 485.35 493.45 501.95 510.25 518.75 527.25 535.55
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 0.9808 0.9860 0.9911 0.9960 1.0017 1.0067 1.0122 1.0178 1.0241
20 0.9711 0.9759 0.9806 0.9853 0.9902 0.9949 1.0000 1.0051 1.0107
40 0.9629 0.9673 0.9718 0.9762 0.9806 0.9852 0.9897 0.9944 0.9997
60 0.9553 0.9595 0.9636 0.9678 0.9721 0.9764 0.9807 0.9850 0.9898
80 0.9483 0.9523 0.9562 0.9602 0.9643 0.9684 0.9723 0.9765 0.9811
100 0.9421 0.9458 0.9496 0.9534 0.9573 0.9611 0.9648 0.9689 0.9731
120 0.9360 0.9396 0.9432 0.9468 0.9507 0.9542 0.9578 0.9615 0.9659
140 0.9302 0.9338 0.9373 0.9409 0.9443 0.9478 0.9513 0.9549 0.9589
160 0.9249 0.9283 0.9316 0.9351 0.9385 0.9419 0.9452 0.9486 0.9525
180 0.9199 0.9232 0.9265 0.9297 0.9330 0.9363 0.9394 0.9428 0.9465
200 0.9151 0.9182 0.9214 0.9246 0.9278 0.9309 0.9340 0.9374 0.9409
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa T/K
466.45 475.05 483.35 491.55 499.05 507.75 516.05 524.15 531.75
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 0.9527 0.9576 0.9621 0.9671 0.9713 0.9767 0.9818 0.9889 0.9982
20 0.9445 0.9489 0.9531 0.9575 0.9617 0.9663 0.9712 0.9779 0.9865
40 0.9372 0.9413 0.9453 0.9493 0.9535 0.9575 0.9621 0.9686 0.9768
60 0.9306 0.9344 0.9382 0.9420 0.9460 0.9497 0.9541 0.9603 0.9680
80 0.9243 0.9280 0.9315 0.9351 0.9390 0.9426 0.9467 0.9528 0.9600
100 0.9186 0.9221 0.9256 0.9289 0.9326 0.9359 0.9400 0.9458 0.9528
120 0.9132 0.9164 0.9197 0.9230 0.9266 0.9298 0.9336 0.9394 0.9462
140 0.9081 0.9114 0.9144 0.9176 0.9210 0.9240 0.9279 0.9334 0.9397
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
P/MPa T/K
466.45 475.05 483.35
491.55 499.05 507.75 516.05 524.15 531.75
Vspez/cm3g−1
____________________________________________________________________________________
160 0.9032 0.9063 0.9093 0.9125 0.9158 0.9186 0.9224 0.9277 0.9338
180 0.8986 0.9016 0.9046 0.9075 0.9108 0.9136 0.9171 0.9224 0.9283
200 0.8943 0.8973 0.9000 0.9029 0.9060 0.9087 0.9122 0.9174 0.9231
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa T/K
469.25 477.75 486.15
494.35 502.65 511.35 519.55 527.85 536.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.9386 0.9431 0.9479 0.9514 0.9561 0.9610 0.9658 0.9711 0.9765
20 0.9299 0.9342 0.9385 0.9419 0.9462 0.9506 0.9551 0.9597 0.9648
40 0.9228 0.9269 0.9308 0.9340 0.9381 0.9422 0.9464 0.9508 0.9555
60 0.9163 0.9201 0.9238 0.9268 0.9307 0.9346 0.9386 0.9429 0.9472
80 0.9102 0.9139 0.9174 0.9203 0.9240 0.9276 0.9314 0.9354 0.9397
100 0.9047 0.9082 0.9115 0.9142 0.9178 0.9214 0.9251 0.9288 0.9328
120 0.8994 0.9028 0.9059 0.9086 0.9120 0.9154 0.9188 0.9224 0.9263
140 0.8944 0.8976 0.9007 0.9032 0.9065 0.9097 0.9130 0.9165 0.9202
160 0.8896 0.8928 0.8957 0.8981 0.9013 0.9043 0.9076 0.9110 0.9146
180 0.8851 0.8882 0.8909 0.8933 0.8964 0.8994 0.9025 0.9058 0.9092
200 0.8807 0.8838 0.8864 0.8887 0.8918 0.8946 0.8976 0.9008 0.9042
____________________________________________________________________________________
Polymer (B): perfluoro(oxyethylene/oxymethylene) copolymer 1995DAN

Characterization: Mn/g.mol−1 = 465, Mw/g.mol−1 = 500, 12.4 wt% endgroups −CH2OH
43 mol% perfluorooxymethylene
P/MPa = 0.1
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15 333.15
Vspez/cm3g−1 0.5585 0.5636 0.5687 0.5738 0.5789 0.5843 0.5895 0.5949 0.6003

−1 −1
Characterization: Mn/g.mol = 850, Mw/g.mol = 1045, 7.3 wt% endgroups −CH2OH
P/MPa = 0.1
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15 333.15
Vspez/cm3g−1 0.5457 0.5512 0.5566 0.5621 0.5674 0.5729 0.5785 0.5840 0.5896
6. PVT Data 433
____________________________________________________________________________________

P/MPa = 0.1
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15 333.15
Vspez/cm3g−1 0.5625 0.5674 0.5723 0.5773 0.5823 0.5874 0.5924 0.5973 0.6027

P/MPa = 0.1
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15 333.15
Vspez/cm3g−1 0.5476 0.5529 0.5583 0.5638 0.5691 0.5748 0.5803 0.5858 0.5914

−1 −1
P/MPa = 0.1
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15 333.15
Vspez/cm3g−1 0.5311 0.5367 0.5423 0.5479 0.5534 0.5592 0.5646 0.5705 0.5764

P/MPa = 0.1
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15 333.15
Vspez/cm3g−1 0.5280 0.5336 0.5393 0.5450 0.5506 0.5566 0.5624 0.5681 0.5738

P/MPa = 0.1
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15 333.15
3 −1
Vspez/cm g 0.5255 0.5312 0.5369 0.5427 0.5483 0.5543 0.5599 0.5656 0.5711

−1 −1
P/MPa = 0.1
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15 333.15
Vspez/cm3g−1 0.5246 0.5302 0.5359 0.5416 0.5471 0.5529 0.5588 0.5644 0.5701
____________________________________________________________________________________

P/MPa = 0.1
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15 333.15
Vspez/cm3g−1 0.5223 0.5280 0.5337 0.5395 0.5452 0.5512 0.5570 0.5626 0.5682

−1 −1
P/MPa = 0.1
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15 333.15
Vspez/cm3g−1 0.5405 0.5461 0.5518 0.5575 0.5631 0.5692 0.5747 0.5806 0.5862
Polymer (B): poly(1,2-butylene glycol) dimethyl ether 1997MAI

−1 −1
Characterization: Mn/g.mol = 340, Mw/g.mol = 360, Dow Chemical Company
P/MPa = 0.1
T/K 303.15 313.15 323.15 333.15 343.15 353.15 363.15
Vspez/cm3g−1 1.078 1.088 1.097 1.107 1.116 1.126 1.136

Characterization: Mn/g.mol−1 = 440, Mw/g.mol−1 = 460, Dow Chemical Company
P/MPa = 0.1
T/K 303.15 313.15 323.15 333.15 343.15 353.15 363.15
Vspez/cm3g−1 1.065 1.074 1.083 1.092 1.101 1.110 1.119

−1 −1
Characterization: Mn/g.mol = 800, Mw/g.mol = 820, Dow Chemical Company
P/MPa = 0.1
T/K 303.15 313.15 323.15 333.15 343.15 353.15 363.15
Vspez/cm3g−1 1.052 1.060 1.068 1.076 1.085 1.093 1.102

Characterization: Mn/g.mol−1 = 4540, Mw/g.mol−1 = 5130, Dow Chemical Company
P/MPa = 0.1
T/K 303.15 313.15 323.15 333.15 343.15 353.15 363.15
Vspez/cm3g−1 1.040 1.047 1.055 1.063 1.071 1.079 1.087
6. PVT Data 435
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 2000LEE

____________________________________________________________________________________
P/MPa T/K
298.15 318.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.89453 0.90843 0.91718
10.0 0.89008 0.90188 0.91491
20.0 0.88668 0.89839 0.91158
30.0 0.88370 0.89477 0.90752
40.0 0.88020 0.89166 0.90383
50.0 0.87712 0.88842 0.89928
____________________________________________________________________________________
Comments: Additional data for PEG200 can be found in 1998LEE.
Polymer (B): poly(ethylene glycol) 1999CHA

____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15
328.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.8930 0.8996 0.9060 0.9125 0.9189
5.0 0.8913 0.8977 0.9040 0.9104 0.9168
10.0 0.8895 0.8959 0.9020 0.9083 0.9146
15.0 0.8879 0.8941 0.9002 0.9063 0.9125
20.0 0.8863 0.8924 0.8984 0.9044 0.9106
25.0 0.8846 0.8907 0.8966 0.9025 0.9087
30.0 0.8831 0.8890 0.8948 0.9007 0.9067
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15
328.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.8921 0.8987 0.9053 0.9117 0.9184
5.0 0.8903 0.8969 0.9033 0.9096 0.9163
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15328.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
10.0 0.8886 0.8950 0.9012 0.9075 0.9142
15.0 0.8869 0.8932 0.8993 0.9056 0.9121
20.0 0.8853 0.8914 0.8974 0.9037 0.9101
25.0 0.8835 0.8897 0.8957 0.9018 0.9081
30.0 0.8820 0.8880 0.8941 0.8999 0.9063
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15 328.15 338.15
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 0.8917 0.8986 0.9051 0.9117 0.9183
5.0 0.8898 0.8965 0.9030 0.9095 0.9160
10.0 0.8881 0.8947 0.9011 0.9074 0.9139
15.0 0.8864 0.8929 0.8991 0.9054 0.9117
20.0 0.8848 0.8911 0.8973 0.9035 0.9097
25.0 0.8832 0.8894 0.8953 0.9016 0.9078
30.0 0.8815 0.8877 0.8937 0.8998 0.9058
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa T/K
298.15 318.15 328.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.89190 0.90514 0.91224 0.91886
5.0 0.89015 0.90317 0.91083 0.91659
10.0 0.88833 0.90114 0.90793 0.91441
15.0 0.88762 0.89928 0.90587 0.91224
20.0 0.88495 0.89734 0.90391 0.91016
25.0 0.88331 0.89549 0.90203 0.90818
30.0 0.88175 0.89373 0.90017 0.90628
____________________________________________________________________________________
6. PVT Data 437
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15 328.15 338.15
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 0.8917 0.8982 0.9051 0.9117 0.9180
5.0 0.8899 0.8964 0.9030 0.9094 0.9158
10.0 0.8881 0.8945 0.9009 0.9073 0.9136
15.0 0.8864 0.8927 0.8990 0.9052 0.9114
20.0 0.8847 0.8909 0.8971 0.9032 0.9093
25.0 0.8831 0.8891 0.8953 0.9014 0.9074
30.0 0.8814 0.8874 0.8935 0.8995 0.9056
____________________________________________________________________________________
Comments: Additional data for poly(ethylene glycol)s can be found in 1995ZOL.
Polymer (B): poly(ethylene glycol) dimethyl ether 1998CON

Characterization: Mn/g.mol−1 = 298.2, PEGDME250, Fluka AG, Buchs, Switzerland
2.4% triethylene glycol dimethylether
12.8% tetraethylene glycol dimethylether
26.6% pentaethylene glycol dimethylether
31.8% hexaethylene glycol dimethylether
20.8% heptaethylene glycol dimethylether
5.04% octaethylene glycol dimethylether
0.5% nonaethylene glycol dimethylether
P/MPa = 0.1
T/K 283.15 293.15 303.15 313.15 323.15 333.15 343.15 353.15 363.15
Vspez/cm3g−1 0.95748 0.96571 0.97427 0.98289 0.99166 1.00049 1.00947 1.01864 1.0279
T/K 373.15 383.15 393.15 403.15 413.15 423.15
Vspez/cm3g−1 1.03759 1.04701 1.05690 1.06701 1.07738 1.08799
Polymer (B): poly(ethylene glycol) dimethyl ether 1997MAI

−1 −1
Characterization: Mn/g.mol = 290, Mw/g.mol = 313, Fluka AG, Buchs, Switzerland
P/MPa = 0.1
T/K 303.15 313.15 323.15 333.15 343.15 353.15 363.15
Vspez/cm3g−1 0.962 0.970 0.978 0.987 0.996 1.004 1.013
____________________________________________________________________________________

P/MPa = 0.1
T/K 303.15 313.15 323.15 333.15 343.15 353.15 363.15
Vspez/cm3g−1 0.931 0.939 0.946 0.954 0.962 0.969 0.977

−1 −1
Characterization: Mn/g.mol = 910, Mw/g.mol = 950, Fluka AG, Buchs, Switzerland
P/MPa = 0.1
T/K 303.15 313.15 323.15 333.15 343.15 353.15 363.15
Vspez/cm3g−1 0.916 0.924 0.931 0.939 0.946 0.953 0.961

Characterization: Mn/g.mol−1 = 1700, Mw/g.mol−1 = 1750, Fluka AG, Buchs, Switzerland
P/MPa = 0.1
T/K 303.15 313.15 323.15 333.15 343.15 353.15 363.15
Vspez/cm3g−1 0.907 0.914 0.921 0.928 0.935 0.942 0.949
Polymer (B): poly(ethylene glycol) monomethyl ether 2000LEE

____________________________________________________________________________________
P/MPa T/K
298.15 318.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.92362 0.93738 0.95320
10.0 0.91844 0.93275 0.94706
20.0 0.91458 0.92816 0.94224
30.0 0.91042 0.92379 0.93773
40.0 0.90703 0.91979 0.93275
50.0 0.90326 0.91600 0.92876
____________________________________________________________________________________
Comments: Additional data for PEGMME350 can be found in 1998LEE. Additional data for
other poly(ethylene glycol) ethers can be found in 1995ZOL.
6. PVT Data 439
____________________________________________________________________________________
Polymer (B): poly(ethylene oxide) 1987VE1, 1987VE2

Characterization: Mw/g.mol−1 = 25000 – 30000, Mw/Mn < 1.1
____________________________________________________________________________________
P/MPa T/K
353.15 363.15 373.85 388.75 393.45
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 0.92902 0.93589 0.94322 0.95012 0.95657
5.0 0.92644 0.93327 0.94056 0.94742 0.95374
10.0 0.92413 0.93075 0.93791 0.94455 0.95066
15.0 0.92191 0.92842 0.93537 0.94188 0.94787
20.0 0.91946 0.92592 0.93275 0.93914 0.94491
25.0 0.91709 0.92336 0.93015 0.93633 0.94206
30.0 0.91474 0.92090 0.92747 0.93362 0.93923
35.0 0.91232 0.91844 0.92498 0.93101 0.93650
40.0 0.90984 0.91592 0.92242 0.92842 0.93388
____________________________________________________________________________________

T/K = 293.15 P/MPa = 0.1

zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
V/cm3 basemol−1 18.229 18.530 18.841 19.381 20.861 21.552 22.770 23.561
T/K = 293.15 P/MPa = 10
zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
V/cm3 basemol−1 18.148 18.483 18.764 19.304 20.782 21.477 22.692 23.469
T/K = 293.15 P/MPa = 20
zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
V/cm3 basemol−1 18.071 18.375 18.688 19.229 20.710 21.404 22.617 23.393
T/K = 293.15 P/MPa = 30
zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
V/cm3 basemol−1 17.995 18.301 18.616 19.156 20.642 21.333 22.545 23.310
T/K = 293.15 P/MPa = 40
zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
V/cm3 basemol−1 17.992 18.228 18.542 19.085 20.572 21.264 22.474 23.246
Comments: V is given in cm3/basemol mixture calculated with MA = 18.015 g/mol and
V0A = 18.068 cm3/mol for water and M0B = 44.053 g/mol and V0B = 39.382 cm3/mol
for the repeating unit of PEO.
____________________________________________________________________________________

b-poly(ethylene oxide) triblock copolymer 1990BLO
Characterization: Mn/g.mol−1 = 3400, Mw/g.mol−1 = 3800, 19 mol% propylene oxide
17 units propylene oxide, 74 units ethylene oxide
P/MPa = 0.1
T/K 333.15 343.15 353.15 363.15
3 −1
Vspez/cm g 0.9333 0.9397 0.9468 0.9535

P/MPa = 0.1
T/K 333.15 343.15 353.15 363.15
Vspez/cm3g−1 0.9340 0.9407 0.9478 0.9547

P/MPa = 0.1
T/K 333.15 343.15 353.15 363.15
Vspez/cm3g−1 0.9303 0.9378 0.9445 0.9514

−1 −1
Characterization: Mn/g.mol = 4200, Mw/g.mol = 4600, 23 mol% propylene oxide
P/MPa = 0.1
T/K 333.15 343.15 353.15 363.15
Vspez/cm3g−1 0.93835 0.94535 0.95250 0.95910

−1 −1
P/MPa = 0.1
T/K 333.15 343.15 353.15 363.15
3 −1
Vspez/cm g 0.9560 0.9623 0.9697 0.9769
6. PVT Data 441
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 1999CHA

____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15 328.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.9975 1.0055 1.0136 1.0219 1.0300
5.0 0.9944 1.0022 1.0101 1.0182 1.0261
10.0 0.9915 0.9990 1.0068 1.0145 1.0224
15.0 0.9885 0.9959 1.0035 1.0110 1.0188
20.0 0.9857 0.9930 1.0004 1.0078 1.0154
25.0 0.9831 0.9903 0.9974 1.0046 1.0121
30.0 0.9804 0.9875 0.9945 1.0016 1.0090
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15 328.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.9997 1.0076 1.0156 1.0239 1.0319
5.0 0.9966 1.0042 1.0121 1.0200 1.0280
10.0 0.9935 1.0009 1.0087 1.0163 1.0242
15.0 0.9906 0.9978 1.0054 1.0128 1.0205
20.0 0.9878 0.9948 1.0023 1.0095 1.0169
25.0 0.9849 0.9919 0.9991 1.0063 1.0137
30.0 0.9824 0.9891 0.9961 1.0033 1.0105
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15 328.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.9999 1.0082 1.0158 1.0240 1.0322
5.0 0.9969 1.0048 1.0122 1.0202 1.0282
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15
328.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
10.0 0.9938 1.0014 1.0088 1.0166 1.0244
15.0 0.9909 0.9982 1.0055 1.0132 1.0207
20.0 0.9880 0.9952 1.0023 1.0099 1.0172
25.0 0.9852 0.9923 0.9993 1.0067 1.0138
30.0 0.9826 0.9895 0.9963 1.0036 1.0107
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 1990BLO

P/MPa = 0.1
T/K 303.15 313.15 323.15 333.15 343.15 353.15 363.15
Vspez/cm3g−1 1.0022 1.0100 1.0177 1.0253 1.0331 1.0409 1.0491

____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15
328.15 338.15
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 1.0009 1.0087 1.0164 1.0243 1.0324
5.0 0.9977 1.0052 1.0127 1.0205 1.0284
10.0 0.9946 1.0019 1.0092 1.0169 1.0246
15.0 0.9916 0.9988 1.0059 1.0135 1.0209
20.0 0.9888 0.9957 1.0027 1.0101 1.0174
25.0 0.9861 0.9929 0.9997 1.0069 1.0140
30.0 0.9834 0.9901 0.9967 1.0041 1.0108
____________________________________________________________________________________

continued
6. PVT Data 443
____________________________________________________________________________________
continued
____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15328.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 1.0014 1.0092 1.0168 1.0246 1.0325
5.0 0.9983 1.0057 1.0133 1.0208 1.0286
10.0 0.9952 1.0024 1.0097 1.0173 1.0247
15.0 0.9922 0.9993 1.0064 1.0138 1.0210
20.0 0.9894 0.9961 1.0033 1.0105 1.0176
25.0 0.9867 0.9933 1.0001 1.0073 1.0142
30.0 0.9841 0.9905 0.9971 1.0041 1.0111
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa T/K
298.15 308.15 318.15328.15 338.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 1.0016 1.0092 1.0170 1.0248 1.0327
5.0 0.9985 1.0058 1.0133 1.0209 1.0288
10.0 0.9954 1.0026 1.0098 1.0173 1.0249
15.0 0.9925 0.9994 1.0064 1.0138 1.0212
20.0 0.9895 0.9964 1.0033 1.0105 1.0177
25.0 0.9869 0.9935 1.0002 1.0075 1.0144
30.0 0.9843 0.9908 0.9973 1.0043 1.0112
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 2001LIN

____________________________________________________________________________________
P/MPa T/K
298.15 318.15 348.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 1.0021 1.0175 1.0417
10 0.9958 1.0105 1.0336
15 0.9930 1.0073 1.0297
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
P/MPa T/K
298.15 318.15 348.15
Vspez/cm3g−1
____________________________________________________________________________________
20 0.9901 1.0041 1.0260
25 0.9874 1.0010 1.0224
30 0.9846 0.9981 1.0190
35 0.9821 0.9952 1.0156
40 0.9796 0.9925 1.0125
45 0.9772 0.9898 1.0094
50 0.9748 0.9872 1.0064
____________________________________________________________________________________
Comments: Additional data for poly(propylene glycol)s can be found in 1995ZOL.
Polymer (B): poly(propylene glycol) 1999CRE

Characterization: Mw/g.mol−1 = 400, Mw/Mn < 1.5
T-range/K = 298.15 to 328.15 P-range/MPa = 0.1 to 40

Coefficients of Tait-equation for density ρ (standard deviation is 0.1 kg m−3):
{ }
ρ = ( B1 + B2T + B3T 2 ) / 1 − B4 ln ( P + B5 e− B6T ) / ( P0 + B5 e − B6T ) 
____________________________________________________________________________________
xA 10−3B1/kg m−3 B2/kg m−3 K−1 103B3/kg m−3 K−2 10B4 10−3B5/MPa 102B6/K−1
____________________________________________________________________________________
0.00000 1.2567 −0.8796 0.1104 0.6849 0.4869 0.5079
0.20105 1.2663 −0.9207 0.1560 0.8552 0.6609 0.5150
0.37701 1.2390 −0.7150 −0.1751 0.9205 0.7391 0.5148
0.61406 1.2227 −0.5678 −0.4161 0.7870 0.5934 0.4837
0.85537 1.2576 −0.7013 −0.2619 0.7695 0.7547 0.5296
0.95620 0.7619 2.6343 −5.8048 0.6260 3.4631 1.0627
0.97623 0.6962 2.8673 −5.9522 0.7450 4.3583 1.0479
0.98851 0.6397 2.9702 −5.7338 0.5937 0.6774 0.5301
1.00000 0.2871 4.6433 −7.5582 0.9362 0.1492 −0.1158
____________________________________________________________________________________
Polymer (B): poly(tetramethylene oxide) 1983SHA

Characterization: Mn/g.mol−1 = 650, Quaker Oats Corporation
P/MPa = 0.1
T/K 303.15 308.15 313.15 318.15 321.35 323.15
Vspez/cm3g−1 1.01276 1.01682 1.02722 1.02522 1.02792 1.02946
6. PVT Data 445
____________________________________________________________________________________

P/MPa = 0.1
T/K 303.15 308.15 313.15 318.15 321.35 323.15
Vspez/cm3g−1 1.01688 1.02072 1.02443 1.02822 1.03090 1.03208

P/MPa = 0.1
T/K 303.15 308.15 313.15 318.15 321.35 323.15
Vspez/cm3g−1 1.01838 1.02197 1.02585 1.02953 1.03200 1.03338
Polymer (B): poly(vinyl methyl ether) 2000VIC

Characterization: Mη/g.mol−1 = 32500, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
P/MPa = 0.1
T/K 303.15 313.15 323.15 333.15 343.15 353.15 363.15 373.15
Vspez/cm3g−1 0.9828 0.9888 0.9947 1.0004 1.0067 1.0126 1.0189 1.0254
T/K 383.15 393.15 403.15 413.15 423.15
Vspez/cm3g−1 1.0315 1.0377 1.0438 1.0500 1.0561
Polymer (B): poly(vinyl methyl ether) 1993JAN

____________________________________________________________________________________
P/MPa T/K
311.5 340.3 353.5 374.5 394.5 415.5
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 0.9671 0.9861 0.9935 1.0053 1.0189 1.0344
5.0 0.9646 0.9830 0.9902 1.0016 1.0149 1.0299
10.0 0.9621 0.9799 0.9870 0.9981 1.0110 1.0257
15.0 0.9597 0.9770 0.9838 0.9946 1.0074 1.0214
20.0 0.9574 0.9742 0.9809 0.9913 1.0038 1.0174
25.0 0.9550 0.9715 0.9782 0.9883 1.0005 1.0139
30.0 0.9528 0.9687 0.9754 0.9853 0.9973 1.0105
35.0 0.9506 0.9662 0.9729 0.9823 0.9939 1.0070
40.0 0.9485 0.9637 0.9703 0.9795 0.9909 1.0034
45.0 0.9485 0.9612 0.9678 0.9768 0.9879 1.0004
50.0 0.9443 0.9589 0.9654 0.9742 0.9850 0.9971
55.0 0.9423 0.9567 0.9631 0.9717 0.9823 0.9943
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
P/MPa T/K
311.5 340.3 353.5 374.5 394.5 415.5
3 −1
Vspez/cm g
____________________________________________________________________________________
60.0 0.9404 0.9545 0.9608 0.9692 0.9796 0.9915
65.0 0.9385 0.9523 0.9586 0.9667 0.9771 0.9887
70.0 0.9366 0.9501 0.9564 0.9645 0.9747 0.9859
75.0 0.9348 0.9481 0.9545 0.9622 0.9721 0.9833
80.0 0.9329 0.9462 0.9523 0.9600 0.9699 0.9808
85.0 0.9313 0.9442 0.9504 0.9579 0.9677 0.9784
90.0 0.9296 0.9423 0.9484 0.9558 0.9653 0.9760
95.0 0.9279 0.9404 0.9465 0.9539 0.9631 0.9736
100.0 0.9263 0.9387 0.9447 0.9518 0.9609 0.9714
105.0 0.9248 0.9368 0.9429 0.9499 0.9590 0.9694
110.0 0.9232 0.9351 0.9412 0.9480 0.9571 0.9671
115.0 0.9217 0.9335 0.9394 0.9461 0.9550 0.9650
120.0 0.9202 0.9318 0.9379 0.9443 0.9531 0.9630
____________________________________________________________________________________
Comments: Additional data for poly(vinyl methyl ether) can be found in 1995ZOL.
Polymer (B): tetra(ethylene glycol) dimethyl ether 2000COM

Characterization: M/g.mol−1 = 222.28, Aldrich Chem. Co., Inc., Milwaukee, WI, USA
____________________________________________________________________________________
P/MPa T/K
278.15 283.15 293.15 303.15 313.15 323.15 328.15
3 −1
Vspez/cm g
____________________________________________________________________________________
1 0.97510 0.97965 0.98878 0.99794 1.00719 1.01658 1.02133
2 0.97455 0.97909 0.98816 0.99728 1.00647 1.01580 1.02052
3 0.97401 0.97853 0.98756 0.99662 1.00576 1.01503 1.01973
4 0.97348 0.97798 0.98695 0.99597 1.00505 1.01426 1.01894
5 0.97295 0.97742 0.98635 0.99531 1.00435 1.01351 1.01815
6 0.97242 0.97687 0.98576 0.99466 1.00364 1.01276 1.01738
7 0.97189 0.97632 0.98515 0.99402 1.00295 1.01201 1.01660
8 0.97137 0.97577 0.98457 0.99338 1.00227 1.01127 1.01584
9 0.97085 0.97524 0.98398 0.99274 1.00158 1.01054 1.01508
10 0.97034 0.97470 0.98340 0.99211 1.00090 1.00981 1.01432
11 0.96983 0.97417 0.98282 0.99149 1.00023 1.00908 1.01358
12 0.96932 0.97363 0.98224 0.99087 0.99956 1.00837 1.01284
____________________________________________________________________________________
6. PVT Data 447
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa T/K
293.15 303.15 313.15 323.15 333.15 343.15 353.15 363.15 373.15
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 0.9889 0.9982 1.0076 1.0170 1.0267 1.0365 1.0465 1.0561 1.0667
5 0.9860 0.9950 1.0041 1.0134 1.0227 1.0323 1.0419 1.0512 1.0612
10 0.9831 0.9919 1.0008 1.0098 1.0190 1.0282 1.0375 1.0464 1.0562
15 0.9803 0.9888 0.9975 1.0063 1.0152 1.0242 1.0332 1.0419 1.0514
20 0.9776 0.9859 0.9945 1.0030 1.0118 1.0204 1.0292 1.0375 1.0469
25 0.9749 0.9831 0.9915 0.9999 1.0084 1.0168 1.0254 1.0336 1.0424
30 0.9724 0.9804 0.9885 0.9968 1.0050 1.0133 1.0217 1.0297 1.0383
35 0.9699 0.9778 0.9858 0.9937 1.0018 1.0100 1.0182 1.0259 1.0342
40 0.9675 0.9752 0.9831 0.9910 0.9988 1.0068 1.0147 1.0222 1.0305
45 0.9652 0.9727 0.9803 0.9880 0.9958 1.0037 1.0115 1.0188 1.0268
50 0.9629 0.9703 0.9779 0.9855 0.9930 1.0007 1.0084 1.0156 1.0234
55 0.9606 0.9679 0.9754 0.9828 0.9903 0.9977 1.0053 1.0121 1.0199
60 0.9584 0.9657 0.9730 0.9802 0.9876 0.9950 1.0024 1.0091 1.0165
____________________________________________________________________________________
Polymer (B): tri(ethylene glycol) dimethyl ether 2000COM

____________________________________________________________________________________
P/MPa T/K
278.15 283.15 293.15 303.15 313.15 323.15 328.15
3 −1
Vspez/cm g
____________________________________________________________________________________
1 1.00007 1.00484 1.01458 1.02455 1.03473 1.04508 1.05031
2 0.99947 1.00421 1.01389 1.02380 1.03391 1.04420 1.04940
3 0.99887 1.00358 1.01321 1.02306 1.03311 1.04332 1.04848
4 0.99827 1.00296 1.01254 1.02233 1.03231 1.04246 1.04758
5 0.99768 1.00235 1.01186 1.02160 1.03151 1.04160 1.04669
6 0.99709 1.00173 1.01119 1.02088 1.03074 1.04075 1.04581
7 0.99650 1.00112 1.01053 1.02016 1.02995 1.03990 1.04492
8 0.99593 1.00052 1.00988 1.01944 1.02918 1.03907 1.04406
9 0.99535 0.99992 1.00922 1.01873 1.02842 1.03824 1.04320
10 0.99478 0.99932 1.00858 1.01803 1.02765 1.03742 1.04234
11 0.99420 0.99873 1.00793 1.01734 1.02690 1.03660 1.04149
12 0.99364 0.99814 1.00729 1.01664 1.02616 1.03580 1.04066
____________________________________________________________________________________
____________________________________________________________________________________
6.2. Excess volumes and/or densities of aqueous polymer solutions

Lot 21072, Serva, Heidelberg, Germany
T/K = 293.15
wB 0.0065 0.0124 0.0249 0.0501 0.0999 0.2505 0.3010
ρ/g cm−3 1.0008 1.0031 1.0080 1.0183 1.0391 1.1067 1.1307
T/K = 313.15
wB 0.0065 0.0124 0.0249 0.0501 0.0999 0.2505 0.3010
ρ/g cm−3 0.9950 0.9971 1.0020 1.0120 1.0330 1.0995 1.1236

T/K = 293.15
wB 0.0000 0.0062 0.0100 0.0121 0.0200 0.0242 0.0500 0.1001 0.1501
ρ/g cm−3 0.9982 1.0015 1.0022 1.0029 1.0061 1.0075 1.0182 1.0391 1.0608
wB 0.1979 0.3002 0.3499
ρ/g cm−3 1.0822 1.1310 1.1544
T/K = 313.15
wB 0.0000 0.0062 0.0100 0.0121 0.0200 0.0242 0.0500 0.1001 0.1501
ρ/g cm−3 0.9922 0.9956 0.9961 0.9975 1.0001 1.0015 1.0121 1.0326 1.0540
wB 0.1979 0.3002 0.3499
ρ/g cm−3 1.0751 1.1243 1.1473

T/K = 293.15
wB 0.0038 0.0074 0.0147 0.0505 0.1003 0.2496 0.2992
ρ/g cm−3 0.9998 1.0010 1.0039 1.0186 1.0394 1.1062 1.1300
T/K = 313.15
wB 0.0038 0.0074 0.0147 0.0505 0.1003 0.2496 0.2992
ρ/g cm−3 0.9932 0.9951 0.9974 1.0121 1.0327 1.0991 1.1229
6. PVT Data 449
____________________________________________________________________________________

T/K = 293.15
wB 0.0023 0.0044 0.0089 0.0491 0.0998 0.2500 0.3001
−3
ρ/g cm 0.9991 0.9999 1.0017 1.0178 1.0390 1.1062 1.1303
T/K = 313.15
wB 0.0023 0.0044 0.0089 0.0491 0.0998 0.2500 0.3001
−3
ρ/g cm 0.9933 0.9941 0.9956 1.0117 1.0326 1.0993 1.1233

T/K = 293.15
wB 0.0010 0.0030 0.0102 0.0470 0.1019 0.1999 0.3327
−3
ρ/g cm 0.9994 0.9998 1.0022 1.0171 1.0404 1.0840 1.1468
T/K = 313.15
wB 0.0010 0.0030 0.0102 0.0470 0.1019 0.1999 0.3327
−3
ρ/g cm 0.9934 0.9937 0.9959 1.0130 1.0343 1.0762 1.1420
Polymer (B): dextran 1996CES

Characterization: Mw/g.mol−1 = 250000, Sigma Chemical Co., St. Louis, MO, USA
T/K = 293.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200 0.250
ρ/g cm−3 0.9982 1.0022 1.0062 1.0184 1.0394 1.0612 1.0839 1.1076
T/K = 298.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200 0.250
ρ/g cm−3 0.9970 1.0010 1.0050 1.0172 1.0381 1.0597 1.0823 1.1058
T/K = 303.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200 0.250
ρ/g cm−3 0.9957 0.9996 1.0036 1.0157 1.0365 1.0581 1.0804 1.1039
T/K = 308.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200 0.250
ρ/g cm−3 0.9941 0.9980 1.0019 1.0140 1.0348 1.0562 1.0785 1.1018
continued
____________________________________________________________________________________
continued
T/K = 313.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200 0.250
ρ/g cm−3 0.9923 0.9962 1.0001 1.0122 1.0329 1.0542 1.0766 1.0996
T/K = 318.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200 0.250
ρ/g cm−3 0.9903 0.9942 0.9981 1.0101 1.0308 1.0520 1.0744 1.0974
T/K = 323.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200 0.250
ρ/g cm−3 0.9880 0.9920 0.9959 1.0079 1.0285 1.0498 1.0721 1.0949
Polymer (B): ethylene oxide/propylene oxide copolymer 1991LOU

Characterization: Mw/g.mol−1 = 32500, 80 mol% ethylene oxide
wB = 0.4
T/K 280.15 288.15 297.95 303.15 319.65
VE/cm3g−1 −0.0265 −0.0320 −0.0325 −0.030 −0.025
Comments: The values were taken from Figs. 9 and 10 in the original source.
Polymer (B): poly(1,3-dioxolane) 1992BEN

T/K = 293.15 T/K = 298.15
wB 0.07 0.10 0.20 wB 0.07 0.10 0.20
VBE/cm3g−1 −0.003 −0.009 −0.022 VBE/cm3g−1 −0.023 −0.026 −0.031
T/K = 303.15 T/K = 313.15
wB 0.07 0.10 0.20 wB 0.07 0.10 0.20
VBE/cm3g−1 −0.032 −0.032 −0.033 VBE/cm3g−1 −0.039 −0.037 −0.034
T/K = 323.15 T/K = 333.15
wB 0.07 0.10 0.20 wB 0.07 0.10 0.20
VBE/cm3g−1 −0.038 −0.034 −0.037 VBE/cm3g−1 −0.032 −0.030 −0.030
T/K = 343.15
wB 0.07 0.10 0.20
VBE/cm3g−1 −0.014 −0.017 −0.018
Comments: The data were taken from Fig. 10 in the original source.
6. PVT Data 451
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1985SIK

T/K 288.15 298.15 308.15 423.15
VBE∞/cm3g−1 −0.0365 −0.0364 −0.0363 −0.0362
Polymer (B): poly(ethylene glycol) 1998KIR

T/K = 298.15
wB 0.0763 0.1095 0.1455 0.1868 0.2347 0.3048 0.3462 0.5921
ρ/g cm−3 1.00801 1.01243 1.01704 1.02202 1.02748 1.03484 1.03888 1.05862
VE/cm3g−1 −0.0001 −0.0002 −0.0004 −0.0006 −0.0009 −0.0013 −0.0016 −0.0026

T/K = 298.15
wB 0.0477 0.0729 0.0978 0.1588 0.2917 0.3624 0.4826 0.6801
ρ/g cm−3 1.00414 1.00768 1.01110 1.01893 1.03399 1.04100 1.05149 1.06535
VE/cm3g−1 −0.0001 −0.0001 −0.0002 −0.0004 −0.0012 −0.0017 −0.0024 −0.0030

T/K = 300.15
wB 0.0500 0.0980 0.1501 0.1980 0.2514 0.3005 0.3451 0.3884
VE/cm3g−1 −0.0017 −0.0042 −0.0070 −0.0093 −0.0118 −0.0139 −0.0155 −0.0170
wB 0.4998 0.6000 0.6922 0.7987 0.8999
VE/cm3g−1 −0.0213 −0.0224 −0.0213 −0.0168 −0.0090
T/K = 310.15
wB 0.0500 0.0980 0.1501 0.1980 0.2514 0.3005 0.3451 0.3884
VE/cm3g−1 −0.0011 −0.0037 −0.0054 −0.0083 −0.0109 −0.0124 −0.0145 −0.0159
wB 0.4998 0.6000 0.6922 0.7987 0.8999
VE/cm3g−1 −0.0206 −0.0217 −0.0210 −0.0180 −0.0099
T/K = 313.15
wB 0.0500 0.0980 0.1501 0.1980 0.2514 0.3005 0.3451 0.3884
VE/cm3g−1 −0.0016 −0.0041 −0.0061 −0.0090 −0.0116 −0.0130 −0.0152 −0.0167
wB 0.4998 0.6000 0.6922 0.7987 0.8999
VE/cm3g−1 −0.0209 −0.0218 −0.0210 −0.0171 −0.0098
continued
____________________________________________________________________________________
continued
T/K = 318.15
wB 0.0500 0.0980 0.1501 0.1980 0.2514 0.3005 0.3451 0.3884
VE/cm3g−1 −0.0012 −0.0038 −0.0065 −0.0082 −0.0109 −0.0128 −0.0145 −0.0157
wB 0.4998 0.6000 0.6922 0.7987 0.8999
VE/cm3g−1 −0.0200 −0.0209 −0.0204 −0.0168 −0.0094
T/K = 323.15
wB 0.0500 0.0980 0.1501 0.1980 0.2514 0.3005 0.3451 0.3884
VE/cm3g−1 −0.0010 −0.0038 −0.0061 −0.0081 −0.0104 −0.0124 −0.0146 −0.0157
wB 0.4998 0.6000 0.6922 0.7987 0.8999
VE/cm3g−1 −0.0194 −0.0208 −0.0202 −0.0168 −0.0100
T/K = 328.15
wB 0.0500 0.0980 0.1501 0.1980 0.2514 0.3005 0.3451 0.3884
VE/cm3g−1 −0.0008 −0.0045 −0.0064 −0.0086 −0.0105 −0.0127 −0.0148 −0.0155
wB 0.4998 0.6000 0.6922 0.7987 0.8999
VE/cm3g−1 −0.0203 −0.0206 −0.0198 −0.0169 −0.0101
Polymer (B): poly(ethylene glycol) 1991MUE

T/K = 298.05
wB 0.1022 0.3119 0.3979 0.4985 0.6005 0.7007 0.7997 0.9004
VE/cm3g−1 −0.00460 −0.01481 −0.01874 −0.02234 −0.02392 −0.02247 −0.01769 −0.00982
T/K = 308.05
wB 0.1022 0.3119 0.3979 0.4985 0.6005 0.7007 0.7997 0.9004
VE/cm3g−1 −0.00427 −0.01402 −0.01771 −0.02110 −0.02259 −0.02131 −0.01688 −0.00944
T/K = 318.15
wB 0.0996 0.2993 0.4008 0.4999 0.5986 0.6921 0.8009 0.8821
VE/cm3g−1 −0.00425 −0.01313 −0.01716 −0.02020 −0.02156 −0.02055 −0.01611 −0.01062
T/K = 328.15
wB 0.0996 0.2993 0.4008 0.4999 0.5986 0.6921 0.8009 0.8821
VE/cm3g−1 −0.00422 −0.01268 −0.01653 −0.01936 −0.02064 −0.01955 −0.01549 −0.01025

T/K 287.75 297.95 308.15
VBE∞/cm3g−1 −0.0433 −0.0435 −0.0417
6. PVT Data 453
____________________________________________________________________________________

T/K 298.15 308.15 423.15
VBE∞/cm3g−1 −0.0467 −0.0459 −0.0460
Polymer (B): poly(ethylene glycol) 1978LEP

E∞ 3 −1
T/K = 298.15 VB /cm g −0.0479

T/K = 298.15
wB 0.0491 0.0824 0.1263 0.1723 0.2713 0.3241 0.4353 0.5555
ρ/g cm−3 1.00448 1.00926 1.01524 1.02115 1.03265 1.03820 1.04863 1.05825
VE/cm3g−1 −0.0000 −0.0001 −0.0003 −0.0006 −0.0012 −0.0015 −0.0021 −0.0026

T/K = 298.15
wB 0.0800 0.1267 0.1843 0.2429 0.3396 0.4518 0.6754 0.8132
ρ/g cm−3 1.00903 1.01546 1.02281 1.02973 1.04002 1.05045 1.06720 1.07521
VE/cm3g−1 −0.0001 −0.0002 −0.0005 −0.0008 −0.0013 −0.0019 −0.0026 −0.0023
Polymer (B): poly(ethylene glycol) 1978LEP

E∞ 3 −1
T/K = 298.15 VB /cm g −0.0488

−1
Characterization: Mw/g.mol = 1000, Sigma Chemical Co., St. Louis, MO, USA
T/K = 277
wB 0.00 0.10 0.20 0.30 0.040 0.50
ρ/g cm−3 1.00000 1.0141 1.0312 1.0485 1.0665 1.0841
continued
____________________________________________________________________________________
continued
T/K = 298
wB 0.00 0.10 0.20 0.30 0.040 0.50
ρ/g cm−3 0.99707 1.0192 1.0382 1.0584 1.0780 1.0977

T/K = 298.15
wB 0.1034 0.1162 0.1650 0.2132 0.2809 0.3609 0.3983 0.6155
ρ/g cm−3 1.01225 1.01411 1.02049 1.02638 1.03406 1.04227 1.04581 1.06332
VE/cm3g−1 −0.0002 −0.0002 −0.0004 −0.0006 −0.0009 −0.0014 −0.0015 −0.0023

T/K = 298.15
wB 0.1055 0.1668 0.2437 0.2944 0.4282 0.5473 0.6496 0.7960
ρ/g cm−3 1.01277 1.02088 1.03016 1.03578 1.04888 1.05880 1.06617 1.07521
VE/cm3g−1 −0.0001 −0.0003 −0.0006 −0.0009 −0.0014 −0.0019 −0.0021 −0.0020

T/K = 298.15
wB 0.0701 0.1116 0.1915 0.2432 0.3065 0.3969 0.6036 0.7074
ρ/g cm−3 1.00777 1.01364 1.02409 1.03028 1.03729 1.04632 1.06332 1.07010
VE/cm3g−1 −0.0001 −0.0002 −0.0006 −0.0009 −0.0013 −0.0018 −0.0027 −0.0026

T/K = 298.15
wB 0.0107 0.0204 0.0311 0.0403 0.0501 0.0596 0.0698 0.0797 0.0910
ρ/g cm−3 0.99880 1.00040 1.00217 1.00369 1.00532 1.00694 1.00862 1.01030 1.01225
wB 0.1015 0.1508 0.1992 0.2502 0.3051
ρ/g cm−3 1.01401 1.02253 1.03108 1.04025 1.05029
T/K = 308.15
wB 0.0107 0.0204 0.0311 0.0403 0.0501 0.0596 0.0698 0.0797 0.0910
ρ/g cm−3 0.99573 0.99727 0.99897 1.00042 1.00200 1.00352 1.00513 1.00679 1.00864
continued
6. PVT Data 455
____________________________________________________________________________________
continued
wB 0.1015 0.1508 0.1992 0.2502 0.3051
ρ/g cm−3 1.01029 1.01847 1.02662 1.03536 1.04495
T/K = 318.15
wB 0.0107 0.0204 0.0311 0.0403 0.0501 0.0596 0.0698 0.0797 0.0910
ρ/g cm−3 0.99182 0.99328 0.99490 0.99630 0.99778 0.99924 1.00075 1.00234 1.00403
wB 0.1015 0.1508 0.1992 0.2502 0.3051
ρ/g cm−3 1.00575 1.01345 1.02148 1.02970 1.03910

T/K = 298.15
wB 0.0723 0.1206 0.1635 0.2096 0.3065 0.4166 0.6174 0.7373
ρ/g cm−3 1.00817 1.01497 1.02065 1.02638 1.03735 1.04821 1.06447 1.07236
VE/cm3g−1 −0.0001 −0.0002 −0.0003 −0.0005 −0.0009 −0.0014 −0.0020 −0.0021

T/K = 277
wB 0.00 0.10 0.20 0.30 0.040 0.50
−3
ρ/g cm 1.00000 1.0194 1.0383 1.0580 1.0803 1.0995
T/K = 298
wB 0.00 0.10 0.20 0.30 0.040 0.50
−3
ρ/g cm 0.99707 1.0140 1.0313 1.0482 1.0669 1.0849

T/K = 298.15
wB 0.0668 0.1124 0.1705 0.2492 0.3361 0.3793 0.4321 0.5383
ρ/g cm−3 1.00742 1.01392 1.02163 1.03117 1.04062 1.04495 1.04990 1.05894
VE/cm3g−1 −0.0001 −0.0001 −0.0003 −0.0006 −0.0010 −0.0013 −0.0015 −0.0020

T/K = 298.15
continued
____________________________________________________________________________________
continued
wB 0.0100 0.0202 0.0301 0.0382 0.0500 0.0598 0.0699 0.0790 0.0892
ρ/g cm−3 0.99866 1.00033 1.00195 1.00329 1.00525 1.00689 1.00859 1.01013 1.01187
wB 0.0997 0.1487 0.1956 0.2450 0.2974
ρ/g cm−3 1.01367 1.02215 1.03042 1.03934 1.04899
T/K = 308.15
wB 0.0100 0.0202 0.0301 0.0382 0.0500 0.0598 0.0699 0.0790 0.0892
ρ/g cm−3 0.99561 0.99722 0.99879 1.00008 1.00197 1.00354 1.00517 1.00666 1.00832
wB 0.0997 0.1487 0.1956 0.2450 0.2974
−3
ρ/g cm 1.01003 1.01812 1.02600 1.03445 1.04355
T/K = 318.15
wB 0.0100 0.0202 0.0301 0.0382 0.0500 0.0598 0.0699 0.0790 0.0892
ρ/g cm−3 0.99174 0.99329 0.99481 0.99605 0.99787 0.99938 1.00095 1.00237 1.00394
wB 0.0997 0.1487 0.1956 0.2450 0.2974
ρ/g cm−3 1.00558 1.01330 1.02078 1.02873 1.03735

E 3 −1
T/K = 338.15 wB = 0.70 V /cm g −0.021
Comments: The minimum was taken from Fig. 4 in the original source.

T/K = 298.15
wB 0.0973 0.1096 0.1732 0.2953 0.3452 0.4526 0.5572 0.6209
ρ/g cm−3 1.01186 1.01358 1.02205 1.03645 1.04169 1.05191 1.06064 1.06537
VE/cm3g−1 −0.0001 −0.0001 −0.0003 −0.0009 −0.0011 −0.0016 −0.0021 −0.0023
Polymer (B): poly(ethylene glycol) 1995HAS, 1998KAN

T/K = 278.15
wB 0.0000 0.0500 0.1004 0.2005 0.3003 0.3974 0.4965
ρ/g cm−3 1.0000 1.0090 1.0185 1.0381 1.0586 1.0797 1.0993
continued
6. PVT Data 457
____________________________________________________________________________________
continued
T/K = 293.15
wB 0.0000 0.0500 0.1004 0.2005 0.3003 0.3974 0.4965
ρ/g cm−3 0.9982 1.0066 1.0153 1.0331 1.0521 1.0709 1.0893
T/K = 313.15
wB 0.0000 0.0500 0.1004 0.2005 0.3003 0.3974 0.4965 0.5996
ρ/g cm−3 0.9922 1.0009 1.0088 1.0252 1.0422 1.0590 1.0755 1.0898
T/K = 333.15
wB 0.0000 0.0500 0.1004 0.2005 0.3003 0.3974 0.4965 0.5996
ρ/g cm−3 0.9832 0.9910 0.9984 1.0139 1.0307 1.0453 1.0608 1.0733

T/K = 277
wB 0.00 0.10 0.20 0.30 0.040 0.50
ρ/g cm−3 1.00000 1.0200 1.0392 1.0597 1.0801 1.1007
T/K = 298
wB 0.00 0.10 0.20 0.30 0.040 0.50
ρ/g cm−3 0.99707 1.0148 1.0317 1.0487 1.0671 1.0862

T/K = 298.15
wB 0.1074 0.1859 0.2179 0.2890 0.3622 0.3840 0.4734 0.5631
ρ/g cm−3 1.01342 1.02393 1.02789 1.03610 1.04389 1.04606 1.05431 1.06174
VE/cm3g−1 −0.0002 −0.0004 −0.0006 −0.0009 −0.0013 −0.0014 −0.0018 −0.0022

T/K = 298.15
wB 0.0633 0.1155 0.1733 0.2694 0.2768 0.3879 0.4971 0.5728
ρ/g cm−3 1.00707 1.01461 1.02241 1.03413 1.03499 1.04668 1.05662 1.06276
VE/cm3g−1 −0.0001 −0.0002 −0.0004 −0.0008 −0.0009 −0.0015 −0.0020 −0.0022
____________________________________________________________________________________

T/K = 298.15
wB 0.0922 0.1106 0.1763 0.2090 0.2525 0.3559 0.4291 0.5397
ρ/g cm−3 1.01128 1.01391 1.02277 1.02689 1.03213 1.04337 1.05043 1.05982
VE/cm3g−1 −0.0002 −0.0002 −0.0005 −0.0006 −0.0009 −0.0015 −0.0018 −0.0021

T/K = 298.15
wB 0.0527 0.1161 0.1648 0.1765 0.2115 0.3022 0.4060 0.5548
ρ/g cm−3 1.00543 1.01470 1.02129 1.02280 1.02723 1.03772 1.04825 1.06105
VE/cm3g−1 −0.0000 −0.0002 −0.0003 −0.0004 −0.0006 −0.0010 −0.0014 −0.0019
Polymer (B): poly(ethylene glycol) 1996CES

Characterization: Mw/g.mol−1 = 20000, Merck-Schuchard, Hohenbrunn, Germany
T/K = 293.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200
ρ/g cm−3 0.9982 0.9999 1.0016 1.0067 1.0152 1.0241 1.0331
T/K = 298.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200
ρ/g cm−3 0.9970 0.9988 1.0005 1.0054 1.0138 1.0226 1.0316
T/K = 303.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200
ρ/g cm−3 0.9957 0.9974 0.9990 1.0039 1.0121 1.0206 1.0294
T/K = 308.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200
ρ/g cm−3 0.9940 0.9958 0.9973 1.0021 1.0102 1.0185 1.0270
T/K = 313.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200
ρ/g cm−3 0.9922 0.9939 0.9955 1.0001 1.0081 1.0162 1.0246
T/K = 318.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200
ρ/g cm−3 0.9902 0.9919 0.9934 0.9980 1.0058 1.0137 1.0219
T/K = 323.15
wB 0.000 0.010 0.020 0.050 0.100 0.150 0.200
ρ/g cm−3 0.9880 0.9895 0.9910 0.9956 1.0033 1.0112 1.0192
6. PVT Data 459
____________________________________________________________________________________

T/K = 298.15
wB 0.0493 0.0970 0.1287 0.1833 0.2516 0.4163 0.4727 0.5623
ρ/g cm−3 1.00493 1.01207 1.01656 1.02383 1.03222 1.04946 1.05447 1.06165
VE/cm3g−1 −0.0000 −0.0002 −0.0003 −0.0005 −0.0009 −0.0016 −0.0017 −0.0017
Polymer (B): poly(ethylene glycol) 1995HAS, 1998KAN

T/K = 278.15
wB 0.0493 0.1001 0.2021 0.3005 0.3995
ρ/g cm−3 1.0091 1.0187 1.0390 1.0584 1.0797
T/K = 293.15
wB 0.0493 0.1001 0.2021 0.3005 0.3995
ρ/g cm−3 1.0067 1.0155 1.0346 1.0523 1.0720
T/K = 313.15
wB 0.0493 0.1001 0.2021 0.3005 0.3995 0.5035
−3
ρ/g cm 1.0010 1.0089 1.0260 1.0432 1.0585 1.0777
T/K = 333.15
wB 0.0493 0.1001 0.2021 0.3005 0.3995 0.5035 0.5957
ρ/g cm−3 0.9910 0.9987 1.0148 1.0312 1.0444 1.0645 1.0747

wB 0.0093 0.0186 0.0338 0.0616 0.0712 0.1267 0.1576 0.2190 0.2994
wC 0.0531 0.0474 0.0393 0.0314 0.0238 0.0150 0.0118 0.0061 0.0045
T/K = 298.15
ρ/g cm−3 1.05002 1.04629 1.04095 1.03784 1.03177 1.03280 1.03512 1.04047 1.05371
T/K = 308.15
ρ/g cm−3 1.04632 1.04258 1.03719 1.03406 1.02801 1.02801 1.03076 1.03584 1.04838
T/K = 318.15
ρ/g cm−3 1.04195 1.03838 1.03314 1.02981 1.02377 1.02423 1.02615 1.03080 1.04276
____________________________________________________________________________________

wB 0.0188 0.0308 0.0554 0.0691 0.0837 0.1247 0.1583 0.2115 0.2897
wC 0.0478 0.0382 0.0277 0.0225 0.0194 0.0142 0.0094 0.0064 0.0060
T/K = 298.15
ρ/g cm−3 1.04660 1.03929 1.03324 1.03055 1.02981 1.03138 1.03344 1.03948 1.05348
T/K = 308.15
ρ/g cm−3 1.04287 1.03553 1.02943 1.02680 1.02607 1.02729 1.02926 1.03490 1.04813
T/K = 318.15
ρ/g cm−3 1.03871 1.03135 1.02521 1.02257 1.02181 1.02272 1.02462 1.02992 1.04227

wB 0.0104 0.0325 0.0529 0.0688 0.0812 0.1001 0.1514 0.2017 0.2965
wC 0.1408 0.1175 0.1019 0.0850 0.0774 0.0580 0.0408 0.0381 0.0306
T/K = 298.15
ρ/g cm−3 1.10951 1.09446 1.08585 1.07481 1.07125 1.05885 1.05464 1.06146 1.07294
T/K = 308.15
ρ/g cm−3 1.10508 1.09024 1.08155 1.07056 1.06654 1.05453 1.05030 1.05672 1.06736
T/K = 318.15
ρ/g cm−3 1.10020 1.08553 1.07683 1.06577 1.06211 1.04980 1.04509 1.05247 1.06136

wB 0.0102 0.0294 0.0502 0.0705 0.0902 0.0998 0.1488 0.2021 0.2481
wC 0.1235 0.1180 0.1082 0.0990 0.0894 0.0871 0.0773 0.0638 0.0573
T/K = 298.15
ρ/g cm−3 1.09456 1.09443 1.09011 1.08676 1.08217 1.08176 1.08336 1.08246 1.08581
T/K = 308.15
ρ/g cm−3 1.09053 1.08952 1.08587 1.08236 1.07776 1.07746 1.07860 1.07752 1.08030
T/K = 318.15
ρ/g cm−3 1.08677 1.08720 1.08300 1.07881 1.07469 1.07456 1.07534 1.07406 1.07560
6. PVT Data 461
____________________________________________________________________________________

Salt (D): sodium dihydrogen phosphate NaH2PO4 7558-80-7
wB 0.0099 0.0241 0.0432 0.0689 0.0905 0.1192 0.1609 0.2058 0.2984
wC 0.0581 0.0524 0.0467 0.0298 0.0244 0.0187 0.0144 0.0089 0.0067
wD 0.0306 0.0276 0.0246 0.0157 0.0128 0.0099 0.0076 0.0047 0.0036
T/K = 298.15
ρ/g cm−3 1.07870 1.07302 1.06836 1.04916 1.04543 1.04248 1.04384 1.04439 1.05870
T/K = 308.15
ρ/g cm−3 1.07475 1.06911 1.06430 1.04528 1.04139 1.03844 1.03949 1.03985 1.05346
T/K = 318.15
ρ/g cm−3 1.07475 1.06911 1.06430 1.04528 1.04139 1.03844 1.03949 1.03985 1.05346

Salt (D): sodium dihydrogen phosphate NaH2PO4 7558-80-7
wB 0.0088 0.0219 0.0411 0.0655 0.0883 0.1103 0.1626 0.2235 0.3090
wC 0.0552 0.0499 0.0342 0.0313 0.0260 0.0182 0.0118 0.0074 0.0061
wD 0.0290 0.0262 0.0180 0.0165 0.0137 0.0096 0.0062 0.0039 0.0032
T/K = 298.15
ρ/g cm−3 1.07435 1.06906 1.05034 1.05089 1.04760 1.04055 1.04086 1.04570 1.05947
T/K = 308.15
ρ/g cm−3 1.07040 1.06529 1.04652 1.04700 1.04356 1.03657 1.03651 1.04097 1.05407
T/K = 318.15
ρ/g cm−3 1.06582 1.06081 1.04206 1.04244 1.03872 1.03189 1.03159 1.03568 1.04787

wB 0.0195 0.0398 0.0601 0.0808 0.1006 0.1502 0.2008 0.2517 0.3020
wC 0.2143 0.2052 0.1880 0.1645 0.1404 0.1007 0.0649 0.0442 0.0357
T/K = 298.15
ρ/g cm−3 1.16518 1.16089 1.14965 1.13510 1.11943 1.09750 1.07850 1.07328 1.07620
continued
____________________________________________________________________________________
continued
T/K = 308.15
ρ/g cm−3 1.15863 1.15448 1.14358 1.12920 1.11346 1.09211 1.07340 1.06814 1.07070
T/K = 318.15
ρ/g cm−3 1.15217 1.14811 1.13693 1.12312 1.10745 1.08620 1.06768 1.06220 1.06454

wB 0.0203 0.0401 0.0614 0.0799 0.0967 0.1497 0.1989 0.2432 0.2987
wC 0.1717 0.1408 0.1035 0.0859 0.0873 0.0547 0.0363 0.0313 0.0185
T/K = 298.15
ρ/g cm−3 1.13004 1.10922 1.08331 1.07392 1.07778 1.06286 1.05793 1.06216 1.06279
T/K = 308.15
ρ/g cm−3 1.12422 1.10378 1.07838 1.06914 1.07287 1.05790 1.05321 1.05721 1.05751
T/K = 318.15
ρ/g cm−3 1.12071 1.10034 1.07542 1.06594 1.06957 1.05475 1.04988 1.05369 1.05363

Characterization: Mw/g.mol−1 = 3500-4500, Merck KGaA, Darmstadt, Germany
T/K = 288.15
wB 0.12 0.12 0.12 0.12 0.12 0.12 0.12 0.12
wC 0.03 0.06 0.09 0.12 0.15 0.18 0.21 0.24
ρ/g cm−3 1.04101 1.06219 1.08381 1.10582 1.12853 1.15169 1.17559 1.20018
VE/cm3mol−1 0.025 0.069 0.123 0.190 0.265 0.354 0.453 0.565
wB 0.03 0.06 0.09 0.15 0.18 0.21 0.24 0.06
wC 0.12 0.12 0.12 0.12 0.12 0.12 0.12 0.06
ρ/g cm−3 1.08954 1.09498 1.10040 1.11146 1.11687 1.12263 1.12814 1.05139
VE/cm3mol−1 0.134 0.150 0.169 0.209 0.236 0.259 0.291 0.054
wB 0.18 0.06 0.18 0.24
wC 0.06 0.18 0.18 0.24
ρ/g cm−3 1.07320 1.14067 1.16303 1.22281
VE/cm3mol−1 0.086 0.287 0.432 0.839
T/K = 293.15
wB 0.12 0.12 0.12 0.12 0.12 0.12 0.12 0.12
wC 0.03 0.06 0.09 0.12 0.15 0.18 0.21 0.24
ρ/g cm−3 1.03941 1.06032 1.08171 1.10350 1.12600 1.14897 1.17269 1.19716
VE/cm3mol−1 0.022 0.058 0.103 0.160 0.223 0.300 0.385 0.481
continued
6. PVT Data 463
____________________________________________________________________________________
continued
wB 0.03 0.06 0.09 0.15 0.18 0.21 0.24
wC 0.12 0.12 0.12 0.12 0.12 0.12 0.12
ρ/g cm−3 1.08748 1.09281 1.09816 1.10904 1.11432 1.12002 1.12541
VE/cm3mol−1 0.107 0.123 0.140 0.178 0.205 0.226 0.257
T/K = 298.15
wB 0.12 0.12 0.12 0.12 0.12 0.12 0.12 0.12
wC 0.03 0.06 0.09 0.12 0.15 0.18 0.21 0.24
ρ/g cm−3 1.03744 1.05811 1.07926 1.10085 1.12317 1.14594 1.16949 1.19383
VE/cm3mol−1 0.020 0.053 0.094 0.146 0.204 0.274 0.352 0.439
wB 0.03 0.06 0.09 0.15 0.18 0.21 0.24 0.06
wC 0.12 0.12 0.12 0.12 0.12 0.12 0.12 0.06
ρ/g cm−3 1.08507 1.09036 1.09559 1.10629 1.11153 1.11710 1.12240 1.04769
VE/cm3mol−1 0.099 0.112 0.128 0.162 0.185 0.204 0.232 0.041
wB 0.18 0.06 0.18 0.24
wC 0.06 0.18 0.18 0.24
ρ/g cm−3 1.06864 1.13519 1.15695 1.21586
VE/cm3mol−1 0.069 0.218 0.340 0.672
T/K = 303.15
wB 0.12 0.12 0.12 0.12 0.12 0.12 0.12 0.12
wC 0.03 0.06 0.09 0.12 0.15 0.18 0.21 0.24
ρ/g cm−3 1.03539 1.05583 1.07679 1.09819 1.12034 1.14293 1.16634 1.19053
VE/cm3mol−1 0.018 0.048 0.085 0.133 0.185 0.250 0.321 0.401
wB 0.03 0.06 0.09 0.15 0.18 0.21 0.24
wC 0.12 0.12 0.12 0.12 0.12 0.12 0.12
ρ/g cm−3 1.08264 1.08786 1.09301 1.10354 1.10870 1.11419 1.11940
VE/cm3mol−1 0.090 0.102 0.116 0.148 0.169 0.186 0.212
T/K = 313.15
wB 0.12 0.12 0.12 0.12 0.12 0.12 0.12 0.12
wC 0.03 0.06 0.09 0.12 0.15 0.18 0.21 0.24
ρ/g cm−3 1.03084 1.05091 1.07151 1.09261 1.11443 1.13673 1.15988 1.18383
VE/cm3mol−1 0.018 0.046 0.081 0.125 0.174 0.234 0.298 0.371
wB 0.03 0.06 0.09 0.15 0.18 0.21 0.24 0.06
wC 0.12 0.12 0.12 0.12 0.12 0.12 0.12 0.06
ρ/g cm−3 1.07745 1.08280 1.08755 1.09779 1.10282 1.10815 1.11321 1.04102
VE/cm3mol−1 0.087 0.093 0.111 0.139 0.158 0.174 0.198 0.036
wB 0.18 0.06 0.18 0.24
wC 0.06 0.18 0.18 0.24
ρ/g cm−3 1.06089 1.12638 1.14737 1.20523
VE/cm3mol−1 0.060 0.187 0.288 0.568
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) allyl ether methyl ether 1980MED

T/K = 298.15 wB = 0.6 VE/cm3g−1 −0.029
Polymer (B): poly(ethylene glycol) monoallyl ether 1980MED

T/K = 298.15 wB = 0.6 VE/cm3g−1 −0.0275
Polymer (B): poly(ethylene glycol) monoallyl ether acetate 1980MED

E 3 −1
T/K = 298.15 wB = 0.6 V /cm g −0.025
Polymer (B): poly(ethylene glycol) monoallyl ether phenylurethane 1980MED

E 3 −1
T/K = 298.15 wB = 0.65 V /cm g −0.0175
Polymer (B): poly(ethylene oxide) 1981NOR

Characterization: Mn/g.mol−1 = 400, ρB = 1.1052 g/cm3
Dow Chemical Company, USA
E id
T/K = 323.15 xB = 0.07 V /V −0.021

E id
T/K = 323.15 xB = 0.04 V /V −0.020
6. PVT Data 465
____________________________________________________________________________________

E id
T/K = 323.15 xB = 0.03 V /V −0.023

Serva, Heidelberg, Germany
T/K = 298.15
zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
VE/cm3 basemol−1 −0.020 −0.062 −0.103 −0.181 −0.396 −0.493 −0.646 −0.718
Comments: VE is given in cm3/base mol mixture calculated with MA = 18.015 g/mol and

−1 −1
17 units propylene oxide, 74 units ethylene oxide
T/K = 333.15
wB 0.170 0.255 0.340 0.425 0.510 0.595 0.680 0.765 0.850
VE/Vid −0.0085 −0.0117 −0.0151 −0.0196 −0.0215 −0.0271 −0.0237 −0.0201 −0.0148
T/K = 343.15
wB 0.170 0.255 0.340 0.425 0.510 0.595 0.680 0.765 0.850
VE/Vid −0.0080 −0.0111 −0.0139 −0.0186 −0.0201 −0.0253 −0.0223 −0.0189 −0.0138
T/K = 353.15
wB 0.170 0.255 0.340 0.425 0.510 0.595 0.680 0.765 0.850
VE/Vid −0.0070 −0.0104 −0.0129 −0.0174 −0.0186 −0.0238 −0.0209 −0.0179 −0.0128

T/K = 278.15
wB 0.0046 0.0120 0.0193 0.0501 0.1022 0.1927
ρ/g cm−3 1.0010 1.0019 1.0032 1.0074 1.0150 1.0295
continued
____________________________________________________________________________________
continued
T/K = 293.15
wB 0.0046 0.0120 0.0193 0.0501 0.1022 0.1927 0.2961 0.4104
−3
ρ/g cm 0.9990 1.0000 1.0010 1.0050 1.0122 1.0252 1.0408 1.0607
T/K = 333.15
wB 0.0046 0.0120 0.0193 0.0501 0.1022 0.1927 0.4104
ρ/g cm−3 0.9840 0.9848 0.9858 0.9897 0.9959 1.0075 1.0370

T/K = 278.15
wB 0.0046 0.0983 0.0190 0.0987 0.1862 0.2907
ρ/g cm−3 1.0009 1.0016 1.0031 1.0147 1.0298 1.0459
T/K = 293.15
wB 0.0046 0.0983 0.0190 0.0987 0.1862 0.2907 0.4012
ρ/g cm−3 0.9988 0.9995 1.0007 1.0114 1.0256 1.0402 1.0585
T/K = 333.15
wB 0.0046 0.0983 0.0190 0.0987 0.2907 0.4012
ρ/g cm−3 0.9837 0.9846 0.9857 0.9956 1.0200 1.0347

T/K = 278.15
wB 0.0054 0.0103 0.0208 0.0521 0.1998 0.3092
ρ/g cm−3 1.0011 1.0017 1.0033 1.0080 1.0312 1.0503
T/K = 293.15
wB 0.0054 0.0103 0.0208 0.0521 0.1998 0.3092 0.4250
ρ/g cm−3 0.9990 0.9996 1.0011 1.0053 1.0271 1.0443 1.0625
T/K = 333.15
wB 0.0054 0.0103 0.0208 0.0521 0.1998 0.3092 0.4250
ρ/g cm−3 0.9839 0.9848 0.9860 0.9899 1.0091 1.0241 1.0388

continued
6. PVT Data 467
____________________________________________________________________________________
continued
T/K = 278.15
wB 0.0051 0.0125 0.0214 0.0988 0.1961
ρ/g cm−3 1.0008 1.0028 1.0035 1.0147 1.0305
T/K = 293.15
wB 0.0051 0.0125 0.0214 0.0988 0.1961
ρ/g cm−3 0.9987 0.9996 1.0002 1.0113 1.0247

T/K = 278.15
wB 0.0050 0.0103 0.0176 0.0502 0.1015
ρ/g cm−3 1.0006 1.0012 1.0024 1.0070 1.0150
T/K = 293.15
wB 0.0047 0.0106 0.0200 0.0504 0.0576
ρ/g cm−3 0.9986 0.9994 1.0006 1.0043 1.0054
Polymer (B): poly(propylene glycol) 1979SIM

T/K = 298.15 wB = 0.50 VE/cm3g−1 −0.030
Polymer (B): poly(propylene glycol) 1957MAL

E 3 −1
T/K = 323.15 wB = 0.65 V /cm g −0.027
Polymer (B): poly(propylene glycol) 1972TAG

E
wB = 0.60 (at the minimum of the V -curve)
T/K 283.15 298.15 312.15
VE/cm3g−1 −0.040 −0.035 −0.028
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 1969KUZ

T/K = 295.15
wB 0.10 0.20 0.40 0.60 0.80
VE/cm3g−1 −0.009 −0.020 −0.032 −0.031 −0.016
T/K = 353.15
wB 0.10 0.20 0.40 0.60 0.80
VE/cm3g−1 −0.001 −0.002 −0.0095 −0.0065 −0.000
Polymer (B): poly(1-vinyl-2-pyrrolidinone) 1998KAN

T/K = 278.15
wB 0.0052 0.0103 0.0252 0.0484 0.0918 0.1957 0.2979
ρ/g cm−3 1.0011 1.0022 1.0055 1.0107 1.0205 1.0446 1.0705
T/K = 293.15
wB 0.0124 0.0288 0.0563 0.0940 0.1884 0.3728
ρ/g cm−3 1.0005 1.0044 1.0106 1.0187 1.0399 1.0859
T/K = 333.15
wB 0.0124 0.0288 0.0563 0.0940 0.1884 0.3728
ρ/g cm−3 0.9865 0.9945 0.9946 1.0025 1.0223 1.0652

T/K = 278.15
wB 0.0061 0.0128 0.0200 0.0491 0.1034 0.1886 0.2899
ρ/g cm−3 1.0013 1.0028 1.0044 1.0109 1.0234 1.0441 1.0701
T/K = 293.15
wB 0.0010 0.0295 0.0436 0.0993 0.1975 0.3890
ρ/g cm−3 1.0004 1.0047 1.0081 1.0208 1.0432 1.0919
T/K = 333.15
wB 0.0010 0.0295 0.0436 0.0993 0.1975 0.3890
ρ/g cm−3 0.9854 0.9895 0.9926 1.0047 1.0261 1.0734
6. PVT Data 469
____________________________________________________________________________________

T/K = 278.15
wB 0.0051 0.0100 0.0201 0.0483
ρ/g cm−3 1.0012 1.0023 1.0041 1.0113
T/K = 293.15
wB 0.0061 0.0113 0.0263 0.0513 0.0945 0.2000
ρ/g cm−3 0.9996 1.0007 1.0040 1.0084 1.0204 1.0453
T/K = 333.15
wB 0.0061 0.0113 0.0263 0.0513 0.0945
ρ/g cm−3 0.9848 0.9857 0.9889 0.9947 1.0044
Polymer (B): tetra(ethylene glycol) 1991MUE

T/K = 298.15
wB 0.1032 0.2995 0.3998 0.5007 0.5944 0.7008 0.7993 0.8990
VE/cm3g−1 −0.00400 −0.01234 −0.01623 −0.01914 −0.02032 −0.01917 −0.01523 −0.00872
T/K = 308.15
wB 0.1032 0.2995 0.3998 0.5007 0.5944 0.7008 0.7993 0.8990
VE/cm3g−1 −0.00390 −0.01176 −0.01542 −0.01816 −0.01929 −0.01824 −0.01464 −0.00843
T/K = 318.15
wB 0.1030 0.3034 0.4035 0.5139 0.5999 0.7042 0.7886 0.8811
VE/cm3g−1 −0.00381 −0.01147 −0.01485 −0.01755 −0.01836 −0.01731 −0.01452 −0.00938
T/K = 328.15
wB 0.1030 0.3034 0.4035 0.5139 0.5999 0.7042 0.7886 0.8811
VE/cm3g−1 −0.00373 −0.01108 −0.01430 −0.01678 −0.01758 −0.01662 −0.01399 −0.00914
Polymer (B): tetra(ethylene glycol) monooctyl ether 1997WIE

T/K = 278.149
xB 0.000116 0.000262 0.000442 0.000679 0.000994 0.001379 0.001495 0.001654
VE/cm3mol−1 −0.00252 −0.00568 −0.00803 −0.01072 −0.01415 −0.01823−0.01946 −0.02116
T/K = 288.146
xB 0.000119 0.000283 0.000508 0.000763 0.001024 0.001370 0.001512 0.001792
VE/cm3mol−1 −0.00275 −0.00525 −0.00752 −0.01014 −0.01251 −0.01580 −0.01733 −0.01951
continued
____________________________________________________________________________________
continued
T/K = 298.114
xB 0.000116 0.000296 0.000527 0.000780 0.001025 0.001349 0.001514 0.001697
VE/cm3mol−1 −0.00226 −0.00436 −0.00643 −0.00868 −0.01082 −0.01370 −0.01513 −0.01678
T/K = 308.141
xB 0.000117 0.000303 0.000529 0.000757 0.001026 0.001338 0.001466 0.001660
VE/cm3mol−1 −0.00220 −0.00394 −0.00569 −0.00737 −0.00948 −0.01191 −0.01296 −0.01426
Comments: More data can be found in the original source.
Polymer (B): tri(ethylene glycol) monohexyl ether 1992WIE

T/K = 288.15
xB 0.00238 0.07278 0.1433 0.1875 0.2373 0.3054 0.3553 0.3953
VE/cm3mol−1 −0.0367 −0.5107 −0.8117 −0.9261 −0.9969 −1.0268 −1.0150 −0.9890
xB 0.4572 0.5193 0.5932 0.7188 0.8661
VE/cm3mol−1 −0.9270 −0.8508 −0.7394 −0.5276 −0.2528
T/K = 293.15
xB 0.00110 0.00466 0.01051 0.05028 0.07495 0.1004 0.1486 0.2118
VE/cm3mol−1 −0.0161 −0.0524 −0.0959 −0.3577 −0.4960 −0.6212 −0.7999 −0.9330
xB 0.2475 0.3145 0.3597 0.4101 0.4538 0.5570 0.6425 0.8343
VE/cm3mol−1 −0.9749 −1.0007 −0.9925 −0.9564 −0.9135 −0.7804 −0.6464 −0.3123
T/K = 298.15
xB 0.00116 0.00523 0.01022 0.04989 0.1002 0.1515 0.2034 0.2358
VE/cm3mol−1 −0.0180 −0.0529 −0.0823 −0.3400 −0.5939 −0.7768 −0.8916 −0.9352
xB 0.2565 0.2823 0.3129 0.3747 0.4202 0.4947 0.6036 0.7674
VE/cm3mol−1 −0.9535 −0.9685 −0.9747 −0.9554 −0.9273 −0.8489 −0.6997 −0.4246
T/K = 308.15
xB 0.00221 0.00693 0.01176 0.03155 0.05011 0.07789 0.1030 0.1656
VE/cm3mol−1 −0.0274 −0.0592 −0.0899 −0.2078 −0.3110 −0.4501 −0.5585 −0.7587
xB 0.2112 0.2465 0.2891 0.3437 0.3747 0.4125 0.4583 0.5310
VE/cm3mol−1 −0.8475 −0.8899 −0.9168 −0.9201 −0.9081 −0.8846 −0.8474 −0.7636
xB 0.5970 0.6645 0.7916 0.9142
VE/cm3mol−1 −0.6739 −0.5739 −0.3631 −0.1496
Comments: More data can be found in the original source.
6. PVT Data 471
____________________________________________________________________________________
6.3. Table of systems where additional information on volume effects

in aqueous polymer solutions can be found
_____________________________________________________________________________
Polymer (B) T-range Ref.
_____________________________________________________________________________
Gelatine 274-303 K 1994COE
_____________________________________________________________________________
Hydroxypropyl starch 293-323 K 1996CES
_____________________________________________________________________________
Penta(ethylene glycol) dimethyl ether 288-313 K 2000BER
298 K 2001BER
_____________________________________________________________________________
Polyacrylamide 293 K 1983LIN
298 K 1970ROY
298 K 1981DAY
298 K 1983SAR
_____________________________________________________________________________
Poly(acrylic acid) 293 K 1970CAI
298 K 1970ROY
_____________________________________________________________________________
Poly(N,N-dimethylacrylamide) 298 K 1981DAY
_____________________________________________________________________________
Poly(ethylene glycol) 278-418 K 1998SAS
293 K 1980UEB
298 K 1982MED
298 K 1992SNY
298 K 1993AUC
298 K 1996AMB
298 K 1997SAB
298 K 2002VER
298-308 K 1968LAK
303 K 1979KOL
300-330 K 1993GRA
338 K 1957MAL
_____________________________________________________________________________
Poly(ethylene oxide) 288-353 K 1993EAG
293-333 K 1977SAE
298 K 1972BOJ
298 K 1979MON
298 K 1983SAR
300-320 K 1993GRA
_____________________________________________________________________________
____________________________________________________________________________________
Polymer (B) T-range Ref.

_____________________________________________________________________________
b-poly(ethylene oxide) triblock copolymer 288-328 K 2002SEN
_____________________________________________________________________________
Poly(N-isopropylacrylamide) 288-306 K 1968HES
_____________________________________________________________________________
Poly(methacrylic acid) 329-332 K 1974TAN
_____________________________________________________________________________
Poly(N-methylacrylamide) 298 K 1972BOJ
298 K 1981DAY
_____________________________________________________________________________
Poly(propylene glycol) 298 K 1979SIM
298 K 1982MED
298-328 K 1999CRE
308 K 1998COM
303-320 K 1974TAN
323 K 1957MAL
_____________________________________________________________________________
Poly(propylene oxide) 278-328 K 1996CRO
_____________________________________________________________________________
Poly(styrenesulfonic acid) 298 K 1976SKE
_____________________________________________________________________________
Poly(vinyl alcohol) 278-303 K 1974TAN
283-303 K 1982EAG
_____________________________________________________________________________
Poly(vinylidene fluoride) 293 K 1993AMB
_____________________________________________________________________________
Poly(1-vinyl-2-pyrrolidinone) 298 K 1968GOL
_____________________________________________________________________________
Tetra(ethylene glycol) 293 K 1980UEB
_____________________________________________________________________________
Tri(ethylene glycol) dimethyl ether 288-313 K 2000BER
298 K 2001BER
_____________________________________________________________________________
Vinyl acetate/vinyl alcohol copolymer 283-303 K 1982EAG
_____________________________________________________________________________
Vinyl acetate/1-vinyl-2-pyrrolidinone 278-303 K 1974TAN
_____________________________________________________________________________
6. PVT Data 473
____________________________________________________________________________________
6.4. References
1957MAL Malcolm, G.N. and Rowlinson, J.S., The thermodynamic properties of aqueous solutions of
polyethylene glycol, polypropylene glycol, and dioxane, Trans. Faraday Soc., 53, 921,
1957.
1968GOL Goldfarb, J. and Rodriguez, S., Aqueous solutions of polyvinylpyrrolidone, Makromol.
Chem., 116, 96, 1968.
1968HES Heskins, M. and Guillet, J.E., Solution properties of poly(N-isopropylacrylamide), J.
Macromol. Sci.-Chem. A, 2, 1441, 1968.
1968LAK Lakhanpal, M.L., Chhina, K.S., and Sharma, S.C., Thermodynamic properties of aqueous
solutions of polyoxyethleneglycols, Indian J. Chem., 6, 505, 1968.
1969KUZ Kuznetsov, V.I., Kogan, V.B., and Vilesova, M.S., Investigation of mutual solubility of
poly(oxypropylene) polyoles and water (Russ.), Vysokomol. Soedin., Ser. A, 11, 1330,
1969.
1970CAI Caille, A., Daoust, H., and Friedman, S., Apparent molal volume of poly(acrylic acid) in
aqueous solution, Macromolecules, 3, 700, 1970.
1970ROY Roy-Chowdhury, P. and Male, K.M., The adiabatic compressibility of poly(acrylic acid)
and polyacrylamide in aqueous solution, J. Appl. Polym. Sci., 14, 2937, 1970.
1972BOJ Boje, L. and Hvidt, A., Volume effects in aqueous solutions of macromolecules containing
non-polar groups, Biopolymers, 11, 2357, 1972.
A, 14, 1991, 1972.
1976SKE Skerjanc, J., Kozak, D., Hocevar, S., Vesnaver, G., Jus, B., and Dolar, D., Thermodynamic
properties of polyelectrolyte solutions containing mixtures of monovalent and trivalent
counterions, Biophys. Chem., 6, 9 1976.
1977SAE Saeki, S., Kuwahara, N., Nakata, M., and Kaneko, M., Phase separation of poly(ethylene
glycol)-water-salt systems, Polymer, 18, 1027, 1977.
1978LEP Lepori, L. and Mollica, V., Volumetric properties of dilute aqueous solutions of
poly(ethylene glycols), J. Polym. Sci. Polym. Phys. Ed., 16, 1123, 1978.
1979KOL Koller, J., Kalorimetrische Untersuchungen der inter- und intramolekularen Wechsel-
wirkungen von Polyethylenglycolen in wäßriger und benzolischer Lösung, Dissertation, TU
München, 1979.
1979MON Monshausen, F.W., Kalorimetrische Messungen am System Wasser – Polyethylenoxid,
Dissertation, RWTH Aachen, 1979.
1979SIM Simenido, A.V., Medved, Z.N., Denisova, L.L., Tarakanov, O.G., and Starikova, N.A.,
Some physicochemical properties of the mixtures of polypropylene polyols with water
1980MED Medved, Z.N. and Bulgakova, M.V., Phase equilibrium in aqueous solutions of
poly(ethylene oxide) derivatives possessing eng groups of different hydrophilic character
(Russ.), Zh. Prikl. Khim., 53, 1669, 1980.
1980UEB Überreiter, K., Change of water structure by polyalcohols. Density and viscosity
measurements, 2, Macromol. Chem., Rapid Commun., 1, 143, 1980.
____________________________________________________________________________________
1981DAY Day, J.C. and Robb, I.D., Thermodynamic parameters of polyacrylamides in water,
Polymer, 22, 1530, 1981.
1981NOR North, A.M., Pethrick, R.A., and Poh, B.T., Adiabatic compressibility studies of mixtures of
polyethyleneoxide with hydrophilic solvents, Adv. Mol. Relax. Interact. Process., 19, 209,
1981.
1982EAG Eagland, D. and Crowther, N.J., Hydrophobic interactions in dilute solutions of poly(vinyl
alcohol), Faraday Symp. Chem. Soc., 17, 141, 1982.
1982MED Medved, Z.N., Petrova, N.I., and Tarakanov, O.G., Comparative study of the thermo-
dynamics of mixing ethylene oxide and propylene oxide oligomers with water (Russ.),
1993AMB Ambrosone, L., Sartorio, R., and Vitagliano, V., Density measurements in the ternary
system poly(vinylidene fluoride)-water-N,N-dimethyl formamide at 20°C, Fluid Phase
Equil., 91, 177, 1993.
1983LIN Linow, K.-J., Okatova, O., and Philipp, B., Determination of the partial specific volume of
dissolved polymers by continuous density measurement, Acta Polym., 34, 376, 1983.
1983SAR Sarazin, D. and Francois, J., Apparent specific volumes of polymers in dilute solutions,
Polymer, 24, 547, 1983.
1983SHA Sharma, S.C. and Lakhanpal, M.L., Thermodynamics of mixtures of poly(tetramethylene
oxide)s and 1,4-dioxane, J. Polym. Sci., Polym. Phys. Ed., 21, 353, 1983.
1985SIK Sikora, A., Volume properties of dilute aqueous solutions of poly(oxyethylene) and its low
molecular models, Coll. Czech. Chem. Commun., 50, 2146, 1985.
1987VE1 Vennemann, N., Lechner, M.D., and Oberthür, R.C., Thermodynamics and conformation of
polyoxyethylene in aqueous solution under high pressure. 1. Small-angle neutron scattering
and densitometric measurements at room temperature, Polymer, 28, 1738, 1987.
1987VE2 Vennemann, N., Der Einfluss von hohem Druck auf thermodynamische und strukturelle
Eigenschaften von Polyoxiethylen in wäßriger Lösung, Dissertation, Universität Osnabrück,
1987.
1989BLO Bloss, P., Hergeth, W.-D., Döring, E., Witkowski, K., Wartewig, S., Association of
polyoxyethylene-polyoxypropylene block copolymers in aqueous solution, Acta Polym., 40,
260, 1989.
1990BLO Bloss, P., Poly(oxyethylen)-Poly(oxypropylen)-Blockcopolymere in wäßriger Lösung −
Struktur und Eigenschaften, Dissertation, TH Leuna-Merseburg, 1990.
1991MUE Müller, E.A. and Rasmussen, P., Densities and excess volumes in aqueous poly(ethylene
glycol) solutions, J. Chem. Eng. Data, 36, 214, 1991.
1992BEN Benkhira, A., Franta, E., and Francois, J., Polydioxolane in aqueous solutions. 1. Phase
diagram, Macromolecules, 25, 5697, 1992.
1992SNY Snyder, S.M., Cole, K.D., and Szlag, D.C., Phase compositions, viscosities, and densities
for aqueous two-phase systems composed of polyethylene glycol and various salts at 25°C,
J. Chem. Eng. Data, 37, 268, 1992.
1992WIE Wieczorek, S.A., Thermodynamics of aqueous mixtures of polyoxethene glycol mono-
ethers II. Excess molar volumes of (n-hexyl trioxyethene glycol monoether + water), J.
Chem. Thermodyn., 24, 129, 1992.
1993AUC Aucouturier, C. and Roux, A.H., Thermodynamic study of polyethylene glycol in micellar
aqueous solutions of sodium dodecylsulfate, Calorim. Anal. Therm., 24, 9, 1993.
1993EAG Eagland, D., Crowther, N.J., and Butler, C.J., Interaction of poly(oxyethylene) with water as
a function of molar mass, Polymer, 34, 2804, 1993.
1993GRA Graham, N.B. and Chen, C.F., Interaction of poly(ethylene oxide) with solvent−5. The
densities of water/poly(ethylene glycol) mixtures, Eur. Polym. J., 29, 149, 1993.
6. PVT Data 475
____________________________________________________________________________________
1993JAN Janssen, S., Schwahn, D., Mortensen, K., and Springer, T., Pressure dependence of the
Flory-Huggins interaction parameter in polymer blends. A SANS study and a comparison to
the Flory-Orwoll-Vrij equation of state (experimental PVT-data by private communication
with S. Janssen), Macromolecules, 26, 5587, 1993.
1994COE Coelfen, H. and Borchard, W., Determination of the partial specific volumes of thermo-
reversible gelatin/water and K-carrageenan/water gels, Macromol. Chem. Phys., 195, 1165,
1994.
1994GON Gonzales-Tello, P., Camacho, F., and Blazquez, G., Density and viscosity of concentrated
aqueous solutions of polyethylene glycol, J. Chem. Eng. Data, 39, 611, 1994.
1995DAN Danusso, F., Levi, M., Gianotti, G., and Turri, S., Thermovolumetric properties versus glass
transition temperature of diolic perfluoro-poly(oxyethylene-ran-oxymethylene) oligomers,
1995HAS Hasse, H., Kany, H.-P., Tintinger, R., and Maurer, G., Osmotic virial coefficients of
aqueous poly(ethylene glycol) from laser-light scattering and isopiestic measurements,
1996AMB Ambrosone, L., Sartorio, R., Vescio, A., and Vitagliano, V., Volumetric properties of
aqueous solutions of ethylene glycol oligomers at 25°C, J. Chem. Soc. Faraday Trans., 92,
1163, 1996.
1996CES Cesi, V., Katzbauer, B., Narodoslawsky, M., and Moser, A., Thermophysical properties of
polymers in aqueous two-phase systems, Int. J. Thermophys., 17, 127, 1996.
1997MAI Mai, S.-M., Booth, C., and Nace, V.M., Specific volumes of poly(oxybutylene) and
poly(oxyethylene) dimethyl ethers in the liquid state, Eur. Polym. J., 33, 991, 1997.
1997SAB Sabadini, E., Assano, E.M., and Atvars, T.D.Z., Stoichiometry of poly(ethylene glycol) in
water and benzene by excess volume, J. Appl. Polym. Sci., 63, 301, 1997.
1997WIE Wieczorek, S.A., Thermodynamics of aqueous mixtures of polyoxyethylene glycol mono-
ethers IV. Excess molar volumes of (n-octyl tetraoxyethylene glycol monoether + water) in
the vicinity of the critical micelle composition, J. Chem. Thermodyn., 29, 1269, 1997.
1998COM Compostizo, A., Crespo Colin, A., Cancho, S.M., Rubio, R.G., Equation of state study of
hydrogen-bonded polymer systems, Recent Res. Devel. Phys. Chem., 2, 535, 1998.
1998CON Conesa, A., Shen, S., and Coronas, A., Liquid densities, kinematic viscosities, and heat ca-
pacities of some ethylene glycol dimethyl ethers at temperatures from 283.15 to 423.15 K,
Int. J. Thermophys., 19, 1343, 1998.
1998ELI Eliassi, A., Modarress, H., and Mansoori, G.A., Densities of poly(ethylene glycol) + water
mixtures in the 298.15-328.15 temperature range, J. Chem. Eng. Data, 43, 719, 1998.
1998KAN Kany, H.-P., Thermodynamische Eigenschaften wäßriger Polymer-Lösungen, Dissertation,
Universität Kaiserslautern, 1998.
1998KIR Kirincic, S. and Klofutar, C., A volumetric study of aqueous solutions of poly(ethylene
glycol)s, Fluid Phase Equil., 149, 233, 1998.
1998LEE Lee, M.-J., Lo, C.-K., and Lin, H.-M., PVT measurements for mixtures of poly(ethylene
glycol methyl ether) with poly(ethylene glycol) from 298 K to 338 K and pressures up to 30
MPa, J. Chem. Eng. Data, 43, 1076, 1998.
1998SAS Sasahara, K., Sakurai, M., and Nitta, K., Volume and compressibility changes for poly
(ethylene glycol)-water system at various temperatures, Colloid Polym. Sci., 276, 643, 1998.
1999CHA Chang, J.-S., Lee, M.-J., and Lin, H.-M., PVT of fractionation cuts of poly(ethylene glycol)
and poly(propylene glycol) from 298 K to 338 K and pressures up to 30 MPa, J. Chem.
Eng. Japan, 32, 611, 1999.
1999CRE Crespo Colin, A., Cancho, S.M., Rubio, R.G., and Compostizo, A., Equation of state of
aqueous polymer systems: poly(propylene glycol) + water, Phys. Chem. Chem. Phys., 1,
319, 1999.
____________________________________________________________________________________
2000BER Bernal, P., Bunn, A., Logan, J., and McCluan, J., Apparent molar volumes and adiabatic
compressibilities of crown ethers and glymes in aqueous solutions at various temperatures,
J. Solution Chem., 29, 651, 2000.
2000COM Comunas, M.J.P., Lopez, E.R., Pires, P., Garcia, J., Fernandez, J., PVT measurements of
polyethylene glycol dimethyl ethers between 278.15 and 328.15 K at pressures to 12 MPa,
Int. J. Thermophys., 21, 831, 2000.
2000LEE Lee, M.-J., Tuan, Y.-C., and Lin, H.-M., Pressure, volume, and temperature for mixtures of
poly(ethylene glycol methyl ether)-350 + anisole and poly(ethylene glycol)-200 + anisole
from 298 K to 338 K and pressures up to 50MPa, J. Chem. Eng. Data, 45, 1100, 2000.
2000VIC Vicini, S. and Pedemonte, E., Thermodynamic of polymer mixtures: parameters of the state
equation for poly(styrene), poly(vinyl methyl ether) and their mixtures, Macromol. Chem.
Phys., 201, 2586, 2000.
2000ZAF Zafarani-Moattar, M.T. and Mehrdad, A., Measurement and correlation of density for PEG
+ H2O + NaHSO4, NaH2PO4, and Na2HPO4 at three temperatures, J. Chem. Eng. Data, 45,
386, 2000.
2001BER Bernal, P and McCluan, J., Apparent molar volumes and adiabatic compressibilities of
crown ethers and glymes in H2O and D2O at 25 °C, J. Solution Chem., 30, 119, 2001.
2001LIN Lin, H.-M., Hsu, T.-S., and Lee, M.-J., Pressure-volume-temperature properties for binary
polymer solutions of poly(propylene glycol) with 1-octanol and acetophenone,
2002COM Comunas, M.J.P., Baylaucq, A., Boned, C., Canet, X., and Fernandez, J., High-pressure
volumetric behavior of x 1,1,1,2-tetrafluoroethane + (1-x) 2,5,8,11,14-pentaoxapentadecane
(TEGDME) mixtures, J. Chem. Eng. Data, 47, 233, 2002.
2002GRA Graber, T.A., Galleguillos, H., Asenjo, J.A., and Andrews, B. A., Refractive index, density,
and viscosity in the NaNO3 + H2O + poly(ethylene glycol) system at various temperatures,
J. Chem. Eng. Data, 47, 174, 2002.
2002SEN Senkow, S., Mehta, S.K., Douheret, G., Roux, A.H., and Roux-Desgranges, G., Aqueous
solutions of some amphiphilic poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene
oxide) triblock copolymers. A thermodynamic study over a wide concentration range at
temperatures between 288.15 and 328.15 K, Phys. Chem. Chem. Phys., 4, 4472, 2002.
2002VER Vergara, A., Paduano, L., Capuano, F., and Sartorio, R., Kirkwood-Buff integrals for
polymer-solvent mixtures. Preferential solvation and volumetric analysis in aqueous PEG
solutions, Phys. Chem. Chem. Phys., 4, 4716, 2002.
7. SECOND VIRIAL COEFFICIENTS (A2) OF AQUEOUS
POLYMER SOLUTIONS
7.1. Experimental A2 data
____________________________________________________________________________________
Polymer (B) Mn/ Mw / T/ A2 104/ Ref.

g/mol g/mol K cm3mol/g2
____________________________________________________________________________________
Acrylamide/maleic anhydride copolymer
(50 mol% acrylamide)
in 0.6 M NaNO3 aqueous solution 24400 298.15 3.0 1983ION
____________________________________________________________________________________
Acrylamide/sodium acrylate copolymer
in 0.1 M Na2SO4 aqueous solution
(3.7 mol% acrylamide) 6500000 298.15 2.8 1985KUL
(36 mol% acrylamide) 6110000 298.15 9.7 1985KUL
____________________________________________________________________________________
Acrylamide/sodium 3-methylacrylamido-
3-methylbutanoate copolymer
(31.7 mol% acrylamide) 2000000 298.15 3.2 1986MCC
____________________________________________________________________________________
Dextran
618 310.15 −40.5 1971GEK
618 333.15 −53.9 1971GEK
1220 310.15 − 5.36 1971GEK
1220 333.15 −18.8 1971GEK
1460 310.15 + 2.17 1971GEK
1460 333.15 − 6.19 1971GEK
2040 310.15 10.9 1971GEK
2040 333.15 12.0 1971GEK
4930 310.15 7.66 1971GEK
4930 333.15 9.36 1971GEK
8980 310.15 6.42 1971GEK
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Dextran 8980 333.15 8.60 1971GEK
9900 298.15 13.8 1993WUC
10100 298.15 8.2 1993HAY
39700 298.15 9.2 1993WUC
23600 40000 293.15 13.1 1993GAU
23600 40000 313.15 12.4 1993GAU
23600 40000 333.15 9.3 1993GAU
43400 298.15 5.0 1993HAY
65000 298.15 7.7 1993WUC
68100 298.15 4.0 1993HAY
29630 74540 298.15 8.5 1989HAY
46300 70000 293.15 9.9 1993GAU
46300 70000 313.15 9.4 1993GAU
46300 70000 333.15 7.2 1993GAU
80000 288.15 8.85 1993NOR
80000 298.15 7.14 1993NOR
80000 313.15 6.59 1993NOR
80000 323.15 5.54 1993NOR
80000 333.15 4.57 1993NOR
64800 110000 293.15 6.5 1993GAU
64800 110000 313.15 5.6 1993GAU
64800 110000 333.15 4.5 1993GAU
400000 288.15 3.56 1993NOR
400000 298.15 1.88 1993NOR
400000 313.15 1.81 1993NOR
400000 323.15 1.42 1993NOR
400000 333.15 1.12 1993NOR
101000 500000 293.15 6.4 1993GAU
101000 500000 313.15 5.7 1993GAU
101000 500000 333.15 3.9 1993GAU
481000 298.15 3.9 1993WUC
249000 485000 293.15 4.6 1993BES
249000 485000 293.15 4.6 1994TIN
167000 509000 298.15 3.2 1989HAY
508900 298.15 1.3 1993HAY
1000000 303.15 0.85 1991STA
1000000 343.15 2.1 1991STA
1000000 373.15 1.8 1991STA
2000000 288.15 1.22 1993NOR
2000000 298.15 0.74 1993NOR
2000000 313.15 0.43 1993NOR
2000000 323.15 0.39 1993NOR
2000000 333.15 0.24 1993NOR
2270000 298.15 0.90 1993WUC
3250000 298.15 0.70 1993WUC
7400000 303.15 0.099 1991STA
7400000 343.15 0.064 1991STA
____________________________________________________________________________________
7. A2 Data 479
_____________________________________________________________________________

____________________________________________________________________________________
Dextran 7400000 373.15 0.078 1991STA
7400000 288.15 0.47 1993NOR
7400000 298.15 0.29 1993NOR
7400000 313.15 0.17 1993NOR
7400000 323.15 0.13 1993NOR
7400000 333.15 0.0576 1993NOR
17500000 303.15 0.013 1991STA
17500000 323.15 0.018 1991STA
17500000 343.15 0.014 1991STA
17500000 373.15 0.011 1991STA
17500000 288.15 0.30 1993NOR
17500000 298.15 0.17 1993NOR
17500000 313.15 0.0965 1993NOR
17500000 323.15 0.0623 1993NOR
17500000 333.15 0.0189 1993NOR
21100000 303.15 0.017 1991STA
21100000 323.15 0.015 1991STA
21100000 343.15 0.015 1991STA
21100000 373.15 0.0045 1991STA
33000000 288.15 0.21 1993NOR
33000000 298.15 0.12 1993NOR
33000000 313.15 0.0621 1993NOR
33000000 323.15 0.0337 1993NOR
33000000 333.15 0.0024 1993NOR
100000000 288.15 0.0768 1993NOR
100000000 298.15 0.0429 1993NOR
100000000 313.15 0.0178 1993NOR
100000000 323.15 0.0108 1993NOR
100000000 333.15 0.00011 1993NOR
____________________________________________________________________________________
Ethylene oxide/propylene oxide
copolymer
(72.4 mol% ethylene oxide) 36000 298.15 6.0 1991LOU
32500 298.15 12.5 1991LOU
____________________________________________________________________________________
N-Isopropylacrylamide/acrylamide
copolymer
(15 mol% acrylamide) 3100000 298.15 3.01 1994MUM
____________________________________________________________________________________
Poly(allylamine hydrochloride) in
0.05 − 3 M NaCl aqueous solution 180000 298.15 33.7 – 2.4 1985OCH
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Poly(acrylamide) 390000 293.15 42.9 1957SIL
390000 303.15 48.7 1957SIL
390000 313.15 54.1 1957SIL
390000 323.15 59.1 1957SIL
390000 333.15 63.9 1957SIL
1200000 298.15 4.9 1982STE
5000000 298.15 3.7 1985KUL
8900000 298.15 3.5 1986MCC
560000 1400000 298.15 1.8 1982LECH
in 0.1 M NaCl aqueous solution 33000 277.15 3.3 1985KAN
33000 282.65 4.5 1985KAN
33000 291.15 5.2 1985KAN
33000 298.15 6.1 1985KAN
33000 301.15 6.0 1985KAN
33000 312.15 6.5 1985KAN
33000 322.15 6.8 1985KAN
33000 333.15 6.8 1985KAN
129000 220000 277.65 2.0 1985KAN
129000 220000 287.15 2.4 1985KAN
129000 220000 297.65 3.0 1985KAN
129000 220000 298.15 2.8 1985KAN
129000 220000 307.65 3.0 1985KAN
129000 220000 317.15 3.1 1985KAN
129000 220000 328.65 3.2 1985KAN
3045000 6700000 275.65 0.3 1985KAN
3045000 6700000 279.65 0.5 1985KAN
3045000 6700000 283.15 0.7 1985KAN
3045000 6700000 291.65 1.1 1985KAN
3045000 6700000 299.55 1.3 1985KAN
3045000 6700000 306.15 1.8 1985KAN
in 0.2 M NaCl aqueous solution 255000 293.15 3.06 1982AMI
616000 293.15 3.31 1982AMI
1010000 293.15 3.12 1982AMI
2430000 293.15 2.90 1982AMI
2750000 293.15 2.81 1982AMI
in 0.1 M Na2SO4 aqueous solution 5000000 298.15 2.4 1985KUL
____________________________________________________________________________________
Poly(acrylic acid)
in 0.01 M HCl aqueous solution 500000 298.15 88.0 1980HAR
in 0.2 M HCl aqueous solution 1100000 293.15 1.0 1957SIL
1100000 303.15 2.6 1957SIL
1100000 323.15 5.6 1957SIL
1100000 333.15 6.9 1957SIL
1100000 343.15 8.1 1957SIL
____________________________________________________________________________________
7. A2 Data 481
_____________________________________________________________________________

____________________________________________________________________________________
Poly(dimethyldiallylammonium chloride)
in 1.0 M NaCl aqueous solution
89000 296.15 0.278 1987BUR
114000 296.15 0.247 1987BUR
281000 296.15 0.150 1987BUR
352000 296.15 0.122 1987BUR
418000 296.15 0.127 1987BUR
473000 296.15 0.222 1987BUR
____________________________________________________________________________________
200 293.15 71.6 1993GAU
200 313.15 56.4 1993GAU
200 333.15 48.9 1993GAU
595 293.15 42.6 1993GAU
595 313.15 29.9 1993GAU
595 333.15 29.2 1993GAU
1450 1550 293.15 31.0 1993GAU
1450 1550 313.15 24.2 1993GAU
1450 1550 333.15 14.6 1993GAU
2840 3000 293.15 27.2 1993GAU
2840 3000 313.15 23.7 1993GAU
2840 3000 333.15 12.0 1993GAU
3790 3860 298.15 36.4 1989HAY
3790 3860 298.15 43.2 1989HAY
3860 298.15 36.3 1993HAY
5750 6000 293.15 26.0 1993GAU
5750 6000 313.15 22.5 1993GAU
5750 6000 333.15 15.3 1993GAU
6230 6480 278.15 24.8 1995HAS
6230 6480 298.15 19.0 1995HAS
6230 6480 313.15 12.4 1995HAS
11700 298.15 30.3 1993HAY
9037 11800 298.15 30.5 1989HAY
9037 11800 298.15 41.7 1989HAY
20000 20500 298.15 16.7 1995HAS
20000 20500 313.15 9.7 1995HAS
34400 35700 278.15 25.7 1995HAS
34400 35700 298.15 18.0 1995HAS
34400 35700 313.15 14.4 1995HAS
____________________________________________________________________________________
20000 298.15 24.0 1987VEN
263000 274000 298.15 20.8 1984KAM
481000 505000 298.15 27.7 1984KAM
1161000 1300000 298.15 35.6 1984KAM
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
b-poly(ethylene oxide) triblock copolymer 3600 277.15 −190 1998CRO
(70 mol% ethylene oxide) 3600 281.25 −210 1998CRO
3600 282.55 −230 1998CRO
3600 283.55 −240 1998CRO
3600 284.65 −170 1998CRO
3600 286.75 −220 1998CRO
3600 288.65 −180 1998CRO
____________________________________________________________________________________
Polyethylenimine
47500 90400 308.15 3.15 1996PAR
117000 258000 308.15 1.75 1996PAR
246000 443000 308.15 1.34 1996PAR
236000 581000 308.15 1.22 1996PAR
1100000 2420000 308.15 0.583 1996PAR
2530000 5320000 308.15 0.316 1996PAR
____________________________________________________________________________________
Poly(L-glutamic acid) in 0.02 −
0.5 M NaCl aqueous solution 112000 298.15 88 − 42 1984KID
____________________________________________________________________________________
Poly(N-isopropylmethacrylamide)
130000 293.15 3.6 1990KUB
422000 293.15 2.0 1990KUB
875000 293.15 1.8 1990KUB
944000 293.15 1.7 1990KUB
993000 293.15 1.7 1990KUB
1110000 293.15 1.7 1990KUB
1150000 293.15 2.0 1990KUB
1240000 293.15 1.7 1990KUB
1840000 293.15 1.4 1990KUB
1870000 293.15 2.1 1990KUB
2520000 293.15 1.6 1990KUB
____________________________________________________________________________________
Poly(methacrylamide)
320000 293.15 0.21 1957SIL
320000 303.15 0.35 1957SIL
320000 313.15 0.49 1957SIL
320000 323.15 0.61 1957SIL
320000 333.15 0.73 1957SIL
____________________________________________________________________________________
in 0.1 M HCl aqueous solution146000 298.15 2.02 1955ARN
540000 298.15 1.61 1955ARN
682000 298.15 1.65 1955ARN
____________________________________________________________________________________
7. A2 Data 483
_____________________________________________________________________________

____________________________________________________________________________________
in 0.114 M HCl aqueous solution 200000 298.15 8.80 1955ARN
256000 298.15 24.0 1955ARN
329000 298.15 22.9 1955ARN
346000 298.15 13.8 1955ARN
427000 298.15 15.4 1955ARN
590000 293.15 1.8 1957SIL
590000 303.15 1.3 1957SIL
590000 314.15 0.7 1957SIL
in 1.0 M HCl aqueous solution 84000 298.15 −2.0 1955ARN
89000 298.15 13.2 1955ARN
168000 298.15 0.4 1955ARN
505000 308.15 0.8 1964KAN
505000 323.15 0.255 1964KAN
505000 333.15 0.0 1964KAN
510000 303.15 0.49 1964KAN
510000 313.15 0.1 1964KAN
____________________________________________________________________________________
Poly(3-methylacrylamido-3-methyl-
butanoic acid) sodium salt
2600000 298.15 3.5 1986MCC
____________________________________________________________________________________
Poly(sodium acrylate)
30000 298.15 0.27 1957TAK
60700 298.15 0.55 1957TAK
128800 298.15 0.95 1957TAK
211900 298.15 0.51 1957TAK
335000 298.15 0.97 1957TAK
644000 298.15 0.79 1957TAK
____________________________________________________________________________________
Poly(sodium sulfodecyl methacrylate)
in 0.1 M NaCl aqueous solution 349500 734000 298.15 1.91 1996PEI
____________________________________________________________________________________
Poly(sodium sulfoethyl methacrylate)
____________________________________________________________________________________
Poly(sodium sulfohexyl methacrylate)
____________________________________________________________________________________
Poly(sodium sulfooctyl methacrylate)
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Poly(vinyl alcohol)
180000 303.15 3.9 1962MA1
196000 303.15 5.2 1962MA1
245000 346.65 1.119 1962MA2
195000 353.15 0.995 1962MA2
259000 353.15 0.930 1962MA2
352000 353.15 0.739 1962MA2
458000 353.15 0.775 1962MA2
____________________________________________________________________________________
4600 8900 293.15 2.62 2003KAN
4600 8900 333.15 1.68 2003KAN
11600 298.15 3.35 1952HEN
15000 298.15 3.7 1952HEN
21900 298.15 3.0 1952HEN
28500 298.15 3.5 1952HEN
28900 298.15 3.4 1952HEN
37700 298.15 3.1 1952HEN
40800 298.15 3.7 1952HEN
45700 298.15 3.75 1952HEN
48600 298.15 3.15 1952HEN
60200 298.15 3.45 1952HEN
75400 298.15 3.2 1952HEN
207000 310000 293.15 4.2 1993DES
207000 310000 293.15 4.2 1994TIN
____________________________________________________________________________________
Poly(2-vinylpyridine) in 0.01 –
10.3 M H2SO4 aqueous solution ≈500000 298.15 11.0 – 3.0 1993YOS
____________________________________________________________________________________
Pullulan
300000 288.15 2.82 1993NOR
300000 298.15 2.76 1993NOR
300000 313.15 2.78 1993NOR
300000 323.15 2.64 1993NOR
300000 333.15 2.56 1993NOR
510000 288.15 2.66 1993NOR
510000 298.15 2.53 1993NOR
510000 313.15 2.51 1993NOR
510000 323.15 2.38 1993NOR
510000 333.15 2.43 1993NOR
1000000 288.15 2.47 1993NOR
1000000 298.15 2.25 1993NOR
1000000 313.15 2.20 1993NOR
1000000 323.15 2.16 1993NOR
1000000 333.15 2.07 1993NOR
____________________________________________________________________________________
7. A2 Data 485
_____________________________________________________________________________
7.2. References
1952HEN Hengstenberg, J. and Schuch, E., Molekulargewichtsbestimmung von Polyvinylpyrroli-

donen (PVP) mittels des osmotischen Drucks und der Lichtstreuung ihrer Lösungen,
Makromol. Chem., 7, 236, 1952.
1955ARN Arnold, R. and Caplan, S.R., Solutions of polymethacrylic acid 1. Molecular weights and
second virial coefficients of the undissociated acid, Trans. Faraday Soc., 51, 857, 1955.
1957SIL Silberberg, A., Eliassaf, J., and Katchalsky, A., Temperature-dependence of light scattering
and intrinsic viscosity of hydrogen bonding polymers, J. Polym. Sci., 23, 259, 1957.
1957TAK Takahashi, A., Hayashi, N., and Kagawa, I., Molecular weight determination of sodium
polyacrylate by the osmotic method (Jap.), Kogyo Kagaku Zasshi, 60, 1059, 1957.
1962MA1 Matsuo, T. and Inagaki, H., Über den Lösungszustand des Polyvinylalkohols in Wasser 1.
Mitt.: Metastabiler Zustand der Lösung, Makromol. Chem., 53, 130, 1962.
1962MA2 Matsuo, T. and Inagaki, H., Über den Lösungszustand des Polyvinylalkohols in Wasser 2.
Mitt.: Molekulargewichtsbestimmung durch Streulichtmessungen, Makromol. Chem., 55,
150, 1962.
1964KAN Kanevskaya, E.A., Zubov, P.I., Ivanova, L.V., and Lipatov, Yu.S., Temperature dependence
of the light scattering and viscosity of polymethacrylic acid solutions (Russ.), Vysokomol.
Soedin., 6, 981, 1964.
1971GEK Gekko, K., Physicochemical studies of oligodextran (III) Thermodynamic studies of dextran
aqueous solutions by vapor pressure lowering method, J. Sci. Hiroshima Univ., Ser. A, 35,
111, 1971.
1980HAR Hara, M. and Nakajima, A., Characteristic behaviors of light scattering from polyelectrolyte
in dilute solution region, Polym. J., 12, 701, 1980.
1981LEC Lechner, M.D. and Steinmeier, D.G., Das Verhalten von Polyacrylamidlösungen unter
hohen Drücken, Makromol. Chem., Rapid Commun., 2, 421, 1981.
1982AMI Aminabhavi, T.M., Patel, R.C., Bridger, K., and Jayadevappa, E.S., Evaluation of excluded
volume parameter for polymer-solvent system, J. Macromol. Sci.-Chem. A, 17, 1283, 1982.
1982STE Stejskal, J. and Horska, J., Refractive index increments of polyacrylamide and comments on
the light scattering from its solutions, Makromol. Chem., 183, 2527, 1982.
1983ION Ionescu, L.M., Petrea, I., Bujor, I.I., and Demetrescu, I., Light scattering from aqueous
solutions of poly(acrylamide-co-maleic anhydride), Makromol. Chem., 184, 1005, 1983.
1984KAM Kambe, Y. and Honda, C., Diffusion of poly(ethylene oxide) in water, Polym. Commun.,
25, 154, 1984.
1984KID Kidera, A. and Nakajima, A., Light scattering from poly(L-glutamic acid) in aqueous
solution in the helix-coil transition region, Macromolecules, 17, 659, 1984.
1985KAN Kanda, A., Duval, M., Sarazin, D., and Francois, J., Theta point of polyacrylamide in
aqueous solution and temperature dependence of the molecular dimensions, Polymer, 26,
406, 1985.
1985KUL Kulicke, W.-M. and Hörl, H.-H., Preparation and characterization of a series of
poly(acrylamide-co-acrylates) with a copolymer composition between 0-96.3 mol% acrylate
units with the same degree and distribution of polymerization, Colloid Polym. Sci., 263,
530, 1985.
1985OCH Ochiai, H., Handa, M., Matsumoto, H., Moriga, T., and Murakami, I., Dilute solution
properties of poly(allylammonium chloride) in aqueous sodium chloride solution,
Makromol. Chem., 186, 2547, 1985.
1986MCC McCormick, C.L. and Blackmon, K.P., Water-soluble copolymers. 17. Copolymers of
acrylamide with sodium 3-methylacrylamido-3-methylbutanoate: synthesis and characteri-
zation, Macromolecules, 19, 1512, 1986.
_____________________________________________________________________________
1987BUR Burkhardt, C.W., McCarthy, K.J., and Parazak, D.P., Solution properties of poly(dime-
thyldiallylammonium chloride), J. Polym. Sci.: Part C: Polym. Lett., 25, 209, 1987.
1987VEN Vennemann, N., Lechner, M.D., and Oberthür, R.C., Thermodynamics and conformation of
1989HAY Haynes, C.A., Beynon, R.A., King, R.S., Blanch, H.W., and Prausnitz, J.M., Thermo-
dynamic properties of aqueous polymer solutions: poly(ethylene glycol)/dextran, J. Phys.
Chem., 93, 5612, 1989.
1990KUB Kubota, K., Hamano, K., Kuwahara, N., Fujishige, S., and Ando, I., Characterization of
poly(N-isopropylmethacrylamide) in water, Polym. J., 22, 1051, 1990.
1991STA Stankovic, R.I., Jovanovic, S., Ilic, L., Nordmeier, E., and Lechner, M.D., Study of aqueous
dextran solutions under high pressures and different temperatures by dynamic light
scattering, Polymer, 32, 235, 1991.
1993DES Desbrieres, J., Borsali, R., Rinaudo, M., and Milas, M., χF Interaction parameter and single-
chain diffusion coefficients of dextran/poly(vinylpyrrolidone)/water: dynamic light scatte-
ring experiments, Macromolecules, 26, 2592, 1993.
1993GAU Gaube, J., Pfennig, A., and Stumpf, M., Vapor-liquid equilibrium in binary and ternary
aqueous solutions of poly(ethylene glycol) and dextran, J. Chem. Eng. Data, 38, 163, 1993.
1993HAY Haynes, C.A., Benitez, F.J., Blanch, H.W., and Prausnitz, J.M., Application of integral-
equation theory to aqueous two-phase partitioning systems, AIChE-J., 39, 1539, 1993.
1993NOR Nordmeier, E., Static and dynamic light-scattering solution behavior of pullulan and dextran
in comparison, J. Phys. Chem., 97, 5770, 1993.
1993WUC Wu, C., Laser light-scattering characterization of the molecular weight distribution of
dextran, Macromolecules, 26, 3821, 1993.
1993YOS Yoshida, M., Sakamoto, N., Ikemi, K., and Arichi, S., Solution properties of
polyvinylpyridine in acidic solvent. I. Solution properties of poly(2-vinylpyridine) in
aqueous solution of sulfuric acid, Bull. Chem. Soc. Japan, 66, 1598, 1993.
1994MUM Mumick, P.S. and McCormick, C.L., Water soluble copolymers. 54: N-isopropyl-
1994TIN Tinland, B. and Borsali, R., Single-chain diffusion coefficient of F-dextran in poly(vinyl
pyrrolidone)/water: fluorescence recovery after photobleaching experiments,
1995HAS Hasse, H., Kany, H.-P., Tintinger, R., and Maurer, G., Osmotic virial coefficients of
aqueous poly(ethylene glycol) from laser-light scattering and isopiestic measurements,
1996PAR Park, I.H. and Choi, E.-J., Characterization of branched polyethyleneimine by laser light
scattering and viscometry, Polymer, 37, 313, 1996.
1996PEI Peiqiang, W., Siddiq, M., Huiying, C., Di, Q., and Wu, C., Laser light-scattering study of
poly(sulfoalkyl methacrylate)s in 0.1 M NaCl aqueous solution, Macromolecules, 29, 277,
1996.
1998CRO Crowther, N.J. and Eagland, D., Studies of aggregation in dilute solutions of the triblock
copolymer POE-POP-POE, Synperonic F87-I, Eur. Polym. J., 34, 605, 1998.
2003KAN Kany, H.-P., Hasse, H., and Maurer, G., Thermodynamic properties of aqueous poly(vinyl-
pyrrolidone) solutions from laser-light-scattering, membrane osmometry, and isopiestic
measurements, J. Chem. Eng. Data, 48, 689, 2003.
APPENDICES
Appendix 1 List of systems and properties in order of the polymers
_____________________________________________________________________________
Polymer(s) Solvent(s) Property Page(s)
_____________________________________________________________________________
Acrylamide/maleic anhydride copolymer
water A2 477
____________________________________________________________________________________
Acrylamide/sodium acrylate copolymer
water A2 477
____________________________________________________________________________________
Acrylamide/sodium 3-methylacrylamido-
3-methylbutanoate copolymer
water A2 477
____________________________________________________________________________________
Casein + ficoll
water LLE 105
____________________________________________________________________________________
Cellulose acetate
water enthalpy 413
____________________________________________________________________________________
Cellulose monoacetate
water enthalpy 413
____________________________________________________________________________________
Cellulose triacetate
water enthalpy 413
____________________________________________________________________________________
N-Cyclopropylacrylamide/vinylferrocene
copolymer
water LLE 81
____________________________________________________________________________________
Dextran
water VLE 29-32
water LLE 105-106
ethanol + water LLE 106-111
water enthalpy 377-378
water density 448-450
water A2 477-479
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Dextran + ficoll
water LLE 112
Dextran + gelatin
water LLE 113-115
Dextran + hydroxypropyldextran
water LLE 116
Dextran + methylcellulose
water LLE 117-118
Dextran + poly(ethylene glycol)
water VLE 60-65
water LLE 125-144,
306-309
water + amino acids or low
molecular peptides LLE 302-306
molecular peptides + salts LLE 318-323
water + salts LLE 315-318
water + urea LLE 306-312
Dextran + poly(ethylene glycol) monomethyl
ether
water LLE 118
Dextran + poly(N-vinylacetamide)
water LLE 119
Dextran + poly(vinyl alcohol)
water LLE 263-264
____________________________________________________________________________________
N,N-Diallylammonioethanoic acid/sulfur
dioxide copolymer + poly(ethylene glycol)
water LLE 167
____________________________________________________________________________________
N,N-Diethylacrylamide/vinylferrocene
copolymer
water LLE 81
____________________________________________________________________________________
N,N-Diethylaminoethyl methacrylate/
methyl methacrylate copolymer
water VLE 32
____________________________________________________________________________________
N,N-Dimethylacrylamide/butyl
acrylate copolymer
water LLE 331
____________________________________________________________________________________
N,N-Dimethylacrylamide/2-butoxyethyl
acrylate copolymer
water LLE 331
____________________________________________________________________________________
Appendices 489
_____________________________________________________________________________

_____________________________________________________________________________
N,N-Dimethylacrylamide/2-ethoxyethyl
acrylate copolymer
water LLE 331
____________________________________________________________________________________
N,N-Dimethylacrylamide/ethyl
acrylate copolymer
water LLE 331
____________________________________________________________________________________
N,N-Dimethylacrylamide/2-methoxyethyl
acrylate copolymer
water LLE 331
____________________________________________________________________________________
N,N-Dimethylacrylamide/methyl
acrylate copolymer
water LLE 332
____________________________________________________________________________________
N,N-Dimethylacrylamide/propyl
acrylate copolymer
water LLE 332
____________________________________________________________________________________
N-Ethylacrylamide/vinylferrocene copolymer
water LLE 81
____________________________________________________________________________________
Ethylcellulose
water enthalpy 414
____________________________________________________________________________________
Ethylene/vinyl acetate copolymer
water Henry 74
water enthalpy 414
____________________________________________________________________________________
water LLE 332
− PVT 431-432
____________________________________________________________________________________
water VLE 32-33, 58
water LLE 82
water LLE 332
water VE 450
water A2 479
+ hydroxypropyl starch
water LLE 119-122
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Ethyl(hydroxyethyl)cellulose
water + salts LLE 171
water LLE 332
____________________________________________________________________________________
Ficoll + casein
water LLE 105
Ficoll + dextran
water LLE 112
____________________________________________________________________________________
Gelatin
water enthalpy 378
Gelatin + dextran
water LLE 113-115
____________________________________________________________________________________
Hydroxyethylcellulose
water VLE 33
____________________________________________________________________________________
water VLE 33
water LLE 333
water Henry 74
____________________________________________________________________________________
Hydroxypropyldextran + dextran
water LLE 116
____________________________________________________________________________________
Hydroxypropyl starch
water VLE 33-34
Hydroxypropyl starch + ethylene oxide/
propylene oxide copolymer
water LLE 119-122
Hydroxypropyl starch + poly(ethylene glycol)
water VLE 65-66
water LLE 145-148
____________________________________________________________________________________
water LLE 333
water A2 479
____________________________________________________________________________________
N-Isopropylacrylamide/acrylic acid copolymer
water LLE 82-83
____________________________________________________________________________________
Appendices 491
_____________________________________________________________________________

____________________________________________________________________________________
amido-D-glucitol copolymer
water LLE 83-84
water LLE 333
water HPPE 365-366
____________________________________________________________________________________
N-Isopropylacrylamide/N-isopropylmeth-
water LLE 333-334
_____________________________________________________________________________
N-Isopropylacrylamide/itaconic acid copolymer
water LLE 84
____________________________________________________________________________________
N-Isopropylacrylamide/vinylferrocene
copolymer
water LLE 84
____________________________________________________________________________________
N-Isopropylacrylamide/1-vinylimidazole
copolymer
water LLE 84
____________________________________________________________________________________
Maltodextrin + poly(ethylene glycol)
water LLE 148-151
Maltodextrin + poly(propylene glycol)
water LLE 160-161
____________________________________________________________________________________
Maltopentaose
water VLE 34
water enthalpy 378
____________________________________________________________________________________
Maltotetraose
water VLE 34
water enthalpy 378
____________________________________________________________________________________
Maltotriose
water VLE 34
water enthalpy 379
____________________________________________________________________________________
Methylcellulose
water LLE 85
water LLE 334
water enthalpy 415
Methylcellulose + dextran
water LLE 117-118
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Methylcellulose + sodium dextran sulfate
water LLE 171-172
____________________________________________________________________________________
Methyl(hydroxypropyl)cellulose
water LLE 334
____________________________________________________________________________________
Oxyethylcellulose
water enthalpy 379
____________________________________________________________________________________
Penta(ethylene glycol)
water enthalpy 379
____________________________________________________________________________________
Penta(ethylene glycol) monodecyl ether
water LLE 334
____________________________________________________________________________________
Penta(ethylene glycol) monododecyl ether
water LLE 334
____________________________________________________________________________________
water HPPE 366-367
____________________________________________________________________________________
water LLE 334
____________________________________________________________________________________
Perfluoro(oxyethylene/oxymethylene)
copolymer
− PVT 432-434
____________________________________________________________________________________
Poly(acrylic acid)
water VLE 35
water A2 480
____________________________________________________________________________________
Poly(acrylic acid) salts
2-propanol + water LLE 173
water A2 483
Poly(acrylic acid) salts + poly(ethylene glycol)
water LLE 212-218
Poly(acrylic acid) salts + poly(ethylene oxide)
water LLE 247-251
Poly(acrylic acid) salts + poly(1-vinyl-2-
pyrrolidinone)
water LLE 266-272
____________________________________________________________________________________
Appendices 493
_____________________________________________________________________________

_____________________________________________________________________________
Poly(acrylamide)
water VLE 58-59
water A2 480
____________________________________________________________________________________
Poly(allylamine hydrochloride)
water A2 479
____________________________________________________________________________________
Poly[bis(2-(2'-methoxyethoxy)ethoxy)
phosphazene]
water LLE 335
____________________________________________________________________________________
Poly[bis(2,3-bis(2-methoxyethoxy)propanoxy)
phosphazene]
water LLE 335
____________________________________________________________________________________
Poly[bis(2,3-bis(2-(2'-methoxyethoxy)ethoxy)
propanoxy)phosphazene]
water LLE 335
____________________________________________________________________________________
Poly[bis(2,3-bis(2-(2'-(2''-dimethoxyethoxy)
ethoxy)ethoxy)propanoxy)phosphazene]
water LLE 335
____________________________________________________________________________________
Poly(1,2-butylene glycol) dimethyl ether
− PVT 434
____________________________________________________________________________________
Polycarbonate-bisphenol-A
water VLE 35
____________________________________________________________________________________
Poly(N-cyclopropylacrylamide)
water LLE 85
____________________________________________________________________________________
Poly(N,N-diethylacrylamide)
water LLE 86, 335
methanol + water LLE 122
____________________________________________________________________________________
Poly(N,N-diethylaminoethyl methacrylate)
water VLE 35
____________________________________________________________________________________
Poly(dimethyldiallylammonium chloride)
water A2 481
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Poly(1,3-dioxolane)
water VE 450
____________________________________________________________________________________
Polyester (hyperbranched, aliphatic)
water VLE 35-36
water LLE 86
water + carbon dioxide HPPE 370
____________________________________________________________________________________
Polyesteramide (hyperbranched)
water VLE 36
____________________________________________________________________________________
Polyetherimide
water Henry 74
N,N-dimethylformamide +
water LLE 122
N,N-dimethylformamide
+ 1-methyl-2-pyrrolidinone
+ water LLE 301
Polyetherimide + poly(1-vinyl-2-pyrrolidinone)
1-methyl-2-pyrrolidinone
+ water LLE 301-302
____________________________________________________________________________________
Polyethersulfone
water VLE 59
water LLE 123-124
____________________________________________________________________________________
Polyetherurethane
water LLE 124
____________________________________________________________________________________
Poly(N-ethylacrylamide)
water LLE 86
____________________________________________________________________________________
water VLE
36-51
water + salts VLE
60, 66-67,
70-72
water Henry 74-76
water LLE 86-90,
335
1,2-ethanediol + water LLE 144
water + glucose LLE 145
1,2,3-propanetriol + water LLE 152
____________________________________________________________________________________
Appendices 495
_____________________________________________________________________________

_____________________________________________________________________________
water + salts LLE 173-212,
227-233,
234-247,
water + salts + urea LLE 323-327
− PVT 434-437
water VE 451-459
water A2 481
Poly(ethylene glycol) + deca(ethylene glycol)
monocetyl ether
water LLE 124
Poly(ethylene glycol) + deca(ethylene glycol)
monooleyl ether
water LLE 125
Poly(ethylene glycol) + dextran
water VLE 60-65
water LLE 125-144,
306-309
molecular peptides LLE 302-306
molecular peptides + salts LLE 318-323
water + urea LLE 306-312
Poly(ethylene glycol) + N,N-diallylammonio-
ethanoic acid/sulfur dioxide copolymer
water LLE 167
Poly(ethylene glycol) + hydroxypropyl starch
water VLE 65-66
water LLE 145-148
Poly(ethylene glycol) + maltodextrin
water LLE 148-151
Poly(ethylene glycol) + poly(acrylic acid) salts
water LLE 212-218
Poly(ethylene glycol) + poly(diallyldimethyl-
ammonium chloride)
water LLE 218-219
Poly(ethylene glycol) + poly(ethylene glycol)
water VLE 67-69
water LLE 312-314
Poly(ethylene glycol) + poly(ethylene sulfonic
acid) sodium salt
water LLE 219-222
Poly(ethylene glycol) + poly(methacrylic acid)
sodium salt
water LLE 222-226
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Poly(ethylene glycol) + poly(propylene glycol)
water VLE 69-70
Poly(ethylene glycol) + polysaccharide
water LLE 151
Poly(ethylene glycol) + poly(styrene sulfonic
acid) sodium salt
water LLE 226-227
Poly(ethylene glycol) + sodium dextran sulfate
water LLE 233-234
____________________________________________________________________________________
Poly(ethylene glycol) allyl ether methyl ether
water VE 464
____________________________________________________________________________________
Poly(ethylene glycol) dimethyl ether
carbon dioxide +
diisopropanolamine + water HPPE 371
hydrogen +
diisopropanolamine + water HPPE 371-372
nitrogen +
diisopropanolamine + water HPPE 372
− PVT 437-438
____________________________________________________________________________________
Poly(ethylene glycol) monoallyl ether
water VE 464
____________________________________________________________________________________
Poly(ethylene glycol) monoallyl ether acetate
water VE 464
____________________________________________________________________________________
Poly(ethylene glycol) monoallyl ether
phenylurethane
water VE 464
____________________________________________________________________________________
Poly(ethylene glycol) monododecyl ether
water enthalpy 397
____________________________________________________________________________________
Poly(ethylene glycol) monomethyl ether
− PVT 438
+ dextran
water LLE 118
____________________________________________________________________________________
water VLE 51
water Henry 76-77
____________________________________________________________________________________
Appendices 497
_____________________________________________________________________________

_____________________________________________________________________________
water LLE 336
water + salts LLE 247, 254-
255
water HPPE 367
water enthalpy 398
− PVT 439
water VE 464-465
water A2 481
Poly(ethylene oxide) + poly(acrylic acid)
sodium salt
water LLE 247-251
Poly(ethylene oxide) + poly(ethylene sulfonic
acid) sodium salt
water LLE 251-253
Poly(ethylene oxide) + poly(propylene oxide)
water LLE 152
Poly(ethylene oxide) + poly(vinyl methyl ether)
water LLE 152-154
____________________________________________________________________________________
fumarate)-b-poly(ethylene oxide) dimethyl
ether triblock copolymer
water LLE 90
____________________________________________________________________________________
diblock copolymer
water + maltose LLE 154
water + N-methylacetamide LLE 155
____________________________________________________________________________________
b-poly(ethylene oxide) triblock copolymer
water LLE 90, 336
− PVT 440
water VE 465
water A2 482
____________________________________________________________________________________
Poly(ethylene sulfonic acid) sodium salt
+ poly(ethylene glycol)
water LLE 219-222
+ poly(ethylene oxide)
water LLE 251-253
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
+ poly(1-vinyl-2-pyrrolidinone)
water LLE 272-275
____________________________________________________________________________________
Polyethylenimine
water VLE 51-52
water A2 482
____________________________________________________________________________________
Polyglycerol
water VLE 52-53
ethanol + water VLE 72
water LLE 91
tetrahydrofuran + water LLE 155-156
____________________________________________________________________________________
Poly(L-glutamic acid)
water A2 482
____________________________________________________________________________________
water VLE 53
water LLE 91-93,
336
1-butanol + water LLE 156
dimethylsulfoxide + water LLE 156
ethanol + water LLE 156
1,2,3-propanetriol + water LLE 157
water + urea LLE 157
water HPPE 367-368
water enthalpy 399
____________________________________________________________________________________
Poly(N-isopropyl methacrylamide)
water LLE 336
____________________________________________________________________________________
Poly(N-isopropylmethacrylamide) -poly[(N-
acetylimino)ethylene] block copolymer
water LLE 336
____________________________________________________________________________________
Poly(N-isopropylmethacrylamide) -poly[(N-
acetylimino)ethylene] graft copolymer
water LLE 336
____________________________________________________________________________________
Appendices 499
_____________________________________________________________________________

_____________________________________________________________________________
Poly(methacrylamide)
water A2 482
____________________________________________________________________________________
water A2 482-483
____________________________________________________________________________________
Poly(methacrylic acid) sodium salt
water LLE 222-226
Poly(methacrylic acid) sodium salt
water LLE 275-278
____________________________________________________________________________________
Poly(3-methylacrylamido-3-methyl-
butanoic acid) sodium salt
water A2 483
____________________________________________________________________________________
Polyol (hyperbranched)
water LLE 93
____________________________________________________________________________________
water VLE 53-54
water LLE 336
water + maltose LLE 158-159
− PVT 441-444
water VE 467-468
Poly(propylene glycol) + maltodextrin
water LLE 160-161
Poly(propylene glycol) + poly(ethylene glycol)
water VLE 69-70
____________________________________________________________________________________
Poly(propylene oxide)
water VLE 54
Poly(propylene oxide) + poly(ethylene oxide)
water LLE 152
____________________________________________________________________________________
Polysaccharide + poly(ethylene glycol)
water LLE 151
____________________________________________________________________________________
Poly(sodium sulfodecyl methacrylate)
water A2 483
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Poly(sodium sulfoethyl methacrylate)
water A2 483
____________________________________________________________________________________
Poly(sodium sulfohexyl methacrylate)
water A2 483
____________________________________________________________________________________
Poly(sodium sulfooctyl methacrylate)
water A2 483
____________________________________________________________________________________
Polystyrene
water Henry 77
water enthalpy 415
____________________________________________________________________________________
Poly(styrene sulfonic acid) + salts
Poly(styrene sulfonic acid) sodium salt
water LLE 226-227
____________________________________________________________________________________
Poly(styrene sulfonic acid) sodium salt
water LLE 278
____________________________________________________________________________________
Polysulfone
water VLE 73
water Henry 77
water LLE 161-164
Polysulfone + poly(1-vinyl-2-pyrrolidinone)
+ water LLE 314
____________________________________________________________________________________
Poly(tetramethylene glycol)
water VLE 54
____________________________________________________________________________________
Poly(tetramethylene oxide)
− PVT 445
____________________________________________________________________________________
Poly(N-vinylacetamide)
Poly(N-vinylacetamide) + dextran
water LLE 119
____________________________________________________________________________________
Appendices 501
_____________________________________________________________________________

_____________________________________________________________________________
Poly(vinyl alcohol)
water VLE 55-56
ethanol + water VLE 73
water LLE 336
water A2 484
Poly(vinyl alcohol) + dextran
water LLE 263-264
Poly(vinyl alcohol) + sodium dextran sulfate
water LLE 264
____________________________________________________________________________________
Poly(vinylbenzyltrimethylammonium)
halogenide
____________________________________________________________________________________
Poly(1-vinyl-N-butylpyridinium bromide)
water enthalpy 406
____________________________________________________________________________________
water LLE 94, 337
____________________________________________________________________________________
Poly(vinyl chloride)
tetrahydrofuran + water HPPE 372-373
water enthalpy 415
____________________________________________________________________________________
Poly(1-vinyl-3,5-dimethyl-1,2,4-triazole)
water enthalpy 407
____________________________________________________________________________________
Poly(1-vinylimidazole)
water enthalpy 407
____________________________________________________________________________________
water LLE 94, 337
____________________________________________________________________________________
water VLE 56
water LLE 95, 337
ethanol + water LLE 165
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
− PVT 445-446
Poly(vinyl methyl ether) + poly(ethylene oxide)
water LLE 152-154
____________________________________________________________________________________
Poly(N-vinyl-N-propylacetamide)
water LLE 337
____________________________________________________________________________________
water VLE 56-57
water enthalpy 407
water A2 484
Poly(1-vinyl-2-pyrrolidinone) + poly(acrylic
acid) salts
water LLE 266-272
Poly(1-vinyl-2-pyrrolidinone) + polyetherimide
+ water LLE 301-302
Poly(1-vinyl-2-pyrrolidinone) + poly(ethylene
sulfonic acid) sodium salt
water LLE 272-275
Poly(1-vinyl-2-pyrrolidinone) + poly(meth-
acrylic acid) sodium salt
water LLE 275-278
Poly(1-vinyl-2-pyrrolidinone) + poly(styrene
sulfonic acid) sodium salt
water LLE 278
Poly(1-vinyl-2-pyrrolidinone) + polysulfone
+ water LLE 314
____________________________________________________________________________________
Poly(2-vinylpyridine)
water A2 484
____________________________________________________________________________________
Poly(1-vinyl-1,2,4-triazole)
water enthalpy 407
____________________________________________________________________________________
Pullulan
water A2 484
____________________________________________________________________________________
Appendices 503
_____________________________________________________________________________

_____________________________________________________________________________
Sodium dextran sulfate + methylcellulose
water LLE 171-172
Sodium dextran sulfate + poly(ethylene glycol)
water LLE 233-234
Sodium dextran sulfate + poly(vinyl alcohol)
water LLE 264
____________________________________________________________________________________
Tetra(ethylene glycol)
water VE 469
____________________________________________________________________________________
Tetra(ethylene glycol) diethyl ether
water LLE 337
water enthalpy 408
____________________________________________________________________________________
Tetra(ethylene glycol) dimethyl ether
water enthalpy 408
− PVT 446-447
____________________________________________________________________________________
Tetra(ethylene glycol) monodecyl ether
water LLE 95, 337
____________________________________________________________________________________
water LLE 337
____________________________________________________________________________________
Tetra(ethylene glycol) monohexyl ether
water LLE 337
____________________________________________________________________________________
water LLE 337
water enthalpy 409
water VE 469-470
____________________________________________________________________________________
Tri(ethylene glycol) dimethyl ether
− PVT 447
____________________________________________________________________________________
Tri(ethylene glycol) monohexyl ether
water LLE 337
water VE 470
____________________________________________________________________________________
water LLE 337
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
N-Vinylacetamide/vinyl acetate copolymer
water LLE 338
____________________________________________________________________________________
Vinyl acetate/vinyl alcohol copolymer
water VLE 57
water LLE 95
____________________________________________________________________________________
water LLE 338
____________________________________________________________________________________
Vinylamine/N-vinylcaprolactam copolymer
water LLE 338
____________________________________________________________________________________
N-Vinylcaprolactam/1-vinylimidazole
copolymer
water LLE 96
____________________________________________________________________________________
N-Vinylisobutyramide/N-vinylamine
copolymer
water LLE 96
____________________________________________________________________________________
water LLE 338
____________________________________________________________________________________
Appendices 505
_____________________________________________________________________________
Appendix 2 List of solvents in alphabetical order
_____________________________________________________________________________
Name Formula CAS-RN Page(s)
_____________________________________________________________________________
acetic acid C2H4O2 64-19-7 283, 417
2,3-butanediol C4H10O2 513-85-9 329
butanoic acid C4H8O2 107-92-6 286
1-butanol C4H10O 71-36-3 156, 286, 294, 296, 329
2-butoxyethanol C6H14O2 111-76-2 290, 293
carbon dioxide CO2 124-38-9 370, 374
chlorobenzene C6H5Cl 108-90-7 293
cyclohexane C6H12 110-82-7 296, 374
cyclohexanol C6H12O 108-93-0 296
dichloromethane CH2Cl2 75-09-2 293
1,3-diethylurea C5H12N2O 623-76-7 296, 300
diisopropanolamine C6H15NO2 110-97-4 371-372
N,N-dimethylacetamide C4H9NO 127-19-5 162-163, 290, 294, 297-298,
329
N,N-dimethylformamide C3H7NO 68-12-2 59, 73, 123-124, 163, 290, 294-
295, 297-298, 301, 329-330
dimethylpropyleneurea C6H12N2O 89607-25-0 290, 297-298
1,3-dimethylurea C3H8N2O 96-31-1 296, 300
2,6-dimethylpyridine C7H9N 108-48-5 293
dimethylsulfoxide C2H6OS 67-68-5 157, 164-165, 286, 290, 294-
295, 297-298
1,4-dioxane C4H8O2 123-91-1 283, 289, 294-296, 330
n-dodecane C12H26 112-40-3 374
1,2-ethanediol C2H6O2 107-21-1 144, 291
ethanol C2H6O 64-17-5 72-73, 106-110, 157, 165, 172,
261, 284, 286, 289, 294-297,
329
formamide CH3NO 75-12-7 296, 300, 328
formic acid CH2O2 64-18-6 288-289
1-heptanol C7H16O 111-70-6 286
hexamethylphosphotriamide C6H18N3OP 680-31-9 298
n-hexane C6H14 110-54-3 293
1,2-hexanediol C6H14O2 6920-22-5 330
1-hexanol C6H14O 111-27-3 286, 329
hydrogen H2 1333-74-0 371
isobutyric acid C4H8O2 79-31-2 293
isopropyl myristate C17H34O2 110-27-0 294, 330
methacrylic acid C4H6O2 79-41-4 296
methanol CH4O 67-56-1 122, 157, 165-166, 287, 290,
295-296, 298-299, 422
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
methanol-d4 CD4O 811-98-3 165
N-methylacetamide C3H7NO 79-16-3 155, 294
1-methyl-2-pyrrolidinone C5H9NO 872-50-4 122-123, 290, 294, 296-297,
301, 314, 329-330
nitrogen N2 7727-37-9 372
n-octane C8H18 111-65-9 296, 328, 330
1,2-octanediol C8H18O2 1117-86-8 330
1-octanol C8H18O 111-87-5 328, 330
1-pentanol C5H12O 71-41-0 287, 329
1-phenylbutane C10H14 104-51-8 297
2-phenylethanol C8H10O 60-12-8 294
1-phenylheptane C13H20 1078-71-3 297
1-phenylhexane C12H18 1077-16-3 297
1-phenyloctane C14H22 2189-60-8 297
1-phenylpentane C11H16 538-68-1 297
3-phenyl-1-propanol C9H12O 122-97-4 329
1,2,3-propanetriol C3H8O3 56-81-5 152, 157, 288, 292
propanoic acid C3H6O2 79-09-4 286-287
1-propanol C3H8O 71-23-8 158, 287, 295-297, 329
2-propanol C3H8O 67-63-0 166, 172, 262, 286, 295-296
2-propanone C3H6O 67-64-1 284, 294-296
tetrahydrofuran C4H8O 109-99-9 156, 284, 289, 293-294, 296-
297, 372-373
tetramethylurea C5H12N2O 632-22-4 290, 297-298
trichloromethane CHCl3 67-66-3 293
triethyl phosphate C6H15O4P 78-40-0 298
trimethyl phosphate C3H9O4P 512-56-1 298
water H2O 7732-18-5 all data pages
_____________________________________________________________________________
Appendices 507
_____________________________________________________________________________
Appendix 3 List of solvents in order of their molecular formulas
_____________________________________________________________________________
Formula Name CAS-RN Page(s)
_____________________________________________________________________________
CD4O methanol-d4 811-98-3 165
CHCl3 trichloromethane 67-66-3 293
CH2Cl2 dichloromethane 75-09-2 293
CH2O2 formic acid 64-18-6 288-289
CH3NO formamide 75-12-7 296, 300, 328
CH4O methanol 67-56-1 122, 157, 165-166, 287, 290,
295-296, 298-299, 422
CO2 carbon dioxide 124-38-9 370, 374
C2H4O2 acetic acid 64-19-7 283, 417
C2H6O ethanol 64-17-5 72-73, 106-110, 157, 165, 172,
261, 284, 286, 289, 294-297,
329
C2H6OS dimethylsulfoxide 67-68-5 157, 164-165, 286, 290, 294-
295, 297-298
C2H6O2 1,2-ethanediol 107-21-1 144, 291
C3H6O 2-propanone 67-64-1 284, 294-296
C3H6O2 propanoic acid 79-09-4 286-287
C3H7NO N,N-dimethylformamide 68-12-2 59, 73, 123-124, 163, 290, 294-
295, 297-298, 301, 329-330
C3H7NO N-methylacetamide 79-16-3 155, 294
C3H8N2O 1,3-dimethylurea 96-31-1 296, 300
C3H8O 1-propanol 71-23-8 158, 287, 295-297, 329
C3H8O 2-propanol 67-63-0 166, 172, 262, 286, 295-296
C3H8O3 1,2,3-propanetriol 56-81-5 152, 157, 288, 292
C3H9O4P trimethyl phosphate 512-56-1 298
C4H6O2 methacrylic acid 79-41-4 296
C4H8O tetrahydrofuran 109-99-9 156, 284, 289, 293-294, 296-
297, 372-373
C4H8O2 butanoic acid 107-92-6 286
C4H8O2 1,4-dioxane 123-91-1 283, 289, 294-296, 330
C4H8O2 isobutyric acid 79-31-2 293
C4H9NO N,N-dimethylacetamide 127-19-5 162-163, 290, 294, 297-298,
329
C4H10O 1-butanol 71-36-3 156, 286, 294, 296, 329
C4H10O2 2,3-butanediol 513-85-9 329
C5H9NO 1-methyl-2-pyrrolidinone 872-50-4 122-123, 290, 294, 296-298,
301, 314, 329-330
C5H12N2O 1,3-diethylurea 623-76-7 296, 300
C5H12N2O tetramethylurea 632-22-4 290, 297-298
C5H12O 1-pentanol 71-41-0 287, 329
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
C6H5Cl chlorobenzene 108-90-7 293
C6H12 cyclohexane 110-82-7 296, 374
C6H12N2O dimethylpropyleneurea 89607-25-0 290, 297-298
C6H12O cyclohexanol 108-93-0 296
C6H14 n-hexane 110-54-3 293
C6H14O 1-hexanol 111-27-3 286, 329
C6H14O2 2-butoxyethanol 111-76-2 290, 293
C6H14O2 1,2-hexanediol 6920-22-5 330
C6H15NO2 diisopropanolamine 110-97-4 371-372
C6H15O4P triethyl phosphate 78-40-0 298
C6H18N3OP hexamethylphosphotriamide 680-31-9 298
C7H9N 2,6-dimethylpyridine 108-48-5 293
C7H16O 1-heptanol 111-70-6 286
C8H10O 2-phenylethanol 60-12-8 294
C8H18 n-octane 111-65-9 296, 328, 330
C8H18O 1-octanol 111-87-5 328, 330
C8H18O2 1,2-octanediol 1117-86-8 330
C9H12O 3-phenyl-1-propanol 122-97-4 329
C10H14 1-phenylbutane 104-51-8 297
C11H16 1-phenylpentane 538-68-1 297
C12H18 1-phenylhexane 1077-16-3 297
C12H26 n-dodecane 112-40-3 374
C13H20 1-phenylheptane 1078-71-3 297
C14H22 1-phenyloctane 2189-60-8 297
C17H34O2 isopropyl myristate 110-27-0 294, 330
H2 hydrogen 1333-74-0 371
H 2O water 7732-18-5 all data pages
N2 nitrogen 7727-37-9 372
_____________________________________________________________________________
509
INDEX
A F experimental methods, 16
experimental data, 431-447
Activity Freezing point depression, 18
experimental data, 29-73 S
solvent, 2-19 G
Activity coefficient, 8-9,16 Scattering methods, 18-19
Gas-liquid chromatography Second virial coefficient
B data reduction, 8-9 experimental methods, 17
experimental methods, 6-7 experimental data, 477-484
Boiling point increase, 18 inverse, definition, 6 Sedimentation
coefficient, 19
C H diffusion equilibrium, 19
Concentration Heat, see: Enthalpy T

critical, 12 Henry’s constant
feed, 11 equation, 9 Temperature
lowering, 4 data, 74-77 LCST, 11, 331-338
measures, 21-22 High-pressure phase equilibrium UCST, 11, 331-338
Continuous thermodynamics, 12 experimental data, 365-374
Critical exponent, 12 experimental methods, 12-13 U
Critical point
definition, 11-12 L Ultracentrifuge, 19
Liquid-liquid equilibrium (LLE) V
D experimental data, 81-338
experimental methods, 11-12 Vapor-liquid equilibrium (VLE)
Density experimental data, 29-73
experimental methods, 16 experimental methods, 2-6
experimental data, 448-470 M measurement, 2-6
mixture, 17 Vapor pressure
Diffusion Molar mass depression, 18
coefficient, 10, 19 averages, definition, 20 experimental data, 29-73
effect, 2 distribution function, 11-12, 20 experimental methods, 2-6
in equations, 8-9, 17-19 partial, 8, 18, 29-73
E Vapor-pressure osmometry
O data reduction, 10-11
Enthalpy experimental methods, 10
data reduction, 13-16 Osmotic pressure, 18 Volume
excess, see: Enthalpy of mixing excess, 17, 448-470
experimental data, 377-423 P molar, 9, 18
experimental methods, 13 Pressure specific, 17
partial, 13-15, 413-415 column inlet, 8
Enthalpy of mixing, 13, 377-412 column outlet, 8
Enthalpy of solution, 14, 377-413 PVT-behavior
3246_half 11/23/04 12:31 PM Page 1
CRC HANDBOOK OF
THERMODYNAMIC
DATA of
POLYMER
SOLUTIONS at
ELEVATED
PRESSURES
3246_title 12/16/04 10:18 AM Page 1
CRC HANDBOOK OF
THERMODYNAMIC
DATA of
POLYMER
SOLUTIONS at
ELEVATED
PRESSURES
Christian Wohlfarth
Boca Raton London New York Singapore
A CRC title, part of the Taylor & Francis imprint, a member of the
Taylor & Francis Group, the academic division of T&F Informa plc.
3246-discl. Page 1 Monday, December 6, 2004 12:12 PM
Library of Congress Cataloging-in-Publication Data
Wohlfarth, C.
CRC handbook of thermodynamics data of polymer solutions at elevated pressures / Christian Wohlfarth.
p. cm.
Includes bibliographical references and index.
ISBN 0-8493-3246-X (alk. paper)
1. Polymer solutions--Thermal properties--Handbooks, manuals, etc. 2. Thermodynamics--
Handbooks, manuals, etc. I. Title.
QD381.9.S65W636 2005
547'.704569--dc22 2004058530
This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with
permission, and sources are indicated. A wide variety of references are listed. Reasonable efforts have been made to publish
reliable data and information, but the author and the publisher cannot assume responsibility for the validity of all materials
or for the consequences of their use.
Neither this book nor any part may be reproduced or transmitted in any form or by any means, electronic or mechanical,
including photocopying, microfilming, and recording, or by any information storage or retrieval system, without prior
permission in writing from the publisher.
The consent of CRC Press LLC does not extend to copying for general distribution, for promotion, for creating new works,
or for resale. Specific permission must be obtained in writing from CRC Press LLC for such copying.
Direct all inquiries to CRC Press LLC, 2000 N.W. Corporate Blvd., Boca Raton, Florida 33431.
identification and explanation, without intent to infringe.
Visit the CRC Press Web site at www.crcpress.com
© 2005 by CRC Press LLC

International Standard Book Number 0-8493-3246-X
Library of Congress Card Number 2004058530
Printed in the United States of America 1 2 3 4 5 6 7 8 9 0
Printed on acid-free paper
PREFACE

polymer solutions, for studying intermolecular interactions, and for gaining insights into the molecular
Polymer Solutions at Elevated Pressures continues the two former ones, the CRC Handbook of
Thermodynamic Data of Copolymer Solutions and the CRC Handbook of Thermodynamic Data of
Aqueous Polymer Solutions, in providing a reliable collection of data for polymer solutions from the
original literature.,
The Handbook is again divided into seven chapters: (1) Introduction, (2) Vapor-Liquid
Equilibrium (VLE) Data and Gas Solubilities at Elevated Pressures, (3) Liquid-Liquid Equilibrium (LLE)
Data of Polymer Solutions at Elevated Pressures, (4) High-Pressure Fluid Phase Equilibrium (HPPE) Data
of Polymer Solutions, (5) Enthalpy Changes in Polymer Solutions at Elevated Pressures, (6) PVT Data of
Polymers and Solutions, and (7) Pressure Dependence of the Second Virial Coefficients (A2) of Polymer
Solutions. Finally, appendices quickly route the user to the desired data sets. Thus, the book covers all the
necessary areas for researchers and engineers who work in this field.
In comparison with low-molecular systems, the amount of data for polymer solutions at elevated
pressures is still rather small. About 650 literature sources were perused for the purpose of this Handbook,
including some dissertations and diploma papers. About 1600 data sets, i.e., about 400 VLE/gas solubility
isotherms, 250 LLE and 800 HPPE data sets, a number of volumetric and enthalpic data and some second
virial coefficients, are reported. Additionally, tables of systems are provided where results were published
only in graphical form in the original literature to lead the reader to further sources. Data are included
only if numerical values were published or authors provided their numerical results by personal
communication (and I wish to thank all those who did so). No digitized data have been included in this
data collection. The Handbook is the first complete overview about this subject in the world’s literature.
The closing day for the data collection was June, 30, 2004. The Handbook results from parts of a more
general database, Thermodynamic Properties of Polymer Systems, which is continuously updated by the
author. Thus, the user who is in need of new additional data sets is kindly invited to ask for new
information beyond this book via e-mail at wohlfarth@chemie.uni-halle.de. Additionally, the author will
be grateful to users who call his attention to mistakes and make suggestions for improvements.
The CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures will be
useful to researchers, specialists, and engineers working in the fields of polymer science, physical
chemistry, chemical engineering, material science, biological science and technology, and those
developing computerized predictive packages. The Handbook should also be of use as a data source to
Ph.D. students and faculty in Chemistry, Physics, Chemical Engineering, Biotechnology, and Materials
Science Departments at universities.
Christian Wohlfarth
Merseburg, August 2004
About the Author
Halle-Wittenberg, Germany. He earned his degree in chemistry in 1974 and wrote his Ph.D. thesis on
Since then, Dr. Wohlfarth’s main research has been related to polymer systems. Currently, his
research topics are molecular thermodynamics, continuous thermodynamics, phase equilibria in polymer
mixtures and solutions, polymers in supercritical fluids, PVT behavior and equations of state, and sorption
properties of polymers, about which he has published approximately 100 original papers. He has written
the books Vapor-Liquid Equilibria of Binary Polymer Solutions, CRC Handbook of Thermodynamic Data
of Copolymer Solutions, and CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions.

compounds and binary mixtures resulting in six volumes of the Landolt-Börnstein New Series. He is a
respected contributor to the CRC Handbook of Chemistry and Physics.
CONTENTS
1. INTRODUCTION
1.1. Objectives of the handbook...............................................................................................1
1.2. Experimental methods involved........................................................................................2
1.3. Guide to the data tables.....................................................................................................9
1.4. List of symbols................................................................................................................13
1.5. References.......................................................................................................................15
2. VAPOR-LIQUID EQUILIBRIUM (VLE) DATA AND GAS

SOLUBILITIES AT ELEVATED PRESSURES
2.1. Binary polymer solutions...................................................................................................17
2.2. Table of binary systems where data were published only
in graphical form as phase diagrams or related figures......................................................74
2.3. Ternary and quaternary polymer solutions.........................................................................84
2.4. Table of ternary systems where data were published only
2.5. References....................................................................................................................... 102

OF POLYMER SOLUTIONS AT ELEVATED PRESSURES
3.1. Cloud-point and/or coexistence curves of quasibinary solutions.....................................111
in graphical form as phase diagrams or related figures................................................... 196
3.3. Cloud-point and/or coexistence curves of quasiternary
and/or quasiquaternary solutions ....................................................................................202
3.4. Table of ternary or quaternary systems where data were published only
in graphical form as phase diagrams or related figures................................................... 215
temperatures at elevated pressures.................................................................................. 217
3.6. References.......................................................................................................................221
4. HIGH-PRESSURE FLUID PHASE EQUILIBRIUM (HPPE) DATA

OF POLYMER SOLUTIONS
4.1. Cloud-point and/or coexistence curves of quasibinary solutions.....................................227
4.3. Cloud-point and/or coexistence curves of quasiternary
and/or quasiquaternary solutions ....................................................................................407
4.4. Table of ternary or quaternary systems where data were published only
4.5. References .......................................................................................................................537
5. ENTHALPY CHANGES IN POLYMER SOLUTIONS
AT ELEVATED PRESSURES
5.1. Enthalpies of mixing or intermediary enthalpies of dilution ..........................................549
5.2. References......................................................................................................................550

6.1. PVT data of selected polymers ......................................................................................551
6.2. Excess volumes and/or densities at elevated pressures...................................................567
6.2.1. Binary polymer solutions...............................................................................567
6.2.2. Ternary polymer solutions.............................................................................592
6.3. References......................................................................................................................602
7. PRESSURE DEPENDENCE OF THE SECOND VIRIAL COEFFICIENTS (A2)

7.1. Experimental A2 data......................................................................................................605
7.2. Pressure coefficient of the second virial coefficient
(∂A2/∂P)T at zero pressure..............................................................................................612
7.3. References......................................................................................................................614
APPENDICES
Appendix 1 List of systems and properties in order of the polymers.....................................615
Appendix 2 List of solvents in alphabetical order..................................................................633
Appendix 3 List of solvents in order of their molecular formulas..........................................637
INDEX.....................................................................................................................................................641
1. INTRODUCTION

behavior of polymer solutions, for studying intermolecular interactions, and for gaining insights into the
database for polymer solutions at elevated pressures is even smaller. On the other hand, especially
polymer solutions in supercritical fluids are gaining increasing interest (1994MCH, 1997KIR) because of
their unique physical properties, and thermodynamic data at elevated pressures are needed for optimizing
applications, e.g., separation operations of complex mixtures in the high-pressure synthesis of polymers,
recovery of polymer wastes, precipitation, fractionation and purification of polymers, and polymers in
green chemistry processes.
Basic information on polymers can be found in the Polymer Handbook (1999BRA). Some data
books on polymer solutions appeared in the early 1990s (1990BAR, 1992WEN, 1993DAN, and
1994WOH), but most data for polymer solutions have been compiled during the last decade. A data book
with information on copolymer solutions appeared in 2001 (2001WOH) and on aqueous polymer
solutions in 2004 (2004WOH). No databooks or databases dedicated specially to polymer solutions at
elevated pressures presently exist. Thus, the intention of the Handbook is to fill this gap and to provide
scientists and engineers with an up-to-date compilation from the literature of the available thermodynamic
data on polymer solutions at elevated pressures. The Handbook does not present theories and models for
polymer solution thermodynamics. Other publications (1971YAM, 1990FUJ, 1990KAM, 1999KLE,
1999PRA, and 2001KON) can serve as starting points for investigating those issues.
• Vapor-liquid equilibrium (VLE) data and gas solubilities for binary or ternary
polymer solutions
• Liquid-liquid equilibrium (LLE) data of (quasi)binary, ternary, or quaternary
polymer solutions
• High-pressure fluid phase equilibrium (HPPE) data of (quasi)binary, ternary, or
quaternary polymer solutions
• Enthalpy changes for polymer solutions at elevated pressures
• PVT data of some selected polymers and their solutions as well as excess volumes
and densities at elevated pressures
• Second virial coefficients (A2) of polymer solutions at elevated pressures
chapters. Data are included only if numerical values were published or authors provided their results by
personal communication (and I wish to thank all those who did so). No digitized data have been included
in this data collection, but a number of tables include systems based on data published in graphical form.
2 CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures
____________________________________________________________________________________
At higher pressures, the classification of experimental data into vapor-liquid, liquid-liquid, or

fluid-fluid equilibrium data is not always simple. Also the expression ”elevated pressure” is more or less
relative. With respect to the latter, data are included here if at least some data points of a system were
measured at a pressure above normal pressure. With respect to a classification of experimental data into
the chapters 2, 3, or 4, practical reasons as well as theoretical considerations are applied. Practical reasons
are often chosen for systems when gas solubility data are given, but for some systems, gas solubilities are
given together with the cloud points in chapter 4. Theoretical considerations are taken into account for
most polymer systems with subcritical solvents and supercritical fluids. Van Konynenburg and Scott
(1980VAN) cited six classes of phase diagrams and showed that almost all known types of phase
equilibria of binary mixtures can be classified within their scheme. More recently, Yelash and Kraska
(1999YEL) developed global phase diagrams for mixtures of spherical molecules with non-spherical
molecules also including polymers. So, most of the systems in this book could at least be categorized into
the corresponding chapters in accordance to their rules. Nevertheless, sometimes problems remain for a
number of systems with subcritical or supercritical fluid solvents. Therefore, in chapter 4, the type of
equilibrium within one data set is sometimes stated individually for each data point.
Accordingly, a classical discussion of experimental methods for vapor-liquid or liquid-liquid

equilibrium measurements does not really fit here. Information about experimental methods for polymer
solutions at ordinary pressures can be found in (1975BON) and (2000WOH) or in the two former
handbooks (2001WOH and 2004WOH). Here, the classification also used by Christov and Dohrn
(2002CHR) is chosen where experimental methods for the investigation of high-pressure phase equilibria
are divided into two main classes, depending on how the composition is determined: analytical methods
(or direct sampling methods) and synthetic methods (or indirect methods).
Analytical methods
Analytical methods involve the determination of the composition of the coexisting phases. This
can be done by taking samples from each phase and analyzing them outside the equilibrium cell at normal
pressure or by using physicochemical methods of analysis inside the equilibrium cell under pressure. If
one needs the determination of more information than the total polymer composition, i.e., if one wants to
characterize the polymer with respect to molar mass (distribution) or chemical composition (distribution),
the sampling technique is unavoidable.
Withdrawing a large sample from an autoclave causes a considerable pressure drop, which
disturbs the phase equilibrium significantly. This pressure drop can be avoided by using a variable-volume
cell, by using a buffer autoclave in combination with a syringe pump or by blocking off a large sampling
volume from the equilibrium cell before pressure reduction. If only a small sample is withdrawn or if a
relatively large equilibrium cell is used, the slight pressure drop does not affect the phase composition
significantly. Small samples can be withdrawn using capillaries or special sampling valves. Often
sampling valves are directly coupled to analytical equipment.
Analytical methods can be classified as isothermal methods, isobaric-isothermal methods, and

isobaric methods.
Using the isothermal mode, an equilibrium cell is charged with the system of interest, the mixture
is heated to the desired temperature, and this temperature is then kept constant. The pressure is adjusted in
the heterogeneous region above or below the desired equilibrium value depending on how the equilibrium
1. Introduction 3
____________________________________________________________________________________
will change pressure. After intensive mixing over the time necessary for equilibrating the system, the
pressure reaches a plateau value. The equilibration time is the most important point for polymer solutions.
Due to their (high) viscosity and slow diffusion, equilibration will often need many hours or even days.
The pressure can be readjusted by adding or withdrawing of material or by changing the volume of the
cell if necessary. Before analyzing the compositions of the coexisting phases, the mixture is usually given
some time for a clear phase separation. Sampling through capillaries can lead to differential vaporization
(especially for mixtures containing gases and high-boiling solvents as well) when no precautions have
been taken to prevent a pressure drop all along the capillary. This problem can be avoided with an
experimental design that ensures that most of the pressure drop occurs at the end of the capillary.
Sometimes, one or more phases will be recirculated to reduce sampling problems. The use of
physicochemical methods of analysis inside the equilibrium cell, e.g., by a spectrometer, avoids the
problems related to sampling. On the other hand, time-consuming calibrations can be necessary. At the
end, isothermal methods need relatively simple and inexpensive laboratory equipment. If carried out
carefully, they can produce reliable results.
Isobaric-isothermal methods are often also called dynamic methods. One or more fluid streams
are pumped continuously into a thermostated equilibrium cell. The pressure is kept constant during the
experiment by controlling an effluent stream, usually of the vapor phase. One can distinguish between
continuous-flow methods and semi-flow methods. In continuous-flow methods, both phases flow through
the equilibrium cell. They can be used only for systems where the time needed to attain phase equilibrium
is sufficiently short. Therefore, such equipment is usually not applied to polymer solutions. In semi-flow
methods, only one phase is flowing while the other stays in the equilibrium phase. They are sometimes
called gas-saturation methods or pure-gas circulation methods and can be used to measure gas solubilities
in liquids and melts or solubilities of liquid or solid substances in supercritical fluids.
Isobaric methods provide an alternative to direct measurements of pressure-temperature

compositions in liquid phase compositions in vapor phase (P-T-wL-wV) data. This is the measurement of
(P-T-wL) data followed by a consistent thermodynamic analysis. Such isobaric analytical methods are
usually made in dynamic mode, too.
The main advantages of the analytical methods are that systems with more than two components
can be studied, several isotherms or isobars can be studied with one filling, and the coexistence data are
determined directly. The main disadvantage is that the method is not suitable near critical states or for
systems where the phases do not separate well. Furthermore, dynamic methods can be difficult in their
application to highly viscous media like concentrated polymer solutions where foaming may cause further
problems.
Synthetic methods
In synthetic methods, a mixture of known composition is prepared and the phase equilibrium is
observed subsequently in an equilibrium cell (the problem of analyzing fluid mixtures is replaced by the
problem of ”synthesizing” them). After known amounts of the components have been placed into an
equilibrium cell, pressure and temperature are adjusted so that the mixture is homogeneous. Then
temperature or pressure is varied until formation of a new phase is observed. This is the common way to
observe cloud points in demixing polymer systems. No sampling is necessary. Therefore, the experimental
equipment is often relatively simple and inexpensive. For multicomponent systems, experiments with
synthetic methods yield less information than with analytical methods, because the tie lines cannot be
determined without additional experiments. This is specially true for polymer solutions where
fractionation accompanies demixing.
____________________________________________________________________________________
The appearance of a new phase is either detected visually or by monitoring physical properties.
Visually, the beginning of turbidity in the system or the meniscus in a view cell can be observed.
Otherwise, light scattering is the common method to detect the formation of the new phase. Both visual
and non-visual synthetic methods are widely used in investigations on polymer systems at elevated
pressures. The problem of isorefractive systems (where the coexisting phases have approximately the
same refractive index) does not belong to polymer solutions where the usually strong concentration
dependence of their refractive index prevents such a behavior. If the total volume of a variable-volume
cell can be measured accurately, the appearance of a new phase can be observed from the abrupt change in
the slope of a pressure-volume plot. An example is given in chapter 4. The changes of other physical
properties like viscosity, ultrasonic absorption, thermal expansion, dielectric constant, heat capacity, or
UV and IR absorption are also applied as non-visual synthetic methods for polymer solutions.
A common synthetic method for polymer solutions is the (P-T-wL) experiment. An equilibrium
cell is charged with a known amount of polymer, evacuated and thermostated to the measuring
temperature. Then the second component (gas, fluid, solvent) is added and the pressure increases. The
second component dissolves into the (amorphous or molten) polymer and the pressure in the equilibrium
cell decreases. Therefore, this method is sometimes called pressure-decay method. Pressure and
temperature are registered after equilibration. No samples are taken. The composition of the vapor phase
is calculated using a phase equilibrium model if two or more gases or solvents are involved. The
determination of the volume of gas or solvent vaporized in the unoccupied space of the apparatus is
important as it can cause serious errors in the determination of their final concentrations. The composition
of the liquid phase is often obtained by weighing and using the material balance. By repeating the addition
of the second component into the cell, several points along the vapor/gas-liquid equilibrium line can be
measured. This method is usually applied for all gas solubility/vapor sorption/vapor pressure investiga-
tions in systems with polymers.
The synthetic method is particularly suitable for measurements near critical states. Simultaneous
determination of PVT data is possible.
Some problems related to systems with polymers
Details of experimental equipment can be found in the original papers compiled for this book and
will not be presented here. Only some problems should be summarized that have to be obeyed and solved
during the experiment.
The polymer solution is often of an amount of some cm3 and may contain about 1g of polymer or
even more. Therefore, the equilibration of prepared solutions can be difficult and equilibration is usually
very time consuming (liquid oligomers do not need so much time, of course). Increasing viscosity makes
the preparation of concentrated solutions more and more difficult with further increasing the amount of
polymer. Solutions above 50-60 wt% can hardly be prepared (depending on the solvent/polymer pair
under investigation). All impurities in the pure solvents have to be eliminated. Degassing of solvents (and
sometimes of polymers too) is absolutely necessary. Polymers and solvents must keep dry. Sometimes,
inhibitors and antioxidants are added to polymers. They may probably influence the position of the
equilibrium. The thermal stability of polymers must be obeyed, otherwise, depolymerization or formation
of networks by chemical processes can change the sample during the experiment.
1. Introduction 5
____________________________________________________________________________________
Certain principles must be obeyed for experiments where liquid-liquid equilibrium is observed in
polymer-solvent (or supercritical fluid) systems. To understand the results of LLE experiments in polymer
solutions, one has to take into account the strong influence of polymer distribution functions on LLE,
because fractionation occurs during demixing. Fractionation takes place with respect to molar mass
distribution as well as to chemical distribution if copolymers are involved. Fractionation during demixing
leads to some effects by which the LLE phase behavior differs from that of an ordinary, strictly binary
mixture, because a common polymer solution is a multicomponent system. Cloud-point curves are
measured instead of binodals; and per each individual feed concentration of the mixture, two parts of a
coexistence curve occur below (for upper critical solution temperature, UCST, behavior) or above the
cloud-point curve (for lower critical solution temperature, LCST, behavior), i.e., produce an infinite
number of coexistence data.
Distribution functions of the feed polymer belong only to cloud-point data. On the other hand,
polymer distribution function. The threshold point (maximum or minimum corresponding to either UCST
or LCST behavior) temperature (or pressure) is not equal to the critical point, since the critical point is to
be found at a shoulder of the cloud-point curve. Details were discussed by Koningsveld (1968KON,
1972KON). Thus, LLE data have to be specified in the tables as cloud-point or coexistence data, and
coexistence data make sense only if the feed concentration is given. This is not always the case, however.
polymers, the critical point is the maximum (or minimum) of the binodal. Binodals of polymer solutions
can be rather broad and flat. Then, the exact position of the critical point can be obtained by the method of
the rectilinear diameter:
I II
(ϕ B − ϕ B ) T 1−α
− ϕ B ,crit ∝ (1 − ) (1)
2 Tcrit
where:
ϕBI volume fraction of the polymer B in coexisting phase I
ϕBII volume fraction of the polymer B in coexisting phase II
ϕB,crit volume fraction of the polymer B at the critical point
Tcrit critical temperature (LLE)
For solutions of polydisperse polymers, such a procedure cannot be used because the critical
methods were developed to solve this problem: the phase-volume-ratio method (1968KON) where one
uses the fact that this ratio is exactly equal to one only at the critical point, and the coexistence
concentration plot (1969WOL) where an isoplethal diagram of values of ϕBI and ϕBII vs. the feed
concentration, ϕ0B, gives the critical point as the intersection of cloud-point curve and shadow curve.
Details will not be discussed here. Treating polymer solutions with distribution functions by continuous
thermodynamics is reviewed in (1989RAE) and (1990RAE).
____________________________________________________________________________________
Measurement of enthalpy changes in polymer solutions
Up to now, there is only one paper on measuring the excess enthalpy of a polymer solution at
elevated pressures (1999LOP) where a liquid oligomer was investigated, see chapter 5. Measurement of
the enthalpy change caused by mixing a given amount of a liquid polymer with an amount of pure solvent
in a mixing experiment was made there with a flow mixing cell and flow rates were selected to cover the
whole composition range. To determine the heat effect, a modified Setaram calorimeter based on heat-flux
principle was used.
The enthalpy of mixing, ∆Mh, is given by

E
and the excess enthalpy, H , is given by
HE = ∆Mh/(nA + nB) (2b)
where:
HB partial molar enthalpy of polymer B
H0B molar enthalpy of pure polymer B
PVT/density measurement for polymer melt and solution
There are two widely practiced methods for the PVT measurement of polymers and polymer
solutions:
which were described in detail by Zoller in papers and books (1986ZOL and 1995ZOL). Thus, a short
1. Introduction 7
____________________________________________________________________________________
used.
The tables in chapter 6 do not provide specific volumes below the melting transition of
semicrystalline materials or below the glass transition of amorphous samples, because PVT data of solid
polymer samples are non-equilibrium data and depend on sample history and experimental procedure
(which will not be discussed here).
PVT data of polymers have been measured by many authors and it is not the intention of this
handbook to present all available data. Only a certain number of polymers and their data sets are selected
here to provide the necessary information with respect to the pressure dependence of the thermodynamic
properties for the main classes of polymer solutions in the preceding chapters. Further PVT data for many
polymers are given in (1995ZOL), for copolymers in (2001WOH). Parameters of the Tait equation for a
number of polymers are given in (1999BRA) and (2003WOH).
Measurement of densities for polymer solutions at elevated pressures can be made today by U-
tube vibrating densimeters. Such instruments are commercially available. Calibration is often made with
pure water. Otherwise, densities can also be measured by the above discussed PVT equipment or in the
equilibrium cell of a synthetic method.
Excess volumes are determined by
VEspez = Vspez − (wAV0A, spez + wBV0B, spez) (3a)
or
VE = (xAMA + xBMB)/ρ − (xAMA/ρA + xBMB/ρB) (3b)
where:
VE molar excess volume at temperature T
VEspez specific excess volume at temperature T
V0A, spez specific volume of pure solvent A at temperature T
V0B, spez specific volume of pure polymer B at temperature T
ρ density of the mixture at temperature T
ρA density of pure solvent A at temperature T
ρB density of pure polymer B at temperature T
____________________________________________________________________________________
The osmotic virial coefficients are defined via the concentration dependence of the osmotic
pressure, π , of a polymer solution, e.g., (1974TOM):
π  1 2 
= RT  + A2 cB + A3cB + ... (4)
cB  Mn 
where
A2 second osmotic virial coefficient
A3 third osmotic virial coefficient
Mn number-average relative molar mass of the polymer
R gas constant
There are a couple of methods for the experimental determination of the second virial coefficient.
Scattering methods (classical light scattering, X-ray scattering, neutron scattering) are usually applied to
investigate its pressure dependence, e.g., (1972SCH).
KcB 1
= + 2 A2Q ( q )cB + ... (5)
R ( q) M w Pz ( q )
with
4π θ
q= sin (6)
λ 2
where:
Mw mass-average relative molar mass of the polymer
q scattering vector
λ wavelength
θ scattering angle
calculated from different relations. For experimental and theoretical details please see the corresponding
textbooks (1972HUG, 1975CAS, 1982GLA, 1986HIG, 1987BER, 1987KRA, 1987WIG, and 1991CHU).
1. Introduction 9
____________________________________________________________________________________

Characterization of the polymers
Polymers vary by a number of characterization variables (1991BAR, 1999PET). The molar

mass and their distribution function are the most important variables. However, tacticity, sequence
distribution, branching, and end groups determine their thermodynamic behavior in solution too.
Unfortunately, much less information is provided with respect to the polymers that were applied in most
of the thermodynamic investigations in the original literature. For copolymers, the chemical distribution
and the average chemical composition are also to be given. But, in many cases, the samples are
characterized only by one or two molar mass averages and some additional information (e.g., Tg, Tm, ρB,
or how and where they were synthesized). Sometimes even this information is missed.
number average Mn
Mn = i
= i
(7)
∑n i
Bi ∑w
i
Bi / M Bi
mass average Mw
Mw = i
= i
(8)
∑ni
Bi M Bi ∑w i
Bi
z-average Mz
Mz = i
= i
(9)
∑n
i
2
Bi M Bi ∑w i
Bi M Bi
1/ a
 ∑ wBi M Bai 
M η =  i 
 (10)
 ∑ wBi 
 i 
where:
MBi relative molar mass of the polymer species Bi
nBi amount of substance of polymer species Bi
wBi mass fraction of polymer species Bi
____________________________________________________________________________________
Measures for the polymer concentration
denotes the main polymer, A denotes the solvent, and in ternary systems C denotes the third component):
mass/volume concentration
mass fraction
mole fraction
volume fraction
segment fraction
base mole fraction
where:
MA relative molar mass of the solvent A
MB relative molar mass of the polymer B
1. Introduction 11
____________________________________________________________________________________

For high-molecular polymers, a mole fraction is not an appropriate unit to characterize

on the chosen equation of state or simply some group contribution schemes, e.g., (1968BON, 1990KRE)
and have to be specified.
neglect excess volumes of mixing and, very often, the densities of the polymer in the state of the solution
are not known correctly. However, volume fractions can be calculated without the exact knowledge of the
polymer molar mass (or its averages). Base mole fractions are sometimes applied for polymer systems in
earlier literature. The value for M0 is the molar mass of a basic unit of the polymer. Sometimes it is chosen
Tables of experimental data
The data tables in each chapter are provided there in order of the names of the polymers. In this
data book, mostly source-based polymer names are applied. These names are more common in use, and
they are usually given in the original sources, too. Structure-based names, for which details about their
nomenclature can be found in the Polymer Handbook (1999BRA), are chosen in some single cases only.
CAS index names for polymers are not applied here. Finally, the list of systems and properties in order of
the polymers in Appendix 1 is made by using the names as given in the chapters of this book.
Within types of polymers the individual samples are ordered by their increasing average molar
mass, and, when necessary, systems are ordered by increasing temperature. In ternary systems, ordering is
additionally made subsequently according to the name of the third component in the system. Each data set
begins with the lines for the solution components, e.g., in binary systems
Polymer (B): poly(dimethylsiloxane) 2002PFO

Characterization: Mn/kg.mol−1 = 20, Mw/kg.mol−1 = 60,
Baysilone M10000, GE Bayer Silicones, Germany
Solvent (A): chlorodifluoromethane CHClF2 75-45-6
where the polymer sample is given in the first line together with the reference. The second line provides
then the characterization available for the polymer sample. The following line gives the solvent’s chemical
name, molecular formula, and CAS registry number.
____________________________________________________________________________________
In ternary and quaternary systems, the following lines are either for a second solvent or a second
polymer or a salt or another chemical compound, e.g., in ternary systems with two solvents
Polymer (B): polyethylene 1990KEN

Characterization: Mn/kg.mol−1 = 8, Mw/kg.mol−1 = 177, Mz/kg.mol−1 = 1000,
HDPE, DSM, Geleen, The Netherlands
Solvent (A): n-hexane C6H14 110-54-3
Solvent (C): nitrogen N2 7727-37-9
or, e.g., in ternary systems with a second polymer
Polymer (B): polystyrene 2000BEH

Characterization: Mn/kg.mol−1 = 93, Mw/kg.mol−1 = 101.4, Mz/kg.mol−1 = 111.9,
BASF AG, Germany
Solvent (A): cyclohexane C6H12 110-82-7
Polymer (C): polyethylene
LDPE, Stamylan, DSM, Geleen, The Netherlands
or, e.g., in quaternary (or higher) systems like
Polymer (B): ethylene/norbornene copolymer 2003LEE

Characterization: Mn/kg.mol−1 = 34.8, Mw/kg.mol−1 = 83.3, 50 mol% ethylene,
Tg/K = 408.15, Union Chemical Laboratories, Taiwan
Solvent (A): ethene C2H4 74-85-1
Solvent (C): toluene C7H8 108-88-3
Solvent (D): bicyclo[2,2,1]-2-heptene (norbornene) C7H10 498-66-8
There are some exceptions from this type of presentation within the tables for A2 data, the UCST
and LCST data, or the PVT data of pure polymers. These tables are prepared in the forms as chosen in
2001WOH .
The originally measured data for each single system are sometimes listed together with some
comment lines if necessary. The data are usually given as published, but temperatures are always given in
K. Pressures are sometimes recalculated into kPa or MPa.
Because many investigations on liquid-liquid or fluid-fluid equilibrium in polymer solutions at

elevated pressures are provided in the literature in figures only, chapters 3 and 4 contain additional tables
referring to types of systems, included components, and references.
Final day for including data into this Handbook was June, 30, 2004.
1. Introduction 13
____________________________________________________________________________________

A2 second osmotic virial coefficient
A, B, C parameters of the Tait equation
HE excess enthalpy
K∞ weight fraction-based partition coefficient at infinite dilution
MI melting index
P pressure
P0 standard pressure (= 0.101325 MPa)
P0A vapor pressure of the pure liquid solvent A at temperature T
Pcrit critical pressure
q scattering vector
R gas constant
Tcrit critical temperature
Tm melting transition temperature
V, Vspez volume or specific volume at temperature T
V0 reference volume
VE excess volume at temperature T
VvdW hard-core van der Waals volume
∆V volume difference V − V0 (in swelling experiments)
____________________________________________________________________________________

wB,crit mass fraction of the polymer B at the critical point
λ wavelength
ϕB,crit volume fraction of the polymer B at the critical point
ρ density (of the mixture) at temperature T
π osmotic pressure
θ scattering angle
activity aA = wAΩA
1. Introduction 15
____________________________________________________________________________________
1.5. References
Makromol. Chem., 128, 284, 1969.
1972.
1972KON Koningsveld, R., Polymer solutions and fractionation, in Polymer Science, Jenkins, E.D.,
1972SCH Schulz, G.V. and Lechner, M.D., Influence of pressure and temperature, in Light Scattering
from Polymer Solutions, Huglin, M.B., Ed., Academic Press, New York, 1972, 503.
1980VAN Van Konynenburg, P.H. and Scott, R.L., Critical lines and phase equilibria in binary van-
der-Waals mixtures, Philos. Trans. Roy. Soc., 298, 495, 1980.
1982.
1987.
1989RAE Rätzsch, M.T. and Kehlen, H., Continuous thermodynamics of polymer systems, Prog.
Polym. Sci., 14, 1, 1989.
1990RAE Rätzsch, M.T. and Wohlfarth, C., Continuous thermodynamics of copolymer systems, Adv.
Polym. Sci., 98, 49, 1990.
____________________________________________________________________________________
1991BAR Barth, H.G. and Mays, J.W., Eds., Modern Methods of Polymer Characterization, J. Wiley
& Sons, New York, 1991, 201.
1994WOH Wohlfarth, C., Vapour-Liquid Equilibrium Data of Binary Polymer Solutions: Physical
Chem. Rev., 99, 565, 1999.
1999KLE Klenin, V.J., Thermodynamics of Systems Containing Flexible-Chain Polymers, Elsevier,
Amsterdam, 1999.
1999LOP Lopez, E.R., Coxam, J.-Y., Fernandez, J., and Grolier, J.-P.E., Pressure and temperature
dependence of excess enthalpies of methanol + tetraethylene glycol dimethyl ether and
methanol + polyethylene glycol dimethyl ether 250, J. Chem. Eng. Data, 44, 1409, 1999.
1999YEL Yelash, L.V. and Kraska, T., The global phase behaviour of binary mixtures of chain
molecules. Theory and application, Phys. Chem. Chem. Phys., 1, 4315, 1999.
2000WOH Wohlfarth, C., Methods for the measurement of solvent activity of polymer solutions, in
2001KON Koningsveld, R., Stockmayer, W.H., and Nies, E., Polymer Phase Diagrams, Oxford
University Press, Oxford, 2001.
2002CHR Christov, M. and Dohrn, R., High-pressure fluid phase equilibria. Experimental methods
and systems investigated (1994-1999), Fluid Phase Equil., 202, 153, 2002.
2003WOH Wohlfarth, C., Pressure-volume-temperature relationship for polymer melts, in CRC
Handbook of Chemistry and Physics, Lide, D.R., Ed., 84th ed., pp. 13-16 to 13-20, 2003.
2004WOH Wohlfarth, C., CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions,
CRC Press, Boca Raton, 2004.
2. VAPOR-LIQUID EQUILIBRIUM (VLE) DATA AND GAS
SOLUBILITIES AT ELEVATED PRESSURES
2.1. Binary polymer solutions
Polymer (B): butylene succinate/butylene adipate copolymer 2000SA1

Characterization: Mn/kg.mol−1 = 53, Mw/kg.mol−1 = 180, 20.0 mol% adipate,
Tg/K = 231, Tm/K = 365, 25 wt% crystallinity

T/K = 323.15
P/MPa 1.098 2.097 3.065 4.053 6.016 7.870 9.844
mA/(g CO2/kg polymer) 12.59 24.18 35.59 47.49 73.64 103.6 150.3
Comments: The isotherm at 323 K is below the melting temperature. Below Tm, only the
amorphous parts absorb CO2. Thus, the solubility can be recalculated with respect to
the amount of the amorphous parts of PBS.
P/MPa 1.098 2.097 3.065 4.053 6.016 7.870 9.844
mA/(g CO2/kg amorphous) 16.79 32.24 47.45 63.32 98.19 138.1 200.4
T/K = 393.15
P/MPa 2.082 2.581 4.028 4.610 6.200 6.681 8.053
mA/(g CO2/kg polymer) 18.39 22.85 35.91 41.22 55.78 60.20 72.80
P/MPa 8.630 11.997 12.460 16.024 16.548 20.036
mA/(g CO2/kg polymer) 78.14 108.4 112.7 142.3 146.7 174.1
T/K = 423.15
P/MPa 2.102 2.676 4.118 4.684 6.098 6.700 8.177
mA/(g CO2/kg polymer) 14.51 18.51 28.63 32.63 42.64 46.92 57.49
P/MPa 8.699 12.314 16.027 16.572 20.074
mA/(g CO2/kg polymer) 61.17 86.49 111.5 115.0 137.4
T/K = 453.15
P/MPa 2.079 2.600 4.126 4.698 6.070 6.628 8.259
mA/(g CO2/kg polymer) 11.84 14.83 23.57 26.89 34.85 38.09 47.63
P/MPa 8.973 12.009 12.766 16.139 20.127
mA/(g CO2/kg polymer) 51.50 69.20 73.49 92.35 113.6
_____________________________________________________________________________
Polymer (B): butyl methacrylate/N,N-dimethylaminoethyl

methacrylate block copolymer 2003WAN
Characterization: Mw/kg.mol−1 = 95.7, 59.43 mol% butyl methacrylate

T/K = 298.15
P/MPa 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
wA 0.0054 0.0090 0.0122 0.0154 0.0185 0.0220 0.0255 0.0286 0.0317


T/K = 298.15
P/MPa 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
wA 0.0060 0.0091 0.0121 0.0152 0.0183 0.0216 0.0248 0.0278 0.0311

Characterization: Mw/kg.mol−1 = 90, 93.94 mol% butyl methacrylate

T/K = 298.15
P/MPa 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
wA 0.0055 0.0082 0.0115 0.0150 0.0183 0.0223 0.0256 0.0291 0.0326


T/K = 298.15
P/MPa 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
wA 0.0091 0.0133 0.0170 0.0213 0.0249 0.0291 0.0329 0.0368 0.0406
2. Vapor-Liquid Equilibrium (VLE) Data and Gas Solubilities 19
_____________________________________________________________________________
Polymer (B): butyl methacrylate/perfluoroalkylethyl

acrylate block copolymer 2003WAN
Characterization: Mw/kg.mol−1 = 18.9, 81.99 mol% butyl methacrylate,
perfluoroalkyl = (CF2)8.6CF3

T/K = 298.15
P/MPa 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
wA 0.0054 0.0080 0.0111 0.0151 0.0185 0.0221 0.0249 0.0318
Polymer (B): butyl methacrylate/perfluoroalkylethyl

acrylate block copolymer 2003WAN
Characterization: Mw/kg.mol−1 = 14.9, 94.50 mol% butyl methacrylate,
perfluoroalkyl = (CF2)8.6CF3

T/K = 298.15
P/MPa 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
wA 0.0074 0.0111 0.0149 0.0185 0.0221 0.0258 0.0293 0.0328
Polymer (B): ethylene/propylene copolymer 1992CH1

Characterization: Mn/kg.mol−1 = 0.78, Mw/kg.mol−1 = 0.79, 50 mol% propene,
alternating ethylene/propylene units from complete
hydrogenation of polyisoprene
Solvent (A): 1-butene C4H8 106-98-9
Type of data: vapor-liquid equilibrium

wB 0.151 was kept constant
T/K 355.05 373.15 398.15 421.65 424.05 426.35 428.15 432.95 444.45
P/bar 11.5 16.4 27.1 39.8 42.5 44.8 46.5 51.7 63.4
T/K 473.15
P/bar 90.8
Polymer (B): ethylene/propylene block copolymer 2000SA2

Characterization: Mw/kg.mol−1 = 240, 4.9 wt% ethene, 90% isotactic,
58.1 wt% crystallinity, impact propylene copolymer,
Mitsubishi Chemical, Kurashiki, Japan
continued
_____________________________________________________________________________
continued
T/K = 323.15
P/MPa 0.3800 0.8987 1.4021 1.9014 2.4131 3.0362
wA 0.00252 0.00580 0.00898 0.01213 0.01535 0.01927
T/K = 343.15
P/MPa 0.3738 0.8009 1.2862 1.7985 2.3093 2.8260
wA 0.00197 0.00416 0.00664 0.00926 0.01185 0.01447
T/K = 363.15
P/MPa 0.3836 0.8533 1.3355 1.8383 2.3135 2.8231
wA 0.00169 0.00374 0.00583 0.00800 0.01003 0.01219

Solvent (A): propene C3H6 115-07-1

T/K = 323.15
P/MPa 0.2143 0.6207 1.0232 1.3323 1.6264 1.7866
wA 0.00664 0.02097 0.03989 0.05663 0.07448 0.08682
T/K = 343.15
P/MPa 0.3024 0.7554 1.4385 1.8452 2.2823 2.6448
wA 0.00736 0.01898 0.03884 0.05417 0.07091 0.08703
T/K = 363.15
P/MPa 0.3659 0.9153 1.4844 2.0138 2.5029 3.0951
wA 0.00628 0.01671 0.02847 0.04058 0.05306 0.07089
Polymer (B): ethylene/vinyl acetate copolymer 1991FIN

Characterization: Mn/kg.mol−1 = 2.2, Mw/kg.mol−1 = 5.7, 29.0 wt% vinyl acetate,
Leuna-Werke, Germany

T/K = 443.15
P/MPa 1.991 3.041 5.882 8.972 12.864 14.415 16.768 20.788 24.318
wA 0.0116 0.0184 0.0657 0.0538 0.0777 0.0884 0.1005 0.1207 0.1430
P/MPa 28.143
wA 0.1619
_____________________________________________________________________________


T/K = 473.15
P/MPa 2.695 4.683 6.464 6.551 6.779 8.847 11.356 14.006 16.135
wA 0.0135 0.0264 0.0336 0.0337 0.0373 0.0462 0.0577 0.0652 0.0752
P/MPa 22.361 29.520
wA 0.1091 0.1323

Solvent (A): vinyl acetate C4H6O2 108-05-4

T/K = 413.15
P/MPa 0.152 0.169 0.186 0.273 0.288 0.371 0.405 0.435 0.444
wA 0.042 0.077 0.079 0.114 0.115 0.205 0.245 0.237 0.318
P/MPa 0.464
wA 0.299
T/K = 443.15
P/MPa 0.125 0.144 0.165 0.166 0.185 0.265 0.494 0.557 0.567
wA 0.028 0.030 0.047 0.050 0.065 0.071 0.116 0.127 0.129
P/MPa 0.886 1.02 1.14
wA 0.322 0.456 0.684
T/K = 473.15
P/MPa 0.179 0.211 0.234 0.425 0.495 0.543 0.788 0.935
wA 0.024 0.037 0.039 0.055 0.056 0.086 0.122 0.155
Polymer (B): nylon 6 2003XUQ

Characterization: ρ (298 K) = 1.140 g/cm3, 1020C, Mitsubishi, Japan

T/K = 313.15
P/MPa 8 10 12 14 16
wA 0.0177 0.0172 0.0083 0.0105 0.0132
_____________________________________________________________________________
Polymer (B): nylon 6 2003XUQ

Characterization: ρ (298 K) = 1.140 g/cm3, 1020C, Mitsubishi, Japan
Solvent (A): styrene C8H8 100-42-5
Type of data: vapor solubility

T/K = 313.15
P/MPa 8 10 12 14 16
wA 0.0104 0.0059 0.0024 0.0024 0.0035
Polymer (B): polybutadiene 2002JOU

−1
Characterization: Mw/kg.mol = 420, Aldrich Chem. Co., Inc., Milwaukee, WI
Type of data: vapor pressure

T/K 363.15 373.15 383.15 393.15 403.15 413.15 423.15 433.15 443.15
PA/MPa 0.5 0.6 0.6 0.8 0.9 1.0 1.2 1.4 1.6
T/K 453.15 463.15 473.15
PA/MPa 1.9 2.1 2.5
Polymer (B): poly(butylene succinate) 2000SA1

branched, Tg/K = 243, Tm/K = 388, 35 wt% crystallinity

T/K = 323.15
P/MPa 1.025 2.209 3.068 4.245 6.272 8.008 10.129
mA/(g CO2/kg polymer) 9.84 20.63 28.26 38.79 56.81 73.00 107.6
T/K = 353.15
P/MPa 1.148 2.103 3.158 4.218 6.169 8.050 10.451
mA/(g CO2/kg polymer) 8.76 15.23 22.43 29.61 43.32 56.01 72.50
Comments: The isotherms at 323 and 353 are below the melting temperature where only the
amorphous parts absorb CO2. The original paper provides a column where the solubility
is also calculated with respect to the amount of the amorphous parts of PBS.
T/K = 393.15
P/MPa 2.351 2.947 4.141 4.725 6.060 6.599 8.076
mA/(g CO2/kg polymer) 21.74 27.08 37.76 43.08 55.21 60.14 73.57
P/MPa 8.928 12.076 12.606 16.035 16.544 19.987
mA/(g CO2/kg polymer) 81.30 109.8 114.6 144.0 148.1 176.1
continued
_____________________________________________________________________________
continued
T/K = 423.15
P/MPa 2.221 2.935 4.065 4.705 6.035 6.572 8.242
mA/(g CO2/kg polymer) 15.01 19.93 27.77 32.16 41.45 45.29 57.10
P/MPa 8.696 12.036 12.572 16.038 16.541 20.095
mA/(g CO2/kg polymer) 60.41 83.09 87.33 110.7 113.9 135.5
T/K = 453.15
P/MPa 2.133 2.798 4.132 4.627 6.039 6.626 8.037
mA/(g CO2/kg polymer) 11.92 15.66 23.15 26.04 34.11 37.36 45.34
P/MPa 8.570 12.007 12.592 16.071 16.574 20.144
mA/(g CO2/kg polymer) 48.40 68.30 71.53 90.82 93.67 112.6
Polymer (B): poly(butyl methacrylate) 2003WAN

Characterization: Mw/kg.mol−1 = 13.6

T/K = 298.15
P/MPa 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
wA 0.0078 0.0125 0.0171 0.0212 0.0263 0.0314 0.0365 0.0415
Polymer (B): poly(butyl methacrylate) 1990WAN, 1994WAN

Characterization: Mη/kg.mol−1 = 126, Aldrich Chem. Co., Inc., Milwaukee, WI

T/K = 313.2
P/MPa 0.549 0.971 1.01 1.49 1.65 2.06 2.32 2.82 2.96
wA 0.0147 0.0284 0.0269 0.0400 0.0469 0.0551 0.0627 0.0756 0.0835
P/MPa 3.65 3.78 4.35 4.74 5.01 5.62 5.70 6.41 6.46
wA 0.104 0.105 0.125 0.138 0.145 0.172 0.169 0.197 0.208
P/MPa 7.23 7.77
wA 0.232 0.252
T/K = 333.2
P/MPa 0.691 0.971 1.26 1.67 1.94 2.34 2.67 3.01 3.43
wA 0.0148 0.0220 0.0270 0.0365 0.0411 0.0506 0.0564 0.0649 0.0744
P/MPa 3.73 4.23 4.36 4.92 5.05 5.68 5.74 6.54 7.47
wA 0.0802 0.0919 0.0941 0.108 0.110 0.128 0.127 0.148 0.172
P/MPa 8.12 8.67
wA 0.195 0.204
continued
_____________________________________________________________________________
continued
T/K = 353.2
P/MPa 0.701 1.09 1.30 1.76 1.94 2.48 2.63 3.10 3.26
wA 0.0133 0.0214 0.0236 0.0328 0.0354 0.0461 0.0477 0.0572 0.0591
P/MPa 3.78 3.95 4.55 4.63 5.26 5.34 5.60 5.98 6.82
wA 0.0693 0.0711 0.0833 0.0822 0.0966 0.0941 0.0987 0.111 0.125
P/MPa 7.47 8.24 8.98 9.68 10.2
wA 0.142 0.155 0.173 0.187 0.199
Polymer (B): polycarbonate bisphenol-A 1999KEL


T/K = 293.15
P/MPa 0.992 1.994 3.458 3.976 4.495 5.032 5.836
wA 0.0321 0.0588 0.0897 0.0984 0.1075 0.1151 0.1282
Polymer (B): polycarbonate bisphenol-A 2004TAN

Characterization: Mw/kg.mol−1 = 64, Acros

T/K 313.15 313.15 313.15 323.15 323.15 323.15 333.15 333.15 333.15
P/MPa 20 30 40 20 30 40 20 30 40
wA 0.1241 0.1344 0.1470 0.1171 0.1313 0.1459 0.1087 0.1298 0.1432
Polymer (B): poly(chlorotrifluoroethylene) 1999WEB

Characterization: Modern Plastics, Springfield, MA

T/K = 313.15 P/MPa 10.5 wA 0.0416
Polymer (B): poly(2,6-dimethyl-1,4-phenylene ether) 2002SAT

Tg/K = 477.1, Asahi Chemicals Inc., Kawasaki, Japan

T/K = 373.15
continued
_____________________________________________________________________________
continued
P/MPa 2.125 4.118 6.098 8.051 12.043 16.023 19.964
wA 0.02894 0.04675 0.06102 0.07354 0.09978 0.12540 0.15421
T/K = 423.15
P/MPa 2.150 4.150 6.040 8.133 12.121 16.077
wA 0.01438 0.02546 0.03419 0.04373 0.06326 0.08317
T/K = 473.15
P/MPa 2.097 4.155 6.120 8.048 12.122 16.072
wA 0.00869 0.01678 0.02414 0.03136 0.04805 0.06013


T/K = 373.15
P/MPa 2.058 4.003 8.100 10.111 11.965 13.935 15.993 17.933 20.006
wA 0.03459 0.05113 0.07517 0.08534 0.09585 0.10727 0.12086 0.13498 0.14852
T/K = 423.15
P/MPa 1.983 4.105 8.056 10.061 12.108 14.078 16.098 18.076 20.076
wA 0.01486 0.02653 0.04350 0.05299 0.06378 0.07373 0.08340 0.09299 0.10261
T/K = 473.15
P/MPa 2.179 4.142 8.085 10.082 12.078 14.063 16.032 18.106 20.208
wA 0.00699 0.01560 0.03310 0.04134 0.05000 0.00182 0.06606 0.07502 0.08289
Polymer (B): poly(2,6-dimethyl-1,4-phenylene ether) 1994HAN

Type of data: Tg at saturation gas solubility

P/atm 0.0 13.6 27.2 34.0 40.8 54.4 61.2
Tg/K 489.15 484.55 476.75 475.25 468.95 466.15 457.55
Polymer (B): poly(dimethylsiloxane) 2002FLI

Polymer Source, Inc., Quebec
Type of data: gas solubility and swelling

continued
_____________________________________________________________________________
continued
T/K = 296.15
P/MPa 2.14 4.24 6.24 8.27 10.45
wA 0.1205 0.2107 0.3632 0.3867 0.4089
(∆V/V)/(%) 9.31 24.03 83.05 94.29 104.77
T/K = 323.15
P/MPa 1.38 2.83 4.17 5.62 7.00 8.31 9.83 11.17
wA 0.0438 0.0842 0.1161 0.1488 0.1811 0.2163 0.2553 0.2842
(∆V/V)/(%) 3.31 7.25 11.77 17.81 25.53 35.19 48.70 59.58
Polymer (B): poly(dimethylsiloxane) 1999WEB

Characterization: cross-linked in the laboratory by using a sample from
GE-Plastics, Electrical Insulation Suppliers, Atlanta, GA

T/K = 313.15 P/MPa 10.5 wA 0.1019
Polymer (B): poly(dimethylsiloxane) 1998VIN

Characterization: United Chemical Technologies, Inc., Petrarch Silanes & Silicones,
cross-linked using benzoyl peroxide
Type of data: swelling at equilbrium pressure

T/K = 314.65
P/bar 1.0 6.6 12.0 33.0 33.4 54.3 55.3 57.7 65.7
V/V0 1.012 1.025 1.040 1.112 1.129 1.217 1.194 1.240 1.309
P/bar 68.9 77.3 80.9 83.3 89.0 96.9 103.9 108.1 112.4
V/V0 1.344 1.449 1.473 1.511 1.557 1.634 1.671 1.682 1.718
P/bar 115.2 120.8 122.0 128.1 131.3 140.9 148.2 150.4 154.2
V/V0 1.713 1.758 1.771 1.792 1.817 1.861 1.899 1.889 1.931
P/bar 158.6 163.5 171.8 172.5
V/V0 1.950 1.983 2.027 2.038
Polymer (B): poly(dimethylsiloxane) 2002PFO

Baysilone M10000, GE Bayer Silicones, Germany

T/K = 298.15
continued
_____________________________________________________________________________
continued
P/kPa 2.8 8.7 16.2 32.7 61.3 115.0
wA 0.00068 0.00223 0.00423 0.00899 0.01640 0.03126
aA 0.0033 0.0100 0.0186 0.0376 0.0701 0.1303
T/K = 343.15
P/kPa 30.5 66.5 109.7 151.0 181.1 213.5
wA 0.00315 0.00742 0.01224 0.01689 0.02030 0.02405
aA 0.0153 0.0331 0.0544 0.0744 0.0889 0.1044

−1 −1
Characterization: Mn/kg.mol = 1.6, Mw/kg.mol = 2.1,
Solvent (A): ethanol C2H6O 64-17-5

T/K 316.5 323.2 329.0 336.6 343.0 351.1 359.6 371.9 386.2
PA/MPa 0.036 0.047 0.058 0.077 0.096 0.127 0.174 0.237 0.377
T/K 400.4 415.0 429.9 439.1 451.0 464.0 472.1
PA/MPa 0.515 0.740 1.083 1.340 1.756 2.309 2.709

Characterization: Mn/kg.mol−1 = 1.6, Mw/kg.mol−1 = 2.1,
Boltorn H20, for details see the above data set

T/K 348.2 353.7 361.2 366.5 370.1 375.5 381.0 386.6 393.4
PA/MPa 0.045 0.052 0.069 0.083 0.095 0.113 0.135 0.163 0.203
T/K 398.3 405.4 411.4 415.4
PA/MPa 0.235 0.291 0.346 0.387

continued
_____________________________________________________________________________
continued
T/K 350.6 358.4 363.1 368.2 374.0 378.2 383.1 390.9 403.3
PA/MPa 0.046 0.062 0.073 0.087 0.107 0.123 0.145 0.185 0.271
T/K 408.8 413.2 418.2 423.2 428.7 433.4
PA/MPa 0.320 0.363 0.418 0.477 0.553 0.622
Polymer (B): polyethylene 1992WOH

LDPE-wax, ρ = 0.9238 g/cm3, Leuna-Werke, Germany

T/K = 493.15
P/MPa 0.526 1.096 1.606 2.067 2.861 4.585 4.869 5.433 7.614
wA 0.0142 0.0357 0.0532 0.0688 0.0943 0.1543 0.1603 0.1860 0.2706
Comments: High-pressure fluid phase equilibrium data for this system are given in Chapter 4.
Polymer (B): polyethylene 2001MOO

Characterization: Mn/kg.mol−1 = 22, Mw/kg.mol−1 = 104, ρ = 0.923 g/cm3,
50.4% crystallinity, LDPE

T/K = 302.95
P/kPa 119.968 228.904 286.130
mA/(g/g polymer) 0.01764 0.04359 0.06633
mA/(g/g amorphous polymer) 0.03556 0.08788 0.13372
T/K = 322.45
P/kPa 197.188 359.214 528.823
mA/(g/g polymer) 0.02339 0.05141 0.11382
T/K = 341.95
P/kPa 292.335 570.192 819.090
mA/(g/g polymer) 0.02566 0.06770 0.15770
T/K = 361.05
P/kPa 526.066 872.869 1243.804
mA/(g/g polymer) 0.04693 0.10323 0.26743
_____________________________________________________________________________

Characterization: Mn/kg.mol−1 = 11.5, Mw/kg.mol−1 = 110.5, ρ = 0.954 g/cm3,
70.2% crystallinity, HDPE

T/K = 303.15
P/kPa 122.726 233.041 290.956
mA/(g/g polymer) 0.01036 0.02288 0.03284
T/K = 322.45
P/kPa 197.188 389.551 564.676
mA/(g/g polymer) 0.01087 0.02535 0.04961
T/K = 322.75
P/kPa 212.357 350.940 540.544
mA/(g/g polymer) 0.01271 0.02220 0.04525
T/K = 342.05
P/kPa 281.304 550.197 836.327
mA/(g/g polymer) 0.01294 0.02617 0.05072
T/K = 361.05
P/kPa 580.534 913.548 1225.878
mA/(g/g polymer) 0.01805 0.03515 0.06289

−1 −1 3
Characterization: Mn/kg.mol = 25.9, Mw/kg.mol = 85.2, ρ = 0.917 g/cm ,
47.0% crystallinity, LLDPE with 1-butene

T/K = 303.15
P/kPa 117.899 228.904 286.820
mA/(g/g polymer) 0.02075 0.05094 0.07919
T/K = 322.65
P/kPa 203.394 365.419 532.960
mA/(g/g polymer) 0.02574 0.05797 0.13351
continued
_____________________________________________________________________________
continued
T/K = 342.05
P/kPa 290.956 560.539 819.780
mA/(g/g polymer) 0.03121 0.07302 0.17059
T/K = 361.15
P/kPa 559.850 881.143 1241.046
mA/(g/g polymer) 0.05130 0.10614 0.24769

18.5% crystallinity, LLDPE with 1-hexene

T/K = 303.15
P/kPa 118.589 229.594 283.372
mA/(g/g polymer) 0.04011 0.11308 0.19134
T/K = 322.65
P/kPa 209.599 393.687 535.718
mA/(g/g polymer) 0.05225 0.14751 0.39621
T/K = 342.05
P/kPa 287.509 573.639 666.028
mA/(g/g polymer) 0.05853 0.16911 0.23187
T/K = 342.35
P/kPa 285.441 589.497 814.264
mA/(g/g polymer) 0.05840 0.17304 0.41314
Polymer (B): polyethylene 2004SOL

Characterization: HDPE, ρ = 0.955 g/cm3

T/K = 293.15
P/bar 22.1 22.1 24.0 24.0 31.3 31.3 39.1 39.1
wA 0.00884 0.00894 0.00964 0.00975 0.01215 0.01225 0.01468 0.01468
continued
_____________________________________________________________________________
continued
T/K = 305.15
P/bar 18.8 18.8 29.9 31.4 31.6 31.6 37.4 42.5 42.5
wA 0.00649 0.00655 0.00946 0.00970 0.00990 0.00979 0.01088 0.01205 0.01215
T/K = 313.15
P/bar 20.4 20.4 29.8 29.8 40.7 40.7
wA 0.00685 0.00706 0.00956 0.00959 0.01215 0.01235
T/K = 323.15
P/bar 22.5 22.5 29.3 29.3 40.0 40.0
wA 0.00695 0.00700 0.00831 0.00849 0.01049 0.01049
Polymer (B): polyethylene 2004DAV

Characterization: Mw/kg.mol−1 = 250, LDPE, Dow Chemical

T/K = 423.15
P/psia 95 227 326 435 488
wA 0.005 0.011 0.015 0.020 0.023
Polymer (B): polyethylene 1999SAT

Characterization: Mw/kg.mol−1 = 8.2, Mw/kg.mol−1 = 111, HDPE,
Nippon Petrochemicals, Kawasaki, Japan

T/K = 433.15
P/MPa 6.936 11.066 13.644 15.286 16.347 17.453
wA 0.0391 0.0695 0.0888 0.1024 0.1095 0.1166
T/K = 453.15
P/MPa 7.055 11.326 14.013 15.762 16.896 18.123
wA 0.0338 0.0629 0.0817 0.0913 0.0986 0.1070
T/K = 473.15
P/MPa 6.608 10.731 13.344 15.034 17.019
wA 0.0309 0.0522 0.0694 0.0803 0.0936
Polymer (B): polyethylene 1997SUR

Characterization: Mn/kg.mol−1 = 76, LDPE, MI = 65, ρ = 0.919 g/cm3,
DSM, Geleen, The Netherlands
Solvent (A): cyclopentane C5H10 287-92-3
continued
_____________________________________________________________________________
continued
T/K = 425.65
wB 0.9513 0.8873 0.7981 0.7013 0.6038 0.5069
PA/bar 1.76 3.56 5.79 7.63 9.02 10.10
T/K = 474.15
wB 0.9587 0.9085 0.8108 0.6992 0.5921 0.5032
PA/bar 2.68 5.74 10.72 15.53 19.44 22.41
Polymer (B): polyethylene 1977CHE

Characterization: Mn/kg.mol−1 = 31.7, Mw/kg.mol−1 = 248.7, Mz/kg.mol−1 = 2378,
LDPE, ρ = 0.9188 g/cm3, Union Carbide Corp., NY
T/K = 399.15
P/atm 4.40 7.80 11.2 14.6 18.0 21.4 24.8 28.2 31.6
wA 0.0018 0.0037 0.0055 0.0075 0.0107 0.0136 0.0158 0.0175 0.0198
P/atm 35.0 38.4 41.8 45.2 48.6 52.0 55.4 58.8 62.2
wA 0.0221 0.0242 0.0255 0.0285 0.0305 0.0330 0.0359 0.0381 0.0417
P/atm 65.6 69.0
wA 0.0438 0.0469
T/K = 413.15
P/atm 4.40 7.80 11.2 14.6 18.0 21.4 24.8 28.2 31.6
wA 0.0015 0.0034 0.0048 0.0068 0.0087 0.0112 0.0131 0.0151 0.0166
P/atm 35.0 38.4 41.8 45.2 48.6 52.0 55.4 58.8 62.2
wA 0.0189 0.0208 0.0235 0.0250 0.0277 0.0296 0.0328 0.0341 0.0370
P/atm 65.6 69.0
wA 0.0382 0.0415
T/K = 428.15
P/atm 4.40 7.80 11.2 14.6 18.0 21.4 24.8 28.2 31.6
wA 0.0013 0.0029 0.0039 0.0055 0.0074 0.0090 0.0105 0.0120 0.0146
P/atm 35.0 38.4 41.8 45.2 48.6 52.0 55.4 58.8 62.2
wA 0.0164 0.0178 0.0207 0.0222 0.0242 0.0265 0.0286 0.0304 0.0329
P/atm 65.6 69.0
wA 0.0352 0.0372
Polymer (B): polyethylene 1985ROU

HDPE, Barex 2000, CDF Chimie, France
continued
_____________________________________________________________________________
continued
Type of data: gas solubility/bubble pressures/densities
T/K = 403.1
wA 0.0275 0.0637 0.0773 0.1182 0.1189 0.1284 0.1482
P/MPa 3.39 8.06 10.01 15.71 15.49 17.23 22.14
ρ/(g/cm3) 0.768 0.747 0.740 0.719 0.716 0.711 0.703
T/K = 433.1
wA 0.0275 0.0637 0.0773 0.1182 0.1189 0.1284 0.1482
P/MPa 3.89 9.17 11.49 17.72 17.46 19.45 24.33
ρ/(g/cm3) 0.747 0.723 0.723 0.703 0.701 0.697 0.687
T/K = 463.1
wA 0.0275 0.0637 0.0772 0.0773 0.1182 0.1189 0.1284 0.1482
P/MPa 4.35 10.24 12.64 12.76 19.35 19.09 21.17 26.13
ρ/(g/cm3) 0.733 0.712 0.706 0.706 0.688 0.685 0.685 0.673
T/K = 493.1
wA 0.0275 0.0637 0.1189 0.1284
P/MPa 4.73 11.02 20.32 22.49
Polymer (B): polyethylene 1985ROU

Characterization: Mn/kg.mol−1 = 12.5, Mw/kg.mol−1 = 41,
HDPE, ZMP16, CDF Chimie, France
Type of data: gas solubility/bubble pressures/densities

T/K 403.1 463.1 523.1
wA 0.0127 0.0127 0.0127
P/MPa 1.52 1.91 2.28
ρ/(g/cm3) 0.7724 0.7247
Polymer (B): polyethylene 1987KOB

Characterization: Mn/kg.mol−1 = 3.65, Mw/kg.mol−1 = 7.6, LDPE-wax

T/K = 393.2
wB 0.958 0.920 0.870 0.835 0.795 0.755 0.715 0.665 0.605
P/MPa 4.90 9.80 19.61 29.42 39.22 49.03 58.84 68.54 78.45
wB 0.535 0.455 0.365 0.270
P/MPa 88.25 98.06 107.82 117.67
continued
_____________________________________________________________________________
continued
T/K = 433.2
wB 0.958 0.920 0.865 0.820 0.780 0.735 0.690 0.630 0.560
P/MPa 4.90 9.80 19.61 29.42 39.22 49.03 58.84 68.54 78.45
wB 0.485 0.395 0.300
P/MPa 88.25 98.06 107.82
T/K = 473.2
wB 0.958 0.920 0.855 0.805 0.765 0.710 0.655 0.585 0.510
P/MPa 4.90 9.80 19.61 29.42 39.22 49.03 58.84 68.54 78.45
wB 0.430 0.345
P/MPa 88.25 98.06

Characterization: Mn/kg.mol−1 = 4.95, Mw/kg.mol−1 = 11.0, LDPE

T/K = 393.2
wB 0.958 0.920 0.870 0.835 0.800 0.765 0.725 0.685 0.640
P/MPa 4.90 9.80 19.61 29.42 39.22 49.03 58.84 68.54 78.45
wB 0.585 0.525 0.380
P/MPa 88.25 98.06 117.67
T/K = 433.2
wB 0.958 0.920 0.865 0.825 0.785 0.745 0.700 0.655 0.600
P/MPa 4.90 9.80 19.61 29.42 39.22 49.03 58.84 68.54 78.45
wB 0.540 0.475 0.305
P/MPa 88.25 98.06 117.67
T/K = 473.2
wB 0.958 0.920 0.860 0.815 0.765 0.715 0.660 0.605 0.485
P/MPa 4.90 9.80 19.61 29.42 39.22 49.03 58.84 68.54 78.45
wB 0.454 0.415
P/MPa 88.25 98.06


T/K = 300.75
continued
_____________________________________________________________________________
continued
P/kPa 783.238 2154.594 3547.323
mA/(g/g polymer) 0.00430 0.01163 0.02022
T/K = 320.85
P/kPa 805.990 2154.594 3530.086
mA/(g/g polymer) 0.00389 0.01076 0.01792
T/K = 340.85
P/kPa 785.996 2138.736 3512.850
mA/(g/g polymer) 0.00356 0.00971 0.01607
T/K = 360.95
P/kPa 795.648 2140.804 3526.639
mA/(g/g polymer) 0.00320 0.00921 0.01606


T/K = 300.85
P/kPa 859.080 2186.309 3561.113
mA/(g/g polymer) 0.00276 0.00697 0.01074
T/K = 320.75
P/kPa 864.595 2147.699 3568.697
mA/(g/g polymer) 0.00226 0.00553 0.00929
T/K = 340.75
P/kPa 852.185 2148.389 3534.223
mA/(g/g polymer) 0.00308 0.00450 0.00731
T/K = 361.05
P/kPa 852.185 2175.278 3540.428
mA/(g/g polymer) 0.00136 0.00351 0.00554
_____________________________________________________________________________


T/K = 303.05
P/kPa 819.780 2173.209 3531.465
mA/(g/g polymer) 0.00395 0.01090 0.01793
T/K = 322.75
P/kPa 807.369 2210.441 3539.739
mA/(g/g polymer) 0.00464 0.01052 0.01672
T/K = 342.25
P/kPa 808.748 2210.441 3545.944
mA/(g/g polymer) 0.00331 0.00873 0.01429
T/K = 361.05
P/kPa 810.817 2244.914 3605.928
mA/(g/g polymer) 0.00306 0.00872 0.01493


T/K = 300.85
P/kPa 814.954 2169.762 3547.323
mA/(g/g polymer) 0.00810 0.02359 0.04077
T/K = 320.85
P/kPa 838.396 2169.073 3545.255
mA/(g/g polymer) 0.00798 0.02121 0.03613
T/K = 340.85
P/kPa 814.954 2180.104 3526.639
mA/(g/g polymer) 0.00724 0.01999 0.03317
_____________________________________________________________________________


T/K = 423.15
P/psia 266 473 553 633 763
wA 0.011 0.020 0.022 0.025 0.031
Polymer (B): polyethylene 2002JOU

−1
Solvent (A): n-heptane C7H16 142-82-5

T/K 393.15 408.15 423.15 438.15 443.15 453.15
PA/MPa 0.6 0.7 0.9 1.1 1.2 1.2
Comments: Liquid-liquid equilibrium data for this system are given in Chapter 3.


wB 0.0053 0.0053 0.0053 0.0053 0.0095 0.0095 0.0095 0.0095 0.0954
T/K 392.62 394.62 396.61 402.54 396.90 397.94 398.93 399.90 402.62
P/bar 4.0 4.2 4.4 5.0 4.5 4.6 4.7 4.8 5.8
wB 0.0954 0.0954 0.0954 0.0954 0.0954 0.1313 0.1313 0.1313 0.1313
T/K 404.58 406.57 414.54 418.51 420.51 414.94 417.93 419.93 421.87
P/bar 6.0 6.2 7.1 7.7 8.0 6.6 7.1 7.4 7.6
wB 0.1313 0.1313
T/K 423.69 425.66
P/bar 7.9 8.2
Comments: Liquid-liquid equilibrium and liquid-liquid-vapor equilibrium data for this system are
given in Chapter 3.
Polymer (B): polyethylene 2001TOR

continued
_____________________________________________________________________________
continued
wB 0.2128 0.1382 0.0813 0.0138 0.0138
T/K 446.2 436.5 431.3 423.4 433.6
P/MPa 1.05 0.92 0.77 0.68 0.78
Comments: LLE and LLVE data for this system are given in Chapter 3.

−1 −1
Characterization: Mn/kg.mol = 14.4, Mw/kg.mol = 15.5, completely hydrogenated
polybutadiene, Scientific Polymer Products, Inc., Ontario, NY

wB 0.0906 0.0906 0.0906 0.0906 0.0906
T/K 373.21 393.21 413.12 433.14 443.14
P/MPa 0.4 0.6 0.9 1.1 1.3

Characterization: Mn/kg.mol−1 = 82, Mw/kg.mol−1 = 108, completely hydrogenated

wB 0.0829 0.0829 0.0829
T/K 373.23 393.18 413.15
P/MPa 0.4 0.7 0.8

Characterization: Mn/kg.mol−1 = 23.3, Mw/kg.mol−1 = 60.4, Mz/kg.mol−1 = 100.7,
metallocene LLDPE, unspecified comonomer, industrial source

wB 0.0822 0.0822
T/K 393.09 413.15
P/MPa 0.6 0.9
_____________________________________________________________________________

Solvent (A): 1-hexene C6H12 592-41-6
T/K = 342.25
P/kPa 51.021 67.568 106.178
mA/(g/g polymer) 0.02077 0.03031 0.07508
T/K = 361.05
P/kPa 71.705 128.931 190.294
mA/(g/g polymer) 0.01842 0.04169 0.10961

T/K = 342.25
P/kPa 55.158 68.947 110.315
mA/(g/g polymer) 0.05371 0.08019 0.27483
T/K = 361.15
P/kPa 75.842 132.378 191.673
mA/(g/g polymer) 0.07117 0.17575 0.50437

T/K = 342.05
P/kPa 46.884 76.531 113.763
mA/(g/g polymer) 0.04459 0.09503 0.30252
T/K = 361.25
P/kPa 78.600 135.826 178.573
mA/(g/g polymer) 0.05581 0.14184 0.32805
_____________________________________________________________________________


T/K = 342.25
P/kPa 51.021 75.152 91.010
mA/(g/g polymer) 0.10675 0.22058 0.46488
Polymer (B): polyethylene 2004SOL

Characterization: HDPE, ρ = 0.955 g/cm3
Solvent (A): methane CH4 74-82-8

T/K = 293.15
P/bar 50.1 50.1 106.0 106.0 142.2 142.2
wA 0.00296 0.00267 0.00515 0.00512 0.00601 0.00634
T/K = 305.15
P/bar 48.3 55.5 103.8 105.0 150.0 151.0 151.0 157.1 157.1
wA 0.00196 0.00215 0.00311 0.00310 0.00357 0.00409 0.00419 0.00413 0.00388
T/K = 313.15
P/bar 49.6 49.6 105.0 105.0 135.2 135.2
wA 0.00244 0.00245 0.00411 0.00427 0.00484 0.00490
T/K = 323.15
P/bar 50.2 50.2 50.9 50.9 105.4 105.4 106.3 106.3 128.6
wA 0.00217 0.00223 0.00220 0.00247 0.00353 0.00377 0.00380 0.00387 0.00396
P/bar 128.6 142.2 142.2
wA 0.00424 0.00422 0.00440
Polymer (B): polyethylene 1981PAR

77.5% crystallinity, HDPE, Marlex EMN 6030
Solvent (A): 2-methylpropane C4H10 75-28-5

T/K = 338.75
P/bar 0.97 1.03 2.74 4.55 6.20 7.91 9.13
wA 0.0022 0.0023 0.0070 0.0122 0.0179 0.0246 0.0313
continued
_____________________________________________________________________________
continued
T/K = 347.05
P/bar 1.03 2.76 4.51 6.24 7.94 9.67
wA 0.0024 0.0065 0.0106 0.0155 0.0212 0.0277
T/K = 355.35
P/bar 1.00 2.77 4.53 6.25 7.97 9.72 11.41
wA 0.0020 0.0056 0.0092 0.0129 0.0171 0.0223 0.0277
T/K = 366.45
P/bar 1.01 2.82 4.57 6.29 8.01 10.75 11.47
wA 0.0017 0.0047 0.0079 0.0112 0.0146 0.0183 0.0224
Polymer (B): polyethylene 1983MEY

Characterization: Mn/kg.mol−1 = 14, Mw/kg.mol−1 = 94, ρ = 0.951 g/cm3, HDPE

T/K = 422.0
P/Torr 99.9 129 197 335 646 867 1095 1351 1496
wA 0.00056 0.00101 0.00118 0.00202 0.00376 0.00513 0.00650 0.00818 0.00911
T/K = 477.6
P/Torr 58.1 101 185 202 438 654 926 1369 1649
wA 0.00021 0.00038 0.00066 0.00079 0.00165 0.00246 0.00344 0.00528 0.00591
T/K = 533.2
P/Torr 45.0 106 200 421 727 1015 1262 1454 1722
wA 0.00012 0.00025 0.00053 0.00112 0.00196 0.00276 0.00353 0.00395 0.00434

Characterization: Mn/kg.mol−1 = 18, Mw/kg.mol−1 = 109, ρ = 0.919 g/cm3, LDPE

T/K = 422.0
P/Torr 67.6 139 300 682 1120 1380
wA 0.00037 0.00072 0.00168 0.00388 0.00579 0.00820
T/K = 477.6
P/Torr 72.5 162 350 774 1310 1566
wA 0.00024 0.00054 0.00125 0.00280 0.00491 0.00595
T/K = 533.2
P/Torr 83.2 179 387 895 1453 1745
wA 0.00022 0.00056 0.00131 0.00203 0.00365 0.00420
_____________________________________________________________________________
Polymer (B): polyethylene 1995LEE

Characterization: Mw/kg.mol−1 = 800, LDPE

T/K = 394.3
P/atm 10 20 50 100 125
wA 0.00209 0.00392 0.00621 0.01002 0.01118
ϕA 0.00192 0.00360 0.00572 0.00924 0.01031
T/K = 408.2
P/atm 10 20 50 100 125
wA 0.00229 0.00424 0.00771 0.01248 0.01374
ϕA 0.00209 0.00386 0.00701 0.01135 0.01251
T/K = 422.1
P/atm 10 20 50 100 125
wA 0.00233 0.00454 0.00878 0.01420 0.01615
ϕA 0.00210 0.00409 0.00790 0.01277 0.01453
T/K = 436.0
P/atm 10 20 50 100 125
wA 0.00252 0.00482 0.00974 0.01535 0.01764
ϕA 0.00225 0.00429 0.00866 0.01365 0.01570
T/K = 449.9
P/atm 10 20 50 100 125
wA 0.00272 0.00518 0.01059 0.01729 0.01981
ϕA 0.00240 0.00457 0.00932 0.01522 0.01744
Polymer (B): polyethylene 1999SAT

Characterization: Mn/kg.mol−1 = 8.2, Mw/kg.mol−1 = 111, HDPE,

T/K = 433.15
P/MPa 2.541 4.278 5.463 7.935 10.089 11.555 14.629
wA 0.00257 0.00430 0.00549 0.00773 0.00945 0.01144 0.01444
T/K = 453.15
P/MPa 3.743 6.330 8.192 9.401 11.809
wA 0.00371 0.00652 0.00842 0.00957 0.01245
T/K = 473.15
P/MPa 2.818 4.704 5.958 6.792 8.386 10.695 12.682 15.214
wA 0.00287 0.00516 0.00666 0.00754 0.00975 0.01170 0.01472 0.01695
_____________________________________________________________________________


T/K = 423.15
P/psia 922 953
wA 0.004 0.005

Solvent (A): 1-octene C8H16 111-66-0

T/K = 503
wB 0.1791 0.0897 0.0439 0.0198
P/MPa 0.97 0.94 0.95 0.95
T/K = 513
wB 0.1791 0.0897 0.0439
P/MPa 1.14 1.13 1.11

Solvent (A): n-pentane C5H12 109-66-0

T/K = 423.65
wB 0.9477 0.9054 0.8088 0.7049 0.6274 0.5191
PA/bar 2.47 5.36 9.48 12.26 13.63 15.01
T/K = 474.15
wB 0.9705 0.9202 0.8410 0.7417 0.6404 0.5571
PA/bar 2.64 7.16 13.61 20.86 26.80 30.58

Solvent (A): 3-pentanol C5H12O 584-02-1
continued
_____________________________________________________________________________
continued
T/K = 423.15
wB 0.9536 0.8929 0.7894 0.7036 0.6128 0.5134
PA/bar 0.83 1.53 2.12 2.48 2.69 2.81
T/K = 473.15
wB 0.9600 0.9095 0.8136 0.6415 0.5027
PA/bar 1.40 3.08 5.21 7.55 8.32

Solvent (A): 3-pentanone C5H10O 96-22-0

T/K = 425.15
wB 0.9538 0.8961 0.7950 0.7049 0.6002 0.5054
PA/bar 0.78 1.61 2.51 2.90 3.21 3.38
T/K = 477.15
wB 0.9597 0.9071 0.8171 0.7113 0.6054 0.5078
PA/bar 1.55 3.21 5.73 7.66 8.77 9.37

Solvent (A): 1-pentene C5H10 109-67-1

T/K = 423.65
wB 0.9741 0.9096 0.8092 0.6704 0.5286
PA/bar 1.58 5.01 9.40 14.05 16.50
T/K = 474.15
wB 0.9602 0.9088 0.8082 0.6972 0.5840
PA/bar 4.20 9.36 17.57 25.63 32.74

−1 −1 3
Characterization: Mn/kg.mol = 14, Mw/kg.mol = 94, ρ = 0.951 g/cm , HDPE
Solvent (A): propane C3H8 74-98-6

continued
_____________________________________________________________________________
continued
T/K = 422.0
P/Torr 124 250 479 793 1182 1337
wA 0.00036 0.00073 0.00140 0.00242 0.00338 0.00370
T/K = 477.6
P/Torr 119 250 589 815 1093 1443
wA 0.00023 0.00049 0.00120 0.00169 0.00226 0.00291
T/K = 533.2
P/Torr 84.5 280 487 905 1233 1447
wA 0.00013 0.00048 0.00082 0.00155 0.00215 0.00261

Solvent (A): propyl acetate C5H10O2 109-60-4

T/K = 426.15
wB 0.9521 0.8891 0.7831 0.6457 0.5005
PA/bar 0.86 1.78 2.77 3.39 3.77
T/K = 474.15
wB 0.9621 0.8963 0.8030 0.6666 0.5117
PA/bar 1.59 3.77 6.31 8.77 10.39

Solvent (A): 2-propylamine C3H9N 75-31-0
T/K = 427.15
wB 0.95478 0.8959 0.8140 0.6776 0.5245
PA/bar 4.32 8.90 13.53 17.76 19.95
T/K = 475.15
wB 0.96168 0.90917 0.8370 0.7163 0.5692
PA/bar 4.56 10.76 18.85 29.77 38.37
Polymer (B): poly(ethylene glycol) 2004WEI

Characterization: Mw/kg.mol−1 = 0.2, Hoechst AG, Frankfurt/M., Germany
continued
_____________________________________________________________________________
continued
T/K = 303.15
P/bar 22 44 69 78 98 157 190 221 242
wA 0.077 0.114 0.198 0.208 0.214 0.224 0.233 0.250 0.253
T/K = 323.15
P/bar 23 37 60 81 116 148 194 241 278
wA 0.057 0.081 0.128 0.160 0.188 0.203 0.215 0.230 0.236
T/K = 353.15
P/bar 32 40 61 80 102 127 174 190 218
wA 0.052 0.061 0.079 0.107 0.134 0.152 0.165 0.182 0.192
P/bar 258 285
wA 0.210 0.217
T/K = 373.15
P/bar 25 37 51 66 78 90 107 123 143
wA 0.036 0.048 0.058 0.077 0.085 0.100 0.114 0.130 0.142
P/bar 158 198 237 252 285
wA 0.152 0.170 0.190 0.197 0.203
Polymer (B): poly(ethylene glycol) 2000WIE, 2004WEI


T/K = 316.15
P/bar 20 41 61 82 116 137 181 232 284
wA 0.041 0.090 0.148 0.198 0.232 0.238 0.262 0.281 0.295
T/K = 323.15
P/bar 21 41 54 78 118 157 203 240 271
wA 0.034 0.090 0.117 0.169 0.200 0.215 0.263 0.298 0.300
T/K = 333.15
P/bar 21 45 74 106 138 211 230 286
wA 0.034 0.080 0.143 0.187 0.215 0.249 0.253 0.260
T/K = 353.15
P/bar 20 41 61 79 98 130 162 202 270
wA 0.021 0.050 0.081 0.108 0.137 0.156 0.179 0.206 0.245
Comments: Other gas solubilities are given together with the cloud points in Chapter 4.
_____________________________________________________________________________


T/K = 328.15
P/bar 43 60 81 138 182 221 260 282
wA 0.098 0.119 0.158 0.205 0.238 0.260 0.271 0.286
T/K = 333.15
P/bar 5 9 20 34 40 61 80 115 139
wA 0.013 0.022 0.044 0.062 0.073 0.109 0.147 0.162 0.198
P/bar 220 286
wA 0.249 0.266
T/K = 353.15
P/bar 6 16 24 31 44 54 66 79 117
wA 0.011 0.022 0.037 0.042 0.054 0.073 0.089 0.106 0.133
P/bar 140 181 219 265
wA 0.157 0.193 0.215 0.234
T/K = 373.15
P/bar 11 20 32 40 44 53 58 81 101
wA 0.011 0.015 0.032 0.042 0.047 0.054 0.062 0.087 0.102
P/bar 149 178 220 257
wA 0.157 0.159 0.188 0.197
Polymer (B): poly(ethylene glycol) 2000WIE

Comments: The gas solubilities are given together with the cloud points in Chapter 4.


T/K = 323.15
P/bar 49 62 87 98 110 137 188
wB 0.9994 0.9990 0.9986 0.9982 0.9978 0.9971 0.9961
continued
_____________________________________________________________________________
continued
T/K = 333.15
P/bar 88 112 140 172 187
wB 0.9981 0.9976 0.9968 0.9959 0.9954
T/K = 353.15
P/bar 65 76 89 115 140 183 192
wB 0.9983 0.9981 0.9978 0.9972 0.9965 0.9951 0.9948


T/K = 338.15
P/bar 69 81 120 138 139 175 200
wB 0.9990 0.9984 0.9971 0.9965 0.9965 0.9958 0.9953
T/K = 353.15
P/bar 80 100 123 145 180 200
wB 0.9979 0.9973 0.9964 0.9959 0.9947 0.9944
T/K = 373.15
P/bar 62 84 104 118 137 181 199
wB 0.9982 0.9975 0.9966 0.9962 0.9955 0.9939 0.9932


T/K = 353.15
P/bar 82 95 116 143 178 199
wB 0.9976 0.9972 0.9968 0.9962 0.9951 0.9932
T/K = 373.15
P/bar 58 78 99 120 138 176 199
wB 0.9986 0.9972 0.9968 0.9961 0.9955 0.9941 0.9932


continued
_____________________________________________________________________________
continued
T/K = 393.15
P/bar 7 20 31 39 51 62 83 120 162
wA 0.0023 0.0113 0.0209 0.0262 0.0330 0.0364 0.0394 0.0424 0.0468


T/K = 393.15
P/bar 38 49 78 114 156 198
wA 0.033 0.048 0.057 0.059 0.063 0.066


T/K = 393.15
P/bar 10 21 30 41 50 66
wA 0.012 0.023 0.032 0.045 0.052 0.061
Comments: Other solubilities are given together with the cloud points in Chapter 4.

−1
Characterization: Mw/kg.mol = 4.0, Hoechst AG, Frankfurt/M., Germany

T/K = 333.15
P/bar 20 23 31 50 120 160 220
wA 0.042 0.050 0.052 0.053 0.056 0.057 0.058
T/K = 353.15
P/bar 11 21 52 64 80 110 120 160 250
wA 0.020 0.038 0.059 0.061 0.058 0.064 0.061 0.062 0.064
T/K = 373.15
P/bar 9 20 30 40 62 90 150 200 250
wA 0.014 0.026 0.040 0.053 0.062 0.070 0.073 0.076 0.077
continued
_____________________________________________________________________________
continued
T/K = 393.15
P/bar 11 20 30 40 50 60 70 100 110
wA 0.010 0.021 0.034 0.044 0.054 0.060 0.065 0.072 0.076
P/bar 140 190 250
wA 0.077 0.088 0.094


T/K = 393.15
P/bar 11 20 30 46 59 68 110 150
wA 0.013 0.024 0.037 0.054 0.062 0.067 0.075 0.077
Comments: Other solubilities are given together with the cloud points in Chapter 4.
Polymer (B): poly(ethylene glycol) dimethyl ether 2004WEI

Type of data: liquid-gas equilibrium (first line – liquid, second line – gas phase)
T/K = 298.15
P/bar 10 20 30 41 49 57
wA 0.0517 0.1255 0.2344 0.3064 0.4073 0.5604
P/bar 10 20 30 41 49 57
wA 0.9731 0.9787 0.9632 0.9812 0.9843 0.9863
T/K = 311.15
P/bar 10 20 40 61 75
wA 0.0185 0.0689 0.1626 0.3220 0.5175
P/bar 10 20 40 61 75
wA 0.9864 0.9754 0.9870 0.9855
T/K = 351.15
P/bar 20 41 67 105 127 142 151 165
wA 0.0507 0.1127 0.2164 0.3152 0.3991 0.4593 0.4645 0.5260
P/bar 105 127 142 151 165
wA 0.9757 0.9798 0.9735 0.9567 0.9397
continued
_____________________________________________________________________________
continued
T/K = 373.15
P/bar 14 42 68 106 126 150 167 178 196
wA 0.0288 0.0810 0.1451 0.2300 0.2988 0.3573 0.4008 0.4490 0.4977
P/bar 13 41 68 106 126 150 167 178 196
wA 0.9955 0.9614 0.9628 0.9775 0.9789 0.9667 0.9638 0.9490 0.9178
T/K = 393.15
P/bar 20 45 70 106 131 165 181 198
wA 0.0364 0.0733 0.1304 0.2014 0.2556 0.3240 0.3545 0.3909
P/bar 106 131 165 181 198
wA 0.9768 0.9696 0.9675 0.9533 0.9557
Polymer (B): poly(ethylene glycol) dimethyl ether 2004WEI


T/K = 316.15
P/bar 20 41 61 82 116 137 181 211 232
wA 0.041 0.090 0.148 0.198 0.232 0.238 0.262 0.262 0.281
T/K = 333.15
P/bar 21 45 74 106 138 211 230 286
wA 0.034 0.080 0.143 0.187 0.215 0.249 0.253 0.260
T/K = 353.15
P/bar 20 41 61 79 98 130 162 202 270
wA 0.021 0.050 0.081 0.108 0.137 0.156 0.179 0.206 0.245

Characterization: PEGDM mixture used for the Selexol process
diethylene glycol dimethylether 2.07 wt%
diethylene glycol monomethylether 0.16 wt%
triethylene glycol dimethylether 21.01 wt%
triethylene glycol monomethylether 0.72 wt%
tetraethylene glycol dimethylether 33.68 wt%
tetraethylene glycol monomethylether 0.67 wt%
pentaethylene glycol dimethylether 26.39 wt%
pentaethylene glycol monomethylether 0.38 wt%
hexaethylene glycol dimethylether 12.78 wt%
hexaethylene glycol monomethylether 0.10 wt%
heptaethylene glycol dimethylether 1.87 wt%

continued
_____________________________________________________________________________
continued
T/K = 298.15
P/MPa 0.486 0.800 1.064 1.530 2.037 2.553 3.141 3.557 4.023
xA 0.1110 0.1745 0.2208 0.2947 0.3725 0.4364 0.5060 0.5523 0.6162
T/K = 313.15
P/MPa 0.456 0.790 1.034 1.550 2.067 2.543 3.080 3.617 4.418
xA 0.0813 0.1384 0.1753 0.2426 0.2955 0.3554 0.4116 0.4621 0.5438
T/K = 333.15
P/MPa 0.527 0.760 1.023 1.550 2.067 2.726 3.019 3.597 4.104
xA 0.0641 0.0998 0.1263 0.1821 0.2347 0.2955 0.3270 0.3820 0.4292

see data set above

T/K = 298.15
P/MPa 1.023 1.419 1.692 1.925 2.260 2.543 3.060 3.577 4.104
xA 0.0048 0.0067 0.0078 0.0089 0.0105 0.0119 0.0141 0.0165 0.0189
T/K = 313.15
P/MPa 1.044 1.398 1.571 1.945 2.401 2.624 3.101 3.567 4.063
xA 0.0052 0.0069 0.0077 0.0095 0.0118 0.0129 0.0151 0.0174 0.0197
T/K = 333.15
P/MPa 1.003 1.358 1.601 1.834 2.270 2.503 2.969 3.445 4.043
xA 0.0053 0.0072 0.0084 0.0096 0.0120 0.0131 0.0156 0.0180 0.0210
Polymer (B): poly(ethylene glycol) dimethyl ether 1998HER

Characterization: Mn/kg.mol−1 = 0.283, Aldrich Chem. Co., Inc., Milwaukee, WI
octaethylene glycol dimethylether 8.51 wt%
nonaethylene glycol dimethylether 2.64 wt%
Solvent (A): methanol CH4O 67-56-1
continued
_____________________________________________________________________________
continued
T/K = 343.15
xB 0.6010 0.5201 0.4443 0.3572 0.2833 0.1928 0.1173 0.0392 0.0297
PA/kPa 43.11 53.89 62.71 74.10 84.45 96.83 109.82 118.84 121.51
T/K = 353.15
xB 0.6010 0.5201 0.4443 0.3572 0.2833 0.1928 0.1173 0.0392 0.0297
PA/kPa 60.64 76.14 89.34 105.49 120.70 139.16 157.80 172.01 175.50
T/K = 363.15
xB 0.6008 0.5201 0.4443 0.3572 0.2833 0.1928 0.1173 0.0392 0.0297
PA/kPa 83.42 104.85 123.26 146.98 168.25 195.19 222.17 243.60 246.59
T/K = 373.15
xB 0.6009 0.5201 0.4443 0.3572 0.2833 0.1928 0.1173 0.0392 0.0297
PA/kPa 112.61 141.17 167.20 200.29 231.07 268.50 305.54 337.30 340.69
T/K = 383.15
xB 0.9159 0.8413 0.7629 0.6803 0.6009 0.5201 0.4443 0.3572 0.2833
PA/kPa 28.46 54.23 83.00 115.11 148.96 186.39 222.04 267.55 307.61
xB 0.1928 0.1173 0.0392 0.0297
PA/kPa 361.77 412.33 457.40 462.35
T/K = 393.15
xB 0.9159 0.8413 0.7629 0.6803 0.6009 0.5201 0.4443 0.3572 0.2833
PA/kPa 36.70 69.87 106.95 149.12 193.10 241.40 289.66 350.85 408.64
xB 0.1928 0.1173 0.0392 0.0297
PA/kPa 477.72 546.34 609.59 617.00
T/K = 403.15
xB 0.9159 0.8413 0.7629 0.6803 0.6009 0.5201 0.4443 0.3572 0.2833
PA/kPa 46.90 88.45 135.60 189.55 246.06 307.07 371.52 452.18 529.20
xB 0.1928 0.1173 0.0392 0.0297
PA/kPa 621.44 712.08 799.30 811.56
T/K = 413.15
xB 0.9159 0.8413 0.7628 0.6803 0.6009 0.5200 0.4443 0.3571 0.2833
PA/kPa 58.86 110.32 169.50 237.39 306.80 382.60 467.78 573.95 673.97
xB 0.1928 0.1173 0.0392
PA/kPa 795.58 914.30 914.30
T/K = 423.15
xB 0.8413 0.7628 0.6803 0.6009 0.5200 0.4442 0.3571 0.2833 0.1928
PA/kPa 135.70 208.70 292.61 377.15 467.80 581.00 717.44 846.21 1004.6
Comments: Additional data below 343 K can be found in the original source.
_____________________________________________________________________________


T/K = 298.15
P/MPa 1.044 1.368 1.581 1.834 2.047 2.331 2.574 3.010 3.547
xA 0.0058 0.0076 0.0089 0.0103 0.0114 0.0130 0.0143 0.0167 0.0197
T/K = 313.15
P/MPa 1.084 1.409 1.571 1.783 2.037 2.432 2.918 3.466 3.770
xA 0.0066 0.0085 0.0094 0.0108 0.0124 0.0146 0.0175 0.0206 0.0224
T/K = 333.15
P/MPa 1.074 1.297 1.530 1.844 2.057 2.543 2.837 3.182 3.597
xA 0.0071 0.0087 0.0101 0.0122 0.0136 0.0168 0.0186 0.0210 0.0235
Polymer (B): poly(ethylene glycol) monododecyl ether-

b-poly(propylene glycol) diblock copolymer 2002LIU
−1
Characterization: Mn/kg.mol = 0.67, 3 EO und 6 PPO units, Ls-36 Surfactant,
Henkel AG, Germany

T/K = 308.15
P/MPa 11.10 14.50 16.73 18.71 19.74
cB/mol.l−1 0.01 0.02 0.03 0.04 0.05
T/K = 318.15
P/MPa 15.31 17.56 19.78 21.33
cB/mol.l−1 0.01 0.02 0.03 0.04
_____________________________________________________________________________
Polymer (B): poly(ethylene glycol) monododecyl ether-

b-poly(propylene glycol) diblock copolymer 2002LIU
Characterization: Mn/kg.mol−1 = 0.65, 4 EO und 5 PPO units, Ls-45 Surfactant,
Henkel AG, Germany

T/K = 308.15
P/MPa 12.97 16.73 19.32 21.05
cB/mol.l−1 0.01 0.02 0.03 0.04
T/K = 318.15
P/MPa 16.46 20.11 22.37
cB/mol.l−1 0.01 0.02 0.03
Polymer (B): polyisobutylene 2002JOU

Aldrich Chem. Co., Inc., Milwaukee, WI

T/K 363.15 373.15 383.95 398.25 403.15 413.15 423.15 433.15
PA/MPa 0.4 0.5 0.5 0.6 0.7 0.9 1.0 1.1
Comments: Liquid-liquid equilibrium data for this system are given in Chapter 3.
Polymer (B): polyisoprene 1997ZHA

Characterization: Mη/kg.mol−1 = 100, synthesized in the laboratory
T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0256 0.0481 0.0720 0.0975 0.1197 0.1582 0.2019
(∆V/V)/(%) 2.25 3.75 6.07 8.69 10.6 13.9 17.0
Polymer (B): poly(methyl methacrylate) 1997ZHA


continued
_____________________________________________________________________________
continued
T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0381 0.0650 0.0897 0.1119 0.1379 0.1590 0.1817
(∆V/V)/(%) 3.15 5.63 8.52 11.1 13.6 15.7 17.1
Polymer (B): poly(methyl methacrylate) 1991WI1, 1991WI2

Characterization: Mw/kg.mol−1 = 90, Tg/K = 378,
Scientific Polymer Products, Inc., Ontario, NY
Type of data: gas solubility and swelling at Tg

Tg/K 331.95 315.15 305.85
P/atm 39 40 39
cA/(cm3(STP)/g polymer) 37 50 61
(∆V/V)/(%) 5.8 8.3 10.4
Polymer (B): poly(methyl methacrylate) 1996HAN

Röhm and Haas

P/atm 0.0 8.8 18.2 22.3 29.5 37.2
Tg/K 363.85 353.65 342.35 336.85 332.85 323.95
Polymer (B): poly(methyl methacrylate) 1998EDW


T/K = 263.15
P/atm 15
cA/(cm3(STP)/g polymer) 46.1
T/K = 273.15
P/atm 15 30
cA/(cm3(STP)/g polymer) 40.2 78.4
T/K = 283.15
P/atm 15 30
cA/(cm3(STP)/g polymer) 29.4 67.7
continued
_____________________________________________________________________________
continued
T/K = 293.15
P/atm 15 30 45
cA/(cm3(STP)/g polymer) 25.0 55.8 74.9
T/K = 303.15
P/atm 15 30 45 60 75
cA/(cm3(STP)/g polymer) 22.0 42.1 60.7 88.6 115.3
T/K = 313.15
P/atm 15 30 45 60 75 90
cA/(cm3(STP)/g polymer) 19.2 36.6 48.9 72.4 90.4 129.7
T/K = 323.15
P/atm 15 30 45 60 75 90
T/K = 333.15
P/atm 15 30 45 60 75 90
T/K = 343.15
P/atm 30 45 60 90
cA/(cm3(STP)/g polymer) 19.9 29.9 43.5 59.3
T/K = 353.15
P/atm 15 30 45 60 75 90
T/K = 363.15
P/atm 30 60 90
T/K = 373.15
P/atm 15 30 45 60 75 90
T/K = 383.15
P/atm 30 60 90
T/K = 393.15
P/atm 15 30 45 60 75 90
T/K = 413.15
P/atm 15 30 45 60 75 90
continued
_____________________________________________________________________________
continued
T/K = 433.15
P/atm 15 30 45 60 75 90
T/K = 453.15
P/atm 15 30 45 60 75 90
Polymer (B): poly(methyl methacrylate) 2003WAN


T/K = 298.15
P/MPa 0.2 0.3 0.4
wA 0.0152 0.0218 0.0269
Polymer (B): poly(methyl methacrylate) 1999WEB

Characterization: Laird Plastics, Atlanta, GA

T/K = 313.15 P/MPa 10.5 wA 0.1817

Röhm and Haas

P/atm 0.0 11.0 21.8 21.8 36.3 54.5
Tg/K 363.85 353.35 347.85 346.85 339.95 330.45

Röhm and Haas

P/atm 0.0 11.4 24.5 48.4 97.0 152 218
Tg/K 363.85 361.15 360.35 357.45 353.95 348.65 346.65
_____________________________________________________________________________
Polymer (B): polypropylene 1999SAT

Characterization: Mw/kg.mol−1 = 52, Mw/kg.mol−1 = 220,
Idemitsu Petrochemical, Ichihara, Japan

T/K = 453.15
P/MPa 7.083 11.443 14.212 16.037 17.242
wA 0.0400 0.0739 0.0999 0.1169 0.1249


T/K = 433.15
P/MPa 7.400 11.803 14.558 16.355 17.529
wA 0.0479 0.0866 0.1113 0.1267 0.1370
T/K = 453.15
P/MPa 5.419 7.160 8.797 10.953 11.558 12.352 14.889 16.170 17.376
wA 0.0313 0.0422 0.0561 0.0730 0.0780 0.0840 0.1038 0.1155 0.1242
T/K = 473.15
P/MPa 6.204 10.113 12.637 14.296 15.397
wA 0.0293 0.0570 0.0766 0.0883 0.0980


T/K = 453.15
P/MPa 4.233 7.115 9.031 10.898 12.699 14.938 17.999
wA 0.00437 0.00752 0.00965 0.01173 0.01351 0.01675 0.01892
T/K = 473.15
P/MPa 4.013 6.726 8.545 9.878 11.998 14.819 17.838
wA 0.00450 0.00848 0.01048 0.01206 0.01491 0.01960 0.02200
_____________________________________________________________________________
Polymer (B): polypropylene 2000SA2

Characterization: Mw/kg.mol−1 = 190, 98.5% isotactic, 66.9 wt% crystallinity,

T/K = 323.15
P/MPa 0.2761 0.3256 0.6050 0.6405 1.1073 1.1720 1.4685 1.5334 1.6131
wA 0.00862 0.01021 0.01869 0.01969 0.03474 0.03760 0.04754 0.05008 0.05341
P/MPa 1.7000 1.8215 1.9223
wA 0.05673 0.06299 0.07023
T/K = 343.15
P/MPa 0.3226 0.6268 0.9238 1.0580 1.5331 2.1616 2.4071 2.8347
wA 0.00661 0.01302 0.01911 0.02182 0.03285 0.04929 0.05592 0.07129
T/K = 363.15
P/MPa 0.3621 0.6992 1.2676 1.7470 2.3472 2.7945 3.6261
wA 0.00550 0.01057 0.01959 0.02781 0.03889 0.04818 0.06491
Polymer (B): polystyrene 2003WAN

Characterization: Mw/kg.mol−1 = 50, Tg/K = 373.2

T/K = 298.15
P/MPa 0.4 0.5 0.6 0.7 0.8 0.9
wA 0.0064 0.0081 0.0092 0.0103 0.0110 0.0117
Polymer (B): polystyrene 1997ZHA


T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0181 0.0318 0.0475 0.0547 0.0559 0.0426 0.0527
(∆V/V)/(%) 1.58 2.77 4.14 5.48 7.11 7.93 8.61
Polymer (B): polystyrene 1996SAT

Mitsui Toatsu Chemicals, Inc., Japan
continued
_____________________________________________________________________________
continued
T/K = 373.15
P/MPa 3.617 5.860 7.921 11.928 14.348 15.908 17.476 18.554
wA 0.0221 0.0347 0.0462 0.0724 0.0850 0.0909 0.0994 0.1037
T/K = 413.15
P/MPa 7.290 10.721 11.594 11.994 14.316 14.738 16.110 17.087 18.097
wA 0.0335 0.0500 0.0548 0.0568 0.0678 0.0666 0.0769 0.0789 0.0852
P/MPa 19.739 20.036
wA 0.0919 0.0949
T/K = 453.15
P/MPa 2.472 6.276 10.188 12.704 14.379 15.444 17.372
wA 0.0093 0.0214 0.0374 0.0488 0.0539 0.0562 0.0643
Polymer (B): polystyrene 2001HIL

Lacqrene 1450N, ATOFINA, France

T/K = 338.22
P/MPa 3.71 7.54 10.25 11.96 16.54 18.33 24.52
wA 0.03581 0.06942 0.08684 0.09596 0.12205 0.12786 0.13510
(∆V/V)/(%) 3.860 7.300 9.440
T/K = 362.50
P/MPa 4.30 8.09 11.47 14.15 16.50 18.92 21.60 24.65
wA 0.03627 0.05866 0.08056 0.09271 0.10826 0.11540 0.12188 0.12690
(∆V/V)/(%) 4.16 7.00 9.19 10.94 12.03 12.69 13.13 13.34
T/K = 383.22
P/MPa 6.55 11.04 14.51 17.66 20.42 23.55 27.03 30.61
wA 0.03472 0.05488 0.06907 0.08483 0.09514 0.10423 0.10962 0.12137
(∆V/V)/(%) 5.24 7.14 8.73 9.74 10.46 11.03 11.27 12.04
P/MPa 34.38 38.63 42.81
wA 0.12603 0.13073 0.13835
(∆V/V)/(%) 12.32 12.86 13.05
T/K = 402.51
P/MPa 5.14 9.39 21.48 33.05 44.41
wA 0.01441 0.04225 0.08759 0.11887 0.12914
_____________________________________________________________________________
Polymer (B): polystyrene 2001SA2

Asahi Chemicals Inc., Kawasaki, Japan
T/K = 373.15
P/MPa 2.068 2.627 4.093 4.629 6.038 6.502 8.054 8.585 12.105
wA 0.0126 0.0159 0.0247 0.0279 0.0362 0.0388 0.0475 0.0506 0.0690
P/MPa 12.631 16.059 20.067
wA 0.0717 0.0898 0.1086
T/K = 423.15
P/MPa 2.159 2.689 4.073 4.732 6.049 6.530 8.071 8.566 12.046
wA 0.00896 0.0112 0.0168 0.0194 0.0247 0.0267 0.0327 0.0346 0.0473
P/MPa 12.593 16.143
wA 0.0492 0.0606
T/K = 473.15
P/MPa 2.167 2.884 4.232 4.795 6.108 6.685 8.027 8.813 12.165
wA 0.0071 0.0094 0.0137 0.0155 0.0197 0.0215 0.0257 0.0282 0.0381
P/MPa 12.659 16.040 20.151
wA 0.0397 0.0489 0.0587
Polymer (B): polystyrene 1991WI1, 1991WI2

Characterization: Mw/kg.mol−1 = 250, Tg/K = 373,
Type of data: gas solubility and swelling at Tg
Tg/K 338.15 323.15 308.15
P/atm 36 48 60
cA/(cm3(STP)/g polymer) 19 30 46
(∆V/V)/(%) 4.1 5.5 7.4

Solvent (A): 1-chloro-1,1-difluoroethane C2H3ClF2 75-68-3
T/K = 347.92
P/MPa 0.091 0.156 0.341 0.506 0.525 0.644 0.678
wA 0.0098 0.0135 0.0401 0.0638 0.0661 0.0858 0.0912
continued
_____________________________________________________________________________
continued
T/K = 373.62
P/MPa 0.124 0.185 0.474 0.728 0.743 0.940 0.989
wA 0.0089 0.0131 0.0365 0.0590 0.0603 0.0794 0.0837
T/K = 422.15
P/MPa 0.194 0.291 0.758 1.207 1.225 1.605 1.674
wA 0.0074 0.0113 0.0302 0.0503 0.0502 0.0679 0.0696
T/K = 471.42
P/MPa 0.263 0.402 1.030 1.666 1.726 2.289 2.353
wA 0.0063 0.0099 0.0258 0.0430 0.0438 0.0588 0.0594
Polymer (B): polystyrene 1986GOR

Characterization: Dow Styron 430U
PA/P0A 0.3557 0.2668 0.1353
T/K 323.15 358.15 443.15
wA 0.0699 0.0580 0.0415
ϕA 0.0661 0.0607 0.0554

Solvent (A): dichlorodifluoromethane CCl2F2 75-71-8

PA/P0A 0.6486 0.3360 0.1477
T/K 323.15 358.15 443.15
wA 0.0514 0.0523 0.0392
ϕA 0.04392 0.04838 0.04302

Solvent (A): 1,2-dichloro-1,1,2,2-tetrafluoroethane C2Cl2F4 76-14-2

PA/P0A 0.6966 0.3453 0.0885
T/K 323.15 358.15 443.15
wA 0.00802 0.00430 0.00587
ϕA 0.006192 0.003540 0.005581
_____________________________________________________________________________

Solvent (A): 1,1-difluoroethane C2H4F2 75-37-6

T/K = 348.15
P/MPa 0.283 0.485 0.678 0.689 0.829 0.991 1.200
wA 0.0122 0.0212 0.0308 0.0310 0.0381 0.0479 0.0594
T/K = 373.13
P/MPa 0.367 0.639 0.889 0.904 1.090 1.322 1.603
wA 0.0107 0.0188 0.0272 0.0274 0.0337 0.0426 0.0521
T/K = 423.14
P/MPa 0.529 0.938 1.289 1.314 1.592 1.964 2.375
wA 0.0087 0.0157 0.0222 0.0224 0.0274 0.0352 0.0422
T/K = 473.09
P/MPa 0.677 1.218 1.659 1.707 2.059 2.568 3.116
wA 0.0074 0.0136 0.0192 0.0192 0.0238 0.0310 0.0365
Polymer (B): polystyrene 1948NEW


T/K = 443.2
P/atm 49.0 77.5 92.5 92.5
cA/(cm3/g polymer) 5.27 8.05 9.20 10.30
Polymer (B): polystyrene 1948NEW


T/K = 443.2
P/atm 80.0 142.0 224.5 233.0 243.0 306.5
cA/(cm3/g polymer) 2.89 5.35 8.48 9.42 9.66 11.95
Polymer (B): polystyrene 1963LUN

continued
_____________________________________________________________________________
continued
T/K = 373.35
P/atm 67.1 239.0 319.8
cA/(cm3/g polymer) 8.15 22.15 32.12
T/K = 398.57
P/atm 49.7 214.1 299.2 343.6
cA/(cm3/g polymer) 4.98 18.82 25.54 27.94
T/K = 428.57
P/atm 47.6 161.7 241.3
cA/(cm3/g polymer) 5.44 15.59 23.45
T/K = 461.55
P/atm 122.2 198.2 249.8 313.6
cA/(cm3/g polymer) 14.19 21.49 26.07 31.45
Polymer (B): polystyrene 1997END

Solvent (A): methylcyclohexane C7H14 108-87-2
wB 0.060 0.060 0.060 0.060 0.060 0.060 0.060 0.060 0.060
T/K 492.32 494.74 497.21 499.68 502.15 504.32 506.80 509.18 511.46
P/bar 10.6 11.0 11.5 12.0 12.5 13.0 13.5 14.1 14.6
wB 0.065 0.065 0.065 0.065 0.065 0.065 0.065 0.065 0.065
T/K 489.72 492.21 494.69 497.20 499.45 502.12 504.64 507.12 509.61
P/bar 10.0 10.5 10.9 11.4 11.9 12.4 12.9 13.5 14.0
wB 0.065 0.065 0.065 0.065 0.098 0.098 0.098 0.098 0.098
T/K 512.10 514.59 517.04 519.50 488.73 491.25 493.81 496.06 498.56
P/bar 14.6 15.1 15.7 16.6 9.5 9.9 10.3 10.9 11.3
wB 0.098 0.098 0.098 0.098 0.098 0.098 0.098 0.098 0.098
T/K 498.69 501.30 503.80 506.47 508.41 508.55 511.16 513.88 516.07
P/bar 11.4 11.9 12.3 12.9 13.4 13.3 14.0 14.6 15.0
wB 0.098 0.152 0.152 0.152 0.152 0.152 0.152 0.152 0.152
T/K 518.60 489.74 492.32 494.53 496.07 498.70 501.30 503.81 506.46
P/bar 15.8 9.0 9.5 9.9 10.2 10.9 11.3 11.9 12.5
wB 0.152 0.152 0.152 0.152 0.152 0.187 0.187 0.187 0.187
T/K 508.42 511.15 513.88 516.05 518.84 489.74 492.31 494.54 496.06
P/bar 12.8 13.4 14.0 14.5 15.0 8.7 9.2 9.6 9.9
wB 0.187 0.187 0.187 0.187 0.187 0.187 0.187 0.187 0.187
T/K 498.69 501.30 503.80 506.47 508.41 511.16 513.88 516.08 518.85
P/bar 10.6 11.0 11.7 12.2 12.5 13.0 13.6 14.1 14.6
Comments: Cloud-points and spinodal points for this system are given in Chapter 3.
_____________________________________________________________________________
Polymer (B): polystyrene 1992WAN

Characterization: Mw/kg.mol−1 = 69.3, Mw/kg.mol−1 = 187

T/K = 323.2
P/MPa 2.0 5.0 8.0 11.0 14.0 17.0 20.0 23.0 25.0
wA 0.0020 0.0037 0.0050 0.0062 0.0073 0.0084 0.0095 0.0105 0.0112
T/K = 353.2
P/MPa 2.0 5.0 8.0 11.0 14.0 17.0 20.0 23.0 25.0
wA 0.0016 0.0034 0.0050 0.0066 0.0080 0.0095 0.0109 0.0123 0.0132
T/K = 393.2
P/MPa 2.0 5.0 8.0 11.0 14.0 17.0 20.0 23.0 25.0
wA 0.0017 0.0037 0.0056 0.0074 0.0092 0.0109 0.0126 0.0143 0.0155

Characterization: Mw/kg.mol−1 = 70.3, Mw/kg.mol−1 = 187,

T/K = 313.15
P/MPa 4.934 8.378 10.771 12.450 16.136
wA 0.00220 0.00438 0.00591 0.00627 0.00818
T/K = 333.15
P/MPa 5.037 6.149 7.882 9.868 11.034 11.674 13.457 16.542
wA 0.00182 0.00215 0.00305 0.00355 0.00426 0.00428 0.00484 0.00630
T/K = 353.15
P/MPa 2.989 3.645 5.053 5.295 6.476 7.945 9.042 9.535 11.660
wA 0.00106 0.00131 0.00168 0.00180 0.00232 0.00295 0.00308 0.00339 0.00395
P/MPa 11.770 14.071 17.521
wA 0.00417 0.00497 0.00627
Polymer (B): polystyrene 2001HIL

Lacqrene 1450N, ATOFINA, France

T/K = 313.11
continued
_____________________________________________________________________________
continued
P/MPa 3.11 5.32 6.91 9.15 10.88 14.26 18.17 22.11
wA 0.00217 0.00341 0.00415 0.00484 0.00593 0.00753 0.00916 0.01033
(∆V/V)/(%) 0.102 0.219 0.300 0.408 0.487 0.627 0.772 0.937
P/MPa 26.65 31.73 46.77 69.47
wA 0.01236 0.01466 0.02099 0.02535
(∆V/V)/(%) 1.08 1.23 1.60 2.22
T/K = 333.23
P/MPa 3.05 6.43 9.82 13.47 16.43 20.29 24.34 28.14
wA 0.00109 0.00235 0.00425 0.00580 0.00689 0.00834 0.01063 0.01247
(∆V/V)/(%) 0.149 0.270 0.380 0.480 0.557 0.646 0.726 0.796
P/MPa 32.54 37.31 41.54 45.84 50.11
wA 0.01310 0.01482 0.01660 0.01815 0.02035
(∆V/V)/(%) 0.872 0.948 1.012 1.078 1.135
T/K = 353.15
P/MPa 3.29 7.00 10.42 13.95 17.26 21.38 25.35 30.26
wA 0.00157 0.00284 0.00414 0.00494 0.00615 0.00709 0.00849 0.00911
(∆V/V)/(%) 0.211 0.280 0.325 0.365 0.398 0.430 0.458 0.485
P/MPa 35.10 40.12 44.76 49.27 53.94 58.40 62.50
wA 0.01011 0.01151 0.01261 0.01436 0.01578 0.01674 0.01781
(∆V/V)/(%) 0.515 0.556 0.567 0.590 0.612 0.630 0.661

Characterization: Mw/kg.mol−1 = 70.3, Mw/kg.mol−1 = 187,

T/K = 373.15
P/MPa 9.467 12.165 14.008 16.113 17.815
wA 0.00379 0.00485 0.00556 0.00645 0.00710
T/K = 413.15
P/MPa 6.452 8.247 9.574 11.902 13.991 18.011
wA 0.00333 0.00393 0.00446 0.00606 0.00669 0.00853
T/K = 453.15
P/MPa 7.092 9.020 10.057 10.296 11.136 15.031 16.170
wA 0.00392 0.00523 0.00577 0.00588 0.00661 0.00890 0.00973
_____________________________________________________________________________
Polymer (B): polystyrene 1981ALB

BASF Telomerstyrol
Solvent (A): sulfur dioxide SO2 7446-09-5

T/K 292.95 283.65 275.55 264.45 254.05 242.85
PA/MPa 0.2828 0.2118 0.1578 0.1013 0.0668 0.0376
PA/P0A 0.8829 0.9145 0.9255 0.9414 0.9970 0.9691
Comments: More phase equilibrium data for this system are given in Chapter 4.

Solvent (A): 1,1,1,2-tetrafluoroethane C2H2F4 811-97-2

T/K = 348.16
P/MPa 0.333 0.496 0.745 0.863 1.150 1.308
wA 0.0108 0.0155 0.0232 0.0264 0.0363 0.0424
T/K = 373.16
P/MPa 0.414 0.609 0.911 1.057 1.420 1.621
wA 0.0092 0.0133 0.0202 0.0228 0.0311 0.0364
T/K = 423.15
P/MPa 0.552 0.811 1.214 1.421 1.919 2.199
wA 0.0075 0.0110 0.0169 0.0187 0.0255 0.0303
T/K = 473.16
P/MPa 0.682 1.000 1.501 1.757 2.384 2.748
wA 0.0067 0.0097 0.0151 0.0167 0.0229 0.0273

Solvent (A): trichlorofluoromethane CCl3F 75-69-4

PA/P0A 0.5789 0.4930 0.4132
T/K 323.15 358.15 403.15
wA 0.1586 0.1521 0.1414
ϕA 0.1236 0.1244 0.1207
_____________________________________________________________________________
Polymer (B): polystyrene-b-polybutadiene-b-polystyrene

triblock copolymer 2003WAN
Characterization: Mw/kg.mol−1 = 100, 70 mol% butadiene

T/K = 298.15
P/MPa 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
wA 0.0043 0.0064 0.0081 0.0105 0.0120 0.0140 0.0159 0.0180 0.0202
Polymer (B): polystyrene-b-polyisoprene diblock copolymer 1997ZHA

Characterization: Mη /kg.mol−1 = 100, 25 mol% isoprene,

T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0202 0.0349 0.0534 0.0646 0.0763 0.0858 0.0934
(∆V/V)/% 1.75 2.87 4.39 6.18 7.72 9.11 11.0


T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0210 0.0397 0.0592 0.0777 0.0848 0.0958 0.1119
(∆V/V)/% 1.84 3.23 5.21 7.01 8.54 11.1 12.0


T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0208 0.0384 0.0652 0.0839 0.1007 0.1197 0.1416
(∆V/V)/% 2.39 3.44 5.45 7.84 9.84 12.4 15.1
_____________________________________________________________________________
Polymer (B): polystyrene-b-poly(methyl methacrylate)

diblock copolymer 1997ZHA
Characterization: Mη /kg.mol−1 = 75, 18 mol% methyl methacrylate,

continued
T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0221 0.0388 0.0561 0.0667 0.0733 0.0767 0.0784
(∆V/V)/% 1.89 3.34 5.01 6.61 8.40 9.48 10.3


T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0277 0.0481 0.0666 0.0774 0.0908 0.0950 0.1031
(∆V/V)/% 2.78 4.44 5.85 7.68 9.68 12.1 13.2


T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0300 0.0522 0.0638 0.0850 0.1047 0.1150 0.1319
(∆V/V)/% 2.52 4.49 6.76 8.86 11.0 12.6 13.7
_____________________________________________________________________________

diblock copolymer 2003WAN
Characterization: Mw/kg.mol−1 = 12.1, 58.55 mol% methyl methacrylate

T/K = 298.15
P/MPa 0.2 0.3 0.4
wA 0.0224 0.0329 0.0424
Polymer (B): polystyrene-b-poly(vinyl pyridine)

Characterization: Mη /kg.mol−1 = 70, 44 mol% vinyl pyridine,

T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0207 0.0350 0.0513 0.0658 0.0777 0.0830 0.0950
(∆V/V)/% 2.62 4.49 5.81 6.91 8.43 9.05 10.5
Polymer (B): polystyrene-b-poly(vinyl pyridine)

Characterization: Mη /kg.mol−1 = 90, 77 mol% vinyl pyridine,

T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0224 0.0368 0.0515 0.0691 0.0832 0.1023 0.1150
(∆V/V)/% 3.09 5.21 6.68 7.73 8.94 9.78 13.4
Polymer (B): poly(vinyl acetate) 1990WAN, 1994WAN

Characterization: Mη/kg.mol−1 = 158, Aldrich Chem. Co., Inc., Milwaukee, WI

T/K = 313.2
continued
_____________________________________________________________________________
continued
P/MPa 0.294 0.667 1.16 1.86 2.41 2.52 3.16 3.29 4.07
wA 0.0113 0.0249 0.0428 0.0686 0.0953 0.0940 0.118 0.129 0.159
P/MPa 4.19 4.74 5.23 5.32 5.88 6.03 6.44 7.18
wA 0.158 0.182 0.209 0.210 0.251 0.256 0.282 0.327
T/K = 333.2
P/MPa 0.814 1.41 1.99 2.69 3.15 3.52 4.02 4.27 4.96
wA 0.0235 0.0383 0.0535 0.0720 0.0891 0.0948 0.112 0.115 0.136
P/MPa 5.12 5.71 6.12 6.99 7.93 8.88
wA 0.144 0.158 0.175 0.205 0.241 0.285
T/K = 353.2
P/MPa 0.843 1.50 2.18 2.18 2.90 3.03 3.51 3.96 4.30
wA 0.0193 0.0335 0.0476 0.0516 0.0625 0.0689 0.0752 0.0888 0.0914
P/MPa 4.64 5.12 5.46 5.70 6.32 7.27 8.05 9.22 10.1
wA 0.103 0.110 0.121 0.124 0.143 0.168 0.189 0.224 0.244
Polymer (B): poly(vinyl acetate) 1990TAK

−1
Characterization: Mη/kg.mol = 158, Aldrich Chem. Co., Inc., Milwaukee, WI

T/K = 313.2
P/MPa 1.258 1.449 2.650 3.467 3.846 4.583 5.659 6.885 8.755
wA 0.0416 0.0532 0.0936 0.1264 0.1429 0.1723 0.2123 0.2789 0.3909
T/K = 323.2
P/MPa 0.898 1.819 1.906 3.309 4.698 5.655 6.519 7.861
wA 0.0254 0.0485 0.0533 0.0978 0.1397 0.1696 0.2073 0.2668
Type of data: swelling (volume dilation)

T/K = 313.2
P/MPa 2.374 3.522 4.210 6.364 6.955 8.020 8.893
(∆V/V)/% 10.09 19.36 20.69 37.22 41.88 52.74 55.44
T/K = 323.2
P/MPa 1.725 3.793 4.804 5.444 6.187 6.850 8.403
(∆V/V)/% 5.99 15.21 19.12 23.97 25.85 31.18 39.01
_____________________________________________________________________________
Polymer (B): poly(vinyl acetate) 2001SA2

Characterization: Mn/kg.mol−1 = 167, Aldrich Chem. Co., Inc., Milwaukee, WI

T/K = 313.15
P/MPa 0.199 0.459 0.858 1.271 1.949 2.375 2.818 3.260 3.589
wA 0.0055 0.0144 0.0274 0.0410 0.0639 0.0785 0.0941 0.1100 0.1220
P/MPa 3.979 4.449 4.978 5.407 5.916 6.375 6.876
wA 0.1366 0.1545 0.1753 0.1927 0.2141 0.2341 0.2576
T/K = 333.15
P/MPa 2.263 4.104 6.010 7.772 9.694
wA 0.0531 0.0979 0.1463 0.1931 0.2495
T/K = 353.15
P/MPa 2.211 4.199 6.110 8.015 9.876
wA 0.0384 0.0737 0.1086 0.1433 0.1765
T/K = 373.15
P/MPa 2.257 6.389 10.194 13.688 17.449
wA 0.0296 0.0892 0.1453 0.1920 0.2303
Polymer (B): poly(vinyl pyridine) 1997ZHA

Characterization: Mη /kg.mol−1 = 65, synthesized in the laboratory

T/K = 308.15
P/MPa 1.379 2.758 4.137 5.516 6.895 8.274 10.342
wA 0.0252 0.0388 0.0538 0.0734 0.0967 0.1446 0.1518
(∆V/V)/% 3.52 6.19 7.48 8.42 9.52 10.5 15.0
_____________________________________________________________________________

____________________________________________________________________________________
____________________________________________________________________________________
Carboxymethylcellulose
carbon dioxide 1999KIK
____________________________________________________________________________________
Cellulose acetate
carbon dioxide 1978STE
carbon dioxide 1989BER
____________________________________________________________________________________
Cellulose acetate butyrate
carbon dioxide 1996SH2
____________________________________________________________________________________
Chloropolyethylene
carbon dioxide 1998AUB
____________________________________________________________________________________
Ethylcellulose
____________________________________________________________________________________
Ethylene/propylene copolymer
ethane 2001TSU
ethene 1994YOO
ethene 2001TSU
propane 2001TSU
propene 1994YOO
propene 2001TSU
____________________________________________________________________________________
carbon dioxide 1994KAM
carbon dioxide 2002SHI
methane 1994KAM
nitrogen 1994KAM
____________________________________________________________________________________
Natural rubber
carbon dioxide 2003WAN
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Nylon-66
____________________________________________________________________________________
Poly(acrylic acid)
____________________________________________________________________________________
Polyamide-11
carbon dioxide 2001MAR
____________________________________________________________________________________
Polyarylene
____________________________________________________________________________________
Poly(benzyl methacrylate)
____________________________________________________________________________________
Polybutadiene
argon 1989KA2
carbon dioxide 1989KA2
carbon dioxide 1997KRY
carbon dioxide 2003KOG
carbon dioxide 2003RAM
ethane 1989KA2
ethene 1989KA2
helium 1989KA2
hydrogen 1989KA2
methane 1989KA2
nitrogen 1989KA2
oxygen 1989KA2
____________________________________________________________________________________
Poly(butylene terephthalate)
carbon dioxide 1988THU
carbon dioxide 1991SCH
carbon monoxide 1991SCH
helium 1991SCH
methane 1991SCH
neon 1991SCH
nitrogen 1991SCH
water 1991SCH
____________________________________________________________________________________
Poly(butyl methacrylate)
carbon dioxide 2002NIK
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Poly(ε-caprolactone)
carbon dioxide 2003COT
____________________________________________________________________________________
Polycarbonate bisphenol-A
carbon dioxide 1976KOR
carbon dioxide 1986FLE
carbon dioxide 1987SAD
carbon dioxide 1987WIS
carbon dioxide 1993CON
carbon dioxide 1998ZHA
carbon dioxide 2003ALE
chlorodifluoromethane 1986GOR
chlorotrifluoromethane 1986GOR
dichlorodifluoromethane 1986GOR
1,2-dichloro-1,1,2,2-tetrafluoroethane 1986GOR
methane 1987SAD
____________________________________________________________________________________
Polycarbonate hexafluorobisphenol-A
____________________________________________________________________________________
Polycarbonate tetramethylene bisphenol-A
____________________________________________________________________________________
Poly(chlorotrifluoroethylene)
carbon dioxide 1999WEB
____________________________________________________________________________________
Poly(2-chloroxylylene)
____________________________________________________________________________________
Poly(2,3-dichloroxylylene)
____________________________________________________________________________________
Poly(2,6-dimethyl-1,4-phenylene oxide)
carbon dioxide 1982MOR
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Poly(dimethylsilmethylene)
carbon dioxide 1993SHA
methane 1993SHA
propane 1993SHA
____________________________________________________________________________________
Poly(dimethylsiloxane)
carbon dioxide 1986FLE
carbon dioxide 1991BRI
carbon dioxide 1991POP
carbon dioxide 1994GAR
carbon dioxide 1998WES
carbon dioxide 1999ANG
carbon dioxide 1999ROY
carbon dioxide 2001SIR
carbon dioxide 2002FLI
ethane 1991POP
ethane 1999ANG
methane 1986SHA
methane 1991POP
methane 1999ANG
nitrogen 1991POP
nitrogen 1999ANG
oxygen 1999ANG
propane 1986SHA
propane 1999ANG
____________________________________________________________________________________
Polyetherimide
____________________________________________________________________________________
Poly(ether sulfone)
carbon dioxide 1998BOE
dinitrogen oxide 1998BOE
methane 1998BOE
____________________________________________________________________________________
Polyethylene
argon 1987KOL
n-butane 1974DOS
n-butane 1975HOR
n-butane 1987CAS
1-butene 1974DOS
1-butene 1992WOH
carbon dioxide 1986HIR
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Polyethylene (continued)
carbon dioxide 2002AR1
carbon dioxide 2002AR2
ethane 1987HEU
ethene 1978CHE
ethene 1984FON
ethene 1984KOB
ethene 1987HEU
ethene 1992WOH
ethene 1995LOO
ethene 2000FEN
fluorotrichloromethane 1975HOR
n-hexane 1973BRO
n-hexane 1987CAS
n-hexane 1990KEN
4-methyl-1-pentene 1992WOH
2-methylpropane 1974DOS
2-methylpropene 1974DOS
methane 1963LUN
methane 1977BON
nitrogen 1962LUN
nitrogen 1963LUN
nitrogen 1975BON
nitrogen 1977BON
nitrogen 1978CHE
nitrogen 1986KA2
nitrogen 1986KOL
nitrogen 1987KOL
n-pentane 1987CAS
2,2,4-trimethylpentane 1973BRO
____________________________________________________________________________________
carbon dioxide 1997WEI
carbon dioxide 2001HAT
____________________________________________________________________________________
carbon dioxide 2001HAT
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Poly(ethylene terephthalate)
argon 1964VIE
carbon dioxide 1964VIE
carbon dioxide 1991LAM
carbon dioxide 2000BRA
methane 1964VIE
nitrogen 1964VIE
oxygen 1964VIE
____________________________________________________________________________________
Poly(ethyl methacrylate)
argon 1989CHI
carbon dioxide 1989CHI
methane 1989CHI
nitrogen 1989CHI
propane 1987GOR
____________________________________________________________________________________
Polyimide
____________________________________________________________________________________
Polyisobutylene
methane 1969LUN
methane 1977BON
n-pentane 2002JOU
____________________________________________________________________________________
Polyisoprene
carbon dioxide 2003RAM
____________________________________________________________________________________
carbon dioxide 1987WIS
carbon dioxide 1992CO1
carbon dioxide 1994GOE
carbon dioxide 1997VIN
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Poly(methyl methacrylate) (continued)
carbon dioxide 1998KAM
carbon dioxide 2002SIR
____________________________________________________________________________________
Poly(methyloctylsiloxane)
methane 1986SHA
propane 1986SHA
____________________________________________________________________________________
Poly(4-methyl-1-pentene)
____________________________________________________________________________________
Poly(methyltrifluoropropylsiloxane)
methane 1986SHA
propane 1986SHA
____________________________________________________________________________________
Poly(oxymethylene)
____________________________________________________________________________________
Poly(phenylmethylsiloxane)
methane 1986SHA
propane 1986SHA
____________________________________________________________________________________
Polypropylene
n-butane 1994HOR
n-butane 2001NAG
ethene 1994HOR
n-heptane 1994HOR
n-pentane 1994HOR
propene 1994HOR
propene 2001SA1
propene 2001TSU
propene 2003PAL
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Polystyrene
carbon dioxide 1982MOR
carbon dioxide 1982TOI
carbon dioxide 1986CAR
carbon dioxide 1989HAC
carbon dioxide 1998WON
carbon dioxide 2000FEN
carbon dioxide 2004CAO
1,1,1-chlorodifluoroethane 1999HON
chlorodifluoromethane 1999HON
1,1-difluoroethane 1994GAR
1,1-difluoroethane 1998HON
1,1-difluoroethane 1999HON
methane 1962LUN
methane 1963LUN
methane 1987SAD
nitrogen 2000FEN
nitrogen 2000HIL
nitrogen 1990KUM
1,1,1,2-tetrafluoroethane 1998WON
1,1,1,2-tetrafluoroethane 1998ZHA
1,1,1,2-tetrafluoroethane 1999HON
1,1,1-trifluoroethane 1999HON
____________________________________________________________________________________
Polysulfone
carbon dioxide 1998BOE
dinitrogen oxide 1998BOE
ethane 1986KA2
methane 1986KA2
methane 1998BOE
nitrogen 1986KA2
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Polytetrafluoroethylene
carbon dioxide 1991BRI
____________________________________________________________________________________
Poly(tetramethylsilhexylenesiloxane)
methane 1993SHA
propane 1993SHA
____________________________________________________________________________________
Poly(1-trimethyl-1-propyne)
carbon dioxide 1994POP
methane 1994POP
____________________________________________________________________________________
Polyurethane and precursors
____________________________________________________________________________________
Poly(vinyl acetate)
carbon dioxide 1988MAS
carbon dioxide 2003PAL
____________________________________________________________________________________
Poly(vinyl benzoate)
argon 1986KA1
nitrogen 1986KA1
____________________________________________________________________________________
carbon dioxide 1998WON
carbon dioxide 2001MUT
____________________________________________________________________________________
Poly(vinylidene fluoride)
carbon dioxide 2003SHE
____________________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
____________________________________________________________________________________
Polyxylylene
____________________________________________________________________________________
Styrene/butadiene copolymer
____________________________________________________________________________________
Styrene/methyl methacrylate copolymer
carbon dioxide 1990RA1
____________________________________________________________________________________
Tetrafluoroethylene/2,2-bistrifluoromethyl-
4,5-difluoro-1,3-dioxole copolymer
n-butane 1999BON
n-butane 2002DEA
carbon dioxide 1999BON
carbon dioxide 2002DEA
ethane 1999BON
ethane 2002DEA
helium 1999BON
methane 1999BON
methane 2002DEA
nitrogen 1999BON
nitrogen 2002DEA
oxygen 1999BON
oxygen 2002DEA
propane 1999BON
propane 2002DEA
tetrafluoroethane 1999BON
tetrafluoroethane 2002DEA
tetrafluoromethane 1999BON
tetrafluoromethane 2002DEA
____________________________________________________________________________________
Vinyl acetate/vinylidene cyanide copolymer
____________________________________________________________________________________
Vinyl acetate/1-vinyl-2-pyrrolidinone copolymer
____________________________________________________________________________________
_____________________________________________________________________________
2.3. Ternary and quaternary polymer solutions


Comments: The mass fractions of B/C/D belong to the feed liquid copolymer solution.
T/K = 323.15
wB/wC/wD = 0.04/0.40/0.56
P/bar 5.1 9.9 14.6 19.2 23.8
mA/(g/g feed liquid copolymer solution) 0.0160 0.0321 0.0502 0.0698 0.0915
wB/wC/wD = 0.16/0.35/0.49
P/bar 6.4 10.8 14.6 19.1 25.2
wB/wC/wD = 0.28/0.30/0.42
P/bar 5.7 9.4 16.0 20.6 23.3
T/K = 373.15
wB/wC/wD = 0.04/0.40/0.56
P/bar 6.1 10.7 15.4 20.5 23.7
wB/wC/wD = 0.16/0.35/0.49
P/bar 5.6 9.9 13.7 19.4 25.6
T/K = 423.15
wB/wC/wD = 0.04/0.40/0.56
P/bar 7.0 10.5 14.8 19.9 25.3
wB/wC/wD = 0.16/0.35/0.49
P/bar 6.8 10.7 15.4 20.0 23.9
_____________________________________________________________________________


T/K = 323.15
________________________________________________________________________________
liquid phase vapor phase
P/bar xA xB xC xD yA yC yD
________________________________________________________________________________
5.1 0.0526 0.0001 0.3995 0.5478 0.9625 0.0088 0.0287
9.9 0.1001 0.0001 0.3794 0.5204 0.9767 0.0057 0.0176
14.6 0.1481 0.0001 0.3592 0.4926 0.9860 0.0037 0.0103
19.2 0.1948 0.0001 0.3395 0.4656 0.9876 0.0030 0.0094
23.8 0.2406 0.0001 0.3202 0.4391 0.9893 0.0029 0.0078
6.4 0.0583 0.0005 0.3968 0.5444 0.9660 0.0093 0.0247
10.8 0.1057 0.0004 0.3768 0.5171 0.9852 0.0034 0.0114
14.6 0.1471 0.0004 0.3594 0.4931 0.9867 0.0033 0.0100
19.1 0.1894 0.0004 0.3416 0.4686 0.9900 0.0021 0.0079
25.2 0.2486 0.0004 0.3166 0.4344 0.9908 0.0024 0.0068
5.7 0.0494 0.0010 0.4003 0.5493 0.9622 0.0122 0.0256
9.4 0.0958 0.0010 0.3807 0.5225 0.9757 0.0072 0.0171
16.0 0.1479 0.0009 0.3588 0.4924 0.9855 0.0043 0.0102
20.6 0.1928 0.0008 0.3399 0.4665 0.9886 0.0032 0.0082
23.3 0.2339 0.0008 0.3227 0.4426 0.9902 0.0032 0.0066
________________________________________________________________________________
T/K = 373.15
________________________________________________________________________________
________________________________________________________________________________
6.1 0.0371 0.0001 0.4147 0.5481 0.8305 0.0681 0.1014
10.7 0.0719 0.0001 0.3997 0.5283 0.9012 0.0276 0.0712
15.4 0.1032 0.0001 0.3863 0.5104 0.9257 0.0208 0.0535
20.5 0.1385 0.0001 0.3710 0.4904 0.9411 0.0167 0.0422
23.7 0.1630 0.0001 0.3605 0.4764 0.9476 0.0153 0.0371
5.6 0.0337 0.0005 0.4090 0.5568 0.8305 0.0762 0.0933
9.9 0.0627 0.0005 0.3968 0.5400 0.8919 0.0614 0.0467
13.7 0.0904 0.0005 0.3850 0.5241 0.9210 0.0371 0.0419
19.4 0.1306 0.0004 0.3680 0.5010 0.9402 0.0258 0.0340
25.6 0.1734 0.0004 0.3499 0.4763 0.9500 0.0238 0.0262
________________________________________________________________________________
continued
_____________________________________________________________________________
continued
T/K = 423.15
________________________________________________________________________________
________________________________________________________________________________
7.0 0.0185 0.0001 0.4149 0.5665 0.4610 0.1940 0.3450
10.5 0.0393 0.0001 0.4061 0.5545 0.6322 0.1223 0.2455
14.8 0.0583 0.0001 0.3980 0.5436 0.7084 0.0942 0.1974
19.9 0.0906 0.0001 0.3844 0.5249 0.7833 0.0692 0.1475
25.3 0.1177 0.0001 0.3729 0.5093 0.8162 0.0469 0.1369
6.8 0.0181 0.0005 0.4140 0.5674 0.4725 0.1784 0.3491
10.7 0.0382 0.0005 0.4055 0.5558 0.6479 0.1113 0.2408
15.4 0.0632 0.0005 0.3950 0.5413 0.7411 0.0820 0.1769
20.0 0.0866 0.0005 0.3851 0.5278 0.7878 0.0655 0.1467
23.9 0.1102 0.0005 0.3752 0.5141 0.8170 0.0559 0.1271
________________________________________________________________________________

Solvent (C): n-hexane C6H14 110-54-3
Type of data: weight fraction-based partition coefficient at infinite dilution, K∞ = wCgas/wCliq

T/K = 323.15
P/MPa 0.6 1.2 1.8
K∞ 30.6 15.2 12.0
T/K = 343.15
P/MPa 0.6 1.2 1.8 2.4
K∞ 43.9 20.7 15.9 13.1
T/K = 363.15
P/MPa 0.6 1.2 1.8 2.4
K∞ 59.7 31.9 23.2 17.4
Comments: The weight fraction-based partition coefficients of n-hexane at infinite dilution are given
for the equilibrated system of C2H4 + polymer at binary system equilibrium temperature,
pressure, and concentration (please see Chapter 2.1. for the binary data).

continued
_____________________________________________________________________________
continued

T/K = 323.15
P/MPa 1.2 1.6 1.8
K∞ 12.4 9.4 8.6
T/K = 343.15
P/MPa 1.2 1.6 1.8 2.4
K∞ 21.2 15.7 14.1 11.2
T/K = 363.15
P/MPa 1.2 1.8 2.4
K∞ 38.2 20.4 14.7
Comments: The weight fraction-based partition coefficients of n-hexane at infinite dilution are given
for the equilibrated system of C3H6 + polymer at binary system equilibrium temperature,
Polymer (B): poly(butyl methacrylate) 2000BY1

Characterization: Aldrich Chem. Co., Inc., Milwaukee, WI
Solvent (C): butyl methacrylate C8H14O2 97-88-1

wA 0.400 wB 0.05 wC 0.550 were kept constant
T/K 339.05 323.95 312.95
P/bar 95 78 65

−1
Solvent (C): cyclohexane C6H12 110-82-7
Type of data: gas/vapor solubility

wA 0.081 0.081 0.081 0.081 0.081 0.081 0.081 0.081 0.081
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.869 0.869 0.869 0.869 0.869 0.869 0.869 0.869 0.869
T/K 353.15 363.15 373.15 383.15 393.15 403.15 413.15 423.15 433.15
P/MPa 2.6 2.9 3.4 3.6 3.7 4.4 4.5 4.9 5.2
continued
_____________________________________________________________________________
continued
wA 0.081 0.081 0.081 0.081 0.172 0.172 0.172 0.172 0.172
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.869 0.869 0.869 0.869 0.778 0.778 0.778 0.778 0.778
T/K 443.15 453.15 463.15 473.15 353.15 363.15 373.15 383.15 393.15
P/MPa 5.7 6.1 6.5 6.6 5.3 5.5 6.6 7.2 7.7
wA 0.172 0.172 0.240 0.240 0.240 0.240 0.240 0.300
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.778 0.778 0.710 0.710 0.710 0.710 0.710 0.650
T/K 403.15 413.15 353.15 363.15 373.15 383.15 393.15 353.15
P/MPa 8.1 8.5 6.5 6.9 7.7 8.5 9.1 7.6
Polymer (B): polybutadiene 1999INO

low cis-butadiene rubber
T/K = 318.2
ρ(CO2)/(g/cm3) 0.142 0.161 0.183 0.221 0.241 0.282 0.353
K∞ 0.301 0.304 0.322 0.390 0.456 0.548 0.967
T/K = 333.2
ρ(CO2)/(g/cm3) 0.125 0.140 0.162 0.184 0.204 0.303 0.351 0.396
K∞ 0.400 0.403 0.450 0.472 0.519 0.880 1.040 1.315
T/K = 358.2
ρ(CO2)/(g/cm3) 0.107 0.144 0.166 0.196 0.261
K∞ 0.714 0.719 0.823 0.877 1.013
Comments: The values of K∞ are given for the equilibrated system of CO2 + polymer at binary
system equilibrium temperature, density, pressure, and concentration.

−1
Type of data: gas/vapor solubility
wA 0.108 0.108 0.108 0.108 0.108 0.108 0.108 0.108 0.108
wB 0.059 0.059 0.059 0.059 0.059 0.059 0.059 0.059 0.059
wC 0.833 0.833 0.833 0.833 0.833 0.833 0.833 0.833 0.833
T/K 323.15 343.15 363.15 383.15 403.15 423.15 443.15 463.15 473.15
P/MPa 1.9 2.9 4.0 4.8 5.4 6.1 6.9 7.6 8.0
continued
_____________________________________________________________________________
continued
wA 0.186 0.186 0.186 0.186 0.186 0.186 0.186 0.186 0.278
wB 0.059 0.059 0.059 0.059 0.059 0.059 0.059 0.059 0.059
wC 0.755 0.755 0.755 0.755 0.755 0.755 0.755 0.755 0.663
T/K 323.15 343.15 363.15 383.15 403.15 423.15 443.15 453.15 323.15
P/MPa 2.8 3.7 4.4 6.3 7.9 9.2 10.6 11.0 4.9
wA 0.278 0.278 0.278 0.278 0.337 0.337 0.337 0.337
wB 0.059 0.059 0.059 0.059 0.059 0.059 0.059 0.059
wC 0.663 0.663 0.663 0.663 0.604 0.604 0.604 0.604
T/K 343.15 363.15 383.15 403.15 323.15 343.15 363.15 383.15
P/MPa 6.3 8.3 10.3 11.9 6.6 7.9 9.9 11.4

Polymer (C): polystyrene

wB/wC = 25/75 was kept constant
T/K = 373.15
P/MPa 2.127 4.107 6.051 8.095 11.887 15.965 20.110
wA 0.01356 0.02551 0.03706 0.04849 0.06670 0.08206 0.09478
T/K = 423.15
P/MPa 2.113 4.125 6.023 8.047 12.023 15.995 20.013
wA 0.00987 0.01913 0.02767 0.03641 0.05229 0.06532 0.07693
T/K = 473.15
P/MPa 2.219 4.113 6.111 8.088 12.092 16.065 20.060
wA 0.00680 0.01393 0.02133 0.02849 0.04239 0.05451 0.06582
wB/wC = 50/50 was kept constant
T/K = 373.15
P/MPa 2.147 4.087 6.085 8.108 12.059 16.012 19.789
wA 0.01687 0.02896 0.03977 0.05122 0.07187 0.09238 0.11116
T/K = 423.15
P/MPa 2.167 4.126 6.091 8.115 12.110 16.059 20.104
wA 0.01020 0.01950 0.02868 0.03794 0.05452 0.06850 0.08005
T/K = 473.15
P/MPa 2.148 4.148 6.127 8.110 12.117 16.144 20.046
wA 0.00830 0.01587 0.02313 0.03050 0.04453 0.05648 0.06640
_____________________________________________________________________________

Solvent (C): 1,1,1,3,3,3-hexadeutero-2-propanone C3D6O 666-52-4
Type of data: partition coefficient at equilibrium swelling, Kc = cC (in swollen PDMS)/cC (in CO2)
T/K = 314.65
The concentration of C3D6O in CO2 is 0.040 M.
P/bar 10.2 15.6 22.6 29.5 41.1 51.1 58.8 65.5 72.8
Kc 81.593 77.151 106.08 77.390 44.694 33.904 26.644 21.346 12.686
P/bar 79.7 85.2 91.5 96.5 105.0 111.2 173.8
Kc 8.975 4.778 3.652 2.990 2.099 1.963 0.207
P/bar 82.8 84.4 86.6 90.2 91.7 96.5 98.5 105.0 111.0
Kc 5.376 4.437 3.428 2.046 1.934 1.625 1.433 1.287 1.026
P/bar 80.1 83.0 84.1 86.1 89.4 91.7 96.0 103.4 116.0
Kc 6.903 3.764 2.996 2.647 1.793 1.603 1.542 1.533 0.789
P/bar 125.5 138.5 152.5 173.5
Kc 0.705 0.329 0.146 0.225


T/K = 314.65
The concentration of CH4O in CO2 is 0.0892 M.
P/bar 82.7 89.4 96.8 102.6 110.0 116.2 123.6 131.1 138.1
V/V0 1.638 1.605 1.636 1.651 1.707 1.739 1.760 1.822 1.857
P/bar 146.2 152.8 159.9 168.3 173.3
V/V0 1.912 1.941 1.952 1.992 2.021
P/bar 84.2 85.3 86.8 88.2 89.5 91.6 93.5 99.0 105.3
V/V0 1.717 1.687 1.652 1.627 1.610 1.611 1.620 1.643 1.674
P/bar 112.0 118.0 125.5 132.2 138.3 146.1 153.3 162.0 171.3
V/V0 1.713 1.749 1.792 1.815 1.853 1.883 1.935 1.970 1.998
continued
_____________________________________________________________________________
continued
P/bar 83.9 85.0 86.6 92.1 96.0 99.4 102.1 108.5 112.6
V/V0 1.879 1.817 1.800 1.767 1.760 1.776 1.784 1.809 1.848
P/bar 118.6 125.1 131.7 141.5 149.2 160.8 172.5
V/V0 1.877 1.935 1.976 2.042 2.089 2.176 2.236
The concentration of CH4O in CO2 is its concentration at saturated conditions.
P/bar 0.0 1.0 14.1 20.5 34.4 41.6 41.9 52.3 56.3
V/V0 1.028 1.057 1.104 1.111 1.172 1.231 1.248 1.368 1.408
P/bar 63.2 64.4 68.8 68.8 70.4 72.8 75.9 76.5 77.7
V/V0 1.554 1.596 1.717 1.664 1.671 1.901 1.978 2.128 2.204
P/bar 78.5 79.2 80.3 80.4 80.9 81.1 81.6 82.1 83.0
V/V0 2.214 2.256 2.211 2.268 2.275 2.193 2.228 2.165 1.988
Comments: The equilibrium swelling data in pure CO2 are given above in Chapter 2.1.

Solvent (C): methanol-d4 CD4O 811-98-3
T/K = 314.65
The concentration of CD4O in CO2 is 0.0480 M.
P/bar 52.1 58.8 63.5 67.5 69.9 71.8 74.4 78.5 81.0
Kc 13.186 15.680 9.806 8.356 8.104 6.526 5.763 4.891 4.292
P/bar 84.0 91.1 96.4 103.9 112.4 118.7 126.8 132.9 139.4
Kc 2.717 2.759 2.750 2.284 1.700 1.613 2.059 2.108 1.515
P/bar 147.4 154.3 175.4
Kc 1.361 1.823 1.416
P/bar 71.9 80.6 84.1 88.3 91.4 93.7 97.2 104.0 110.1
Kc 19.337 7.311 5.092 3.679 2.508 2.712 2.776 2.555 2.259
P/bar 120.0 126.8 132.9 138.6 146.7 151.5 159.2 166.4 174.4
Kc 1.883 1.983 2.015 1.525 1.473 1.477 1.605 1.448 1.421
P/bar 78.1 79.3 81.8 83.7 85.9 87.8 91.0 96.5 104.1
Kc 13.889 11.517 8.101 6.102 4.814 3.982 2.904 2.649 2.372
P/bar 111.0 120.8 125.1 132.6 141.5 147.3 153.8 165.6 176.1
Kc 2.404 1.815 1.737 1.979 1.932 1.532 1.698 1.340 1.253
_____________________________________________________________________________


T/K = 314.65
The concentration of C3H8O in CO2 is 0.160 M.
P/bar 81.2 82.7 87.0 96.3 110.2 123.7 143.0 157.2 173.1
V/V0 1.790 1.721 1.610 1.649 1.738 1.810 1.914 1.985 2.109
P/bar 81.1 87.1 95.0 100.9 107.2 117.8 132.3 153.9 171.7
V/V0 2.147 2.092 2.065 2.058 2.086 2.178 2.261 2.519 2.643
The concentration of C3H8O in CO2 is its concentration at saturated conditions.
P/bar 1.0 1.0 4.4 5.9 12.5 14.1 17.9 22.5 30.0
V/V0 1.910 1.967 2.240 2.187 2.832 2.567 3.268 3.439 3.887
P/bar 35.0 41.4 49.6 55.7 56.6 60.8 64.2 69.1 69.3
V/V0 4.184 5.440 6.362 6.749 7.201 7.515 8.417 8.561 7.354
P/bar 73.4 76.7 76.9 78.5 80.2
V/V0 5.149 3.108 2.917 2.296 2.234

Solvent (C): 2-propanol-d8 C3D8O 22739-76-0
T/K = 314.65
P/bar 80.6 82.4 84.0 86.7 91.4 97.7 104.6 111.7 124.5
Kc 17.349 9.142 6.062 4.155 2.578 2.085 1.998 2.001 1.715
P/bar 139.1 156.1 174.2
Kc 1.305 1.281 1.321
P/bar 8.5 15.5 21.9 29.0 38.4 44.5 51.1 58.6 64.4
Kc 35.033 57.339 78.837 87.014 105.269 105.004 90.562 63.572 40.862
continued
_____________________________________________________________________________
continued
P/bar 71.9 78.9 83.9 86.3 86.7 91.1 94.2 97.9 105.0
Kc 21.143 9.474 5.246 4.432 2.282 2.635 2.305 1.978 1.861
P/bar 112.7 115.8 119.0 127.8 128.0 142.5 143.9 160.2 174.2
Kc 1.606 1.981 1.387 1.870 2.058 2.059 1.346 1.454 1.355

Solvent (C): 2-propanone C3H6O 67-64-1

T/K = 314.65
P/bar 1.0 8.2 16.8 22.7 31.9 39.2 49.9 61.4 78.1
V/V0 1.507 1.583 1.538 1.445 1.343 1.346 1.357 1.383 1.521
P/bar 84.8 90.6 96.6 106.9 116.3 130.2 142.7 156.3 171.6
V/V0 1.580 1.586 1.624 1.686 1.749 1.832 1.904 1.969 2.048
P/bar 77.4 79.8 82.1 83.9 85.2 87.1 91.2 90.9 99.0
V/V0 1.969 1.830 1.661 1.623 1.597 1.584 1.588 1.584 1.606
P/bar 101.4 110.1 120.7 143.3 155.4 172.1
V/V0 1.630 1.671 1.721 1.858 1.932 2.038
P/bar 79.3 82.4 84.9 87.9 92.0 99.7 170.5
V/V0 2.199 2.210 2.228 2.216 2.206 2.263 2.512
The concentration of C3H6O in CO2 is its concentration at saturated conditions.
P/bar 1.0 1.0 6.5 13.2 20.7 26.9 29.4 34.7 36.6
V/V0 1.897 1.735 1.986 2.413 2.873 3.567 4.039 4.483 4.913
P/bar 41.4 44.1 50.2 51.0 55.2 60.2 66.4 70.0 72.3
V/V0 5.315 5.510 6.011 5.809 5.778 4.982 3.487 2.702 2.442
P/bar 72.8 73.9 74.8
V/V0 2.294 2.298 2.115
Polymer (B): poly(dimethylsiloxane) 1989SHI

Characterization: silicone rubber, cross-linked
continued
_____________________________________________________________________________
continued
Comments: The sorption of toluene is given in the equilibrated system of CO2 + PDMS at binary
system equilibrium temperature, pressure, and concentration (these binary data were
published in the original source in diagrams only).
T/K = 308.15
P/bar 40.5 60.8 60.8 60.8 70.9 70.9 81.0 81.0
mC/(g/g polymer) 0.06427 0.04390 0.04694 0.04245 0.03012 0.03159 0.00910 0.00871
P/bar 81.0 101.3 101.3 101.3 121.6 121.6 141.8 141.8
mC/(g/g polymer) 0.00762 0.00662 0.00583 0.00683 0.00680 0.00718 0.00715 0.00634
P/bar 141.8 202.6 253.3
mC/(g/g polymer) 0.00654 0.00490 0.00537
T/K = 343.15
P/bar 40.5 60.8 70.9 81.0 101.3 121.6 141.8 202.6
mC/(g/g polymer) 0.01535 0.01580 0.01534 0.01381 0.00706 0.00735 0.00601 0.00421

−1 −1 −1
Characterization: Mn/kg.mol = 8, Mw/kg.mol = 177, Mz/kg.mol = 1000,

wA 0.99218 0.99218 0.99218 0.99218 0.97801 0.97801 0.97801 0.93668 0.93668
wB 0.00557 0.00557 0.00557 0.00557 0.01970 0.01970 0.01970 0.06110 0.06110
wC 0.00225 0.00225 0.00225 0.00225 0.00229 0.00229 0.00229 0.00222 0.00222
T/K 396.71 398.67 400.68 402.67 396.64 398.65 400.63 401.78 403.80
P/bar 8.6 8.8 9.0 9.1 8.8 8.9 9.1 9.9 10.0
wA 0.93668 0.93668 0.91660 0.91660 0.91660 0.91660 0.87440 0.87440 0.87440
wB 0.06110 0.06110 0.08180 0.08180 0.08180 0.08180 0.12350 0.12350 0.12350
wC 0.00222 0.00222 0.00160 0.00160 0.00160 0.00160 0.00210 0.00210 0.00210
T/K 405.79 407.75 407.59 410.06 412.55 417.54 417.51 419.98 422.51
P/bar 10.2 10.4 9.9 10.2 10.5 11.1 11.4 11.7 12.1
wA 0.86616 0.86616 0.86616 0.86616 0.98317 0.98317 0.98317 0.97797 0.97797
wB 0.13160 0.13160 0.13160 0.13160 0.00443 0.00443 0.00443 0.00973 0.00973
wC 0.00224 0.00224 0.00224 0.00224 0.01240 0.01240 0.01240 0.01230 0.01230
T/K 417.54 419.98 422.51 424.98 384.67 385.69 386.65 384.28 386.24
P/bar 11.4 11.7 12.1 12.4 25.6 25.7 25.7 25.8 25.9
wA 0.97797 0.97637 0.97637 0.97637 0.96690 0.96690 0.96690 0.96600 0.96600
wB 0.00973 0.01093 0.01093 0.01093 0.02060 0.02060 0.02060 0.02130 0.02130
wC 0.01230 0.01270 0.01270 0.01270 0.01250 0.01250 0.01250 0.01270 0.01270
T/K 388.21 384.67 386.68 388.15 384.10 386.13 388.11 384.75 386.70
P/bar 26.0 26.4 26.4 26.5 26.4 26.4 26.5 26.7 26.8
continued
_____________________________________________________________________________
continued
wA 0.96600 0.92590 0.92590 0.92590 0.90640 0.90640 0.90640 0.90640 0.88390
wB 0.02130 0.06140 0.06140 0.06140 0.08120 0.08120 0.08120 0.08120 0.10390
wC 0.01270 0.01270 0.01270 0.01270 0.01240 0.01240 0.01240 0.01240 0.01220
T/K 388.63 394.62 396.19 397.32 394.62 396.19 400.03 401.97 400.03
P/bar 26.9 27.6 27.7 27.8 28.4 28.5 28.7 28.8 28.9
wA 0.88390 0.88390 0.92975 0.92975 0.92975 0.93350 0.93350 0.93350 0.98115
wB 0.10390 0.10390 0.05980 0.05980 0.05980 0.06040 0.06040 0.06040 0.00986
wC 0.01220 0.01220 0.01045 0.01045 0.01045 0.00610 0.00610 0.00610 0.00899
T/K 402.02 404.01 392.04 394.62 396.61 401.94 403.95 405.91 387.28
P/bar 29.0 29.1 24.2 24.3 24.4 16.6 16.7 16.8 20.0
wA 0.98115 0.98115 0.89158 0.89158 0.89158 0.88122 0.88122 0.88122
wB 0.00986 0.00986 0.10340 0.10340 0.10340 0.11110 0.11110 0.11110
wC 0.00899 0.00899 0.00502 0.00502 0.00502 0.00768 0.00768 0.00768
T/K 390.69 392.69 407.80 409.83 411.83 406.59 408.64 412.57
P/bar 20.2 20.4 16.0 16.1 16.2 20.8 20.9 21.2
Comments: High-pressure fluid phase demixing data for this system are given in Chapter 4.

Solvent (C): 1-octene C8H16 111-66-0
wA 0.7385 0.7385 0.5932 0.5932 0.3210 0.3210 0.3210 0.2156 0.2156
wB 0.1794 0.1794 0.1441 0.1441 0.1971 0.1971 0.1971 0.1324 0.1324
wC 0.0821 0.0821 0.2627 0.2627 0.4819 0.4819 0.4819 0.6520 0.6520
T/K 441.7 451.9 452.6 462.4 472.5 482.7 493.1 482.6 493.1
P/MPa 0.92 1.10 0.93 1.10 1.00 1.22 1.46 1.02 1.25
Comments: Liquid-liquid equilibrium and liquid-liquid-vapor equilibrium data for this system
are given in Chapter 3.

continued
_____________________________________________________________________________
continued

T/K = 298.15
P/MPa 0.385 0.730 1.327 1.753 2.077 2.533 3.030 3.587 4.053
xA 0.0798 0.1386 0.2100 0.2584 0.2856 0.3224 0.3650 0.4139 0.4600
T/K = 313.15
P/MPa 0.517 0.963 1.317 1.814 2.148 2.614 2.908 3.567 4.063
xA 0.0753 0.1374 0.1748 0.2211 0.2474 0.2772 0.2976 0.3366 0.3716
T/K = 333.15
P/MPa 0.547 0.922 1.327 1.854 2.290 2.553 2.928 3.526 4.083
xA 0.0558 0.0879 0.1215 0.1557 0.1814 0.1958 0.2188 0.2562 0.2996

see data set above

T/K = 298.15
P/MPa 1.023 1.510 1.672 2.057 2.361 2.634 3.009 3.405 3.769
xA 0.0022 0.0031 0.0035 0.0042 0.0049 0.0055 0.0062 0.0070 0.0078
T/K = 313.15
P/MPa 1.013 1.398 1.601 2.097 2.341 2.564 2.999 3.263 3.587
xA 0.0023 0.0032 0.0036 0.0048 0.0054 0.0058 0.0068 0.0074 0.0081
T/K = 333.15
P/MPa 1.023 1.419 1.702 1.935 2.280 2.564 2.979 3.212 3.840
xA 0.0027 0.0038 0.0045 0.0052 0.0060 0.0068 0.0079 0.0086 0.0102

see data set above
continued
_____________________________________________________________________________
continued

T/K = 298.15
P/MPa 1.034 1.439 1.925 2.239 2.564 2.817 3.081 3.405 3.699
xA 0.0031 0.0043 0.0058 0.0067 0.0077 0.0085 0.0092 0.0103 0.0111
T/K = 313.15
P/MPa 1.023 1.419 1.672 1.935 2.219 2.604 2.717 3.091 3.526
xA 0.0035 0.0049 0.0057 0.0067 0.0076 0.0089 0.0096 0.0106 0.0121
T/K = 333.15
P/MPa 1.013 1.409 1.804 1.996 2.169 2.462 2.888 3.101 3.506
xA 0.0037 0.0053 0.0067 0.0074 0.0080 0.0091 0.0106 0.0115 0.0129
Polymer (B): poly(ethyl methacrylate) 2000BY2

Solvent (C): ethyl methacrylate C6H10O2 97-63-2

wA 0.493 0.493 0.493 0.493 0.493
wB 0.05 0.05 0.05 0.05 0.05
wC 0.457 0.457 0.457 0.457 0.457
T/K 298.75 306.85 308.35 309.75 316.85
P/bar 44.3 52.7 54.5 56.2 62.4

Solvent (C): n-heptane C7H16 142-82-5

T/K 323.15 338.15 353.15 373.15 393.15
P/MPa 1.9 2.0 2.3 3.0 3.0
_____________________________________________________________________________
Polymer (B): polypropylene 2000OLI

Characterization: Mn/kg.mol−1 = 48.9, Mw/kg.mol−1 = 245, 92% isotactic,
Polibrasil Resinas S.A., Brazil
Solvent (A): n-butane C4H10 106-97-8

wA 0.8905 0.8905 0.8905 0.8905 0.8508 0.8508 0.8508 0.8508 0.8012
wB 0.0996 0.0996 0.0996 0.0996 0.0983 0.0983 0.0983 0.0983 0.0992
wC 0.0099 0.0099 0.0099 0.0099 0.0509 0.0509 0.0509 0.0509 0.0996
T/K 373.15 368.15 363.15 358.15 373.15 368.15 363.15 358.15 383.15
P/bar 18.1 15.9 14.5 12.9 17.5 15.8 14.3 12.6 19.9
wA 0.8012 0.8012 0.8012 0.8012 0.8012
wB 0.0992 0.0992 0.0992 0.0992 0.0992
wC 0.0996 0.0996 0.0996 0.0996 0.0996
T/K 373.15 368.15 363.15 358.15 353.15
P/bar 16.0 15.0 13.9 12.0 10.7
Comments: Liquid-liquid equilibrium data are given in Chapter 3.


wA 0.8910 0.8512 0.8512 0.8512 0.8022 0.8022 0.8022 0.8022
wB 0.0986 0.0974 0.0974 0.0974 0.0993 0.0993 0.0993 0.0993
wC 0.0104 0.0514 0.0514 0.0514 0.0985 0.0985 0.0985 0.0985
T/K 363.15 368.15 363.15 358.15 373.15 368.15 363.15 358.15
P/bar 17.0 17.5 15.3 12.9 18.3 16.2 14.0 11.8
Comments: Liquid-liquid equilibrium data are given in Chapter 3.

−1
Solvent (C): benzene C6H6 71-43-2

T/K = 313.2
P/MPa 2.04 3.01 4.33 4.95 5.93 6.87 7.85
K∞ 0.14 0.12 0.11 0.12 0.14 0.16 0.25
continued
_____________________________________________________________________________
continued
T/K = 333.2
P/MPa 1.88 2.72 3.81 4.81 5.01 6.16 7.18 7.95
K∞ 0.38 0.29 0.23 0.21 0.22 0.23 0.25 0.29
Comments: The weight fraction-based partition coefficients of benzene at infinite dilution are given
for the equilibrated system of CO2 + polymer at binary system equilibrium temperature,

−1

T/K = 313.2
P/MPa 1.97 2.86 2.92 2.95 3.91 4.68 5.79 6.85 7.73
K∞ 0.099 0.072 0.078 0.075 0.066 0.071 0.079 0.11 0.18
T/K = 333.2
P/MPa 2.03 3.04 3.98 4.02 5.00 5.98 6.96 6.97 7.97
K∞ 0.19 0.15 0.13 0.14 0.14 0.15 0.17 0.17 0.20
Comments: The weight fraction-based partition coefficients of toluene at infinite dilution are given
for the equilibrated system of CO2 + polymer at binary system equilibrium temperature,
Polymer (B): starch 1996SIN

Characterization: degermed yellow cornmeal, Lauhoff Grain Co., Danville, IL

T/K = 343.15
wA 0.0037 0.0086 0.0121 0.0162 0.0037 0.0080 0.0131 0.0171 0.0035
wB 0.6057 0.6014 0.6006 0.5982 0.6057 0.6031 0.6000 0.5975 0.6378
wC 0.3906 0.3900 0.3873 0.3856 0.3906 0.3889 0.3869 0.3854 0.3587
P/bar 26.39 58.41 92.11 118.31 25.41 58.76 92.82 117.58 22.92
wA 0.0074 0.0117 0.0152 0.0037 0.0080 0.0127 0.0171 0.0035 0.0075
wB 0.6353 0.6325 0.6303 0.6376 0.6349 0.6319 0.6291 0.6527 0.6501
wC 0.3573 0.3558 0.3545 0.3587 0.3571 0.3554 0.3538 0.3438 0.3424
P/bar 55.78 90.56 114.24 22.00 56.62 92.67 117.99 24.09 57.61
wA 0.0118 0.0157 0.0035 0.0076 0.0121 0.0167
wB 0.6473 0.6447 0.6527 0.6500 0.6471 0.6441
wC 0.3409 0.3396 0.3438 0.3424 0.3408 0.3392
P/bar 91.14 116.85 23.07 58.27 93.88 116.82
_____________________________________________________________________________
2.4. Table of ternary or quaternary systems where data were

published only in graphical form as phase diagrams or
related figures
____________________________________________________________________________________
Polymer (B) Second/third/fourth component Ref.
____________________________________________________________________________________
ethene and propene 1994YOO
____________________________________________________________________________________
carbon dioxide and polystyrene 1997KAT
____________________________________________________________________________________
Polycarbonate bisphenol chloral
carbon dioxide and poly(methyl methacrylate) 1990RA2
methane and poly(methyl methacrylate) 1990RA2
____________________________________________________________________________________
Poly(cyanopropylmethylsiloxane)
carbon dioxide and methanol 1999BRA
carbon dioxide and 2-propanol 1999BRA
____________________________________________________________________________________
Poly(2,6-dimethyl-1,4-phenylene oxide)
carbon dioxide and polystyrene 1982MOR
carbon dioxide and polystyrene 1996CON
____________________________________________________________________________________
carbon dioxide and methanol 1998VIN
carbon dioxide and methanol 1998WES
carbon dioxide and methanol 1999BRA
carbon dioxide and 2-propanol 1998VIN
carbon dioxide and 2-propanol 1999BRA
carbon dioxide and 2-propanone 1998VIN
carbon dioxide and 2-propanone 1998WES
carbon dioxide and toluene 1998WES
____________________________________________________________________________________
Polyethylene
ethene and 4-methyl-1-pentene 1992WOH
n-hexane and nitrogen 1990KEN
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
oxide)-b-poly(ethylene oxide)
triblock copolymer
carbon dioxide and p-xylene 2002ZHA
____________________________________________________________________________________
carbon dioxide and bisphenol chloral
polycarbonate 1990RA2
methane and bisphenol chloral polycarbonate 1990RA2
carbon dioxide and water 1997VIN
carbon dioxide and water 1998KAZ
____________________________________________________________________________________
Polypropylene
ethene and propene 1994HOR
____________________________________________________________________________________
Polystyrene
benzene and carbon dioxide 1989SAS
carbon dioxide and polycarbonate bisphenol-A 1997KAT
carbon dioxide and poly(2,6-dimethyl-1,4-
phenylene oxide) 1982MOR
carbon dioxide and poly(2,6-dimethyl-1,4-
phenylene oxide) 1996CON
carbon dioxide and poly(vinyl methyl ether) 1989HAC
carbon dioxide and poly(vinyl methyl ether) 1998MOK
carbon dioxide and pyrene 2004CAO
____________________________________________________________________________________
Poly(vinyl acetate)
benzene and carbon dioxide 1988MAS
benzene and carbon dioxide 1992HAT
carbon dioxide and toluene 1992HAT
____________________________________________________________________________________
carbon dioxide and polystyrene 1989HAC
carbon dioxide and polystyrene 1998MOK
____________________________________________________________________________________
_____________________________________________________________________________
2.5. References
1948NEW Newitt, D.M. and Weale, K.E., Solution and diffusion of gases in polystyrene at high
pressures, J. Chem. Soc. London, 1541, 1948.
1962LUN Lundberg, J.L., Wilk, M.B., and Huyett, M.J., Estimation of diffusivities and solubilities
from sorption studies, J. Polym. Sci., 57, 275, 1962.
1963LUN Lundberg, J.L., Wilk, M.B., and Huyett, M.J., Sorption studies using automation and
computation, Ind. Eng. Chem. Fundam., 2, 37, 1963.
1964VIE Vieth, W.R., Alcalay, H.H., and Frabetti, A.J., Solution of gases in oriented poly(ethylene
terephthalate), J. Appl. Polym. Sci., 8, 2125, 1964.
1969LUN Lundberg, J.L., Mooney, E.J., and Rogers, C.E., Diffusion and solubility of methane in
polyisobutylene, J. Polym. Sci.: Part A-2, 7, 947, 1969.
1973BRO Brockmeier, N.F., Carlson, R.E., and McCoy, R.W., Gas chromatographic determination of
thermodynamic properties of polymer solutions at high pressure, AIChE-J., 19, 1133, 1973.
1974DOS DosSantos, M.L., Correa, N.F., and Leitao, D.M., Interaction of polyethylene with
isobutane, isobutylene, 1-butene and normal butane, J. Coll. Interface Sci., 47, 621, 1974.
1975BON Bonner, D.C. and Cheng, Y., A new method for determination of equilibrium sorption of
gases by polymers at elevated temperatures and pressures, J. Polym. Sci.: Polym. Lett. Ed.,
13, 259, 1975.
1975HOR Horacek, H., Gleichgewichtsdrücke, Löslichkeit und Mischbarkeit des Systems Polyethylen
niedriger Dichte und Kohlenwasserstoffen bzw. halogenierten Kohlenwasserstoffen,
Makromol. Chem., Suppl., 1, 415, 1975.
1976KOR Koros, W.J., Paul, D.R., and Rocha, A.A., Carbon dioxide sorption and transport in
polycarbonate, J. Polym. Sci.: Polym. Phys. Ed., 14, 687, 1976.
1977BON Bonner, D.G., Solubility of supercritical gases in polymers, Polym. Eng. Sci., 17, 65, 1977.
1977CHE Cheng, Y.L. and Bonner, D.C., Solubility of ethylene in liquid, low-density polyethylene to
69 atmospheres, J. Polym. Sci.: Polym. Phys. Ed., 15, 593, 1977.
1978CHE Cheng, Y.L. and Bonner, D.C., Solubility of nitrogen and ethylene in molten, low-density
polyethylene to 69 atmospheres, J. Polym. Sci.: Polym. Phys. Ed., 16, 319, 1978.
1978STE Stern, S.A. and DeMeringo, A.H., Solubility of carbon dioxide in cellulose acetate at
elevated pressure, J. Polym. Sci.: Polym. Phys. Ed., 16, 735, 1978.
1981ALB Albihn, P. and Kubat, J., Phase equilibria in the two-phase system polystyrene-liquid
sulphur dioxide, Brit. Polym. J., 13, 137, 1981.
1981KOR Koros, W.J., Smith, G.N., and Stannett, V., High-pressure sorption of carbon dioxide in
solvent-cast poly(methyl methacrylate) and poly(ethyl methacrylate) films, J. Appl. Polym.
Sci., 26, 159, 1981.
1981PAR Parrish, WM.R., Solubility of isobutane in two high-density polyethylene polymer fluffs, J.
Appl. Polym. Sci., 26, 2279, 1981.
1982MOR Morel, G. and Paul, D.R., CO2 sorption and transport in miscible poly(phenylene oxide)/
polystyrene blends, J. Membrane Sci., 10, 273, 1982.
1982TOI Toit, K. and Paul, D.R., Effect of polystyrene molecular weight on the carbon dioxide
sorption isotherm, Macromolecules, 15, 1104, 1982.
1983MEY Meyer, J.A. and Blanks, R.F., Solubility of isobutane and propane in polyethylene at high
temperatures and low pressures, J. Appl. Polym. Sci., 28, 725, 1983.
1984FON Fonin, M.F., Saltanova, V.B., Anishchuk, V.V., Evdokimova, T.N., Shvyd'ko, T.I., and
Gordeev, V.K., Solubility of ethylene and its diffusion in freshly prepared high-pressure
polyethylene (Russ.), Plast.Massy, 7, 16, 1984.
1984KOB Kobyakov, V.M. and Zernov, V.S., Solubility of ethylene in polyethylene at high pressures
and temperatures (Russ.), in Sintez, Svoistva, Pererab. Poliolefinov, 1984, 60.
_____________________________________________________________________________
1985ROU Rousseaux, P., Richon, D., and Renon, H., Ethylene-polyethylene mixtures, saturated liquid
densities and bubble pressures up to 26.1 MPa and 493.1 K, J. Polym. Sci.: Polym. Chem.
Ed., 23, 1771 1985.
1986CAR Carfagna, C., Nicodemo, L., Nicolais, L., and Campanile, G., CO2 sorption in uniaxially
drawn atactic polystyrene, J.Polym.Sci.: Part B: Polym.Phys., 24, 1805, 1986.
1986FLE Fleming, G.K. and Koros, W.J., Dilation of polymers by sorption of carbon dioxide at
elevated pressures. 1. Silicone rubber and unconditioned polycarbonate, Macromolecules,
19, 2285, 1986.
1986GOR Gorski, R.A., Ramsey, R.B., and Dishart, K.T., Physical properties of blowing agent
polymer systems - I. Solubility of fluorocarbon blowing agents in thermoplastic resins, J.
Cell. Plast., 22, 21, 1986.
1986HIR Hirose, T., Mizoguchi, K., and Kamiya, Y., Dilation of polyethylene by sorption of carbon
dioxide, J. Polym. Sci.: Part B: Polym. Phys., 24, 2107, 1986.
1986KA1 Kamiya, Y., Mizoguchi, K., Naito, Y., and Hirose, T., Gas sorption in poly(vinyl benzoate),
J. Polym. Sci.: Part B: Polym. Phys., 24, 535, 1986.
1986KA2 Kamiya, Y., Hirose, T., Mizoguchi, K., and Naito, Y., Gravimetric study of high-pressure
sorption of gases in polymers, J. Polym. Sci.: Part B: Polym. Phys., 24, 1525, 1986.
1986KOL Kolmacka, J. and Smilek, P., Methods and problems in the measurement of gas solubility in
polymer melts II. (Czech.), Plasty Kaucuk, 23, 13, 1986.
1986SHA Shah, V.M., Hardy, B.J., and Stern, S.A., Solubility of carbon dioxide, methane, and
propane in silicone polymers. Effect of polymer side chains, J. Polym. Sci.: Part B: Polym.
Phys., 24, 2033, 1986.
1987CAS Castro, E.F., Gonzo, E.E., and Gottifredi, J.C., Thermodynamics of the absorption of
hydrocarbon vapors in polyethylene films, J. Membrane Sci., 31, 235, 1987.
1987GOR Goradia, U.B. and Spencer, H.G., Sorption of propane in poly(ethyl methacrylate) near Tg,
J. Appl. Polym. Sci., 33, 1525, 1987.
1987HEU Heuer, T., Untersuchungen zur Löslichkeit von Gasen in Polymerschmelzen, Dissertation,
TH Leuna-Merseburg, 1987.
1987KOB Kobyakov, V.M., Kogan, V.B., and Zernov, V.S., Metod otsenki dannykh o parozhidkost-
nom ravnovesii pri vysokikh davleniyakh, Zh. Prikl. Khim., 60, 81, 1987.
1987KOL Kolmacka, J. and Smilek, P., Solubility of gases in a polyethylene melt and its importance
for the manufacture of plastic foams by a physical method, Plasty Kaucuk, 24, 65, 1987.
1987SAD Sada, E., Kumazawa, H., Yakushij, H., Bamba, Y., Sakata, K., and Wang, S.-T., Sorption
and diffusion of gases in glassy polymers, Ind. Eng. Chem. Res., 26, 433, 1987.
1987WIS Wissinger, R.G. and Paulaitis, M.E., Swelling and sorption in polymer-CO2 mixtures at
elevated pressures, J. Polym. Sci.: Part B: Polym. Phys., 25, 2497, 1987.
1988HAC Hachisuka, H., Tsujita, Y., Takizawa, A., and Kinoshita, T., CO2 sorption properties and
enthalpy relaxation in alternating copoly(vinylidene cyanide-vinyl acetate)s, Polymer, 29,
2050, 1988.
1988MAS Masuoka, H., Takishima, S., and Wang, N.-H., Supercritical fluid extraction of high-boiling
materials from polymers, Rep. Asahi Glass Found. Ind. Technol., 52, 275, 1988.
1988SAD Sada, E., Kumazawa, H., and Xu, P., Sorption and diffusion of carbon dioxide in polyimide
films, J. Appl. Polym. Sci., 35, 1497, 1988.
1988THU Thuy, L.P. and Springer, J., Carbon dioxide sorption in poly(butylene terephthalate),
Colloid Polym. Sci., 266, 614, 1988.
1989BER Berens, A.R. and Huvard, G.S., Interaction of polymers with near-critical carbon dioxide,
ACS Symp. Ser., 406, 207, 1989.
1989CHI Chiou, J.S. and Paul, D.R., Gas sorption and permeation in poly(ethyl methacrylate), J.
Membrane Sci., 45, 167, 1989.
1989HAC Hachisuka, H., Sato, T., Tsujita, Y., Takizawa, A., and Kinoshita, T., CO2 gas sorption
properties in single-phase and phase-separated polystyrene/poly(vinyl methyl ether) blends,
Polym. J., 21, 417, 1989.
_____________________________________________________________________________
1989KA1 Kamiya, Y., Mizoguchi, K., Hirose, T., and Naito, Y., Sorption and dilation in poly(ethyl
methacrylate)-carbon dioxide system, J. Polym. Sci.: Part B: Polym. Phys., 27, 879, 1989.
1989KA2 Kamiya, Y., Naito, Y., and Mizoguchi, K., Sorption and partial molar volume of gases in
polybutadiene, J. Polym. Sci.: Part B: Polym. Phys., 27, 2243, 1989.
1989SAS Sasaki, M., Takishima, S., and Masuoka, H., Supercritical carbon dioxide extraction of
benzene in poly(vinyl acetate) and polystyrene, Sekiyu Gakkaishi, 32, 67, 1989.
1989SHI Shim, J.-J. and Johnston, K.P., Adjustable solute distribution between polymers and super-
critical fluids, AIChE-J., 35, 1097, 1989.
1990HAT Hattori, K., Wang, N., Takishima, S., Masioka, H., Chromatographic measurement of
vapor-liquid equilibrium ratios of organic solvents in supercritical CO2 + poly(vinyl acetate)
system, in Solvent Extraction 1990, Ed. T. Sekine, Elsevier Sci. Publ., 1990, 1671.
1990KEN Kennis, H.A.J., Loos, Th.W. de, DeSwaan Arons, J., Van der Haegen, R., and Kleintjens,
L.A., The influence of nitrogen on the liquid-liquid phase behaviour of the system n-
hexane-polyethylene: experimental results and predictions with the mean-field lattice-gas
model, (experimental data by Th.W. de Loos), Chem. Eng. Sci., 45, 1875, 1990.
1990KUM Kumar, V. and Suh, N.P., A process for making microcellular thermoplastic parts, Polym.
Eng. Sci., 30, 1323, 1990.
1990RA1 Raymond, P.C. and Paul, D.R., Sorption and transport of pure gases in random styrene/
methyl methacrylate copolymers, J. Polym. Sci.: Part B: Polym. Phys., 28, 2079, 1990.
1990RA2 Raymond, P.C. and Paul, D.R., Sorption and transport of pure CO2 and CH4 in miscible
bisphenol chloral polycarbonate/poly(methyl methacrylate) blends, J. Polym. Sci.: Part B:
Polym. Phys., 28, 2103, 1990.
benzene in poly(vinyl acetate) and polystyrene (Part 2), Sekiyu Gakkaishi, 33, 304, 1990.
1990TAK Takashima, S., Nakamura, K., Sasaki, M., and Masuoka, H., Dilatation and solubility in
carbon dioxide + poly(vinyl acetate) system at high pressures, Sekiyu Gakkaishi, 33, 332,
1990.
1990WAN Wang, N.-H., Takishima, S., and Masuoka, H., Solubility measurements of gas in polymer
by piezoelectric-quartz sorption method at high pressures and its correlation, Kogaku
Ronbunshu, 16, 931, 1990.
1991BRI Briscoe, B.J. and Zakaria, S., Interaction of CO2 gas with silicone elastomer at high ambient
pressures, J. Polym. Sci.: Part B: Polym. Phys., 29, 989, 1991.
1991FIN Finck, U., Phasengleichgewichte in Monomer + Copolymer - Systemen, Diploma Paper,
1991LAM Lambert, S.M. and Paulaitis, M.E., Crystallization of poly(ethylene terephthalate) induced
by carbon dioxide sorption at elevated pressures, J. Supercrit. Fluids, 4, 15, 1991.
1991POP Pope, D.S., Sanchez, I.C., Koros, W.J., and Fleming, G.K., Statistical thermodynamic
interpretation of sorption/dilation behavior of gases in silicone rubber, Macromolecules, 24,
1779, 1991.
critical test of the influence of molecular gas data, Angew. Makromol. Chem., 185-186, 265,
1991.
1991WAN Wang, N.H., Hattori, K., Takashima, S., and Masuoka, H., Measurement and prediction of
vapor-liquid equilibrium solutes at infinite dilution in carbon dioxide + poly(vinyl acetate)
system at high pressures, Kagaku Kogaku Ronbunshu, 17, 1138, 1991.
1991WI1 Wissinger, R.G. and Paulaitis, M.E., Glass transitions in polymer/CO2 mixtures at elevated
pressures, J. Polym. Sci.: Part B: Polym. Phys., 29, 631, 1991.
1991WI2 Wissinger, R.G. and Paulaitis, M.E., Molecular thermodynamic model for sorption and
swelling in glassy polymer-CO2 systems at elevated pressures, Ind. Eng. Chem. Res., 29,
842, 1991.
1992CO1 Condo, P.D. and Johnston, K.P., Retrograde vitrification of polymers with compressed fluid
diluents: experimental confirmation, Macromolecules, 25, 6730, 1992.
_____________________________________________________________________________
1992CO2 Condo, P.D., Sanchez, I.C., Panayiotou, C.G., and Johnston, K.P., Glass transition behavior
including retrograde vitrification of polymers with compressed fluid diluents,
1992HAT Hattori, K., Wang, N., Takishima, S., and Masuoka, H., Chromatographic measurement of
vapor-liquid equilibrium ratios of organic solvents in supercritical CO2 + poly(vinyl acetate)
system, in Solvent Extraction 1990, Ed. T. Sekine, Elsevier Sci. Publ., 1992, 1671.
1992WAN Wang, N.-H., Ishida, S., Takishima, S., and Masuoka, H., Sorption measurement of nitrogen
in polystyrene at high pressure and its correlation by a modified dual-sorption model,
Kagaku Kogaku Ronbunshu, 18, 226, 1992.
1992WOH Wohlfarth, C., Finck, U., Schultz, R., and Heuer, T., Investigation of phase equilibria in
mixtures composed of ethene, 1-butene, 4-methyl-1-pentene and a polyethylene wax,
Angew. Makromol. Chem., 198, 91, 1992.
1993CON Conforti, R.M. and Barbari, T.A., A thermodynamic analysis of gas sorption-desorption
hystereses in glassy polymers, Macromolecules, 26, 5209, 1993.
1993SHA Shah, V.M., Hardy, B.J., and Stern, S.A., Solubility of carbon dioxide, methane, and
propane in silicone polymers. Effect of polymer backbone chains, J. Polym. Sci.: Part B:
Polym. Phys., 31, 313, 1993.
1993WAN Wang, N. and Masuoka, H., Measurement and prediction of vapor-liquid equilibrium ratios
for solutes at infinite dilution in CO2 + polyvinylacetate system at high pressures, Dalian
Ligong Daxue Xuebao, 33, Suppl. 2, 175, 1993.
1994CON Condo, P.D. and Johnston, K.P., In situ measurement of the glass transition temperature of
polymers with compressed fluids, J. Polym. Sci.: Part B: Polym. Phys., 32, 523, 1994.
1994GAR Garg, A., Gulari, E., and Manke, C.W., Thermodynamics of polymer melts swollen with
supercritical gases, Macromolecules, 27, 5643, 1994.
1994GOE Goel, S.K. and Beckman, E.J., Generation of microcellular polymeric foams using
supercritical carbon dioxide. I. Effect of pressure and temperature on nucleation, Polym.
Eng. Sci., 34, 1137, 1994.
1994HAN Handa, Y.P., Lampron, S., and O'Neill, M.L., On the plasticization of poly(2,6-dimethyl
phenylene oxide) by CO2, J. Polym. Sci.: Part B: Polym. Phys., 32, 2549, 1994.
1994HOR Horacek, H., Extrapolation of solubility data of monomeric, oligomeric and polymeric
hydrocarbons, Macromol. Chem. Phys., 195, 3381, 1994.
1994KAM Kamiya, Y., Naito, Y., and Borubon, D., Sorption and partial molar volumes of gases in
poly(ethylene-co-vinyl acetate), J. Polym. Sci.: Part B: Polym. Phys., 32, 281, 1994.
1994POP Pope, D.S., Koros, W.J., and Hopfenberg, H.B., Sorption and dilation of poly(1-trimethyl-
1-propyne) by carbon dioxide and methane, Macromolecules, 27, 5839, 1994.
1994WAN Wang, N.-H., Takishima, S., and Masuoka, H., Measurement and correlation of solubility of
a high pressure gas in a polymer by piezoelectric quartz sorption: CO2 + PVAc and CO2 +
PBMA systems, Int. Chem. Eng., 34, 255, 1994.
1994YOO Yoon, J.S., Chung, C.Y., and Lee, I.H., Solubility and diffusion coefficient of gaseous
ethylene and α-olefin in ethylene/α-olefin random copolymers, Eur. Polym. J., 30, 1209,
1994.
1995GAI Gainar, I. and Anitescu, G., The solubility of CO2, N2, and H2 in a mixture of dimethyl ether
polyethylene glycols at high pressures, Fluid Phase Equil., 109, 281, 1995.
1995LEE Lee, J.G. and Flumerfelt, W., Nitrogen solubilities in low-density polyethylene at high
temperatures and high pressures, J. Appl. Polym. Sci., 58, 2213, 1995.
1995LOO Loos, Th.W. de, Poot, W., and Lichtenthaler, R.N., The influence of branching on high-
pressure vapor-liquid equilibria in systems of ethylene and polyethylene (experimental data
by Th.W. de Loos), J. Supercrit. Fluids, 8, 282, 1995.
1996CON Conforti, R.M., Barbari, T.A., and Pozo de Fernandes, M.E., Enthalpy of mixing for a
glassy polymer blend from CO2 sorption and dilation measurements, Macromolecules, 29,
6629, 1996.
_____________________________________________________________________________
1996HAN Handa, Y.P., Kruus, P., and O'Neill, M., High-pressure calorimetric study of plastification
of poly(methyl methacrylate) by methane, ethylene, and carbon dioxide, J. Polym. Sci.: Part
B: Polym. Phys., 34, 2635, 1996.
1996SAT Sato, Y., Yurugi, M., Fujiwara, K., Takishima, S., and Masuoka, H., Solubilities of carbon
dioxide and nitrogen in polystyrene under high temperature and pressure, Fluid Phase
Equil., 125, 129, 1996.
1996SH1 Shieh, Y.-T., Su, J.-H., Manivannan, G., Lee, P.H.C., Sawan, S.P., and Spall, W.D., Inter-
action of supercritical carbon dioxide with polymers. I. Crystalline polymers, J. Appl.
Polym. Sci., 59, 695, 1996.
1996SH2 Shieh, Y.-T., Su, J.-H., Manivannan, G., Lee, P.H.C., Sawan, S.P., and Spall, W.D. Inter-
action of supercritical carbon dioxide with polymers. II. Amorphous polymers, J. Appl.
Polym. Sci., 59, 707, 1996.
1996SIN Singh, B., Rizvi, S.S.H., and Harriott, P., Measurement of diffusivity and solubility of
carbon dioxide in gelatinized starch at elevated pressures, Ind. Eng. Chem. Res., 35, 4457,
1996.
1996WAN Wang, J.-S., Naito, Y., and Kamiya, Y., Effect of the penetrant-induced isothermal glass
transition on sorption, dilation, and diffusion behavior of polybenzylmethacrylate/CO2, J.
Polym. Sci.: Part B: Polym. Phys., 34, 2027, 1996.
1997END Enders, S. and Loos, Th.W. de, Pressure dependence of the phase behaviour of polystyrene
in methylcyclohexane (experimental data by S. Enders), Fluid Phase Equil., 139, 335,
1997.
1997KAT Kato, S., Tsujita, Y., Yoshimizu, H., Kinoshita, T., and Higgins, J.S., Characterization and
CO2 sorption behaviour of polystyrene/polycarbonate blend system, Polymer, 38, 2807,
1997.
1997KRY Krykin, M.A., Bondar, V.I., Kukharsky, Yu.M., and Tarasov, A.V., Gas sorption and
diffusion processes in polymer matrices at high pressures, J. Polym. Sci.: Part B: Polym.
Phys., 35, 1339, 1997.
1997SUR Surana, R.K., Danner, R.P., DeHaan, A.B., and Beckers, N., New technique to measure
high-pressure and high-temperature polymer-solvent vapor-liquid equilibrium, Fluid Phase
Equil., 139, 361, 1997.
1997VIN Vincent, M.F., Kazarian, S.G., and Eckert, C.A., Tunable diffusion of D2O in CO2-swollen
poly(methyl methacrylate) films, AIChE-J., 43, 1838, 1997.
1997WEI Weidner, E., Wiesmet, V., Knez, Z., and Skerget, M., Phase equilibrium (solid-liquid-gas)
in polyethyleneglycol-carbon dioxide systems, J. Supercrit. Fluids, 10, 139, 1997.
1997ZHA Zhang, Y., Gangwani, K.K., and Lemert, R.M., Sorption and swelling of block copolymers
in the presence of supercritical carbon dioxide, J. Supercrit. Fluids, 11, 115, 1997.
1998AUB Aubert, J.H., Solubility of carbon dioxide in polymers by the quartz crystal microbalance
technique, J. Supercrit. Fluids, 11, 163, 1998.
1998BOE Böhning, M. and Springer, J., Sorptive dilation and relaxational processes in glassy
polymer/gas systems - I. Poly(sulfone) and poly(ether sulfone), Polymer, 39, 5183, 1998.
1998EDW Edwards, R.R., Tao, Y., Xu, S., Wells, P.S., Yun, K.S., and Parcher, J.F., Chromatographic
investigation of CO2-polymer interactions at near-critical conditions, J. Phys. Chem. B, 102,
1287, 1998.
1998HER Herraiz, J., Shen, S., and Coronas, A., Vapor-liquid equilibria for methanol + poly(ethylene
glycol)-250 dimethyl ether, J. Chem. Eng. Data, 43, 191, 1998.
1998HON Hong, S.-U. and Pretel, E.J., Predicting the solubility of 1,1-difluoroethane in polystyrene
using the perturbed soft chain theory, Polym. Int., 45, 55, 1998.
1998KAM Kamiya, Y., Miziguchi, K., Terada, K., Fujiwara, Y., and Wang, J.-S., CO2 sorption and
dilation of poly(methyl methacrylate), Macromolecules, 31, 472, 1998.
1998KAZ Kazarian, S.G., Vincent, M.F., and Eckert, C.A., Partitioning of solutes and cosolvents
between supercritical CO2 and polymer phases, J. Supercrit. Fluids, 13, 107, 1998.
_____________________________________________________________________________
1998MOK Mokdad, A., Dubault, A., and Monnerie, L., Sorption and diffusion of carbon dioxide in
single-phase polystyrene/poly(vinyl methyl ether) blends, J. Polym. Sci.: Part B: Polym.
Phys., 34, 2723, 1998.
1998VIN Vincent, M.F., Kazarian, S.G., West, B.L., Berkner, J.A., Bright, F.V., Liotta, C.L., and
Eckert, C.A., Cosolvent effects of modified supercritical carbon dioxide on cross-linked
poly(dimethylsiloxane), J. Phys. Chem. B, 102, 2176, 1998.
1998WES West, B.L., Bush, D., Brantley, N.H., Vincent, M.F., Kazarian, S.G., and Eckert, C.A.,
Modeling the effects of cosolvent-modified supercritical fluids on polymers with a lattice
fluid equation of state, Ind. Eng. Chem. Res., 37, 3305, 1998.
1998WON Wong, B., Zhang, Z., and Handa, Y.P., High-precision gravimetric technique for
determining the solubility and diffusivity of gases in polymers, J. Polym. Sci.: Part B:
Polym. Phys., 36, 2025, 1998.
1998ZHA Zhang, Z. and Handa, Y.P., An in situ study of plasticization of polymers by high-pressure
gases, J. Polym. Sci.: Part B: Polym. Phys., 36, 977, 1998.
1999ANG Angelis, M.G.de, Merkel, T.C., Bondar, V.I., Freeman, B.D., Doghieri, F., and Sartim G.C.,
Hydrocarbon and fluorocarbon solubility and dilation in poly(dimethylsiloxane):
comparison of experimental data with predictions of the Sanchez-Lacombe equation of
state, J. Polym. Sci.: Part B: Polym. Phys., 37, 3011, 1999.
1999BON Bondar, V.I., Freeman, B.D., and Yampolskii, Yu.P., Sorption of gases and vapors in an
amorphous glassy perfluorodioxole copolymer, Macromolecules, 32, 6163, 1999.
1999BRA Brantley, N.H., Bush, D., Kazarian, S.G., and Eckert, C.A., Spectroscopic measurement of
solute and cosolvent partitioning between supercritical CO2 and polymers, J. Phys. Chem.
B, 103, 10007, 1999.
1999INO Inomata, H., Honma, Y., Imahori, M., and Arai, K., Fundamental study of de-solventing
polymer solutions with supercritical CO2, Fluid Phase Equil., 158-160, 857, 1999.
1999KIK Kikic, I., Lora, M., Cortesi, A., and Sist, P., Sorption of CO2 in biocompatible polymers:
experimental data and qualitative interpretation, Fluid Phase Equil., 158-160, 913, 1999.
1999HON Hong, S.U., Albouy, A., and Duda, J.L., Measurement and prediction of blowing agent
solubility in polystyrene at supercritical conditions, Cell. Polym., 18, 301, 1999.
1999KEL Keller, J.U., Rave, H., and Staudt, R., Measurement of gas absorption in a swelling
polymeric material by a combined gravimetric-dynamic method, Macromol. Chem. Phys.,
200, 2269, 1999.
1999ROY Royer, J.R., DeSimone, J.M., and Khan, S.A., Carbon dioxide-induced swelling of
poly(dimethylsiloxane), Macromolecules, 32, 8965, 1999.
1999SAT Sato, Y., Fujiwara, K., Takikawa, T., Takishima, S., and Masuoka, H., Solubilities and
diffusion coefficients of carbon dioxide and nitrogen in polypropylene, high-density
polyethylene, and polystyrene under high pressures and temperatures, Fluid Phase Equil.,
162, 261, 1999.
1999WEB Webb, K.F. and Teja, A.S., Solubility and diffusion of carbon dioxide in polymers, Fluid
Phase Equil., 158-160, 1029, 1999.
2000BRA Brantley, N.H., Kazarian, S.G., and Eckert, C.A., In situ FTIR measurement of carbon
dioxide sorption into poly(ethylene terephthalate) at elevated pressures, J. Appl. Polym.
Sci., 77, 764, 2000.
2000BY1 Byun, H.-S. and McHugh, M.A., Impact of ”free” monomer concentration on the phase
behavior of supercritical carbon dioxide-polymer mixtures, Ind. Eng. Chem. Res., 39, 4658,
2000.
2000BY2 Byun, H.-S. and Choi, T.-H., Effect of monomer concentration on the phase behavior of
supercritical carbon dioxide-poly(ethyl methacrylate) mixture, J. Korean Ind. Eng. Chem.,
11, 396, 2000.
2000FEN Feng, W., Wen, H., Xu, Z., and Wang, W., Comparison of perturbed hard-sphere-chain
theory with statistical associating fluid theory for square-well fluids, Ind. Eng. Chem. Res.,
39, 2559, 2000.
_____________________________________________________________________________
2000HIL Hilic, S., Padua, A.A.H., and Grolier, J.-P.E., Simultaneous measurement of the solubility
of gases in polymers and of the associated volume change, Rev. Sci. Instrum., 71, 4236,
2000.
2000OLI Oliveira, J.V., Dariva, C., and Pinto, J.C., High-pressure phase equilibria for polypropylene-
hydrocarbon systems, Ind. Eng. Chem. Res., 39, 4627, 2000.
2000SA1 Sato, Y., Takikawa, T., Sorakubo, A., Takishima, S., Masuoka, H., and Imaizumi, M.,
Solubility and diffusion coefficient of carbon dioxide in biodegradable polymers, Ind. Eng.
Chem. Res., 39, 4813, 2000.
2000SA2 Sato, Y., Tsuboi, A., Sorakubo, A., Takishima, S., Masuoka, H., and Ishikawa, T., Vapor-
liquid equilibrium ratios for hexane at infinite dilution in ethylene + impact polypropylene
copolymer and propylene + impact polypropylene copolymer, Fluid Phase Equil., 170, 49,
2000.
2000SA3 Sato, Y., Iketani, T., Takishima, S., and Masuoka, H., Solubility of hydrofluorocarbon
(HFC-134a, HFC-152a) and hydrochlorofluorocarbon (HCFC-142b) blowing agents in
polystyrene, Polym. Eng. Sci., 40, 1369, 2000.
2000WIE Wiesmet, V., Weidner, E., Behme, S., Sadowski, G., and Arlt, W., Measurement and
modelling of high-pressure phase equilibria in the systems polyethyleneglycol (PEG)-
propane, PEG-nitrogen and PEG-carbon dioxide, J. Supercrit. Fluids, 17, 1, 2000.
2001HAT Hata, K., The sorption properties of supercritical carbon dioxide in poly(ethylene glycol)
and poly(ethylene oxide) with high-pressure thermogravimetry-differential thermal analysis
(Jap.), Kobunshi Ronbunshu, 58, 714, 2001.
2001HIL Hilic, S., Boyer, S.A.E., Padua, A.A.H., and Grolier, J.-P.E., Simultaneous measurement of
the solubility of nitrogen and carbon dioxide in polystyrene and of the associated polymer
swelling, J. Polym. Sci.: Part B: Polym. Phys., 39, 2063, 2001.
2001MAR Martinache, J.D., Royer, J.R., Siripurapu, S., Henon, F.E., Genzer, J., Khan, S.A., and
Carbonell, R.G., Processing of polyamide-11 with supercritical carbon dioxide, Ind. Eng.
Chem. Res., 40, 5570, 2001.
2001MCC McCabe, C., Galindo, A., Garcia-Lisbona, M.N., and Jackson, G., Examining the absorp-
tion (vapor-liquid equilibria) of short-chain hydrocarbons in low-density polyethylene with
SAFT-VR approach, Ind. Eng. Chem. Res., 40, 3835, 2001.
2001MOO Moore, S.J. and Wanke, S.E., Solubility of ethylene, 1-butene and 1-hexene in
polyethylenes (experimental data by S.E. Wanke), Chem. Eng. Sci., 56, 4121, 2001.
2001MUT Muth, O., Hirth, Th., and Vogel, O., Investigation of sorption and diffusion of supercritical
carbon dioxide into poly(vinyl chloride), J. Supercrit. Fluids, 19, 299, 2001.
2001NAG Naguib, H. E., Richards, E. V., Pop-Iliev, R., Xu, X., and Park, C. B., Measurement of the
swelling of polypropylene melts with dissolved butane, Annual Technical Conference -
Society of Plastics Engineers, 59th ,Vol. 2, 1537, 2001.
2001SA1 Sato, Y., Yurugi, M., Yamabiki, T., Takishima, S., and Masuoka, H., Solubility of
propylene in semicrystalline polypropylene, J. Appl. Polym. Sci., 79, 1134, 2001.
2001SA2 Sato, Y., Takikawa, T., Takishima, S., and Masuoka, H., Solubilities and diffusion
coefficients of carbon dioxide in poly(vinyl acetate) and polystyrene, J. Supercrit. Fluids,
19, 187, 2001.
2001TOR Tork, T., Measurement and calculation of phase equilibria in polyolefin/solvent systems
(Ger.), Dissertation, TU Berlin, 2001.
2001SIR Sirard, S.M., Green, P.F., and Johnston, K.P., Spectroscopic ellipsometry investigation of
the swelling of poly(dimethylsiloxane) thin films with high pressure carbon dioxide, J.
Phys. Chem. B, 105, 766, 2001.
2001TSU Tsuboi, A., Kolar, P., Ishikawa, T., Kamiya, Y., and Masuoka, H., Sorption and partial
molar volumes of C2 and C3 hydrocarbons in polypropylene copolymers, J. Polym. Sci.:
Part B: Polym. Phys., 39, 1255, 2001.
_____________________________________________________________________________
2002AR1 Areerat, S., Hayata, Y., Katsumoto, R., Kegaswaa, T., Engami, H., and Ohshima, M.,
Solubility of carbon dioxide in polyethylene/titanium dioxide composite under high
pressure and temperature, J. Appl. Polym. Sci., 86, 282, 2002.
2002AR2 Areerat, S., Nagata, T., and Ohshima, M., Measurement and prediction of LDPE/CO2
solution viscosity, Polym. Eng. Sci., 42, 2234, 2002.
2002DEA DeAngelis, M.G., Merkel, T.C., Bondar, V.I., Freeman, B.D., Doghieri, F., and Sarti, G.C.,
Gas sorption and dilation in poly(2,2-bistrifluoromethyl-4,5-difluoro-1,3-dioxole-co-tetra-
fluoroethylene): comparison of experimental data with predictions of the nonequilibrium
lattice fluid model, Macromolecules, 35, 1276, 2002.
2002FLI Flichy, N.M.B., Kazarian, S.G., Lawrence, C.J., and Briscoe, B.J., An ATR-IR study of
poly(dimethylsiloxane) under high-pressure carbon dioxide: simultaneous measurement of
sorption and swelling, J. Phys. Chem. B, 106, 754, 2002.
2002JOU Joung, S.N., Park, J.-U., Kim, S.Y., and Yoo, K.-P., High-pressure phase behavior of
polymer-solvent systems with addition of supercritical CO2 at temperatures from 323.15 K
to 503.15 K, J. Chem. Eng. Data, 47, 270, 2002.
2002LIU Liu, J., Han, B., Wang, Z., Zhang, J., Li, G., and Yang, G., Solubility of Ls-36 and Ls-45
surfactants in supercritical CO2 and loading water in the CO2/water/surfactant system,
Langmuir, 18, 3086, 2002.
2002NIK Nikitin, L.N., Said-Galiyev, E.E., Vinokur, R.A., Khokhlov, A.R., Gallayamov, M.O., and
Schaumburg, K., Poly(methyl methacrylate) and poly(butyl methacrylate) swelling in
supercritical carbon dioxide, Macromolecules, 35, 934, 2002.
2002PFO Pfohl, O., Riebesell, C., and Dohrn, R., Measurement and calculation of phase equilibria in
the system n-pentane + poly(dimethylsiloxane) at 308.15-423.15 K, Fluid Phase Equil.,
202, 289, 2002.
2002SAT Sato, Y., Takikawa, T., Yamane, M., Takishima, S., and Masuoka, H., Solubility of carbon
dioxide in PPO and PPO/PS blends, Fluid Phase Equil., 194-197, 847, 2002.
2002SHI Shieh, Y.-T. and Lin, Y.-G., Equilibrium solubility of CO2 in rubbery EVA over a wide
pressure range: effects of carbonyl group content and crystallinity, Polymer, 43, 1849,
2002.
2002SIR Sirard, S.M., Ziegler, K.J., Sanchez, I.C., Green, P.F., and Johnston, K.P., Anomalous
properties of poly(methyl methacrylate) thin films in supercritical carbon dioxide,
2002ZHA Zhang, R., Liu, J., He, J., Han, B., Zhang, X, Liu, Z., Jiang, T., and Hu, G., Compressed
CO2-assisted formation of reverse micelles of PEO-PPO-PEO copolymer, Macromolecules,
35, 7869, 2002.
2003ALE Alessi, P., Cortesi, A., Kikic, I., and Vecchione, F., Plasticization of polymers with
supercritical carbon dioxide: experimental determination of glass-transition temperatures, J.
Appl. Polym. Sci., 88, 2189, 2003.
2003COT Cotugno, S., DiMaio, E., Ciardiello, C., Iannace, S., Mensitieri, G., and Nicolais, L., Sorp-
tion thermodynamics and mutual diffusivity of carbon dioxide in molten polycaprolactone,
Ind. Eng. Chem. Res., 42, 4398, 2003.
2003DIM Dimos, V., Anastasiadis, A., Chasiotis, A., and Kiparissides, C., An experimental and
theoretical investigation of solubility and diffusion of ethylene in semi-crystalline PE at
elevated pressures and temperatures, J. Appl. Polym. Sci., 87, 953, 2003.
2003KIK Kikic, I., Vecchione, F., Alessi, P., Cortesi, A., Eva, F., and Elvassore, N., Polymer
plasticization using supercritical carbon dioxide: experiment and modeling, Ind. Eng. Chem.
Res., 42, 3022, 2003.
2003KOG Koga, T., Seo, Y.-S., Shin, K., Zhang, Y., Rafailovich, M.H., Sokolov, J.C., Chu, B., and
Satija, S.K., The role of elasticity in the anomalous swelling of polymer thin films in density
fluctuating supercritical fluids, Macromolecules, 36, 5236, 2003.
_____________________________________________________________________________
2003LEE Lee, L.-S., Shih, R.-F., Ou, H.-J., and Lee, T.-S., Solubility of ethylene in mixtures of
toluene, norbornene, and cyclic olefin copolymer at various temperatures and pressures,
Ind. Eng. Chem. Res., 42, 6977, 2003.
2003NIK Nikitin, L.N., Gallayamov, M.O., Vinokur, R.A., Nikolaec, A.Yu., Said-Galiyev, E.E., and
Khokhlov, A.R., Swelling and impregnation of polystyrene using supercritical carbon
dioxide, J. Supercrit. Fluids, 26, 263, 2003.
2003PAL Palamara, J.E., Davis, P.K., Suriyapraphadilok, U., Danner, R.P., Duda, J.L., Kitzhoffer,
R.J., and Zielinski, J.M., A static sorption technique for vapor solubility measurements, Ind.
Eng. Chem. Res., 42, 1557, 2003.
2003RAM Ramachandrarao, V.S., Vogt, B.D., Gupta, R.R., and Watkins, J.J., Effect of carbon dioxide
sorption on the phase behavior of weakly interacting polymer mixtures: solvent-induced
segregation in deuterated polybutadiene/polyisoprene blends, J. Polym. Sci.: Part B: Polym.
Phys., 41, 3114, 2003.
2003SHE Shenoy, S.L., Fujiwara, T., and Wynne, K.J., Quantifying plasticization and melting
behavior of poly(vinylidene fluoride) in supercritical CO2 utilizing a linear variable
differential transformer, Macromolecules, 36, 3380, 2003.
2003SHI Shieh, Y.-T. and Liu, K.-H., The effect of carbonyl group on sorption of CO2 in glassy
polymers, J. Supercrit. Fluids, 25, 261, 2003.
2003WAN Wang, S., Peng, C., Li, K., Wang, J., Shi, J., and Liu, H., Measurement of solubilities of
CO2 in polymers by quartz crystal micobalance (Chin.), J. Chem. Ind. Eng. (China), 54,
141, 2003.
2003WI1 Wind, J.D., Sirard, S.M., Paul, D.R., Green, P.F., Johnston, K.P., and Koros, W.J.: Carbon
dioxide-induced plasticization of polyimide membranes: pseudo-equilibrium relationships
of diffusion, sorption, and swelling, Macromolecules, 36, 6433, 2003.
2003WI2 Wind, J.D., Sirard, S.M., Paul, D.R., Green, P.F., Johnston, K.P., and Koros, W.J.:
Relaxation dynamics of CO2 diffusion, sorption, and polymer swelling for plasticized
polyimide membranes, Macromolecules, 36, 6442, 2003.
2003XUQ Xu, Q., Chang, Y., He, J., Han, B., and Liu, Y., Supercritical CO2-assisted synthesis of
poly(acrylic acid)/nylon-6 and polystyrene/nylon-6 blends, Polymer, 44, 5449, 2003.
2004CAO Cao, T., Johnston, K.P., and Webber, S.E., CO2-Enhanced transport of small molecules in
thin films: a fluorescence study, Macromolecules, 37, 1897, 2004.
2004CHE Chen, X., Yasuda, K., Sato, Y., Takishima, S., and Masuoka, H., Measurement and
correlation of phase equilibria of ethylene + n-hexane + metallocene polyethylene at
temperatures between 373 and 473 K and at pressures up to 20 MPa, Fluid Phase Equil.,
215, 105, 2004.
2004DAV Davis, P.K., Lundy, G.D., Palamara, J.E., Duda, J.L., and Danner, R.P., New pressure-
decay techniques to study gas sorption and diffusion in polymers at elevated pressures, Ind.
Eng. Chem. Res., 43, 1537, 2004.
2004SOL Solms, N. von, Nielsen, J.K., Hassager, O., Rubin, A., Dandekar, A.Y., Andersen, S.I., and
Stenby, E.H., Direct measurement of gas solubilities in polymers with a high-pressure
microbalance, J. Appl. Polym. Sci., 91, 1476, 2004.
2004TAN Tang, M., Du, T.-B., and Chen, Y.-P., Sorption and diffusion of supercritical carbon
dioxide in polycarbonate, J. Supercrit. Fluids, 28, 207, 2004.
2004WEI Weidner, E. and Wiesmet, V., Phase equilibrium (solid-liquid-gas) in binary systems of
poly(ethylene glycol)s, poly(ethylene glycol) dimethyl ether with carbon dioxide, propane,
and nitrogen, in Thermodynamic Properties of Complex Fluid Mixtures, Wiley-VCH,
Deutsche Forschungsgemeinschaft, Ed. G. Maurer, 2004, 511.
3. LIQUID-LIQUID EQUILIBRIUM (LLE) DATA OF POLYMER
SOLUTIONS AT ELEVATED PRESSURES
Polymer (B): ethylene/vinyl acetate copolymer 1999BEY

Characterization: Mn/kg.mol−1 = 74, Mw/kg.mol−1 = 285, 70.0 wt% vinyl acetate,

wB 0.06 0.06 0.06 0.06 0.06 0.06
T/K 462.55 480.05 494.45 507.05 518.35 530.35
P/bar 34.6 60.7 80.9 97.4 113.3 125.3
Polymer (B): ethylene/vinyl acetate copolymer 1999BEY

Solvent (A): cyclopentene C5H8 142-29-0

wB 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06
T/K 475.75 475.95 485.25 486.35 496.75 497.95 505.65 507.15
P/bar 37.3 37.6 51.9 53.4 68.4 70.1 80.7 83.2

amido-D-glucitol copolymer 2002RE1
Characterization: Mn/kg.mol−1 = 28.6, Mw/kg.mol−1 = 56, 13.3 mol% glucitol,

wB 0.0102 0.0174 0.0233 0.0263 0.0397 0.0550 0.0102 0.0102 0.0102
T/K 413.2 384.8 368.5 358.1 353.0 366.0 428.6 450.3 465.0
P/bar 1.00 1.00 1.00 1.00 1.00 1.00 2.90 3.87 4.48
wB 0.0174 0.0174 0.0233 0.0233 0.0233 0.0233 0.0233 0.0397 0.0397
T/K 401.6 432.5 391.3 395.0 419.0 433.5 453.0 377.8 400.0
P/bar 2.27 3.87 2.10 2.27 3.58 5.71 8.57 2.57 3.65
wB 0.0550 0.0550 0.0550 0.0550 0.0550 0.0550 0.0550 0.0550
T/K 373.0 388.5 392.2 403.8 411.5 421.6 440.2 451.6
P/bar 1.62 2.26 2.45 2.90 3.58 4.70 7.43 8.84
_____________________________________________________________________________

Characterization: Mn/kg.mol−1 = 51.6, Mw/kg.mol−1 = 110, 13.7 mol% glucitol,

wB 0.01001 0.03914 0.0400 0.08810 0.0070 0.0070 0.0070 0.0070 0.0070
T/K 321.1 315.6 313.7 315.1 320.9 321.8 322.7 323.4 323.8
P/bar 1.0 1.0 1.0 1.0 20.0 100.0 200.0 300.0 500.0
wB 0.0070 0.0230 0.0230 0.0230 0.0230 0.0230 0.0230
T/K 324.0 317.6 319.0 320.3 320.7 321.9 322.4
P/bar 600.0 20.0 200.0 300.0 400.0 600.0 700.0

Characterization: Mn/kg.mol−1 = 145, Mw/kg.mol−1 = 432, 14.0 mol% glucitol,

wB 0.0050 0.0100 0.0305 0.0432 0.0530 0.0983 0.1103 0.1294 0.0038
T/K 313.1 311.3 310.1 309.8 309.3 308.6 308.0 307.3 311.7
P/bar 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 3.5
wB 0.0038 0.0038 0.0038 0.0038 0.0038 0.0038 0.0038 0.0038 0.0432
T/K 312.0 312.4 313.3 313.6 313.7 314.3 314.3 314.0 310.0
P/bar 62.0 110.0 200.0 300.0 400.0 500.0 600.0 700.0 10.0
wB 0.0432 0.0432 0.0432 0.0432 0.0432 0.0432 0.0432 0.0432 0.0432
T/K 310.1 310.3 310.5 310.8 311.1 311.4 311.8 311.8 312.0
P/bar 40.0 70.0 100.0 150.0 200.0 250.0 300.0 350.0 400.0
wB 0.0432 0.0432 0.0432 0.0432
T/K 312.1 312.3 312.3 312.0
P/bar 450.0 550.0 600.0 700.0

Characterization: Mn/kg.mol−1 = 0.34, surfactant C7E5, Bachem, purity > 98 wt%
Solvent (A): n-dodecane C12H26 112-40-3

wB 0.0499 0.0499 0.0499 0.0499 0.0499 0.0499 0.0499 0.0857 0.0857
T/K 273.71 275.64 277.35 279.18 281.00 282.71 284.51 277.92 279.31
P/MPa 9.80 24.00 36.80 51.00 65.20 79.60 95.00 13.20 23.40
continued
_____________________________________________________________________________
continued
wB 0.0857 0.0857 0.0857 0.0857 0.0857 0.0999 0.0999 0.0999 0.0999
T/K 280.42 281.97 283.65 285.78 287.59 280.05 282.03 284.17 286.20
P/MPa 31.20 43.40 55.45 69.05 85.25 14.65 28.35 43.95 58.75
wB 0.0999 0.0999 0.1680 0.1680 0.1680 0.1680 0.1680 0.1680 0.1680
T/K 288.20 290.08 279.57 281.63 283.57 285.66 287.58 289.57 291.52
P/MPa 73.45 88.05 7.95 22.95 37.35 52.95 67.55 82.85 98.35
wB 0.2037 0.2037 0.2037 0.2037 0.2037 0.2037 0.2037 0.3010 0.3010
T/K 279.68 281.66 283.54 285.57 287.55 289.51 291.48 279.45 281.56
P/MPa 8.22 22.45 36.35 51.45 66.35 81.55 97.05 11.95 27.45
wB 0.3010 0.3010 0.3010 0.3010 0.4013 0.4013 0.4013 0.4013 0.4013
T/K 283.48 285.51 287.51 289.47 277.39 279.19 281.06 283.75 285.38
P/MPa 41.75 57.05 72.55 88.75 7.55 21.55 35.75 55.55 68.25
wB 0.4013 0.4013 0.4681 0.4681 0.4681 0.4681 0.4681 0.4681 0.6025
T/K 287.14 289.05 276.54 278.43 280.29 282.47 285.76 288.09 273.38
P/MPa 82.25 97.45 8.45 22.35 36.55 53.10 78.45 97.05 6.15
wB 0.6025 0.6025 0.6025 0.6025 0.6025 0.6025
T/K 274.50 276.36 278.23 280.03 281.50 283.66
P/MPa 14.35 29.15 43.45 58.25 70.65 88.95

Characterization: Mn/kg.mol−1 = 0.34, surfactant C7E5, Bachem, purity > 98 wt%

wB 0.0100 0.0100 0.0100 0.0100 0.0100 0.0302 0.0302 0.0302 0.0302
T/K 341.74 342.82 343.92 345.93 348.12 341.34 342.28 343.02 345.04
P/MPa 6.35 15.34 25.65 46.20 71.60 8.35 15.45 21.45 39.35
wB 0.0302 0.0302 0.0302 0.0799 0.0799 0.0799 0.0799 0.0799 0.0799
T/K 346.98 347.88 349.98 339.94 340.96 341.91 343.15 344.14 345.06
P/MPa 59.25 70.15 96.15 1.88 9.85 17.55 28.65 38.15 47.45
wB 0.0799 0.0799 0.0987 0.0987 0.0987 0.0987 0.0987 0.0987 0.0987
T/K 347.03 348.93 340.88 341.93 342.97 345.08 346.89 347.77 348.75
P/MPa 70.25 95.95 7.95 16.55 25.75 46.15 66.75 77.65 91.15
wB 0.1595 0.1595 0.1595 0.1595 0.1595 0.1595 0.1595 0.1862 0.1862
T/K 340.81 341.84 342.85 344.87 346.94 348.05 349.40 340.56 342.65
P/MPa 6.65 15.05 23.85 43.15 66.15 80.05 99.15 2.83 19.65
wB 0.1862 0.1862 0.1862 0.2488 0.2488 0.2488 0.2488 0.2488 0.2488
T/K 344.78 346.67 348.65 340.79 341.91 342.89 344.06 345.84 347.81
P/MPa 39.45 59.75 84.75 1.03 9.75 17.95 28.55 46.25 68.65
wB 0.2488 0.2488 0.3489 0.3489 0.3489 0.3489 0.3489 0.3489 0.3489
T/K 348.80 349.79 343.87 345.05 345.92 347.86 349.80 350.75 351.88
P/MPa 81.45 95.35 10.55 20.65 28.55 47.95 70.55 83.05 99.35
continued
_____________________________________________________________________________
continued
wB 0.4006 0.4006 0.4006 0.4006 0.4006 0.4006 0.4006 0.5029 0.5029
T/K 345.04 346.19 347.36 347.88 350.71 351.73 353.05 349.77 350.70
P/MPa 5.95 15.45 25.35 30.05 58.45 70.35 87.45 7.15 14.45
wB 0.5029 0.5029 0.5029 0.5029 0.5029 0.5029
T/K 351.74 352.61 354.53 356.43 357.44 358.37
P/MPa 23.15 30.85 49.35 69.55 81.55 93.15
Polymer (B): poly(butyl methacrylate) 1984SAN, 1986SAN

Röhm GmbH, Darmstadt, Germany

T/K 315.35 314.15 313.15 312.15 311.15 310.15
P/bar 1 105 198 400 625 1054
Polymer (B): poly(dimethylsiloxane) 1972ZE1

Characterization: Mη /kg.mol−1 = 626, Dow-Corning

T/K = 392.95 wB = 0.0369 (dT/dP)P=1/K.bar−1 = +0.92

Characterization: Mη /kg.mol−1 = 1.2, 10 cSt viscosity, Dow-Corning
Solvent (A): ethane C2H6 74-84-0

T/K = 280.65 wB = 0.366 (dT/dP)P=1/K.bar−1 = +0.92


T/K = 273.15 wB = 0.262 (dT/dP)P=1/K.bar−1 = +0.90
_____________________________________________________________________________


T/K = 272.15 wB = 0.0364 (dT/dP)P=1/K.bar−1 = +0.89


T/K = 259.65 wB = 0.0651 (dT/dP)P=1/K.bar−1 = +0.85


T/K = 340.15 wB = 0.0400 (dT/dP)P=1/K.bar−1 = +0.92


T/K = 337.75 wB = 0.0402 (dT/dP)P=1/K.bar−1 = +0.91
Polymer (B): polyethylene 2000BEH


wB 0.0766 0.0766 0.0766 0.0766 0.0766 0.1083 0.1083 0.1083
T/K 514.49 517.75 521.00 522.25 526.45 515.38 520.75 526.19
P/bar 26.4 32.9 39.7 41.8 48.6 25.60 30.43 38.43
_____________________________________________________________________________
Polymer (B): polyethylene 2002HOR


T/K 554.06 560.69 564.14 570.03 574.22 578.33 584.85 589.48 592.73
P/bar 62 68 73 78 82 86 91 95 98
T/K 598.74 603.65 610.30 614.57 619.14 628.86
P/bar 103 107 112 115 118 124
Polymer (B): polyethylene 1999BEY

Characterization: Mn/kg.mol−1 = 20.1, Mw/kg.mol−1 = 106

wB 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06
T/K 482.95 483.35 492.45 492.95 501.65 502.55 513.65 526.05 528.75
P/bar 47.4 48.5 61.7 62.3 74.5 75.4 90.4 106.4 110.4


wB 0.06 0.06 0.06 0.06 0.06 0.06 0.06
T/K 482.85 483.95 488.55 489.15 498.05 498.75 510.35
P/bar 39.4 41.0 47.8 48.6 62.3 63.1 79.6

Characterization: Mw/kg.mol−1 = 125, Aldrich Chem. Co., Inc., Milwaukee, WI

T/K 463.15 473.15 483.15 493.15 503.15
P/MPa 2.0 3.2 4.6 5.7 7.1
Comments: Vapor-liquid equilibrium data for this system are given in Chapter 2.
_____________________________________________________________________________
Polymer (B): polyethylene 2004SCH

Characterization: Mn/kg.mol−1 = 6.28, Mw/kg.mol−1 = 6.5, linear, completely
hydrogenated polybutadiene, Polymer Source, Inc., Dorval, Quebec

wB 0.018 0.018 0.018 0.018 0.018 0.018 0.0355 0.0355 0.0355
T/K 470.15 479.15 488.15 498.15 505.15 515.15 464.15 473.65 480.15
P/bar 30 41 48 54 60 69 19 31 38
wB 0.0355 0.0355 0.0355 0.0355 0.051 0.051 0.051 0.051 0.0564
T/K 488.15 497.15 507.15 519.15 472.15 489.15 499.15 508.15 482.15
P/bar 49 58 67 76 28 45 55 66 68
wB 0.0564 0.0564 0.0564 0.0564 0.065 0.065 0.083 0.083 0.083
T/K 492.15 502.15 514.15 522.15 487.15 496.15 479.15 488.15 497.15
P/bar 75 81 87 97 35 44 28 37 48
wB 0.083 0.083 0.085 0.085 0.085 0.085 0.085 0.085 0.090
T/K 507.65 516.15 466.15 474.15 483.15 492.15 500.15 510.15 494.15
P/bar 56 63 34 43 52 57 63 72 67
wB 0.090 0.090 0.090 0.103 0.103 0.103 0.103 0.155 0.155
T/K 504.15 514.15 524.15 489.15 496.15 506.15 515.15 502.15 509.15
P/bar 78 88 100 45 58 66 75 43 45
wB 0.155 0.279 0.279 0.279
T/K 521.15 518.15 527.65 536.65
P/bar 57 38 50 54
Type of data: critical points

ϕB, crit 0.138 0.138 0.138
T/K 451 463 476
P/bar 20 40 60


wB 0.0053 0.0053 0.0053 0.0053 0.0053 0.0055 0.0055 0.0055 0.0055
T/K 412.50 419.93 422.43 427.40 434.77 412.60 415.07 417.59 420.03
P/bar 16.3 29.0 32.2 40.2 51.0 23.1 27.1 31.1 34.6
wB 0.0055 0.0055 0.0055 0.0095 0.0095 0.0095 0.0095 0.0095 0.0095
T/K 422.50 427.49 432.47 411.76 414.28 416.83 419.29 421.80 421.78
P/bar 38.1 45.6 52.6 18.2 21.2 26.1 30.8 33.1 33.7
continued
_____________________________________________________________________________
continued
wB 0.0095 0.0095 0.0095 0.0199 0.0199 0.0199 0.0199 0.0199 0.0199
T/K 426.80 429.78 436.70 412.52 417.54 422.51 424.93 427.46 432.36
P/bar 40.8 45.1 55.2 15.2 23.4 30.9 35.0 38.3 46.0
wB 0.0199 0.0199 0.0298 0.0298 0.0298 0.0298 0.0298 0.0298 0.0298
T/K 437.33 442.29 412.49 417.46 419.93 422.45 424.93 427.41 429.88
P/bar 52.7 59.8 11.3 19.3 23.4 27.2 31.2 35.2 38.6
wB 0.0298 0.0298 0.0298 0.0423 0.0423 0.0423 0.0423 0.0423 0.0423
T/K 432.39 437.39 442.36 412.52 417.51 419.98 422.48 424.95 427.46
P/bar 42.6 49.8 57.2 7.6 16.1 19.5 23.7 27.8 32.1
wB 0.0423 0.0423 0.0423 0.0423 0.0498 0.0498 0.0498 0.0498 0.0498
T/K 429.91 432.44 434.90 437.39 417.54 419.95 422.51 425.01 427.48
P/bar 35.2 38.9 42.7 46.3 13.8 17.3 21.8 25.6 29.2
wB 0.0498 0.0612 0.0612 0.0612 0.0612 0.0612 0.0612 0.0612 0.0612
T/K 432.44 417.45 419.93 422.43 424.90 427.40 427.38 429.86 432.36
P/bar 36.8 10.4 14.5 18.4 22.2 26.2 26.4 30.1 34.0
wB 0.0612 0.0612 0.0666 0.0666 0.0666 0.0666 0.0666 0.0666 0.0666
T/K 437.33 439.82 421.63 423.11 424.64 426.59 428.09 429.54 431.55
P/bar 41.0 44.6 14.6 17.0 19.2 22.1 24.4 26.5 29.8
wB 0.0666 0.0666 0.0666 0.0820 0.0820 0.0820 0.0820 0.0820 0.0954
T/K 436.51 439.47 441.43 421.75 423.72 425.69 427.67 429.62 422.52
P/bar 37.1 41.4 44.3 11.3 14.2 17.2 20.4 23.2 9.8
wB 0.0954 0.0954 0.0954 0.0954 0.0954 0.0954 0.0954 0.0954 0.0954
T/K 424.82 427.30 429.78 432.29 433.79 434.77 437.25 439.82 442.31
P/bar 13.3 17.3 21.1 24.9 27.3 28.7 32.4 36.3 39.9
wB 0.0954 0.0954 0.0954 0.1313 0.1313 0.1313 0.1313 0.1313 0.1313
T/K 444.80 447.29 452.26 429.15 432.45 434.11 437.41 439.03 446.55
P/bar 43.5 47.0 54.3 10.3 15.5 18.2 23.1 25.4 36.6
wB 0.1313 0.1313
T/K 451.46 457.15
P/bar 43.7 52.0

wB 0.0055 0.0053 0.0095 0.0199 0.0298 0.0423 0.0498 0.0612 0.0666
T/K 401.45 405.75 404.35 407.05 409.55 411.85 413.75 415.55 417.35
P/bar 4.8 5.5 5.3 5.8 6.3 6.8 7.1 7.4 7.7
wB 0.0820 0.0954 0.1313
T/K 419.85 421.55 428.15
P/bar 8.0 8.2 8.5
_____________________________________________________________________________

Characterization: Mn/kg.mol−1 = 14.4, Mw/kg.mol−1 = 15.5, completely hydrogenated

wB 0.0322 0.0322 0.0322 0.0824 0.0824 0.0824 0.0906 0.0906 0.0906
T/K 453.17 463.11 473.15 453.07 463.11 473.12 453.11 463.17 473.09
P/MPa 1.7 3.0 4.3 2.1 3.4 4.8 2.0 3.4 4.7
wB 0.0984 0.0984 0.0984 0.1187 0.1187 0.1187 0.1379 0.1379 0.1379
T/K 453.18 463.15 473.22 453.21 463.10 473.18 453.17 463.15 473.20
P/MPa 2.0 3.3 4.7 1.9 3.2 4.5 1.8 3.2 4.5
wB 0.0906 0.0906 0.0906
T/K 453.13 463.14 473.12
P/MPa 1.5 1.8 2.0
VLLE VLLE VLLE

HDPE, metallocene product, BASF AG, Germany

wB 0.0497 0.0497 0.0497 0.0497 0.0497 0.0497 0.0497 0.0497 0.0497
T/K 430.52 438.64 446.86 455.16 463.47 471.86 479.83 488.05 496.17
P/bar 15.5 28.4 40.5 52.3 63.9 74.1 83.8 93.9 102.4
wB 0.0497 0.1037 0.1037 0.1037 0.1037 0.1037 0.1037 0.1037 0.1037
T/K 503.21 430.94 437.29 445.42 453.63 462.15 470.24 478.48 486.85
P/bar 110.0 10.1 20.0 31.0 42.1 53.9 64.9 75.3 84.9
wB 0.1037 0.1037 0.1508 0.1508 0.1508 0.1508 0.1508 0.1508 0.1508
T/K 495.09 503.07 434.00 439.84 446.61 446.86 454.32 461.36 469.38
P/bar 94.6 103.1 9.5 16.9 26.6 27.0 37.3 46.7 55.5
wB 0.1508 0.1508 0.1508 0.1508 0.1508
T/K 475.84 482.86 490.05 497.37 503.34
P/bar 62.3 73.6 81.8 90.1 96.9

HDPE, BASF AG, Germany

continued
_____________________________________________________________________________
continued
wB 0.0488 0.0488 0.0488 0.0488 0.0488 0.0488 0.0488 0.0488 0.0488
T/K 436.15 440.77 446.20 452.04 456.57 461.96 467.33 472.64 478.75
P/bar 42.3 47.1 54.2 61.2 66.8 74.5 81.4 88.4 96.4
wB 0.0488 0.0488 0.0488 0.0488 0.1097 0.1097 0.1097 0.1097 0.1097
T/K 484.21 487.39 495.09 504.53 423.75 430.13 435.31 441.82 448.99
P/bar 103.0 107.1 114.3 126.2 21.6 29.9 35.1 43.8 51.7
wB 0.1097 0.1097 0.1097 0.1097 0.1097 0.1097 0.1097 0.1097 0.1097
T/K 455.25 462.02 462.15 469.19 476.63 483.67 490.59 496.95 503.85
P/bar 59.3 67.2 67.4 75.5 83.7 94.4 94.4 105.7 113.5

HDPE, BASF AG, Germany

wB 0.0477 0.0477 0.0477 0.0477 0.0477 0.0477 0.0477 0.0477 0.0477
T/K 423.48 429.84 436.07 443.68 451.38 459.90 467.99 475.57 483.40
P/bar 25.6 34.1 43.3 52.4 62.5 74.2 84.9 94.8 104.2
wB 0.0477 0.0477 0.0477 0.0994 0.0994 0.0994 0.0994 0.0994 0.0994
T/K 491.11 498.15 504.39 422.96 431.18 438.64 447.27 454.83 462.95
P/bar 111.7 120.3 127.0 8.8 19.8 31.0 40.6 51.6 62.5
wB 0.0994 0.0994 0.0994 0.0994 0.0994 0.1482 0.1482 0.1482 0.1482
T/K 470.39 478.90 487.54 495.36 502.94 438.88 439.03 446.08 452.85
P/bar 72.6 83.7 94.5 103.3 111.5 12.7 13.0 24.9 36.7
wB 0.1482 0.1482 0.1482 0.1482 0.1482 0.1482 0.1482
T/K 460.29 467.60 474.64 481.93 488.98 496.56 503.61
P/bar 47.6 58.9 68.2 77.7 86.0 94.5 102.4

−1 −1 −1
Characterization: Mn/kg.mol = 23.3, Mw/kg.mol = 60.4, Mz/kg.mol = 100.7,

wB 0.0049 0.0049 0.0049 0.0049 0.0148 0.0148 0.0148 0.0148 0.0364
T/K 443.13 453.13 463.18 473.22 443.25 453.15 463.14 473.05 443.49
P/MPa 2.5 3.9 5.2 6.6 2.6 4.1 5.5 6.6 2.6
wB 0.0364 0.0364 0.0364 0.0822 0.0822 0.0822 0.0888 0.0888 0.0888
T/K 453.54 463.58 473.55 433.15 453.10 473.14 443.34 453.36 463.37
P/MPa 4.0 5.4 6.6 1.6 4.5 7.2 2.1 3.4 4.9
continued
_____________________________________________________________________________
continued
wB 0.0888 0.1083 0.1083 0.1083 0.1083 0.1535 0.1535 0.1535 0.1535
T/K 473.41 443.42 453.38 463.42 473.45 443.03 453.04 463.05 473.01
P/MPa 6.3 1.9 3.2 4.7 6.1 1.4 2.8 4.1 5.4
wB 0.1952 0.1952 0.1952
T/K 452.98 463.09 473.21
P/MPa 2.4 3.8 5.1
wB 0.0822 0.0822 0.0822
T/K 433.18 453.13 473.13
P/MPa 1.1 1.5 1.9 (three VLLE data points)


wB 0.2128 0.2128 0.2128 0.2128 0.2128 0.2128 0.2128 0.2128 0.2128
T/K 446.2 457.4 467.6 478.0 457.4 467.6 478.0 488.2 498.4
P/MPa 1.05 1.33 1.60 1.88 2.29 3.78 5.16 6.45 7.65
VLE VLLE VLLE VLLE LLE LLE LLE LLE LLE
wB 0.2128 0.2128 0.1382 0.1382 0.1382 0.1382 0.1382 0.1382 0.1382
T/K 508.5 519.0 436.5 446.9 456.2 467.5 446.9 456.2 467.5
P/MPa 8.79 9.87 0.92 1.06 1.26 1.52 1.91 3.25 4.81
LLE LLE VLE VLLE VLLE VLLE LLE LLE LLE
wB 0.1382 0.1382 0.1382 0.1382 0.1382 0.0813 0.0813 0.0813 0.0813
T/K 477.7 488.1 498.4 508.5 519.0 431.3 441.2 451.4 461.9
P/MPa 6.13 7.44 8.67 9.80 10.89 0.77 0.93 1.14 1.38
LLE LLE LLE LLE LLE VLE VLLE VLLE VLLE
wB 0.0813 0.0813 0.0813 0.0813 0.0813 0.0813 0.0813 0.0813 0.0582
T/K 441.2 451.4 461.9 472.0 482.5 492.9 502.9 513.0 441.2
P/MPa 1.48 3.00 4.50 5.86 7.16 8.45 9.59 10.60 1.63
LLE LLE LLE LLE LLE LLE LLE LLE LLE
wB 0.0582 0.0582 0.0582 0.0582 0.0221 0.0221 0.0221 0.0221 0.0221
T/K 451.5 461.9 472.2 482.5 464.0 474.4 482.7 492.6 502.9
P/MPa 3.15 4.63 6.01 7.29 5.11 6.49 7.53 8.73 9.90
wB 0.0221 0.0138 0.0138 0.0138 0.0138 0.0138 0.0138 0.0138 0.0138
T/K 513.3 423.4 433.6 443.4 453.6 462.9 473.4 483.5 493.8
P/MPa 10.98 0.68 0.78 2.15 3.64 4.92 6.30 7.57 8.76
LLE VLE VLE LLE LLE LLE LLE LLE LLE
wB 0.0138 0.0138
T/K 503. 513.4
P/MPa 9.82 10.86
LLE LLE
_____________________________________________________________________________

Characterization: Mn/kg.mol−1 = 61.0, Mw/kg.mol−1 = 67.1, linear, completely
wB 0.0207 0.0207 0.0207 0.0207 0.0207 0.0207 0.0374 0.0374 0.0374
T/K 436.15 446.15 453.15 463.15 481.15 490.15 423.15 436.65 446.15
P/bar 15 27 37 52 72 94 22 30 46
wB 0.0374 0.0374 0.0374 0.0374 0.050 0.050 0.069 0.069 0.069
T/K 454.15 463.15 471.15 478.15 428.15 437.15 436.15 454.65 464.15
P/bar 59 71 81 91 22 35 22 49 58
wB 0.069 0.106 0.106 0.106 0.106 0.106 0.106 0.118 0.118
T/K 473.15 448.65 458.65 466.15 474.15 481.65 493.15 443.55 451.35
P/bar 76 42 54 60 70 80 91 23 34
wB 0.118 0.118 0.118 0.118 0.285 0.285 0.285 0.285 0.285
T/K 469.65 478.15 487.15 496.15 479.15 488.15 498.15 507.65 517.15
P/bar 63 71 77 92 54 69 83 93 101

ϕB, crit 0.026 0.025 0.024
T/K 429.0 444.0 461.0
P/bar 20 40 60

Characterization: Mn/kg.mol−1 = 82, Mw/kg.mol−1 = 108, completely hydrogenated
wB 0.0076 0.0076 0.0076 0.0076 0.0186 0.0186 0.0186 0.0186 0.0310
T/K 443.67 453.14 463.18 473.12 443.15 453.16 463.15 473.15 443.15
P/MPa 3.8 5.3 6.6 7.9 3.9 5.4 6.7 8.0 4.2
wB 0.0310 0.0310 0.0310 0.0536 0.0536 0.0536 0.0536 0.0829 0.0829
T/K 453.16 463.16 473.16 443.17 453.15 463.17 473.15 433.13 453.13
P/MPa 5.6 6.9 8.2 4.0 5.4 6.7 8.0 2.4 5.3
wB 0.0829 0.0886 0.0886 0.0886 0.0886 0.1026 0.1026 0.1026 0.1026
T/K 473.13 443.24 453.16 463.16 473.17 443.08 453.15 463.16 473.19
P/MPa 8.0 3.8 5.3 6.6 7.9 3.8 5.1 6.5 7.8
wB 0.1310 0.1310 0.1310 0.1310
T/K 443.14 453.14 463.18 473.15
P/MPa 3.6 5.0 6.4 7.7
wB 0.0829 0.0829 0.0829
T/K 433.13 453.13 473.12
P/MPa 1.1 1.5 2.0 (three VLLE data points)
_____________________________________________________________________________

Characterization: Mn/kg.mol−1 = 322, Mw/kg.mol−1 = 383, linear, completely

wB 0.00422 0.00422 0.00422 0.00422 0.00422 0.00422 0.00422 0.00422 0.006
T/K 437.65 447.35 456.15 465.65 475.05 484.75 494.55 503.75 434.15
P/bar 50 62 75 87 99 110 119.5 129.5 41
wB 0.006 0.006 0.006 0.006 0.006 0.006 0.0175 0.0175 0.0175
T/K 442.15 452.15 461.15 469.15 478.15 487.15 453.15 461.15 469.15
P/bar 54 66 79 90 101 111 69 81 91
wB 0.0175 0.0175 0.0175 0.0428 0.0428 0.0428 0.0428 0.0428 0.0428
T/K 478.15 488.15 496.65 430.15 437.15 445.15 454.15 462.15 473.15
P/bar 104 115 125 29 43 57 69 83 94
wB 0.0428 0.0428 0.060 0.060 0.060 0.060 0.060 0.060 0.060
T/K 482.15 492.15 429.85 437.55 448.15 456.15 464.85 474.65 483.65
P/bar 107 117 34 48 63 74 85 96 107
wB 0.060 0.0838 0.0838 0.0838 0.0838 0.0838 0.0838 0.0838 0.127
T/K 491.95 444.15 452.65 460.15 468.15 477.15 486.15 495.15 442.15
P/bar 115 46 58 69 80 93 101 114 32
wB 0.127 0.127 0.127 0.127 0.127 0.127 0.237 0.237 0.237
T/K 453.15 461.15 472.15 479.15 489.15 497.15 467.65 482.85 494.45
P/bar 43 56 74 86 98 112 47 66 83

ϕB, crit 0.012 0.012 0.013
T/K 416.2 431.4 446.3
P/bar 20 40 60

Solvent (A): 1-octene C8H16 111-66-0

wB 0.1791 0.1791 0.1791 0.1791 0.1791 0.1791 0.1791 0.0897 0.0897
T/K 503.3 513.4 524.3 533.9 524.3 533.9 544.8 503.2 512.8
P/MPa 0.97 1.14 1.35 1.57 1.38 2.30 3.30 0.94 1.13
VLE VLE VLLE VLLE LLE LLE LLE VLE VLE
wB 0.0897 0.0897 0.0897 0.0897 0.0897 0.0439 0.0439 0.0439 0.0439
T/K 523.8 535.0 523.8 534.9 544.3 503.3 513.4 524.5 533.4
P/MPa 1.35 1.60 1.93 3.07 3.95 0.95 1.11 1.34 1.54
VLLE VLLE LLE LLE LLE VLE VLE VLLE VLLE
continued
_____________________________________________________________________________
continued
wB 0.0439 0.0439 0.0439 0.0198 0.0198 0.0198 0.0198 0.0198 0.0198
T/K 524.4 533.4 544.1 503.3 513.3 523.9 533.5 523.9 533.5
P/MPa 2.19 3.09 4.10 0.95 1.14 1.35 1.58 2.22 3.16
LLE LLE LLE VLE VLLE VLLE VLLE LLE LLE
wB 0.0198
T/K 544.5
P/MPa 4.16
LLE
Polymer (B): polyethylene 2002YEO

Pressure Chemical Company, Pittsburgh, PA

T/K = 403.15
wB 0.003 0.010 0.015 0.020 0.030 0.035 0.037 0.039 0.040
P/bar 97.2 113.1 112.4 109.6 108.9 111.7 109.6 111.7 111.7
wB 0.043 0.045 0.050 0.060 0.070
P/bar 108.2 109.6 108.9 102.0 101.3
critical concentration: wB, crit = 0.0395
T/K = 423.15
wB 0.003 0.010 0.015 0.020 0.030 0.035 0.037 0.039 0.040
P/bar 124.8 137.9 137.9 133.7 135.1 137.2 135.1 136.5 136.5
wB 0.043 0.045 0.050 0.060 0.070
P/bar 131.7 133.7 131.0 127.5 127.5
T/K = 443.15
wB 0.003 0.010 0.015 0.020 0.030 0.035 0.037 0.039 0.040
P/bar 153.7 160.0 160.6 157.9 159.3 158.6 157.2 156.5 158.6
wB 0.043 0.045 0.050 0.060 0.070
P/bar 155.1 156.5 153.7 150.3 149.6
Polymer (B): polyethylene 2002YEO


continued
_____________________________________________________________________________
continued
T/K = 403.15
wB 0.003 0.020 0.040 0.060 0.062 0.065 0.068 0.070 0.075
P/bar 46.2 78.6 70.3 66.2 66.2 66.9 64.1 63.4 62.7
wB 0.080 0.100 0.110
P/bar 62.0 47.5 42.7
T/K = 423.15
wB 0.003 0.020 0.040 0.060 0.062 0.065 0.068 0.070 0.075
P/bar 79.3 108.9 100.6 93.1 92.4 92.4 90.3 89.6 88.9
wB 0.080 0.100 0.110
P/bar 88.2 75.8 70.3
T/K = 443.15
wB 0.003 0.020 0.040 0.060 0.062 0.065 0.068 0.070 0.075
P/bar 115.8 130.3 126.2 120.0 119.3 117.9 117.2 115.8 115.1
wB 0.080 0.100 0.110
P/bar 113.1 102.7 95.8


−1
cB/g.dl 1.0 20.0
T/K 295.65 295.65
P/MPa 557 539

American Polymer Standards

−1
cB/g.dl 0.3 1.0
T/K 295.65 295.65
P/MPa 430 435
_____________________________________________________________________________
Polymer (B): polyisobutylene 1972ZE1

Characterization: Mη /kg.mol−1 = 6.0, laboratory fractions, Mw/Mn = 1.14 by GPC

T/K = 344.35 wB = 0.0079 (dT/dP)P=1/K.bar−1 = +0.47
T/K = 337.85 wB = 0.0272 (dT/dP)P=1/K.bar−1 = +0.50
T/K = 321.85 wB = 0.0466 (dT/dP)P=1/K.bar−1 = +0.58

Characterization: Mη /kg.mol−1 = 703, laboratory fractions, Mw/Mn = 1.14 by GPC

T/K = 264.75 wB = 0.0114 (dT/dP)P=1/K.bar−1 = +0.37

−1
Characterization: Mη /kg.mol = 1660, laboratory fractions, Mw/Mn = 1.14 by GPC

T/K = 253.85 wB = 0.0061 (dT/dP)P=1/K.bar−1 = +0.37
T/K = 253.85 wB = 0.0112 (dT/dP)P=1/K.bar−1 = +0.37
T/K = 253.85 wB = 0.0466 (dT/dP)P=1/K.bar−1 = +0.37


T/K 443.15 453.15 463.95 473.25 483.15 493.15
P/MPa 1.3 2.5 3.9 5.4 6.7 8.3


T/K = 409.65 wB = 0.0204 (dT/dP)P=1/K.bar−1 = +0.61
_____________________________________________________________________________

Solvent (A): 2-methylbutane C6H12 78-78-4

T/K = 387.85 wB = 0.0235 (dT/dP)P=1/K.bar−1 = +0.55


T/K = 330.55 wB = 0.0220 (dT/dP)P=1/K.bar−1 = +0.45

−1
Characterization: Mη /kg.mol = 1660, laboratory fractions, Mw/Mn = 1.14 by GPC

T/K = 323.35 wB = 0.0220 (dT/dP)P=1/K.bar−1 = +0.44

−1
Characterization: Mη /kg.mol = 6.0, laboratory fractions, Mw/Mn = 1.14 by GPC

T/K = 403.55 wB = 0.0226 (dT/dP)P=1/K.bar−1 = +0.57


T/K = 353.55 wB = 0.0247 (dT/dP)P=1/K.bar−1 = +0.42


T/K = 347.35 wB = 0.0243 (dT/dP)P=1/K.bar−1 = +0.45
_____________________________________________________________________________


T/K = 291.55 wB = 0.0135 (dT/dP)P=1/K.bar−1 = +0.33
T/K = 279.85 wB = 0.0374 (dT/dP)P=1/K.bar−1 = +0.48
Polymer (B): poly(N-isopropylacrylamide) 2004SHI


cB/mol.l−1 = 0.690 T/K = 308.45 − 5.99 10−4 (P/MPa − 48.2)2
Polymer (B): poly(N-isopropylacrylamide) 2002RE1


wB 0.0035 0.0035 0.0035 0.0035 0.0035 0.0035 0.0035 0.0035 0.0307
T/K 313.0 313.7 314.2 314.9 315.1 315.6 315.8 315.4 310.2
P/bar 100.0 202.0 354.5 507.5 558.5 609.5 660.5 711.5 20.5
wB 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307
T/K 311.2 311.7 312.5 313.1 313.2 313.4 313.4 313.3 313.0
P/bar 148.5 262.5 365.0 426.0 477.0 507.5 538.5 558.5 609.5


wB 0.0039 0.0039 0.0039 0.0039 0.0039 0.0039 0.0039 0.0039 0.0295
T/K 307.2 307.5 308.1 308.4 308.4 308.4 308.2 308.0 306.6
P/bar 20.55 50.00 148.50 252.50 354.50 426.00 507.50 609.50 20.55
wB 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295
T/K 307.0 307.7 308.1 308.1 308.0 307.9 307.9
P/bar 50.00 148.50 283.50 354.50 426.00 507.50 609.50
_____________________________________________________________________________
Polymer (B): poly(N-isopropylacrylamide) 2001GOM

wB 0.01030 0.02011 0.02502 0.03574 0.03701 0.04167 0.04167 0.04167 0.04167
T/K 307.20 306.74 306.65 306.46 305.59 305.50 305.60 305.70 305.73
P/MPa 0.1 0.1 0.1 0.1 0.1 0.1 1.0 2.5 3.0
wB 0.04167 0.04167 0.04167 0.04167 0.04167 0.05646 0.06402 0.06774 0.07670
T/K 305.86 305.90 308.12 308.27 308.32 306.10 306.25 306.40 306.35
P/MPa 4.0 5.0 20.0 30.0 40.0 0.1 0.1 0.1 0.1
wB 0.08839 0.1057 0.1146 0.1474 0.1757
T/K 306.46 305.89 306.20 305.84 305.72
P/MPa 0.1 0.1 0.1 0.1 0.1
Type of data: spinodal points (LCST behavior)
wB 0.02011 0.03574 0.04167 0.04167 0.04167 0.04167 0.04167 0.04167 0.04529
T/K 321.6 312.1 309.2 308.5 309.2 308.2 307.6 307.4 310.7
P/MPa 0.10 0.10 0.10 1.0 2.5 3.0 4.0 5.0 0.10
wB 0.05646 0.06402 0.06774 0.07670 0.08839 0.1146 0.1474 0.1757
T/K 308.9 307.8 308.7 309.1 308.7 309.1 308.7 310.9
P/MPa 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10

wB 0.0103 0.0201 0.0250 0.0357 0.0370 0.0417 0.0417 0.0417 0.0417
T/K 307.2 306.7 306.6 306.5 305.6 305.5 305.6 305.7 305.7
P/bar 1.0 1.0 1.0 1.0 1.0 1.0 10.0 25.0 30.0
wB 0.0417 0.0417 0.0417 0.0417 0.0417 0.0417 0.0453 0.0565 0.0640
T/K 305.9 305.9 306.7 308.0 308.0 308.0 306.3 306.1 306.2
P/bar 40.0 50.0 100.0 200.0 300.0 400.0 1.0 1.0 1.0
wB 0.0677 0.0767 0.0884 0.1057 0.1146 0.1474 0.1757
T/K 306.4 306.3 306.5 305.9 306.2 305.8 305.7
P/bar 1.0 1.0 1.0 1.0 1.0 1.0 1.0
Polymer (B): poly(N-isopropylacrylamide) 2004SHI

−1
cB/mol.l = 0.690 T/K = 306.75 − 5.59 10−4 (P/MPa − 51.7)2
_____________________________________________________________________________
Polymer (B): polystyrene 1997DES

Solvent (A): acetaldehyde C2H4O 75-07-0

wB 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090
T/K 276.17 276.18 276.17 276.67 276.67 277.17 277.18 277.18 277.67
P/MPa 2.91 2.92 2.92 2.50 2.51 2.02 2.02 2.05 1.55
wB 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1374
T/K 277.67 277.67 278.47 278.48 278.67 278.66 278.97 278.97 281.66
P/MPa 1.57 1.58 0.79 0.74 0.61 0.62 0.34 0.32 2.69
wB 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374
T/K 281.66 281.66 282.16 282.16 282.16 282.16 282.66 282.66 282.66
P/MPa 2.65 2.67 2.27 2.28 2.26 2.27 1.83 1.81 1.81
wB 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1709
T/K 283.16 283.16 283.16 283.97 283.97 284.16 284.16 284.32 284.16
P/MPa 1.36 1.38 1.37 0.60 0.61 0.46 0.46 0.31 2.96
wB 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709
T/K 284.16 284.16 284.67 284.67 284.67 285.17 285.16 285.17 285.67
P/MPa 2.96 2.97 2.42 2.41 2.42 1.89 1.89 1.91 1.39
wB 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709
T/K 285.67 285.87 285.86 286.26 286.26 286.48 286.47 286.66 286.66
P/MPa 1.38 1.14 1.16 0.73 0.74 0.54 0.54 0.34 0.35
wB 0.1766 0.1766 0.1766 0.1766 0.1766 0.1766 0.1766 0.1766 0.1766
T/K 290.07 290.07 290.07 291.17 291.17 291.38 291.38 289.67 289.67
P/MPa 1.51 1.54 1.50 0.74 0.73 0.65 0.65 1.75 1.72
wB 0.1766 0.1766 0.1766 0.1766 0.1766 0.1986 0.1986 0.1986 0.1986
T/K 289.46 289.46 288.76 288.76 288.67 286.67 286.66 287.17 287.17
P/MPa 1.93 1.90 2.41 2.43 2.68 3.10 3.10 2.65 2.67
wB 0.1986 0.1986 0.1986 0.1986 0.1986 0.1986 0.1986 0.1986 0.1986
T/K 287.66 287.66 287.66 288.17 288.17 288.67 288.67 288.97 288.97
P/MPa 2.25 2.25 2.25 1.82 1.83 1.39 1.41 1.19 1.16
wB 0.1986 0.1986 0.1986 0.1986 0.2076 0.2076 0.2076 0.2076 0.2076
T/K 289.97 289.97 290.27 290.27 281.66 282.16 282.67 283.16 283.16
P/MPa 0.46 0.46 0.22 0.23 2.93 2.55 2.18 1.80 1.75
wB 0.2076 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225
T/K 284.68 290.67 290.68 291.17 291.18 291.66 291.66 292.17 292.17
P/MPa 0.43 2.96 3.02 2.64 2.64 2.24 2.23 1.90 1.88
wB 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225 0.2329
T/K 292.67 292.67 293.16 293.16 294.16 294.16 294.67 294.68 286.17
P/MPa 1.54 1.56 1.23 1.24 0.58 0.59 0.29 0.29 2.82
continued
_____________________________________________________________________________
continued
wB 0.2329 0.2329 0.2329 0.2329 0.2329 0.2329 0.2329 0.2329 0.2329
T/K 286.17 286.66 287.17 287.66 287.66 287.67 287.66 288.17 288.17
P/MPa 2.83 2.38 1.99 1.65 1.63 1.63 1.62 1.29 1.28
wB 0.2329 0.2329 0.2329 0.2329 0.2329 0.2329 0.2631 0.2631 0.2631
T/K 288.17 289.16 289.16 289.57 289.57 289.77 285.68 286.17 286.17
P/MPa 1.26 0.62 0.62 0.30 0.30 0.17 3.08 2.70 2.71
wB 0.2631 0.2631 0.2631 0.2631 0.2631 0.2631 0.2631 0.2631 0.2631
T/K 286.66 286.66 286.66 287.17 287.17 287.67 287.67 288.17 288.17
P/MPa 2.33 2.31 2.31 1.95 1.94 1.53 1.52 1.15 1.13
wB 0.2631 0.2631 0.2631 0.2631 0.3363 0.3363 0.3363 0.3363 0.3363
T/K 288.67 288.67 289.16 289.16 284.17 284.17 284.68 284.68 285.17
P/MPa 0.77 0.78 0.43 0.43 2.97 2.96 2.52 2.52 2.11
wB 0.3363 0.3363 0.3363 0.3363 0.3363 0.3363 0.3363 0.3363 0.3363
T/K 285.17 285.68 285.68 286.17 286.17 286.66 286.66 287.17 287.17
P/MPa 2.10 1.61 1.61 1.27 1.28 0.87 0.88 0.49 0.50

wB 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090
T/K 276.17 276.18 276.17 276.67 276.67 277.17 277.18 277.18 277.67
P/MPa 2.77 2.81 2.78 2.40 2.41 1.89 1.90 1.92 1.44
wB 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1374
T/K 277.67 277.67 278.47 278.48 278.67 278.66 278.97 278.97 281.66
P/MPa 1.46 1.45 0.70 0.65 0.53 0.51 0.22 0.19 2.51
wB 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374
T/K 281.66 281.66 282.16 282.16 282.16 282.16 282.66 282.66 282.66
P/MPa 2.51 2.51 2.12 2.09 2.10 2.12 1.68 1.66 1.67
wB 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1374 0.1709
T/K 283.16 283.16 283.16 283.97 283.97 284.16 284.16 284.32 284.16
P/MPa 1.21 1.21 1.23 0.47 0.50 0.34 0.35 0.18 2.83
wB 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709
T/K 284.16 284.16 284.67 284.67 284.67 285.17 285.16 285.17 285.67
P/MPa 2.84 2.82 2.28 2.28 2.29 1.74 1.76 1.77 1.24
wB 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709 0.1709
T/K 285.67 285.87 285.86 286.26 286.26 286.48 286.47 286.66 286.66
P/MPa 1.21 1.00 1.01 0.62 0.63 0.42 0.41 0.21 0.22
wB 0.1766 0.1766 0.1766 0.1766 0.1766 0.1766 0.1766 0.1766 0.1766
T/K 290.07 290.07 290.07 291.17 291.17 291.38 291.38 289.67 289.67
P/MPa 1.33 1.40 1.32 0.57 0.60 0.53 0.50 1.61 1.61
wB 0.1766 0.1766 0.1766 0.1766 0.1766 0.1986 0.1986 0.1986 0.1986
T/K 289.46 289.46 288.76 288.76 288.67 286.67 286.66 287.17 287.17
P/MPa 1.80 1.76 2.25 2.24 2.49 2.96 2.97 2.48 2.51
wB 0.1986 0.1986 0.1986 0.1986 0.1986 0.1986 0.1986 0.1986 0.1986
T/K 287.66 287.66 287.66 288.17 288.17 288.67 288.67 288.97 288.97
P/MPa 2.10 2.12 2.13 1.71 1.69 1.28 1.28 1.05 1.02
continued
_____________________________________________________________________________
continued
wB 0.1986 0.1986 0.1986 0.1986 0.2076 0.2076 0.2076 0.2076 0.2076
T/K 289.97 289.97 290.27 290.27 281.66 282.16 282.67 283.16 283.16
P/MPa 0.33 0.34 0.09 0.10 2.85 2.43 2.06 1.65 1.60
wB 0.2076 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225
T/K 284.68 290.67 290.68 291.17 291.18 291.66 291.66 292.17 292.17
P/MPa 0.32 2.91 2.93 2.55 2.55 2.15 2.15 1.80 1.81
wB 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225 0.2225 0.2329
T/K 292.67 292.67 293.16 293.16 294.16 294.16 294.67 294.68 286.17
P/MPa 1.50 1.52 1.16 1.19 0.52 0.53 0.22 0.22 2.71
wB 0.2329 0.2329 0.2329 0.2329 0.2329 0.2329 0.2329 0.2329 0.2329
T/K 286.17 286.66 287.17 287.66 287.66 287.67 287.66 288.17 288.17
P/MPa 2.72 2.27 1.91 1.58 1.57 1.56 1.53 1.22 1.19
wB 0.2329 0.2329 0.2329 0.2329 0.2329 0.2329 0.2631 0.2631 0.2631
T/K 288.17 289.16 289.16 289.57 289.57 289.77 285.68 286.17 286.17
P/MPa 1.18 0.57 0.54 0.25 0.25 0.10 2.98 2.59 2.60
wB 0.2631 0.2631 0.2631 0.2631 0.2631 0.2631 0.2631 0.2631 0.2631
T/K 286.66 286.66 286.66 287.17 287.17 287.67 287.67 288.17 288.17
P/MPa 2.26 2.22 2.20 1.84 1.84 1.42 1.42 1.01 1.03
wB 0.2631 0.2631 0.2631 0.2631 0.3363 0.3363 0.3363 0.3363 0.3363
T/K 288.67 288.67 289.16 289.16 284.17 284.17 284.68 284.68 285.17
P/MPa 0.73 0.70 0.33 0.37 2.88 2.90 2.43 2.45 2.02
wB 0.3363 0.3363 0.3363 0.3363 0.3363 0.3363 0.3363 0.3363 0.3363
T/K 285.17 285.68 285.68 286.17 286.17 286.66 286.66 287.17 287.17
P/MPa 2.02 1.54 1.53 1.18 1.20 0.79 0.79 0.41 0.42
Polymer (B): polystyrene 1997DES


wB 0.0736 0.0736 0.0736 0.0736 0.0736 0.0736 0.0736 0.0736 0.0736
T/K 286.16 286.65 287.16 287.65 288.66 289.66 290.15 290.67 290.86
P/MPa 4.32 3.91 3.51 3.10 2.33 1.64 1.30 0.96 0.84
wB 0.0736 0.0736 0.0736 0.0892 0.0892 0.0892 0.0892 0.0892 0.0892
T/K 291.16 291.46 291.76 294.68 295.17 295.67 296.67 296.67 297.16
P/MPa 0.67 0.46 0.26 3.25 3.01 2.72 2.19 2.20 1.87
wB 0.0892 0.0892 0.0892 0.0892 0.0892 0.1058 0.1058 0.1058 0.1058
T/K 297.65 298.16 299.15 299.56 299.76 297.25 297.05 296.96 296.85
P/MPa 1.60 1.35 0.83 0.62 0.52 0.15 0.26 0.31 0.36
wB 0.1058 0.1058 0.1058 0.1058 0.1058 0.1058 0.1058 0.1058 0.1058
T/K 296.76 296.66 296.56 296.45 296.35 295.17 294.16 293.16 292.17
P/MPa 0.41 0.47 0.53 0.59 0.63 1.27 1.86 2.47 3.05
continued
_____________________________________________________________________________
continued
wB 0.1058 0.1058 0.1184 0.1184 0.1184 0.1184 0.1184 0.1184 0.1184
T/K 291.66 291.15 295.66 296.17 296.66 297.66 298.16 299.15 299.66
P/MPa 3.40 3.78 3.34 3.02 2.74 2.19 1.92 1.40 1.17
wB 0.1184 0.1184 0.1184 0.1184 0.1184 0.1184 0.1415 0.1415 0.1415
T/K 300.65 301.15 301.34 301.56 301.75 301.95 309.14 309.14 309.65
P/MPa 0.65 0.48 0.40 0.29 0.24 0.16 4.18 4.20 3.95
wB 0.1415 0.1415 0.1415 0.1415 0.1415 0.1415 0.1415 0.1415 0.1415
T/K 310.14 312.15 314.14 317.14 318.65 320.63 321.63 322.63 323.63
P/MPa 3.71 3.00 2.38 1.60 1.21 0.81 0.60 0.44 0.29
wB 0.1415 0.1561 0.1561 0.1561 0.1561 0.1561 0.1561 0.1561 0.1561
T/K 324.14 315.64 316.64 317.64 318.65 320.63 323.12 326.14 327.63
P/MPa 0.23 4.03 3.72 3.38 3.10 2.57 2.00 1.43 1.21
wB 0.1561 0.1561 0.1561 0.1561 0.1561 0.1654 0.1654 0.1654 0.1654
T/K 330.62 331.62 333.11 334.12 335.12 314.64 315.64 316.64 317.65
P/MPa 0.80 0.70 0.57 0.46 0.41 3.80 3.45 3.20 2.93
wB 0.1654 0.1654 0.1654 0.1654 0.1654 0.1654 0.1654 0.1654 0.1654
T/K 318.65 320.63 322.63 325.14 328.63 329.62 330.63 331.63 333.12
P/MPa 2.62 2.13 1.72 1.28 0.80 0.70 0.57 0.48 0.35
wB 0.1654 0.1654 0.1676 0.1676 0.1676 0.1676 0.1676 0.1676 0.1676
T/K 334.22 334.71 289.85 290.67 291.16 292.17 293.16 294.16 294.37
P/MPa 0.25 0.23 4.08 3.52 3.19 2.55 1.96 1.40 1.26
wB 0.1676 0.1676 0.1676 0.1676 0.1676 0.1676 0.1676 0.1702 0.1702
T/K 295.46 295.56 295.75 295.96 296.17 296.35 296.56 275.17 275.66
P/MPa 0.69 0.64 0.53 0.45 0.32 0.23 0.13 4.11 3.43
wB 0.1702 0.1702 0.1702 0.1702 0.1702 0.1702 0.1702 0.1702 0.1702
T/K 276.17 277.17 277.66 277.76 278.26 278.47 278.66 278.76 278.87
P/MPa 2.90 1.89 1.39 1.30 0.84 0.65 0.50 0.40 0.32
wB 0.1702 0.1786 0.1786 0.1786 0.1786 0.1786 0.1786 0.1786 0.1786
T/K 278.96 270.17 270.68 271.17 271.67 272.67 273.06 273.67 273.76
P/MPa 0.25 4.56 3.95 3.33 2.74 1.66 1.24 0.65 0.55
wB 0.1786 0.1786 0.1786 0.1932 0.1932 0.1932 0.1932 0.1932 0.1932
T/K 273.87 273.97 274.06 282.15 283.15 284.15 284.67 285.16 285.67
P/MPa 0.42 0.32 0.21 4.11 3.27 2.45 2.06 1.68 1.32
wB 0.1932 0.1932 0.1932 0.1932 0.1932 0.1932 0.2069 0.2069 0.2069
T/K 286.46 286.66 287.07 287.16 287.35 287.46 312.64 313.13 314.13
P/MPa 0.72 0.60 0.33 0.27 0.14 0.08 4.35 4.18 3.84
wB 0.2069 0.2069 0.2069 0.2069 0.2069 0.2069 0.2069 0.2069 0.2069
T/K 315.64 317.13 319.14 321.13 323.13 325.64 326.64 327.32 327.93
P/MPa 3.26 2.81 2.21 1.71 1.26 0.78 0.60 0.49 0.40
wB 0.2069 0.2253 0.2253 0.2253 0.2253 0.2253 0.2253 0.2253 0.2253
T/K 328.43 316.91 317.64 318.65 320.63 323.13 325.64 328.13 329.63
P/MPa 0.33 4.12 3.89 3.58 3.02 2.41 1.88 1.46 1.20
continued
_____________________________________________________________________________
continued
wB 0.2253 0.2253 0.2253 0.2253 0.2253 0.2253 0.2253 0.2461 0.2461
T/K 333.12 334.11 335.61 337.62 339.10 340.10 341.10 316.14 317.14
P/MPa 0.78 0.67 0.55 0.39 0.30 0.22 0.17 3.89 3.58
wB 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461
T/K 318.13 320.14 322.13 325.14 328.13 331.62 333.12 334.12 335.12
P/MPa 3.30 2.76 2.29 1.70 1.23 0.79 0.64 0.55 0.45
wB 0.2461 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196
T/K 337.12 316.64 317.14 318.13 320.13 322.13 324.14 327.13 330.12
P/MPa 0.34 4.55 4.35 4.02 3.43 2.90 2.44 1.85 1.37
wB 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196
T/K 333.62 336.12 338.12 340.10 341.10 342.10
P/MPa 0.92 0.69 0.54 0.39 0.32 0.27

wB 0.0736 0.0736 0.0736 0.0736 0.0736 0.0736 0.0736 0.0736 0.0736
T/K 286.16 286.65 287.16 287.65 288.66 289.66 290.15 290.86 291.16
P/MPa 4.18 3.79 3.37 3.02 2.27 1.56 1.23 0.79 0.56
wB 0.0736 0.0736 0.1058 0.1058 0.1058 0.1058 0.1058 0.1058 0.1058
T/K 291.46 291.76 297.25 297.05 296.96 296.85 296.76 296.66 296.45
P/MPa 0.38 0.19 0.06 0.19 0.21 0.26 0.30 0.35 0.52
wB 0.1058 0.1058 0.1058 0.1058 0.1058 0.1058 0.1415 0.1415 0.1415
T/K 295.17 294.16 293.16 292.18 291.66 291.15 309.14 309.65 310.14
P/MPa 1.12 1.75 2.39 2.90 3.25 3.63 3.94 3.74 3.63
wB 0.1415 0.1415 0.1415 0.1415 0.1415 0.1415 0.1415 0.1415 0.1561
T/K 312.15 314.14 317.14 318.64 321.63 322.63 323.63 324.14 315.64
P/MPa 2.88 2.30 1.50 1.14 0.50 0.34 0.19 0.15 3.90
wB 0.1561 0.1561 0.1561 0.1561 0.1561 0.1561 0.1561 0.1561 0.1561
T/K 316.64 317.64 318.65 320.63 323.12 326.14 327.63 330.62 333.11
P/MPa 3.57 3.28 2.96 2.49 1.94 1.32 1.14 0.76 0.50
wB 0.1561 0.1561 0.1654 0.1654 0.1654 0.1654 0.1654 0.1654 0.1654
T/K 334.12 335.12 314.64 315.65 316.64 317.65 318.66 320.63 322.63
P/MPa 0.36 0.28 3.69 3.40 3.12 2.81 2.59 2.04 1.66
wB 0.1654 0.1654 0.1654 0.1654 0.1654 0.1654 0.1654 0.1676 0.1676
T/K 325.14 329.62 330.63 331.63 333.12 334.22 334.71 289.85 290.67
P/MPa 1.23 0.68 0.53 0.43 0.27 0.19 0.17 3.95 3.33
wB 0.1676 0.1676 0.1676 0.1676 0.1676 0.1676 0.1676 0.1676 0.1676
T/K 291.16 292.17 293.16 294.16 294.37 295.46 295.56 295.75 295.96
P/MPa 3.13 2.49 1.89 1.29 1.18 0.63 0.58 0.48 0.35
wB 0.1676 0.1676 0.1702 0.1702 0.1702 0.1702 0.1702 0.1702 0.1702
T/K 296.17 296.35 275.17 275.66 276.17 277.17 277.66 277.76 278.26
P/MPa 0.24 0.11 3.95 3.32 2.76 1.76 1.30 1.22 0.75
wB 0.1702 0.1702 0.1702 0.1702 0.1702 0.1786 0.1786 0.1786 0.1786
T/K 278.47 278.66 278.76 278.87 278.96 270.17 270.68 271.17 271.67
P/MPa 0.53 0.38 0.29 0.22 0.18 4.47 3.86 3.20 2.63
continued
_____________________________________________________________________________
continued
wB 0.1786 0.1786 0.1786 0.1786 0.1786 0.1786 0.1786 0.1932 0.1932
T/K 272.67 273.06 273.67 273.76 273.87 273.97 274.06 282.15 283.15
P/MPa 1.52 1.16 0.54 0.41 0.35 0.23 0.15 3.95 3.05
wB 0.1932 0.1932 0.1932 0.1932 0.1932 0.1932 0.1932 0.1932 0.2069
T/K 284.16 284.67 285.16 285.67 286.66 287.07 287.16 287.35 312.64
P/MPa 2.31 1.95 1.51 1.18 0.48 0.20 0.14 0.03 4.27
wB 0.2069 0.2069 0.2069 0.2069 0.2069 0.2069 0.2069 0.2069 0.2069
T/K 313.13 314.13 315.64 317.14 319.14 321.13 323.13 325.64 326.64
P/MPa 4.08 3.73 3.19 2.71 2.16 1.63 1.16 0.71 0.56
wB 0.2069 0.2069 0.2069 0.2253 0.2253 0.2253 0.2253 0.2253 0.2253
T/K 327.32 327.93 328.43 316.90 317.64 318.65 320.63 323.13 325.64
P/MPa 0.45 0.32 0.25 4.05 3.81 3.51 2.95 2.34 1.82
wB 0.2253 0.2253 0.2253 0.2253 0.2253 0.2253 0.2253 0.2253 0.2253
T/K 328.13 329.63 333.12 334.11 335.61 337.62 339.10 340.10 341.10
P/MPa 1.38 1.14 0.73 0.62 0.46 0.32 0.23 0.18 0.11
wB 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461
T/K 316.14 317.14 318.13 320.14 322.13 325.14 328.13 331.62 333.12
P/MPa 3.69 3.43 3.19 2.66 2.12 1.55 1.13 0.64 0.51
wB 0.2461 0.2461 0.2461 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196
T/K 334.12 335.12 337.12 316.64 317.14 318.13 320.13 322.13 324.14
P/MPa 0.37 0.28 0.19 4.45 4.25 3.93 3.35 2.82 2.33
wB 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196
T/K 327.13 330.12 333.62 336.12 338.12 340.10 341.10 342.10
P/MPa 1.77 1.29 0.90 0.63 0.47 0.33 0.25 0.17
Polymer (B): polystyrene 1997DES, 1997REB


wB 0.0563 0.0563 0.0563 0.0563 0.0563 0.0563 0.0563 0.0563 0.0563
T/K 268.07 268.65 269.16 270.19 270.95 271.55 272.07 272.57 428.05
P/MPa 4.94 4.34 3.68 2.33 1.60 0.93 0.53 0.10 5.29
wB 0.0563 0.0563 0.0703 0.0703 0.0703 0.0703 0.0703 0.0703 0.0703
T/K 427.05 426.23 293.61 295.21 298.19 300.63 302.21 302.79 304.31
P/MPa 4.37 3.41 5.58 4.80 3.19 2.11 1.59 1.26 0.80
wB 0.0703 0.0703 0.0703 0.0703 0.0985 0.0985 0.0985 0.0985 0.0985
T/K 304.59 305.19 305.47 306.02 323.61 326.12 328.65 332.09 337.08
P/MPa 0.71 0.55 0.40 0.28 4.22 3.65 3.18 2.70 2.14
wB 0.0985 0.0985 0.0985 0.0985 0.0985 0.0985 0.0985 0.0985 0.0985
T/K 342.07 348.10 353.13 356.60 361.59 363.61 368.08 371.12 375.11
P/MPa 1.89 1.78 1.81 1.92 2.01 2.08 2.46 2.64 3.07
continued
_____________________________________________________________________________
continued
wB 0.0985 0.0985 0.1115 0.1115 0.1115 0.1115 0.1115 0.1115 0.1115
T/K 380.13 385.12 281.66 282.62 283.73 284.70 285.47 286.57 286.72
P/MPa 3.58 4.04 4.39 3.63 2.81 2.04 1.50 0.68 0.56
wB 0.1115 0.1115 0.1115 0.1115 0.1115 0.1115 0.1115 0.1253 0.1253
T/K 287.02 287.20 413.23 412.69 412.22 411.75 411.11 278.68 279.57
P/MPa 0.41 0.27 4.27 3.64 3.11 2.54 2.09 5.64 4.77
wB 0.1253 0.1253 0.1253 0.1253 0.1253 0.1253 0.1253 0.1253 0.1253
T/K 280.74 281.75 282.75 283.68 284.14 284.45 284.74 285.01 285.19
P/MPa 3.75 2.91 2.08 1.35 0.99 0.74 0.53 0.29 0.24
wB 0.1253 0.1253 0.1253 0.1253 0.1253 0.1419 0.1419 0.1419 0.1419
T/K 414.25 413.66 413.54 413.22 412.84 280.17 281.19 282.17 283.17
P/MPa 4.05 3.44 3.00 2.53 2.18 5.80 4.83 3.87 3.12
wB 0.1419 0.1419 0.1419 0.1419 0.1419 0.1419 0.1419 0.1419 0.1419
T/K 284.18 285.07 285.66 286.27 286.61 286.76 287.19 415.13 414.13
P/MPa 2.35 1.59 1.24 0.89 0.63 0.48 0.22 4.39 3.79
wB 0.1419 0.1419 0.1419 0.1630 0.1630 0.1630 0.1630 0.1630 0.1630
T/K 413.15 412.56 412.19 306.08 307.09 309.15 311.05 313.14 315.11
P/MPa 3.14 2.61 2.21 4.78 4.37 3.65 2.98 2.40 1.87
wB 0.1630 0.1630 0.1630 0.1630 0.1630 0.1630 0.1630 0.1630 0.1630
T/K 317.14 319.62 320.63 322.11 323.53 324.20 389.62 389.12 387.11
P/MPa 1.37 0.87 0.70 0.51 0.26 0.17 4.88 4.58 4.01
wB 0.1630 0.1630 0.1630 0.1630 0.1630 0.1700 0.1700 0.1700 0.1700
T/K 385.11 383.10 380.16 377.14 376.08 305.02 306.15 308.10 310.09
P/MPa 3.51 2.97 2.26 1.53 1.19 4.70 4.29 3.49 2.80
wB 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700
T/K 312.03 313.95 315.22 317.02 317.99 319.10 319.93 320.64 391.13
P/MPa 2.13 1.56 1.34 0.89 0.69 0.50 0.34 0.20 4.85
wB 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1731
T/K 390.20 388.18 386.15 384.19 382.15 380.18 378.10 376.09 304.18
P/MPa 4.48 3.98 3.49 3.05 2.61 2.11 1.66 1.23 4.74
wB 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731
T/K 305.13 307.02 308.99 311.12 313.02 314.13 316.57 317.06 318.07
P/MPa 4.27 3.50 2.83 2.21 1.61 1.38 0.79 0.67 0.45
wB 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731
T/K 305.13 307.02 308.99 311.12 313.02 314.13 316.57 317.06 318.07
P/MPa 4.19 3.44 2.74 2.10 1.53 1.33 0.72 0.60 0.37
wB 0.1731 0.1731 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870
T/K 318.62 319.03 306.14 308.19 310.02 312.12 314.16 316.11 318.15
P/MPa 0.33 0.25 4.91 4.09 3.41 2.77 2.20 1.71 1.28
wB 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870
T/K 320.59 322.07 323.99 393.13 391.16 389.13 386.15 383.14 380.09
P/MPa 0.79 0.52 0.28 5.35 4.76 4.21 3.46 2.77 2.10
continued
_____________________________________________________________________________
continued
wB 0.1870 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201
T/K 377.14 303.08 305.14 307.11 309.12 311.16 313.18 315.18 316.18
P/MPa 1.43 4.91 4.08 3.30 2.59 1.94 1.36 0.88 0.65
wB 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201
T/K 317.31 318.23 393.15 391.12 389.19 386.15 383.13 380.11 377.13
P/MPa 0.45 0.23 4.98 4.41 3.91 3.22 2.56 1.93 1.31
wB 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201
T/K 317.31 318.23 393.15 391.12 389.19 386.15 383.13 380.11 377.13
P/MPa 0.36 0.16 4.79 4.29 3.75 3.13 2.44 1.76 1.15

wB 0.0563 0.0563 0.0563 0.0563 0.0563 0.0563 0.0563 0.0563
T/K 268.07 268.65 269.16 270.19 270.95 271.55 272.07 272.57
P/MPa 4.85 4.24 3.59 2.25 1.54 0.89 0.47 0.03
wB 0.0563 0.0563 0.0703 0.0703 0.0703 0.0703 0.0703 0.0703 0.0703
T/K 427.05 426.23 293.61 295.21 298.19 300.63 302.21 302.79 304.31
P/MPa 4.30 3.36 5.53 4.74 3.10 2.05 1.51 1.18 0.77
wB 0.0703 0.0703 0.0703 0.0703 0.0985 0.0985 0.0985 0.0985 0.0985
T/K 304.59 305.19 305.47 306.02 323.61 326.12 328.65 332.09 337.08
P/MPa 0.65 0.49 0.34 0.21 4.13 3.56 3.09 2.64 2.10
wB 0.0985 0.0985 0.0985 0.0985 0.0985 0.0985 0.0985 0.0985 0.0985
T/K 342.07 348.10 353.13 356.60 361.59 363.61 368.08 371.12 375.11
P/MPa 1.85 1.71 1.76 1.90 1.96 2.05 2.38 2.61 3.02
wB 0.0985 0.0985 0.1115 0.1115 0.1115 0.1115 0.1115 0.1115 0.1115
T/K 380.13 385.12 281.66 282.62 283.73 284.70 285.47 286.57 286.72
P/MPa 3.56 3.99 4.28 3.54 2.71 1.93 1.41 0.60 0.47
wB 0.1115 0.1115 0.1115 0.1115 0.1115 0.1115 0.1115 0.1253 0.1253
T/K 287.02 287.20 413.23 412.69 412.22 411.75 411.11 278.68 279.57
P/MPa 0.39 0.21 4.25 3.61 3.04 2.50 2.06 5.48 4.67
wB 0.1253 0.1253 0.1253 0.1253 0.1253 0.1253 0.1253 0.1253 0.1253
T/K 280.74 281.75 282.75 283.68 284.14 284.45 284.74 285.01 285.19
P/MPa 3.61 2.79 1.95 1.25 0.92 0.66 0.46 0.21 0.17
wB 0.1253 0.1253 0.1253 0.1253 0.1253 0.1419 0.1419 0.1419 0.1419
T/K 414.25 413.66 413.54 413.22 412.84 280.17 281.19 282.17 283.17
P/MPa 3.94 3.37 2.91 2.41 2.07 5.68 4.76 3.80 3.03
wB 0.1419 0.1419 0.1419 0.1419 0.1419 0.1419 0.1419 0.1419 0.1419
T/K 284.18 285.07 285.66 286.27 286.61 286.76 287.19 415.13 414.13
P/MPa 2.28 1.52 1.13 0.78 0.58 0.42 0.16 4.34 3.74
wB 0.1419 0.1419 0.1419 0.1630 0.1630 0.1630 0.1630 0.1630 0.1630
T/K 413.15 412.56 412.19 306.08 307.09 309.15 311.05 313.14 315.11
P/MPa 3.08 2.53 2.17 4.69 4.29 3.57 2.91 2.33 1.77
wB 0.1630 0.1630 0.1630 0.1630 0.1630 0.1630 0.1630 0.1630 0.1630
T/K 317.14 319.62 320.63 322.11 323.53 324.20 389.62 389.12 387.11
P/MPa 1.32 0.82 0.64 0.44 0.19 0.11 4.79 4.49 3.97
continued
_____________________________________________________________________________
continued
wB 0.1630 0.1630 0.1630 0.1630 0.1630 0.1700 0.1700 0.1700 0.1700
T/K 385.11 383.10 380.16 377.14 376.08 305.02 306.15 308.10 310.09
P/MPa 3.47 2.91 2.23 1.48 1.15 4.62 4.19 3.39 2.70
wB 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700
T/K 312.03 313.95 315.22 317.02 317.99 319.10 319.93 320.64 391.13
P/MPa 2.07 1.50 1.28 0.85 0.64 0.45 0.27 0.14 4.78
wB 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1731
T/K 390.20 388.18 386.15 384.19 382.15 380.18 378.10 376.09 304.18
P/MPa 4.45 3.93 3.42 3.00 2.55 2.08 1.62 1.19 4.62
wB 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731 0.1731
T/K 305.13 307.02 308.99 311.12 313.02 314.13 316.57 317.06 318.07
P/MPa 4.19 3.44 2.74 2.10 1.53 1.33 0.72 0.60 0.37
wB 0.1731 0.1731 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870
T/K 318.62 319.03 306.14 308.19 310.02 312.12 314.16 316.11 318.15
P/MPa 0.27 0.18 4.84 4.01 3.33 2.68 2.14 1.67 1.22
wB 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870 0.1870
T/K 320.59 322.07 323.99 393.13 391.16 389.13 386.15 383.14 380.09
P/MPa 0.75 0.47 0.23 5.30 4.72 4.14 3.43 2.70 2.05
wB 0.1870 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201 0.2201
T/K 377.14 303.08 305.14 307.11 309.12 311.16 313.18 315.18 316.18
P/MPa 1.38 4.77 3.95 3.22 2.50 1.89 1.29 0.81 0.58
Polymer (B): polystyrene 1981WOL

Type of data: cloud points (UCST behavior)

wB 0.060 was kept constant at the critical concentration
T/K 301.34 301.11 300.95 300.96 301.12 301.43 301.68
P/bar 1 37 88 152 187 260 300
Polymer (B): polystyrene 1999BUN

BASF AG, Germany

T/K 496.35 498.35 501.45 505.45 511.05 515.15 522.45 530.95
P/bar 20.6 23.5 27.6 33.9 43.6 51.0 61.0 74.0
continued
_____________________________________________________________________________
continued
Type of data: coexistence data
T/K = 530.95
Total feed concentration of the homogeneous system before demixing: wB = 0.1138.

___________________________________________________________________
P/ wB wB
bar gel phase sol phase
___________________________________________________________________
74.0 0.1138 (cloud point)
63.8 0.2553 0.0184
55.5 0.2749 0.0073
41.9 0.3500
32.0 0.3600
___________________________________________________________________
Polymer (B): polystyrene 2002HOR

BASF AG, Germany

T/K 496.09 498.61 501.22 503.56 506.14 508.65 511.10 513.56 516.10
P/bar 24 26 32 34 38 41 44 48 51
Polymer (B): polystyrene 2003JI1, 2004JIA

Solvent (A): trans-decalin C10H18 493-02-7

ϕB 0.042 0.084 0.128 0.172 0.216 0.042 0.084 0.128 0.172
T/K 279.0 282.0 284.9 284.0 273.0 279.7 283.0 285.5 284.3
P/bar 1 1 1 1 1 100 100 100 100
ϕB 0.216 0.042 0.084 0.128 0.172 0.216 0.042 0.084 0.128
T/K 274.8 280.7 283.7 286.1 284.9 275.9 281.5 284.4 286.6
P/bar 100 200 200 200 200 200 300 300 300
ϕB 0.172 0.216 0.042 0.084 0.128 0.172 0.216 0.042 0.084
T/K 285.5 277.0 282.3 285.1 287.2 286.1 278.1 283.2 285.7
P/bar 300 300 400 400 400 400 400 500 500
continued
_____________________________________________________________________________
continued
ϕB 0.128 0.172 0.216 0.042 0.084 0.128 0.172 0.216 0.042
T/K 287.8 286.7 279.2 284.0 286.5 288.4 287.3 280.3 284.8
P/bar 500 500 500 600 600 600 600 600 700
ϕB 0.084 0.128 0.172 0.216 0.042 0.084 0.128 0.172 0.216
T/K 287.1 289.0 287.9 281.5 285.7 287.8 289.6 288.5 282.6
P/bar 700 700 700 700 800 800 800 800 800
Comments: The volume fractions were determined at 1 bar.
Polymer (B): polystyrene 1986SAE

Solvent (A): diethyl oxalate C6H10O4 95-92-1

T/K = 261.96 ϕB = 0.1578 (dT/dP)P=1/K.atm−1 = +0.00126


T/K = 280.05 ϕB = 0.1302 (dT/dP)P=1/K.atm−1 = −0.0045


T/K = 292.59 ϕB = 0.0927 (dT/dP)P=1/K.atm−1 = −0.0105


T/K = 309.96 ϕB = 0.0427 (dT/dP)P=1/K.atm−1 = −0.019
_____________________________________________________________________________
Polymer (B): polystyrene 1992SZY

Solvent (A): 1,1,1,3,3,3-hexadeutero-2-propanone C3D6O 666-52-4

wB 0.072 0.090 0.110 0.130 0.149 0.162 0.293
ϕB = 0.060 0.075 0.092 0.109 0.125 0.137 0.253
T/K 277.63 281.52 284.58 286.07 286.75 286.85 284.72
(dT/dP)P=0/K.MPa−1 −1.70 −1.40 −1.30 −1.27 −1.25 −1.26 −1.31

wB 0.072 0.090 0.110 0.162 0.293
ϕB = 0.060 0.075 0.092 0.137 0.253
T/K 276.60 279.73 283.30 286.50 284.01
(dT/dP)P=0/K.MPa−1 −1.63 −1.35 −1.23 −1.27 −1.26


wB 0.090 0.140 0.220 0.240
ϕB = 0.075 0.115 0.185 0.203
T/K 280.95 284.14 283.23 283.02
(dT/dP)P=0/K.MPa−1 −1.25 −1.29 −1.29 −1.32

wB 0.090 0.140 0.220 0.240
ϕB = 0.075 0.115 0.185 0.203
T/K 280.48 284.00 283.23 282.93
(dT/dP)P=0/K.MPa−1 −1.28 −1.43 −1.29 −1.37
Polymer (B): polystyrene 1995LUS


wB 0.101 0.101 0.101 0.101 0.101 0.101 0.101 0.101 0.114
T/K 328.09 332.09 334.55 336.41 337.92 339.34 380.82 379.15 331.96
P/MPa 2.33 1.65 1.05 0.81 0.56 0.45 1.34 0.92 2.25
continued
_____________________________________________________________________________
continued
wB 0.114 0.114 0.114 0.114 0.114 0.114 0.114 0.114 0.123
T/K 334.66 337.41 340.13 342.71 378.77 380.57 371.78 374.31 332.14
P/MPa 1.72 1.43 1.04 0.92 1.22 1.39 0.93 1.01 2.67
wB 0.123 0.123 0.123 0.123 0.123 0.123 0.123 0.123 0.123
T/K 333.44 337.59 341.36 344.53 346.66 350.05 352.68 358.35 364.62
P/MPa 2.35 1.64 1.27 1.11 0.86 0.85 0.90 1.31 1.78
wB 0.123 0.131 0.131 0.131 0.131 0.131 0.131 0.131 0.131
T/K 368.55 334.51 339.31 343.41 345.83 351.16 356.50 358.36 363.62
P/MPa 2.46 2.20 1.59 1.18 1.13 0.84 0.82 0.91 1.06
wB 0.131 0.131 0.131 0.147 0.147 0.147 0.147 0.147 0.147
T/K 366.71 369.29 372.79 332.28 336.35 340.25 344.21 345.44 348.79
P/MPa 1.08 1.28 1.68 2.48 1.81 1.25 1.01 0.84 0.72
wB 0.147 0.147 0.147 0.147 0.147 0.147 0.147 0.163 0.163
T/K 351.74 352.11 354.97 358.01 363.66 367.13 371.58 336.06 338.37
P/MPa 0.51 0.49 0.45 0.45 0.53 0.71 0.92 1.77 1.45
wB 0.163 0.163 0.163 0.163 0.163 0.163 0.163 0.163 0.194
T/K 341.10 345.26 347.69 352.92 358.34 362.11 366.28 368.08 337.28
P/MPa 1.09 0.74 0.59 0.39 0.37 0.41 0.51 0.59 1.54
wB 0.194 0.194 0.194 0.194 0.194 0.194 0.194 0.204 0.204
T/K 341.73 340.81 344.61 344.60 342.87 339.09 333.17 330.56 333.13
P/MPa 1.05 1.12 0.75 0.76 0.88 1.31 2.24 2.77 2.24
wB 0.204 0.204 0.204 0.204 0.204 0.204 0.204 0.204 0.204
T/K 333.13 338.53 341.31 346.48 349.67 355.46 358.33 362.83 365.49
P/MPa 2.23 1.38 1.11 0.66 0.49 0.32 0.33 0.40 0.49
wB 0.204 0.204 0.204 0.229 0.229 0.229 0.229 0.229 0.229
T/K 369.33 372.62 379.32 329.85 332.52 335.22 340.82 343.52 346.05
P/MPa 0.68 0.88 1.39 2.49 2.01 1.54 0.83 0.58 0.39
wB 0.229 0.229 0.229 0.229 0.229 0.229
T/K 348.33 370.51 372.95 376.66 379.86 384.97
P/MPa 0.26 0.55 0.69 0.97 1.23 1.72

wB 0.101 0.101 0.101 0.101 0.101 0.101 0.101 0.101 0.114
T/K 328.09 332.09 334.55 336.41 337.92 339.34 380.82 379.15 331.96
P/MPa 1.25 0.73 −0.25 −0.45 −0.52 −0.81 0.34 0.01 1.55
wB 0.114 0.114 0.114 0.114 0.114 0.114 0.114 0.114 0.123
T/K 334.66 337.41 340.13 342.71 378.77 380.57 371.78 374.31 332.14
P/MPa 0.85 0.64 −0.06 −0.13 0.58 0.70 0.24 0.29 0.79
wB 0.123 0.123 0.123 0.123 0.123 0.123 0.123 0.123 0.123
T/K 333.44 337.59 341.36 344.53 346.66 350.05 352.68 358.35 364.62
P/MPa 0.54 0.29 0.04 −0.005 −0.18 −0.11 −0.04 0.35 0.74
wB 0.123 0.131 0.131 0.131 0.131 0.131 0.131 0.131 0.131
T/K 368.55 334.51 339.31 343.41 345.83 351.16 356.50 358.36 363.62
P/MPa 1.06 1.65 1.11 0.68 0.48 −0.24 0.006 0.03 −0.04
continued
_____________________________________________________________________________
continued
wB 0.131 0.131 0.131 0.147 0.147 0.147 0.147 0.147 0.147
T/K 366.71 369.29 372.79 332.28 336.35 340.25 344.21 345.44 348.79
P/MPa 0.17 0.47 0.36 2.08 1.07 0.64 −0.16 0.51 0.47
wB 0.147 0.147 0.147 0.147 0.147 0.147 0.147 0.163 0.163
T/K 351.74 352.11 354.97 358.01 363.66 367.13 371.58 336.06 338.37
P/MPa 0.31 0.13 0.17 0.29 0.37 0.55 0.13 1.44 1.18
wB 0.163 0.163 0.163 0.163 0.163 0.163 0.163 0.163 0.194
T/K 341.10 345.26 347.69 352.92 358.34 362.11 366.28 368.08 337.28
P/MPa 0.74 0.47 0.41 0.19 0.15 0.21 0.40 0.46 1.44
wB 0.194 0.194 0.194 0.194 0.194 0.194 0.194 0.204 0.204
T/K 341.73 340.81 344.61 344.60 342.87 339.09 333.17 330.56 333.13
P/MPa 0.95 1.04 0.67 0.68 0.80 1.23 2.15 2.63 2.13
wB 0.204 0.204 0.204 0.204 0.204 0.204 0.204 0.204 0.204
T/K 333.13 338.53 341.31 346.48 349.67 355.46 358.33 362.83 365.49
P/MPa 2.14 1.32 0.95 0.53 0.36 0.20 0.19 0.28 0.39
wB 0.204 0.204 0.204 0.229 0.229 0.229 0.229 0.229 0.229
T/K 369.33 372.62 379.32 329.85 332.52 335.22 340.82 348.33 370.51
P/MPa 0.56 0.75 1.28 1.51 1.12 0.81 0.04 −0.32 −0.05
wB 0.229 0.229 0.229 0.229
T/K 372.95 376.66 379.86 384.97
P/MPa 0.02 0.26 0.42 0.69
Polymer (B): polystyrene-d8 1995LUS

completely deuterated, Polymer Laboratories, Amherst, MA

wB 0.219 0.219 0.219 0.219
T/K 266.69 267.22 268.05 268.78
P/MPa 2.61 2.03 1.22 0.47

−1 −1

wB 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.140 0.140
T/K 330.21 336.97 343.05 350.07 357.01 363.63 370.11 330.34 337.04
P/MPa 4.04 3.22 2.79 2.57 2.61 2.62 3.18 4.45 3.59
continued
_____________________________________________________________________________
continued
wB 0.140 0.140 0.140 0.140 0.140 0.150 0.150 0.150 0.150
T/K 343.20 350.05 356.97 363.50 369.96 330.76 337.14 343.16 350.01
P/MPa 3.12 2.87 2.66 3.07 3.40 4.52 3.70 3.22 2.96
wB 0.150 0.150 0.150 0.160 0.160 0.160 0.160 0.160 0.160
T/K 357.04 363.44 370.06 336.24 336.23 342.24 348.99 355.63 363.30
P/MPa 2.96 3.13 3.46 3.86 3.83 3.33 3.04 3.00 3.18
wB 0.160 0.170 0.170 0.170 0.170 0.170 0.170 0.185 0.185
T/K 369.95 337.45 343.67 350.09 356.66 363.67 370.10 329.96 336.98
P/MPa 3.51 3.67 3.30 3.05 3.05 3.23 3.57 4.04 3.23
wB 0.185 0.185 0.185 0.185 0.185 0.193 0.193 0.193 0.193
T/K 343.41 350.03 356.99 363.52 369.66 330.21 337.13 343.25 349.95
P/MPa 2.84 2.67 2.75 3.02 3.36 3.95 3.16 2.80 2.62
wB 0.193 0.193 0.193 0.205 0.205 0.205 0.205 0.205 0.205
T/K 357.07 363.73 370.00 357.26 363.67 370.07 329.97 336.99 343.12
P/MPa 2.71 2.93 3.32 2.65 2.89 3.27 3.86 3.11 2.73
wB 0.205 0.212 0.212 0.212 0.212 0.212 0.212 0.212 0.217
T/K 349.98 330.01 336.89 342.35 349.87 357.01 363.25 369.96 330.04
P/MPa 2.57 3.85 3.08 2.70 2.50 2.60 2.82 3.22 3.33
wB 0.217 0.217 0.217 0.217 0.217 0.217 0.225 0.225 0.225
T/K 337.00 343.13 350.01 357.16 363.54 370.02 329.98 336.89 342.98
P/MPa 2.83 2.57 2.47 2.55 2.79 3.18 3.59 2.85 2.51
wB 0.225 0.225 0.225 0.225 0.239 0.239 0.239 0.239 0.239
T/K 350.08 357.37 363.48 370.03 331.21 341.82 345.75 350.19 357.17
P/MPa 2.38 2.47 2.73 3.13 3.12 2.33 2.22 2.21 2.31
wB 0.239 0.239 0.259 0.259 0.259 0.259 0.259 0.259 0.259
T/K 363.37 369.78 337.02 340.82 347.67 352.05 358.22 363.07 368.57
P/MPa 2.56 2.97 1.86 1.69 1.54 1.58 1.79 2.05 2.41

wB 0.140 0.140 0.140 0.140 0.140 0.150 0.150 0.150 0.150
T/K 330.34 337.04 343.20 363.50 369.96 330.76 337.14 343.16 350.01
P/MPa 4.17 3.26 2.69 2.79 3.11 4.29 3.50 3.01 2.66
wB 0.150 0.150 0.150 0.160 0.160 0.160 0.160 0.160 0.160
T/K 357.04 363.44 370.06 336.24 336.23 342.24 348.99 355.63 363.30
P/MPa 2.82 2.99 3.29 3.55 3.64 3.22 2.90 2.67 3.05
wB 0.160 0.170 0.170 0.170 0.170 0.170 0.170 0.185 0.185
T/K 369.95 337.45 343.67 350.09 356.66 363.67 370.10 329.96 336.98
P/MPa 3.39 3.43 3.04 2.64 2.63 3.07 3.37 3.83 3.04
wB 0.185 0.185 0.185 0.185 0.185 0.193 0.193 0.193 0.193
T/K 343.41 350.03 356.99 363.52 369.66 330.21 337.13 343.25 349.95
P/MPa 2.65 2.52 2.56 2.76 3.18 3.81 3.06 2.66 2.52
wB 0.193 0.193 0.193 0.205 0.205 0.205 0.205 0.205 0.205
T/K 357.07 363.73 370.00 357.26 363.67 370.07 329.97 336.99 343.12
P/MPa 2.59 2.85 3.21 2.51 2.78 3.17 3.75 2.98 2.61
continued
_____________________________________________________________________________
continued
wB 0.205 0.212 0.212 0.212 0.212 0.212 0.212 0.212 0.217
T/K 349.98 330.01 336.89 342.35 349.87 357.01 363.25 369.96 330.04
P/MPa 2.43 3.66 2.91 2.56 2.40 2.43 2.70 3.06 3.15
wB 0.217 0.217 0.217 0.217 0.217 0.225 0.225 0.225 0.225
T/K 337.00 350.01 357.16 363.54 370.02 329.98 342.98 350.08 357.37
P/MPa 2.60 2.23 2.39 2.59 3.07 3.23 2.17 2.01 2.18
wB 0.225 0.225 0.239 0.239 0.239 0.239 0.239
T/K 363.48 370.03 331.21 341.82 357.17 363.37 369.78
P/MPa 2.55 2.88 2.68 1.89 1.88 2.12 2.60
Polymer (B): polystyrene 1972ZE2

Characterization: Mw/kg.mol−1 = 51, Mw/Mn < 1.1,
Solvent (A): methyl acetate C3H6O2 79-20-9
T/K = 423.35 wB = 0.023 − 0.024 (dT/dP)P=1/K.bar−1 = +0.47 (LCST behavior)

Characterization: Mw/kg.mol−1 = 97.2, Mw/Mn < 1.1,
T/K = 275.15 wB = 0.023 − 0.024 (dT/dP)P=1/K.bar−1 = −0.018 (UCST behavior)



_____________________________________________________________________________








wB 0.092 0.140
T/K 293 294
(dT/dP)P=0/K.MPa−1 −0.22 −0.26
Polymer (B): polystyrene 1993HOS

continued
_____________________________________________________________________________
continued
T/K 285.72 285.58 285.29 285.00 284.58 284.38 284.06 283.92 283.80
P/MPa 0.10 1.18 3.43 6.28 11.28 14.51 19.91 24.61 28.83
T/K 283.73 283.70 283.73 283.83 283.93 284.03 284.16 284.30 284.48
P/MPa 34.32 40.31 45.11 50.50 55.31 59.53 63.84 67.86 72.37
T/K 284.65 284.83 285.03
P/MPa 76.59 80.41 84.93
critical double point: Tdcrit/K = 283.71 Pdcrit/MPa = 38.3


wB 0.0786 0.0786 0.0786 0.0786 0.0786 0.0786 0.0786 0.0786 0.0786
T/K 295.69 295.37 295.05 294.75 294.47 294.17 293.91 293.63 293.24
P/MPa 0.10 1.86 3.82 5.79 7.55 9.81 11.96 14.32 18.93
wB 0.0786 0.0786 0.0786 0.0786 0.0786 0.0786 0.0786 0.0786 0.0786
T/K 293.03 292.82 292.65 292.51 292.38 292.32 292.30 292.33 292.39
P/MPa 21.97 25.20 28.93 33.05 38.15 43.44 49.13 53.64 58.15
wB 0.0786 0.0786 0.0786 0.0786 0.0998 0.0998 0.0998 0.0998 0.0998
T/K 292.45 292.55 292.73 292.88 296.05 294.96 294.55 294.28 294.08
P/MPa 63.06 67.67 72.86 77.47 0.10 6.67 9.32 11.57 13.53
wB 0.0998 0.0998 0.0998 0.0998 0.0998 0.0998 0.0998 0.0998 0.0998
T/K 293.82 293.54 293.30 293.11 292.81 292.67 292.60 292.53 292.55
P/MPa 15.98 18.93 22.56 27.36 32.75 37.27 42.66 48.05 52.86
wB 0.0998 0.0998 0.0998 0.0998 0.0998 0.0998 0.0998 0.1287 0.1287
T/K 292.63 292.68 292.81 292.95 293.13 293.35 293.51 296.32 295.17
P/MPa 57.86 62.27 67.27 72.77 77.57 83.55 87.28 0.10 6.86
wB 0.1287 0.1287 0.1287 0.1287 0.1287 0.1287 0.1287 0.1287 0.1287
T/K 294.90 294.58 294.47 294.10 293.89 293.59 293.42 293.20 293.03
P/MPa 8.83 10.98 12.75 15.30 17.85 21.57 24.61 28.24 32.36
wB 0.1287 0.1287 0.1287 0.1287 0.1287 0.1287 0.1287 0.1287 0.1287
T/K 292.92 292.83 292.78 292.78 292.81 292.89 292.96 293.10 293.24
P/MPa 36.48 41.48 46.78 51.68 56.29 60.90 65.51 70.41 74.73
wB 0.1287 0.1721 0.1721 0.1721 0.1721 0.1721 0.1721 0.1721 0.1721
T/K 293.34 296.21 295.91 295.44 295.12 294.85 294.47 294.12 293.88
P/MPa 78.26 0.10 1.86 4.22 6.47 8.53 11.57 14.12 16.87
continued
_____________________________________________________________________________
continued
wB 0.1721 0.1721 0.1721 0.1721 0.1721 0.1721 0.1721 0.1721 0.1721
T/K 293.67 293.43 293.23 293.05 292.89 292.78 292.70 292.68 292.68
P/MPa 19.42 22.36 25.99 29.62 33.44 37.76 42.46 47.27 51.78
wB 0.1721 0.1721 0.1721 0.1721 0.1721 0.1721 0.2044 0.2044 0.2044
T/K 292.72 292.78 292.85 292.95 293.07 293.21 296.27 295.92 295.48
P/MPa 56.19 60.61 64.82 68.84 72.96 77.28 0.10 1.77 4.31
wB 0.2044 0.2044 0.2044 0.2044 0.2044 0.2044 0.2044 0.2044 0.2044
T/K 295.25 294.96 294.70 294.40 294.13 293.90 293.68 293.44 293.16
P/MPa 5.88 7.85 9.81 12.26 14.51 16.77 19.61 22.85 27.16
wB 0.2044 0.2044 0.2044 0.2044 0.2044 0.2044 0.2044 0.2044 0.2044
T/K 293.02 292.85 292.77 292.70 292.70 292.75 292.81 292.92 293.05
P/MPa 31.19 35.79 40.70 46.29 51.78 56.88 61.78 66.69 71.78
wB 0.2044 0.2044 0.2044 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461
T/K 293.20 293.35 293.51 295.79 294.57 294.23 294.00 293.73 293.47
P/MPa 76.49 81.20 86.00 0.10 7.06 9.12 11.38 13.73 15.98
wB 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461
T/K 293.22 292.95 292.68 292.52 292.35 292.24 292.16 292.20 292.20
P/MPa 18.83 22.85 27.07 31.97 36.19 41.78 48.44 49.03 53.84
wB 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2461 0.2952 0.2952
T/K 292.25 292.35 292.45 292.57 292.74 292.87 293.03 294.79 293.70
P/MPa 58.55 63.74 68.65 73.55 78.16 82.08 85.51 0.10 6.57
wB 0.2952 0.2952 0.2952 0.2952 0.2952 0.2952 0.2952 0.2952 0.2952
T/K 293.42 293.20 292.93 292.70 292.44 292.23 291.95 291.73 291.55
P/MPa 8.53 10.59 12.75 15.20 18.24 21.28 25.60 30.60 35.50
wB 0.2952 0.2952 0.2952 0.2952 0.2952 0.2952 0.2952 0.2952 0.2952
T/K 291.45 291.40 291.40 291.45 291.53 291.65 291.78 291.92 292.13
P/MPa 40.40 45.50 50.41 54.92 61.78 66.78 71.69 75.90 81.49

Characterization: Mn/kg.mol−1 = 33, Mw/kg.mol−1 = 34.9,

T/K 308.87 308.48 308.10 307.80 307.44 307.08 306.73 306.33 305.86
P/MPa 0.10 1.27 2.65 3.82 5.20 6.67 8.24 9.90 12.36
T/K 305.51 305.23 304.77 304.53 304.22 303.90 303.58 303.25 302.97
P/MPa 14.42 16.38 19.61 21.97 24.42 27.65 31.77 36.68 43.44
T/K 302.76 302.71 302.71 302.81 302.91 303.05 303.25
P/MPa 51.39 58.94 65.51 72.37 78.36 84.53 90.61
_____________________________________________________________________________
Polymer (B): polystyrene 1993WEL

Characterization: Mn/kg.mol−1 = 21.4, Mw/kg.mol−1 = 22.0
Type of data: spinodal points (UCST behavior)

wB 0.055 0.055 0.055 0.055 0.055 0.055 0.055 0.055 0.055
T/K 298.20 297.99 297.39 297.11 296.64 296.24 295.75 295.41 294.93
P/bar 5.42 9.64 43.97 62.05 90.96 120.48 160.84 195.78 253.61
wB 0.055 0.055 0.055 0.055 0.055 0.094 0.094 0.094 0.094
T/K 294.61 294.34 294.29 294.32 294.51 300.25 299.75 299.45 299.05
P/bar 315.66 402.41 481.32 551.81 682.53 18.07 39.76 56.63 80.12
wB 0.094 0.094 0.094 0.094 0.094 0.094 0.094 0.094 0.094
T/K 298.68 298.35 298.02 297.53 297.08 296.86 296.68 296.13 296.17
P/bar 100.60 124.70 146.38 152.41 239.15 283.13 304.22 509.04 653.61
wB 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
T/K 301.09 300.76 300.47 300.09 300.13 299.42 298.93 298.41 298.39
P/bar 24.10 28.31 42.17 62.05 63.25 100.00 134.94 184.34 189.16
wB 0.200 0.200 0.200 0.200 0.200
T/K 297.74 297.34 297.09 296.89 297.04
P/bar 256.63 333.73 424.70 533.73 680.12
critical point: wB, crit = 0.200 and Tcrit/K = 300.85 at P/bar = 1.
Polymer (B): polystyrene 1994VA1


wB 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15
T/K 296.751 296.044 295.337 294.739 294.433 294.200 293.892 293.953 294.203
P/bar 48.54 90.14 144.85 210.13 249.33 309.56 385.50 638.82 743.95
wB 0.15 0.27 0.27 0.27 0.27 0.27 0.27 0.27 0.27
T/K 294.490 296.418 295.687 295.080 294.603 294.257 293.944 293.603 293.653
P/bar 828.10 53.06 98.49 151.24 201.30 249.66 306.13 428.80 645.79
wB 0.27 0.27 0.30 0.30 0.30 0.30 0.30 0.30 0.30
T/K 293.944 294.323 296.448 295.705 294.949 294.449 293.935 293.690 293.492
P/bar 758.94 857.25 37.87 76.82 134.13 185.03 252.98 311.90 377.40
wB 0.30 0.30 0.30 0.09374 0.12389 0.15492 0.18487 0.21412 0.23366
T/K 293.444 293.694 294.041 295.053 295.673 295.885 295.925 295.954 295.915
P/bar 620.16 726.60 822.60 100 100 100 100 100 100
wB 0.24524 0.27350 0.30267 0.09374 0.12389 0.15492 0.18487 0.21412 0.23366
T/K 295.822 295.623 295.406 294.014 294.675 294.853 294.871 294.882 294.857
P/bar 100 100 100 200 200 200 200 200 200
continued
_____________________________________________________________________________
continued
wB 0.24524 0.15492 0.18487 0.21412 0.23366 0.24524 0.15492 0.18487 0.21412
T/K 294.727 294.853 294.871 294.882 294.857 294.727 294.853 294.871 294.882
P/bar 200 200 200 200 200 200 200 200 200
wB 0.23366 0.24524 0.18487 0.21412 0.23366 0.24524 0.27350 0.30267 0.09111
T/K 294.857 294.727 293.915 293.928 293.912 293.804 293.631 293.425 293.105
P/bar 200 200 400 400 400 400 400 400 500
wB 0.12100 0.14958 0.17954 0.20815 0.23883 0.26815 0.29882 0.09374 0.12389
T/K 293.615 293.800 293.844 293.846 293.717 293.556 293.417 293.409 293.890
P/bar 500 500 500 500 500 500 500 700 700
wB 0.15492 0.18487 0.21412 0.23366 0.24524 0.27350 0.30267 0.09374 0.12389
T/K 294.039 294.045 294.059 294.031 293.991 293.792 293.578 293.726 294.200
P/bar 700 700 700 700 700 700 700 800 800
wB 0.15492 0.18487 0.21412 0.23366 0.24524 0.27350 0.30267 0.09208 0.12272
T/K 294.353 294.344 294.362 294.330 294.223 294.117 293.944 293.744 294.234
P/bar 800 800 800 800 800 800 800 800 800
wB 0.18131 0.23075 0.24135 0.27272 0.30123 0.14889 0.20957
T/K 294.393 294.366 294.249 294.137 293.969 294.389 294.402
P/bar 800 800 800 800 800 800 800

wB 0.120 0.120 0.120 0.120 0.121 0.121 0.121 0.121 0.121
T/K 293.950 292.858 293.510 293.950 295.762 293.850 293.750 293.850 293.950
P/bar 173.70 500.00 800.00 896.52 1.00 190.05 854.92 876.42 895.35
wB 0.148 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
T/K 294.025 297.026 296.753 296.046 294.742 294.192 293.950 293.910 293.750
P/bar 800.00 1.00 15.73 50.77 155.01 229.50 278.00 283.15 317.31
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.151 0.151
T/K 293.465 293.750 293.935 293.950 294.198 294.487 295.352 293.850 293.850
P/bar 500.00 710.59 767.42 779.15 855.49 896.34 989.29 305.54 737.38
wB 0.151 0.178 0.180 0.180 0.180 0.181 0.181 0.181 0.181
T/K 293.950 297.536 293.950 293.758 293.950 293.950 293.850 293.850 293.950
P/bar 777.24 1.00 361.10 500.00 656.00 365.40 423.39 594.39 657.92
wB 0.181 0.198 0.210 0.210 0.210 0.210 0.210 0.210 0.230
T/K 294.307 293.750 297.656 293.950 293.850 293.856 293.850 293.950 293.950
P/bar 800.00 198.38 1.00 382.00 496.32 500.00 545.18 645.00 378.36
wB 0.230 0.230 0.230 0.240 0.240 0.240 0.240 0.240 0.240
T/K 293.850 293.850 293.950 293.950 293.950 293.850 293.750 293.717 293.750
P/bar 438.57 603.26 656.78 339.77 343.30 384.87 448.77 500.00 595.03
wB 0.240 0.240 0.240 0.268 0.268 0.268 0.269 0.269 0.269
T/K 293.850 293.950 293.950 293.750 293.362 293.750 293.950 293.950 293.850
P/bar 664.64 702.90 705.41 294.68 500.00 763.80 258.52 260.73 789.57
wB 0.269 0.270 0.270 0.270 0.270 0.270 0.270 0.270 0.270
T/K 293.950 296.398 295.693 295.070 294.605 294.276 293.953 293.850 293.658
P/bar 823.87 35.94 81.43 130.13 177.20 222.59 255.95 286.81 733.15
continued
_____________________________________________________________________________
continued
wB 0.270 0.270 0.270 0.270 0.271 0.300 0.300 0.300 0.300
T/K 293.874 293.950 293.923 294.325 296.981 296.200 295.707 294.939 294.403
P/bar 800.00 820.69 830.18 904.40 1.00 1.00 32.20 86.88 129.89
wB 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
T/K 293.952 293.950 293.850 293.707 293.750 293.498 292.920 293.442 293.459
P/bar 169.00 181.00 194.26 202.98 203.43 264.54 500.00 800.00 807.83
wB 0.300 0.300 0.300 0.300
T/K 293.750 293.746 293.850 293.950
P/bar 880.57 893.29 903.48 925.00
Type of data: cloud points (hour glass shaped)

T/K = 293.75
wB 0.09346 0.12511 0.12575 0.09717 0.30657 0.27626 0.24389 0.27265 0.30324
P/bar 242.30 390.04 628.77 807.35 750.55 691.49 458.09 366.24 307.93

T/K = 293.75
wB 0.09047 0.12062 0.12013 0.08932 0.29871 0.26886 0.23907 0.26842 0.29852
P/bar 797.75 617.66 379.31 237.63 298.77 358.60 448.76 678.21 739.72

T/K = 293.85
wB 0.09098 0.12146 0.15103 0.18096 0.18206 0.15130 0.12167 0.09115 0.29925
P/bar 829.50 672.32 608.93 530.56 501.39 433.99 346.08 225.87 280.15
wB 0.26965 0.23964 0.23028 0.21022 0.20997 0.23038 0.23969 0.26923 0.29875
P/bar 333.30 384.09 437.78 497.12 544.41 604.05 664.62 723.37 774.25
Type of data: cloud points (LCP and UCP branch)

T/K = 293.95
wB 0.09764 0.12742 0.15562 0.18612 0.21626 0.23594 0.24565 0.27551 0.30541
P/bar 867.74 722.59 667.50 646.92 650.97 664.81 712.02 761.05 803.69
wB 0.09764 0.12742 0.15562 0.18612 0.21626 0.23594 0.24565 0.27551 0.30541
P/bar 215.73 322.72 373.59 391.89 395.86 386.19 346.92 310.12 265.02

T/K = 293.95
wB 0.09048 0.12000 0.15048 0.18044 0.20992 0.22902 0.23962 0.26936 0.29906
P/bar 851.13 717.32 658.03 639.52 635.14 655.21 703.69 754.97 821.17
wB 0.09048 0.12000 0.15048 0.18044 0.20992 0.22902 0.23962 0.26936 0.29906
P/bar 207.21 314.20 365.48 383.05 383.37 376.80 339.77 304.79 258.84
continued
_____________________________________________________________________________
continued
T/K = 293.95
wB 0.09071 0.12052 0.15092 0.18080 0.21015 0.24062 0.27109 0.29993
P/bar 852.80 719.97 658.02 642.46 637.21 704.12 758.15 822.49
wB 0.09071 0.12052 0.15092 0.18080 0.21015 0.24062 0.27109
P/bar 208.48 316.63 366.78 386.02 384.63 342.01 304.55

T/K = 294.15
wB 0.09764 0.12742 0.15562 0.18612 0.21626 0.23594 0.24565 0.27551 0.30541
P/bar 907.31 784.78 745.01 734.67 733.53 739.27 775.31 812.97 852.68
wB 0.09764 0.12742 0.15562 0.18612 0.21626 0.23594 0.24565 0.27551 0.30541
P/bar 189.20 279.93 314.50 324.57 326.57 317.03 293.78 270.23 232.38

T/K = 294.35
wB 0.09764 0.12742 0.15562 0.18612 0.21626 0.23594 0.24565 0.27551 0.30541
P/bar 955.28 842.03 805.16 802.03 797.84 804.64 831.39 859.88 891.35
wB 0.09764 0.12742 0.15562 0.18612 0.21626 0.23594 0.24565 0.27551 0.30541
P/bar 161.74 246.23 274.68 280.64 282.68 276.23 257.06 235.71 204.83
Type of data: cloud points (UCP behavior)

T/K = 295.15
wB 0.09764 0.12742 0.15562 0.18612 0.21626 0.23594 0.24565 0.27551 0.30541
P/bar 92.17 151.23 168.52 172.56 176.52 168.00 160.15 141.73 122.22
Type of data: cloud points (UCP behavior)

T/K = 296.55
wB 0.09764 0.12742 0.15562 0.18612 0.21626 0.23594 0.24565 0.27551 0.30541
P/bar 11.69 44.21 59.46 62.41 66.45 62.94 57.16 40.75 32.56
Polymer (B): polystyrene 1997END

Type of data: cloud points (UCST behavior, measured by PPICS)

wB 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067
T/K 331.18 330.54 330.06 329.47 329.02 328.57 328.04 327.23 326.43
P/bar 17.71 19.64 20.60 23.92 30.00 37.97 47.02 60.22 74.35
continued
_____________________________________________________________________________
continued
wB 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067
T/K 325.95 325.50 325.04 324.51 323.82 323.12 322.63 322.29 321.79
P/bar 84.72 92.67 108.28 122.42 143.15 160.12 174.25 187.45 211.95
wB 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067
T/K 321.47 321.04 320.61 320.33 319.54 319.01 318.41 318.05 317.24
P/bar 225.15 243.05 270.39 297.72 331.65 362.75 393.85 417.41 462.65
wB 0.018 0.018 0.018 0.018 0.018 0.018 0.018 0.018 0.018
T/K 331.16 330.65 330.05 329.58 329.25 328.78 328.10 327.56 326.81
P/bar 12.55 13.26 19.64 29.31 36.41 44.64 55.16 66.85 82.16
wB 0.018 0.018 0.018 0.018 0.018 0.018 0.018 0.018 0.018
T/K 326.02 324.96 324.09 323.36 322.98 322.23 321.65 321.15 320.48
P/bar 101.19 127.38 157.74 181.35 196.63 217.61 247.92 269.92 294.99
wB 0.018 0.018 0.018 0.018 0.018 0.025 0.025 0.025 0.025
T/K 320.00 319.12 318.54 317.64 317.11 331.38 330.80 330.13 329.50
P/bar 325.99 356.25 386.56 426.54 456.84 11.57 18.18 29.14 40.89
wB 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025
T/K 329.02 328.49 327.67 326.99 326.37 325.88 325.40 324.94 324.17
P/bar 45.25 52.50 73.34 80.95 99.21 115.74 123.63 145.09 169.36
wB 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025
T/K 323.41 322.93 322.39 321.68 321.01 320.40 320.13 319.70 319.48
P/bar 182.49 196.35 223.73 253.42 279.26 300.20 312.85 337.30 346.84
wB 0.025 0.025 0.025 0.025 0.025 0.025 0.0458 0.0458 0.0458
T/K 319.13 318.62 318.16 317.74 317.09 316.18 331.22 330.73 330.33
P/bar 364.87 393.05 414.95 442.06 490.77 592.86 27.39 34.03 38.51
wB 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458
T/K 329.71 329.35 328.60 328.51 327.92 327.41 326.85 326.17 325.63
P/bar 51.45 61.25 71.41 73.00 87.75 102.49 117.62 137.17 152.61
wB 0.0458 0.0458 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482
T/K 325.23 324.84 332.61 332.11 331.63 331.26 330.98 330.23 329.49
P/bar 160.12 170.49 9.84 14.09 19.33 27.87 30.81 44.51 57.70
wB 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482
T/K 328.66 328.30 327.77 327.44 326.98 326.50 325.87 324.89 324.44
P/bar 73.68 84.18 91.10 112.05 126.19 139.38 153.52 174.26 194.05
wB 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482
T/K 324.26 323.40 322.92 322.45 322.18 321.59 320.96 320.52 320.22
P/bar 201.59 218.55 235.52 256.06 273.62 299.65 329.25 354.85 376.00
wB 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482
T/K 320.15 319.94 319.41 318.92 318.51 317.96 317.53 317.11 316.94
P/bar 373.11 388.53 410.81 435.32 459.50 500.35 558.78 613.44 658.68
wB 0.0482 0.0482 0.0482 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682
T/K 316.84 316.79 316.68 331.79 331.34 330.90 329.89 329.11 328.22
P/bar 692.61 719.94 754.81 19.69 19.69 29.12 49.85 57.39 78.12
continued
_____________________________________________________________________________
continued
wB 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682
T/K 327.73 327.41 326.45 325.90 325.30 324.79 324.12 323.57 323.25
P/bar 84.72 91.32 126.19 143.15 163.89 177.08 197.82 209.13 218.55
wB 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682
T/K 322.50 321.92 321.43 321.06 320.52 319.85 319.35 318.93 318.40
P/bar 243.05 273.21 293.95 318.45 352.38 376.88 409.40 439.80 478.50
wB 0.0682 0.0682
T/K 318.12 317.82
P/bar 517.31 551.88
Type of data: spinodal points (UCST behavior, measured by PPICS)

wB 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067
T/K 331.18 330.54 330.06 329.47 329.02 328.57 328.04 327.23 326.43
P/bar 2.93 4.02 2.60 5.92 12.00 19.97 29.02 42.22 56.35
wB 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067
T/K 325.95 325.50 325.04 324.51 323.82 323.12 322.63 322.29 321.79
P/bar 66.72 74.67 90.28 104.42 125.15 142.12 156.26 169.45 193.95
wB 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067
T/K 321.47 321.04 320.61 320.33 319.54 319.01 318.41 318.05 317.24
P/bar 209.18 225.06 252.39 277.93 313.65 342.31 375.85 399.41 444.65
wB 0.018 0.018 0.018 0.018 0.018 0.018 0.018 0.018 0.018
T/K 331.16 330.65 330.05 329.58 329.25 328.78 328.10 327.56 326.81
P/bar 2.38 5.13 11.66 18.20 26.93 32.94 44.94 58.03 70.04
wB 0.018 0.018 0.018 0.018 0.018 0.018 0.018 0.018 0.018
T/K 326.02 324.96 324.09 323.36 322.98 322.23 321.65 321.15 320.48
P/bar 91.32 115.33 150.25 169.89 184.08 204.81 237.31 252.28 276.29
wB 0.018 0.018 0.018 0.018 0.018 0.025 0.025 0.025 0.025
T/K 320.00 319.12 318.54 317.64 317.11 331.38 330.80 330.13 329.50
P/bar 306.84 327.38 361.96 408.50 441.62 4.86 10.42 20.83 32.64
wB 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025
T/K 329.02 328.49 327.67 326.99 326.37 325.88 325.40 324.94 324.17
P/bar 38.19 42.36 65.28 72.92 93.05 107.64 113.89 138.19 158.33
wB 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025
T/K 323.41 322.93 322.39 321.68 321.01 320.40 320.13 319.70 319.48
P/bar 165.11 188.69 214.13 229.58 271.75 288.89 302.00 325.00 333.33
wB 0.025 0.025 0.025 0.025 0.025 0.025 0.0458 0.0458 0.0458
T/K 319.13 318.62 318.16 317.74 317.09 316.18 331.22 330.73 330.33
P/bar 352.08 382.64 403.47 431.81 477.78 578.47 21.99 26.95 32.92
wB 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458
T/K 329.71 329.35 328.60 328.51 327.92 327.41 326.85 326.17 325.63
P/bar 46.25 55.72 66.36 68.09 82.72 97.20 112.07 130.72 146.59
wB 0.0458 0.0458 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482
T/K 325.23 324.84 332.61 332.11 331.63 331.26 330.98 330.23 329.49
P/bar 153.54 164.65 8.61 9.13 13.09 23.02 25.00 43.19 56.00
continued
_____________________________________________________________________________
continued
wB 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482
T/K 328.66 328.30 327.77 327.44 326.98 326.50 325.87 324.89 324.44
P/bar 72.14 83.06 89.37 107.34 120.24 134.13 149.01 167.86 184.72
wB 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482
T/K 324.26 323.40 322.92 322.45 322.18 321.59 320.96 320.52 320.22
P/bar 193.65 212.5 228.37 252.82 271.57 297.84 325.89 350.68 371.23
wB 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482 0.0482
T/K 320.15 319.94 319.41 318.92 318.51 317.96 317.53 317.11 316.94
P/bar 365.28 385.73 400.99 427.78 457.89 493.25 551.79 605.36 646.63
wB 0.0482 0.0482 0.0482 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682
T/K 316.84 316.79 316.68 331.79 331.34 330.90 329.89 329.11 328.22
P/bar 682.74 711.51 746.23 15.77 17.06 24.80 46.73 54.46 74.45
wB 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682
T/K 327.73 327.41 326.45 325.90 325.30 324.79 324.12 323.57 323.25
P/bar 82.19 86.06 123.46 138.29 159.35 174.40 193.75 204.07 213.74
wB 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682 0.0682
T/K 322.50 321.92 321.43 321.06 320.52 319.85 319.35 318.93 318.40
P/bar 239.53 268.55 291.12 313.69 349.16 374.30 405.26 436.85 472.97
wB 0.0682 0.0682
T/K 318.12 317.82
P/bar 514.24 549.06

wB 0.011 0.011 0.011 0.011 0.011 0.011 0.011 0.011 0.011
T/K 330.17 329.93 329.88 329.57 329.38 329.30 329.00 328.84 328.77
P/bar 7.0 12.0 13.2 19.2 23.0 24.2 30.6 33.6 35.3
wB 0.011 0.011 0.011 0.011 0.011 0.011 0.011 0.011 0.011
T/K 328.49 328.37 328.26 327.96 327.80 327.67 327.39 327.32 327.03
P/bar 40.8 43.5 45.8 51.6 55.3 57.7 64.2 65.6 71.3
wB 0.011 0.011 0.011 0.011 0.011 0.011 0.011 0.011 0.011
T/K 326.71 326.67 326.62 326.47 326.38 326.17 326.15 326.09 325.97
P/bar 78.8 79.8 81.0 84.0 86.0 90.8 91.3 92.5 95.0
wB 0.011 0.060 0.060 0.060 0.060 0.060 0.060 0.060 0.060
T/K 325.63 331.66 331.47 331.28 331.09 330.91 330.71 330.50 330.30
P/bar 103.3 23.0 26.0 28.4 31.8 34.4 37.6 41.1 44.6
wB 0.060 0.060 0.060 0.060 0.060 0.060 0.060 0.060 0.060
T/K 330.09 329.96 329.72 329.51 329.30 329.13 328.94 328.78 328.52
P/bar 48.3 50.5 55.0 58.7 62.7 66.2 70.1 73.3 78.5
wB 0.060 0.060 0.060 0.060 0.060 0.060 0.060 0.120 0.120
T/K 328.29 328.11 327.90 327.74 327.52 327.31 327.12 329.96 329.76
P/bar 83.7 87.5 92.4 96.0 101.0 106.5 111.0 11.6 14.8
wB 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.120
T/K 329.55 329.35 329.14 328.94 328.75 328.56 328.35 328.16 327.97
P/bar 17.7 21.0 24.3 28.0 31.0 34.3 38.3 42.3 45.8
continued
_____________________________________________________________________________
continued
wB 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.120
T/K 327.75 327.57 327.38 327.19 326.98 326.79 326.57 326.39 326.16
P/bar 51.0 54.7 58.8 63.2 68.0 72.5 78.0 82.3 88.5
wB 0.120 0.120 0.187 0.187 0.187 0.187 0.187 0.187 0.187
T/K 325.98 325.78 327.54 327.33 327.12 326.92 326.73 326.55 326.35
P/bar 93.6 99.0 10.1 13.2 17.0 19.7 23.3 27.0 31.0
wB 0.187 0.187 0.187 0.187 0.187 0.187 0.187 0.187 0.187
T/K 326.15 325.97 325.75 325.55 325.34 325.14 324.94 324.78 324.58
P/bar 35.1 39.5 44.5 49.6 54.8 60.2 66.0 71.0 77.0
wB 0.187 0.187 0.187
T/K 324.35 324.13 323.91
P/bar 84.0 91.0 99.0

wB 0.065 0.065 0.065 0.065 0.065 0.065 0.065 0.065 0.065
T/K 499.45 502.12 504.64 507.12 509.61 512.10 514.59 517.04 519.50
P/bar 18.0 21.2 24.5 27.5 30.6 33.6 37.05 39.8 42.9
wB 0.187 0.187 0.187 0.187 0.187 0.187 0.187
T/K 503.80 506.47 508.41 511.16 513.88 516.08 518.85
P/bar 13.2 16.1 18.4 21.7 24.7 27.6 30.8

wB 0.0113 0.0516 0.0600 0.0655 0.0989 0.1207 0.1520 0.18699
T/K 500.92 495.35 493.67 493.90 492.92 496.35 498.78 502.30
P/bar 12.78 11.47 10.81 10.77 9.82 10.68 10.84 11.29
Polymer (B): polystyrene 1998KOA

wB 0.0323 0.0323 0.0323 0.0323 0.0323 0.0323 0.0323 0.0494 0.0494
T/K 299.38 298.99 298.58 298.25 297.92 297.60 297.14 301.30 301.01
P/MPa 1.05 3.05 5.05 7.05 9.05 11.05 13.05 1.05 2.05
wB 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494
T/K 300.78 300.60 300.41 300.22 300.03 299.85 299.68 299.50 299.19
P/MPa 3.05 4.05 5.05 6.05 7.05 8.05 9.05 10.05 12.05
wB 0.0494 0.0726 0.0726 0.0726 0.0726 0.0726 0.0726 0.0726 0.0726
T/K 298.95 302.53 302.29 302.04 301.82 301.61 301.41 301.25 301.05
P/MPa 14.05 1.05 2.05 3.05 4.05 5.05 6.05 7.05 8.05
wB 0.0726 0.0726 0.0726 0.0726 0.0882 0.0882 0.0882 0.0882 0.0882
T/K 300.88 300.73 300.42 300.13 303.46 303.39 302.93 302.72 302.47
P/MPa 9.05 10.05 12.05 14.05 1.05 2.05 3.05 4.05 5.05
continued
_____________________________________________________________________________
continued
wB 0.0882 0.0882 0.0882 0.0882 0.0882 0.0882 0.0882 0.1097 0.1097
T/K 302.37 302.10 301.90 301.79 301.52 301.24 300.90 304.05 303.48
P/MPa 6.05 7.05 8.05 9.05 10.05 12.05 14.05 1.05 3.05
wB 0.1097 0.1097 0.1097 0.1097 0.1097 0.1281 0.1281 0.1281 0.1281
T/K 303.06 302.69 302.25 301.88 301.52 304.44 303.88 303.45 302.97
P/MPa 5.05 7.05 9.05 11.05 13.05 1.05 3.05 5.05 7.05
wB 0.1281 0.1281 0.1281 0.1281 0.1519 0.1519 0.1519 0.1519 0.1519
T/K 302.56 302.24 301.93 301.68 305.03 304.44 304.00 303.53 303.11
P/MPa 9.05 11.05 13.05 14.05 1.05 3.05 5.05 7.05 9.05
wB 0.1519 0.1519 0.1519 0.1821 0.1821 0.1821 0.1821 0.2060 0.2060
T/K 302.62 302.35 302.17 305.45 304.41 304.00 303.53 305.42 304.95
P/MPa 11.05 13.05 14.05 1.05 5.05 7.05 9.05 1.05 3.05
wB 0.2060 0.2060 0.2060 0.2060 0.2060 0.2251 0.2251 0.2251 0.2251
T/K 304.53 303.89 303.52 303.15 302.80 305.43 304.96 304.35 303.91
P/MPa 5.05 7.05 9.05 11.05 13.05 1.05 3.05 5.05 7.05
wB 0.2251 0.2251 0.2251 0.2634 0.2634 0.2634 0.2634 0.2634 0.2634
T/K 303.45 303.08 302.75 305.03 304.44 303.90 303.51 303.02 302.70
P/MPa 9.05 11.05 13.05 1.05 3.05 5.05 7.05 9.05 11.05
wB 0.2634
T/K 302.32
P/MPa 13.05
Comments: Cloud points for mixtures of this system + carbon dioxide are given in Chapter 4.

Novacor Technology and Research Corporation

wB 0.0211 0.0211 0.0211 0.0211 0.0211 0.0211 0.0330 0.0330 0.0330
T/K 329.81 329.35 328.50 327.87 327.24 326.63 330.76 330.37 329.87
P/MPa 3.95 4.90 6.55 7.95 9.25 10.85 2.40 3.15 4.00
wB 0.0330 0.0330 0.0330 0.0330 0.0511 0.0511 0.0511 0.0511 0.0511
T/K 329.01 328.09 327.43 326.35 330.91 330.35 329.46 328.62 327.71
P/MPa 5.65 7.60 9.05 11.80 1.45 2.40 3.95 5.60 7.60
wB 0.0511 0.0511 0.0511 0.0648 0.0648 0.0648 0.0648 0.0648 0.0648
T/K 326.91 326.23 325.75 330.11 330.09 329.04 328.98 327.83 326.85
P/MPa 9.50 11.30 12.60 2.00 2.00 3.90 4.00 6.30 8.60
wB 0.0648 0.0648 0.0648 0.0971 0.0971 0.0971 0.0971 0.0971 0.0971
T/K 326.37 325.83 325.26 329.34 328.59 327.81 327.05 326.30 325.47
P/MPa 9.75 11.15 12.85 1.60 3.05 4.55 6.10 7.70 9.80
wB 0.0971 0.1360 0.1360 0.1360 0.1360 0.1360 0.1360 0.1360 0.1360
T/K 324.86 328.36 328.29 327.68 327.33 326.63 325.86 325.15 324.47
P/MPa 11.55 1.50 1.60 3.00 3.50 4.85 6.55 8.25 10.10
_____________________________________________________________________________

Solvent (A): methylcyclopentane C6H12 96-37-7

wB 0.181 0.181
T/K 259.49 259.62
P/MPa 3.70 1.30


wB 0.165 0.165 0.165 0.165 0.165
T/K 291.30 291.43 291.53 291.68 291.78
P/MPa 2.00 1.49 1.27 0.79 0.45

Polymer Laboratories, Amherst, MA

wB 0.153 0.153 0.153 0.153 0.153
T/K 299.99 300.12 300.33 300.57 300.75
P/MPa 2.59 2.24 1.64 1.02 0.51


wB 0.142 0.142 0.142 0.142 0.148 0.148 0.148 0.148 0.157
T/K 302.58 302.93 303.20 303.38 302.60 302.88 303.18 303.46 302.60
P/MPa 2.20 1.36 0.67 0.23 2.31 1.59 0.84 0.19 2.32
wB 0.157 0.157 0.157 0.164 0.164 0.164 0.164 0.164 0.165
T/K 302.87 303.24 303.44 302.53 302.76 302.98 303.19 303.43 302.64
P/MPa 1.67 0.77 0.32 2.90 2.25 1.67 1.15 0.55 2.33
continued
_____________________________________________________________________________
continued
wB 0.165 0.165 0.165 0.177 0.177 0.177 0.177 0.188 0.188
T/K 302.93 303.25 303.47 302.68 302.98 303.28 303.51 302.60 302.90
P/MPa 1.60 0.90 0.38 2.27 1.51 0.83 0.28 2.13 1.45
wB 0.188 0.188
T/K 303.16 303.41
P/MPa 0.84 0.26

wB 0.155 0.155 0.155 0.155 0.155
T/K 325.19 325.42 325.96 326.38 327.01
P/MPa 2.45 2.15 1.63 1.16 0.55

wB 0.179 0.179 0.179 0.179 0.179
T/K 302.48 302.90 303.11 303.20 303.39
P/MPa 2.52 1.51 0.95 0.70 0.23
Polymer (B): polystyrene 2000DE1

Solvent (A): nitroethane C2H5NO2 79-24-3
wB 0.3145 0.3145 0.3145 0.3145 0.3145 0.2867 0.2867 0.2867 0.2867
T/K 277.16 277.27 277.37 277.45 277.55 277.47 277.58 277.67 277.77
P/MPa 4.96 3.71 2.46 1.54 0.36 6.04 4.72 3.71 2.41
wB 0.2867 0.2867 0.2634 0.2634 0.2634 0.2634 0.2634 0.2634 0.2348
T/K 277.85 277.93 278.08 278.18 278.17 278.29 278.38 278.53 278.59
P/MPa 1.47 0.51 5.56 4.36 4.45 3.16 2.04 0.33 5.33
wB 0.2348 0.2348 0.2348 0.2348 0.2242 0.2242 0.2242 0.2242 0.2242
T/K 278.69 278.79 278.88 279.01 278.96 279.05 279.16 279.25 279.37
P/MPa 4.14 3.00 1.76 0.27 5.11 4.05 2.66 1.61 0.26
continued
_____________________________________________________________________________
continued
wB 0.2048 0.2048 0.2048 0.2048 0.2048 0.1799 0.1799 0.1799 0.1799
T/K 279.05 279.16 279.26 279.32 279.42 279.16 279.23 279.36 279.43
P/MPa 4.79 3.49 2.26 1.56 0.40 5.22 4.35 2.83 2.00
wB 0.1562 0.1562 0.1562 0.1562 0.1340 0.1340 0.1340 0.1340 0.1340
T/K 279.32 279.41 279.49 279.63 279.30 279.40 279.49 279.61 279.75
P/MPa 5.45 4.28 3.31 1.59 5.42 4.28 3.22 1.89 0.15
wB 0.1179 0.1179 0.1179 0.1801 0.1801 0.1801 0.1801 0.1801 0.1611
T/K 279.19 279.30 279.40 279.19 279.30 279.40 279.45 279.54 279.19
P/MPa 5.72 4.40 3.20 4.59 3.21 2.09 1.52 0.37 5.24
wB 0.1611 0.1611 0.1611 0.1611 0.1385 0.1385 0.1385 0.1385 0.1385
T/K 279.30 279.39 279.49 279.60 279.49 279.60 279.70 279.80 279.96
P/MPa 3.89 2.72 1.56 0.30 5.76 4.65 3.52 2.26 0.38
wB 0.1215 0.1215 0.1215 0.0999 0.0999 0.0999 0.0999 0.0999 0.0833
T/K 279.49 279.39 279.50 279.39 279.49 279.60 279.70 279.80 279.30
P/MPa 5.72 5.56 4.39 5.37 4.21 2.94 1.65 0.37 4.99
wB 0.0833 0.0833 0.0833 0.0833 0.0714 0.0714 0.0714 0.0714 0.0625
T/K 279.40 279.49 279.61 279.66 277.27 277.37 277.46 277.57 276.28
P/MPa 3.84 2.75 1.38 0.67 5.30 4.17 2.96 1.56 4.75
wB 0.0625 0.0625 0.0625
T/K 276.38 276.47 276.58
P/MPa 3.53 2.54 1.07

wB 0.3145 0.3145 0.3145 0.3145 0.3145 0.2867 0.2867 0.2867 0.2867
T/K 277.16 277.27 277.37 277.45 277.55 277.47 277.58 277.67 277.77
P/MPa 4.85 3.59 2.36 1.45 0.29 5.88 4.59 3.56 2.29
wB 0.2867 0.2867 0.2634 0.2634 0.2634 0.2634 0.2634 0.2634 0.2348
T/K 277.85 277.93 278.08 278.18 278.17 278.29 278.38 278.53 278.59
P/MPa 1.35 0.36 5.42 4.25 4.32 3.05 1.93 0.23 5.14
wB 0.2348 0.2348 0.2348 0.2348 0.2242 0.2242 0.2242 0.2242 0.2242
T/K 278.69 278.79 278.88 279.01 278.96 279.05 279.16 279.25 279.37
P/MPa 3.98 2.81 1.58 0.14 4.78 3.68 2.33 1.28 −0.01
wB 0.2048 0.2048 0.2048 0.2048 0.2048 0.1799 0.1799 0.1799 0.1799
T/K 279.05 279.16 279.26 279.32 279.42 279.16 279.23 279.36 279.43
P/MPa 4.44 3.12 1.95 1.25 0.10 5.04 4.12 2.61 1.78
wB 0.1562 0.1562 0.1562 0.1562 0.1340 0.1340 0.1340 0.1340 0.1340
T/K 279.32 279.41 279.49 279.63 279.30 279.40 279.49 279.61 279.75
P/MPa 5.18 4.05 3.14 1.39 5.19 4.05 3.00 1.62 −0.08
wB 0.1179 0.1179 0.1179 0.1801 0.1801 0.1801 0.1801 0.1801 0.1611
T/K 279.19 279.30 279.40 279.19 279.30 279.40 279.45 279.54 279.19
P/MPa 5.52 4.11 2.97 4.32 2.87 1.81 1.26 0.15 5.06
wB 0.1611 0.1611 0.1611 0.1611 0.1385 0.1385 0.1385 0.1385 0.1385
T/K 279.30 279.39 279.49 279.60 279.49 279.60 279.70 279.80 279.96
P/MPa 3.70 2.58 1.38 0.11 5.54 4.45 3.28 2.09 0.24
continued
_____________________________________________________________________________
continued
wB 0.1215 0.1215 0.1215 0.0999 0.0999 0.0999 0.0999 0.0999 0.0833
T/K 279.49 279.39 279.50 279.39 279.49 279.60 279.70 279.80 279.30
P/MPa 5.63 5.28 4.16 4.95 3.82 2.51 1.34 −0.02 4.47
wB 0.0833 0.0833 0.0833 0.0833 0.0714 0.0714 0.0714 0.0714 0.0625
T/K 279.40 279.49 279.61 279.66 277.27 277.37 277.46 277.57 276.28
P/MPa 3.25 2.27 0.99 0.19 4.92 3.81 2.66 1.27 4.51
wB 0.0625 0.0625 0.0625
T/K 276.38 276.47 276.58
P/MPa 3.22 0.80


wB 0.3649 0.3649 0.3649 0.3649 0.3649 0.1977 0.1977 0.1977 0.1977
T/K 289.05 289.10 289.15 289.26 289.42 296.25 296.44 296.55 296.65
P/MPa 4.49 4.02 3.67 2.84 1.66 5.29 3.70 3.17 2.57
wB 0.1977 0.1977 0.1977 0.1977 0.1654 0.1654 0.1654 0.1654 0.1654
T/K 296.79 296.88 296.95 296.98 296.65 296.74 296.84 297.04 297.24
P/MPa 1.57 1.03 0.66 0.48 4.90 4.35 3.64 2.39 1.22
wB 0.1654 0.1503 0.1503 0.1503 0.1503 0.1503 0.1503 0.1503 0.1503
T/K 297.35 296.65 296.74 296.84 297.05 297.24 297.35 297.45 297.49
P/MPa 0.49 5.64 5.05 4.44 3.08 1.90 1.26 0.63 0.34
wB 0.1503 0.1503 0.1393 0.1393 0.1393 0.1393 0.1393 0.1393 0.1393
T/K 297.54 297.54 296.61 296.66 296.77 296.98 297.05 297.15 297.25
P/MPa 0.13 0.05 4.83 4.49 3.80 2.41 1.94 1.36 0.76
wB 0.1393 0.1393 0.1388 0.1388 0.1388 0.1388 0.1388 0.1388 0.1388
T/K 297.30 297.35 296.65 296.75 296.95 297.05 297.15 297.24 297.35
P/MPa 0.46 0.12 4.93 4.32 3.09 2.45 1.82 1.22 0.56
wB 0.1388 0.1388 0.1126 0.1126 0.1126 0.1126 0.1126 0.1126 0.1126
T/K 297.40 297.43 296.48 296.58 296.65 296.86 296.96 297.05 297.10
P/MPa 0.30 0.10 5.25 4.62 4.17 2.72 2.18 1.59 1.28
wB 0.1126 0.1126 0.1126 0.0977 0.0977 0.0977 0.0977 0.0977 0.0977
T/K 297.17 297.25 297.27 296.33 296.44 296.55 296.74 296.89 297.00
P/MPa 0.79 0.39 0.23 4.79 4.16 3.46 2.21 1.26 0.57
wB 0.0977 0.0944 0.0944 0.0944 0.0944 0.0944 0.0944 0.0944 0.0944
T/K 297.06 296.24 296.36 296.46 296.67 296.73 296.86 296.92 296.99
P/MPa 0.14 5.17 4.39 3.75 2.43 1.98 1.22 0.84 0.43
wB 0.0944 0.0861 0.0861 0.0861 0.0861 0.0861 0.0861 0.0861 0.0861
T/K 297.02 296.06 296.17 296.25 296.45 296.64 296.79 296.81 296.87
P/MPa 0.23 5.33 4.62 3.98 2.74 1.56 0.53 0.44 0.04
continued
_____________________________________________________________________________
continued
wB 0.0727 0.0727 0.0727 0.0727 0.0727 0.0727 0.0622 0.0622 0.0622
T/K 295.57 295.65 295.75 295.95 296.16 296.25 294.89 294.95 295.08
P/MPa 4.85 4.28 3.67 2.33 0.95 0.36 4.89 4.47 3.60
wB 0.0622 0.0622 0.0622 0.0622
T/K 295.26 295.43 295.49 295.60
P/MPa 2.34 1.18 0.73 0.03

wB 0.3649 0.3649 0.3649 0.3649 0.3649 0.1977 0.1977 0.1977 0.1977
T/K 289.05 289.10 289.15 289.26 289.42 296.25 296.44 296.55 296.65
P/MPa 4.27 3.72 3.48 2.63 1.46 5.02 3.49 3.03 2.32
wB 0.1977 0.1977 0.1977 0.1977 0.1654 0.1654 0.1654 0.1654 0.1654
T/K 296.79 296.88 296.95 296.98 296.65 296.74 296.84 297.04 297.24
P/MPa 1.41 0.86 0.50 0.29 4.65 3.98 3.34 2.05 0.87
wB 0.1654 0.1503 0.1503 0.1503 0.1503 0.1503 0.1503 0.1503 0.1503
T/K 297.35 296.65 296.74 296.84 297.05 297.24 297.35 297.45 297.49
P/MPa 0.20 5.35 4.75 4.16 2.75 1.57 1.04 0.33 0.10
wB 0.1503 0.1503 0.1393 0.1393 0.1393 0.1393 0.1393 0.1393 0.1393
T/K 297.54 297.54 296.61 296.66 296.77 296.98 297.05 297.15 297.25
P/MPa −0.18 −0.19 4.49 4.24 3.54 2.15 1.70 1.14 0.57
wB 0.1393 0.1393 0.1388 0.1388 0.1388 0.1388 0.1388 0.1388 0.1388
T/K 297.30 297.35 296.65 296.75 296.95 297.05 297.15 297.24 297.35
P/MPa 0.24 −0.08 4.72 4.12 2.74 2.11 1.54 1.01 0.20
wB 0.1388 0.1388 0.1126 0.1126 0.1126 0.1126 0.1126 0.1126 0.1126
T/K 297.40 297.43 296.48 296.58 296.65 296.86 296.96 297.05 297.10
P/MPa 0.07 −0.20 4.98 4.27 3.92 2.52 1.93 1.28 1.06
wB 0.1126 0.1126 0.1126 0.0977 0.0977 0.0977 0.0977 0.0977 0.0977
T/K 297.17 297.25 297.27 296.33 296.44 296.55 296.74 296.89 297.00
P/MPa 0.52 0.05 −0.03 3.99 3.28 2.06 1.07 0.40
wB 0.0977 0.0944 0.0944 0.0944 0.0944 0.0944 0.0944 0.0944 0.0944
T/K 297.06 296.24 296.36 296.46 296.67 296.73 296.86 296.92 296.99
P/MPa 0.06 4.25 3.52 2.34 1.89 1.06 0.60
wB 0.0944 0.0861 0.0861 0.0861 0.0861 0.0861 0.0861 0.0861 0.0861
T/K 297.02 296.06 296.17 296.25 296.45 296.64 296.79 296.81 296.87
P/MPa −0.07 5.29 4.52 3.86 2.64 1.49 0.40 0.35 −0.11
wB 0.0727 0.0727 0.0727 0.0727 0.0727 0.0727 0.0622 0.0622 0.0622
T/K 295.57 295.65 295.75 295.95 296.16 296.25 294.89 294.95 295.08
P/MPa 4.69 4.19 3.53 2.17 0.83 0.23 4.79 4.30 3.45
wB 0.0622 0.0622 0.0622 0.0622
T/K 295.26 295.43 295.49 295.60
P/MPa 2.19 1.03 −0.07
_____________________________________________________________________________


wB 0.2265 0.2265 0.2265 0.2265 0.2265 0.2265 0.2265 0.1911 0.1911
T/K 309.43 309.43 309.74 309.73 310.14 310.45 310.68 312.43 312.83
P/MPa 4.96 4.96 3.89 3.90 2.42 1.35 0.44 5.27 3.80
wB 0.1911 0.1911 0.1911 0.1651 0.1651 0.1651 0.1651 0.1651 0.1454
T/K 313.14 313.44 313.84 314.13 314.45 314.75 315.16 315.39 315.44
P/MPa 2.74 1.63 0.22 5.18 4.04 2.90 1.42 0.56 3.68
wB 0.1454 0.1454 0.1454 0.1390 0.1390 0.1390 0.1390 0.1390 0.1245
T/K 315.75 316.05 316.39 314.84 315.15 315.44 315.65 316.00 315.15
P/MPa 2.64 1.53 0.31 4.68 3.54 2.47 1.69 0.44 4.66
wB 0.1245 0.1245 0.1245 0.1245 0.1059 0.1059 0.1059 0.1059 0.1059
T/K 315.44 315.74 316.05 316.30 315.44 315.34 315.74 316.05 316.64
P/MPa 3.67 2.54 1.39 0.54 4.63 5.03 3.57 2.42 0.28
wB 0.0922 0.0922 0.0922 0.0922 0.0922 0.0633 0.0633 0.0633 0.0633
T/K 315.44 315.75 316.05 316.34 316.74 315.34 315.74 316.05 316.34
P/MPa 4.98 3.86 2.75 1.62 0.14 5.22 3.68 2.56 1.52
wB 0.0633 0.0519 0.0519 0.0519 0.0519 0.0519 0.0519 0.0440 0.0440
T/K 316.65 315.04 315.03 315.44 315.74 316.05 316.45 314.84 315.15
P/MPa 0.47 5.21 5.23 3.78 2.69 1.55 0.13 4.33 3.08
wB 0.0440 0.0440 0.0440 0.0337 0.0337 0.0337 0.0337 0.0337
T/K 315.44 315.55 315.84 313.63 314.04 314.34 314.54 314.94
P/MPa 1.95 1.47 0.40 4.98 3.51 2.41 1.71 0.19

wB 0.2265 0.2265 0.2265 0.2265 0.2265 0.2265 0.2265 0.1911 0.1911
T/K 309.43 309.43 309.74 309.73 310.14 310.45 310.68 312.43 312.83
P/MPa 4.80 4.81 3.75 3.74 2.27 1.21 0.31 5.09 3.63
wB 0.1911 0.1911 0.1911 0.1651 0.1651 0.1651 0.1651 0.1651 0.1454
T/K 313.14 313.44 313.84 314.13 314.45 314.75 315.16 315.39 315.44
P/MPa 2.56 1.47 0.07 5.06 3.94 2.79 1.31 0.48 3.51
wB 0.1454 0.1454 0.1454 0.1390 0.1390 0.1390 0.1390 0.1390 0.1245
T/K 315.75 316.05 316.39 314.84 315.15 315.44 315.65 316.00 315.15
P/MPa 2.48 1.36 0.14 4.54 3.39 2.32 1.56 0.35 4.50
wB 0.1245 0.1245 0.1245 0.1245 0.1059 0.1059 0.1059 0.1059 0.1059
T/K 315.44 315.74 316.05 316.30 315.44 315.34 315.74 316.05 316.64
P/MPa 3.51 2.34 1.22 0.43 4.43 4.78 3.32 2.22 0.11
wB 0.0922 0.0922 0.0922 0.0922 0.0922 0.0633 0.0633 0.0633 0.0633
T/K 315.44 315.75 316.05 316.34 316.74 315.34 315.74 316.05 316.34
P/MPa 4.68 3.59 2.47 1.36 −0.11 5.06 3.50 2.39 1.35
continued
_____________________________________________________________________________
continued
wB 0.0633 0.0519 0.0519 0.0519 0.0519 0.0519 0.0519 0.0440 0.0440
T/K 316.65 315.04 315.03 315.44 315.74 316.05 316.45 314.84 315.15
P/MPa 0.32 5.05 5.04 3.63 2.52 1.40 −0.00 4.14 2.80
wB 0.0440 0.0440 0.0440 0.0337 0.0337 0.0337 0.0337 0.0337
T/K 315.44 315.55 315.84 313.63 314.04 314.34 314.54 314.94
P/MPa 1.72 1.22 0.12 4.71 3.22 2.18 1.49 −0.04


wB 0.1322 0.1322 0.1322 0.1322 0.1322 0.1212 0.1212 0.1212 0.1212
T/K 321.54 321.94 322.34 322.74 323.03 321.84 322.23 322.63 322.94
P/MPa 5.44 4.03 2.67 1.34 0.27 4.70 3.45 2.12 1.15
wB 0.1212 0.1119 0.1119 0.1119 0.1119 0.1119 0.0929 0.0929 0.0929
T/K 323.11 321.94 322.34 322.74 322.84 323.24 321.84 321.93 322.03
P/MPa 0.53 4.61 3.26 1.91 1.59 0.29 4.27 3.92 3.62
wB 0.0929 0.0929 0.0929 0.0929 0.0929 0.0929 0.0812 0.0812 0.0812
T/K 322.22 322.43 322.63 322.84 323.03 323.20 321.63 321.84 322.03
P/MPa 3.06 2.39 1.76 1.17 0.58 0.11 5.52 4.90 4.30
wB 0.0812 0.0812 0.0812 0.0812 0.0645 0.0645 0.0645 0.0645 0.0645
T/K 322.44 322.84 323.03 323.44 321.72 322.14 322.53 322.84 323.13
P/MPa 3.10 1.92 1.38 0.29 5.61 4.25 3.02 2.10 1.23
wB 0.0645 0.0535 0.0535 0.0535 0.0535 0.0535 0.0535 0.0457 0.0457
T/K 323.44 321.43 321.94 322.34 322.54 322.85 323.14 321.04 321.44
P/MPa 0.37 5.73 4.06 2.82 2.21 1.30 0.41 6.13 4.77
wB 0.0457 0.0457 0.0457 0.0457 0.0457 0.0355 0.0355 0.0355 0.0355
T/K 321.63 322.03 322.43 322.74 322.93 320.74 321.13 321.54 321.94
P/MPa 4.21 2.86 1.65 0.76 0.16 5.84 4.58 3.27 1.98
wB 0.0355 0.0355 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307 0.0250
T/K 322.13 322.39 319.64 320.04 320.44 320.73 320.94 321.23 318.35
P/MPa 1.35 0.60 5.37 4.14 2.89 1.99 1.24 0.36 4.55
wB 0.0250 0.0250 0.0250 0.0250
T/K 318.74 319.15 319.44 319.75
P/MPa 3.43 2.23 1.26 0.37

wB 0.1322 0.1322 0.1322 0.1322 0.1322 0.1212 0.1212 0.1212 0.1212
T/K 321.54 321.94 322.34 322.74 323.03 321.84 322.23 322.63 322.94
P/MPa 5.27 3.89 2.50 1.20 0.13 4.52 3.24 1.90 0.93
continued
_____________________________________________________________________________
continued
wB 0.1212 0.1119 0.1119 0.1119 0.1119 0.1119 0.0929 0.0929 0.0929
T/K 323.11 321.94 322.34 322.74 322.84 323.24 321.84 321.93 322.03
P/MPa 0.40 4.34 3.02 1.67 1.37 0.13 3.92 3.63 3.33
wB 0.0929 0.0929 0.0929 0.0929 0.0929 0.0929 0.0812 0.0812 0.0812
T/K 322.22 322.43 322.63 322.84 323.03 323.20 321.63 321.84 322.03
P/MPa 2.75 2.07 1.48 0.88 0.33 −0.15 5.37 4.70 4.12
wB 0.0812 0.0812 0.0812 0.0812 0.0645 0.0645 0.0645 0.0645 0.0645
T/K 322.44 322.84 323.03 323.44 321.72 322.14 322.53 322.84 323.13
P/MPa 2.89 1.69 1.19 0.11 5.46 3.93 2.83 1.84 0.94
wB 0.0645 0.0535 0.0535 0.0535 0.0535 0.0535 0.0535 0.0457 0.0457
T/K 323.44 321.43 321.94 322.34 322.54 322.85 323.14 321.04 321.44
P/MPa 0.11 5.68 3.98 2.73 2.13 1.22 0.34 6.09 4.69
wB 0.0457 0.0457 0.0457 0.0457 0.0457 0.0355 0.0355 0.0355 0.0355
T/K 321.63 322.03 322.43 322.74 322.93 320.74 321.13 321.54 321.94
P/MPa 4.10 2.76 1.57 0.68 0.10 5.68 4.44 3.12 1.84
wB 0.0355 0.0355 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307 0.0250
T/K 322.13 322.39 319.64 320.04 320.44 320.73 320.94 321.23 318.35
P/MPa 1.23 0.49 5.20 3.96 2.66 1.80 1.09 0.22 4.39
wB 0.0250 0.0250 0.0250 0.0250
T/K 318.74 319.15 319.44 319.75
P/MPa 3.28 2.04 1.11 0.20

Solvent (A): nitroethane-d5 C2D5NO2 57817-88-6
wB 0.2291 0.2291 0.2291 0.2291 0.2291 0.2291 0.2291 0.2291 0.1844
T/K 336.41 336.41 336.52 336.61 336.82 337.11 337.43 337.74 338.53
P/MPa 4.32 4.25 3.90 3.60 3.02 2.21 1.37 0.58 4.17
wB 0.1844 0.1844 0.1844 0.1844 0.1543 0.1543 0.1543 0.1543 0.1543
T/K 338.75 338.94 339.24 339.84 339.02 339.25 339.55 339.85 340.47
P/MPa 3.56 2.96 2.12 0.53 4.17 3.54 2.77 2.03 0.48
wB 0.1326 0.1326 0.1326 0.1326 0.1326 0.1205 0.1205 0.1205 0.1205
T/K 339.31 339.62 339.95 340.25 340.67 339.35 339.35 339.66 339.50
P/MPa 4.17 3.33 2.45 1.63 0.57 4.57 4.54 3.70 2.91
wB 0.1205 0.1205 0.0995 0.0995 0.0995 0.0995 0.0995 0.0848 0.0848
T/K 340.34 340.93 339.47 339.86 340.26 340.65 341.11 339.16 339.66
P/MPa 1.92 0.49 4.52 3.50 2.56 1.58 0.49 4.87 3.53
wB 0.0848 0.0848 0.0848 0.0738 0.0738 0.0738 0.0738 0.0738 0.0669
T/K 340.07 340.44 340.92 339.05 339.54 340.06 340.25 340.85 338.96
P/MPa 2.57 1.62 0.44 4.81 3.51 2.26 1.80 0.37 4.60
continued
_____________________________________________________________________________
continued
wB 0.0669 0.0669 0.0669 0.0669
T/K 339.48 339.87 340.24 340.63
P/MPa 3.33 2.33 1.34 0.47

wB 0.2291 0.2291 0.2291 0.2291 0.2291 0.2291 0.2291 0.2291 0.1844
T/K 336.41 336.41 336.52 336.61 336.82 337.11 337.43 337.74 338.53
P/MPa 4.25 4.14 3.79 3.53 2.92 2.14 1.25 0.52 4.06
wB 0.1844 0.1844 0.1844 0.1844 0.1543 0.1543 0.1543 0.1543 0.1543
T/K 338.75 338.94 339.24 339.84 339.02 339.25 339.55 339.85 340.47
P/MPa 3.40 2.86 2.03 0.44 3.99 3.29 2.60 1.88 0.27
wB 0.1326 0.1326 0.1326 0.1326 0.1326 0.1205 0.1205 0.1205 0.1205
T/K 339.31 339.62 339.95 340.25 340.67 339.35 339.35 339.66 339.50
P/MPa 3.90 3.08 2.24 1.44 0.44 4.34 4.35 3.47 2.71
wB 0.1205 0.1205 0.0995 0.0995 0.0995 0.0995 0.0995 0.0848 0.0848
T/K 340.34 340.93 339.47 339.86 340.26 340.65 341.11 339.16 339.66
P/MPa 1.73 0.29 4.24 3.26 2.30 1.38 0.23 4.66 3.29
wB 0.0848 0.0848 0.0848 0.0738 0.0738 0.0738 0.0738 0.0738 0.0669
T/K 340.07 340.44 340.92 339.05 339.54 340.06 340.25 340.85 338.96
P/MPa 2.33 1.44 0.21 4.66 3.28 1.99 1.63 0.11 4.45
wB 0.0669 0.0669 0.0669 0.0669
T/K 339.48 339.87 340.24 340.63
P/MPa 3.05 2.08 1.11 0.25
Polymer (B): polystyrene-d8 2000DE1

−1 −1

wB 0.2362 0.2362 0.2362 0.2362 0.2362 0.2362 0.2121 0.2121 0.2121
T/K 268.58 268.58 268.68 268.77 268.88 269.01 268.68 268.68 268.78
P/MPa 5.26 5.19 4.07 3.02 1.78 0.32 5.11 5.11 3.99
wB 0.2121 0.2121 0.2121 0.1866 0.1866 0.1866 0.1866 0.1866 0.1866
T/K 268.89 268.98 269.11 268.89 268.88 268.98 269.07 269.19 269.28
P/MPa 2.75 1.66 0.34 4.95 4.94 3.84 2.75 1.49 0.48
wB 0.1644 0.1644 0.1644 0.1644 0.1644 0.1644 0.1453 0.1453 0.1453
T/K 269.07 269.07 269.19 269.28 269.35 269.42 269.07 269.07 269.18
P/MPa 4.44 4.43 3.25 2.14 1.40 0.48 4.52 4.52 3.21
wB 0.1453 0.1453 0.1453 0.1395 0.1395 0.1395 0.1395 0.1395 0.1395
T/K 269.28 269.34 269.42 269.28 269.28 269.38 269.49 269.54 269.62
P/MPa 2.09 1.41 0.54 4.59 4.55 3.34 1.98 1.33 0.39
continued
_____________________________________________________________________________
continued
wB 0.1202 0.1202 0.1202 0.1202 0.1202 0.1202 0.1021 0.1021 0.1021
T/K 269.18 269.18 269.29 269.38 269.49 269.57 268.98 268.98 269.07
P/MPa 4.73 4.71 3.52 2.45 1.28 0.39 4.46 4.48 3.32
wB 0.1021 0.1021 0.1021 0.0874 0.0874 0.0874 0.0874 0.0874 0.0874
T/K 269.17 269.27 269.34 268.54 268.54 268.64 268.74 268.84 268.93
P/MPa 2.33 1.23 0.35 5.06 5.07 3.98 2.77 1.65 0.60
wB 0.0764 0.0764 0.0764 0.0764 0.0764 0.0764
T/K 268.13 268.13 268.25 268.34 268.43 268.51
P/MPa 4.88 4.90 3.58 2.42 1.41 0.49

wB 0.2362 0.2362 0.2362 0.2362 0.2362 0.2362 0.2121 0.2121 0.2121
T/K 268.58 268.58 268.68 268.77 268.88 269.01 268.68 268.68 268.78
P/MPa 5.13 5.06 3.91 2.90 1.66 0.26 4.93 4.99 3.81
wB 0.2121 0.2121 0.2121 0.1866 0.1866 0.1866 0.1866 0.1866 0.1866
T/K 268.89 268.98 269.11 268.89 268.88 268.98 269.07 269.19 269.28
P/MPa 2.57 1.49 0.15 4.62 4.68 3.52 2.51 1.23 0.21
wB 0.1644 0.1644 0.1644 0.1644 0.1644 0.1644 0.1453 0.1453 0.1453
T/K 269.07 269.07 269.19 269.28 269.35 269.42 269.07 269.07 269.18
P/MPa 4.05 4.03 2.88 1.86 1.10 0.11 4.23 4.23 2.93
wB 0.1453 0.1453 0.1453 0.1395 0.1395 0.1395 0.1395 0.1395 0.1395
T/K 269.28 269.34 269.42 269.28 269.28 269.38 269.49 269.54 269.62
P/MPa 1.88 1.22 0.33 4.28 4.22 3.03 1.66 1.01 0.17
wB 0.1202 0.1202 0.1202 0.1202 0.1202 0.1202 0.1021 0.1021 0.1021
T/K 269.18 269.18 269.29 269.38 269.49 269.57 268.98 268.98 269.07
P/MPa 4.60 4.58 3.41 2.36 1.19 0.29 4.35 4.39 3.22
wB 0.1021 0.1021 0.1021 0.0874 0.0874 0.0874 0.0874 0.0874 0.0874
T/K 269.17 269.27 269.34 268.54 268.54 268.64 268.74 268.84 268.93
P/MPa 2.22 1.09 0.26 4.94 4.92 3.84 2.64 1.48 0.49
wB 0.0764 0.0764 0.0764 0.0764 0.0764 0.0764
T/K 268.13 268.13 268.25 268.34 268.43 268.51
P/MPa 4.76 4.78 3.48 2.29 1.31 0.39

−1 −1

wB 0.2273 0.2273 0.2273 0.2273 0.2273 0.2273 0.2273 0.2273 0.1992
T/K 285.98 285.98 286.19 286.29 286.38 286.59 286.65 286.85 286.49
P/MPa 5.25 5.27 4.08 3.53 3.02 1.81 1.50 0.46 4.65
continued
_____________________________________________________________________________
continued
wB 0.1992 0.1992 0.1992 0.1992 0.1992 0.1773 0.1773 0.1773 0.1773
T/K 286.49 286.69 286.90 287.09 287.29 286.99 286.99 287.20 287.40
P/MPa 4.65 3.64 2.49 1.40 0.46 4.74 4.74 3.53 2.43
wB 0.1773 0.1773 0.1522 0.1522 0.1522 0.1522 0.1522 0.1522 0.1315
T/K 287.61 287.77 287.30 287.30 287.49 287.71 287.92 288.06 287.49
P/MPa 1.35 0.47 4.80 4.82 3.72 2.52 1.33 0.61 4.77
wB 0.1315 0.1315 0.1315 0.1315 0.1315 0.1158 0.1158 0.1158 0.1158
T/K 287.49 287.70 287.91 288.08 288.27 287.49 287.50 287.70 287.92
P/MPa 4.80 3.56 2.37 1.45 0.41 4.87 4.86 3.61 2.38
wB 0.1158 0.1158 0.1124 0.1124 0.1124 0.1124 0.1124 0.0995 0.0995
T/K 288.08 288.25 288.06 288.07 288.09 288.12 288.14 287.40 287.40
P/MPa 1.51 0.53 0.67 0.61 0.51 0.36 0.25 4.61 4.62
wB 0.0995 0.0995 0.0995 0.0995 0.0840 0.0840 0.0840 0.0840 0.0840
T/K 287.61 287.80 287.96 288.11 287.30 287.30 287.49 287.71 287.85
P/MPa 3.42 2.30 1.37 0.56 4.65 4.66 3.49 2.28 1.46
wB 0.0840 0.0703 0.0703 0.0703 0.0703 0.0703 0.0703 0.0531 0.0531
T/K 288.06 286.99 287.00 287.21 287.40 287.56 287.75 286.28 286.28
P/MPa 0.27 4.82 4.82 3.53 2.42 1.45 0.38 4.92 4.92
wB 0.0531 0.0531 0.0531 0.0531
T/K 286.50 286.70 286.85 287.05
P/MPa 3.64 2.43 1.54 0.34

wB 0.2273 0.2273 0.2273 0.2273 0.2273 0.2273 0.2273 0.2273 0.1992
T/K 285.98 285.98 286.19 286.29 286.38 286.59 286.65 286.85 286.49
P/MPa 5.08 5.09 3.91 3.23 2.80 1.67 1.31 0.28 4.53
wB 0.1992 0.1992 0.1992 0.1992 0.1992 0.1773 0.1773 0.1773 0.1773
T/K 286.49 286.69 286.90 287.09 287.29 286.99 286.99 287.20 287.40
P/MPa 4.54 3.49 2.36 1.30 0.36 4.65 4.65 3.40 2.34
wB 0.1773 0.1773 0.1522 0.1522 0.1522 0.1522 0.1522 0.1522 0.1315
T/K 287.61 287.77 287.30 287.30 287.49 287.71 287.92 288.06 287.49
P/MPa 1.25 0.40 4.76 4.76 3.64 2.41 1.25 0.54 4.62
wB 0.1315 0.1315 0.1315 0.1315 0.1315 0.1158 0.1158 0.1158 0.1158
T/K 287.49 287.70 287.91 288.08 288.27 287.49 287.50 287.70 287.92
P/MPa 4.65 3.37 2.17 1.30 0.24 4.61 4.61 3.34 2.14
wB 0.1158 0.1158 0.1124 0.1124 0.1124 0.1124 0.1124 0.0995 0.0995
T/K 288.08 288.25 288.06 288.07 288.09 288.12 288.14 287.40 287.40
P/MPa 1.29 0.32 0.43 0.33 0.23 0.08 0.02 4.40 4.41
wB 0.0995 0.0995 0.0995 0.0995 0.0840 0.0840 0.0840 0.0840 0.0840
T/K 287.61 287.80 287.96 288.11 287.30 287.30 287.49 287.71 287.85
P/MPa 3.24 2.08 1.16 0.39 4.52 4.58 3.38 2.14 1.35
wB 0.0840 0.0703 0.0703 0.0703 0.0703 0.0703 0.0703 0.0531 0.0531
T/K 288.06 286.99 287.00 287.21 287.40 287.56 287.75 286.28 286.28
P/MPa 0.15 4.72 4.72 3.42 2.31 1.37 0.26 4.80 4.81
continued
_____________________________________________________________________________
continued
wB 0.0531 0.0531 0.0531 0.0531
T/K 286.50 286.70 286.85 287.05
P/MPa 3.52 2.28 1.41 0.22

−1 −1
Solvent (A): nitroethane-d5 C2D5NO2 57817-88-6

wB 0.1964 0.1964 0.1964 0.1964 0.1964 0.1964 0.1964 0.1964 0.1964
T/K 308.08 308.09 308.18 308.28 308.48 308.76 309.06 309.25 309.65
P/MPa 6.28 6.28 5.85 5.38 4.69 3.58 2.45 1.72 0.24
wB 0.1741 0.1741 0.1741 0.1741 0.1741 0.1519 0.1519 0.1519 0.1519
T/K 309.65 309.95 310.26 310.51 310.83 310.46 310.78 311.03 311.23
P/MPa 4.85 3.61 2.60 1.67 0.47 4.59 3.33 2.28 1.57
wB 0.1519 0.1330 0.1330 0.1330 0.1330 0.1330 0.1237 0.1237 0.1237
T/K 311.51 310.68 310.86 311.18 311.37 311.65 310.87 310.87 311.18
P/MPa 0.47 4.53 3.78 2.57 1.70 0.63 4.37 4.36 3.19
wB 0.1237 0.1237 0.1237 0.1183 0.1183 0.1183 0.1183 0.1183 0.1069
T/K 311.37 311.59 311.81 310.77 310.99 311.27 311.49 311.78 310.90
P/MPa 2.30 1.43 0.61 4.48 3.56 2.43 1.61 0.50 4.72
wB 0.1069 0.1069 0.1069 0.1069 0.0927 0.0927 0.0927 0.0927 0.0927
T/K 311.18 311.38 311.59 311.92 310.77 311.09 311.27 311.49 311.83
P/MPa 3.53 2.63 1.81 0.55 4.60 3.37 2.59 1.83 0.47
wB 0.0807 0.0807 0.0807 0.0807 0.0807 0.0715 0.0715 0.0715 0.0715
T/K 310.57 310.77 311.08 311.38 311.73 310.60 310.78 311.10 311.30
P/MPa 5.12 4.34 3.05 1.89 0.50 4.45 3.60 2.35 1.56

wB 0.1964 0.1964 0.1964 0.1964 0.1964 0.1964 0.1964 0.1964 0.1964
T/K 308.08 308.09 308.18 308.28 308.48 308.76 309.06 309.25 309.65
P/MPa 6.10 6.22 5.63 5.23 4.45 3.45 2.24 1.58 0.05
wB 0.1741 0.1741 0.1741 0.1741 0.1741 0.1519 0.1519 0.1519 0.1519
T/K 309.65 309.95 310.26 310.51 310.83 310.46 310.78 311.03 311.23
P/MPa 4.65 3.48 2.44 1.50 0.27 4.46 3.20 2.13 1.44
wB 0.1519 0.1330 0.1330 0.1330 0.1330 0.1330 0.1237 0.1237 0.1237
T/K 311.51 310.68 310.86 311.18 311.37 311.65 310.87 310.87 311.18
P/MPa 0.37 4.36 3.59 2.43 1.49 0.42 4.10 4.12 2.90
wB 0.1237 0.1237 0.1237 0.1183 0.1183 0.1183 0.1183 0.1183 0.1069
T/K 311.37 311.59 311.81 310.77 310.99 311.27 311.49 311.78 310.90
P/MPa 2.01 1.12 0.35 4.13 3.26 2.16 1.36 0.25 4.50
continued
_____________________________________________________________________________
continued
wB 0.1069 0.1069 0.1069 0.1069 0.0927 0.0927 0.0927 0.0927 0.0927
T/K 311.18 311.38 311.59 311.92 310.77 311.09 311.27 311.49 311.83
P/MPa 3.24 2.37 1.54 0.27 4.37 3.10 2.38 1.51 0.22
wB 0.0807 0.0807 0.0807 0.0807 0.0807 0.0715 0.0715 0.0715 0.0715
T/K 310.57 310.77 311.08 311.38 311.73 310.60 310.78 311.10 311.30
P/MPa 4.93 4.08 2.82 1.66 0.26 4.31 3.47 2.12 1.33

Solvent (A): 2-propanone C3H6O 67-64-1
wB = 0.20 T/K = 270 (dT/dP)P=0/K.MPa−1 = −1.10

wB 0.19 0.20 0.23
T/K 287 286 285
(dT/dP)P=0/K.MPa−1 −1.70 −1.75 −1.76

wB = 0.20 T/K = 400 (dT/dP)P=0/K.MPa−1 = +6.53

wB 0.077 0.090 0.112 0.145 0.170 0.200 0.325
ϕB = 0.059 0.069 0.087 0.113 0.133 0.158 0.265
T/K 248.40 249.75 252.60 254.20 254.53 254.46 251.65
(dT/dP)P=1/K.MPa−1 −1.10 −0.95 −0.76 −0.70 −0.73 −0.78 −0.74
continued
_____________________________________________________________________________
continued
wB 0.077 0.090 0.112 0.145 0.170 0.200 0.325
ϕB = 0.059 0.069 0.087 0.113 0.133 0.158 0.265
T/K 247.40 249.50 251.75 253.70 254.29 254.00 251.43
(dT/dP)P=1/K.MPa−1 −0.90 −0.76 −0.68 −0.70

wB 0.090 0.146 0.164 0.218 0.292
ϕB = 0.068 0.112 0.126 0.171 0.234
T/K 245.15 247.92 248.18 247.52 246.09
(dT/dP)P=0/K.MPa−1 −0.74 −0.74 −0.75 −0.75 −0.72

wB 0.090 0.146 0.164 0.218 0.292
ϕB = 0.068 0.112 0.126 0.171 0.234
T/K 244.87 247.77 247.86 247.52 246.00
(dT/dP)P=0/K.MPa−1 −0.78 −0.79 −0.73 −0.75 −0.80

wB 0.222 0.222 0.222 0.222 0.222
T/K 253.77 253.45 253.19 252.98 252.83
P/MPa 0.07 0.34 0.72 1.02 1.25

wB 0.210 0.210 0.210 0.210
T/K 273.75 274.16 274.68 274.91
P/MPa 1.42 1.07 0.61 0.41
_____________________________________________________________________________


wB 0.102 0.102 0.102 0.102 0.102 0.102 0.107 0.107 0.107
T/K 281.41 281.42 281.83 282.19 282.42 282.78 283.19 282.37 281.91
P/MPa 1.08 1.11 0.92 0.64 0.65 0.31 0.62 1.13 1.24
wB 0.107 0.107 0.163 0.163 0.163 0.163 0.163 0.163 0.163
T/K 281.60 281.30 287.13 287.11 286.65 286.44 285.96 285.49 285.27
P/MPa 1.27 1.47 0.08 0.09 0.30 0.42 0.70 0.97 1.12
wB 0.163 0.197 0.197 0.197 0.197 0.212 0.212 0.212 0.212
T/K 284.71 285.60 285.26 284.89 284.60 286.l2 285.42 285.26 284.50
P/MPa 1.45 0.40 0.59 0.84 0.98 0.05 0.44 0.56 0.99
wB 0.212 0.212 0.229 0.229 0.229 0.229 0.229 0.229 0.229
T/K 284.11 283.63 285.77 285.35 285.17 284.79 284.52 284.14 283.80
P/MPa 1.21 1.55 0.07 0.31 0.41 0.64 0.82 1.04 1.28
wB 0.264 0.264 0.264 0.264 0.264 0.264 0.264 0.264 0.264
T/K 285.10 285.04 284.82 284.60 284.39 284.07 283.64 283.32 283.23
P/MPa 0.07 0.09 0.20 0.33 0.46 0.66 0.90 1.10 1.16

wB 0.102 0.102 0.102 0.102 0.102 0.102 0.107 0.107 0.107
T/K 281.41 281.42 281.83 282.19 282.42 282.78 283.19 282.37 281.91
P/MPa 0.84 0.94 0.73 0.47 0.39 0.05 0.27 0.80 0.97
wB 0.107 0.107 0.163 0.163 0.163 0.163 0.163 0.163 0.197
T/K 281.60 281.30 286.65 286.44 285.96 285.49 285.27 284.71 285.60
P/MPa 1.06 1.24 −0.09 0.07 0.25 0.62 0.69 1.06 0.30
wB 0.197 0.197 0.197 0.212 0.212 0.212 0.212 0.212 0.229
T/K 285.26 284.89 284.60 285.42 285.26 284.50 284.11 283.63 285.35
P/MPa 0.51 0.72 0.88 0.34 0.43 0.88 1.12 1.41 0.21
wB 0.229 0.229 0.229 0.229 0.229 0.264 0.264 0.264 0.264
T/K 285.17 284.79 284.52 284.14 283.80 284.82 284.60 284.39 284.07
P/MPa 0.32 0.53 0.70 0.92 1.12 −0.11 0.04 0.17 0.35
wB 0.264 0.264 0.264
T/K 283.64 283.32 283.23
P/MPa 0.65 0.81 0.85
_____________________________________________________________________________


wB 0.111 0.111 0.111 0.111 0.111 0.111 0.111 0.111 0.111
T/K 321.22 322.81 322.82 326.73 329.25 330.88 365.52 367.63 371.30
P/MPa 1.56 1.18 1.19 0.74 0.47 0.31 0.55 0.75 0.99
wB 0.111 0.111 0.146 0.146 0.146 0.146 0.146 0.146 0.146
T/K 375.80 378.48 325.87 327.52 330.55 333.20 337.06 340.93 342.45
P/MPa 1.49 1.78 1.55 1.33 0.98 0.75 0.47 0.33 0.32
wB 0.146 0.146 0.146 0.146 0.146 0.146 0.146 0.146 0.146
T/K 344.05 351.54 353.15 355.25 358.39 362.31 366.80 371.68 374.10
P/MPa 0.26 0.29 0.30 0.45 0.60 0.86 1.18 1.59 1.82
wB 0.158 0.158 0.158 0.158 0.158 0.158 0.158 0.158 0.158
T/K 325.17 329.19 332.14 340.37 344.55 348.88 354.68 359.23 366.57
P/MPa 1.81 1.29 0.98 0.48 0.39 0.38 0.51 0.71 1.19
wB 0.158 0.163 0.163 0.163 0.163 0.163 0.163 0.163 0.163
T/K 372.72 327.82 330.90 334.09 337.43 340.81 344.46 346.55 349.25
P/MPa 1.73 1.56 1.20 0.92 0.68 0.55 0.48 0.47 0.47
wB 0.163 0.163 0.163 0.163 0.163 0.169 0.169 0.169 0.169
T/K 352.96 358.40 362.91 367.21 372.39 327.38 327.25 330.92 334.48
P/MPa 0.54 0.75 1.00 1.30 1.73 1.45 1.43 1.01 0.71
wB 0.169 0.169 0.169 0.169 0.169 0.169 0.169 0.174 0.174
T/K 337.35 341.57 346.73 351.19 357.06 367.75 375.89 328.21 331.83
P/MPa 0.54 0.39 0.35 0.41 0.59 1.29 2.00 1.38 0.97
wB 0.174 0.174 0.174 0.174 0.174 0.174 0.174 0.174 0.174
T/K 335.82 339.91 342.81 347.19 351.33 356.23 361.75 367.39 373.22
P/MPa 0.68 0.45 0.37 0.34 0.40 0.58 0.85 1.25 1.75
wB 0.185 0.185 0.185 0.185 0.185 0.185 0.185 0.185 0.185
T/K 329.45 332.27 335.50 338.67 342.72 345.75 350.24 353.05 358.41
P/MPa 1.23 0.96 0.72 0.55 0.40 0.37 0.38 0.44 0.67
wB 0.185 0.185 0.185 0.213 0.213 0.213 0.213 0.213 0.213
T/K 363.93 368.03 373.76 326.70 329.17 332.66 335.29 342.10 344.41
P/MPa 0.99 1.29 1.79 1.61 1.31 0.95 0.77 0.46 0.44
wB 0.213 0.213 0.213 0.213 0.213 0.213 0.249 0.249 0.249
T/K 346.66 352.30 357.91 364.35 369.74 372.95 324.78 328.07 331.15
P/MPa 0.45 0.53 0.73 1.11 1.52 1.80 1.59 1.14 0.79
wB 0.249 0.249 0.249 0.249 0.249 0.249 0.249 0.273 0.273
T/K 334.45 339.12 354.98 358.42 364.97 371.79 376.92 321.19 324.14
P/MPa 0.51 0.27 0.30 0.46 0.86 1.40 1.89 1.71 1.30
wB 0.273 0.273 0.273 0.273 0.273 0.273
T/K 327.28 329.31 362.71 365.18 373.24 378.35
P/MPa 0.87 0.63 0.47 0.64 1.29 1.83
_____________________________________________________________________________


wB 0.111 0.111 0.111 0.111 0.111 0.111 0.111 0.111 0.111
T/K 321.22 322.81 322.82 326.73 329.25 330.88 365.52 367.63 371.30
P/MPa 0.95 0.85 0.88 0.14 0.14 0.37 0.32 0.32 0.71
wB 0.111 0.111 0.146 0.146 0.146 0.146 0.146 0.146 0.146
T/K 375.80 378.48 325.87 330.55 333.20 340.93 342.45 344.05 351.54
P/MPa 1.17 1.32 0.78 0.27 0.09 0.28 0.22 0.29 0.22
wB 0.146 0.146 0.146 0.146 0.146 0.158 0.158 0.158 0.158
T/K 355.25 358.39 362.31 366.80 374.10 325.17 329.19 332.14 340.37
P/MPa 0.09 0.24 0.20 0.59 1.39 1.39 0.88 0.47 0.11
wB 0.158 0.158 0.158 0.158 0.163 0.163 0.163 0.163 0.163
T/K 348.88 354.68 359.23 366.57 327.82 330.90 334.09 337.43 340.81
P/MPa 0.07 0.31 0.50 1.04 1.34 0.89 0.64 0.42 0.18
wB 0.163 0.163 0.163 0.163 0.163 0.163 0.169 0.169 0.169
T/K 344.46 349.25 358.40 362.91 367.21 372.39 327.38 327.25 330.92
P/MPa 0.18 0.23 0.32 0.12 0.25 0.18 0.87 1.56 1.08
wB 0.169 0.169 0.169 0.169 0.169 0.169 0.169 0.169 0.174
T/K 334.48 337.35 341.57 346.73 351.19 357.06 367.75 375.89 328.21
P/MPa 0.14 0.17 0.49 0.74 1.10 1.57 0.97 1.00 0.63
wB 0.174 0.174 0.174 0.174 0.174 0.174 0.174 0.174 0.174
T/K 331.83 335.82 339.91 342.81 347.19 351.33 356.23 361.75 367.39
P/MPa 0.67 0.33 0.20 0.17 0.13 0.17 0.30 0.64 1.06
wB 0.174 0.185 0.185 0.185 0.185 0.185 0.185 0.185 0.185
T/K 373.22 329.45 332.27 335.50 338.67 342.72 345.75 350.24 353.05
P/MPa 1.57 1.09 0.77 0.49 0.34 0.19 0.18 0.24 0.31
wB 0.185 0.185 0.185 0.185 0.213 0.213 0.213 0.213 0.213
T/K 358.41 363.93 368.03 373.76 326.70 329.17 332.66 335.29 342.10
P/MPa 0.51 0.83 1.15 1.62 1.47 1.12 0.60 0.59 0.25
wB 0.213 0.213 0.213 0.213 0.213 0.213 0.213 0.249 0.249
T/K 344.41 346.66 352.30 357.91 364.35 369.74 372.95 324.78 328.07
P/MPa 0.27 0.17 0.34 0.61 0.92 1.35 1.65 0.80 0.28
wB 0.249 0.249 0.249 0.249 0.249 0.249 0.249 0.249 0.273
T/K 331.15 334.45 339.12 354.98 358.42 364.97 371.79 376.92 321.19
P/MPa 0.25 0.19 0.28 0.34 0.14 0.27 0.95 1.49 1.46
wB 0.273 0.273 0.273 0.273 0.273 0.273 0.273
T/K 324.14 327.28 329.31 362.71 365.18 373.24 378.35
P/MPa 1.17 0.73 0.47 0.19 0.38 1.15 1.63
_____________________________________________________________________________


wB 0.209 0.209 0.209 0.209
T/K 234.95 234.60 235.98 235.25
P/MPa 1.55 2.02 0.15 1.11


wB 0.132 0.132 0.132 0.132 0.157 0.157 0.157 0.181 0.181
T/K 274.49 275.63 276.62 277.47 275.91 276.65 277.79 276.13 276.79
P/MPa 1.89 1.31 0.73 0.29 1.69 1.30 0.71 1.89 1.53
wB 0.181 0.214 0.214 0.214 0.214 0.214 0.233 0.233 0.233
T/K 279.62 275.36 276.70 277.34 277.93 279.30 275.02 277.09 278.16
P/MPa 1.14 2.57 1.83 1.49 1.14 0.47 2.48 1.41 0.88
wB 0.233 0.253 0.253 0.253 0.253 0.270 0.270 0.270 0.270
T/K 279.03 274.58 275.75 277.78 278.61 273.48 274.46 275.94 277.36
P/MPa 0.45 2.23 1.73 0.71 0.35 2.25 1.76 1.03 0.31
wB 0.300 0.300 0.300 0.300
T/K 270.82 271.26 271.87 272.42
P/MPa 1.11 0.84 0.57 0.28
Polymer (B): polystyrene 2002RE2

Type of data: cloud points (negative pressures were measured using a Berthelot tube technique)
wB = 0.180 was kept constant
T/K 257.4 258.1 258.2 258.9 262.9 265.0 273.0 280.0 283.0
P/bar 767.0 634.3 600.0 525.0 425.0 370.0 255.0 158.6 125.5
T/K 289.0 293.0 298.0 303.0 307.5 308.0 313.0 323.0 336.5
P/bar 82.5 62.5 32.5 0.4 −15.2 −20.2 −26.1 −32.4 −32.8
T/K 351.5 368.0 380.0 403.5 417.0 430.5
P/bar −26.1 −10.2 4.4 43.0 61.5 97.0
_____________________________________________________________________________
Polymer (B): polystyrene 2002RE2

Type of data: cloud points (negative pressures were measured using a Berthelot tube technique)
T/K 251.0 251.5 253.0 253.0 256.3 258.0 263.0 265.0 273.0
P/bar 700.00 590.00 536.50 630.00 455.00 403.00 296.80 260.00 156.00
T/K 277.3 281.8 286.0 293.4 295.0 298.5 299.8 301.0 301.6
P/bar 113.00 78.80 49.30 10.00 0.28 −21.60 −27.70 −26.40 −29.40
T/K 301.9 303.2 304.0 308.0 368.0 375.0 381.0 383.0 390.3
P/bar −30.30 −35.10 −41.00 −42.00 −26.70 −15.60 −12.40 −6.20 5.70
T/K 401.0 413.0 422.5 433.0
P/bar 20.00 40.00 50.00 73.00
Polymer (B): polystyrene 1994IMR

Solvent (A): propionitrile C3H5N 107-12-0

wB 0.044 0.044 0.044 0.063 0.063 0.063 0.063 0.063 0.104
T/K 316.75 323.15 330.05 335.05 337.35 339.95 341.55 345.55 346.65
P/MPa 3.23 0.02 −1.95 3.77 1.81 0.03 −0.95 −1.15 2.60
wB 0.104 0.104 0.104 0.104 0.201 0.201 0.201 0.201 0.201
T/K 351.65 359.35 371.15 372.00 347.15 350.65 353.10 356.15 358.55
P/MPa 1.37 0.95 −0.40 −0.50 2.01 1.80 1.39 0.70 0.32
wB 0.201 0.201 0.201 0.201 0.201 0.201 0.201 0.201 0.201
T/K 362.05 369.80 372.35 377.55 391.55 392.75 396.75 401.10 420.80
P/MPa 0.21 −0.36 −0.42 −0.51 −0.48 −0.31 −0.27 0.01 1.45
Comments: The negative pressures were measured using a Berthelot tube technique.


wB 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1600 0.1600 0.1600
T/K 267.151 267.623 267.948 268.421 268.936 268.397 268.856 269.421 269.981
P/MPa 3.518 2.869 2.366 1.511 0.917 0.508 3.682 2.903 2.045
continued
_____________________________________________________________________________
continued
wB 0.1600 0.1600 0.1600 0.1800 0.1800 0.1800 0.1800 0.1800 0.1800
T/K 270.454 270.934 271.222 267.979 268.447 268.999 268.503 269.986 270.522
P/MPa 1.430 0.721 0.369 4.058 3.390 2.688 1.866 1.255 0.427
wB 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.2100 0.2100 0.2100
T/K 268.939 269.449 269.938 270.553 271.086 271.395 268.077 268.470 268.923
P/MPa 4.139 3.412 2.658 1.979 1.267 0.906 3.025 2.602 4.196
wB 0.2100 0.2100 0.2100 0.2100 0.2100 0.2200 0.2200 0.2200 0.2200
T/K 269.513 269.977 270.491 270.960 271.482 268.994 268.436 270.010 270.486
P/MPa 3.780 2.820 2.048 1.532 0.840 4.086 3.622 2.461 2.274
wB 0.2200 0.2200 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400
T/K 270.988 271.483 268.877 269.461 270.028 270.518 270.930 271.494 271.950
P/MPa 1.346 0.749 4.896 4.305 3.623 2.952 2.319 1.613 1.180
wB 0.2400 0.2500 0.2500 0.2500 0.2500 0.2500 0.2600 0.2600 0.2600
T/K 272.245 269.072 269.576 270.128 271.130 271.525 269.531 269.954 270.493
P/MPa 0.688 3.971 3.267 2.763 1.249 0.845 4.404 3.874 3.162
wB 0.2600 0.2600 0.2600 0.2600 0.2800 0.2800 0.2800 0.2800 0.2800
T/K 271.082 271.468 271.926 272.497 269.840 270.538 270.957 271.445 271.979
P/MPa 2.399 1.901 1.328 0.558 4.802 3.565 2.914 2.111 1.649
wB 0.2800 0.2800 0.2800 0.3000 0.3000 0.3000 0.3000 0.3000 0.3000
T/K 272.465 272.465 272.784 268.445 269.027 269.466 270.143 270.641 271.018
P/MPa 0.922 1.137 0.742 5.566 4.813 4.417 3.424 2.562 2.075
wB 0.3000 0.3000 0.3300 0.3300 0.3300 0.3300 0.3300 0.3300 0.3300
T/K 271.438 271.933 267.859 268.475 268.972 269.397 269.948 270.515 271.032
P/MPa 1.653 1.022 4.575 3.748 3.230 2.672 1.964 1.409 0.718
wB 0.3591 0.3591 0.3591 0.3591 0.3591 0.3591 0.3591
T/K 268.225 268.594 268.977 269.516 270.019 270.425 270.995
P/MPa 4.441 3.952 3.393 2.711 1.981 1.421 0.654

wB 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1600 0.1600 0.1600
T/K 267.151 267.623 267.948 268.421 268.936 268.397 268.856 269.421 269.981
P/MPa 3.256 4.479 2.004 1.337 0.595 −0.197 3.076 2.304 1.666
wB 0.1600 0.1600 0.1600 0.1800 0.1800 0.1800 0.1800 0.1800 0.1800
T/K 270.454 270.934 271.222 267.979 268.447 268.999 268.503 269.986 270.522
P/MPa 0.843 0.225 0.185 3.442 2.705 1.800 1.183 0.483 0.036
wB 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.2100 0.2100 0.2100
T/K 268.939 269.449 269.938 270.553 271.086 271.395 268.077 268.470 268.923
P/MPa 3.880 3.007 2.365 1.585 0.820 0.498 2.204 2.070 3.689
wB 0.2100 0.2100 0.2100 0.2100 0.2100 0.2200 0.2200 0.2200 0.2200
T/K 269.513 269.977 270.491 270.960 271.482 268.994 268.436 270.010 270.486
P/MPa 2.325 1.547 0.752 0.194 3.860 3.077 2.359 1.755
wB 0.2200 0.2200 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400
T/K 270.988 271.483 268.877 269.461 270.028 270.518 270.930 271.494 271.950
P/MPa 1.105 0.462 4.691 3.420 3.118 2.020 1.596 0.800 0.258
continued
_____________________________________________________________________________
continued
wB 0.2400 0.2500 0.2500 0.2500 0.2500 0.2500 0.2600 0.2600 0.2600
T/K 272.245 269.072 269.576 270.128 271.130 271.525 269.531 269.954 270.493
P/MPa 0.128 3.785 3.075 2.181 0.783 0.381 4.214 3.680 2.923
wB 0.2600 0.2600 0.2600 0.2600 0.2800 0.2800 0.2800 0.2800 0.2800
T/K 271.082 271.468 271.926 272.497 269.840 270.538 270.957 271.445 271.979
P/MPa 2.187 1.662 0.988 0.279 4.369 3.224 2.689 1.882 1.404
wB 0.2800 0.2800 0.2800 0.3000 0.3000 0.3000 0.3000 0.3000 0.3000
T/K 272.465 272.465 272.784 268.445 269.027 269.466 270.143 270.641 271.018
P/MPa 0.277 4.339 0.701 3.811 1.633 1.652 1.349
wB 0.3000 0.3000 0.3300 0.3300 0.3300 0.3300 0.3300 0.3300 0.3300
T/K 271.438 271.933 267.859 268.475 268.972 269.397 269.948 270.515 271.032
P/MPa 0.964 0.223 3.622 2.053 2.356 1.947 1.144 −0.153 −0.756
wB 0.3591 0.3591 0.3591 0.3591 0.3591 0.3591 0.3591
T/K 268.225 268.594 268.977 269.516 270.019 270.425 270.995
P/MPa 3.870 1.465 2.669 −0.458 −0.750 −0.247 −0.959


wB 0.1600 0.1600 0.1600 0.1600 0.1600 0.1906 0.1906 0.1906 0.1906
T/K 307.292 307.952 308.506 308.947 309.475 308.495 308.969 309.496 309.974
P/MPa 2.554 2.133 1.900 1.487 1.256 1.778 1.459 1.194 0.921
wB 0.1906 0.2256 0.2256 0.2256 0.2256 0.2256
T/K 310.369 305.873 306.207 307.297 308.274 309.210
P/MPa 0.744 3.351 3.035 2.300 1.674 1.098

wB 0.1600 0.1600 0.1600 0.1600 0.1600 0.1906 0.1906 0.1906 0.1906
T/K 307.292 307.952 308.506 308.947 309.475 308.495 308.969 309.496 309.974
P/MPa 2.252 1.841 1.600 1.304 1.066 1.140 0.796 0.447 0.080
wB 0.1906 0.2256 0.2256 0.2256 0.2256 0.2256
T/K 310.369 305.873 306.207 307.297 308.274 309.210
P/MPa 0.181 2.909 2.712 2.034 1.484 1.018

Solvent (A): propionitrile (75% deuterated at CH2)
C3H5N/C3H3D2N 107-12-0/24300-23-0
continued
_____________________________________________________________________________
continued
wB 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000
T/K 323.698 323.695 330.240 330.239 337.046 337.039 337.037 445.521 445.513
P/MPa 5.540 5.539 2.922 2.964 0.549 0.445 0.514 1.015 0.882
wB 0.1000 0.1000 0.1000 0.1000 0.1499 0.1499 0.1499 0.1499 0.1499
T/K 445.513 454.443 463.595 463.592 330.263 330.274 338.051 338.047 343.830
P/MPa 0.820 1.858 2.894 2.834 5.203 5.211 2.282 2.249 0.575
wB 0.1499 0.1499 0.1499 0.1499 0.1499 0.1499 0.1499 0.2000 0.2000
T/K 343.827 436.837 436.823 445.574 445.555 454.465 454.469 330.240 330.247
P/MPa 0.582 0.716 0.765 1.744 1.735 2.778 2.812 5.238 5.253
wB 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000
T/K 336.994 336.992 343.826 343.832 436.736 436.730 445.503 445.498 454.431
P/MPa 2.686 2.664 0.659 0.665 0.791 0.803 1.903 1.897 3.008
wB 0.2402 0.2402 0.2402 0.2402 0.2402 0.2402 0.2402 0.2402 0.2402
T/K 330.365 330.351 330.355 330.343 335.772 335.766 341.227 341.219 342.888
P/MPa 3.865 4.352 4.666 4.714 2.837 2.628 1.061 0.967 0.580
wB 0.2533 0.2533 0.2533 0.2533 0.2533 0.2533 0.2533 0.2533 0.2533
T/K 330.270 337.948 340.070 340.049 436.726 436.737 445.534 445.527 454.467
P/MPa 4.519 1.847 1.170 1.186 0.712 0.706 1.819 1.820 3.012
wB 0.2533 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610
T/K 454.453 462.646 462.497 454.442 454.446 447.535 447.536 441.496 436.768
P/MPa 3.014 3.972 3.975 2.975 2.965 2.122 2.156 1.366 0.843
wB 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610
T/K 436.755 325.361 325.333 330.352 330.346 335.723 335.723 341.393 341.386
P/MPa 0.815 5.693 5.476 3.577 3.607 2.207 2.140 0.443 0.421

wB 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000
T/K 323.698 323.695 330.240 330.239 337.046 337.039 337.037 445.521 445.513
P/MPa 3.503 4.817 1.695 0.751 −4.110 −2.901 −2.867 0.445 −4.122
wB 0.1000 0.1000 0.1000 0.1000 0.1499 0.1499 0.1499 0.1499 0.1499

T/K 445.513 454.443 463.595 463.592 330.263 330.274 338.051 338.047 343.830
P/MPa −0.104 1.328 2.332 2.469 3.994 4.045 −0.607 0.744 −2.058
wB 0.1499 0.1499 0.1499 0.1499 0.1499 0.1499 0.1499 0.2000 0.2000
T/K 343.827 436.837 436.823 445.574 445.555 454.465 454.469 330.240 330.247
P/MPa −1.279 −0.367 −3.810 0.551 −1.090 2.052 0.082 4.914 5.007
wB 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000
T/K 336.994 336.992 343.826 343.832 436.736 436.730 445.503 445.498 454.431
P/MPa 1.975 2.148 0.113 0.286 0.471 0.554 1.492 1.518 2.591
wB 0.2402 0.2402 0.2402 0.2402 0.2402 0.2402 0.2402 0.2402 0.2402
T/K 330.365 330.351 330.355 330.343 335.772 335.766 341.227 341.219 342.888
P/MPa −0.504 3.703 4.459 4.543 1.976 2.489 0.623 0.828 0.359
continued
_____________________________________________________________________________
continued
wB 0.2533 0.2533 0.2533 0.2533 0.2533 0.2533 0.2533 0.2533 0.2533
T/K 330.270 337.948 340.070 340.049 436.726 436.737 445.534 445.527 454.467
P/MPa 1.074 0.545 0.637 0.281 0.463 1.240 1.291 2.010
wB 0.2533 0.2533 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610
T/K 454.453 462.646 462.497 454.442 454.446 447.535 447.536 441.496 436.768
P/MPa 2.301 3.406 3.497 2.319 2.326 1.077 1.264 0.510 0.603
wB 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610 0.2610
T/K 436.755 325.361 325.333 330.352 330.346 335.723 335.723 341.393 341.386
P/MPa 0.344 5.134 5.411 1.571 2.304 1.828 1.436 −0.371 −0.157

Characterization: Mn/kg.mol−1 = 21.45, Mw/.g.mol−1 = 22.1,

wB 0.0600 0.0600 0.0600 0.0600 0.0600 0.0600 0.0600 0.0600 0.0600
T/K 331.770 331.771 337.301 337.300 433.404 433.385 445.537 454.400 454.407
P/MPa 2.413 2.049 0.893 0.534 1.044 0.987 2.223 3.527 3.433
wB 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900
T/K 336.255 336.243 344.053 344.053 351.039 351.037 421.594 421.573 421.571
P/MPa 4.261 4.383 2.451 2.075 0.676 0.617 0.920 0.955 1.070
wB 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.1076
T/K 428.369 428.371 436.952 436.953 445.765 445.767 454.720 454.712 337.250
P/MPa 1.454 1.713 2.403 2.184 3.425 3.430 4.388 4.403 4.400
wB 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076
T/K 337.250 344.098 344.100 351.095 351.082 351.083 355.350 355.351 420.023
P/MPa 4.353 3.033 2.973 1.946 1.736 1.377 1.009 0.861 1.086
wB 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076
T/K 428.443 428.439 437.035 437.038 437.036 445.843 445.842 454.781 454.778
P/MPa 1.956 1.930 2.804 2.667 2.922 3.708 3.838 4.900 4.926
wB 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1600 0.1600
T/K 337.180 337.179 337.173 344.101 344.102 351.080 351.072 337.157 337.142
P/MPa 4.889 4.804 4.633 2.668 2.905 1.375 1.362 5.387 5.140
wB 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600
T/K 337.138 343.960 343.961 343.965 350.936 350.939 357.997 357.991 360.818
P/MPa 5.109 3.149 3.193 3.084 1.545 1.750 0.568 0.602 0.241
wB 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600
T/K 360.815 410.364 410.302 419.885 419.884 428.336 428.344 436.922 436.920
P/MPa 0.182 0.616 0.488 1.144 1.179 1.940 1.909 2.878 2.854
wB 0.1600 0.1600 0.1600 0.1600 0.1899 0.1899 0.1899 0.1899 0.1899
T/K 445.755 445.746 454.689 454.691 336.998 336.994 343.823 343.823 350.807
P/MPa 3.850 3.817 4.729 4.848 4.956 4.915 3.093 3.030 1.606
continued
_____________________________________________________________________________
continued
wB 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899
T/K 350.806 355.097 355.095 357.836 357.831 360.710 410.135 410.099 419.836
P/MPa 1.601 0.951 0.929 0.576 0.569 0.241 0.352 0.357 1.134
wB 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899
T/K 419.829 428.285 428.284 436.891 436.895 445.680 445.682 454.629 454.635
P/MPa 1.153 1.968 1.947 2.834 2.818 3.777 3.823 4.881 4.834
wB 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199
T/K 336.988 336.992 343.807 343.804 350.815 350.801 355.202 355.197 359.272
P/MPa 4.741 5.059 3.274 3.130 1.745 1.659 1.055 1.128 0.476
wB 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199
T/K 359.268 411.469 411.480 419.692 419.662 428.099 428.101 436.717 436.694
P/MPa 0.502 0.542 0.599 1.424 1.241 1.991 2.026 2.821 2.883
wB 0.2199 0.2199 0.2199 0.2199 0.2499 0.2499 0.2499 0.2499 0.2499
T/K 445.482 445.484 454.423 454.416 336.980 336.977 343.788 343.813 350.806
P/MPa 3.859 3.922 4.847 4.729 4.546 4.539 2.699 2.680 1.281
wB 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499
T/K 350.798 355.232 355.226 357.840 357.841 414.134 414.392 419.714 419.704
P/MPa 1.308 0.620 0.584 0.269 0.275 0.498 0.577 1.001 0.995
wB 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2750
T/K 428.141 428.149 436.737 436.713 445.540 445.539 454.457 454.465 337.076
P/MPa 1.857 1.822 2.688 2.699 3.650 3.660 4.732 4.704 4.304
wB 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750
T/K 337.069 343.873 343.877 345.600 345.581 350.878 350.880 353.764 353.758
P/MPa 4.294 2.477 2.460 2.033 2.042 0.978 0.985 0.489 0.470
wB 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750
T/K 416.490 416.452 419.623 419.624 428.112 428.111 436.712 436.673 445.469
P/MPa 0.546 0.537 0.935 0.951 1.765 1.758 2.644 2.629 3.582
wB 0.2750 0.2750 0.2750
T/K 445.463 454.396 454.380
P/MPa 3.608 4.670 4.671

wB 0.0600 0.0600 0.0600 0.0600 0.0600 0.0600 0.0600 0.0600 0.0600
T/K 331.770 331.771 337.301 337.300 433.404 433.385 445.537 454.400 454.407
P/MPa 1.324 1.593 −0.239 0.017 0.188 −0.248 0.760 2.990 2.663
wB 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900
T/K 336.255 336.243 344.053 344.053 351.039 351.037 421.594 421.573 421.571
P/MPa 3.706 3.699 1.450 1.632 0.355 0.286 0.460 0.499 0.524
wB 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.1076
T/K 428.369 428.371 436.952 436.953 445.765 445.767 454.720 454.712 337.250
P/MPa 1.173 1.100 2.068 2.140 3.093 3.098 4.210 4.175 3.679
wB 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076
T/K 337.250 344.098 344.100 351.095 351.082 351.083 355.350 355.351 420.023
P/MPa 3.863 1.572 1.640 −0.457 1.113 0.682 −0.190 −0.326 0.539
continued
_____________________________________________________________________________
continued
wB 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076 0.1076
T/K 428.443 428.439 437.035 437.038 437.036 445.843 445.842 454.781 454.778
P/MPa 1.318 1.482 2.272 1.928 2.502 3.327 3.274 4.218 4.418
wB 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1600 0.1600
T/K 337.180 337.179 337.173 344.101 344.102 351.080 351.072 337.157 337.142
P/MPa 4.137 3.640 3.614 2.078 1.532 0.308 1.042 4.759 4.415
wB 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600
T/K 337.138 343.960 343.961 343.965 350.936 350.939 357.997 357.991 360.818
P/MPa 4.642 2.519 2.577 2.399 1.091 0.824 −0.122 0.025 −0.239
wB 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600
T/K 360.815 410.364 410.302 419.885 419.884 428.336 428.344 436.922 436.920
P/MPa −0.170 −0.070 −0.011 0.705 0.612 1.774 1.799 2.561 2.595
wB 0.1600 0.1600 0.1600 0.1600 0.1899 0.1899 0.1899 0.1899 0.1899
T/K 445.755 445.746 454.689 454.691 336.998 336.994 343.823 343.823 350.807
P/MPa 3.387 3.505 3.782 4.573 4.505 4.668 2.689 2.831 1.340
wB 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899
T/K 350.806 355.097 355.095 357.836 357.831 360.710 410.135 410.099 419.836
P/MPa 1.426 0.626 0.764 0.392 0.391 0.054 0.183 0.163 0.910
wB 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899 0.1899
T/K 419.829 428.285 428.284 436.891 436.895 445.680 445.682 454.629 454.635
P/MPa 0.908 1.547 1.682 2.431 2.618 3.591 3.473 4.641 4.622
wB 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199
T/K 336.988 336.992 343.807 343.804 350.815 350.801 355.202 355.197 359.272
P/MPa 4.736 4.752 2.745 2.865 1.382 1.490 0.720 0.739 0.292
wB 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199 0.2199
T/K 359.268 411.469 411.480 419.692 419.662 428.099 428.101 436.717 436.694
P/MPa 0.244 0.263 0.325 1.001 0.950 1.757 1.702 2.693 2.642
wB 0.2199 0.2199 0.2199 0.2199 0.2499 0.2499 0.2499 0.2499 0.2499
T/K 445.482 445.484 454.423 454.416 336.980 336.977 343.788 343.813 350.806
P/MPa 3.630 3.691 4.658 4.708 4.413 4.348 2.568 2.492 1.122
wB 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499
T/K 350.798 355.232 355.226 357.840 357.841 414.134 414.392 419.714 419.704
P/MPa 1.126 0.437 0.504 0.165 0.157 0.428 0.421 0.871 0.895
wB 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2750
T/K 428.141 428.149 436.737 436.713 445.540 445.539 454.457 454.465 337.076
P/MPa 1.665 1.628 2.553 2.581 3.579 3.574 4.589 4.615 3.066
wB 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750
T/K 337.069 343.873 343.877 345.600 345.581 350.878 350.880 353.764 353.758
P/MPa 3.203 0.915 1.384 0.998 0.835 −0.072 0.000 −0.694 −0.525
wB 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750
T/K 416.490 416.452 419.623 419.624 428.112 428.111 436.712 436.673 445.469
P/MPa −0.060 −0.007 0.530 −0.150 0.869 0.586 1.964 2.289 3.316
wB 0.2750 0.2750 0.2750
T/K 445.463 454.396 454.380
P/MPa 3.305 4.278 4.007
_____________________________________________________________________________

C3H5N/C3H3D2N 107-12-0/24300-23-0

wB 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800
T/K 357.740 357.741 364.997 364.993 372.356 372.360 379.893 379.888 387.404
P/MPa 3.687 3.572 2.253 2.670 1.582 1.547 1.306 1.058 0.913
wB 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800
T/K 387.413 395.342 395.341 403.261 403.256 411.385 411.387 419.576 419.550
P/MPa 0.956 0.836 0.911 0.999 0.952 1.301 1.613 1.865 1.820
wB 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.1101 0.1101 0.1101
T/K 427.986 427.979 436.500 436.496 445.337 445.331 357.758 357.760 365.093
P/MPa 2.442 2.653 3.267 3.221 4.257 4.172 5.301 5.141 3.882
wB 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101
T/K 365.090 372.385 372.383 380.021 380.015 387.561 387.560 395.380 395.383
P/MPa 3.782 3.423 3.031 2.269 2.364 2.172 2.038 1.815 1.939
wB 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101
T/K 403.309 403.290 411.400 411.397 411.393 419.617 419.610 428.072 428.067
P/MPa 1.885 1.872 2.510 2.338 1.591 2.763 2.728 3.441 3.520
wB 0.1101 0.1101 0.1101 0.1101 0.1200 0.1200 0.1200 0.1200 0.1200
T/K 436.644 436.648 445.454 445.456 357.802 357.800 365.036 365.032 365.033
P/MPa 4.157 4.086 5.234 5.289 5.495 5.274 3.549 4.109 4.973
wB 0.1200 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447
T/K 365.042 365.034 365.039 372.386 372.391 379.919 379.920 387.571 387.572
P/MPa 3.935 4.785 4.768 3.573 3.491 2.842 2.670 2.583 2.472
wB 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447
T/K 395.378 395.380 403.301 403.303 411.419 411.421 419.613 419.608 428.062
P/MPa 2.513 2.350 2.543 2.624 2.724 2.161 3.116 3.078 3.534
wB 0.1447 0.1447 0.1447 0.1447 0.1447 0.1500 0.1500 0.1500 0.1500
T/K 428.064 436.687 436.684 445.457 445.458 357.796 357.794 365.057 365.038
P/MPa 3.658 4.475 4.358 5.160 5.159 5.693 5.807 4.340 4.329
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 372.399 372.390 379.932 379.930 387.551 387.550 395.365 395.370 403.281
P/MPa 3.342 3.359 2.656 2.674 2.305 2.300 2.155 2.142 2.245
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 403.280 411.410 411.409 411.404 419.630 419.629 419.628 428.095 428.092
P/MPa 2.244 2.580 2.620 2.579 2.986 3.015 2.948 3.544 3.595
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1799 0.1799 0.1799 0.1799
T/K 436.673 436.675 445.478 445.474 445.471 357.783 357.786 365.044 365.038
P/MPa 4.254 4.296 5.091 5.016 5.116 5.770 5.510 4.360 4.312
continued
_____________________________________________________________________________
continued
wB 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799
T/K 372.394 372.391 379.930 379.930 387.575 387.575 395.401 395.393 403.293
P/MPa 3.393 3.047 2.754 2.796 2.232 2.282 2.201 2.085 2.141
wB 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799
T/K 403.286 411.442 411.435 419.663 419.656 428.114 428.114 436.551 436.557
P/MPa 2.221 2.485 2.518 2.957 2.944 3.608 3.586 4.288 4.332
wB 0.1799 0.1799 0.1799 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101
T/K 445.492 445.484 445.491 357.790 357.791 365.030 365.043 372.407 372.406
P/MPa 5.110 5.100 4.893 5.199 5.179 3.898 3.859 2.902 2.888
wB 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101
T/K 379.933 379.930 387.540 387.541 395.392 395.390 403.305 403.303 411.427
P/MPa 2.254 2.255 1.911 1.888 1.778 1.785 1.901 1.927 2.198
wB 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101
T/K 411.427 419.658 419.655 428.105 428.104 436.673 436.670 445.498 445.493
P/MPa 2.181 2.655 2.661 3.255 3.302 3.993 3.986 4.817 4.810
wB 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400
T/K 357.803 357.802 365.054 365.051 372.419 372.416 379.949 379.942 387.470
P/MPa 4.785 4.774 3.474 3.465 2.527 2.534 1.931 1.927 1.596
wB 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400
T/K 387.467 395.430 395.425 403.326 403.322 411.443 411.441 419.684 419.684
P/MPa 1.594 1.518 1.512 1.648 1.614 1.964 1.965 2.443 2.452
wB 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2726 0.2726 0.2726
T/K 428.131 428.133 436.696 436.693 445.529 445.535 350.782 350.783 357.901
P/MPa 3.037 3.072 3.802 3.794 4.751 4.792 4.841 4.879 3.343
wB 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726
T/K 357.895 365.668 365.646 372.512 372.510 380.038 380.031 387.713 387.690
P/MPa 3.325 2.139 2.089 1.362 1.334 0.790 0.782 0.578 0.573
wB 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726
T/K 395.511 395.508 403.446 403.441 411.723 411.703 419.644 419.644 428.302
P/MPa 0.628 0.633 0.885 0.886 1.308 1.348 1.848 1.845 2.526
wB 0.2726 0.2726 0.2726 0.2726 0.2726 0.3073 0.3073
T/K 428.297 436.690 436.684 445.492 445.485 343.805 343.803
P/MPa 2.521 3.343 3.292 4.234 4.123 4.981 4.984

wB 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800
T/K 357.740 357.741 364.997 364.993 372.356 372.360 379.893 379.888 387.404
P/MPa 3.059 3.354 2.133 2.043 1.293 1.309 0.578 0.753 0.455
wB 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800
T/K 387.413 395.342 395.341 403.261 403.256 411.385 411.387 419.576 419.550
P/MPa 0.189 0.356 0.186 0.577 0.531 0.955 0.738 1.317 1.545
wB 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.1101 0.1101 0.1101
T/K 427.986 427.979 436.500 436.496 445.337 445.331 357.758 357.760 365.093
P/MPa 2.101 2.077 2.737 2.560 3.746 3.747 5.139 5.020 3.691
continued
_____________________________________________________________________________
continued
wB 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101
T/K 365.090 372.385 372.383 380.021 380.015 387.561 387.560 395.380 395.383
P/MPa 3.655 1.673 2.769 2.026 2.069 1.726 1.731 1.588 1.239
wB 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101 0.1101
T/K 403.309 403.290 411.400 411.397 411.393 419.617 419.610 428.072 428.067
P/MPa 1.712 1.635 1.798 1.234 1.884 2.330 2.416 2.889 3.106
wB 0.1101 0.1101 0.1101 0.1101 0.1200 0.1200 0.1200 0.1200 0.1200
T/K 436.644 436.648 445.454 445.456 357.802 357.800 365.036 365.032 365.033
P/MPa 3.797 3.845 4.696 4.198 4.609 3.342 2.014 3.902 3.828
wB 0.1200 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447
T/K 365.042 365.034 365.039 372.386 372.391 379.919 379.920 387.571 387.572
P/MPa 3.821 4.308 4.311 3.100 3.137 2.475 2.527 1.972 1.993
wB 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447 0.1447
T/K 395.378 395.380 403.301 403.303 411.419 411.421 419.613 419.608 428.062
P/MPa 1.672 2.079 1.973 2.048 2.111 2.373 2.871 2.741 3.362
wB 0.1447 0.1447 0.1447 0.1447 0.1447 0.1500 0.1500 0.1500 0.1500
T/K 428.064 436.687 436.684 445.457 445.458 357.796 357.794 365.057 365.038
P/MPa 3.306 4.181 4.019 4.835 4.897 5.602 5.475 4.142 4.169
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 372.399 372.390 379.932 379.930 387.551 387.550 395.365 395.370 403.281
P/MPa 3.032 3.047 2.429 2.346 2.074 2.046 1.878 1.903 2.037
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 403.280 411.410 411.409 411.404 419.630 419.629 419.628 428.095 428.092
P/MPa 2.029 2.382 2.204 2.222 2.631 2.776 2.731 3.294 3.276
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1799 0.1799 0.1799 0.1799
T/K 436.673 436.675 445.478 445.474 445.471 357.783 357.786 365.044 365.038
P/MPa 3.941 4.052 4.841 4.778 4.805 5.475 5.422 3.998 4.008
wB 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799
T/K 372.394 372.391 379.930 379.930 387.575 387.575 395.401 395.393 403.293
P/MPa 2.751 3.046 2.062 2.424 1.949 1.965 1.835 1.846 1.958
wB 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799
T/K 403.286 411.442 411.435 419.663 419.656 428.114 428.114 436.551 436.557
P/MPa 1.954 2.203 2.192 2.633 2.672 3.354 3.313 3.990 3.961
wB 0.1799 0.1799 0.1799 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101
T/K 445.492 445.484 445.491 357.790 357.791 365.030 365.043 372.407 372.406
P/MPa 4.820 4.843 4.500 4.938 4.997 3.597 3.652 2.6250 2.761
wB 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101
T/K 379.933 379.930 387.540 387.541 395.392 395.390 403.305 403.303 411.427
P/MPa 2.109 2.070 1.697 1.757 1.657 1.679 1.744 1.723 2.124
wB 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101 0.2101
T/K 411.427 419.658 419.655 428.105 428.104 436.673 436.670 445.498 445.493
P/MPa 2.527 2.508 3.119 3.081 3.837 3.835 4.709 4.713
continued
_____________________________________________________________________________
continued
wB 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400
T/K 357.803 357.802 365.054 365.051 372.419 372.416 379.949 379.942 387.470
P/MPa 3.863 3.711 2.925 2.885 1.850 1.669 0.808 0.968 0.323
wB 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400
T/K 387.467 395.430 395.425 403.326 403.322 411.443 411.441 419.684 419.684
P/MPa 0.097 −0.144 0.373 0.579 −0.119 1.225 0.985 0.497 1.566
wB 0.2400 0.2400 0.2400 0.2400 0.2400 0.2400 0.2726 0.2726 0.2726
T/K 428.131 428.133 436.696 436.693 445.529 445.535 350.782 350.783 357.901
P/MPa 2.303 1.513 2.048 2.533 4.146 2.331 3.881 3.195 1.081
wB 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726
T/K 357.895 365.668 365.646 372.512 372.510 380.038 380.031 387.713 387.690
P/MPa 0.787 0.551 1.166 −0.653 −0.137 −0.217 −0.354 −0.448 0.045
wB 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726 0.2726
T/K 395.511 395.508 403.446 403.441 411.723 411.703 419.644 419.644 428.302
P/MPa 0.195 0.269 0.290 0.174 −0.087 −0.232 1.166 1.211 1.924
wB 0.2726 0.2726 0.2726 0.2726 0.2726 0.3073 0.3073
T/K 428.297 436.690 436.684 445.492 445.485 343.805 343.803
P/MPa 1.284 1.494 2.093 3.297 3.256 4.370 4.278

Solvent (A): propionitrile (63.55% deuterated at CH2)
C3H5N/C3H3D2N 107-12-0/24300-23-0
wB 0.1800 0.1800 0.1800 0.1800 0.1800 0.1800 0.1800 0.1800 0.1800
T/K 372.424 372.414 379.970 379.948 387.582 387.588 395.407 395.408 403.104
P/MPa 5.410 5.410 4.542 4.553 3.998 3.977 3.686 3.706 3.612
wB 0.1800 0.1800 0.1800 0.1800 0.2098 0.2098 0.2098 0.2098 0.2098
T/K 403.112 411.471 411.469 419.685 372.404 372.415 372.415 372.415 380.378
P/MPa 3.620 3.759 3.766 4.106 4.879 5.401 5.385 4.957 3.992
wB 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098
T/K 380.344 387.507 387.501 395.424 395.416 403.327 403.325 403.325 411.445
P/MPa 4.004 3.510 3.566 3.340 3.324 3.379 3.625 3.322 3.554
wB 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098
T/K 411.443 419.645 419.644 428.072 428.080 436.643 436.646 445.447 445.446
P/MPa 3.458 4.211 4.290 4.736 4.737 5.381 5.424 6.063 6.116
wB 0.2098 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401
T/K 419.650 365.080 365.078 372.387 372.388 380.020 380.015 387.610 387.607
P/MPa 4.423 5.712 5.711 4.510 4.509 3.644 3.659 3.121 3.115
wB 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401
T/K 395.885 395.866 403.342 403.343 411.695 411.666 419.709 419.700 428.139
P/MPa 2.872 2.866 2.847 2.856 3.052 3.019 3.505 3.520 4.026
continued
_____________________________________________________________________________
continued
wB 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2700 0.2700 0.2700
T/K 428.143 436.720 436.724 445.520 445.520 445.522 365.092 365.087 372.436
P/MPa 4.054 4.717 4.709 5.515 5.536 5.485 5.552 5.597 4.408
wB 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700
T/K 372.430 379.984 379.988 387.570 387.570 395.407 395.407 403.304 403.303
P/MPa 4.348 3.512 3.514 2.952 2.958 2.683 2.716 2.674 2.684
wB 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700
T/K 411.453 411.449 419.630 419.630 428.111 428.110 436.743 436.723 445.577
P/MPa 2.944 2.927 3.330 3.310 3.859 3.835 4.525 4.521 5.350
wB 0.2700 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964
T/K 445.528 360.685 360.684 365.226 365.183 372.427 372.428 372.431 379.999
P/MPa 5.325 6.047 6.067 5.150 5.140 3.691 3.775 3.817 3.008
wB 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964
T/K 379.998 387.592 387.596 395.420 395.425 403.292 403.283 411.438 411.424
P/MPa 3.024 2.549 2.550 2.339 2.342 2.398 2.362 2.595 2.602
wB 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964
T/K 419.485 419.472 428.097 428.098 436.487 436.485 445.468 445.437 454.411
P/MPa 2.981 2.989 3.532 3.559 4.396 4.356 5.259 5.169 6.119

wB 0.1800 0.1800 0.1800 0.1800 0.1800 0.1800 0.1800 0.1800 0.1800
T/K 372.424 372.414 379.970 379.948 387.582 387.588 395.407 395.408 403.104
P/MPa 5.105 5.268 4.203 4.395 3.741 3.800 3.423 3.403 3.432
wB 0.1800 0.1800 0.1800 0.1800 0.2098 0.2098 0.2098 0.2098 0.2098
T/K 403.112 411.471 411.469 419.685 372.404 372.415 372.415 372.415 380.378
P/MPa 3.372 3.563 3.583 3.902 4.693 4.715 4.710 4.714 3.808
wB 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098
T/K 380.344 387.507 387.501 395.424 395.416 403.327 403.325 403.325 411.445
P/MPa 3.853 3.352 3.389 3.084 3.098 3.051 3.118 3.123 3.294
wB 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098 0.2098
T/K 411.443 419.645 419.644 428.072 428.080 436.643 436.646 445.447 445.446
P/MPa 3.288 4.051 3.994 4.505 4.528 5.202 5.174 5.951 5.929
wB 0.2098 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401
T/K 419.650 365.080 365.078 372.387 372.388 380.020 380.015 387.610 387.607
P/MPa 4.154 5.586 5.549 4.291 4.420 3.412 3.489 2.865 2.948
wB 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401
T/K 395.885 395.866 403.342 403.343 411.695 411.666 419.709 419.700 428.139
P/MPa 2.647 2.706 2.657 2.661 2.829 2.911 3.321 3.339 3.906
wB 0.2401 0.2401 0.2401 0.2401 0.2401 0.2401 0.2700 0.2700 0.2700
T/K 428.143 436.720 436.724 445.520 445.520 445.522 365.092 365.087 372.436
P/MPa 4.575 4.400 5.371 5.315 5.0290 4.561 4.941 3.007
wB 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700
T/K 372.430 379.984 379.988 387.570 387.570 395.407 395.407 403.304 403.303
P/MPa 3.786 2.944 2.421 2.422 2.423 1.903 2.539 2.157 2.252
continued
_____________________________________________________________________________
continued
wB 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700 0.2700
T/K 411.453 411.449 419.630 419.630 428.111 428.110 436.743 436.723 445.577
P/MPa 2.297 2.506 2.724 2.891 3.340 3.333 3.844 3.803 4.487
wB 0.2700 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964
T/K 445.528 360.685 360.684 365.226 365.183 372.427 372.428 372.431 379.999
P/MPa 4.661 5.559 5.001 3.842 2.937 2.299 1.875 2.998 1.921
wB 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964
T/K 379.998 387.592 387.596 395.420 395.425 403.292 403.283 411.438 411.424
P/MPa 2.240 1.297 1.125 1.557 1.221 1.005 1.628 1.920 1.609
wB 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964 0.2964
T/K 419.485 419.472 428.097 428.098 436.487 436.485 445.468 445.437 454.411
P/MPa 2.187 1.591 2.971 3.021 3.491 3.662 3.286 3.225 5.652

C3H5N/C3H3D2N 107-12-0/24300-23-0
wB 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399
T/K 373.109 373.104 373.105 380.614 380.623 388.293 388.293 388.293 388.293
P/MPa 5.777 5.735 5.555 4.700 5.179 3.590 4.146 3.389 4.268
wB 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399
T/K 396.073 396.076 403.969 403.971 412.105 412.145 420.378 420.372 428.821
P/MPa 3.794 3.648 3.725 3.651 3.845 3.741 4.223 3.960 4.385
wB 0.1399 0.1399 0.1399 0.1399 0.1700 0.1700 0.1700 0.1700 0.1700
T/K 428.847 437.480 437.450 446.484 373.092 373.092 373.095 380.624 380.623
P/MPa 4.616 5.349 5.181 5.891 5.711 5.715 5.698 4.744 4.733
wB 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700
T/K 388.244 388.245 396.093 396.085 404.061 404.031 413.878 420.348 420.350
P/MPa 4.092 4.100 3.743 3.746 3.629 3.633 3.803 4.084 4.094
wB 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.2202 0.2202 0.2202
T/K 428.803 428.802 437.412 437.415 446.239 446.209 372.913 372.917 372.915
P/MPa 4.490 4.497 5.099 5.102 5.860 5.855 5.851 5.919 5.835
wB 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202
T/K 380.578 380.575 388.239 388.241 396.057 396.063 403.989 403.989 403.989
P/MPa 4.838 4.871 4.105 4.367 3.885 3.905 3.762 3.820 3.775
wB 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202
T/K 403.989 412.142 412.127 420.351 420.337 428.830 428.830 437.450 428.830
P/MPa 3.720 3.826 3.670 4.119 4.095 4.655 4.655 5.143 4.573
wB 0.2202 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299
T/K 437.431 372.488 372.492 379.987 387.629 387.629 395.570 395.567 403.590
P/MPa 5.101 6.065 6.082 5.157 4.407 4.262 3.907 3.919 3.799
continued
_____________________________________________________________________________
continued
wB 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299
T/K 403.606 411.920 411.938 420.160 420.145 428.615 428.604 437.210 437.189
P/MPa 3.729 3.894 3.895 4.171 4.124 4.632 4.699 5.213 5.132
wB 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588
T/K 380.009 380.009 387.600 387.593 395.371 395.384 403.281 403.320 411.465
P/MPa 4.883 4.868 4.189 4.218 3.789 3.826 3,694 3.742 3.823
wB 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588
T/K 411.469 419.692 419.679 428.165 428.154 436.707 436.691
P/MPa 3.814 4.079 4.082 4.542 4.561 5.134 5.139
wB 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399
T/K 373.109 373.104 373.105 380.614 380.623 388.293 388.293 388.293 388.293
P/MPa 5.344 5.154 5.306 4.279 4.337 3.590 3.611 3.389 3.325
wB 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399 0.1399
T/K 396.073 396.076 403.969 403.971 412.105 412.145 420.378 420.372 428.821
P/MPa 3.272 3.400 3.187 2.980 3.476 3.424 3.715 3.812 4.241
wB 0.1399 0.1399 0.1399 0.1399 0.1700 0.1700 0.1700 0.1700 0.1700
T/K 428.847 437.480 437.450 446.484 373.092 373.092 373.095 380.624 380.623
P/MPa 4.378 4.730 4.764 5.561 5.560 5.553 5.592 4.4960 4.509
wB 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700
T/K 388.244 388.245 396.093 396.085 404.061 404.031 413.878 420.348 420.350
P/MPa 3.875 3.916 3.481 3.528 3.400 3.369 3.564 3.896 3.858
wB 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.2202 0.2202 0.2202
T/K 428.803 428.802 437.412 437.415 446.239 446.209 372.913 372.917 372.915
P/MPa 4.264 4.319 4.903 4.924 5.653 5.683 5.515 5.652 5.729
wB 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202
T/K 380.578 380.575 388.239 388.241 396.057 396.063 403.989 403.989 403.989
P/MPa 4.725 4.729 4.108 4.013 3.629 3.717 3.606 3.585 3.628
wB 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202 0.2202
T/K 403.989 412.142 412.127 420.351 420.337 428.830 428.830 437.450 428.830
P/MPa 3.631 3.738 3.743 3.991 4.015 4.492 4.492 5.059 4.456
wB 0.2202 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299
T/K 437.431 372.488 372.492 379.987 387.629 387.629 395.570 395.567 403.590
P/MPa 5.072 5.976 5.999 4.778 4.247 4.192 3.806 3.818 3.678
wB 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299 0.2299
T/K 403.606 411.920 411.938 420.160 420.145 428.615 428.604 437.210 437.189
P/MPa 3.689 3.790 3.782 4.066 4.052 4.531 4.545 5.129 5.096
wB 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588
T/K 380.009 380.009 387.600 387.593 395.371 395.384 403.281 403.320 411.465
P/MPa 4.625 4.677 4.025 3.884 3.715 3.673 3.529 3.546 3.721
wB 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588 0.2588
T/K 411.469 419.692 419.679 428.165 428.154 436.707 436.691
P/MPa 3.737 4.019 4.052 4.441 4.436 5.045 5.035
_____________________________________________________________________________


wB 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687
T/K 436.982 436.984 428.529 420.105 420.101 413.475 403.751 403.747 397.076
P/MPa 4.593 4.560 3.946 3.229 3.170 2.763 2.275 2.269 2.077
wB 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687
T/K 397.085 387.998 387.989 380.095 380.110 380.107 372.753 372.723 366.403
P/MPa 2.044 1.997 2.001 2.174 1.401 2.176 2.601 2.607 3.198
wB 0.1687 0.1687 0.1687 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799
T/K 366.009 358.121 358.116 365.993 365.996 373.340 373.345 380.978 380.974
P/MPa 3.237 4.333 4.405 4.905 4.924 4.151 3.995 3.521 3.434
wB 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799
T/K 388.677 388.669 396.524 396.529 396.529 396.529 404.434 404.432 412.646
P/MPa 3.140 2.902 3.080 3.046 2.955 3.013 3.299 3.212 3.456
wB 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1999 0.1999
T/K 412.646 420.921 420.904 429.373 429.330 437.974 437.977 437.501 437.500
P/MPa 3.388 3.956 3.871 4.423 4.230 5.206 5.240 5.261 5.333
wB 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999
T/K 437.510 428.865 428.857 420.705 420.674 412.373 412.350 404.353 404.339
P/MPa 5.477 4.726 4.522 4.183 3.909 3.583 3.589 3.244 3.286
wB 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999
T/K 396.419 396.415 388.628 381.025 381.030 381.030 373.334 373.328 366.011
P/MPa 3.130 3.049 3.073 3.366 4.238 3.367 3.971 3.999 4.599
wB 0.1999 0.1999 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200
T/K 366.011 366.016 365.570 365.567 373.014 373.018 380.604 380.601 388.270
P/MPa 4.717 4.790 4.655 4.630 3.779 3.736 3.156 3.165 2.861
wB 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200
T/K 388.259 396.102 396.100 403.934 403.933 412.096 412.100 420.560 420.572
P/MPa 2.864 2.800 2.813 2.913 2.932 3.235 3.221 3.710 3.699
wB 0.2200 0.2200 0.2200 0.2200 0.2308 0.2459 0.2459 0.2459 0.2459
T/K 428.894 428.892 437.472 437.482 437.064 437.175 437.181 428.700 428.636
P/MPa 4.297 4.293 5.005 5.023 4.683 4.651 4.676 3.932 4.050
wB 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459
T/K 420.286 420.277 420.214 412.202 412.045 404.140 404.135 396.033 396.035
P/MPa 3.452 3.474 3.473 3.035 3.002 2.523 2.446 2.314 2.341
wB 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459
T/K 388.125 388.129 380.387 380.385 372.911 372.914 365.658 365.666 358.452
P/MPa 2.433 2.422 2.748 2.762 3.258 3.228 4.060 4.232 5.406
continued
_____________________________________________________________________________
continued
wB 0.2459 0.2459 0.2798 0.2798 0.2798 0.2798 0.2798 0.2798 0.2798
T/K 358.449 358.453 437.980 429.468 429.462 429.464 420.935 420.934 412.739
P/MPa 5.451 5.388 3.211 2.832 2.759 2.532 1.932 1.881 1.004
wB 0.2798 0.2798 0.2798 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971
T/K 412.710 344.822 344.826 438.267 438.256 429.743 429.731 429.728 421.267
P/MPa 0.969 0.644 0.714 3.767 3.849 3.112 2.980 2.976 2.213
wB 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971
T/K 421.249 413.028 413.027 413.024 404.747 404.741 396.954 358.883 358.883
P/MPa 2.192 1.618 1.600 1.670 0.963 0.979 0.637 0.757 0.778
wB 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971
T/K 351.969 351.969 344.974 344.967 406.035 412.749 420.973 429.415 437.999
P/MPa 1.693 1.698 2.988 3.066 0.707 1.360 2.665 2.767 3.618

wB 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687
T/K 436.982 436.984 428.529 420.105 420.101 413.475 403.751 403.747 397.076
P/MPa 4.075 3.939 2.479 2.155 2.935 2.118 1.765 1.771 1.411
wB 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687 0.1687
T/K 397.085 387.998 387.989 380.095 380.110 380.107 372.753 372.723 366.403
P/MPa 1.748 1.569 1.615 1.886 −0.373 1.739 2.217 2.135 2.904
wB 0.1687 0.1687 0.1687 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799
T/K 366.009 358.121 358.116 365.993 365.996 373.340 373.345 380.978 380.974
P/MPa 2.979 4.216 3.897 4.729 4.760 3.769 3.905 3.245 3.280
wB 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799
T/K 388.677 388.669 396.524 396.529 396.529 396.529 404.434 404.432 412.646
P/MPa 2.964 3.015 2.815 2.894 2.909 2.895 2.912 2.979 3.200
wB 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1799 0.1999 0.1999
T/K 412.646 420.921 420.904 429.373 429.330 437.974 437.977 437.501 437.500
P/MPa 3.252 3.794 3.811 4.423 4.376 5.097 5.093 5.180 5.091
wB 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999
T/K 437.510 428.865 428.857 420.705 420.674 412.373 412.350 404.353 404.339
P/MPa 5.194 4.351 4.393 3.708 3.861 3.311 3.328 3.006 3.058
wB 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999
T/K 396.419 396.415 388.628 381.025 381.030 381.030 373.334 373.328 366.011
P/MPa 2.841 2.943 2.976 3.294 3.341 3.312 3.866 3.846 4.753
wB 0.1999 0.1999 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200
T/K 366.011 366.016 365.570 365.567 373.014 373.018 380.604 380.601 388.270
P/MPa 4.740 4.719 3.941 3.904 2.780 3.340 2.656 2.842 2.443
wB 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200 0.2200
T/K 388.259 396.102 396.100 403.934 403.933 412.096 412.100 420.560 420.572
P/MPa 2.393 2.186 2.313 2.514 2.572 2.862 2.852 3.355 3.361
wB 0.2200 0.2200 0.2200 0.2200 0.2308 0.2459 0.2459 0.2459 0.2459
T/K 428.894 428.892 437.472 437.482 437.064 437.175 437.181 428.700 428.636
P/MPa 3.848 3.773 4.513 4.497 4.644 3.676 3.596 1.903 3.113
continued
_____________________________________________________________________________
continued
wB 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459
T/K 420.286 420.277 420.214 412.202 412.045 404.140 404.135 396.033 396.035
P/MPa 1.939 2.197 1.978 0.418 0.075 −1.632 −2.350 −3.799 −2.979
wB 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459 0.2459
T/K 388.125 388.129 380.387 380.385 372.911 372.914 365.658 365.666 358.452
P/MPa −2.024 −1.773 −2.851 −2.208 −1.389 −1.877 −2.593 −1.551 1.046
wB 0.2459 0.2459 0.2798 0.2798 0.2798 0.2798 0.2798 0.2798 0.2798
T/K 358.449 358.453 437.980 429.468 429.462 429.464 420.935 420.934 412.739
P/MPa −1.537 −1.562 3.092 2.003 1.453 2.316 0.451 1.073 −4.083
wB 0.2798 0.2798 0.2798 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971
T/K 412.710 344.822 344.826 438.267 438.256 429.743 429.731 429.728 421.267
P/MPa −1.355 −0.010 −0.119 3.627 3.711 2.884 2.865 2.864 2.152
wB 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971
T/K 421.249 413.028 413.027 413.024 404.747 404.741 396.954 358.883 358.883
P/MPa 2.117 −2.544 0.959 0.725 −0.169 −0.153 −1.035 0.111 −0.306
wB 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971 0.2971
T/K 351.969 351.969 344.974 344.967 406.035 412.749 420.973 429.415 437.999
P/MPa 1.036 1.225 2.440 1.469 −0.756 0.352 1.426 2.522 3.348


wB 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100
T/K 298.411 298.417 300.909 300.912 304.551 304.550 304.548 433.682 433.647
P/MPa 3.855 3.881 2.595 2.622 0.970 0.884 0.945 0.722 0.716
wB 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100
T/K 436.659 436.648 445.435 445.434 445.430 454.325 454.326 463.495 463.490
P/MPa 1.141 1.135 2.199 2.282 2.249 3.555 3.552 4.830 4.842
wB 0.1100 0.1100 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401
T/K 463.484 463.487 298.413 298.407 301.744 301.746 305.074 307.000 306.987
P/MPa 4.757 4.673 4.434 4.431 2.763 2.740 1.272 0.495 0.501
wB 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401
T/K 431.523 431.515 436.657 436.664 445.455 445.436 454.385 454.377 463.517
P/MPa 0.613 0.607 1.309 1.286 2.487 2.478 3.733 3.706 4.969
wB 0.1401 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699
T/K 463.506 299.564 299.418 301.930 301.903 305.638 305.560 308.075 308.082
P/MPa 4.999 4.609 4.914 3.627 3.589 2.294 1.825 0.860 1.037
wB 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699
T/K 431.307 431.300 436.635 436.638 445.431 445.424 454.336 455.293 455.293
P/MPa 0.720 0.825 1.418 1.550 2.791 2.760 3.906 3.987 3.981
continued
_____________________________________________________________________________
continued
wB 0.1699 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999
T/K 463.488 298.698 298.691 301.242 301.215 304.599 304.609 306.836 306.866
P/MPa 5.198 4.400 4.386 3.097 3.104 1.548 1.572 0.674 0.689
wB 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999
T/K 433.304 433.303 436.649 436.646 445.412 445.426 454.364 454.359 463.517
P/MPa 0.943 0.991 1.460 1.469 2.663 2.653 3.876 3.881 5.222
wB 0.1999 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301
T/K 463.520 294.662 294.663 294.674 298.524 298.527 298.522 301.023 301.014
P/MPa 5.207 4.966 5.030 5.011 2.894 3.026 3.087 1.854 1.889
wB 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301
T/K 303.396 303.411 303.408 304.645 304.647 431.698 431.701 436.840 436.841
P/MPa 1.239 1.075 1.465 1.047 1.147 0.657 0.672 1.360 1.377
wB 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2581 0.2581 0.2581
T/K 445.825 445.819 454.766 454.759 463.931 463.929 294.668 294.670 298.405
P/MPa 2.626 2.600 3.842 3.846 5.346 5.407 5.183 5.193 3.291
wB 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581
T/K 298.404 300.847 300.853 304.522 304.533 431.546 431.558 435.041 435.039
P/MPa 3.258 2.104 2.169 0.578 0.574 0.559 0.575 1.056 1.060
wB 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581
T/K 439.829 439.790 445.466 445.456 454.364 454.367 463.608 463.610
P/MPa 1.704 1.708 2.503 2.497 3.694 3.753 5.042 4.984

wB 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100
T/K 298.411 298.417 300.909 300.912 304.551 304.550 304.548 433.682 433.647
P/MPa 2.884 3.316 1.645 1.592 −0.103 0.147 0.198 −0.098 −0.246
wB 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100 0.1100
T/K 436.659 436.648 445.435 445.434 445.430 454.325 454.326 463.495 463.490
P/MPa 0.314 0.246 1.254 1.282 1.141 3.019 2.795 4.043 4.017
wB 0.1100 0.1100 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401
T/K 463.484 463.487 298.413 298.407 301.744 301.746 305.074 307.000 306.987
P/MPa 3.137 2.334 4.206 4.195 2.407 2.546 0.998 0.261 0.272
wB 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401 0.1401
T/K 431.523 431.515 436.657 436.664 445.455 445.436 454.385 454.377 463.517
P/MPa 0.279 0.378 0.958 1.061 2.323 2.260 3.533 3.514 4.666
wB 0.1401 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699
T/K 463.506 299.564 299.418 301.930 301.903 305.638 305.560 308.075 308.082
P/MPa 4.721 4.579 4.687 3.327 3.347 1.566 1.664 0.659 0.715
wB 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699 0.1699
T/K 431.307 431.300 436.635 436.638 445.431 445.424 454.336 455.293 455.293
P/MPa 0.613 0.554 1.343 1.215 2.469 2.448 3.678 3.623 3.631
wB 0.1699 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999
T/K 463.488 298.698 298.691 301.242 301.215 304.599 304.609 306.836 306.866
P/MPa 5.014 3.980 4.111 2.791 2.801 1.200 1.382 0.458 0.432
continued
_____________________________________________________________________________
continued
wB 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999 0.1999
T/K 433.304 433.303 436.649 436.646 445.412 445.426 454.364 454.359 463.517
P/MPa 0.848 0.839 1.303 1.335 2.513 2.503 3.794 3.799 5.014
wB 0.1999 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301
T/K 463.520 294.662 294.663 294.674 298.524 298.527 298.522 301.023 301.014
P/MPa 5.036 1.051 3.672 −2.596 −1.244 1.298 1.044 −9.850 −3.048
wB 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301
T/K 303.396 303.411 303.408 304.645 304.647 431.698 431.701 436.840 436.841
P/MPa −2.994 −6.011 0.470 −2.238 −1.003 0.473 0.496 1.216 1.199
wB 0.2301 0.2301 0.2301 0.2301 0.2301 0.2301 0.2581 0.2581 0.2581
T/K 445.825 445.819 454.766 454.759 463.931 463.929 294.668 294.670 298.405
P/MPa 2.389 2.389 3.595 3.623 4.663 4.910 −1.464 1.175 −3.335
wB 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581
T/K 298.404 300.847 300.853 304.522 304.533 431.546 431.558 435.041 435.039
P/MPa −1.763 −1.739 −1.038 −3.486 −2.691 0.404 0.320 0.755 0.811
wB 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581 0.2581
T/K 439.829 439.790 445.466 445.456 454.364 454.367 463.608 463.610
P/MPa 1.500 1.411 2.260 2.286 3.225 3.308 4.716 4.714
Polymer (B): poly(vinyl acetate) 1999BEY


wB 0.06 0.06 0.06 0.06 0.06 0.06
T/K 516.55 519.35 524.95 531.45 536.25 541.15
P/bar 316.0 302.0 278.0 254.0 246.0 243.0
Polymer (B): poly(vinyl acetate) 1999BEY


wB 0.06 0.06 0.06 0.06 0.06 0.06
T/K 445.65 451.75 460.45 469.55 478.45 490.85
P/bar 270.6 168.2 115.9 97.2 84.2 98.3
_____________________________________________________________________________
Polymer (B): poly(vinyl chloride) 1985GE1

Solvent (A): 1,2-dimethylbenzene C8H10 95-47-6

T/K 323.45 320.55 316.45 312.45 309.15
P/bar 1 250 500 750 1000

Solvent (A): phenetole C8H10O 103-73-1

T/K 295.65 292.85 290.15 288.45 287.05
P/bar 1 250 500 750 1000

Solvent (A): phenetole C8H10O 103-73-1

T/K 317.65 313.35 311.05 309.85 309.05
P/bar 1 250 500 750 1000
_____________________________________________________________________________

____________________________________________________________________________________
____________________________________________________________________________________
Ethylene/1-butene copolymer
n-heptane 1996LOO
____________________________________________________________________________________
Ethylene/1-hexene copolymer
n-heptane 1996LOO
____________________________________________________________________________________
Ethylene/methyl acrylate copolymer
n-hexane 1994LOS
____________________________________________________________________________________
Ethylene/4-methyl-1-pentene copolymer
n-heptane 1996LOO
____________________________________________________________________________________
Ethylene/1-octene copolymer
cyclohexane 1996LOO
n-heptane 1996LOO
n-hexane 1996LOO
2-methylpentane 1996LOO
____________________________________________________________________________________
n-heptane 1996LOO
____________________________________________________________________________________
cyclopentane 1999BEY
cyclopentene 1999BEY
____________________________________________________________________________________
water 2001KUN
____________________________________________________________________________________
N-Isopropylacrylamide/acrylic acid copolymer
water 1993OTA
water 2000YAM
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
amide-D-glucitol copolymer water 2001GOM
____________________________________________________________________________________
N-Isopropylacrylamide/4-pentenoic acid copolymer
water 1999KUN
____________________________________________________________________________________
ethanol 1986SAN
____________________________________________________________________________________
Poly(decyl methacrylate)
cyclopentane 1983MA2
n-heptane 1983MA2
n-hexane 1983MA2
n-pentane 1983MA2
toluene 1983MA2
2,2,4-trimethylpentane 1983MA1
2,2,4-trimethylpentane 1983MA2
2,2,4-trimethylpentane 1997WOL
____________________________________________________________________________________
n-butane 1972ZE1
ethane 1972ZE1
propane 1972ZE1
____________________________________________________________________________________
Polyethylene
n-butane 1963EHR
n-butane 1975HOR
n-butane 1994KI2
dichlorodifluoroethene 1975HOR
dichlorodifluoromethane 1975HOR
fluorotrichloromethane 1975HOR
n-heptane 1973HAM
n-heptane 1975HOR
n-heptane 1980KLE
n-heptane 1996LOO
n-hexane 1973HAM
n-hexane 1975HOR
n-hexane 1980KLE
n-hexane 1989HAE
n-hexane 1990KEN
n-hexane 1996LOO
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
2-methylpropane 1975HOR
n-octane 1973HAM
n-octane 1975HOR
n-octane 1980KLE
n-octane 1996LOO
n-pentane 1963EHR
n-pentane 1973HAM
n-pentane 1975HOR
n-pentane 1992KIR
n-pentane 1993KI2
n-pentane 1994KI2
n-pentane 1998ZHU
n-pentane 2003ZH2
perfluoro-2-butene 1975HOR
1,1,2-trichlorotrifluoroethane 1975HOR
____________________________________________________________________________________
water 1976SA1
____________________________________________________________________________________
water 1992COO
____________________________________________________________________________________
Polyisobutylene
n-butane 1972ZE1
n-hexane 1972ZE1
2-methylbutane 1965ALL
2-methylbutane 1972ZE1
n-pentane 2002JOU
n-pentane 1972ZE1
n-pentane 1997WOL
propane 1972ZE1
____________________________________________________________________________________
deuterium oxide 2004SHI
water 1993OTA
water 1997KUN
water 1999KUN
water 2004SHI
____________________________________________________________________________________
water 1974TAN
____________________________________________________________________________________
Polypeptide
water 2003YAM
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Polypropylene
n-pentane 1998KI2
____________________________________________________________________________________
water 1974TAN
____________________________________________________________________________________
propane 1972ZE2
____________________________________________________________________________________
Polystyrene
acetaldehyde 1997REB
tert-butyl acetate 1976SA2
cyclohexane 1962HAM
cyclohexane 1975SAE
cyclohexane 1980HOS
cyclohexane 1981WOL
cyclohexane 1997WOL
cyclohexane 1999HOO
cyclohexane 2000KOI
cyclopentane 1978ISH
cyclopentane 1981WOL
cyclopentane 1997WOL
trans-decalin 1977WO1
trans-decalin 1977WO2
trans-decalin 2003JI1
trans-decalin 2004JIA
n-decane 2001IMR
n-decane 2002IMR
diethyl ether 1976SA2
diethyl ether 1997WOL
diethyl malonate 1981WOL
diethyl oxalate 1986SAE
1,4-dimethylcyclohexane 1999IM1
1,4-dimethylcyclohexane 2002IMR
n-dodecane 2001IMR
n-dodecane 2002IMR
dodecyl acetate 2000IMR
ethyl formate 1997IMR
1,1,1,3,3,3-hexadeutero-2-propanone 1991SZY
n-hexane 1997XIO
methyl acetate 1965MYR
methyl acetate 1972ZE2
methyl acetate 1997IMR
methylcyclohexane 1988KI1
methylcyclohexane 1991KIE
methylcyclohexane 1993HOS
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Polystyrene (continued)
methylcyclohexane 1993WEL
methylcyclohexane 1996DOB
methylcyclohexane 1996IMR
methylcyclohexane 1997END
methylcyclohexane 1998SZY
methylcyclohexane 1999HOO
methylcyclohexane 2000XIO
methylcyclopentane 1991SZY
nitroethane 2000DE2
n-octane 2001IMR
n-octane 2002IMR
n-pentane 1988KI1
n-pentane 1988KI2
n-pentane 1988KI3
n-pentane 1988KI4
n-pentane 1991KIE
n-pentane 1994KI1
n-pentane 2001LI4
1-phenyldecane 1981WOL
1-phenyldecane 1997WOL
2-propanone 1972ZE2
2-propanone 1991SZY
2-propanone 1993REB
2-propanone 1999IM1
propionitrile 1998IMR
n-tetradecane 2001IMR
n-tetradecane 2002IMR
____________________________________________________________________________________
Polytetrafluoroethylene
perfluorocarbon ether 1995TUM
perfluorodecalin 1995TUM
n-tetradecafluorohexane 1995TUM
1,1,2-trichloro-1,2,2-trifluoroethane 1995TUM
____________________________________________________________________________________
Poly(vinyl acetate)
____________________________________________________________________________________
water 1997KUN
water 1999KUN
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
N-Vinylacetylamide/vinyl acetate copolymer
water 2003SET
____________________________________________________________________________________
water 2003SET
____________________________________________________________________________________
N-Vinylisobutyramide/N-vinylamine copolymer
water 2000KUN
____________________________________________________________________________________
_____________________________________________________________________________
3.3. Cloud-point and/or coexistence curves of quasiternary and/or

quasiquaternary solutions

Solvent (C): 1-octene C8H16 111-66-0

wA 0.7385 0.7385 0.7385 0.7385 0.7385 0.7385 0.7385 0.7385 0.7385
wB 0.1794 0.1794 0.1794 0.1794 0.1794 0.1794 0.1794 0.1794 0.1794
wC 0.0821 0.0821 0.0821 0.0821 0.0821 0.0821 0.0821 0.0821 0.0821
T/K 441.7 451.9 462.3 472.6 462.4 472.6 483.0 493.1 503.3
P/MPa 0.92 1.10 1.33 1.55 2.47 3.44 5.22 6.45 7.61
VLE VLE VLLE VLLE LLE LLE LLE LLE LLE
wA 0.7385 0.7385 0.5932 0.5932 0.5932 0.5932 0.5932 0.5932 0.5932
wB 0.1794 0.1794 0.1441 0.1441 0.1441 0.1441 0.1441 0.1441 0.1441
wC 0.0821 0.0821 0.2627 0.2627 0.2627 0.2627 0.2627 0.2627 0.2627
T/K 513.5 523.2 452.6 462.4 472.6 483.0 472.6 483. 493.4
P/MPa 8.71 9.71 0.93 1.10 1.32 1.58 2.07 3.44 4.72
LLE LLE VLE VLE VLLE VLLE LLE LLE LLE
wA 0.5932 0.5932 0.5932 0.3210 0.3210 0.3210 0.3210 0.3210 0.3210
wB 0.1441 0.1441 0.1441 0.1971 0.1971 0.1971 0.1971 0.1971 0.1971
wC 0.2627 0.2627 0.2627 0.4819 0.4819 0.4819 0.4819 0.4819 0.4819
T/K 503.5 513.3 523.9 472.5 482.7 493.1 503.1 503.1 513.4
P/MPa 5.99 7.09 8.22 1.00 1.22 1.46 1.69 2.52 3.67
LLE LLE LLE VLE VLE VLE VLLE LLE LLE
wA 0.3210 0.3210 0.2156 0.2156 0.2156 0.2156 0.2156 0.2156 0.2156
wB 0.1971 0.1971 0.1324 0.1324 0.1324 0.1324 0.1324 0.1324 0.1324
wC 0.4819 0.4819 0.6520 0.6520 0.6520 0.6520 0.6520 0.6520 0.6520
T/K 523.3 534.0 482.6 493.1 503.2 513.4 503.2 513.2 523.1
P/MPa 4.72 5.83 1.02 1.25 1.40 1.66 1.73 2.85 3.84
LLE LLE VLE VLE VLLE VLLE LLE LLE LLE
wA 0.2156 0.2156
wB 0.1324 0.1324
wC 0.6520 0.6520
T/K 534.4 545.0
P/MPa 4.99 5.98
LLE LLE
_____________________________________________________________________________
Polymer (B): poly(ethylene oxide)-b-poly(dimethylsiloxane) 2003JI2

diblock copolymer
Characterization: Mw/kg.mol−1 = 1.8, 77 mol% ethylene oxide, EO27-b-DMS8
Solvent (A): toluene C7H8 108-88-3
Polymer (C): poly(ethylene oxide)
Characterization: Mw/kg.mol−1 = 35, Fluka AG, Buchs, Switzerland

wA 0.695 0.695 0.695 0.695 0.695 0.438 0.438 0.438 0.438
wB 0.169 0.169 0.169 0.169 0.169 0.386 0.386 0.386 0.386
wC 0.172 0.172 0.172 0.172 0.172 0.176 0.176 0.176 0.176
T/K 309.2 308.2 307.2 306.2 305.2 318.2 317.2 316.2 315.2
P/bar 588 441 342 112 23 617 483 364 159
wA 0.438 0.255 0.255 0.255 0.255 0.255 0.209 0.209 0.209
wB 0.386 0.558 0.558 0.558 0.558 0.558 0.626 0.626 0.626
wC 0.176 0.187 0.187 0.187 0.187 0.187 0.165 0.165 0.165
T/K 314.2 328.2 327.2 326.2 325.2 324.2 333.2 332.2 331.2
P/bar 21 160 223 265 321 383 85 114 163
wA 0.209 0.209 0.209 0.209 0.209
wB 0.626 0.626 0.626 0.626 0.626
wC 0.165 0.165 0.165 0.165 0.165
T/K 330.2 329.2 328.2 327.2 326.2
P/bar 212 258 322 369 408


wA 0.8905 0.8905 0.8905 0.8905 0.8905 0.8508 0.8508 0.8508 0.8508
wB 0.0996 0.0996 0.0996 0.0996 0.0996 0.0983 0.0983 0.0983 0.0983
wC 0.0099 0.0099 0.0099 0.0099 0.0099 0.0509 0.0509 0.0509 0.0509
T/K 423.15 413.15 403.15 393.15 383.15 423.15 413.15 403.15 393.15
P/bar 108.4 92.3 75.3 56.4 36.9 99.0 84.1 66.9 49.1
wA 0.8508 0.8012 0.8012 0.8012 0.8012
wB 0.0983 0.0992 0.0992 0.0992 0.0992
wC 0.0509 0.0996 0.0996 0.0996 0.0996
T/K 383.15 423.15 413.15 403.15 393.15
P/bar 30.8 87.2 68.8 51.5 33.2
Comments: Vapor-liquid equilibrium data are given in Chapter 2.
_____________________________________________________________________________


wA 0.8910 0.8910 0.8910 0.8910 0.8910 0.8910 0.8910 0.8512 0.8512
wB 0.0986 0.0986 0.0986 0.0986 0.0986 0.0986 0.0986 0.0974 0.0974
wC 0.0104 0.0104 0.0104 0.0104 0.0104 0.0104 0.0104 0.0514 0.0514
T/K 423.15 413.15 403.15 393.15 383.15 373.15 368.15 423.15 413.15
P/bar 127.5 111.0 95.4 75.2 56.6 35.6 26.3 117.7 97.2
wA 0.8512 0.8512 0.8512 0.8512 0.8022 0.8022 0.8022 0.8022 0.8022
wB 0.0974 0.0974 0.0974 0.0974 0.0993 0.0993 0.0993 0.0993 0.0993
wC 0.0514 0.0514 0.0514 0.0514 0.0985 0.0985 0.0985 0.0985 0.0985
T/K 403.15 393.15 383.15 373.15 423.15 413.15 403.15 393.15 383.15
P/bar 78.8 60.6 41.6 21.0 102.8 82.6 66.4 46.2 26.5
Comments: Vapor-liquid equilibrium data are given in Chapter 2.
Polymer (B): polystyrene 2000BEH

BASF AG, Germany

wA 0.9131 0.9131 0.9131 0.9131 0.9131 0.9156 0.9156 0.9156 0.9156
wB 0.0797 0.0797 0.0797 0.0797 0.0797 0.0718 0.0718 0.0718 0.0718
wC 0.0072 0.0072 0.0072 0.0072 0.0072 0.0126 0.0126 0.0126 0.0126
T/K 401.29 403.75 403.96 405.45 404.75 435.05 433.85 433.31 434.92
P/bar 154.1 98.3 64.3 40.5 15.4 241.7 155.5 100.1 52.2
wA 0.9156
wB 0.0718
wC 0.0126
T/K 436.37
P/bar 21.4

wA 0.9131 0.9131 0.9131 0.9131 0.9131 0.9131 0.9131 0.9156 0.9156
wB 0.0797 0.0797 0.0797 0.0797 0.0797 0.0797 0.0797 0.0718 0.0718
wC 0.0072 0.0072 0.0072 0.0072 0.0072 0.0072 0.0072 0.0126 0.0126
T/K 495.51 501.21 506.00 510.65 516.02 520.97 527.38 465.74 470.30
P/bar 29.8 37.3 41.5 47.2 53.7 59.4 67.1 11.1 13.7
continued
_____________________________________________________________________________
continued
wA 0.9156 0.9156 0.9156 0.9156 0.9156
wB 0.0718 0.0718 0.0718 0.0718 0.0718
wC 0.0126 0.0126 0.0126 0.0126 0.0126
T/K 475.97 480.61 486.19 491.25 496.44 506.12
P/bar 15.5 19.3 24.2 30.1 35.5 46.0
Type of data: cloud points (1:1 polymer blend)

T/K 445.15 449.85 454.98 460.09 465.17 469.07 470.30 471.86 473.65
P/bar 228.1 136.6 91.1 71.2 61.0 60.6 54.1 56.8 56.3
T/K 476.70 485.80 496.17 506.27 516.76 527.38
P/bar 55.6 56.8 61.9 69.5 78.7 88.8
Polymer (B): polystyrene 2002FRI

−1 −1
Solvent (A): 1,2-dichlorobenzene C6H4Cl2 95-50-1
Polymer (C): polybutadiene (deuterated)
Characterization: Mn/kg.mol−1 = 1.9, Mw/kg.mol−1 = 2.1, 46% 1,4- (unspecified)
and 54% 1,2-content, synthesized in the laboratory
Type of data: binodal points

Comments: The concentration of the polymer mixture is kept constant close to the critical
concentration of the polymer blend, i.e., ϕC/ϕB = 0.477/0.523.
ϕA 0.00 0.00 0.00 0.00 0.00 0.05 0.05 0.05 0.05
P/MPa 0.1 50 100 150 200 0.1 50 100 150
T/K 358.65 361.97 365.05 368.21 372.12 344.94 348.59 351.75 354.90
ϕA 0.05 0.20 0.20 0.20 0.20 0.20 0.20
P/MPa 200 0.1 50 100 150 180 200
T/K 358.05 292.47 294.49 298.10 299.45 302.84 301.60

ϕA 0.00 0.00 0.00 0.00 0.00 0.05 0.05 0.05 0.05
P/MPa 0.1 50 100 150 200 0.1 50 100 150
T/K 355.750 359.483 362.259 365.682 369.246 343.625 346.447 349.770 353.040
ϕA 0.05 0.20 0.20 0.20 0.20 0.20 0.20
P/MPa 200 0.1 50 100 150 180 200
T/K 356.253 291.126 293.477 295.811 298.476 301.210 301.226
_____________________________________________________________________________
Polymer (B): polystyrene 2002FRI

Solvent (A): 1,2-dichlorobenzene C6H4Cl2 95-50-1
Polymer (C): polybutadiene (deuterated)
Characterization: Mn/kg.mol−1 = 2.1, Mw/kg.mol−1 = 2.3, 40% 1,4-cis-, 53% 1,4-trans-,
and 7% 1,2-content, synthesized in the laboratory
Type of data: binodal points
Comments: The concentration of the polymer mixture is kept constant close to the critical
concentration of the polymer blend, i.e., ϕC/ϕB = 0.43/0.57.
ϕA 0.00 0.00 0.00 0.00
P/MPa 0.1 50 100 150
T/K 338.31 342.15 343.10 349.72

ϕA 0.00 0.00 0.00 0.00 0.05 0.05 0.05 0.05 0.05
P/MPa 0.1 50 100 150 0.1 50 100 150 200
T/K 336.534 340.520 344.352 349.116 331.779 335.483 339.267 342.280 345.696
ϕA 0.20 0.20 0.20 0.20 0.20
P/MPa 0.1 50 100 150 200
T/K 295.388 298.722 301.750 304.939 308.190

Solvent (C): dodecadeuteromethylcyclopentane C6D12 144120-51-4
Comments: The mole fraction ratio of C6D12/C6H12 = 0.943 is kept constant.
wB 0.140 0.140 0.140 0.140 0.140
T/K 308.58 308.83 309.21 309.51 309.76
P/MPa 2.88 2.38 1.62 1.05 0.59

wB 0.134 0.134 0.134 0.134
T/K 336.23 336.75 337.35 338.45
P/MPa 2.13 1.74 1.36 0.64
_____________________________________________________________________________


wB 0.137 0.137 0.137 0.137
T/K 307.74 308.04 308.32 308.67
P/MPa 2.25 1.64 1.09 0.42


Comments: The mole fraction ratio of C3D6O/C3H6O = 0.546 is kept constant.
wB 0.219 0.219 0.219 0.219 0.219 0.219
T/K 271.41 271.42 271.27 271.26 270.95 270.67
P/MPa 0.24 0.25 0.42 0.42 0.75 1.07
wB 0.211 0.211 0.211 0.211 0.211 0.211 0.211 0.211 0.211
T/K 275.75 275.78 275.72 275.55 275.35 275.10 274.90 274.76 274.54
P/MPa 0.06 0.06 0.07 0.18 0.38 0.63 0.84 1.02 1.27


wB 0.205 0.205 0.205 0.205 0.205
T/K 302.77 303.49 304.93 306.86 307.34
P/MPa 1.89 1.63 1.27 0.63 0.37
continued
_____________________________________________________________________________
continued
wB 0.205 0.205 0.205 0.205 0.205
T/K 302.77 303.49 304.93 306.86 307.34
P/MPa 1.85 1.58 1.23 0.59 0.32

wB 0.207 0.207 0.207 0.207 0.207 0.207
T/K 313.76 318.51 319.15 316.83 315.61 314.73
P/MPa 1.99 0.58 0.42 1.00 1.39 1.66
wB 0.207 0.207 0.207 0.207 0.207 0.207
T/K 313.76 318.51 319.15 316.83 315.61 314.73
P/MPa 1.95 0.55 0.38 0.97 1.34 1.62

wB 0.206 0.206 0.206 0.206 0.206 0.206 0.206 0.206 0.206
T/K 330.82 330.82 331.84 332.91 333.91 335.96 338.37 340.36 343.28
P/MPa 2.11 2.09 1.86 1.67 1.53 1.15 0.90 0.61 0.34
wB 0.206 0.206 0.206 0.206
T/K 373.09 375.93 378.69 384.87
P/MPa 0.59 0.77 0.99 1.57
wB 0.206 0.206 0.206 0.206 0.206 0.206 0.206 0.206 0.206
T/K 330.82 330.82 331.84 332.91 333.91 335.96 338.37 340.36 343.28
P/MPa 1.91 1.91 1.73 1.55 1.35 1.05 0.71 0.51 0.23
wB 0.206 0.206 0.206 0.206
T/K 373.09 375.93 378.69 384.87
P/MPa 0.45 0.69 0.92 1.49

continued
_____________________________________________________________________________
continued
Polymer (D): polystyrene

The mole fraction ratio of polymer(D)/polymer(B) = 0.500 is kept constant.
wB+D 0.210 0.210 0.210 0.210 0.210 0.210 0.210 0.210 0.210
T/K 335.83 340.15 343.69 347.37 351.31 353.49 358.40 362.30 368.51
P/MPa 2.55 2.10 1.81 1.62 1.51 1.47 1.52 1.63 1.90
wB+D 0.210
T/K 378.34
P/MPa 2.58
wB+D 0.210 0.210 0.210 0.210 0.210 0.210 0.210 0.210 0.210
T/K 335.83 340.15 343.69 347.37 351.31 353.49 358.40 362.30 368.51
P/MPa 2.46 2.01 1.76 1.56 1.45 1.39 1.49 1.56 1.85
wB+D 0.210
T/K 378.34
P/MPa 2.53
critical concentration: wB+D, crit = 0.210

wB+D 0.103 0.103 0.103 0.103 0.103 0.103 0.103 0.103 0.103
T/K 325.99 329.97 335.66 341.31 347.11 356.39 364.63 373.45 381.86
P/MPa 2.35 1.76 1.05 0.73 0.54 0.59 0.79 1.35 2.20
wB+D 0.265 0.265 0.265 0.265 0.265 0.265 0.265 0.265
T/K 324.00 328.57 334.53 338.01 366.05 373.78 379.64 384.82
P/MPa 2.39 1.53 0.71 0.38 0.43 1.00 1.52 2.03
wB+D 0.103 0.103 0.103 0.103 0.103 0.103 0.103 0.103 0.103
T/K 325.99 329.97 335.66 341.31 347.11 356.39 364.63 373.45 381.86
P/MPa 1.33 1.00 0.46 0.01 0.35 0.27 0.50 1.63
wB+D 0.265 0.265 0.265 0.265 0.265 0.265 0.265 0.265
T/K 324.00 328.57 334.53 338.01 366.05 373.78 379.64 384.82
P/MPa 2.22 1.33 0.62 0.13 0.22 0.84 1.42 1.77
continued
_____________________________________________________________________________
continued
wB+D 0.126 0.126 0.126 0.126 0.126 0.126 0.126 0.126 0.126
T/K 331.06 335.10 339.51 343.35 350.12 354.21 356.36 364.60 372.36
P/MPa 2.11 1.65 1.29 1.05 0.67 0.81 0.92 1.15 1.63
wB+D 0.126 0.145 0.145 0.145 0.145 0.145 0.145 0.145 0.145
T/K 380.49 331.95 335.12 337.71 341.63 345.55 351.27 356.14 365.16
P/MPa 2.36 2.51 2.07 1.75 1.43 1.22 1.07 1.13 1.37
wB+D 0.145 0.145 0.167 0.167 0.167 0.167 0.167 0.167 0.167
T/K 372.07 379.54 331.56 335.91 341.02 345.32 350.63 353.45 356.39
P/MPa 1.80 2.40 2.58 1.96 1.48 1.22 1.08 1.07 1.13
wB+D 0.167 0.167 0.167
T/K 365.41 372.96 360.01
P/MPa 1.39 1.66 2.43
wB+D 0.126 0.126 0.126 0.126 0.126 0.126 0.126 0.126 0.167
T/K 331.06 335.10 339.51 343.35 350.12 364.60 372.36 380.49 331.56
P/MPa 1.81 1.34 0.67 0.45 0.36 0.52 1.26 1.66 2.21
wB+D 0.167 0.167 0.167 0.167 0.167 0.167 0.167 0.167 0.167
T/K 335.91 341.02 345.32 350.63 353.45 356.39 365.41 372.96 360.01
P/MPa 1.72 1.36 1.13 0.96 0.96 1.00 1.32 1.75 2.32

wB+D 0.245 0.245 0.245 0.245 0.245 0.245 0.245 0.245
T/K 332.25 336.80 343.55 349.28 358.29 363.91 372.41 379.29
P/MPa 2.53 1.93 1.34 1.09 1.06 1.22 1.69 2.25
wB+D 0.245 0.245 0.245 0.245 0.245 0.245 0.245 0.245
T/K 332.25 336.80 343.55 349.28 358.29 363.91 372.41 379.29
P/MPa 2.45 1.82 1.27 0.99 0.97 1.07 1.62 2.00

wB+D 0.186 0.186 0.186 0.186 0.186 0.186 0.186 0.186 0.186
T/K 334.35 337.99 341.51 346.27 351.43 354.56 358.37 365.30 372.69
P/MPa 2.27 1.85 1.55 1.27 1.14 1.12 1.16 1.41 1.83
continued
_____________________________________________________________________________
continued
wB+D 0.186 0.236 0.236 0.236 0.236 0.236 0.236 0.236 0.236
T/K 379.72 331.15 335.67 338.49 342.30 347.37 351.79 354.86 358.45
P/MPa 2.40 3.17 2.48 2.16 1.82 1.53 1.40 1.36 1.39
wB+D 0.236 0.236 0.236
T/K 365.87 371.73 376.61
P/MPa 1.63 1.97 2.32
wB+D 0.186 0.186 0.186 0.186 0.186 0.186 0.186 0.186 0.186
T/K 334.35 337.99 341.51 346.27 351.43 354.56 358.37 365.30 372.69
P/MPa 2.09 1.72 1.45 1.19 1.05 1.05 1.11 1.35 1.79
wB+D 0.186 0.236 0.236 0.236 0.236 0.236 0.236 0.236 0.236
T/K 379.72 331.15 335.67 338.49 342.30 347.37 351.79 354.86 358.45
P/MPa 2.33 3.02 2.34 2.03 1.71 1.43 1.29 1.27 1.30
wB+D 0.236 0.236 0.236
T/K 365.87 371.73 376.61
P/MPa 1.57 1.89 2.27

Polymer (C): polystyrene-d8
Comments: The mole fraction ratio of polymer(C)/polymer(B) = 0.50 is kept constant.

wB+C 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300
T/K 330.309 330.309 330.305 330.305 337.064 337.052 343.871 343.869 351.509
P/MPa 5.017 5.009 4.991 4.996 3.032 3.036 1.604 1.583 0.396
wB+C 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300
T/K 351.391 411.479 411.466 411.477 419.828 419.828 419.828 419.828 419.814
P/MPa 0.402 0.563 0.620 0.699 1.439 1.452 1.476 1.445 1.432
wB+C 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300
T/K 419.814 428.203 428.197 428.197 436.813 436.813 436.817 436.817 436.817
P/MPa 1.436 2.269 2.160 2.165 3.198 3.201 3.195 3.224 3.202
wB+C 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300
T/K 436.817 436.817 445.655 445.650 445.650 445.650 454.681 454.681 454.681
P/MPa 3.191 3.198 4.182 4.202 4.204 4.202 5.246 5.252 5.261
continued
_____________________________________________________________________________
continued
wB+C 0.1300 0.1300 0.1300 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599
T/K 454.658 454.658 454.658 330.291 330.290 337.001 336.998 343.823 343.821
P/MPa 5.273 5.271 5.270 4.938 4.934 3.105 3.018 1.638 1.547
wB+C 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599
T/K 350.797 350.796 411.521 411.522 419.731 419.733 428.235 428.234 436.879
P/MPa 0.509 0.483 0.684 0.689 1.479 1.520 2.356 2.305 3.254
wB+C 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1900
T/K 436.875 436.875 436.875 445.699 445.699 445.698 454.664 454.674 330.206
P/MPa 3.138 3.158 3.274 4.353 4.267 4.253 5.276 5.376 5.257
wB+C 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900
T/K 330.206 337.173 337.133 343.716 343.716 351.032 351.030 411.488 411.485
P/MPa 5.453 3.364 3.257 1.992 1.923 0.864 0.764 0.904 1.073
wB+C 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900
T/K 420.694 420.679 428.290 428.292 436.890 436.888 445.686 445.684 454.553
P/MPa 1.878 1.809 2.509 2.585 3.459 3.464 4.439 4.503 5.515
wB+C 0.1900 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198
T/K 454.575 333.385 333.385 333.415 333.397 340.168 340.181 347.027 345.281
P/MPa 5.559 4.889 4.836 4.657 4.684 3.069 2.770 1.419 1.366
wB+C 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198
T/K 350.852 350.851 411.434 411.433 411.432 419.661 419.655 428.097 428.086
P/MPa 0.375 0.302 0.691 0.879 0.659 1.359 1.458 2.227 2.069
wB+C 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2499 0.2499 0.2499
T/K 436.660 436.655 445.476 445.468 454.374 454.380 334.038 333.672 333.672
P/MPa 3.172 3.277 4.378 4.166 5.327 5.342 4.333 4.341 4.337
wB+C 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499
T/K 340.277 340.222 346.716 346.689 352.653 352.728 416.714 423.091 423.027
P/MPa 2.553 2.529 1.185 1.177 0.197 0.177 0.685 1.251 1.251
wB+C 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499
T/K 431.439 431.438 440.118 440.116 449.061 449.009 457.927 458.073
P/MPa 2.096 2.108 2.996 3.006 4.015 4.080 5.175 5.118

wB+C 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300
T/K 330.309 330.309 330.305 330.305 337.064 337.052 343.871 343.869 351.509
P/MPa 4.421 4.447 4.381 4.311 2.206 2.349 0.810 0.937 −0.456
wB+C 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300
T/K 351.391 411.479 411.466 411.477 419.828 419.828 419.828 419.828 419.814
P/MPa −0.319 −0.041 0.062 0.178 0.783 0.831 0.398 0.942 0.974
wB+C 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300
T/K 419.814 428.203 428.197 428.197 436.813 436.813 436.817 436.817 436.817
P/MPa 0.918 1.773 1.676 1.565 2.829 2.776 2.804 2.698 2.698
wB+C 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300 0.1300
T/K 436.817 436.817 445.655 445.650 445.650 445.650 454.681 454.681 454.681
P/MPa 2.879 2.755 3.876 3.854 3.821 3.862 4.946 4.7900 4.641
continued
_____________________________________________________________________________
continued
wB+C 0.1300 0.1300 0.1300 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599
T/K 454.658 454.658 454.658 330.291 330.290 337.001 336.998 343.823 343.821
P/MPa 4.655 4.709 4.714 4.761 4.805 2.576 2.859 1.232 1.427
wB+C 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599
T/K 350.797 350.796 411.521 411.522 419.731 419.733 428.235 428.234 436.879
P/MPa 0.233 0.287 0.580 0.549 1.327 1.221 1.899 1.947 3.036
wB+C 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1599 0.1900
T/K 436.875 436.875 436.875 445.699 445.699 445.698 454.664 454.674 330.206
P/MPa 3.138 3.138 2.898 3.778 3.9990 4.010 5.199 5.071 4.926
wB+C 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900
T/K 330.206 337.173 337.133 343.716 343.716 351.032 351.030 411.488 411.485
P/MPa 4.951 2.582 2.930 1.236 1.452 0.178 0.358 0.4800 0.329
wB+C 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900
T/K 420.694 420.679 428.290 428.292 436.890 436.888 445.686 445.684 454.553
P/MPa 1.438 1.275 2.104 2.1230 3.081 3.001 4.0440 4.0080 4.964
wB+C 0.1900 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198
T/K 454.575 333.385 333.385 333.415 333.397 340.168 340.181 347.027 345.281
P/MPa 4.971 4.608 4.606 4.545 4.474 2.092 2.664 1.095 1.222
wB+C 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198
T/K 350.852 350.851 411.434 411.433 411.432 419.661 419.655 428.097 428.086
P/MPa 0.084 0.096 0.412 0.126 0.356 1.266 1.169 2.041 2.106
wB+C 0.2198 0.2198 0.2198 0.2198 0.2198 0.2198 0.2499 0.2499 0.2499
T/K 436.660 436.655 445.476 445.468 454.374 454.380 334.038 333.672 333.672
P/MPa 2.933 2.913 3.887 3.986 5.073 5.005 3.740 3.883 3.950
wB+C 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499
T/K 340.277 340.222 346.716 346.689 352.653 352.728 416.714 423.091 423.027
P/MPa −0.180 1.919 0.279 0.462 −0.407 −0.254 0.262 0.938 1.007
wB+C 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499 0.2499
T/K 431.439 431.438 440.118 440.116 449.061 449.009 457.927 458.073
P/MPa 1.719 1.550 2.780 2.629 3.910 3.334 4.484 4.760

−1 −1
Characterization: Mn/kg.mol = 16.7, Mw/kg.mol = 20, fractionated in the laboratory

wA 0.8145 0.8145 0.8145 0.8094 0.8094 0.8094 0.8065 0.8065 0.8065
wB 0.0795 0.0795 0.0795 0.0790 0.0790 0.0790 0.0787 0.0787 0.0787
wC 0.1060 0.1060 0.1060 0.1116 0.1116 0.1116 0.1148 0.1148 0.1148
T/K 283.85 286.85 290.25 295.85 299.05 303.45 303.55 306.75 311.55
P/bar 1 500 1000 1 500 1000 1 500 1000
_____________________________________________________________________________

Characterization: Mn/kg.mol−1 = 31.4, Mw/kg.mol−1 = 37, fractionated in the laboratory

wA 0.8194 0.8194 0.8194 0.8151 0.8151 0.8151 0.8097 0.8097 0.8097
wB 0.0800 0.0800 0.0800 0.0796 0.0796 0.0796 0.0789 0.0789 0.0789
wC 0.1006 0.1006 0.1006 0.1053 0.1053 0.1053 0.1114 0.1114 0.1114
T/K 282.85 286.95 291.35 293.25 298.25 302.55 307.15 310.25 315.65
P/bar 1 500 1000 1 500 1000 1 500 1000

Characterization: Mn/kg.mol−1 = 58.8, Mw/kg.mol−1 = 70, fractionated in the laboratory

wA 0.8546 0.8546 0.8546 0.8498 0.8498 0.8498 0.8547 0.8547 0.8547
wB 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0199 0.0199 0.0199
wC 0.1254 0.1254 0.1254 0.1302 0.1302 0.1302 0.1254 0.1254 0.1254
T/K 279.65 283.95 292.65 293.65 302.05 309.65 309.65 319.15 327.15
P/bar 1 500 1000 1 500 1000 1 500 1000
wA 0.8439 0.8439 0.8439 0.8389 0.8389 0.8389 0.8334 0.8334 0.8334
wB 0.0407 0.0407 0.0407 0.0405 0.0405 0.0405 0.0403 0.0403 0.0403
wC 0.1154 0.1154 0.1154 0.1206 0.1206 0.1206 0.1263 0.1263 0.1263
T/K 284.05 289.25 296.05 299.25 305.25 311.55 310.95 319.75 326.15
P/bar 1 500 1000 1 500 1000 1 500 1000
wA 0.8338 0.8338 0.8338 0.8292 0.8292 0.8292 0.8245 0.8245 0.8245
wB 0.0613 0.0613 0.0613 0.0609 0.0609 0.0609 0.0607 0.0607 0.0607
wC 0.1049 0.1049 0.1049 0.1099 0.1099 0.1099 0.1148 0.1148 0.1148
T/K 285.25 287.85 293.15 296.75 301.65 306.05 308.75 314.35 320.45
P/bar 1 500 1000 1 500 1000 1 500 1000
wA 0.8244 0.8244 0.8244 0.8200 0.8200 0.8200 0.8150 0.8150 0.8150
wB 0.0952 0.0952 0.0952 0.0999 0.0999 0.0999 0.1056 0.1056 0.1056
wC 0.0952 0.0952 0.0952 0.0999 0.0999 0.0999 0.1056 0.1056 0.1056
T/K 275.45 277.55 280.35 287.95 290.15 294.45 299.85 304.65 308.45
P/bar 1 500 1000 1 500 1000 1 500 1000
_____________________________________________________________________________

related figures
____________________________________________________________________________________
____________________________________________________________________________________
water and potassium chloride 2001KUN
water and potassium iodide 2001KUN
water and potassium isocyanate 2001KUN
water and potassium sulfate 2001KUN
____________________________________________________________________________________
n-dodecane and water 1992SAS
____________________________________________________________________________________
Polybutadiene
1,2-dichlorobenzene and polystyrene 2002FRI
____________________________________________________________________________________
n-pentane and polyethylene 2002KIR
____________________________________________________________________________________
Polyethylene
n-hexane and nitrogen 1990KEN
n-hexane and n-octane 1989HAE
n-pentane and poly(dimethylsiloxane) 2002KIR
____________________________________________________________________________________
water and magnesium chloride 1998SUW
water and potassium chloride 1998SUW
water and potassium iodide 1998SUW
water and potassium sulfate 1998SUW
water and sodium isocyanate 1998SUW
water and sodium isocyanate 1999KUN
____________________________________________________________________________________
Polypeptide
potassium chloride and water 2003YAM
potassium iodide and water 2003YAM
potassium sulfate and water 2003YAM
sodium chloride and water 2003YAM
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
Polystyrene
acetone and diethyl ether 1976WOL
cyclohexane and water 1991DEE
1,2-dichlorobenzene and polybutadiene 2002FRI
n-heptane and methylcyclohexane 1999IM2
____________________________________________________________________________________
water and magnesium chloride 1998SUW
water and potassium chloride 1998SUW
water and potassium chloride 1999KUN
water and potassium iodide 1998SUW
water and potassium isocyanate 1998SUW
water and potassium sulfate 1998SUW
water and sodium iodide 1998SUW
water and sodium isocyanate 1998SUW
water and sodium isocyanate 1999KUN
water and sodium sulfate 1999KUN
____________________________________________________________________________________
water and potassium chloride 2003SET
water and potassium iodide 2003SET
water and potassium sulfate 2003SET
____________________________________________________________________________________
_____________________________________________________________________________

temperatures at elevated pressures
Note: LCST values are measured in many cases at the vapor pressure of the solvent, i.e., a high
pressure that is often near the critical pressure of the pure solvent. Nevertheless, this table presents only
LCST data for polymer solutions where a pressure dependence was explicitly investigated.
____________________________________________________________________________________
Polymer Mn Mw Solvent P/ UCST/ LCST/ Ref.
kg/mol kg/mol MPa K K
____________________________________________________________________________________
Polystyrene
583 670 tert-butyl acetate 0.1 270.8 393.7 1976SA2
583 670 tert-butyl acetate 1 269.7 400.2 1976SA2
583 670 tert-butyl acetate 5 265.5 1976SA2
infinite tert-butyl acetate 0.1 296.1 359.3 1976SA2
infinite tert-butyl acetate 1 293.1 366.3 1976SA2
infinite tert-butyl acetate 5 285.5 1976SA2
34.9 37.0 cyclohexane 0.1 285.41 1975SAE
34.9 37.0 cyclohexane 1 285.43 1975SAE
34.9 37.0 cyclohexane 2 285.46 1975SAE
34.9 37.0 cyclohexane 3 285.49 1975SAE
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
34.9 37.0 cyclohexane 4 285.53 1975SAE
34.9 37.0 cyclohexane 5 285.56 1975SAE
104 110 cyclohexane 0.1 294.38 1975SAE
104 110 cyclohexane 1 295.36 1975SAE
104 110 cyclohexane 2 294.35 1975SAE
104 110 cyclohexane 3 294.36 1975SAE
104 110 cyclohexane 4 294.35 1975SAE
104 110 cyclohexane 5 294.35 1975SAE
545.5 600 cyclohexane 0.1 301.34 1981WOL
545.5 600 cyclohexane 3.7 301.11 1981WOL
545.5 600 cyclohexane 8.8 300.95 1981WOL
545.5 600 cyclohexane 15.2 300.96 1981WOL
545.5 600 cyclohexane 18.7 301.12 1981WOL
545.5 600 cyclohexane 26.0 301.43 1981WOL
545.5 600 cyclohexane 30.0 301.68 1981WOL
583 670 cyclohexane 0.1 300.97 1975SAE
583 670 cyclohexane 1 300.91 1975SAE
583 670 cyclohexane 2 300.86 1975SAE
583 670 cyclohexane 3 300.81 1975SAE
583 670 cyclohexane 4 300.79 1975SAE
583 670 cyclohexane 5 300.75 1975SAE
1320 1450 cyclohexane 0.1 303.27 1975SAE
1320 1450 cyclohexane 1 303.21 1975SAE
1320 1450 cyclohexane 2 303.15 1975SAE
1320 1450 cyclohexane 3 303.10 1975SAE
1320 1450 cyclohexane 4 303.04 1975SAE
1320 1450 cyclohexane 5 302.98 1975SAE
infinite cyclohexane 0.1 306.51 2003SIP
infinite cyclohexane 2 306.36 2003SIP
583 670 cyclopentane 1 286.0 1978ISH
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
19.2 20.4 diethyl ether 0.1 228.4 314.5 1976SA2
19.2 20.4 diethyl ether 1 226.2 320.8 1976SA2
19.2 20.4 diethyl ether 2 224.0 327.1 1976SA2
19.2 20.4 diethyl ether 3 222.2 333.2 1976SA2
19.2 20.4 diethyl ether 4 220.6 339.4 1976SA2
19.2 20.4 diethyl ether 5 219.2 1976SA2
11.3 11.6 ethyl formate 1 273.3 443.8 1997IMR
377 400 ethyl formate 6 379.6 380.8 1997IMR
8.5 9.0 methylcyclohexane 4.1 329.420 1994VA1
____________________________________________________________________________________
_____________________________________________________________________________

____________________________________________________________________________________
7.1 7.5 2-propanone 0.5 253.3 442 1996LUS
7.3 8.0 2-propanone 0.5 260 437 1996LUS
11.4 11.7 2-propanone 0.5 274.8 421 1996LUS
12.7 13.5 2-propanone 0.5 285.3 400 1996LUS
____________________________________________________________________________________
_____________________________________________________________________________
3.6. References
1962HAM Ham, J.S., Bolen, M.C., and Hughes, J.K., The use of high pressure to study polymer-
solvent interaction, J. Polym. Sci., 57, 25, 1962.
1963EHR Ehrlich, P. and Kurpen, J.J., Phase equilibria of polymer-solvent systems at high pressure
near their critical loci, polyethylene with n-alkanes, J. Polym. Sci.: Part A, 1, 3217, 1963.
1965ALL Allen, G. and Baker, C.H., Lower critical solution phenomena in polymer-solvent systems,
Polymer, 6, 181, 1965.
1965MYR Myrat, C.D. and Rowlinson, J.S., The separation and fractionation of polystyrene at a lower
critical solution point, Polymer, 6, 645, 1965.
1972ZE1 Zeman, L., Biros, J., Delmas, G., and Patterson, D., Pressure effects in polymer solution
phase equilibria. I. The lower critical solution temperature of polyisobutylene and
polydimethylsiloxane in lower alkanes, J. Phys. Chem., 76, 1206, 1972.
1972ZE2 Zeman, L. and Patterson, D., Pressure effects in polymer solution phase equilibria. II.
Systems showing upper and lower critical solution temperatures, J. Phys. Chem., 76, 1214,
1972.
1973HAM Hamada, F., Fujisawa, K., and Nakajima, A.: Lower critical solution temperature in linear
polyethylene-n-alkane systems, Polym. J., 4, 316, 1973.
1975HOR Horacek, H., Gleichgewichtsdrücke, Löslichkeit und Mischbarkeit des Systems Polyethylen
niedriger Dichte und Kohlenwasserstoffen bzw. halogenierten Kohlenwasserstoffen,
Makromol. Chem., Suppl., 1, 415, 1975.
1975SAE Saeki, S., Kuwahara, N., Nakata, M., and Kaneko, M., Pressure dependence of upper
critical solutions temperatures in the polystyrene-cyclohexane system, Polymer, 16, 445,
1975.
1976SA1 Saeki, S., Kuwahara, N., Nakata, M., and Kaneko, M., Upper and lower critical solution
1976SA2 Saeki, S., Kuwahara, N., and Kaneko, M., Pressure dependence of upper and lower critical
solution temperatures in polystyrene solutions, Macromolecules, 9, 101, 1976.
1976WOL Wolf, B.A. and Blaum, G., Pressure influence on true cosolvency, Makromol. Chem., 177,
1073, 1976.
1977WO1 Wolf, B.A. and Jend, R., Pressure and molecular-weight dependence of polymer solubility
in the case of trans-decahydronaphthalene-polystyrene, High Temp. High Press., 9, 561,
1977.
1977WO2 Wolf, B.A. and Jend, R., Über die Möglichkeiten zur Bestimmung von Mischungsenthal-
pien und -volumina aus der Molekulargewichtsabhängigkeit der kritischen Entmischungs-
temperaturen und -drücke am Beispiel des Systems trans-Decahydronaphthalin/Polystyrol,
Makromol. Chem., 178, 1811, 1977.
1978ISH Ishizawa, M., Kuwahara, N., Nakata, M., Nagayama, W., and Kaneko, M.: Pressure
dependence of upper critical solution temperatures in the system polystyrene-cyclopentane,
1980HOS Hosokawa, H., Nakata, M., Dobashi, T., and Kaneko, M., Pressure dependence of the upper
critical solution temperature in the system polystyrene + cyclohexane, Rep. Progr. Polym.
Phys. Japan, 23, 13, 1980.
1980KLE Kleintjens, L.A. and Koningsveld, R., Liquid-liquid phase separation in multicomponent
polymer systems XIX. Mean-field lattice-gas treatment of the system n-alkane/linear
polyethylene, Colloid Polym. Sci., 258, 711, 1980.
_____________________________________________________________________________
1981WOL Wolf, B.A. and Geerissen, H., Pressure dependence of the demixing of polymer solutions
determined by viscometry (some experimental data by B. A. Wolf), Colloid Polym. Sci.,
259, 1214, 1981.
1983MA1 Maderek, E., Schulz, G.V, and Wolf, B.A, High temperature demixing of poly(decyl
methacrylate) solutions in isooctane and its pressure dependence, Makromol. Chem., 184,
1303, 1983.
1983MA2 Maderek, E., Schulz, G.V., and Wolf, B.A., Lower critical solution temperatures of
poly(decyl methacrylate) in hydrocarbons, Eur. Polym. J., 19, 963, 1983.
1984SAN Sander, U., Löslichkeit von Polybutylmethacrylat und Fliessverhalten verdünnter Lösungen,
Diploma Paper, Johannes Gutenberg University, Mainz, 1984.
1985GE1 Geerissen, H., Roos, J., and Wolf, B.A., Continuous fractionation and solution properties of
PVC 3. Pressure dependence of the solubility in single solvents, Makromol. Chem., 186,
769, 1985.
1985GE2 Geerissen, H., Roos, J., and Wolf, B.A., Continuous fractionation and solution properties of
PVC 4. Pressure dependence of the solubility in a mixed solvent, Makromol. Chem., 186,
777, 1985.
1986SAE Saeki, S., Kuwahara, N., Hamano, K., Kenmochi, Y., and Yamaguchi, T., Pressure
dependence of upper critical solution temperatures in polymer solutions, Macromolecules,
19, 2353, 1986.
1986SAN Sander, U. and Wolf, B.A., Solubility of poly(n-alkylmethacrylate)s in hydrocarbons and in
alcohols, Angew. Makromol. Chem., 139, 149, 1986.
1998IMR Imre, A. and van Hook, A.W., Liquid-liquid equilibria in polymer solutions at negative
pressure, Chem. Soc. Rev., 27, 117, 1998.
1988KI1 Kiepen, F., Streulichtuntersuchungen an den Systemen Oligostyrol/n-Pentan und Polystyrol/
Methylcyclohexan unter hohen Drücken in der Nähe der Mischungslücke, Dissertation,
Universität Duisburg, 1988.
1988KI2 Kiepen, F. and Borchard, W., Pressure-pulse-induced critical scattering of oligostyrene in n-
pentane, Macromolecules, 21, 1784, 1988.
1988KI3 Kiepen, F. and Borchard, W., Critical opalescence of polymer solutions at high pressures,
Makromol. Chem., 189, 2595, 1988.
1988KI4 Kiepen, F. and Borchard, W., Determination of binodal and spinodal points by means of the
pressure pulse-induced critical scattering method, Integr. Fundam. Polym. Sci. Technol.,
Elsevier, London, 2, 227, 1988.
1989HAE Haegen, R. van der, Kleintjens, L.A., Opstal, L. van, and Koningsveld, R., Thermodynamics
of polymer solutions, Pure Appl. Chem., 61, 159, 1989.
model (experimental data by Th.W. de Loos from M.Sc. Thesis by H.A.J. Kennis, TU Delft
1987), Chem. Eng. Sci., 45, 1875, 1990.
1991DEE Dee, G.T., The application of equation-of-state theories to polar-nonpolar liquid mixtures,
1991KIE Kiepen, F., Brinkmann, D., Koningsveld, R., and Borchard, W., Phase diagrams in
temperature, pressure and concentration-space of polystyrenes in n-pentane and
methylcyclohexane near the critical solution point, Integr. Fundam. Polym. Sci. Technol.,
Elsevier, Amsterdam, 5, 25, 1991.
critical test of the influence of gas data, Angew. Makromol. Chem., 185-186, 265, 1991.
1991SZY Szydlowski, J. and van Hook, W.A., Isotope and pressure effects on liquid-liquid equilibria
in polymer solutions. H/D solvent isotope effects in acetone-polystyrene solutions,
_____________________________________________________________________________
1992COO Cook, R.L., King, H.E., and Peiffer, D.G., Pressure-induced crossover from good to poor
solvent behavior for polyethylene oxide in water, Phys. Rev. Lett., 69, 3072, 1992.
1992KIR Kiran, E. and Zhuang, W., Solubility of polyethylene in n-pentane at high pressures,
Polymer, 33, 5259, 1992.
1992SAS Sassen, C.L., Gonzales Casielles, A., Loos, Th.W. de, and DeSwaan Arons, J., The
influence of pressure and temperature on the phase behaviour of the system H2O + C12 +
C7E5 and relevant binary subsystems, Fluid Phase Equil., 72, 173, 1992.
1992SZY Szydlowski, J., Rebelo, L., and van Hook, W.A., A new apparatus for the detection of phase
equilibria in polymer solvent systems by light scattering, Rev. Sci. Instrum., 63, 1717, 1992.
1993HOS Hosokawa, H., Nakata, M., and Dobashi,T., Coexistence curve of polystyrene in methyl-
cyclohexane. VII. Coexistence surface and critical double point of binary system in T-p-ϕ
space (experimental data by M. Nakata and T. Dobashi), J. Chem. Phys., 98, 10078, 1993.
1993KI2 Kiran, E., Xiong, Y., and Zhunag, W., Modeling polyethylene solutions in near and super-
critical fluids using the Sanchez-Lacombe model, J. Supercrit. Fluids, 6, 193, 1993.
1993OTA Otake, K., Karaki, R., Ebina, T., Yokoyama, C., and Takahashi, S., Pressure effects on the
aggregation of poly(N-isopropylacrylamide) and poly(N-isopropylacrylamide-co-acrylic
acid) in aqueous solutions, Macromolecules, 26, 2194, 1993.
1993REB Rebelo, L.P. and van Hook, W.A., An unusual phase diagram: the polystyrene-acetone
system in its hypercritical region; near tricritical behavior in a pseudo-binary solution, J.
1993WEL Wells, P.A., Loos, Th.W. de, and Kleintjens, L.A., Pressure pulsed induced critical
scattering: spinodal and binodal curves for the system polystyrene + methylcyclohexane
(experimental data by Th.W. de Loos), Fluid Phase Equil., 83, 383, 1993.
1994IMR Imre, A. and van Hook, W.A., Polymer-solvent demixing under tension. Isotope and pres-
sure effects on liquid-liquid transitions. VII. Propionitrile-polystyrene solutions at negative
pressure, J. Polym. Sci.: Part B: Polym. Phys., 32, 2283, 1994.
1994KI1 Kiran, E. and Zhuang, W., A new experimental method to study kinetics of phase separation
in high-pressure polymer solutions. Multiple rapid pressure-drop technique – MRPD, J.
Supercrit. Fluids, 7, 1, 1994.
1994KI2 Kiran, E., Xiong, Y., and Zhuang, W., Effect of polydispersity on the demixing pressures of
polyethylene in near- or supercritical alkanes, J. Supercrit. Fluids, 7, 283, 1994.
1994LOS LoStracco, M.A., Lee, S.-H., and McHugh, M.A., Comparison of the effect of density and
hydrogen bonding on the cloud point behavior of poly(ethylene-co-methyl acrylate)-
propane-cosolvent mixtures, Polymer, 35, 3272, 1994.
1994VA1 Vanhee, S., Kiepen, F., Brinkmann, D., Borchard, W., Koningsveld, R., and Berghmans, H.,
The system methylcyclohexane/polystyrene. Experimental critical curves, cloud-point and
spinodal isopleths, and their description with a semi-phenomenological treatment,
Makromol. Chem. Phys., 195, 759, 1994.
1995LUS Luszczyk, M., Rebelo, L.P.N., and van Hook, W.A., Isotope and pressure dependence of
liquid-liquid equilibria in polymer solutions. 5. and 6. (experimental data by L.P.N. Rebelo),
1995TUM Tuminello, W.H., Brill, D.J., Walsh, D.J., and Paulaitis, M.E., Dissolving poly(tetrafluoro-
ethylene) in low boiling halocarbons, J. Appl. Polym. Sci., 56, 495, 1995.
1996LOO Loos, Th.W. de, Graaf, L.J. de, and DeSwaan Arons, J., Liquid-liquid phase separation in
linear low density polyethylene-solvent systems, Fluid Phase Equil., 117, 40, 1996.
1996DOB Dobashi, T., Koshiba, T., and Nakata, M., Coexistence curve of polystyrene in methyl-
cyclohexane. IX. Pressure dependence of tricritical point, J. Chem. Phys., 105, 2906, 1996.
1996IMR Imre, A. and van Hook, W.A., Demixing in polystyrene/methylcyclohexane solutions, J.
Polym. Sci.: Part B: Polym. Sci., 34, 751, 1996.
_____________________________________________________________________________
1996LUS Luszczyk, M. and van Hook, W.A., Isotope and pressure dependence of liquid-liquid
equilibria in polymer solutions. 7. Solute and solvent H/D isotope effects in polystyrene-
propionitrile solutions, Macromolecules, 29, 6612, 1996.
1997DES DeSousa, H.C., Phase equilibria in polymer + solvent systems: experimental results and
modeling (Portug.), Ph.D. Thesis, New University of Lisbon, Portugal, 1997.
1997END Enders, S. and Loos, Th.W. de, Pressure dependence of the phase behaviour of polystyrene
in methylcyclohexane (experimental data by S. Enders), Fluid Phase Equil., 139, 335,
1997.
1997IMR Imre, A. and van Hook, W.A., Continuity of solvent quality in polymer solutions. Poor-
solvent to theta-solvent continuity in some polystyrene solutions, J. Polym. Sci.: Part B:
Polym. Phys., 35, 1251, 1997.
1997KUN Kunugi, S., Takano, K., Tanaka, N., Suwa, K., and Akashi, M., Effects of pressure on the
behavior of the thermoresponsive polymer poly(N-vinylisobutyramide) (PNVIBA),
1997REB Rebelo, L.P.N., DeSousa, H.C., and van Hook, W.A., Hypercritically enhanced distortion of
a phase diagram: The (polystyrene + acetaldehyde) system (experimental data by H.C. De
Sousa), J.Polym.Sci.: Part B: Polym.Phys., 35, 631, 1997.
1997WOL Wolf, B.A., Improvment of polymer solubility: influence of shear and pressure, Pure Appl.
Chem., 69, 929, 1997.
1997XIO Xiong, Y. and Kiran, E., Miscibility, density and viscosity of polystyrene in n-hexane at
high pressures, Polymer, 38, 5185, 1997.
1998KI2 Kiran, E. and Xiong, Y., Miscibility of isotactic polypropylene in n-pentane and n-pentane
+ carbon dioxide mixtures at high pressures, J. Supercrit. Fluids, 11, 173, 1998.
1998KOA Koak, N., Loos, Th.W. de, and Heidemann, R.A., Upper-critical-solution-temperature
behavior of the system polystyrene + methylcyclohexane. Influence of CO2 on the liquid-
liquid equilibria, Fluid Phase Equil., 145, 311, 1998.
1998SUW Suwa, K., Yamamoto, K., Akhashi, M., Takano, K., Tanaka, N., and Kunugi, S., Effects of
salt on the temperature and pressure responsive properties of poly(N-vinylisobutyramide)
aqueous solutions, Colloid Polym. Sci., 276, 529, 1998.
1998SZY Szydlowski, J. and van Hook, W.A., Liquid-liquid demixing from polystyrene solutions.
Studies on temperature and pressure dependeces using dynamic light scattering and neutron
scattering, Fluid Phase Equil., 150-151, 687, 1998.
1998ZHU Zhuang, W. and Kiran, E., Kinetics of pressure-induced phase separation (PIPS) from
polymer solutions by time resolved light scattering. Polyethylene + n-pentane, Polymer, 39,
2903, 1998.
1999BEY Beyer, C., Oellrich, L.R., and McHugh, M.A., Effect of copolymer composition and solvent
polarity on the phase behavior of mixtures of poly(ethylene-co-vinyl acetate) with
cyclopentane and cyclopentene (experimental data by C. Beyer), Chem. Ing. Techn., 71,
1306, 1999.
1999BUN Bungert, B., Komplexe Phasengleichgewichte von Polymerlösungen, Dissertation, TU
Berlin, Shaker Vlg., Aachen, 1999.
1999HOO Hook, W.A. van, Wilczura, H., and Rebelo, L.P.N., Dynamic light scattering of polymer/
solvent solutions under pressure. Near critical demixing (0.1<P/MPa<200) for polystyrene/
cyclohexane and polystyrene/methylcyclohexane, Macromolecules, 32, 7299, 1999.
1999IM1 Imre, A.R., Melnichenko, G., and van Hook, W.A., Liquid-liquid equilibria in polystyrene
solutions: The general pressure dependence, Phys. Chem. Chem. Phys., 1, 4287, 1999.
1999IM2 Imre, A.R., Melnichenko, G., and van Hook, W.A., A polymer-solvent system with two
homogeneous double critical points: Polystyrene (PS)/(n-heptane + methylcyclohexane), J.
1999KUN Kunugi, S., Yamazaki, Y., Takano, K., and Tanaka, N., Effects of ionic additives and ionic
comonomers on the temperature and pressure responsive behavior of thermoresponsive
polymers in aqueous solutions, Langmuir, 15, 4056, 1999.
_____________________________________________________________________________
2000BEH Behme, S., Thermodynamik von Polymersystemen bei hohen Drucken, Dissertation, TU
Berlin, 2000.
2000BEY Beyer, C., Oellrich, L.R., and McHugh, M.A., Effect of copolymer composition and solvent
polarity on the phase behavior of mixtures of poly(ethylene-co-vinyl acetate) with
cyclopentane and cyclopentene, Chem. Eng. Technol., 23, 592, 2000.
2000DE1 DeSousa, H.C. and Rebelo, L.P.N., (Liquid + liquid) equilibria of (polystyrene + nitro-
ethane). Molecular weight, pressure, and isotope effects, J. Chem. Thermodyn., 32, 355,
2000.
2000DE2 DeSousa, H.C. and Rebelo, L.P.N., A continuous polydisperse thermodynamic algorithm
for a modified Flory-Huggins model: The (polystyrene + nitroethane) example, J. Polym.
2000IMR Imre, A. and van Hook, W.A., End group effects on liquid-liquid demixing of polystyrene/
oligomethylene solutions. Polystyrene/dodecyl acetate solubility, Macromolecules, 33,
5308, 2000.
2000KOI Koizumi, J., Kawashima, Y., Kita, R., Dobashi, T., Hosokawa, H., and Nakata, M.,
Coexistence curves of polystyrene in cyclohexane near the critical double point in
composition-pressure space, J. Phys. Soc. Japan, 69, 2543, 2000.
2000KUN Kunugi, S., Tada, T., Yamazaki, Y., Yamamoto, K., and Akashi, M., Thermodynamic
studies on coil-globule transitions of poly(N-vinylisobutyramide-co-vinylamine) in aqueous
solutions, Langmuir, 16, 2042, 2000.
2000XIO Xiong, Y. and Kiran, E., Kinetics of pressure-induced phase separation (PIPS) in
polystyrene + methylcyclohexane solutions at high pressure, Polymer, 41, 3759, 2000.
2001GOM Gomes de Azevedo, R., Rebelo, L.P.N., Ramos, A.M., Szydlowski, J., DeSousa, H.C., and
2001IMR Imre, A.R., Melnichenko, G., van Hook, W.A., and Wolf, B.A., On the effect of pressure on
the phase transition of polymer blends and polymer solutions. Oligostyrene/n-alkane
systems, Phys. Chem. Chem. Phys., 3, 1063, 2004.
2001KUN Kunugi, S., Yoshida, D., and Kiminami, H., Effects of pressure on the behavior of
(hydroxypropyl)cellulose in aqueous solution, Colloid Polym. Sci., 279, 1139, 2001.
2001LIU Liu, K. and Kiran, E., Pressure-induced phase separation in polymer solutions: kinetics of
phase separation and crossover from nucleation and growth to spinodal decomposition in
solutions of polyethylene in n-pentane, Macromolecules, 34, 3060, 2001.
2001TOR Tork, T., Measurement and calculation of phase equilibria in polyolefin/solvent systems,
Dissertation, TU Berlin, 2001.
2002FRI Frielinghaus, H., Schwahn, D., Willner, L., and Freed, K.F., Small angle neutron scattering
studies of a polybutadiene/polystyrene blend with small additions of ortho-dichlorobenzene
for varying temperatures and pressures. II. Phase boundaries and Flory-Huggins parameter
(experimental data by H. Frielinghaus), J. Chem. Phys., 116, 2241, 2002.
2002HOR Horst, M.H. ter, Behme, S., Sadowski, G., and Loos, Th.W. de, The influence of
supercritical gases on the phase behavior of polystyrene-cyclohexane and polyethylene-
cyclohexane systems: experimental results and modeling with the SAFT equation of state, J.
2002IMR Imre, A.R., van Hook, W., and Wolf, B.A., Liquid-liquid phase equilibria in polymer
solutions and polymer mixtures, Macromol. Symp., 181, 363, 2002.
2002KIR Kiran, E. and Liu, K., The miscibility and phase behavior of polyethylene with
poly(dimethylsiloxane) in near critical pentane, Korean J. Chem. Eng., 19, 153, 2002.
_____________________________________________________________________________
2002RE1 Rebelo, L.P.N., Visak, Z.P., DeSousa, H.C., Szydlowski, J., Gomes de Azevedo, R.,
2002RE2 Rebelo, L.P.N., Visak, Z.P., and Szydlowski, J., Metastable critical lines in (acetone +
polystyrene) solutions and the continuity of solvent-quality states, Phys. Chem. Chem.
Phys., 4, 1046, 2002.
2002YEO Yeo, S.-D., Kang, I.-S., and Kiran, E., Critical polymer concentrations of polyethylene
solutions in pentane, J. Chem. Eng. Data, 47, 571, 2002.
2003JI1 Jiang, S., An, L., Jiang, B., and Wolf, B. A., Pressure effects on the thermodynamics of
trans-decahydronaphthalene/polystyrene polymer solutions: application of the Sanchez-
Lacombe lattice fluid theory (experimental data by S. Jiang), Macromol. Chem. Phys., 204,
692, 2003.
2003JI2 Jiang, S., An, L., Jiang, B., and Wolf, B.A., Liquid-liquid phase behavior of toluene/
polyethylene oxide/poly(ethylene oxide-b-dimethylsiloxane) polymer-containing ternary
mixtures (experimental data by S. Jiang), Phys. Chem. Chem. Phys., 5, 2066, 2003.
2003SET Seto, Y., Kameyama, K., Tanaka, N., Kunugi, S., Yamamoto, K., and Akashi, M., High-
pressure studies on the coacervation of copoly(N-vinylformamide-vinylacetate) and
copoly(N-vinylacetylamide-vinylacetate), Colloid Polym. Sci., 281, 690, 2003.
2003SIP Siporska, A., Szydlowski, J., and Rebelo, L.P.N., Solvent H/D isotope effects on miscibility
and theta-temperature in the polystyrene-cyclohexane system, Phys. Chem. Chem. Phys., 5,
2996, 2003.
2003YAM Yamaoka, T., Tamura, T., Seto, Y., Tada, T., Kunugi, S., and Tirrell, D.A., Mechanism for
the phase transition of a genetically engineered elastin model peptide (VPGIG) 40 in
aqueous solution, Biomacromolecules, 4, 1680, 2003.
2003ZH1 Zhang, W. and Kiran, E., (p, V, T) Behaviour and miscibility of (polysulfone + THF +
carbon dioxide) at high pressures, J. Chem. Thermodyn., 35, 605, 2003.
2003ZH2 Zhang, W., Dindar, C., Bayraktar, Z., and Kiran, E., Phase behavior, density, and
crystallization of polyethylene in n-pentane and in n-pentane/CO2 at high pressures, J. Appl.
Polym. Sci., 89, 2201, -2003.
215, 105, 2004.
2004JIA Jiang, S., An, L., Jiang, B., and Wolf, B. A., Temperature and pressure dependence of phase
separation of trans-decahydronaphthalene/polystyrene solution, Chem. Phys., 298, 37, 2004.
2004SCH Schnell, M., Stryuk, S., and Wolf, B.A., Liquid/liquid demixing in the system n-hexane/
narrowly distributed linear polyethylene (experimental data by M. Schnell and B.A. Wolf),
Ind. Eng. Chem. Res., 43, 2852, 2004.
2004SHI Shibayama, M., Isono, K., Okabe, S., Karino, T., and Nagao, M., SANS study on pressure-
induced phase separation of poly(N-isopropylacrylamide) aqueous solutions and gels,
4. HIGH-PRESSURE FLUID PHASE EQUILIBRIUM (HPPE) DATA
Polymer (B): ethylene/acrylic acid copolymer 1992WIN

−1 −1
Characterization: Mn/kg.mol = 37.5, Mw/kg.mol = 183, 3.0 wt% acrylic acid
wB 0.019 0.019 0.019 0.019 0.019 0.082 0.082 0.082 0.082
T/K 413.15 433.15 453.15 473.15 493.15 413.15 433.15 453.15 473.15
P/MPa 196.8 178.4 163.1 152.2 141.7 186.7 166.6 153.1 143.3
wB 0.082 0.128 0.128 0.128 0.128 0.128 0.186 0.186 0.186
T/K 493.15 413.15 433.15 453.15 473.15 493.15 413.15 433.15 453.15
P/MPa 135.4 181.2 162.8 150.1 140.3 132.2 172.1 154.3 142.5
wB 0.186 0.186 0.231 0.231 0.231 0.231 0.231 0.295 0.295
T/K 473.15 493.15 413.15 433.15 453.15 473.15 493.15 413.15 433.15
P/MPa 134.0 128.5 165.6 148.9 137.7 129.8 124.2 153.1 139.8
wB 0.295 0.295 0.295 0.318 0.318 0.318 0.318 0.318 0.338
T/K 453.15 473.15 493.15 413.15 433.15 453.15 473.15 493.15 413.15
P/MPa 130.2 123.1 118.0 150.4 136.6 127.9 121.3 115.8 146.0
wB 0.338 0.338 0.338 0.338 0.428 0.428 0.428 0.428 0.428
T/K 433.15 453.15 473.15 493.15 413.15 433.15 453.15 473.15 493.15
P/MPa 134.1 125.3 118.9 113.4 127.5 119.4 113.4 108.7 105.1
wB 0.510 0.510 0.510 0.510 0.510
T/K 413.15 433.15 453.15 473.15 493.15
P/MPa 109.8 105.5 102.0 99.0 96.0
T/K = 403.15
Total feed concentration of the copolymer in the homogeneous system: wB = 0.155.
____________________________________________________________________________________
Demixing wA Fractionation during demixing
pressure bottom phase top phase bottom phase top phase
____________________________________________________________________________________
P/ Mn/ M w/ M z/ Mn/ M w/ M z/
MPa kg/mol kg/mol kg/mol kg/mol kg/mol kg/mol
____________________________________________________________________________________
116.0 0.508 0.982 2.82 8.80 18.92
161.0 0.711 0.951 9.19 31.06 73.72
178.5 0.789 0.918 42.88 176.3 510.7 13.17 52.62 156.1
188.0 0.845 (cloud-point) 37.50 183.0 601.0 (feed sample)
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
94.0 0.438 0.993 1.5 6.75 13.9
113.0 0.536 0.982 2.5 8.3 17.6
129.0 0.633 0.966 8.2 29.1 69.6
147.7 0.766 0.939 41.5 173.7 472.8 11.6 47.0 146.2
157.5 0.836 (cloud-point) 37.5 183.0 601.0 (feed sample)
____________________________________________________________________________________
Polymer (B): ethylene/acrylic acid copolymer 2003BUB

Characterization: Mn/kg.mol−1 = 21.7, Mw/kg.mol−1 = 86, 3.5 mol% acrylic acid

T/K 433.15 438.15 443.15 448.15 453.15 458.15 463.15 468.15 473.15
P/bar 2815 2645 2535 2425 2270 2135 2040 1950 1830
T/K 483.15 493.15 503.15 513.15 523.15 533.15
P/bar 1725 1610 1520 1435 1370 1299

Characterization: Mn/kg.mol−1 = 19.1, Mw/kg.mol−1 = 63.3, 3.8 mol% acrylic acid

T/K 438.15 443.15 448.15 453.15 458.15 463.15 468.15 473.15 478.15
P/bar 2880 2730 2615 2465 2355 2220 2085 1995 1895
T/K 483.15 493.15 503.15 513.15 523.15 533.15
P/bar 1810 1685 1570 1470 1395 1325
4. High-Pressure Fluid Phase Equilibrium (HPPE) Data 229
____________________________________________________________________________________


T/K 473.15 478.15 483.15 488.15 493.15 498.15 503.15 513.15 523.15
P/bar 2820 2700 2540 2390 2255 2110 1990 1785 1630
T/K 533.15
P/bar 1490

Characterization: Mn/kg.mol−1 = 31, Mw/kg.mol−1 = 82.3, 5.7 mol% acrylic acid

T/K 483.15 488.15 493.15 498.15 503.15 508.15 513.15 518.15 523.15
P/bar 2585 2435 2295 2150 2040 1930 1820 1730 1660
T/K 533.15
P/bar 1520

−1 −1
Characterization: Mn/kg.mol = 30, Mw/kg.mol = 150, 6.0 wt% acrylic acid

wB 0.038 0.038 0.038 0.038 0.057 0.057 0.057 0.057 0.076
T/K 433.15 453.15 473.15 493.15 433.15 453.15 473.15 493.15 433.15
P/MPa 203.4 176.8 157.3 142.0 195.7 170.5 152.3 138.9 191.2
wB 0.076 0.076 0.076 0.116 0.116 0.116 0.116 0.150 0.150
T/K 453.15 473.15 493.15 433.15 453.15 473.15 493.15 433.15 453.15
P/MPa 167.2 148.9 134.0 189.5 164.2 146.2 132.5 183.9 161.1
wB 0.150 0.150 0.215 0.215 0.215 0.215 0.260 0.260 0.260
T/K 473.15 493.15 433.15 453.15 473.15 493.15 433.15 453.15 473.15
P/MPa 145.2 130.5 172.4 152.2 135.4 125.4 165.3 146.3 132.6
wB 0.260 0.295 0.295 0.295 0.295 0.335 0.335 0.335 0.335
T/K 493.15 433.15 453.15 473.15 493.15 433.15 453.15 473.15 493.15
P/MPa 121.8 158.3 142.0 129.8 119.0 147.5 135.9 125.6 115.5
wB 0.383 0.383 0.383 0.383 0.430 0.430 0.430 0.430 0.505
T/K 433.15 453.15 473.15 493.15 433.15 453.15 473.15 493.15 433.15
P/MPa 137.5 126.9 118.5 112.2 130.1 120.2 112.0 106.3 114.4
continued
____________________________________________________________________________________
continued
wB 0.505 0.505 0.505
T/K 453.15 473.15 493.15
P/MPa 108.0 103.1 99.2

T/K = 433.15
____________________________________________________________________________________
P/ wA
MPa bottom phase top phase
____________________________________________________________________________________
124.9 0.5550 0.9870
138.1 0.6130 0.9735
158.6 0.7130 0.9540
172.0 0.7855 0.9300
182.0 0.8435 (cloud-point)
____________________________________________________________________________________
Polymer (B): ethylene/acrylic acid copolymer 2002BEY

−1 −1
Characterization: Mn/kg.mol = 22.7, Mw/kg.mol = 258, 6.0 wt% acrylic acid
Exxon Co., Machelen, Belgium

wB 0.05 0.05 0.05 0.05 0.05
T/K 522.65 497.55 472.75 447.05 423.05
P/bar 1302 1394 1539 1779 2153


T/K 488.15 493.15 498.15 503.15 508.15 513.15 518.15 523.15 529.15
P/bar 2960 2760 2555 2370 2200 2050 1910 1800 1695
T/K 533.15
P/bar 1610
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 25, Mw/kg.mol−1 = 126, 7.3 wt% acrylic acid
wB 0.043 0.043 0.043 0.102 0.102 0.102 0.102 0.160 0.160
T/K 453.15 473.15 493.15 443.15 453.15 473.15 493.15 443.15 453.15
P/MPa 192.4 165.6 143.9 196.2 181.4 157.7 140.2 186.0 171.4
wB 0.160 0.160 0.203 0.203 0.203 0.203 0.272 0.272 0.272
T/K 473.15 493.15 443.15 453.15 473.15 493.15 443.15 453.15 473.15
P/MPa 150.8 135.3 178.2 165.3 146.3 132.5 166.0 156.4 140.6
wB 0.272 0.330 0.330 0.330 0.330 0.410 0.410 0.410 0.410
T/K 493.15 443.15 453.15 473.15 493.15 443.15 453.15 473.15 493.15
P/MPa 126.8 155.5 147.0 134.0 122.5 141.0 134.3 123.6 114.9
wB 0.500 0.500 0.500 0.500
T/K 443.15 453.15 473.15 493.15
P/MPa 121.4 117.0 110.8 104.8

Characterization: Mn/kg.mol−1 = 19.9, Mw/kg.mol−1 = 235, 7.5 wt% acrylic acid
wB 0.05 0.05 0.05 0.05 0.05
T/K 523.35 497.85 472.35 447.85 434.25
P/bar 1340 1442 1637 1946 2196

Characterization: 8.0 wt% acrylic acid, Exxon Co., Machelen, Belgium
wB 0.05 0.05 0.05 0.05 0.05
T/K 523.05 497.95 472.65 447.65 433.05
P/bar 1349 1469 1692 2037 2367

−1 −1
Characterization: Mn/kg.mol = 23.4, Mw/kg.mol = 227, 9.0 wt% acrylic acid,
wB 0.05 0.05 0.05 0.05
T/K 522.65 497.75 471.85 447.55
P/bar 1390 1521 1779 2209
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 23.7, Mw/kg.mol−1 = 205, 11.0 wt% acrylic acid,

wB 0.05 0.05 0.05
T/K 524.05 497.35 472.35
P/bar 1484 1686 2104

Characterization: 15.0 wt% acrylic acid, Exxon Co., Machelen, Belgium

wB 0.05 0.05 0.05
T/K 522.05 498.05 475.45
P/bar 1732 2066 2647
Polymer (B): ethylene/1-butene copolymer 1999CHE

Characterization: Mn/kg.mol−1 = 6.43, Mw/kg.mol−1 = 6.69, 8.6 mol% 1-butene,
completely hydrogenated polybutadiene, 8.6 mol% 1,2-units,
Polymer Source, Inc., Dorval, Quebec

T/K 428.65 428.15 420.95 415.95 409.15 401.25 395.05 391.95 383.85
P/bar 90.1 88.8 80.5 72.3 63.5 50.3 40.7 34.6 23.5
T/K 381.55 328.85 327.75 326.85
P/bar 20.8 48.4 89.0 132.3
Comments: The last three data points are temperature-induced phase transitions.
T/K 428.45 428.35 418.85 411.25 402.65 396.75 391.55 381.95 375.35
P/bar 131.6 131.4 119.3 107.3 96.4 85.8 78.8 63.0 52.3
T/K 366.75 362.95 357.65 352.55 350.85 349.35 348.15
P/bar 37.0 31.0 21.5 12.0 58.6 96.0 162.2
____________________________________________________________________________________

completely hydrogenated polybutadiene, 29 mol% 1,2-units,

T/K 429.45 426.75 419.55 415.55 409.95 406.35 399.45 396.95 389.95
P/bar 93.1 87.4 79.8 73.6 66.0 59.9 49.3 45.1 33.7
T/K 387.35 381.45 259.65 258.85 258.35
P/bar 29.0 20.5 31.1 79.6 144.5
T/K 428.95 417.15 412.75 408.95 406.95 398.65 396.55 390.95 386.95
P/bar 134.2 122.8 117.1 107.1 106.4 85.3 83.9 70.6 62.1
T/K 378.75 377.05 372.15 367.45 364.95 277.75 276.85
P/bar 44.7 39.4 30.1 23.6 15.1 22.2 192.4
Comments: The last two data points are temperature-induced phase transitions.

Characterization: Mn/kg.mol−1 = 115, Mw/kg.mol−1 = 120, 87.5 mol% 1-butene,

T/K 431.85 430.25 424.25 419.35 416.15 405.75 400.95 394.15 389.45
P/bar 98.4 96.6 86.7 82.3 74.5 58.4 58.4 39.4 29.2
T/K 386.45 384.45 257.35 255.85
P/bar 24.9 20.7 52.3 140.3
T/K 429.05 419.75 416.25 415.85 408.05 405.25 396.75 396.25 388.55
P/bar 96.7 81.0 78.2 77.1 64.2 59.2 44.3 43.9 29.2
T/K 386.15 383.15
P/bar 27.2 20.6
____________________________________________________________________________________

T/K 431.05 430.35 414.65 413.75 398.75 398.55 382.55 367.75 367.55
P/bar 591.1 591.3 596.4 589.1 598.7 596.9 602.2 620.0 621.3
T/K 352.45 352.45 337.65 324.15 317.15 310.35
P/bar 653.1 652.5 683.5 761.4 998.9 1418
T/K 425.55 424.55 414.45 411.75 404.15 401.05 391.75 383.75 372.35
P/bar 742.8 745.8 751.8 753.4 763.1 765.2 776.8 790.2 812.5
T/K 361.95 355.05 347.95 346.65
P/bar 855.5 995.2 1280 1471
T/K 426.95 426.85 414.85 413.15 400.05 397.05 389.25 387.55 379.65
P/bar 892.8 896.2 923.8 928.8 970.1 977.6 1010 1018 1055
T/K 377.05 370.45 369.75 368.95 368.25
P/bar 1063 1163 1290 1370 1469

T/K 432.35 419.45 407.15 403.95 388.85 387.85 372.45 372.15 357.55
P/bar 732.5 737.8 739.1 752.0 772.0 770.7 800.0 797.0 833.4
T/K 357.25 345.05 343.35 328.55 327.45 316.65 306.55 295.75 288.35
P/bar 834.2 867.7 870.2 928.9 933.9 985.0 1043 1124 1265
T/K 425.75 412.05 398.55 384.25 383.15 368.65 367.15 353.05 337.75
P/bar 846.8 860.4 884.1 919.3 922.2 965.2 965.4 1024 1092
T/K 323.35 322.65 313.65 307.25
P/bar 1097 1208 1285 1385
____________________________________________________________________________________


T/K 424.25 409.25 389.35 372.25 353.25 352.45 333.45 318.25 305.05
P/bar 594.1 595.2 596.4 582.4 577.8 578.8 576.2 583.8 586.8
T/K 288.55 281.35 271.75 266.55 261.15 257.65 253.55 249.75 246.05
P/bar 591.8 593.7 597.9 604.6 629.1 645.8 674.2 693.2 711.1
T/K 235.85 230.25 225.15
P/bar 768.1 821.4 862.2
T/K 429.45 407.95 388.05 365.85 350.15 334.95 320.05 300.95 299.35
P/bar 702.9 705.0 709.7 708.3 708.7 712.0 718.5 745.6 754.1
T/K 297.75 292.45 273.75 266.75 260.75 257.45 252.75 245.45 240.15
P/bar 759.6 768.1 818.2 851.6 880.2 901.2 933.7 988.1 1034
T/K 235.25 231.65 229.55
P/bar 1089 1136 1168
Polymer (B): ethylene/1-butene copolymer 1998HAN

−1 −1
Characterization: Mn/kg.mol = 52.45, Mw/kg.mol = 104.9, 5.3 mol% 1-butene,
Tm/K = 385.2, synthesized with metallocene catalyst

wB 0.05 0.05 0.05 0.05 0.05
T/K 374.55 398.45 423.55 446.95 471.65
P/bar 592.2 580.8 576.9 576.6 577.6


wB 0.01 0.01 0.01 0.01 0.01 0.01 0.05 0.05 0.05
T/K 353.85 374.35 397.95 423.35 447.25 471.65 373.15 398.35 423.05
P/bar 587.1 569.4 560.5 561.7 561.5 563.4 571.9 563.6 561.8
wB 0.05 0.05
T/K 446.55 473.15
P/bar 562.7 565.6
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 50, Mw/kg.mol−1 = 94.9, 8.8 mol% 1-butene,

wB 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.05 0.05
T/K 348.35 363.55 373.95 400.35 421.65 446.35 471.05 374.15 397.85
P/bar 580.1 565.8 556.6 556.2 553.4 558.0 561.1 563.5 556.2
wB 0.05 0.05 0.05
T/K 423.45 447.15 472.05
P/bar 556.4 558.4 561.9

−1 −1
Characterization: Mn/kg.mol = 41.6, Mw/kg.mol = 79, 15.9 mol% 1-butene,

wB 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.05
T/K 313.55 322.95 348.85 373.15 396.55 423.25 446.55 470.35 373.15
P/bar 616.1 523.2 502.6 506.7 500.3 509.1 515.2 523.5 497.4
wB 0.05 0.05 0.05 0.05
T/K 398.65 422.45 447.65 474.35
P/bar 501.8 508.6 517.0 525.0

Characterization: Mn/kg.mol−1 = 29, Mw/kg.mol−1 = 58.1, 18.0 mol% 1-butene,

wB 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.05
T/K 324.25 334.55 348.15 373.55 398.85 422.15 446.65 471.85 348.25
P/bar 448.3 443.7 442.1 448.4 460.4 471.7 482.7 493.7 448.2
wB 0.05 0.05 0.05 0.05 0.05
T/K 372.55 395.95 422.95 447.45 469.65
P/bar 453.2 462.7 475.7 487.7 496.5

Tm/K = 319.2, completely hydrogenated polybutadiene
continued
____________________________________________________________________________________
continued
wB 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.05 0.05
T/K 295.45 324.05 348.75 374.65 398.15 423.05 447.65 295.15 324.15
P/bar 376.5 373.1 384.1 401.2 418.3 437.1 450.6 391.0 385.4
wB 0.05 0.05 0.05 0.05 0.05
T/K 348.85 373.95 397.95 422.95 447.55
P/bar 396.2 411.0 428.2 445.2 460.4

amorphous, completely hydrogenated polybutadiene
wB 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.05
T/K 296.55 323.15 349.05 373.95 397.25 423.55 445.25 472.15 333.85
P/bar 82.4 147.3 200.3 244.4 279.7 313.5 338.0 362.2 289.7
wB 0.05 0.05 0.05 0.05 0.05 0.05
T/K 348.25 372.65 398.75 422.95 447.65 473.05
P/bar 282.6 317.6 355.5 387.8 412.9 431.3
Polymer (B): ethylene/butyl acrylate copolymer 1996MU1

Characterization: Mn/kg.mol−1 = 6.9, Mw/kg.mol−1 = 34.9, 15.0 wt% butyl acrylate,
sample from BASF AG, Germany
wB 0.025 0.025 0.025 0.025 0.025 0.050 0.050 0.050 0.050
T/K 522.85 498.05 473.05 448.55 423.85 524.05 498.35 473.85 449.15
P/MPa 117.7 121.5 126.3 132.3 139.6 116.9 120.8 125.5 131.3
wB 0.050 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150
T/K 423.75 522.85 498.05 473.15 448.95 424.15 524.15 498.25 473.55
P/MPa 138.8 121.2 124.1 127.5 132.1 139.4 120.8 122.5 125.1
wB 0.150 0.150 0.200 0.200 0.200 0.200 0.200
T/K 448.95 424.35 523.35 498.05 473.35 449.15 423.35
P/MPa 128.5 133.6 117.3 118.8 121.5 124.8 128.7


continued
____________________________________________________________________________________
continued
wB 0.034 0.034 0.034 0.034 0.034 0.050 0.050 0.050 0.050
T/K 523.05 498.55 472.65 448.15 423.15 523.95 497.85 473.05 449.25
P/MPa 116.8 120.6 125.4 131.6 138.4 118.4 121.3 125.3 130.8
wB 0.050 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150
T/K 423.95 523.55 498.85 473.45 449.05 424.25 524.85 498.15 472.65
P/MPa 139.0 121.7 123.6 128.2 131.6 139.4 120.3 122.1 128.4
wB 0.150 0.150 0.199 0.199 0.199 0.199
T/K 448.95 424.25 523.25 498.55 473.35 448.95
P/MPa 130.6 134.7 120.7 123.0 126.1 129.8
Polymer (B): ethylene/butyl acrylate copolymer 1999DIE

1.0 mol% butyl acrylate, synthesized in the laboratory

T/K 383.15 393.15 403.15 413.15 423.15
P/bar 1900 1803 1725 1670 1600


T/K 388.15 393.15 393.15 398.15 398.15 403.15 408.15 413.15 418.15
P/bar 1900 1881 1870 1822 1796 1750 1677 1673 1628
T/K 423.15 423.15 433.15 434.15 438.15 443.15 443.15 453.15 463.15
P/bar 1581 1565 1546 1545 1541 1498 1490 1490 1452
T/K 472.15 483.15
P/bar 1419 1392


T/K 363.15 368.15 384.15 403.15 423.15
P/bar 1770 1750 1595 1510 1438
____________________________________________________________________________________


T/K 333.15 343.15 343.15 353.15 353.15 363.15 363.15 373.15 373.15
P/bar 1655 1582 1562 1503 1472 1460 1432 1415 1402
T/K 383.15 384.15 393.15 403.15 403.15 413.15 423.15 423.15 432.15
P/bar 1355 1380 1320 1320 1318 1289 1270 1259 1255
T/K 443.15 443.15 453.15 463.15 473.15 483.15
P/bar 1230 1242 1212 1189 1173 1160

Characterization: 17.2 mol% butyl acrylate, synthesized in the laboratory

T/K 328.15 331.15 336.15 341.15 347.15 354.15 364.15 383.15 405.15
P/bar 1400 1400 1370 1340 1324 1300 1290 1220 1190
T/K 421.15 443.15
P/bar 1260 1130


T/K 318.15 323.15 333.15 343.15 353.15 363.15 383.15 393.15 403.15
P/bar 1355 1320 1295 1260 1230 1210 1175 1158 1145
T/K 413.15 423.15 433.15 443.15 453.15 463.15 473.15
P/bar 1130 1127 1125 1120 1092 1090 1080


continued
____________________________________________________________________________________
continued
T/K 343.15 363.15 383.15 403.15 403.15 423.15 443.15 463.15 473.15
P/bar 1240 1173 1165 1132 1125 1092 1058 1040 1037
Polymer (B): ethylene/butyl acrylate copolymer 2004BEC

Characterization: Mn/kg.mol−1 = 49.8, Mw/kg.mol−1 = 159.5, 27.0 mol% butyl acrylate,

T/K 354.15 374.15 393.15 412.15 432.15 452.15 471.15 489.15 510.15
P/MPa 1144 1106 1071 1052 1033 1014 993 977 965
T/K 530.15
P/MPa 953


wB 0.025 0.025 0.025 0.025 0.025 0.050 0.050 0.050 0.050
T/K 523.65 498.55 473.05 448.55 423.45 523.75 498.05 472.95 448.05
P/MPa 111.5 115.9 120.4 127.2 134.4 109.4 113.1 117.2 122.3
wB 0.050 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150
T/K 423.25 523.45 498.05 473.15 448.45 423.45 523.85 498.35 472.95
P/MPa 129.7 107.1 109.8 113.1 116.9 121.9 105.9 108.1 111.5
wB 0.150 0.150 0.199 0.199 0.199 0.199 0.199
T/K 448.05 423.85 523.75 498.05 473.25 449.15 424.05
P/MPa 115.1 119.8 104.9 106.7 109.5 115.4 120.5


wB 0.168 0.168 0.168 0.168 0.168
T/K 522.35 498.15 473.65 448.35 424.65
P/MPa 96.6 98.4 100.1 102.3 104.0
____________________________________________________________________________________


wB 0.069 0.069 0.069 0.069 0.069 0.069
T/K 524.05 499.05 474.45 448.65 423.75 398.75
P/MPa 89.4 90.3 92.9 96.5 99.8 102.1
Polymer (B): ethylene/butyl methacrylate copolymer 2004BEC

12.0 mol% butyl methacrylate, synthesized in the laboratory

T/K 373.15 393.15 413.15 433.15 453.15 473.15 488.15 508.15 528.15
P/bar 1250 1200 1151 1114 1089 1062 1041 1021 1000


T/K 353.15 373.15 393.15 413.15 433.15 453.15 473.15 488.15 508.15
P/bar 1082 1045 1016 993 973 958 946 930 915
T/K 528.15
P/bar 901


T/K 383.15 393.15 413.15 433.15 453.15 473.15 493.15 513.15 533.15
P/bar 885 878 866 857 847 840 834 823 813
____________________________________________________________________________________
Polymer (B): ethylene/ethyl acrylate copolymer 2004BEC

Characterization: 4.0 mol% ethyl acrylate, synthesized in the laboratory

T/K 384.05 395.15 414.85 435.15 454.15 473.15 492.15 514.15 531.15
P/bar 1631 1568 1471 1394 1336 1288 1247 1207 1175

Characterization: 6.0 mol% ethyl acrylate, synthesized in the laboratory

T/K 372.15 393.15 413.15 433.15 452.15 472.55 492.15 511.15 531.35
P/bar 1510 1420 1351 1295 1252 1212 1181 1147 1122

23 mol% ethyl acrylate, synthesized in the laboratory

T/K 353.15 364.15 373.75 393.15 413.15 434.15 454.15 473.15 493.65
P/bar 1280 1256 1236 1190 1155 1123 1095 1072 1047
T/K 513.55 533.15
P/bar 1025 1000

29 mol% ethyl acrylate, synthesized in the laboratory

T/K 363.15 373.15 383.15 393.15 413.15 433.15 453.15 473.15 493.15
P/bar 1236 1206 1183 1165 1131 1100 1072 1048 1022
T/K 513.15 533.15
P/bar 1000 982
____________________________________________________________________________________
Polymer (B): ethylene/2-ethylhexyl acrylate copolymer 1999DIE

9.3 mol% 2-ethylhexyl acrylate, synthesized in the laboratory

T/K 363.15 383.15 403.15 423.15 443.15 462.15 483.15
P/bar 1640 1590 1440 1390 1340 1310 1290

−1 −1

T/K 363.15 383.15 403.15 423.15 443.15 463.15 483.15
P/bar 1240 1220 1145 1125 1085 1060 1010

Characterization: 22.8 mol% 2-ethylhexyl acrylate, synthesized in the laboratory

T/K 353.15 363.15 383.15 403.15 423.15 443.15 463.15 483.15
P/bar 1070 1055 1025 1005 995 995 965 945
Polymer (B): ethylene/1-hexene copolymer 2000CH3

−1 −1
Characterization: Mn/kg.mol = 52.6, Mw/kg.mol = 80, 10.6 wt% 1-hexene

wB 0.148 0.148 0.148 0.148
T/K 393.25 413.15 433.25 453.15
P/MPa 168.0 154.5 146.0 138.9
Polymer (B): ethylene/1-hexene copolymer 1999KIN, 2001DOE

−1 −1
Characterization: Mn/kg.mol = 60, Mw/kg.mol = 129, 16.1 wt% 1-hexene
continued
____________________________________________________________________________________
continued
wB 0.150 0.150 0.150 0.150 0.150 0.150
T/K 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 156.0 144.3 137.3 129.1 123.1 118.6

Characterization: Mn/kg.mol−1 = 48.1, Mw/kg.mol−1 = 103, 35.0 wt% 1-hexene
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100
T/K 393.15 403.15 413.15 423.15 433.15 443.15 453.15 393.15 403.15
P/MPa 136.3 132.6 129.6 127.0 124.9 122.9 121.0 134.8 131.4
wB 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150 0.150
T/K 413.15 423.15 433.15 443.15 453.15 393.15 403.15 413.15 423.15
P/MPa 128.3 125.8 123.7 121.8 120.8 129.4 126.1 123.6 121.5
wB 0.150 0.150 0.150
T/K 433.15 443.15 453.15
P/MPa 119.8 118.7 119.4
Polymer (B): ethylene/1-hexene copolymer 1999PAN

Characterization: Mn/kg.mol−1 = 46.5, Mw/kg.mol−1 = 102, 8.5 wt% 1-hexene,
MI = 1.2, ρ = 0.912 g/cm3, Tm/K = 409.95
wB 0.110 0.110 0.110 0.110 0.110 0.110 0.110 0.110 0.110
T/K 362.15 362.25 376.75 377.55 379.35 393.15 393.35 399.45 405.15
P/bar 353.4 353.4 352.8 352.5 353.0 354.2 354.8 356.0 356.5
wB 0.110 0.110 0.110 0.110
T/K 407.55 410.45 423.05 423.25
P/bar 357.9 358.5 362.8 364.3

−1 −1
Characterization: Mn/kg.mol = 54.8, Mw/kg.mol = 109.5, 13.6 wt% 1-hexene,
MI = 1.2, ρ = 0.900 g/cm3, Tm/K = 406.25
wB 0.112 0.112 0.112 0.112 0.112 0.112 0.112 0.112 0.112
T/K 355.65 358.35 368.55 368.55 377.85 378.65 392.05 395.25 405.45
P/bar 317.9 318.7 318.0 318.2 319.8 319.7 324.8 324.6 330.4
wB 0.112 0.112 0.112 0.112
T/K 407.55 410.25 421.75 424.65
P/bar 331.5 331.3 338.0 338.5
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 45.5, Mw/kg.mol−1 = 90.8, 13.7 wt% 1-hexene,
MI = 2.2, ρ = 0.900 g/cm3, Tm/K = 406.25

wB 0.111 0.111 0.111 0.111 0.111 0.111 0.111 0.111 0.111
T/K 362.65 362.65 373.15 373.25 383.15 383.25 392.55 393.35 407.95
P/bar 312.5 313.1 314.5 313.3 315.8 315.8 321.1 322.9 327.6
wB 0.111 0.111 0.111
T/K 408.75 423.25 423.45
P/bar 328.7 335.3 336.2

−1 −1
MI = 3.5, ρ = 0.900 g/cm3, Tm/K = 405.95

wB 0.110 0.110 0.110 0.110 0.110 0.110 0.110 0.110 0.110
T/K 358.25 358.75 368.15 368.95 377.45 380.25 393.25 394.15 406.45
P/bar 305.1 305.7 306.6 307.0 309.4 311.0 316.7 316.4 322.3
wB 0.110 0.110 0.110
T/K 408.85 423.45 423.85
P/bar 323.6 331.2 331.1

Characterization: Mn/kg.mol−1 = 31.3, Mw/kg.mol−1 = 68.8, 14.6wt% 1-hexene,
MI = 7.5, ρ = 0.900 g/cm3, Tm/K = 405.55

wB 0.112 0.112 0.112 0.112 0.112 0.112 0.112 0.112 0.112
T/K 357.45 360.35 366.35 368.25 376.65 378.45 393.15 394.05 406.15
P/bar 301.3 301.8 302.5 302.5 306.6 306.5 312.9 313.4 320.0
wB 0.112 0.112 0.112
T/K 409.15 422.95 423.25
P/bar 320.9 327.5 327.1

Characterization: Mn/kg.mol−1 = 47.5, Mw/kg.mol−1 = 94.9, 21.6wt% 1-hexene,
MI = 2.2, ρ = 0.885 g/cm3, Tm/K = 400.25
continued
____________________________________________________________________________________
continued
wB 0.109 0.109 0.109 0.109 0.109 0.109 0.109 0.109 0.109
T/K 358.55 359.75 362.75 367.95 368.95 377.55 377.65 391.95 393.85
P/bar 273.0 273.4 273.8 275.9 276.8 280.8 281.4 289.8 290.4
wB 0.109 0.109 0.109 0.109 0.109
T/K 395.35 407.15 409.15 423.55 423.55
P/bar 292.1 298.9 300.7 309.9 310.2
Polymer (B): ethylene/1-hexene copolymer 1998HAN

−1 −1
Characterization: Mn/kg.mol = 42.4, Mw/kg.mol = 93.2, 2.6 mol% 1-hexene,

wB 0.05 0.05 0.05 0.05
T/K 400.75 423.55 448.35 471.95
P/bar 591.2 586.0 584.2 584.7

−1 −1
Characterization: Mn/kg.mol = 53, Mw/kg.mol = 101, 4.6 mol% 1-hexene,

wB 0.05 0.05 0.05 0.05 0.05
T/K 373.65 398.75 427.55 447.55 471.75
P/bar 575.2 565.8 563.9 565.3 567.4

−1 −1
Characterization: Mn/kg.mol = 24.1, Mw/kg.mol = 72.3, 13.0 mol% 1-hexene,

wB 0.05 0.05 0.05 0.05 0.05 0.05
T/K 353.05 378.45 401.75 426.35 448.95 474.95
P/bar 471.5 472.9 479.3 489.3 495.9 505.5

−1 −1
Characterization: Mn/kg.mol = 46.5, Mw/kg.mol = 102, 8.5 wt% 1-hexene,
MI = 1.2, ρ = 0.912 g/cm3, Tm/K = 409.95
continued
____________________________________________________________________________________
continued
wB 0.111 0.111 0.111 0.111 0.111 0.111 0.111 0.111 0.111
T/K 367.15 367.95 377.55 378.05 390.75 393.35 407.95 408.65 422.75
P/bar 520.8 521.1 520.0 520.4 520.4 521.2 521.8 522.1 525.3
wB 0.111
T/K 423.45
P/bar 525.0

MI = 1.2, ρ = 0.900 g/cm3, Tm/K = 406.25
wB 0.109 0.109 0.109 0.109 0.109 0.109 0.109 0.109 0.109
T/K 357.15 358.75 367.35 367.55 379.95 381.65 390.55 394.05 408.65
P/bar 481.8 483.0 484.3 484.3 486.2 486.2 489.1 490.8 495.3
wB 0.109 0.109 0.109
T/K 412.15 422.45 422.75
P/bar 496.7 500.1 500.1

MI = 2.2, ρ = 0.900 g/cm3, Tm/K = 406.25
wB 0.109 0.109 0.109 0.109 0.109 0.109 0.109 0.109 0.109
T/K 356.55 359.35 366.65 368.35 376.25 377.85 393.15 395.55 406.15
P/bar 460.9 461.5 461.8 462.1 463.8 464.3 468.8 468.9 473.9
wB 0.109 0.109 0.109
T/K 408.15 423.15 424.15
P/bar 474.9 481.0 481.3

MI = 3.5, ρ = 0.900 g/cm3, Tm/K = 405.95
wB 0.109 0.109 0.109 0.109 0.109 0.109 0.109 0.109 0.109
T/K 353.25 355.65 364.05 365.15 375.15 377.75 390.15 393.55 408.45
P/bar 459.0 459.2 459.9 461.3 463.2 464.1 468.3 469.9 474.4
continued
____________________________________________________________________________________
continued
wB 0.109 0.109 0.109
T/K 408.55 422.75 423.15
P/bar 474.2 478.2 478.4

−1 −1
MI = 2.2, ρ = 0.885 g/cm3, Tm/K = 400.25

wB 0.110 0.110 0.110 0.110 0.110 0.110 0.110 0.110 0.110
T/K 355.95 358.65 367.45 368.55 376.95 378.35 392.85 395.65 406.25
P/bar 425.1 426.4 429.5 430.5 435.0 435.1 444.4 444.9 451.2
wB 0.110 0.110 0.110
T/K 409.35 422.85 423.65
P/bar 453.8 459.9 461.5


wB 0.010 0.010 0.010 0.010 0.051 0.051 0.051 0.051 0.148
T/K 363.15 373.25 413.15 453.15 363.15 373.15 413.15 453.15 373.25
P/MPa 50.3 50.0 49.9 50.7 51.0 50.4 50.4 50.4 50.6
wB 0.148 0.148
T/K 413.15 453.15
P/MPa 50.4 51.1

−1 −1
Characterization: Mn/kg.mol = 51.3, Mw/kg.mol = 126, 20.6 wt% 1-hexene

T/K = 453.15
wB 0.018 0.031 0.055 0.066 0.075 0.079 0.089 0.098 0.100
P/bar 446.0 454.0 456.0 459.0 468.0 475.0 478.0 470.0 474.0
wB 0.108 0.114 0.148
P/bar 471.0 466.0 459.0
____________________________________________________________________________________


wB 0.150 0.150 0.150 0.150 0.150 0.150
T/K 313.15 343.15 363.05 373.05 413.15 453.15
P/MPa 37.3 38.1 39.1 39.7 42.3 44.6

Characterization: Mn/kg.mol−1 = 112, Mw/kg.mol−1 = 139, 35.0 wt% 1-hexene

wB 0.009 0.009 0.009 0.009 0.009 0.009 0.152 0.152 0.152
T/K 313.25 353.25 368.25 373.15 413.15 453.15 353.25 373.15 413.15
P/MPa 39.0 36.8 37.6 37.9 40.6 42.9 37.8 39.2 41.5
wB 0.152
T/K 453.15
P/MPa 43.7
Polymer (B): ethylene/methacrylic acid copolymer 2003BUB

Characterization: Mn/kg.mol−1 = 25.7, Mw/kg.mol−1 = 83.2, 1.0 mol% methacrylic acid

T/K 383.15 393.15 403.15 418.15 433.15 453.15 464.15 473.15 483.15
P/bar 2730 2390 2190 1940 1760 1595 1520 1475 1425
T/K 493.15 503.15 513.15 523.15 533.15
P/bar 1375 1345 1320 1285 1260

Characterization: 2.2 mol% methacrylic acid, synthesized in the laboratory

T/K 420.15 426.15 431.15 438.15 443.15 453.15 463.15 473.15 482.15
P/bar 2450 2295 2190 2060 1975 1840 1730 1645 1570
T/K 493.15 503.15 512.15 522.15 533.15
P/bar 1490 1435 1395 1360 1315
____________________________________________________________________________________


T/K 443.15 453.15 463.15 473.15 483.15 493.15 503.15 513.15 523.15
P/bar 2355 2160 1950 1805 1690 1585 1495 1440 1385
T/K 533.15
P/bar 1340


T/K 451.15 453.15 468.15 473.15 478.15 483.15 488.15 493.15 503.15
P/bar 2450 2350 2250 2140 2040 1935 1860 1800 1690
T/K 513.15 523.15 533.15
P/bar 1580 1510 1435

−1 −1
Characterization: Mn/kg.mol = 15.1, Mw/kg.mol = 43.9, 5.8 mol% methacrylic acid

T/K 473.15 483.15 493.15 503.15 513.15 523.15 533.15
P/bar 2390 2120 1940 1780 1660 1575 1440


T/K 494.15 498.15 501.15 512.15 523.15 533.15
P/bar 2320 2190 2055 1805 1625 1480
____________________________________________________________________________________

Characterization: 9.0 mol% methacrylic acid, synthesized in the laboratory

T/K 508.15 513.15 518.15 523.15 528.15 533.15
P/bar 2650 2440 2250 2125 1990 1860
Polymer (B): ethylene/methyl acrylate copolymer 2003BUB

Characterization: 5.5 mol% mol% methyl acrylate, synthesized in the laboratory

T/K 383.15 393.15 403.15 413.15 423.15 433.15 443.15 453.15 463.15
P/bar 1530 1420 1369 1331 1300 1269 1248 1222 1200
T/K 473.15 483.15
P/bar 1182 1165
Polymer (B): ethylene/methyl acrylate copolymer 2004BEC

6.0 mol% methyl acrylate, synthesized in the laboratory

T/K 373.15 383.15 393.15 403.15 413.15 423.15 433.15 443.15 453.15
P/bar 1642 1583 1533 1492 1448 1412 1381 1354 1324
T/K 463.15 473.15 483.15 493.15
P/bar 1300 1282 1262 1244
Polymer (B): ethylene/methyl acrylate copolymer 1999DIE


T/K 373.15 383.15 393.15 403.15 413.15 423.15 433.15 443.15 453.15
P/bar 1780 1700 1590 1540 1510 1485 1450 1440 1395
T/K 463.15 483.15
P/bar 1390 1350
____________________________________________________________________________________

13 mol% methyl acrylate, synthesized in the laboratory

T/K 493.15 483.15 473.15 463.15 453.15 443.15 433.15 423.15 413.15
P/bar 1185 1215 1223 1239 1260 1276 1288 1310 1351
T/K 403.15 393.15
P/bar 1388 1408


T/K 393.15 403.15 413.15 423.15 433.15 443.15 453.15 463.15 473.15
P/bar 1823 1780 1703 1612 1565 1510 1455 1429 1378
T/K 482.15
P/bar 1360


T/K 391.15 395.15 403.15 413.15 423.15 433.15 443.15 453.15 463.15
P/bar 2040 1980 1849 1768 1685 1605 1545 1490 1450
T/K 473.15 483.15
P/bar 1410 1382

44 mol% methyl acrylate, synthesized in the laboratory

continued
____________________________________________________________________________________
continued
T/K 393.15 403.15 413.15 423.15 433.15 443.15 453.15 463.15 473.15
P/bar 2115 2010 1923 1854 1790 1728 1679 1631 1585
T/K 483.15 493.15
P/bar 1545 1508
Polymer (B): ethylene/methyl acrylate copolymer 1996MU1

Characterization: Mn/kg.mol−1 = 17, Mw/kg.mol−1 = 75.4,
25 wt% methyl acrylate, synthesized in the laboratory

wB 0.010 0.010 0.010 0.010 0.010 0.050 0.050 0.050 0.050
T/K 522.65 498.15 473.85 448.55 424.05 523.95 498.85 472.75 449.15
P/MPa 113.7 119.8 123.6 128.8 133.0 115.9 119.4 123.2 127.5
wB 0.050 0.050 0.100 0.100 0.100 0.100 0.100 0.113 0.113
T/K 423.95 404.15 525.05 498.35 474.35 448.65 424.95 523.15 498.35
P/MPa 134.2 140.0 117.3 117.4 120.2 124.6 129.2 117.2 119.0
wB 0.113 0.113 0.113 0.149 0.149 0.149 0.149 0.149 0.207
T/K 473.55 448.85 423.45 522.85 498.55 473.25 448.45 423.05 523.95
P/MPa 122.7 125.5 131.2 116.7 118.8 121.2 125.0 130.2 109.4
wB 0.207 0.207 0.207 0.207
T/K 497.85 473.05 448.85 424.15
P/MPa 112.2 115.5 119.5 124.1


wB 0.010 0.010 0.010 0.010 0.010 0.050 0.050 0.050 0.050
T/K 523.75 498.35 473.75 448.05 423.55 522.95 498.65 473.95 449.05
P/MPa 125.8 133.7 140.6 149.7 161.3 124.9 130.8 138.2 148.5
wB 0.050 0.050 0.101 0.101 0.101 0.101 0.101 0.150 0.150
T/K 423.95 404.05 524.65 499.15 473.25 448.45 424.05 524.05 498.95
P/MPa 163.1 178.8 123.0 128.4 135.6 145.0 162.0 122.7 127.8
wB 0.150 0.150 0.150 0.200 0.200 0.200 0.200
T/K 473.45 448.95 423.55 523.75 498.45 473.85 448.45
P/MPa 132.3 140.6 150.6 117.3 122.1 128.2 136.2
____________________________________________________________________________________


wB 0.011 0.011 0.011 0.011 0.011 0.050 0.050 0.050 0.050
T/K 523.85 498.95 473.55 448.45 423.75 523.25 498.35 473.15 448.85
P/MPa 136.5 145.5 157.8 165.2 206.4 136.1 145.2 157.7 174.4
wB 0.050 0.050 0.101 0.101 0.101 0.101 0.101 0.150 0.150
T/K 423.85 403.65 523.65 498.25 473.25 448.25 423.15 523.35 498.15
P/MPa 201.3 234.3 133.6 142.0 153.0 167.4 189.3 133.9 141.0
wB 0.150 0.150 0.150 0.192 0.192 0.192 0.192 0.192
T/K 473.05 448.95 424.35 523.45 497.95 472.65 448.85 423.45
P/MPa 151.8 164.9 184.1 132.0 139.9 150.0 163.2 181.9
Polymer (B): ethylene/methyl methacrylate copolymer 2003BUB

Characterization: 5.8 mol% mol% methyl methacrylate, synthesized in the laboratory

T/K 383.15 393.15 403.15 413.15 423.15 433.15 443.15 453.15 473.15
P/bar 1433 1366 1320 1290 1266 1241 1215 1195 1156
T/K 483.15
P/bar 1140
Polymer (B): ethylene/methyl methacrylate copolymer 2004BEC

17 mol% methyl methacrylate, synthesized in the laboratory

T/K 383.15 393.15 413.15 433.15 453.15 473.15
P/bar 1465 1435 1354 1292 1237 1208


continued
____________________________________________________________________________________
continued
T/K 353.15 373.15 393.15 413.15 433.15 453.15 473.15 488.15 508.15
P/bar 1430 1309 1252 1206 1176 1137 1108 1086 1057
T/K 528.15
P/bar 1039

−1 −1
Characterization: Mn/kg.mol = 50, Mw/kg.mol = 83.5,

T/K 393.15 413.15 433.15 453.15 473.15 488.15 508.15
P/bar 1500 1419 1341 1286 1238 1202 1152


T/K 393.15 403.15 413.15 423.15 443.15 463.15 473.15 483.15 493.15
P/bar 1673 1585 1533 1478 1378 1306 1271 1242 1210

−1 −1

T/K 393.15 413.15 453.15 473.15 488.15 508.15
P/bar 1855 1716 1507 1436 1366 1328
Polymer (B): ethylene/1-octene copolymer 2000CH4

13.9 wt% 1-octene, 4 hexyl branches/100 ethyl units
continued
____________________________________________________________________________________
continued
wB 0.099 0.099 0.099 0.099 0.099 0.099 0.099 0.099
T/K 453.15 438.15 423.15 413.15 403.15 393.15 388.15 385.15
P/bar 1362 1410 1477 1510 1556 1614 1644 1668


wB 0.105 0.105 0.105 0.105
T/K 453.15 433.15 413.15 393.15
P/bar 1303 1350 1408 1504

36.5 wt% 1-octene, 12.6 hexyl branches/100 ethyl units

wB 0.099 0.099 0.099 0.099 0.099 0.099 0.099 0.099 0.099
T/K 453.15 443.15 433.15 423.15 413.15 403.15 393.15 383.15 373.15
P/bar 1097 1116 1135 1156 1182 1210 1246 1286 1332


wB 0.047 0.047 0.047 0.047 0.047 0.047 0.047 0.099 0.099
T/K 453.15 443.15 433.15 423.15 413.15 403.15 393.15 453.15 443.15
P/bar 1221 1231 1249 1270 1297 1330 1363 1199 1217
wB 0.099 0.099 0.099 0.099 0.099 0.124 0.124 0.124 0.124
T/K 433.15 423.15 413.15 403.15 393.15 453.15 443.15 433.15 423.15
P/bar 1264 1254 1281 1311 1345 1168 1182 1194 1215
wB 0.124 0.124
T/K 413.15 403.15
P/bar 1241 1268
____________________________________________________________________________________
Polymer (B): ethylene/1-octene copolymer 1998HAN

Characterization: Mn/kg.mol−1 = 40.7, Mw/kg.mol−1 = 93.6, 7.6 mol% 1-octene,

wB 0.05 0.05 0.05 0.05 0.05
T/K 374.25 399.25 422.65 446.75 471.55
P/bar 531.2 515.5 520.4 524.0 529.5


wB 0.050 0.050 0.050 0.050 0.050 0.050
T/K 453.15 413.15 393.15 373.15 368.15 363.15
P/MPa 53.4 52.8 52.8 53.2 53.5 53.7


wB 0.049 0.049 0.049
T/K 453.15 413.15 373.15
P/MPa 48.5 47.1 46.3


wB 0.010 0.010 0.010 0.010 0.010 0.049 0.049 0.049 0.049
T/K 453.15 413.15 373.15 343.15 333.15 453.15 413.15 373.15 343.15
P/MPa 38.6 36.0 33.2 34.8 37.8 40.8 38.4 35.6 33.7
wB 0.049 0.100 0.100 0.100
T/K 333.15 453.15 413.15 373.15
P/MPa 33.6 40.4 37.9 35.5
____________________________________________________________________________________
Polymer (B): ethylene/propyl acrylate copolymer 2004BEC

Characterization: 7.0 mol% propyl acrylate, synthesized in the laboratory

T/K 366.45 376.15 386.65 393.15 413.15 423.15 442.15 452.15 472.15
P/bar 1527 1476 1433 1408 1338 1310 1262 1244 1204
T/K 491.15 511.15 531.15
P/bar 1173 1141 1115

14 mol% propyl acrylate, synthesized in the laboratory

T/K 353.15 363.15 373.65 397.85 415.45 434.15 452.15 473.15 492.15
P/bar 1380 1330 1297 1234 1192 1150 1127 1098 1074
T/K 509.15 532.15
P/bar 1056 1035


T/K 367.15 373.15 393.15 412.15 431.15 451.15 468.15 491.55 512.15
P/bar 1250 1226 1183 1153 1124 1097 1077 1055 1031
T/K 529.85
P/bar 1018


continued
____________________________________________________________________________________
continued
T/K 354.15 374.15 392.15 413.15 433.15 451.15 471.15 491.15 512.15
P/bar 1208 1182 1147 1112 1083 1062 1038 1017 995
T/K 530.15
P/bar 978

−1 −1
Characterization: Mn/kg.mol = 0.78, Mw/kg.mol = 0.79, 50 mol% propene,

T/K 355.05 373.15 398.15 421.65 424.05 426.35 428.15 432.95 444.45
P/bar 11.5 16.4 27.1 39.8 42.5 44.8 46.5 51.7 63.4
T/K 473.15
P/bar 90.8


T/K 376.15 378.85 382.65 397.95 423.15 447.95 473.15
P/bar 21.3 27.2 35.5 66.7 110.0 146.0 172.5
Comments: A lower critical endpoint is found at 373.15 K.


T/K 346.35 348.35 350.35 355.15 361.35 361.85 367.45 373.15 398.15
P/bar 12.3 15.2 20.5 29.0 40.2 38.2 50.3 61.2 108.0
continued
____________________________________________________________________________________
continued
T/K 416.35 423.15 448.35 473.35
P/bar 137.3 149.0 183.0 213.4


T/K 334.45 336.05 339.55 343.75 355.15 373.15 398.15 423.75 448.15
P/bar 8.4 13.1 19.5 28.4 54.0 90.8 137.3 177.3 210.1
T/K 473.15
P/bar 240.5
Polymer (B): ethylene/propylene copolymer 2000VRI

42 mol% propene, 21 methyl groups/100 C-atoms

wB 0.0357 0.0357 0.0357 0.0357 0.0357 0.0357 0.0357 0.0498 0.0498
T/K 312.54 317.69 322.51 327.48 332.66 337.28 342.13 312.62 317.58
P/bar 2181 2077 1985 1897 1816 1756 1702 2163 2057
wB 0.0498 0.0498 0.0498 0.0498 0.0498 0.0756 0.0756 0.0756 0.0756
T/K 322.53 327.10 332.09 337.40 342.30 312.76 317.91 322.27 327.47
P/bar 1961 1885 1809 1741 1684 2115 2006 1926 1843
wB 0.0756 0.0756 0.0756 0.0989 0.0989 0.0989 0.0989 0.0989 0.0989
T/K 332.22 337.10 341.96 312.54 317.71 322.64 327.50 332.21 337.36
P/bar 1776 1715 1661 2083 1977 1890 1811 1749 1687
wB 0.0989 0.1230 0.1230 0.1230 0.1230 0.1230 0.1230 0.1230 0.1491
T/K 342.25 312.38 317.41 322.40 327.20 332.31 337.13 342.06 312.62
P/bar 1634 2061 1960 1874 1797 1730 1673 1619 2011
wB 0.1491 0.1491 0.1491 0.1491 0.1491 0.1491
T/K 317.54 322.33 327.28 332.16 337.03 341.77
P/bar 1917 1837 1765 1703 1647 1597
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 8.7, Mw/kg.mol−1 = 24, Mz/kg.mol−1 = 47,

wB 0.0468 0.0468 0.0468 0.0468 0.0468 0.0468 0.0468 0.1168 0.1168
T/K 312.82 317.56 323.16 327.72 332.74 337.29 342.55 312.66 317.71
P/bar 1827 1748 1666 1610 1555 1512 1465 1759 1682
wB 0.1668 0.1168 0.1168 0.1168 0.1168 0.1503 0.1503 0.1503 0.1503
T/K 322.51 327.38 332.26 337.28 42.01 312.75 317.60 322.28 327.76
P/bar 1617 1559 1505 1457 1413 1715 1646 1586 1524
wB 0.1503 0.1503 0.1503 0.1983 0.1983 0.1983 0.1983 0.1983 0.1983
T/K 332.25 337.59 342.52 312.66 317.59 322.98 327.48 332.79 337.26
P/bar 1480 1432 1395 1615 1553 1492 1447 1399 1364
wB 0.1983
T/K 342.69
P/bar 1325
Polymer (B): ethylene/propylene copolymer 1993GRE, 1994GR4


wB 0.156 0.156 0.156 0.152 0.152
T/K 293.15 323.15 363.15 423.15 475.15
P/bar 571.5 555.0 550.0 600.9 689.6

−1 −1

wB 0.156 0.156 0.156 0.158 0.158 0.157 0.158 0.158 0.158
T/K 308.15 323.15 325.65 348.15 373.15 398.15 448.15 468.15 473.15
P/bar 1080.1 1018.6 1001.1 941.9 897.9 899.9 899.1 892.8 900.0
____________________________________________________________________________________

wB 0.038 0.038 0.038 0.038 0.038
T/K 353.15 373.15 398.15 423.15 473.15
P/bar 1722.5 1569.0 1389.0 1235.5 1132.7
Polymer (B): ethylene/propylene copolymer 1997HAN

−1 −1
Tg/K = 209.2, alternating ethylene/propylene units from
complete hydrogenation (98%) of polyisoprene
wB 0.001 0.001 0.001 0.0067 0.0067 0.0067 0.0067 0.0095 0.0095
T/K 323.15 372.95 423.15 294.55 323.35 373.05 423.05 295.05 323.35
P/bar 381.2 396.7 410.5 490.4 484.3 483.1 491.0 539.4 523.0
wB 0.0095 0.0095 0.026 0.026 0.026 0.026 0.034 0.034 0.034
T/K 373.15 423.15 298.45 323.35 373.05 423.05 323.35 372.95 423.55
P/bar 517.1 522.8 623.3 600.1 576.5 570.4 622.7 596.2 588.9

T/K = 423.15
______________________________________________________
P/ wB
bar feed phase gel phase sol phase
______________________________________________________
505 0.034 unknown 0.016
______________________________________________________
Polymer (B): ethylene/propylene copolymer 1992CH1, 1992CH2

−1 −1
T/K 427.15 447.95 467.85 473.15 477.95 478.65 473.15 477.95 478.55
P/bar 7.2 12.7 17.2 23.5 29.4 31.6 19.3 20.0 20.4
(VLE VLE VLE LLE LLE LLE VLLE VLLE VLLE)
____________________________________________________________________________________


T/K 416.95 453.15 459.35 454.95 474.45 463.95
P/bar 8.3 14.0 18.3 28.5 43.3 17.3
(VLE VLE LLE LLE LLE VLLE)

Characterization: Mn/kg.mol−1 = 32.3, Mw/kg.mol−1 = 71, 8.7 mol% propene,

wB 0.05 0.05 0.05 0.05 0.05
T/K 372.65 397.65 420.15 445.15 472.15
P/bar 568.7 559.3 559.6 558.9 560.9

−1 −1
Characterization: Mn/kg.mol = 34.5, Mw/kg.mol = 72.5, 10.3 mol% propene,

wB 0.05 0.05 0.05 0.05 0.05
T/K 376.25 400.35 424.35 446.95 472.15
P/bar 565.4 550.3 551.2 554.0 557.8

−1 −1

wB 0.05 0.05 0.05 0.05 0.05 0.05
T/K 351.55 375.95 400.55 426.05 446.55 470.45
P/bar 471.2 474.4 482.9 493.7 502.3 511.5
____________________________________________________________________________________

wB 0.009 0.009 0.009 0.009 0.043 0.043 0.043 0.043 0.132
T/K 324.15 373.55 375.15 422.95 323.65 373.35 375.95 423.25 323.15
P/bar 43.7 139.4 142.5 198.6 53.7 152.0 156.3 224.2 70.4
wB 0.132 0.132 0.343 0.343 0.343
T/K 372.95 423.45 323.05 373.25 423.35
P/bar 175.6 261.8 32.4 137.2 210.2

complete hydrogenation of polyisoprene
wB 0.045 0.045
T/K 373.15 423.15
P/bar 363.0 413.8

wB 0.048 0.048 0.048 0.099 0.099 0.099
T/K 323.45 372.95 422.85 323.25 373.15 423.05
P/bar 218.1 288.0 348.5 216.9 286.9 348.9

−1 −1
Characterization: Mn/kg.mol = 177, Mw/kg.mol = 195, 50 mol% propene,
wB 0.008 0.008 0.008 0.050 0.050 0.050 0.100 0.100
T/K 323.35 372.85 423.25 322.95 372.95 423.45 323.35 423.35
P/bar 341.2 387.9 437.0 346.9 393.0 441.9 229.8 438.6
____________________________________________________________________________________


T/K 319.45 343.35 350.55 352.15 355.05 373.35 397.95 423.15 447.95
P/bar 19.0 30.2 34.4 37.7 43.0 73.0 113.0 144.0 170.0
(VLE VLE VLE LLE LLE LLE LLE LLE LLE)
T/K 473.35 352.15 353.75 355.05
P/bar 180.0 35.9 36.9 38.3
(LLE VLLE VLLE VLLE)

−1 −1

T/K 272.65 298.15 325.15 356.15 373.15 398.95 423.35 447.95 472.75
P/bar 5.5 64.0 126.0 190.5 224.4 267.0 296.0 325.0 344.0
Polymer (B): ethylene/propylene copolymer 1993GRE, 1994GR4, 1994GR5


wB 0.018 0.073 0.150 0.216 0.281 0.392 0.018 0.073 0.150
T/K 373.15 373.75 373.15 373.35 373.45 373.15 423.15 423.15 423.15
P/bar 179.5 202.8 212.5 209.8 200.2 189.1 248.6 273.7 295.0
wB 0.216 0.329
T/K 423.15 423.15
P/bar 293.0 267.1
____________________________________________________________________________________


T/K 323.55 355.55 373.55 398.05 423.55 448.15
P/bar 273.0 312.0 332.0 361.2 388.0 412.0


T/K 264.15 265.85 271.15 274.15 277.95 280.35 285.25 287.05 293.55
P/bar 354.0 347.0 337.0 331.0 325.5 322.5 316.7 315.0 311.0
T/K 303.05 317.15 322.55 331.15 354.65 373.05 397.75 423.35 447.95
P/bar 310.6 319.5 322.3 330.0 352.0 371.0 396.4 423.0 442.3
T/K 473.55
P/bar 461.0
Polymer (B): ethylene/propylene copolymer 1993GRE, 1994GR4, 1994GR5

−1 −1

wB 0.008 0.045 0.088 0.158 0.231 0.008 0.045 0.088 0.158
T/K 373.15 373.15 373.15 373.15 373.15 423.15 423.15 423.15 423.15
P/bar 393.1 363.0 371.3 371.2 343.0 402.1 413.8 423.0 423.1
wB 0.231
T/K 423.15
P/bar 393.0
____________________________________________________________________________________
Polymer (B): ethylene/propylene/isoprene terpolymer 1996ALB

Characterization: Mn/kg.mol−1 = 7.65, Mw/kg.mol−1 = 13.6, 28.2 mol% propene,
43.6 mol% isoprene, alternating ethylene/propylene units from
partial hydrogenation of polyisoprene
Solvent (A): dimethyl ether C2H6O 115-10-6

T/K 424.75 383.25 347.55 329.95
P/bar 216.6 133.0 46.2 12.2


T/K 423.45 411.95 410.65 384.35 362.35 348.65 328.15
P/bar 208.9 186.1 184.4 132.9 85.5 53.5 11.9

−1 −1

T/K 423.65 414.15 393.75 392.85 383.05 382.25 373.75 364.85 362.25
P/bar 818.1 824.2 869.4 874.3 918.7 923.0 964.9 1005.4 1038.7


continued
____________________________________________________________________________________
continued
T/K 423.75 423.15 421.65 409.15 394.35
P/bar 1249.1 1250.5 1256.2 1293.2 1352.9


T/K 422.75 422.05 390.05 389.85 388.75 388.45 363.95 347.75 333.65
P/bar 377.8 378.3 370.2 370.2 366.6 369.5 398.0 423.0 453.0
T/K 327.25
P/bar 472.3

−1 −1

T/K 424.25 390.45 363.65 339.05 335.85 310.95
P/bar 357.5 320.7 301.1 304.5 305.0 337.5
Polymer (B): ethylene/vinyl acetate copolymer 1982RAE

−1 −1
Characterization: Mn/kg.mol = 20.4, Mw/kg.mol = 145, 7.5 wt% vinyl acetate,

T/K = 433.15
wB 0.05 0.10 0.15 0.20 0.30
P/MPa 140.3 139.3 137.3 131.2 121.0
____________________________________________________________________________________
Polymer (B): ethylene/vinyl acetate copolymer 1984WAG

Characterization: Mn/kg.mol−1 = 20.4, Mw/kg.mol−1 = 145, 7.5 wt% vinyl acetate,

wB 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15 0.20
T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 155.0 154.5 149.5 144.9 133.2 146.4 144.9 141.9 136.8
wB 0.30 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15
T/K 413.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 126.1 140.7 139.3 137.9 131.2 121.0 135.3 134.8 133.2
wB 0.20 0.30 0.05 0.10 0.15 0.20 0.30
T/K 453.15 453.15 473.15 473.15 473.15 473.15 473.15
P/MPa 127.2 116.0 130.7 129.7 126.7 122.6 113.0
Polymer (B): ethylene/vinyl acetate copolymer 1991NIE

Exxon Chemical Company

T/K = 403.15
____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
88.6 0.449 0.991
108.8 0.567 0.983
125.5 0.674 0.968
136.2 0.768 0.949
____________________________________________________________________________________

−1 −1

T/K = 433.15
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
94.8 0.501 0.992
104.9 0.568 0.985
115.2 0.652 0.975
128.2 0.782 0.952
____________________________________________________________________________________

−1 −1

T/K = 433.15
wB 0.05 0.10 0.15 0.20 0.30
P/MPa 132.4 128.5 125.0 121.6 114.7

−1 −1

wB 0.05 0.075 0.10 0.15 0.20 0.30 0.05 0.075 0.10
T/K 393.15 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15
P/MPa 146.6 145.1 143.3 138.9 133.9 125.5 137.8 137.3 134.8
wB 0.15 0.20 0.30 0.05 0.075 0.10 0.15 0.20 0.30
T/K 413.15 413.15 413.15 433.15 433.15 433.15 433.15 433.15 433.15
P/MPa 130.4 127.0 119.6 132.4 130.4 128.5 125.0 121.6 114.7
wB 0.05 0.075 0.10 0.15 0.20 0.30 0.05 0.075 0.10
T/K 453.15 453.15 453.15 453.15 453.15 453.15 473.15 473.15 473.15
P/MPa 127.5 125.5 124.0 120.6 117.7 109.8 122.6 121.1 119.6
wB 0.15 0.20 0.30
T/K 473.15 473.15 473.15
P/MPa 116.7 113.8 105.5
____________________________________________________________________________________

wB 0.030 0.030 0.030 0.081 0.081 0.081 0.081 0.211 0.211
T/K 373.65 403.15 433.15 363.15 393.15 423.15 453.15 388.15 403.15
P/MPa 158.6 143.5 133.0 156.2 141.4 131.8 124.5 136.5 130.5
wB 0.211 0.211 0.344 0.344 0.344 0.344 0.462 0.462 0.462
T/K 433.15 448.15 398.65 403.15 433.15 453.15 373.15 433.15 463.15
P/MPa 122.8 119.6 125.5 117.5 111.4 108.2 104.2 95.0 93.5
wB 0.585 0.585 0.585
T/K 393.15 433.15 453.15
P/MPa 78.2 77.2 76.8

T/K = 403.15
____________________________________________________________________________________
____________________________________________________________________________________
P/ Mn/ M w/ Mn/ M w/ M z/
MPa kg/mol kg/mol kg/mol kg/mol kg/mol
____________________________________________________________________________________
48.7 0.276 0.9992
100.1 0.543 0.989 7.8 15.3 30.6
118.7 0.680 0.980 11.7 23.8 42.4
134.1 0.855 (cloud point) 33.4 137.7 (feed sample)
____________________________________________________________________________________
T/K = 433.15
____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
43.1 0.280
47.8 0.999
75.5 0.410
77.5 0.995
89.7 0.497 0.993
103.5 0.584 0.984
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
107.9 0.623 0.985
113.8 0.679 0.972
121.0 0.757 0.948
123.8 0.792 0.940
____________________________________________________________________________________
T/K = 463.15
____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
48.1 0.252 0.9994
97.4 0.542 0.9905
108.7 0.650 0.9792
____________________________________________________________________________________

−1 −1

wB 0.040 0.040 0.040 0.067 0.067 0.101 0.101 0.101 0.157
T/K 373.15 403.15 463.15 393.15 433.15 393.15 433.15 453.15 373.15
P/MPa 146.6 139.8 125.5 139.7 129.0 138.5 128.0 123.8 143.5
wB 0.157 0.157 0.157 0.262 0.262 0.262 0.262 0.360 0.360
T/K 393.15 433.15 453.15 393.15 413.15 433.15 453.15 403.15 418.15
P/MPa 136.5 126.2 122.5 130.2 125.4 121.2 117.0 115.5 113.0
wB 0.360 0.408 0.408 0.408 0.408 0.480 0.480 0.480 0.480
T/K 453.15 393.15 413.15 433.15 453.15 373.15 393.15 433.15 449.15
P/MPa 108.2 110.6 107.5 105.2 102.8 99.2 96.5 94.0 93.8

continued
____________________________________________________________________________________
continued
T/K = 433.15
wB 0.05 0.10 0.15 0.20 0.30
P/MPa 121.0 120.0 118.0 115.5 109.0

wB 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15 0.20
T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 128.5 127.5 125.5 123.0 116.5 125.5 124.0 122.0 119.0
wB 0.30 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15
T/K 413.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 112.0 121.0 120.0 118.0 115.5 109.0 118.5 117.0 115.0
wB 0.20 0.30 0.05 0.10 0.15 0.20 0.30
T/K 453.15 453.15 473.15 473.15 473.15 473.15 473.15
P/MPa 112.0 105.0 115.5 113.5 111.5 109.0 102.5

Characterization: Mn/kg.mol−1 = 35, Mw/.g.mol−1 = 126.5, 27.5 wt% vinyl acetate,
T/K = 433.15
____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
70.8 0.998
80.0 0.996
80.8 0.450
92.8 0.551 0.987
104.0 0.981
104.2 0.600
113.8 0.693
114.2 0.964
119.0 0.745 0.945
120.5 0.936
123.8 0.792
____________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): ethylene/vinyl acetate copolymer 1999KIN

Characterization: Mn/kg.mol−1 = 61.9, Mw/kg.mol−1 = 167, 27.5 wt% vinyl acetate

wB 0.030 0.060 0.100 0.150 0.200 0.230 0.240 0.250 0.270
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15
P/MPa 121.6 128.7 128.3 125.9 121.4 118.0 116.9 115.7 113.4
wB 0.300 0.350 0.030 0.060 0.100 0.150 0.200 0.230 0.240
T/K 393.15 393.15 413.15 413.15 413.15 413.15 413.15 413.15 413.15
P/MPa 111.4 110.4 117.5 124.0 123.6 121.5 117.4 114.5 113.4
wB 0.250 0.270 0.300 0.350 0.030 0.060 0.100 0.150 0.200
T/K 413.15 413.15 413.15 413.15 433.15 433.15 433.15 433.15 433.15
P/MPa 112.3 110.2 108.0 107.0 113.7 119.5 119.2 117.4 113.6
wB 0.230 0.240 0.250 0.270 0.300 0.350 0.030 0.060 0.100
T/K 433.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 110.7 109.8 109.2 107.3 105.4 104.4 110.5 116.3 116.0
wB 0.150 0.200 0.230 0.240 0.250 0.270 0.300 0.350 0.030
T/K 453.15 453.15 453.15 453.15 453.15 453.15 453.15 453.15 473.15
P/MPa 113.9 110.5 108.1 107.1 106.4 104.7 102.9 101.9 108.1
wB 0.060 0.100 0.150 0.200 0.230 0.240 0.250 0.270 0.300
T/K 473.15 473.15 473.15 473.15 473.15 473.15 473.15 473.15 473.15
P/MPa 113.0 112.9 111.2 108.0 105.9 104.9 104.2 102.1 100.8
wB 0.350 0.030 0.060 0.100 0.150 0.200 0.230 0.240 0.250
T/K 473.15 493.15 493.15 493.15 493.15 493.15 493.15 493.15 493.15
P/MPa 99.8 105.7 110.4 110.3 108.5 105.7 103.7 102.8 101.9
wB 0.270 0.300 0.350
T/K 493.15 493.15 493.15
P/MPa 100.0 98.8 97.8


wB 0.014 0.04 0.07 0.10 0.20 0.25 0.30 0.05 0.10
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 433.15 433.15
P/MPa 122.6 124.0 123.1 121.6 118.7 115.2 114.2 117.9 115.1
wB 0.20 0.30 0.014 0.04 0.07 0.10 0.20 0.25 0.30
T/K 433.15 433.15 473.15 473.15 473.15 473.15 473.15 473.15 473.15
P/MPa 112.0 108.3 111.3 113.3 110.3 107.4 106.4 103.9 102.5
____________________________________________________________________________________


T/K = 443.15
____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
48.06 0.2719
52.08 0.9710
55.12 0.3199
67.77 0.4045 0.9364
80.71 0.5468 0.8985
81.49 0.5211 0.8930
90.12 0.7401 0.7584
____________________________________________________________________________________

−1 −1
Characterization: Mn/kg.mol = 27.5, Mw/kg.mol = 60.3, 31.4 wt% vinyl acetate,

wB 0.014 0.04 0.07 0.10 0.15 0.20 0.25 0.30 0.014
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15 413.15
P/MPa 122.6 124.0 123.1 121.6 122.1 119.7 115.2 114.2 119.2
wB 0.04 0.07 0.10 0.15 0.20 0.25 0.30 0.014 0.04
T/K 413.15 413.15 413.15 413.15 413.15 413.15 413.15 433.15 433.15
P/MPa 121.6 118.7 118.1 118.7 115.2 112.8 110.3 116.2 118.2
wB 0.07 0.10 0.15 0.20 0.25 0.30 0.014 0.04 0.07
T/K 433.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 115.7 114.5 114.5 110.8 110.3 108.4 114.2 115.2 112.8
wB 0.10 0.15 0.20 0.25 0.30 0.014 0.04 0.07 0.10
T/K 453.15 453.15 453.15 453.15 453.15 473.15 473.15 473.15 473.15
P/MPa 111.8 111.8 108.8 108.8 106.4 111.3 113.3 110.3 107.4
wB 0.15 0.20 0.25 0.30
T/K 473.15 473.15 473.15 473.15
P/MPa 108.4 106.4 105.9 102.5
____________________________________________________________________________________


T/K = 433.15
wB 0.05 0.10 0.15 0.20 0.30
P/MPa 119.7 119.5 117.5 115.5 111.5

−1 −1

wB 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15 0.20
T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 126.8 126.0 125.8 124.5 119.5 123.0 122.2 121.0 120.0
wB 0.30 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15
T/K 413.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 115.5 119.7 119.5 117.5 115.5 111.5 116.0 115.7 114.0
wB 0.20 0.30 0.05 0.10 0.15 0.20 0.30
T/K 453.15 453.15 473.15 473.15 473.15 473.15 473.15
P/MPa 112.0 108.0 113.5 112.5 111.0 109.2 105.5

−1 −1

wB 0.12 0.16 0.20 0.25 0.30 0.0075 0.12 0.16 0.20
T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 121.1 120.6 118.7 116.2 112.3 114.2 117.2 117.2 114.7
wB 0.25 0.30 0.0075 0.04 0.08 0.12 0.16 0.20 0.25
T/K 413.15 413.15 433.15 433.15 433.15 433.15 433.15 433.15 433.15
P/MPa 113.7 108.8 111.3 114.2 113.7 114.7 113.7 111.8 110.3
wB 0.30 0.0075 0.04 0.08 0.12 0.16 0.20 0.25 0.30
T/K 433.15 453.15 453.15 453.15 453.15 453.15 453.15 453.15 453.15
P/MPa 106.9 110.9 112.3 110.8 111.8 110.8 109.8 107.4 103.9
wB 0.0075 0.04 0.08 0.12 0.16 0.20 0.25 0.30
T/K 473.15 473.15 473.15 473.15 473.15 473.15 473.15 473.15
P/MPa 108.4 109.8 108.4 108.8 107.9 105.9 104.9 102.0
____________________________________________________________________________________

wB 0.009 0.04 0.08 0.12 0.20 0.25 0.30 0.009 0.04
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 473.15 473.15
P/MPa 118.7 120.1 118.2 117.4 114.9 111.8 105.9 107.9 109.8
wB 0.08 0.12 0.20 0.25 0.30
T/K 473.15 473.15 473.15 473.15 473.15
P/MPa 107.9 106.9 105.9 102.7 99.1

wB 0.009 0.04 0.08 0.12 0.20 0.25 0.304 0.009 0.04
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 413.15 413.15
P/MPa 118.7 120.1 118.2 117.4 114.9 111.8 105.9 116.2 118.2
wB 0.08 0.12 0.20 0.25 0.304 0.009 0.04 0.08 0.12
T/K 413.15 413.15 413.15 413.15 413.15 433.15 433.15 433.15 433.15
P/MPa 115.2 114.9 112.3 108.4 104.5 112.3 115.2 112.8 112.5
wB 0.20 0.25 0.304 0.009 0.04 0.08 0.12 0.20 0.25
T/K 433.15 433.15 433.15 453.15 453.15 453.15 453.15 453.15 453.15
P/MPa 110.3 106.4 103.2 110.8 112.8 110.3 108.9 107.9 104.5
wB 0.304 0.009 0.04 0.08 0.12 0.20 0.25 0.30
T/K 453.15 473.15 473.15 473.15 473.15 473.15 473.15 473.15
P/MPa 100.2 107.9 109.8 107.9 106.9 105.9 102.7 99.1

−1 −1
wB 0.068 0.068 0.068 0.068 0.157 0.157 0.178 0.178 0.178
T/K 383.15 393.15 433.15 453.15 383.15 433.15 373.15 403.15 453.15
P/MPa 118.2 115.8 108.5 105.7 116.5 107.0 116.0 110.0 103.2
wB 0.300 0.300 0.300 0.393 0.393 0.393 0.393 0.393 0.439
T/K 393.15 403.15 433.15 353.15 373.15 403.15 433.15 453.15 373.15
P/MPa 107.5 106.0 102.3 107.4 103.5 99.2 96.4 95.0 98.0
wB 0.439
T/K 433.15
P/MPa 92.2
____________________________________________________________________________________


wB 0.014 0.04 0.08 0.12 0.20 0.25 0.32 0.014 0.04
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 473.15 473.15
P/MPa 92.7 98.6 100.0 99.0 98.6 96.6 94.3 86.8 93.6
wB 0.08 0.12 0.20 0.25 0.32
T/K 473.15 473.15 473.15 473.15 473.15
P/MPa 93.2 91.2 90.7 88.7 86.8

−1 −1

wB 0.014 0.04 0.08 0.12 0.16 0.20 0.25 0.32 0.014
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15 413.15
P/MPa 92.7 98.6 100.0 99.0 98.6 99.0 96.6 94.2 90.2
wB 0.04 0.08 0.12 0.16 0.20 0.25 0.32 0.014 0.04
T/K 413.15 413.15 413.15 413.15 413.15 413.15 413.15 433.15 433.15
P/MPa 97.1 98.1 96.8 97.1 96.9 95.1 93.2 88.7 96.1
wB 0.08 0.12 0.16 0.20 0.25 0.32 0.014 0.04 0.08
T/K 433.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 96.1 94.6 95.1 94.3 92.7 90.2 87.8 95.1 94.6
wB 0.12 0.16 0.20 0.25 0.32 0.014 0.04 0.08 0.12
T/K 453.15 453.15 453.15 453.15 453.15 473.15 473.15 473.15 473.15
P/MPa 92.7 93.2 92.7 90.4 88.7 86.8 93.6 93.2 91.2
wB 0.16 0.20 0.25 0.32
T/K 473.15 473.15 473.15 473.15
P/MPa 91.2 90.7 88.7 80.8


wB 0.05 0.10 0.20 0.30
T/K 433.15 433.15 433.15 433.15
P/MPa 111.2 111.0 108.4 104.4
____________________________________________________________________________________


wB 0.007 0.03 0.08 0.12 0.16 0.20 0.25 0.30 0.007
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15 413.15
P/MPa 114.2 116.2 118.2 116.7 116.7 115.2 113.3 110.8 110.8
wB 0.03 0.08 0.12 0.16 0.20 0.25 0.30 0.007 0.03
T/K 413.15 413.15 413.15 413.15 413.15 413.15 413.15 433.15 433.15
P/MPa 113.3 114.9 112.8 112.8 112.3 109.8 106.7 108.4 110.8
wB 0.08 0.12 0.16 0.20 0.25 0.30 0.007 0.03 0.08
T/K 433.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 111.8 109.3 108.8 108.4 107.4 104.1 105.9 108.4 108.4
wB 0.12 0.16 0.20 0.25 0.30 0.007 0.03 0.08 0.12
T/K 453.15 453.15 453.15 453.15 453.15 473.15 473.15 473.15 473.15
P/MPa 106.9 106.9 105.9 103.9 100.8 104.4 105.9 106.4 104.4
wB 0.16 0.20 0.25 0.30
T/K 473.15 473.15 473.15 473.15
P/MPa 104.4 103.0 101.0 98.6

−1 −1

wB 0.0105 0.04 0.08 0.12 0.16 0.20 0.25 0.30 0.0105
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15 413.15
P/MPa 114.2 114.7 110.8 110.3 110.3 107.8 107.8 106.4 111.0
wB 0.04 0.08 0.12 0.16 0.20 0.25 0.30 0.0105 0.04
T/K 413.15 413.15 413.15 413.15 413.15 413.15 413.15 433.15 433.15
P/MPa 111.8 108.4 107.4 105.9 103.9 104.2 103.5 108.4 108.8
wB 0.08 0.12 0.16 0.20 0.25 0.30 0.0105 0.04 0.08
T/K 433.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 105.4 104.4 102.5 102.0 102.0 100.5 106.9 106.4 103.0
wB 0.12 0.16 0.20 0.25 0.30 0.0105 0.04 0.08 0.12
T/K 453.15 453.15 453.15 453.15 453.15 473.15 473.15 473.15 473.15
P/MPa 101.5 100.5 100.1 100.1 98.5 104.4 104.4 101.0 99.5
wB 0.16 0.20 0.25 0.30
T/K 473.15 473.15 473.15 473.15
P/MPa 98.5 98.0 97.6 96.6
____________________________________________________________________________________
Polymer (B): ethylene/vinyl acetate copolymer 1983RAE, 1984WAG


wB 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15 0.20
T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 121.3 118.6 116.5 114.1 112.4 117.2 115.5 112.7 110.3
wB 0.30 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15
T/K 413.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 109.6 114.5 112.0 109.8 107.5 106.2 111.3 108.9 106.9
wB 0.20 0.30 0.05 0.10 0.15 0.20 0.30
T/K 453.15 453.15 473.15 473.15 473.15 473.15 473.15
P/MPa 105.5 103.4 108.6 106.8 103.4 102.7 101.0

Characterization: Mn/kg.mol−1 = 35, 58.0 wt% vinyl acetate,

T/K = 463.15
____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
93.5 0.376
133.0 0.980
139.5 0.560
151.6 0.602
156.2 0.972
160.2 0.630
164.5 0.964
170.0 0.942
171.5 0.718
174.5 0.920
____________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): DL-lactide/glycolide copolymer 2001CON

Characterization: Mn/kg.mol−1 = 61.7, Mw/kg.mol−1 = 95, 15 mol% glycolide,
Tg/K = 320.55, Alkermes, Inc., Cincinnati, OH

wB 0.05 0.05 0.05 0.05 0.05
T/K 312.15 317.95 333.95 347.55 364.85
P/bar 1822 1815 1801 1784 1770


wB 0.05 0.05 0.05 0.05 0.05
T/K 309.85 315.75 329.45 345.75 358.65
P/bar 1918 1901 1881 1860 1843
Polymer (B): DL-lactide/glycolidecopolymer 2001CON

−1 −1
Characterization: Mn/kg.mol = 77.7, Mw/kg.mol = 130, 25 mol% glycolide,

wB 0.05 0.05 0.05 0.05 0.05
T/K 312.05 320.25 335.35 352.85 352.95
P/bar 2394 2373 2322 2249 2198

−1 −1

wB 0.05 0.05 0.05 0.05
T/K 314.65 328.75 343.95 359.85
P/bar 2999 2946 2877 2791
____________________________________________________________________________________


wB 0.05 0.05 0.05 0.05
T/K 316.55 333.55 353.05 369.85
P/bar 3108 3022 2922 2822
Polymer (B): DL-lactide/glycolide copolymer 2000LE1

Characterization: Mη /kg.mol−1 = 5.0, 10 wt% glycolide,
Polysciences, Inc., Warrington, PA

wB 0.0370 0.0370 0.0370 0.0370 0.0370 0.0370
T/K 331.85 343.05 352.75 362.85 372.85 383.15
P/MPa 3.73 7.70 11.06 14.05 16.95 19.67

−1
Characterization: Mη /kg.mol = 5.0, 20 wt% glycolide,

wB 0.0399 0.0399 0.0399 0.0399 0.0399 0.0399 0.0399
T/K 325.05 334.55 344.05 352.95 362.95 374.05 382.55
P/MPa 3.45 7.10 10.65 13.60 16.85 20.15 22.60

−1
Characterization: Mη /kg.mol = 10, 30 wt% glycolide,

wB 0.0314 0.0314 0.0314 0.0314 0.0314 0.0314 0.0314 0.0314
T/K 314.65 324.85 334.75 344.55 352.45 362.85 372.75 382.55
P/MPa 3.80 8.35 12.50 16.50 19.45 23.25 26.62 29.65
____________________________________________________________________________________

Resomer RG502, Boehringer Ingelheim Chemicals

wB 0.0324 0.0324 0.0324 0.0324
T/K 313.65 335.25 353.15 373.15
P/MPa 7.55 17.35 24.75 31.45


wB 0.05 0.05 0.05 0.05
T/K 309.35 315.85 324.95 337.95
P/bar 14.5 25.8 63.8 118.9

−1 −1
Characterization: Mn/kg.mol = 50.8, Mw/kg.mol = 69.6, 50 mol% glycolide,

wB 0.05 0.05 0.05
T/K 311.75 325.65 340.05
P/bar 105.1 174.1 241.0
Polymer (B): DL-lactide/glycolide copolymer 2001KUK

−1

wB 0.0314 0.0314 0.0314 0.0314 0.0314 0.0314 0.0314 0.0314
T/K 303.65 314.35 323.55 333.15 343.25 352.75 363.05 373.25
P/MPa 8.55 11.37 13.50 15.62 17.65 19.50 21.44 23.29
____________________________________________________________________________________


wB 0.0293 0.0293 0.0293 0.0293 0.0293 0.0293 0.0293 0.0293
T/K 303.35 312.85 323.75 333.75 343.15 353.45 363.45 373.05
P/MPa 21.65 23.55 25.10 26.50 28.00 29.75 31.25 32.65

Characterization: Mη /kg.mol−1 = 10, 30 wt% glycolide,

wB 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275 0.0275
T/K 305.15 314.15 323.75 333.65 343.25 353.25 362.95 373.45
P/MPa 49.05 48.45 47.95 47.35 46.65 46.05 45.15 44.25
Polymer (B): DL-lactide/glycolide

copolymer 2001KUK
−1
Resomer RG502, Boehringer Ingelheim Chemicals

wB 0.0309 0.0309 0.0309 0.0309 0.0309 0.0309
T/K 324.85 333.85 343.35 353.05 363.35 373.35
P/MPa 61.35 58.85 56.65 55.25 53.75 52.35

−1 −1
Solvent (A): trifluoromethane CHF3 75-46-7

wB 0.05 0.05 0.05 0.05 0.05
T/K 301.75 310.55 310.65 339.45 354.25
P/bar 1341 1360 1394 1436 1474
____________________________________________________________________________________
Polymer (B): polybutadiene, hydrogenated 2003TRU

Characterization: Mn/kg.mol−1 = 48 (osmometry) or 43 (GPC),
Mw/kg.mol−1 = 52 (light scattering) or 49 (GPC),
Mw/kg.mol−1 = 54 (GPC), BD(CH3/100 C) = 2.05,
PBD 50000, DSM, Geleen, The Netherlands

wB 0.0050 0.0050 0.0050 0.0050 0.0050 0.0050 0.0050 0.0050 0.0050
T/K 399.45 403.35 407.65 412.15 416.95 421.55 427.35 432.15 437.45
P/MPa 160.2 157.7 155.0 152.4 149.7 147.2 144.4 142.1 139.8
wB 0.0075 0.0075 0.0075 0.0075 0.0075 0.0075 0.0075 0.0075 0.0100
T/K 401.45 406.45 411.95 417.75 423.35 428.25 434.35 439.35 400.05
P/MPa 161.7 158.3 154.9 151.6 148.6 146.1 143.2 141.1 164.5
wB 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0125
T/K 403.95 408.65 412.85 417.65 423.65 428.55 433.75 438.45 401.05
P/MPa 161.8 158.6 155.9 153.1 150.0 147.4 144.9 142.9 165.1
wB 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0150 0.0150
T/K 406.95 411.45 417.25 422.95 428.45 433.85 438.85 400.35 403.75
P/MPa 161.0 158.2 154.6 151.5 148.6 146.1 143.7 166.7 164.2
wB 0.0150 0.0150 0.0150 0.0150 0.0150 0.0150 0.0150 0.0199 0.0199
T/K 408.25 413.25 417.85 423.15 427.95 432.95 438.65 399.95 403.55
P/MPa 161.1 157.8 155.1 152.3 149.7 147.2 144.8 168.5 165.9
wB 0.0199 0.0199 0.0199 0.0199 0.0199 0.0199 0.0199 0.0249 0.0249
T/K 408.35 413.65 419.25 424.15 428.35 433.35 437.25 399.95 403.45
P/MPa 162.6 159.2 156.0 153.2 151.1 148.6 146.9 169.5 166.8
wB 0.0249 0.0249 0.0249 0.0249 0.0249 0.0249 0.0249 0.0301 0.0301
T/K 408.15 413.15 418.65 423.75 428.95 433.45 437.85 398.95 403.95
P/MPa 163.5 160.3 157.0 154.2 151.4 149.2 147.2 170.7 167.0
wB 0.0301 0.0301 0.0301 0.0301 0.0301 0.0301 0.0350 0.0350 0.0350
T/K 408.55 413.95 419.05 423.75 430.25 435.65 400.05 404.15 408.45
P/MPa 163.8 160.4 157.3 154.6 151.2 148.5 170.6 167.5 164.5
wB 0.0350 0.0350 0.0350 0.0350 0.0350 0.0350 0.0402 0.0402 0.0402
T/K 413.25 418.15 423.45 429.05 434.05 437.65 399.15 403.15 407.15
P/MPa 161.4 158.3 155.3 152.3 150.0 148.1 171.8 168.6 165.8
wB 0.0402 0.0402 0.0402 0.0402 0.0402 0.0402 0.0450 0.0450 0.0450
T/K 412.95 418.95 424.25 429.55 434.75 439.15 401.45 403.25 408.15
P/MPa 162.1 158.3 155.3 152.5 150.0 148.0 170.0 168.6 165.2
wB 0.0450 0.0450 0.0450 0.0450 0.0450 0.0450 0.0500 0.0500 0.0500
T/K 413.65 418.55 423.95 428.55 434.05 438.25 398.95 401.85 406.85
P/MPa 161.7 158.6 155.5 153.1 150.4 148.3 172.2 169.6 166.3
wB 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0549 0.0549 0.0549
T/K 411.65 417.15 422.45 427.85 432.55 438.25 399.65 403.25 407.25
P/MPa 162.9 159.7 156.6 153.6 151.3 148.5 171.7 169.0 166.1
continued
____________________________________________________________________________________
continued
wB 0.0549 0.0549 0.0549 0.0549 0.0549 0.0549 0.0600 0.0600 0.0600
T/K 412.55 417.65 422.75 427.35 432.55 437.35 398.85 402.25 407.85
P/MPa 162.6 159.4 156.5 153.9 151.3 149.0 172.5 169.7 165.8
wB 0.0600 0.0600 0.0600 0.0600 0.0600 0.0600 0.0646 0.0646 0.0646
T/K 412.25 416.75 422.85 427.45 432.35 437.95 400.55 403.95 408.25
P/MPa 162.8 160.1 156.4 153.9 151.5 148.8 171.1 168.5 165.6
wB 0.0646 0.0646 0.0646 0.0646 0.0646 0.0646 0.0701 0.0701 0.0701
T/K 413.25 417.85 422.15 427.45 431.55 437.45 400.55 405.15 408.45
P/MPa 162.4 159.5 157.1 154.1 152.2 149.2 171.2 167.8 165.4
wB 0.0701 0.0701 0.0701 0.0701 0.0701 0.0701 0.0751 0.0751 0.0751
T/K 416.05 419.65 425.15 429.65 432.75 438.15 399.95 402.65 408.05
P/MPa 160.6 158.3 155.4 153.0 151.5 148.8 171.5 169.4 165.6
wB 0.0751 0.0751 0.0751 0.0751 0.0751 0.0751 0.0795 0.0795 0.0795
T/K 412.15 417.15 422.45 427.15 432.55 437.45 399.35 403.75 407.45
P/MPa 162.8 159.8 156.7 154.1 151.4 149.1 172.0 168.7 166.0
wB 0.0795 0.0795 0.0795 0.0795 0.0795 0.0795 0.0795 0.0852 0.0852
T/K 411.85 416.15 420.45 426.95 430.95 434.85 438.35 400.25 402.95
P/MPa 163.0 160.3 157.7 154.2 152.2 150.3 148.6 170.9 168.8
wB 0.0852 0.0852 0.0852 0.0852 0.0852 0.0852 0.0852 0.0897 0.0897
T/K 408.05 412.15 418.15 421.95 426.75 432.35 438.25 400.65 404.35
P/MPa 165.2 162.6 158.8 156.6 153.9 151.1 148.3 170.4 167.8
wB 0.0897 0.0897 0.0897 0.0897 0.0897 0.0995 0.0995 0.0995 0.0995
T/K 410.65 416.85 423.25 429.25 435.65 401.05 406.25 412.45 417.75
P/MPa 163.3 159.5 155.9 152.6 149.5 169.9 166.2 162.1 158.9
wB 0.0995 0.0995 0.1098 0.1098 0.1098 0.1098 0.1098 0.1098 0.1197
T/K 427.75 432.75 400.65 407.35 415.35 423.65 431.15 436.95 400.65
P/MPa 153.3 150.8 170.2 165.2 160.1 155.3 151.4 148.5 169.4
wB 0.1197 0.1197 0.1197 0.1197 0.1197 0.1197 0.1197 0.1303 0.1303
T/K 405.05 410.45 416.65 422.45 427.65 434.15 439.05 400.35 405.95
P/MPa 166.2 162.6 158.8 155.5 152.7 149.5 147.2 169.2 165.2
wB 0.1303 0.1303 0.1303 0.1303 0.1303 0.1303 0.1396 0.1396 0.1396
T/K 411.25 417.05 422.65 427.55 433.25 438.75 400.05 405.95 411.35
P/MPa 161.8 158.1 155.0 152.4 149.6 147.2 168.8 164.8 161.3
wB 0.1396 0.1396 0.1396 0.1396 0.1492 0.1492 0.1492 0.1492 0.1492
T/K 417.65 423.35 428.35 435.85 401.05 405.95 410.55 416.85 422.65
P/MPa 157.5 154.4 151.8 148.2 167.9 164.5 161.5 157.6 154.4
wB 0.1492 0.1492 0.1492 0.1589 0.1589 0.1589 0.1589 0.1589 0.1589
T/K 427.45 432.55 438.65 400.95 406.35 411.75 416.65 422.75 428.85
P/MPa 152.0 149.6 146.7 167.5 163.7 160.2 157.4 154.0 150.9
wB 0.1589 0.1589 0.1697 0.1697 0.1697 0.1697 0.1697 0.1697 0.1697
T/K 433.75 438.75 400.45 405.15 408.85 416.05 421.55 426.85 431.85
P/MPa 148.6 146.4 167.1 163.5 161.3 157.0 153.9 151.2 148.7
wB 0.1697 0.1805 0.1805 0.1805 0.1805 0.1805 0.1805 0.1805 0.1805
T/K 437.55 400.55 405.55 410.65 416.35 421.55 426.75 432.35 437.35
P/MPa 146.2 165.9 162.4 159.2 155.8 153.0 150.4 147.7 145.5
____________________________________________________________________________________
Polymer (B): poly(1-butene) 1999KOA

Characterization: Mn/kg.mol−1 = 270, Mw/kg.mol−1 = 1280

wB 0.0031 0.0031 0.0031 0.0031 0.0031 0.0031 0.0031 0.0031 0.0031
T/K 406.13 406.17 410.97 416.12 420.84 426.09 431.54 436.27 440.16
P/bar 101.6 101.8 110.0 118.6 126.7 135.2 144.0 151.4 156.9
wB 0.0031 0.0054 0.0054 0.0054 0.0054 0.0054 0.0054 0.0054 0.0054
T/K 445.86 406.60 411.50 416.51 421.41 426.28 431.11 436.01 440.91
P/bar 164.5 103.6 113.0 120.3 128.4 136.2 143.9 151.4 158.3
wB 0.0054 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067 0.0067
T/K 445.84 405.84 410.63 415.81 420.38 425.37 430.81 435.67 439.42
P/bar 165.4 102.0 110.8 118.8 127.1 135.2 143.3 151.4 154.7
wB 0.0067 0.0067 0.0108 0.0108 0.0108 0.0108 0.0108 0.0108 0.0108
T/K 445.33 445.22 406.22 410.98 415.89 420.99 425.76 430.71 435.54
P/bar 165.4 165.1 103.1 111.9 120.2 128.1 136.0 143.1 150.7
wB 0.0108 0.0108 0.0140 0.0140 0.0140 0.0140 0.0140 0.0140 0.0140
T/K 440.76 445.64 405.82 410.94 416.23 421.34 426.30 431.17 436.07
P/bar 158.4 165.4 103.0 111.9 120.5 128.7 136.9 144.6 151.9
wB 0.0140 0.0140 0.0236 0.0236 0.0236 0.0236 0.0236 0.0236 0.0236
T/K 440.90 445.84 406.46 411.48 416.40 421.29 426.16 431.08 436.12
P/bar 159.0 166.1 103.0 111.6 119.8 128.3 136.2 144.1 151.4
wB 0.0236 0.0236 0.0236 0.0337 0.0337 0.0337 0.0337 0.0337 0.0337
T/K 436.14 441.11 446.22 406.53 411.52 416.45 421.28 426.12 430.97
P/bar 151.7 159.1 166.4 102.2 110.8 119.2 127.6 135.2 143.0
wB 0.0337 0.0337 0.0337 0.0434 0.0434 0.0434 0.0434 0.0434 0.0434
T/K 435.95 440.77 445.19 406.39 411.35 416.35 421.26 426.21 431.04
P/bar 150.9 158.1 164.7 101.6 110.6 118.7 126.9 135.0 142.6
wB 0.0434 0.0434 0.0434 0.0549 0.0549 0.0549 0.0549 0.0549 0.0549
T/K 436.02 440.80 445.71 406.56 411.35 416.42 421.30 426.30 431.22
P/bar 150.1 157.7 164.3 100.6 108.9 117.9 126.3 134.2 142.0
wB 0.0549 0.0549 0.0549 0.0628 0.0628 0.0628 0.0628 0.0628 0.0628
T/K 436.39 441.37 446.44 406.63 410.69 411.51 420.59 421.30 426.16
P/bar 149.8 157.3 164.1 101.1 107.9 109.5 124.9 126.4 133.8
wB 0.0628 0.0628 0.0628 0.0628 0.0628 0.0690 0.0690 0.0690 0.0690
T/K 430.36 430.99 436.29 441.24 446.88 411.48 416.46 421.34 426.20
P/bar 140.5 141.1 149.7 156.8 165.1 108.8 116.9 125.4 133.1
wB 0.0690 0.0690 0.0690 0.0690 0.0690 0.0770 0.0770 0.0770 0.0770
T/K 431.24 431.22 435.91 441.20 446.28 406.84 411.71 416.75 421.57
P/bar 141.1 140.8 148.4 156.1 163.6 100.1 108.9 117.1 125.4
wB 0.0770 0.0770 0.0770 0.0770 0.0828 0.0828 0.0828 0.0828 0.0828
T/K 426.70 431.72 435.57 445.58 406.61 416.41 417.35 412.43 421.32
P/bar 134.3 141.6 147.8 161.2 98.2 116.5 118.1 109.6 124.5
continued
____________________________________________________________________________________
continued
wB 0.0828 0.0828 0.0828 0.0828 0.0828 0.0862 0.0862 0.0862 0.0862
T/K 426.33 431.25 436.04 440.82 445.85 407.25 412.31 416.76 421.68
P/bar 132.7 140.1 147.9 154.9 161.8 99.6 108.9 116.6 124.7
wB 0.0862 0.0862 0.0862 0.0862 0.0955 0.0955 0.0955 0.0955 0.0955
T/K 426.70 431.71 436.57 441.50 406.29 411.15 416.16 421.10 426.05
P/bar 132.5 140.6 148.0 155.3 98.7 106.8 115.1 123.9 132.0
wB 0.0955 0.0955 0.0955 0.0955 0.0960 0.0960 0.0960 0.0960 0.0960
T/K 430.98 435.98 440.63 445.47 406.47 411.27 416.14 420.94 425.74
P/bar 139.5 147.4 153.9 161.2 98.9 107.1 115.4 123.5 131.1
wB 0.0960 0.0960 0.0960 0.0960 0.1079 0.1079 0.1079 0.1079 0.1079
T/K 430.64 435.49 440.39 445.54 406.42 411.32 416.18 420.95 425.92
P/bar 138.7 146.2 153.8 160.9 98.0 105.9 114.1 122.3 130.1
wB 0.1079 0.1079 0.1079 0.1079 0.1200 0.1200 0.1200 0.1200 0.1200
T/K 430.81 435.74 440.76 445.92 406.13 411.07 416.18 421.14 425.96
P/bar 137.7 145.4 153.2 160.2 95.7 104.8 112.8 121.7 129.6
wB 0.1200 0.1200 0.1200 0.1200 0.1282 0.1282 0.1282 0.1282 0.1282
T/K 430.71 435.56 440.52 445.65 406.30 411.21 416.25 421.18 426.13
P/bar 136.7 144.2 151.9 159.2 95.7 104.8 112.8 121.0 129.1
wB 0.1282 0.1282 0.1282 0.1282 0.1360 0.1360 0.1360 0.1360 0.1360
T/K 431.05 436.04 441.22 446.36 406.38 411.32 416.49 417.17 421.44
P/bar 136.9 144.6 151.9 159.8 95.2 103.7 112.8 113.8 120.8
wB 0.1360 0.1360 0.1360 0.1360 0.1360 0.1518 0.1518 0.1518 0.1518
T/K 426.37 431.22 436.23 442.30 446.81 405.90 410.64 420.79 425.73
P/bar 128.9 136.4 144.2 153.2 159.8 93.3 101.6 118.6 126.7
wB 0.1518 0.1518 0.1518 0.1518 0.1665 0.1665 0.1665 0.1665 0.1665
T/K 430.50 435.37 440.21 445.37 405.98 410.69 415.79 420.84 425.85
P/bar 134.4 141.9 149.0 156.6 91.9 100.4 108.9 117.3 125.7
wB 0.1665 0.1665 0.1665 0.1665
T/K 430.86 435.82 440.79 445.47
P/bar 133.8 141.1 148.3 155.6
Polymer (B): poly(butyl acrylate) 1998ONE

Characterization: Mn/kg.mol−1 = 5.6, Air Products

wB 0.00113 0.00113 0.00113 0.00113 0.00113
T/K 298.15 308.15 318.15 328.15 338.15
P/MPa 21.99 24.13 27.10 29.58 31.92
Polymer (B): poly(butyl methacrylate) 2000BY1, 2000KIM

continued
____________________________________________________________________________________
continued
wB 0.05 0.05 0.05 0.05 0.05
T/K 426.35 446.85 465.85 485.85 507.45
P/bar 2021.9 1716.8 1572.3 1484.1 1419.3
ρ/(g/cm3) 1.085 1.020 0.973 0.932 0.895
Polymer (B): poly(butylene glycol) 1998ONE

Characterization: Mn/kg.mol−1 = 0.8, Air Products

wB 0.0050 T/K 298.15 P/MPa 12.27
Polymer (B): poly(butylene oxide)-b-poly(ethylene oxide) 1998ONE

diblock copolymer
Characterization: Mn/kg.mol−1 = 1.62 ( = 0.96 + 0.66), 44.4 mol% ethylene oxide,
SAM 185, hydroxyl terminated

wB 0.00005 0.00005 0.00050 0.001
T/K 296.15 308.15 296.15 308.15
P/MPa 11.86 14.00 12.55 27.58
Polymer (B): poly(butyl methacrylate) 2004BEC


T/K 373.15 393.15 413.15 433.15 453.15 473.15 488.15 508.15
P/bar 1380 1320 1215 1161 1147 1111 1077 1031
Polymer (B): poly(εε-caprolactone) 1993HA4

Tg/K = 213, Union Carbide Corp.

Comments: 50 < (T/K − 273.15) < 150.
continued
____________________________________________________________________________________
continued
wB = 0.00029 P/MPa = −20.871 + 0.43397 (T/K − 273.15) − 6.7838 10−4 (T/K − 273.15)2
wB = 0.00288 P/MPa = −19.636 + 0.42290 (T/K − 273.15) − 4.4064 10−4 (T/K − 273.15)2
wB = 0.00973 P/MPa = −18.914 + 0.43503 (T/K − 273.15) − 5.7375 10−4 (T/K − 273.15)2
wB = 0.0206 P/MPa = −20.629 + 0.47439 (T/K − 273.15) − 7.6059 10−4 (T/K − 273.15)2
wB = 0.0310 P/MPa = −20.806 + 0.47302 (T/K − 273.15) − 7.3343 10−4 (T/K − 273.15)2
wB = 0.0406 P/MPa = −20.118 + 0.46526 (T/K − 273.15) − 7.1455 10−4 (T/K − 273.15)2
wB = 0.0497 P/MPa = −20.174 + 0.46303 (T/K − 273.15) − 6.9886 10−4 (T/K − 273.15)2
wB = 0.0725 P/MPa = −20.729 + 0.46978 (T/K − 273.15) − 7.2765 10−4 (T/K − 273.15)2
wB = 0.1489 P/MPa = −23.208 + 0.49300 (T/K − 273.15) − 8.4772 10−4 (T/K − 273.15)2
wB = 0.1887 P/MPa = −22.928 + 0.44778 (T/K − 273.15) − 6.0281 10−4 (T/K − 273.15)2
Polymer (B): poly(εε-caprolactone) 1993HA4

Tg/K = 213, Union Carbide Corp.

Comments: 50 < (T/K − 273.15) < 150.
wB = 0.00031 P/MPa = −20.927 + 0.48674 (T/K − 273.15) − 7.8029 10−4 (T/K − 273.15)2
wB = 0.00308 P/MPa = −19.729 + 0.47761 (T/K − 273.15) − 7.1376 10−4 (T/K − 273.15)2
wB = 0.0100 P/MPa = −20.096 + 0.49072 (T/K − 273.15) − 7.5342 10−4 (T/K − 273.15)2
wB = 0.0307 P/MPa = −18.227 + 0.45775 (T/K − 273.15) − 6.1003 10−4 (T/K − 273.15)2
wB = 0.0505 P/MPa = −19.114 + 0.47121 (T/K − 273.15) − 6.5685 10−4 (T/K − 273.15)2
wB = 0.0724 P/MPa = −19.939 + 0.47596 (T/K − 273.15) − 6.4877 10−4 (T/K − 273.15)2
Polymer (B): poly(1,1-dihydroperfluorooctyl acrylate) 1996HAR

Characterization: Mw/kg.mol−1 = 100

wB 0.010 T/K 318.15 P/bar 177.9
Polymer (B): poly(dimethylsiloxane) 1999LIJ

Characterization: Mn/kg.mol−1 = 31.3, Mn/kg.mol−1 = 93.7,

wB 0.05 0.05 0.05 0.05 0.05 0.05 0.05
T/K 313.2 307.7 306.0 303.7 348.2 341.2 340.8
P/MPa 30.7 33.0 35.0 38.4 34.8 33.4 32.2
____________________________________________________________________________________
Polymer (B): poly(dimethylsiloxane) 1998ONE

Characterization: Mn/kg.mol−1 = 13, low polydispersity
wB 0.00227 0.00505 0.01060 0.02420 0.00227 0.07160
T/K 283.15 283.15 283.15 283.15 293.15 293.15
P/MPa 7.58 9.58 13.24 18.62 10.20 21.65
wB 0.00227 0.00505 0.01060 0.01870 0.02420 0.03830 0.07160 0.09470 0.17300
T/K 298.15 298.15 298.15 298.15 298.15 298.15 298.15 298.15 298.15
P/MPa 11.72 13.10 14.96 15.72 16.41 19.03 20.34 21.03 20.89
wB 0.00227 0.00505 0.01060 0.01870 0.02420 0.03830 0.07160 0.09470 0.17300
T/K 308.15 308.15 308.15 308.15 308.15 308.15 308.15 308.15 308.15
P/MPa 14.75 16.13 17.31 17.65 25.23 20.41 21.30 21.51 21.51
wB 0.00227 0.00505 0.01060 0.01870 0.02420 0.03830 0.07160 0.09470 0.17300
T/K 323.15 323.15 323.15 323.15 323.15 323.15 323.15 323.15 323.15
P/MPa 18.41 20.34 21.44 21.86 22.13 23.72 24.34 24.68 24.48
wB 0.00227 0.00505 0.01060 0.01870 0.02420 0.03830 0.07160 0.09470 0.17300
T/K 338.15 338.15 338.15 338.15 338.15 338.15 338.15 338.15 338.15
P/MPa 22.55 24.27 25.51 25.65 25.99 27.44 30.34 28.06 28.06
Polymer (B): poly(dimethylsiloxane) 1998ONE

Characterization: end-capped with C3H6NH2, prepared in the laboratory
wB 0.0040 0.0040 0.0040 0.0040 0.0040
T/K 298.15 308.15 318.15 328.15 338.15
P/MPa 24.13 21.51 22.75 24.61 25.68
Polymer (B): poly(dimethylsiloxane) monomethacrylate 1998ONE

Characterization: Mn/kg.mol−1 = 10, Aldrich Chem. Co., Inc., Milwaukee, WI
T/K = 298.15
wB 0.00230 0.00507 0.01050 0.01490 0.02290
P/MPa 10.76 11.31 13.17 13.86 14.41
T/K = 303.15
wB 0.00230 0.00507 0.01050 0.01490 0.02290
P/MPa 12.00 12.62 14.82 15.03 15.72
T/K = 313.15
wB 0.00230 0.00507 0.01050 0.01490 0.02290
P/MPa 15.31 16.13 17.44 17.79 18.48
continued
____________________________________________________________________________________
continued
T/K = 323.15
wB 0.00230 0.00507 0.01050 0.01490 0.02290
P/MPa 18.27 18.89 20.48 27.37 21.44
T/K = 333.15
wB 0.00230 0.00507 0.01050 0.01490 0.02290
P/MPa 20.82 21.99 23.10 23.17 23.86
Polymer (B): poly(dimethylsiloxane)-g-poly(ethylene oxide) 1998ONE

graft copolymer
Characterization: unknown composition and molar mass,
DABCO DC5357, Dow Corning

wB 0.00110 0.00110 0.00110 0.00110 0.00110
T/K 298.15 303.15 313.15 323.15 333.15
P/MPa 22.96 24.89 28.61 31.44 35.03

graft copolymer
Characterization: unknown composition and molar mass, fractionated in the laboratory
from DABCO DC5357, Dow Corning

wB 0.00110 0.00110 0.00110 0.00110 0.00110
T/K 298.15 303.15 313.15 323.15 333.15
P/MPa 7.79 9.72 12.55 15.72 18.13

graft copolymer
Characterization: unknown composition and molar mass, made in the laboratory

wB 0.00575 0.00789 0.00575 0.00789 0.01120 0.00575 0.00789 0.01120 0.00575
T/K 298.15 298.15 308.15 308.15 308.15 318.15 318.15 318.15 328.15
P/MPa 13.93 21.03 14.48 15.65 16.89 15.79 17.58 19.24 18.96
wB 0.00789 0.01120 0.00575 0.00789 0.01120
T/K 328.15 328.15 338.15 338.15 338.15
P/MPa 20.96 23.86 20.82 23.37 25.37
____________________________________________________________________________________

graft copolymer (trifluoroacetate end-capped)
Characterization: unknown composition and molar mass, made in the laboratory
wB 0.00150 0.00430 0.00575 0.00789 0.00150 0.00430 0.00575 0.00789 0.01120
T/K 298.15 298.15 298.15 298.15 303.15 303.15 308.15 308.15 308.15
P/MPa 13.51 17.03 13.93 21.03 16.20 19.72 14.48 15.65 16.89
wB 0.00150 0.00430 0.00575 0.00789 0.01120 0.00150 0.00430 0.00575 0.00789
T/K 313.15 313.15 318.15 318.15 318.15 323.15 323.15 328.15 328.15
P/MPa 19.86 24.89 15.79 17.58 19.24 23.37 29.37 18.96 20.96
wB 0.01120 0.00150 0.00430 0.00575 0.00789 0.01120
T/K 328.15 333.15 333.15 338.15 338.15 338.15
P/MPa 23.86 27.79 34.89 20.82 23.37 25.37

graft copolymer (PDMS13-g-EO10)
Characterization: Mn/kg.mol−1 = 1.7, synthesized by Unilever Research,
Edgewater, NJ
wB 0.00381 0.00381 0.00381
T/K 298.15 308.15 333.15
P/MPa 15.17 19.86 29.99

graft copolymer (PDMS20-g-EO10-g-EO10)
Characterization: Mn/kg.mol−1 = 2.8, synthesized by Unilever Research,
Edgewater, NJ
wB 0.00148 0.00148 0.00148
T/K 298.15 313.15 333.15
P/MPa 16.69 21.86 29.37
Polymer (B): poly(dimethylsiloxane)-g-poly(ethylene oxide)-g- 1998ONE

poly(propylene oxide) graft copolymer
[PDMS22-g-(PEO/PPO = 75/25)]
Characterization: Mn/kg.mol−1 = 6.0, Abil B-8851 Surfactant, Goldschmidt
continued
____________________________________________________________________________________
continued
wB 0.00119 0.00119 0.00119 0.00119
T/K 298.15 313.15 323.15 333.15
P/MPa 28.75 32.61 33.03 34.13
Polymer (B): poly(dimethylsiloxane)-g-poly(ethylene oxide)-g- 1998ONE

poly(propylene oxide) graft copolymer
[PDMS73-g-(PEO/PPO = 75/25)]
Characterization: Mn/kg.mol−1 = 13, Abil B-88184 Surfactant, Goldschmidt

wB 0.00165 0.00165 0.00165 0.00165 0.00563 0.00563
T/K 298.15 313.15 323.15 333.15 313.15 333.15
P/MPa 28.61 32.82 35.30 37.23 37.23 40.95
Polymer (B): poly(di-1H,1H,2H,2H-perfluorodecyl diitaconate) 2003LID

Characterization: Mw/kg.mol−1 = 150 (this is an estimated value only),

wB 0.0096 0.0096 0.0096 0.0096 0.0096 0.0096 0.0096 0.0096 0.0150
T/K 424.45 396.05 372.15 358.05 342.75 328.45 316.05 295.05 395.35
P/bar 398 359 321 299 260 238 218 118 364
ρ/(g/cm3) 0.635 0.676 0.710 0.736 0.770 0.816 0.859 0.870
wB 0.0150 0.0150 0.0150 0.0150 0.0150 0.0150 0.0150 0.0670 0.0670
T/K 375.55 356.15 345.75 334.85 328.45 319.25 306.15 419.45 389.65
P/bar 336 326 309 291 276 258 221 396 355
ρ/(g/cm3) 0.711 0.752
wB 0.0670 0.0670 0.0670 0.0670 0.1100 0.1100 0.1100 0.1100 0.1100
T/K 355.55 334.65 314.85 296.95 385.65 352.85 337.15 325.25 310.65
P/bar 287 237 180 126 349 281 239 209 163
ρ/(g/cm3) 0.802 0.838 0.872 0.907 0.749 0.798 0.826 0.847 0.877
Polymer (B): poly(di-1H,1H,2H,2H-perfluorododecyl diitaconate) 2003LID


wB 0.0095 0.0095 0.0095 0.0095 0.0206 0.0206 0.0206 0.0206
T/K 386.35 349.95 324.85 297.25 377.45 345.75 312.45 297.85
P/bar 293.1 225.5 161.7 81.4 282.4 221.7 130.2 88.3
____________________________________________________________________________________
Polymer (B): poly(di-1H,1H,2H,2H-perfluorohexyl diitaconate) 2003LID


T/K 409.35 381.95 358.85 342.55 333.45 324.05 318.75 306.05 294.65
P/bar 388 343 294 252 228 215 182 137 95
ρ/(g/cm3) 0.675 0.709 0.744 0.773 0.783 0.806 0.818 0.820 0.838
Polymer (B): poly(di-1H,1H,2H,2H-perfluorooctyl diitaconate) 2003LID


T/K 421.25 404.15 373.35 358.45 342.15 315.65 306.25 294.85
P/bar 402 379 327 313 256 177 146 106
ρ/(g/cm3) 0.644 0.669 0.713 0.757 0.761 0.810 0.827 0.847
Polymer (B): poly(di-1H,1H,2H,2H-perfluorodecyl monoitaconate) 2003LID


wB 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0305 0.0305
T/K 387.35 369.55 350.25 337.45 322.95 301.15 293.25 398.65 365.15
P/bar 335 318 298 275 244 183 142 351 306
ρ/(g/cm3) 0.733 0.809 0.855 0.883 0.941 0.963 1.001 0.702 0.817
wB 0.0305 0.0305 0.0305 0.0305 0.0305 0.0550 0.0550 0.0550 0.0550
T/K 346.45 337.55 323.45 306.55 296.15 374.25 349.25 343.35 325.45
P/bar 283 267 237 210 170 326 284 274 243
ρ/(g/cm3) 0.870 0.887 0.930 0.950 0.978 0.744 0.835 0.844 0.882
wB 0.0550 0.0550 0.0992 0.0992 0.0992 0.0992 0.0992 0.0992
T/K 314.95 296.15 379.75 356.75 340.85 331.55 322.55 309.95
P/bar 217 171 344 297 258 246 227 186
ρ/(g/cm3) 0.935 0.972 0.752 0.822 0.897 0.909 0.919 0.928
____________________________________________________________________________________
Polymer (B): poly(di-1H,1H,2H,2H-perfluorododecyl monoitaconate) 2003LID

T/K 402.05 369.65 359.25 348.65 342.35 326.05 319.55 300.15
P/bar 401 361 357 345 335 320 306 287
ρ/(g/cm3) 0.804 0.884 0.923 0.961 0.983 1.047 1.069 1.147
Polymer (B): poly(di-1H,1H,2H,2H-perfluorohexyl monoitaconate) 2003LID

T/K 400.95 382.45 366.15 352.45 335.75
P/bar 450 487 498 518 539
ρ/(g/cm3) 0.850 0.927 0.982 1.030 1.114
Polymer (B): poly(di-1H,1H,2H,2H-perfluorooctyl monoitaconate) 2003LID

T/K 388.55 370.55 359.65 347.55 336.05 321.75 306.05 293.45
P/bar 355 356 359 364 345 318 252 265
ρ/(g/cm3) 0.766 0.854 0.907 0.971 1.009 1.057 1.120 1.154
Polymer (B): poly(ethyl acrylate) 2004BEC

T/K 354.15 364.15 373.15 393.15 414.35 434.65 453.85 473.45 492.35
P/bar 1613 1541 1485 1376 1288 1217 1162 1117 1077
T/K 513.55 533.15
P/bar 1038 1010
____________________________________________________________________________________


T/K = 493.15
Total feed concentrations of the homogeneous system before demixing: wA = 0.75 and wB = 0.25.
____________________________________________________________________________________
P/ wA
MPa liquid phase gas phase
____________________________________________________________________________________
9.030 0.2985
9.180 0.9936
9.220 0.3299
9.313 0.3234
9.317 0.9893
9.410 0.9866
9.601 0.9834
9.838 0.3441
10.027 0.9875
12.062 0.9819
12.250 0.4023
12.440 0.4093 0.9730
12.720 0.4161 0.9730
12.960 0.9663
13.010 0.4246
13.860 0.9651
14.620 0.4739
14.711 0.9528
15.280 0.9365
15.520 0.4942
15.685 0.9396
15.940 0.9310
16.317 0.5054
16.685 0.5196
17.074 0.9146
18.305 0.8966
18.876 0.5837
18.929 0.6014
19.717 0.8440
20.400 0.7361
22.263 0.7497
23.400 0.7369
____________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): polyethylene 1993HA3

Characterization: Mn/kg.mol−1 = 37, Mw/kg.mol−1 = 49, 36% crystallinity, Tm/K = 371

T/K 371.15 385.15 394.45 402.85 424.75
P/bar 1070.0 1060.0 1054.9 1034.2 996.3

−1 −1
Characterization: Mn/kg.mol = 37, Mw/kg.mol = 46, 57% crystallinity, Tm/K = 396

T/K 388.95 389.45 398.45 408.25 424.55
P/bar 1187.0 1185.9 1158.3 1134.2 1096.2


T/K 382.05 388.45 393.75 403.65 413.15 423.35
P/bar 1148.0 1137.6 1123.8 1099.7 1079.0 1061.8

−1 −1

T/K 380.95 386.95 398.55 410.05 424.15
P/bar 1138.0 1130.7 1099.7 1072.1 1044.5


continued
____________________________________________________________________________________
continued
T/K 389.15 391.55 393.15 402.65 403.35 412.85 413.05 423.75 425.75
P/bar 1281.0 1280.7 1273.8 1246.2 1239.3 1206.6 1199.7 1158.3 1170.4


T/K 390.15 392.15 393.85 403.65 413.05 425.05
P/bar 1244.0 1242.8 1235.9 1206.6 1179.0 1144.5
Polymer (B): polyethylene 1996HEU

−1 −1 −1
Exxon Polywax 655

T/K = 413.15
xB 0.0504 0.0434 0.0380 0.0309 0.0283 0.0265 0.0245 0.0230 0.0205
P/MPa 42.8 43.8 44.4 45.2 45.4 45.5 45.9 46.2 46.6
xB 0.0160 0.0096 0.0070
P/MPa 46.8 45.8 45.1
critical concentration: xB, crit = 0.0265, critical pressure: Pcrit/MPa = 45.5
T/K = 433.15
xB 0.0504 0.0434 0.0380 0.0309 0.0283 0.0265 0.0245 0.0230 0.0205
P/MPa 43.0 44.0 44.6 45.4 45.6 45.8 46.2 46.5 46.9
xB 0.0160 0.0096 0.0070
P/MPa 47.0 46.1 45.4
T/K = 453.15
xB 0.0504 0.0434 0.0380 0.0309 0.0283 0.0265 0.0245 0.0230 0.0205
P/MPa 43.1 44.1 44.8 45.6 45.8 46.0 46.4 46.8 47.2
xB 0.0160 0.0096 0.0070
P/MPa 47.3 46.4 45.6
T/K = 473.15
continued
____________________________________________________________________________________
continued
xB 0.0504 0.0434 0.0380 0.0309 0.0283 0.0265 0.0245 0.0230 0.0205
P/MPa 43.3 44.3 45.0 45.8 46.0 46.2 46.6 47.0 47.4
xB 0.0160 0.0096 0.0070
P/MPa 47.6 46.7 45.9
T/K = 493.15
xB 0.0504 0.0434 0.0380 0.0309 0.0283 0.0265 0.0245 0.0230 0.0205
P/MPa 43.5 44.5 45.2 46.0 46.2 46.4 46.9 47.3 47.7
xB 0.0160 0.0096 0.0070
P/MPa 47.8 46.9 46.2
T/K = 513.15
xB 0.0504 0.0434 0.0380 0.0309 0.0283 0.0265 0.0245 0.0230 0.0205
P/MPa 43.6 44.8 45.4 46.2 46.4 46.6 47.1 47.6 48.0
xB 0.0160 0.0096 0.0070
P/MPa 48.1 47.3 46.5

Exxon Polywax 1000

T/K = 413.15
xB 0.0320 0.0290 0.0270 0.0250 0.0230 0.0210 0.0180 0.0150 0.0132
P/MPa 54.1 55.4 56.1 56.8 57.4 58.1 58.8 59.4 59.7
xB 0.0120 0.0110 0.0100 0.0080 0.0050 0.0030
P/MPa 59.8 60.3 60.8 61.5 61.2 59.2
T/K = 433.15
xB 0.0320 0.0290 0.0270 0.0250 0.0230 0.0210 0.0180 0.0150 0.0132
P/MPa 53.9 55.1 55.8 56.4 57.0 57.6 58.3 58.8 59.1
xB 0.0120 0.0110 0.0100 0.0080 0.0050 0.0030
P/MPa 59.2 59.5 59.9 60.4 60.1 58.1
T/K = 453.15
continued
____________________________________________________________________________________
continued
xB 0.0320 0.0290 0.0270 0.0250 0.0230 0.0210 0.0180 0.0150 0.0132
P/MPa 53.7 54.8 55.5 56.0 56.7 57.3 57.8 58.2 58.5
xB 0.0120 0.0110 0.0100 0.0080 0.0050 0.0030
P/MPa 58.6 59.0 59.4 59.7 59.2 57.4
T/K = 473.15
xB 0.0320 0.0290 0.0270 0.0250 0.0230 0.0210 0.0180 0.0150 0.0132
P/MPa 53.5 54.6 55.2 55.7 56.2 56.7 57.3 57.7 57.9
xB 0.0120 0.0110 0.0100 0.0080 0.0050 0.0030
P/MPa 58.0 58.3 58.7 59.1 58.5 56.4
T/K = 493.15
xB 0.0320 0.0290 0.0270 0.0250 0.0230 0.0210 0.0180 0.0150 0.0132
P/MPa 53.2 54.2 54.7 55.2 55.6 56.0 56.5 56.9 57.1
xB 0.0120 0.0110 0.0100 0.0080 0.0050 0.0030
P/MPa 57.2 57.7 58.1 58.5 57.6 55.4
T/K = 513.15
xB 0.0320 0.0290 0.0270 0.0250 0.0230 0.0210 0.0180 0.0150 0.0132
P/MPa 52.9 53.7 54.2 54.6 55.0 55.4 55.8 56.2 56.3
xB 0.0120 0.0110 0.0100 0.0080 0.0050 0.0030
P/MPa 56.4 57.0 57.5 58.0 57.0 54.7

−1 −1 −1
Exxon Polywax H101

T/K = 413.15
xB 0.0197 0.0165 0.0134 0.0125 0.0118 0.0111 0.0105 0.0099 0.0093
P/MPa 56.7 60.6 63.0 63.6 63.8 64.0 64.7 65.4 66.0
xB 0.0080 0.0060 0.0049 0.0036 0.0030 0.0024
P/MPa 67.6 69.8 70.6 70.8 70.3 69.7
T/K = 433.15
continued
____________________________________________________________________________________
continued
xB 0.0197 0.0165 0.0134 0.0125 0.0118 0.0111 0.0105 0.0099 0.0093
P/MPa 56.3 60.1 62.3 62.8 63.1 63.2 63.9 64.4 65.0
xB 0.0080 0.0060 0.0049 0.0036 0.0030 0.0024
P/MPa 66.5 68.6 69.5 69.5 69.0 68.3
T/K = 453.15
xB 0.0197 0.0165 0.0134 0.0125 0.0118 0.0111 0.0105 0.0099 0.0093
P/MPa 55.9 59.5 61.7 62.1 62.3 62.4 62.9 63.5 64.1
xB 0.0080 0.0060 0.0049 0.0036 0.0030 0.0024
P/MPa 65.6 67.4 68.2 68.4 67.8 67.1
T/K = 473.15
xB 0.0197 0.0165 0.0134 0.0125 0.0118 0.0111 0.0105 0.0099 0.0093
P/MPa 55.6 59.1 60.9 61.3 61.4 61.5 62.1 62.7 63.3
xB 0.0080 0.0060 0.0049 0.0036 0.0030 0.0024
P/MPa 64.6 66.3 66.9 67.1 66.6 65.7
T/K = 493.15
xB 0.0197 0.0165 0.0134 0.0125 0.0118 0.0111 0.0105 0.0099 0.0093
P/MPa 55.2 58.6 60.3 60.6 60.7 60.8 61.3 61.9 62.5
xB 0.0080 0.0060 0.0049 0.0036 0.0030 0.0024
P/MPa 63.7 65.3 65.8 65.8 65.1 64.1
T/K = 513.15
xB 0.0197 0.0165 0.0134 0.0125 0.0118 0.0111 0.0105 0.0099 0.0093
P/MPa 54.8 57.9 59.4 59.6 59.7 59.9 60.3 60.9 61.4
xB 0.0080 0.0060 0.0049 0.0036 0.0030 0.0024
P/MPa 62.7 64.3 64.7 64.4 63.8 62.8
Polymer (B): polyethylene 1981SP2, 1983SPA, 1986SPA

LDPE-wax, ρ = 0.865 g/cm3 at 295 K

wB 0.132 0.295 0.140 0.270 0.250 0.139 0.646
T/K 383.15 383.15 433.15 433.15 473.15 473.15 473.15
P/bar 57.5 60.9 59.2 61.1 65.4 64.0 50.9
continued
____________________________________________________________________________________
continued
T/K = 383.15
_____________________________________________________________________________________________
Demixing wB Fractionation during demixing
pressure gel phase sol phase gel phase sol phase
_____________________________________________________________________________________________
P/ Mn/ M w/ Mn/ M w/
MPa kg/mol kg/mol kg/mol kg/mol
_____________________________________________________________________________________________
57.5 0.140 1.13 4.04
56.9 0.120 1.06 1.59
53.9 0.604 1.41 5.84
53.0 0.077 0.88 1.13
43.2 0.032 0.85 1.06
42.2 0.700 1.22 4.77
_____________________________________________________________________________________________
T/K = 433.15
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
59.2 0.140 1.13 4.04
54.9 0.605 1.58 7.11
54.3 0.102 0.94 1.32
46.6 0.056 0.91 1.21
43.7 0.701 1.31 5.52
_____________________________________________________________________________________________
T/K = 473.15
_____________________________________________________________________________________________
_____________________________________________________________________________________________
_____________________________________________________________________________________________
64.0 0.139 1.13 4.04
62.3 0.124 1.06 1.83
________________________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
_____________________________________________________________________________________________
_____________________________________________________________________________________________
61.3 0.624 1.96 9.63
60.6 0.112 1.00 1.55
59.7 0.642 1.92 9.08
54.3 0.072 0.95 1.33
51.4 0.692 1.61 7.32
49.4 0.700 1.49 6.54
38.4 0.768 1.28 5.54
____________________________________________________________________________________
T/K = 473.15
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
50.9 0.646 1.13 4.04
49.8 0.654 1.22 6.23
47.4 0.073 0.89 1.17
44.8 0.701 1.29 6.49
38.6 0.028 0.79 1.02
37.7 0.767 1.26 5.54
23.3 0.847 1.18 4.48
____________________________________________________________________________________
Polymer (B): polyethylene 1981SP1

LDPE-wax, ρ = 0.865 g/cm3 at 295 K
T/K = 383.15
wB 0.132 0.247 0.316 0.370 0.435 0.610 0.641
P/MPa 57.5 60.4 60.7 58.5 57.4 48.6 46.0
critical concentration: wB, crit = 0.370, critical pressure: Pcrit/MPa = 58.5
T/K = 433.15
wB 0.114 0.140 0.186 0.280 0.365 0.381 0.425 0.484 0.515
P/MPa 58.3 59.2 60.3 61.0 59.7 58.6 58.1 56.9 55.7
continued
____________________________________________________________________________________
continued
wB 0.548 0.589 0.719 0.819 0.855
P/MPa 54.4 52.1 40.5 26.0 19.8
T/K = 473.15
wB 0.139 0.268 0.392 0.430 0.455 0.646
P/MPa 64.0 65.4 63.2 61.0 59.1 50.9

T/K = 383.15
______________________________________________________
P/ wB
MPa gel phase sol phase
______________________________________________________
57.5 0.555 0.132 (cloud and shadow points)
56.9 0.120
55.4 0.584
53.9 0.604
53.0 0.077
52.1 0.066
43.2 0.032
42.2 0.700
31.0 0.003
______________________________________________________
T/K = 383.15
______________________________________________________
P/ wB
______________________________________________________
57.5 0.515
55.8 0.550
54.8 0.124
49.5 0.073
47.9 0.635
46.7 0.056
36.6 0.722
35.8 0.020
23.0 0.812
______________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 383.15
______________________________________________________
P/ wB
______________________________________________________
58.7 0.229
57.5 0.493
56.7 0.173
56.0 0.526
48.7 0.622
47.6 0.058
46.2 0.059
35.4 0.016
34.6 0.735
33.7 0.021
20.6 0.813
______________________________________________________
T/K = 383.15
______________________________________________________
P/ wB
______________________________________________________
58.5 0.370 0.370 (cloud and shadow points at the critical concentration)
58.3 0.396
57.8 0.306
56.7 0.228
56.0 0.470
28.4 0.008
27.7 0.780
25.3 0.793
23.1 0.803
20.6 0.827
20.6 0.815
12.7 0.875
______________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 383.15
______________________________________________________
P/ wB
______________________________________________________
56.3 0.454
54.7 0.176
53.8 0.517
51.3 0.575
48.4 0.091
44.6 0.652
43.7 0.061
39.0 0.699
36.7 0.033
27.3 0.781
26.5 0.003
22.7 0.810
21.6 0.813
______________________________________________________
T/K = 383.15
______________________________________________________
P/ wB
______________________________________________________
45.2 0.648
44.1 0.656
43.4 0.064
36.6 0.722
33.6 0.745
33.0 0.013
25.1 0.001
24.0 0.000
23.6 0.795
22.7 0.800
22.0 0.000
15.0 0.854
14.5 0.000
14.2 0.852
10.4 0.883
7.5 0.918
4.4 0.950
______________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
53.6 0.064
52.3 0.061
50.3 0.049
46.6 0.038
39.0 0.730
______________________________________________________
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
57.4 0.106
56.1 0.098
55.3 0.635
52.7 0.643
51.5 0.065
50.5 0.667
48.8 0.060
46.0 0.041
44.2 0.695
38.5 0.024
37.8 0.761
26.4 0.005
17.2 0.000
______________________________________________________
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
57.8 0.129
55.8 0.117
______________________________________________________
continued
____________________________________________________________________________________
continued
__________________________________________________________________
P/ wB
__________________________________________________________________
54.9 0.605
54.3 0.102
53.3 0.619
46.6 0.056
43.7 0.701
43.3 0.039
______________________________________________________
T/K = 433.15
__________________________________________________________________
P/ wB
__________________________________________________________________
58.4 0.165
57.6 0.563
56.1 0.136
55.1 0.593
53.9 0.114
52.7 0.619
46.2 0.061
45.2 0.686
38.4 0.734
37.4 0.028
__________________________________________________________________
T/K = 433.15
__________________________________________________________________
P/ wB
__________________________________________________________________
56.5 0.541
56.2 0.177
55.4 0.563
54.4 0.150
53.0 0.605
51.4 0.105
49.5 0.643
44.3 0.696
40.6 0.041
__________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
57.8 0.468
56.2 0.512
55.8 0.204
54.7 0.558
51.9 0.611
50.0 0.105
48.6 0.646
46.7 0.075
45.7 0.682
______________________________________________________
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
58.6 0.381 0.381 (cloud and shadow points at the critical concentration)
57.3 0.265
55.9 0.513
55.2 0.187
54.4 0.543
______________________________________________________
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
56.4 0.221
55.6 0.517
55.3 0.195
54.2 0.196
52.8 0.574
______________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
55.0 0.535
53.1 0.582
51.1 0.129
49.6 0.622
47.7 0.083
34.6 0.018
34.1 0.772
______________________________________________________
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
55.3 0.521
53.0 0.149
52.0 0.135
______________________________________________________
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
53.9 0.558
52.7 0.132
51.2 0.118
49.4 0.636
47.9 0.090
______________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
51.4 0.604
48.6 0.093
47.0 0.657
45.4 0.065
43.4 0.696
41.8 0.043
______________________________________________________
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
39.9 0.728
38.9 0.026
37.6 0.739
______________________________________________________
T/K = 433.15
______________________________________________________
P/ wB
______________________________________________________
25.3 0.822
24.7 0.000
22.8 0.843
21.7 0.844
______________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
__________________________________________________________________
P/ wB
__________________________________________________________________
19.5 0.000
17.9 0.869
14.1 0.893
10.5 0.920
__________________________________________________________________
T/K = 473.15
__________________________________________________________________
P/ wB
__________________________________________________________________
62.3 0.124
61.3 0.624
60.6 0.112
59.7 0.642
53.7 0.072
52.2 0.061
51.4 0.692
39.3 0.019
38.4 0.768
__________________________________________________________________
T/K = 473.15
__________________________________________________________________
P/ wB
__________________________________________________________________
64.0 0.249
61.8 0.217
60.1 0.582
59.5 0.203
58.6 0.590
55.8 0.142
55.2 0.625
50.8 0.085
49.6 0.671
__________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 473.15
__________________________________________________________________
P/ wB
__________________________________________________________________

62.1 0.368
60.3 0.305
59.1 0.565
58.2 0.582
52.4 0.099
51.6 0.652
50.0 0.671
48.9 0.065
40.2 0.029
39.4 0.757
30.0 0.008
28.9 0.815
__________________________________________________________________
T/K = 473.15
__________________________________________________________________
P/ wB
__________________________________________________________________

60.7 0.471
59.9 0.376
58.1 0.276
56.4 0.580
__________________________________________________________________
T/K = 473.15
__________________________________________________________________
P/ wB
__________________________________________________________________

58.1 0.315
57.6 0.545
56.7 0.213
55.8 0.587
__________________________________________________________________
continued
____________________________________________________________________________________
continued
__________________________________________________________________
P/ wB
__________________________________________________________________
55.0 0.176
53.9 0.609
52.5 0.128
43.6 0.711
42.2 0.033
28.2 0.006
25.8 0.005
23.9 0.001
17.2 0.885
12.3 0.919
______________________________________________________
T/K = 473.15
______________________________________________________
P/ wB
______________________________________________________
49.8 0.654
48.6 0.077
47.4 0.073
44.8 0.701
38.6 0.028
37.7 0.767
37.2 0.767
36.3 0.026
24.8 0.005
23.9 0.002
23.3 0.847
23.0 0.860
15.3 0.885
15.2 0.889
6.6 0.956
______________________________________________________
Polymer (B): polyethylene 1980RAE


continued
____________________________________________________________________________________
continued
wB 0.05 0.05 0.10 0.10 0.10 0.10 0.10 0.10 0.10
T/K 403.15 433.15 403.15 413.15 433.15 453.15 473.15 493.15 513.15
P/MPa 102.5 98.1 116.2 113.3 108.4 104.4 100.0 96.6 94.6
wB 0.20 0.20 0.30 0.30
T/K 403.15 433.15 403.15 433.15
P/MPa 114.3 106.9 102.0 96.6
Polymer (B): polyethylene 1991NIE

Characterization: Mn/kg.mol−1 = 2.41, Mw/kg.mol−1 = 4.88, HDPE,
Exxon Polymer Plant, Antwerp, fractionated in the laboratory

wB 0.072 0.072 0.115 0.115 0.195 0.195 0.195 0.271 0.271
T/K 403.65 443.15 423.15 463.65 407.65 418.15 453.15 413.15 443.15
P/MPa 107.8 100.2 103.0 97.1 104.8 102.6 97.5 98.0 93.2
wB 0.271 0.360 0.360 0.360
T/K 462.15 406.15 433.15 462.15
P/MPa 91.3 91.2 87.0 84.2

−1 −1 −1
Exxon Polywax 2000

T/K = 413.15
xB 0.0118 0.0102 0.0089 0.0068 0.0056 0.0045 0.0040 0.0036 0.0030
P/MPa 72.7 75.3 77.9 82.3 84.7 86.1 86.6 86.8 87.0
xB 0.0027 0.0023 0.0019 0.0017 0.0012 0.0008
P/MPa 87.5 87.9 88.2 88.0 87.1 85.4
T/K = 433.15
xB 0.0118 0.0102 0.0089 0.0068 0.0056 0.0045 0.0040 0.0036 0.0030
P/MPa 71.5 73.9 76.2 80.0 82.0 83.2 83.6 83.8 84.0
xB 0.0027 0.0023 0.0019 0.0017 0.0012 0.0008
P/MPa 84.4 84.8 85.0 84.9 84.1 82.6
continued
____________________________________________________________________________________
continued
T/K = 453.15
xB 0.0118 0.0102 0.0089 0.0068 0.0056 0.0045 0.0040 0.0036 0.0030
P/MPa 70.5 72.6 74.8 78.4 80.1 81.1 81.4 81.5 81.6
xB 0.0027 0.0023 0.0019 0.0017 0.0012 0.0008
P/MPa 81.9 82.3 82.5 82.4 81.5 79.8
T/K = 473.15
xB 0.0118 0.0102 0.0089 0.0068 0.0056 0.0045 0.0040 0.0036 0.0030
P/MPa 69.6 71.4 73.4 76.5 78.1 79.0 79.3 79.4 79.6
xB 0.0027 0.0023 0.0019 0.0017 0.0012 0.0008
P/MPa 80.1 80.5 80.7 80.5 79.4 77.9
T/K = 493.15
xB 0.0118 0.0102 0.0089 0.0068 0.0056 0.0045 0.0040 0.0036 0.0030
P/MPa 68.5 70.3 72.0 74.9 76.3 77.1 77.4 77.6 77.7
xB 0.0027 0.0023 0.0019 0.0017 0.0012 0.0008
P/MPa 78.5 79.3 79.4 79.2 77.9 76.3
T/K = 513.15
xB 0.0118 0.0102 0.0089 0.0068 0.0056 0.0045 0.0040 0.0036 0.0030
P/MPa 67.5 69.3 70.9 73.5 74.8 75.6 75.8 76.0 76.2
xB 0.0027 0.0023 0.0019 0.0017 0.0012 0.0008
P/MPa 77.1 77.8 78.0 77.8 76.4 74.4
Polymer (B): polyethylene 1981LOO

linear, Central Lab. DSM, Geleen, The Netherlands
wB 0.1514 0.1514 0.1514 0.1514 0.1514 0.1514 0.1514 0.1514 0.1514
T/K 390.79 395.30 399.17 403.90 409.01 413.81 418.24 423.19 427.84
P/bar 1085 1072 1059 1045 1034 1020 1011 1000 991
wB 0.1514 0.1514 0.1514 0.1596 0.1596 0.1596 0.1596 0.1596 0.1596
T/K 432.16 437.78 442.03 404.69 409.64 413.81 418.56 422.65 428.13
P/bar 982 972 964 1040 1024 1016 1005 996 986
wB 0.1596 0.1596 0.1596 0.1711 0.1711 0.1711 0.1711 0.1711 0.1711
T/K 432.90 437.28 442.28 384.22 388.12 392.50 396.94 403.09 406.80
P/bar 977 969 960 1094 1081 1067 1054 1037 1028
continued
____________________________________________________________________________________
continued
wB 0.1711 0.1711 0.1711 0.1711 0.1711 0.1711 0.1711 0.1711 0.1809
T/K 410.90 414.83 419.56 424.24 428.75 433.33 438.53 443.03 386.43
P/bar 1017 1007 996 988 979 970 960 953 1083
wB 0.1809 0.1809 0.1809 0.1809 0.1809 0.1809 0.1809 0.1809 0.1809
T/K 391.63 396.28 401.19 405.29 410.15 414.96 418.81 423.31 428.17
P/bar 1067 1054 1040 1029 1016 1004 996 986 977
wB 0.1809 0.1809 0.1809 0.1892 0.1892 0.1892 0.1892 0.1892 0.1892
T/K 432.86 437.61 442.41 385.89 390.01 394.34 399.64 403.43 407.90
P/bar 968 960 952 1093 1072 1059 1043 1033 1021
wB 0.1892 0.1892 0.1892 0.1892 0.1892 0.1892 0.1892 0.2003 0.2003
T/K 412.30 416.51 421.20 426.25 430.93 435.89 439.12 385.82 390.59
P/bar 1011 1001 991 980 972 963 957 1081 1065
wB 0.2003 0.2003 0.2003 0.2003 0.2003 0.2003 0.2003 0.2003 0.2003
T/K 394.94 399.19 403.26 408.79 413.12 417.74 422.74 427.28 431.14
P/bar 1051 1040 1029 1014 1004 993 984 975 967
wB 0.2003 0.2003 0.2111 0.2111 0.2111 0.2111 0.2111 0.2111 0.2111
T/K 436.18 441.21 387.41 391.69 396.85 400.18 404.68 409.20 414.85
P/bar 958 949 1076 1062 1046 1037 1025 1013 1001
wB 0.2111 0.2111 0.2111 0.2111 0.2111 0.2111 0.2194 0.2194 0.2194
T/K 419.03 424.17 428.31 432.99 438.43 443.28 387.21 392.26 396.71
P/bar 990 980 972 963 954 945 1075 1058 1045
wB 0.2194 0.2194 0.2194 0.2194 0.2194 0.2194 0.2194 0.2194 0.2194
T/K 400.30 404.04 409.14 413.76 418.20 422.33 427.11 431.56 436.49
P/bar 1036 1025 1012 1001 991 983 974 965 956
wB 0.2194 0.2303 0.2303 0.2303 0.2303 0.2303 0.2303 0.2303 0.2303
T/K 441.54 386.89 391.01 394.99 399.48 403.93 408.92 413.10 417.61
P/bar 948 1073 1060 1047 1035 1023 1010 1000 991
wB 0.2303 0.2303 0.2303 0.2303 0.2303 0.2389 0.2389 0.2389 0.2389
T/K 421.51 426.70 431.47 436.80 439.63 386.20 391.75 396.39 400.63
P/bar 983 973 963 954 949 1074 1056 1042 1031
wB 0.2389 0.2389 0.2389 0.2389 0.2389 0.2389 0.2389 0.2389 0.2389
T/K 405.11 409.98 414.30 418.18 422.63 428.35 432.85 436.89 441.80
P/bar 1018 1006 996 988 979 967 959 952 944
wB 0.2502 0.2502 0.2502 0.2502 0.2502 0.2502 0.2502 0.2502 0.2502
T/K 387.26 391.60 395.90 400.58 405.07 409.48 413.31 417.58 422.23
P/bar 1068 1054 1041 1028 1017 1006 997 989 978
wB 0.2502 0.2502 0.2502 0.2502 0.2575 0.2575 0.2575 0.2575 0.2575
T/K 426.27 431.03 435.65 441.30 385.84 390.30 395.60 400.18 404.28
P/bar 970 961 953 943 1071 1057 1040 1028 1017
wB 0.2575 0.2575 0.2575 0.2575 0.2575 0.2575 0.2575 0.2575 0.2698
T/K 409.73 413.39 418.11 422.17 426.63 432.22 437.16 442.22 386.41
P/bar 1004 995 985 977 967 958 949 941 1066
continued
____________________________________________________________________________________
continued
wB 0.2698 0.2698 0.2698 0.2698 0.2698 0.2698 0.2698 0.2698 0.2698
T/K 391.42 395.69 400.48 404.31 408.64 412.98 417.87 422.31 427.20
P/bar 1050 1038 1025 1014 1004 994 983 974 965
wB 0.2698 0.2698 0.2698 0.2781 0.2781 0.2781 0.2781 0.2781 0.2781
T/K 431.74 436.77 441.49 386.07 391.37 394.94 399.29 403.49 408.15
P/bar 956 947 940 1062 1049 1038 1026 1015 1003
wB 0.2781 0.2781 0.2781 0.2781 0.2781 0.2781 0.2781 0.2909 0.2909
T/K 413.43 417.65 421.34 426.67 431.77 436.78 441.58 386.75 391.18
P/bar 991 982 975 964 955 946 939 1062 1048
wB 0.2909 0.2909 0.2909 0.2909 0.2909 0.2909 0.2909 0.2909 0.2909
T/K 394.69 399.77 404.02 409.15 411.89 417.03 421.20 426.52 431.09
P/bar 1035 1023 1012 1000 993 982 974 964 955
wB 0.2909 0.2909 0.2954 0.2954 0.2954 0.2954 0.2954 0.2954 0.2954
T/K 435.87 440.35 386.33 390.42 394.71 398.67 403.67 407.91 413.24
P/bar 947 940 1063 1053 1038 1026 1013 1002 990
wB 0.2954 0.2954 0.2954 0.2954 0.2954 0.2954
T/K 417.88 421.58 426.90 431.20 435.82 440.40
P/bar 980 973 963 955 947 939

wB 0.056 0.056 0.056 0.112 0.112 0.112 0.185 0.185 0.185
T/K 403.65 434.15 459.15 404.65 435.15 465.15 403.15 408.15 418.15
P/MPa 142.3 125.6 119.0 139.5 123.9 117.0 137.1 133.3 127.8
wB 0.185 0.185 0.248 0.248 0.248
T/K 433.15 457.65 404.65 433.65 464.15
P/MPa 122.3 116.5 130.6 118.5 112.5

wB 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0143
T/K 414.55 420.04 425.88 429.99 433.83 437.08 440.26 443.92 414.68
P/bar 1219 1194 1180 1164 1154 1144 1139 1127 1248
wB 0.0143 0.0143 0.0143 0.0143 0.0143 0.0143 0.0153 0.0153 0.0153
T/K 420.49 423.43 429.26 434.23 439.91 445.35 411.80 416.94 420.85
P/bar 1225 1216 1194 1180 1162 1147 1259 1238 1223
continued
____________________________________________________________________________________
continued
wB 0.0153 0.0153 0.0153 0.0153 0.0153 0.0158 0.0158 0.0158 0.0158
T/K 425.66 430.02 434.29 438.90 443.31 414.56 415.72 420.29 425.27
P/bar 1205 1192 1178 1165 1152 1254 1250 1233 1215
wB 0.0158 0.0158 0.0158 0.0158 0.0198 0.0198 0.0198 0.0198 0.0198
T/K 429.21 434.20 439.15 443.99 409.66 413.40 416.97 421.46 427.06
P/bar 1201 1185 1169 1156 1293 1273 1262 1243 1224
wB 0.0198 0.0198 0.0198 0.0198 0.0230 0.0230 0.0230 0.0230 0.0230
T/K 431.47 435.57 440.13 441.32 409.48 414.04 419.34 423.26 427.07
P/bar 1209 1195 1182 1178 1298 1276 1257 1243 1228
wB 0.0230 0.0230 0.0230 0.0230 0.0252 0.0252 0.0252 0.0252 0.0252
T/K 430.37 432.91 436.69 441.79 413.38 416.09 421.13 426.77 430.96
P/bar 1217 1208 1197 1181 1289 1279 1258 1237 1222
wB 0.0252 0.0252 0.0252 0.0298 0.0298 0.0298 0.0298 0.0298 0.0298
T/K 435.04 439.34 443.17 410.53 415.61 419.46 424.87 428.67 433.11
P/bar 1209 1195 1184 1313 1291 1275 1253 1240 1224
wB 0.0298 0.0298 0.0308 0.0308 0.0308 0.0308 0.0308 0.0308 0.0308
T/K 438.18 442.41 410.75 416.80 419.19 425.40 429.42 434.91 438.94
P/bar 1207 1194 1310 1282 1266 1250 1236 1217 1204
wB 0.0308 0.0345 0.0345 0.0345 0.0345 0.0345 0.0345 0.0345 0.0345
T/K 444.13 410.55 414.74 418.50 423.22 428.02 432.49 436.83 441.23
P/bar 1189 1319 1299 1284 1266 1248 1232 1218 1204
wB 0.0406 0.0406 0.0406 0.0406 0.0406 0.0406 0.0406 0.0406 0.0494
T/K 410.35 414.75 420.35 424.66 429.28 433.80 438.49 442.85 411.23
P/bar 1331 1312 1288 1271 1254 1238 1223 1209 1334
wB 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494 0.0545 0.0545
T/K 414.90 419.72 425.27 428.85 434.49 437.80 442.03 410.10 414.87
P/bar 1317 1297 1275 1262 1243 1232 1217 1345 1324
wB 0.0545 0.0545 0.0545 0.0545 0.0545 0.0545 0.0545 0.0587 0.0587
T/K 419.04 421.07 424.87 429.52 434.51 438.33 442.90 410.35 415.70
P/bar 1305 1297 1292 1264 1247 1234 1219 1345 1322
wB 0.0587 0.0587 0.0587 0.0587 0.0587 0.0587 0.0636 0.0636 0.0636
T/K 419.19 424.40 428.05 432.33 436.93 441.75 410.40 415.23 419.06
P/bar 1306 1287 1272 1257 1241 1224 1347 1326 1309
wB 0.0636 0.0636 0.0636 0.0636 0.0636 0.0700 0.0700 0.0700 0.0700
T/K 424.37 429.01 434.20 439.00 442.79 410.10 414.11 418.37 422.88
P/bar 1288 1270 1251 1237 1223 1349 1331 1312 1294
wB 0.0700 0.0700 0.0700 0.0700 0.0831 0.0831 0.0831 0.0831 0.0831
T/K 427.26 431.78 436.87 441.22 412.06 417.79 421.70 426.39 431.00
P/bar 1278 1261 1243 1230 1344 1318 1302 1284 1267
wB 0.0831 0.0831 0.0831 0.0895 0.0895 0.0895 0.0895 0.0895 0.0895
T/K 435.15 440.28 444.79 411.68 416.78 421.97 425.62 430.54 436.03
P/bar 1252 1236 1222 1345 1322 1300 1287 1268 1249
continued
____________________________________________________________________________________
continued
wB 0.0895 0.0895 0.0996 0.0996 0.0996 0.0996 0.0996 0.0996 0.0996
T/K 440.13 444.60 412.60 415.74 419.39 423.42 428.54 431.97 436.19
P/bar 1237 1223 1339 1326 1310 1294 1275 1263 1248
wB 0.0996 0.0996 0.1035 0.1035 0.1035 0.1035 0.1035 0.1035 0.1035
T/K 440.72 442.69 411.83 416.39 420.77 424.98 430.64 435.28 439.57
P/bar 1234 1227 1343 1323 1304 1289 1267 1251 1237
wB 0.1035 0.1099 0.1099 0.1099 0.1099 0.1099 0.1099 0.1099 0.1099
T/K 444.18 413.05 417.06 421.48 427.23 430.96 435.71 439.81 445.96
P/bar 1223 1337 1319 1301 1279 1265 1249 1237 1217
wB 0.1197 0.1197 0.1197 0.1197 0.1197 0.1197 0.1197 0.1197 0.1227
T/K 413.19 416.76 421.90 425.99 430.36 435.96 439.89 444.73 414.83
P/bar 1339 1319 1297 1282 1266 1246 1235 1220 1324
wB 0.1227 0.1227 0.1227 0.1227 0.1227 0.1227 0.1227 0.1229 0.1229
T/K 417.89 421.28 425.56 430.96 437.21 439.29 443.51 413.93 419.11
P/bar 1312 1298 1282 1262 1241 1235 1222 1329 1307
wB 0.1229 0.1229 0.1229 0.1229 0.1229 0.1229 0.1229 0.1298 0.1298
T/K 422.28 426.65 431.24 432.33 435.61 441.75 446.39 413.28 417.89
P/bar 1294 1278 1261 1258 1246 1227 1213 1331 1311
wB 0.1298 0.1298 0.1298 0.1298 0.1298 0.1298 0.1310 0.1310 0.1310
T/K 421.89 426.64 431.01 435.86 440.60 445.97 415.33 418.42 420.96
P/bar 1295 1277 1261 1245 1230 1214 1321 1308 1297
wB 0.1310 0.1310 0.1310 0.1310 0.1310 0.1379 0.1379 0.1379 0.1379
T/K 425.01 430.76 433.83 438.06 443.22 410.36 414.35 420.33 423.73
P/bar 1282 1261 1250 1237 1221 1342 1324 1298 1287
wB 0.1379 0.1379 0.1379 0.1379 0.1406 0.1406 0.1406 0.1406 0.1406
T/K 429.78 433.41 438.03 442.86 412.97 417.14 421.64 427.02 431.40
P/bar 1263 1251 1236 1221 1330 1313 1294 1274 1258
wB 0.1406 0.1406 0.1503 0.1503 0.1503 0.1503 0.1503 0.1503 0.1503
T/K 436.40 440.93 411.79 416.48 422.17 429.55 435.34 439.59 444.30
P/bar 1242 1228 1334 1313 1290 1263 1243 1230 1215
wB 0.1532 0.1532 0.1532 0.1532 0.1532 0.1532 0.1532 0.1532 0.1616
T/K 411.26 416.97 420.92 426.83 431.82 436.24 440.46 445.83 412.59
P/bar 1334 1309 1293 1270 1253 1239 1225 1209 1328
wB 0.1616 0.1616 0.1616 0.1616 0.1616 0.1616 0.1616 0.1702 0.1702
T/K 416.92 422.05 427.17 431.32 436.16 440.63 445.32 412.02 417.01
P/bar 1309 1289 1270 1255 1240 1225 1211 1329 1307
wB 0.1702 0.1702 0.1702 0.1702 0.1702 0.1702 0.1752 0.1752 0.1752
T/K 421.63 426.01 430.61 435.39 440.57 445.06 413.91 417.86 422.77
P/bar 1289 1272 1256 1241 1224 1211 1318 1300 1282
wB 0.1752 0.1752 0.1752 0.1752 0.1785 0.1785 0.1785 0.1785 0.1785
T/K 425.14 431.30 435.52 441.43 412.11 416.58 420.88 426.24 430.66
P/bar 1273 1250 1237 1218 1325 1306 1289 1269 1253
continued
____________________________________________________________________________________
continued
wB 0.1785 0.1785 0.1785 0.1933 0.1933 0.1933 0.1933 0.1933 0.1933
T/K 435.25 440.00 445.07 414.15 419.27 424.33 427.21 429.72 432.54
P/bar 1238 1223 1208 1314 1306 1293 1273 1263 1254
wB 0.1933 0.1933 0.1933 0.1972 0.1972 0.1972 0.1972 0.1972 0.1972
T/K 437.84 439.91 443.33 412.40 416.11 420.17 424.73 430.06 434.98
P/bar 1245 1222 1211 1320 1304 1289 1271 1252 1236
wB 0.1972 0.1972 0.2138 0.2138 0.2138 0.2138 0.2138 0.2138 0.2138
T/K 439.15 443.73 412.65 416.24 421.78 425.56 431.16 434.82 439.52
P/bar 1222 1209 1318 1301 1279 1265 1245 1234 1219
wB 0.2138 0.2313 0.2313 0.2313 0.2313 0.2313 0.2313 0.2313 0.2313
T/K 443.30 411.21 416.17 420.82 426.55 431.65 434.71 438.57 445.61
P/bar 1208 1318 1301 1279 1265 1245 1234 1219 1208


wB 0.1523 0.1523 0.1523 0.1523 0.1523 0.1523 0.1523 0.1523 0.1523
T/K 403.15 407.52 413.10 418.07 423.20 427.59 432.99 438.19 443.31
P/bar 1549 1523 1491 1465 1440 1420 1396 1376 1357


wB 0.1350 0.1350 0.1350 0.1350 0.1350 0.1350 0.1350
T/K 407.40 411.85 412.70 418.30 429.30 434.40 440.40
P/bar 1726 1663 1591 1557 1498 1475 1447


wB 0.0971 0.0971 0.0971 0.0971 0.0971 0.0971 0.1190 0.1190 0.1190
T/K 416.62 419.14 423.86 428.21 433.04 437.49 413.92 417.55 421.79
P/bar 1671 1653 1626 1603 1579 1557 1656 1638 1611
continued
____________________________________________________________________________________
continued
wB 0.1190 0.1190 0.1190 0.1190 0.1302 0.1302 0.1302 0.1302 0.1302
T/K 426.24 430.97 435.34 440.34 414.61 419.82 424.60 428.98 433.31
P/bar 1588 1562 1541 1517 1626 1596 1567 1544 1522
wB 0.1302 0.1406 0.1406 0.1406 0.1406 0.1406 0.1406 0.1406 0.1406
T/K 437.92 407.88 412.42 416.66 420.14 424.83 429.23 434.21 438.28
P/bar 1499 1656 1627 1600 1581 1554 1531 1507 1489
wB 0.1531 0.1531 0.1531 0.1531 0.1531 0.1531 0.1531 0.1531
T/K 405.79 412.49 416.37 420.42 424.46 428.50 433.17 437.70
P/bar 1653 1609 1586 1563 1541 1520 1497 1477

Characterization: Mn/kg.mol−1 = 8.4, Mw/kg.mol−1 = 32, branched,
5.3 CH3/100 C-atoms, DSM Research, Geleen, The Netherlands

T/K = 393.15
wB 0.01992 0.03010 0.03990 0.05008 0.06024 0.07985 0.08980 0.10021 0.11018
P/MPa 132.7 134.5 133.3 132.7 132.3 131.2 130.3 129.5 128.5
wB 0.12022 0.13069 0.14108 0.15072 0.16028 0.17087 0.18041 0.20120 0.22374
P/MPa 127.9 126.9 126.3 125.8 125.2 124.6 124.1 123.2 122.1
T/K = 413.15
wB 0.01992 0.03010 0.03990 0.05008 0.06024 0.07985 0.08980 0.10021 0.11018
P/MPa 124.5 125.4 125.1 124.7 124.2 123.3 122.9 122.2 121.0
wB 0.12022 0.13069 0.14108 0.15072 0.16028 0.17087 0.18041 0.20120 0.22374
P/MPa 120.5 119.8 119.2 118.7 118.2 117.6 117.2 116.4 115.5
T/K = 433.15
wB 0.01992 0.03010 0.03990 0.05008 0.06024 0.07985 0.08980 0.10021 0.11018
P/MPa 118.3 119.3 118.9 118.6 118.4 117.4 116.5 116.5 115.6
wB 0.12022 0.13069 0.14108 0.15072 0.16028 0.17087 0.18041 0.20120 0.22374
P/MPa 114.8 114.3 113.8 113.2 112.8 112.3 111.9 111.3 110.4
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 10.6, Mw/kg.mol−1 = 15.4, LDPE,

wB 0.102 0.102 0.102 0.163 0.163 0.163 0.223 0.223 0.223
T/K 404.65 444.65 473.65 394.65 424.65 453.65 390.15 425.15 455.15
P/MPa 132.8 118.8 113.0 134.2 123.0 115.0 131.2 118.0 111.2
wB 0.284 0.284 0.284 0.385 0.385 0.385 0.455 0.455 0.455
T/K 393.65 414.65 455.15 395.65 415.15 445.65 395.65 415.15 445.15
P/MPa 124.2 117.0 108.0 113.2 108.2 103.0 103.0 99.2 96.0
wB 0.455 0.548 0.548 0.548 0.548 0.548
T/K 463.15 390.15 404.15 425.15 435.15 453.15
P/MPa 94.5 86.5 84.5 82.6 82.3 81.9

LDPE, ρ = 0.921 g/cm3, Leuna-Werke, Germany

wB 0.05 0.05 0.05 0.05 0.05 0.05 0.10 0.10 0.10
T/K 413.15 433.15 453.15 473.15 493.15 513.15 393.15 413.15 433.15
P/MPa 123.6 115.7 110.8 105.4 103.9 102.5 141.2 134.4 125.5
wB 0.10 0.20 0.20 0.20 0.20 0.20 0.20 0.30 0.30
T/K 453.15 393.15 413.15 433.15 453.15 473.15 493.15 403.15 413.15
P/MPa 119.6 132.4 125.5 118.7 114.3 109.8 105.9 115.5 112.1
wB 0.30 0.30 0.30 0.30 0.30
T/K 433.15 453.15 473.15 493.15 513.15
P/MPa 106.3 103.5 99.8 96.6 94.1
Polymer (B): polyethylene 2004BEC

Characterization: Mn/kg.mol−1 = 12, Mw/kg.mol−1 = 45.3, LDPE

T/K 403.15 414.15 423.15 434.15 442.15 454.15 463.15 473.15 482.15
P/bar 1637 1585 1522 1468 1428 1389 1356 1323 1299
T/K 492.15 502.15 512.15 521.15
P/bar 1275 1249 1226 1204
____________________________________________________________________________________


wB 0.1224 0.1224 0.1224 0.1224 0.1224 0.1224 0.1224 0.1224 0.1224
T/K 399.71 404.53 409.75 414.34 419.00 424.72 430.57 435.84 441.65
P/bar 1743 1706 1667 1640 1610 1578 1547 1520 1494

Characterization: Mn/kg.mol−1 = 14, Mw/kg.mol−1 = 70, branched,

T/K = 393.15
wB 0.05995 0.06995 0.08038 0.09086 0.10122 0.11012 0.12054 0.12983 0.14096
P/MPa 170.7 169.2 167.1 165.1 163.8 161.8 160.3 159.6 158.7
wB 0.15070 0.15916 0.16967 0.17995 0.19177 0.20004
P/MPa 158.3 157.6 157.0 156.6 155.4 155.4
T/K = 413.15
wB 0.05995 0.06995 0.08038 0.09086 0.10122 0.11012 0.12054 0.12983 0.14096
P/MPa 156.6 155.6 154.2 152.3 150.8 149.5 148.3 147.3 146.5
wB 0.15070 0.15916 0.16967 0.17995 0.19177 0.20004
P/MPa 146.3 145.9 145.3 144.9 144.1 143.7
T/K = 433.15
wB 0.05995 0.06995 0.08038 0.09086 0.10122 0.11012 0.12054 0.12983 0.14096
P/MPa 147.0 145.8 144.2 143.0 141.5 140.5 139.2 138.3 137.7
wB 0.15070 0.15916 0.16967 0.17995 0.19177 0.20004
P/MPa 137.3 137.1 136.2 136.2 135.6 135.3


continued
____________________________________________________________________________________
continued
T/K = 393.15
wB 0.00521 0.01007 0.01486 0.02010 0.02502 0.02990 0.03969 0.04998 0.06002
P/MPa 184.8 189.0 187.6 186.8 185.9 185.6 183.7 181.1 180.3
wB 0.06991 0.07989 0.08987 0.09981 0.10985 0.12046 0.12931 0.14017 0.15189
P/MPa 178.2 176.8 175.2 174.5 173.2 172.3 171.0 169.7 168.8
wB 0.16261 0.16737 0.17862 0.19022 0.20012
P/MPa 166.8 165.8 165.3 163.5 162.9
T/K = 413.15
wB 0.00521 0.01007 0.01486 0.02010 0.02502 0.02990 0.03969 0.04998 0.06002
P/MPa 169.7 170.3 171.2 171.3 170.2 169.7 168.0 166.3 165.0
wB 0.06991 0.07989 0.08987 0.09981 0.10985 0.12046 0.12931 0.14017 0.15189
P/MPa 163.7 162.3 160.8 159.9 159.1 158.2 157.1 156.1 155.1
wB 0.16261 0.16737 0.17862 0.19022 0.20012
P/MPa 154.1 153.5 152.8 151.6 150.5
T/K = 433.15
wB 0.00521 0.01007 0.01486 0.02010 0.02502 0.02990 0.03969 0.04998 0.06002
P/MPa 157.6 158.6 159.0 159.1 158.0 157.6 156.2 154.5 153.6
wB 0.06991 0.07989 0.08987 0.09981 0.10985 0.12046 0.12931 0.14017 0.15189
P/MPa 152.5 151.2 150.1 149.3 148.6 147.8 146.9 146.0 145.1
wB 0.16261 0.16737 0.17862 0.19022 0.20012
P/MPa 144.2 143.7 143.2 142.1 141.3

T/K = 393.15
wB 0.02003 0.02990 0.04011 0.04997 0.05993 0.07050 0.08049 0.08976 0.09532
P/MPa 190.4 190.5 187.5 185.1 182.9 180.9 179.1 177.4 176.6
wB 0.10090 0.10795 0.12307 0.11532 0.11961 0.13015 0.13933 0.14036 0.14915
P/MPa 176.0 175.1 174.6 174.2 174.0 172.7 171.7 171.6 170.4
wB 0.16035 0.17063
P/MPa 169.2 168.2
continued
____________________________________________________________________________________
continued
T/K = 413.15
wB 0.02003 0.02990 0.04011 0.04997 0.05993 0.07050 0.08049 0.08976 0.09532
P/MPa 174.1 172.6 170.3 169.0 166.8 165.3 163.9 162.5 161.7
wB 0.10090 0.10795 0.12307 0.11532 0.11961 0.13015 0.13933 0.14036 0.14915
P/MPa 161.1 160.5 160.1 159.8 159.5 158.4 157.6 157.5 156.6
wB 0.16035 0.17063
P/MPa 155.5 154.8
T/K = 433.15
wB 0.02003 0.02990 0.04011 0.04997 0.05993 0.07050 0.08049 0.08976 0.09532
P/MPa 161.7 160.1 157.9 157.0 155.5 154.0 152.7 151.4 150.7
wB 0.10090 0.10795 0.12307 0.11532 0.11961 0.13015 0.13933 0.14036 0.14915
P/MPa 150.2 149.6 149.3 149.1 148.8 147.8 147.2 147.1 146.3
wB 0.16035 0.17063
P/MPa 145.4 144.9
Polymer (B): polyethylene 1996MU1

LDPE, PE15280, BASF AG, Germany

wB 0.010 0.010 0.010 0.010 0.010 0.074 0.074 0.074 0.074
T/K 523.35 498.35 473.35 449.25 423.45 498.55 473.55 448.45 424.65
P/MPa 124.8 130.7 137.3 145.9 156.5 127.2 133.9 142.4 153.1
wB 0.075 0.075 0.075 0.075 0.075 0.100 0.100 0.100 0.100
T/K 523.75 498.15 473.75 448.05 423.65 524.65 498.85 473.55 449.35
P/MPa 121.7 127.1 133.6 142.4 152.5 118.8 124.1 130.5 138.5
wB 0.100 0.114 0.114 0.114 0.114 0.114 0.128 0.128 0.128
T/K 423.65 523.45 499.45 473.65 449.05 424.15 522.55 498.95 472.85
P/MPa 149.0 119.9 124.9 131.0 139.1 150.1 118.3 123.2 129.2
wB 0.128 0.128 0.144 0.144 0.144 0.144 0.144 0.200 0.200
T/K 448.45 424.35 524.25 498.75 474.15 449.05 422.65 523.35 499.65
P/MPa 136.8 146.9 115.4 119.7 125.6 133.3 143.5 110.9 115.0
wB 0.200 0.200 0.200 0.261 0.261 0.261 0.261 0.261 0.362
T/K 474.15 449.75 423.05 523.45 498.35 474.45 447.55 424.45 523.55
P/MPa 120.0 125.1 135.1 108.9 111.8 116.5 122.2 129.4 89.1
wB 0.362 0.362 0.362 0.362
T/K 499.15 473.05 447.25 425.05
P/MPa 91.4 92.9 95.9 99.1
____________________________________________________________________________________

LDPE, PE15280, BASF AG, Germany
wB 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05
T/K 521.65 497.95 472.55 447.85 423.55 413.15 403.45 393.45 383.75
P/bar 1221 1272 1341 1421 1529 1591 1653 1725 1813

−1 −1 −1
Characterization: Mn/kg.mol = 19.5, Mw/kg.mol = 192, Mz/kg.mol = 1450,
LDPE, ρ = 0.9225 g/cm3 at 295 K
T/K = 433.15
wB 0.060 0.077 0.100 0.122 0.239 0.265
P/MPa 152.0 153.2 150.9 146.3 133.8 129.5
T/K = 473.15
wB 0.074 0.077 0.115 0.253 0.691
P/MPa 138.0 138.1 134.0 120.3 63.0

T/K = 433.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
146.1 0.200
143.3 0.211
130.8 0.022
129.8 0.277
124.0 0.317
122.4 0.314
119.5 0.338
114.2 0.014
108.8 0.397
94.3 0.005
84.8 0.003
74.4 0.003
_____________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
148.1 0.083
145.3 0.170
143.9 0.076
140.5 0.204
136.0 0.049
131.7 0.039
116.8 0.023
112.3 0.374
106.4 0.431
103.5 0.013
100.6 0.458
99.5 0.012
67.0 0.004
64.7 0.003
54.2 0.002
48.2 0.002
42.5 0.001
_____________________________________________________________________________________________
T/K = 433.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
143.8 0.155
142.1 0.105
139.1 0.205
136.0 0.057
133.0 0.245
130.2 0.253
127.2 0.042
123.4 0.041
121.7 0.311
107.8 0.422
99.5 0.019
96.6 0.490
87.8 0.007
59.8 0.003
_____________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
128.3 0.055
120.0 0.038
117.5 0.330
111.3 0.377
100.2 0.019
97.0 0.486
85.7 0.555
74.6 0.007
48.3 0.001
_____________________________________________________________________________________________
T/K = 433.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
127.8 0.274
126.0 0.283
122.1 0.050
119.3 0.316
115.3 0.048
111.4 0.372
106.1 0.032
103.4 0.445
100.8 0.025
99.7 0.457
91.0 0.018
89.4 0.533
80.3 0.013
79.2 0.592
65.0 0.006
63.6 0.675
51.0 0.739
49.5 0.004
46.0 0.764
_____________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 473.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
136.0 0.172
135.3 0.061
127.6 0.041
125.3 0.237
123.0 0.035
121.5 0.261
117.5 0.286
112.2 0.024
100.4 0.012
99.2 0.395
96.5 0.409
88.5 0.491
86.0 0.520
81.8 0.004
48.2 0.002
_____________________________________________________________________________________________
T/K = 473.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
134.0 0.115 0.115 (critical point)
131.7 0.166
131.5 0.075
128.2 0.202
124.2 0.226
120.4 0.045
117.2 0.272
112.3 0.028
111.5 0.305
94.5 0.012
87.0 0.522
72.3 0.628
58.0 0.002
42.4 0.001
_____________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 473.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
117.0 0.275
112.8 0.061
105.1 0.352
101.2 0.036
95.8 0.034
93.6 0.453
91.5 0.464
85.3 0.509
84.7 0.533
82.3 0.018
75.2 0.601
72.8 0.010
60.6 0.003
59.2 0.709
51.7 0.005
_____________________________________________________________________________________________
T/K = 473.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
61.6 0.005
58.8 0.725
53.3 0.742
42.6 0.799
_____________________________________________________________________________________________

wB 0.0691 0.0691 0.0691 0.0691 0.0691 0.0691 0.0691 0.0857 0.0857
T/K 408.99 415.94 419.96 423.18 427.38 431.04 436.91 414.66 420.17
P/bar 1831 1775 1749 1729 1701 1678 1644 1750 1712
continued
____________________________________________________________________________________
continued
wB 0.0857 0.0857 0.0857 0.0857 0.0997 0.0997 0.0997 0.0997 0.0997
T/K 424.87 430.69 435.40 440.97 412.80 416.99 419.38 424.36 428.50
P/bar 1683 1649 1622 1595 1735 1707 1688 1659 1634
wB 0.0997 0.0997 0.1129 0.1129 0.1129 0.1129 0.1129 0.1129 0.1129
T/K 432.23 439.10 408.53 415.11 419.51 420.81 423.57 427.38 432.65
P/bar 1611 1577 1739 1691 1662 1653 1639 1616 1588
wB 0.1129 0.1129 0.1290 0.1290 0.1290 0.1290 0.1290 0.1290 0.1290
T/K 436.67 440.60 410.18 415.22 419.45 423.99 428.09 433.71 439.75
P/bar 1567 1547 1699 1663 1638 1609 1585 1554 1524

Exxon Polymer Plant, Antwerp

wB 0.072 0.095 0.095 0.095 0.174 0.174 0.174 0.243 0.243
T/K 427.15 399.15 428.65 468.15 399.15 428.15 466.65 400.65 430.15
P/MPa 148.8 156.2 141.0 127.6 148.2 134.8 123.0 140.6 128.2
wB 0.243 0.346 0.346 0.346 0.445 0.445 0.445
T/K 460.15 419.65 451.15 471.15 397.65 427.65 462.15
P/MPa 120.0 122.5 114.5 111.0 111.4 104.8 99.5

T/K = 403.15
______________________________________________________
P/ wA
______________________________________________________
123.3 0.693 0.961
107.0 0.567 0.987
89.2 0.456 0.989
72.6 0.369 0.995
______________________________________________________

Characterization: Mn/kg.mol−1 = 23, Mw/kg.mol−1 = 160, LDPE,

continued
____________________________________________________________________________________
continued
T/K = 420.15
wB 0.184 0.184 0.184 0.184
P/bar 1396 1400 1405 1408
shear rate/s 0 500 1000 1500
T/K = 422.15
wB 0.274 0.274 0.274 0.274
P/bar 1314 1319 1324 1328
shear rate/s 0 500 1000 1500
T/K = 431.15
wB 0.184 0.184 0.184 0.184
P/bar 1347 1352 1358 1361
shear rate/s 0 500 1000 1500
T/K = 439.15
wB 0.274 0.274 0.274 0.274
P/bar 1249 1254 1258 1262
shear rate/s 0 500 1000 1500
T/K = 441.15
wB 0.225 0.225 0.225 0.225
P/bar 1281 1290 1300 1304
shear rate/s 0 500 1000 1500
T/K = 453.15
wB 0.225 0.225 0.225 0.225
P/bar 1245 1255 1260 1263
shear rate/s 0 500 1000 1500
T/K = 468.15
wB 0.225 0.225 0.225 0.225
P/bar 1203 1214 1219 1222
shear rate/s 0 500 1000 1500


wB 0.05 0.05 0.10 0.10 0.10 0.10 0.10 0.10 0.15
T/K 403.15 433.15 413.15 433.15 453.15 473.15 493.15 513.154 403.15
P/MPa 142.7 127.9 152.8 141.6 153.4 128.7 123.7 119.6 145.7
wB 0.15
T/K 433.15
P/MPa 137.5
____________________________________________________________________________________
Polymer (B): polyethylene 2000CH4

Characterization: Mn/kg.mol−1 = 28.8, Mw/kg.mol−1 = 32.0, NIST SRM1483

wB 0.050 0.050 0.050 0.050 0.050 0.050 0.075 0.075 0.075
T/K 453.15 443.15 433.15 423.15 413.15 403.15 453.15 443.15 433.15
P/bar 1406 1445 1488 1534 1590 1650 1431 1454 1500
wB 0.075 0.075 0.075 0.100 0.100 0.100 0.100 0.100 0.100
T/K 423.15 413.15 403.15 453.15 443.15 433.15 423.15 413.15 403.15
P/bar 1536 1591 1654 1422 1452 1502 1536 1591 1651
wB 0.124 0.124 0.124 0.124 0.124 0.124 0.150 0.150 0.150
T/K 453.15 443.15 433.15 423.15 413.15 403.15 453.15 443.15 433.15
P/bar 1445 1475 1515 1559 1610 1668 1425 1453 1495
wB 0.150 0.150
T/K 423.15 413.15
P/bar 1527 1594


wB 0.05 0.05 0.05 0.05 0.05 0.10 0.10 0.10 0.15
T/K 433.15 453.15 473.15 493.15 513.154 473.15 493.15 513.15 493.15
P/MPa 152.0 144.2 138.3 132.4 126.5 144.2 134.4 124.1 128.0
wB 0.15 0.20 0.20 0.20 0.20 0.20 0.30 0.30 0.30
T/K 513.15 443.15 453.15 473.15 493.15 513.15 473.15 493.15 513.15
P/MPa 121.1 128.5 125.0 119.6 115.7 111.8 97.6 92.2 89.7

−1 −1
Characterization: Mn/kg.mol = 30, Mw/kg.mol = 223, branched,

T/K = 393.15
wB 0.01001 0.01500 0.02505 0.03011 0.04000 0.05014 0.06031 0.07409 0.07981
P/MPa 171.3 172.2 172.0 171.6 170.5 169.7 168.7 167.9 167.6
wB 0.08537 0.09035 0.10035 0.11036 0.12001 0.12989 0.13512 0.14555 0.15929
P/MPa 167.2 166.6 166.4 165.6 165.0 164.6 164.0 163.1 162.1
continued
____________________________________________________________________________________
continued
wB 0.17102 0.18313
P/MPa 161.2 160.1
T/K = 413.15
wB 0.01001 0.01500 0.02505 0.03011 0.04000 0.05014 0.06031 0.07409 0.07981
P/MPa 157.6 158.1 158.0 157.8 156.8 156.1 155.4 154.5 154.3
wB 0.08537 0.09035 0.10035 0.11036 0.12001 0.12989 0.13512 0.14555 0.15929
P/MPa 154.0 153.5 153.4 152.7 152.3 151.8 151.3 150.6 149.7
wB 0.17102 0.18313
P/MPa 149.1 148.2
T/K = 433.15
wB 0.01001 0.01500 0.02505 0.03011 0.04000 0.05014 0.06031 0.07409 0.07981
P/MPa 147.2 147.7 147.5 147.3 146.7 146.0 145.3 144.6 144.4
wB 0.08537 0.09035 0.10035 0.11036 0.12001 0.12989 0.13512 0.14555 0.15929
P/MPa 144.1 143.7 143.7 143.1 142.6 142.3 141.9 141.2 140.5
wB 0.17102 0.18313
P/MPa 139.9 139.2

Type of data: critical points (cloud points)

wB 0.102 0.102 0.102
T/K 393.15 413.15 433.15
P/MPa 176.2 161.4 150.3
Polymer (B): polyethylene 2003BUB

synthesized in the laboratory by high-pressure polymerization

T/K 403.15 413.15 422.15 433.15 452.15 462.15 473.15 483.15 493.15
P/bar 1748 1666 1606 1542 1458 1418 1383 1351 1324
T/K 503.15 513.15 523.15 532.15
P/bar 1297 1274 1255 1239
____________________________________________________________________________________


T/K = 393.15
wB 0.05455 0.06532 0.07490 0.08566 0.09653 0.10998 0.12111 0.13189 0.13990
P/MPa 176.2 174.7 173.9 173.3 172.7 171.4 171.3 170.5 170.0
wB 0.14871 0.15965 0.17140 0.17983 0.19003 0.20131 0.21076
P/MPa 169.3 168.4 167.2 166.2 165.2 163.9 162.6
T/K = 413.15
wB 0.05455 0.06532 0.07490 0.08566 0.09653 0.10998 0.12111 0.13189 0.13990
P/MPa 161.7 160.5 159.5 159.1 158.6 157.5 157.4 156.8 156.5
wB 0.14871 0.15965 0.17140 0.17983 0.19003 0.20131 0.21076
P/MPa 155.8 155.1 154.2 153.6 152.5 151.5 150.5
T/K = 433.15
wB 0.05455 0.06532 0.07490 0.08566 0.09653 0.10998 0.12111 0.13189 0.13990
P/MPa 150.8 149.8 149.0 148.6 148.2 147.2 147.0 146.6 146.5
wB 0.14871 0.15965 0.17140 0.17983 0.19003 0.20131 0.21076
P/MPa 145.8 145.2 144.5 144.0 143.1 142.3 141.4


wB 0.029 0.029 0.029 0.029 0.029 0.042 0.042 0.042 0.047
T/K 413.15 427.15 437.15 467.15 470.15 407.15 437.15 467.15 407.15
P/MPa 169.8 161.0 155.6 142.8 141.8 172.7 154.0 141.7 170.7
wB 0.047 0.047 0.047 0.061 0.061 0.061 0.061 0.084 0.084
T/K 417.15 437.15 467.15 407.15 417.15 437.15 467.15 422.65 457.15
P/MPa 163.5 152.5 140.6 169.0 162.5 151.5 139.5 157.2 141.5
wB 0.100 0.100 0.100 0.100 0.100 0.100 0.138 0.138 0.180
T/K 402.65 407.65 427.65 447.65 457.65 473.65 426.15 446.15 407.15
P/MPa 167.0 163.5 152.0 143.2 139.5 134.5 149.0 140.3 155.0
wB 0.180 0.180 0.180 0.242 0.242 0.242 0.283 0.283 0.283
T/K 427.15 447.15 476.65 425.15 450.15 476.15 407.15 427.15 447.15
P/MPa 144.5 136.7 128.0 138.0 129.6 123.0 139.5 132.0 126.0
continued
____________________________________________________________________________________
continued
wB 0.283 0.409 0.409 0.409 0.409 0.434 0.434 0.434 0.572
T/K 472.15 409.65 429.15 447.65 466.15 424.15 460.65 476.15 416.65
P/MPa 120.3 119.2 114.0 109.7 106.5 111.0 104.2 102.0 89.0
wB 0.572 0.572 0.572
T/K 426.65 446.65 466.15
P/MPa 87.5 85.3 83.5

T/K = 403.15
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
162.0 0.863 36.3 220.5 (feed sample, cloud point)
154.8 0.767 0.956 49.9 209.3 505.4 14.7 35.9 65.4
138.4 0.674 0.981
122.8 0.649 0.983 6.5 15.1 27.4
111.4 0.620
92.6 0.993
68.1 0.996
46.3 0.997
____________________________________________________________________________________
T/K = 433.15
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
138.9 0.778 0.963
127.5 0.682 0.977
110.8 0.571 0.985
103.0 0.526 0.990
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 463.15
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
124.2 0.719 0.968 56.9 221.3 508.2 10.6 24.8 42.8
112.7 0.612 0.976
97.8 0.504 0.984 5.9 12.3 29.2
78.7 0.440 0.988
57.7 0.372 0.993
37.0 0.289 0.998
____________________________________________________________________________________


wB 0.0099 0.0099 0.0099 0.0099 0.0099 0.0099 0.0109 0.0109 0.0109
T/K 421.01 421.30 425.91 430.03 434.57 439.03 420.92 425.60 430.18
P/bar 1825 1821 1784 1760 1731 1698 1831 1796 1762
wB 0.0109 0.0109 0.0149 0.0149 0.0149 0.0149 0.0149 0.0149 0.0149
T/K 434.96 439.31 412.54 416.83 420.89 425.05 429.91 434.62 439.25
P/bar 1733 1707 1900 1868 1835 1803 1772 1739 1709
wB 0.0201 0.0201 0.0201 0.0201 0.0201 0.0201 0.0249 0.0249 0.0249
T/K 416.80 420.52 425.83 430.22 435.00 439.40 421.40 426.26 430.73
P/bar 1864 1834 1795 1762 1731 1705 1824 1786 1756
wB 0.0249 0.0249 0.0297 0.0297 0.0297 0.0297 0.0297 0.0297 0.0297
T/K 435.46 440.20 414.88 420.10 424.22 428.39 433.26 438.21 442.35
P/bar 1727 1696 1870 1828 1794 1763 1733 1701 1679
wB 0.0348 0.0348 0.0348 0.0348 0.0348 0.0373 0.0373 0.0373 0.0373
T/K 422.56 426.96 431.71 436.17 440.49 413.82 418.18 422.36 427.12
P/bar 1803 1772 1740 1713 1687 1869 1836 1804 1769
wB 0.0373 0.0373 0.0373 0.0398 0.0398 0.0398 0.0398 0.0398 0.0398
T/K 431.74 436.36 440.92 405.17 409.72 414.40 418.47 422.83 427.09
P/bar 1739 1709 1681 1939 1898 1860 1827 1794 1762
continued
____________________________________________________________________________________
continued
wB 0.0398 0.0398 0.0398 0.0450 0.0450 0.0450 0.0450 0.0450 0.0450
T/K 432.35 436.96 441.97 417.54 418.18 422.24 427.20 431.60 436.60
P/bar 1730 1700 1671 1830 1824 1787 1753 1720 1694
wB 0.0450 0.0477 0.0477 0.0477 0.0477 0.0477 0.0477 0.0499 0.0499
T/K 441.03 418.58 422.95 427.29 431.79 436.84 441.17 409.01 414.15
P/bar 1667 1812 1778 1749 1719 1689 1665 1884 1845
wB 0.0499 0.0499 0.0499 0.0499 0.0499 0.0499 0.0550 0.0550 0.0550
T/K 418.72 422.93 427.34 432.33 436.74 441.74 419.28 423.33 423.89
P/bar 1806 1777 1745 1712 1684 1657 1791 1766 1760
wB 0.0550 0.0550 0.0550 0.0550 0.0573 0.0573 0.0573 0.0573 0.0573
T/K 427.55 432.58 436.93 441.80 404.74 409.86 414.62 414.79 419.02
P/bar 1737 1703 1678 1650 1913 1866 1826 1824 1795
wB 0.0573 0.0573 0.0573 0.0573 0.0573 0.0580 0.0580 0.0580 0.0580
T/K 423.29 428.29 432.79 437.61 442.36 409.63 414.21 418.36 422.62
P/bar 1764 1729 1701 1671 1645 1865 1827 1797 1764
wB 0.0580 0.0580 0.0580 0.0580 0.0587 0.0587 0.0587 0.0587 0.0587
T/K 427.70 432.28 436.79 441.54 418.80 423.13 427.81 432.38 437.47
P/bar 1728 1700 1673 1647 1793 1762 1731 1701 1670
wB 0.0587 0.0605 0.0605 0.0605 0.0605 0.0605 0.0605 0.0605 0.0605
T/K 442.01 405.43 409.85 414.55 419.09 423.41 427.42 433.00 437.77
P/bar 1646 1897 1857 1820 1783 1752 1724 1690 1661
wB 0.0605 0.0622 0.0622 0.0622 0.0622 0.0622 0.0622 0.0622 0.0652
T/K 441.88 418.78 422.44 426.93 427.23 431.84 436.68 441.03 405.09
P/bar 1639 1785 1758 1730 1726 1697 1666 1643 1895
wB 0.0652 0.0652 0.0652 0.0652 0.0652 0.0652 0.0652 0.0652 0.0683
T/K 409.84 414.46 418.94 423.54 428.68 432.77 437.44 441.51 404.38
P/bar 1853 1814 1781 1748 1713 1689 1661 1637 1897
wB 0.0683 0.0683 0.0683 0.0683 0.0683 0.0683 0.0683 0.0683 0.0700
T/K 409.13 413.65 418.21 422.36 427.61 432.09 436.74 441.18 405.26
P/bar 1854 1816 1781 1751 1717 1688 1659 1635 1890
wB 0.0700 0.0700 0.0700 0.0700 0.0700 0.0700 0.0700 0.0700 0.0750
T/K 409.84 414.82 419.82 423.26 428.46 433.57 438.19 442.32 405.58
P/bar 1849 1807 1769 1742 1709 1677 1650 1627 1881
wB 0.0750 0.0750 0.0750 0.0750 0.0750 0.0750 0.0750 0.0750 0.0797
T/K 410.21 414.77 418.96 423.64 428.31 432.86 437.32 441.95 404.76
P/bar 1841 1802 1771 1739 1707 1679 1652 1627 1886
wB 0.0797 0.0797 0.0797 0.0797 0.0797 0.0797 0.0797 0.0797 0.0869
T/K 409.38 414.14 418.27 422.68 427.34 432.04 436.64 441.37 411.81
P/bar 1845 1805 1774 1743 1711 1681 1653 1627 1821
wB 0.0869 0.0869 0.0869 0.0869 0.0869 0.0869 0.0869 0.0902 0.0902
T/K 417.19 418.00 422.67 426.84 431.92 436.11 442.35 405.18 409.84
P/bar 1779 1778 1740 1712 1679 1654 1619 1874 1834
continued
____________________________________________________________________________________
continued
wB 0.0902 0.0902 0.0902 0.0902 0.0902 0.0902 0.0902 0.0953 0.0953
T/K 413.91 418.56 423.08 428.24 432.76 437.16 442.10 412.46 416.52
P/bar 1801 1765 1733 1699 1671 1645 1618 1808 1777
wB 0.0953 0.0953 0.0953 0.0953 0.0953 0.0953 0.0998 0.0998 0.0998
T/K 420.57 425.44 429.77 434.03 438.53 443.12 411.33 415.38 419.16
P/bar 1747 1714 1686 1660 1635 1610 1815 1783 1754
wB 0.0998 0.0998 0.0998 0.0998 0.0998 0.1048 0.1048 0.1048 0.1048
T/K 423.23 427.54 431.79 435.89 440.40 412.74 417.02 421.06 425.41
P/bar 1727 1699 1672 1648 1623 1799 1766 1738 1708
wB 0.1048 0.1048 0.1048 0.1048 0.1100 0.1100 0.1100 0.1100 0.1100
T/K 429.62 434.32 438.32 443.01 405.24 409.84 414.34 418.62 422.83
P/bar 1682 1654 1631 1606 1858 1820 1783 1751 1722
wB 0.1100 0.1100 0.1100 0.1100 0.1149 0.1149 0.1149 0.1149 0.1149
T/K 427.58 432.18 437.42 441.61 413.29 417.09 420.66 424.84 429.28
P/bar 1692 1663 1633 1610 1787 1758 1734 1706 1678
wB 0.1149 0.1149 0.1149 0.1247 0.1247 0.1247 0.1247 0.1247 0.1247
T/K 433.87 438.27 442.59 411.99 416.88 420.82 424.73 429.14 433.38
P/bar 1650 1626 1603 1790 1753 1725 1699 1672 1647
wB 0.1247 0.1247 0.1292 0.1292 0.1292 0.1292 0.1292 0.1292 0.1292
T/K 437.66 442.05 409.85 413.90 418.14 423.21 427.93 432.68 437.34
P/bar 1623 1599 1798 1767 1736 1701 1672 1644 1617
wB 0.1292 0.1292 0.1292 0.1292 0.1292 0.1292 0.1292 0.1292 0.1292
T/K 441.75 408.07 413.16 416.59 421.01 425.90 430.63 436.33 441.63
P/bar 1594 1809 1769 1745 1713 1682 1653 1623 1593
wB 0.1403 0.1403 0.1403 0.1403 0.1403 0.1403 0.1403 0.1403 0.1403
T/K 405.29 409.91 413.99 417.79 422.89 427.71 432.35 436.99 441.65
P/bar 1822 1784 1754 1725 1692 1661 1634 1608 1584
wB 0.1440 0.1440 0.1440 0.1440 0.1440 0.1440 0.1440 0.1440 0.1497
T/K 410.14 415.10 419.19 423.59 428.02 433.13 438.04 443.61 410.64
P/bar 1778 1742 1712 1684 1656 1627 1600 1572 1767
wB 0.1497 0.1497 0.1497 0.1497 0.1497 0.1497 0.1497 0.1546 0.1546
T/K 415.37 419.17 423.78 428.00 432.45 437.02 441.55 410.97 414.92
P/bar 1732 1705 1676 1650 1624 1599 1577 1762 1732
wB 0.1546 0.1546 0.1546 0.1546 0.1546 0.1546 0.1604 0.1604 0.1604
T/K 419.85 424.41 429.17 433.69 438.86 442.65 407.49 411.78 416.21
P/bar 1699 1669 1641 1616 1588 1569 1799 1746 1716
wB 0.1604 0.1604 0.1604 0.1604 0.1604 0.1604
T/K 419.74 424.29 428.80 433.32 437.77 442.68
P/bar 1691 1682 1635 1610 1586 1562
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 47.3, Mw/kg.mol−1 = 52.0, branched,

T/K = 393.15
wB 0.00497 0.00753 0.01000 0.01249 0.01503 0.01994 0.02491 0.03005 0.03498
P/MPa 164.6 167.4 169.5 170.8 172.1 173.8 175.0 175.0 175.8
wB 0.04018 0.04500 0.04995 0.05491 0.06004 0.06462 0.07007 0.07511 0.07950
P/MPa 176.3 176.2 176.4 176.7 176.8 176.6 177.3 176.7 177.1
wB 0.08524 0.08967 0.09948 0.10978 0.11968 0.13029 0.13961 0.14923 0.15890
P/MPa 176.3 176.1 175.8 175.8 175.3 174.5 173.9 173.7 173.0
wB 0.16967 0.18046
P/MPa 172.2 171.5
T/K = 413.15
wB 0.00497 0.00753 0.01000 0.01249 0.01503 0.01994 0.02491 0.03005 0.03498
P/MPa 151.8 154.2 155.8 157.1 157.9 159.5 160.2 160.8 161.4
wB 0.04018 0.04500 0.04995 0.05491 0.06004 0.06462 0.07007 0.07511 0.07950
P/MPa 161.8 161.9 162.1 162.2 162.2 162.4 162.3 162.2 162.1
wB 0.08524 0.08967 0.09948 0.10978 0.11968 0.13029 0.13961 0.14923 0.15890
P/MPa 161.8 161.8 161.6 161.4 160.8 160.5 160.1 159.9 159.4
wB 0.16967 0.18046
P/MPa 158.6 157.6
T/K = 433.15
wB 0.00497 0.00753 0.01000 0.01249 0.01503 0.01994 0.02491 0.03005 0.03498
P/MPa 141.6 143.7 145.2 146.3 147.1 148.7 149.3 149.7 150.2
wB 0.04018 0.04500 0.04995 0.05491 0.06004 0.06462 0.07007 0.07511 0.07950
P/MPa 150.7 150.7 150.9 150.9 151.0 151.2 151.2 151.0 151.0
wB 0.08524 0.08967 0.09948 0.10978 0.11968 0.13029 0.13961 0.14923 0.15890
P/MPa 150.6 150.7 150.6 150.3 150.0 149.6 149.4 149.1 148.8
wB 0.16967 0.18046
P/MPa 148.1 147.3
____________________________________________________________________________________

LDPE, ρ = 0.9270 g/cm3 at 295 K
T/K = 433.15
wB 0.045 0.053 0.065 0.164
P/MPa 164.2 163.8 161.0 148.8
T/K = 473.15
wB 0.040 0.045 0.050 0.065 0.251
P/MPa 144.9 145.0 144.6 142.0 128.8

T/K = 433.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
160.5 0.040
159.1 0.038
157.9 0.122
157.0 0.123
155.5 0.031
153.1 0.153
151.3 0.162
145.0 0.025
141.7 0.200
140.8 0.207
138.5 0.022
123.6 0.014
121.2 0.350
119.0 0.010
109.7 0.009
108.5 0.448
105.5 0.008
100.0 0.509
97.5 0.007
82.7 0.006
66.8 0.002
47.0 0.001
_____________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
161.0 0.065 0.065 (critical point)
160.3 0.054
159.8 0.076
158.7 0.097
156.0 0.050
152.4 0.152
150.0 0.039
147.3 0.171
146.2 0.176
143.0 0.030
139.5 0.206
135.8 0.022
130.5 0.260
118.8 0.014
117.1 0.388
116.0 0.397
113.6 0.418
110.3 0.011
92.0 0.007
69.7 0.003
68.0 0.002
_____________________________________________________________________________________________
T/K = 433.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
147.1 0.173
143.6 0.056
141.5 0.197
140.0 0.206
137.5 0.041
136.9 0.221
135.1 0.234
131.6 0.036
127.4 0.290
126.4 0.294
_____________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
123.2 0.029
118.0 0.023
117.6 0.378
114.8 0.409
113.9 0.414
105.0 0.017
101.0 0.016
98.3 0.459
93.9 0.493
91.7 0.013
89.9 0.572
87.2 0.008
84.7 0.559
80.5 0.004
73.5 0.003
52.5 0.002
47.5 0.001
_____________________________________________________________________________________________
T/K = 473.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
143.0 0.032
140.8 0.030
139.5 0.162
137.2 0.190
136.8 0.027
135.7 0.201
127.6 0.261
124.0 0.016
121.3 0.014
120.2 0.279
114.1 0.011
107.0 0.008
105.5 0.365
89.0 0.005
73.7 0.003
72.0 0.002
_____________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 473.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
142.0 0.065 0.065 (critical point)
131.8 0.242
129.6 0.032
128.7 0.253
121.7 0.021
118.2 0.286
108.4 0.011
104.2 0.380
97.3 0.009
91.2 0.497
88.2 0.007
72.0 0.004
_____________________________________________________________________________________________
T/K = 473.15
_____________________________________________________________________________________________
P/ wB
_____________________________________________________________________________________________
125.4 0.268
116.5 0.292
111.1 0.045
108.5 0.340
104.8 0.038
101.3 0.416
98.8 0.033
96.0 0.459
88.0 0.016
86.6 0.015
84.0 0.554
80.5 0.013
75.5 0.008
74.7 0.618
73.3 0.009
65.8 0.005
_____________________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): polyethylene 1999DIE

Characterization: Mn/kg.mol−1 = 69.2, Mw/kg.mol−1 = 198, 54.0 % crystallinity

T/K 384.15 388.15 393.15 403.15 413.15 423.15 433.15 443.15 453.15
P/bar 2200 2060 2000 1910 1840 1760 1673 1615 1562
T/K 463.15 473.15 483.15
P/bar 1519 1489 1452
Polymer (B): polyethylene 1981WO2


wB 0.05 0.05 0.05 0.05 0.05 0.10 0.10 0.10 0.20
T/K 473.15 483.15 493.15 503.15 513.15 493.15 503.15 513.154 503.15
P/MPa 128.7 125.5 122.6 121.2 118.2 113.7 112.1 110.0 100.7
wB 0.20
T/K 513.15
P/MPa 99.4

−1 −1
Characterization: Mn/kg.mol = 126, Mw/kg.mol = 216, HDPE,

wB 0.061 0.061 0.061 0.101 0.101 0.101 0.101 0.124 0.124
T/K 403.75 423.35 460.55 402.65 422.15 443.25 462.65 403.65 423.15
P/MPa 202.5 182.0 161.2 199.2 179.0 164.9 155.2 193.1 175.5
wB 0.124 0.166 0.166 0.166 0.166 0.315 0.315 0.315 0.315
T/K 453.15 403.15 418.15 433.35 452.95 405.65 423.15 452.95 465.45
P/MPa 157.8 185.2 173.1 163.3 155.0 156.3 148.0 136.3 133.5
wB 0.394 0.394 0.394
T/K 406.15 432.15 458.15
P/MPa 139.0 130.4 124.5
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 259, Mw/kg.mol−1 = 499, LDPE,

wB 0.042 0.042 0.042 0.074 0.074 0.120 0.120 0.120 0.120
T/K 418.15 433.15 453.15 433.15 463.15 404.15 418.15 433.15 463.15
P/MPa 171.0 160.5 150.7 159.7 146.0 180.2 168.2 158.1 144.5
wB 0.216 0.216 0.216 0.216 0.310 0.310 0.310 0.371 0.371
T/K 403.15 433.15 458.15 473.15 403.15 433.15 453.15 403.15 433.15
P/MPa 166.0 148.8 138.8 134.0 145.8 133.7 128.2 133.6 123.5
wB 0.371 0.431 0.431 0.431 0.431
T/K 463.15 393.15 413.15 433.15 452.65
P/MPa 116.0 122.8 116.5 111.8 108.0
Polymer (B): polyethylene 1965SWE

Characterization: Mw/kg.mol−1 = 315, LDPE, Stamylan 3401, 2 CH3/100 C-atoms,

wB 0.0022 0.0022 0.0022 0.0022 0.0022 0.0022 0.0022 0.0035 0.0035
T/K 381.43 385.70 385.96 391.21 398.11 398.43 409.83 387.55 395.66
P/kg.cm−2 1952 1916 1908 1840 1784 1788 1688 1904 1820
wB 0.0035 0.0035 0.0045 0.0045 0.0045 0.0045 0.0077 0.0077 0.0077
T/K 401.24 401.78 396.72 400.24 408.44 408.63 383.34 388.93 394.62
P/kg.cm−2 1762 1764 1820 1792 1726 1720 1960 1900 1846
wB 0.0077 0.0077 0.0176 0.0176 0.0176 0.0176 0.0176 0.0441 0.0441
T/K 404.07 410.20 378.75 384.49 389.62 402.72 409.77 384.53 389.94
P/kg.cm−2 1770 1722 1994 1928 1874 1760 1708 1890 1834
wB 0.0441 0.0441 0.0493 0.0493 0.0493 0.0493 0.0493 0.0493 0.0493
T/K 390.15 403.20 380.43 383.93 388.98 393.50 400.13 407.90 408.01
P/kg.cm−2 1832 1722 1924 1884 1834 1798 1738 1686 1684
wB 0.0662 0.0662 0.0662 0.0662 0.0662 0.0662 0.0662 0.0662 0.0867
T/K 379.28 383.02 388.42 393.77 394.04 399.87 400.08 409.43 381.67
P/kg.cm−2 1909 1867 1808 1769 1767 1720 1715 1652 1852
wB 0.0867 0.0867 0.0867 0.0867 0.0867 0.1066 0.1066 0.1066 0.1066
T/K 389.65 400.00 404.73 407.37 407.62 378.99 383.99 388.64 393.32
P/kg.cm−2 1781 1695 1661 1644 1642 1850 1804 1759 1720
wB 0.1066 0.1066 0.1066 0.1066 0.1265 0.1265 0.1265 0.1265 0.1265
T/K 398.50 403.10 407.97 411.87 386.94 395.55 402.38 405.69 411.76
P/kg.cm−2 1681 1644 1616 1593 1754 1684 1636 1614 1576
continued
____________________________________________________________________________________
continued
wB 0.1445 0.1445 0.1445 0.1445 0.1445 0.1672 0.1672 0.1672 0.1672
T/K 379.71 382.44 390.82 395.95 409.30 387.92 394.83 398.48 406.71
P/kg.cm−2 1804 1774 1704 1664 1574 1700 1644 1620 1568
wB 0.1890 0.1890 0.1890 0.1890 0.2186 0.2186 0.2186 0.2186 0.2429
T/K 385.99 387.47 398.22 401.02 389.01 389.60 399.42 408.58 384.21
P/kg.cm−2 1692 1680 1600 1584 1632 1630 1566 1514 1624
wB 0.2429 0.2429 0.2429 0.2429 0.2988 0.2988 0.2988 0.2988 0.2988
T/K 391.53 397.50 401.90 409.38 382.49 392.94 398.30 399.85 404.35
P/kg.cm−2 1568 1531 1508 1464 1544 1480 1434 1436 1402
Polymer (B): polyethylene 1972STE

Characterization: LDPE, synthesized by radical polymerization at high pressures
wB 0.168 0.155 0.141 0.071 0.067
T/K 542.15 533.15 523.15 448.15 448.15
P/at 1190 1200 1230 1550 1530
Comments: The initiator was oxygen.
wB 0.046 0.036 0.032 0.030 0.021 0.027 0.120 0.077
T/K 424.15 404.15 394.15 415.15 394.15 384.15 412.15 424.15
P/at 1520 1630 1680 1420 1550 1750 1720 1580
Comments: The initiator was 0.1 wt% peroxide.
wB 0.045 0.040 0.050 0.027 0.039 0.139 0.028 0.043
T/K 422.15 409.15 437.15 414.15 409.15 430.15 408.15 429.15
P/at 1540 1600 1400 1450 1450 1610 1630 1550
Comments: The initiator was 5.0 wt% peroxide.

wB 0.055 0.055 0.055 0.055 0.055
T/K 366.15 389.05 398.35 408.55 423.45
P/bar 455.9 451.6 451.6 451.6 455.9

wB 0.055 0.055 0.055 0.055 0.055
T/K 380.35 381.85 394.55 408.05 422.85
P/bar 527.9 527.4 524.0 524.0 524.0
____________________________________________________________________________________


wB 0.055 0.055 0.055 0.055 0.055 0.055
T/K 377.15 380.15 384.15 393.05 407.85 424.05
P/bar 510.2 510.2 506.8 506.8 506.8 506.8


wB 0.055 0.055 0.055 0.055 0.055
T/K 375.15 380.95 392.55 408.95 424.05
P/bar 499.0 499.9 503.3 503.3 506.8

−1 −1

wB 0.055 0.055 0.055
T/K 380.65 392.45 425.45
P/bar 575.7 575.7 575.7

−1 −1

wB 0.055 0.055 0.055 0.055 0.055
T/K 380.15 385.35 394.55 409.45 424.65
P/bar 551.6 558.5 558.5 551.6 551.6
Polymer (B): polyethylene 1998HAN

Characterization: Mn/kg.mol−1 = 26.75, Mw/kg.mol−1 = 32.1, linear, HDPE,
Tm/K = 407.2, NIST 1483

wB 0.01 0.01 0.01 0.01 0.01
T/K 388.65 398.35 422.05 447.45 471.65
P/bar 571.6 566.7 566.1 560.5 560.8
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1999GOU

Characterization: Mn/kg.mol−1 = 0.2, Sigma Chemical Co., Inc., St. Louis, MO

____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
T/K = 313.15
3.87 0.0818 1.0000
7.75 0.1556 1.0000
9.72 0.1846 1.0000
12.05 0.1983 1.0000
15.83 0.2010 0.9965
18.41 0.2187 0.9834
24.55 0.2299 0.9759
____________________________________________________________________________________
T/K = 333.15
4.26 0.0413 1.0000
7.38 0.1138 1.0000
10.90 0.1488 1.0000
14.37 0.1749 0.9962
17.80 0.1970 0.9895
20.96 0.2115 0.9819
24.45 0.2193 0.9830
____________________________________________________________________________________
T/K = 348.15
5.94 0.0836 1.0000
8.31 0.1056 1.0000
11.27 0.1384 0.9972
14.32 0.1532 0.9991
17.85 0.1748 0.9931
21.38 0.1978 0.9844
24.87 0.2084 0.9852
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1990DAN

continued
____________________________________________________________________________________
continued
________________________________________________________________________________________________________
P/ wA
________________________________________________________________________________________________________
T/K = 313.15
1.41 0.0259 1.0000
3.00 0.0578 1.0000
6.49 0.1402 1.0000
7.94 0.2860 1.0000
9.90 0.3225 0.99763
12.48 0.4023 0.99703
13.92 0.4245 0.99579
17.10 0.4317 0.99476
18.39 0.4338 0.99186
20.41 0.4606 0.98754
22.07 0.5306 0.98672
________________________________________________________________________________________________________
T/K = 323.15
1.92 0.0164 1.0000
4.06 0.0348 1.0000
7.15 0.0707 1.0000
8.31 0.1081 1.0000
12.00 0.2501 0.99759
15.33 0.2781 0.99485
18.35 0.3506 0.99132
20.38 0.3649 0.99114
22.17 0.3658 0.98383
23.27 0.3704 0.98287
26.43 0.3975 0.97875
________________________________________________________________________________________________________

________________________________________________________________________________________________________
P/ wA
________________________________________________________________________________________________________
T/K = 313.15
5.23 0.1423 1.0000
10.62 0.2478 1.0000
16.11 0.2683 0.9933
19.74 0.2862 0.9928
24.01 0.3007 0.9897
________________________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
________________________________________________________________________________________________________
P/ wA
________________________________________________________________________________________________________
T/K = 333.15
5.28 0.0949 1.0000
10.37 0.1801 1.0000
14.98 0.2227 0.9990
20.63 0.2534 0.9961
24.62 0.2616 0.9927
____________________________________________________________________________________
T/K = 348.15
5.89 0.0888 1.0000
11.22 0.1522 1.0000
16.34 0.2078 0.9991
20.80 0.2235 0.9963
24.40 0.2390 0.9929
____________________________________________________________________________________

____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
T/K = 313.15
1.13 0.0183 1.0000
2.37 0.0469 1.0000
3.61 0.0711 1.0000
5.84 0.1251 1.0000
7.13 0.1385 1.0000
8.02 0.2438 1.0000
10.49 0.4147 1.0000
13.68 0.4625 1.0000
14.86 0.5076 0.99892
15.86 0.5437 0.99851
18.80 0.5559 0.99798
20.40 0.5570 0.99746
21.44 0.5720 0.99607
22.75 0.6243 0.99560
25.16 0.6242 0.99445
28.42 0.6139 0.99118
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
________________________________________________________________________________________________________
P/ wA
________________________________________________________________________________________________________
T/K = 323.15
1.99-11.80 up to 0.2156 1.0000
13.88 0.4413 0.99990
16.79 0.4598 0.99980
18.03 0.4840 0.99959
20.36 0.5110 0.99921
22.71 0.5365 0.99873
24.33 0.5360 0.99825
27.45 0.5828 0.99817
29.00 0.5863 0.99757
____________________________________________________________________________________


____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
T/K = 313.15
5.71 0.0958 1.0000
10.16 0.2303 1.0000
15.41 0.2467 1.0000
21.34 0.2739 0.9995
26.34 0.2875 0.9946
____________________________________________________________________________________
T/K = 333.15
5.63 0.0921 1.0000
10.07 0.1789 1.0000
16.37 0.2144 1.0000
21.24 0.2408 0.9991
26.50 0.2671 0.9979
____________________________________________________________________________________
T/K = 348.15
5.63 0.0831 1.0000
10.31 0.1422 1.0000
14.82 0.1803 1.0000
19.13 0.2083 0.9998
24.78 0.2312 0.9993
____________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) 1998ONE

Characterization: Mn/kg.mol−1 = 0.6, Polysciences, Inc., Warrington, PA
T/K = 298.15
wB 0.00296 0.00355 0.00394 0.00610 0.00708 0.00924
P/MPa 13.72 20.55 17.65 25.51 21.77 30.99
T/K = 308.15
wB 0.00296 0.00355 0.00394 0.00610 0.00708 0.00924
P/MPa 17.03 20.89 28.41 33.41
T/K = 313.15
wB 0.00296 0.00355 0.00394 0.00610 0.00708 0.00924
P/MPa 19.93 26.37 22.06 29.58 26.20 33.72
T/K = 318.15
wB 0.00296 0.00355 0.00394 0.00610 0.00708 0.00924
P/MPa 21.51 27.44 30.44 27.51
T/K = 323.15
wB 0.00296 0.00355 0.00394 0.00610 0.00708 0.00924
P/MPa 23.03 28.61 24.61 30.72 28.48 34.68
T/K = 328.15
wB 0.00296 0.00355 0.00394 0.00610 0.00708 0.00924
P/MPa 24.75 31.47 35.34
T/K = 338.15
wB 0.00296 0.00355 0.00394 0.00610 0.00708 0.00924
P/MPa 27.96 28.75 32.89 36.58

Type of data: gas solubilities and cloud points
T/K = 338.15
P/bar 41 54 78 118 157 203 240 271 274
wB 0.910 0.883 0.831 0.800 0.785 0.737 0.702 0.700 0.713
T/K = 353.15
P/bar 45 74 106 138 200 286
wB 0.920 0.857 0.813 0.785 0.735 0.740
T/K = 373.15
P/bar 41 61 79 98 130 162 202 244 270
wB 0.950 0.919 0.892 0.863 0.844 0.821 0.794 0.792 0.755
____________________________________________________________________________________

____________________________________________________________________________________
P/ wA
____________________________________________________________________________________
T/K = 313.15
1.75 0.0386 1.0000
3.59 0.0706 1.0000
5.75 0.1205 1.0000
8.47 0.1752 1.0000
10.20 0.1852 1.0000
11.90 0.2424 1.0000
15.07 0.4583 0.99984
18.01 0.5020 0.99980
19.32 0.4973 0.99975
21.65 0.5388 0.99956
23.01 0.5285 0.99934
24.51 0.5530 0.99928
26.31 0.5779 0.99925
____________________________________________________________________________________

T/K = 328.15
P/bar 43 60 81 138 182 221 260 282
wB 0.902 0.881 0.842 0.795 0.762 0.740 0.729 0.714
T/K = 333.15
P/bar 5 20 34 40 61 80 139 220 286
wB 0.987 0.956 0.938 0.927 0.891 0.853 0.802 0.751 0.734
T/K = 353.15
P/bar 6 16 24 31 44 54 66 79 117
wB 0.989 0.978 0.963 0.958 0.946 0.927 0.911 0.894 0.867
P/bar 140 181 219 265
wB 0.843 0.807 0.785 0.766
T/K = 373.15
P/bar 11 20 32 40 44 53 58 81 101
wB 0.989 0.985 0.968 0.958 0.953 0.946 0.938 0.913 0.898
P/bar 178 220 257
wB 0.841 0.812 0.803
____________________________________________________________________________________


T/K = 353.15
P/bar 40 63 81 98 140 178 218 256
wB 0.947 0.912 0.891 0.874 0.831 0.802 0.783 0.768


T/K = 303.15
P/bar 8 14 14 24 56 74 132 205 246
wB 0.9961 0.9821 0.9817 0.9799 0.9787 0.9793 0.9786 0.9797 0.9792
T/K = 323.15
P/bar 12 14 17 22 33 80 112 200 246
wB 0.9883 0.9856 0.9808 0.9769 0.9768 0.9765 0.9759 0.9755 0.9736
T/K = 373.15
P/bar 15 22 28 34 54 102 157 194 240
wB 0.9929 0.9860 0.9789 0.9699 0.9677 0.9644 0.9622 0.9629 0.9631
T/K = 393.15
P/bar 31 39 51 62 83 120 162 201 241
wB 0.9797 0.9738 0.9670 0.9636 0.9606 0.9576 0.9540 0.9532 0.9528


T/K = 323.15
P/bar 10 20 31 38 49 59 140 160 180
wB 0.9781 0.9570 0.9535 0.9530 0.9530 0.9536 0.9520 0.9520 0.9510
T/K = 353.15
P/bar 10 21 41 50 59 70 90 120 160
wB 0.9842 0.9680 0.9483 0.9454 0.9446 0.9440 0.9440 0.9410 0.9410
T/K = 373.15
continued
____________________________________________________________________________________
continued
P/bar 10 20 30 40 51 61 90 110 170
wB 0.9877 0.9738 0.9620 0.9469 0.9434 0.9428 0.9380 0.9370 0.9310
T/K = 393.15
P/bar 10 21 30 41 50 66
wB 0.9881 0.9770 0.9678 0.9548 0.9479 0.9393


T/K = 333.15
P/bar 20 23 31 50 51 120 160 190 220
wB 0.9577 0.9499 0.9485 0.9470 0.9458 0.944 0.943 0.944 0.942
T/K = 353.15
P/bar 11 21 52 64 120 160 200 200 250
wB 0.9798 0.9625 0.9409 0.9394 0.9390 0.938 0.935 0.935 0.936
T/K = 373.15
P/bar 9 20 30 40 53 90 150 210 250
wB 0.9865 0.9744 0.9603 0.9473 0.9362 0.930 0.927 0.924 0.923
T/K = 393.15
P/bar 11 20 30 40 50 60 70 100 110
wB 0.9899 0.9788 0.9661 0.9563 0.9462 0.9397 0.9350 0.9280 0.9240
P/bar 140 190 250
wB 0.9230 0.9120 0.9060


T/K = 353.15
P/bar 15 27 35 45 80 110 150 190 250
wB 0.9750 0.9512 0.9435 0.9403 0.9360 0.9350 0.9340 0.9290 0.9220
T/K = 373.15
P/bar 12 25 36 47 55 80 130 170 210
wB 0.9815 0.9650 0.9475 0.9376 0.9371 0.9340 0.9260 0.9240 0.9240
P/bar 250
wB 0.9200
continued
____________________________________________________________________________________
continued
T/K = 393.15
P/bar 11 20 30 46 59 68 110 150 200
wB 0.9874 0.9761 0.9632 0.9460 0.9380 0.9329 0.9250 0.9230 0.9130
P/bar 250
wB 0.9090
Polymer (B): poly(ethylene glycol) dimethyl ether 1998ONE


wB 0.00848 0.01390 0.02200 0.03510 0.00848 0.01390 0.02200 0.03510
T/K 298.15 298.15 298.15 298.15 313.15 313.15 313.15 313.15
P/MPa 8.76 9.79 10.48 10.34 13.03 14.75 15.93 15.17
wB 0.00848 0.01390 0.02200 0.03510 0.00848 0.01390 0.02200 0.03510
T/K 323.15 323.15 323.15 323.15 333.15 333.15 333.15 333.15
P/MPa 16.13 17.10 17.37 16.89 18.48 19.86 20.27 19.65
Polymer (B): poly(ethylene glycol) dimethyl ether 1998ONE


wB 0.00431 0.01010 0.01490 0.02390 0.00431 0.01010 0.01490 0.02390
T/K 298.15 298.15 298.15 298.15 303.15 303.15 303.15 303.15
P/MPa 17.03 19.65 21.79 27.30 17.93 21.72 22.41 28.54
wB 0.00431 0.01010 0.01490 0.02390 0.00431 0.01010 0.01490 0.02390
T/K 313.15 313.15 313.15 313.15 323.15 323.15 323.15 323.15
P/MPa 22.20 25.30 26.75 31.72 24.96 28.89 29.23 36.40
wB 0.00431 0.01010 0.01490 0.02390
T/K 333.15 333.15 333.15 333.15
P/MPa 28.75 31.30 32.75 40.27
Polymer (B): poly(ethylene oxide)-b-poly(propylene oxide) 1998ONE

diblock copolymer
Characterization: Mn/kg.mol−1 = 2.0 (= 0.14 + 1.86), 8.6 mol% ethylene oxide,
Jeffamine M2000, hydroxyl terminated EO, NH2 terminated PO

wB 0.001 T/K 308.15 P/MPa 27.58
____________________________________________________________________________________
Polymer (B): poly(ethylene oxide)-b-poly(propylene oxide) 1998ONE

diblock copolymer
Characterization: Mn/kg.mol−1 = 0.6 (= 0.04 + 0.56), 10.0 mol% ethylene oxide,
Jeffamine M600, hydroxyl terminated EO, NH2 terminated PO

wB 0.00785 0.00785 0.00785 0.00785 0.00785
T/K 298.15 308.15 318.15 328.15 338.15
P/MPa 27.37 29.51 29.85 30.34 31.51
Polymer (B): poly(ethylene oxide)-b-poly(propylene oxide)- 1998ONE

Characterization: Mn/kg.mol−1 = 1.05 (= 0.05 + 0.95 + 0.05), 11.8 mol% ethylene oxide,
(1.1/16.5/1.1), Pluronic L31, hydroxyl terminated

T/K = 298.15
wB 0.00278 0.00558 0.00834 0.01110 0.01390 0.01670 0.01950 0.02500 0.03060
P/MPa 10.69 12.27 13.72 16.41 18.89 19.86 20.48 22.41 23.72
T/K = 303.15
wB 0.00278 0.00558 0.00834 0.01110 0.01390 0.01670 0.01950 0.02500 0.03060
P/MPa 12.13 14.55 15.31 18.06 19.99 20.96 22.55 24.06 25.17
T/K = 313.15
wB 0.00278 0.00558 0.00834 0.01110 0.01390 0.01670 0.01950 0.02500 0.03060
P/MPa 16.55 17.51 18.75 21.93 23.92 23.58 25.44 27.03 28.27
T/K = 323.15
wB 0.00278 0.00558 0.00834 0.01110 0.01390 0.01670 0.01950 0.02500 0.03060
P/MPa 19.99 21.61 22.61 24.89 26.13 27.23 28.61 29.65 30.89
T/K = 333.15
wB 0.00278 0.00558 0.00834 0.01110 0.01390 0.01670 0.01950 0.02500 0.03060
P/MPa 22.75 25.23 26.75 27.85 29.72 30.34 31.03 32.13 33.65
T/K = 338.15
wB 0.00278 0.00558 0.00834 0.01110 0.01390 0.01670 0.01950 0.02500 0.03060
P/MPa 23.65 27.85 29.37 30.82 31.58 32.34 33.44
____________________________________________________________________________________


wB 0.00123 0.00123 0.00123 0.00123 0.00123 0.00123
T/K 298.15 303.15 313.15 323.15 333.15 338.15
P/MPa 19.65 21.17 24.27 29.30 33.03 33.78


T/K = 298.15
wB 0.00278 0.00558 0.00834 0.01110 0.01340
P/MPa 16.62 20.13 25.37 27.58 30.82
T/K = 303.15
wB 0.00278 0.00558 0.00834 0.01110 0.01340
P/MPa 16.96 21.72 26.34 28.96 31.37
T/K = 313.15
wB 0.00278 0.00558 0.00834 0.01110 0.01340
P/MPa 20.62 26.13 27.65 31.51 33.44
T/K = 323.15
wB 0.00278 0.00558 0.00834 0.01110 0.01340
P/MPa 23.30 27.99 30.61 34.13 35.51
T/K = 333.15
wB 0.00278 0.00558 0.00834 0.01110 0.01340
P/MPa 25.92 32.13 34.75 36.34 37.85
T/K = 338.15
wB 0.00278 0.00558 0.00834 0.01110 0.01340
P/MPa 27.51 32.54 35.44 37.16 39.09
____________________________________________________________________________________


wB 0.00207 0.00207 0.00207 0.00207 0.00207 0.00207
T/K 298.15 303.15 313.15 323.15 333.15 338.15
P/MPa 28.61 29.51 31.03 35.23 38.27 33.78

Characterization: Mn/kg.mol−1 = 3.75 (= 0.375 + 3.0 + 0.375), 24.8 mol% ethylene
oxide, (8.5/51.6/8.5), Pluronic L92, hydroxyl terminated

wB 0.00207 0.00207 0.00207
T/K 298.15 303.15 318.15
P/MPa 30.33 32.33 36.20


wB 0.0028 0.003
T/K 298.15 308.15
P/MPa 25.51 27.58
Polymer (B): poly(fluoroalkoxyphosphazene) 1998ONE

Characterization: molar mass unknown, EYPEL-F gum

wB 0.00386 0.00930 0.02080 0.04010 0.00386 0.00930 0.02080 0.04010
T/K 298.15 298.15 298.15 298.15 308.15 308.15 308.15 308.15
P/MPa 15.17 15.44 15.58 15.10 9.37 19.93 19.86 19.44
wB 0.00386 0.00930 0.02080 0.04010 0.00386 0.00930 0.02080 0.04010
T/K 323.15 323.15 323.15 323.15 338.15 338.15 338.15 338.15
P/MPa 25.51 25.58 25.86 25.44 30.27 30.82 31.10 30.82
____________________________________________________________________________________
Polymer (B): poly(hexyl acrylate) 2004BYU

Characterization: Mw/kg.mol−1 = 90,

T/K 398.45 399.35 403.45 405.65 414.85 435.05
P/bar 2553.4 1932.8 1743.1 1598.3 1450.0 1186.2
Polymer (B): poly(hexyl methacrylate) 2004BYU

−1

T/K 429.85 431.45 433.35 437.75 446.05 467.95 472.05
P/bar 2208.6 2070.7 1953.4 1805.2 1683.1 1462.1 1424.1
Polymer (B): β -hydroxybutyrate)

poly(β 2003KHO
Type of data: polymer solubility

T/K = 308.15
P/bar 122 152 182 213 243 274 304 334 355
−3
ρA/g.dm 771 818 850 876 897 916 931 946 955
cB/g.dm−3 0.54 0.68 1.07 1.13 1.46 1.58 1.86 1.96 2.41
T/K = 318.15
P/bar 122 152 182 213 243 274 304 334 355
ρA/g.dm−3 661 745 792 826 852 875 893 910 919
cB/g.dm−3 0.31 0.58 1.06 1.37 1.67 1.98 2.11 2.43 2.65
T/K = 328.15
P/bar 122 152 182 213 243 274 304 334 355
ρA/g.dm−3 504 657 726 771 804 831 853 872 884
cB/g.dm−3 0.23 0.59 1.05 1.44 1.79 2.38 2.69 2.98 3.49
T/K = 338.15
P/bar 122 152 182 213 243 274 304 334 355
ρA/g.dm−3 398 561 654 712 754 786 812 834 848
cB/g.dm−3 0.18 0.43 1.01 1.43 2.23 2.78 3.18 3.69 4.77
continued
____________________________________________________________________________________
continued
T/K = 348.15
P/bar 122 152 182 213 243 274 304 334 355
ρA/g.dm−3 327 477 585 652 702 740 772 796 811
cB/g.dm−3 0.15 0.29 0.69 1.49 2.65 3.65 4.71 5.33 8.01
Polymer (B): polyisobutylene 1994GR1, 1994GR4

−1 −1
synthesized in the laboratory by living carbocationic polymerization

T/K 459.25 459.05 456.85 423.15 418.95 413.25 407.45 398.25 390.15
P/bar 812.5 826.9 823.4 839.0 870.7 891.0 1009.0 1122.8 1343.1
T/K 386.45 383.95
P/bar 1680.2 1903.9
Polymer (B): polyisobutylene (monohydroxy) 1994GR1, 1994GR4

−1 −1

T/K 448.15 438.15 433.15 428.15 423.15 413.15
P/bar 909.7 986.1 1044.0 1127.4 1190.0 1502.6
Polymer (B): polyisobutylene (dihydroxy) 1994GR1, 1994GR4


T/K 423.15 418.15 413.15 407.45 400.45 398.15 388.15 386.15 385.15
P/bar 855.9 868.1 884.4 943.6 999.3 1028.2 1190.7 1232.1 1265.3
T/K 384.25 383.15 382.15
P/bar 1290.8 1323.3 1379.3
____________________________________________________________________________________

wB 0.0348 0.0348 0.0348 0.0400 0.0400 0.0458 0.0458 0.0458 0.0458
T/K 398.15 373.15 348.15 398.15 348.15 473.15 448.15 398.15 393.15
P/bar 242.7 236.2 267.7 243.7 287.1 318.1 295.2 251.2 247.3
wB 0.0458 0.0458 0.0458 0.0458 0.0458 0.0459 0.0459 0.0459 0.0459
T/K 388.15 383.15 378.15 369.65 363.15 423.15 398.15 358.15 353.15
P/bar 245.8 243.1 243.2 243.1 252.2 268.5 250.4 262.0 279.1
wB 0.0459 0.0459 0.0459 0.0459
T/K 348.15 343.15 335.65 333.15
P/bar 294.4 327.0 388.0 416.1

wB 0.0414 0.0414 0.0414 0.0414 0.0414 0.0414 0.0414 0.0414 0.0414
T/K 398.15 393.15 388.15 383.15 378.15 373.15 368.15 363.15 358.15
P/bar 306.7 309.4 310.9 314.5 317.8 321.7 328.2 336.2 345.2
wB 0.0414 0.0414 0.0414 0.0414 0.0441 0.0441 0.0441 0.0441 0.0441
T/K 353.15 348.15 342.45 338.15 448.05 423.15 398.15 393.15 388.15
P/bar 364.1 391.1 430.7 470.4 332.1 304.7 300.0 300.2 303.7
wB 0.0441
T/K 383.15
P/bar 308.1

wB 0.0449 0.0449 0.0449 0.0449 0.0458 0.0458 0.0458 0.0458 0.0458
T/K 472.65 448.15 423.15 398.15 393.15 388.15 383.15 373.15 368.15
P/bar 324.4 305.7 283.4 261.6 256.3 252.7 249.2 244.6 243.7
wB 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458 0.0458
T/K 363.15 358.15 353.15 348.15 343.15 338.15 333.15 328.15 323.15
P/bar 243.0 244.4 248.5 254.5 264.5 279.6 302.7 338.0 386.8
continued
____________________________________________________________________________________
continued
wB 0.0462 0.0462 0.0462 0.0462 0.0462
T/K 393.15 387.75 383.15 373.15 348.25
P/bar 257.1 252.9 249.2 243.5 249.5

−1 −1
Characterization: Mn/kg.mol = 3.7, Mw/kg.mol = 4.1 (1.37 per arm),

T/K 448.65 433.15 423.15 413.25 403.15 401.15 399.15 397.15 395.05
P/bar 575.2 619.4 656.0 727.6 825.3 860.7 900.5 937.4 985.1
T/K 393.15 390.25 389.15 388.15
P/bar 1044.7 1139.2 1178.7 1233.2


wB 0.0552 0.0552 0.0552 0.0552 0.0552 0.0552 0.0754 0.0754 0.0754
T/K 465.15 461.45 448.15 408.15 390.15 390.15 423.15 397.75 388.35
P/bar 165.1 158.8 141.8 80.1 44.4 43.5 104.4 62.2 43.3
wB 0.0754 0.0754
T/K 387.55 293.35
P/bar 42.7 5.7
lower critical end point: wB = 0.0552, T/K = 390.15, P/bar = 43.5

−1 −1

T/K 423.15 412.25 401.45 394.05 383.15 373.15 368.45 363.15 358.15
P/bar 404.0 403.8 401.6 397.5 405.4 429.9 442.2 461.6 488.6
T/K 352.25 348.15 347.85 344.85 343.35
P/bar 523.0 557.2 557.0 584.9 605.4
____________________________________________________________________________________


T/K 423.15 413.15 403.15 386.15 378.15 371.85 371.65 348.15 323.15
P/bar 145.0 133.4 119.8 94.1 74.0 57.7 57.6 27.3 12.7

−1 −1

T/K 423.15 403.15 393.15 383.15 374.65 373.15 363.15 354.75 353.05
P/bar 354.4 348.4 345.3 345.9 351.7 351.1 364.2 385.0 393.8
T/K 348.15 343.15 339.15 334.35 332.35 333.15 328.15 323.15 320.65
P/bar 414.6 442.3 477.4 530.8 559.3 554.9 646.8 794.0 904.7


T/K 472.75 448.05 423.15 408.15 378.15 388.15 388.15 363.25 333.25
P/bar 183.5 150.4 110.4 88.1 66.7 43.2 42.2 22.4 14.5
T/K 328.15 293.45
P/bar 11.2 5.5


continued
____________________________________________________________________________________
continued
T/K 423.65 413.15 403.15 393.15 383.15 373.15 363.15 353.15 343.15
P/bar 376.9 373.7 367.9 366.0 366.0 375.8 389.2 420.9 466.8
T/K 333.05 328.15 323.15 320.55
P/bar 566.7 654.1 794.5 913.2

Characterization: Mn/kg.mol−1 = 3.7, Mw/kg.mol−1 = 4.1 (1.37 per arm),

T/K 423.65 409.85 403.15 391.95 383.15 372.65 367.15 351.15 343.15
P/bar 212.0 192.0 181.1 161.9 147.0 129.4 120.4 93.4 89.1
T/K 332.55 328.65 322.75 312.15 309.15 303.25 297.35 292.85 288.05
P/bar 79.5 77.1 75.7 84.3 91.1 117.1 148.9 191.8 261.1
T/K 283.15 282.85 282.15 280.95 280.55 280.45 280.25 279.25
P/bar 387.2 421.7 456.3 506.9 529.8 545.9 592.9 652.0


T/K 423.15 418.15 408.15 391.15 387.65 382.85 377.45 373.15 367.15
P/bar 389.2 385.5 378.3 366.5 363.2 357.6 353.5 348.0 341.0
T/K 358.15 348.15 338.15 327.15 323.45 293.85 292.85
P/bar 328.7 313.4 300.8 283.6 275.9 229.9 37.7


T/K 423.15 403.15 394.05 377.15 352.25 347.35 337.05 317.35 307.55
P/bar 1009.8 1014.9 1022.8 1028.0 1039.9 1046.2 1051.4 1085.6 1125.6
T/K 298.15
P/bar 1180.0
____________________________________________________________________________________


wB 0.1061 0.1061 0.1061 0.1061 0.1061 0.1061 0.1061 0.1061 0.1061
T/K 423.05 413.15 407.65 403.15 397.65 393.15 383.05 363.05 353.15
P/bar 451.3 449.0 444.6 440.0 427.4 433.8 432.0 419.6 417.7
wB 0.1061 0.1344 0.1344 0.1344 0.1344 0.1344 0.1344 0.1344 0.1344
T/K 340.55 423.15 413.15 406.25 401.35 397.85 393.15 388.15 382.95
P/bar 407.8 451.2 451.5 447.1 442.0 440.0 436.4 432.6 429.1
wB 0.1344 0.1344 0.1344 0.1344
T/K 372.15 358.65 340.95 321.55
P/bar 431.5 430.4 415.4 412.2


T/K 423.15 393.15 383.15 353.15 333.15 323.15 308.15
P/bar 983.8 1015.0 1036.7 1066.1 1111.1 1147.3 1205.4

−1 −1

wB 0.1039 0.1039 0.1039 0.1039 0.1039 0.1039 0.1039 0.1039 0.1039
T/K 423.15 417.65 413.15 403.15 393.15 389.65 383.15 377.15 373.15
P/bar 464.7 465.1 465.0 465.6 467.0 468.0 470.9 475.3 479.1
wB 0.1039 0.1039 0.1039 0.1039 0.1039 0.1039 0.1039 0.2437 0.2437
T/K 368.15 363.15 358.15 353.15 348.15 346.25 343.15 448.15 443.15
P/bar 485.5 493.7 505.0 519.4 538.2 546.3 562.2 521.6 521.6
____________________________________________________________________________________


T/K 423.15 403.15 383.95 353.25 333.15
P/bar 985.8 1006.0 1018.0 1038.3 1092.7

−1 −1

T/K 423.05 403.15 392.35 383.55 371.65 363.25 362.55 353.05 343.15
P/bar 656.4 650.4 646.4 642.3 636.6 633.4 632.7 631.3 627.0
T/K 333.65 323.65 313.65 307.65 304.85 298.25 277.65 269.65 266.65
P/bar 621.4 617.9 613.5 611.8 610.2 608.8 605.9 606.5 607.3
T/K 258.65 252.65 243.05 237.95 234.45
P/bar 609.8 613.0 621.3 628.0 631.6
Polymer (B): polyisobutylene 1999CHE


T/K 447.45 435.35 422.25 409.45 399.75 386.05 374.85 358.25 346.85
P/bar 249.2 277.0 269.5 244.4 240.4 227.7 215.6 195.2 175.7
T/K 332.15 323.45 312.85 302.75 295.25
P/bar 167.8 156.8 143.1 119.1 110.5
T/K 429.35 413.55 408.15 398.95 381.55 366.25 351.75 339.25 325.85
P/bar 352.2 338.7 332.4 321.5 302.8 275.3 256.3 237.7 215.0
T/K 315.95 293.05 271.25 253.55 239.75 229.95
P/bar 194.7 165.2 122.3 86.6 62.0 60.2
____________________________________________________________________________________


wB 0.0636 0.0617 0.0636 0.0713 0.0713 0.0713 0.0636 0.0713
T/K 423.15 398.15 373.15 373.15 347.65 328.35 293.35 293.15
P/bar 151.5 118.5 72.1 76.9 26.1 19.7 8.3 8.3

−1 −1

T/K 423.65 398.15 373.15 368.15 362.65 353.15 328.15 323.15 317.05
P/bar 270.8 239.6 202.2 194.2 185.2 171.9 124.4 112.5 99.4
T/K 312.15 308.15 298.25 293.15 291.15 288.15 281.45
P/bar 89.6 79.0 56.7 46.1 41.6 33.7 17.2

−1 −1

T/K 423.15 398.15 373.45 372.55 348.65 337.05 323.05 312.75 303.15
P/bar 419.5 395.8 366.5 365.9 335.7 314.3 294.2 278.6 259.1
T/K 302.55
P/bar 10.4


continued
____________________________________________________________________________________
continued
wB 0.0732 0.0727 0.0697 0.0723 0.0717 0.0697 0.0697
T/K 423.15 398.15 373.15 348.15 328.35 325.05 295.35
P/bar 175.0 142.5 108.6 69.8 35.6 19.7 8.7


T/K 423.15 397.95 387.95 382.15 373.25 348.05 323.15 321.35
P/bar 413.3 388.1 376.7 369.6 358.5 328.8 291.0 16.4


wB 0.0688 0.0688 0.0688 0.0688 0.0688 0.0688 0.0688 0.0688
T/K 423.15 373.15 341.95 325.65 321.95 310.65 298.15 294.05
P/bar 193.0 136.3 115.1 105.0 114.8 160.8 208.1 214.2


T/K 423.15 418.15 413.15 402.85 391.85 380.55 360.15 352.85 342.85
P/bar 438.0 430.0 425.3 416.2 404.7 392.6 366.4 357.9 344.9
T/K 332.85 322.75 310.25 307.25
P/bar 322.4 318.1 296.3 295.6
Polymer (B): polyisoprene 1996ALB

continued
____________________________________________________________________________________
continued
T/K 424.25 422.25 410.75 383.75 382.65 363.25 348.25 347.95 332.75
P/bar 210.1 206.0 185.6 133.5 131.5 89.9 55.3 54.5 13.4


T/K 423.05 412.95 411.95 390.45 390.35 362.35 339.55 336.55 333.65
P/bar 787.5 783.1 799.2 811.3 815.3 846.6 932.3 964.9 985.1
T/K 333.25
P/bar 993.2


T/K 424.45 423.55 399.45 393.15 389.75 389.45 388.15 388.05
P/bar 972.3 972.8 998.0 1002.5 1003.6 1011.1 1018.5 1023.3


T/K 423.15 390.05 389.35 363.35 348.25 336.45 336.15 326.25 324.85
P/bar 324.65
T/K 383.7 375.3 376.0 377.1 387.0 420.7 416.6 455.5 467.3
P/bar 467.5
____________________________________________________________________________________


T/K 423.35 390.75 363.05 362.85 336.55 323.25 309.75 299.05 292.05
P/bar 338.1 301.6 265.5 261.4 221.0 202.4 185.6 176.2 172.5
T/K 284.05 283.65 280.95
P/bar 175.3 173.9 174.8
Polymer (B): polyisoprene (hydrogenated) 1997HAN

−1 −1
Characterization: Mn/kg.mol = 2.4, Mw/kg.mol = 2.6, 38% hydrogenation,
Tg/K = 208.2, synthesized in the laboratory

wB 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.008 0.113
T/K 305.65 315.25 336.75 357.75 376.65 401.35 423.95 421.95 422.15
P/bar 14.2 40.4 91.7 134.7 169.3 208.2 238.4 156.8 230.4
wB 0.289 0.360 0.477 0.623
T/K 423.05 422.35 423.25 422.95
P/bar 233.3 220.1 215.6 170.3

T/K = 422.75
____________________________________________________________________________________
P/ wB
____________________________________________________________________________________
180 0.289 0.571 0.016
150 0.360 0.656 0.007
____________________________________________________________________________________
Polymer (B): poly(DL-lactide) 1996KIM

Characterization: Mη /kg.mol−1 = 2.0, Boehringer Ingelheim Co., Germany
Type of data: polymer solubility/cloud points

T/K = 333.15
P/bar 137.9 151.7 165.5 179.3 193.1
wB 0.000018 0.000029 0.000040 0.000072 0.000118
____________________________________________________________________________________
Polymer (B): poly(L-lactide) 1991TOM

L104, Boehringer Ingelheim Chemicals

T/K = 318.15
P/bar 200 250 300
wB 0.000128 0.000200 0.000427
T/K = 328.15
P/bar 200 250 300
wB 0.000241 0.000260 0.000535
T/K = 338.15
P/bar 200 250 300
wB 0.000280 0.000477 0.000738
Polymer (B): poly(DL-lactide) 2001CON

Characterization: Mn/kg.mol−1 = 60.6, Mw/kg.mol−1 = 84.5, Tg/K = 323.05

wB 0.05 0.05 0.05 0.05 0.05
T/K 317.55 329.65 336.85 349.45 363.75
P/bar 1312 1323 1332 1345 1360
ρ/(g/cm3) 1.213 1.193 1.182 1.161 1.137


wB 0.05 0.05 0.05 0.05 0.05
T/K 305.85 314.35 329.35 345.75 365.85
P/bar 1389 1398 1408 1418 1429
ρ/(g/cm3) 1.192 1.179 1.154 1.130 1.099
Polymer (B): poly(DL-lactide) 2002KUK

Characterization: Mη /kg.mol−1 = 2.0, Resomer R104, Boehringer Ingelheim Chemicals
wB 0.0274 0.0274 0.0274 0.0274 0.0274
T/K 342.85 353.15 362.35 372.95 383.05
P/MPa 3.61 6.43 8.89 11.50 13.84
____________________________________________________________________________________
Polymer (B): poly(DL-lactide) 2000LE1

wB 0.0568 0.0568 0.0568 0.0568 0.0568 0.0568
T/K 346.95 355.15 364.75 373.05 382.45 392.75
P/MPa 4.25 6.40 8.85 11.05 13.43 15.72
Polymer (B): poly(L-lactide) 2000LE1

Characterization: Mη /kg.mol−1 = 2.0, Polysciences, Inc., Warrington, PA
wB 0.0009 0.0009 0.0009 0.0009 0.0009 0.0009 0.0106 0.0106 0.0106
T/K 346.95 354.65 364.55 373.35 383.75 393.55 344.35 353.55 363.45
P/MPa 3.85 6.05 8.65 10.80 13.45 15.20 3.35 5.80 8.55
wB 0.0106 0.0106 0.0106 0.0288 0.0288 0.0288 0.0288 0.0288 0.0288
T/K 373.45 383.55 392.85 344.35 353.05 363.35 372.75 382.05 392.75
P/MPa 11.05 13.25 15.20 3.60 5.95 8.72 10.90 13.05 15.62
wB 0.0371 0.0371 0.0371 0.0371 0.0371 0.0371 0.0577 0.0577 0.0577
T/K 345.85 352.85 363.35 372.85 382.95 392.45 347.35 353.75 363.25
P/MPa 4.10 5.96 8.66 11.00 13.35 15.42 4.55 6.23 8.85
wB 0.0577 0.0577 0.0577 0.1029 0.1029 0.1029 0.1029 0.1029 0.1391
T/K 373.95 383.15 392.75 352.65 362.95 372.05 383.05 393.65 345.35
P/MPa 11.30 13.50 15.85 6.20 8.95 11.05 13.50 15.70 3.68
wB 0.1391 0.1391 0.1391 0.1391 0.1391 0.1798 0.1798 0.1798 0.1798
T/K 355.85 364.55 373.95 383.65 393.95 346.55 355.25 366.45 374.55
P/MPa 6.60 8.94 11.25 13.53 15.87 3.40 5.77 8.87 10.95
wB 0.1798 0.1798
T/K 383.05 393.35
P/MPa 12.93 15.22

Characterization: Mη /kg.mol−1 = 30, Resomer R203, Boehringer Ingelheim Chemicals
wB 0.0050 0.0050 0.0050 0.0050 0.0050 0.0287 0.0287 0.0287 0.0287
T/K 343.05 352.85 362.85 373.05 382.55 338.25 343.65 352.75 362.75
P/MPa 4.23 7.13 9.81 12.45 14.85 3.35 5.03 7.71 10.55
wB 0.0287 0.0287 0.0477 0.0477 0.0477 0.0477 0.0477 0.0477 0.0784
T/K 372.95 382.75 338.15 343.25 352.95 362.85 372.95 382.25 338.15
P/MPa 13.13 15.55 3.25 4.81 7.68 10.53 13.25 15.63 3.09
continued
____________________________________________________________________________________
continued
wB 0.0784 0.0784 0.0784 0.0784 0.0784 0.1468 0.1468 0.1468 0.1468
T/K 342.75 352.85 363.35 372.85 382.05 339.95 343.25 352.85 363.35
P/MPa 4.50 7.45 10.55 13.17 15.45 3.26 4.29 7.20 10.25
wB 0.1468 0.1468
T/K 373.15 382.75
P/MPa 12.84 15.30

Characterization: Mη /kg.mol−1 = 50, Polysciences, Inc., Warrington, PA

wB 0.0359 0.0359 0.0359 0.0359 0.0359 0.0359 0.0359
T/K 334.85 339.45 353.25 362.35 372.05 382.45 392.05
P/MPa 3.25 4.78 9.10 11.90 14.68 17.48 20.00


wB 0.05 0.05 0.05 0.05
T/K 323.45 328.15 333.65 345.05
P/bar 20.3 36.9 58.3 99.3
ρ/(g/cm3) 1.106 1.101 1.096 1.084


wB 0.0382 0.0382 0.0382 0.0382 0.0382 0.0382 0.0382
T/K 333.55 342.95 353.45 362.15 372.25 383.35 392.55
P/MPa 3.15 6.25 9.55 12.13 15.00 18.00 20.25


wB 0.0568 0.0568 0.0568 0.0568
T/K 344.55 343.25 363.05 384.05
P/MPa 4.55 7.15 13.46 19.50
____________________________________________________________________________________

Solvent (A): difluoromethane CH2F2 75-10-5

wB 0.0322 0.0322 0.0322 0.0322 0.0322 0.0322 0.0322 0.0322
T/K 304.45 315.55 322.75 333.25 342.95 353.15 362.85 372.75
P/MPa 33.00 33.00 33.45 34.55 36.00 37.65 39.25 40.90

Solvent (A): difluoromethane CH2F2 75-10-5

wB 0.0047 0.0047 0.0047 0.0047 0.0047 0.0047 0.0047 0.0047 0.0164
T/K 305.05 311.95 323.85 333.75 343.55 352.85 362.95 372.95 303.55
P/MPa 49.65 48.25 47.35 48.05 48.55 49.25 49.95 50.75 54.75
wB 0.0164 0.0164 0.0164 0.0164 0.0164 0.0164 0.0164 0.0278 0.0278
T/K 313.15 323.25 333.55 342.65 353.15 363.05 372.95 304.85 313.55
P/MPa 52.55 51.65 51.55 52.05 52.95 53.85 54.75 55.05 53.15
wB 0.0278 0.0278 0.0278 0.0278 0.0278 0.0278 0.0480 0.0480 0.0480
T/K 323.85 334.45 343.35 352.95 363.45 373.05 304.15 313.25 323.75
P/MPa 52.05 52.15 52.55 53.45 54.55 55.45 55.55 53.05 52.05
wB 0.0480 0.0480 0.0480 0.0480 0.0480 0.0908 0.0908 0.0908 0.0908
T/K 333.95 343.35 353.35 363.05 373.05 304.35 312.85 323.15 334.75
P/MPa 52.05 52.55 53.55 54.45 55.35 52.85 50.85 50.05 50.25
wB 0.0908 0.0908 0.0908 0.0908 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 342.85 352.85 363.35 375.55 303.45 313.45 323.15 333.45 342.85
P/MPa 50.75 51.65 52.85 54.25 49.35 47.65 47.25 47.75 48.55
wB 0.1500 0.1500 0.1500
T/K 352.85 362.95 372.75
P/MPa 49.65 50.95 52.15

−1
Characterization: Mη /kg.mol = 2.0, Resomer R104, Boehringer Ingelheim Chemicals

wB 0.0297 0.0297 0.0297 0.0297
T/K 358.35 363.15 367.75 375.15
P/MPa 4.25 5.50 6.35 8.10
____________________________________________________________________________________


wB 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0291 0.0291 0.0291
T/K 333.25 338.75 343.15 352.65 363.85 372.45 328.55 333.15 343.75
P/MPa 1.65 3.05 4.25 6.85 9.65 11.75 2.19 3.42 6.29
wB 0.0291 0.0291 0.0291 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500
T/K 352.75 362.85 373.35 328.65 333.05 343.05 354.15 363.35 372.95
P/MPa 8.53 11.04 13.45 2.47 3.75 6.55 9.27 11.45 13.73
wB 0.0799 0.0799 0.0799 0.0799 0.0799 0.0799 0.1467 0.1467 0.1467
T/K 327.15 333.55 343.95 352.95 363.15 373.25 329.25 332.95 343.55
P/MPa 1.70 3.65 6.65 8.93 11.60 13.83 1.70 2.80 5.90
wB 0.1467 0.1467 0.1467
T/K 353.05 363.05 372.45
P/MPa 8.50 11.01 13.23

−1

wB 0.0292 0.0292 0.0292 0.0292 0.0292 0.0292 0.0292 0.0292
T/K 306.75 315.05 325.05 334.65 346.15 353.65 363.85 373.45
P/MPa 19.18 20.43 21.95 23.65 25.60 26.90 28.50 30.05

−1
Characterization: Mη /kg.mol = 30, Resomer R203, Boehringer Ingelheim Chemicals

wB 0.0054 0.0054 0.0054 0.0054 0.0054 0.0054 0.0054 0.0054 0.0304
T/K 302.95 313.45 324.25 333.85 343.15 352.85 362.75 372.95 304.05
P/MPa 21.75 24.45 26.95 29.35 31.55 33.35 34.95 36.85 24.95
wB 0.0304 0.0304 0.0304 0.0304 0.0304 0.0304 0.0304 0.0526 0.0526
T/K 314.75 323.75 333.25 343.15 353.25 363.35 372.95 303.65 313.25
P/MPa 27.37 29.55 31.75 34.03 36.15 38.38 40.15 25.24 27.30
wB 0.0526 0.0526 0.0526 0.0526 0.0526 0.0526 0.0855 0.0855 0.0855
T/K 323.85 333.35 342.95 352.85 363.05 373.05 304.95 313.35 323.75
P/MPa 29.70 31.95 34.15 36.25 38.35 40.12 23.85 25.80 28.23
wB 0.0855 0.0855 0.0855 0.0855 0.0855 0.1505 0.1505 0.1505 0.1505
T/K 333.35 343.35 352.75 363.15 373.05 303.75 313.85 323.85 333.45
P/MPa 30.50 32.85 34.95 37.09 38.91 21.63 24.25 26.81 29.13
continued
____________________________________________________________________________________
continued
wB 0.1505 0.1505 0.1505 0.1505
T/K 343.15 352.95 363.25 373.25
P/MPa 31.41 33.60 35.71 37.60

−1

wB 0.0306 0.0306 0.0306 0.0306 0.0306 0.0306 0.0306 0.0306
T/K 306.05 313.25 323.35 332.75 342.65 352.55 363.05 373.85
P/MPa 46.05 48.75 52.35 55.75 59.05 62.05 64.85 67.35

−1

wB 0.0055 0.0055 0.0055 0.0055 0.0055 0.0055 0.0055 0.0055 0.0310
T/K 303.75 313.25 323.65 333.15 342.85 353.15 363.25 372.85 303.95
P/MPa 49.05 53.75 58.25 63.25 67.45 71.85 75.35 78.25 53.75
wB 0.0310 0.0310 0.0310 0.0310 0.0310 0.0310 0.0310 0.0793 0.0793
T/K 313.25 323.25 333.15 343.15 353.55 363.35 372.85 304.05 313.25
P/MPa 58.55 63.35 67.95 72.35 76.55 80.25 83.45 55.45 60.05
wB 0.0793 0.0793 0.0793 0.0793 0.0793 0.0793 0.1317 0.1317 0.1317
T/K 323.55 333.35 343.55 353.25 363.15 373.35 303.65 313.55 323.75
P/MPa 64.95 69.45 73.95 77.75 81.35 84.75 54.15 59.15 64.05
wB 0.1317 0.1317 0.1317 0.1317 0.1317
T/K 333.15 343.45 353.05 363.15 372.95
P/MPa 68.25 72.65 76.55 80.15 83.45


wB 0.05 0.05 0.05 0.05 0.05
T/K 300.55 306.35 317.25 330.95 344.15
P/bar 543 575 633 705 767
ρ/(g/cm3) 1.334 1.332 1.321 1.311 1.302
____________________________________________________________________________________
Polymer (B): poly(methyl acrylate) 2004BEC


T/K 473.15 480.15 481.15 482.15 483.15 491.15 493.75 501.15 510.15
P/bar 2750 2465 2418 2391 2361 2109 2018 1850 1691
T/K 512.75 521.95 523.45 525.45 526.45 531.65
P/bar 1641 1513 1487 1465 1457 1399
Polymer (B): poly(methyl methacrylate) 1993HA4

Characterization: Mn/kg.mol−1 = 70, Mw/kg.mol−1 = 74, 57% syndiotactic, 6% isotactic,
37% atactic triads, Tg/K = 398, synthesized in the laboratory via group
transfer polymerization by S. Smith, Procter & Gamble Co.

Comments: 65 < (T/K − 273.15) < 150.
wB = 0.00030 P/MPa = −20.369 + 0.37989 (T/K − 273.15) − 4.2093 10−4 (T/K − 273.15)2
wB = 0.00311 P/MPa = −21.274 + 0.41400 (T/K − 273.15) − 5.4051 10−4 (T/K − 273.15)2
wB = 0.00983 P/MPa = −22.489 + 0.44372 (T/K − 273.15) − 6.4710 10−4 (T/K − 273.15)2
wB = 0.0311 P/MPa = −20.804 + 0.41613 (T/K − 273.15) − 5.0146 10−4 (T/K − 273.15)2
wB = 0.0507 P/MPa = −22.873 + 0.46489 (T/K − 273.15) − 7.6064 10−4 (T/K − 273.15)2
wB = 0.0826 P/MPa = −21.010 + 0.41800 (T/K − 273.15) − 4.9133 10−4 (T/K − 273.15)2
wB = 0.1542 P/MPa = −24.096 + 0.45924 (T/K − 273.15) − 6.8208 10−4 (T/K − 273.15)2
Polymer (B): poly(methyl methacrylate) 2004BEC


T/K 427.15 433.15 433.65 443.35 444.15 453.15 461.15 462.15 462.65
P/bar 2700 2379 2356 2060 2027 1891 1739 1728 1712
T/K 471.15 471.85 472.35 481.15 490.65 502.15 511.15 523.15 532.15
P/bar 1577 1573 1563 1458 1364 1265 1204 1122 1078
____________________________________________________________________________________
Polymer (B): poly(octadecyl acrylate) 2002BYU

Characterization: Mw/kg.mol−1 = 93.3, Tg/K = 313,
T/K 314.45 324.25 342.05 364.55 383.85 402.65 423.95
P/bar 750.0 739.7 730.7 726.6 723.8 724.5 725.9
Polymer (B): poly(propyl acrylate) 2004BEC

T/K 352.95 363.25 373.25 393.15 412.15 432.15 452.15 472.15 491.15
P/bar 1093 1059 1033 992 961 936 914 892 881
T/K 511.15 531.15
P/bar 877 874

92 % isotactic, Polibrasil Resinas S.A.
wB 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030
T/K 423.15 413.15 413.15 403.15 403.15 393.15 393.15 383.15 383.15
P/bar 106.3 88.6 33.5 69.8 28.5 51.6 24.4 31.7 21.1
LLE LLE VLLE LLE VLLE LLE VLLE LLE VLLE
wB 0.0030 0.0030 0.0030 0.0030 0.0069 0.0069 0.0069 0.0069 0.0069
T/K 373.15 368.15 363.15 358.15 423.15 413.15 413.15 403.15 403.15
P/bar 16.7 15.2 13.9 12.4 112.4 95.0 33.6 77.4 28.4
VLE VLE VLE VLE LLE LLE VLLE LLE VLLE
wB 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069 0.0069
T/K 393.15 393.15 383.15 383.15 373.15 373.15 368.15 363.15 358.15
P/bar 58.4 24.6 38.9 21.1 21.5 17.0 16.0 15.0 13.6
LLE VLLE LLE VLLE LLE VLLE VLE VLE VLSE
wB 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100
T/K 423.15 413.15 413.15 403.15 403.15 393.15 393.15 383.15 383.15
P/bar 113.4 95.7 33.4 77.4 28.4 58.9 24.4 40.9 21.4
continued
____________________________________________________________________________________
continued
wB 0.0100 0.0100 0.0100 0.0100 0.0100 0.0298 0.0298 0.0298 0.0298
T/K 373.15 373.15 368.15 363.15 358.15 423.15 423.15 413.15 413.15
P/bar 22.5 17.0 16.7 15.5 13.6 114.2 39.2 96.0 33.6
LLE VLLE VLE VLE VLSE LLE VLLE LLE VLLE
wB 0.0298 0.0298 0.0298 0.0298 0.0298 0.0298 0.0298 0.0298 0.0298
T/K 403.15 403.15 393.15 393.15 383.15 383.15 373.15 373.15 368.15
P/bar 77.9 29.2 60.5 25.3 42.2 21.5 22.0 17.2 17.0
LLE VLLE LLE VLLE LLE VLLE LLE VLLE VLE
wB 0.0298 0.0298 0.0496 0.0496 0.0496 0.0496 0.0496 0.0496 0.0496
T/K 363.15 358.15 423.15 423.15 413.15 413.15 403.15 403.15 393.15
P/bar 15.7 13.7 114.8 39.5 98.5 33.7 82.9 28.7 64.8
VLE VLSE LLE VLLE LLE VLLE LLE VLLE LLE
wB 0.0496 0.0496 0.0496 0.0496 0.0496 0.0496 0.0496 0.0496 0.0742
T/K 393.15 383.15 383.15 373.15 373.15 368.15 363.15 358.15 423.15
P/bar 24.8 45.1 21.0 24.5 17.1 17.2 15.6 13.9 112.1
VLLE LLE VLLE LLE VLLE VLE VLE VLSE LLE
wB 0.0742 0.0742 0.0742 0.0742 0.0742 0.0742 0.0742 0.0992 0.0992
T/K 413.15 403.15 393.15 383.15 373.15 363.15 358.15 423.15 413.15
P/bar 95.4 78.1 60.0 41.2 21.9 14.7 13.3 109.0 93.9
LLE LLE LLE LLE LLE VLE VLSE LLE LLE
wB 0.0992 0.0992 0.0992 0.0992 0.0992 0.0992 0.0992
T/K 403.15 393.15 383.15 373.15 368.15 363.15 358.15
P/bar 77.0 57.4 38.1 21.3 16.0 14.5 13.1
LLE LLE LLE LLE VLE VLE VLSE
Polymer (B): polypropylene 2001DAR


wB 0.00995 0.00995 0.00995 0.00995 0.00995 0.00995 0.00995 0.04975 0.04975
T/K 423.15 413.15 403.15 393.15 383.15 373.15 363.15 423.15 413.15
P/bar 111.9 95.9 80.2 60.0 40.6 22.7 15.4 113.2 98.0
LLE LLE LLE LLE LLE LLE VLE LLE LLE
wB 0.04975 0.04975 0.04975 0.04975 0.07318 0.07318 0.07318 0.07318 0.07318
T/K 403.15 383.15 373.15 363.15 423.15 403.15 393.15 383.15 373.15
P/bar 82.3 42.1 22.7 15.7 111.3 79.8 61.2 41.2 21.8
LLE LLE LLE VLE LLE LLE LLE LLE LLE
wB 0.07318
T/K 363.15
P/bar 15.7
VLE
____________________________________________________________________________________


wB 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0069 0.0069
T/K 423.15 413.15 403.15 393.15 383.15 373.15 363.15 423.15 413.15
P/bar 113.7 100.7 91.1 73.9 53.1 35.8 15.9 127.3 110.4
LLE LLE LLE LLE LLE LLE VLSE LLE LLE
wB 0.0069 0.0069 0.0069 0.0069 0.0069 0.0099 0.0099 0.0099 0.0099
T/K 403.15 393.15 383.15 373.15 363.15 423.15 418.15 413.15 408.15
P/bar 96.6 78.2 58.9 38.6 17.6 129.2 120.2 114.5 106.7
LLE LLE LLE LLE VLSE LLE LLE LLE LLE
wB 0.0099 0.0099 0.0099 0.0099 0.0099 0.0099 0.0099 0.0099 0.0099
T/K 403.15 398.15 393.15 388.15 383.15 378.15 373.15 368.15 363.15
P/bar 99.2 90.2 80.7 71.4 61.4 51.2 41.1 29.8 18.4
LLE LLE LLE LLE LLE LLE LLE LLE LLSE
wB 0.0099 0.0996 0.0996 0.0996 0.0996 0.0996 0.0996 0.0996 0.0996
T/K 358.15 423.15 418.15 413.15 408.15 403.15 398.15 393.15 383.15
P/bar 14.7 129.1 120.3 112.8 106.1 97.2 88.2 77.5 58.8
VLSE LLE LLE LLE LLE LLE LLE LLE LLE
wB 0.0996 0.0996 0.0297 0.0297 0.0297 0.0297 0.0297 0.0297 0.0297
T/K 373.15 363.15 423.15 418.15 413.15 408.15 403.15 398.15 393.15
P/bar 38.9 18.9 132.3 124.1 116.2 106.7 98.3 89.4 80.1
LLE LLSE LLE LLE LLE LLE LLE LLE LLE
wB 0.0297 0.0297 0.0297 0.0297 0.0297 0.0297 0.0496 0.0496 0.0496
T/K 388.15 383.15 378.15 373.15 368.15 363.15 423.15 418.15 413.15
P/bar 69.4 60.8 50.1 40.1 29.0 18.4 132.2 124.7 116.1
LLE LLE LLE LLE LLE LLSE LLE LLE LLE
wB 0.0496 0.0496 0.0496 0.0496 0.0496 0.0496 0.0496 0.0742 0.0742
T/K 408.15 403.15 398.15 393.15 383.15 373.15 363.15 423.15 418.15
P/bar 107.5 99.8 89.5 80.9 61.1 40.5 18.4 133.1 125.9
LLE LLE LLE LLE LLE LLE LLSE LLE LLE
wB 0.0742 0.0742 0.0742 0.0742 0.0742 0.0742 0.0742 0.0742
T/K 413.15 408.15 403.15 398.15 393.15 383.15 373.15 363.15
P/bar 116.3 107.3 101.2 89.9 82.1 62.1 42.6 20.3
LLE LLE LLE LLE LLE LLE LLE LLSE

98 % isotactic, metallocene product

continued
____________________________________________________________________________________
continued
wB 0.00285 0.00285 0.00285 0.00285 0.00285 0.00285 0.00285 0.00285 0.00285
T/K 423.15 413.15 403.15 393.15 383.15 373.15 368.15 363.15 358.15
P/bar 112.5 97.3 82.1 63.8 46.0 27.7 19.6 16.4 14.6
LLE LLE LLE LLE LLE LLE LLE VLE VLE
wB 0.00285 0.00285 0.00992 0.00992 0.00992 0.00992 0.00992 0.00992 0.00992
T/K 353.15 348.15 423.15 413.15 403.15 393.15 383.15 373.15 368.15
P/bar 13.2 11.9 127.3 111.3 93.9 75.7 56.4 36.7 26.5
VLE VLSE LLE LLE LLE LLE LLE LLE LLE
wB 0.00992 0.00992 0.00992 0.00992 0.04932 0.04932 0.04932 0.04932 0.04932
T/K 363.15 358.15 353.15 348.15 423.15 408.15 403.15 393.15 383.15
P/bar 17.7 15.7 13.8 12.1 129.2 104.4 95.7 78.1 59.1
VLE VLE VLE VLSE LLE LLE LLE LLE LLE
wB 0.04932 0.04932 0.04932 0.04932 0.04932 0.07434 0.07434 0.07434 0.07434
T/K 373.15 363.15 358.15 353.15 348.15 423.15 413.15 403.15 393.15
P/bar 37.8 19.8 16.9 15.5 14.4 124.5 108.0 90.6 73.1
LLE LLE VLE VLE VLE LLE LLE LLE LLE
wB 0.07434 0.07434 0.07434 0.07434 0.07434 0.07434 0.07434 0.09885 0.09885
T/K 383.15 373.15 368.15 363.15 358.15 353.15 348.15 423.15 413.15
P/bar 54.3 33.9 24.9 18.1 16.6 15.2 14.5 122.1 106.6
LLE LLE LLE VLE VLE VLE VLSE LLE LLE
wB 0.09885 0.09885 0.09885 0.09885 0.09885 0.09885 0.09885 0.09885 0.09885
T/K 403.15 393.15 383.15 373.15 368.15 363.15 358.15 353.15 348.15
P/bar 89.2 72.1 52.8 32.3 23.7 16.6 15.4 13.9 12.6
LLE LLE LLE LLE LLE VLE VLE VLE VLSE


wB 0.00983 0.00983 0.00983 0.00983 0.00983 0.00983 0.00983 0.04985 0.04985
T/K 423.15 413.15 403.15 393.15 383.15 373.15 363.15 423.15 413.15
P/bar 131.0 116.7 98.6 80.5 61.6 41.9 20.3 132.3 116.9
wB 0.04985 0.04985 0.04985 0.04985 0.04985 0.07432 0.07432 0.07432 0.07432
T/K 403.15 393.15 383.15 373.15 363.15 423.15 413.15 403.15 393.15
P/bar 100.9 85.7 63.7 43.2 21.0 132.4 116.0 99.1 82.5
wB 0.07432 0.07432 0.07432
T/K 383.15 373.15 363.15
P/bar 62.8 41.9 21.0
LLE LLE LLE
____________________________________________________________________________________
Polymer (B): polypropylene 1998HAN

Characterization: Mn/kg.mol−1 = 45.5, Mw/kg.mol−1 = 91, isotactic,

wB 0.05 0.05 0.05
T/K 422.65 447.35 471.55
P/bar 436.6 444.9 456.0


wB 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0100
T/K 403.15 398.15 393.15 388.15 383.15 378.15 373.15 368.15 403.15
P/bar 252.4 243.0 234.1 224.9 216.7 207.9 199.7 190.8 263.7
LLE LLE LLE LLE LLE LLE LLE LLSE LLE
wB 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0498 0.0498
T/K 398.15 393.15 388.15 383.15 378.15 373.15 368.15 403.15 398.15
P/bar 255.3 246.3 237.2 229.1 220.1 211.0 202.3 262.7 254.2
LLE LLE LLE LLE LLE LLE LLSE LLE LLE
wB 0.0498 0.0498 0.0498 0.0498 0.0498 0.0498 0.0748 0.0748 0.0748
T/K 393.15 388.15 383.15 378.15 373.15 368.15 403.15 398.15 393.15
P/bar 246.0 236.9 227.9 219.3 210.5 202.4 263.4 254.6 247.1
LLE LLE LLE LLE LLE LLSE LLE LLE LLE
wB 0.0748 0.0748 0.0748 0.0748 0.0748 0.1000 0.1000 0.1000 0.1000
T/K 388.15 383.15 378.15 373.15 368.15 403.15 398.15 393.15 388.15
P/bar 237.1 228.9 220.2 211.0 202.5 259.4 251.1 242.7 234.5
LLE LLE LLE LLE LLSE LLE LLE LLE LLE
wB 0.1000 0.1000 0.1000 0.1000
T/K 383.15 378.15 373.15 368.15
P/bar 225.0 216.7 207.1 198.8
LLE LLE LLE LLSE
Polymer (B): polypropylene 1995PRA

Characterization: isotactic, Scientific Polymer Products, Inc., Ontario, NY

wB 0.04 0.075 0.15 0.15 0.22
T/K 398.15 414.15 402.15 403.15 403.15
P/bar 297.2 297.2 295.1 291.0 259.1
____________________________________________________________________________________


wB 0.0030 0.0030 0.0030 0.0030 0.0030 0.0099 0.0099 0.0099 0.0099
T/K 388.15 383.15 378.15 373.15 368.15 383.15 378.15 373.15 368.15
P/bar 253.7 245.0 236.4 228.5 220.7 261.0 253.1 242.9 234.4
LLE LLE LLE LLE LLSE LLE LLE LLE LLSE
wB 0.0297 0.0297 0.0297 0.0297 0.0497 0.0497 0.0497 0.0497 0.0740
T/K 383.15 378.15 373.15 368.15 383.15 378.15 373.15 368.15 383.15
P/bar 267.2 258.7 249.4 240.7 266.4 257.6 248.5 240.6 259.1
LLE LLE LLE LLSE LLE LLE LLE LLSE LLE
wB 0.0740 0.0740 0.0740 0.0984 0.0984 0.0984 0.0984
T/K 378.15 373.15 368.15 383.15 378.15 373.15 368.15
P/bar 250.7 242.3 232.6 257.5 248.3 240.1 231.2
LLE LLE VLSE LLE LLE LLE VLSE

98 % isotactic, metallocene product

wB 0.00294 0.00294 0.00294 0.00294 0.00294 0.00294 0.00975 0.00975 0.00975
T/K 383.15 378.15 373.15 368.15 363.15 358.15 383.15 378.15 373.15
P/bar 241.2 232.8 223.5 215.2 207.0 198.5 249.7 241.1 233.5
wB 0.00975 0.00975 0.00975 0.03012 0.03012 0.03012 0.03012 0.03012 0.03012
T/K 368.15 363.15 358.15 383.15 378.15 373.15 368.15 363.15 358.15
P/bar 224.2 215.6 207.7 257.5 248.5 240.0 229.8 220.2 212.3
wB 0.04888 0.04888 0.04888 0.04888 0.04888 0.04888 0.07329 0.07329 0.07329
T/K 383.15 378.15 373.15 368.15 363.15 358.15 383.15 378.15 373.15
P/bar 257.9 248.6 240.2 230.9 221.0 212.8 249.4 241.0 232.6
wB 0.07329 0.07329 0.07329 0.09786 0.09786 0.09786 0.09786 0.09786 0.09786
T/K 368.15 363.15 358.15 383.15 378.15 373.15 368.15 363.15 358.15
P/bar 225.0 216.3 206.7 245.4 237.5 229.2 220.0 211.2 201.9
____________________________________________________________________________________
Polymer (B): poly(propylene oxide) 1998ONE

T/K = 303.15
wB 0.014 0.017 0.024 0.031 0.037 0.047 0.082 0.095
P/MPa 7.10 7.24 7.52 7.93 8.20 8.76 8.89 9.03
T/K = 313.15
wB 0.0035 0.007 0.010 0.014 0.017 0.024 0.031 0.037 0.047
P/MPa 8.96 9.38 9.65 9.86 10.14 10.62 11.10 11.38 12.00
wB 0.082 0.095
P/MPa 12.27 12.13
T/K = 323.15
wB 0.0035 0.007 0.010 0.014 0.017 0.024 0.031 0.037 0.047
P/MPa 10.76 11.38 11.72 12.27 12.69 13.24 13.72 14.20 14.82
wB 0.095
P/MPa 15.51

T/K = 303.15
wB 0.005 0.016 0.027 0.037 0.047 0.057 0.067 0.086 0.104
P/MPa 8.07 9.86 11.31 12.41 13.58 14.34 15.31 17.93 20.41
T/K = 313.15
wB 0.005 0.016 0.027 0.037 0.047 0.057 0.067 0.086 0.104
P/MPa 11.03 13.10 14.75 15.79 16.89 17.79 18.82 20.96 23.30
T/K = 323.15
wB 0.005 0.016 0.027 0.037 0.047 0.057 0.067 0.086 0.104
P/MPa 14.13 16.20 17.79 18.96 20.13 20.89 21.99 23.72 2

T/K 298.15 298.15 298.15 308.15 308.15 308.15 323.15 323.15 323.15
wB 0.00219 0.00495 0.01040 0.00219 0.00495 0.01040 0.00219 0.00495 0.01040
P/MPa 13.51 17.79 21.37 17.24 21.03 24.55 21.58 24.55 28.61
continued
____________________________________________________________________________________
continued
T/K 333.15 333.15 333.15
wB 0.00219 0.00495 0.01040
P/MPa 23.58 28.13 31.37
Polymer (B): poly(propylene oxide)-b-poly(ethylene oxide)- 1998ONE

b-poly(propylene oxide) triblock copolymer
oxide, (21.6/14.2/21.6), Pluronic 25R2, hydroxyl terminated

wB 0.00128 0.00128 0.00128 0.00128
T/K 298.15 308.15 318.15 328.15
P/MPa 24.06 28.96 30.27 33.03

oxide, (14.7/9.7/14.7), Pluronic 17R2, hydroxyl terminated

T/K = 298.15
wB 0.00202 0.00478 0.00753 0.01030 0.01570
P/MPa 15.93 22.89 25.92 28.27 33.72
T/K = 303.15
wB 0.00202 0.00478 0.00753 0.01030 0.01570
P/MPa 17.79 24.48 27.92 29.92 35.37
T/K = 313.15
wB 0.00202 0.00478 0.00753 0.01030 0.01570
P/MPa 21.65 26.89 30.06 32.75 38.13
T/K = 323.15
wB 0.00202 0.00478 0.00753 0.01030 0.01570
P/MPa 25.51 29.85 33.72 35.78 40.27
T/K = 333.15
wB 0.00202 0.00478 0.00753 0.01030
P/MPa 27.23 33.16 36.06 37.92
T/K = 338.15
wB 0.00202 0.00478 0.00753 0.01030
P/MPa 28.96 34.34 37.78 39.58
____________________________________________________________________________________

trifluoroacetate end-capped
oxide, (14.7/9.7/14.7), Pluronic 17R2, trifluoroacetate end-capped

wB 0.00346 0.00346 0.00346 0.00346 0.00548 0.00548 0.00548 0.00548
T/K 298.15 308.15 323.15 338.15 298.15 308.15 323.15 338.15
P/MPa 11.65 15.17 20.62 24.82 13.51 13.51 17.31 27.17

(14.7/25.8/14.7), Pluronic 17R4, hydroxyl terminated

wB 0.00134 0.00134 0.00134 0.00134
T/K 298.15 303.15 318.15 333.15
P/MPa 26.06 29.92 33.30 37.44

(14.7/25.8/14.7), Pluronic 17R4, trifluoroacetate end-capped

wB 0.00127 0.00127 0.00127 0.00127 0.00127 0.00402 0.00402 0.00402 0.00402
T/K 298.15 308.15 318.15 328.15 338.15 298.15 308.15 318.15 328.15
P/MPa 16.06 19.24 23.24 26.06 28.13 18.48 22.89 26.54 29.85
wB 0.00402 0.00961 0.00961 0.00961 0.00961
T/K 338.15 298.15 308.15 318.15 328.15
P/MPa 33.51 21.03 24.96 28.27 31.72

(8.6/22.7/8.6), Pluronic 10R5, hydroxyl terminated
continued
____________________________________________________________________________________
continued
wB 0.00167 0.00167 0.00167 0.00167 0.00167 0.00444 0.00444 0.00444 0.00444
T/K 298.15 308.15 313.15 323.15 338.15 298.15 308.15 313.15 323.15
P/MPa 19.99 23.79 25.79 27.99 31.92 26.89 31.16 32.41 35.71

(8.6/22.7/8.6), Pluronic 10R5, trifluoroacetate end-capped in the
laboratory

wB 0.00188 0.00426 0.01070 0.01720 0.00188 0.00426 0.01070 0.01720 0.00426
T/K 298.15 298.15 298.15 298.15 308.15 308.15 308.15 308.15 313.15
P/MPa 11.86 18.96 23.79 26.82 16.55 22.55 26.82 29.99 24.96
wB 0.01070 0.01720 0.00188 0.00426 0.01070 0.01720 0.00426 0.01070 0.00426
T/K 313.15 313.15 323.15 323.15 323.15 323.15 333.15 333.15 338.15
P/MPa 29.03 32.34 19.58 26.96 31.92 35.51 27.85 34.89 31.30

Comments: PS/SO2 weight ratio wB/wA in the total system was about 1/5. The equilibration time was
12 hours.
T/K = 293.15 PA/MPa = 0.326
____________________________________________________________________________________
upper phase lower phase
wB Mn/ M w/ wB Mn/ M w/
kg/mol kg/mol kg/mol kg/mol
____________________________________________________________________________________
0.315 16.6 35.8 0.0037 4.1 10.0
____________________________________________________________________________________

continued
____________________________________________________________________________________
continued
12 hours.
T/K = 293.15 PA/MPa = 0.326
____________________________________________________________________________________
____________________________________________________________________________________
0.343 63.8 194 0.0037 4.9 17.5
____________________________________________________________________________________

12 hours.
T/K = 293.15 PA/MPa = 0.326
____________________________________________________________________________________
____________________________________________________________________________________
0.349 139 401 0.0023 4.01 9.81
____________________________________________________________________________________
Polymer (B): poly(1,1,2,2-tetrahydroperfluorodecyl acrylate) 2002BLA


T/K = 298.15
wB 0.0591 0.0392 0.0307 0.0204 0.0050 0.0050 0.003 0.002 0.001
P/bar 114.05 115.80 117.93 116.16 110.82 110.03 110.05 110.14 109.22
wB 0.001 0.001 0.001 0.0005 0.0005 0.0001 0.0001 0.0001
P/bar 108.88 108.81 109.85 108.50 106.30 82.99 90.63 97.08
continued
____________________________________________________________________________________
continued
T/K = 323.15
wB 0.0591 0.0392 0.0307 0.0204 0.0050 0.0050 0.003 0.002 0.001
P/bar 201.62 203.74 204.16 202.72 197.46 195.76 198.02 196.23 195.27
wB 0.001 0.001 0.001 0.0005 0.0001 0.0001
P/bar 197.10 195.57 195.78 193.55 176.55 179.58
T/K = 343.15
wB 0.0591 0.0392 0.0307 0.0204 0.0050 0.0050 0.003 0.002 0.001
P/bar 259.58 262.09 262.09 260.84 257.62 255.15 255.89 254.01 254.02
wB 0.001 0.001 0.0005 0.0001 0.0001
P/bar 253.73 253.84 250.34 237.60 237.85
T/K = 373.15
wB 0.0591 0.0392 0.0307 0.0204 0.0050 0.003 0.002 0.001 0.001
P/bar 330.83 332.90 332.94 332.62 327.78 326.96 324.97 325.03 324.39
wB 0.0005 0.0001 0.0001
P/bar 322.57 308.28 303.97
Type of data: liquid-liquid-vapor three phase equilibrium data

T/K = 298.15
wB 0.01 0.05 0.1 0.2
P/bar 63.95 64.39 64.25 64.39
Polymer (B): poly[P-tris(trifluoroethoxy)-N-trimethylsilyl] 1998ONE

phosphazene

wB 0.00516 0.0103 0.0187 0.0405 0.00516 0.0103 0.0187 0.0405
T/K 298.15 298.15 298.15 298.15 308.15 308.15 308.15 308.15
P/MPa 13.10 13.82 13.96 14.10 17.41 18.00 18.20 18.42
wB 0.00516 0.01030 0.01870 0.04050 0.00516 0.01030 0.01870 0.04050
T/K 323.15 323.15 323.15 323.15 338.15 338.15 338.15 338.15
P/MPa 22.82 23.61 23.82 24.17 27.72 28.51 28.99 29.23
Polymer (B): poly(vinyl ethyl ether) 1992KIA, 1994KIA

Characterization: Mw/kg.mol−1 = 3.8, Scientific Polymer Products, Ontario, NY
continued
____________________________________________________________________________________
continued
wB 0.850 0.850 0.850 0.850 0.850 0.850 0.850 0.850 0.850
T/K 304.05 308.35 310.55 313.15 313.45 317.05 323.15 328.15 333.15
P/bar 37.34 39.01 40.84 43.34 45.02 46.17 52.63 56.64 60.52
wB 0.850 0.850 0.800 0.800 0.800 0.800 0.800 0.800 0.800
T/K 338.05 343.05 303.75 308.15 313.15 318.15 323.15 328.15 333.15
P/bar 65.21 70.26 45.51 48.73 53.12 58.21 63.54 68.26 74.89
wB 0.800 0.800 0.750 0.750 0.750 0.750 0.750 0.750 0.750
T/K 338.15 343.15 300.75 303.35 308.15 313.15 317.35 323.15 327.85
P/bar 81.23 87.56 49.09 50.48 54.74 61.23 68.66 75.81 81.89
wB 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
T/K 332.45 337.45 342.95 302.95 308.15 313.35 318.25 323.15 328.15
P/bar 88.65 95.94 104.77 58.12 62.58 69.97 79.39 88.78 98.90
wB 0.700 0.700 0.700 0.624 0.624 0.624 0.624 0.624 0.624
T/K 333.15 340.25 342.65 309.05 310.25 311.25 312.75 313.65 314.45
P/bar 110.45 126.51 131.86 72.56 75.10 76.40 79.23 81.79 83.70
wB 0.624
T/K 315.95
P/bar 87.40
Polymer (B): tetraethylene glycol monododecyl ether 1996HAR

Characterization: M/kg.mol−1 = 0.362

wB 0.010 T/K 318.15 P/bar 149.6
Polymer (B): tetraethylene glycol monododecyl ether 2001LIU

Characterization: M/kg.mol−1 = 0.362, surfactant C12E4,

T/K 313.15
wB 0.00645 0.01127 0.01589 0.02017 0.02480 0.02920
P/MPa 10.20 13.02 15.15 16.87 18.35 19.65
ρ/(g/cm3) 0.642 0.736 0.775 0.798 0.814 0.828
T/K 323.15
wB 0.00392 0.00729 0.01166 0.01780 0.02107
P/MPa 11.25 13.27 15.86 18.18 19.37
ρ/(g/cm3) 0.521 0.634 0.703 0.748 0.765
____________________________________________________________________________________

____________________________________________________________________________________
____________________________________________________________________________________
Cellulose acetate/cellulose butyrate copolymer
carbon dioxide 1997DIN
____________________________________________________________________________________
Dimethylsiloxane/(3-acetoxypropyl)methylsiloxane
copolymer
carbon dioxide 2003KIL
____________________________________________________________________________________
Dimethylsiloxane/(4-acetylbutyl)methylsiloxane copolymer
____________________________________________________________________________________
Dimethylsiloxane/(4,4-dimethylpentyl)methylsiloxane
copolymer
____________________________________________________________________________________
Dimethylsiloxane/(3-ethoxypropyl)methylsiloxane copolymer
____________________________________________________________________________________
Dimethylsiloxane/glycidyloxypropylsiloxane/
tris(trimethylsiloxy)silylpropylsiloxane terpolymer
carbon dioxide 1993HOE
____________________________________________________________________________________
Dimethylsiloxane/hydromethylsiloxane copolymer
carbon dioxide 1993HOE
____________________________________________________________________________________
Dimethylsiloxane/(3-methoxycarbonylpropyl)methylsiloxane
copolymer
____________________________________________________________________________________
Dimethylsiloxane/(3-trimethylsilylpropyl)methylsiloxane
copolymer
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
Ethylcellulose
carbon dioxide 2004LI2
1-chloro-1,1-difluoroethane 2004LI2
chlorodifluoromethane 2004LI2
1,1-difluoroethane 2004LI2
difluoromethane 2004LI2
dimethylether 2004LI2
____________________________________________________________________________________
Ethylene/acrylic acid copolymer
n-butane 1994LE1
n-butane 1996LE3
1-butene 1993HA2
1-butene 1994LE1
1-butene 1994LE2
1-butene 1996LE3
dimethyl ether 1994LE1
ethene 1992LUF
ethene 1993HA2
ethene 1997LEE
propane 1994LE1
propane 1996LE1
propene 1993HA2
propene 1994LE1
propene 1996LE1
____________________________________________________________________________________
1-butene 1999CHE
dimethyl ether 2000BY3
ethene 1999CHE
propane 1995CHE
propane 1998HAN
____________________________________________________________________________________
Ethylene/butyl acrylate copolymer
ethene 1996BYU
____________________________________________________________________________________
2-methylpropane 1999PAN
propane 1998HAN
propane 1999PAN
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
Ethylene/methacrylic acid copolymer
n-butane 1997LEE
1-butene 1997LEE
dimethyl ether 1997LEE
ethene 1997LEE
propane 1997LEE
____________________________________________________________________________________
n-butane 1993PRA
n-butane 1994LOS
n-butane 1994LE2
n-butane 1996LE1
n-butane 1996LE3
1-butene 1993PRA
1-butene 1996LE1
carbon dioxide 1999LO2
chlorodifluoromethane 1991MEI
chlorodifluoromethane 1993HA1
chlorodifluoromethane 1993PRA
ethane 1992HAS
ethane 1993HA2
ethane 1994LOS
ethane 1996LE3
ethene 1992HAS
ethene 1993HA2
ethene 1996BYU
ethene 1996LE3
n-hexane 1994LOS
methanol 1996LE3
propane 1991MEI
propane 1992HAS
propane 1993HA1
propane 1993HA2
propane 1994LOS
propene 1992HAS
propene 1993HA2
propene 1996LE3
____________________________________________________________________________________
propane 1997WH2
propane 1998HAN
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
1-butene 1993CHE
ethene 1997HAN
ethene 2001KEM
propane 1997WH2
propane 1998HAN
propene 1993CHE
propene 1997HAN
____________________________________________________________________________________
Ethylene/propylene/diene terpolymer
ethene 2004PFO
____________________________________________________________________________________
ethene 1982WOH
ethene 1996FOL
ethene 2000KIN
____________________________________________________________________________________
Ethylene glycol/propylene glycol copolymer
carbon dioxide 2002DRO
____________________________________________________________________________________
Methyl methacrylate/2-hydroxyethyl methacrylate
copolymer
carbon dioxide 1997LEP
____________________________________________________________________________________
Perfluoropolyether diamide
carbon dioxide 2001CHE
____________________________________________________________________________________
Polybutadiene, fluorinated
carbon dioxide 2002MC1
____________________________________________________________________________________
Poly(1-butene)
propane 1997WH2
____________________________________________________________________________________
Poly(butyl acrylate)
carbon dioxide 1996RIN
ethene 1996BYU
ethene 1999LO2
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
chlorodifluoromethane 1994LEL
____________________________________________________________________________________
carbon dioxide 1998CHA
____________________________________________________________________________________
Poly(decyl methacrylate)
____________________________________________________________________________________
Poly(1,1-dihydroperfluorooctyl acrylate)
carbon dioxide 1998LUN
____________________________________________________________________________________
Poly(1,1-dihydroperfluorooctyl acrylate)-
b-polystyrene diblock copolymer
carbon dioxide 2002TAY
____________________________________________________________________________________
Poly(1,1-dihydroperfluorooctyl acrylate)-
b-poly(vinyl acetate) diblock copolymer
carbon dioxide 2002TAY
____________________________________________________________________________________
Poly(1,1-dihydroperfluorooctyl methacrylate)
carbon dioxide 2004DIC
____________________________________________________________________________________
carbon dioxide 1995XI1
carbon dioxide 2000TEP
____________________________________________________________________________________
Poly(ethyl acrylate)
ethene 1999LO2
____________________________________________________________________________________
Polyethylene
n-butane 1963EHR
n-butane 1989KIR
n-butane 1994KI2
n-butane 1994LE1
n-butane 1994XI2
n-butane 1995HAS
n-butane 1995XI2
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
1-butene 1992WOH
1-butene 1994LE1
1-butene 1995HAS
dimethyl ether 1995HAS
ethane 1963EHR
ethane 1992HAS
ethane 1993HA2
ethene 1965CE1
ethene 1965CE2
ethene 1965EHR
ethene 1966KON
ethene 1975LIN
ethene 1976LUF
ethene 1976STE
ethene 1977LIN
ethene 1979KOB
ethene 1980RAE
ethene 1981SP2
ethene 1981WO1
ethene 1981WO2
ethene 1983LOO
ethene 1983SPA
ethene 1984FON
ethene 1984KOB
ethene 1992HAS
ethene 1992WOH
ethene 1993HA2
ethene 1994CHE
ethene 1995LOO
ethene 1996BYU
ethene 1998HEU
fluorotrichloromethane 1988WAL
4-methyl-1-pentene 1992WOH
n-pentane 1963EHR
n-pentane 1989KIR
n-pentane 1994KI2
n-pentane 1994XI1
n-pentane 1994XI2
n-pentane 1995XI2
n-pentane 1997KIR
n-pentane 1998ZHU
n-pentane 1999MAR
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
propane 1963EHR
propane 1991MEI
propane 1991WAT
propane 1992CO3
propane 1992HAS
propane 1993HA1
propane 1994LE1
propane 1995HAS
propane 1995PRA
propane 1997WH2
propane 1998HAN
propene 1992HAS
propene 1993HA2
propene 1994LE1
propene 1995HAS
____________________________________________________________________________________
carbon dioxide 1989DAN
carbon dioxide 1997WEI
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
Poly(ethylene glycol) nonylphenyl ether
carbon dioxide 1998DIM
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
Poly(ethylhexyl acrylate)
ethene 1999LO2
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
____________________________________________________________________________________
Poly(ethyl vinyl ether)
____________________________________________________________________________________
Polyglycolide
carbon dioxide 1993DEB
____________________________________________________________________________________
Poly(hexyl methacrylate)
____________________________________________________________________________________
Polyisobutylene
n-butane 1983ALI
ethene 1999CHE
____________________________________________________________________________________
Polyisoprene, fluorinated
____________________________________________________________________________________
Poly(DL-lactide)
carbon dioxide 1993DEB
____________________________________________________________________________________
Poly(methyl acrylate)
____________________________________________________________________________________
carbon dioxide 1976SC2
carbon dioxide 1990BEC
____________________________________________________________________________________
Poly(4-methyl-1-pentene
propane 1997WH2
____________________________________________________________________________________
Poly(methylpropenoxyalkylsiloxane)
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
Poly(methylpropenoxyperfluoroalkylsiloxane)
____________________________________________________________________________________
Poly(octadecyl acrylate)
ethene 1999LO2
____________________________________________________________________________________
Poly(octyl methacrylate)
____________________________________________________________________________________
Poly(perfluoropropylene oxide) acid sorbitol ester
carbon dioxide 1997SIN
____________________________________________________________________________________
Poly(propyl acrylate)
____________________________________________________________________________________
Polypropylene
n-butane 2001NDI
1-butene 2001NDI
n-pentane 1998KI2
n-pentane 1999MAR
propane 1995CHE
propane 1997WH1
propene 1997WH1
____________________________________________________________________________________
carbon dioxide 1996PAR
ethane 2000MAR
____________________________________________________________________________________
Poly(propylene glycol) monobutyl ether
____________________________________________________________________________________
Poly(propylene glycol) monomethyl ether
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
Poly(propylene oxide)-b-poly(ethylene oxide)-
____________________________________________________________________________________
Polystyrene
n-butane 1983ALI
n-butane 1988SA1
n-butane 1988SA2
carbon dioxide 1987KUM
ethane 1987KUM
ethane 1994PRA
n-pentane 1988SA1
n-pentane 1988SA2
propane 1994PRA
____________________________________________________________________________________
Poly(1,1,2,2-tetrahydroperfluorodecyl acrylate)
carbon dioxide 1995MAW
carbon dioxide 2002BLA
____________________________________________________________________________________
Poly(1,1,2,2-tetrahydroperfluorodecyl methacrylate)
____________________________________________________________________________________
Poly(1,1,2,2-tetrahydroperfluorohexyl methacrylate)
____________________________________________________________________________________
Poly(1,1,2,2-tetrahydroperfluorooctyl methacrylate)
____________________________________________________________________________________
Polyurethane and precursors
carbon dioxide 1996PAR
____________________________________________________________________________________
Poly(vinyl acetate)
carbon dioxide 1988MAS
____________________________________________________________________________________
Poly(vinyl acetate)-b-poly(1,1,2,2-tetrahydro-
perfluorooctyl acrylate) diblock copolymer
carbon dioxide 2002COL
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
____________________________________________________________________________________
carbon dioxide 1994KIA
____________________________________________________________________________________
Poly(vinyl formate)
____________________________________________________________________________________
1,1,1-chlorodifluoroethane 2000DIN
chlorodifluoromethane 2000DIN
difluoromethane 2000DIN
1,1,1,2-tetrafluoroethane 2000DIN
trifluoromethane 2000DIN
____________________________________________________________________________________
Tetrafluoroethylene/hexafluoropropylene copolymer
carbon dioxide 1995TUM
carbon dioxide 1996MER
chlorotrifluoromethane 1996MER
hexafluoroethane 1996MER
hexafluoropropene 1996MER
octafluoropropane 1996MER
sulfur hexafluoride 1996MER
sulfur hexafluoride 1998MC1
tetrafluoromethane 1996MER
tetrafluoromethane 1998MC1
trifluoromethane 1999MER
____________________________________________________________________________________
Tetrafluoroethylene/2,2-bis(trifluoromethyl)-
____________________________________________________________________________________
Vinylidene fluoride/chlorotrifluoroethylene copolymer
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
Vinylidene fluoride/hexafluoropropylene copolymer
carbon dioxide 19 97MER
1-chloro-1,1-difluoroethane 2000DIN
chlorotrifluoromethane 2000DIN
1,1-difluoroethane 2000DIN
pentafluoroethane 2000DIN
____________________________________________________________________________________
____________________________________________________________________________________
4.3. Cloud-point and/or coexistence curves of quasiternary and/or

quasiquaternary solutions

Characterization: Mn/kg.mol−1 = 37.5, Mw/kg.mol−1 = 183, 3.0 wt% acrylic acid
Solvent (C): acrylic acid C3H4O2 79-10-7

T/K = 413.15
wA 0.858 0.851 0.839 0.822 0.797 0.770
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.007 0.014 0.026 0.043 0.068 0.095
P/MPa 164.4 157.1 152.9 148.0 142.7 138.2
T/K = 433.15
wA 0.858 0.851 0.839 0.822 0.797 0.770
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.007 0.014 0.026 0.043 0.068 0.095
P/MPa 150.6 146.2 143.2 139.4 134.1 130.5
T/K = 453.15
wA 0.858 0.851 0.839 0.822 0.797 0.770
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.007 0.014 0.026 0.043 0.068 0.095
P/MPa 141.3 138.2 135.8 132.7 128.4 124.7
T/K = 473.15
wA 0.858 0.851 0.839 0.822 0.797 0.770
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.007 0.014 0.026 0.043 0.068 0.095
P/MPa 133.8 131.7 129.7 127.5 123.7 120.5

−1 −1

T/K = 413.15
wA 0.860 0.848 0.839 0.822 0.797 0.761
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.005 0.017 0.026 0.043 0.068 0.104
P/MPa 195.1 175.5 166.0 157.5 150.4 144.0
continued
____________________________________________________________________________________
continued
T/K = 433.15
wA 0.860 0.851 0.848 0.839 0.822 0.797 0.761
wB 0.135 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.005 0.014 0.017 0.026 0.043 0.068 0.104
P/MPa 173.4 163.2 169.4 154.5 147.2 141.2 135.1
T/K = 453.15
wA 0.860 0.851 0.848 0.839 0.822 0.797 0.761
wB 0.135 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.005 0.014 0.017 0.026 0.043 0.068 0.104
P/MPa 155.2 149.1 147.5 144.5 139.1 134.1 130.0
T/K = 473.15
wA 0.860 0.851 0.848 0.839 0.822 0.797 0.761
wB 0.135 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.005 0.014 0.017 0.026 0.043 0.068 0.104
P/MPa 143.1 140.5 139.2 137.5 133.3 128.5 124.6

−1 −1

T/K = 413.15
wA 0.858 0.851 0.842 0.814 0.791 0.752
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.007 0.014 0.023 0.051 0.074 0.113
P/MPa 210.3 189.5 174.4 157.6 152.8 150.3
T/K = 433.15
wA 0.858 0.851 0.842 0.814 0.791 0.752
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.007 0.014 0.023 0.051 0.074 0.113
P/MPa 180.1 169.3 160.2 147.3 144.0 142.4
T/K = 453.15
wA 0.858 0.851 0.842 0.814 0.791 0.752
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.007 0.014 0.023 0.051 0.074 0.113
P/MPa 162.4 155.3 149.0 139.5 137.3 136.5
T/K = 473.15
wA 0.858 0.851 0.842 0.814 0.791 0.752
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.007 0.014 0.023 0.051 0.074 0.113
P/MPa 148.5 144.7 140.5 134.1 131.9 130.5
____________________________________________________________________________________

Solvent (C): n-decane C10H22 124-18-5

wA 0.900 0.900 0.900 0.900 0.900 0.900 0.548 0.548 0.548
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.402 0.402 0.402
T/K 522.55 497.85 472.85 447.95 423.55 413.65 522.65 498.35 473.15
P/bar 1242 1330 1468 1691 2074 2306 799 844 917
wA 0.548 0.548 0.548 0.548 0.548
wB 0.050 0.050 0.050 0.050 0.050
wC 0.402 0.402 0.402 0.402 0.402
T/K 448.55 423.75 413.55 403.85 393.35
P/bar 1041 1260 1406 1581 1818

−1 −1

wA 0.900 0.900 0.900 0.900 0.900 0.900 0.900 0.801 0.801
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.149 0.149
T/K 522.85 497.55 472.25 447.55 423.65 413.15 403.65 523.25 497.95
P/bar 1168 1212 1276 1371 1491 1591 1607 1036 1074
wA 0.801 0.801 0.801 0.801 0.801 0.703 0.703 0.703 0.703
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.149 0.149 0.149 0.149 0.149 0.247 0.247 0.247 0.247
T/K 472.95 448.15 424.45 414.15 404.15 523.15 498.05 472.65 447.45
P/bar 1119 1161 1271 1301 1339 966 981 1016 1069
wA 0.703 0.703 0.703 0.543 0.543 0.543 0.543 0.543 0.543
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.247 0.247 0.247 0.407 0.407 0.407 0.407 0.407 0.407
T/K 423.15 413.75 403.65 521.85 497.95 473.05 448.15 423.55 414.05
P/bar 1154 1209 1264 811 834 886 989 1256 1483

continued
____________________________________________________________________________________
continued
wA 0.893 0.893 0.893 0.893 0.893 0.893 0.893 0.548 0.548
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.057 0.057 0.057 0.057 0.057 0.057 0.057 0.402 0.402
T/K 523.35 497.75 472.55 447.95 423.75 414.15 403.85 523.15 497.65
P/bar 1189 1234 1310 1411 1546 1604 1673 766 774
wA 0.548 0.548 0.548 0.548
wB 0.050 0.050 0.050 0.050
wC 0.402 0.402 0.402 0.402
T/K 472.75 448.25 433.25 423.35
P/bar 809 890 989 1079

−1 −1
wA 0.900 0.900 0.900 0.900 0.900 0.900 0.900 0.556 0.556
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.394 0.394
T/K 523.35 497.95 473.05 448.05 423.85 413.85 403.65 524.05 498.15
P/bar 1200 1243 1331 1439 1601 1669 1746 795 804
wA 0.556 0.556 0.556 0.556 0.556 0.556
wB 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.394 0.394 0.394 0.394 0.394 0.394
T/K 472.65 447.95 423.55 413.65 403.65 393.95
P/bar 826 873 978 1051 1164 1334

Solvent (C): ethyl acetate C4H8O2 141-78-6
wA 0.850 0.850 0.850 0.850 0.850 0.850 0.552 0.552 0.552
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.055 0.055 0.055 0.055 0.055 0.055 0.398 0.398 0.398
T/K 521.95 497.45 472.15 447.25 432.85 423.85 523.25 498.15 472.85
P/bar 1252 1339 1464 1657 1825 1954 936 974 1019
continued
____________________________________________________________________________________
continued
wA 0.552 0.552 0.552 0.552 0.552 0.258 0.258 0.258 0.258
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.398 0.398 0.398 0.398 0.398 0.692 0.692 0.692 0.692
T/K 448.15 433.25 423.65 414.05 403.15 522.95 498.35 473.15 448.65
P/bar 1099 1168 1224 1298 1396 666 677 701 746
wA 0.258 0.258 0.258 0.258
wB 0.050 0.050 0.050 0.050
wC 0.692 0.692 0.692 0.692
T/K 423.75 414.15 403.65 393.75
P/bar 842 910 1010 1156

wA 0.900 0.900 0.900 0.900 0.900 0.900 0.552 0.552 0.552
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.398 0.398 0.398
T/K 522.45 497.95 472.45 447.75 423.35 413.35 522.85 498.05 473.05
P/bar 1257 1340 1476 1695 2056 2290 863 910 993
wA 0.552 0.552 0.552 0.552 0.552
wB 0.050 0.050 0.050 0.050 0.050
wC 0.398 0.398 0.398 0.398 0.398
T/K 448.35 423.75 413.75 403.45 393.65
P/bar 1129 1366 1515 1709 1961

Solvent (C): octanoic acid C8H16O2 124-07-2
wA 0.904 0.904 0.904 0.904 0.904 0.904 0.904 0.904 0.904
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.046 0.046 0.046 0.046 0.046 0.046 0.046 0.046 0.046
T/K 521.85 497.55 472.55 447.85 423.75 413.75 404.05 393.25 383.75
P/bar 1145 1180 1236 1308 1401 1454 1505 1565 1637
wA 0.552 0.552 0.552 0.552 0.552 0.552 0.552 0.552 0.552
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.398 0.398 0.398 0.398 0.398 0.398 0.398 0.398 0.398
T/K 521.95 498.05 472.75 447.75 423.65 414.15 403.85 393.65 384.05
P/bar 697 691 696 706 719 728 738 749 764
continued
____________________________________________________________________________________
continued
wA 0.292 0.292 0.292 0.292 0.292 0.292 0.292 0.292 0.292
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.658 0.658 0.658 0.658 0.658 0.658 0.658 0.658 0.658
T/K 522.65 497.95 472.65 448.65 424.05 414.25 404.25 393.55 384.15
P/bar 346 325 307 289 269 260 251 243 235

−1 −1
Solvent (C): 2,2,4-trimethylpentane C8H18 540-84-1
wA 0.900 0.900 0.900 0.900 0.900 0.900 0.551 0.551 0.551
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.399 0.399 0.399
T/K 522.45 497.95 472.55 447.95 423.65 413.55 522.95 498.05 472.25
P/bar 1233 1314 1445 1648 2005 2211 888 944 1036
wA 0.551 0.551 0.551 0.551
wB 0.050 0.050 0.050 0.050
wC 0.399 0.399 0.399 0.399
T/K 447.95 423.75 413.25 403.55
P/bar 1181 1430 1586 1784

Solvent (C): 1-butene C4H8 106-98-9
wA 0.49105 wB 0.00085 wC 0.50810
T/K 431.85 430.45 418.95 410.95 401.25 399.75 381.75 373.35 368.95
P/bar 400.7 399.3 395.4 391.1 386.6 385.7 376.9 373.0 369.3
T/K 363.75 357.65 353.95 350.05 348.85 347.35
P/bar 365.9 361.4 353.8 407.4 555.0 983.2
wA 0.40287 wB 0.00927 wC 0.58786
T/K 428.85 428.85 415.05 412.05 398.45 396.95 384.25 381.45 368.65
P/bar 698.7 692.7 676.2 674.2 649.6 645.1 606.2 607.0 544.7
T/K 367.95 353.65 352.75 352.75 352.65 352.55
P/bar 538.2 498.6 494.0 600.6 995.1 1426
____________________________________________________________________________________

Solvent (C): butyl acrylate C7H12O2 141-32-2

xC 0.0044 0.0044 0.0044 0.0044 0.0044 0.0044 0.0108 0.0108 0.0108
T/K 383.15 388.15 393.15 403.15 413.15 423.15 383.15 388.15 393.15
P/bar 1838 1795 1735 1658 1600 1552 1783 1748 1699
xC 0.0108 0.0108 0.0108 0.0154 0.0154 0.0154 0.0154 0.0154 0.0154
T/K 403.15 413.15 423.15 383.15 388.15 393.15 403.15 413.15 423.15
P/bar 1628 1570 1507 1770 1730 1684 1607 1545 1485
xC 0.0268 0.0268 0.0268 0.0268 0.0268 0.0268 0.0396 0.0396 0.0396
T/K 383.15 388.15 393.15 403.15 413.15 423.15 383.15 388.15 393.15
P/bar 1690 1640 1610 1520 1470 1420 1609 1555 1515
xC 0.0396 0.0396 0.0396
T/K 403.15 413.15 423.15
P/bar 1442 1390 1340
Comments: The mole fraction xC is given for the monomer mixture, i.e., without the polymer.


xC 0.0075 0.0075 0.0075 0.0075 0.0075 0.0075 0.0075 0.0075 0.0075
T/K 343.15 353.15 363.15 373.15 383.15 393.15 403.15 413.15 423.15
P/bar 1510 1420 1370 1345 1315 1290 1272 1250 1215
xC 0.0094 0.0094 0.0094 0.0094 0.0094 0.0094 0.0094 0.0210 0.0210
T/K 363.15 373.15 383.15 393.15 403.15 413.15 423.15 343.15 353.15
P/bar 1330 1305 1270 1240 1240 1200 1200 1360 1320
xC 0.0210 0.0210 0.0210 0.0210 0.0210 0.0210 0.0210 0.0242 0.0242
T/K 363.15 373.15 383.15 393.15 403.15 413.15 423.15 343.15 353.15
P/bar 1290 1240 1210 1190 1165 1160 1140 1320 1270
xC 0.0242 0.0242 0.0242 0.0242 0.0242 0.0242 0.0242 0.0315 0.0315
T/K 363.15 373.15 383.15 393.15 403.15 413.15 423.15 343.15 353.15
P/bar 1250 1215 1195 1165 1145 1130 1110 1245 1220
continued
____________________________________________________________________________________
continued
xC 0.0315 0.0315 0.0315 0.0315 0.0315 0.0315 0.0315 0.0382 0.0382
T/K 363.15 373.15 383.15 393.15 403.15 413.15 423.15 343.15 353.15
P/bar 1180 1155 1130 1110 1100 1070 1050 1215 1165
xC 0.0382 0.0382 0.0382 0.0382 0.0382 0.0382
T/K 363.15 373.15 383.15 403.15 413.15 423.15
P/bar 1135 1120 1095 1060 1035 1010

xC 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030 0.0030
T/K 323.15 333.15 343.15 353.15 363.15 373.15 383.15 393.15 403.15
P/bar 1285 1260 1230 1195 1175 1155 1142 1130 1120
xC 0.0030 0.0030 0.0130 0.0130 0.0130 0.0130 0.0130 0.0130 0.0130
T/K 413.15 423.15 323.15 333.15 343.15 353.15 363.15 373.15 383.15
P/bar 1115 1095 1200 1160 1145 1120 1110 1090 1080
xC 0.0130 0.0130 0.0130 0.0130 0.0220 0.0220 0.0220 0.0220 0.0220
T/K 393.15 403.15 413.15 423.15 323.15 333.15 343.15 353.15 363.15
P/bar 1065 1050 1040 1035 1110 1090 1070 1060 1045
xC 0.0220 0.0220 0.0220 0.0220 0.0220 0.0360 0.0360 0.0360 0.0360
T/K 383.15 393.15 403.15 413.15 423.15 323.15 333.15 343.15 353.15
P/bar 1015 1010 1005 997 990 975 970 955 950
xC 0.0360 0.0360 0.0360 0.0360 0.0360 0.0360 0.0360
T/K 363.15 373.15 383.15 393.15 403.15 413.15 423.15
P/bar 940 930 925 920 915 910 890

Solvent (C): methyl acrylate C4H6O2 96-33-3
xC 0.0213 0.0213 0.0213 0.0213 0.0213 0.0213 0.0213 0.0431 0.0431
T/K 353.15 363.15 373.15 383.15 393.15 403.15 423.15 353.15 363.15
P/bar 1390 1350 1310 1290 1260 1230 1200 1300 1280
continued
____________________________________________________________________________________
continued
xC 0.0431 0.0431 0.0431 0.0431 0.0431 0.0431 0.0675 0.0675 0.0675
T/K 373.15 383.15 393.15 403.15 413.15 423.15 353.15 363.15 373.15
P/bar 1250 1220 1200 1170 1160 1130 1260 1200 1160
xC 0.0675 0.0675 0.0675 0.0675 0.0675
T/K 383.15 393.15 403.15 413.15 423.15
P/bar 1150 1125 1110 1095 1065

−1 −1
Solvent (C): 2-ethylhexyl acrylate C11H20O2 103-11-7
xC 0.0000 0.0000 0.0000 0.0324 0.0324 0.0324 0.0368 0.0368 0.0368
T/K 403.15 423.15 443.15 403.15 423.15 443.15 403.15 423.15 443.15
P/bar 1440 1390 1335 1240 1200 1100 1170 1140 1080

Solvent (C): n-butane C4H10 106-97-8
wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 145.0 135.3 127.3 121.2 116.6 113.0 134.0 125.9 119.1
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 113.6 109.6 106.2 125.4 117.8 111.7 107.1 103.7 101.0
Polymer (B): ethylene/1-hexene copolymer 2001DOE

continued
____________________________________________________________________________________
continued
wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 160.0 148.2 138.3 130.8 125.7 122.0 168.3 153.7 142.3
wA 0.750 0.750 0.750
wB 0.150 0.150 0.150
wC 0.100 0.100 0.100
T/K 393.15 413.15 433.15
P/MPa 134.0 128.2 124.0

−1 −1
Solvent (C): ethane C2H6 74-84-0

wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 151.7 140.7 133.4 126.3 120.8 116.5 147.1 136.8 129.1
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 123.0 118.1 114.3 143.2 133.5 125.5 120.0 116.0 112.0

Solvent (C): helium He 7440-59-7

wA 0.840 0.840 0.840 0.840 0.840 0.840 0.830 0.830 0.830
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.010 0.010 0.010 0.010 0.010 0.010 0.020 0.020 0.020
T/K 393.15 413.15 433.15 453.15 473.15 493.15 433.15 453.15 473.15
P/MPa 195.0 178.6 165.8 155.4 148.2 143.0 214.6 200.7 188.3
wA 0.830
wB 0.150
wC 0.020
T/K 493.15
P/MPa 176.8
____________________________________________________________________________________

Solvent (C): 1-hexene C6H12 592-41-6

wA 0.4255 0.4255 0.4255 0.2755 0.2755 0.2755
wB 0.1490 0.1490 0.1490 0.1390 0.1390 0.1390
wC 0.4255 0.4255 0.4255 0.5855 0.5855 0.5855
T/K 393.15 423.15 453.35 393.25 423.15 453.25
P/MPa 65.4 66.5 65.1 44.2 45.1 44.6


wA 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.4250 0.4250 0.4250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.4250 0.4250 0.4250
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 108.2 103.2 99.2 95.7 93.3 91.4 59.0 59.0 59.1
wA 0.4250 0.4250 0.4250 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4250 0.4250 0.4250 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 59.0 59.1 59.1 25.6 27.0 28.3 30.3 32.3 34.6


wA 0.6800 0.6800 0.6800 0.6800 0.6800 0.6800 0.4250 0.4250 0.4250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1700 0.1700 0.1700 0.1700 0.1700 0.1700 0.4250 0.4250 0.4250
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 118.5 112.0 106.4 102.5 99.6 96.9 63.7 63.6 63.1
wA 0.4250 0.4250 0.4250 0.1275 0.1275 0.1275 0.1275 0.1275 0.1725
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4250 0.4250 0.4250 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 62.6 62.3 62.1 12.7 15.4 17.8 19.9 21.9 23.5
____________________________________________________________________________________


wA 0.4558 0.4558 0.4558 0.4558
wB 0.1400 0.1400 0.1400 0.1400
wC 0.4042 0.4042 0.4042 0.4042
T/K 393.15 413.15 433.15 453.15
P/MPa 55.7 55.7 56.2 57.7
Polymer (B): ethylene/1-hexene copolymer 1999KIN

Solvent (D): n-butane C4H10 106-97-8

wA 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 99.9 95.8 91.6 89.7 87.7 86.0 90.5 87.2 84.6
wA 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 82.6 81.1 79.9 85.5 83.1 81.1 79.5 78.2 77.2
wA 0.4000 0.4000 0.4000 0.4000 0.4000 0.4000 0.3750 0.3750 0.3750
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4000 0.4000 0.4000 0.4000 0.4000 0.4000 0.3750 0.3750 0.3750
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 57.0 57.1 57.2 57.3 57.3 57.4 55.6 55.6 55.7
wA 0.3750 0.3750 0.3750 0.3500 0.3500 0.3500 0.3500 0.3500 0.3500
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.3750 0.3750 0.3750 0.3500 0.3500 0.3500 0.3500 0.3500 0.3500
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 55.8 55.9 56.1 54.9 54.9 55.1 55.4 55.6 55.6
continued
____________________________________________________________________________________
continued
wA 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1785
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 25.1 26.6 27.7 29.7 32.0 34.0 23.7 25.1 26.6
wA 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 28.6 30.8 33.1 23.4 24.9 26.5 28.4 30.6 32.8

−1 −1
Solvent (D): helium He 7440-59-7

wA 0.6300 0.6300 0.6300 0.6300 0.6300 0.6300 0.6225 0.6225 0.6225
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2100 0.2100 0.2100 0.2100 0.2100 0.2100 0.2075 0.2075 0.2075
wD 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 0.0200 0.0200
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 150.3 139.9 131.5 125.1 119.9 115.5 200.5 185.5 172.6
wA 0.6225 0.6225 0.6225 0.4200 0.4200 0.4200 0.4200 0.4200 0.4200
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2075 0.2075 0.2075 0.4200 0.4200 0.4200 0.4200 0.4200 0.4200
wD 0.0200 0.0200 0.0200 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 161.4 152.5 147.7 100.0 95.1 91.2 88.2 86.1 84.4
wA 0.4150 0.4150 0.4150 0.4150 0.4150 0.4150 0.4100 0.4100 0.4100
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4150 0.4150 0.4150 0.4150 0.4150 0.4150 0.4100 0.4100 0.4100
wD 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 149.7 139.0 130.5 123.6 118.2 113.6 209.9 189.9 172.9
wA 0.4100 0.4100 0.4100 0.2100 0.2100 0.2100 0.2100 0.2100 0.2100
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4100 0.4100 0.4100 0.6300 0.6300 0.6300 0.6300 0.6300 0.6300
wD 0.0300 0.0300 0.0300 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 161.6 153.8 148.4 54.4 54.6 54.5 54.3 54.0 54.0
continued
____________________________________________________________________________________
continued
wA 0.2075 0.2075 0.2075 0.2075 0.2075 0.2075 0.2050 0.2050 0.2050
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6225 0.6225 0.6225 0.6225 0.6225 0.6225 0.6150 0.6150 0.6150
wD 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 93.3 88.8 85.1 82.1 79.8 78.0 134.5 127.1 121.7
wA 0.2050 0.2050 0.2050
wB 0.1500 0.1500 0.1500
wC 0.6150 0.6150 0.6150
wD 0.0300 0.0300 0.0300
T/K 453.15 473.15 493.15
P/MPa 117.1 113.3 110.2

Solvent (D): methane CH4 74-82-8

wA 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 123.0 117.5 112.4 108.1 104.7 102.0 137.2 129.7 124.2
wA 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 119.6 115.8 112.8 151.9 144.0 137.1 131.4 127.0 123.4
wA 0.4000 0.4000 0.4000 0.4000 0.4000 0.4000 0.3750 0.3750 0.3750
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4000 0.4000 0.4000 0.4000 0.4000 0.4000 0.3750 0.3750 0.3750
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 83.0 80.9 79.0 77.4 76.0 74.8 100.5 97.1 94.0
wA 0.3750 0.3750 0.3750 0.3500 0.3500 0.3500 0.3500 0.3500 0.3500
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.3750 0.3750 0.3750 0.3500 0.3500 0.3500 0.3500 0.3500 0.3500
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 91.3 89.1 87.2 121.6 115.2 109.6 105.4 101.9 99.0
continued
____________________________________________________________________________________
continued
wA 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1785
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 40.9 42.5 44.0 45.5 46.9 48.3 58.6 58.8 59.1
wA 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 59.2 59.4 59.5 82.5 81.0 79.6 78.5 77.4 76.6

−1 −1
Solvent (D): nitrogen N2 7727-37-9

wA 0.6400 0.6400 0.6400 0.6400 0.6400 0.6400 0.6000 0.6000 0.6000
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1500 0.1500 0.1500
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 141.5 131.7 123.8 117.7 112.9 109.5 166.4 151.7 141.4
wA 0.6000 0.6000 0.6000 0.4000 0.4000 0.4000 0.4000 0.4000 0.4000
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1500 0.1500 0.1500 0.4000 0.4000 0.4000 0.4000 0.4000 0.4000
wD 0.1000 0.1000 0.1000 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 132.8 126.5 122.0 85.3 81.9 79.2 77.0 75.7 74.2
wA 0.3750 0.3750 0.3750 0.3750 0.3750 0.3750 0.1200 0.1200 0.1200
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.3750 0.3750 0.3750 0.3750 0.3750 0.3750 0.6800 0.6800 0.6800
wD 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.0500 0.0500 0.0500
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 114.6 107.7 100.3 96.1 91.6 88.7 28.4 29.9 31.3
wA 0.1200 0.1200 0.1200 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6800 0.6800 0.6800 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
wD 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 32.6 33.8 34.9 49.1 48.8 48.6 48.6 48.8 49.0
____________________________________________________________________________________

Solvent (C): methane CH4 74-82-8

wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 169.0 156.7 147.1 139.4 132.4 126.4 186.5 170.5 157.8
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 149.0 142.0 137.5 202.0 186.9 174.0 162.8 153.7 149.1


wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 179.5 166.8 153.3 144.8 138.0 134.4 206.5 188.6 173.2
wA 0.750 0.750 0.750
wB 0.150 0.150 0.150
wC 0.100 0.100 0.100
T/K 453.15 473.15 493.15
P/MPa 161.8 152.8 145.6

Solvent (C): propane C3H8 74-98-6

wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 145.8 136.0 128.1 122.1 117.4 113.6 138.3 129.3 123.3
continued
____________________________________________________________________________________
continued
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 117.1 113.3 110.0 130.3 122.1 116.0 111.8 108.9 106.6

Characterization: Mn/kg.mol−1 = 40.9, Mw/kg.mol−1 = 90, 13.6 wt% 1-hexene,
MI = 1.2, ρ = 0.904 g/cm3, Tm/K = 406.25
wA 0.892 0.892 0.892 0.892 0.892 0.892 0.892 0.892 0.892
wB 0.108 0.108 0.108 0.108 0.108 0.108 0.108 0.108 0.108
wC 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
T/K 378.45 386.75 393.05 394.05 400.05 407.75 415.55 421.95 422.75
P/bar 333.5 334.5 336.4 336.8 338.1 340.8 342.8 343.4 344.1
wA 0.84835 0.84835 0.84835 0.84835 0.84835 0.84835 0.84835 0.84835 0.84835
wB 0.107 0.107 0.107 0.107 0.107 0.107 0.107 0.107 0.107
wC 0.04465 0.04465 0.04465 0.04465 0.04465 0.04465 0.04465 0.04465 0.04465
T/K 368.35 373.55 378.85 385.75 393.45 400.05 408.45 415.45 423.75
P/bar 301.55 302.95 304.15 307.55 311.55 313.6 317.95 321.55 324.8
wA 0.40275 0.40275 0.40275 0.40275 0.40275 0.40275
wB 0.105 0.105 0.105 0.105 0.105 0.105
wC 0.49225 0.49225 0.49225 0.49225 0.49225 0.49225
T/K 367.15 373.15 376.35 377.85 383.35 393.15
P/bar 32.5 41.5 46.2 48.9 56.4 71.1

xC 0.0129 0.0129 0.0129 0.0129 0.0129 0.0129 0.0288 0.0288 0.0288
T/K 373.15 383.15 393.15 403.15 413.15 423.15 383.15 393.15 403.15
P/bar 1645 1570 1520 1485 1470 1440 1480 1435 1415
xC 0.0288 0.0288 0.0305 0.0305 0.0305 0.0305 0.0305 0.0403 0.0403
T/K 413.15 423.15 383.15 393.15 403.15 413.15 423.15 373.15 383.15
P/bar 1390 1360 1450 1410 1390 1370 1370 1440 1420
xC 0.0403 0.0403 0.0403 0.0403
T/K 393.15 403.15 413.15 423.15
P/bar 1375 1340 1340 1320
Comments: The mole fraction xC is given for the solvent mixture, i.e., without the polymer.
____________________________________________________________________________________

Solvent (C): 2-ethylhexyl acrylate C11H20O2 103-11-7

xC 0.0120 0.0120 0.0120 0.0185 0.0185 0.0185 0.0194 0.0194 0.0194
T/K 403.15 423.15 443.15 403.15 423.15 443.15 403.15 423.15 443.15
P/bar 1390 1340 1290 1370 1250 1210 1290 1275 1260
xC 0.0324 0.0324 0.0324 0.0339 0.0339 0.0339
T/K 403.15 423.15 443.15 403.15 423.15 443.15
P/bar 1240 1200 1140 1250 1170 1190


xC 0.0136 0.0136 0.0136 0.0136 0.0136 0.0261 0.0261 0.0261 0.0261
T/K 383.15 393.15 403.15 413.15 423.15 383.15 393.15 403.15 413.15
P/bar 1500 1460 1405 1380 1360 1420 1400 1370 1340
xC 0.0261 0.0414 0.0414 0.0414 0.0414 0.0414 0.0599 0.0599 0.0599
T/K 423.15 383.15 393.15 403.15 413.15 423.15 383.15 393.15 403.15
P/bar 1300 1350 1315 1290 1255 1250 1240 1225 1210
xC 0.0599 0.0599 0.0977 0.0977 0.0977 0.0977
T/K 413.15 423.15 383.15 403.15 413.15 423.15
P/bar 1165 1150 1000 975 970 950

Solvent (C): methyl acrylate C4H6O2 96-33-3

continued
____________________________________________________________________________________
continued
xC 0.0144 0.0144 0.0144 0.0144 0.0144 0.0590 0.0590 0.0590 0.0590
T/K 393.15 403.15 423.15 433.15 443.15 383.15 393.15 403.15 413.15
P/bar 1550 1470 1440 1440 1410 1400 1390 1380 1365
xC 0.0590 0.0855 0.0855 0.0855 0.0855 0.0855 0.0855 0.0855 0.0855
T/K 423.15 373.15 383.15 393.15 403.15 413.15 423.15 433.15 443.15
P/bar 1350 1300 1290 1300 1340 1370 1350 1380 1360

−1 −1
Solvent (C): 1-butene C4H8 106-98-9
wA 0.074 0.074 0.074 0.074 0.074 0.074 0.117 0.117 0.117
wB 0.187 0.187 0.187 0.187 0.187 0.187 0.162 0.162 0.162
wC 0.739 0.739 0.739 0.739 0.739 0.739 0.721 0.721 0.721
T/K 355.35 373.45 398.15 423.15 448.15 473.55 355.35 373.35 398.25
P/bar 144.0 177.0 215.3 250.3 278.0 303.0 200.4 232.0 266.4
wA 0.117 0.117 0.117 0.234 0.234 0.234 0.234
wB 0.162 0.162 0.162 0.154 0.154 0.154 0.154
wC 0.721 0.721 0.721 0.612 0.612 0.612 0.612
T/K 423.15 447.95 473.45 355.35 373.55 398.15 423.25
P/bar 296.8 322.0 344.5 318.5 340.2 365.0 389.0

wA 0.9025 0.9025 0.9025 0.9025 0.9025 0.9025 0.9025 0.8550 0.8550
wB 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500
wC 0.0475 0.0475 0.0475 0.0475 0.0475 0.0475 0.0475 0.0950 0.0950
T/K 312.59 317.69 322.45 327.31 332.20 336.74 342.05 312.44 317.45
P/bar 2342 2204 2094 1996 1910 1844 1764 2585 2413
wA 0.8550 0.8550 0.8550 0.8550 0.8550 0.8075 0.8075 0.8075 0.8075
wB 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500
wC 0.0950 0.0950 0.0950 0.0950 0.0950 0.1425 0.1425 0.1425 0.1425
T/K 322.59 327.36 332.22 337.07 342.01 312.67 317.61 322.38 327.24
P/bar 2263 2144 2041 1949 1871 2959 2712 2519 2355
continued
____________________________________________________________________________________
continued
wA 0.8075 0.8075 0.8075 0.7600 0.7600 0.7600 0.7600 0.7600 0.7600
wB 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500
wC 0.1425 0.1425 0.1425 0.1900 0.1900 0.1900 0.1900 0.1900 0.1900
T/K 332.15 337.04 341.86 312.43 317.52 322.42 327.33 332.19 337.15
P/bar 2218 2101 2001 3705 3240 2913 2666 2470 2311
wA 0.7600 0.8550 0.8550 0.8550 0.8550 0.8550 0.8550 0.8550 0.8100
wB 0.0500 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000
wC 0.1900 0.0450 0.0450 0.0450 0.0450 0.0450 0.0450 0.0450 0.0900
T/K 342.00 312.57 317.48 322.32 327.21 332.18 336.83 342.08 312.68
P/bar 2181 2265 2140 2032 1938 1858 1785 1718 2496
wA 0.8100 0.8100 0.8100 0.8100 0.8100 0.8100 0.7650 0.7650 0.7650
wB 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000
wC 0.0900 0.0900 0.0900 0.0900 0.0900 0.0900 0.1350 0.1350 0.1350
T/K 2334 2193 2081 1981 1894 1818 2900 2654 2457
wA 0.7650 0.7650 0.7650 0.7650 0.7200 0.7200 0.7200 0.7200 0.7200
wB 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000 0.1000
wC 0.1350 0.1350 0.1350 0.1350 0.1800 0.1800 0.1800 0.1800 0.1800
T/K 327.41 332.17 336.99 342.23 312.50 317.48 322.35 327.28 332.16
P/bar 2290 2166 2055 1950 3665 3191 2867 2618 2419
wA 0.7200 0.7200
wB 0.1000 0.1000
wC 0.1800 0.1800
T/K 337.30 342.12
P/bar 2258 2132

−1 −1

wA = 0.122 wB = 0.158 wC = 0.820
T/K 299.65 323.15 353.45 373.65 384.05 397.15 405.75 413.15 422.15
P/bar 16.9 23.0 32.1 38.5 41.2 44.0 58.0 68.0 85.0
(VLE VLE VLE VLE VLE VLE LLE LLE LLE)
T/K 424.75 433.45 447.65 463.65 468.55 473.35 424.75 433.45 447.65
P/bar 89.2 100.0 124.0 138.0 144.0 148.0 53.1 54.1 59.8
(LLE LLE LLE LLE LLE LLE VLLE VLLE VLLE)
T/K 468.15
P/bar 63.2
(VLLE)
continued
____________________________________________________________________________________
continued
wA = 0.243 wB = 0.150 wC = 0.607
T/K 300.65 306.15 314.15 321.85 353.75 371.95 395.85 425.55 447.85
P/bar 28.0 31.7 43.0 56.5 114.0 144.0 179.0 222.0 246.0
(VLE VLE LLE LLE LLE LLE LLE LLE LLE)
T/K 472.55 315.95 323.35 341.15 353.75 371.95 395.85 424.15
P/bar 266.0 35.0 39.2 47.0 55.6 63.4 73.0 81.2
(LLE VLLE VLLE VLLE VLLE VLLE VLLE VLLE)
wA = 0.355 wB = 0.153 wC = 0.492
T/K 251.15 264.65 271.15 282.75 295.45 311.65 324.65 355.45 373.45
P/bar 187.0 176.0 175.0 182.5 194.7 216.5 233.0 269.0 290.0
(LLE LLE LLE LLE LLE LLE LLE LLE LLE)
T/K 398.15 423.95 449.15 473.45 258.85 282.75 295.45 311.65 324.65
P/bar 320.5 348.0 370.0 384.0 17.2 30.0 36.5 45.8 55.0
(LLE LLE LLE LLE VLLE VLLE VLLE VLLE VLLE)
T/K 355.45 373.45 398.15
P/bar 75.5 85.0 91.8
(VLLE VLLE VLLE)
wA = 0.504 wB = 0.149 wC = 0.347
T/K 296.05 310.85 325.75 343.25 358.85 374.85 397.25 424.15 446.55
P/bar 488.0 464.0 456.0 452.0 459.0 468.0 479.0 492.0 502.0
T/K 469.65 295.65 311.15 325.95 343.25 358.85 374.85
P/bar 511.0 48.6 59.4 70.0 79.0 88.6 92.0
(LLE VLLE VLLE VLLE VLLE VLLE VLLE)

Polymer (C): ethylene/propylene copolymer
Characterization: Mn/kg.mol−1 = 177, Mw/kg.mol−1 = 195, 50 mol% propene,

Comments: The weight ratio of wB/wC was kept constant at 75/25 = 3/1 and the resulting molar
mass averages are Mn/kg.mol−1 = 3.47 and Mw/kg.mol−1 = 51.
wB+wC 0.012 0.012 0.012 0.050 0.050 0.050 0.100 0.100 0.100
T/K 322.95 372.85 423.15 323.45 373.05 423.05 323.15 372.95 423.35
P/bar 324.5 375.1 424.6 310.3 364.5 417.1 282.0 340.8 396.8
continued
____________________________________________________________________________________
continued
T/K = 423.15
______________________________________________________
P/ wB
______________________________________________________
356 0.050 unknown 0.041
______________________________________________________

Polymer (C): ethylene/propylene copolymer
Characterization: Mn/kg.mol−1 = 177, Mw/kg.mol−1 = 195, 50 mol% propene,
Solvent (D): n-dodecane C12H26 112-40-3

Comments: The weight ratio of wB/wC/wD was kept constant at 3/1/1 and the resulting molar mass
averages are Mn/kg.mol−1 = 3.47 and Mw/kg.mol−1 = 51.
wA 0.05 0.05 0.05
T/K 323.15 372.95 423.05
P/bar 282.0 340.8 396.8

−1 −1
Characterization: Mn/kg.mol = 61.9, Mw/kg.mol = 167, 27.5 wt% vinyl acetate

wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 127.7 123.0 119.2 115.9 113.0 110.2 128.5 123.8 120.1
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 117.0 113.9 111.2 130.3 125.7 121.8 118.9 115.8 113.1
____________________________________________________________________________________


wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 125.6 121.2 117.2 113.9 110.8 108.0 126.0 121.5 117.3
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 114.0 111.3 108.4 124.8 120.0 115.8 112.4 109.7 107.5

Solvent (C): helium He 7440-59-7

wA 0.955 0.955 0.955 0.955 0.955 0.955 0.920 0.920 0.920
wB 0.035 0.035 0.035 0.035 0.035 0.035 0.070 0.070 0.070
wC 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 163.6 156.1 149.2 142.8 137.5 132.7 168.1 159.3 151.5
wA 0.920 0.920 0.920 0.870 0.870 0.870 0.870 0.870 0.870
wB 0.070 0.070 0.070 0.120 0.120 0.120 0.120 0.120 0.120
wC 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 145.4 139.9 135.3 165.2 157.6 150.7 144.6 139.2 134.5
wA 0.840 0.840 0.840 0.840 0.840 0.840 0.790 0.790 0.790
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.200 0.200 0.200
wC 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 163.8 156.2 149.4 143.3 137.9 133.3 163.2 155.7 148.8
wA 0.790 0.790 0.790 0.640 0.640 0.640 0.640 0.640 0.640
wB 0.200 0.200 0.200 0.350 0.350 0.350 0.350 0.350 0.350
wC 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 142.5 137.5 132.6 158.7 150.1 142.7 137.4 132.5 128.4
____________________________________________________________________________________


wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 146.5 140.5 135.8 130.5 125.4 120.5 172.5 164.7 155.6
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 148.8 142.5 137.5 193.0 184.8 176.8 168.9 161.4 154.4


wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 122.0 117.7 113.6 110.5 107.6 104.9 116.3 112.4 109.0
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 105.8 103.4 100.8 112.9 109.2 105.9 103.0 100.4 98.0

−1 −1
Solvent (C): vinyl acetate C4H6O2 108-05-4

T/K = 403.15
Total feed concentrations of the homogeneous system before demixing:
wA = 0.590, wB = 0.153, wC = 0.257.
continued
____________________________________________________________________________________
continued
________________________________________________________________________________________________________
P/ wA wB wC wA wB wC
________________________________________________________________________________________________________
56.5 0.311 0.542 0.147
75.5 0.683 0.016 0.301
87.8 0.450 0.352 0.198 0.678 0.023 0.299
100.2 0.546 0.212 0.242 0.660 0.048 0.292
104.1 0.590 0.153 0.257 (cloud point)
________________________________________________________________________________________________________
T/K = 403.15
wA = 0.347, wB = 0.157, wC = 0.496.
________________________________________________________________________________________________________
________________________________________________________________________________________________________
58.5 0.387 0.037 0.576
68.0 0.322 0.215 0.463 0.380 0.056 0.564
72.7 0.347 0.157 0.496 (cloud point)
________________________________________________________________________________________________________
T/K = 433.15
wA = 0.254, wB = 0.155, wC = 0.591.
________________________________________________________________________________________________________
________________________________________________________________________________________________________
48.7 0.231 0.230 0.539 0.277 0.050 0.673
53.4 0.254 0.155 0.591 (cloud point)
________________________________________________________________________________________________________

wA 0.422 0.422 0.422 0.217 0.217 0.217 0.120 0.120 0.120
wB 0.159 0.159 0.159 0.156 0.156 0.156 0.298 0.298 0.298
wC 0.419 0.419 0.419 0.627 0.627 0.627 0.582 0.582 0.582
T/K 373.15 403.15 433.15 373.15 403.15 433.15 378.15 388.15 403.15
P/MPa 75.3 69.8 68.0 45.8 38.3 39.0 21.4 19.5 18.0
continued
____________________________________________________________________________________
continued
wA 0.120 0.120 0.120
wB 0298 0.298 0.298
wC 0.582 0.582 0.582
T/K 423.15 433.15 443.15
P/MPa 19.4 20.5 22.2

T/K = 433.15
wA = 0.217, wB = 0.156, wC = 0.627.
________________________________________________________________________________________________________
________________________________________________________________________________________________________
27.5 0.160 0.360 0.480 0.251 0.041 0.708

33.5 0.188 0.276 0.536 0.242 0.061 0.697
39.0 0.217 0.156 0.627 (cloud point)
________________________________________________________________________________________________________
T/K = 433.15
wA = 0.343, wB = 0.136, wC = 0.521.
________________________________________________________________________________________________________
________________________________________________________________________________________________________
19.9 0.4042 0.0004 0.5954

43.0 0.256 0.361 0.383 0.3936 0.0127 0.5937
57.3 0.343 0.136 0.521 (cloud point)
________________________________________________________________________________________________________
T/K = 433.15
wA = 0.422, wB = 0.159, wC = 0.419.
________________________________________________________________________________________________________
________________________________________________________________________________________________________
37.7 0.221 0.532 0.247 0.498 0.025 0.477

50.0 0.288 0.404 0.308 0.487 0.038 0.475
61.9 0.365 0.272 0.363 0.476 0.062 0.462
68.0 0.422 0.159 0.419 (cloud point)
________________________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
wA = 0.645, wB = 0.158, wC = 0.197.
________________________________________________________________________________________________________
________________________________________________________________________________________________________
30.4 0.176 0.760 0.064 0.779 0.0008 0.221

43.7 0.244 0.670 0.086 0.766 0.0009 0.233
66.6 0.370 0.506 0.124 0.754 0.0130 0.233
86.0 0.513 0.325 0.162 0.736 0.0290 0.235
97.2 0.645 0.158 0.197 (cloud point)
________________________________________________________________________________________________________
T/K = 463.15
wA = 0.460, wB = 0.135, wC = 0.405.
________________________________________________________________________________________________________
________________________________________________________________________________________________________
47.3 0.273 0.506 0.221 0.582 0.012 0.406

58.8 0.346 0.363 0.291 0.546 0.051 0.403
70.7 0.460 0.135 0.405 (cloud point)
____________________________________________________________________________________
Fractionation during demixing

________________________________________________________________________________________________________
Demixing molar mass averages

pressure bottom phase top phase
________________________________________________________________________________________________________
________________________________________________________________________________________________________
47.3 5.61 13.63 27.45

58.8 11.96 26.06 44.20
70.7 33.4 137.7 (feed sample)
________________________________________________________________________________________________________

−1 −1
continued
____________________________________________________________________________________
continued
wA 0.317 0.317 0.317 0.317 0.317 0.317 0.340 0.340 0.413
wB 0.360 0.360 0.360 0.360 0.360 0.360 0.322 0.322 0.207
wC 0.323 0.323 0.323 0.323 0.323 0.323 0.338 0.338 0.380
T/K 363.15 373.15 393.15 413.15 438.15 453.15 383.15 433.15 403.15
P/MPa 52.3 53.1 54.0 55.2 57.2 58.5 62.4 64.5 75.4
wA 0.413 0.505 0.505 0.505 0.505 0.505 0.631 0.631 0.631
wB 0.207 0.257 0.257 0.257 0.257 0.257 0.187 0.187 0.187
wC 0.380 0.238 0.238 0.238 0.238 0.238 0.182 0.182 0.182
T/K 433.15 363.15 383.15 403.15 438.15 453.15 363.15 383.15 403.15
P/MPa 75.1 88.3 86.1 83.7 82.0 81.8 106.8 102.8 100.0
wA 0.631 0.795 0.795 0.795
wB 0.187 0.105 0.105 0.105
wC 0.182 0.100 0.100 0.100
T/K 443.15 383.15 403.15 433.15
P/MPa 96.5 122.0 118.5 113.0

−1 −1
Characterization: Mn/kg.mol = 35, Mw/kg.mol = 126.5, 27.5 wt% vinyl acetate,
wA 0.594 0.594 0.594 0.200 0.200 0.200
wB 0.148 0.148 0.148 0.152 0.152 0.152
wC 0.258 0.258 0.258 0.648 0.648 0.648
T/K 398.15 403.15 433.15 401.15 413.15 433.15
P/MPa 90.2 86.4 84.6 26.1 27.2 29.0

T/K = 403.15
wA = 0.353, wB = 0.159, wC = 0.488.
________________________________________________________________________________________________________
________________________________________________________________________________________________________
30.7 0.415 0.016 0.569
31.2 0.220 0.446 0.334
39.1 0.409 0.025 0.563
39.7 0.255 0.349 0.396
46.7 0.319 0.224 0.457 0.403 0.044 0.553
49.5 0.353 0.159 0.488 (cloud point)
________________________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 433.15
wA = 0.594, wB = 0.148, wC = 0.258.
____________________________________________________________________________________
____________________________________________________________________________________
35.5 0.204 0.702 0.094
48.2 0.273 0.613 0.114 0.709 0.008 0.283
56.6 0.322 0.551 0.127 0.705 0.013 0.282
67.0 0.392 0.447 0.161 0.692 0.020 0.288
78.6 0.500 0.290 0.210 0.677 0.040 0.283
84.6 0.594 0.148 0.258 (cloud point)
____________________________________________________________________________________
T/K = 433.15
wA = 0.349, wB = 0.152, wC = 0.499.
____________________________________________________________________________________
____________________________________________________________________________________
27.8 0.176 0.529 0.295 0.419 0.012 0.567
35.8 0.221 0.439 0.340 0.413 0.021 0.566
46.2 0.289 0.308 0.403 0.402 0.051 0.547
51.0 0.349 0.152 0.499 (cloud point)
____________________________________________________________________________________
T/K = 433.15
wA = 0.200, wB = 0.152, wC = 0.648.
____________________________________________________________________________________
____________________________________________________________________________________
14.5 0.140 0.400 0.460 0.238 0.014 0.748
19.5 0.154 0.356 0.490 0.231 0.031 0.738
26.0 0.181 0.233 0.586 0.228 0.051 0.721
29.0 0.200 0.152 0.648 (cloud point)
____________________________________________________________________________________
____________________________________________________________________________________


wA 0.6715 0.6715 0.6715 0.6715 0.6715 0.6715 0.6375 0.6375 0.6375
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1785 0.1785 0.1785 0.1785 0.1785 0.1785 0.2125 0.2125 0.2125
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 99.5 97.5 95.5 94.1 92.7 91.5 94.3 92.6 91.1
wA 0.6375 0.6375 0.6375 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2125 0.2125 0.2125 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 89.8 88.6 87.5 60.7 61.1 61.6 62.0 62.4 62.7
wA 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.0850 0.0850 0.0850
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.7650 0.7650 0.7650
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 26.7 28.9 30.9 33.1 34.8 37.6 4.8 7.1 9.8
wA 0.0850 0.0850 0.0850
wB 0.1500 0.1500 0.1500
wC 0.7650 0.7650 0.7650
T/K 453.15 473.15 493.15
P/MPa 13.2 17.5 19.5
wA 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250 0.3060 0.3060
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250 0.5440 0.5440
T/K 348.15 353.15 358.15 368.15 383.15 393.15 423.15 348.15 353.15
P/MPa 48.7 47.5 46.8 46.7 47.5 48.0 50.8 42.2 41.4
wA 0.3060 0.3060 0.3060 0.3060 0.3060 0.3060 0.3060 0.3060 0.3060
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.5440 0.5440 0.5440 0.5440 0.5440 0.5440 0.5440 0.5440 0.5440
T/K 358.15 368.15 373.15 383.15 393.15 403.15 423.15 443.15 463.15
P/MPa 41.0 40.9 41.0 41.1 41.5 42.0 43.9 45.3 46.9
wA 0.0850 0.0850 0.0850 0.0850 0.0850 0.0850 0.0850 0.0850 0.0850
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.7650 0.7650 0.7650 0.7650 0.7650 0.7650 0.7650 0.7650 0.7650
T/K 341.15 343.15 348.15 353.15 358.15 368.15 373.15 383.15 403.15
P/MPa 4.8 3.5 2.9 2.8 2.7 3.0 3.4 4.0 5.7
wA 0.0850 0.0850 0.0850
wB 0.1500 0.1500 0.1500
wC 0.7650 0.7650 0.7650
T/K 423.15 443.15 463.15
P/MPa 8.6 11.0 15.5
continued
____________________________________________________________________________________
continued
wA 0.4825 0.4825 0.4825 0.4825 0.4825 0.4825 0.4600 0.4600 0.4600
wB 0.0350 0.0350 0.0350 0.0350 0.0350 0.0350 0.0800 0.0800 0.0800
wC 0.4825 0.4825 0.4825 0.4825 0.4825 0.4825 0.4600 0.4600 0.4600
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 59.0 59.9 60.6 61.2 61.6 61.9 61.9 62.3 62.9
wA 0.4600 0.4600 0.4600 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250
wB 0.0800 0.0800 0.0800 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4600 0.4600 0.4600 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 63.3 63.8 64.1 60.7 61.1 61.6 62.0 62.4 62.7
wA 0.3750 0.3750 0.3750 0.3750 0.3750 0.3750
wB 0.2500 0.2500 0.2500 0.2500 0.2500 0.2500
wC 0.3750 0.3750 0.3750 0.3750 0.3750 0.3750
T/K 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 53.8 54.9 56.0 56.9 58.0 58.9
wA 0.3450 0.3450 0.3450 0.3450 0.3450 0.3450 0.3400 0.3400 0.3400
wB 0.3100 0.3100 0.3100 0.3100 0.3100 0.3100 0.3200 0.3200 0.3200
wC 0.3450 0.3450 0.3450 0.3450 0.3450 0.3450 0.3400 0.3400 0.3400
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 47.5 49.2 50.7 52.1 53.5 54.7 49.0 50.4 51.8
wA 0.3400 0.3400 0.3400 0.3250 0.3250 0.3250 0.3250 0.3250 0.3250
wB 0.3200 0.3200 0.3200 0.3500 0.3500 0.3500 0.3500 0.3500 0.3500
wC 0.3400 0.3400 0.3400 0.3250 0.3250 0.3250 0.3250 0.3250 0.3250
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 53.2 54.5 55.7 48.6 50.1 51.6 53.0 54.3 55.5
wA 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750
wB 0.4500 0.4500 0.4500 0.4500 0.4500 0.4500
wC 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750
T/K 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 42.8 44.6 46.2 47.7 49.1 50.3
Polymer (B): ethylene/vinyl acetate copolymer 1984WOH

Characterization: Mn/kg.mol−1 = 15.5, Mw/kg.mol−1 = 40.8, 32.3 wt% vinyl acetate
Comments: The total monomer weight fraction ratio wA/wC = 64/36 was kept constant.
wB 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15 0.20
T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 80.4 77.8 75.8 73.3 71.3 78.3 76.8 75.0 72.3
wB 0.30 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15
T/K 413.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 70.3 76.8 76.0 74.0 70.3 68.8 76.3 74.8 73.3
wB 0.20 0.30
T/K 453.15 453.15
P/MPa 68.8 67.8
____________________________________________________________________________________

wA 0.761 0.761 0.761 0.761 0.761 0.657 0.657 0.657 0.657
wB 0.073 0.073 0.073 0.073 0.073 0.136 0.136 0.136 0.136
wC 0.166 0.166 0.166 0.166 0.166 0.207 0.207 0.207 0.207
T/K 348.15 373.15 403.15 433.15 453.15 373.15 403.15 433.15 453.15
P/MPa 65.8 65.4 65.8 66.8 67.8 84.9 82.9 81.4 80.6
wA 0.505 0.505 0.505 0.361 0.361 0.361 0.430 0.430 0.521
wB 0.184 0.184 0.184 0.246 0.246 0.246 0.273 0.273 0.084
wC 0.311 0.311 0.311 0.393 0.393 0.393 0.297 0.297 0.395
T/K 358.15 383.15 438.15 373.15 403.15 433.15 373.15 433.15 373.15
P/MPa 98.1 94.6 90.2 53.4 55.6 58.5 63.1 64.3 61.7
wA 0.521
wB 0.084
wC 0.395
T/K 433.15
P/MPa 64.1

T/K = 473.15
wA = 0.4395, wB = 0.2500, wC = 0.2565.
____________________________________________________________________________________
____________________________________________________________________________________
28.15 0.1554 0.7016 0.1489
29.32 0.1640 0.6923 0.1515 0.6095 0.0700 0.3299
31.28 0.1720 0.7010 0.1498 0.6801 0.0090 0.3305
32.54 0.1863 0.6719 0.1600 0.6573 0.0307 0.3314
36.19 0.1968 0.6550 0.1507
38.05 0.2118 0.6400 0.1557 0.6211 0.0314 0.3279
50.12 0.2594 0.6017 0.1591 0.6653 0.0381 0.3331
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
____________________________________________________________________________________
51.40 0.2736 0.5415 0.1870 0.6590 0.0266 0.3318
52.54 0.3404 0.4725 0.2066 0.6541 0.0300 0.3441
59.01 0.3348 0.4848 0.2051 0.6361 0.0552 0.3302
64.90 0.3782 0.4188 0.2262 0.6550 0.0692 0.3210
66.94 0.4114 0.3811 0.2295 0.6427 0.0483 0.3296
71.00 0.4675 0.3011 0.2425 0.6232 0.0734 0.3230
____________________________________________________________________________________
T/K = 473.15
wA = 0.4125, wB = 0.2500, wC = 0.3375.
____________________________________________________________________________________
____________________________________________________________________________________
20.11 0.1116 0.7008 0.1876 0.5426 0.0392 0.4182
20.70 0.1193 0.6861 0.1947 0.5672 0.0000 0.4328
20.99 0.1171 0.6957 0.1872 0.5395 0.0169 0.4436
21.09 0.1166 0.6876 0.1959 0.5397 0.0303 0.4299
21.68 0.1191 0.6864 0.1944 0.5416 0.0299 0.4284
21.68 0.1204 0.6815 0.1981 0.5366 0.0214 0.4420
29.32 0.1650 0.6410 0.2009 0.5621 0.0232 0.4292
30.70 0.1742 0.6255 0.2047 0.5571 0.0330 0.4217
36.58 0.2132 0.5672 0.2132 0.5274 0.0362 0.4432
38.35 0.2273 0.5445 0.2405 0.5283 0.0414 0.4431
42.77 0.2487 0.6113 0.2400 0.5705 0.0215 0.4070
44.63 0.2630 0.4983 0.2387 0.5659 0.0281 0.4060
48.16 0.2846 0.4441 0.2714 0.5340 0.0547 0.4112
49.15 0.3009 0.4163 0.2828 0.5317 0.0330 0.4350
50.81 0.3188 0.3966 0.2846 0.5334 0.0512 0.4154
51.60 0.3308 0.3757 0.2935 0.4975 0.0870 0.4155
56.99 0.3618 0.3357 0.3025 0.5201 0.0696 0.4102
60.43 0.3881 0.2553 0.3567 0.5047 0.0974 0.3979
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 35, 58.0 wt% vinyl acetate,
continued
____________________________________________________________________________________
continued
wA 0.096 0.096 0.096 0.148 0.152 0.152 0.160 0.196 0.196
wB 0.200 0.200 0.200 0.214 0.214 0.214 0.205 0.198 0.198
wC 0.704 0.704 0.704 0.638 0.642 0.642 0.635 0.606 0.606
T/K 363.15 393.15 423.15 393.15 363.15 393.15 393.15 363.15 393.15
P/MPa 4.2 5.3 6.8 7.9 6.3 8.4 9.8 12.0 18.0
wA 0.196 0.299 0.401 0.401 0.401
wB 0.198 0.203 0.204 0.204 0.204
wC 0.606 0.498 0.405 0.405 0.405
T/K 423.15 363.15 363.15 393.15 423.15
P/MPa 23.3 36.0 65.0 64.5 64.2

T/K = 393.15
wA = 0.167, wB = 0.219, wC = 0.614.
____________________________________________________________________________________
____________________________________________________________________________________
8.3 0.231 0.013 0.756
8.65 0.128 0.350 0.522
9.6 0.130 0.337 0.533 0.227 0.021 0.752
11.0 0.151 0.286 0.563
11.65 0.217 0.050 0.733
12.1 0.167 0.219 0.614 (cloud point)
____________________________________________________________________________________
T/K = 393.15
wA = 0.251, wB = 0.200, wC = 0.549.
____________________________________________________________________________________
____________________________________________________________________________________
9.85 0.112 0.489 0.399 0.330 0.004 0.666
13.9 0.132 0.487 0.381 0.346 0.004 0.645
17.4 0.150 0.441 0.409 0.343 0.007 0.650
20.0 0.164 0.415 0.421 0.336 0.009 0.650
24.9 0.200 0.328 0.472
25.2 0.319 0.037 0.644
27.1 0.224 0.272 0.504
27.7 0.311 0.061 0.628
28.1 0.251 0.200 0.549 (cloud point)
____________________________________________________________________________________
Comments: Some three-phase demixing data below 10 MPa can be found in the original source.
____________________________________________________________________________________

Solvent (D): carbon dioxide CO2 124-38-9

wA 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 97.9 96.0 94.3 92.6 91.1 90.0 101.5 99.4 97.3
wA 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 95.7 94.2 92.9 105.1 102.4 100.1 97.7 95.9 94.3
wA 0.400 0.400 0.400 0.400 0.400 0.400 0.375 0.375 0.375
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.400 0.400 0.400 0.400 0.400 0.400 0.375 0.375 0.375
wD 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 64.9 65.1 65.3 65.5 65.7 65.8 69.6 69.6 69.5
wA 0.375 0.375 0.375 0.350 0.350 0.350 0.350 0.350 0.350
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.375 0.375 0.375 0.350 0.350 0.350 0.350 0.350 0.350
wD 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 69.5 69.4 69.3 74.9 74.6 74.3 74.1 73.7 73.5
wA 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 32.5 34.4 36.1 38.0 39.4 40.9 38.9 40.3 41.8
wA 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 43.1 44.2 45.2 45.2 46.1 47.2 48.3 48.9 49.6
____________________________________________________________________________________

Solvent (D): helium He 7440-59-7

wA 0.8300 0.8300 0.8300 0.8300 0.8300 0.8300 0.6300 0.6300 0.6300
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.2100 0.2100 0.2100
wD 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0100 0.0100 0.0100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 209.4 197.5 185.4 174.8 165.9 158.5 139.1 133.4 127.4
wA 0.6300 0.6300 0.6300 0.6225 0.6225 0.6225 0.6225 0.6225 0.6225
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2100 0.2100 0.2100 0.2075 0.2075 0.2075 0.2075 0.2075 0.0750
wD 0.0100 0.0100 0.0100 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 122.6 118.7 116.3 186.5 176.6 166.4 157.7 151.3 147.1
wA 0.420 0.420 0.420 0.420 0.420 0.420 0.415 0.415 0.415
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.420 0.420 0.420 0.420 0.420 0.420 0.415 0.415 0.415
wD 0.010 0.010 0.010 0.010 0.010 0.010 0.020 0.020 0.020
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 99.2 96.8 95.0 93.0 91.3 89.9 148.0 139.6 132.0
wA 0.415 0.415 0.415 0.410 0.410 0.410 0.410 0.410 0.410
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.415 0.415 0.415 0.410 0.410 0.410 0.410 0.410 0.410
wD 0.020 0.020 0.020 0.030 0.030 0.030 0.030 0.030 0.030
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 126.8 121.7 117.3 215.6 201.1 185.4 173.2 163.1 153.5
wA 0.2100 0.2100 0.2100 0.2100 0.2100 0.2100 0.2075 0.2075 0.2075
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6300 0.6300 0.6300 0.6300 0.6300 0.6300 0.6225 0.6225 0.6225
wD 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 0.0200 0.0200
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 69.4 67.1 65.1 63.7 62.9 62.8 117.3 109.4 102.8
wA 0.2075 0.2075 0.2075 0.2050 0.2050 0.2050 0.2050 0.2050 0.2050
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6225 0.6225 0.6225 0.6150 0.6150 0.6150 0.6150 0.6150 0.6150
wD 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300 0.0300 0.0300 0.0300
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 97.6 94.0 91.8 165.0 151.9 140.6 131.5 124.9 120.6
____________________________________________________________________________________
Polymer (B): ethylene/vinyl acetate copolymer 1989WIL

Bayer AG, Leverkusen, Germany
Solvent (D): 2-methyl-2-propanol C4H10O 75-65-0

wA 0.431 0.431 0.431 0.413 0.413 0.413 0.322 0.322 0.322
wB 0.057 0.057 0.057 0.112 0.112 0.112 0.229 0.229 0.229
wC 0.173 0.173 0.173 0.148 0.148 0.148 0.113 0.113 0.113
wD 0.339 0.339 0.339 0.327 0.327 0.327 0.336 0.336 0.336
T/K 333.15 353.15 373.15 333.15 353.15 373.15 333.15 353.15 373.15
P/bar 480 480 480 485 480 480 365 380 390

wA 0.413 0.413 0.413 0.413 0.368 0.368 0.368 0.368
wB 0.044 0.044 0.044 0.044 0.093 0.093 0.093 0.093
wC 0.184 0.184 0.184 0.184 0.168 0.168 0.168 0.168
wD 0.358 0.358 0.358 0.358 0.372 0.372 0.372 0.372
T/K 313.15 333.15 353.15 373.15 313.15 333.15 353.15 373.15
P/bar 337 345 363 385 300 310 328 355
wA 0.370 0.370 0.370 0.370 0.316 0.316 0.316 0.316
wB 0.133 0.133 0.133 0.133 0.227 0.227 0.227 0.227
wC 0.141 0.141 0.141 0.141 0.099 0.099 0.099 0.099
wD 0.356 0.356 0.356 0.356 0.357 0.357 0.357 0.357
T/K 313.15 333.15 353.15 373.15 313.15 333.15 353.15 373.15
P/bar 318 326 345 370 295 316 322 344
wA 0.041 0.041 0.041 0.349 0.349 0.349 0.349 0.403 0.403
wB 0.077 0.077 0.077 0.024 0.024 0.024 0.024 0.048 0.048
wC 0.295 0.295 0.295 0.219 0.219 0.219 0.219 0.184 0.184
wD 0.587 0.587 0.587 0.407 0.407 0.407 0.407 0.365 0.365
T/K 313.15 333.15 353.15 313.15 333.15 353.15 373.15 313.15 333.15
P/bar 21 21 21 248 265 286 309 335 342
wA 0.403 0.403 0.335 0.335 0.335 0.335 0.295 0.295 0.295
wB 0.048 0.048 0.097 0.097 0.097 0.097 0.148 0.148 0.148
wC 0.184 0.184 0.171 0.171 0.171 0.171 0.158 0.158 0.158
wD 0.365 0.365 0.392 0.392 0.392 0.392 0.399 0.399 0.399
T/K 353.15 373.15 313.15 333.15 353.15 373.15 313.15 333.15 353.15
P/bar 360 382 269 276 294 318 170 195 222
continued
____________________________________________________________________________________
continued
wA 0.295 0.247 0.247 0.247 0.247 0.205 0.205 0.205 0.205
wB 0.148 0.203 0.203 0.203 0.203 0.258 0.258 0.258 0.258
wC 0.158 0.140 0.140 0.140 0.140 0.119 0.119 0.119 0.119
wD 0.399 0.410 0.410 0.410 0.410 0.419 0.419 0.419 0.419
T/K 373.15 313.15 333.15 353.15 373.15 313.15 333.15 353.15 373.15
P/bar 252 128 156 180 209 75 102 138 175
wA 0.324 0.324 0.324 0.324 0.304 0.304 0.304 0.304 0.263
wB 0.023 0.023 0.023 0.023 0.049 0.049 0.049 0.049 0.096
wC 0.198 0.198 0.198 0.198 0.188 0.188 0.188 0.188 0.173
wD 0.456 0.456 0.456 0.456 0.459 0.459 0.459 0.459 0.468
T/K 313.15 333.15 353.15 373.15 313.15 333.15 353.15 373.15 313.15
P/bar 187 204 226 256 170 186 210 243 120
wA 0.263 0.263 0.241 0.241 0.241
wB 0.096 0.096 0.089 0.089 0.089
wC 0.173 0.173 0.160 0.160 0.160
wD 0.468 0.468 0.510 0.510 0.510
T/K 333.15 353.15 313.15 333.15 353.15
P/bar 141 170 82 104 130

−1 −1
Characterization: Mn/kg.mol = 51, Mw/kg.mol = 360, 70.0 wt% vinyl acetate,

wA 0.145 0.145 0.217 0.217 0.217 0.217 0.371 0.371 0.371
wB 0.054 0.054 0.062 0.062 0.062 0.062 0.050 0.050 0.050
wC 0.379 0.379 0.212 0.212 0.212 0.212 0.194 0.194 0.194
wD 0.422 0.422 0.479 0.479 0.479 0.479 0.385 0.385 0.385
T/K 323.15 353.15 313.15 333.15 353.15 373.15 313.15 333.15 353.15
P/bar 36 48 47 57 67 87 210 230 255
wA 0.371
wB 0.050
wB 0.194
wB 0.385
T/K 373.15
P/bar 286

Solvent (D): nitrogen N2 7727-37-9
continued
____________________________________________________________________________________
continued
wA 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 115.4 112.5 110.0 108.0 105.4 103.0 142.2 136.6 131.1
wA 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 125.5 120.6 116.1 170.0 160.9 153.2 146.2 139.8 133.9
wA 0.400 0.400 0.400 0.400 0.400 0.400 0.375 0.375 0.375
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.400 0.400 0.400 0.400 0.400 0.400 0.375 0.375 0.375
wD 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 84.1 82.5 81.3 79.7 78.5 77.3 107.0 104.0 101.1
wA 0.375 0.375 0.375 0.350 0.350 0.350 0.350 0.350 0.350
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.375 0.375 0.375 0.350 0.350 0.350 0.350 0.350 0.350
wD 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 98.4 96.1 93.9 130.8 126.1 122.0 118.6 115.5 112.5
wA 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 48.4 49.0 49.4 49.6 50.2 50.7 73.6 72.2 70.9
wA 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 70.0 69.3 68.7 99.8 97.7 95.8 94.1 92.6 91.3
Polymer (B): nylon 6 1994SUR

Solvent (C): 2,2,2-trifluoroethanol C2H3F3O 75-89-8

T/K = 373.15
continued
____________________________________________________________________________________
continued
wA 0.3632 0.3950 0.4195 0.4455 0.4635 0.3311 0.3596 0.3970 0.4229
wB 0.0367 0.0349 0.0334 0.0320 0.0309 0.0694 0.0664 0.0626 0.0599
wC 0.6001 0.5701 0.5471 0.5225 0.5056 0.5995 0.5740 0.5404 0.5172
P/MPa 14.48 19.31 23.45 29.65 33.10 14.48 18.62 25.17 30.00
wA 0.4540 0.2651 0.3019 0.3297 0.3560 0.3797 0.3300 0.3626 0.3853
wB 0.0566 0.1100 0.1045 0.1003 0.0964 0.0928 0.1129 0.1074 0.1035
wC 0.4894 0.6249 0.5936 0.5700 0.5476 0.5275 0.5571 0.5300 0.5112
P/MPa 35.17 13.10 17.59 22.41 26.55 32.07 20.69 26.89 33.79
wA 0.2825 0.3067 0.3324 0.3520
wB 0.1394 0.1347 0.1297 0.1259
wC 0.5781 0.5586 0.5379 0.5221
P/MPa 13.45 16.90 21.93 24.14


wA 0.172 0.172 0.172 0.172 0.172 0.172 0.240 0.240 0.240
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.778 0.778 0.778 0.778 0.778 0.778 0.710 0.710 0.710
T/K 423.15 433.15 443.15 453.15 463.15 473.15 403.15 413.15 423.15
P/MPa 9.0 10.8 12.4 14.1 15.6 17.1 9.7 10.8 12.8
wA 0.240 0.240 0.240 0.240 0.240 0.300 0.300 0.300 0.300
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.710 0.710 0.710 0.710 0.710 0.650 0.650 0.650 0.650
T/K 433.15 443.15 453.15 463.15 473.15 363.15 373.15 383.15 393.15
P/MPa 14.7 16.8 18.3 19.9 21.5 8.6 11.5 13.4 16.1
wA 0.300 0.300
wB 0.050 0.050
wC 0.650 0.650
T/K 403.15 413.15
P/MPa 18.2 20.0
Comments: Gas solubilities and VLE data for this system are given in Chapter 2.
Polymer (B): polybutadiene 1992KIA, 1994KIA

Characterization: Mw/kg.mol−1 = 420, 36% 1,4-cis, 55% 1,4-trans, 9% 1,2-vinyl,
Scientific Polymer Products, Ontario, NY
Type of data: cloud points (VLE-type)

continued
____________________________________________________________________________________
continued
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040
wC 0.760 0.760 0.760 0.760 0.760 0.760 0.760 0.760 0.760
T/K 301.35 303.15 308.15 313.15 318.15 323.15 328.15 333.15 338.15
P/bar 14.71 14.74 15.96 17.34 18.72 20.42 22.10 23.81 25.77
wA 0.200 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.040 0.0375 0.0375 0.0375 0.0375 0.0375 0.0375 0.0375 0.0375
wC 0.760 0.7125 0.7125 0.7125 0.7125 0.7125 0.7125 0.7125 0.7125
T/K 339.65 306.05 308.15 313.95 318.15 323.15 328.15 333.15 338.15
P/bar 26.40 21.94 22.52 24.56 26.66 28.60 31.03 33.76 35.89
wA 0.250 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.0375 0.035 0.035 0.035 0.035 0.035 0.035 0.035 0.035
wC 0.7125 0.665 0.665 0.665 0.665 0.665 0.665 0.665 0.665
T/K 342.85 299.65 303.15 308.15 313.15 318.15 323.15 330.25 333.15
P/bar 38.81 23.38 24.13 26.14 28.34 31.54 34.38 37.76 40.06
wA 0.300 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350
wB 0.035 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325 0.0325
wC 0.665 0.6175 0.6175 0.6175 0.6175 0.6175 0.6175 0.6175 0.6175
T/K 342.75 301.15 303.15 308.15 313.15 318.15 323.15 328.15 333.15
P/bar 46.49 27.42 28.04 30.37 32.83 35.89 39.20 42.06 45.11
wA 0.350 0.350 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.0325 0.0325 0.075 0.075 0.075 0.075 0.075 0.075 0.075
wC 0.6175 0.6175 0.675 0.675 0.675 0.675 0.675 0.675 0.675
T/K 338.95 342.95 309.45 311.55 314.15 317.95 320.65 324.15 329.15
P/bar 49.25 52.17 24.98 25.63 26.76 28.23 29.87 31.52 33.81
wA 0.250 0.250 0.250 0.250 0.250 0.300 0.300 0.300 0.300
wB 0.075 0.075 0.075 0.075 0.075 0.070 0.070 0.070 0.070
wC 0.675 0.675 0.675 0.675 0.675 0.630 0.630 0.630 0.630
T/K 331.35 333.25 337.45 340.55 342.95 303.75 308.15 313.15 318.15
P/bar 33.92 35.78 37.56 39.04 41.13 26.30 27.12 29.32 31.65
wA 0.300 0.300 0.300 0.300 0.300 0.350 0.350 0.350 0.350
wB 0.070 0.070 0.070 0.070 0.070 0.065 0.065 0.065 0.065
wC 0.630 0.630 0.630 0.630 0.630 0.585 0.585 0.585 0.585
T/K 323.15 328.15 333.15 341.65 343.15 303.35 308.15 313.15 318.15
P/bar 34.05 36.70 39.43 44.95 46.82 28.83 30.01 32.43 35.06
wA 0.350 0.350 0.350 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.065 0.065 0.065 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125
wC 0.585 0.585 0.585 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 323.15 328.95 333.15 310.45 313.25 322.65 324.35 329.55 332.25
P/bar 38.25 41.63 44.93 27.02 28.30 32.27 33.23 35.98 37.43
wA 0.250 0.250 0.250 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.1125 0.1125 0.1125 0.105 0.105 0.105 0.105 0.105 0.105
wC 0.6375 0.6375 0.6375 0.595 0.595 0.595 0.595 0.595 0.595
T/K 336.65 339.05 343.15 308.55 313.95 320.55 326.75 331.25 335.35
P/bar 39.73 41.31 42.75 30.21 33.00 37.49 41.01 43.77 46.26
continued
____________________________________________________________________________________
continued
wA 0.300 0.300 0.350 0.350
wB 0.105 0.105 0.0975 0.0975
wC 0.595 0.595 0.5525 0.5525
T/K 339.05 343.15 322.95 327.25
P/bar 48.59 50.79 42.55 46.82

−1
Characterization: Mw/kg.mol = 5, 80% (1,4-cis + 1,4-trans), 20% 1,2-vinyl,

wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.201 0.201
wB 0.510 0.510 0.510 0.510 0.510 0.510 0.510 0.4794 0.4794
wC 0.340 0.340 0.340 0.340 0.340 0.340 0.340 0.3196 0.3196
T/K 301.45 321.15 323.15 328.05 333.15 337.45 343.15 301.45 303.15
P/bar 38.84 51.05 52.82 55.52 58.61 61.69 64.78 47.21 47.77
VLE VLE VLE VLE VLE VLE VLE VLE VLE
wA 0.201 0.201 0.201 0.201 0.201 0.201 0.201 0.201 0.250
wB 0.4794 0.4794 0.4794 0.4794 0.4794 0.4794 0.4794 0.4794 0.450
wC 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196 0.3196 0.300
T/K 308.15 313.25 318.15 323.15 328.55 333.15 338.15 343.05 301.35
P/bar 50.95 55.09 58.63 63.07 69.39 73.74 80.21 85.95 62.18
VLE VLE VLE VLE VLE VLE VLE VLE LLE
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.450 0.450 0.450 0.450 0.450 0.450 0.450 0.450 0.450
wC 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
T/K 303.15 308.35 313.45 318.25 323.35 328.15 333.15 338.15 339.35
P/bar 62.15 64.61 69.21 75.48 83.03 90.85 100.04 108.57 110.87
wA 0.266 0.266 0.266 0.266 0.266 0.266 0.266 0.266 0.266
wB 0.4404 0.4404 0.4404 0.4404 0.4404 0.4404 0.4404 0.4404 0.4404
wC 0.2936 0.2936 0.2936 0.2936 0.2936 0.2936 0.2936 0.2936 0.2936
T/K 301.15 302.65 303.15 304.15 305.15 306.15 307.15 308.15 309.15
P/bar 134.84 133.39 131.79 130.18 128.47 126.93 126.46 125.88 125.15
wA 0.266 0.266 0.266 0.266 0.266 0.266 0.266 0.266 0.266
wB 0.4404 0.4404 0.4404 0.4404 0.4404 0.4404 0.4404 0.4404 0.4404
wC 0.2936 0.2936 0.2936 0.2936 0.2936 0.2936 0.2936 0.2936 0.2936
T/K 310.15 311.35 313.15 315.65 317.15 318.15 321.15 324.65 325.65
P/bar 124.24 124.24 122.60 122.52 123.62 124.53 125.19 129.55 130.04
continued
____________________________________________________________________________________
continued
wA 0.266 0.266 0.266 0.266 0.266 0.266 0.150 0.150 0.150
wB 0.4404 0.4404 0.4404 0.4404 0.4404 0.4404 0.6375 0.6375 0.6375
wC 0.2936 0.2936 0.2936 0.2936 0.2936 0.2936 0.2125 0.2125 0.2125
T/K 327.15 328.25 329.65 330.65 332.15 333.15 304.65 308.45 309.45
P/bar 131.82 132.26 134.08 135.66 137.50 138.52 41.37 43.23 45.42
LLE LLE LLE LLE LLE LLE VLE VLE VLE
wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.765 0.765
wC 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.085 0.085
T/K 313.15 318.45 323.45 328.05 333.35 338.05 343.25 303.85 307.95
P/bar 47.59 52.68 56.72 59.67 64.72 68.75 71.58 56.61 61.41
wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.765 0.765 0.765 0.765 0.765 0.765 0.765
wC 0.085 0.085 0.085 0.085 0.085 0.085 0.085
T/K 313.85 317.65 323.05 328.25 333.35 338.35 343.15
P/bar 66.88 70.82 75.24 80.68 85.43 93.90 98.53
VLE VLE VLE VLE VLE VLE VLE
Comments: VLE- or LLE-type could not always be distinguished in a clear manner.

Characterization: Mw/kg.mol−1 = 420, 36% 1,4-cis, 55% 1,4-trans, 9% 1,2-vinyl,
Type of data: cloud points (VLE-type)

wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.200 0.200
wB 0.085 0.085 0.085 0.085 0.085 0.085 0.085 0.080 0.080
wC 0.765 0.765 0.765 0.765 0.765 0.765 0.765 0.720 0.720
T/K 314.25 318.75 323.25 328.15 333.15 338.05 343.15 311.45 313.15
P/bar 33.13 34.84 36.78 38.55 40.55 42.69 44.59 38.35 39.00
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.250 0.250 0.250
wB 0.080 0.080 0.080 0.080 0.080 0.080 0.075 0.075 0.075
wC 0.720 0.720 0.720 0.720 0.720 0.720 0.675 0.675 0.675
T/K 316.05 323.15 328.25 333.15 339.15 343.15 301.75 308.15 313.15
P/bar 41.18 45.21 48.20 50.64 54.31 56.67 37.92 39.76 42.69
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.300 0.300 0.300
wB 0.075 0.075 0.075 0.075 0.075 0.075 0.070 0.070 0.070
wC 0.675 0.675 0.675 0.675 0.675 0.675 0.630 0.630 0.630
T/K 318.15 324.05 327.95 332.75 338.15 342.75 304.65 305.25 314.25
P/bar 45.37 52.63 55.92 59.36 63.14 65.34 43.47 44.40 50.80
continued
____________________________________________________________________________________
continued
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.350 0.350 0.350
wB 0.070 0.070 0.070 0.070 0.070 0.070 0.065 0.065 0.065
wC 0.630 0.630 0.630 0.630 0.630 0.630 0.585 0.585 0.585
T/K 317.15 323.15 328.15 333.15 338.15 343.15 302.25 303.15 308.25
P/bar 53.42 58.18 61.73 65.93 70.12 74.53 44.62 44.72 47.74
wA 0.350 0.350 0.350 0.350 0.350 0.350 0.350
wB 0.065 0.065 0.065 0.065 0.065 0.065 0.065
wC 0.585 0.585 0.585 0.585 0.585 0.585 0.585
T/K 313.25 318.15 323.35 328.25 333.15 338.25 342.05
P/bar 51.55 55.00 59.56 63.96 68.16 73.51 78.04

−1
wA 0.186 0.186 0.278 0.278 0.278 0.278 0.278 0.278 0.278
wB 0.059 0.059 0.059 0.059 0.059 0.059 0.059 0.059 0.059
wC 0.755 0.755 0.663 0.663 0.663 0.663 0.663 0.663 0.663
T/K 463.15 473.15 413.15 423.15 433.15 443.15 453.15 463.15 473.15
P/MPa 11.7 12.0 12.5 13.4 14.1 15.2 17.3 19.0 20.6
wA 0.337 0.337 0.337 0.337 0.337 0.337 0.337
wB 0.059 0.059 0.059 0.059 0.059 0.059 0.059
wC 0.604 0.604 0.604 0.604 0.604 0.604 0.604
T/K 393.15 403.15 413.15 423.15 433.15 443.15 453.15
P/MPa 12.4 13.1 15.6 17.5 19.5 21.8 23.7
Polymer (B): poly(butyl methacrylate) 2000BY1, 2000KIM

Solvent (C): butyl methacrylate C8H14O2 97-88-1
wA 0.870 0.870 0.870 0.870 0.870 0.870 0.785 0.785 0.785
wB 0.051 0.051 0.051 0.051 0.051 0.051 0.053 0.053 0.053
wC 0.079 0.079 0.079 0.079 0.079 0.079 0.162 0.162 0.162
T/K 360.55 371.25 388.65 409.35 428.45 449.75 324.05 330.15 338.35
P/bar 1923.9 1463.4 1270.3 1179.3 1138.0 1118.7 1739.2 1291.0 1115.9
wA 0.785 0.785 0.785 0.785 0.785 0.650 0.650 0.650 0.650
wB 0.053 0.053 0.053 0.053 0.053 0.052 0.052 0.052 0.052
wC 0.162 0.162 0.162 0.162 0.162 0.298 0.298 0.298 0.298
T/K 347.35 365.15 383.45 405.35 424.45 313.15 323.25 333.75 353.05
P/bar 1029.0 955.9 923.9 908.4 895.3 550.5 553.3 565.4 591.2
continued
____________________________________________________________________________________
continued
wA 0.650 0.650 0.541 0.541 0.541 0.541 0.541 0.541 0.401
wB 0.052 0.052 0.052 0.052 0.052 0.052 0.052 0.052 0.049
wC 0.298 0.298 0.407 0.407 0.407 0.407 0.407 0.407 0.550
T/K 372.45 391.35 309.15 316.75 325.25 339.15 359.65 379.55 453.45
P/bar 609.5 629.1 150.0 187.2 215.5 263.0 313.0 331.3 329.2
wA 0.401 0.401 0.401 0.401 0.401 0.401 0.401 0.401 0.401
wB 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049
wC 0.550 0.550 0.550 0.550 0.550 0.550 0.550 0.550 0.550
T/K 436.05 416.45 403.85 395.15 379.55 367.15 351.25 347.05 339.05
P/bar 301.8 269.6 243.7 222.7 187.2 156.2 115.5 95.5 94.5
wA 0.401 0.401
wB 0.049 0.049
wC 0.550 0.550
T/K 323.95 312.95
P/bar 78.3 65.2
Comments: The last four data points belong to a vapor-liquid phase transition.


wA 0.00 0.00 0.00 0.00 0.00 0.153 0.153 0.153
wB 0.10 0.10 0.10 0.10 0.10 0.0847 0.0847 0.0847
wC 0.90 0.90 0.90 0.90 0.90 0.7623 0.7623 0.7623
T/K 332.9 332.1 331.2 333.5 332.4 331.8 331.5 331.6
P/MPa 1.10 3.10 6.10 10.10 15.10 3.10 4.10 12.00
Type of data: cloud points (UCST/LCST merging behavior)

wA 0.505 0.505 0.505 0.505 0.505 0.505 0.505 0.505 0.505
wB 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495
wC 0.4455 0.4455 0.4455 0.4455 0.4455 0.4455 0.4455 0.4455 0.4455
T/K 335.0 333.8 333.5 333.2 335.5 335.7 337.3 337.4 338.6
P/MPa 10.4 10.9 11.6 12.6 10.09 10.27 10.75 10.90 11.28
wA 0.505 0.505 0.505 0.505 0.505 0.532 0.532 0.532 0.532
wB 0.0495 0.0495 0.0495 0.0495 0.0495 0.0468 0.0468 0.0468 0.0468
wC 0.4455 0.4455 0.4455 0.4455 0.4455 0.4212 0.4212 0.4212 0.4212
T/K 341.3 345.3 347.3 352.4 355.4 333.8 334.1 334.1 334.0
P/MPa 12.05 13.47 14.10 15.97 16.50 15.60 16.10 16.60 17.10
continued
____________________________________________________________________________________
continued
wA 0.532 0.532 0.532 0.532 0.532 0.532 0.532
wB 0.0468 0.0468 0.0468 0.0468 0.0468 0.0468 0.0468
wC 0.4212 0.4212 0.4212 0.4212 0.4212 0.4212 0.4212
T/K 334.1 335.2 336.0 336.8 337.6 338.2 338.7
P/MPa 15.20 15.59 15.86 16.07 16.38 16.76 17.02
wA 0.271 0.271 0.271 0.271 0.271 0.271 0.328 0.328 0.328
wB 0.0729 0.0729 0.0729 0.0729 0.0729 0.0729 0.0672 0.0672 0.0672
wC 0.6561 0.6561 0.6561 0.6561 0.6561 0.6561 0.6048 0.6048 0.6048
T/K 446.2 448.9 450.9 456.7 459.8 465.2 438.5 441.8 445.4
P/MPa 12.97 13.78 14.26 15.38 16.83 17.57 14.94 15.74 16.56
wA 0.328 0.328 0.352 0.352 0.352 0.352 0.352 0.396 0.396
wB 0.0672 0.0672 0.0648 0.0648 0.0648 0.0648 0.0648 0.0604 0.0604
wC 0.6048 0.6048 0.5832 0.5832 0.5832 0.5832 0.5832 0.5436 0.5436
T/K 448.7 452.3 413.8 414.4 416.6 421.0 429.7 407.2 409.8
P/MPa 17.23 17.95 13.21 13.32 14.09 15.07 17.06 16.32 16.99
wA 0.396 0.396 0.456 0.456 0.483 0.483 0.483 0.483 0.483
wB 0.0604 0.0604 0.0544 0.0544 0.0517 0.0517 0.0517 0.0517 0.0517
wC 0.5436 0.5436 0.4896 0.4896 0.4653 0.4653 0.4653 0.4653 0.4653
T/K 413.4 416.6 381.5 384.3 354.7 357.0 361.7 364.5 366.8
P/MPa 17.98 18.73 17.10 17.84 13.56 14.30 15.72 16.63 17.31

−1 −1

wA 0.90 0.90 0.90 0.90 0.864 0.864 0.864 0.864
wB 0.10 0.10 0.10 0.10 0.096 0.096 0.096 0.096
wC 0.00 0.00 0.00 0.00 0.04 0.04 0.04 0.04
T/K 369.9 370.2 369.8 369.9 356.7 355.7 355.5 355.1
P/MPa 1.10 3.10 6.10 8.10 12.10 13.60 15.10 17.10

continued
____________________________________________________________________________________
continued

wA 0.00 0.00 0.00 0.00 0.00 0.00 0.02 0.02 0.02
wB 0.10 0.10 0.10 0.10 0.10 0.10 0.098 0.098 0.098
wC 0.90 0.90 0.90 0.90 0.90 0.90 0.882 0.882 0.882
T/K 414.7 415.0 414.0 413.8 412.8 414.7 407.1 405.0 405.3
P/MPa 1.10 3.10 7.10 10.10 12.10 16.10 4.40 10.10 13.10
wA 0.02 0.04 0.04 0.04
wB 0.098 0.096 0.096 0.096
wC 0.882 0.864 0.864 0.864
T/K 405.2 395.6 394.7 393.9
P/MPa 15.90 11.93 14.10 16.60


wA 0.0437 0.0437 0.0437 0.0437 0.0437 0.0956 0.0956 0.0956 0.0956
wB 0.0527 0.0527 0.0527 0.0527 0.0527 0.0474 0.0474 0.0474 0.0474
wC 0.9037 0.9037 0.9037 0.9037 0.9037 0.8571 0.8571 0.8571 0.8571
T/K 517.28 522.34 526.99 532.72 533.23 501.75 506.27 511.19 516.35
P/bar 49.7 55.9 61.4 68.1 68.6 76.2 81.9 87.5 92.1
wA 0.0956 0.0956
wB 0.0474 0.0474
wC 0.8571 0.8571
T/K 527.11 537.22
P/bar 103.6 115.1

Characterization: Mn/kg.mol−1 = 93, Mw/kg.mol−1 = 101, Mz/kg.mol−1 = 112

wA 0.0667 0.0667 0.0667 0.0667 0.0667 0.0667 0.1346 0.1346 0.1346
wB 0.1150 0.1150 0.1150 0.1150 0.1150 0.1150 0.1067 0.1067 0.1067
wC 0.8183 0.8183 0.8183 0.8183 0.8183 0.8183 0.8587 0.8587 0.8587
T/K 469.93 479.59 489.52 499.09 509.41 519.73 423.92 434.17 444.30
P/bar 58.5 74.2 89.3 103.8 118.0 131.6 76.3 94.7 112.0
continued
____________________________________________________________________________________
continued
wA 0.1346 0.1346 0.1346 0.1346 0.1346 0.1346 0.1346
wB 0.1067 0.1067 0.1067 0.1067 0.1067 0.1067 0.1067
wC 0.8587 0.8587 0.8587 0.8587 0.8587 0.8587 0.8587
T/K 454.37 464.03 473.96 484.04 493.70 504.30 514.25
P/bar 129.0 144.3 159.3 174.1 188.0 201.3 213.5

−1

wA 0.125 0.125 0.125 0.125 0.125 0.125 0.125 0.125 0.125
wB 0.024 0.024 0.024 0.024 0.024 0.024 0.024 0.024 0.024
wC 0.851 0.851 0.851 0.851 0.851 0.851 0.851 0.851 0.851
T/K 383.15 393.15 403.15 413.15 423.15 433.15 443.15 453.15 463.15
P/MPa 6.2 8.0 9.3 10.8 12.0 13.2 14.3 15.4 16.5
wA 0.125 0.273 0.273 0.273 0.273 0.273 0.273
wB 0.024 0.024 0.024 0.024 0.024 0.024 0.024
wC 0.851 0.703 0.703 0.703 0.703 0.703 0.703
T/K 473.15 383.15 393.15 403.15 413.15 423.15 433.15
P/MPa 17.7 28.0 29.7 30.8 32.0 32.9 33.5


wA 0.856 0.856 0.856 0.856 0.856 0.856 0.846 0.846 0.846
wB 0.104 0.104 0.104 0.104 0.104 0.104 0.103 0.103 0.103
wC 0.040 0.040 0.040 0.040 0.040 0.040 0.050 0.050 0.050
T/K 505.43 506.23 507.19 508.15 508.92 509.83 504.55 505.48 506.53
P/bar 95.0 96.0 97.0 98.0 99.0 100.0 111.5 112.5 113.5
wA 0.846 0.846 0.846 0.846 0.846 0.837 0.837 0.837 0.837
wB 0.103 0.103 0.103 0.103 0.103 0.102 0.102 0.102 0.102
wC 0.050 0.050 0.050 0.050 0.050 0.061 0.061 0.061 0.061
T/K 507.55 508.51 510.47 512.43 514.47 498.67 501.19 503.70 506.17
P/bar 114.9 115.9 117.9 119.9 121.9 133.7 136.1 138.5 140.9
wA 0.837 0.837 0.837
wB 0.102 0.102 0.102
wC 0.061 0.061 0.061
T/K 508.65 511.16 513.64
P/bar 143.3 145.7 147.9
____________________________________________________________________________________


wA 0.052 0.052 0.052 0.052 0.052 0.052 0.052 0.068 0.068
wB 0.104 0.104 0.104 0.104 0.104 0.104 0.104 0.100 0.100
wC 0.844 0.844 0.844 0.844 0.844 0.844 0.844 0.832 0.832
T/K 499.75 502.22 502.88 503.78 504.69 505.57 506.47 493.67 496.17
P/bar 48.5 52.0 53.0 54.0 55.5 56.5 58.0 54.9 58.3
wA 0.068 0.068 0.068 0.068 0.068 0.068 0.101 0.101 0.101
wB 0.100 0.100 0.100 0.100 0.100 0.100 0.098 0.098 0.098
wC 0.832 0.832 0.832 0.832 0.832 0.832 0.801 0.801 0.801
T/K 498.64 501.11 503.59 506.06 508.59 511.13 473.64 473.70 476.15
P/bar 61.9 65.3 68.3 71.3 74.3 77.3 61.9 61.9 65.5
wA 0.101 0.101 0.101 0.101 0.101 0.101 0.101 0.101
wB 0.098 0.098 0.098 0.098 0.098 0.098 0.098 0.098
wC 0.801 0.801 0.801 0.801 0.801 0.801 0.801 0.801
T/K 478.66 478.71 483.68 488.66 493.62 498.64 503.64 508.62
P/bar 68.9 68.9 75.9 82.5 89.3 95.9 101.9 107.9
Polymer (B): polyethylene 1999DIE

−1 −1
Characterization: Mn/kg.mol = 69.2, Mw/kg.mol = 198, 54.0 % crystallinity

xC 0.0000 0.0029 0.0053 0.0124 0.0202 0.0342 0.0489
T/K = 393.15
P/bar 2000 1990 1960 1900 1845 1765 1700
T/K = 403.15
P/bar 1910 1893 1861 1820 1750 1670 1610
T/K = 413.15
P/bar 1840 1818 1756 1765 1660 1600 1522
T/K = 423.15
P/bar 1760 1745 1708 1690 1610 1517 1490
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 14.4, Mw/kg.mol−1 = 15.2, PE standard, hydrogenated

wA 0.0390 0.0390 0.0390 0.0390 0.0390 0.0390 0.0390 0.0390 0.0390
wB 0.0874 0.0874 0.0874 0.0874 0.0874 0.0874 0.0874 0.0874 0.0874
wC 0.8736 0.8736 0.8736 0.8736 0.8736 0.8736 0.8736 0.8736 0.8736
T/K 373.21 393.12 413.12 433.17 433.17 453.14 453.17 473.10 473.14
P/MPa 1.9 2.0 2.4 4.0 2.8 6.7 3.2 9.2 3.7
VLE VLE VLE LLE VLLE LLE VLLE LLE VLLE
wA 0.0605 0.0605 0.0605 0.0605 0.0605 0.0605 0.0605 0.0605 0.0605
wB 0.0789 0.0789 0.0789 0.0789 0.0789 0.0789 0.0789 0.0789 0.0789
wC 0.8606 0.8606 0.8606 0.8606 0.8606 0.8606 0.8606 0.8606 0.8606
T/K 373.20 393.09 413.03 413.14 433.07 433.23 453.12 453.21 473.13
P/MPa 2.2 2.7 3.6 3.1 6.5 3.6 9.2 4.0 4.5
VLE VLE LLE VLLE LLE VLLE LLE VLLE VLLE
wA 0.0605 0.1277 0.1277 0.1277 0.1277 0.1277 0.1277 0.1277 0.1277
wB 0.0789 0.0733 0.0733 0.0733 0.0733 0.0733 0.0733 0.0733 0.0733
wC 0.8606 0.7990 0.7990 0.7990 0.7990 0.7990 0.7990 0.7990 0.7990
T/K 473.15 373.15 373.15 393.09 393.11 413.08 413.11 433.06 433.10
P/MPa 11.6 8.8 4.5 11.6 5.1 14.4 5.7 16.9 6.3
wA 0.1277 0.1277 0.1277 0.1277
wB 0.0733 0.0733 0.0733 0.0733
wC 0.7990 0.7990 0.7990 0.7990
T/K 453.18 453.18 473.10 473.11
P/MPa 19.1 7.0 20.9 8.0
LLE VLLE LLE VLLE

−1 −1 −1

wA 0.0217 0.0217 0.0217 0.0217 0.0217 0.0217 0.0217 0.0217 0.0217
wB 0.0802 0.0802 0.0802 0.0802 0.0802 0.0802 0.0802 0.0802 0.0802
wC 0.8981 0.8981 0.8981 0.8981 0.8981 0.8981 0.8981 0.8981 0.8981
T/K 393.13 413.20 413.20 433.15 433.13 453.16 453.17 473.16 473.15
P/MPa 1.5 2.1 1.8 5.2 2.2 7.9 2.6 10.4 3.1
VLE LLE VLLE LLE VLLE LLE VLLE LLE VLLE
continued
____________________________________________________________________________________
continued
wA 0.0416 0.0416 0.0416 0.0416 0.0416 0.0416 0.0416 0.0416 0.0416
wB 0.0896 0.0896 0.0896 0.0896 0.0896 0.0896 0.0896 0.0896 0.0896
wC 0.8688 0.8688 0.8688 0.8688 0.8688 0.8688 0.8688 0.8688 0.8688
T/K 393.10 413.11 413.12 433.12 433.19 453.16 453.16 473.13 473.13
P/MPa 2.2 4.6 2.5 7.6 2.9 10.3 3.4 12.7 3.8
VLE LLE VLLE LLE VLLE LLE VLLE LLE VLLE
wA 0.0636 0.0636 0.0636 0.0636 0.0636 0.0636 0.0636 0.0636 0.0636
wB 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875
wC 0.8489 0.8489 0.8489 0.8489 0.8489 0.8489 0.8489 0.8489 0.8489
T/K 393.10 393.16 413.20 413.16 433.17 433.16 453.18 453.17 473.14
P/MPa 5.2 3.0 8.3 3.4 11.1 3.9 13.4 4.3 15.7
LLE VLLE LLE VLLE LLE VLLE LLE VLLE LLE


wA 0.0207 0.0207 0.0207 0.0207 0.0207 0.0207 0.0207 0.0207 0.0207
wB 0.0997 0.0997 0.0997 0.0997 0.0997 0.0997 0.0997 0.0997 0.0997
wC 0.8796 0.8796 0.8796 0.8796 0.8796 0.8796 0.8796 0.8796 0.8796
T/K 408.9 429.1 429.0 433.7 443.3 453.4 463.5 473.9 484.2
P/MPa 1.36 1.64 2.31 3.11 4.54 5.91 1.28 8.63 9.87
VLE VLLE LLE LLE LLE LLE LLE LLE LLE
wA 0.0207 0.0374 0.0374 0.0374 0.0374 0.0374 0.0374 0.0374 0.0374
wB 0.0997 0.0969 0.0969 0.0969 0.0969 0.0969 0.0969 0.0969 0.0969
wC 0.8796 0.8657 0.8657 0.8657 0.8657 0.8657 0.8657 0.8657 0.8657
T/K 493.2 404.5 413.3 423.2 433.5 423.3 433.5 443.5 453.4
P/MPa 10.85 1.74 1.94 2.09 2.31 3.40 4.96 6.43 7.67
LLE VLE VLE VLLE VLLE LLE LLE LLE LLE
wA 0.0374 0.0374 0.0374 0.0691 0.0691 0.0691 0.0691 0.0691 0.0691
wB 0.0969 0.0969 0.0969 0.0937 0.0937 0.0937 0.0937 0.0937 0.0937
wC 0.8657 0.8657 0.8657 0.8372 0.8372 0.8372 0.8372 0.8372 0.8372
T/K 463.5 473.7 482.7 382.0 392.8 403.3 413.4 392.7 403.3
P/MPa 8.98 10.23 11.30 2.60 2.97 3.20 3.38 3.03 4.70
LLE LLE LLE VLE VLLE VLLE VLLE LLE LLE
wA 0.0691 0.0691 0.0691 0.0691 0.0691 0.1188 0.1188 0.1188 0.1188
wB 0.0937 0.0937 0.0937 0.0937 0.0937 0.0898 0.0898 0.0898 0.0898
wC 0.8372 0.8372 0.8372 0.8372 0.8372 0.7914 0.7914 0.7914 0.7914
T/K 413.3 422.8 433.3 442.9 454.0 377.2 388.0 398.9 409.0
P/MPa 6.26 7.76 9.25 10.56 12.02 10.01 11.45 12.97 14.32
continued
____________________________________________________________________________________
continued
wA 0.1188
wB 0.0898
wC 0.7914
T/K 418.8
P/MPa 15.60
LLE

Solvent (D): 1-octene C8H16 111-66-0

wA 0.0202 0.0202 0.0202 0.0202 0.0202 0.0202 0.0202 0.0202 0.0202
wB 0.1856 0.1856 0.1856 0.1856 0.1856 0.1856 0.1856 0.1856 0.1856
wC 0.6354 0.6354 0.6354 0.6354 0.6354 0.6354 0.6354 0.6354 0.6354
wD 0.1588 0.1588 0.1588 0.1588 0.1588 0.1588 0.1588 0.1588 0.1588
T/K 423.2 433.8 443.7 454.2 454.2 462.4 472.8 483.1 493.2
P/MPa 1.59 1.80 2.02 2.21 3.34 4.45 5.86 7.16 8.38
VLE VLE VLE VLLE LLE LLE LLE LLE LLE
wA 0.0202 0.0202 0.0202 0.0548 0.0548 0.0548 0.0548 0.0548 0.0548
wB 0.1856 0.1856 0.1856 0.1790 0.1790 0.1790 0.1790 0.1790 0.1790
wC 0.6354 0.6354 0.6354 0.6130 0.6130 0.6130 0.6130 0.6130 0.6130
wD 0.1588 0.1588 0.1588 0.1532 0.1532 0.1532 0.1532 0.1532 0.1532
T/K 503.2 513.4 524.1 404.7 413.3 423.2 433.7 423.2 433.6
P/MPa 9.49 10.56 11.59 2.91 3.06 3.26 3.49 4.10 5.60
LLE LLE LLE VLE VLE VLLE VLLE LLE LLE
wA 0.0548 0.0548 0.0548 0.0548 0.0548 0.0186 0.0186 0.0186 0.0186
wB 0.1790 0.1790 0.1790 0.1790 0.1790 0.0921 0.0921 0.0921 0.0921
wC 0.6130 0.6130 0.6130 0.6130 0.6130 0.7114 0.7114 0.7114 0.7114
wD 0.1532 0.1532 0.1532 0.1532 0.1532 0.1779 0.1779 0.1779 0.1779
T/K 442.7 453.0 463.3 473.6 484.2 424.0 433.3 443.0 453.5
P/MPa 6.98 8.44 9.75 11.00 12.26 1.42 1.59 1.75 1.98
LLE LLE LLE LLE LLE VLE VLE VLLE VLLE
wA 0.0186 0.0186 0.0186 0.0186 0.0186 0.0186 0.0186 0.0186 0.0544
wB 0.0921 0.0921 0.0921 0.0921 0.0921 0.0921 0.0921 0.0921 0.0887
wC 0.7114 0.7114 0.7114 0.7114 0.7114 0.7114 0.7114 0.7114 0.6855
wD 0.1779 0.1779 0.1779 0.1779 0.1779 0.1779 0.1779 0.1779 0.1714
T/K 443.0 453.4 463.7 473.9 484.0 493.4 503.2 513.4 403.3
P/MPa 2.20 3.73 5.17 6.49 7.76 8.85 9.93 10.98 2.67
LLE LLE LLE LLE LLE LLE LLE LLE VLE
continued
____________________________________________________________________________________
continued
wA 0.0544 0.0544 0.0544 0.0544 0.0544 0.0544 0.0544 0.0544 0.0544
wB 0.0887 0.0887 0.0887 0.0887 0.0887 0.0887 0.0887 0.0887 0.0887
wC 0.6855 0.6855 0.6855 0.6855 0.6855 0.6855 0.6855 0.6855 0.6855
wD 0.1714 0.1714 0.1714 0.1714 0.1714 0.1714 0.1714 0.1714 0.1714
T/K 413.3 423.6 433.3 423.5 433.2 443.7 453.7 464.1 473.5
P/MPa 2.88 3.07 3.21 4.35 5.83 7.35 8.72 10.06 11.23
VLE VLLE VLLE LLE LLE LLE LLE LLE LLE
wA 0.0544
wB 0.0887
wC 0.6855
wD 0.1714
T/K 483.8
P/MPa 12.41
LLE

−1 −1
Characterization: Mn/kg.mol = 82, Mw/kg.mol = 108, PE standard, hydrogenated

wA 0.0280 0.0280 0.0280 0.0280 0.0280 0.0280 0.0280 0.0280 0.0280
wB 0.0803 0.0803 0.0803 0.0803 0.0803 0.0803 0.0803 0.0803 0.0803
wC 0.8917 0.8917 0.8917 0.8917 0.8917 0.8917 0.8917 0.8917 0.8917
T/K 373.20 393.14 413.12 413.15 433.13 433.14 453.11 453.14 473.12
P/MPa 1.3 1.6 3.5 1.9 6.5 2.3 9.3 2.7 11.8
VLE VLE LLE VLLE LLE VLLE LLE VLLE LLE
wA 0.0280 0.0512 0.0512 0.0512 0.0512 0.0512 0.0512 0.0512 0.0512
wB 0.0803 0.0784 0.0784 0.0784 0.0784 0.0784 0.0784 0.0784 0.0784
wC 0.8917 0.8704 0.8704 0.8704 0.8704 0.8704 0.8704 0.8704 0.8704
T/K 473.14 373.21 393.16 393.16 413.13 413.10 433.15 433.18 453.19
P/MPa 3.2 2.1 4.3 2.5 7.5 2.8 10.3 3.3 12.7
VLLE VLE LLE VLLE LLE VLLE LLE VLLE LLE
wA 0.0280 0.0512 0.0512 0.0668 0.0668 0.0668 0.0668 0.0668 0.0668
wB 0.0803 0.0784 0.0784 0.0771 0.0771 0.0771 0.0771 0.0771 0.0771
wC 0.8917 0.8704 0.8704 0.8561 0.8561 0.8561 0.8561 0.8561 0.8561
T/K 453.16 473.15 473.10 373.19 373.20 393.16 393.13 413.14 413.13
P/MPa 3.7 14.9 4.3 3.4 2.6 6.7 3.0 9.7 3.4
VLLE LLE VLLE LLE VLLE LLE VLLE LLE VLLE
wA 0.0668 0.0668 0.0668 0.0668 0.0668 0.0668
wB 0.0771 0.0771 0.0771 0.0771 0.0771 0.0771
wC 0.8561 0.8561 0.8561 0.8561 0.8561 0.8561
T/K 433.16 433.18 453.14 453.18 473.15 473.17
P/MPa 12.2 3.9 14.8 4.4 17.0 4.9
LLE VLLE LLE VLLE LLE VLLE
____________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 14.4, Mw/kg.mol−1 = 15.2, PE standard, hydrogenated
Polymer (D): polyethylene
Characterization: Mn/kg.mol−1 = 82, Mw/kg.mol−1 = 108, PE standard, hydrogenated

Comments: wB/wD = 0.2501/0.2503 was kept constant.
wA 0.0175 0.0175 0.0175 0.0175 0.0282 0.0282 0.0282 0.0282 0.0668
wB 0.04853 0.04853 0.04853 0.04853 0.04798 0.04798 0.04798 0.04798 0.03853
wC 0.8854 0.8854 0.8854 0.8854 0.8758 0.8758 0.8758 0.8758 0.8561
wD 0.04857 0.04857 0.04857 0.04857 0.04802 0.04802 0.04802 0.04802 0.03857
T/K 443.19 453.18 463.16 473.14 443.19 453.20 463.18 473.18 443.19
P/MPa 5.6 7.0 8.3 9.5 8.1 9.4 10.6 11.8 11.2
wA 0.0668 0.0668 0.0668
wB 0.03853 0.03853 0.03853
wC 0.8561 0.8561 0.8561
wD 0.03857 0.03857 0.03857
T/K 453.19 463.12 473.09
P/MPa 12.5 13.7 14.8
Polymer (B): polyethylene 2000CH3

−1 −1
Characterization: Mn/kg.mol = 101, Mw/kg.mol = 120,
DSC transition temperature range 392.2-407.2 K, NIST SRM1484

wA 0.418 0.418 0.418 0.418 0.418 0.418
wB 0.147 0.147 0.147 0.147 0.147 0.147
wC 0.435 0.435 0.435 0.435 0.435 0.435
T/K 392.85 398.55 413.25 433.45 445.25 455.65
P/MPa 76.1 73.1 74.2 72.8 73.0 73.0

Solvent (C): 4-methyl-1-pentene C6H12 691-37-2

continued
____________________________________________________________________________________
continued
T/K = 493.15 P/MPa = 24.5
____________________________________________________________________________________
wA wB wC wA wB wC
gel phase sol phase
____________________________________________________________________________________
0.1290 0.8710 0.0000 1.0000 0.0000 0.0000
0.1287 0.8219 0.0494 0.8847 0.0150 0.1003
0.1274 0.7840 0.0886 0.7905 0.0140 0.1955
0.1373 0.7754 0.0873 0.7430 0.0200 0.2370
0.1371 0.7626 0.1003 0.6449 0.0240 0.3311
0.1429 0.6750 0.1821 0.5780 0.0310 0.3910
0.1416 0.6380 0.2204 0.4765 0.0340 0.4895
0.1398 0.5787 0.2815 0.3880 0.0380 0.5740
0.1462 0.5365 0.3173 0.3380 0.0570 0.6050
0.1510 0.4662 0.3828 0.2699 0.1073 0.6228
0.1479 0.4498 0.4023 0.2417 0.1111 0.6472
0.1490 0.4037 0.4473 0.2609 0.1254 0.6137
0.1520 0.3981 0.4499 0.2317 0.1421 0.6262
____________________________________________________________________________________

Exxon Polywax 500
Exxon Polywax 1000
Comments: The polymer mixture concentration is kept constant at wB/wC = 0.50/0.50 to simulate a
bimodal polyethylene with Mn/kg.mol−1 = 0.638 and Mw/Mn = 1.44.

T/K = 413.15
xB+C 0.0500 0.0429 0.0359 0.0306 0.0274 0.0257 0.0245 0.0234 0.0200
P/MPa 44.1 45.8 47.1 47.8 48.1 48.2 49.1 49.7 51.3
xB+C 0.0165 0.0115 0.0085 0.0050
P/MPa 52.3 52.0 50.8 48.6
critical concentration: xB+C, crit = 0.0257, critical pressure: Pcrit/MPa = 48.2
T/K = 433.15
xB+C 0.0500 0.0429 0.0359 0.0306 0.0274 0.0257 0.0245 0.0234 0.0200
P/MPa 44.4 46.1 47.4 48.1 48.3 48.5 49.2 49.9 51.5
xB+C 0.0165 0.0115 0.0085 0.0050
P/MPa 52.3 52.0 50.9 48.7
continued
____________________________________________________________________________________
continued
T/K = 453.15
xB+C 0.0500 0.0429 0.0359 0.0306 0.0274 0.0257 0.0245 0.0234 0.0200
P/MPa 44.7 46.3 47.6 48.3 48.5 48.6 49.4 50.0 51.5
xB+C 0.0165 0.0115 0.0085 0.0050
P/MPa 52.4 52.1 51.0 48.8
T/K = 473.15
xB+C 0.0500 0.0429 0.0359 0.0306 0.0274 0.0257 0.0245 0.0234 0.0200
P/MPa 44.9 46.5 47.8 48.5 48.8 48.9 49.6 50.1 51.6
xB+C 0.0165 0.0115 0.0085 0.0050
P/MPa 52.4 52.2 51.1 49.0
T/K = 493.15
xB+C 0.0500 0.0429 0.0359 0.0306 0.0274 0.0257 0.0245 0.0234 0.0200
P/MPa 45.2 46.7 48.0 48.6 48.9 49.0 49.6 50.2 51.6
xB+C 0.0165 0.0115 0.0085 0.0050
P/MPa 52.4 52.2 51.1 49.1
T/K = 513.15
xB+C 0.0500 0.0429 0.0359 0.0306 0.0274 0.0257 0.0245 0.0234 0.0200
P/MPa 45.4 46.9 48.1 48.8 49.1 49.2 49.7 50.3 51.7
xB+C 0.0165 0.0115 0.0085 0.0050
P/MPa 52.5 52.2 51.2 49.2

Exxon Polywax 500
Exxon Polywax 2000

T/K = 413.15
xB+C 0.0480 0.0334 0.0300 0.0264 0.0244 0.0226 0.0211 0.0200 0.0160
P/MPa 48.4 56.2 57.7 58.9 59.4 59.7 62.6 64.0 67.8
continued
____________________________________________________________________________________
continued
xB+C 0.0118 0.0050
P/MPa 69.4 66.6
T/K = 433.15
xB+C 0.0480 0.0334 0.0300 0.0264 0.0244 0.0226 0.0211 0.0200 0.0160
P/MPa 48.8 55.7 57.1 58.4 59.0 59.3 61.8 63.1 67.0
xB+C 0.0118 0.0050
P/MPa 68.8 65.8
T/K = 453.15
xB+C 0.0480 0.0334 0.0300 0.0264 0.0244 0.0226 0.0211 0.0200 0.0160
P/MPa 49.2 55.4 56.7 58.0 58.6 59.0 61.3 62.5 66.2
xB+C 0.0118 0.0050
P/MPa 68.5 64.9
T/K = 473.15
xB+C 0.0480 0.0334 0.0300 0.0264 0.0244 0.0226 0.0211 0.0200 0.0160
P/MPa 49.4 55.1 56.3 57.6 58.1 58.7 60.6 61.9 65.8
xB+C 0.0118 0.0050
P/MPa 68.0 64.3
T/K = 493.15
xB+C 0.0480 0.0334 0.0300 0.0264 0.0244 0.0226 0.0211 0.0200 0.0160
P/MPa 49.7 54.7 55.9 57.2 57.7 58.3 60.0 61.1 65.0
xB+C 0.0118 0.0050
P/MPa 67.5 63.3
T/K = 513.15
xB+C 0.0480 0.0334 0.0300 0.0264 0.0244 0.0226 0.0211 0.0200 0.0160
P/MPa 50.0 54.4 55.6 56.8 57.4 58.0 59.6 60.6 64.4
xB+C 0.0118 0.0050
P/MPa 67.0 62.4
____________________________________________________________________________________

Exxon Polywax 500
Exxon Polywax 2000

T/K = 413.15
xB+C 0.0280 0.0250 0.0204 0.0160 0.0121 0.0106 0.0089 0.0080 0.0071
P/MPa 62.1 65.2 69.2 72.7 75.3 76.2 76.7 77.0 78.2
xB+C 0.0061
P/MPa 79.4
T/K = 433.15
xB+C 0.0280 0.0250 0.0204 0.0160 0.0121 0.0106 0.0089 0.0080 0.0071
P/MPa 61.4 64.6 67.6 70.1 73.2 74.6 74.4 75.9 75.2
xB+C 0.0061
P/MPa 76.3
T/K = 453.15
xB+C 0.0280 0.0250 0.0204 0.0160 0.0121 0.0106 0.0089 0.0080 0.0071
P/MPa 61.2 63.3 66.4 69.3 71.7 72.6 73.4 73.9 75.0
xB+C 0.0061
P/MPa 76.2
T/K = 473.15
xB+C 0.0280 0.0250 0.0204 0.0160 0.0121 0.0106 0.0089 0.0080 0.0071
P/MPa 60.8 62.6 65.6 68.3 70.5 71.3 72.2 72.5 73.7
xB+C 0.0061
P/MPa 74.9
T/K = 493.15
xB+C 0.0280 0.0250 0.0204 0.0160 0.0121 0.0106 0.0089 0.0080 0.0071
P/MPa 60.5 62.3 64.8 67.1 69.9 70.2 71.2 71.1 72.9
continued
____________________________________________________________________________________
continued
xB+C 0.0061
P/MPa 73.8
T/K = 513.15
xB+C 0.0280 0.0250 0.0204 0.0160 0.0121 0.0106 0.0089 0.0080 0.0071
P/MPa 59.2 61.7 63.9 66.1 68.9 69.1 70.0 70.7 71.7
xB+C 0.0061
P/MPa 72.0

−1 −1 −1
Exxon Polywax 500
Exxon Polywax 3000

T/K = 413.15
xB+C 0.0490 0.0329 0.0270 0.0238 0.0220 0.0204 0.0190 0.0180 0.0160
P/MPa 50.5 61.8 65.8 67.6 68.5 69.7 71.4 72.6 75.0
xB+C 0.0120 0.0085 0.0050
P/MPa 78.6 80.4 80.8
T/K = 433.15
xB+C 0.0490 0.0329 0.0270 0.0238 0.0220 0.0204 0.0190 0.0180 0.0160
P/MPa 50.6 61.3 64.9 66.8 67.5 68.6 70.4 71.8 74.0
xB+C 0.0120 0.0085 0.0050
P/MPa 77.3 78.9 79.4
T/K = 453.15
xB+C 0.0490 0.0329 0.0270 0.0238 0.0220 0.0204 0.0190 0.0180 0.0160
P/MPa 50.8 60.6 64.2 66.1 66.9 67.7 69.6 70.8 72.9
xB+C 0.0120 0.0085 0.0050
P/MPa 76.3 77.6 78.2
continued
____________________________________________________________________________________
continued
T/K = 473.15
xB+C 0.0490 0.0329 0.0270 0.0238 0.0220 0.0204 0.0190 0.0180 0.0160
P/MPa 51.9 60.2 63.7 65.5 66.2 66.9 68.7 70.0 72.3
xB+C 0.0120 0.0085 0.0050
P/MPa 75.2 76.9 77.2
T/K = 493.15
xB+C 0.0490 0.0329 0.0270 0.0238 0.0220 0.0204 0.0190 0.0180 0.0160
P/MPa 51.1 59.9 63.2 64.9 65.6 66.2 67.9 69.1 71.4
xB+C 0.0120 0.0085 0.0050
P/MPa 74.7 76.2 76.6
T/K = 513.15
xB+C 0.0490 0.0329 0.0270 0.0238 0.0220 0.0204 0.0190 0.0180 0.0160
P/MPa 51.3 59.7 62.9 64.2 64.8 65.4 67.0 68.3 70.5
xB+C 0.0120 0.0085 0.0050
P/MPa 73.8 75.4 75.9

Exxon Polywax 500
Exxon Polywax 3000

T/K = 413.15
xB+C 0.0278 0.0204 0.0161 0.0120 0.0083 0.0073 0.0065 0.0059 0.0053
P/MPa 66.1 74.2 79.2 84.0 88.5 89.7 90.8 91.5 92.4
xB+C 0.0048 0.0042 0.0030
P/MPa 93.9 95.6 98.9
T/K = 433.15
xB+C 0.0278 0.0204 0.0161 0.0120 0.0083 0.0073 0.0065 0.0059 0.0053
P/MPa 65.3 72.7 77.1 81.5 85.6 86.7 87.6 88.1 89.0
continued
____________________________________________________________________________________
continued
xB+C 0.0048 0.0042 0.0030
P/MPa 90.6 92.3 95.1
T/K = 453.15
xB+C 0.0278 0.0204 0.0161 0.0120 0.0083 0.0073 0.0065 0.0059 0.0053
P/MPa 64.6 71.3 75.4 79.5 83.3 84.4 85.4 86.1 87.0
xB+C 0.0048 0.0042 0.0030
P/MPa 88.6 90.2 93.1
T/K = 473.15
xB+C 0.0278 0.0204 0.0161 0.0120 0.0083 0.0073 0.0065 0.0059 0.0053
P/MPa 64.2 70.6 74.5 78.3 82.2 83.2 84.1 84.8 85.5
xB+C 0.0048 0.0042 0.0030
P/MPa 87.1 88.6 91.5
T/K = 493.15
xB+C 0.0278 0.0204 0.0161 0.0120 0.0083 0.0073 0.0065 0.0059 0.0053
P/MPa 63.5 69.5 73.2 76.8 80.7 81.6 82.7 83.2 84.1
xB+C 0.0048 0.0042 0.0030
P/MPa 85.4 86.8 89.6
T/K = 513.15
xB+C 0.0278 0.0204 0.0161 0.0120 0.0083 0.0073 0.0065 0.0059 0.0053
P/MPa 62.6 68.0 71.7 75.4 79.2 80.2 81.1 81.9 82.6
xB+C 0.0048 0.0042 0.0030
P/MPa 83.9 85.3 88.0

−1 −1 −1
Exxon Polywax 655
Exxon Polywax 2000

continued
____________________________________________________________________________________
continued
T/K = 413.15
xB+C 0.0280 0.0200 0.0160 0.0120 0.0098 0.0090 0.0084 0.0080 0.0060
P/MPa 58.8 65.8 68.9 71.2 72.3 72.7 73.6 74.2 76.6
xB+C 0.0030 0.0010
P/MPa 76.8 74.8
T/K = 433.15
xB+C 0.0280 0.0200 0.0160 0.0120 0.0098 0.0090 0.0084 0.0080 0.0060
P/MPa 58.4 64.6 67.6 70.1 71.2 71.6 72.4 72.9 75.2
xB+C 0.0030 0.0010
P/MPa 75.3 73.2
T/K = 453.15
xB+C 0.0280 0.0200 0.0160 0.0120 0.0098 0.0090 0.0084 0.0080 0.0060
P/MPa 58.0 63.7 66.6 69.0 70.0 70.2 71.0 71.7 73.8
xB+C 0.0030 0.0010
P/MPa 73.7 71.4
T/K = 473.15
xB+C 0.0280 0.0200 0.0160 0.0120 0.0098 0.0090 0.0084 0.0080 0.0060
P/MPa 57.8 63.0 65.6 67.9 68.7 69.0 70.1 70.8 72.7
xB+C 0.0030 0.0010
P/MPa 72.2 69.7
T/K = 493.15
xB+C 0.0280 0.0200 0.0160 0.0120 0.0098 0.0090 0.0084 0.0080 0.0060
P/MPa 57.5 62.3 64.8 67.1 67.9 68.2 68.2 69.1 69.9
xB+C 0.0030 0.0010
P/MPa 71.8 71.2
T/K = 513.15
xB+C 0.0280 0.0200 0.0160 0.0120 0.0098 0.0090 0.0084 0.0080 0.0060
P/MPa 57.2 61.7 63.9 66.1 66.9 67.1 68.0 68.7 70.7
xB+C 0.0030 0.0010
P/MPa 70.0 67.4
____________________________________________________________________________________

Exxon Polywax 655
Exxon Polywax 3000

T/K = 413.15
xB+C 0.0277 0.0204 0.0161 0.0121 0.0100 0.0086 0.0075 0.0068 0.0063
P/MPa 61.9 68.7 72.7 76.7 78.7 80.2 81.4 82.1 83.6
xB+C 0.0053 0.0045
P/MPa 86.3 88.5
T/K = 433.15
xB+C 0.0277 0.0204 0.0161 0.0121 0.0100 0.0086 0.0075 0.0068 0.0063
P/MPa 61.4 67.3 71.3 74.9 76.9 78.5 79.7 80.4 81.7
xB+C 0.0053 0.0045
P/MPa 84.6 86.8
T/K = 453.15
xB+C 0.0277 0.0204 0.0161 0.0121 0.0100 0.0086 0.0075 0.0068 0.0063
P/MPa 61.0 66.5 70.1 73.5 75.5 76.7 77.7 78.3 79.5
xB+C 0.0053 0.0045
P/MPa 82.3 84.5
T/K = 473.15
xB+C 0.0277 0.0204 0.0161 0.0121 0.0100 0.0086 0.0075 0.0068 0.0063
P/MPa 60.4 65.7 69.0 72.4 74.3 75.7 76.8 77.2 78.4
xB+C 0.0053 0.0045
P/MPa 81.2 83.4
T/K = 493.15
xB+C 0.0277 0.0204 0.0161 0.0121 0.0100 0.0086 0.0075 0.0068 0.0063
P/MPa 60.0 65.0 68.3 71.6 73.3 74.5 75.6 76.4 77.7
xB+C 0.0053 0.0045
P/MPa 80.4 82.1
continued
____________________________________________________________________________________
continued
T/K = 513.15
xB+C 0.0277 0.0204 0.0161 0.0121 0.0100 0.0086 0.0075 0.0068 0.0063
P/MPa 59.5 64.0 67.2 70.6 72.4 73.8 74.7 75.6 76.8
xB+C 0.0053 0.0045
P/MPa 78.9 81.0

Exxon Polywax 655
Exxon Polywax 3000

T/K = 413.15
xB+C 0.0106 0.0087 0.0079 0.0057 0.0046 0.0038 0.0030 0.0025 0.0022
P/MPa 80.0 84.7 88.8 91.4 93.8 95.5 97.3 98.6 99.4
xB+C 0.0019 0.0017
P/MPa 101.3 103.0
T/K = 433.15
xB+C 0.0106 0.0087 0.0079 0.0057 0.0046 0.0038 0.0030 0.0025 0.0022
P/MPa 78.2 82.8 86.8 89.4 91.8 93.5 95.3 96.3 97.2
xB+C 0.0019 0.0017
P/MPa 98.8 100.4
T/K = 453.15
xB+C 0.0106 0.0087 0.0079 0.0057 0.0046 0.0038 0.0030 0.0025 0.0022
P/MPa 76.5 80.7 84.6 87.2 89.4 91.1 92.7 93.9 94.5
xB+C 0.0019 0.0017
P/MPa 96.3 97.9
T/K = 473.15
xB+C 0.0106 0.0087 0.0079 0.0057 0.0046 0.0038 0.0030 0.0025 0.0022
P/MPa 74.8 78.9 82.9 85.2 87.5 89.0 90.7 91.6 92.2
continued
____________________________________________________________________________________
continued
xB+C 0.0019 0.0017
P/MPa 93.3 94.4
T/K = 493.15
xB+C 0.0106 0.0087 0.0079 0.0057 0.0046 0.0038 0.0030 0.0025 0.0022
P/MPa 73.3 77.0 80.8 83.0 85.2 86.7 88.5 89.7 90.2
xB+C 0.0019 0.0017
P/MPa 91.6 92.8
T/K = 513.15
xB+C 0.0106 0.0087 0.0079 0.0057 0.0046 0.0038 0.0030 0.0025 0.0022
P/MPa 71.6 75.3 78.7 81.0 83.2 84.9 86.5 87.5 88.3
xB+C 0.0019 0.0017
P/MPa 89.8 91.1

Exxon Polywax 1000
Exxon Polywax 3000

T/K = 413.15
xB+C 0.0107 0.0096 0.0084 0.0067 0.0057 0.0045 0.0037 0.0031 0.0025
P/MPa 76.6 79.9 83.1 86.6 89.2 91.7 93.6 94.8 96.2
xB+C 0.0023 0.0020 0.0018
P/MPa 96.7 98.5 99.8
T/K = 433.15
xB+C 0.0107 0.0096 0.0084 0.0067 0.0057 0.0045 0.0037 0.0031 0.0025
P/MPa 75.0 77.9 80.7 84.1 86.7 89.2 91.0 92.2 93.5
xB+C 0.0023 0.0020 0.0018
P/MPa 94.1 95.7 96.9
continued
____________________________________________________________________________________
continued
T/K = 453.15
xB+C 0.0107 0.0096 0.0084 0.0067 0.0057 0.0045 0.0037 0.0031 0.0025
P/MPa 73.7 76.5 79.1 82.3 84.6 86.9 88.4 89.4 90.3
xB+C 0.0023 0.0020 0.0018
P/MPa 90.9 92.7 93.9
T/K = 473.15
xB+C 0.0107 0.0096 0.0084 0.0067 0.0057 0.0045 0.0037 0.0031 0.0025
P/MPa 72.6 75.1 77.6 80.2 82.4 84.5 85.9 86.9 87.9
xB+C 0.0023 0.0020 0.0018
P/MPa 88.4 90.2 91.4
T/K = 493.15
xB+C 0.0107 0.0096 0.0084 0.0067 0.0057 0.0045 0.0037 0.0031 0.0025
P/MPa 71.3 73.8 76.1 78.8 80.8 82.5 83.9 84.9 85.7
xB+C 0.0023 0.0020 0.0018
P/MPa 86.2 87.0 89.3
T/K = 513.15
xB+C 0.0107 0.0096 0.0084 0.0067 0.0057 0.0045 0.0037 0.0031 0.0025
P/MPa 70.0 72.3 74.6 77.2 79.2 80.9 82.4 83.2 84.1
xB+C 0.0023 0.0020 0.0018
P/MPa 84.5 86.0 87.1

wA 0.651 0.651 0.510 0.510 0.510 0.379 0.379 0.379 0.230
wB 0.086 0.086 0.114 0.114 0.114 0.159 0.159 0.159 0.230
wC 0.263 0.263 0.376 0.376 0.376 0.462 0.462 0.462 0.540
T/K 413.15 433.65 404.15 413.15 447.65 413.15 428.15 457.55 413.15
P/MPa 82.4 79.8 69.8 68.0 62.9 55.5 53.0 49.1 39.5
wA 0.230 0.230
wB 0.230 0.230
wC 0.540 0.540
T/K 442.65 453.15
P/MPa 36.0 35.5
____________________________________________________________________________________

wA 0.834 0.834 0.834 0.834 0.834 0.574 0.574 0.574 0.574
wB 0.048 0.048 0.048 0.048 0.048 0.077 0.077 0.077 0.077
wC 0.118 0.118 0.118 0.118 0.118 0.349 0.349 0.349 0.349
T/K 390.15 395.15 425.15 444.65 463.65 388.15 403.15 433.65 453.65
P/MPa 142.6 138.6 120.2 111.4 106.5 112.0 102.2 89.4 84.3
wA 0.574 0.408 0.678 0.678 0.678 0.678 0.573 0.573 0.573
wB 0.077 0.280 0.156 0.156 0.156 0.156 0.255 0.255 0.255
wC 0.349 0.312 0.166 0.166 0.166 0.166 0.172 0.172 0.172
T/K 463.65 393.15 389.15 403.15 423.65 443.65 388.15 403.15 423.15
P/MPa 82.4 82.4 118.8 112.4 104.9 100.2 107.6 102.5 95.8
wA 0.573 0.573 0.408 0.408 0.408 0.482 0.482 0.482 0.248
wB 0.255 0.255 0.280 0.280 0.280 0.353 0.353 0.353 0.381
wC 0.172 0.172 0.312 0.312 0.312 0.163 0.163 0.163 0.371
T/K 443.15 458.65 413.65 448.65 459.15 393.15 423.15 448.65 393.15
P/MPa 91.5 88.9 74.1 71.0 70.6 94.5 86.6 82.5 56.2
wA 0.248 0.248 0.248 0.248
wB 0.381 0.381 0.381 0.381
wC 0.371 0.371 0.371 0.371
T/K 403.15 423.15 443.15 457.65
P/MPa 52.7 49.5 48.3 48.0

T/K = 403.15
wA = 0.483, wB = 0.138, wC = 0.379.
________________________________________________________________________________________________________
________________________________________________________________________________________________________
131.4 0.483 0.138 0.379 (cloud point)
121.8 0.447 0.205 0.348 0.539 0.036 0.425
99.0 0.423 0.254 0.322 0.546 0.029 0.425
69.6 0.337 0.404 0.258 0.553 0.019 0.428
42.4 0.556 0.002 0.442
________________________________________________________________________________________________________
____________________________________________________________________________________

wA 0.99218 0.99218 0.99218 0.99218 0.99218 0.99218 0.97801 0.97801 0.97801
wB 0.00557 0.00557 0.00557 0.00557 0.00557 0.00557 0.01970 0.01970 0.01970
wC 0.00225 0.00225 0.00225 0.00225 0.00225 0.00225 0.00229 0.00229 0.00229
T/K 404.66 408.64 414.59 418.61 422.55 428.53 407.57 410.03 412.54
P/bar 17.6 24.1 33.1 39.1 45.1 53.6 17.4 21.4 25.4
wA 0.97801 0.97801 0.97801 0.97801 0.97801 0.95555 0.95555 0.95555 0.95555
wB 0.01970 0.01970 0.01970 0.01970 0.01970 0.04220 0.04220 0.04220 0.04220
wC 0.00229 0.00229 0.00229 0.00229 0.00229 0.00225 0.00225 0.00225 0.00225
T/K 415.04 417.56 422.48 427.46 432.45 410.03 412.52 415.02 417.51
P/bar 29.3 32.9 40.4 47.6 54.7 13.4 17.8 21.6 25.0
wA 0.95555 0.93668 0.93668 0.93668 0.93668 0.93668 0.93668 0.93668 0.93668
wB 0.04220 0.06110 0.06110 0.06110 0.06110 0.06110 0.06110 0.06110 0.06110
wC 0.00225 0.00222 0.00222 0.00222 0.00222 0.00222 0.00222 0.00222 0.00222
T/K 420.00 417.56 420.09 422.56 425.03 427.51 429.99 432.47 437.47
P/bar 29.0 18.2 23.2 27.2 30.6 35.0 38.3 41.8 49.4
wA 0.93668 0.91600 0.91600 0.91600 0.91600 0.91600 0.91600 0.91600 0.91600
wB 0.06110 0.08180 0.08180 0.08180 0.08180 0.08180 0.08180 0.08180 0.08180
wC 0.00222 0.00220 0.00220 0.00220 0.00220 0.00220 0.00220 0.00220 0.00220
T/K 442.34 420.01 419.95 422.53 422.43 424.98 424.93 427.48 427.51
P/bar 56.4 14.6 14.8 18.4 18.6 22.4 22.6 26.4 26.4
wA 0.91600 0.91600 0.91600 0.91600 0.91600 0.91600 0.87440 0.87440 0.87440
wB 0.08180 0.08180 0.08180 0.08180 0.08180 0.08180 0.12350 0.12350 0.12350
wC 0.00220 0.00220 0.00220 0.00220 0.00220 0.00220 0.00210 0.00210 0.00210
T/K 429.96 429.96 432.47 437.44 442.41 447.35 427.49 432.42 437.36
P/bar 30.1 30.2 34.0 41.1 48.3 55.6 18.0 25.4 32.8
wA 0.87440 0.87440 0.87440 0.87440 0.86626 0.86626 0.86626 0.86626 0.86626
wB 0.12350 0.12350 0.12350 0.12350 0.13160 0.13160 0.13160 0.13160 0.13160
wC 0.00210 0.00210 0.00210 0.00210 0.00214 0.00214 0.00214 0.00214 0.00214
T/K 442.36 447.33 452.31 457.26 427.49 429.96 432.45 434.93 437.41
P/bar 40.1 47.3 54.4 61.4 15.4 19.3 23.2 27.0 30.8
wA 0.86626 0.86626 0.86626 0.86626 0.98317 0.98317 0.98317 0.98317 0.98317
wB 0.13160 0.13160 0.13160 0.13160 0.00443 0.00443 0.00443 0.00443 0.00443
wC 0.00214 0.00214 0.00214 0.00214 0.01240 0.01240 0.01240 0.01240 0.01240
T/K 442.36 447.33 452.31 457.26 392.62 397.32 402.57 407.59 412.57
P/bar 37.9 45.0 52.4 58.8 34.5 41.6 49.6 57.0 64.3
wA 0.98317 0.98317 0.98317 0.97797 0.97797 0.97797 0.97797 0.97797 0.97797
wB 0.00443 0.00443 0.00443 0.00973 0.00973 0.00973 0.00973 0.00973 0.00973
wC 0.01240 0.01240 0.01240 0.01230 0.01230 0.01230 0.01230 0.01230 0.01230
T/K 417.56 422.53 427.48 396.66 402.38 407.59 412.29 421.90 427.46
P/bar 71.4 78.4 85.0 38.2 46.8 54.6 61.6 75.2 82.3
continued
____________________________________________________________________________________
continued
wA 0.97637 0.97637 0.97637 0.97637 0.97637 0.97637 0.97637 0.97637 0.96690
wB 0.01093 0.01093 0.01093 0.01093 0.01093 0.01093 0.01093 0.01093 0.02060
wC 0.01270 0.01270 0.01270 0.01270 0.01270 0.01270 0.01270 0.01270 0.01250
T/K 396.64 400.63 401.99 407.57 412.52 417.56 422.43 427.40 392.62
P/bar 39.4 45.5 47.5 55.8 63.2 70.4 77.2 84.0 29.8
wA 0.96690 0.96690 0.96690 0.96690 0.96690 0.96690 0.96690 0.96600 0.96600
wB 0.02060 0.02060 0.02060 0.02060 0.02060 0.02060 0.02060 0.02130 0.02130
wC 0.01250 0.01250 0.01250 0.01250 0.01250 0.01250 0.01250 0.01270 0.01270
T/K 396.66 401.97 407.59 411.89 417.56 422.53 427.48 396.66 402.62
P/bar 36.0 44.2 52.0 59.0 67.2 74.2 80.7 37.2 46.2
wA 0.96600 0.96600 0.96600 0.96600 0.96600 0.95800 0.95800 0.95800 0.95800
wB 0.02130 0.02130 0.02130 0.02130 0.02130 0.02950 0.02950 0.02950 0.02950
wC 0.01270 0.01270 0.01270 0.01270 0.01270 0.01250 0.01250 0.01250 0.01250
T/K 407.59 412.57 417.56 422.53 427.46 397.03 401.99 407.59 416.93
P/bar 53.7 61.1 68.3 75.0 81.4 33.2 40.8 49.1 63.0
wA 0.95800 0.95800 0.95800 0.94630 0.94630 0.94630 0.94630 0.94630 0.94630
wB 0.02950 0.02950 0.02950 0.04120 0.04120 0.04120 0.04120 0.04120 0.04120
wC 0.01250 0.01250 0.01250 0.01250 0.01250 0.01250 0.01250 0.01250 0.01250
T/K 421.92 426.79 431.76 402.41 404.63 406.62 408.61 412.57 417.56
P/bar 70.1 76.5 82.9 37.0 40.5 43.6 46.5 52.3 59.6
wA 0.94630 0.94630 0.94630 0.92590 0.92590 0.92590 0.92590 0.92590 0.92590
wB 0.04120 0.04120 0.04120 0.06140 0.06140 0.06140 0.06140 0.06140 0.06140
wC 0.01250 0.01250 0.01250 0.01270 0.01270 0.01270 0.01270 0.01270 0.01270
T/K 422.53 427.46 432.42 402.22 407.20 412.18 417.17 422.16 427.15
P/bar 66.9 73.6 80.4 30.6 37.9 45.4 52.8 60.1 67.2
wA 0.92590 0.92590 0.90640 0.90640 0.90640 0.90640 0.90640 0.90640 0.90640
wB 0.06140 0.06140 0.08120 0.08120 0.08120 0.08120 0.08120 0.08120 0.08120
wC 0.01270 0.01270 0.01240 0.01240 0.01240 0.01240 0.01240 0.01240 0.01240
T/K 432.11 437.07 407.59 411.89 412.57 416.93 421.80 421.92 426.79
P/bar 74.1 80.5 32.9 39.2 40.3 46.8 54.0 54.2 61.2
wA 0.90640 0.90640 0.90640 0.88390 0.88390 0.88390 0.88390 0.88390 0.88390
wB 0.08120 0.08120 0.08120 0.10390 0.10390 0.10390 0.10390 0.10390 0.10390
wC 0.01240 0.01240 0.01240 0.01220 0.01220 0.01220 0.01220 0.01220 0.01220
T/K 431.76 436.70 441.62 412.12 414.57 416.56 422.06 427.48 431.97
P/bar 68.2 74.9 81.2 32.9 36.5 39.5 47.8 55.8 62.2
wA 0.88390 0.92975 0.92975 0.92975 0.92975 0.92975 0.92975 0.93350 0.93350
wB 0.10390 0.05980 0.05980 0.05980 0.05980 0.05980 0.05980 0.06040 0.06040
wC 0.01220 0.01045 0.01045 0.01045 0.01045 0.01045 0.01045 0.00610 0.00610
T/K 437.39 411.81 416.56 421.71 426.73 431.62 441.54 411.86 417.54
P/bar 69.8 38.5 45.6 53.3 50.6 57.6 31.0 23.4 32.3
wA 0.93350 0.93350 0.93350 0.93350 0.93350 0.89241 0.89241 0.89241 0.89241
wB 0.06040 0.06040 0.06040 0.06040 0.06040 0.09860 0.09860 0.09860 0.09860
wC 0.00610 0.00610 0.00610 0.00610 0.00610 0.00899 0.00899 0.00899 0.00899
T/K 421.79 427.49 431.68 437.41 442.36 396.61 401.99 402.17 407.15
P/bar 38.8 47.5 53.7 62.3 69.1 26.2 34.8 35.0 43.0
continued
____________________________________________________________________________________
continued
wA 0.89241 0.89241 0.89241 0.89241 0.89158 0.89158 0.89158 0.89158 0.89158
wB 0.09860 0.09860 0.09860 0.09860 0.10340 0.10340 0.10340 0.10340 0.10340
wC 0.00899 0.00899 0.00899 0.00899 0.00502 0.00502 0.00502 0.00502 0.00502
T/K 411.89 412.07 416.56 426.73 417.87 421.75 426.73 431.63 436.59
P/bar 50.2 50.6 57.2 72.2 17.7 23.7 31.3 38.6 45.8
wA 0.89158 0.89158 0.88122 0.88122 0.88122 0.88122 0.88122 0.88122 0.88122
wB 0.10340 0.10340 0.11110 0.11110 0.11110 0.11110 0.11110 0.11110 0.11110
wC 0.00502 0.00502 0.00768 0.00768 0.00768 0.00768 0.00768 0.00768 0.00768
T/K 441.57 449.43 417.54 422.48 427.49 432.42 437.41 442.36 447.33
P/bar 53.0 64.0 24.2 31.5 38.9 46.2 53.5 60.3 67.1
Type of data: liquid-liquid-vapor three phase equilibrium data

wA 0.99215 0.97801 0.95555 0.93668 0.91660 0.87440 0.86616 0.98320 0.97800
wB 0.00560 0.01970 0.04220 0.06110 0.08180 0.12350 0.13160 0.00440 0.00970
wC 0.00225 0.00229 0.00225 0.00222 0.00160 0.00210 0.00224 0.01240 0.01230
T/K 399.15 402.45 408.15 412.35 417.85 423.85 425.65 387.05 388.75
P/bar 8.8 9.3 10.1 10.8 11.1 12.3 12.6 25.8 26.0
wA 0.97640 0.96690 0.96600 0.95800 0.94630 0.92590 0.90640 0.88390 0.92975
wB 0.01090 0.02060 0.02130 0.02950 0.04120 0.06140 0.08120 0.10390 0.05980
wC 0.01270 0.01250 0.01270 0.01250 0.01250 0.01270 0.01240 0.01220 0.01045
T/K 388.35 390.75 390.05 393.15 395.95 400.55 404.95 409.85 402.95
P/bar 26.5 26.7 27.0 27.1 27.2 27.9 28.9 29.4 24.8
wA 0.93350 0.98111 0.89158 0.88122
wB 0.06040 0.00990 0.10340 0.11110
wC 0.00610 0.00899 0.00502 0.00768
T/K 407.85 392.95 417.15 415.75
P/bar 17.0 20.4 16.6 21.4


wA 0.100 0.100 0.100 0.100 0.100 0.100 0.100 0.100 0.100
wB 0.097 0.097 0.097 0.097 0.097 0.097 0.097 0.097 0.097
wC 0.803 0.803 0.803 0.803 0.803 0.803 0.803 0.803 0.803
T/K 493.13 495.21 495.42 497.45 497.48 499.62 499.75 502.06 504.69
P/bar 40.0 43.0 43.5 46.5 46.5 50.0 50.0 53.0 56.0
wA 0.100 0.154 0.154 0.154 0.154 0.154 0.154 0.154 0.154
wB 0.097 0.094 0.094 0.094 0.094 0.094 0.094 0.094 0.094
wC 0.803 0.752 0.752 0.752 0.752 0.752 0.752 0.752 0.752
T/K 506.72 473.48 473.72 475.99 478.47 478.58 480.95 483.60 488.50
P/bar 59.0 41.0 40.9 44.5 48.0 47.9 51.5 54.9 61.9
continued
____________________________________________________________________________________
continued
wA 0.154 0.154 0.154 0.154 0.200 0.200 0.200 0.200 0.200
wB 0.094 0.094 0.094 0.094 0.086 0.086 0.086 0.086 0.086
wC 0.752 0.752 0.752 0.752 0.714 0.714 0.714 0.714 0.714
T/K 493.51 498.50 503.48 508.46 455.40 460.29 465.25 470.02 474.75
P/bar 68.9 75.5 81.9 87.9 44.5 52.5 59.5 66.5 74.0
wA 0.200 0.200 0.200
wB 0.086 0.086 0.086
wC 0.714 0.714 0.714
T/K 484.44 493.89 503.10
P/bar 87.5 100.5 113.0
Polymer (B): poly(ethylene glycol) 1992KIA

Characterization: Mw/kg.mol−1 = 8.0, Aldrich Chem. Co., Inc., Milwaukee, WI
wA 0.196 0.196 0.196 0.196 0.196 0.196 0.196 0.351 0.351
wB 0.1206 0.1206 0.1206 0.1206 0.1206 0.1206 0.1206 0.09735 0.09735
wC 0.6834 0.6834 0.6834 0.6834 0.6834 0.6834 0.6834 0.55165 0.55165
T/K 304.35 308.55 313.45 318.45 323.35 333.35 343.15 304.75 323.15
P/bar 35.89 39.17 42.75 46.46 50.37 58.74 67.01 49.21 65.44
wA 0.351 0.351 0.505 0.505 0.505 0.505 0.505 0.200 0.200
wB 0.09735 0.09735 0.07425 0.07425 0.07425 0.07425 0.07425 0.240 0.240
wC 0.55165 0.55165 0.42075 0.42075 0.42075 0.42075 0.42075 0.560 0.560
T/K 333.25 343.25 304.95 313.55 323.35 333.05 338.45 308.45 313.45
P/bar 76.17 87.76 57.13 68.46 81.36 96.13 103.62 34.05 36.77
wA 0.200 0.200 0.200 0.200 0.295 0.295 0.295 0.295 0.399
wB 0.240 0.240 0.240 0.240 0.2115 0.2115 0.2115 0.2115 0.1803
wC 0.560 0.560 0.560 0.560 0.4935 0.4935 0.4935 0.4935 0.4207
T/K 318.25 323.25 333.15 343.15 313.15 324.05 333.15 343.15 304.85
P/bar 40.22 43.33 50.90 59.72 48.36 59.13 65.04 76.40 51.58
wA 0.399 0.399 0.399 0.399 0.498 0.498 0.498 0.498 0.498
wB 0.1803 0.1803 0.1803 0.1803 0.1506 0.1506 0.1506 0.1506 0.1506
wC 0.4207 0.4207 0.4207 0.4207 0.3514 0.3514 0.3514 0.3514 0.3514
T/K 312.95 323.25 333.15 343.15 303.85 308.45 313.15 318.15 323.15
P/bar 60.60 73.77 87.40 101.58 56.17 62.31 67.60 76.01 81.88
wA 0.498 0.498 0.498 0.200 0.200 0.200 0.300 0.300 0.300
wB 0.1506 0.1506 0.1506 0.400 0.400 0.400 0.350 0.350 0.350
wC 0.3514 0.3514 0.3514 0.400 0.400 0.400 0.350 0.350 0.350
T/K 328.15 333.15 343.15 313.15 323.15 333.15 313.15 323.15 333.15
P/bar 91.83 97.88 133.23 30.96 36.54 42.39 54.11 60.35 66.49
VLE VLE LLE VLE VLE VLE VLE VLE VLE
continued
____________________________________________________________________________________
continued
wA 0.400 0.400 0.400 0.500 0.500 0.200 0.200 0.200 0.200
wB 0.300 0.300 0.300 0.250 0.250 0.560 0.560 0.560 0.560
wC 0.300 0.300 0.300 0.250 0.250 0.240 0.240 0.240 0.240
T/K 313.15 323.15 333.15 313.15 323.15 304.45 308.65 313.15 318.25
P/bar 62.48 77.59 95.68 92.46 137.37 39.82 43.83 49.63 52.20
VLE VLE LLE LLE LLE VLE VLE VLE VLE
wA 0.200 0.200 0.200 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.560 0.560 0.560 0.525 0.525 0.525 0.525 0.525 0.525
wC 0.240 0.240 0.240 0.225 0.225 0.225 0.225 0.225 0.225
T/K 323.15 333.15 343.15 305.05 308.55 313.15 318.15 323.15 328.15
P/bar 59.32 65.69 77.48 44.42 48.16 49.15 53.19 62.08 65.47
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.300
wB 0.525 0.525 0.525 0.525 0.525 0.525 0.525 0.525 0.490
wC 0.225 0.225 0.225 0.225 0.225 0.225 0.225 0.225 0.210
T/K 333.15 343.15 313.15 318.15 323.15 328.15 333.15 343.15 313.15
P/bar 66.84 78.92 75.08 74.12 84.41 101.71 129.69 168.23 57.19
VLE VLE LLE LLE LLE LLE LLE LLE VLE
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.490 0.490 0.490 0.490 0.490 0.490 0.490 0.490 0.490
wC 0.210 0.210 0.210 0.210 0.210 0.210 0.210 0.210 0.210
T/K 318.15 323.15 333.15 343.15 313.15 318.15 323.15 333.15 343.15
P/bar 63.72 68.52 84.70 98.40 80.73 79.43 92.12 100.36 158.58
VLE VLE VLE VLE LLE LLE LLE LLE LLE
Polymer (B): poly(ethyl methacrylate) 2000BY1, 2000BY2

Solvent (C): ethyl methacrylate C6H10O2 97-63-2

wA 0.825 0.825 0.825 0.825 0.825 0.697 0.697 0.697 0.697
wB 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05
wC 0.125 0.125 0.125 0.125 0.125 0.253 0.253 0.253 0.253
T/K 436.75 450.45 458.65 472.75 490.45 316.05 336.15 355.65 374.25
P/bar 1201 929 940 957 975 546 605 657 702
wA 0.697 0.697 0.697 0.697 0.568 0.568 0.568 0.568 0.568
wB 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05
wC 0.253 0.253 0.253 0.253 0.382 0.382 0.382 0.382 0.382
T/K 393.95 415.65 438.05 466.75 314.85 333.55 354.95 374.55 395.55
P/bar 742 781 815 853 246 321 396 448 476
wA 0.493 0.493 0.493 0.493 0.493 0.493 0.493 0.493 0.493
wB 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05
wC 0.457 0.457 0.457 0.457 0.457 0.457 0.457 0.457 0.457
T/K 319.15 324.25 333.75 343.45 363.55 383.55 403.45 423.55
P/bar 67 85 122 163 228 284 328 353
____________________________________________________________________________________
Polymer (B): poly(hexyl acrylate) 2004BYU

Solvent (C): hexyl acrylate C9H16O2 2499-95-8

wA 0.899 0.899 0.899 0.899 0.899 0.822 0.822 0.822 0.822
wB 0.051 0.051 0.051 0.051 0.051 0.050 0.050 0.050 0.050
wC 0.050 0.050 0.050 0.050 0.050 0.128 0.128 0.128 0.128
T/K 358.25 362.45 383.85 402.85 428.65 317.45 318.35 319.05 328.95
P/bar 2246.6 1343.1 1077.6 983.5 902.4 1408.6 1115.5 1022.4 805.5
wA 0.822 0.822 0.822 0.822 0.822 0.739 0.739 0.739 0.739
wB 0.050 0.050 0.050 0.050 0.050 0.054 0.054 0.054 0.054
wC 0.128 0.128 0.128 0.128 0.128 0.207 0.207 0.207 0.207
T/K 345.05 365.05 385.35 404.75 424.55 312.25 327.85 345.05 365.05
P/bar 705.9 679.3 681.0 691.4 702.1 316.6 338.6 375.5 417.2
wA 0.739 0.739 0.739 0.611 0.611 0.611 0.611 0.611 0.611
wB 0.054 0.054 0.054 0.050 0.050 0.050 0.050 0.050 0.050
wC 0.207 0.207 0.207 0.339 0.339 0.339 0.339 0.339 0.339
T/K 385.75 409.25 428.75 303.25 307.45 313.85 323.85 332.55 323.75
P/bar 460.4 496.6 516.6 67.2 71.0 80.4 90.0 99.8 110.4
VLE VLE VLE VLLE VLLE LLE
wA 0.611 0.611 0.611 0.611
wB 0.050 0.050 0.050 0.050
wC 0.339 0.339 0.339 0.339
T/K 335.45 356.05 377.35 396.75
P/bar 149.7 213.5 268.3 306.6
Polymer (B): poly(hexyl methacrylate) 2004BYU

Solvent (C): hexyl methacrylate C10H18O2 142-09-6

wA 0.852 0.852 0.852 0.852 0.852 0.852 0.811 0.811 0.811
wB 0.056 0.056 0.056 0.056 0.056 0.056 0.045 0.045 0.045
wC 0.092 0.092 0.092 0.092 0.092 0.092 0.144 0.144 0.144
T/K 384.75 387.85 390.65 404.25 424.55 444.65 355.45 357.25 361.25
P/bar 1794.8 1612.1 1508.6 1227.6 1058.6 1022.4 1825.9 1541.7 1336.2
wA 0.811 0.811 0.811 0.811 0.811 0.626 0.626 0.626 0.626
wB 0.045 0.045 0.045 0.045 0.045 0.050 0.050 0.050 0.050
wC 0.144 0.144 0.144 0.144 0.144 0.324 0.324 0.324 0.324
T/K 366.05 386.45 405.35425.95 449.35 334.15 354.75 373.15 393.25
P/bar 1205.2 976.6 901.0 871.4 859.3 501.7 507.6 519.3 524.5
continued
____________________________________________________________________________________
continued
wA 0.626 0.626 0.525 0.525 0.525 0.525 0.525 0.525 0.525
wB 0.050 0.050 0.047 0.047 0.047 0.047 0.047 0.047 0.047
wC 0.324 0.324 0.428 0.428 0.428 0.428 0.428 0.428 0.428
T/K 415.15 434.55 313.05 323.95 333.35 351.65 355.95 373.15 353.55
P/bar 528.3 493.8 67.2 81.7 92.1 112.2 119.2 139.8 131.0
VLE VLE VLE VLLE VLLE VLLE LLE
wA 0.525 0.525
wB 0.047 0.047
wC 0.428 0.428
T/K 374.45 395.05
P/bar 192.1 241.7


wA 0.088 0.088 0.088 0.088 0.088 0.088 0.088 0.088 0.260
wB 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025
wC 0.887 0.887 0.887 0.887 0.887 0.887 0.887 0.887 0.715
T/K 403.15 413.15 423.15 433.15 443.15 453.15 463.15 473.15 323.15
P/MPa 3.8 5.7 7.6 9.1 10.2 12.3 13.9 15.3 10.1
wA 0.260 0.260 0.260 0.260 0.260 0.260 0.260 0.260
wB 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025
wC 0.715 0.715 0.715 0.715 0.715 0.715 0.715 0.715
T/K 333.15 343.15 353.15 363.15 373.15 383.15 393.15 403.15
P/MPa 11.6 13.6 15.2 17.6 19.5 21.2 22.9 23.7
Polymer (B): poly(L-lactide) 2000LE2, 2000LE3

−1
Characterization: Mη /kg.mol = 2.0, Polysciences, Inc., Warrington, PA
Solvent (C): chlorodifluoromethane CHClF2 75-45-6

wA 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0722 0.0722 0.0722
wB 0.0288 0.0288 0.0288 0.0288 0.0288 0.0288 0.0278 0.0278 0.0278
wC 0.9712 0.9712 0.9712 0.9712 0.9712 0.9712 0.9000 0.9000 0.9000
T/K 344.35 353.05 363.35 372.75 382.05 392.75 305.45 314.45 323.95
P/MPa 3.60 5.95 8.72 10.90 13.05 15.62 1.76 2.15 2.69
continued
____________________________________________________________________________________
continued
wA 0.0722 0.0722 0.0722 0.0722 0.0722 0.0722 0.0722 0.0722 0.0722
wB 0.0278 0.0278 0.0278 0.0278 0.0278 0.0278 0.0278 0.0278 0.0278
wC 0.9000 0.9000 0.9000 0.9000 0.9000 0.9000 0.9000 0.9000 0.9000
T/K 328.75 333.85 342.65 353.15 357.45 360.55 361.55 363.05 333.85
P/MPa 3.00 3.30 3.97 4.80 5.10 5.33 5.40 5.50 3.98
VLE VLLE VLLE VLLE VLLE VLLE VLLE CP LLE
wA 0.0722 0.0722 0.0722 0.0722 0.0722 0.0722 0.1470 0.1470 0.1470
wB 0.0278 0.0278 0.0278 0.0278 0.0278 0.0278 0.0310 0.0310 0.0310
wC 0.9000 0.9000 0.9000 0.9000 0.9000 0.9000 0.8220 0.8220 0.8220
T/K 342.45 352.95 362.85 373.35 382.35 392.55 309.05 314.25 325.55
P/MPa 6.53 9.70 12.53 15.20 17.37 19.70 2.58 2.94 3.60
LLE LLE LLE LLE LLE LLE VLE VLE VLLE
wA 0.1470 0.1470 0.1470 0.1470 0.1470 0.1470 0.1470 0.1470 0.1470
wB 0.0310 0.0310 0.0310 0.0310 0.0310 0.0310 0.0310 0.0310 0.0310
wC 0.8220 0.8220 0.8220 0.8220 0.8220 0.8220 0.8220 0.8220 0.8220
T/K 333.95 344.35 354.35 356.35 325.35 333.75 344.45 355.55 364.55
P/MPa 4.27 5.03 5.95 6.10 3.97 6.70 10.03 13.20 16.10
VLLE VLLE VLLE CP LLE LLE LLE LLE LLE
wA 0.1470 0.1470 0.1470 0.3066 0.3066 0.3066 0.3066 0.3066 0.3066
wB 0.0310 0.0310 0.0310 0.0316 0.0316 0.0316 0.0316 0.0316 0.0316
wC 0.8220 0.8220 0.8220 0.6618 0.6618 0.6618 0.6618 0.6618 0.6618
T/K 372.65 382.65 391.85 304.05 310.25 316.35 323.75 333.25 336.35
P/MPa 18.10 20.60 22.75 3.45 3.72 4.15 4.75 5.65 5.95
LLE LLE LLE VLE VLLE VLLE VLLE VLLE VLLE
wA 0.3066 0.3066 0.3066 0.3066 0.3066 0.3066 0.3066 0.3066 0.3066
wB 0.0316 0.0316 0.0316 0.0316 0.0316 0.0316 0.0316 0.0316 0.0316
wC 0.6618 0.6618 0.6618 0.6618 0.6618 0.6618 0.6618 0.6618 0.6618
T/K 337.45 338.65 339.25 340.95 342.05 342.95 343.85 344.85 309.75
P/MPa 6.05 6.15 6.22 6.35 6.45 6.55 6.60 6.63 5.07
VLLE VLLE VLLE VLLE VLLE VLLE VLLE CP LLE
wA 0.3066 0.3066 0.3066 0.3066 0.3066 0.3066 0.3066 0.3066 0.3066
wB 0.0316 0.0316 0.0316 0.0316 0.0316 0.0316 0.0316 0.0316 0.0316
wC 0.6618 0.6618 0.6618 0.6618 0.6618 0.6618 0.6618 0.6618 0.6618
T/K 316.75 324.05 333.95 344.75 353.85 362.25 372.85 382.15 392.35
P/MPa 8.10 10.93 14.50 18.05 21.07 23.50 26.42 28.97 31.35
wA 0.4257 0.4257 0.4257 0.4257 0.4257 0.4257 0.4257 0.4257 0.4257
wB 0.0326 0.0326 0.0326 0.0326 0.0326 0.0326 0.0326 0.0326 0.0326
wC 0.5417 0.5417 0.5417 0.5417 0.5417 0.5417 0.5417 0.5417 0.5417
T/K 305.05 315.35 323.75 329.05 333.05 333.75 334.15 334.85 335.55
P/MPa 4.47 5.20 6.00 6.51 6.93 6.98 7.02 7.06 7.10
VLLE VLLE VLLE VLLE VLLE VLLE VLLE VLLE VLLE
continued
____________________________________________________________________________________
continued
wA 0.4257 0.4257 0.4257 0.4257 0.4257 0.4257 0.4257 0.4257 0.4257
wB 0.0326 0.0326 0.0326 0.0326 0.0326 0.0326 0.0326 0.0326 0.0326
wC 0.5417 0.5417 0.5417 0.5417 0.5417 0.5417 0.5417 0.5417 0.5417
T/K 336.25 337.15 305.05 315.35 324.35 328.05 338.15 350.85 362.45
P/MPa 7.13 7.15 9.25 13.90 17.40 18.95 22.40 26.97 30.70
VLLE CP LLE LLE LLE LLE LLE LLE LLE
wA 0.4257 0.4257 0.4257 0.5014 0.5014 0.5014 0.5014 0.5014 0.5014
wB 0.0326 0.0326 0.0326 0.0281 0.0281 0.0281 0.0281 0.0281 0.0281
wC 0.5417 0.5417 0.5417 0.4705 0.4705 0.4705 0.4705 0.4705 0.4705
T/K 372.85 383.05 393.45 302.45 315.85 325.05 333.75 342.55 354.05
P/MPa 33.60 36.30 38.15 12.62 18.22 22.55 25.72 28.90 33.02
wA 0.5014 0.5014 0.5014 0.6470 0.6470 0.6470 0.6470 0.6470 0.6470
wB 0.0281 0.0281 0.0281 0.0260 0.0260 0.0260 0.0260 0.0260 0.0260
wC 0.4705 0.4705 0.4705 0.3270 0.3270 0.3270 0.3270 0.3270 0.3270
T/K 363.65 373.35 383.55 315.35 324.55 335.15 343.85 352.95 362.95
P/MPa 35.87 38.65 41.22 30.25 34.42 38.18 41.50 44.45 47.75
wA 0.6470 0.6470 0.7996 0.7996 0.7996 0.7996 0.7996 0.7996
wB 0.0260 0.0260 0.0282 0.0282 0.0282 0.0282 0.0282 0.0282
wC 0.3270 0.3270 0.1722 0.1722 0.1722 0.1722 0.1722 0.1722
T/K 372.85 382.65 323.95 334.35 343.45 353.25 363.35 372.05
P/MPa 50.65 53.40 56.55 60.65 63.75 66.55 69.15 71.47
LLE LLE LLE LLE LLE LLE LLE LLE
Comments: CP is a critical point.


wA 0.0000 0.0000 0.0000 0.0000 0.1166 0.1166 0.1166 0.1166 0.1166
wB 0.0303 0.0303 0.0303 0.0303 0.0276 0.0276 0.0276 0.0276 0.0276
wC 0.9697 0.9697 0.9697 0.9697 0.8558 0.8558 0.8558 0.8558 0.8558
T/K 336.95 350.95 360.35 373.85 323.85 333.55 343.15 353.05 363.25
P/MPa 4.08 8.60 11.38 15.03 5.75 9.45 12.85 16.30 19.65
wA 0.1166 0.2978 0.2978 0.2978 0.2978 0.2978 0.2978 0.2978 0.2978
wB 0.0276 0.0266 0.0266 0.0266 0.0266 0.0266 0.0266 0.0266 0.0266
wC 0.8558 0.6756 0.6756 0.6756 0.6756 0.6756 0.6756 0.6756 0.6756
T/K 373.05 303.55 313.25 323.75 333.45 343.45 353.05 363.15 373.25
P/MPa 22.70 6.70 11.30 16.00 20.20 24.20 27.90 31.55 34.95
continued
____________________________________________________________________________________
continued
wA 0.3783 0.3783 0.3783 0.3783 0.3783 0.3783 0.3783 0.3783 0.5102
wB 0.0278 0.0278 0.0278 0.0278 0.0278 0.0278 0.0278 0.0278 0.0281
wC 0.5939 0.5939 0.5939 0.5939 0.5939 0.5939 0.5939 0.5939 0.4617
T/K 303.15 313.35 323.95 333.35 343.35 353.05 362.95 372.95 323.45
P/MPa 11.50 16.50 21.60 25.80 30.05 33.95 37.70 41.15 32.80
wA 0.5102 0.5102 0.5102 0.5102 0.5102 0.5890 0.5890 0.5890 0.5890
wB 0.0281 0.0281 0.0281 0.0281 0.0281 0.0254 0.0254 0.0254 0.0254
wC 0.4617 0.4617 0.4617 0.4617 0.4617 0.3856 0.3856 0.3856 0.3856
T/K 333.55 343.05 353.15 363.15 373.15 323.65 333.75 343.05 353.15
P/MPa 37.65 41.90 46.15 50.10 53.50 43.20 48.15 52.30 56.65
wA 0.5890 0.5890 0.1853 0.1853 0.1853 0.1853 0.1853 0.1853 0.1853
wB 0.0254 0.0254 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307 0.0307
wC 0.3856 0.3856 0.7840 0.7840 0.7840 0.7840 0.7840 0.7840 0.7840
T/K 363.25 373.25 313.55 323.45 333.55 343.35 353.55 363.05 373.25
P/MPa 60.65 64.05 5.50 9.65 13.60 17.30 21.00 24.25 27.57


wA 0.0000 0.0000 0.0000 0.0000 0.0000 0.1006 0.1006 0.1006 0.1006
wB 0.0291 0.0291 0.0291 0.0291 0.0291 0.0284 0.0284 0.0284 0.0284
wC 0.9709 0.9709 0.9709 0.9709 0.9709 0.8710 0.8710 0.8710 0.8710
T/K 334.25 342.55 353.15 364.45 373.95 323.85 333.85 343.25 352.95
P/MPa 3.60 6.30 9.63 12.86 15.76 5.57 9.40 12.70 16.05
wA 0.1006 0.1006 0.2016 0.2016 0.2016 0.2016 0.2016 0.2016 0.2016
wB 0.0284 0.0284 0.0296 0.0296 0.0296 0.0296 0.0296 0.0296 0.0296
wC 0.8710 0.8710 0.7688 0.7688 0.7688 0.7688 0.7688 0.7688 0.7688
T/K 362.75 373.35 312.85 323.95 333.65 343.65 353.65 362.95 372.85
P/MPa 19.30 22.58 6.95 11.50 15.55 19.35 23.15 26.45 29.70
wA 0.2855 0.2855 0.2855 0.2855 0.2855 0.2855 0.2855 0.2855 0.3734
wB 0.0302 0.0302 0.0302 0.0302 0.0302 0.0302 0.0302 0.0302 0.0311
wC 0.6843 0.6843 0.6843 0.6843 0.6843 0.6843 0.6843 0.6843 0.5955
T/K 303.15 313.55 323.95 333.55 343.65 353.15 363.25 373.85 303.15
P/MPa 6.85 11.65 16.30 20.50 24.70 28.35 32.05 35.75 12.55
wA 0.3734 0.3734 0.3734 0.3734 0.3734 0.3734 0.3734 0.6058 0.6058
wB 0.0311 0.0311 0.0311 0.0311 0.0311 0.0311 0.0311 0.0289 0.0289
wC 0.5955 0.5955 0.5955 0.5955 0.5955 0.5955 0.5955 0.3653 0.3653
T/K 313.15 323.65 333.25 343.05 353.25 362.95 373.35 323.85 333.95
P/MPa 17.65 22.60 26.95 31.20 35.35 39.12 42.85 47.85 52.68
continued
____________________________________________________________________________________
continued
wA 0.6058 0.6058 0.6058 0.6058 0.4849 0.4849 0.4849 0.4849 0.4849
wB 0.0289 0.0289 0.0289 0.0289 0.0310 0.0310 0.0310 0.0310 0.0310
wC 0.3653 0.3653 0.3653 0.3653 0.4841 0.4841 0.4841 0.4841 0.4841
T/K 343.15 353.05 363.25 373.25 313.15 323.75 333.25 343.15 353.05
P/MPa 56.90 61.00 65.00 68.50 27.70 33.15 37.75 42.28 46.45
wA 0.4849 0.4849
wB 0.0310 0.0310
wC 0.4841 0.4841
T/K 363.15 373.15
P/MPa 50.55 54.15
Polymer (B): poly(L-lactide) 2002LEE

Characterization: Mη /kg.mol−1 = 2.0, Polysciences, Inc., Warrington, PA
Solvent (C): dichloromethane CH2Cl2 75-09-2

wA 0.8733 0.8733 0.8733 0.8733 0.8733 0.8733 0.8366 0.8366 0.8366
wB 0.0506 0.0506 0.0506 0.0506 0.0506 0.0506 0.0477 0.0477 0.0477
wC 0.0761 0.0761 0.0761 0.0761 0.0761 0.0761 0.1157 0.1157 0.1157
T/K 322.65 333.45 343.15 353.15 363.15 373.35 324.55 333.65 343.45
P/MPa 76.65 78.45 80.45 82.05 83.35 84.75 66.05 68.25 70.35
wA 0.8366 0.8366 0.8366 0.8054 0.8054 0.8054 0.8054 0.8054 0.8054
wB 0.0477 0.0477 0.0477 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495
wC 0.1157 0.1157 0.1157 0.1451 0.1451 0.1451 0.1451 0.1451 0.1451
T/K 353.55 363.25 372.95 323.65 333.35 343.25 353.25 363.55 375.15
P/MPa 72.15 74.15 75.65 56.75 59.65 62.35 64.75 67.05 69.35
wA 0.7444 0.7444 0.7444 0.7444 0.7444 0.7444 0.6725 0.6725 0.6725
wB 0.0515 0.0515 0.0515 0.0515 0.0515 0.0515 0.0492 0.0492 0.0492
wC 0.2041 0.2041 0.2041 0.2041 0.2041 0.2041 0.2783 0.2783 0.2783
T/K 323.15 333.25 343.25 353.15 363.25 373.25 323.25 333.35 343.35
P/MPa 42.55 46.05 49.25 52.05 54.65 57.05 29.75 33.65 37.15
wA 0.6725 0.6725 0.6725 0.5690 0.5690 0.5690 0.5690 0.5690 0.5690
wB 0.0492 0.0492 0.0492 0.0498 0.0498 0.0498 0.0498 0.0498 0.0498
wC 0.2783 0.2783 0.2783 0.3812 0.3812 0.3812 0.3812 0.3812 0.3812
T/K 353.15 362.75 373.15 323.75 333.25 343.15 353.15 363.45 373.15
P/MPa 40.35 43.05 45.95 14.85 18.55 22.25 25.55 28.75 31.25
wA 0.4448 0.4448 0.4448 0.4448 0.4448 0.4448 0.4448 0.4448
wB 0.0522 0.0522 0.0522 0.0522 0.0522 0.0522 0.0522 0.0522
wC 0.5030 0.5030 0.5030 0.5030 0.5030 0.5030 0.5030 0.5030
T/K 304.05 313.95 323.75 333.85 343.25 353.25 363.25 372.65
P/MPa 4.82 5.65 6.55 7.58 8.60 11.37 14.45 17.05
____________________________________________________________________________________


wA 0.7398 0.7398 0.7398 0.7398 0.7398 0.7398 0.7398 0.6666 0.6666
wB 0.0508 0.0508 0.0508 0.0508 0.0508 0.0508 0.0508 0.0484 0.0484
wC 0.2094 0.2094 0.2094 0.2094 0.2094 0.2094 0.2094 0.2850 0.2850
T/K 318.15 326.15 334.35 343.25 352.75 362.95 372.85 318.05 322.65
P/MPa 52.75 55.93 58.78 62.00 65.07 68.14 70.85 35.30 37.28
wA 0.6666 0.6666 0.6666 0.6666 0.6666 0.5648 0.5648 0.5648 0.5648
wB 0.0484 0.0484 0.0484 0.0484 0.0484 0.0507 0.0507 0.0507 0.0507
wC 0.2850 0.2850 0.2850 0.2850 0.2850 0.3845 0.3845 0.3845 0.3845
T/K 333.25 343.55 352.45 363.35 373.25 313.95 323.05 333.35 343.45
P/MPa 41.78 45.82 49.06 52.75 55.67 15.07 19.30 23.87 27.84
wA 0.5648 0.5648 0.5648 0.4408 0.4408 0.4408 0.4408 0.4408 0.4408
wB 0.0507 0.0507 0.0507 0.0508 0.0508 0.0508 0.0508 0.0508 0.0508
wC 0.3845 0.3845 0.3845 0.5084 0.5084 0.5084 0.5084 0.5084 0.5084
T/K 352.75 363.75 372.65 312.35 322.35 333.55 342.45 353.15 362.55
P/MPa 31.44 35.27 38.15 5.26 6.14 8.67 12.29 16.23 19.50
wA 0.4408 0.3865 0.3865 0.3865 0.3865 0.3865 0.3865 0.3865
wB 0.0508 0.0509 0.0509 0.0509 0.0509 0.0509 0.0509 0.0509
wC 0.5084 0.5626 0.5626 0.5626 0.5626 0.5626 0.5626 0.5626
T/K 372.45 311.65 322.75 332.45 345.05 352.35 361.75 373.15
P/MPa 22.75 4.82 5.75 6.76 7.97 10.73 13.55 17.43


wA 0.7479 0.7479 0.7479 0.7479 0.7479 0.7479 0.7479 0.6549 0.6549
wB 0.0509 0.0509 0.0509 0.0509 0.0509 0.0509 0.0509 0.0531 0.0531
wC 0.2012 0.2012 0.2012 0.2012 0.2012 0.2012 0.2012 0.2920 0.2920
T/K 318.45 324.75 333.45 343.25 352.75 362.35 372.25 316.85 324.45
P/MPa 58.20 60.55 63.67 67.05 69.97 72.85 75.52 34.94 38.55
wA 0.6549 0.6549 0.6549 0.6549 0.6549 0.6023 0.6023 0.6023 0.6023
wB 0.0531 0.0531 0.0531 0.0531 0.0531 0.0499 0.0499 0.0499 0.0499
wC 0.2920 0.2920 0.2920 0.2920 0.2920 0.3478 0.3478 0.3478 0.3478
T/K 333.75 343.55 352.85 363.05 373.05 317.95 324.15 334.75 345.75
P/MPa 42.37 46.18 49.64 53.07 56.15 20.47 23.40 27.95 32.55
continued
____________________________________________________________________________________
continued
wA 0.6023 0.6023 0.6023 0.4590 0.4590 0.4590 0.4590 0.4590 0.4590
wB 0.0499 0.0499 0.0499 0.0513 0.0513 0.0513 0.0513 0.0513 0.0513
wC 0.3478 0.3478 0.3478 0.4897 0.4897 0.4897 0.4897 0.4897 0.4897
T/K 352.05 362.75 372.65 314.35 322.85 333.15 343.55 352.95 364.25
P/MPa 34.85 38.70 42.05 5.45 7.37 11.72 15.00 19.50 23.56
wA 0.4590
wB 0.0513
wC 0.4897
T/K 372.95
P/MPa 26.05

−1
Solvent (C): dimethyl ether C2H6O 115-10-6

wA 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.1216 0.1216 0.1216
wB 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.0521 0.0521 0.0521
wC 0.9500 0.9500 0.9500 0.9500 0.9500 0.9500 0.8263 0.8263 0.8263
T/K 328.65 333.05 343.05 354.15 363.35 372.95 303.45 313.95 323.15
P/MPa 2.47 3.75 6.55 9.27 11.45 13.73 2.52 5.73 8.55
wA 0.1216 0.1216 0.1216 0.1216 0.1216 0.2034 0.2034 0.2034 0.2034
wB 0.0521 0.0521 0.0521 0.0521 0.0521 0.0439 0.0439 0.0439 0.0439
wC 0.8263 0.8263 0.8263 0.8263 0.8263 0.7527 0.7527 0.7527 0.7527
T/K 333.55 342.85 353.55 362.75 373.35 303.05 314.25 325.95 333.65
P/MPa 11.50 13.75 16.12 18.25 20.65 8.55 11.95 15.15 17.39
wA 0.2034 0.2034 0.2034 0.2034 0.3126 0.3126 0.3126 0.3126 0.3126
wB 0.0439 0.0439 0.0439 0.0439 0.0468 0.0468 0.0468 0.0468 0.0468
wC 0.7527 0.7527 0.7527 0.7527 0.6406 0.6406 0.6406 0.6406 0.6406
T/K 342.85 353.15 363.05 372.95 303.25 313.25 323.45 333.65 342.95
P/MPa 19.65 21.70 23.82 25.95 18.70 21.35 23.99 26.42 28.80
wA 0.3126 0.3126 0.3126 0.4017 0.4017 0.4017 0.4017 0.4017 0.4017
wB 0.0468 0.0468 0.0468 0.0485 0.0485 0.0485 0.0485 0.0485 0.0485
wC 0.6406 0.6406 0.6406 0.5498 0.5498 0.5498 0.5498 0.5498 0.5498
T/K 353.75 362.85 372.95 304.55 313.05 322.95 333.85 342.95 353.45
P/MPa 30.82 32.35 34.28 27.12 29.33 31.72 34.12 36.20 37.79
wA 0.4017 0.4017 0.4729 0.4729 0.4729 0.4729 0.4729 0.4729 0.4729
wB 0.0485 0.0485 0.0456 0.0456 0.0456 0.0456 0.0456 0.0456 0.0456
wC 0.5498 0.5498 0.4815 0.4815 0.4815 0.4815 0.4815 0.4815 0.4815
T/K 362.75 372.75 304.05 313.45 323.55 333.55 343.05 353.05 362.75
P/MPa 39.49 41.40 33.90 35.99 38.48 40.79 42.95 44.95 46.15
continued
____________________________________________________________________________________
continued
wA 0.4729 0.6040 0.6040 0.6040 0.6040 0.6040 0.6040 0.6040 0.6040
wB 0.0456 0.0428 0.0428 0.0428 0.0428 0.0428 0.0428 0.0428 0.0428
wC 0.4815 0.3532 0.3532 0.3532 0.3532 0.3532 0.3532 0.3532 0.3532
T/K 373.15 303.65 313.75 323.25 333.05 343.35 353.25 363.25 373.25
P/MPa 47.75 45.95 48.95 51.35 53.75 56.25 57.75 58.65 60.25
wA 0.6908 0.6908 0.6908 0.6908 0.6908 0.6908 0.6908 0.6908
wB 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510 0.0510
wC 0.2582 0.2582 0.2582 0.2582 0.2582 0.2582 0.2582 0.2582
T/K 304.15 313.25 324.55 334.15 342.95 353.05 363.45 373.35
P/MPa 56.25 59.35 62.75 65.45 67.85 69.75 70.85 72.45
Polymer (B): poly(L-lactide) 1991TOM

L104, Boehringer Ingelheim Chemicals

Comments: Solubility measurements were carried out using a mixture of 99 wt% CO2 and
1 wt% C3H6O.
T/K = 318.15
P/bar 150 200 250 300
wB 0.000485 0.000554 0.000839 0.00157
T/K = 328.15
P/bar 150 200 250 300
wB 0.000561 0.00127 0.00123 0.00254
T/K = 338.15
P/bar 200 250 300
wB 0.00214 0.00220 0.00368
Polymer (B): poly(L-lactide) 2002BOT

Characterization: Mn/kg.mol−1 = 44, Mw/kg.mol−1 = 100, semicrystalline,
Solvent (C): trichloromethane CHCl3 67-66-3

T/K = 318.15
cB/(mg/ml CHCl3) 3 8
P/bar 62.8−65.5 63.2−67.6
Comments: Cloud points were obtained at different CO2 pressurization rates.
____________________________________________________________________________________
Polymer (B): poly(DL-lactide) 2002BOT

Sigma Chemical Co., Inc., St. Louis, MO

T/K = 318.15
cB/(mg/ml CHCl3) 3 8
P/bar 64.8−65.1 64.3−67.2
Comments: Cloud points were obtained at different CO2 pressurization rates.
Polymer (B): poly(methyl methacrylate) 1992KIA

−1
Solvent (C): 2-butanone C4H8O 78-93-3

wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275
wC 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225
T/K 298.15 303.15 308.15 313.15 318.15 323.15 328.15 333.15 338.15
P/bar 13.79 14.99 16.32 17.96 20.10 21.33 23.26 24.76 26.79
wA 0.150 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.1275 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.120
wC 0.7225 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680
T/K 343.15 299.35 303.15 308.15 314.15 318.15 323.15 328.15 333.15
P/bar 27.71 19.86 21.04 22.99 25.37 27.45 29.72 32.54 34.81
wA 0.200 0.200 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.120 0.120 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125
wC 0.680 0.680 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 338.15 343.05 300.65 308.25 313.35 315.25 323.25 328.15 333.35
P/bar 37.30 40.68 23.94 27.74 30.57 32.18 54.77 69.97 84.45
VLE VLE VLE VLE VLE VLE LLE LLE LLE
wA 0.250 0.250 0.264 0.264 0.264 0.264 0.264 0.264 0.264
wB 0.1125 0.1125 0.1104 0.1104 0.1104 0.1104 0.1104 0.1104 0.1104
wC 0.6375 0.6375 0.6256 0.6256 0.6256 0.6256 0.6256 0.6256 0.6256
T/K 337.65 343.15 300.55 303.85 308.35 313.15 318.15 323.15 328.15
P/bar 95.48 114.21 27.55 40.65 49.06 62.16 77.78 93.18 107.46
continued
____________________________________________________________________________________
continued
wA 0.264 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.1104 0.170 0.170 0.170 0.170 0.170 0.170 0.170 0.170
wC 0.6256 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680
T/K 332.65 303.35 308.15 313.15 318.15 323.15 328.15 333.15 338.15
P/bar 120.10 17.66 18.62 20.46 21.90 23.37 25.21 27.25 29.05
LLE VLE VLE VLE VLE VLE VLE VLE VLE
wA 0.150 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.170 0.160 0.160 0.160 0.160 0.160 0.160 0.160 0.160
wC 0.680 0.640 0.640 0.640 0.640 0.640 0.640 0.640 0.640
T/K 342.15 302.65 315.75 318.35 323.15 328.15 332.95 337.95 343.05
P/bar 31.06 24.76 28.79 30.01 31.92 34.27 36.41 39.17 41.99
wA 0.223 0.223 0.223 0.223 0.223 0.223 0.223 0.223 0.223
wB 0.1554 0.1554 0.1554 0.1554 0.1554 0.1554 0.1554 0.1554 0.1554
wC 0.6216 0.6216 0.6216 0.6216 0.6216 0.6216 0.6216 0.6216 0.6216
T/K 302.45 303.15 308.15 313.15 318.15 324.15 329.15 333.15 338.15
P/bar 25.74 25.84 27.81 29.98 32.60 35.72 38.54 40.81 43.53
wA 0.223 0.247 0.247 0.247 0.247 0.247 0.247 0.247 0.247
wB 0.1554 0.1506 0.1506 0.1506 0.1506 0.1506 0.1506 0.1506 0.1506
wC 0.6216 0.6024 0.6024 0.6024 0.6024 0.6024 0.6024 0.6024 0.6024
T/K 342.45 301.45 303.15 308.15 313.15 318.15 323.15 325.65 328.15
P/bar 46.19 27.19 27.68 29.87 33.16 35.46 38.05 41.60 50.37
wA 0.247 0.247 0.247 0.264 0.264 0.264 0.264 0.264 0.264
wB 0.1506 0.1506 0.1506 0.1472 0.1472 0.1472 0.1472 0.1472 0.1472
wC 0.6024 0.6024 0.6024 0.5888 0.5888 0.5888 0.5888 0.5888 0.5888
T/K 333.15 338.35 343.05 303.05 308.15 313.35 318.25 323.25 328.15
P/bar 56.41 69.47 82.64 33.45 37.33 57.39 72.56 84.71 100.07
LLE LLE LLE VLE LLE LLE LLE LLE LLE
wA 0.264 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.1472 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125
wC 0.5888 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 333.15 303.15 308.15 313.15 318.15 323.15 328.15 333.15 338.15
P/bar 116.26 18.88 20.13 21.93 23.80 25.77 27.77 29.68 32.34
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wC 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600
T/K 304.45 308.15 313.15 318.15 323.15 328.15 333.25 338.15 342.45
P/bar 26.13 27.08 28.76 31.85 34.01 37.89 40.02 42.75 46.13
continued
____________________________________________________________________________________
continued
wA 0.229 0.229 0.229 0.229 0.229 0.229 0.229 0.229 0.229
wB 0.19275 0.19275 0.19275 0.19275 0.19275 0.19275 0.19275 0.19275 0.19275
wC 0.57825 0.57825 0.57825 0.57825 0.57825 0.57825 0.57825 0.57825 0.57825
T/K 304.75 310.35 318.95 319.95 323.45 326.15 330.75 338.25 343.05
P/bar 29.55 32.47 37.56 37.85 40.05 42.71 54.04 75.06 92.58
wA 0.245 0.245 0.245 0.245 0.245 0.245
wB 0.18875 0.18875 0.18875 0.18875 0.18875 0.18875
wC 0.56625 0.56625 0.56625 0.56625 0.56625 0.56625
T/K 302.75 308.65 313.55 318.45 323.15 328.25
P/bar 33.55 49.77 65.67 80.14 97.02 114.06
LLE LLE LLE LLE LLE LLE
Polymer (B): poly(methyl methacrylate) 2003DOM

Characterization: Mw/kg.mol−1 = 540, synthesized in the laboratory

T/K = 313 P/MPa = 18
wA 0.99999 0.842 0.780 0.617 0.564
wB 0.00001 0.00002 0.00008 0.00020 0.00025
wC 0.000 0.158 0.220 0.383 0.436


T/K = 313 P/MPa = 18
wA 0.99999 0.923 0.870 0.731 0.685
wB 0.00001 0.00001 0.00001 0.00002 0.00001
wC 0.000 0.077 0.130 0.269 0.315
Polymer (B): poly(methyl methacrylate) 1999LO1

Solvent (C): methyl methacrylate C5H8O2 82-62-6

continued
____________________________________________________________________________________
continued
wA 0.846 0.846 0.846 0.846 0.846 0.846 0.660 0.660 0.660
wB 0.050 0.050 0.050 0.050 0.050 0.050 0.051 0.051 0.051
wC 0.104 0.104 0.104 0.104 0.104 0.104 0.289 0.289 0.289
T/K 380.15 389.25 398.45 410.05 423.05 445.55 300.15 319.65 337.95
P/bar 2482.1 2302.8 2163.2 2030.5 1925.3 1801.2 887.3 906.6 919.4
wA 0.660 0.660 0.660 0.660 0.660 0.465 0.465 0.465 0.465
wB 0.051 0.051 0.051 0.051 0.051 0.051 0.051 0.051 0.051
wC 0.289 0.289 0.289 0.289 0.289 0.484 0.484 0.484 0.484
T/K 358.75 378.35 398.15 419.25 443.65 300.15 318.25 332.45 348.85
P/bar 930.8 939.7 948.0 956.3 965.9 108.2 183.4 237.2 290.9
wA 0.465 0.465 0.465 0.465
wB 0.051 0.051 0.051 0.051
wC 0.484 0.484 0.484 0.484
T/K 362.85 377.75 397.75 422.25
P/bar 329.9 367.5 412.3 463.3
Polymer (B): poly(methyl methacrylate) 1994MUR

Type of data: cloud points (a) - visually (b) - from p-V data
wA 0.29 0.29 0.26 0.26
wB 0.11 0.11 0.16 0.16
wC 0.60 0.60 0.58 0.58
T/K 338.15 338.15 343.15 343.15
P/bar 61.63 71.91 53.91 76.81
(a) (b) (a) (b)


wA 0.150 0.150 0.150 0.150 0.150 0.150 0.200 0.200 0.200
wB 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.120 0.120 0.120
wC 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.680 0.680 0.680
T/K 308.25 313.15 318.15 323.15 328.15 333.05 297.45 308.15 313.15
P/bar 11.87 12.97 14.09 15.27 16.49 17.22 13.95 15.22 16.56
continued
____________________________________________________________________________________
continued
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.245 0.250 0.250
wB 0.120 0.120 0.120 0.120 0.120 0.120 0.11325 0.1125 0.1125
wC 0.680 0.680 0.680 0.680 0.680 0.680 0.64175 0.6375 0.6375
T/K 318.15 323.15 328.15 333.15 338.15 342.35 342.65 303.65 318.35
P/bar 18.13 19.87 21.53 23.84 25.31 27.24 36.60 19.77 25.38
VLE VLE VLE VLE VLE VLE LLE VLE VLE
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125
wC 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 323.05 325.65 328.15 331.85 332.45 333.45 334.25 334.55 335.25
P/bar 28.14 29.54 30.63 32.30 32.34 32.70 33.23 33.92 34.87
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.273
wB 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.10905
wC 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.61795
T/K 336.35 337.15 337.55 338.45 340.35 341.15 342.75 342.95 303.45
P/bar 38.02 39.27 40.25 41.89 46.54 49.37 51.94 53.54 21.24
LLE LLE LLE LLE LLE LLE LLE LLE VLE
wA 0.273 0.273 0.273 0.273 0.273 0.273 0.273 0.273 0.273
wB 0.10905 0.10905 0.10905 0.10905 0.10905 0.10905 0.10905 0.10905 0.10905
wC 0.61795 0.61795 0.61795 0.61795 0.61795 0.61795 0.61795 0.61795 0.61795
T/K 308.15 313.15 317.65 317.95 318.15 318.45 319.15 320.05 320.55
P/bar 22.85 25.18 29.25 31.29 31.42 31.88 33.03 35.81 36.11
VLE VLE VLE VLE VLE LLE LLE LLE LLE
wA 0.273 0.273 0.273 0.273 0.273 0.273 0.273 0.273 0.273
wB 0.10905 0.10905 0.10905 0.10905 0.10905 0.10905 0.10905 0.10905 0.10905
wC 0.61795 0.61795 0.61795 0.61795 0.61795 0.61795 0.61795 0.61795 0.61795
T/K 320.95 321.35 322.45 324.15 325.15 326.15 327.15 328.15 330.75
P/bar 36.84 38.80 40.78 44.75 48.85 50.13 53.06 56.30 61.63
wA 0.273 0.273 0.303 0.303 0.303 0.303 0.303 0.303 0.303
wB 0.10905 0.10905 0.10455 0.10455 0.10455 0.10455 0.10455 0.10455 0.10455
wC 0.61795 0.61795 0.59245 0.59245 0.59245 0.59245 0.59245 0.59245 0.59245
T/K 332.95 333.75 298.85 299.05 299.15 299.25 300.15 301.55 302.35
P/bar 67.63 70.75 41.73 43.07 43.57 43.39 44.00 49.74 49.48
wA 0.303 0.303 0.303 0.303 0.303 0.303 0.303 0.303 0.303
wB 0.10455 0.10455 0.10455 0.10455 0.10455 0.10455 0.10455 0.10455 0.10455
wC 0.59245 0.59245 0.59245 0.59245 0.59245 0.59245 0.59245 0.59245 0.59245
T/K 303.85 305.55 306.15 307.35 308.75 309.15 310.25 315.85 317.85
P/bar 53.59 56.86 57.94 59.52 62.94 64.09 66.75 79.01 83.50
continued
____________________________________________________________________________________
continued
wA 0.303 0.303 0.303 0.303 0.303 0.303 0.303 0.303 0.303
wB 0.10455 0.10455 0.10455 0.10455 0.10455 0.10455 0.10455 0.10455 0.10455
wC 0.59245 0.59245 0.59245 0.59245 0.59245 0.59245 0.59245 0.59245 0.59245
T/K 320.45 321.05 322.25 323.15 323.85 324.65 326.85 329.15 330.85
P/bar 88.25 89.99 93.64 95.08 96.89 98.73 103.06 108.64 114.85
wA 0.303 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.10455 0.170 0.170 0.170 0.170 0.170 0.170 0.170 0.170
wC 0.59245 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680
T/K 331.45 305.85 308.15 313.15 318.15 323.55 328.45 333.15 338.15
P/bar 115.70 14.38 14.61 15.40 16.93 18.51 20.15 21.88 23.66
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.250 0.250 0.250
wB 0.160 0.160 0.160 0.160 0.160 0.160 0.150 0.150 0.150
wC 0.640 0.640 0.640 0.640 0.640 0.640 0.600 0.600 0.600
T/K 318.15 323.15 327.55 333.15 338.15 343.15 307.15 312.85 315.45
P/bar 23.15 25.21 27.18 28.90 31.38 33.88 25.90 27.06 28.27
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600
T/K 315.85 316.95 317.65 318.75 319.85 320.05 320.85 321.15 321.55
P/bar 28.33 29.35 29.84 30.83 31.49 32.37 33.65 33.23 34.27
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600
T/K 321.95 322.45 322.85 323.25 323.65 324.75 325.35 326.45 327.85
P/bar 35.26 36.11 36.80 38.11 39.69 41.01 43.44 46.13 49.15
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600
T/K 328.15 329.35 330.25 330.95 332.05 332.95 335.25 336.15 336.75
P/bar 49.41 53.45 55.65 56.93 60.41 61.56 68.49 71.05 72.59
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600
T/K 337.65 337.95 338.75 339.05 339.55 340.05 340.15 340.35 340.75
P/bar 75.48 76.46 78.66 78.83 79.91 81.55 82.57 83.30 83.65
continued
____________________________________________________________________________________
continued
wA 0.250 0.250 0.250 0.250 0.250 0.268 0.268 0.268 0.268
wB 0.150 0.150 0.150 0.150 0.150 0.1464 0.1464 0.1464 0.1464
wC 0.600 0.600 0.600 0.600 0.600 0.5856 0.5856 0.5856 0.5856
T/K 341.45 341.65 342.25 342.65 342.85 307.65 311.95 312.35 312.65
P/bar 87.20 86.84 89.30 88.98 89.40 35.39 40.71 43.86 44.78
wA 0.268 0.268 0.268 0.268 0.268 0.268 0.268 0.268 0.268
wB 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464
wC 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856
T/K 315.85 316.25 316.45 316.65 316.95 317.25 317.55 320.45 320.75
P/bar 50.99 54.47 54.17 55.68 55.88 56.11 57.49 64.48 64.61
wA 0.268 0.268 0.268 0.268 0.268 0.268 0.268 0.268 0.268
wB 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464
wC 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856
T/K 320.95 321.25 324.25 324.45 324.75 325.05 328.75 328.95 329.15
P/bar 65.17 66.16 73.28 73.57 74.33 74.95 84.38 85.66 86.38
wA 0.268 0.268 0.268 0.268 0.268 0.268 0.268 0.268 0.268
wB 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464 0.1464
wC 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856 0.5856
T/K 329.85 330.15 333.85 334.05 334.55 334.65 334.85 335.65 336.15
P/bar 87.49 89.20 98.20 98.93 100.76 100.04 101.88 102.17 102.86
wA 0.268 0.268 0.268 0.268 0.268 0.283 0.283 0.283 0.283
wB 0.1464 0.1464 0.1464 0.1464 0.1464 0.1434 0.1434 0.1434 0.1434
wC 0.5856 0.5856 0.5856 0.5856 0.5856 0.5736 0.5736 0.5736 0.5736
T/K 336.25 336.45 336.55 336.75 337.85 311.75 311.95 312.05 312.35
P/bar 104.01 104.15 104.83 106.34 108.41 68.65 69.08 70.62 70.72
wA 0.283 0.283 0.283 0.283 0.283 0.283 0.283 0.283 0.283
wB 0.1434 0.1434 0.1434 0.1434 0.1434 0.1434 0.1434 0.1434 0.1434
wC 0.5736 0.5736 0.5736 0.5736 0.5736 0.5736 0.5736 0.5736 0.5736
T/K 314.65 314.95 318.25 318.55 318.65 318.95 321.85 322.15 322.35
P/bar 74.63 75.38 83.30 85.03 85.07 85.83 91.67 93.27 93.62
wA 0.283 0.283 0.283 0.283 0.283 0.283 0.283 0.283 0.283
wB 0.1434 0.1434 0.1434 0.1434 0.1434 0.1434 0.1434 0.1434 0.1434
wC 0.5736 0.5736 0.5736 0.5736 0.5736 0.5736 0.5736 0.5736 0.5736
T/K 322.55 322.75 322.95 323.25 326.05 326.45 326.55 329.45 329.95
P/bar 93.67 94.42 95.44 95.84 103.08 103.68 104.48 111.99 112.32
continued
____________________________________________________________________________________
continued
wA 0.283 0.283 0.283 0.283 0.150 0.150 0.150 0.150 0.150
wB 0.1434 0.1434 0.1434 0.1434 0.2125 0.2125 0.2125 0.2125 0.2125
wC 0.5736 0.5736 0.5736 0.5736 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 330.15 330.65 331.05 331.35 324.95 328.35 333.35 338.15 343.15
P/bar 113.47 114.75 115.18 115.60 23.72 24.83 27.31 29.38 31.72
LLE LLE LLE LLE VLE VLE VLE VLE VLE
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wC 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600
T/K 300.75 303.15 308.15 313.15 318.15 323.65 329.75 333.15 338.15
P/bar 19.72 20.04 21.48 23.59 25.67 28.08 31.22 32.63 35.68
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wC 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600
T/K 342.15 342.45 342.55 342.65 342.75 342.85 342.95 343.05 343.15
P/bar 38.94 41.77 41.27 43.17 42.91 43.50 44.92 44.42 44.49
wA 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222
wB 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945
wC 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835
T/K 312.05 318.15 323.15 324.75 326.15 327.75 328.85 329.45 329.65
P/bar 25.75 27.59 29.47 31.52 32.21 33.09 37.69 39.57 39.46
wA 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222
wB 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945
wC 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835
T/K 329.85 330.65 330.85 331.05 331.35 331.85 332.15 332.45 332.65
P/bar 40.61 42.26 41.37 44.06 43.51 44.36 44.88 46.73 47.42
wA 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222
wB 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945
wC 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835
T/K 332.85 333.95 334.35 334.55 334.75 334.85 334.95 334.95 335.25
P/bar 47.18 49.15 51.22 51.06 48.37 52.47 49.12 52.27 49.94
wA 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222
wB 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945
wC 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835
T/K 335.25 335.45 335.45 335.75 335.85 335.95 336.15 336.35 336.45
P/bar 52.59 50.17 53.68 53.54 51.95 54.83 52.17 54.74 52.47
continued
____________________________________________________________________________________
continued
wA 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222
wB 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945
wC 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835
T/K 336.75 336.95 337.05 337.15 337.35 337.45 337.55 337.65 337.75
P/bar 56.05 56.74 54.41 54.54 55.19 55.30 57.89 55.49 55.26
wA 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222
wB 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945
wC 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835
T/K 337.95 338.45 339.25 339.45 339.55 339.65 339.75 339.85 340.05
P/bar 59.20 61.23 60.71 61.23 63.30 61.20 61.52 62.45 62.74
wA 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222
wB 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945 0.1945
wC 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835 0.5835
T/K 340.15 341.35 341.45 341.65 341.85 342.05 342.35 342.45 343.05
P/bar 64.55 66.69 67.67 67.60 68.49 68.53 72.95 73.99 70.91
wA 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241
wB 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975
wC 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925
T/K 297.45 303.15 308.15 309.05 310.45 311.05 311.65 311.95 312.25
P/bar 21.80 24.00 26.39 27.09 27.61 26.99 30.07 29.68 32.18
wA 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241
wB 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975
wC 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925
T/K 312.55 312.85 313.25 314.55 314.85 315.75 316.05 316.35 316.65
P/bar 33.78 33.95 35.16 39.14 39.67 42.09 43.90 43.64 44.68
wA 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241
wB 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975
wC 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925
T/K 317.55 317.75 318.05 318.25 318.55 318.85 319.15 319.45 320.25
P/bar 46.00 47.48 48.79 50.07 49.44 50.40 51.81 51.85 52.47
wA 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241
wB 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975
wC 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925
T/K 320.45 320.95 321.15 323.15 323.65 324.05 324.45 324.75 325.25
P/bar 52.77 54.90 54.80 58.58 62.85 64.11 64.51 64.55 65.90
continued
____________________________________________________________________________________
continued
wA 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241
wB 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975
wC 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925
T/K 326.65 327.95 329.05 329.35 329.85 330.55 331.05 331.25 331.55
P/bar 68.29 72.50 75.10 76.01 77.26 78.47 80.90 80.34 82.21
wA 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241
wB 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975
wC 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925
T/K 331.65 332.65 332.95 333.35 333.35 333.55 333.65 333.65 334.25
P/bar 82.41 82.94 83.92 77.22 84.32 77.85 78.34 85.86 87.72
wA 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241
wB 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975
wC 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925
T/K 335.55 336.35 336.45 336.55 337.25 337.35 337.45 338.15 338.25
P/bar 82.58 91.67 91.90 92.72 94.32 95.55 96.24 90.19 98.50
wA 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241 0.241
wB 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975 0.18975
wC 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925 0.56925
T/K 338.45 339.15 339.25 340.45 340.85 341.75 342.35 342.85 343.35
P/bar 99.42 93.48 93.35 96.99 97.35 100.52 101.98 102.91 103.85
wA 0.241 0.241 0.241
wB 0.18975 0.18975 0.18975
wC 0.56925 0.56925 0.56925
T/K 343.45 343.55 343.65
P/bar 104.08 104.70 104.43
LLE LLE LLE


T/K = 313 P/MPa = 18
wA 0.99999 0.930 0.855 0.734 0.682
wB 0.00001 0.00016 0.00022 0.00007 0.00003
wC 0.000 0.070 0.145 0.266 0.318
____________________________________________________________________________________
Polymer (B): poly(methyl methacrylate) 1992KIA, 1994KIA

wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275
wC 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225
T/K 304.35 308.15 313.15 318.15 323.25 328.15 333.15 338.35 341.65
P/bar 16.07 17.20 18.44 19.68 22.30 23.73 25.64 27.71 29.60
wA 0.150 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.250
wB 0.1275 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.1125
wC 0.7225 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.6375
T/K 342.65 315.45 319.55 325.55 328.25 333.45 337.55 342.95 306.45
P/bar 29.98 25.21 27.40 30.07 31.84 34.14 36.47 39.10 25.45
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.300 0.300 0.300
wB 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.105 0.105 0.105
wC 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.595 0.595 0.595
T/K 313.15 319.55 324.75 328.15 333.35 337.15 301.35 316.25 320.95
P/bar 27.72 31.17 33.65 36.12 39.02 41.27 26.17 34.76 37.82
wA 0.300 0.300 0.300 0.300 0.323 0.323 0.323 0.323 0.323
wB 0.105 0.105 0.105 0.105 0.10155 0.10155 0.10155 0.10155 0.10155
wC 0.595 0.595 0.595 0.595 0.57545 0.57545 0.57545 0.57545 0.57545
T/K 327.75 332.75 337.85 342.75 300.25 303.15 313.15 318.15 323.15
P/bar 41.67 44.53 48.08 51.77 27.32 28.40 34.87 37.31 41.47
wA 0.323 0.323 0.323 0.323 0.323 0.323 0.323 0.323 0.323
wB 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155
wC 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545
T/K 325.75 326.35 326.75 327.05 328.55 328.95 329.35 329.75 330.45
P/bar 43.61 44.42 45.44 45.57 46.53 47.04 52.40 53.09 55.49
wA 0.323 0.323 0.323 0.323 0.323 0.323 0.323 0.323 0.323
wB 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155
wC 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545
T/K 330.85 331.25 331.85 332.35 332.95 333.95 334.35 334.85 336.95
P/bar 53.29 55.19 57.69 58.44 60.35 65.18 65.83 65.83 72.73
wA 0.323 0.323 0.323 0.323 0.323 0.323 0.323 0.323 0.323
wB 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155 0.10155
wC 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545 0.57545
T/K 337.35 337.75 338.45 338.65 339.05 339.25 341.15 341.45 341.55
P/bar 73.51 73.94 81.72 78.11 84.01 77.61 89.07 87.17 89.50
continued
____________________________________________________________________________________
continued
wA 0.323 0.323 0.323 0.337 0.337 0.337 0.337 0.337 0.337
wB 0.10155 0.10155 0.10155 0.09945 0.09945 0.09945 0.09945 0.09945 0.09945
wC 0.57545 0.57545 0.57545 0.56355 0.56355 0.56355 0.56355 0.56355 0.56355
T/K 341.65 342.55 342.65 296.85 297.25 303.15 308.15 313.15 318.15
P/bar 89.50 95.53 91.98 28.76 35.96 45.57 54.97 72.10 85.66
wA 0.337 0.337 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.09945 0.09945 0.160 0.160 0.160 0.160 0.160 0.160 0.160
wC 0.56355 0.56355 0.640 0.640 0.640 0.640 0.640 0.640 0.640
T/K 322.95 327.85 303.95 308.15 313.25 318.15 325.25 328.15 342.75
P/bar 98.40 110.32 18.12 19.27 21.20 22.62 25.12 26.63 32.73
LLE LLE VLE VLE VLE VLE VLE VLE VLE
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.300 0.300
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.140 0.140
wC 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.560 0.560
T/K 303.35 318.95 323.15 328.15 333.15 338.15 340.15 303.75 308.15
P/bar 23.50 30.17 32.54 35.07 37.76 40.91 42.45 28.79 30.23
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.317 0.317
wB 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.1366 0.1366
wC 0.560 0.560 0.560 0.560 0.560 0.560 0.560 0.5464 0.5464
T/K 313.15 318.45 325.55 328.15 333.15 338.45 343.15 298.65 315.05
P/bar 33.03 35.85 40.12 42.09 46.09 49.48 53.10 28.07 35.95
wA 0.317 0.317 0.317 0.317 0.317 0.317 0.330 0.330 0.330
wB 0.1366 0.1366 0.1366 0.1366 0.1366 0.1366 0.134 0.134 0.134
wC 0.5464 0.5464 0.5464 0.5464 0.5464 0.5464 0.536 0.536 0.536
T/K 318.45 323.25 326.55 333.15 336.65 343.15 303.15 313.15 318.15
P/bar 37.53 40.74 42.79 62.58 73.90 92.56 38.84 62.63 77.52
VLE VLE VLE LLE LLE LLE LLE LLE LLE
wA 0.330 0.330 0.330 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.134 0.134 0.134 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125
wC 0.536 0.536 0.536 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 323.15 328.15 333.15 313.15 318.15 323.15 328.15 333.15 338.15
P/bar 93.80 105.12 118.22 18.95 20.85 22.46 24.68 25.77 27.35
LLE LLE LLE VLE VLE VLE VLE VLE VLE
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wC 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600
T/K 297.75 310.05 313.75 318.15 328.45 332.75 338.15 342.85 343.05
P/bar 26.79 26.92 28.92 30.96 38.51 39.76 43.31 45.54 46.03
continued
____________________________________________________________________________________
continued
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.1875 0.1875 0.1875 0.1875 0.1875 0.1875 0.1875 0.1875 0.1875
wC 0.5625 0.5625 0.5625 0.5625 0.5625 0.5625 0.5625 0.5625 0.5625
T/K 303.15 308.15 313.15 318.15 323.15 330.65 333.15 338.15 343.15
P/bar 28.73 31.58 34.64 37.56 40.55 64.06 74.00 84.12 101.15
wA 0.271 0.271 0.271 0.271 0.271 0.271 0.271 0.271 0.291
wB 0.18225 0.18225 0.18225 0.18225 0.18225 0.18225 0.18225 0.18225 0.17725
wC 0.54675 0.54675 0.54675 0.54675 0.54675 0.54675 0.54675 0.54675 0.53175
T/K 297.85 303.45 308.25 313.25 318.15 323.25 328.25 333.15 300.85
P/bar 27.35 33.56 44.95 58.51 71.35 84.28 95.48 107.63 68.59
VLE LLE LLE LLE LLE LLE LLE LLE LLE
wA 0.291 0.291 0.291
wB 0.17725 0.17725 0.17725
wC 0.53175 0.53175 0.53175
T/K 308.25 313.15 318.15
P/bar 90.62 107.69 119.97
LLE LLE LLE
Polymer (B): poly(methyl methacrylate) 1994MUR

wA 0.33 0.33
wB 0.15 0.15
wC 0.52 0.52
T/K 318.15 318.15
P/bar 82.94 92.26
(a) (b)
Polymer (B): poly(methyl methacrylate) 1992KIA, 1994KIA


wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275
wC 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225
T/K 303.35 304.25 308.15 313.15 318.15 323.15 328.15 333.15 338.15
P/bar 24.79 25.32 26.66 28.33 30.30 32.50 33.94 36.22 37.96
continued
____________________________________________________________________________________
continued
wA 0.200 0.200 0.200 0.250 0.250 0.250 0.250 0.300 0.300
wB 0.120 0.120 0.120 0.1125 0.1125 0.1125 0.1125 0.105 0.105
wC 0.680 0.680 0.680 0.6375 0.6375 0.6375 0.6375 0.595 0.595
T/K 333.15 338.15 343.15 330.35 334.35 338.55 344.35 303.95 308.15
P/bar 48.35 51.66 54.84 52.64 56.89 59.92 63.76 39.20 41.61
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.358 0.358
wB 0.105 0.105 0.105 0.105 0.105 0.105 0.105 0.0963 0.0963
wC 0.595 0.595 0.595 0.595 0.595 0.595 0.595 0.5457 0.5457
T/K 313.95 318.15 323.15 328.15 333.15 339.05 343.15 307.15 308.15
P/bar 45.91 48.61 53.06 56.96 59.79 64.88 69.11 43.84 44.52
wA 0.358 0.358 0.358 0.358 0.358 0.358 0.358 0.358 0.358
wB 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963
wC 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457
T/K 313.15 318.15 320.65 321.15 322.15 323.15 323.95 324.95 326.55
P/bar 48.62 53.08 54.05 55.69 56.34 57.72 58.79 59.54 62.06
wA 0.358 0.358 0.358 0.358 0.358 0.358 0.358 0.358 0.358
wB 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963
wC 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457
T/K 326.85 327.25 327.65 328.75 326.75 327.75 327.95 328.15 328.45
P/bar 60.01 62.89 62.71 61.63 67.09 75.25 75.37 76.81 78.48
wA 0.358 0.358 0.358 0.358 0.358 0.358 0.358 0.358 0.358
wB 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963
wC 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457
T/K 328.95 329.55 329.85 330.05 330.75 331.25 331.45 331.95 332.05
P/bar 81.59 82.19 82.28 82.15 84.98 88.52 91.55 90.53 93.56
wA 0.358 0.358 0.358 0.358 0.358 0.358 0.374 0.374 0.374
wB 0.0963 0.0963 0.0963 0.0963 0.0963 0.0963 0.0939 0.0939 0.0939
wC 0.5457 0.5457 0.5457 0.5457 0.5457 0.5457 0.5321 0.5321 0.5321
T/K 332.55 333.55 333.85 333.95 337.45 337.65 301.55 304.25 308.15
P/bar 92.51 94.02 96.11 97.57 104.96 107.50 43.15 44.72 47.84
wA 0.374 0.374 0.374 0.374 0.374 0.374 0.374 0.374 0.374
wB 0.0939 0.0939 0.0939 0.0939 0.0939 0.0939 0.0939 0.0939 0.0939
wC 0.5321 0.5321 0.5321 0.5321 0.5321 0.5321 0.5321 0.5321 0.5321
T/K 313.15 314.45 315.85 317.05 317.95 320.05 321.95 324.55 325.35
P/bar 50.89 53.17 54.97 55.49 56.83 58.56 65.11 77.61 80.56
continued
____________________________________________________________________________________
continued
wA 0.374 0.374 0.399 0.399 0.399 0.399 0.399 0.399 0.399
wB 0.0939 0.0939 0.09015 0.09015 0.09015 0.09015 0.09015 0.09015 0.09015
wC 0.5321 0.5321 0.51085 0.51085 0.51085 0.51085 0.51085 0.51085 0.51085
T/K 327.95 328.45 298.55 303.15 307.95 309.75 312.35 312.65 313.25
P/bar 94.68 96.41 42.14 45.37 50.43 51.24 57.07 65.30 67.04
LLE LLE VLE VLE VLE VLE LLE LLE LLE
wA 0.399 0.399 0.399 0.413 0.413 0.413 0.413 0.413 0.413
wB 0.09015 0.09015 0.09015 0.08805 0.08805 0.08805 0.08805 0.08805 0.08805
wC 0.51085 0.51085 0.51085 0.49895 0.49895 0.49895 0.49895 0.49895 0.49895
T/K 316.25 316.65 322.65 301.25 303.15 305.85 306.25 307.45 307.85
P/bar 81.64 84.97 103.92 43.67 44.82 48.26 48.15 49.64 52.67
wA 0.413 0.413 0.413 0.413 0.216 0.216 0.216 0.216 0.216
wB 0.08805 0.08805 0.08805 0.08805 0.1568 0.1568 0.1568 0.1568 0.1568
wC 0.49895 0.49895 0.49895 0.49895 0.6272 0.6272 0.6272 0.6272 0.6272
T/K 308.05 309.45 310.25 310.45 298.65 303.15 308.15 313.15 318.15
P/bar 54.67 59.66 63.22 65.19 33.87 34.88 37.41 41.24 43.35
wA 0.216 0.216 0.216 0.216 0.216 0.250 0.250 0.250 0.250
wB 0.1568 0.1568 0.1568 0.1568 0.1568 0.150 0.150 0.150 0.150
wC 0.6272 0.6272 0.6272 0.6272 0.6272 0.600 0.600 0.600 0.600
T/K 323.15 328.45 336.45 338.15 343.15 323.15 328.15 333.15 337.65
P/bar 47.31 50.37 56.60 57.42 61.24 52.25 55.97 59.23 62.49
wA 0.250 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.150 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.140
wC 0.600 0.560 0.560 0.560 0.560 0.560 0.560 0.560 0.560
T/K 342.75 297.15 303.15 303.45 308.15 313.15 318.15 323.15 328.15
P/bar 65.67 38.98 41.63 42.32 46.02 49.71 53.65 58.12 61.22
VLE VLE VLE LLE LLE LLE LLE VLE VLE
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.140
wC 0.560 0.560 0.560 0.560 0.560 0.560 0.560 0.560 0.560
T/K 328.65 333.15 336.55 336.75 337.05 338.05 338.25 338.45 339.25
P/bar 62.61 67.73 69.02 70.40 71.08 71.22 72.68 73.28 73.08
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.140
wC 0.560 0.560 0.560 0.560 0.560 0.560 0.560 0.560 0.560
T/K 341.05 341.85 342.15 342.35 336.55 336.65 336.95 337.05 337.65
P/bar 75.41 76.19 75.29 75.65 69.44 72.71 73.99 74.26 75.85
continued
____________________________________________________________________________________
continued
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.140
wC 0.560 0.560 0.560 0.560 0.560 0.560 0.560 0.560 0.560
T/K 338.15 338.25 338.45 338.95 339.05 339.35 339.95 340.15 341.35
P/bar 79.85 81.81 81.94 86.46 86.60 89.56 89.98 91.63 93.66
wA 0.300 0.300 0.300 0.300 0.316 0.316 0.316 0.316 0.316
wB 0.140 0.140 0.140 0.140 0.1368 0.1368 0.1368 0.1368 0.1368
wC 0.560 0.560 0.560 0.560 0.5472 0.5472 0.5472 0.5472 0.5472
T/K 342.15 342.25 342.35 342.55 297.45 323.75 324.75 324.95 329.25
P/bar 100.39 98.13 98.73 101.66 40.12 60.07 60.09 60.37 63.80
wA 0.316 0.316 0.316 0.316 0.316 0.316 0.316 0.316 0.316
wB 0.1368 0.1368 0.1368 0.1368 0.1368 0.1368 0.1368 0.1368 0.1368
wC 0.5472 0.5472 0.5472 0.5472 0.5472 0.5472 0.5472 0.5472 0.5472
T/K 329.45 331.85 332.25 333.75 333.95 334.15 334.35 336.25 338.15
P/bar 64.55 64.98 68.60 74.66 75.29 75.15 76.22 82.61 90.36
wA 0.316 0.316 0.333 0.333 0.333 0.333 0.333 0.333 0.333
wB 0.1368 0.1368 0.1333 0.1333 0.1333 0.1333 0.1333 0.1333 0.1333
wC 0.5472 0.5472 0.5333 0.5333 0.5333 0.5333 0.5333 0.5333 0.5333
T/K 341.65 342.65 297.35 303.15 308.15 313.15 316.95 317.15 317.35
P/bar 104.70 107.68 40.84 44.52 48.43 53.06 55.98 56.18 56.63
LLE LLE VLE VLE VLE VLE VLE VLE VLE
wA 0.333 0.333 0.333 0.333 0.333 0.333 0.333 0.333 0.333
wB 0.1333 0.1333 0.1333 0.1333 0.1333 0.1333 0.1333 0.1333 0.1333
wC 0.5333 0.5333 0.5333 0.5333 0.5333 0.5333 0.5333 0.5333 0.5333
T/K 319.55 320.55 319.15 319.45 319.55 319.75 320.35 320.65 320.85
P/bar 59.78 58.34 67.87 74.70 74.04 70.40 71.54 76.66 79.81
VLE VLE LLE LLE LLE LLE LLE LLE LLE
wA 0.333 0.333 0.333 0.333 0.333 0.333 0.333 0.333 0.333
wB 0.1333 0.1333 0.1333 0.1333 0.1333 0.1333 0.1333 0.1333 0.1333
wC 0.5333 0.5333 0.5333 0.5333 0.5333 0.5333 0.5333 0.5333 0.5333
T/K 321.05 321.35 321.45 321.55 322.25 323.35 323.65 323.95 324.35
P/bar 73.64 78.17 80.37 82.21 84.50 92.98 92.56 94.40 99.88
wA 0.333 0.333 0.333 0.333 0.349 0.349 0.349 0.349 0.349
wB 0.1333 0.1333 0.1333 0.1333 0.1302 0.1302 0.1302 0.1302 0.1302
wC 0.5333 0.5333 0.5333 0.5333 0.5208 0.5208 0.5208 0.5208 0.5208
T/K 324.45 324.65 324.85 325.05 310.05 312.85 314.35 315.05 315.25
P/bar 96.25 95.11 96.40 101.02 50.07 54.07 53.91 55.29 56.11
continued
____________________________________________________________________________________
continued
wA 0.349 0.349 0.349 0.349 0.349 0.349 0.349 0.363 0.363
wB 0.1302 0.1302 0.1302 0.1302 0.1302 0.1302 0.1302 0.1274 0.1274
wC 0.5208 0.5208 0.5208 0.5208 0.5208 0.5208 0.5208 0.5096 0.5096
T/K 315.95 317.15 317.45 320.95 321.05 322.45 322.55 301.75 301.95
P/bar 57.30 62.05 64.65 78.28 77.12 85.20 85.56 44.55 44.97
VLE VLE VLE LLE LLE LLE LLE VLE VLE
wA 0.363 0.363 0.363 0.363 0.363 0.363 0.363 0.363 0.363
wB 0.1274 0.1274 0.1274 0.1274 0.1274 0.1274 0.1274 0.1274 0.1274
wC 0.5096 0.5096 0.5096 0.5096 0.5096 0.5096 0.5096 0.5096 0.5096
T/K 304.45 304.95 305.65 307.05 307.35 307.45 307.55 307.85 308.35
P/bar 46.04 46.82 48.03 48.00 49.54 55.54 49.77 53.14 56.84
wA 0.363 0.363 0.363 0.363 0.363 0.363 0.363 0.363 0.363
wB 0.1274 0.1274 0.1274 0.1274 0.1274 0.1274 0.1274 0.1274 0.1274
wC 0.5096 0.5096 0.5096 0.5096 0.5096 0.5096 0.5096 0.5096 0.5096
T/K 309.65 311.85 312.15 312.55 312.65 312.85 313.25 313.95 314.85
P/bar 58.84 74.53 74.65 81.01 80.24 80.67 84.34 85.53 90.03
VLE LLE LLE LLE LLE LLE LLE LLE LLE
wA 0.363 0.363 0.385 0.385 0.385 0.385 0.385 0.200 0.200
wB 0.1274 0.1274 0.123 0.123 0.123 0.123 0.123 0.2664 0.2664
wC 0.5096 0.5096 0.492 0.492 0.492 0.492 0.492 0.5336 0.5336
T/K 315.75 315.95 306.75 307.45 307.35 307.75 308.25 316.45 316.95
P/bar 93.91 95.28 67.67 72.66 71.77 72.92 75.57 38.41 38.51
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.2664 0.2664 0.2664 0.2664 0.2664 0.2664 0.2664 0.2664 0.2664
wC 0.5336 0.5336 0.5336 0.5336 0.5336 0.5336 0.5336 0.5336 0.5336
T/K 317.05 321.05 322.25 322.55 324.75 328.85 329.15 329.65 332.95
P/bar 40.09 39.16 40.48 40.37 41.76 43.72 44.62 45.25 46.58
wA 0.200 0.200 0.242 0.242 0.300 0.300 0.300 0.300 0.300
wB 0.2664 0.2664 0.2524 0.2524 0.2331 0.2331 0.2331 0.2331 0.2331
wC 0.5336 0.5336 0.5056 0.5056 0.4669 0.4669 0.4669 0.4669 0.4669
T/K 342.75 343.15 342.75 342.85 312.95 314.45 314.75 314.85 316.05
P/bar 53.72 55.12 63.81 64.51 49.72 50.27 50.17 50.62 50.86
VLE VLE LLE LLE VLE VLE VLE VLE VLE
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331
wC 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669
T/K 316.15 316.65 317.55 317.75 317.95 318.95 319.85 320.25 318.35
P/bar 50.86 50.92 51.81 51.51 51.90 52.99 54.17 53.97 54.86
continued
____________________________________________________________________________________
continued
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331
wC 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669
T/K 322.75 323.55 325.35 326.45 327.95 330.35 333.05 333.45 333.85
P/bar 56.04 56.24 57.98 59.03 59.49 62.71 64.27 64.50 64.84
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331 0.2331
wC 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669 0.4669
T/K 334.35 335.95 336.45 337.25 337.75 338.15 338.65 339.05 339.65
P/bar 65.79 66.61 67.67 70.35 76.63 74.59 81.52 75.84 82.87
wA 0.300 0.300 0.300 0.313 0.313 0.313 0.313 0.313
wB 0.2331 0.2331 0.2331 0.2288 0.2288 0.2288 0.2288 0.2288
wC 0.4669 0.4669 0.4669 0.4582 0.4582 0.4582 0.4582 0.4582
T/K 339.95 340.75 341.55 301.55 305.35 307.95 312.55 313.35
P/bar 81.06 90.22 92.71 44.74 46.42 48.79 58.69 74.43
LLE LLE LLE VLE VLE VLE LLE LLE


wA 0.100 0.100 0.100 0.100 0.100 0.200 0.200 0.200 0.200
wB 0.1503 0.1503 0.1503 0.1503 0.1503 0.1336 0.1336 0.1336 0.1336
wC 0.7497 0.7497 0.7497 0.7497 0.7497 0.6664 0.6664 0.6664 0.6664
T/K 308.15 313.15 323.15 333.15 343.15 313.15 323.15 333.15 343.15
P/bar 22.48 24.10 27.45 30.11 33.92 37.82 44.24 51.51 58.01
wA 0.274 0.274 0.274 0.274 0.274 0.323 0.323 0.323 0.323
wB 0.1212 0.1212 0.1212 0.1212 0.1212 0.1131 0.1131 0.1131 0.1131
wC 0.6048 0.6048 0.6048 0.6048 0.6048 0.5639 0.5639 0.5639 0.5639
T/K 309.45 313.15 323.15 333.15 343.15 313.15 323.15 328.15 329.15
P/bar 41.89 45.00 51.84 60.32 69.08 48.00 56.37 60.94 61.14
wA 0.323 0.323 0.323 0.323 0.201 0.201 0.201 0.201 0.201
wB 0.1131 0.1131 0.1131 0.1131 0.1598 0.1598 0.1598 0.1598 0.1598
wC 0.5639 0.5639 0.5639 0.5639 0.6392 0.6392 0.6392 0.6392 0.6392
T/K 330.65 331.15 333.15 343.15 307.65 313.45 323.15 328.25 333.15
P/bar 63.63 64.32 66.98 103.68 35.48 39.62 46.16 49.84 53.19
continued
____________________________________________________________________________________
continued
wA 0.201 0.201 0.280 0.280 0.280 0.280 0.280 0.280 0.280
wB 0.1598 0.1598 0.144 0.144 0.144 0.144 0.144 0.144 0.144
wC 0.6392 0.6392 0.576 0.576 0.576 0.576 0.576 0.576 0.576
T/K 339.95 343.15 314.65 318.55 323.25 328.65 332.25 338.55 343.15
P/bar 57.03 60.67 47.70 50.66 54.10 59.52 63.04 68.26 73.50
wA 0.341 0.341 0.341 0.341 0.341 0.341 0.341 0.341 0.341
wB 0.1318 0.1318 0.1318 0.1318 0.1318 0.1318 0.1318 0.1318 0.1318
wC 0.5272 0.5272 0.5272 0.5272 0.5272 0.5272 0.5272 0.5272 0.5272
T/K 296.55 299.65 301.15 302.15 303.45 304.05 304.45 308.65 309.65
P/bar 37.00 39.23 40.78 41.47 41.82 42.22 43.53 51.41 56.93
wA 0.341 0.341 0.341 0.350 0.350 0.350 0.350 0.350 0.350
wB 0.1318 0.1318 0.1318 0.130 0.130 0.130 0.130 0.130 0.130
wC 0.5272 0.5272 0.5272 0.520 0.520 0.520 0.520 0.520 0.520
T/K 313.15 318.15 323.15 295.85 296.25 296.45 296.85 297.45 298.05
P/bar 69.27 89.70 111.10 37.09 37.28 37.62 38.45 39.09 39.53
wA 0.350 0.350 0.350 0.350 0.350 0.350 0.362 0.362 0.362
wB 0.130 0.130 0.130 0.130 0.130 0.130 0.1276 0.1276 0.1276
wC 0.520 0.520 0.520 0.520 0.520 0.520 0.5104 0.5104 0.5104
T/K 299.15 300.05 304.65 308.45 313.15 318.15 302.25 304.45 305.35
P/bar 43.76 48.85 67.60 84.01 99.84 121.42 86.54 101.03 100.20
wA 0.362 0.362 0.362 0.362 0.362 0.362 0.154 0.154 0.154
wB 0.1276 0.1276 0.1276 0.1276 0.1276 0.1276 0.2115 0.2115 0.2115
wC 0.5104 0.5104 0.5104 0.5104 0.5104 0.5104 0.6345 0.6345 0.6345
T/K 306.25 308.45 309.85 310.55 316.25 318.35 313.45 318.75 322.15
P/bar 102.75 109.37 121.91 119.41 140.20 150.31 30.47 32.82 34.80
wA 0.154 0.154 0.238 0.238 0.238 0.238 0.238 0.238 0.307
wB 0.2115 0.2115 0.1905 0.1905 0.1905 0.1905 0.1905 0.1905 0.17325
wC 0.6345 0.6345 0.5715 0.5715 0.5715 0.5715 0.5715 0.5715 0.51975
T/K 333.15 343.15 308.15 313.15 323.15 333.15 338.15 343.15 312.95
P/bar 40.91 45.71 37.82 40.98 49.09 58.51 61.50 67.11 48.59
wA 0.307 0.307 0.307 0.307 0.307 0.307 0.307 0.307 0.307
wB 0.17325 0.17325 0.17325 0.17325 0.17325 0.17325 0.17325 0.17325 0.17325
wC 0.51975 0.51975 0.51975 0.51975 0.51975 0.51975 0.51975 0.51975 0.51975
T/K 322.05 328.85 331.05 331.65 332.25 333.35 334.45 336.25 338.15
P/bar 60.31 62.25 68.20 70.79 73.94 76.99 81.99 89.11 96.24
wA 0.307
wB 0.17325
wC 0.51975
T/K 343.15
P/bar 109.08
LLE
____________________________________________________________________________________
Polymer (B): poly(octadecyl acrylate) 2002BYU

Characterization: Mw/kg.mol−1 = 93.3, Tg/K = 313,
Solvent (C): octadecyl acrylate C21H40O2 4813-57-4

wA 0.836 0.836 0.836 0.836 0.836 0.836 0.836 0.799 0.799
wB 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.050 0.050
wC 0.119 0.119 0.119 0.119 0.119 0.119 0.119 0.151 0.151
T/K 416.65 417.45 418.25 420.45 422.25 443.75 466.95 314.05 324.15
P/bar 2100.0 1752.1 1631.4 1408.6 1309.3 1012.4 922.8 515.9 522.1
wA 0.799 0.799 0.799 0.799 0.799 0.690 0.690 0.690 0.690
wB 0.050 0.050 0.050 0.050 0.050 0.052 0.052 0.052 0.052
wC 0.151 0.151 0.151 0.151 0.151 0.258 0.258 0.258 0.258
T/K 343.45 363.65 384.05 403.85 427.45 352.45 354.25 358.45 381.45
P/bar 539.3 545.9 563.1 574.8 584.8 1560.0 870.0 744.1 594.8
wA 0.690 0.690 0.665 0.665 0.665 0.665 0.665 0.665 0.665
wB 0.052 0.052 0.048 0.048 0.048 0.048 0.048 0.048 0.048
wC 0.258 0.258 0.287 0.287 0.287 0.287 0.287 0.287 0.287
T/K 401.75 423.55 333.15 334.35 338.45 343.45 345.95 363.15 384.45
P/bar 558.3 550.0 1656.9 1119.0 698.3 622.4 594.8 504.1 474.5
wA 0.665 0.665 0.603 0.603 0.603 0.603 0.559 0.559 0.559
wB 0.048 0.048 0.047 0.047 0.047 0.047 0.041 0.041 0.041
wC 0.287 0.287 0.350 0.350 0.350 0.350 0.400 0.400 0.400
T/K 407.65 428.75 313.65 333.25 352.95 372.55 309.45 313.95 319.75
P/bar 482.8 488.3 332.8 281.0 286.6 312.1 158.6 167.2 179.0
wA 0.559 0.559 0.559 0.559 0.559 0.559 0.559 0.559 0.559
wB 0.041 0.041 0.041 0.041 0.041 0.041 0.041 0.041 0.041
wC 0.400 0.400 0.400 0.400 0.400 0.400 0.400 0.400 0.400
T/K 325.25 342.75 354.75 364.05 372.85 381.25 391.55 410.95 432.05
P/bar 190.0 223.5 247.9 264.1 277.9 291.4 305.2 326.2 346.6
wA 0.501 0.501 0.501 0.501 0.501 0.501 0.501 0.501 0.501
wB 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049
wC 0.450 0.450 0.450 0.450 0.450 0.450 0.450 0.450 0.450
T/K 314.95 323.85 342.75 362.55 383.25 403.65 308.55 312.45 322.25
P/bar 127.9 150.0 187.9 224.8 258.3 284.1 115.3 119.1 132.2
wA 0.501 0.491 0.491 0.491 0.491 0.491 0.491 0.491
wB 0.049 0.057 0.057 0.057 0.057 0.057 0.057 0.057
wC 0.450 0.452 0.452 0.452 0.452 0.452 0.452 0.452
T/K 327.55 308.35 313.95 334.15 353.15 374.05 392.25 411.15
P/bar 137.0 181.7 189.7 223.6 248.3 271.7 293.1 312.8
Comments: The two data pairs at 308.55 K and 312.45 K for wC = 0.450 correspond to a liquid-
vapor transition, and the two data pairs at 322.25 K and 327.55 K for wC = 0.450
correspond to a liquid-liquid-vapor transition.
____________________________________________________________________________________
Polymer (B): poly(octadecyl methacrylate) 2001BYU

Solvent (C): octadecyl methacrylate C22H42O2 32360-05-7

wA 0.842 0.842 0.842 0.842 0.842 0.842 0.842 0.842 0.842
wB 0.056 0.056 0.056 0.056 0.056 0.056 0.056 0.056 0.056
wC 0.102 0.102 0.102 0.102 0.102 0.102 0.102 0.102 0.102
T/K 452.65 452.95 453.85 455.15 459.55 470.15 487.05 508.75 527.75
P/bar 1946.6 1887.9 1791.4 1687.9 1587.9 1426.2 1236.2 1109.7 1059.3
wA 0.719 0.719 0.719 0.719 0.719 0.719 0.719 0.719 0.719
wB 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049
wC 0.232 0.232 0.232 0.232 0.232 0.232 0.232 0.232 0.232
T/K 384.85 385.05 385.25 385.65 387.25 393.25 413.85 433.95 453.65
P/bar 1794.8 1660.3 1463.1 1387.9 1254.8 1081.7 870.6 781.7 748.3
wA 0.719 0.663 0.663 0.663 0.663 0.663 0.663 0.663 0.557
wB 0.049 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.050
wC 0.232 0.297 0.297 0.297 0.297 0.297 0.297 0.297 0.393
T/K 472.95 359.35 360.15 361.85 363.55 384.05 403.15 424.75 312.65
P/bar 735.9 1374.1 1159.0 1019.0 925.2 652.8 611.7 561.0 499.7
wA 0.557 0.557 0.557 0.557 0.557 0.445 0.445 0.445 0.445
wB 0.050 0.050 0.050 0.050 0.050 0.058 0.058 0.058 0.058
wC 0.393 0.393 0.393 0.393 0.393 0.497 0.497 0.497 0.497
T/K 318.05 333.15 352.75 373.95 392.95 308.15 312.85 333.05 352.85
P/bar 395.5 322.8 311.4 325.5 352.8 113.5 120.7 163.5 199.0
wA 0.445 0.445 0.437 0.437 0.437 0.437 0.437 0.437 0.437
wB 0.058 0.058 0.046 0.046 0.046 0.046 0.046 0.046 0.046
wC 0.497 0.497 0.517 0.517 0.517 0.517 0.517 0.517 0.517
T/K 374.35 393.65 333.65 354.35 378.25 298.15 304.65 313.85 323.65
P/bar 238.3 263.1 164.8 205.2 249.3 92.4 104.5 118.7 131.7
wA 0.437
wB 0.046
wC 0.517
T/K 334.45
P/bar 142.3
Comments: The three data pairs at at 298.15 K, 304.65 and 313.85 K for wC = 0.517 correspond
to a liquid-vapor transition, and the two data pairs at 323.65 K and 334.45 K for
wC = 0.517 correspond to a liquid-liquid-vapor transition.
Polymer (B): polystyrene 1992KIA

continued
____________________________________________________________________________________
continued
Solvent (C): 2-butanone C4H8O 78-93-3

wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275
wC 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225
T/K 303.25 304.65 305.65 308.15 310.65 313.65 315.65 318.15 320.65
P/bar 117.87 116.63 115.53 113.37 108.61 107.23 105.36 104.90 103.17
wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275
wC 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225
T/K 323.35 325.65 328.15 330.65 332.85 333.25 336.15 338.15 340.65
P/bar 103.78 102.37 103.29 102.86 103.95 104.54 105.69 105.98 107.17
wA 0.150 0.100 0.100 0.100 0.100 0.100 0.100 0.100 0.100
wB 0.1275 0.180 0.180 0.180 0.180 0.180 0.180 0.180 0.180
wC 0.7225 0.720 0.720 0.720 0.720 0.720 0.720 0.720 0.720
T/K 343.15 316.45 318.75 321.45 325.65 331.25 336.55 339.25 342.95
P/bar 108.41 14.87 14.94 15.46 16.65 18.35 24.02 27.52 32.57
LLE VLE VLE VLE VLE VLE LLE LLE LLE
Polymer (B): polystyrene 1997BUN, 1999BUN


wA 0.050 0.050 0.050 0.050 0.050 0.050 0.139 0.139 0.139
wB 0.094 0.094 0.094 0.094 0.094 0.094 0.093 0.093 0.093
wC 0.856 0.856 0.856 0.856 0.856 0.856 0.768 0.768 0.768
T/K 471.8 476.41 482.93 486.92 492.39 501.91 418.75 442.45 467.75
P/bar 42.6 50.5 59.5 66.5 75.0 90.5 66.5 73.0 77.0
wA 0.139 0.139 0.139 0.139 0.139 0.165 0.165 0.165 0.1947
wB 0.093 0.093 0.093 0.093 0.093 0.092 0.092 0.092 0.0800
wC 0.768 0.768 0.768 0.768 0.768 0.743 0.743 0.743 0.7253
T/K 418.75 426.45 442.45 443.76 467.75 423.75 433.50 442.65 293.96
P/bar 66.5 81.7 107.2 107.7 150.2 117.7 135.0 149.5 46.0
wA 0.1947 0.1947 0.1947 0.1947 0.1947 0.1947 0.1947 0.1947 0.1947
wB 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800
wC 0.7253 0.7253 0.7253 0.7253 0.7253 0.7253 0.7253 0.7253 0.7253
T/K 294.90 295.35 374.18 375.80 379.29 384.02 384.15 399.55 408.53
P/bar 40.5 37.0 76.3 78.0 84.3 95.1 101.0 122.2 135.7
continued
____________________________________________________________________________________
continued
wA 0.1947 0.1947 0.1947 0.1947 0.1947 0.1947 0.1947 0.1947 0.1947
wB 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800 0.0800
wC 0.7253 0.7253 0.7253 0.7253 0.7253 0.7253 0.7253 0.7253 0.7253
T/K 423.16 293.96 294.90 295.35 297.34 374.18 384.15 408.53 423.16
P/bar 161.8 35.5 35.0 35.7 36.7 70.2 77.0 84.5 89.7
wA 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125
wB 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815
wC 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060
T/K 307.08 311.80 316.60 322.22 326.34 330.75 333.86 335.83 335.89
P/bar 60.9 55.1 53.1 52.0 51.7 54.1 57.3 60.7 59.5
wA 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125
wB 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815
wC 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060
T/K 341.92 345.96 350.14 365.05 389.51 307.08 311.80 316.60 322.22
P/bar 65.0 70.3 76.0 97.9 140.3 42.1 43.45 46.9 50.0
wA 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125
wB 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815 0.0815
wC 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060 0.7060
T/K 326.34 330.75 331.65 333.86 335.83 335.89 341.92 345.96 350.14
P/bar 52.0 71.9 57.6 63.5 53.9 52.5 60.2 55.4 55.5
wA 0.2236 0.2236 0.2236 0.2236 0.2236 0.2236 0.2236 0.2236 0.2236
wB 0.0795 0.0795 0.0795 0.6969 0.6969 0.6969 0.6969 0.6969 0.6969
wC 0.6969 0.6969 0.6969 0.0795 0.0795 0.0795 0.0795 0.0795 0.0795
T/K 305.15 311.76 316.55 321.15 328.85 335.55 353.25 369.85 384.45
P/bar 40.5 43.3 46.2 48.1 51.6 56.5 66.7 74.8 83.2
wA 0.2236 0.2236 0.2236 0.2236 0.2236 0.2236 0.2236 0.2236 0.2236
wC 0.6969 0.6969 0.6969 0.0795 0.0795 0.0795 0.0795 0.0795 0.0795
wB 0.0795 0.0795 0.0795 0.6969 0.6969 0.6969 0.6969 0.6969 0.6969
T/K 305.15 311.76 316.55 321.15 328.85 335.55 353.25 369.85 384.45
P/bar 98.1 90.7 86.3 84.6 89.8 95.6 110.0 133.9 158.7

T/K = 443.75
wA = 0.165, wB = 0.092, wC = 0.743.
___________________________________________________________________________________
P/ Liquid phase I Liquid phase II
bar wA wB wC wA wB wC
___________________________________________________________________________________
149.5 0.165 0.092 0.743 (cloud point)
139.7 0.113 0.262 0.625 0.180 0.024 0.796
132.8 0.083 0.276 0.641 0.170 0.011 0.819
105.4 0.053 0.329 0.618 0.190 0.004 0.806
86.6 0.196 0.006 0.798
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 443.75
wA = 0.139, wB = 0.093, wC = 0.768.
___________________________________________________________________________________
___________________________________________________________________________________
109.0 0.139 0.093 0.768 (cloud point)
99.1 0.077 0.248 0.675 0.140 0.019 0.841
92.4 0.083 0.269 0.648
73.0 0.035 0.333 0.632 0.149 0.007 0.844
___________________________________________________________________________________
T/K = 448.15
wA = 0.1554, wB = 0.0935, wC = 0.7511.
___________________________________________________________________________________
___________________________________________________________________________________
145.0 0.1554 0.0935 0.7511 (cloud point)
124.1 0.121 0.303 0.576 0.1630 0.0270 0.8100
102.6 0.139 0.343 0.518 0.1788 0.0028 0.8184
86.3 0.061 0.365 0.574 0.1900 0.0017 0.8083
___________________________________________________________________________________
T/K = 468.15
wA = 0.141, wB = 0.093, wC = 0.766.
___________________________________________________________________________________
___________________________________________________________________________________
150.2 0.141 0.093 0.766 (cloud point)
136.5 0.065 0.357 0.578 0.142 0.0306 0.8274
121.1 0.162 0.010 0.828
105.7 0.072 0.366 0.562 0.149 0.002 0.849
87.1 0.038 0.3564 0.6056 0.155 0.011 0.883
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 467.85
wA = 0.1018, wB = 0.0980, wC = 0.8002.
___________________________________________________________________________________
___________________________________________________________________________________
89.1 0.0383 0.2350 0.7260 0.1311 0.0300 0.8389
78.3 0.0367 0.3260 0.6373 0.1268 0.0130 0.8602
67.0 0.0314 0.3410 0.6276 0.1310 0.0050 0.8640
___________________________________________________________________________________
T/K = 477.85
wA = 0.0893, wB = 0.0950, wC = 0.8157.
___________________________________________________________________________________
___________________________________________________________________________________
101.5 0.0893 0.0950 0.8157 (cloud point)
93.5 0.0643 0.2940 0.6417 0.0989 0.0370 0.8641
85.6 0.0296 0.3330 0.6374 0.1093 0.0100 0.8807
74.2 0.0281 0.3830 0.5889 0.1071 0.0080 0.8849
62.7 0.0269 0.3860 0.5871 0.1109 0.0060 0.8831
___________________________________________________________________________________
Type of data: liquid-liquid-vapor three-phase equilibrium

T/K = 443.15
___________________________________________________________________________________
Liquid phase I Liquid phase II Vapor phase
___________________________________________________________________________________
P/bar = 71.2
0.096 0.319 0.585 0.151 0.008 0.841 0.650 0.000 0.350
___________________________________________________________________________________
P/bar = 88.0
0.100 0.225 0.675 0.1575 0.0060 0.8365
0.109 0.302 0.589 0.1880 0.0036 0.8084
0.092 0.380 0.528 0.2050 0.0040 0.7910
0.102 0.397 0.501 0.2310 0.0013 0.7677 0.678 0.000 0.322
___________________________________________________________________________________
continued
____________________________________________________________________________________
continued
P/bar = 101
0.038 0.248 0.714 0.139 0.019 0.842
0.064 0.278 0.658 0.152 0.022 0.826
0.087 0.270 0.643 0.182 0.010 0.808
0.073 0.339 0.588 0.217 0.007 0.776
0.091 0.447 0.462 0.251 0.015 0.734 0.652 0.000 0.348
0.092 0.415 0.493 0.669 0.000 0.331
0.068 0.611 0.321 0.739 0.000 0.261
0.080 0.681 0.239 0.803 0.000 0.197
___________________________________________________________________________________
P/bar = 135
0.142 0.291 0.567 0.2030 0.0095 0.7875
0.138 0.3954 0.4666 0.2370 0.0110 0.7520
0.159 0.458 0.383 0.3100 0.0033 0.6867
0.148 0.503 0.349 0.3360 0.0037 0.6603
0.189 0.582 0.229 0.3890 0.0024 0.6086 0.638 0.000 0.362
___________________________________________________________________________________


T/K = 461.85
wA = 0.1286, wB = 0.0341, wC = 0.8373.
___________________________________________________________________________________
___________________________________________________________________________________
125.7 0.1286 0.0341 0.8373 (cloud point)
111.3 0.0819 0.2274 0.6907 0.1444 0.0150 0.8406
97.5 0.0875 0.2833 0.6292 0.1469 0.0122 0.8409
79.7 0.0991 0.3138 0.5871 0.1431 0.0098 0.8471
66.2 0.0977 0.3332 0.5691 0.1210 0.0042 0.8748
___________________________________________________________________________________

Characterization: Mn/kg.mol−1 = 37.8, Mw/kg.mol−1 = 42.7, Mz/kg.mol−1 = 67.7
Polymer (D): polystyrene
continued
____________________________________________________________________________________
continued
Comments: The initial polymer mixture was made 50/50 by weight.
T/K = 443.15
wA = 0.134, wB+D = 0.094, wC = 0.772.
___________________________________________________________________________________
bar wA wB+D wC wA wB+D wC
___________________________________________________________________________________
114.0 0.134 0.094 0.772 (cloud point)
101.5 0.084 0.263 0.653 0.134 0.038 0.828
86.2 0.084 0.266 0.650 0.151 0.021 0.828
74.1 0.101 0.321 0.578 0.174 0.008 0.818
___________________________________________________________________________________


wA 0.108 0.108 0.108 0.108 0.108 0.200 0.200 0.200
wB 0.1784 0.1784 0.1784 0.1784 0.1784 0.160 0.160 0.160
wC 0.7136 0.7136 0.7136 0.7136 0.7136 0.640 0.640 0.640
T/K 306.05 313.65 323.55 333.25 343.25 323.15 333.15 343.15
P/bar 23.84 26.59 29.97 31.35 35.36 83.70 76.86 85.63
VLE VLE VLE VLE VLE LLE LLE LLE

Solvent (C): methylcyclohexane C7H14 108-87-2

wA 0.0377 0.0377 0.0377 0.0377 0.0377 0.0377 0.0377 0.0377 0.0377
wB 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495
wC 0.9128 0.9128 0.9128 0.9128 0.9128 0.9128 0.9128 0.9128 0.9128
T/K 298.40 298.34 297.77 297.55 297.16 296.86 296.73 296.40 295.91
P/MPa 2.40 2.85 4.65 5.40 7.25 8.025 8.50 9.75 12.05
continued
____________________________________________________________________________________
continued
wA 0.0775 0.0775 0.0775 0.0775 0.0775 0.0775 0.0775 0.0775 0.1122
wB 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494
wC 0.8731 0.8731 0.8731 0.8731 0.8731 0.8731 0.8731 0.8731 0.8384
T/K 298.28 297.38 296.40 295.88 295.36 294.84 294.40 294.00 299.37
P/MPa 2.95 4.45 6.60 7.75 9.05 10.40 11.55 12.90 3.00
wA 0.1122 0.1122 0.1122 0.1122 0.1122 0.1122 0.1221 0.1221 0.1221
wB 0.0494 0.0494 0.0494 0.0494 0.0494 0.0494 0.0496 0.0496 0.0496
wC 0.8384 0.8384 0.8384 0.8384 0.8384 0.8384 0.8283 0.8283 0.8283
T/K 298.28 296.73 295.36 294.38 293.52 293.24 299.99 298.16 296.85
P/MPa 4.00 6.60 8.80 10.60 12.35 12.90 3.30 5.45 7.15
wA 0.1221 0.1221 0.1221 0.1221 0.1221 0.1479 0.1479 0.1479 0.1479
wB 0.0496 0.0496 0.0496 0.0496 0.0496 0.0491 0.0491 0.0491 0.0491
wC 0.8283 0.8283 0.8283 0.8283 0.8283 0.8030 0.8030 0.8030 0.8030
T/K 295.73 294.96 294.14 293.59 293.07 303.92 302.89 301.48 299.33
P/MPa 8.80 10.05 11.50 12.45 13.55 3.25 3.95 5.20 6.95
wA 0.1479 0.1479 0.1479 0.1479 0.1812 0.1812 0.1812 0.1812 0.1812
wB 0.0491 0.0491 0.0491 0.0491 0.0494 0.0494 0.0494 0.0494 0.0494
wC 0.8030 0.8030 0.8030 0.8030 0.7694 0.7694 0.7694 0.7694 0.7694
T/K 298.40 296.32 295.36 294.43 315.80 314.29 311.86 308.28 305.83
P/MPa 8.00 10.30 11.45 12.80 4.60 5.10 6.05 7.70 9.05
wA 0.1812 0.1812 0.1812 0.2095 0.2095 0.2095 0.2095 0.2095 0.2095
wB 0.0494 0.0494 0.0494 0.0479 0.0479 0.0479 0.0479 0.0479 0.0479
wC 0.7694 0.7694 0.7694 0.7426 0.7426 0.7426 0.7426 0.7426 0.7426
T/K 304.29 302.28 300.64 368.48 363.49 358.95 354.03 348.36 328.91
P/MPa 10.05 11.50 12.80 8.55 8.10 7.80 7.50 7.30 7.95
wA 0.2095 0.2095 0.2095 0.2095 0.2114 0.2114 0.2114 0.2114 0.2114
wB 0.0479 0.0479 0.0479 0.0479 0.0495 0.0495 0.0495 0.0495 0.0495
wC 0.7426 0.7426 0.7426 0.7426 0.7391 0.7391 0.7391 0.7391 0.7391
T/K 323.61 319.01 316.29 313.30 367.47 359.02 352.44 347.40 344.34
P/MPa 8.80 9.80 10.60 11.65 9.15 8.50 8.15 8.00 7.95
wA 0.2114 0.2114 0.2114 0.2114 0.2114 0.2114 0.2114 0.2114 0.2114
wB 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495 0.0495
wC 0.7391 0.7391 0.7391 0.7391 0.7391 0.7391 0.7391 0.7391 0.7391
T/K 341.34 338.37 336.34 333.33 330.35 328.32 326.28 323.33 318.33
P/MPa 8.00 8.05 8.15 8.35 8.60 8.90 9.10 9.65 10.85
wA 0.2114 0.2114 0.0242 0.0242 0.0242 0.0242 0.0242 0.0242 0.0428
wB 0.0495 0.0495 0.1099 0.1099 0.1099 0.1099 0.1099 0.1099 0.1090
wC 0.7391 0.7391 0.8659 0.8659 0.8659 0.8659 0.8659 0.8659 0.8482
T/K 315.33 313.30 301.62 301.06 300.09 299.52 299.22 298.98 300.92
P/MPa 11.80 12.55 2.25 4.10 7.65 10.10 11.45 12.65 2.05
wA 0.0428 0.0428 0.0428 0.0428 0.0428 0.0428 0.0508 0.0508 0.0508
wB 0.1090 0.1090 0.1090 0.1090 0.1090 0.1090 0.1097 0.1097 0.1097
wC 0.8482 0.8482 0.8482 0.8482 0.8482 0.8482 0.8395 0.8395 0.8395
T/K 300.19 299.56 298.81 298.35 297.85 297.50 301.04 300.41 299.66
P/MPa 4.00 5.75 8.10 9.65 11.50 12.95 1.95 3.45 5.25
continued
____________________________________________________________________________________
continued
wA 0.0508 0.0508 0.0508 0.0508 0.0742 0.0742 0.0742 0.0742 0.0742
wB 0.1097 0.1097 0.1097 0.1097 0.1091 0.1091 0.1091 0.1091 0.1091
wC 0.8395 0.8395 0.8395 0.8395 0.8167 0.8167 0.8167 0.8167 0.8167
T/K 298.80 298.31 297.68 297.12 301.05 301.00 300.30 299.44 298.56
P/MPa 7.60 9.10 11.15 13.05 1.85 1.95 3.10 4.65 6.40
wA 0.0742 0.0742 0.0742 0.1037 0.1037 0.1037 0.1037 0.1037 0.1037
wB 0.1091 0.1091 0.1091 0.1098 0.1098 0.1098 0.1098 0.1098 0.1098
wC 0.8167 0.8167 0.8167 0.7865 0.7865 0.7865 0.7865 0.7865 0.7865
T/K 297.44 296.56 295.89 302.29 301.38 300.25 299.14 298.18 297.10
P/MPa 8.85 11.05 12.85 2.85 4.00 5.40 7.00 8.50 10.30
wA 0.1037 0.1167 0.1167 0.1167 0.1167 0.1167 0.1167 0.1457 0.1457
wB 0.1098 0.1095 0.1095 0.1095 0.1095 0.1095 0.1095 0.1095 0.1095
wC 0.7865 0.7738 0.7738 0.7738 0.7738 0.7738 0.7738 0.7448 0.7448
T/K 296.18 303.57 303.17 301.87 300.72 299.33 297.62 310.79 310.28
P/MPa 12.10 3.10 3.50 4.80 6.20 7.95 10.45 3.825 4.075
wA 0.1457 0.1457 0.1457 0.1457 0.1457 0.1457 0.1457 0.1657 0.1657
wB 0.1095 0.1095 0.1095 0.1095 0.1095 0.1095 0.1095 0.1096 0.1096
wC 0.7448 0.7448 0.7448 0.7448 0.7448 0.7448 0.7448 0.7247 0.7247
T/K 309.28 308.35 305.77 303.74 302.83 301.73 299.37 320.65 317.06
P/MPa 4.625 5.175 6.875 8.425 9.20 10.25 12.70 4.325 5.325
wA 0.1657 0.1657 0.1657 0.1657 0.1657
wB 0.1096 0.1096 0.1096 0.1096 0.1096
wC 0.7247 0.7247 0.7247 0.7247 0.7247
T/K 312.30 309.34 307.24 305.58 303.32
P/MPa 7.175 8.625 9.925 11.00 12.75
Polymer (B): polystyrene 1994MUR

wA 0.29 0.29
wB 0.11 0.11
wC 0.60 0.60
T/K 343.15 343.15
P/bar 62.81 75.98
(a) (b)
____________________________________________________________________________________
Polymer (B): polystyrene 1992KIA, 1994KIA


wA 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.120
wC 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680
T/K 299.15 303.15 308.25 313.15 318.15 323.15 328.15 333.15 337.15
P/bar 17.69 18.35 20.82 22.36 24.30 26.43 28.37 31.29 32.24
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125
wC 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 302.35 303.15 308.35 313.15 318.15 323.15 328.55 333.15 336.65
P/bar 25.70 26.13 28.43 30.50 33.16 36.34 39.49 42.19 49.31
VLE VLE VLE VLE VLE VLE VLE LLE LLE
wA 0.250 0.250 0.250 0.260 0.260 0.260 0.260 0.260 0.260
wB 0.1125 0.1125 0.1125 0.111 0.111 0.111 0.111 0.111 0.111
wC 0.6375 0.6375 0.6375 0.629 0.629 0.629 0.629 0.629 0.629
T/K 338.25 340.65 342.85 297.95 303.15 308.15 313.15 315.65 318.25
P/bar 54.04 61.33 68.15 24.19 26.43 28.76 31.45 36.38 43.14
LLE LLE LLE VLE VLE VLE VLE LLE LLE
wA 0.260 0.260 0.260 0.260 0.260 0.260 0.260 0.260 0.260
wB 0.111 0.111 0.111 0.111 0.111 0.111 0.111 0.111 0.111
wC 0.629 0.629 0.629 0.629 0.629 0.629 0.629 0.629 0.629
T/K 320.65 323.25 325.65 328.65 330.65 333.15 335.65 338.15 340.15
P/bar 49.08 55.68 62.28 70.00 75.74 83.03 89.96 96.03 101.94
wA 0.260 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.111 0.170 0.170 0.170 0.170 0.170 0.170 0.170 0.170
wC 0.629 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680
T/K 341.95 298.85 303.25 308.15 313.15 318.15 323.15 328.15 333.15
P/bar 106.97 16.84 17.83 19.37 21.17 23.08 24.62 26.66 29.12
wA 0.150 0.150 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.170 0.170 0.160 0.160 0.160 0.160 0.160 0.160 0.160
wC 0.680 0.680 0.640 0.640 0.640 0.640 0.640 0.640 0.640
T/K 338.15 341.55 298.15 305.15 307.65 313.55 318.15 323.15 328.15
P/bar 30.96 32.83 21.84 25.12 25.90 28.30 30.41 32.41 35.55
continued
____________________________________________________________________________________
continued
wA 0.200 0.200 0.200 0.210 0.210 0.210 0.210 0.210 0.210
wB 0.160 0.160 0.160 0.158 0.158 0.158 0.158 0.158 0.158
wC 0.640 0.640 0.640 0.632 0.632 0.632 0.632 0.632 0.632
T/K 333.15 338.15 342.55 298.45 303.15 308.15 313.15 318.15 323.15
P/bar 38.12 41.04 44.26 23.54 25.12 27.84 30.60 32.67 35.56
wA 0.210 0.210 0.210 0.210 0.222 0.222 0.222 0.222 0.222
wB 0.158 0.158 0.158 0.158 0.1556 0.1556 0.1556 0.1556 0.1556
wC 0.632 0.632 0.632 0.632 0.6224 0.6224 0.6224 0.6224 0.6224
T/K 328.15 333.15 338.15 342.95 300.65 303.15 308.15 313.15 318.15
P/bar 38.81 41.70 44.78 48.39 26.27 26.89 29.25 31.68 34.27
wA 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.222 0.231
wB 0.1556 0.1556 0.1556 0.1556 0.1556 0.1556 0.1556 0.1556 0.1538
wC 0.6224 0.6224 0.6224 0.6224 0.6224 0.6224 0.6224 0.6224 0.6152
T/K 323.15 328.15 330.15 333.15 335.65 338.15 340.15 343.15 300.95
P/bar 37.30 40.32 41.78 47.31 52.99 61.40 68.20 75.97 27.41
VLE VLE VLE VLE LLE LLE LLE LLE VLE
wA 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231
wB 0.1538 0.1538 0.1538 0.1538 0.1538 0.1538 0.1538 0.1538 0.1538
wC 0.6152 0.6152 0.6152 0.6152 0.6152 0.6152 0.6152 0.6152 0.6152
T/K 303.25 305.65 308.45 310.65 313.15 315.65 318.15 320.65 323.15
P/bar 28.07 30.50 32.63 35.98 41.50 47.22 53.03 60.34 66.12
wA 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.236
wB 0.1538 0.1538 0.1538 0.1538 0.1538 0.1538 0.1538 0.1538 0.1528
wC 0.6152 0.6152 0.6152 0.6152 0.6152 0.6152 0.6152 0.6152 0.6112
T/K 325.65 328.15 330.65 333.15 335.85 338.15 340.65 342.75 302.85
P/bar 73.05 79.22 85.63 93.18 100.66 106.72 112.38 119.49 87.43
wA 0.236 0.236 0.236 0.236 0.236 0.236 0.236 0.236 0.236
wB 0.1528 0.1528 0.1528 0.1528 0.1528 0.1528 0.1528 0.1528 0.1528
wC 0.6112 0.6112 0.6112 0.6112 0.6112 0.6112 0.6112 0.6112 0.6112
T/K 303.15 304.15 305.65 308.15 310.65 313.15 315.65 318.15 320.65
P/bar 87.73 88.22 89.98 93.64 98.79 101.64 106.81 111.96 117.11
wA 0.236 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.1528 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125
wC 0.6112 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 323.35 301.35 303.15 308.25 313.15 318.15 323.15 328.15 333.15
P/bar 121.58 18.22 18.38 19.66 21.11 22.88 24.79 26.79 28.50
continued
____________________________________________________________________________________
continued
wA 0.150 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.2125 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wC 0.6375 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600
T/K 338.15 299.55 315.35 317.45 323.25 328.15 333.15 338.35 342.65
P/bar 30.73 22.62 29.48 30.27 33.23 35.60 38.02 41.11 43.86
wA 0.216 0.216 0.216 0.216 0.216 0.216 0.216 0.216 0.216
wB 0.196 0.196 0.196 0.196 0.196 0.196 0.196 0.196 0.196
wC 0.588 0.588 0.588 0.588 0.588 0.588 0.588 0.588 0.588
T/K 299.65 303.15 308.15 313.15 318.15 323.15 328.15 333.15 337.45
P/bar 25.18 26.17 28.23 30.53 34.05 35.52 38.28 41.43 44.88
wA 0.216 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231
wB 0.196 0.19225 0.19225 0.19225 0.19225 0.19225 0.19225 0.19225 0.19225
wC 0.588 0.57675 0.57675 0.57675 0.57675 0.57675 0.57675 0.57675 0.57675
T/K 342.15 298.65 303.65 308.15 313.15 318.15 323.15 328.15 333.15
P/bar 48.49 25.51 28.43 29.61 32.01 35.23 38.22 42.35 54.57
VLE VLE VLE VLE VLE VLE VLE LLE LLE
wA 0.231 0.231 0.231 0.231 0.240 0.240 0.240 0.240 0.240
wB 0.19225 0.19225 0.19225 0.19225 0.190 0.190 0.190 0.190 0.190
wC 0.57675 0.57675 0.57675 0.57675 0.570 0.570 0.570 0.570 0.570
T/K 338.55 340.65 342.15 342.65 298.85 300.65 303.15 305.65 308.15
P/bar 69.31 76.08 80.17 82.14 50.76 52.56 54.63 59.16 63.33
wA 0.240 0.240 0.240 0.240 0.240 0.240 0.240 0.240 0.240
wB 0.190 0.190 0.190 0.190 0.190 0.190 0.190 0.190 0.190
wC 0.570 0.570 0.570 0.570 0.570 0.570 0.570 0.570 0.570
T/K 310.65 313.15 315.65 318.15 320.65 323.15 325.65 328.15 330.65
P/bar 68.69 72.49 77.68 83.13 89.34 94.69 101.35 105.94 111.72
wA 0.240 0.240 0.240 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.190 0.190 0.190 0.283 0.283 0.283 0.283 0.283 0.283
wC 0.570 0.570 0.570 0.567 0.567 0.567 0.567 0.567 0.567
T/K 333.15 335.15 335.65 305.05 305.65 308.15 313.15 322.65 333.15
P/bar 118.03 121.64 123.97 21.21 21.44 21.74 23.41 28.56 33.42
wA 0.150 0.150 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.283 0.283 0.2664 0.2664 0.2664 0.2664 0.2664 0.2664 0.2664
wC 0.567 0.567 0.5336 0.5336 0.5336 0.5336 0.5336 0.5336 0.5336
T/K 338.15 343.15 302.45 308.15 313.65 318.15 323.15 330.65 333.15
P/bar 35.46 37.66 25.71 27.12 29.65 32.07 34.47 38.98 40.36
wA 0.200 0.200
wB 0.2664 0.2664
wC 0.5336 0.5336
T/K 340.65 343.15
P/bar 45.08 46.82
VLE VLE
____________________________________________________________________________________
Polymer (B): polystyrene 2001LI2

Characterization: Mn/kg.mol−1 = 71, Mw/kg.mol−1 = 78, State Key Laboratory of
Polymer Science, Chinese Academy of Sciences

Comments: Cloud points were determined for a given concentration of polystyrene in the CO2-free
toluene solution, c0B, and the given equilibrium CO2-pressure of the ternary system.
Volume expansion coefficients of the ternary system are given in Chapter 6.
c0B/g.ml−3 0.00046 0.00046 0.00046 0.00046 0.00046 0.00046 0.00046 0.00069 0.00069
T/K 298.15 303.15 308.15 313.15 318.15 323.15 328.15 298.15 303.15
P/MPa 4.70 4.74 4.78 4.85 4.91 4.96 4.99 4.65 4.71
c0B/g.ml−3 0.00069 0.00069 0.00069 0.00069 0.00069 0.00107 0.00107 0.00107 0.00107
T/K 308.15 313.15 318.15 323.15 328.15 298.15 303.15 308.15 313.15
P/MPa 4.74 4.78 4.86 4.91 4.93 4.61 4.67 4.70 4.74
c0B/g.ml−3 0.00107 0.00107 0.00107 0.0032 0.0032 0.0032 0.0032 0.0032 0.0032
T/K 318.15 323.15 328.15 298.15 303.15 308.15 313.15 318.15 323.15
P/MPa 4.82 4.86 4.89 4.59 4.61 4.64 4.70 4.75 4.82
c0B/g.ml−3 0.0032 0.0092 0.0092 0.0092 0.0092 0.0092 0.0092 0.0092
T/K 328.15 298.15 303.15 308.15 313.15 318.15 323.15 328.15
P/MPa 4.84 4.56 4.58 4.61 4.65 4.71 4.78 4.81
Polymer (B): polystyrene 1993DIX


T/K = 395.15 P/bar = 60.6
wA 0.4000 0.3500 0.3400
wB 0.0060 0.0379 0.0845
wC 0.5940 0.6120 0.5750
Polymer (B): polystyrene 1992KIA, 1994KIA


continued
____________________________________________________________________________________
continued
wA 0.146 0.146 0.146 0.146 0.146 0.250 0.250 0.250 0.250
wB 0.2844 0.2844 0.2844 0.2844 0.2844 0.250 0.250 0.250 0.250
wC 0.5696 0.5696 0.5696 0.5696 0.5696 0.500 0.500 0.500 0.500
T/K 307.55 313.15 323.15 333.15 343.15 313.15 320.15 333.15 343.15
P/bar 30.54 32.94 38.38 43.11 48.73 44.95 48.53 58.93 67.01
wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275
wC 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225
T/K 299.25 303.15 308.15 313.15 318.15 323.15 333.15 338.15 342.85
P/bar 30.23 31.52 33.75 36.21 38.91 42.02 46.75 49.39 53.32
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.120 0.120
wC 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680
T/K 299.65 303.15 309.15 313.15 318.15 323.15 330.65 333.15 338.15
P/bar 34.96 36.34 39.56 41.95 45.77 48.66 53.68 55.09 59.04
wA 0.200 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.120 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125 0.1125
wC 0.680 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 342.65 300.75 303.15 308.25 313.45 319.25 323.15 328.15 334.65
P/bar 62.41 40.74 41.56 44.78 47.90 53.19 55.85 60.44 65.27
wA 0.250 0.250 0.276 0.276 0.276 0.276 0.276 0.276 0.276
wB 0.1125 0.1125 0.1086 0.1086 0.1086 0.1086 0.1086 0.1086 0.1086
wC 0.6375 0.6375 0.6154 0.6154 0.6154 0.6154 0.6154 0.6154 0.6154
T/K 338.15 343.15 301.85 304.15 305.15 306.65 307.45 308.15 309.15
P/bar 68.13 73.67 110.58 112.35 114.22 115.24 116.09 117.21 118.06
wA 0.276 0.276 0.276 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.1086 0.1086 0.1086 0.160 0.160 0.160 0.160 0.160 0.160
wC 0.6154 0.6154 0.6154 0.640 0.640 0.640 0.640 0.640 0.640
T/K 310.15 311.15 312.15 308.15 313.15 318.15 323.15 328.15 333.15
P/bar 119.90 120.79 121.49 40.38 42.88 45.96 49.38 52.63 55.98
wA 0.200 0.200 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.160 0.160 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.640 0.640 0.600 0.600 0.600 0.600 0.600 0.600 0.600
T/K 338.15 342.65 305.15 308.15 313.15 318.15 323.15 328.15 333.15
P/bar 59.59 63.53 43.47 44.55 48.23 51.72 55.79 59.56 64.22
continued
____________________________________________________________________________________
continued
wA 0.250 0.250 0.259 0.259 0.259 0.259 0.259 0.259 0.259
wB 0.150 0.150 0.1482 0.1482 0.1482 0.1482 0.1482 0.1482 0.1482
wC 0.600 0.600 0.5928 0.5928 0.5928 0.5928 0.5928 0.5928 0.5928
T/K 338.15 342.95 301.25 303.25 308.15 313.15 318.15 323.15 328.35
P/bar 68.82 72.79 41.99 42.95 46.10 49.41 54.01 61.30 73.64
wA 0.259 0.259 0.259 0.259 0.259 0.273 0.273 0.273 0.273
wB 0.1482 0.1482 0.1482 0.1482 0.1482 0.1454 0.1454 0.1454 0.1454
wC 0.5928 0.5928 0.5928 0.5928 0.5928 0.5816 0.5816 0.5816 0.5816
T/K 333.15 335.55 336.95 338.75 342.95 305.85 308.15 313.15 315.15
P/bar 84.45 90.19 93.51 98.07 109.99 45.51 47.18 50.89 52.30
LLE LLE LLE LLE LLE VLE VLE VLE VLE
wA 0.273 0.273 0.273 0.273 0.273 0.273 0.273 0.273 0.273
wB 0.1454 0.1454 0.1454 0.1454 0.1454 0.1454 0.1454 0.1454 0.1454
wC 0.5816 0.5816 0.5816 0.5816 0.5816 0.5816 0.5816 0.5816 0.5816
T/K 318.15 319.55 321.25 323.05 326.75 329.45 332.95 338.95 340.15
P/bar 54.97 55.94 57.88 61.00 68.07 74.17 82.64 96.33 99.19
wA 0.273 0.273 0.273 0.281 0.281 0.281 0.281 0.281 0.281
wB 0.1454 0.1454 0.1454 0.1438 0.1438 0.1438 0.1438 0.1438 0.1438
wC 0.5816 0.5816 0.5816 0.5752 0.5752 0.5752 0.5752 0.5752 0.5752
T/K 340.65 341.75 343.55 304.45 306.15 308.45 310.15 311.65 313.25
P/bar 99.86 102.99 106.64 98.17 100.86 103.03 106.70 109.46 111.21
wA 0.281 0.281 0.281 0.281 0.281 0.175 0.175 0.175 0.175
wB 0.1438 0.1438 0.1438 0.1438 0.1438 0.2005 0.2005 0.2005 0.2005
wC 0.5752 0.5752 0.5752 0.5752 0.5752 0.6245 0.6245 0.6245 0.6245
T/K 314.65 316.65 318.15 320.15 321.65 328.65 332.95 337.95 343.15
P/bar 112.42 115.64 119.02 121.94 125.13 54.96 57.36 61.07 64.09
LLE LLE LLE LLE LLE VLE VLE VLE VLE
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.225
wB 0.1944 0.1944 0.1944 0.1944 0.1944 0.1944 0.1944 0.1944 0.1883
wC 0.6056 0.6056 0.6056 0.6056 0.6056 0.6056 0.6056 0.6056 0.5867
T/K 307.35 313.15 318.15 323.15 328.15 333.75 338.65 343.15 325.15
P/bar 44.09 47.97 49.61 54.70 57.32 60.96 64.09 67.93 60.64
wA 0.225 0.225 0.225 0.225 0.243 0.243 0.243 0.243 0.243
wB 0.1883 0.1883 0.1883 0.1883 0.184 0.184 0.184 0.184 0.184
wC 0.5867 0.5867 0.5867 0.5867 0.573 0.573 0.573 0.573 0.573
T/K 328.45 333.35 336.45 343.15 309.15 315.35 317.15 319.45 323.05
P/bar 63.60 68.43 70.69 77.12 51.84 55.45 56.34 58.50 62.18
continued
____________________________________________________________________________________
continued
wA 0.243 0.243 0.243 0.243 0.243 0.243 0.243 0.150 0.150
wB 0.184 0.184 0.184 0.184 0.184 0.184 0.184 0.2125 0.2125
wC 0.573 0.573 0.573 0.573 0.573 0.573 0.573 0.6375 0.6375
T/K 326.45 329.65 331.75 335.15 337.75 340.15 343.05 303.85 308.25
P/bar 64.48 67.53 71.08 78.89 84.44 90.61 95.43 31.35 32.14
wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.200 0.200
wB 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.200 0.200
wC 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.600 0.600
T/K 313.15 318.15 323.15 328.95 333.15 338.15 342.15 307.85 313.25
P/bar 34.44 36.71 39.56 42.06 43.86 46.09 49.01 41.20 43.20
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.250 0.250 0.250
wB 0.200 0.200 0.200 0.200 0.200 0.200 0.1875 0.1875 0.1875
wC 0.600 0.600 0.600 0.600 0.600 0.600 0.5625 0.5625 0.5625
T/K 318.15 323.15 328.15 333.15 338.15 343.05 304.95 308.15 313.15
P/bar 46.03 49.81 52.83 56.08 60.18 64.65 43.60 44.78 48.39
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.261 0.261 0.261
wB 0.1875 0.1875 0.1875 0.1875 0.1875 0.1875 0.18475 0.18475 0.18475
wC 0.5625 0.5625 0.5625 0.5625 0.5625 0.5625 0.55425 0.55425 0.55425
T/K 318.25 323.15 328.15 333.15 338.15 342.55 308.15 312.85 318.15
P/bar 51.84 55.94 59.39 64.48 68.78 72.92 48.16 51.84 55.65
wA 0.261 0.261 0.261 0.261 0.261 0.261 0.261 0.269 0.269
wB 0.18475 0.18475 0.18475 0.18475 0.18475 0.18475 0.18475 0.18275 0.18275
wC 0.55425 0.55425 0.55425 0.55425 0.55425 0.55425 0.55425 0.54825 0.54825
T/K 323.85 328.15 333.15 335.65 338.05 340.05 342.85 305.95 308.35
P/bar 61.20 63.96 68.42 70.69 73.18 77.75 84.51 84.25 100.53
wA 0.269 0.269 0.269 0.269 0.269 0.269 0.269 0.269 0.269
wB 0.18275 0.18275 0.18275 0.18275 0.18275 0.18275 0.18275 0.18275 0.18275
wC 0.54825 0.54825 0.54825 0.54825 0.54825 0.54825 0.54825 0.54825 0.54825
T/K 309.95 313.35 314.65 315.65 316.65 318.15 319.65 320.65 321.65
P/bar 102.60 107.02 108.70 109.46 111.27 113.60 116.36 117.31 119.31
wA 0.269 0.269
wB 0.18275 0.18275
wC 0.54825 0.54825
T/K 323.25 324.25
P/bar 121.84 123.91
LLE LLE
____________________________________________________________________________________


wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.085 0.085 0.085 0.085 0.085 0.085 0.085 0.085 0.085
wC 0.765 0.765 0.765 0.765 0.765 0.765 0.765 0.765 0.765
T/K 299.75 303.15 308.15 313.15 318.15 323.15 328.25 333.15 338.15
P/bar 22.69 23.70 25.58 27.97 29.65 31.58 34.31 36.77 39.27
wA 0.150 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.085 0.080 0.080 0.080 0.080 0.080 0.080 0.080 0.080
wC 0.765 0.720 0.720 0.720 0.720 0.720 0.720 0.720 0.720
T/K 343.05 306.75 308.15 313.15 318.15 323.15 328.15 332.95 338.15
P/bar 42.09 33.69 34.41 36.54 39.07 43.64 46.39 49.77 53.22
wA 0.200 0.224 0.224 0.224 0.224 0.224 0.224 0.224 0.224
wB 0.080 0.0776 0.0776 0.0776 0.0776 0.0776 0.0776 0.0776 0.0776
wC 0.720 0.6984 0.6984 0.6984 0.6984 0.6984 0.6984 0.6984 0.6984
T/K 342.95 298.65 303.15 308.15 313.15 318.15 323.15 328.15 332.85
P/bar 55.29 31.32 33.72 35.98 39.56 42.22 46.71 49.77 53.16
wA 0.224 0.224 0.234 0.234 0.234 0.234 0.234 0.234 0.234
wB 0.0776 0.0776 0.0766 0.0766 0.0766 0.0766 0.0766 0.0766 0.0766
wC 0.6984 0.6984 0.6894 0.6894 0.6894 0.6894 0.6894 0.6894 0.6894
T/K 337.25 343.15 300.65 305.35 308.45 310.15 312.05 314.85 317.55
P/bar 59.29 80.93 34.57 37.27 42.88 47.64 53.85 63.17 72.33
LLE LLE VLE VLE LLE LLE LLE LLE LLE
wA 0.234 0.234 0.234 0.234 0.234 0.234 0.234 0.150 0.150
wB 0.0766 0.0766 0.0766 0.0766 0.0766 0.0766 0.0766 0.1275 0.1275
wC 0.6894 0.6894 0.6894 0.6894 0.6894 0.6894 0.6894 0.7225 0.7225
T/K 320.65 322.75 325.85 328.15 330.25 333.15 333.75 302.75 308.15
P/bar 82.41 88.94 98.73 107.26 113.50 123.51 125.48 29.06 30.57
wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.200 0.200
wB 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.1275 0.120 0.120
wC 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.7225 0.680 0.680
T/K 313.15 318.15 323.15 328.15 333.15 338.45 342.95 308.15 318.15
P/bar 32.71 35.49 38.40 40.38 42.95 46.62 49.38 37.47 43.73
continued
____________________________________________________________________________________
continued
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.238 0.238 0.238
wB 0.120 0.120 0.120 0.120 0.120 0.120 0.1143 0.1143 0.1143
wC 0.680 0.680 0.680 0.680 0.680 0.680 0.6477 0.6477 0.6477
T/K 323.15 328.15 333.15 338.15 342.35 343.15 303.15 306.25 309.15
P/bar 46.92 49.84 53.09 57.06 59.89 60.67 73.77 81.56 90.09
wA 0.238 0.238 0.238 0.238 0.238 0.238 0.238 0.150 0.150
wB 0.1143 0.1143 0.1143 0.1143 0.1143 0.1143 0.1143 0.170 0.170
wC 0.6477 0.6477 0.6477 0.6477 0.6477 0.6477 0.6477 0.680 0.680
T/K 310.25 311.25 312.55 314.45 318.15 320.35 322.95 300.85 303.15
P/bar 92.65 95.09 98.04 103.85 114.38 121.32 129.49 27.54 27.77
wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.200
wB 0.170 0.170 0.170 0.170 0.170 0.170 0.170 0.170 0.160
wC 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.640
T/K 308.15 313.15 318.15 323.15 328.15 334.65 338.15 343.05 303.25
P/bar 29.65 32.34 34.37 37.13 39.59 44.15 45.42 49.57 34.96
wA 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.160 0.160 0.160 0.160 0.160 0.160 0.160 0.160 0.160
wC 0.640 0.640 0.640 0.640 0.640 0.640 0.640 0.640 0.640
T/K 308.15 313.15 315.85 319.45 322.35 326.05 330.55 333.55 336.35
P/bar 37.23 41.47 49.08 60.29 68.91 81.03 94.35 104.17 113.01
wA 0.200 0.200 0.213 0.213 0.213 0.213 0.213 0.213 0.213
wB 0.160 0.160 0.1574 0.1574 0.1574 0.1574 0.1574 0.1574 0.1574
wC 0.640 0.640 0.6296 0.6296 0.6296 0.6296 0.6296 0.6296 0.6296
T/K 338.05 339.75 304.25 307.45 311.05 312.65 316.25 320.95 323.05
P/bar 117.78 121.77 91.63 100.30 108.31 112.12 122.24 132.67 135.83
wA 0.213
wB 0.1574
wC 0.6296
T/K 325.15
P/bar 141.07
LLE

BASF AG, Germany
continued
____________________________________________________________________________________
continued
wA 0.846 0.846 0.846 0.846 0.846 0.846 0.846 0.846 0.846
wB 0.104 0.104 0.104 0.104 0.104 0.104 0.104 0.104 0.104
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.050
T/K 453.68 456.17 458.64 463.63 468.63 473.61 478.60 483.57 493.59
P/bar 40 44 47 54 61 66 72 79 93
wA 0.846 0.846 0.826 0.826 0.826 0.826 0.826 0.826 0.826
wB 0.104 0.104 0.100 0.100 0.100 0.100 0.100 0.100 0.100
wC 0.050 0.050 0.074 0.074 0.074 0.074 0.074 0.074 0.074
T/K 503.59 513.58 431.34 433.74 433.79 436.27 438.75 438.75 443.65
P/bar 107 121 39 43 43 47 50 51 59
wA 0.826 0.826 0.826 0.826 0.826 0.826 0.826 0.826 0.826
wB 0.100 0.100 0.100 0.100 0.100 0.100 0.100 0.100 0.100
wC 0.074 0.074 0.074 0.074 0.074 0.074 0.074 0.074 0.074
T/K 448.68 453.65 458.67 463.69 468.66 473.67 483.68 493.65 503.64
P/bar 67 74 81 89 96 103 117 131 144
wA 0.804 0.804 0.804 0.804 0.804 0.804 0.804 0.804 0.804
wB 0.097 0.097 0.097 0.097 0.097 0.097 0.097 0.097 0.097
wC 0.099 0.099 0.099 0.099 0.099 0.099 0.099 0.099 0.099
T/K 388.59 391.08 393.61 396.10 398.58 403.56 413.54 423.53 433.55
P/bar 34 38 42 46 48 55 65 76 92
wA 0.804 0.804
wB 0.097 0.097
wC 0.099 0.099
T/K 443.55 453.52
P/bar 106 120

BASF AG, Germany

wA 0.866 0.866 0.866 0.866 0.866 0.866 0.866 0.866 0.866
wB 0.108 0.108 0.108 0.108 0.108 0.108 0.108 0.108 0.108
wC 0.026 0.026 0.026 0.026 0.026 0.026 0.026 0.026 0.026
T/K 478.71 478.77 481.25 483.68 483.74 486.23 488.66 493.65 498.58
P/bar 75 75 78 82 82 85 88 95 101
wA 0.866 0.866 0.866 0.857 0.857 0.857 0.857 0.857 0.857
wB 0.108 0.108 0.108 0.096 0.096 0.096 0.096 0.096 0.096
wC 0.026 0.026 0.026 0.047 0.047 0.047 0.047 0.047 0.047
T/K 502.27 508.62 513.64 456.17 458.67 458.69 461.19 461.22 463.69
P/bar 108 114 121 115 118 118 122 121 125
continued
____________________________________________________________________________________
continued
wA 0.857 0.857 0.857 0.857 0.857 0.857 0.857 0.838 0.838
wB 0.096 0.096 0.096 0.096 0.096 0.096 0.096 0.101 0.101
wC 0.047 0.047 0.047 0.047 0.047 0.047 0.047 0.060 0.060
T/K 463.71 466.21 468.74 471.19 473.72 476.20 478.74 437.40 438.42
P/bar 125 127 131 134 137 140 143 153 154
wA 0.838 0.838 0.838 0.838 0.838
wB 0.101 0.101 0.101 0.101 0.101
wC 0.060 0.060 0.060 0.060 0.060
T/K 439.41 440.35 441.46 442.42 443.37
P/bar 155.5 156.5 158 159 160

−1 −1 −1
Characterization: Mn/kg.mol = 93, Mw/kg.mol = 101.4, Mz/kg.mol = 111.9,
BASF AG, Germany

wA 0.839 0.839 0.839 0.839 0.839 0.839 0.839 0.839 0.839
wB 0.108 0.108 0.108 0.108 0.108 0.108 0.108 0.108 0.108
wC 0.053 0.053 0.053 0.053 0.053 0.053 0.053 0.053 0.053
T/K 471.05 473.61 476.07 478.58 483.57 488.58 493.56 503.56 513.53
P/bar 25 29 33 37 44 52 59 73 87
wA 0.828 0.828 0.828 0.828 0.828 0.828 0.828 0.828 0.828
wB 0.098 0.098 0.098 0.098 0.098 0.098 0.098 0.098 0.098
wC 0.074 0.074 0.074 0.074 0.074 0.074 0.074 0.074 0.074
T/K 456.20 458.69 458.86 461.19 463.69 463.85 468.80 473.81 478.77
P/bar 23 27 27 31 35 35 43 50 58
wA 0.828 0.828 0.828 0.828 0.828 0.828 0.799 0.799 0.799
wB 0.098 0.098 0.098 0.098 0.098 0.098 0.099 0.099 0.099
wC 0.074 0.074 0.074 0.074 0.074 0.074 0.102 0.102 0.102
T/K 483.76 488.74 493.76 498.64 503.67 508.70 438.58 441.09 443.57
P/bar 65 72 79 86 92 99 23 27 32
wA 0.799 0.799 0.799 0.799 0.799 0.799 0.799 0.799 0.799
wB 0.099 0.099 0.099 0.099 0.099 0.099 0.099 0.099 0.099
wC 0.102 0.102 0.102 0.102 0.102 0.102 0.102 0.102 0.102
T/K 443.65 448.62 453.63 458.59 463.61 468.58 473.61 478.63 483.57
P/bar 30 37 45 53 61 68 75 83 90
wA 0.799 0.799 0.799 0.799 0.799
wB 0.099 0.099 0.099 0.099 0.099
wC 0.102 0.102 0.102 0.102 0.102
T/K 488.55 493.59 498.56 503.56 508.57
P/bar 97 104 111 117 124
____________________________________________________________________________________
Polymer (B): polystyrene 1985MC2

Dow Chemical Company
T/K = 311.1
wA = 0.296, wB = 0.050, wC = 0.654.
____________________________________________________________________________________
____________________________________________________________________________________
9.1 0.258 0.003 0.739 0.199 0.158 0.643
____________________________________________________________________________________
Polymer (B): polysulfone 2003ZH1

Characterization: Mn/kg.mol−1 = 36.1, Mw/kg.mol−1 = 66.5, by GPC using PS
standards, Polymer Products, Inc., Ontario, NY
wA 0.8865 0.8865 0.8865 0.8865 0.8865 0.8865 0.8822 0.8822 0.8822
wB 0.0150 0.0150 0.0150 0.0150 0.0150 0.0150 0.0200 0.0200 0.0200
wC 0.0985 0.0985 0.0985 0.0985 0.0985 0.0985 0.0978 0.0978 0.0978
T/K 299.2 323.3 348.5 373.3 398.4 424.5 297.1 323.5 347.2
P/MPa 23.93 29.34 34.60 39.21 44.02 47.95 13.89 20.64 26.23
wA 0.8822 0.8822 0.8822 0.8780 0.8780 0.8780 0.8780 0.8780 0.8780
wB 0.0200 0.0200 0.0200 0.0246 0.0246 0.0246 0.0246 0.0246 0.0246
wC 0.0978 0.0978 0.0978 0.0974 0.0974 0.0974 0.0974 0.0974 0.0974
T/K 372.7 399.4 425.4 301.2 323.2 345.6 372.4 399.2 425.0
P/MPa 32.25 37.93 42.66 26.39 30.78 35.73 40.57 45.07 49.06
wA 0.8732 0.8732 0.8732 0.8732 0.8732 0.8732 0.8710 0.8710 0.8710
wB 0.0301 0.0301 0.0301 0.0301 0.0301 0.0301 0.0321 0.0321 0.0321
wC 0.0967 0.0967 0.0967 0.0967 0.0967 0.0967 0.0969 0.0969 0.0969
T/K 303.1 320.0 347.8 372.1 397.0 424.3 296.4 324.8 349.4
P/MPa 38.63 38.64 43.79 47.52 50.90 53.85 36.29 40.41 43.71
wA 0.8710 0.8710 0.8710 0.8668 0.8668 0.8668 0.8668 0.8668 0.8668
wB 0.0321 0.0321 0.0321 0.0366 0.0366 0.0366 0.0366 0.0366 0.0366
wC 0.0969 0.0969 0.0969 0.0966 0.0966 0.0966 0.0966 0.0966 0.0966
T/K 375.5 400.0 426.3 298.6 323.6 348.6 373.8 398.8 423.7
P/MPa 47.35 50.68 53.63 13.79 20.94 27.45 33.14 38.42 42.95
continued
____________________________________________________________________________________
continued
wA 0.8608 0.8608 0.8608 0.8608 0.8608 0.8608 0.8550 0.8550 0.8550
wB 0.0444 0.0444 0.0444 0.0444 0.0444 0.0444 0.0496 0.0496 0.0496
wC 0.0948 0.0948 0.0948 0.0948 0.0948 0.0948 0.0954 0.0954 0.0954
T/K 308.3 321.7 346.9 372.2 398.6 426.0 299.2 323.2 348.9
P/MPa 22.97 26.31 31.99 37.18 42.43 46.84 40.37 42.96 46.06
wA 0.8550 0.8550 0.8550
wB 0.0496 0.0496 0.0496
wC 0.0954 0.0954 0.0954
T/K 374.8 400.8 425.3
P/MPa 49.24 52.00 54.91
Comments: Densities are given in Chapter 6.
Polymer (B): poly(vinyl ethyl ether) 1992KIA, 1994KIA

Characterization: Mw/kg.mol−1 = 3.8, Scientific Polymer Products, Ontario, NY

wA 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wB 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680 0.680
wC 0.170 0.170 0.170 0.170 0.170 0.170 0.170 0.170 0.170
T/K 300.85 304.15 308.15 313.15 318.15 323.15 327.25 333.15 338.15
P/bar 36.44 37.95 40.15 43.80 47.73 51.74 57.12 61.56 64.54
wA 0.150 0.200 0.200 0.200 0.200 0.200 0.200 0.200 0.250
wB 0.680 0.640 0.640 0.640 0.640 0.640 0.640 0.640 0.600
wC 0.170 0.160 0.160 0.160 0.160 0.160 0.160 0.160 0.150
T/K 343.15 313.15 318.65 323.15 328.15 333.15 338.15 342.75 299.95
P/bar 68.29 52.37 56.36 60.27 66.06 71.24 77.23 82.76 48.94
wA 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250 0.250
wB 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600 0.600
wC 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
T/K 303.15 308.15 313.25 318.45 323.15 328.15 333.15 338.15 342.65
P/bar 51.97 57.29 62.80 69.80 76.30 83.13 89.96 98.23 105.12
wA 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
wB 0.560 0.560 0.560 0.560 0.560 0.560 0.560 0.560 0.560
wC 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.140 0.140
T/K 299.15 303.15 308.25 313.15 318.15 323.15 328.15 333.15 338.15
P/bar 52.40 56.37 62.51 69.37 76.43 84.14 92.71 101.22 112.52
wA 0.300 0.350 0.350 0.350 0.350 0.350 0.350 0.350 0.350
wB 0.560 0.520 0.520 0.520 0.520 0.520 0.520 0.520 0.520
wC 0.140 0.130 0.130 0.130 0.130 0.130 0.130 0.130 0.130
T/K 342.95 302.65 308.65 316.85 318.15 324.35 328.15 332.15 333.65
P/bar 122.06 58.01 66.64 78.60 81.32 95.84 104.43 116.62 120.69
continued
____________________________________________________________________________________
continued
wA 0.350 0.350 0.350 0.400 0.150 0.150 0.150 0.150 0.150
wB 0.520 0.520 0.520 0.480 0.765 0.765 0.765 0.765 0.765
wC 0.130 0.130 0.130 0.120 0.085 0.085 0.085 0.085 0.085
T/K 335.65 338.15 340.15 300.35 307.45 313.15 318.05 323.55 327.95
P/bar 124.60 132.08 136.91 57.65 36.64 41.20 44.32 49.74 51.39
wA 0.150 0.150 0.150 0.200 0.200 0.200 0.200 0.200 0.200
wB 0.765 0.765 0.765 0.720 0.720 0.720 0.720 0.720 0.720
wC 0.085 0.085 0.085 0.080 0.080 0.080 0.080 0.080 0.080
T/K 331.55 338.15 343.25 301.45 303.35 308.15 313.15 319.45 323.25
P/bar 54.23 60.64 64.05 41.33 41.86 44.78 49.74 55.72 58.93
wA 0.200 0.200 0.200 0.200 0.250 0.250 0.250 0.250 0.250
wB 0.720 0.720 0.720 0.720 0.675 0.675 0.675 0.675 0.675
wC 0.080 0.080 0.080 0.080 0.075 0.075 0.075 0.075 0.075
T/K 328.15 333.15 338.15 341.65 299.85 303.25 308.15 312.85 318.35
P/bar 64.16 70.49 76.63 79.91 47.41 50.13 55.72 60.90 67.93
wA 0.250 0.250 0.250 0.250 0.250 0.300 0.300 0.300 0.300
wB 0.675 0.675 0.675 0.675 0.675 0.630 0.630 0.630 0.630
wC 0.075 0.075 0.075 0.075 0.075 0.070 0.070 0.070 0.070
T/K 323.15 331.85 333.25 337.15 343.05 300.65 303.25 308.35 314.95
P/bar 74.04 88.71 90.65 96.95 108.12 53.45 55.61 63.14 73.51
wA 0.300 0.300 0.300 0.300 0.300 0.350 0.350 0.350 0.350
wB 0.630 0.630 0.630 0.630 0.630 0.585 0.585 0.585 0.585
wC 0.070 0.070 0.070 0.070 0.070 0.065 0.065 0.065 0.065
T/K 319.45 323.15 328.15 333.15 338.15 299.45 303.55 308.55 313.15
P/bar 81.32 89.66 101.02 113.34 124.93 54.47 60.25 68.02 80.83
wA 0.350 0.350 0.350 0.350
wB 0.585 0.585 0.585 0.585
wC 0.065 0.065 0.065 0.065
T/K 318.15 323.15 328.15 331.85
P/bar 95.71 110.90 125.35 137.04
____________________________________________________________________________________

related figures
____________________________________________________________________________________
____________________________________________________________________________________
Cellulose acetate
carbon dioxide and 2-propanone 1998KI1
____________________________________________________________________________________
Cellulose acetate butyrate
carbon dioxide and ethanol 1998KI1
____________________________________________________________________________________
Cellulose propionate
____________________________________________________________________________________
Cellulose triacetate
____________________________________________________________________________________
Ethylcellulose
carbon dioxide and ethanol 2004LI2
carbon dioxide and methanol 2004LI2
____________________________________________________________________________________
n-butane and dimethyl ether 1996LE2
n-butane and ethanol 1996LE1
____________________________________________________________________________________
1-butene and ethene 1999CHE
____________________________________________________________________________________
Ethylene/ethyl acrylate copolymer
1-butene and polyethylene 1998LEE
____________________________________________________________________________________
Ethylene/2-ethylhexyl acrylate copolymer
ethene and 2-ethylhexyl acrylate 1996BUB
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
ethene and n-butane 2000KIN
ethene and carbon dioxide 2000KIN
ethene and 1-hexene 2000KIN
ethene and nitrogen 2000KIN
2-methylpropane and 1-hexene 1999PAN
____________________________________________________________________________________
n-butane and dimethyl ether 1997LEE
n-butane and ethanol 1997LEE
____________________________________________________________________________________
n-butane and ethylene/methyl acrylate copolymer 1998LEE
n-butane and ethylene/vinyl alcohol copolymer 1998LEE
1-butene and ethylene/methyl acrylate copolymer 1998LEE
chlorodifluoromethane and ethanol 1992MEI
chlorodifluoromethane and ethanol 1993HA1
chlorodifluoromethane and 2-propanone 1992MEI
chlorodifluoromethane and 2-propanone 1993HA1
ethene and methyl acrylate 1987LUF
____________________________________________________________________________________
propane and 1-butanol 1994LOS
propane and ethanol 1992MEI
propane and ethanol 1993HA1
propane and ethanol 1994LOS
propane and n-hexane 1994LOS
propane and 1-hexene 1994LOS
propane and methanol 1994LOS
propane and 1-propanol 1994LOS
propane and 2-propanone 1992MEI
propane and 2-propanone 1993HA1
____________________________________________________________________________________
carbon dioxide and ethene 2001KEM
carbon dioxide and C6-fraction solvent 1985MCH
ethene and C6-fraction solvent 1985MCH
ethene and 1-butene 1993CHE
ethene and n-hexane 1985MC1
ethene and 1-hexene 1993CHE
methane and C6-fraction solvent 1985MCH
propene and C6-fraction solvent 1985MCH
propene and C6-fraction solvent 1986IRA
propene and 2-methylbutane 1986IRA
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
n-hexane and propene 2001VLI
____________________________________________________________________________________
ethene and vinyl acetate 1980RAE
ethene and vinyl acetate 1983WOH
ethene and vinyl acetate 1992FIN
ethene and vinyl acetate 1996FOL
ethene and vinyl acetate 2000KIN
____________________________________________________________________________________
n-butane and ethylene/methyl acrylate copolymer 1998LEE
____________________________________________________________________________________
Polyamide 8
carbon dioxide and dimethylsulfoxide 1993YEO
____________________________________________________________________________________
Polybutadiene
carbon dioxide and polyisoprene 2003RAM
carbon dioxide and tetrahydrofuran 1994KIA
carbon dioxide and toluene 1994KIA
____________________________________________________________________________________
carbon dioxide and butyl acrylate 1998MC2
____________________________________________________________________________________
carbon dioxide and tetrahydrofuran 2001LI3
____________________________________________________________________________________
Polycarbosilane
carbon dioxide and toluene 1998KIM
____________________________________________________________________________________
carbon dioxide and poly(ethylmethylsiloxane) 2004WAL
____________________________________________________________________________________
Polyethylene
n-butane and carbon dioxide 1994XI2
carbon dioxide and cyclohexane 1993KI1
carbon dioxide and n-pentane 1993KI1
carbon dioxide and n-pentane 1994XI1
carbon dioxide and n-pentane 1997KIR
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
carbon dioxide and n-pentane 2003ZH2
carbon dioxide and toluene 1993KI1
ethanol and propane 1993HA1
ethene and 4-methyl-1-pentene 1992WOH
n-hexane and nitrogen 1988KLE
____________________________________________________________________________________
carbon dioxide and acetonitrile 2003STR
carbon dioxide and acetonitrile/water 2003STR
carbon dioxide and ethyl acetate 2003STR
carbon dioxide and acetonitrile/ethyl acetate 2003STR
____________________________________________________________________________________
carbon dioxide and ethanol 1998MIS
carbon dioxide and ethanol 1999MIS
____________________________________________________________________________________
carbon dioxide and styrene 2001LI1
____________________________________________________________________________________
Poly(2-ethylhexyl acrylate)
carbon dioxide and 2-ethylhexyl acrylate 1998MC2
____________________________________________________________________________________
Poly(ethylmethylsiloxane)
carbon dioxide and poly(dimethylsiloxane) 2004WAL
____________________________________________________________________________________
Polyisoprene
carbon dioxide and polybutadiene 2003RAM
carbon dioxide and polystyrene 1999WAL
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
Poly(perfluoropropylene oxide) acid
sorbitol ester
carbon dioxide and water 1997SIN
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
Polypropylene
carbon dioxide and n-pentane 1999MAR
propane and 1-butanol 1997WH2
propane and ethanol 1997WH2
propane and 1-propanol 1997WH2
____________________________________________________________________________________
ethane and tetrachloromethane 2000MAR
ethane and trichloromethane 2000MAR
____________________________________________________________________________________
Polystyrene
carbon dioxide and cyclohexane 2001TOR
carbon dioxide and cyclohexane 2002LID
carbon dioxide and polyisoprene 1999WAL
carbon dioxide and poly(vinyl methyl ether) 2000RAO
carbon dioxide and styrene 2002WU1
carbon dioxide and styrene 2002WU2
carbon dioxide and toluene 1985MC2
carbon dioxide and toluene 1998KIM
carbon dioxide and toluene 2001LI2
chlorodifluoromethane and toluene 1998TAN
ethane and propane 1987KUM
ethane and toluene 1985MC2
ethane and toluene 1988SEC
____________________________________________________________________________________
Polysulfone
carbon dioxide and tetrahydrofuran 2002ZHA
dimethyl ether and tetrahydrofuran 2004LI1
dimethyl ether and N,N-dimethylformamide 2004LI1
____________________________________________________________________________________
Poly(vinyl acetate)
benzene and carbon dioxide 1988MAS
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________

____________________________________________________________________________________
carbon dioxide and polystyrene 2000RAO
____________________________________________________________________________________
Tetrafluoroethylene/hexafluoropropylene
copolymer
carbon dioxide and sulfur hexafluoride 1999MER
carbon dioxide and trifluoromethane 1999MER
trifluoromethane and sulfur hexafluoride 1999MER
____________________________________________________________________________________
____________________________________________________________________________________
4.5. References
1963EHR Ehrlich, P. and Kurpen, J.J., Phase equilibria of polymer-solvent systems at high pressure
near their critical loci. Polyethylene with n-alkanes, J. Polym. Sci.: Part A, 1, 3217, 1963.
1965CE1 Cernia, E.M. and Mancini, C., A thermodynamic approach to phase equilibria investigation
of polyethylene-ethylene system at high pressure, Kobunshi Kagaku, 22, 797, 1965.
1965CE2 Cernia, E.M. and Mancini, C., A new method for determination of the solubility parameters
of the polyethylene-ethylene pair at high temperature and pressure, Polym. Lett., 3, 1093,
1965.
1965EHR Ehrlich, P., Phase equilibria of polymer-solvent systems at high pressures near their critical
loci. II. Polyethylene-ethylene, J. Polym. Sci.: Part A, 3, 131, 1965.
1965SWE Swelheim, T., De Swaan Arons, J., and Diepen, G.A.M., Fluid phase equilibria in the
system polyethylene-ethene, Recueil, 84, 261, 1965.
1966KON Koningsveld, R., Diepen, G.A.M., and Chermin, H.A.G., Fluid phase equilibria in the
system polyethylene-ethylene II, Recueil, 85, 504, 1966.
1972STE Steiner, R. and Horle, K., Phasenverhalten von Ethylen/Polyethylen-Gemischen unter
hohem Druck, Chemie-Ing. Techn., 44, 1010, 1972.
1975LIN Lindner, A., Untersuchungen von Phasengleichgewichten bei Monomer-Polymer-Systemen,
Dissertation, TH Darmstadt, 1975.
1976LUF Luft, G. and Lindner, A., Zum Einfluss des Polymermolekulargewichts auf das
Phasenverhalten von Gas-Polymer-Systemen unter Hochdruck, Angew. Makromol. Chemie,
56, 99, 1976.
1976SC1 Schröder, E. and Arndt, K.-F., Löslichkeitsverhalten von Makromolekülen in komprimier-
ten Gasen I. Einführung und Messtechnik, Faserforsch. Textiltechn., 27, 135, 1976.
1976SC2 Schröder, E. and Arndt, K.-F., Löslichkeitsverhalten von Makromolekülen in
komprimierten Gasen II. Experimentelle Ergebnisse. Über das Druckverhalten von PVC,
PMMA und PS in fluidem CO2, Faserforsch. Textiltechn., 27, 141, 1976.
1976STE Steiner, R, Entmischungsvorgänge bei Hochdruckreaktionen, Chem.-Ing. Techn., 48, 533,
1976.
1977LIN Lindner, A. and Luft, G., The influence of the polymer mean molecular weight on the phase
behavior of gas-polymer mixtures under high pressure, High Temp.-High Press., 9, 563,
1977.
1979KOB Kobyakov, V.M., Kogan, V.B., Rätzsch, M., and Zernov, V.S., Fazovye ravnovesiya v
smesyakh etilena s nizkomolekulyarnym polietilenom, Plast. Massy, 8, 24, 1979.
1980RAE Rätzsch, M., Findeisen, R., and Sernov, V.S., Untersuchungen zum Phasenverhalten von
Monomer-Polymer-Systemen unter hohem Druck (experimental data by R. Findeisen), Z.
Phys. Chemie, Leipzig, 261, 995, 1980.
1981LOO Loos, Th.W. de, Evenwichten tussen fluide fasen in systemen van lineair polyetheen en
etheen, Proefschrift, TH Delft, 1981.
1981SP1 Spahl, R., Entmischungsverhalten von Ethylen und niedermolekularem Polyethylen unter
hohem Druck, Dissertation, TH Darmstadt, 1981.
1981SP2 Spahl, R. and Luft, G., Entmischungsverhalten von Ethylen und niedermolekularem
Polyethylen, Ber. Bunsenges. Phys. Chem., 85, 379, 1981.
1981WO1 Wohlfarth, C. and Rätzsch, M.T., Berechnungen zum Hochdruckphasengleichgewicht in
Mischungen aus Ethylen und Polyethylen I, Acta Polym., 32, 733, 1981.
1981WO2 Wohlfarth, C., Rätzsch, M.T., and Weber, K., Berechnungen zum Hochdruckphasengleich-
gewicht in Mischungen aus Ethylen und Polyethylen II (experimental data for PE2 by R.
Findeisen and P.Wagner), Acta Polym., 32, 740, 1981.
____________________________________________________________________________________
1982RAE Rätzsch, M.T., Wagner, P., Wohlfarth, C., and Heise, D., High-pressure phase equilibrium
studies in mixtures of ethylene and (ethylene-vinyl acetate) copolymers. Part I. Dependence
on vinyl acetate content of copolymers (Ger.), Acta Polym., 33, 463, 1982.
1982WOH Wohlfarth, C., Wagner, P., Rätzsch, M.T., and Westmeier, S., High-pressure phase
equilibrium studies in mixtures of ethylene and (ethylene-vinyl acetate) copolymers. Part II.
Temperature effect (Ger.), Acta Polym., 33, 468, 1982.
1983ALI Ali, S., Thermodynamic properties of polymer solutions in compressed gases, Z. Phys.
Chem., N. F., 137, 13, 1983.
1983LOO Loos, Th.W. de, Poot, W., and Diepen, G.A.M., Fluid phase equilibriums in the system
polyethylene + ethylene. 1. Systems of linear polyethylene + ethylene at high pressure,
1983RAE Rätzsch, M.T., Wagner, P., Wohlfarth, C., and Gleditzsch, S., Studies of phase equilib-
riums in mixtures of ethylene and ethylene-vinyl acetate copolymers at high pressures. Part
III. Dependence on the molecular weight distribution (Ger.), Acta Polym., 34, 340, 1983.
1983SPA Spahl, R. and Luft, G., Fraktionierungserscheinungen bei der Entmischung von Ethylen-
Polyethylen-Gemischen, Angew. Makromol. Chemie, 115, 87, 1983.
1983WOH Wohlfarth, C. and Rätzsch, M.T., Calculation of high-pressure phase equilibria in mixtures
of ethylene, vinyl acetate, and ethylene-vinyl acetate copolymers, Acta Polym., 34, 255, 1983.
1984FON Fonin, M.F., Saltanova, V.B., Anishchuk, V.V., Evdokimova, T.N., Shvyd'ko, T.I., and
Gordeev, V.K., Solubility of ethylene and its diffusion in freshly prepared high-pressure
polyethylene (Russ.), Plast.Massy, 7, 16, 1984.
1984KOB Kobyakov, V.M. and Zernov, V.S., Solubility of ethylene in polyethylene at high pressures
and temperatures (Russ.), in Sintez, Svoistva, Pererab. Poliolefinov, 1984, 60.
1984WAG Wagner, P., Zum Phasengleichgewicht im System Ethylen + Ethylen-Vinylacetat-
Copolymer unter hohem Druck, Dissertation, TH Leuna-Merseburg, 1984.
1984WOH Wohlfarth, Ch., Wagner, P., Glindemann, D., Völkner, M., and Rätzsch, M.T., High-
pressure phase equilibrium in the system ethylene + vinyl acetate + (ethylene-vinyl acetate)
copolymers (Ger.), Acta Polym., 35, 498, 1984.
1985MC1 McClellan, A.K. and McHugh, M.A., Separating polymer solutions using high pressure
lower critical solution temperature (LCST) phenomena, Polym. Eng. Sci., 25, 1088, 1985.
1985MC2 McClellan, A.K., Bauman, E.G., and McHugh, M.A., Polymer solution-supercritical fluid
phase behavior, in Supercritical Fluid Technology, Elsevier Sci. Publ., Amsterdam, 1985,
162.
1985MCH McHugh, M.A. and Guckes, T.L., Separating polymer solutions with supercritical fluids,
1986IRA Irani, C.A. and Cozewith, C., Lower critical solution temperature behavior of ethylene
propylene copolymers in multicomponent solvents, J. Appl. Polym. Sci., 31, 1879, 1986.
1986SPA Spahl, R. and Luft, G., Einfluss von Molmasse und Molekülverzweigungen auf das Entmi-
schungsverhalten von Ethylen/Polyethylen-Systemen unter Hochdruck, Ber. Bunsenges.
Phys. Chem., 86, 621, 1986.
1987KUM Kumar, S.K., Chhabria, S.P., Reid, R.C., and Suter, U.W., Solubility of polystyrene in
supercritical fluids, Macromolecules, 20, 2550, 1987.
1987LUF Luft, G. and Subramanian, N.S., Phase behavior of mixtures of ethylene, methyl acrylate,
and copolymers under high pressures, Ind. Eng. Chem. Res., 26, 750, 1987.
1988KLE Kleintjens, L.A., van der Haegen, R., van Opstal, L., and Koningsveld, R., Mean-field
lattice-gas modelling of supercritical phase behavior, J. Supercrit. Fluids, 1, 23, 1988.
1988MAS Masuoka, H., Takishima, S., and Wang, N.-H., Supercritical fluid extraction of high-boiling
materials from polymers, Rep. Asahi Glass Found. Ind. Technol., 52, 275, 1988.
1988SA1 Saraf, V.P. and Kiran, E., Solubility of polystyrenes in supercritical fluids, J. Supercrit.
Fluids, 1, 37, 1988.
1988SA2 Saraf, V.P. and Kiran, E., Supercritical fluid-polymer interactions. Phase equilibrium data
for solutions of polystyrenes in n-butane and n-pentane, Polymer, 29, 2061, 1988.
____________________________________________________________________________________
1988SEC Seckner, A.J., McClellan, A.K., and McHugh, M.A., High-pressure solution behavior of the
polystyrene-toluene-ethane system, AIChE-J., 34, 9, 1988.
1988WAL Walsh, D.J. and Dee, G.T., Calculations of the phase diagrams of polyethylene dissolved in
supercritical solvents, Polymer, 29, 656, 1988.
1989DAN Daneshwar, M. and Gulari, E., Partition coefficients of poly(ethylene glycol) in supercritical
carbon dioxide, ACS Symp. Ser., 406, 72, 1989.
1989KIR Kiran, E., Saraf, V.P., and Sen, Y.L., Solubility of polymers in supercritical fluids, Int. J.
Thermophys., 10, 437, 1989.
benzene in poly(vinyl acetate) and polystyrene, Sekiyu Gakkaishi, 32, 67, 1989.
1989WIL Will, B., Löslichkeit von Ethylen-Vinylacetat-Copolymeren in ethylenhaltigen Mischlö-
sungsmitteln, Dissertation, Johannes-Gutenberg Universität Mainz, 1989.
1990BEC Beckmann, E.J., Koningsveld, R., and Porter, R.S., Mean-field lattice equations of state. 3.
Modeling the phase behavior of supercritical gas-polymer mixtures, Macromolecules, 23,
2321, 1990.
1990DAN Daneshvar, M., Kim, S., and Gulari, E., High-pressure phase equilibria of poly(ethylene
glycol)-carbon dioxide systems, J. Phys. Chem., 94, 2124, 1990.
model (experimental data by Th.W. de Loos from M.Sc. Thesis by H.A.J. Kennis, TU Delft
1987), Chem. Eng. Sci., 45, 1875, 1990.
benzene in poly(vinyl acetate) and polystyrene. Part 2, Sekiyu Gakkaishi, 33, 304, 1990.
1991FIN Finck, U., Phasengleichgewichte in Monomer + Copolymer - Systemen, Diploma paper,
1991MEI Meilchen, M.A., Hasch, B.M., and McHugh, M.A., Effect of copolymer composition on the
phase behavior of mixtures of poly(ethylene-co-methyl acrylate) with propane and chloro-
difluoromethane, Macromolecules, 24, 4874, 1991.
1991NIE Nieszporek, B., Untersuchungen zum Phasenverhalten quasibinärer und quasiternärer
Mischungen aus Polyethylen, Ethylen-Vinylacetat-Copolymeren, Ethylen und Vinylacetat
unter Druck, Dissertation, TH Darmstadt, 1991.
1991TOM Tom, J.W. and Debenedetti, P.G., Formation of bioerodible polymeric microspheres and
microparticles by rapid expansion of supercritical solutions, Biotechnol.Prog., 7, 403, 1991.
1991WAT Watkins, J.J., Krukonis, V.J., Condo, P.D., Pradhan, D., and Ehrlich, P., Fractionation of
high density polyethylene in propane by isothermal pressure profiling and isobaric
temperature profiling, J. Supercrit. Fluids, 4, 24, 1991.
1992CH1 Chen, S.-J. and Radosz, M., Density-tuned polyolefin phase equilibria 1, Macromolecules,
25, 3089, 1992.
1992CH2 Chen, S.-J., Economou, I.G., Radosz, M., Density-tuned polyolefin phase equilibria 2,
1992CO3 Condo, P.D., Colman, E.J., and Ehrlich, P., Phase equilibria in linear polyethylene with
supercritical propane, Macromolecules, 25, 750, 1992.
1992FIN Finck, U., Wohlfarth, Ch., and Heuer, T., Calculation of high pressure phase equilibria of
mixtures of ethylene, vinyl acetate and an (ethylene-vinyl acetate) copolymer, Ber.
1992HAS Hasch, B.A., Meilchen, M.A., Lee, S.-H., and McHugh, M.A., High-pressure phase
behavior of mixtures of poly(ethylene-co-methyl acrylate) with low-molecular weight
hydrocarbons, J. Polym. Sci., Part B: Polym. Phys., 30, 1365, 1992.
1992KIA Kiamos, A.A., M.Sc. Thesis, High-pressure phase-equilibrium studies of polymer-solvent-
supercritical fluid mixtures, John Hopkins University, 1992.
____________________________________________________________________________________
1992LUF Luft, G. and Wind, R.W., Phasenverhalten von Mischungen aus Ethylen und Ethylen-
Acrylsäure-Copolymeren unter hohem Druck, Chem.-Ing.-Techn., 64, 1114, 1992.
1992MEI Meilchen, M.A., Hasch, B.M., Lee, S.-H., and McHugh, M.A., Poly(ethylene-co-methyl
acrylate)-solvent-cosolvent phase behaviour at high pressures, Polymer, 33, 1922, 1992.
1992WIN Wind, R.W., Untersuchungen zum Phasenverhalten von Mischungen aus Ethylen, Acrylsäure
und Ethylen-Acrylsäure-Copolymer unter hohem Druck, Dissertation, TH Darmstadt, 1992.
1992WOH Wohlfarth, C., Finck, U., Schultz, R., and Heuer, T., Investigation of phase equilibria in
mixtures composed of ethene, 1-butene, 4-methyl-1-pentene and a polyethylene wax,
Angew. Makromol. Chem., 198, 91, 1992.
1993CHE Chen, S.-J., Economou, I.G., and Radosz, M., Phase behavior of LCST and UCST solutions
of branchy copolymers, Fluid Phase Equil., 83, 391, 1993.
1993DEB Debenedetti, P.G., Tom, J.W., Yeo, S.-D., and Lim, G.-B., Application of supercritical
fluids for the production of sustained delivery devices, J. Controlled Release, 24, 27, 1993.
1993DIX Dixon, D.J. and Johnston, K.P., Formation of microporous polymer fibers and fibrils by
precipitation with a compressed fluid antisolvent, J. Appl. Polym. Sci., 50, 1929, 1993.
1993GRE Gregg, C.J., Chen, S.-J., Stein, F.P., and Radosz, M., Phase behavior of binary ethylene-
propylene copolymer solutions in sub- and supercritical ethylene and propylene, Fluid
Phase Equil., 83, 375, 1993.
1993HA1 Hasch, B.M., Meilchen, M.A., Lee, S.-H., and McHugh, M.A., Cosolvency effects on
copolymer solutions at high pressure, J. Polym. Sci., Part B: Polym. Phys., 31, 429, 1993.
1993HA2 Hasch, B.M., Lee, S.-H., and McHugh, M.A., The effect of copolymer architecture on
solution behavior, Fluid Phase Equil., 83, 341, 1993.
1993HA3 Hasch, B.M., Lee, S.-H., McHugh, M.A., Watkins, J.J., and Krukonis, V.J., The effect of
backbone structure on the cloud point behaviour of polyethylene-ethane and polyethylene-
propane mixtures (experimental data by M.A. McHugh), Polymer, 34, 2554, 1993.
1993HA4 Haschets, C.W. and Shine, A.D., Phase behavior of polymer-supercritical chlorodifluoro-
methane solutions, Macromolecules, 26, 5052, 1993.
1993HOE Hoefling, T.A., Newman, D.A., Enick, R.M., and Beckman, E.J., Effect of structure on the
cloud-point curves of silicone-based amphiphiles in supercritical carbon dioxide, J.
1993KI1 Kiran, E., Zhuang, W., and Sen, Y.L., Solubility and demixing of polyethylene in super-
critical binary fluid mixtures: Carbon dioxide-cyclohexane, carbon dioxide-toluene, carbon
dioxide-pentane, J. Appl. Polym. Sci., 47, 895, 1993.
1993KI2 Kiran, E., Xiong, Y., and Zhunag, W., Modeling polyethylene solutions in near and super-
critical fluids using the Sanchez-Lacombe model, J. Supercrit. Fluids, 6, 193, 1993.
1993PRA Pratt, J.A., Lee, S.-H., and McHugh, M.A., Supercritical fluid fractionation of copolymers
based on chemical composition and molecular weight, J. Appl. Polym. Sci., 49, 953, 1993.
1993YEO Yeo, S.-D., Debenedetti, P.G., Radosz, M., and Schmidt, H.-W., Supercritical antisolvent
process for substituted para-linked aromatic polyamines: phase equilibrium and morphology
study, Macromolecules, 26, 6207, 1993.
1994CHE Chen, C.-K., Duran, M.A., and Radosz, M., Supercritical antisolvent fractionation of
polyethylene simulated with multistage algorithm and SAFT equation of state: staging leads
to high selectivity enhancements for light fractions, Ind. Eng. Chem. Res., 33, 306, 1994.
1994GR1 Gregg, C.J., Stein, P.S., and Radosz, M., Phase behavior of telechelic polyisobutylene (PIB)
in subcritical and supercritical fluids I., Macromolecules, 27, 4972, 1994.
1994GR2 Gregg, C.J., Stein, P.S., and Radosz, M., Phase behavior of telechelic polyisobutylene (PIB)
in subcritical and supercritical fluids II., Macromolecules, 27, 4981, 1994.
1994GR3 Gregg, C.J., Stein, F.P., and Radosz, M., Phase behavior of telechelic polyisobutylene in
subcritical and supercritical fluids 3., J. Phys. Chem., 98, 10634, 1994.
1994GR4 Gregg, C.J., Phase equilibria of supercritical fluid solutions of associating polymers in
nonpolar and polar fluids, Ph.D. Thesis, Lehigh University, Bethlehem, 1994.
____________________________________________________________________________________
1994GR5 Gregg, C.J., Stein, F.P., Morgan, C.K., and Radosz, M., A variable-volume optical pressure-
volume-temperature cell for high-pressure cloud points, densities, and IR-spectra, applicable
to supercritical fluid solutions of polymers up to 2 kbar, J. Chem. Eng. Data, 39, 219, 1994.
1994KIA Kiamos, A.A. and Donohue, M.D., The effect of supercritical carbon dioxide on polymer-
solvent mixtures, Macromolecules, 27, 357, 1994.
1994KI2 Kiran, E., Xiong, Y., and Zhuang, W., Effect of polydispersity on the demixing pressures of
polyethylene in near- or supercritical alkanes, J. Supercrit. Fluids, 7, 283, 1994.
1994LE1 Lee, S.-H., LoStracco, M.A., Hasch, B.M., and McHugh, M.A., Solubility of poly(ethylene-
co-acrylic acid) in low molecular weight hydrocarbons, J. Phys. Chem., 98, 4055, 1994.
1994LE2 Lee, S.-H., LoStracco, A., and McHugh, M.A., High pressure, molecular weight-dependent
behavior of (co)polymer-solvent mixtures, Macromolecules, 27, 4652, 1994.
1994LEL Lele, A.K. and Shine, A.D., Effect of RESS dynamics on polymer morphology, Ind. Eng.
Chem. Res., 33, 1476, 1994.
1994MUR Muralidharan, V., Donohue, M.D., Argyropoulos, J., and Nielsen, K.A., Determination of
phase boundaries from pressure-volume data for polymer-solvent-carbon dioxide mixtures,
1994PRA Pradhan, D., Chen, C., and Radosz, M., Fractionation of polystyrene with supercritical
propane and ethane: characterisation, semibatch solubility experiments, and SAFT simula-
tions, Ind. Eng. Chem. Res., 33, 1984, 1994.
1994SUR Suresh, S.J., Enick, R.M., and Beckman, E.J., Phase behavior of nylon-6/trifluoro-
ethanol/carbon dioxide mixtures, Macromolecules, 27, 348, 1994.
1994XI1 Xiong, Y. and Kiran, E., Prediction of high-pressure phase behaviour in polyethylene/n-
pentane/carbon dioxide ternary system with the Sanchez-Lacombe model, Polymer, 35,
4408, 1994.
1994XI2 Xiong, Y. and Kiran, E., High pressure phase behavior in polyethylene/n-butane binary and
polyethylene/n-butane/CO2 ternary systems, J. Appl. Polym. Sci., 53, 1179, 1994.
1995CHE Chen, S., Banaszak, M., and Radosz, M., Phase behavior of poly(ethylene-1-butene) in
subcritical and supercritical propane, Macromolecules, 28, 1812, 1995.
1995HAS Hasch, B.M. and McHugh, M.A., Calculating poly(ethylene-co-acrylic acid)-solvent phase
behavior with the SAFT equation of state, J. Polym. Sci.: Part B: Polym. Phys., 33, 715,
1995.
1995LOO Loos, Th.W. de, Poot, W., and Lichtenthaler, R.N., The influence of branching on high-
pressure vapor-liquid equilibria in systems of ethylene and polyethylene (experimental data
by Th.W. de Loos), J. Supercrit. Fluids, 8, 282, 1995.
1995MAW Mawson, S., Johnston, K.P., Combes, J.R., and DeSimone, J.M., Formation of poly(1,1,2,2-
tetrahydroperfluorodecyl acrylate) submicron fibers and particles from supercritical carbon
dioxide solutions, Macromolecules, 28, 3182, 1995.
1995PRA Pradhan, D. and Ehrlich, P., Morphologies of microporous polyethylene and polypropylene
crystallized from solution in supercritical propane, J. Polym. Sci.: Part B: Polym. Phys., 33,
1053, 1995.
1995TUM Tuminello, W.H., Dee, G.T., and McHugh, M.A., Dissolving perfluoropolymers in
supercritical carbon dioxide, Macromolecules, 28, 1506, 1995.
1995XI1 Xiong, Y. and Kiran, E., Miscibility, density and viscosity of poly(dimethylsiloxane) in
supercritical carbon dioxide, Polymer, 36, 4817, 1995.
1995XI2 Xiong, Y. and Kiran, E., Comparison of Sanchez-Lacombe and SAFT model in predicting
solubility of polyethylene in high-pressure fluids, J. Appl. Polym. Sci., 55, 1805, 1995.
1996ALB Albrecht, K.L., Stein, F.P., Han, S.J., Gregg, C.J., and Radosz, M., Phase equilibria of
saturated and unsaturated polyisoprene in sub- and supercritical ethane, ethylene, propane,
propylene, and dimethyl ether, Fluid Phase Equil., 117, 84, 1996.
____________________________________________________________________________________
1996BUB Buback, M., Busch, M., Dietzsch, H., Dröge, T., and Lovis, K., Cloud-point curves in
ethylene-acrylate-poly(ethylene-co-acrylate) systems, in High Pressure Chemical Enginee-
ring, von Rohr, Ph.R., Trepp, Ch., Eds., Elsevier Sci. B.V., 1996, 175.
1996BYU Byun, H.-S., Hasch, B.M., McHugh, M.A., Mähling, F.-O., Busch, M., and Buback, M.,
Poly(ethylene-co-butyl acrylate). Phase behavior in ethylene compared to the poly(ethylene-
co-methyl acrylate)-ethylene system and aspects of copolymerization kinetics at high
pressures, Macromolecules, 29, 1625, 1996.
1996FOL Folie, B., Gregg, C., Luft, G., and Radosz, M., Phase equilibria of poly(ethylene-co-vinyl
acetate) copolymers in subcritical and supercritical ethylene and ethylene-vinyl acetate
mixtures, Fluid Phase Equil., 120, 11, 1996.
1996HAR Harrison, K.L., Johnston, K.P., and Sanchez, I.C., Effect of surfactants on the interfacial
tension between supercritical carbon dioxide and polyethylene glycol, Langmuir, 12, 2637,
1996.
1996HEU Heukelbach, D., Einfluss der Polydispersität von Polyethylen auf das Phasenverhalten mit
überkritischem Ethen, Dissertation, TH Darmstadt, 1996.
1996KIM Kim, J.-H., Paxton, T.E., and Tomasko, D.L., Microencapsulation of Naproxen using rapid
expansion of supercritical solutions, Biotechnol. Progr., 12, 650, 1996.
1996LE1 Lee, S.-H., Hasch, B.M., and McHugh, M.A., Calculating copolymer solution behavior with
statistical associating fluid theory, Fluid Phase Equil., 117, 61, 1996.
1996LE2 Lee, S.-H., LoStracco, M.A., and McHugh, M.A., Cosolvent effect on the phase behavior of
poly(ethylene-co-acrylic acid)-butane mixtures, Macromolecules, 29, 1349, 1996.
1996LE3 Lee, S.-H. and McHugh, M.A., Influence of chain architecture on high-pressure co-polymer
solution behavior: Experiments and modeling, in High Pressure Chemical Engineering, von
Rohr, Ph.R., Trepp, Ch., Eds., Elsevier Sci. B.V., 1996, 11.
1996MER Mertdogan, C.A., Byun, H.-S., McHugh, M.A., and Tuminello, W.H., Solubility of poly
(tetrafluoroethylene-co-19 mol% hexafluoropropylene) in supercritical CO2 and halogenated
supercritical solvents, Macromolecules, 29, 6548, 1996.
1996MU1 Müller, C., Untersuchungen zum Phasenverhalten von quasibinären Gemischen aus Ethylen
und Ethylen-Copolymeren, Dissertation, Univ. Karlsruhe (TH), 1996.
1996MU2 Müller, C. and Oellrich, L.R., The influence of different inhibitors and ethylenes of different
origin on the location of cloud points due to thermal polymerization of ethylene, Acta
Polym., 47, 404, 1996.
1996PAR Parks, K.L. and Beckman, E.J., Generation of microcellular polyurethane foams via
polymerization in carbon dioxide. I. Phase behavior of polyurethane precursors, Polym.
Eng. Sci., 36, 2404, 1996.
1996RIN Rindfleisch, F., DiNoia, T.P., and McHugh, M.A., Solubility of polymers and copolymers
in supercritical CO2, J. Phys. Chem., 100, 15581, 1996.
1997BUN Bungert, B., Sadowski, G., and Arlt, W., Supercritical antisolvent fractionation:
measurements in the systems monodisperse and bidisperse polystyrene-cyclohexane-carbon
dioxide, Fluid Phase Equil., 139, 349, 1997.
1997DIN DiNoia, T.P., McHugh, M.A., Cocchiaro, J.E., and Morris, J.B., Solubility and phase
behavior of PEP binders in supercritical carbon dioxide, Waste Managment, 17, 151, 1997.
1997HAN Han, S.J., Gregg, C.J., and Radosz, M., How the solute polydispersity affects the cloud-
point and coexistence pressures in propylene and ethylene solutions of alternating
poly(ethylene-co-propylene), Ind. Eng. Chem. Res., 36, 5520, 1997.
1997KIR Kiran, E. and Zhuang, W., Miscibility and phase separation of polymers in near- and super-
critical fluids, ACS Symp. Ser., 670, 2, 1997.
1997LEE Lee, S.-H. and McHugh, M.A., Phase behaviour studies with poly(ethylene-co-methacrylic
acid) at high pressures, Polymer, 38, 1317, 1997.
1997LEP Lepilleur, C., Beckman, E.J., Schonemann, H., and Krukonis, V.J., Effect of molecular
architecture on the phase behavior of fluoroether-functional graft copolymers in
supercritical CO2, Fluid Phase Equil., 134, 285, 1997.
____________________________________________________________________________________
1997MER Mertdogan, C.A., DiNoia, T.P., and McHugh, M.A., Impact of backbone architecture on the
solubility of fluoropolymers in supercritical CO2 and halogenated supercritical solvents,
1997SIN Singley, E.J., Liu, W., and Beckman, E.J., Phase behavior and emulsion formation of novel
fluoroether amphiphiles in CO2, Fluid Phase Equil., 128, 199, 1997.
1997WEI Weidner, E., Wiesmet, V., Knez, Z., and Skerget, M., Phase equilibrium (solid-liquid-gas)
in polyethyleneglycol-carbon dioxide systems, J. Supercrit. Fluids, 10, 139, 1997.
1997WH1 Whaley, P.D., Winter, H.H., and Ehrlich, P., Phase equilibria of polypropylene with
compressed propane and related systems. 1. Isotactic and atactic polypropylene with
propane and propylene, Macromolecules, 30, 4882, 1997.
1997WH2 Whaley, P.D., Winter, H.H., and Ehrlich, P., Phase equilibria of polypropylene with
compressed propane and related systems. 2. Fluid phase equilibria of polypropylene with
propane containing alcohols as cosolvents and of some other branched polyolefins with
propane, Macromolecules, 30, 4887, 1997.
1998CHA Chang, S.-H., Park, S.-C., and Shim, J.-J., Phase equilibria of supercritical fluid-polymer
systems, J. Supercrit. Fluids, 13, 113, 1998.
1998DIM Dimitrov, K., Boyadzhiev, L., Tufeu, R., Cansell, F., and Barth, D., Solubility of
poly(ethylene glycol) nonylphenyl ether in supercritical carbon dioxide, J. Supercrit. Fluids,
14, 41, 1998.
1998HAN Han, S.J., Lohse, D.J., Radosz, M., and Sperling, L.H., Short chain branching effect on the
cloud-point pressures of ethylene copolymers in subcritical and supercritical propane,
1998HEU Heukelbach, D. and Luft, G., Critical points of mixtures of ethylene and polyethylene wax
under high pressure, Fluid Phase Equil., 146, 187, 1998.
1998HOR Horst, R., Wolf, B.A., Kinzl, M., Luft, G., and Folie, B., Shear influences on the solubility
of LDPE in ethene, J. Supercrit. Fluids, 14, 49, 1998.
1998KIM Kim, S., Kim, Y.-S., and Lee, S.-B., Phase behaviors and fractionation of polymer solutions
in supercritical carbon dioxide, J. Supercrit. Fluids, 13, 99, 1998.
1998KI1 Kiran, E. and Pöhler, H., Alternative solvents for cellulose derivatives. Miscibility and
density of cellulosic polymers in carbon dioxide + acetone and carbon dioxide + ethanol
binary fluid mixtures, J. Supercrit. Fluids, 13, 135, 1998.
1998KI2 Kiran, E. and Xiong, Y., Miscibility of isotactic polypropylene in n-pentane and n-pentane
+ carbon dioxide mixtures at high pressures, J. Supercrit. Fluids, 11, 173, 1998.
1998KOA Koak, N., Loos, Th.W. de, and Heidemann, R.A., Upper-critical-solution-temperature
behavior of the system polystyrene + methylcyclohexane. Influence of CO2 on the liquid-
liquid equilibria, Fluid Phase Equil., 145, 311, 1998.
1998LEE Lee, S.-H. and McHugh, M.A., Phase behavior of copolymer-copolymer-solvent mixtures at
1998LUN Luna-Barcenas, G., Mawson, S., Takishima, S., DeSimone, J.M., Sanchez, I.C., and
Johnston, K.P., Phase behavior of poly(1,1-dihydroperfluorooctyl acrylate) in supercritical
carbon dioxide, Fluid Phase Equil., 146, 325, 1998.
1998MC1 McHugh, M.A., Mertdogan, C.A., DiNoia, T.P., Anolick, C., Tuminello, W.H., and
Wheland, R., Impact of melting temperature on poly(tetrafluoroethylene-co-hexafluoro-
propylene) solubility in supercritical fluid solvents, Macromolecules, 31, 2252, 1998.
1998MC2 McHugh, M.A., Rindfleisch, F., Kuntz, P.T., Schmaltz, C., and Buback, M., Cosolvent
effect of alkyl acrylates on the phase behaviour of poly(alkyl acrylates)-supercritical CO2
mixtures, Polymer, 39, 6045, 1998.
1998MIS Mishima, K., Tokuyasu, T., Matsuyama, K., Komorita, N., Enjoji, T., and Nagatani, M.,
Solubility of polymer in the mixtures containing supercritical carbon dioxide and
antisolvent, Fluid Phase Equil., 144, 299, 1998.
____________________________________________________________________________________
1998ONE O'Neill, M.L., Cao, Q., Fang, C.M., Johnston, K.P., Wilkinson, S.P., Smith, C.D., Kersch-
ner, J.L., and Jureller, S.H., Solubility of homopolymers and copolymers in carbon dioxide,
Ind. Eng. Chem. Res., 37, 3067, 1998.
1998TAN Tan, C.-S. and Chang, W.-W., Precipitation of polystyrene from toluene with HFC-134a by
the GAS process, Ind. Eng. Chem. Res., 37, 1821, 1998.
1998ZHU Zhuang, W. and Kiran, E., Kinetics of pressure-induced phase separation (PIPS) from
polymer solutions by time resolved light scattering. Polyethylene + n-pentane, Polymer, 39,
2903, 1998.
1999BUN Bungert, B., Komplexe Phasengleichgewichte von Polymerlösungen, Dissertation, TU
Berlin, 1999.
1999CHE Chen, A.-Q. and Radosz, M., Phase equilibria of dilute poly(ethylene-co-1-butene)
solutions in ethylene, 1-butene, and 1-butene+ethylene, J. Chem. Eng. Data, 44, 854, 1999.
1999DIE Dietzsch, H., Hochdruck-Copolymerisation von Ethen und (Meth)Acrylsäureestern,
Dissertation, University Goettingen, 1999.
1999GOU Gourgouillon, D. and Nunes da Ponte, M., High pressure phase equilibria for poly(ethylene
glycol) + CO2: experimental results and modeling, Phys. Chem. Chem. Phys., 1, 5369, 1999.
1999KIN Kinzl, M., Einfluss der Zugabe von Inertkomponenten auf die Phasengleichgewichte von
Copolymerlösungen in überkritischem Ethen, Dissertation, TH Darmstadt, 1999.
1999KOA Koak, N., Visser, R.M., and Loos, Th.W. de, High-pressure phase behavior of the systems
polyethylene + ethylene and polybutene + 1-butene, Fluid Phase Equil., 158-160, 835,
1999.
1999LIJ Li, J., Zhang, M., and Kiran, E., Dynamics of pressure-induced phase separation in polymer
solutions. The dependence of the demixing pressure on the rate of pressure quench in
solutions of poly(dimethylsiloxane) in supercritical carbon dioxide, Ind. Eng. Chem. Res.,
38, 4486, 1999.
1999LO1 Lora, M. and McHugh, M.A., Phase behavior and modeling of the poly(methyl
methacrylate)-CO2-methyl methacrylate system, Fluid Phase Equil., 157, 285, 1999.
1999LO2 Lora, M., Rindfleisch, F., and McHugh, M.A., Influence of the alkyl tail on the solubility of
poly(alkyl acrylates) in ethylene and CO2 at high pressures: experiments and modeling, J.
Appl. Polym. Sci., 73, 1979, 1999.
1999MAR Martin, T.M., Lateef, A.A., and Roberts, C.B., Measurement and modeling of cloud point
behavior for polypropylene/n-pentane and polypropylene/n-pentane/carbon dioxide
mixtures at high pressures, Fluid Phase Equil., 154, 241, 1999.
1999MER Mertdogan, C.A., McHugh, M.A., and Tuminello, W.H., Cosolvency effect of SF6 on the
solubility of poly(tetrafluoroethylene-co-19 mol% hexafluoropropylene) in supercritical
CO2 and CHF3, J. Appl. Polym. Sci., 74, 2039, 1999.
1999MIS Mishima, K., Matsuyama, K., and Nagatani, M., Solubilities of poly(ethylene glycol)s in the
mixtures of supercritical carbon dioxide and cosolvent, Fluid Phase Equil., 161, 315, 1999.
1999PAN Pan, C. and Radosz, M., Phase behavior of poly(ethylene-co-hexene-1) solutions in
isobutane and propane, Ind. Eng. Chem. Res., 38, 2842, 1999.
1999WAL Walker, T.A., Raghavan, S.R., Royer, J.R., Smith, S.D., Wignall, G.D., Melnichenko, Y.,
Khan, S.A., and Spontak, R.J., Enhanced miscibility of low-molecular-weight
polystyrene/polyisoprene blends in supercritical CO2, J. Phys. Chem. B, 103, 5472, 1999.
2000BAY Bayraktar, Z. and Kiran, E., Miscibility, phase separation, and volumetric properties in
solutions of poly(dimethylsiloxane) in supercritical carbon dioxide, J. Appl. Polym. Sci., 75,
1397, 2000.
2000BEH Behme, S., Thermodynamik von Polymersystemen bei hohen Drucken, Dissertation, TU
Berlin, 2000.
2000BY1 Byun, H.-S. and McHugh, M.A., Impact of ‘free’ monomer concentration on the phase
behavior of supercritical carbon dioxide-polymer mixtures, Ind. Eng. Chem. Res., 39, 4658,
2000.
____________________________________________________________________________________
2000BY2 Byun, H.-S. and Choi, T.-H., Effect of monomer comcentration on the phase behavior of
supercritical carbon dioxide-poly(ethyl methacrylate) mixture, J. Korean Ind. Eng. Chem.,
11, 396, 2000.
2000BY3 Byun, H.-S., Kim, K., and Lee, H.-S., High-pressure phase behavior and mixture density of
binary poly(ethylene-co-butene)-dimethyl ether system, Hwahak Konghak, 38, 826, 2000.
2000CH1 Chan, A.K.C., Adidharma, H., and Radosz, M., Fluid-liquid and fluid-solid transitions of
poly(ethylene-co-octene-1) in sub- and supercritical propane solutions, Ind. Eng. Chem.
Res., 39, 3069, 2000.
2000CH2 Chan, A.K.C., Russo, P.S., and Radosz, M., Fluid-liquid equilibria in poly(ethylene-co-
hexene-1) + propane: a light-scattering probe of cloud-point pressure and critical polymer
concentration, Fluid Phase Equil., 173, 149, 2000.
2000CH3 Chan, A.K.C. and Radosz, M., Fluid-liquid and fluid-solid phase behavior of poly(ethylene-
co-hexene-1) solutions in sub- and supercritical propane, ethylene, and ethylene + hexene-1,
2000CH4 Chan, A.K.C., Adidharma, H., and Radosz, M., Fluid-liquid transitions of poly(ethylene-co-
octene-1) in supercritical ethylene solutions, Ind. Eng. Chem. Res., 39, 4370, 2000.
2000DIN DiNoia, T.P., Conway, S.E., Lim, J.S., McHugh, M.A., Solubility of vinylidene fluoride
polymers in supercritical CO2 and halogenated solvents, J. Polym. Sci., Part B: Polym.
Phys., 38, 2832, 2000.
2000KIM Kim, K. and Byun, H.-S., Cosolvent effect on phase behavior of poly(butyl methacrylate)-
CO2-butyl methacrylate system at high pressure, Hwahak Konghak, 38, 479, 2000.
2000KIN Kinzl, M., Luft, G., Adidharma, H., and Radosz, M., SAFT modeling of inert-gas effects on
the cloud-point pressures in ethylene copolymerization systems: Poly(ethylene-co-vinyl
acetate) + vinyl acetate + ethylene and poly(ethylene-co-hex-1-ene) + 1-hexene + ethylene
with carbon dioxide, nitrogen, or butane, Ind. Eng. Chem. Res., 39, 541, 2000.
2000LE1 Lee, J.M., Lee, B.-C., and Lee, S.-H., Cloud points of biodegradable polymers in compres-
sed liquid and supercritical chlorodifluoromethane, J. Chem. Eng. Data, 45, 851, 2000.
2000LE2 Lee, J.M., Lee, B.-C., and Hwang, S.-J., Phase behavior of poly(L-lactide) in supercritical
mixtures of CO2 and chlorodifluoromethane, J. Chem. Eng. Data, 45, 1162, 2000.
2000MAR Martin, T.M., Gupta, R.B., and Roberts, C.B., Measurements and modeling of cloud point
behavior for poly(propylene glycol) in ethane and in ethane + cosolvent mixtures at high
pressure, Ind. Eng. Chem. Res., 39, 185, 2000.
2000RAO Rao, V.S.R. and Watkins, J.J., Phase separation in polystyrene-poly(vinyl methyl ether)
blends dilated with compressed carbon dioxide, Macromolecules, 33, 5143, 2000.
2000TEP Tepper, G. and Levit, N., Polymer deposition from supercritical solutions for sensing
applications, Ind. Eng. Chem. Res., 39, 4445, 2000.
2000VRI Vries, T.J. de, Somers, P.J.A., Loos, Th.W. de, Vorstman, M.A.G., and Keurentjes, J.T.F.,
Phase behavior of poly(ethylene-co-propylene) in ethylene and carbon dioxide:
experimental results and modeling with the SAFT equation of state, Ind. Eng. Chem. Res.,
39, 4510, 2000.
2000WIE Wiesmet, V., Weidner, E., Behme, S., Sadowski, G., and Arlt, W., Measurement and
modelling of high-pressure phase equilibria in the systems polyethyleneglycol (PEG)-
propane, PEG-nitrogen and PEG-carbon dioxide, J. Supercrit. Fluids, 17, 1, 2000.
2001BYU Byun, H.-S., Kim, K., Kim, N.H., and Kwak, C., Cosolvent effect and phase behavior of
poly(octadecyl methacrylate)-CO2 mixtures at high pressure, J. Korean Ind. Eng. Chem.,
12, 212, 2001.
2001CHE Chernyak, Y., Henon, F., Harris, R.B., Gould, R.D., Franklin, R.K., Edwards, J.R., De
Simone, J.M., and Carbonell, R.G., Formation of perfluoropolyether coatings by the rapid
expansion of supercritical solutions (RESS) process. Part 1: Experimental results, Ind. Eng.
Chem. Res., 40, 6118, 2001.
____________________________________________________________________________________
2001CON Conway, S.E., Byun, H.-S., McHugh, M.A., Wang, J.D., and Mandel, F.S., Poly(lactide-co-
glycolide) solution behavior in supercritical CO2, CHF3, and CHClF2, J. Appl. Polym. Sci.,
80, 1155, 2001.
2001DAR Dariva, C., Oliveira, J.V., Tavares, F.W., and Pinto, J.C., Phase equilibria of polypropylene
samples with hydrocarbon solvents at high pressures, J. Appl. Polym. Sci., 81, 3044, 2001.
2001DOE Doerr, H., Kinzl, M., and Luft, G., The influence of inert gases on the high-pressure phase
equilibria of EH-copolymer/1-hexene/ethylene-mixtures, Fluid Phase Equil., 178, 191,
2001.
2001KEM Kemmere, M., de Vries, T.J., Vorstman, M., and Keurentjens J., A novel process for the
catalytic polymerization of olefins in supercritical carbon dioxide, Chem. Eng. Sci., 56,
4197, 2001.
2001KUK Kuk, Y.-M., Lee, B.-C., Lee, Y.W., and Lim, J.S., Phase behavior of biodegradable
polymers in dimethyl ether and dimethyl ether + carbon dioxide, J. Chem. Eng. Data, 46,
1344, 2001.
2001LI1 Li, D., Han, B., Liu, Z., and Zhao, D., Phase behavior of supercritical CO2/styrene/
poly(ethylene terephthalate) (PET) system and preparation of polystyrene/PET composites,
Polymer, 42, 2331, 2001.
2001LI2 Li, D., Han, B., Liu, Z., Liu, J., Zhang, X., Wang, S., and Zhang, X., Effect of gas
antisolvent on conformation of polystyrene in toluene: Viscosity and small-angle X-ray
scattering study (experimental data by B. Han), Macromolecules, 34, 2195, 2001.
2001LI3 Li, D., Han, B., Huo, Q., Wang, J., and Dong, B., Small-angle X-ray scattering by dilute
solutions of bisphenol-A polycarbonate during adding antisolvent CO2, Macromolecules,
34, 4874, 2001.
2001LIU Liu, J., Han, B., Li, G., Liu, Z., He, J., and Yang, G., Solubility of the non-ionic surfactant
tetraethylene glycol n-lauryl ether in supercritical CO2 with n-pentanol, Fluid Phase Equil.
187-188, 247, 2001.
2001NDI Ndiaye, P.M., Dariva, C., Oliveira, J.V., and Tavares, F.W., Phase behavior of isotactic
polypropylene/C4-solvents at high pressure. Experimental data and SAFT modeling, J.
2001TOR Tork, T., Measurement and calculation of phase equilibria in polyolefin/solvent systems
(Ger.), Dissertation, TU Berlin, 2001.
2001VLI Vliet, R.E. van, Tiemersma, T.P., Krooshof, G.J., and Iedema, P.D., The use of liquid-
liquid extraction in the EPDM solution polymerization process, Ind. Eng. Chem. Res., 40,
4586, 2001.
2002BEY Beyer, C. and Oellrich, L.R., Cosolvent studies with the system ethylene/poly(ethylene-co-
acrylic acid): Effects of solvent, density, polarity, hydrogen bonding, and copolymer
composition, Helv. Chim. Acta, 85, 659, 2002.
2002BLA Blasig, A., Shi, C., Enick, R.M., and Thies, M.C., Effect of concentration and degree of
saturation on RESS of a CO2-soluble fluoropolymer (experimental data by A. Blasig and
M.C. Thies), Ind. Eng. Chem. Res., 41, 4976, 2002.
2002BOT Bothum, G.D., White, K.L., and Knutson, B.L., Gas antisolvent fractionation on semicrys-
talline and amorphous poly(lactic acid) using compressed CO2, Polymer, 43, 4445, 2002.
2002BYU Byun, H.-S. and Choi, T.-H., Effect of the octadecyl acrylate concentration on the phase
behavior of poly(octadecyl acrylate)/supercritical CO2 and C2H4 at high pressures, J. Appl.
Polym. Sci., 86, 372, 2002.
2002COL Colina, C.M., Hall, C.K., and Gubbins, K.E., Phase behavior of PVAC-PTAN block copo-
lymer in supercritical carbon dioxide using SAFT, Fluid Phase Equil., 194-197, 553, 2002.
2002DRO Drohmann, C. and Beckman, E.J., Phase behavior of polymers containing ether groups in
carbon dioxide, J. Supercrit. Fluids, 22, 103, 2002.
____________________________________________________________________________________
2002HOR Horst, M.H. ter, Behme, S., Sadowski, G., and Loos, Th.W. de, The influence of
supercritical gases on the phase behavior of polystyrene-cyclohexane and polyethylene-
cyclohexane systems: experimental results and modeling with the SAFT equation of state, J.
2002JOU Joung, S.N., Park, J.-U., Kim, S.Y., and Yoo, K.-P., High-pressure phase behavior of
polymer-solvent systems with addition of supercritical CO2 at temperatures from 323.15 K
to 503.15 K, J. Chem. Eng. Data, 47, 270, 2002.
2002KUK Kuk, Y.-M., Lee, B.-C., Lee, Y.-W., and Lim, J. S., High-pressure phase behavior of
poly(D,L-lactide) in chlorodifluoromethane, difluoromethane, trifluoromethane, and 1,1,1,2-
tetrafluoroethane, J. Chem. Eng. Data, 47, 575, 2002.
2002LEE Lee, B.-C. and Kuk, Y.-M., Phase behavior of poly(L-lactide) in supercritical mixtures of
dichloromethane and carbon dioxide, J. Chem. Eng. Data, 47, 367, 2002.
2002LID Li, D., Liu, Z., Han, N., Yang, G., Song, L., Wang, J., and Dong, B., Thermodynamic
nature of monodisperse polystyrene in mixed solvent of cyclohexane and antisolvent carbon
dioxide using synchrotron small-angle X-ray scattering, Macromolecules, 35, 10114, 2002.
2002MC1 McHugh, M.A., Park, I.-H., Reisinger, J.J., Ren, Y., Lodge, T.P., and Hillmyer, M.A.,
Solubility of CF2-modified polybutadiene and polyisoprene in supercritical carbon dioxide,
2002MC2 McHugh, M.A., Garach-Domech, A., Park, I.-H., Li, D., Barbu, E., Graham, P., Tsibouklis,
J., Impact of fluorination and side-chain length on poly(methylpropenoxyalkylsiloxane) and
poly(alkyl methacrylate) solubility in supercritical carbon dioxide, Macromolecules, 35,
6479, 2002.
2002TAY Taylor, D.K., Keiper, J.S., and DeSimone, J.M., Polymer self-assembly in carbon dioxide,
Ind. Eng. Chem. Res., 41, 4451, 2002.
2002WU1 Wu, J., Pan, Q., and Rempel, G.L., High-pressure phase equilibria for a styrene/CO2/
polystyrene ternary system, J. Appl. Polym. Sci., 85, 1938, 2002.
2002WU2 Wu, J., Pan, Q., and Rempel, G.L., Prediction of phase behavior for styrene/CO2/
polystyrene mixtures, Chin. J. Chem. Eng., 10, 706, 2002.
2002ZHA Zhang, W. and Kiran, E., Phase behavior and density of polysulfone in binary fluid mixtures
of tetrahydrofuran and carbon dioxide under high pressure: miscibility windows, J. Appl.
Polym. Sci., 86, 2357, 2002.
2003BUB Buback, M. and Latz, H., Cloud-point pressure curves of ethene/poly[ethylene-co-
((meth)acrylic acid)] mixtures, Macromol. Chem. Phys., 204, 638, 2003.
2003DOM Domingo, C., Vega, A., Fanovich, M.A., Elvira, C., and Subra, P., Behavior of poly(methyl
methacrylate)-based systems in supercritical CO2 and CO2 plus cosolvent: solubility
measurements and process assessment, J. Appl. Polym. Sci., 90, 3652, 2003.
2003KIL Kilic, S., Michalik, S., Wang, Y., Johnson, J.K., Enick, R.M., and Beckman, E.J., Effect of
grafted Lewis base groups on the phase behavior of model poly(dimethyl siloxanes) in CO2,
Ind. Eng. Chem. Res., 42, 6415, 2003.
2003KHO Khosravi-Darani, K., Vasheghani-Farahani, E., Yamini, Y., and Bahramifar, N., Solubility
of poly(beta-hydroxybutyrate) in supercritical carbon dioxide, J. Chem. Eng. Data, 48, 860,
2003.
2003LEE Lee, B.-C., Lim, J.S., and Lee, Y.-W., Effect of solvent composition and polymer molecular
weight on cloud points of poly(L-lactide) in chlorodifluoromethane + carbon dioxide, J.
Chem. Eng. Data, 48, 774, 2003.
2003LID Li, D., Shen, Z., McHugh, M.A., Tsibouklis, J., and Barbu, E., Solubility of
poly(perfluoromonoitaconates) and poly(perfluorodiitaconates) in supercritical CO2, Ind.
Eng. Chem. Res., 42, 6499, 2003.
2003RAM Ramachandrarao, V.S., Vogt, B.D., Gupta, R.R., and Watkins, J.J., Effect of carbon dioxide
sorption on the phase behavior of weakly interacting polymer mixtures: solvent-induced
segregation in deuterated polybutadiene/polyisoprene blends, J. Polym. Sci.: Part B: Polym.
Phys., 41, 3114, 2003.
____________________________________________________________________________________
2003SHE Shen, Z., McHugh, M.A., Xu, J., Belardi, J., Kilic, S., Mesiano, A., Bane, S., Karnikas, C.,
Beckman, E., and Enick, R., CO2 solubility of oligomers and polymers that contain the
carbonyl group, Polymer, 44, 1491, 2003.
2003STR Striolo, A., Elvassore, N., Parton, T., and Bertucco, A., Relationship between volume
expansion, solvent power, and precipitation in GAS processes, AIChE-J., 49, 2671, 2003.
2003TRU Trumpi, H., Loos, Th.W. de, Krenz, R.A., and Heidemann, R.A., High pressure phase
equilibria in the system linear low density polyethylene + ethylene: experimental results and
modelling, J. Supercrit. Fluids, 27, 205, 2003.
2003ZH2 Zhang, W., Dindar, C., Bayraktar, Z., and Kiran, E., Phase behavior, density, and
crystallization of polyethylene in n-pentane and in n-pentane/CO2 at high pressures, J. Appl.
Polym. Sci., 89, 2201, -2003.
2004BEC Becker, F., Buback, M., Latz, H., Sadowski, G., and Tumakaka, F., Cloud-point curves of
ethylene-(meth)acrylate copolymers in fluid ethene up to high pressures and temperatures:
experimental study and PC-SAFT modeling, Fluid Phase Equil., 215, 263, 2004.
2004BYU Byun, H.-S., Kim, J.-G., and Yang, J.-S., Phase behavior of the poly[hexyl (meth)acrylate]-
supercritical solvents-monomer mixtures at high pressures, Ind. Eng. Chem. Res. 43 (2004)
1543-1552
215, 105, 2004.
2004DIC Dickson, J.L., Ortiz-Estrada, C., Alvarado, J.F.J., Hwang, H.S., Sanchez, I.C., Luna-
Barcenas, G., Lim, K.T., and Johnston, K.P., Critical flocculation density of dilute water-in-
CO2 emulsions stabilized with block copolymers, J. Colloid Interface Sci., 272, 444, 2004.
2004LI1 Li, D. and McHugh, M.A., Limited polysulfone solubility in supercritical dimethyl ether
with THF and DMF cosolvents, J. Supercrit. Fluids, 28, 79, 2004.
2004LI2 Li, D. and McHugh, M.A., Solubility behavior of ethyl cellulose in supercritical fluid
solvents, J. Supercrit. Fluids, 28, 225, 2004.
2004PFO Pfohl, O. and Dohrn, R., Provision of thermodynamic properties of polymer systems for
industrial applications, Fluid Phase Equil., 217, 189, 2004.
2004WAL Walker, T.A., Colina, C.M., Gubbins, K.E., and Spontak, R.J., Thermodynamics of
poly(dimethylsiloxane)/poly(ethylmethylsiloxane) (PDMS/PEMS) blends in the presence of
high-pressure CO2, Macromolecules, 37, 2588, 2004.
5. ENTHALPY CHANGES IN POLYMER SOLUTIONS
AT ELEVATED PRESSURES
5.1. Enthalpies of mixing or intermediary enthalpies of dilution
Polymer (B): poly(ethylene glycol) dimethyl ether 1999LOP

Characterization: Mn/kg.mol−1 = 0.280, PEGDME 250, a mixture of oligomers
of n = 3 to 9, Aldrich Chem. Co., Inc., Milwaukee, WI
T/K = 323.15 P/MPa = 8.0

xA 0.1464 0.2180 0.2992 0.3981 0.4999 0.5002 0.5951 0.7016
∆MH/J.mol−1 115.8 221.8 378.4 515.4 591.7 604.7 612.3 571.3
xA 0.7972 0.8559 0.8987
∆MH/J.mol−1 470.5 363.3 267.7
T/K = 373.15 P/MPa = 8.0
xA 0.0829 0.1202 0.1549 0.1875 0.2181 0.2605 0.2994 0.3572
∆MH/J.mol−1 214.6 296.2 367.4 419.8 474.4 547.3 603.6 684.8
xA 0.3983 0.4264 0.5000 0.5415 0.5950 0.6537 0.7016 0.7590
∆MH/J.mol−1 732.2 765.6 823.4 836.5 840.7 788.1 754.8 674.5
xA 0.7972 0.8558 0.8987 0.9315
∆MH/J.mol−1 608.6 476.8 349.0 236.6
T/K = 423.15 P/MPa = 8.0
xA 0.0829 0.1202 0.1550 0.1875 0.2181 0.2606 0.2994 0.3573
∆MH/J.mol−1 184.7 271.1 349.5 423.8 482.0 563.2 630.3 716.7
xA 0.3984 0.4526 0.4999 0.5415 0.5950 0.6400 0.7016 0.7590
∆MH/J.mol−1 775.6 864.9 905.4 922.7 895.8 882.7 828.0 745.7
xA 0.7972 0.8558 0.8987 0.9314
∆MH/J.mol−1 672.3 516.3 366.2 245.8
_____________________________________________________________________________
Polymer (B): tetra(ethylene glycol) dimethyl ether 1999LOP

T/K = 323.15 P/MPa = 8.0

xA 0.0686 0.1000 0.1441 0.1849 0.2227 0.2907 0.3500 0.4022
∆MH/J.mol−1 134.9 193.3 273.5 336.1 392.5 478.7 538.0 588.1
xA 0.4023 0.4699 0.4700 0.5091 0.5608 0.6056 0.6567 0.7000
∆MH/J.mol−1 577.6 605.6 611.3 616.5 614.0 604.6 586.0 548.7
xA 0.7538 0.7977 0.8550 0.8988 0.9333
∆MH/J.mol−1 481.6 418.8 312.2 220.4 141.3
T/K = 373.15 P/MPa = 8.0
xA 0.0686 0.1001 0.1442 0.1850 0.2229 0.2909 0.3502 0.4024
∆MH/J.mol−1 163.3 242.5 348.6 431.3 499.3 611.0 690.9 734.0
xA 0.4025 0.4701 0.5093 0.5610 0.6058 0.6569 0.7002 0.7540
∆MH/J.mol−1 744.3 779.5 791.8 797.9 787.0 755.7 715.5 643.2
xA 0.7978 0.8551 0.8989 0.9334
∆MH/J.mol−1 564.8 430.5 310.8 205.7
T/K = 423.15 P/MPa = 8.0
xA 0.0686 0.1001 0.1442 0.1850 0.2229 0.2909 0.3502 0.4024
∆MH/J.mol−1 196.2 279.1 382.6 468.9 545.3 668.0 755.4 806.2
xA 0.4024 0.4700 0.5092 0.5610 0.6057 0.6568 0.6991 0.7001
∆MH/J.mol−1 812.3 861.7 577.9 899.4 894.8 871.2 820.0 837.0
xA 0.7002 0.7539 0.7977 0.8449 0.8989 0.9334
∆MH/J.mol−1 811.8 707.0 616.3 485.2 322.7 210.5
5.2. References
1999LOP Lopez, E.R., Coxam, J.-Y., Fernandez, J., and Grolier, J.-P.E., Pressure and temperature
dependence of excess enthalpies of methanol + tetraethylene glycol dimethyl ether and
methanol + polyethylene glycol dimethyl ether 250, J. Chem. Eng. Data, 44, 1409, 1999.
6.1. PVT data of selected polymers

Characterization: Mn/kg.mol−1 = 26, Mw/kg.mol−1 = 130, 12.4 wt% acrylic acid
____________________________________________________________________________________
T/K 393.2 413.2 433.2 453.2 473.2
____________________________________________________________________________________
P/ Vspez/ P/ Vspez/ P/ Vspez/ P/ Vspez/ P/ Vspez/
MPa cm3g−1 MPa cm3g−1 MPa cm3g−1 MPa cm3g−1 MPa cm3g−1
____________________________________________________________________________________
8.6 1.1749 3.4 1.1930 6.1 1.2047 5.6 1.2208 5.3 1.2355
19.6 1.1653 7.6 1.1884 10.7 1.1994 9.8 1.2157 10.2 1.2288
30.4 1.1568 14.7 1.1814 19.2 1.1905 17.9 1.2056 18.2 1.2187
39.7 1.1498 27.9 1.1698 31.6 1.1788 31.1 1.1923 32.2 1.2035
49.6 1.1430 43.1 1.1575 44.2 1.1683 45.5 1.1792 44.4 1.1916
62.8 1.1348 62.8 1.1434 63.4 1.1538 63.5 1.1652 64.1 1.1748
78.9 1.1249 82.0 1.1316 83.3 1.1409 82.8 1.1518 83.1 1.1607
94.1 1.1167 99.0 1.1227 103.1 1.1296 102.7 1.1397 102.8 1.1481
99.3 1.1128102.2 1.1205 122.3 1.1196 122.1 1.1287 121.4 1.1369
112.3 1.1076121.0 1.1114 141.5 1.1105 141.2 1.1189 141.9 1.1263
129.6 1.0995141.7 1.1020 160.4 1.1022 159.8 1.1101 161.0 1.1169
159.9 1.0942 179.3 1.0946 178.6 1.1021 180.0 1.1085
178.3 1.0863 198.3 1.0873 197.5 1.0944 200.1 1.1005
____________________________________________________________________________________
Comments: More data are given in the original source 1992WIN or can also be found in 2001WOH.
Polymer (B): ethylene/1-butene copolymer 1999MAI

Characterization: Mn/kg.mol−1 = 82.8, Mw/kg.mol−1 = 199, 52.2 wt% 1-butene,
ρB = 0.8662 g/cm3, synthesized in the laboratory
____________________________________________________________________________________
P/MPa T/K
424.48 433.74 443.82
454.18 464.52 474.15 484.04 493.79 504.43
Vspez/cm3g−1
____________________________________________________________________________________
0.1 1.2558 1.2645 1.2734 1.2828 1.2924 1.3025 1.3119 1.3210 1.3314
10 1.2443 1.2522 1.2604 1.2692 1.2778 1.2868 1.2953 1.3038 1.3133
20 1.2337 1.2410 1.2487 1.2569 1.2647 1.2728 1.2804 1.2887 1.2974
30 1.2243 1.2313 1.2384 1.2462 1.2534 1.2610 1.2681 1.2756 1.2839
40 1.2158 1.2224 1.2290 1.2365 1.2433 1.2504 1.2571 1.2642 1.2716
50 1.2080 1.2142 1.2205 1.2276 1.2342 1.2409 1.2472 1.2539 1.2611
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
60 1.2007 1.2066 1.2127 1.2193 1.2257 1.2322 1.2382 1.2446 1.2514
70 1.1939 1.1995 1.2053 1.2118 1.2179 1.2240 1.2300 1.2360 1.2425
80 1.1874 1.1929 1.1985 1.2046 1.2107 1.2166 1.2222 1.2281 1.2342
90 1.1815 1.1867 1.1922 1.1980 1.2039 1.2096 1.2150 1.2207 1.2265
100 1.1757 1.1807 1.1861 1.1917 1.1974 1.2029 1.2081 1.2137 1.2193
110 1.1703 1.1752 1.1803 1.1857 1.1913 1.1966 1.2018 1.2072 1.2125
120 1.1651 1.1698 1.1748 1.1802 1.1856 1.1906 1.1957 1.2009 1.2061
130 1.1602 1.1646 1.1696 1.1748 1.1800 1.1850 1.1899 1.1949 1.2000
140 1.1554 1.1597 1.1646 1.1697 1.1747 1.1796 1.1844 1.1893 1.1942
150 1.1508 1.1551 1.1598 1.1647 1.1697 1.1745 1.1791 1.1839 1.1887
160 1.1464 1.1505 1.1550 1.1600 1.1648 1.1695 1.1740 1.1787 1.1834
170 1.1422 1.1462 1.1507 1.1554 1.1601 1.1648 1.1691 1.1738 1.1782
180 1.1382 1.1419 1.1463 1.1510 1.1556 1.1601 1.1645 1.1690 1.1733
200 1.1304 1.1340 1.1383 1.1428 1.1472 1.1516 1.1558 1.1601 1.1642
____________________________________________________________________________________
Comments: More data can be found in 2001WOH.
Polymer (B): ethylene/1-octene copolymer 1999MAI

Characterization: Mn/kg.mol−1 = 41.4, Mw/kg.mol−1 = 86.9, 25.0 wt% 1-octene,
ρB = 0.8750 g/cm3, Dow Chemical
_____________________________________________________________________________________________
P/MPa T/K
423.10 433.01 443.28
453.42 463.80 473.36 483.63 493.64 503.31
Vspez/cm3g−1
____________________________________________________________________________________
0.1 1.2825 1.2930 1.3026 1.3122 1.3227 1.3324 1.3431 1.3533 1.3639
10 1.2704 1.2798 1.2887 1.2977 1.3072 1.3163 1.3256 1.3349 1.3444
20 1.2592 1.2677 1.2763 1.2845 1.2933 1.3019 1.3101 1.3188 1.3275
30 1.2494 1.2574 1.2650 1.2733 1.2814 1.2895 1.2971 1.3050 1.3133
40 1.2403 1.2479 1.2550 1.2625 1.2706 1.2781 1.2853 1.2926 1.3004
50 1.2320 1.2392 1.2459 1.2531 1.2603 1.2679 1.2745 1.2815 1.2888
60 1.2242 1.2311 1.2375 1.2443 1.2514 1.2582 1.2648 1.2714 1.2783
70 1.2169 1.2236 1.2296 1.2363 1.2430 1.2496 1.2556 1.2623 1.2687
80 1.2101 1.2166 1.2224 1.2286 1.2352 1.2416 1.2474 1.2533 1.2600
90 1.2038 1.2099 1.2155 1.2216 1.2279 1.2341 1.2397 1.2454 1.2515
100 1.1977 1.2038 1.2091 1.2150 1.2209 1.2270 1.2324 1.2380 1.2439
110 1.1919 1.1978 1.2030 1.2086 1.2145 1.2203 1.2256 1.2310 1.2366
120 1.1863 1.1922 1.1971 1.2025 1.2083 1.2138 1.2190 1.2243 1.2298
130 1.1811 1.1866 1.1915 1.1968 1.2023 1.2078 1.2127 1.2179 1.2233
140 1.1759 1.1814 1.1861 1.1913 1.1966 1.2019 1.2069 1.2118 1.2172
150 1.1710 1.1765 1.1809 1.1860 1.1912 1.1964 1.2012 1.2061 1.2112
160 1.1662 1.1716 1.1760 1.1808 1.1859 1.1911 1.1958 1.2005 1.2055
170 1.1617 1.1670 1.1712 1.1759 1.1809 1.1860 1.1907 1.1951 1.2001
180 1.1575 1.1624 1.1666 1.1713 1.1761 1.1811 1.1857 1.1902 1.1949
200 1.1492 1.1541 1.1581 1.1624 1.1672 1.1719 1.1764 1.1806 1.1853
_____________________________________________________________________________________________
6. PVT Data 553
____________________________________________________________________________________
Polymer (B): ethylene/propylene copolymer 1999MAI

Characterization: Mn/kg.mol−1 = 104.5, Mw/kg.mol−1 = 178, 31.8 wt% propene,
ρB = 0.8871 g/cm3, synthesized in the laboratory
____________________________________________________________________________________
P/MPa T/K
422.35 432.50 442.35
452.05 462.27 472.37 482.18 492.51 502.28
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 1.2740 1.2836 1.2938 1.3028 1.3122 1.3220 1.3317 1.3422 1.3523
10 1.2624 1.2711 1.2804 1.2886 1.2975 1.3066 1.3155 1.3249 1.3339
20 1.2517 1.2598 1.2681 1.2761 1.2843 1.2929 1.3010 1.3095 1.3178
30 1.2423 1.2498 1.2578 1.2648 1.2731 1.2810 1.2886 1.2966 1.3042
40 1.2337 1.2408 1.2484 1.2550 1.2624 1.2702 1.2776 1.2851 1.2922
50 1.2259 1.2324 1.2399 1.2460 1.2531 1.2601 1.2675 1.2746 1.2814
60 1.2186 1.2247 1.2319 1.2377 1.2445 1.2512 1.2578 1.2651 1.2716
70 1.2118 1.2177 1.2245 1.2301 1.2366 1.2431 1.2494 1.2558 1.2626
80 1.2053 1.2110 1.2176 1.2229 1.2292 1.2354 1.2415 1.2477 1.2536
90 1.1993 1.2047 1.2110 1.2163 1.2222 1.2282 1.2342 1.2400 1.2458
100 1.1935 1.1987 1.2048 1.2100 1.2157 1.2214 1.2272 1.2329 1.2385
110 1.1881 1.1930 1.1990 1.2040 1.2095 1.2151 1.2206 1.2262 1.2315
120 1.1828 1.1876 1.1932 1.1984 1.2036 1.2090 1.2144 1.2197 1.2250
130 1.1777 1.1825 1.1880 1.1930 1.1980 1.2033 1.2086 1.2136 1.2187
140 1.1729 1.1775 1.1828 1.1877 1.1926 1.1978 1.2028 1.2079 1.2128
150 1.1683 1.1726 1.1777 1.1827 1.1875 1.1925 1.1976 1.2023 1.2071
160 1.1639 1.1680 1.1730 1.1778 1.1826 1.1876 1.1923 1.1972 1.2016
170 1.1595 1.1635 1.1684 1.1733 1.1779 1.1828 1.1873 1.1921 1.1966
180 1.1553 1.1593 1.1640 1.1687 1.1733 1.1781 1.1826 1.1872 1.1916
190 1.1513 1.1553 1.1597 1.1645 1.1689 1.1737 1.1780 1.1826 1.1868
200 1.1475 1.1513 1.1557 1.1604 1.1647 1.1694 1.1736 1.1783 1.1822
____________________________________________________________________________________
Polymer (B): ethylene/vinyl acetate copolymer 1995ZOL

Characterization: Scientific Polymer Products, Inc., Ontario, NY
____________________________________________________________________________________
P/MPa T/K
393.85 401.35 409.25 417.75 425.85 432.75 441.65 449.95 457.15
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 1.1796 1.1866 1.1938 1.2014 1.2089 1.2158 1.2238 1.2314 1.2385
20 1.1622 1.1687 1.1752 1.1816 1.1883 1.1947 1.2015 1.2080 1.2140
40 1.1474 1.1532 1.1590 1.1648 1.1711 1.1764 1.1827 1.1885 1.1939
60 1.1341 1.1395 1.1449 1.1503 1.1557 1.1609 1.1666 1.1719 1.1768
80 1.1220 1.1274 1.1324 1.1373 1.1423 1.1472 1.1524 1.1574 1.1619
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
100 1.1119 1.1170 1.1216 1.1262 1.1309 1.1356 1.1404 1.1451 1.1493
120 1.1023 1.1070 1.1114 1.1158 1.1203 1.1247 1.1293 1.1338 1.1377
140 1.0935 1.0980 1.1022 1.1064 1.1108 1.1150 1.1191 1.1233 1.1270
160 1.0855 1.0898 1.0937 1.0976 1.1019 1.1058 1.1099 1.1137 1.1174
180 1.0778 1.0819 1.0858 1.0895 1.0934 1.0976 1.1014 1.1052 1.1085
200 1.0707 1.0747 1.0785 1.0821 1.0857 1.0896 1.0933 1.0970 1.1002
____________________________________________________________________________________
Comments: More data can be found in 1995ZOL.
Polymer (B): poly(1-butene) 1999MAI

Characterization: Mn/kg.mol−1 = 46.7, Mw/kg.mol−1 = 131, isotactic,
synthesized in the laboratory by MBI/MAO metallocene catalysts
____________________________________________________________________________________
P/MPa T/K
454.40 464.75 474.70 484.50 494.55 504.50 514.25 524.63 534.60
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 1.2796 1.2892 1.2980 1.3053 1.3144 1.3237 1.3333 1.3436 1.3534
10 1.2647 1.2735 1.2814 1.2878 1.2958 1.3042 1.3127 1.3217 1.3302
20 1.2515 1.2595 1.2666 1.2725 1.2794 1.2873 1.2949 1.3030 1.3104
30 1.2397 1.2476 1.2542 1.2596 1.2661 1.2731 1.2802 1.2875 1.2943
40 1.2295 1.2364 1.2431 1.2482 1.2541 1.2607 1.2672 1.2740 1.2803
50 1.2203 1.2269 1.2326 1.2378 1.2435 1.2496 1.2558 1.2623 1.2681
60 1.2119 1.2182 1.2236 1.2280 1.2339 1.2396 1.2456 1.2515 1.2571
70 1.2039 1.2100 1.2152 1.2194 1.2246 1.2305 1.2363 1.2420 1.2473
80 1.1967 1.2026 1.2075 1.2115 1.2165 1.2218 1.2276 1.2331 1.2382
90 1.1899 1.1956 1.2002 1.2041 1.2089 1.2140 1.2192 1.2250 1.2297
100 1.1835 1.1890 1.1935 1.1972 1.2019 1.2067 1.2118 1.2169 1.2220
110 1.1774 1.1828 1.1871 1.1906 1.1951 1.1999 1.2048 1.2099 1.2142
120 1.1716 1.1769 1.1811 1.1845 1.1889 1.1934 1.1981 1.2030 1.2074
130 1.1662 1.1713 1.1753 1.1786 1.1829 1.1873 1.1919 1.1967 1.2008
140 1.1609 1.1658 1.1698 1.1731 1.1772 1.1815 1.1859 1.1907 1.1946
150 1.1558 1.1608 1.1646 1.1678 1.1718 1.1760 1.1803 1.1850 1.1888
160 1.1511 1.1558 1.1595 1.1626 1.1666 1.1706 1.1750 1.1795 1.1831
170 1.1465 1.1511 1.1547 1.1578 1.1616 1.1656 1.1697 1.1742 1.1777
180 1.1421 1.1466 1.1501 1.1531 1.1569 1.1607 1.1650 1.1693 1.1725
190 1.1379 1.1423 1.1456 1.1486 1.1523 1.1561 1.1602 1.1643 1.1677
200 1.1339 1.1382 1.1414 1.1443 1.1478 1.1516 1.1556 1.1599 1.1629
____________________________________________________________________________________
Polymer (B): poly(butylene succinate) 2000SAT

Characterization: Mn/kg.mol−1 = 29, Mw/kg.mol−1 = 140, Tg/K = 243,
Tm/K = 388, 35 wt% crystallinity, branched
continued
6. PVT Data 555
____________________________________________________________________________________
continued
____________________________________________________
P/MPa T/K
413.9 433.8 453.6 473.5 493.4
3 −1
Vspez/cm g
____________________________________________________
0.1 0.9012 0.9132 0.9251 0.9375 0.9508
10 0.8954 0.9070 0.9185 0.9302 0.9426
20 0.8902 0.9011 0.9115 0.9235 0.9351
50 0.8763 0.8864 0.8961 0.9062 0.9164
100 0.8565 0.8650 0.8737 0.8824 0.8910
150 0.8416 0.8493 0.8567 0.8647 0.8720
200 0.8274 0.8358 0.8425 0.8498 0.8564
____________________________________________________
Polymer (B): poly(butylene terephthalate) 1991FAK

Tm/K = 508, PBT Valox Grade 295, General Electric Plastics
____________________________________________________________________________________
P/MPa T/K
514.55 529.05 545.05 559.85 575.95 590.85
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 0.8966 0.9048 0.9139 0.9236 0.9372 0.9543
10 0.8899 0.8978 0.9063 0.9155 0.9284 0.9447
20 0.8835 0.8910 0.8991 0.9077 0.9203 0.9360
30 0.8780 0.8851 0.8928 0.9013 0.9131 0.9282
40 0.8726 0.8798 0.8872 0.8953 0.9066 0.9214
50 0.8676 0.8746 0.8817 0.8894 0.9005 0.9148
60 0.8631 0.8697 0.8766 0.8846 0.8950 0.9089
70 0.8586 0.8653 0.8719 0.8794 0.8897 0.9032
80 0.8545 0.8611 0.8675 0.8749 0.8848 0.8979
90 0.8506 0.8570 0.8632 0.8703 0.8801 0.8930
100 0.8469 0.8531 0.8593 0.8662 0.8757 0.8882
110 0.8414 0.8493 0.8554 0.8621 0.8716 0.8837
120 0.8362 0.8457 0.8515 0.8584 0.8674 0.8793
130 0.8291 0.8423 0.8479 0.8546 0.8636 0.8752
140 0.8139 0.8389 0.8444 0.8509 0.8598 0.8711
150 0.8058 0.8356 0.8412 0.8476 0.8561 0.8673
160 0.7985 0.8324 0.8378 0.8441 0.8526 0.8634
170 0.7924 0.8271 0.8347 0.8408 0.8492 0.8597
180 0.7897 0.8223 0.8315 0.8377 0.8458 0.8560
190 0.7872 0.8175 0.8286 0.8347 0.8426 0.8562
200 0.7846 0.8101 0.8256 0.8316 0.8393 0.8491
____________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(butyl acrylate) 1999CHU

____________________________________________________________________________________
P/MPa T/K
303.15 333.15363.15 393.15 423.15 453.15 483.15
Vspez/cm3g−1
____________________________________________________________________________________
10 0.9137 0.9356 0.9546 0.9745 0.9976 1.0192 1.0415
20 0.9076 0.9285 0.9468 0.9654 0.9866 1.0067 1.0266
30 0.9026 0.9227 0.9406 0.9581 0.9786 1.0161
40 0.8980 0.9177 0.9347 0.9515 0.9710 0.9888 1.0066
50 0.8939 0.9127 0.9292 0.9453 0.9641 0.9813 0.9982
60 0.8899 0.9081 0.9242 0.9396 0.9576 0.9743 0.9906
70 0.8861 0.9038 0.9194 0.9343 0.9516 0.9680 0.9834
80 0.8825 0.8992 0.9149 0.9296 0.9455 0.9614 0.9765
90 0.8788 0.8955 0.9106 0.9246 0.9408 0.9556 0.9704
100 0.8753 0.8918 0.9064 0.9204 0.9358 0.9502 0.9648
110 0.8722 0.8885 0.9026 0.9160 0.9309 0.9452 0.9593
120 0.8691 0.8850 0.8987 0.9118 0.9266 0.9404 0.9539
130 0.8663 0.8817 0.8950 0.9080 0.9221 0.9359 0.9488
140 0.8633 0.8789 0.8917 0.9040 0.9182 0.9311 0.9441
150 0.8604 0.8755 0.8884 0.9004 0.9140 0.9271 0.9394
160 0.8577 0.8724 0.8853 0.8966 0.9102 0.9230 0.9352
170 0.8553 0.8698 0.8822 0.8934 0.9065 0.9189 0.9309
180 0.8524 0.8669 0.8788 0.8900 0.9030 0.9150 0.9266
190 0.8500 0.8641 0.8758 0.8866 0.8993 0.9113 0.9228
200 0.8476 0.8729 0.8835 0.8959 0.9077 0.9187
____________________________________________________________________________________
Polymer (B): poly(εε-caprolactone) 1993ROG

−1
Characterization: Mw/kg.mol = 32, Scientific Polymer Products, Inc., Ontario, NY
________________________________________________________________________
P/MPa T/K
373.75 384.05393.35 403.25 412.55 421.35
Vspez/cm3g−1
________________________________________________________________________
0.1 0.9647 0.9719 0.9773 0.9833 0.9890 0.9950
10 0.9584 0.9651 0.9702 0.9760 0.9814 0.9871
20 0.9522 0.9571 0.9628 0.9687 0.9737 0.9789
30 0.9467 0.9523 0.9566 0.9622 0.9678 0.9728
40 0.9415 0.9465 0.9512 0.9566 0.9618 0.9665
50 0.9369 0.9418 0.9461 0.9514 0.9563 0.9607
60 0.9324 0.9369 0.9413 0.9463 0.9507 0.9553
70 0.9280 0.9326 0.9367 0.9417 0.9452 0.9504
________________________________________________________________________
continued
6. PVT Data 557
____________________________________________________________________________________
continued
________________________________________________________________________
80 0.9240 0.9284 0.9323 0.9369 0.9409 0.9455
90 0.9209 0.9243 0.9284 0.9326 0.9367 0.9410
100 0.9164 0.9206 0.9248 0.9287 0.9326 0.9371
110 0.9130 0.9171 0.9212 0.9247 0.9285 0.9329
120 0.9095 0.9138 0.9170 0.9210 0.9247 0.9289
130 0.9064 0.9104 0.9135 0.9176 0.9212 0.9253
140 0.9033 0.9072 0.9103 0.9142 0.9174 0.9216
150 0.9005 0.9041 0.9069 0.9107 0.9138 0.9181
160 0.8974 0.9010 0.9040 0.9075 0.9106 0.9145
170 0.8948 0.8981 0.9012 0.9044 0.9081 0.9111
180 0.8922 0.8953 0.8985 0.9013 0.9046 0.9078
190 0.8894 0.8925 0.8955 0.8986 0.9021 0.9044
200 0.8870 0.8898 0.8928 0.8961 0.8987 0.9013
________________________________________________________________________
Polymer (B): polycarbonate bisphenol-A 1997SAT

−1
Characterization: Mw/kg.mol = 60, Scientific Polymer Products, Inc., Ontario, NY
____________________________________________________________________________________
P/MPa T/K
443.7 463.6 483.5
503.3 523.6 543.5 563.6 583.5 603.4
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.8738 0.8841 0.8934 0.9061 0.9175 0.9281 0.9402 0.9517 0.9643
10 0.8678 0.8777 0.8872 0.8994 0.9102 0.9203 0.9315 0.9423 0.9538
20 0.8627 0.8721 0.8817 0.8930 0.9030 0.9130 0.9231 0.9334 0.9439
50 0.8497 0.8583 0.8670 0.8770 0.8859 0.8946 0.9034 0.9123 0.9213
100 0.8469 0.8556 0.8630 0.8705 0.8781 0.8854 0.8928
150 0.8387 0.8453 0.8518 0.8584 0.8649 0.8716
200 0.8306 0.8365 0.8424 0.8483 0.8542
____________________________________________________________________________________
Polymer (B): polycarbonate tetramethyl bisphenol-A 1992KIM

Characterization: Mw/kg.mol−1 = 33, Bayer AG, Leverkusen, Germany
____________________________________________________________________________________
P/MPa T/K
491.55 497.75 506.65
514.75 524.15 535.75 544.65 553.75 562.75
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.9787 0.9837 0.9912 0.9961 1.0016 1.0091 1.0149 1.0212 1.0306
10 0.9700 0.9746 0.9811 0.9858 0.9911 0.9978 1.0033 1.0090 1.0175
20 0.9612 0.9657 0.9709 0.9753 0.9811 0.9870 0.9923 0.9978 1.0050
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
30 0.9545 0.9588 0.9637 0.9677 0.9727 0.9782 0.9837 0.9885 0.9951
40 0.9481 0.9522 0.9546 0.9604 0.9658 0.9706 0.9753 0.9802 0.9868
50 0.9423 0.9460 0.9500 0.9542 0.9588 0.9636 0.9681 0.9726 0.9791
60 0.9372 0.9402 0.9441 0.9479 0.9523 0.9570 0.9613 0.9655 0.9717
70 0.9354 0.9385 0.9423 0.9467 0.9509 0.9550 0.9590 0.9647
80 0.9411 0.9454 0.9492 0.9531 0.9584
90 0.9359 0.9402 0.9439 0.9480 0.9527
100 0.9352 0.9390 0.9427 0.9475
110 0.9342 0.9377 0.9424
120 0.9298 0.9330 0.9373
130 0.9285 0.9326
140 0.9244 0.9282
150 0.9200 0.9238
160 0.9159 0.9193
____________________________________________________________________________________
Polymer (B): poly(1,1-dihydroxyperfluorooctyl acrylate) 1998LUN

−1
Characterization: Mw/kg.mol = 1200-1600, prepared in the laboratory
by solution-free radical polymerization in supercritical CO2
____________________________________________________________________________________
P/MPa T/K
303.15 313.15 323.15 333.15 343.15 353.15 363.15
3 −1
Vspez/cm g
____________________________________________________________________________________
10 0.5428 0.5483 0.5537 0.5589 0.5685 0.5721 0.5735
20 0.5377 0.5426 0.5477 0.5570 0.5614 0.5652
30 0.5335 0.5386 0.5428 0.5475 0.5520 0.5556 0.5599
40 0.5301 0.5350 0.5389 0.5433 0.5477 0.5511 0.5556
50 0.5269 0.5316 0.5353 0.5395 0.5438 0.5469 0.5517
60 0.5239 0.5286 0.5319 0.5363 0.5404 0.5433 0.5481
70 0.5212 0.5258 0.5286 0.5332 0.5400 0.5445
80 0.5184 0.5230 0.5303 0.5368 0.5413
90 0.5159 0.5205 0.5238 0.5276 0.5314 0.5337 0.5379
100 0.5134 0.5180 0.5212 0.5250 0.5286 0.5310 0.5347
110 0.5115 0.5154 0.5188 0.5226 0.5236 0.5284 0.5312
120 0.5091 0.5131 0.5167 0.5203 0.5212 0.5261 0.5292
130 0.5074 0.5108 0.5145 0.5183 0.5188 0.5235 0.5266
140 0.5057 0.5089 0.5123 0.5161 0.5166 0.5207 0.5245
150 0.5039 0.5069 0.5100 0.5141 0.5145 0.5194 0.5224
160 0.5023 0.5051 0.5079 0.5122 0.5126 0.5174 0.5203
170 0.5006 0.5035 0.5059 0.5103 0.5109 0.5155 0.5183
180 0.4991 0.5019 0.5041 0.5082 0.5090 0.5137 0.5162
190 0.4976 0.5004 0.5025 0.5064 0.5073 0.5117 0.5144
200 0.4963 0.4988 0.5009 0.5043 0.5100 0.5125
____________________________________________________________________________________
6. PVT Data 559
____________________________________________________________________________________
Polymer (B): poly(dimethylsiloxane) 1998SAC

____________________________________________________________________________________
P/MPa T/K
291.25 298.15304.45 307.45 338.15 365.15 394.15 423.05
3 −1
Vspez/cm g
____________________________________________________________________________________
0.1 1.0267 1.0325 1.0407 1.0418 1.0692 1.0957 1.1245 1.1529
22.5 1.0043 1.0092 1.0158 1.0170 1.0396 1.0607 1.0825 1.1034
32.5 0.9959 1.0004 1.0069 1.0078 1.0287 1.0482 1.0686 1.0874
42.5 0.9882 0.9925 0.9987 0.9993 1.0190 1.0376 1.0562 1.0731
52.5 0.9812 0.9853 0.9909 0.9917 1.0104 1.0279 1.0452 1.0607
62.5 0.9746 0.9785 0.9841 0.9844 1.0027 1.0187 1.0353 1.0498
72.5 0.9686 0.9722 0.9774 0.9779 0.9950 1.0105 1.0261 1.0400
82.5 0.9628 0.9661 0.9713 0.9717 0.9881 1.0032 1.0180 1.0312
92.5 0.9574 0.9606 0.9655 0.9659 0.9816 0.9962 1.0103 1.0230
102.5 0.9522 0.9554 0.9600 0.9604 0.9759 0.9895 1.0033 1.0151
112.5 0.9473 0.9505 0.9550 0.9553 0.9700 0.9834 0.9965 1.0082
122.5 0.9427 0.9458 0.9500 0.9504 0.9646 0.9776 0.9904 1.0015
132.5 0.9383 0.9412 0.9453 0.9458 0.9598 0.9724 0.9845 0.9953
142.5 0.9342 0.9370 0.9409 0.9414 0.9550 0.9671 0.9789 0.9891
152.5 0.9301 0.9329 0.9368 0.9372 0.9503 0.9625 0.9740 0.9836
162.5 0.9264 0.9291 0.9328 0.9332 0.9461 0.9578 0.9688 0.9783
172.5 0.9228 0.9252 0.9290 0.9293 0.9417 0.9533 0.9641 0.9730
182.5 0.9192 0.9217 0.9252 0.9257 0.9377 0.9488 0.9595 0.9683
202.5 0.9124 0.9148 0.9182 0.9186 0.9301 0.9409 0.9510 0.9591
____________________________________________________________________________________
Polymer (B): poly(ether sulfone) 2004KIM

−1 −1
Characterization: Mn/kg.mol = 36.5, Mw/kg.mol = 70, GPC against PS standards,
Ultrason-E, ICI America, Inc.
____________________________________________________________________________________
P/MPa T/K
497.05 504.25 513.95
522.95 532.65 542.05 551.05 560.25 569.35
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.7712 0.7758 0.7798 0.7841 0.7880 0.7938 0.7992 0.8047 0.8153
10 0.7663 0.7708 0.7744 0.7785 0.7820 0.7874 0.7924 0.7979 0.8049
20 0.7616 0.7659 0.7692 0.7731 0.7763 0.7811 0.7862 0.7913 0.7945
30 0.7576 0.7621 0.7650 0.7688 0.7718 0.7764 0.7808 0.7863 0.7892
40 0.7540 0.7584 0.7610 0.7646 0.7676 0.7721 0.7763 0.7812 0.7843
50 0.7506 0.7550 0.7573 0.7609 0.7638 0.7680 0.7720 0.7766 0.7793
60 0.7475 0.7517 0.7537 0.7572 0.7600 0.7641 0.7681 0.7725 0.7750
70 0.7445 0.7484 0.7504 0.7537 0.7565 0.7605 0.7644 0.7683 0.7710
80 0.7417 0.7453 0.7472 0.7503 0.7532 0.7571 0.7607 0.7645 0.7669
90 0.7390 0.7424 0.7441 0.7470 0.7500 0.7537 0.7573 0.7607 0.7632
100 0.7366 0.7395 0.7412 0.7438 0.7469 0.7505 0.7539 0.7571 0.7595
____________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): polyethylene 1999MAI

commercial sample, HDPE, linear
____________________________________________________________________________________
P/MPa T/K
452.10 462.80 472.75
482.75 492.80 502.95 512.85 522.85 532.85
Vspez/cm3g−1
____________________________________________________________________________________
0.1 1.3038 1.3142 1.3239 1.3340 1.3443 1.3552 1.3661 1.3770 1.3887
10 1.2906 1.3002 1.3091 1.3184 1.3276 1.3374 1.3470 1.3567 1.3668
20 1.2787 1.2876 1.2957 1.3044 1.3127 1.3216 1.3303 1.3389 1.3479
30 1.2682 1.2765 1.2843 1.2923 1.3000 1.3083 1.3163 1.3244 1.3326
40 1.2586 1.2665 1.2739 1.2813 1.2886 1.2963 1.3039 1.3115 1.3190
50 1.2498 1.2572 1.2643 1.2714 1.2782 1.2856 1.2928 1.3000 1.3070
60 1.2416 1.2487 1.2555 1.2622 1.2688 1.2757 1.2826 1.2896 1.2962
70 1.2340 1.2408 1.2474 1.2537 1.2600 1.2667 1.2734 1.2799 1.2863
80 1.2269 1.2335 1.2398 1.2459 1.2520 1.2583 1.2647 1.2710 1.2772
90 1.2199 1.2265 1.2328 1.2385 1.2443 1.2504 1.2567 1.2628 1.2688
100 1.2136 1.2200 1.2260 1.2317 1.2372 1.2431 1.2492 1.2550 1.2607
110 1.2076 1.2134 1.2197 1.2251 1.2305 1.2361 1.2420 1.2478 1.2533
120 1.2018 1.2075 1.2132 1.2190 1.2243 1.2296 1.2352 1.2409 1.2462
130 1.1965 1.2019 1.2074 1.2130 1.2182 1.2234 1.2289 1.2342 1.2395
140 1.1913 1.1965 1.2019 1.2070 1.2125 1.2174 1.2228 1.2281 1.2330
150 1.1863 1.1913 1.1966 1.2015 1.2065 1.2118 1.2171 1.2222 1.2269
160 1.1814 1.1863 1.1916 1.1964 1.2012 1.2060 1.2116 1.2165 1.2211
170 1.1767 1.1816 1.1868 1.1915 1.1962 1.2007 1.2062 1.2111 1.2156
180 1.1723 1.1770 1.1821 1.1866 1.1913 1.1959 1.2008 1.2060 1.2103
190 1.1680 1.1727 1.1775 1.1821 1.1866 1.1910 1.1958 1.2005 1.2052
200 1.1639 1.1685 1.1732 1.1777 1.1821 1.1864 1.1912 1.1958 1.1998
____________________________________________________________________________________

Characterization: Mw/kg.mol−1 = 25–30, Mw/Mn < 1.1
____________________________________________________________
P/MPa T/K
353.15 363.15 373.85 388.75 393.45
Vspez/cm3g−1
____________________________________________________________
0.1 0.92902 0.93589 0.94322 0.95012 0.95657
5.0 0.92644 0.93327 0.94056 0.94742 0.95374
10.0 0.92413 0.93075 0.93791 0.94455 0.95066
15.0 0.92191 0.92842 0.93537 0.94188 0.94787
20.0 0.91946 0.92592 0.93275 0.93914 0.94491
25.0 0.91709 0.92336 0.93015 0.93633 0.94206
30.0 0.91474 0.92090 0.92747 0.93362 0.93923
35.0 0.91232 0.91844 0.92498 0.93101 0.93650
40.0 0.90984 0.91592 0.92242 0.92842 0.93388
____________________________________________________________
6. PVT Data 561
____________________________________________________________________________________
Polymer (B): poly(DL-lactide) 2000SAT

Tm/K = 441, Lacea H-100E, Mitsumi Chem., Inc., Tokyo, Japan
_________________________________________
P/MPa T/K
453.4 473.3 493.3
Vspez/cm3g−1
_________________________________________
0.1 0.8968 0.9107 0.9251
10 0.8888 0.9019 0.9153
20 0.8814 0.8935 0.9065
50 0.8626 0.8732 0.8844
100 0.8392 0.8481 0.8576
150 0.8209 0.8288 0.8369
200 0.8058 0.8126 0.8202
_________________________________________
Polymer (B): α-methylstyrene)

poly(α 1996MAI
___________________________________________________________
P/MPa T/K
481.65 491.25 501.65 511.95 522.30
3 −1
Vspez/cm g
___________________________________________________________
0.1 0.9812 0.9867 0.9928 0.9996 1.0073
10 0.9743 0.9796 0.9852 0.9917 0.9990
20 0.9676 0.9728 0.9779 0.9841 0.9908
30 0.9623 0.9674 0.9721 0.9781 0.9847
40 0.9573 0.9621 0.9668 0.9724 0.9786
50 0.9527 0.9573 0.9617 0.9672 0.9730
60 0.9482 0.9526 0.9570 0.9622 0.9680
70 0.9441 0.9483 0.9526 0.9576 0.9630
80 0.9443 0.9484 0.9533 0.9587
90 0.9405 0.9445 0.9492 0.9545
100 0.9407 0.9454 0.9504
110 0.9371 0.9417 0.9466
120 0.9336 0.9381 0.9428
130 0.9347 0.9395
140 0.9313 0.9359
150 0.9327
160 0.9296
___________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(1-octene) 1999MAI

Characterization: Mn/kg.mol−1 = 35, Mw/kg.mol−1 = 84, isotactic,
____________________________________________________________________________________
P/MPa T/K
455.90 465.85 476.10
485.95 496.20 505.75 516.50 526.15 536.75
Vspez/cm3g−1
____________________________________________________________________________________
0.1 1.2993 1.3095 1.3195 1.3308 1.3410 1.3511 1.3624 1.3731 1.3842
10 1.2831 1.2923 1.3014 1.3110 1.3202 1.3295 1.3394 1.3487 1.3583
20 1.2687 1.2772 1.2853 1.2935 1.3024 1.3111 1.3196 1.3279 1.3365
30 1.2566 1.2644 1.2719 1.2795 1.2874 1.2952 1.3038 1.3113 1.3191
40 1.2457 1.2532 1.2602 1.2672 1.2745 1.2818 1.2894 1.2968 1.3040
50 1.2358 1.2429 1.2497 1.2565 1.2631 1.2700 1.2771 1.2837 1.2909
60 1.2269 1.2336 1.2401 1.2465 1.2527 1.2593 1.2661 1.2723 1.2788
70 1.2186 1.2250 1.2312 1.2376 1.2436 1.2497 1.2561 1.2620 1.2683
80 1.2110 1.2172 1.2231 1.2292 1.2349 1.2410 1.2469 1.2526 1.2586
90 1.2040 1.2100 1.2156 1.2216 1.2271 1.2328 1.2386 1.2440 1.2497
100 1.1973 1.2031 1.2085 1.2143 1.2195 1.2252 1.2307 1.2359 1.2413
110 1.1910 1.1967 1.2020 1.2075 1.2126 1.2181 1.2233 1.2284 1.2337
120 1.1849 1.1906 1.1957 1.2012 1.2060 1.2114 1.2163 1.2213 1.2263
130 1.1793 1.1847 1.1897 1.1950 1.1999 1.2050 1.2098 1.2145 1.2194
140 1.1740 1.1791 1.1840 1.1892 1.1939 1.1990 1.2036 1.2082 1.2130
150 1.1687 1.1739 1.1785 1.1837 1.1883 1.1932 1.1977 1.2022 1.2067
160 1.1638 1.1687 1.1732 1.1784 1.1830 1.1878 1.1920 1.1964 1.2008
170 1.1591 1.1637 1.1683 1.1734 1.1779 1.1826 1.1867 1.1910 1.1951
180 1.1545 1.1591 1.1636 1.1684 1.1729 1.1776 1.1815 1.1857 1.1898
190 1.1501 1.1545 1.1589 1.1637 1.1681 1.1727 1.1767 1.1807 1.1846
200 1.1461 1.1502 1.1546 1.1591 1.1636 1.1681 1.1718 1.1758 1.1798
____________________________________________________________________________________
Polymer (B): poly(phenylmethylsiloxane) 1993JAN

Characterization: Mw/kg.mol−1 = 2.5
___________________________________________________________
P/MPa T/K
339.6 350.5 361.7 371.5 397.3
Vspez/cm3g−1
___________________________________________________________
10 0.8931 0.9009 0.9086 0.9142 0.9269
15 0.8899 0.8977 0.9052 0.9104 0.9227
20 0.8874 0.8951 0.9022 0.9076 0.9196
25 0.8849 0.8926 0.8996 0.9047 0.9164
30 0.8826 0.8901 0.8970 0.9022 0.9135
35 0.8804 0.8880 0.8948 0.8998 0.9110
40 0.8783 0.8858 0.8925 0.8972 0.9082
45 0.8763 0.8836 0.8901 0.8950 0.9057
___________________________________________________________
continued
6. PVT Data 563
____________________________________________________________________________________
continued
___________________________________________________________
50 0.8744 0.8816 0.8881 0.8928 0.9034
55 0.8723 0.8802 0.8860 0.8905 0.9010
60 0.8705 0.8775 0.8837 0.8884 0.8987
65 0.8687 0.8758 0.8819 0.8864 0.8966
70 0.8669 0.8737 0.8799 0.8843 0.8944
75 0.8650 0.8719 0.8779 0.8823 0.8923
80 0.8634 0.8703 0.8763 0.8805 0.8903
85 0.8617 0.8685 0.8744 0.8785 0.8882
90 0.8599 0.8666 0.8726 0.8766 0.8864
95 0.8585 0.8651 0.8710 0.8749 0.8846
100 0.8569 0.8634 0.8699 0.8732 0.8826
___________________________________________________________
Polymer (B): poly(propylene) 1993ROG

Characterization: Mw/kg.mol−1 = 30, atactic,
_______________________________________________________________
P/MPa T/K
353.15 363.15 373.15 383.15 393.15
3 −1
Vspez/cm g
_______________________________________________________________
0.1 1.2095 1.2164 1.2261 1.2366 1.2468
10 1.1979 1.2137 1.2137 1.2233 1.2326
20 1.1863 1.1939 1.2102 1.2102 1.2187
30 1.1773 1.1844 1.1922 1.1997 1.2081
40 1.1693 1.1761 1.1832 1.1903 1.1983
50 1.1620 1.1685 1.1752 1.1820 1.1897
60 1.1550 1.1615 1.1675 1.1740 1.1815
70 1.1486 1.1548 1.1604 1.1669 1.1736
80 1.1424 1.1481 1.1539 1.1601 1.1666
90 1.1367 1.1428 1.1478 1.1539 1.1599
100 1.1312 1.1369 1.1419 1.1479 1.1536
_______________________________________________________________
Polymer (B): polypropylene 1999MAI

−1 −1
Characterization: Mn/kg.mol = 140, Mw/kg.mol = 280, isotactic,
____________________________________________________________________________________
P/MPa T/K
455.25 465.60 475.80
485.75 495.55 505.70 515.80 525.50 535.50
Vspez/cm3g−1
____________________________________________________________________________________
0.1 1.2993 1.3087 1.3185 1.3281 1.3379 1.3480 1.3589 1.3691 1.3782
10 1.2830 1.2915 1.3003 1.3089 1.3178 1.3266 1.3361 1.3450 1.3526
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
____________________________________________________________________________________
20 1.2685 1.2762 1.2843 1.2921 1.3002 1.3080 1.3165 1.3245 1.3310
30 1.2565 1.2635 1.2712 1.2783 1.2861 1.2930 1.3010 1.3081 1.3140
40 1.2453 1.2524 1.2595 1.2662 1.2735 1.2801 1.2874 1.2941 1.2993
50 1.2355 1.2418 1.2490 1.2555 1.2622 1.2683 1.2753 1.2815 1.2864
60 1.2267 1.2327 1.2392 1.2457 1.2521 1.2580 1.2644 1.2705 1.2749
70 1.2185 1.2243 1.2305 1.2364 1.2428 1.2485 1.2546 1.2603 1.2646
80 1.2109 1.2166 1.2226 1.2281 1.2340 1.2398 1.2455 1.2511 1.2550
90 1.2038 1.2093 1.2150 1.2206 1.2260 1.2312 1.2372 1.2423 1.2463
100 1.1973 1.2025 1.2081 1.2134 1.2186 1.2236 1.2289 1.2344 1.2381
110 1.1910 1.1961 1.2015 1.2066 1.2117 1.2166 1.2217 1.2265 1.2305
120 1.1851 1.1900 1.1953 1.2002 1.2051 1.2098 1.2149 1.2193 1.2228
130 1.1795 1.1842 1.1893 1.1942 1.1991 1.2035 1.2083 1.2127 1.2161
140 1.1741 1.1786 1.1838 1.1884 1.1931 1.1975 1.2021 1.2063 1.2097
150 1.1689 1.1734 1.1783 1.1831 1.1875 1.1918 1.1963 1.2003 1.2036
160 1.1640 1.1684 1.1732 1.1777 1.1821 1.1863 1.1907 1.1946 1.1978
170 1.1594 1.1636 1.1682 1.1728 1.1771 1.1810 1.1853 1.1891 1.1923
180 1.1548 1.1589 1.1634 1.1679 1.1721 1.1760 1.1803 1.1839 1.1870
190 1.1505 1.1545 1.1589 1.1635 1.1674 1.1712 1.1754 1.1788 1.1820
200 1.1463 1.1502 1.1546 1.1589 1.1629 1.1667 1.1708 1.1741 1.1771
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 2004BOL

Characterization: Mn/kg.mol−1 = 0.425
____________________________________________________________________________________
P/MPa T/K
293.15 303.15 313.15 323.15 333.15 343.15 353.15 363.15 373.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.9804 0.9881 0.9950 1.0040 1.0121 1.0215 1.0309 1.0395 1.0493
10 0.9747 0.9823 0.9891 0.9970 1.0050 1.0142 1.0225 1.0320 1.0406
20 0.9699 0.9766 0.9843 0.9911 0.9990 1.0070 1.0152 1.0235 1.0331
30 0.9653 0.9718 0.9785 0.9852 0.9921 1.0000 1.0081 1.0163 1.0246
40 0.9606 0.9671 0.9737 0.9794 0.9872 0.9940 1.0020 1.0101 1.0183
50 0.9560 0.9625 0.9690 0.9747 0.9814 0.9881 0.9960 1.0040 1.0121
60 0.9524 0.9588 0.9643 0.9699 0.9766 0.9833 0.9911 0.9990 1.0060
70 0.9488 0.9551 0.9606 0.9662 0.9728 0.9794 0.9862 0.9940 1.0010
80 0.9452 0.9515 0.9569 0.9625 0.9690 0.9756 0.9823 0.9891 0.9960
90 0.9425 0.9479 0.9533 0.9588 0.9653 0.9718 0.9785 0.9852 0.9921
100 0.9398 0.9452 0.9506 0.9560 0.9615 0.9681 0.9747 0.9814 0.9881
____________________________________________________________________________________
Polymer (B): polystyrene 1989OUG

continued
6. PVT Data 565
____________________________________________________________________________________
continued
____________________________________________________________________________________
P/MPa T/K
391.45 413.75 435.55
455.75 478.55 501.05 534.95 556.25 557.25
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.9858 0.9981 1.0111 1.0231 1.0365 1.0500 1.0711 1.0855 1.1003
10 0.9804 0.9921 1.0044 1.0158 1.0285 1.0411 1.0607 1.0739 1.0875
20 0.9752 0.9865 0.9981 1.0090 1.0209 1.0326 1.0511 1.0632 1.0756
30 0.9704 0.9812 0.9925 1.0028 1.0142 1.0254 1.0428 1.0542 1.0657
40 0.9659 0.9762 0.9870 0.9970 1.0080 1.0186 1.0351 1.0457 1.0567
50 0.9617 0.9715 0.9821 0.9916 1.0021 1.0124 1.0282 1.0383 1.0488
60 0.9580 0.9672 0.9772 0.9866 0.9966 1.0064 1.0215 1.0311 1.0411
70 0.9546 0.9630 0.9728 0.9819 0.9916 1.0010 1.0154 1.0246 1.0342
80 0.9516 0.9589 0.9685 0.9773 0.9867 0.9959 1.0098 1.0187 1.0279
90 0.9486 0.9551 0.9644 0.9731 0.9822 0.9909 1.0045 1.0130 1.0218
100 0.9459 0.9515 0.9605 0.9689 0.9778 0.9863 0.9994 1.0076 1.0163
110 0.9435 0.9480 0.9568 0.9650 0.9737 0.9820 0.9945 1.0026 1.0109
120 0.9409 0.9448 0.9533 0.9613 0.9697 0.9778 0.9902 0.9978 1.0059
130 0.9386 0.9417 0.9498 0.9576 0.9658 0.9737 0.9857 0.9932 1.0016
140 0.9363 0.9388 0.9464 0.9541 0.9623 0.9699 0.9816 0.9890 0.9966
150 0.9342 0.9362 0.9432 0.9507 0.9587 0.9662 0.9775 0.9847 0.9920
160 0.9320 0.9336 0.9401 0.9475 0.9552 0.9625 0.9736 0.9806 0.9878
170 0.9299 0.9312 0.9371 0.9443 0.9518 0.9590 0.9698 0.9767 0.9837
180 0.9279 0.9289 0.9341 0.9412 0.9486 0.9556 0.9662 0.9729 0.9798
190 0.9260 0.9266 0.9313 0.9381 0.9454 0.9523 0.9627 0.9691 0.9759
200 0.9240 0.9246 0.9285 0.9353 0.9424 0.9490 0.9592 0.9656 0.9723
____________________________________________________________________________________
Polymer (B): poly(vinyl chloride) 1993ROG

Characterization: Mw/kg.mol−1 = 63, Vista Chemical
_______________________________________________________________
P/MPa T/K
373.35 383.25393.25 403.25 413.25 423.25
Vspez/cm3g−1
_______________________________________________________________
0.1 0.7401 0.7432 0.7476 0.7519 0.7561 0.7610
10 0.7363 0.7394 0.7436 0.7474 0.7512 0.7561
20 0.7322 0.7358 0.7397 0.7425 0.7456 0.7509
30 0.7289 0.7321 0.7361 0.7391 0.7421 0.7470
40 0.7260 0.7291 0.7329 0.7355 0.7385 0.7431
50 0.7263 0.7296 0.7322 0.7351 0.7396
60 0.7234 0.7266 0.7291 0.7320 0.7362
70 0.7207 0.7238 0.7263 0.7287 0.7330
80 0.7182 0.7211 0.7235 0.7259 0.7301
90 0.7188 0.7208 0.7232 0.7273
100 0.7162 0.7184 0.7208 0.7244
___________________________________________________________
continued
____________________________________________________________________________________
continued
___________________________________________________________
110 0.7139 0.7158 0.7184 0.7219
120 0.7114 0.7136 0.7158 0.7194
130 0.7114 0.7136 0.7171
140 0.7092 0.7113 0.7145
150 0.7071 0.7092 0.7122
160 0.7052 0.7071 0.7099
170 0.7033 0.7048 0.7080
_______________________________________________________________
Polymer (B): poly(vinylidene fluoride) 2001MEK

ATOFINA Chemicals, Inc., Philadelphia, PA
____________________________________________________________________________________
P/MPa T/K
453.15 458.15 463.15
468.15 473.15 478.15 483.15 488.15 493.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.6716 0.6742 0.6766 0.6782 0.6801 0.6813 0.6829 0.6849 0.6866
20 0.6615 0.6640 0.6662 0.6680 0.6697 0.6712 0.6733 0.6752 0.6768
40 0.6514 0.6534 0.6553 0.6574 0.6593 0.6615 0.6636 0.6654 0.6670
80 0.6368 0.6384 0.6398 0.6415 0.6430 0.6446 0.6463 0.6476 0.6490
120 0.6238 0.6267 0.6281 0.6296 0.6310 0.6323 0.6338 0.6352 0.6363
____________________________________________________________________________________
Polymer (B): poly(vinyl methyl ether) 1993JAN

Characterization: Mw/kg.mol−1 = 64
____________________________________________________________________________________
P/MPa T/K
311.5 340.3 353.5 374.5 394.5 415.5
Vspez/cm3g−1
____________________________________________________________________________________
0.1 0.9671 0.9861 0.9935 1.0053 1.0189 1.0344
5.0 0.9646 0.9830 0.9902 1.0016 1.0149 1.0299
10.0 0.9621 0.9799 0.9870 0.9981 1.0110 1.0257
20.0 0.9574 0.9742 0.9809 0.9913 1.0038 1.0174
30.0 0.9528 0.9687 0.9754 0.9853 0.9973 1.0105
40.0 0.9485 0.9637 0.9703 0.9795 0.9909 1.0034
50.0 0.9443 0.9589 0.9654 0.9742 0.9850 0.9971
60.0 0.9404 0.9545 0.9608 0.9692 0.9796 0.9915
70.0 0.9366 0.9501 0.9564 0.9645 0.9747 0.9859
80.0 0.9329 0.9462 0.9523 0.9600 0.9699 0.9808
90.0 0.9296 0.9423 0.9484 0.9558 0.9653 0.9760
100.0 0.9263 0.9387 0.9447 0.9518 0.9609 0.9714
110.0 0.9232 0.9351 0.9412 0.9480 0.9571 0.9671
120.0 0.9202 0.9318 0.9379 0.9443 0.9531 0.9630
____________________________________________________________________________________
6. PVT Data 567
____________________________________________________________________________________
6.2. Excess volumes and/or densities at elevated pressures

6.2.1. Binary polymer solutions
Polymer (B): ethylene/1-butene copolymer 2000BY2

Characterization: Mn/kg.mol−1 = 175, Mw/kg.mol−1 = 177, 94 mol% 1-butene,
Exxon Research and Engineering Co.
T/K = 383.15 wB 0.05
P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5
ρ/g cm−3 0.669 0.683 0.701 0.725 0.763 0.793 0.818 0.840 0.860
T/K = 393.15 wB 0.05
P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5
ρ/g cm−3 0.660 0.675 0.694 0.719 0.759 0.790 0.816 0.839 0.859
T/K = 403.15 wB 0.05
P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5
ρ/g cm−3 0.643 0.659 0.678 0.705 0.746 0.777 0.803 0.826 0.846
T/K = 423.15 wB 0.05
P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5
ρ/g cm−3 0.612 0.632 0.655 0.684 0.727 0.760 0.787 0.811 0.831

Solvent (A): dimethyl ether-d6 C2D6O 17222-37-6
T/K = 383.15 wB 0.05
P/bar 1001.7 1036.2 1105.2 1174.1 1280.6 1381.0 1484.5 1725.9 1932.8
ρ/g cm−3 0.850 0.857 0.860 0.868 0.872 0.889 0.898 0.921 0.938
P/bar 2070.7 2312.1 2401.7
ρ/g cm−3 0.949 0.969 0.980
T/K = 393.15 wB 0.05
P/bar 760.3 829.3 1036.2 1381.0 1725.9 2070.7 2415.5
ρ/g cm−3 0.813 0.823 0.848 0.883 0.915 0.945 0.959
T/K = 403.15 wB 0.05
P/bar 650.0 670.7 691.4 829.3 1036.2 1381.0 1725.9 2139.7 2415.5
ρ/g cm−3 0.778 0.781 0.785 0.804 0.830 0.866 0.896 0.929 0.959
T/K = 423.15 wB 0.05
P/bar 622.4 691.4 829.3 1036.2 1381.0 1725.9 2070.7 2415.5
ρ/g cm−3 0.748 0.760 0.782 0.809 0.846 0.878 0.906 0.933
____________________________________________________________________________________

Solvent (A): dimethyl ether-d6 C2D6O 17222-37-6
T/K = 383.15 wB 0.05
P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5
ρ/g cm−3 0.685 0.698 0.715 0.739 0.776 0.804 0.828 0.849 0.867
T/K = 393.15 wB 0.05
P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5
ρ/g cm−3 0.676 0.690 0.708 0.733 0.772 0.801 0.826 0.847 0.866
T/K = 403.15 wB 0.05
P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5
ρ/g cm−3 0.659 0.675 0.694 0.720 0.759 0.789 0.814 0.835 0.854
T/K = 423.15 wB 0.05
P/bar 346.6 415.5 519.0 691.4 1036.2 1381.0 1725.9 2070.7 2415.5
ρ/g cm−3 0.630 0.649 0.671 0.699 0.740 0.772 0.798 0.821 0.840
Polymer (B): ethylene/1-butene copolymer (deuterated) 2000BY1

synthesized from polymerization of deuterated 1,3-butadiene with
controlled 1,2-addition, Polymer Source, Inc., Dorval, Quebec
T/K = 393.15 wB 0.024
P/bar 1242.8 1311.7 1380.7 1518.5 1725.4 1897.8 2070.1 2242.5 2414.9
ρ/g cm−3 0.511 0.518 0.523 0.532 0.546 0.554 0.563 0.571 0.580
T/K = 403.15 wB 0.024
P/bar 1242.8 1311.7 1380.7 1518.5 1725.4 1897.8 2070.1 2242.5 2414.9
ρ/g cm−3 0.506 0.513 0.518 0.528 0.541 0.551 0.561 0.570 0.578
T/K = 423.15 wB 0.024
P/bar 1242.8 1311.7 1380.7 1518.5 1725.4 1897.8 2070.1 2242.5 2414.9
ρ/g cm−3 0.497 0.503 0.508 0.519 0.533 0.543 0.553 0.562 0.571

T/K = 383.15 wB 0.053
P/bar 70.7 139.6 208.6 277.5 346.5 518.8 691.2 1035.9 1380.7
ρ/g cm−3 0.560 0.575 0.586 0.596 0.605 0.623 0.638 0.664 0.685
continued
6. PVT Data 569
____________________________________________________________________________________
continued
P/bar 2070.1 2414.9
ρ/g cm−3 0.719 0.733
T/K = 403.15 wB 0.053
P/bar 45.2 70.7 139.6 208.6 277.5 346.5 415.4 484.4 553.3
ρ/g cm−3 0.528 0.536 0.555 0.569 0.581 0.591 0.599 0.607 0.614
P/bar 622.2 691.2 760.1 829.1 898.0 967.0 1035.9 1104.9 1173.8
ρ/g cm−3 0.621 0.627 0.633 0.639 0.644 0.649 0.654 0.659 0.663
P/bar 1242.8 1311.7 1380.7 1449.6 1518.5 1587.5 1656.4 1725.4 1794.3
−3
ρ/g cm 0.668 0.672 0.676 0.680 0.684 0.688 0.691 0.695 0.698
P/bar 1863.3 1932.2 2001.2 2070.1
ρ/g cm−3 0.702 0.705 0.708 0.712
T/K = 423.15 wB 0.053
P/bar 105.1 139.6 208.6 277.5 346.5 518.8 691.2 1035.9 1380.7
ρ/g cm−3 0.525 0.535 0.552 0.566 0.577 0.599 0.617 0.645 0.668
P/bar 2070.1 2414.9
−3
ρ/g cm 0.704 0.720

Solvent (A): n-pentane-d12 C5D12 2031-90-5
T/K = 383.15 wB 0.051

P/bar 70.7 139.6 208.6 277.5 346.5 518.8 691.2 1035.9 1380.7
ρ/g cm−3 0.644 0.662 0.676 0.688 0.699 0.722 0.740 0.771 0.796
P/bar 2070.1 2414.9
−3
ρ/g cm 0.837 0.855
T/K = 403.15 wB 0.051
P/bar 70.7 77.6 84.5 91.3 105.1 125.8 139.6 174.1 208.6
ρ/g cm−3 0.617 0.619 0.621 0.624 0.628 0.634 0.638 0.647 0.655
P/bar 277.5 346.5 518.8 689.5 1034.2 1380.7 2070.1 2414.9
ρ/g cm−3 0.669 0.681 0.705 0.725 0.757 0.783 0.826 0.844
T/K = 423.15 wB 0.051
P/bar 108.6 139.6 208.6 277.5 346.5 518.8 691.2 1035.9 1380.7
ρ/g cm−3 0.605 0.616 0.635 0.651 0.664 0.692 0.714 0.747 0.774
P/bar 2070.1 2414.9
−3
ρ/g cm 0.818 0.837
____________________________________________________________________________________
Polymer (B): polybutadiene 1999INO

low cis-butadiene rubber
wB = 0.92
____________________________________________________________________________________
P/MPa T/K
303.15 328.15 353.15
378.15 403.15 428.15 453.15 478.15 503.15
Vspez/cm3g−1
____________________________________________________________________________________
0.1 1.23 1.24 1.26 1.28 1.30 1.32 1.34 1.36 1.38
20 1.22 1.23 1.25 1.26 1.28 1.30 1.31 1.33 1.35
40 1.21 1.22 1.24 1.25 1.26 1.28 1.30 1.31 1.32
60 1.20 1.21 1.22 1.24 1.25 1.27 1.28 1.29 1.31
80 1.19 1.20 1.21 1.23 1.24 1.25 1.27 1.28 1.29
100 1.18 1.19 1.21 1.22 1.23 1.24 1.26 1.27 1.28
120 1.17 1.19 1.20 1.21 1.22 1.23 1.25 1.26 1.27
150 1.17 1.18 1.19 1.20 1.21 1.22 1.23 1.24 1.25
____________________________________________________________________________________
Polymer (B): poly(dimethylsiloxane) 1994MER

Wacker GmbH, Munich, Germany
T/K = 313.15 P/MPa = 30.0

ϕB 0.3 0.5 0.75 0.9
VE/cm3 g−1 −0.0055 −0.0089 −0.0082 −0.0043
Comments: The data were taken from Fig. 4 in the original source.
Polymer (B): poly(dimethylsiloxane) 2002DIN

wB = 0.055 T/K = 328.15

P/MPa 48.70 44.93 41.74 39.29 34.72 33.19 33.19 30.78 28.04
ρ/g cm−3 0.9801 0.9663 0.9534 0.9420 0.9189 0.9090 0.9090 0.8959 0.8765
wB = 0.055 T/K = 343.15
P/MPa 48.45 46.38 44.90 43.38 41.54 40.07 38.17 35.86 35.16
ρ/g cm−3 0.9349 0.9349 0.9222 0.9203 0.9064 0.9030 0.8887 0.8759 0.8723
continued
6. PVT Data 571
____________________________________________________________________________________
continued
wB = 0.055 T/K = 358.15
P/MPa 48.28 44.83 41.59 39.41 37.75
ρ/g cm−3 0.9054 0.8901 0.8734 0.8548 0.8476
wB = 0.055 T/K = 373.15
P/MPa 48.21 46.55 44.83 43.79
ρ/g cm−3 0.8610 0.8503 0.8396 0.8325
Polymer (B): poly(dimethylsiloxane) 1979REN

T-range/K = 298.15 to 338.15 P-range/bar = 0.1 to 1000

Coefficients of Tait equation ( ϑ is the temperature in °C):
{ }
Vspez = ( A1 + A2ϑ + A3ϑ 2 ) / 1 − A4 ln 1 + P / A5 e − A6ϑ 
____________________________________________________________________________________
ϕB A1/g cm−3 103A2/g cm−3 °C−1 106A3/g cm−3 °C−2 100A4 10−3A5/bar 103B6/°C−1
____________________________________________________________________________________
0.3530 1.07707 3.34760 −0.01903 9.136689 0.939672 7.512650
0.5017 1.10646 1.13189 1.24603 9.061028 0.962103 7.913653
____________________________________________________________________________________
Polymer (B): poly(dimethylsiloxane) 1979REN

Solvent (A): hexamethyldisiloxane C6H18OSi2 107-46-0

{ }
____________________________________________________________________________________
____________________________________________________________________________________
0.4370 1.12518 1.38201 0.72986 9.227156 0.701099 7.974029
0.6497 1.04932 1.80918 −3.75208 8.568493 0.681781 7.013003
____________________________________________________________________________________
____________________________________________________________________________________

__________________________________________________________________
P/MPa wB
0.00 0.20 0.40 0.60 0.80 1.00
ρ/g cm−3
__________________________________________________________________
T/K = 393.2
__________________________________________________________________
68.64 2.39 2.15 1.91 1.67 1.43 1.19
78.45 2.30 2.07 1.85 1.62 1.40 1.18
98.67 2.18 1.94 1.77 1.57 1.36 1.16
117.7 2.09 1.90 1.71 1.52 1.33 1.14
137.3 2.01 1.84 1.66 1.48 1.31 1.13
156.9 1.96 1.79 1.62 1.45 1.29 1.12
176.5 1.90 1.75 1.59 1.43 1.27 1.11
196.1 1.86 1.71 1.56 1.40 1.25 1.10
__________________________________________________________________
T/K = 433.2
__________________________________________________________________
68.64 2.58 2.30 2.03 1.76 1.49 1.22
78.45 2.46 2.21 1.96 1.71 1.46 1.21
98.67 2.31 2.08 1.86 1.64 1.41 1.19
117.7 2.19 1.99 1.78 1.58 1.38 1.17
137.3 2.11 1.92 1.73 1.54 1.35 1.16
156.9 2.04 1.86 1.68 1.50 1.32 1.14
176.5 1.98 1.81 1.64 1.47 1.30 1.13
196.1 1.94 1.77 1.61 1.44 1.28 1.12
__________________________________________________________________
T/K = 473.2
__________________________________________________________________
58.84 2.95 2.62 2.28 1.94 1.60 1.26
68.64 2.77 2.47 2.16 1.86 1.56 1.25
78.45 2.63 2.36 2.08 1.80 1.52 1.24
98.67 2.44 2.20 1.95 1.71 1.46 1.22
117.7 2.30 2.08 1.86 1.64 1.42 1.20
137.3 2.21 2.00 1.80 1.59 1.39 1.18
156.9 2.13 1.94 1.74 1.55 1.36 1.17
176.5 2.06 1.88 1.70 1.52 1.34 1.15
196.1 2.01 1.83 1.66 1.49 1.31 1.14
__________________________________________________________________
6. PVT Data 573
____________________________________________________________________________________

__________________________________________________________________
P/MPa wB
0.00 0.20
0.40 0.60 0.80 1.00
ρ/g cm−3
__________________________________________________________________
T/K = 393.2
__________________________________________________________________
137.3 2.01 1.83 1.65 1.47 1.29 1.11
156.9 1.96 1.78 1.61 1.44 1.27 1.10
176.5 1.90 1.74 1.58 1.42 1.26 1.09
196.1 1.86 1.71 1.55 1.40 1.24 1.08
__________________________________________________________________
T/K = 433.2
__________________________________________________________________
137.3 2.11 1.91 1.72 1.53 1.33 1.14
156.9 2.04 1.86 1.67 1.49 1.31 1.13
176.5 1.98 1.81 1.63 1.46 1.29 1.11
196.1 1.94 1.77 1.60 1.44 1.27 1.10
__________________________________________________________________
T/K = 473.2
__________________________________________________________________
137.3 2.21 2.00 1.79 1.58 1.37 1.16
156.9 2.13 1.93 1.73 1.54 1.34 1.15
176.5 2.06 1.87 1.69 1.50 1.32 1.13
196.1 2.01 1.83 1.65 1.47 1.30 1.12
__________________________________________________________________
Polymer (B): polyethylene 2002DIN

wB = 0.0574 T/K = 413.15

P/MPa 48.51 41.81 34.40 24.26 21.55 18.62 17.59
ρ/g cm−3 0.5751 0.5623 0.5511 0.5346 0.5296 0.5296 0.5255
wB = 0.0574 T/K = 423.15
P/MPa 48.29 44.86 41.65 34.88 31.34 27.76 20.83 15.52 12.97
ρ/g cm−3 0.5819 0.5780 0.5737 0.5648 0.5597 0.5538 0.5411 0.5310 0.5255
____________________________________________________________________________________
Polymer (B): polyethylene 1998AAL

Characterization: Mn/kg.mol−1 = 0.30, Mw/kg.mol−1 = 0.49, LLDPE,
Borealis Pilot Plant, Finland
wB = 0.0094
T/K 358.5 358.6 358.6 358.6 358.6 358.6 358.6 363.5 363.5
P/MPa 4.998 5.502 5.998 6.197 6.406 6.596 7.000 5.502 5.998
ρ/g cm−3 0.3881 0.3951 0.3990 0.4008 0.4023 0.4045 0.4070 0.3782 0.3846
T/K 363.5 363.5 363.5 363.6 368.3 368.4 368.4 368.4 368.4
P/MPa 6.197 6.399 6.603 6.995 6.004 6.201 6.399 6.599 7.001
ρ/g cm−3 0.3873 0.3892 0.3925 0.3956 0.3696 0.3727 0.3755 0.3789 0.3826
wB = 0.0097
T/K 353.8 353.9 353.9 353.9 353.9 353.9 353.9 353.9
P/MPa 3.999 4.994 5.498 5.998 6.200 6.400 6.603 7.004
ρ/g cm−3 0.3894 0.4018 0.4070 0.4115 0.4131 0.4149 0.4157 0.4199
T/K 373.5 373.5 373.5 373.5 378.2 378.2 378.2 378.2
P/MPa 6.198 6.399 6.603 6.998 6.202 6.400 6.600 6.999
ρ/g cm−3 0.3560 0.3615 0.3647 0.3708 0.3375 0.3422 0.3469 0.3549
wB = 0.0101
T/K 358.5 358.5 358.5 358.5 358.5 358.5 358.5 363.5 363.5
P/MPa 4.996 5.502 5.997 6.203 6.400 6.602 7.000 5.497 6.003
ρ/g cm−3 0.3877 0.3937 0.3984 0.4006 0.4033 0.4050 0.4090 0.3792 0.3854
T/K 363.5 363.5 363.5 363.5 368.3 368.3 368.3 368.3 368.3
P/MPa 6.200 6.398 6.599 6.998 5.997 6.202 6.402 6.602 6.999
ρ/g cm−3 0.3874 0.3901 0.3922 0.3970 0.3694 0.3728 0.3759 0.3781 0.3837
wB = 0.0232
T/K 358.7 358.7 358.7 358.7 358.7 358.7 358.8 363.7 363.7
P/MPa 5.000 5.498 6.000 6.204 6.398 6.601 7.000 5.501 6.001
ρ/g cm−3 0.3937 0.4005 0.4047 0.4072 0.4092 0.4112 0.4148 0.3853 0.3923
T/K 363.7 363.7 363.7 363.7 368.6 368.6 368.6 368.6 368.6
P/MPa 6.203 6.401 6.603 7.000 5.997 6.202 6.399 6.602 6.999
ρ/g cm−3 0.3947 0.3967 0.3994 0.4033 0.3770 0.3799 0.3829 0.3856 0.3897
wB = 0.0355
T/K 358.7 358.7 358.7 358.7 358.7 358.7 358.7 368.5 368.5
P/MPa 5.001 5.500 6.001 6.202 6.401 6.601 6.999 6.001 6.199
ρ/g cm−3 0.3966 0.4027 0.4079 0.4101 0.4115 0.4131 0.4164 0.3811
T/K 368.5 368.5 368.5 368.5
P/MPa 6.399 6.600 6.997 7.097
ρ/g cm−3 0.3842 0.3871 0.3895 0.3937 0.3950
6. PVT Data 575
____________________________________________________________________________________

Solvent (A): anisole C7H8O 100-66-3
____________________________________________________________________________________
P/MPa wB
0.0000 0.1775 0.3268 0.4542 0.5642 0.6600 0.7444 0.8859 1.0000
−3
ρ/g cm
____________________________________________________________________________________
T/K = 298.15
____________________________________________________________________________________
0.1 0.9888 1.0061 1.0241 1.0405 1.0541 1.0665 1.0773 1.1008 1.1179
10 0.9951 1.0122 1.0298 1.0462 1.0596 1.0724 1.0832 1.1054 1.1235
20 1.0012 1.0177 1.0357 1.0512 1.0644 1.0770 1.0880 1.1101 1.1278
30 1.0068 1.0235 1.0406 1.0561 1.0697 1.0821 1.0926 1.1143 1.1316
40 1.0122 1.0287 1.0456 1.0611 1.0740 1.0863 1.0969 1.1186 1.1361
50 1.0172 1.0336 1.0504 1.0658 1.0789 1.0910 1.1017 1.1227 1.1401
____________________________________________________________________________________
T/K = 318.15
____________________________________________________________________________________
0.1 0.9689 0.9879 1.0061 1.0245 1.0367 1.0484 1.0611 1.0844 1.1108
10 0.9767 0.9943 1.0123 1.0306 1.0431 1.0554 1.0663 1.0894 1.1088
20 0.9836 1.0006 1.0185 1.0346 1.0485 1.0605 1.0713 1.0941 1.1131
30 0.9898 1.0065 1.0242 1.0397 1.0536 1.0657 1.0760 1.0988 1.1176
40 0.9954 1.0122 1.0293 1.0448 1.0585 1.0705 1.0805 1.1031 1.1215
50 1.0010 1.0176 1.0345 1.0499 1.0634 1.0750 1.0859 1.1075 1.1256
____________________________________________________________________________________
T/K = 338.15
____________________________________________________________________________________
0.1 0.9564 0.9692 0.9867 1.0062 1.0184 1.0327 1.0444 1.0659 1.0903
10 0.9581 0.9774 0.9945 1.0125 1.0258 1.0385 1.0502 1.0737 1.0930
20 0.9655 0.9832 1.0005 1.0169 1.0310 1.0434 1.0543 1.0779 1.0970
30 0.9724 0.9889 1.0068 1.0230 1.0369 1.0488 1.0594 1.0834 1.1019
40 0.9789 0.9961 1.0131 1.0290 1.0428 1.0544 1.0651 1.0884 1.1064
50 0.9851 1.0020 1.0187 1.0339 1.0481 1.0596 1.0705 1.0934 1.1120
____________________________________________________________________________________
____________________________________________________________________________________

Solvent (A): 1-octanol C8H18O 111-87-5
_____________________________________________________________________________________________
P/MPa wB
0.1458 0.2774 0.3969 0.5059 0.6056 0.6973 0.7818 0.8600 0.9325
ρ/g cm−3
_____________________________________________________________________________________________
T/K = 298.15
_____________________________________________________________________________________________
0.1 0.8534 0.8849 0.9159 0.9466 0.9765 1.0061 1.0351 1.0634 1.0916
5 0.8566 0.8880 0.9189 0.9495 0.9793 1.0088 1.0376 1.0659 1.0940
10 0.8597 0.8910 0.9218 0.9523 0.9821 1.0114 1.0402 1.0683 1.0963
15 0.8627 0.8939 0.9246 0.9551 0.9847 1.0139 1.0426 1.0706 1.0986
20 0.8656 0.8967 0.9273 0.9577 0.9872 1.0164 1.0450 1.0729 1.1007
25 0.8683 0.8997 0.9299 0.9603 0.9897 1.0187 1.0472 1.0751 1.1028
30 0.8710 0.9020 0.9325 0.9628 0.9921 1.0210 1.0494 1.0772 1.1049
_____________________________________________________________________________________________
T/K = 318.15
_____________________________________________________________________________________________
0.1 0.8394 0.8707 0.9015 0.9321 0.9617 0.9910 1.0199 1.0480 1.0760
5 0.8428 0.8740 0.9047 0.9351 0.9648 0.9929 1.0226 1.0506 1.0785
10 0.8462 0.8773 0.9079 0.9382 0.9677 0.9967 1.0253 1.0532 1.0809
15 0.8495 0.8805 0.9109 0.9411 0.9705 0.9994 1.0279 1.0557 1.0833
20 0.8526 0.8835 0.9138 0.9440 0.9733 1.0021 1.0304 1.0581 1.0856
25 0.8556 0.8865 0.9167 0.9468 0.9761 1.0047 1.0329 1.0605 1.0879
30 0.8586 0.8894 0.9195 0.9495 0.9786 1.0072 1.0354 1.0629 1.0901
_____________________________________________________________________________________________
T/K = 328.15
_____________________________________________________________________________________________
0.1 0.8320 0.8630 0.8936 0.8241 0.9537 0.9830 1.0118 1.0399 1.0680
5 0.8356 0.8665 0.8970 0.8273 0.9569 0.9860 1.0146 1.0426 1.0706
10 0.8392 0.8700 0.9003 0.9305 0.9599 0.9890 1.0175 1.0453 1.0732
15 0.8427 0.8732 0.9035 0.9336 0.9629 0.9918 1.0202 1.0480 1.0757
20 0.8458 0.8764 0.9066 0.9366 0.9667 0.9945 1.0228 1.0505 1.0781
25 0.8489 0.8794 0.9095 0.9394 0.9685 0.9972 1.0254 1.0529 1.0804
30 0.8519 0.8824 0.9124 0.9422 0.9712 0.9998 1.0279 1.0553 1.0827
_____________________________________________________________________________________________
T/K = 338.15
_____________________________________________________________________________________________
0.1 0.8248 0.8558 0.8863 0.9167 0.9462 0.9756 1.0043 1.0322 1.0603
5 0.8286 0.8596 0.8899 0.9201 0.9495 0.9788 1.0072 1.0350 1.0630
10 0.8323 0.8632 0.8934 0.9235 0.9528 0.9818 1.0102 1.0378 1.0656
15 0.8358 0.8666 0.8967 0.9267 0.9558 0.9848 1.0130 1.0405 1.0682
20 0.8392 0.8699 0.8998 0.9297 0.9588 0.9876 1.0157 1.0431 1.0707
25 0.8425 0.8730 0.9029 0.9327 0.9616 0.9904 1.0184 1.0456 1.0731
30 0.8455 0.8760 0.9058 0.9355 0.9644 0.9931 1.0209 1.0481 1.0755
_____________________________________________________________________________________________
6. PVT Data 577
____________________________________________________________________________________

_____________________________________________________________________________________________
P/MPa wB
0.3386 0.5353 0.6638 0.7544 0.8217 0.8736 0.9146 0.9485 0.9765
ρ/g cm−3
_____________________________________________________________________________________________
T/K = 298.15
_____________________________________________________________________________________________
0.1 0.9019 0.9567 0.9968 1.0270 1.0509 1.0704 1.0861 1.0999 1.1113
5 0.9049 0.9596 0.9995 1.0297 1.0534 1.0729 1.0885 1.1023 1.1136
10 0.9079 0.9624 1.0022 1.0322 1.0559 1.0753 1.0909 1.1046 1.1159
15 0.9107 0.9651 1.0048 1.0348 1.0584 1.0777 1.0932 1.1069 1.1181
20 0.9135 0.9677 1.0073 1.0372 1.0607 1.0800 1.0954 1.1091 1.1203
25 0.9161 0.9702 1.0097 1.0395 1.0629 1.0822 1.0976 1.1112 1.1224
30 0.9187 0.9727 1.0120 1.0418 1.0652 1.0843 1.0997 1.1133 1.1244
_____________________________________________________________________________________________
T/K = 318.15
_____________________________________________________________________________________________
0.1 0.8875 0.9418 0.9813 1.0116 1.0351 1.0546 1.0702 1.0838 1.0949
5 0.8907 0.9449 0.9843 1.0144 1.0378 1.0573 1.0728 1.0863 1.0974
10 0.8939 0.9480 0.9872 1.0172 1.0406 1.0599 1.0754 1.0888 1.0999
15 0.8971 0.9509 0.9900 1.0199 1.0432 1.0624 1.0779 1.0912 1.1023
20 0.9001 0.9537 0.9928 1.0226 1.0457 1.0649 1.0803 1.0936 1.1045
25 0.9030 0.9565 0.9954 1.0251 1.0482 1.0673 1.0827 1.0960 1.1070
30 0.9058 0.9592 0.9980 1.0277 1.0507 1.0696 1.0850 1.0973 1.1092
_____________________________________________________________________________________________
T/K = 328.15
_____________________________________________________________________________________________
0.1 0.8797 0.9340 0.9734 1.0035 1.0268 1.0462 1.0617 1.0752 1.0865
5 0.8832 0.9372 0.9764 1.0065 1.0297 1.0490 1.0644 1.0779 1.0892
10 0.8866 0.9404 0.9795 1.0094 1.0326 1.0518 1.0671 1.0806 1.0918
15 0.8898 0.9435 0.9824 1.0122 1.0353 1.0544 1.0697 1.0832 1.0943
20 0.8929 0.9464 0.9852 1.0150 1.0380 1.0570 1.0723 1.0856 1.0967
25 0.8959 0.9493 0.9880 1.0176 1.0406 1.0595 1.0746 1.0880 1.0991
30 0.8988 0.9520 0.9907 1.0201 1.0431 1.0619 1.0771 1.0904 1.1014
_____________________________________________________________________________________________
T/K = 338.15
_____________________________________________________________________________________________
0.1 0.8724 0.9265 0.9657 0.9958 1.0193 1.0384 1.0539 1.0673 1.0786
5 0.8760 0.9299 0.9690 0.9989 1.0222 1.0413 1.0567 1.0701 1.0813
10 0.8795 0.9332 0.9721 1.0020 1.0252 1.0442 1.0595 1.0728 1.0840
15 0.8829 0.9364 0.9752 1.0049 1.0280 1.0470 1.0622 1.0755 1.0866
20 0.8861 0.9394 0.9781 1.0080 1.0308 1.0496 1.0648 1.0781 1.0891
25 0.8892 0.9424 0.9809 1.0104 1.0334 1.0522 1.0674 1.0805 1.0916
30 0.8922 0.9452 0.9836 1.0130 1.0360 1.0547 1.0698 1.0829 1.0940
_____________________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(ethylene glycol) monomethyl ether 2000LEE

Characterization: Mn/kg.mol−1 = 0.36, Mw/kg.mol −1 = 0.39,
____________________________________________________________________________________
P/MPa wB
0.0000 0.2689 0.4528
0.5866 0.6882 0.7680 0.8324 0.9298 1.0000
ρ/g cm−3
____________________________________________________________________________________
T/K = 298.15
____________________________________________________________________________________
0.1 0.9888 1.0119 1.0289 1.0421 1.0509 1.0572 1.0644 1.0727 1.0827
10 0.9951 1.0177 1.0345 1.0479 1.0565 1.0627 1.0694 1.0784 1.0888
20 1.0012 1.0234 1.0400 1.0532 1.0618 1.0678 1.0745 1.0830 1.0934
30 1.0068 1.0290 1.0453 1.0580 1.0668 1.0727 1.0793 1.0882 1.0984
40 1.0122 1.0339 1.0502 1.0630 1.0715 1.0774 1.0839 1.0923 1.1025
50 1.0172 1.0389 1.0551 1.0678 1.0766 1.0820 1.0884 1.0971 1.1071
____________________________________________________________________________________
T/K = 318.15
____________________________________________________________________________________
0.1 0.9689 0.9941 1.0111 1.0243 1.0337 1.0399 1.0468 1.0549 1.0668
10 0.9767 1.0004 1.0171 1.0305 1.0395 1.0457 1.0526 1.0612 1.0721
20 0.9836 1.0060 1.0232 1.0363 1.0450 1.0510 1.0577 1.0669 1.0774
30 0.9898 1.0121 1.0287 1.0418 1.0503 1.0564 1.0630 1.0721 1.0825
40 0.9954 1.0176 1.0339 1.0470 1.0553 1.0613 1.0679 1.0767 1.0872
50 1.0010 1.0229 1.0393 1.0520 1.0608 1.0662 1.0728 1.0815 1.0917
____________________________________________________________________________________
T/K = 338.15
____________________________________________________________________________________
0.1 0.9564 0.9743 0.9926 1.0057 1.0147 1.0223 1.0294 1.0391 1.0491
10 0.9581 0.9819 0.9992 1.0131 1.0227 1.0288 1.0357 1.0447 1.0559
20 0.9655 0.9881 1.0057 1.0192 1.0279 1.0341 1.0409 1.0501 1.0613
30 0.9724 0.9946 1.0118 1.0252 1.0339 1.0401 1.0467 1.0557 1.0664
40 0.9789 1.0012 1.0181 1.0312 1.0398 1.0458 1.0525 1.0614 1.0721
50 0.9851 1.0066 1.0238 1.0360 1.0445 1.0512 1.0574 1.0655 1.0767
____________________________________________________________________________________

Characterization: Mw/kg.mol−1 = 25–30, Mw/Mn < 1.1
T/K = 293.15 P/MPa = 0.1
zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
V/cm3 basemol−1 18.229 18.530 18.841 19.381 20.861 21.552 22.770 23.561
continued
6. PVT Data 579
____________________________________________________________________________________
continued
T/K = 293.15 P/MPa = 10
zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
V/cm3 basemol−1 18.148 18.483 18.764 19.304 20.782 21.477 22.692 23.469
T/K = 293.15 P/MPa = 20
zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
V/cm3 basemol−1 18.071 18.375 18.688 19.229 20.710 21.404 22.617 23.393
T/K = 293.15 P/MPa = 30
zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
V/cm3 basemol−1 17.995 18.301 18.616 19.156 20.642 21.333 22.545 23.310
T/K = 293.15 P/MPa = 40
zB 0.0085 0.0246 0.0411 0.0701 0.1496 0.1866 0.2509 0.2914
V/cm3 basemol−1 17.992 18.228 18.542 19.085 20.572 21.264 22.474 23.246
Comments: V is given in cm3/basemol mixture calculated with MA = 18.015 g/mol and
Polymer (B): poly(4-hydroxystyrene) 1995COM

Coefficients of Tait equation for density ρ (standard deviation is 0.1 kg m−3):
{ }
____________________________________________________________________________________
wA 10−3B1/kg m−3 B2/kg m−3 K−1 103B3/kg m−3 K−2 10B4 10−3B5/MPa 102B6/K−1
____________________________________________________________________________________
0.70005 1.1009 −0.5824 −3.7116 0.7658 0.4740 0.5375
0.74083 1.1351 −0.8828 −0.6885 0.8149 0.5521 0.5803
0.79713 1.0924 −0.7348 −1.8545 0.7925 0.5667 0.6241
0.89815 1.0631 −0.7600 −1.7199 0.7920 0.5833 0.6747
0.97003 1.0106 −0.5710 −4.8404 0.7986 0.5681 0.6920
1.00000 1.0371 −0.7983 −1.2641 0.8428 0.6103 0.7028
____________________________________________________________________________________

continued
____________________________________________________________________________________
continued
Coefficients of Tait equation for density ρ (standard deviation is about 0.0001 g/cm3):
{ }
____________________________________________________________________________________
wA B1/g cm−3 103B2/g cm−3 K−1 106B3/g cm−3 K−2 10B4 10−3B5/MPa 102B6/K−1
____________________________________________________________________________________
0.96748 1.0956 −0.0893 −0.3587 0.9135 1.1777 0.9254
0.93684 1.1691 −0.1296 0.2703 0.9088 1.2046 0.9286
0.92248 1.4034 −0.2787 2.6940 0.9229 1.3020 0.9381
0.87947 1.1693 −0,1165 0.0589 0.9070 1.1966 0.8991
0.77489 1.3852 −0.2382 2.1434 0.8065 0.9405 0.8180
0.73891 1.2048 −0.1133 0.1551 0.8809 1.1722 0.8319
0.68443 1.4138 −0.2402 2.3193 0.8738 0.9886 0.7526
0.62253 1.3365 −0.174 1.2688 0.8034 0.8702 0.7081
0.49111 2.2944 −0.7797 11.6134 0.5368 0.5368 0.3779
____________________________________________________________________________________

T/K = 298.15 P-range/MPa = 0.1 to 40

{ }
____________________________________________________________________________________
wA 10−3B1/kg m−3 B2/kg m−3 K−1 103B3/kg m−3 K−2 10B4 10−3B5/MPa 102B6/K−1
____________________________________________________________________________________
0.69313 0.98051 0.6995 0.1032
0.74866 0.96136 0.7627 0.1025
0.77397 0.95322 0.8161 0.1099
0.79769 0.94655 0.6901 0.0880
0.85693 0.92908 0.8588 0.1070
1.00000 1.21153 −1.0794 −0.6425 0.8176 1.0652 0.8540
____________________________________________________________________________________
Comments: The system had been studied at only one temperature due to the almost negligible
temperature effect observed for the mixture.
6. PVT Data 581
____________________________________________________________________________________
Polymer (B): polyisobutylene 1979REN

Solvent (A): benzene C6H6 71-43-2

{ }
____________________________________________________________________________________
____________________________________________________________________________________
0.1989 1.10102 1.10965 1.56220 8.966583 1.251642 7.851594
0.4355 1.09412 1.05658 −0.60033 8.911763 1.376756 6.862239
0.5923 1.09088 0.90293 0.15281 8.211724 1.381603 6.473317
____________________________________________________________________________________
Polymer (B): polyisobutylene 1979REN


{ }
____________________________________________________________________________________
____________________________________________________________________________________
0.1971 1.19508 1.21136 2.15655 9.125086 1.114994 7.853660
0.3731 1.17033 1.07970 0.92579 8.066102 1.134639 7.460571
0.5445 1.14672 0.91138 0.81216 8.122835 1.281160 6.457454
____________________________________________________________________________________

Solvent (A): acetophenone C8H8O 98-86-2
____________________________________________________________________________________
P/MPa wB
0.0000 0.7872 0.8927
0.9345 0.9569 0.9708 0.9804 0.9873 1.0000
ρ/g cm−3
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 298.15
____________________________________________________________________________________
0.1 1.0224 1.0052 1.0026 1.0011 1.0000 0.9994 0.9987 0.9983 0.9979
10 1.0281 1.0110 1.0086 1.0073 1.0060 1.0054 1.0049 1.0045 1.0042
15 1.0308 1.0140 1.0116 1.0103 1.0089 1.0084 1.0080 1.0075 1.0071
20 1.0335 1.0168 1.0145 1.0132 1.0119 1.0112 1.0109 1.0103 1.0100
25 1.0361 1.0197 1.0172 1.0160 1.0146 1.0141 1.0137 1.0131 1.0128
30 1.0387 1.0223 1.0199 1.0187 1.0173 1.0168 1.0164 1.0158 1.0156
35 1.0411 1.0249 1.0225 1.0214 1.0199 1.0194 1.0190 1.0185 1.0182
40 1.0436 1.0274 1.0250 1.0240 1.0226 1.0220 1.0216 1.0212 1.0208
45 1.0460 1.0300 1.0276 1.0266 1.0250 1.0246 1.0242 1.0237 1.0233
50 1.0483 1.0323 1.0301 1.0290 1.0275 1.0270 1.0267 1.0261 1.0258
____________________________________________________________________________________
T/K = 318.15
____________________________________________________________________________________
0.1 1.0053 0.9892 0.9867 0.9853 0.9844 0.9839 0.9832 0.9828 0.9828
10 1.0115 0.9958 0.9934 0.9920 0.9911 0.9904 0.9900 0.9897 0.9896
15 1.0145 0.9990 0.9966 0.9951 0.9944 0.9937 0.9933 0.9929 0.9928
20 1.0175 1.0020 0.9997 0.9983 0.9975 0.9968 0.9964 0.9961 0.9959
25 1.0204 1.0051 1.0027 1.0013 1.0005 0.9998 0.9994 0.9991 0.9990
30 1.0231 1.0079 1.0056 1.0042 1.0034 1.0028 1.0024 1.0021 1.0019
35 1.0258 1.0107 1.0085 1.0071 1.0063 1.0056 1.0053 1.0050 1.0048
40 1.0284 1.0135 1.0113 1.0099 1.0090 1.0084 1.0080 1.0078 1.0076
45 1.0310 1.0162 1.0140 1.0126 1.0118 1.0111 1.0107 1.0105 1.0103
50 1.0334 1.0188 1.0166 1.0152 1.0144 1.0137 1.0134 1.0132 1.0130
____________________________________________________________________________________
T/K = 348.15
____________________________________________________________________________________
0.1 0.9792 0.9651 0.9632 0.9620 0.9610 0.9606 0.9602 0.9599 0.9600
10 0.9864 0.9725 0.9708 0.9696 0.9685 0.9681 0.9676 0.9675 0.9675
15 0.9898 0.9760 0.9745 0.9732 0.9724 0.9718 0.9713 0.9712 0.9712
20 0.9932 0.9795 0.9779 0.9768 0.9758 0.9753 0.9749 0.9748 0.9747
25 0.9964 0.9828 0.9813 0.9802 0.9792 0.9788 0.9783 0.9782 0.9781
30 0.9995 0.9862 0.9846 0.9834 0.9825 0.9820 0.9815 0.9815 0.9814
35 1.0026 0.9893 0.9878 0.9866 0.9857 0.9852 0.9847 0.9847 0.9846
40 1.0055 0.9923 0.9908 0.9896 0.9887 0.9883 0.9878 0.9878 0.9877
45 1.0084 0.9952 0.9938 0.9927 0.9918 0.9913 0.9908 0.9908 0.9907
50 1.0112 0.9982 0.9967 0.9955 0.9947 0.9942 0.9937 0.9937 0.9936
____________________________________________________________________________________
6. PVT Data 583
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 2003LEE

PPG-425, Aldrich Chem. Co., Inc., Milwaukee, WI
____________________________________________________________________________________
P/MPa wB
0.0000 0.3041 0.4956
0.6275 0.7238 0.7972 0.8550 0.9017 1.0000
ρ/g cm−3
____________________________________________________________________________________
T/K = 298.15
____________________________________________________________________________________
0.1 0.9887 0.9917 0.9953 0.9982 0.9997 1.0007 1.0014 1.0019 1.0031
10 0.9951 0.9981 1.0015 1.0044 1.0058 1.0069 1.0075 1.0080 1.0091
15 0.9981 1.0012 1.0046 1.0074 1.0088 1.0099 1.0105 1.0109 1.0120
20 1.0011 1.0042 1.0075 1.0103 1.0117 1.0127 1.0134 1.0138 1.0149
25 1.0040 1.0070 1.0102 1.0130 1.0145 1.0155 1.0161 1.0165 1.0176
30 1.0068 1.0099 1.0131 1.0158 1.0172 1.0182 1.0188 1.0193 1.0203
35 1.0095 1.0128 1.0158 1.0185 1.0199 1.0209 1.0215 1.0220 1.0230
40 1.0120 1.0153 1.0183 1.0210 1.0224 1.0234 1.0240 1.0245 1.0254
45 1.0147 1.0179 1.0208 1.0236 1.0250 1.0260 1.0265 1.0270 1.0280
50 1.0173 1.0205 1.0234 1.0261 1.0275 1.0284 1.0290 1.0294 1.0304
____________________________________________________________________________________
T/K = 318.15
____________________________________________________________________________________
0.1 0.9700 0.9736 0.9779 0.9810 0.9829 0.9842 0.9850 0.9857 0.9872
10 0.9770 0.9805 0.9847 0.9877 0.9895 0.9908 0.9917 0.9923 0.9938
15 0.9803 0.9839 0.9880 0.9910 0.9929 0.9941 0.9950 0.9956 0.9970
20 0.9836 0.9873 0.9912 0.9942 0.9960 0.9972 0.9981 0.9987 1.0001
25 0.9869 0.9903 0.9943 0.9972 0.9991 1.0003 1.0011 1.0017 1.0031
30 0.9899 0.9934 0.9973 1.0002 1.0020 1.0032 1.0040 1.0046 1.0059
35 0.9929 0.9963 1.0002 1.0030 1.0049 1.0060 1.0069 1.0074 1.0088
40 0.9958 0.9992 1.0030 1.0059 1.0077 1.0089 1.0096 1.0102 1.0116
45 0.9987 1.0020 1.0058 1.0086 1.0103 1.0115 1.0122 1.0128 1.0141
50 1.0014 1.0046 1.0085 1.0113 1.0130 1.0142 1.0149 1.0155 1.0167
____________________________________________________________________________________
T/K = 338.15
____________________________________________________________________________________
0.1 0.9409 0.9460 0.9511 0.9547 0.9571 0.9587 0.9600 0.9609 0.9630
10 0.9493 0.9542 0.9591 0.9627 0.9649 0.9666 0.9677 0.9687 0.9707
15 0.9533 0.9581 0.9630 0.9664 0.9686 0.9703 0.9714 0.9723 0.9743
20 0.9571 0.9618 0.9667 0.9701 0.9722 0.9738 0.9749 0.9759 0.9778
25 0.9607 0.9653 0.9701 0.9735 0.9757 0.9772 0.9784 0.9792 0.9811
30 0.9643 0.9688 0.9736 0.9769 0.9790 0.9806 0.9817 0.9825 0.9844
35 0.9677 0.9721 0.9769 0.9802 0.9822 0.9838 0.9848 0.9857 0.9875
40 0.9711 0.9754 0.9801 0.9834 0.9855 0.9870 0.9880 0.9889 0.9906
45 0.9743 0.9786 0.9832 0.9864 0.9885 0.9900 0.9910 0.9918 0.9936
50 0.9774 0.9816 0.9862 0.9894 0.9914 0.9930 0.9939 0.9947 0.9964
____________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 1997COL


Coefficients of Tait equation for density ρ (standard deviation is about 0.1 kg m−3):
{ }
____________________________________________________________________________________
____________________________________________________________________________________
0.00000 1.2567 −0.8796 0.1104 0.6849 0.4869 0.5079
0.13137 1.2685 −0.9746 0.2541 0.8076 0.6348 0.5292
0.22150 1.2604 −0.9412 0.1968 0.9170 0.6983 0.5157
0.41891 1.2397 −0.8740 0.0826 0.8069 0.6156 0.5330
0.51104 1.2254 −0.8274 0.0057 0.8176 0.6356 0.5429
0.60921 1.2124 −0.8069 −0.0363 0.7984 0.6242 0.5548
0.78808 1.2016 −0.9470 0.1687 0.8841 0.6622 0.5658
0.89978 1.1410 −0.8536 0.0056 0.8198 0.5837 0.5977
1.00000 1.0371 −0.7983 −1.2641 0.8428 0.6103 0.7028
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 1997COL


Coefficients of Tait equation for density ρ (standard deviation is about 0.1 kg m−3):
{ }
____________________________________________________________________________________
____________________________________________________________________________________
0.00000 1.2567 −0.8796 0.1104 0.6849 0.4869 0.5079
0.23651 1.2221 −0.8473 0.0392 0.9199 0.6877 0.5344
0.39687 1.2224 −1.0335 0.3294 0.8340 0.5956 0.5535
0.50500 1.1755 −0.8800 0.0596 0.8548 0.6248 0.5823
0.59756 1.1761 −1.0408 0.2920 0.8268 0.6595 0.6407
0.79920 1.1070 −1.0996 0.3329 0.8354 0.6682 0.7236
0.89964 1.0492 −1.1217 0.3522 0.8441 0.7779 0.8274
1.00000 1.0358 −1.5870 1.0805 0.8521 0.9049 0.9540
____________________________________________________________________________________
6. PVT Data 585
____________________________________________________________________________________

____________________________________________________________________________________
P/MPa wB
0.0000 0.7334 0.8848
0.9294 0.9534 0.9788 0.9862 0.9919 1.0000
ρ/g cm−3
____________________________________________________________________________________
T/K = 298.15
____________________________________________________________________________________
0.1 0.8216 0.9534 0.9745 0.9830 0.9876 0.9928 0.9945 0.9958 0.9979
10 0.8278 0.9596 0.9807 0.9893 0.9938 0.9990 1.0006 1.0021 1.0042
15 0.8308 0.9626 0.9837 0.9923 0.9969 1.0021 1.0036 1.0050 1.0071
20 0.8337 0.9654 0.9865 0.9952 0.9998 1.0050 1.0065 1.0079 1.0100
25 0.8364 0.9682 0.9893 0.9980 1.0025 1.0077 1.0093 1.0107 1.0128
30 0.8391 0.9709 0.9921 1.0007 1.0053 1.0104 1.0121 1.0134 1.0156
35 0.8417 0.9736 0.9947 1.0034 1.0080 1.0132 1.0147 1.0161 1.0182
40 0.8442 0.9762 0.9973 1.0060 1.0105 1.0158 1.0173 1.0187 1.0208
45 0.8467 0.9787 0.9998 1.0085 1.0131 1.0183 1.0198 1.0213 1.0233
50 0.8491 0.9812 1.0023 1.0110 1.0155 1.0208 1.0223 1.0237 1.0258
____________________________________________________________________________________
T/K = 318.15
____________________________________________________________________________________
0.1 0.8077 0.9381 0.9593 0.9680 0.9724 0.9776 0.9792 0.9805 0.9828
10 0.8149 0.9448 0.9659 0.9748 0.9792 0.9844 0.9861 0.9873 0.9896
15 0.8182 0.9481 0.9692 0.9780 0.9823 0.9877 0.9895 0.9906 0.9928
20 0.8213 0.9513 0.9724 0.9812 0.9856 0.9909 0.9925 0.9936 0.9959
25 0.8243 0.9543 0.9755 0.9842 0.9885 0.9940 0.9955 0.9967 0.9990
30 0.8272 0.9572 0.9785 0.9871 0.9914 0.9969 0.9985 0.9996 1.0019
35 0.8300 0.9601 0.9813 0.9900 0.9943 0.9998 1.0014 1.0025 1.0048
40 0.8327 0.9628 0.9841 0.9928 0.9973 1.0024 1.0042 1.0053 1.0076
45 0.8354 0.9655 0.9869 0.9955 0.9998 1.0053 1.0069 1.0080 1.0103
50 0.8380 0.9681 0.9895 0.9982 1.0025 1.0080 1.0095 1.0107 1.0130
____________________________________________________________________________________
T/K = 348.15
____________________________________________________________________________________
0.1 0.7855 0.9149 0.9362 0.9451 0.9496 0.9547 0.9563 0.9576 0.9600
10 0.7933 0.9226 0.9439 0.9529 0.9572 0.9624 0.9640 0.9653 0.9675
15 0.7969 0.9263 0.9476 0.9566 0.9609 0.9661 0.9677 0.9689 0.9712
20 0.8005 0.9298 0.9513 0.9601 0.9645 0.9697 0.9712 0.9724 0.9747
25 0.8039 0.9332 0.9548 0.9636 0.9679 0.9731 0.9746 0.9758 0.9781
30 0.8072 0.9365 0.9580 0.9668 0.9711 0.9764 0.9779 0.9791 0.9814
35 0.8104 0.9397 0.9612 0.9700 0.9743 0.9795 0.9811 0.9824 0.9846
40 0.8135 0.9428 0.9644 0.9731 0.9775 0.9826 0.9842 0.9854 0.9877
45 0.8164 0.9458 0.9673 0.9761 0.9804 0.9856 0.9872 0.9885 0.9907
50 0.8193 0.9486 0.9703 0.9790 0.9833 0.9886 0.9901 0.9914 0.9936
____________________________________________________________________________________
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 1999CRE


{ }
____________________________________________________________________________________
____________________________________________________________________________________
0.00000 1.2567 −0.8796 0.1104 0.6849 0.4869 0.5079
0.20105 1.2663 −0.9207 0.1560 0.8552 0.6609 0.5150
0.37701 1.2390 −0.7150 −0.1751 0.9205 0.7391 0.5148
0.61406 1.2227 −0.5678 −0.4161 0.7870 0.5934 0.4837
0.85537 1.2576 −0.7013 −0.2619 0.7695 0.7547 0.5296
0.95620 0.7619 2.6343 −5.8048 0.6260 3.4631 1.0627
0.97623 0.6962 2.8673 −5.9522 0.7450 4.3583 1.0479
0.98851 0.6397 2.9702 −5.7338 0.5937 0.6774 0.5301
1.00000 0.2871 4.6433 −7.5582 0.9362 0.1492 −0.1158
____________________________________________________________________________________
Polymer (B): tetra(ethylene glycol) dimethyl ether 2003ACE

Characterization: M/kg.mol−1 = 0.222, Fluka AG, Buchs, Switzerland
____________________________________________________________________________________
P/MPa xB
0.00000 0.10504 0.29950 0.40213 0.50997 0.59095 0.69827 0.80114 1.00000
ρ/g cm−3
____________________________________________________________________________________
T/K = 278.15
____________________________________________________________________________________
0.1 0.6963 0.7439 0.8225 0.8588 0.8941 0.9190 0.9499 0.9776 1.0251
1.0 0.6970 0.7446 0.8231 0.8594 0.8948 0.9196 0.9505 0.9782 1.0256
2.5 0.6983 0.7458 0.8243 0.8605 0.8958 0.9206 0.9515 0.9790 1.0265
5.0 0.7003 0.7478 0.8261 0.8623 0.8976 0.9223 0.9531 0.9806 1.0279
7.5 0.7023 0.7497 0.8279 0.8641 0.8993 0.9239 0.9546 0.9821 1.0293
10.0 0.7042 0.7516 0.8297 0.8658 0.9009 0.9255 0.9561 0.9836 1.0307
15.0 0.7079 0.7552 0.8332 0.8692 0.9041 0.9287 0.9592 0.9865 1.0334
20.0 0.7114 0.7586 0.8365 0.8724 0.9072 0.9317 0.9621 0.9893 1.0361
25.0 0.7147 0.7619 0.8755 0.9102 0.9346 0.9649 0.9921 1.0387
____________________________________________________________________________________
continued
6. PVT Data 587
____________________________________________________________________________________
continued
T/K = 283.15
_____________________________________________________________________________________________
0.1 0.6921 0.7396 0.8180 0.8544 0.8896 0.9144 0.9454 0.9728 1.0204
1.0 0.6929 0.7403 0.8187 0.8551 0.8902 0.9151 0.9460 0.9734 1.0209
2.5 0.6942 0.7416 0.8199 0.8562 0.8913 0.9161 0.9470 0.9744 1.0218
5.0 0.6963 0.7437 0.8218 0.8581 0.8931 0.9178 0.9486 0.9759 1.0233
7.5 0.6983 0.7456 0.8237 0.8599 0.8948 0.9195 0.9502 0.9775 1.0247
10.0 0.7002 0.7476 0.8255 0.8617 0.8965 0.9211 0.9518 0.9790 1.0261
15.0 0.7040 0.7513 0.8290 0.8651 0.8998 0.9243 0.9549 0.9820 1.0289
20.0 0.7076 0.7548 0.8324 0.8684 0.9029 0.9274 0.9579 0.9849 1.0316
25.0 0.7111 0.7582 0.8357 0.8716 0.9060 0.9304 0.9607 0.9877 1.0343
_____________________________________________________________________________________________
T/K = 293.15
_____________________________________________________________________________________________
0.1 0.6837 0.7313 0.8090 0.8453 0.8805 0.9053 0.9360 0.9634 1.0111
1.0 0.6846 0.7321 0.8097 0.8461 0.8811 0.9059 0.9366 0.9639 1.0116
2.5 0.6859 0.7335 0.8109 0.8473 0.8823 0.9070 0.9377 0.9649 1.0126
5.0 0.6882 0.7357 0.8129 0.8492 0.8841 0.9088 0.9394 0.9666 1.0141
7.5 0.6904 0.7378 0.8149 0.8511 0.8859 0.9106 0.9411 0.9682 1.0156
10.0 0.6925 0.7399 0.8169 0.8530 0.8877 0.9124 0.9428 0.9698 1.0171
15.0 0.6966 0.7439 0.8206 0.8566 0.8912 0.9158 0.9460 0.9729 1.0200
20.0 0.7004 0.7476 0.8242 0.8601 0.8945 0.9190 0.9491 0.9759 1.0229
25.0 0.7039 0.7512 0.8276 0.8634 0.8977 0.9221 0.9522 0.9789 1.0256
_____________________________________________________________________________________________
T/K = 303.15
_____________________________________________________________________________________________
0.1 0.6753 0.7226 0.8001 0.8366 0.8715 0.8962 0.9269 0.9543 1.0021
1.0 0.6762 0.7235 0.8009 0.8374 0.8722 0.8969 0.9276 0.9550 1.0027
2.5 0.6777 0.7249 0.8023 0.8386 0.8735 0.8980 0.9287 0.9561 1.0037
5.0 0.6801 0.7273 0.8044 0.8407 0.8755 0.9000 0.9305 0.9578 1.0053
7.5 0.6824 0.7295 0.8065 0.8427 0.8774 0.9018 0.9323 0.9595 1.0069
10.0 0.6847 0.7317 0.8085 0.8447 0.8793 0.9036 0.9341 0.9613 1.0085
15.0 0.6890 0.7359 0.8125 0.8485 0.8829 0.9072 0.9375 0.9645 1.0115
20.0 0.6930 0.7398 0.8162 0.8521 0.8865 0.9106 0.9408 0.9677 1.0145
25.0 0.6969 0.7436 0.8198 0.8556 0.8899 0.9139 0.9439 0.9708 1.0174
_____________________________________________________________________________________________
T/K = 313.15
_____________________________________________________________________________________________
0.1 0.6666 0.7137 0.7911 0.8275 0.8624 0.8869 0.9180 0.9453 0.9929
1.0 0.6676 0.7146 0.7920 0.8283 0.8632 0.8877 0.9187 0.9460 0.9935
5.0 0.6717 0.7187 0.7957 0.8318 0.8666 0.8908 0.9218 0.9490 0.9963
7.5 0.6742 0.7211 0.7980 0.8339 0.8687 0.8928 0.9237 0.9508 0.9979
10.0 0.6766 0.7235 0.8001 0.8360 0.8707 0.8947 0.9256 0.9525 0.9996
15.0 0.6812 0.7280 0.8043 0.8401 0.8746 0.8985 0.9292 0.9560 1.0028
20.0 0.6855 0.7322 0.8083 0.8439 0.8783 0.9021 0.9326 0.9593 1.0060
25.0 0.6895 0.7361 0.8121 0.8476 0.8818 0.9055 0.9360 0.9625 1.0090
_____________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
T/K = 323.15
_____________________________________________________________________________________________
0.1 0.6576 0.7049 0.7820 0.8182 0.8533 0.8784 0.9089 0.9361 0.9836
1.0 0.6587 0.7060 0.7830 0.8191 0.8541 0.8792 0.9097 0.9367 0.9843
2.5 0.6604 0.7077 0.7845 0.8205 0.8554 0.8805 0.9109 0.9379 0.9853
5.0 0.6631 0.7103 0.7869 0.8228 0.8577 0.8826 0.9129 0.9398 0.9871
7.5 0.6658 0.7129 0.7893 0.8251 0.8598 0.8847 0.9149 0.9416 0.9889
10.0 0.6684 0.7153 0.7916 0.8273 0.8619 0.8867 0.9168 0.9434 0.9906
15.0 0.6733 0.7201 0.7960 0.8316 0.8660 0.8907 0.9206 0.9471 0.9940
20.0 0.6779 0.7246 0.8002 0.8357 0.8699 0.8944 0.9242 0.9506 0.9973
25.0 0.6821 0.7287 0.8042 0.8395 0.8736 0.8980 0.9277 0.9539 1.0005
_____________________________________________________________________________________________
T/K = 333.15
_____________________________________________________________________________________________
0.1 0.6489 0.6954 0.7725 0.8092 0.8439 0.8683 0.8990 0.9264 0.9741
1.0 0.6500 0.6965 0.7735 0.8101 0.8448 0.8691 0.8998 0.9272 0.9748
2.5 0.6518 0.6983 0.7751 0.8117 0.8462 0.8703 0.9011 0.9284 0.9760
5.0 0.6548 0.7011 0.7777 0.8141 0.8485 0.8725 0.9033 0.9305 0.9779
7.5 0.6576 0.7039 0.7802 0.8166 0.8508 0.8747 0.9053 0.9325 0.9798
10.0 0.6604 0.7065 0.7827 0.8189 0.8530 0.8768 0.9074 0.9344 0.9816
15.0 0.6656 0.7115 0.7873 0.8234 0.8573 0.8809 0.9114 0.9382 0.9851
20.0 0.6704 0.7162 0.7917 0.8277 0.8613 0.8849 0.9151 0.9418 0.9885
25.0 0.6749 0.7206 0.7958 0.8317 0.8652 0.8886 0.9187 0.9453 0.9918
_____________________________________________________________________________________________
T/K = 343.15
_____________________________________________________________________________________________
0.1 0.6398 0.6867 0.7638 0.8000 0.8351 0.8593 0.8904 0.9176 0.9650
1.0 0.6411 0.6879 0.7648 0.8010 0.8360 0.8602 0.8912 0.9184 0.9658
2.5 0.6431 0.6898 0.7666 0.8026 0.8375 0.8617 0.8926 0.9198 0.9670
5.0 0.6463 0.6929 0.7694 0.8052 0.8401 0.8641 0.8949 0.9220 0.9690
7.5 0.6494 0.6958 0.7721 0.8078 0.8425 0.8664 0.8971 0.9241 0.9710
10.0 0.6524 0.6987 0.7747 0.8102 0.8448 0.8687 0.8993 0.9262 0.9729
15.0 0.6580 0.7040 0.7796 0.8150 0.8494 0.8730 0.9034 0.9302 0.9766
20.0 0.6631 0.7090 0.7842 0.8194 0.8537 0.8772 0.9074 0.9340 0.9802
25.0 0.6679 0.7136 0.7886 0.8237 0.8578 0.8812 0.9112 0.9376 0.9837
_____________________________________________________________________________________________
T/K = 353.15
_____________________________________________________________________________________________
0.1 0.6306 0.6775 0.7545 0.7904 0.8257 0.8501 0.8811 0.9083 0.9557
1.0 0.6320 0.6788 0.7556 0.7915 0.8267 0.8511 0.8820 0.9091 0.9565
2.5 0.6342 0.6809 0.7575 0.7933 0.8284 0.8526 0.8835 0.9106 0.9578
5.0 0.6378 0.6842 0.7605 0.7961 0.8310 0.8552 0.8859 0.9128 0.9599
7.5 0.6411 0.6874 0.7634 0.7989 0.8336 0.8576 0.8883 0.9151 0.9620
10.0 0.6443 0.6904 0.7661 0.8015 0.8361 0.8600 0.8905 0.9172 0.9640
15.0 0.6503 0.6961 0.7713 0.8065 0.8409 0.8646 0.8949 0.9214 0.9679
20.0 0.6557 0.7013 0.7762 0.8112 0.8454 0.8689 0.8991 0.9254 0.9717
25.0 0.6608 0.7062 0.7809 0.8157 0.8497 0.8730 0.9031 0.9293 0.9753
_____________________________________________________________________________________________
6. PVT Data 589
____________________________________________________________________________________

Characterization: M/kg.mol−1 = 0.222, Aldrich Chem. Co., Inc., Milwaukee, WI
____________________________________________________________________________________
P/MPa xB
0.0710 0.1273 0.2712
0.3069 0.4298 0.6352 0.7104 0.8886 1.0000
ρ/g cm−3
____________________________________________________________________________________
T/K = 293.15
____________________________________________________________________________________
10 1.2417 1.2182 1.1637 1.1528 1.1172 1.0701 1.0563 1.0315 1.0172
15 1.2545 1.2283 1.1703 1.1589 1.1221 1.0738 1.0598 1.0345 1.0201
20 1.2662 1.2376 1.1765 1.1646 1.1267 1.0774 1.0632 1.0375 1.0229
25 1.2770 1.2463 1.1824 1.1701 1.1313 1.0810 1.0665 1.0405 1.0257
30 1.2869 1.2546 1.1880 1.1754 1.1355 1.0845 1.0697 1.0433 1.0284
35 1.2962 1.2622 1.1934 1.1804 1.1397 1.0877 1.0728 1.0461 1.0310
40 1.3051 1.2695 1.1986 1.1853 1.1438 1.0910 1.0759 1.0488 1.0336
45 1.3134 1.2765 1.2036 1.1900 1.1477 1.0941 1.0788 1.0515 1.0361
50 1.3214 1.2832 1.2084 1.1946 1.1515 1.0972 1.0818 1.0541 1.0385
55 1.3288 1.2896 1.2130 1.1990 1.1552 1.1003 1.0846 1.0567 1.0410
60 1.3360 1.2957 1.2174 1.2032 1.1588 1.1032 1.0874 1.0593 1.0434
____________________________________________________________________________________
T/K = 303.15
____________________________________________________________________________________
10 1.2169 1.1972 1.1480 1.1377 1.1041 1.0593 1.0460 1.0220 1.0082
15 1.2311 1.2083 1.1551 1.1444 1.1094 1.0632 1.0497 1.0254 1.0113
20 1.2438 1.2184 1.1617 1.1505 1.1144 1.0671 1.0533 1.0285 1.0143
25 1.2555 1.2278 1.1680 1.1562 1.1191 1.0708 1.0568 1.0316 1.0172
30 1.2664 1.2366 1.1740 1.1619 1.1236 1.0744 1.0601 1.0346 1.0200
35 1.2765 1.2449 1.1797 1.1673 1.1280 1.0779 1.0634 1.0374 1.0227
40 1.2860 1.2528 1.1852 1.1724 1.1324 1.0813 1.0666 1.0403 1.0254
45 1.2949 1.2601 1.1905 1.1774 1.1364 1.0846 1.0697 1.0431 1.0281
50 1.3032 1.2671 1.1956 1.1822 1.1405 1.0878 1.0727 1.0457 1.0306
55 1.3114 1.2740 1.2004 1.1867 1.1443 1.0910 1.0757 1.0485 1.0332
60 1.3190 1.2803 1.2051 1.1912 1.1482 1.0939 1.0785 1.0510 1.0355
____________________________________________________________________________________
T/K = 313.15
____________________________________________________________________________________
10 1.1920 1.1761 1.1322 1.1227 1.0910 1.0483 1.0357 1.0124 0.9992
15 1.2078 1.1882 1.1398 1.1297 1.0966 1.0526 1.0396 1.0159 1.0025
20 1.2219 1.1992 1.1468 1.1362 1.1019 1.0566 1.0434 1.0192 1.0055
25 1.2343 1.2094 1.1535 1.1425 1.1069 1.0605 1.0470 1.0223 1.0086
30 1.2462 1.2188 1.1599 1.1485 1.1118 1.0643 1.0506 1.0255 1.0116
35 1.2569 1.2276 1.1660 1.1542 1.1164 1.0680 1.0540 1.0286 1.0144
40 1.2671 1.2359 1.1718 1.1595 1.1208 1.0715 1.0573 1.0316 1.0172
45 1.2766 1.2439 1.1773 1.1649 1.1252 1.0750 1.0606 1.0345 1.0201
_____________________________________________________________________________________________
continued
____________________________________________________________________________________
continued
_____________________________________________________________________________________________
50 1.2854 1.2514 1.1827 1.1698 1.1293 1.0783 1.0637 1.0374 1.0226
55 1.2939 1.2584 1.1878 1.1746 1.1334 1.0816 1.0668 1.0401 1.0252
60 1.3020 1.2654 1.1929 1.1795 1.1375 1.0849 1.0699 1.0430 1.0278
_____________________________________________________________________________________________
T/K = 323.15
_____________________________________________________________________________________________
10 1.1657 1.1543 1.1161 1.1074 1.0780 1.0376 1.0255 1.0031 0.9903
15 1.1833 1.1676 1.1242 1.1149 1.0838 1.0420 1.0296 1.0067 0.9937
20 1.1989 1.1797 1.1321 1.1222 1.0897 1.0464 1.0337 1.0103 0.9970
25 1.2128 1.1907 1.1392 1.1287 1.0949 1.0504 1.0375 1.0136 1.0001
30 1.2255 1.2009 1.1459 1.1351 1.1001 1.0544 1.0412 1.0169 1.0032
35 1.2371 1.2103 1.1524 1.1411 1.1050 1.0583 1.0447 1.0201 1.0063
40 1.2479 1.2192 1.1585 1.1469 1.1097 1.0620 1.0482 1.0232 1.0091
45 1.2581 1.2276 1.1644 1.1524 1.1143 1.0657 1.0517 1.0263 1.0121
50 1.2676 1.2355 1.1700 1.1576 1.1187 1.0691 1.0548 1.0291 1.0147
55 1.2766 1.2430 1.1754 1.1627 1.1229 1.0725 1.0581 1.0321 1.0175
60 1.2852 1.2503 1.1806 1.1677 1.1271 1.0759 1.0613 1.0349 1.0202
_____________________________________________________________________________________________
T/K = 333.15
_____________________________________________________________________________________________
10 1.1391 1.1321 1.0998 1.0920 1.0649 1.0267 1.0151 0.9936 0.9814
15 1.1589 1.1469 1.1087 1.1003 1.0712 1.0315 1.0196 0.9975 0.9850
20 1.1759 1.1599 1.1169 1.1078 1.0772 1.0360 1.0237 1.0011 0.9883
25 1.1912 1.1720 1.1247 1.1150 1.0829 1.0404 1.0278 1.0047 0.9917
30 1.2048 1.1830 1.1320 1.1218 1.0884 1.0446 1.0317 1.0081 0.9950
35 1.2175 1.1932 1.1388 1.1281 1.0935 1.0486 1.0355 1.0116 0.9982
40 1.2290 1.2026 1.1453 1.1342 1.0986 1.0526 1.0392 1.0148 1.0012
45 1.2397 1.2115 1.1514 1.1400 1.1034 1.0563 1.0428 1.0179 1.0042
50 1.2499 1.2198 1.1573 1.1455 1.1079 1.0600 1.0461 1.0210 1.0070
55 1.2593 1.2277 1.1629 1.1509 1.1123 1.0635 1.0495 1.0241 1.0098
60 1.2683 1.2352 1.1684 1.1560 1.1166 1.0670 1.0528 1.0269 1.0126
_____________________________________________________________________________________________
T/K = 343.15
_____________________________________________________________________________________________
10 1.1111 1.1092 1.0834 1.0766 1.0516 1.0160 1.0050 0.9844 0.9726
15 1.1336 1.1256 1.0931 1.0854 1.0585 1.0211 1.0097 0.9887 0.9764
20 1.1525 1.1401 1.1019 1.0936 1.0649 1.0259 1.0142 0.9925 0.9800
25 1.1692 1.1531 1.1102 1.1013 1.0710 1.0304 1.0185 0.9962 0.9835
30 1.1842 1.1649 1.1180 1.1084 1.0767 1.0349 1.0225 0.9998 0.9869
35 1.1976 1.1758 1.1253 1.1151 1.0822 1.0391 1.0265 1.0032 0.9901
40 1.2100 1.1859 1.1321 1.1216 1.0874 1.0431 1.0303 1.0065 0.9932
45 1.2214 1.1952 1.1385 1.1276 1.0924 1.0470 1.0339 1.0099 0.9963
50 1.2322 1.2040 1.1447 1.1335 1.0972 1.0508 1.0374 1.0129 0.9993
_____________________________________________________________________________________________
continued
6. PVT Data 591
____________________________________________________________________________________
continued
_____________________________________________________________________________________________
55 1.2422 1.2125 1.1507 1.1391 1.1021 1.0546 1.0410 1.0162 1.0023
60 1.2516 1.2202 1.1563 1.1444 1.1063 1.0581 1.0443 1.0192 1.0050
_____________________________________________________________________________________________
T/K = 353.15
____________________________________________________________________________________
10 1.0824 1.0858 1.0661 1.0609 1.0386 1.0052 0.9948 0.9752 0.9639
15 1.1079 1.1042 1.0768 1.0706 1.0458 1.0106 0.9997 0.9794 0.9679
20 1.1288 1.1200 1.0864 1.0793 1.0526 1.0156 1.0044 0.9834 0.9716
25 1.1473 1.1343 1.0952 1.0874 1.0590 1.0205 1.0089 0.9872 0.9752
30 1.1633 1.1470 1.1034 1.0949 1.0652 1.0251 1.0132 0.9911 0.9788
35 1.1778 1.1584 1.1111 1.1021 1.0707 1.0295 1.0173 0.9947 0.9821
40 1.1910 1.1692 1.1184 1.1089 1.0763 1.0338 1.0213 0.9983 0.9855
45 1.2032 1.1791 1.1253 1.1152 1.0816 1.0379 1.0250 1.0017 0.9886
50 1.2145 1.1884 1.1322 1.1214 1.0866 1.0419 1.0287 1.0050 0.9917
55 1.2252 1.1973 1.1384 1.1272 1.0915 1.0457 1.0325 1.0083 0.9947
60 1.2349 1.2055 1.1444 1.1329 1.0961 1.0495 1.0359 1.0114 0.9976
____________________________________________________________________________________
T/K = 363.15
____________________________________________________________________________________
10 1.0514 1.0613 1.0490 1.0450 1.0250 0.9945 0.9847 0.9659 0.9557
15 1.0806 1.0819 1.0606 1.0553 1.0331 1.0002 0.9899 0.9704 0.9598
20 1.1043 1.0993 1.0709 1.0649 1.0401 1.0055 0.9948 0.9746 0.9639
25 1.1245 1.1147 1.0805 1.0735 1.0471 1.0106 0.9995 0.9787 0.9675
30 1.1420 1.1284 1.0892 1.0816 1.0534 1.0153 1.0039 0.9828 0.9712
35 1.1577 1.1409 1.0975 1.0893 1.0595 1.0201 1.0083 0.9866 0.9748
40 1.1720 1.1523 1.1053 1.0964 1.0654 1.0245 1.0125 0.9903 0.9783
45 1.1848 1.1629 1.1124 1.1031 1.0708 1.0288 1.0164 0.9937 0.9815
50 1.1969 1.1728 1.1194 1.1096 1.0761 1.0330 1.0203 0.9972 0.9846
55 1.2080 1.1820 1.1259 1.1156 1.0813 1.0369 1.0241 1.0006 0.9880
60 1.2185 1.1908 1.1322 1.1216 1.0860 1.0408 1.0277 1.0038 0.9910
____________________________________________________________________________________
T/K = 373.15
____________________________________________________________________________________
10 1.0193 1.0360 1.0317 1.0289 1.0116 0.9835 0.9742 0.9564 0.9468
15 1.0532 1.0593 1.0443 1.0400 1.0200 0.9895 0.9798 0.9611 0.9511
20 1.0798 1.0786 1.0556 1.0502 1.0278 0.9951 0.9850 0.9657 0.9552
25 1.1019 1.0954 1.0658 1.0596 1.0350 1.0005 0.9899 0.9699 0.9593
30 1.1209 1.1102 1.0752 1.0682 1.0419 1.0057 0.9947 0.9742 0.9631
35 1.1377 1.1234 1.0839 1.0762 1.0482 1.0104 0.9991 0.9779 0.9669
40 1.1529 1.1356 1.0919 1.0837 1.0543 1.0151 1.0035 0.9817 0.9704
45 1.1667 1.1468 1.0997 1.0909 1.0601 1.0196 1.0076 0.9854 0.9739
50 1.1792 1.1571 1.1068 1.0976 1.0655 1.0239 1.0116 0.9890 0.9771
55 1.1911 1.1670 1.1137 1.1042 1.0709 1.0281 1.0157 0.9926 0.9805
60 1.2022 1.1762 1.1202 1.1102 1.0760 1.0321 1.0194 0.9955 0.9838
____________________________________________________________________________________
____________________________________________________________________________________
6.2.2. Ternary polymer solutions

synthesized by complete hydrogenation of polybutadiene,
Solvent (C): n-pentane-d12 C5D12 2031-90-5
T/K = 383.15
wA 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231
wB 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049
P/bar 277.5 312.0 346.5 380.9 415.4 484.3 553.3 691.2 1035.9
ρ/g cm−3 0.643 0.650 0.656 0.662 0.667 0.677 0.687 0.702 0.736
wA 0.231 0.231 0.231 0.231
wB 0.049 0.049 0.049 0.049
P/bar 1380.7 1725.4 2070.1 2414.9
ρ/g cm−3 0.762 0.785 0.805 0.822
T/K = 403.15
wA 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231
wB 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049
P/bar 277.5 312.0 346.5 380.9 415.4 484.3 553.3 691.2 1035.9
ρ/g cm−3 0.622 0.630 0.634 0.645 0.651 0.662 0.672 0.689 0.724
wA 0.231 0.231 0.231 0.231
wB 0.049 0.049 0.049 0.049
P/bar 1380.7 1725.4 2070.1 2414.9
ρ/g cm−3 0.752 0.775 0.796 0.814
T/K = 423.15
wA 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231 0.231
wB 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049 0.049
P/bar 346.5 380.9 415.4 484.3 553.3 691.2 1035.9 1380.7 1725.4
ρ/g cm−3 0.619 0.627 0.634 0.646 0.657 0.676 0.712 0.741 0.765
wA 0.231 0.231
wB 0.049 0.049
P/bar 2070.1 2414.9
ρ/g cm−3 0.786 0.805

PEG-200, Aldrich Chem. Co., Inc., Milwaukee, WI
continued
6. PVT Data 593
____________________________________________________________________________________
continued
T/K = 298.15 P/MPa = 0.1 T/K = 298.15 P/MPa = 30

wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 1.0168 1.0261 1.0667 1.0364 1.0335 1.0425 1.0809 1.0522
T/K = 298.15 P/MPa = 10 T/K = 298.15 P/MPa = 35
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 1.0226 1.0318 1.0716 1.0419 1.0360 1.0450 1.0831 1.0547
T/K = 298.15 P/MPa = 15 T/K = 298.15 P/MPa = 40
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 1.0254 1.0346 1.0739 1.0446 1.0384 1.0474 1.0852 1.0570
T/K = 298.15 P/MPa = 20 T/K = 298.15 P/MPa = 45
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 1.0281 1.0372 1.0763 1.0472 1.0409 1.0498 1.0873 1.0593
T/K = 298.15 P/MPa = 25 T/K = 298.15 P/MPa = 50
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 1.0308 1.0399 1.0785 1.0497 1.0432 1.0522 1.0893 1.0615
T/K = 318.15 P/MPa = 0.1 T/K = 318.15 P/MPa = 30
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 1.0005 1.0090 1.0502 1.0197 1.0187 1.0269 1.0661 1.0374
T/K = 318.15 P/MPa = 10 T/K = 318.15 P/MPa = 35
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 1.0069 1.0153 1.0559 1.0260 1.0215 1.0296 1.0685 1.0400
continued
____________________________________________________________________________________
continued
T/K = 318.15 P/MPa = 15 T/K = 318.15 P/MPa = 40
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 1.0100 1.0183 1.0585 1.0290 1.0242 1.0323 1.0709 1.0426
T/K = 318.15 P/MPa = 20 T/K = 318.15 P/MPa = 45
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 1.0130 1.0213 1.0611 1.0319 1.0267 1.0349 1.0731 1.0450
T/K = 318.15 P/MPa = 25 T/K = 318.15 P/MPa = 50
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 1.0159 1.0241 1.0636 1.0347 1.0293 1.0374 1.0754 1.0475
T/K = 338.15 P/MPa = 0.1 T/K = 338.15 P/MPa = 30
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 0.9757 0.9827 1.0243 0.9948 0.9963 1.0033 1.0418 1.0146
T/K = 338.15 P/MPa = 10 T/K = 338.15 P/MPa = 35
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 0.9831 0.9900 1.0305 1.0018 0.9993 1.0064 1.0444 1.0175
T/K = 338.15 P/MPa = 15 T/K = 338.15 P/MPa = 40
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 0.9866 0.9935 1.0334 1.0052 1.0023 1.0094 1.0471 1.0204
T/K = 338.15 P/MPa = 20 T/K = 338.15 P/MPa = 45
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 0.9899 0.9970 1.0364 1.0085 1.0052 1.0123 1.0495 1.0232
T/K = 338.15 P/MPa = 25 T/K = 338.15 P/MPa = 50
wA 0.0592 0.3031 0.0787 0.0797 0.0592 0.3031 0.0787 0.0797
wB 0.1424 0.2429 0.5676 0.3203 0.1424 0.2429 0.5676 0.3203
wC 0.7984 0.4540 0.3537 0.6000 0.7984 0.4540 0.3537 0.6000
ρ/g cm−3 0.9932 1.0002 1.0391 1.0116 1.0080 1.0151 1.0520 1.0259
6. PVT Data 595
____________________________________________________________________________________
Polymer (B): poly(propylene glycol) 2003LEE

Polymer (C): poly(ethylene glycol) monomethyl ether
PEGME-350, Aldrich Chem. Co., Inc., Milwaukee, WI
T/K = 298.15 P/MPa = 0.1 T/K = 298.15 P/MPa = 30
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0546 1.0285 1.0164 1.0334 1.0702 1.0449 1.0333 1.0496
T/K = 298.15 P/MPa = 10 T/K = 298.15 P/MPa = 35
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0599 1.0341 1.0223 1.0390 1.0726 1.0474 1.0359 1.0521
T/K = 298.15 P/MPa = 15 T/K = 298.15 P/MPa = 40
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0626 1.0369 1.0252 1.0413 1.0749 1.0498 1.0383 1.0545
T/K = 298.15 P/MPa = 20 T/K = 298.15 P/MPa = 45
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0652 1.0396 1.0280 1.0444 1.0772 1.0522 1.0408 1.0568
T/K = 298.15 P/MPa = 25 T/K = 298.15 P/MPa = 50
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0677 1.0422 1.0306 1.0470 1.0795 1.0546 1.0432 1.0591
T/K = 318.15 P/MPa = 0.1 T/K = 318.15 P/MPa = 30
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0376 1.0112 0.9998 1.0168 1.0547 1.0293 1.0183 1.0345
T/K = 318.15 P/MPa = 10 T/K = 318.15 P/MPa = 35
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0437 1.0176 1.0064 1.0231 1.0573 1.0320 1.0210 1.0372
continued
____________________________________________________________________________________
continued
T/K = 318.15 P/MPa = 15 T/K = 318.15 P/MPa = 40
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0465 1.0207 1.0094 1.0261 1.0598 1.0347 1.0238 1.0399
T/K = 318.15 P/MPa = 20 T/K = 318.15 P/MPa = 45
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0499 1.0236 1.0125 1.0290 1.0623 1.0373 1.0263 1.0423
T/K = 318.15 P/MPa = 25 T/K = 318.15 P/MPa = 50
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0521 1.0265 1.0154 1.0318 1.0647 1.0398 1.0289 1.0448
T/K = 338.15 P/MPa = 0.1 T/K = 338.15 P/MPa = 30
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0126 0.9852 0.9749 0.9916 1.0319 1.0060 0.9956 1.0120
T/K = 338.15 P/MPa = 10 T/K = 338.15 P/MPa = 35
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0194 0.9926 0.9823 0.9989 1.0348 1.0091 0.9986 1.0149
T/K = 338.15 P/MPa = 15 T/K = 338.15 P/MPa = 40
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0226 0.9961 0.9858 1.0023 1.0376 1.0121 1.0016 1.0179
T/K = 338.15 P/MPa = 20 T/K = 338.15 P/MPa = 45
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0258 0.9995 0.9892 1.0056 1.0403 1.0150 1.0045 1.0208
T/K = 338.15 P/MPa = 25 T/K = 338.15 P/MPa = 50
wA 0.0639 0.2758 0.0560 0.1084 0.0639 0.2758 0.0560 0.1084
wB 0.2872 0.4131 0.7546 0.5247 0.2872 0.4131 0.7546 0.5247
wC 0.6489 0.3111 0.1894 0.3669 0.6489 0.3111 0.1894 0.3669
ρ/g cm−3 1.0289 1.0028 0.9924 1.0088 1.0430 1.0178 1.0072 1.0235
6. PVT Data 597
____________________________________________________________________________________
Polymer (B): polystyrene 2001LI2

Characterization: Mn/kg.mol−1 = 71, Mw/kg.mol−1 = 78, State Key Laboratory of
Polymer Science, Chinese Academy of Sciences
Type of data: volume expansion coefficients

Comments: Volume expansion coefficients, (V − V0)/V0, were determined for a given concentration
of polystyrene in the CO2-free toluene solution, c0B, and the given equilibrium pressure
of CO2 in the ternary system.
T/K = 308.15
c0B/g.ml−3 0.00046 0.00046 0.00046 0.00046 0.00046 0.00046 0.00046 0.00046 0.00046
P/MPa 0.00 0.71 0.99 1.68 2.23 2.43 2.60 2.95 3.10
(V−V0)/V0 0.0000 0.0059 0.0103 0.0678 0.0997 0.1077 0.1237 0.1676 0.1835
c0B/g.ml−3 0.00046 0.00046 0.00046 0.00046 0.00046 0.00046 0.00046 0.00046 0.00046
P/MPa 3.26 3.55 3.63 3.76 3.86 3.96 4.06 4.15 4.20
(V−V0)/V0 0.1935 0.2414 0.2514 0.2654 0.2814 0.2913 0.3093 0.3312 0.3412
c0B/g.ml−3 0.00046 0.00046 0.00046 0.00046 0.00046 0.00096 0.00096 0.00096 0.00096
P/MPa 4.28 4.47 4.65 4.78 4.90 0.00 0.87 1.36 1.79
)/V
(V−V0 0 0.3632 0.4011 0.4670 0.5448 0.5648 0.0000 0.0106 0.0444 0.0824
c0B/g.ml−3 0.00096 0.00096 0.00096 0.00096 0.00096 0.00096 0.00096 0.00096 0.00096
P/MPa 2.29 2.54 2.87 3.14 3.60 3.80 3.98 4.08 4.25
(V−V0)/V0 0.1057 0.1290 0.1501 0.1755 0.2368 0.2939 0.3235 0.3425 0.3827
c0B/g.ml−3 0.00096 0.00096 0.00096 0.00096 0.00107 0.00107 0.00107 0.00107 0.00107
P/MPa 4.32 4.40 4.52 4.81 0.00 0.68 1.19 1.76 2.34
(V−V0)/V0 0.3911 0.4038 0.4419 0.5518 0.0000 0.0196 0.0414 0.0719 0.1220
c0B/g.ml−3 0.00107 0.00107 0.00107 0.00107 0.00107 0.00107 0.00107 0.00107 0.00107
P/MPa 2.98 3.16 3.35 3.65 3.74 3.82 3.88 4.04 4.16
(V−V0)/V0 0.1830 0.2004 0.2179 0.2658 0.2584 0.2941 0.2985 0.3355 0.3617
c0B/g.ml−3 0.00107 0.00107 0.00107 0.00107 0.00107 0.00107 0.00107 0.0032 0.0032
P/MPa 4.33 4.49 4.55 4.63 4.69 4.75 4.82 0.00 1.70
(V−V0)/V0 0.4074 0.4466 0.4575 0.4793 0.4880 0.5316 0.5599 0.0000 0.0466
c0B/g.ml−3 0.0032 0.0032 0.0032 0.0032 0.0032 0.0032 0.0032 0.0032 0.0032
P/MPa 2.07 2.48 3.10 3.47 3.80 3.98 4.12 4.33 4.63
(V−V0)/V0 0.0674 0.1036 0.1736 0.2073 0.2539 0.2850 0.3109 0.3523 0.4404
c0B/g.ml−3 0.0032 0.0092 0.0092 0.0092 0.0092 0.0092 0.0092 0.0092 0.0092
P/MPa 4.80 0.00 1.11 1.82 2.50 3.07 3.66 3.99 4.20
(V−V0)/V0 0.5130 0.0000 0.0483 0.0690 0.1402 0.2207 0.2713 0.2989 0.3494
c0B/g.ml−3 0.0092 0.0092
P/MPa 4.44 4.55
(V−V0)/V0 0.4207 0.4414
Comments: Cloud points of the ternary system are given in Chapter 4.
____________________________________________________________________________________
Polymer (B): polysulfone 2003ZH1

Characterization: Mn/kg.mol−1 = 36.1, Mw/kg.mol−1 = 66.5, by GPC using PS
standards, Scientific Polymer Products, Inc., Ontario, NY
wA = 0.0984 wB = 0.0150 wC = 0.8866
____________________________________________________________________________________
T/K 299.2 323.3 348.5 373.3 398.4 424.5
____________________________________________________________________________________
P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/
MPa g cm−3 MPa g cm−3 MPa g cm−3 MPa g cm−3 MPa g cm−3 MP a g cm−3
____________________________________________________________________________________
45.58 0.8751 46.00 0.8551 49.64 0.8372 50.26 0.8177 54.63 0.8017 57.62 0.7845
40.83 0.8717 41.97 0.8522 45.77 0.8341 46.18 0.8139 51.14 0.7983 54.69 0.7813
35.17 0.8679 37.35 0.8485 42.28 0.8311 42.77 0.8105 47.04 0.7939 52.24 0.7783
29.78 0.8635 33.01 0.8451 38.72 0.8280 39.21 0.8070 44.02 0.7907 49.92 0.7755
25.72 0.8610 29.34 0.8419 35.66 0.8252 35.08 0.8026 40.04 0.7862 47.95 0.7731
23.93 0.8595 25.48 0.8386 34.60 0.8241 31.70 0.7989 35.01 0.7802 44.92 0.7694
20.45 0.8565 21.68 0.8352 30.85 0.8204 27.62 0.7944 30.01 0.7738 41.10 0.7643
16.39 0.8535 17.77 0.8316 26.53 0.8162 23.73 0.7898 25.74 0.7679 37.02 0.7587
12.20 0.8498 13.41 0.8272 22.77 0.8123 32.78 0.7523
____________________________________________________________________________________
wA = 0.0978 wB = 0.0200 wC = 0.8822
____________________________________________________________________________________
T/K 297.1 323.5 347.2 372.7 399.4 425.4
____________________________________________________________________________________
P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/
−3 −3 −3 −3 −3
MPa g cm MPa g cm MPa g cm MPa g cm MPa g cm MP a g cm−3
____________________________________________________________________________________
37.43 0.878442.87 0.8599 45.70 0.8423 49.63 0.8254 53.76 0.8083 57.85 0.7916
33.49 0.875938.61 0.8565 42.05 0.8394 46.14 0.8222 49.76 0.8043 54.16 0.7878
29.15 0.872634.67 0.8536 38.58 0.8362 42.31 0.8186 46.36 0.8009 50.97 0.7842
24.68 0.869430.59 0.8501 34.85 0.8330 38.49 0.8149 42.50 0.7965 47.27 0.7799
21.00 0.866626.88 0.8471 30.96 0.8294 34.90 0.8113 37.93 0.7912 43.56 0.7750
18.58 0.864723.28 0.8440 26.23 0.8248 32.25 0.8084 34.29 0.7867 42.66 0.7738
13.89 0.860820.64 0.8416 22.19 0.8207 28.77 0.8045 30.62 0.7820 38.62 0.7686
11.40 0.858817.34 0.8386 18.96 0.8173 25.60 0.8007 26.98 0.7772 34.86 0.7633
8.49 0.856213.64 0.8349 15.94 0.8140 22.29 0.7967 31.04 0.7577
10.11 0.8312
____________________________________________________________________________________
continued
6. PVT Data 599
____________________________________________________________________________________
continued
wA = 0.0974 wB = 0.0246 wC = 0.8780
____________________________________________________________________________________
T/K 301.2 323.2 345.6 372.4 399.2 425.0
____________________________________________________________________________________
P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/
____________________________________________________________________________________
53.48 0.9049 52.41 0.8850 52.86 0.8667 53.15 0.8455 54.55 0.8249 57.83 0.8076
49.54 0.9023 47.58 0.8816 47.94 0.8627 49.20 0.8420 51.38 0.8218 54.32 0.8035
45.34 0.8994 41.98 0.8772 43.48 0.8589 45.49 0.8383 48.71 0.8189 51.28 0.7999
42.01 0.8972 37.84 0.8740 38.99 0.8550 41.74 0.8346 46.01 0.8159 49.06 0.7971
37.95 0.8940 33.91 0.8709 35.73 0.8518 40.57 0.8332 45.07 0.8148 45.98 0.7933
34.29 0.8914 30.78 0.8683 31.95 0.8483 37.37 0.8298 42.32 0.8116 42.92 0.7892
30.31 0.8885 26.76 0.8648 28.09 0.8444 33.69 0.8258 38.43 0.8069 38.64 0.7832
27.11 0.8858 23.03 0.8614 24.38 0.8407 30.28 0.8219 34.60 0.8022 34.72 0.7775
26.39 0.8852 19.58 0.8582 21.20 0.8373 27.00 0.8179 30.97 0.7973 31.13 0.7719
23.32 0.8829 15.85 0.8546
19.58 0.8797
15.79 0.8765
____________________________________________________________________________________
wA = 0.0967 wB = 0.0301 wC = 0.8732
____________________________________________________________________________________
T/K 303.1 320.0 347.8 372.1 397.0 424.3
____________________________________________________________________________________
P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/
−3 −3 −3 −3 −3
____________________________________________________________________________________
53.29 0.8685 57.95 0.8558 57.06 0.8349 58.19 0.8174 59.53 0.7991 61.57 0.7800
50.21 0.8665 53.44 0.8530 52.95 0.8318 54.00 0.8138 56.62 0.7965 57.86 0.7761
47.69 0.8648 49.37 0.8500 49.80 0.8292 50.11 0.8103 52.72 0.7926 55.22 0.7732
44.06 0.8624 45.27 0.8471 46.07 0.8262 47.52 0.8078 50.90 0.7909 53.85 0.7716
40.99 0.8603 41.48 0.8444 43.79 0.8242 43.83 0.8042 47.42 0.7872 49.92 0.7670
38.63 0.8585 38.64 0.8423 40.01 0.8209 40.35 0.8007 42.96 0.7824 46.48 0.7628
35.01 0.8559 34.54 0.8392 36.64 0.8178 36.79 0.7971 39.09 0.7780 42.21 0.7574
30.89 0.8529 30.70 0.8362 32.74 0.8142 35.71 0.7740
26.84 0.8497 26.61 0.8329 28.77 0.8104
23.20 0.8470
____________________________________________________________________________________
continued
____________________________________________________________________________________
continued
wA = 0.0969 wB = 0.0321 wC = 0.8710
____________________________________________________________________________________
T/K 296.4 324.8 349.4 375.5 400.0 426.3
____________________________________________________________________________________
P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/
____________________________________________________________________________________
56.87 0.9025 58.70 0.8808 56.98 0.8597 57.43 0.8387 57.65 0.8197 57.55 0.7985
52.53 0.8997 54.16 0.8777 53.40 0.8569 53.78 0.8356 54.91 0.8168 55.92 0.7966
45.15 0.8949 49.96 0.8746 49.86 0.8540 50.37 0.8325 53.02 0.8149 53.63 0.7941
42.03 0.8929 46.02 0.8715 46.74 0.8514 47.35 0.8295 50.68 0.8124 50.29 0.7901
37.85 0.8900 42.36 0.8686 43.71 0.8488 43.99 0.8262 46.63 0.8080 46.34 0.7850
36.29 0.8888 40.41 0.8670 40.31 0.8457 39.74 0.8218 42.39 0.8031 41.75 0.7791
31.87 0.8857 36.31 0.8638 36.08 0.8418 35.54 0.8174 37.98 0.7982 37.90 0.7739
26.35 0.8816 31.52 0.8598 31.57 0.8376 31.04 0.8125 33.39 0.7925 34.10 0.7683
22.19 0.8784 25.41 0.8545 26.99 0.8331
17.67 0.8747
____________________________________________________________________________________
wA = 0.0966 wB = 0.0366 wC = 0.8668
____________________________________________________________________________________
T/K 298.6 323.6 348.6 373.8 398.8 423.7
____________________________________________________________________________________
P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/
____________________________________________________________________________________
38.18 0.885241.90 0.8670 45.68 0.8489 46.02 0.8288 50.79 0.8128 53.95 0.7966
32.44 0.881337.51 0.8634 41.07 0.8451 41.89 0.8248 46.28 0.8080 51.02 0.7934
28.24 0.878233.59 0.8604 36.87 0.8413 37.67 0.8203 42.81 0.8042 48.04 0.7898
23.40 0.874729.16 0.8567 33.02 0.8378 34.26 0.8169 39.82 0.8008 44.76 0.7858
18.90 0.871224.89 0.8530 29.90 0.8348 33.14 0.8155 38.42 0.7991 42.95 0.7835
13.79 0.867020.94 0.8495 27.45 0.8325 29.10 0.8111 34.52 0.7946 39.55 0.7788
10.87 0.864417.24 0.8461 22.41 0.8271 25.10 0.8065 30.40 0.7893 35.73 0.7736
8.14 0.862014.17 0.8430 19.16 0.8238 20.67 0.8013 26.42 0.7841 31.42 0.7676
10.43 0.8395 14.42 0.8186 16.84 0.7964 23.47 0.7799 28.09 0.7624
____________________________________________________________________________________
continued
6. PVT Data 601
____________________________________________________________________________________
continued
wA = 0.0948 wB = 0.0444 wC = 0.8608
____________________________________________________________________________________
T/K 308.3 321.7 346.9 372.2 398.6 426.0
____________________________________________________________________________________
P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/
____________________________________________________________________________________
52.72 0.8888 52.04 0.8783 53.25 0.8590 53.17 0.8378 54.16 0.8165 53.98 0.7951
48.62 0.8862 48.02 0.8756 48.45 0.8552 49.62 0.8348 51.05 0.8133 51.17 0.7919
44.32 0.8832 44.02 0.8726 44.66 0.8520 46.45 0.8319 47.19 0.8093 48.81 0.7890
39.86 0.8799 39.21 0.8691 40.73 0.8485 42.73 0.8284 43.98 0.8056 46.84 0.7865
35.16 0.8765 34.70 0.8656 37.81 0.8458 37.18 0.8226 42.43 0.8039 43.60 0.7823
30.89 0.8732 31.04 0.8626 31.99 0.8402 34.45 0.8199 38.31 0.7992 41.03 0.7789
27.38 0.8707 26.31 0.8585 28.13 0.8364 31.12 0.8161 35.07 0.7952 38.20 0.7751
22.97 0.8670 23.17 0.8559 24.21 0.8325 27.29 0.8119 31.39 0.7907 34.86 0.7705
19.47 0.8642 19.77 0.8528 20.20 0.8284
15.94 0.8612 16.21 0.8494
12.35 0.8581 12.24 0.8456
____________________________________________________________________________________
wA = 0.0954 wB = 0.0496 wC = 0.8550
____________________________________________________________________________________
T/K 299.2 323.2 348.9 374.8 400.8 425.3
____________________________________________________________________________________
P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/ P/ ρ/
−3 −3 −3 −3 −3
____________________________________________________________________________________
56.01 0.8837 57.15 0.8682 57.45 0.8480 58.09 0.8282 59.45 0.8089 60.14 0.7906
50.90 0.8810 53.62 0.8659 53.51 0.8450 54.01 0.8247 56.28 0.8061 58.32 0.7887
46.48 0.8783 49.44 0.8629 50.21 0.8423 51.24 0.8220 53.48 0.8031 56.31 0.7863
42.88 0.8761 45.68 0.8601 47.99 0.8405 49.24 0.8200 52.00 0.8015 54.91 0.7846
40.37 0.8745 42.96 0.8582 46.06 0.8388 45.52 0.8166 48.29 0.7976 51.51 0.7807
35.69 0.8713 37.43 0.8537 42.04 0.8354 41.33 0.8124 45.11 0.7941 47.95 0.7765
31.19 0.8682 33.08 0.8503 38.30 0.8320 37.09 0.8081 41.44 0.7902 43.64 0.7714
26.98 0.8648 28.88 0.8467 33.84 0.8280 32.02 0.8028 38.08 0.7863 39.59 0.7661
____________________________________________________________________________________
____________________________________________________________________________________
6.3. References
1976REN Renuncio, J.A.R. and Prausnitz, J.M., Densities of polymer solutions to 1 kbar,
1979KOB Kobyakov, V.M., Kogan, V.B., Rätzsch, M., and Zernov, V.S., Sootnoshenie P-V-T-N dlya
smesey etilena s niskomolekulyarnym polietilenom, Plast. Massy, 8, 21, 1979.
1987VE1 Vennemann, N., Lechner, M.D., and Oberthür, R.C., Thermodynamics and conformation of
1987VE2 Vennemann, N., Der Einfluss von hohem Druck auf thermodynamische und strukturelle
Eigenschaften von Polyoxiethylen in wäßriger Lösung, Ph.D. Thesis, Universität Osnabrück,
1987.
1989OUG Ougizawa, T., Dee, G.T., and Walsh, D.J., PVT properties and equation of state of
polystyrene. Molecular weight dependence of the characteristic parameters in equation-of-
state theories (experimental data by D.J. Walsh), Polymer, 30, 1675, 1989.
1991FAK Fakhreddine, Y.A. and Zoller, P., The equation of state of solid and molten poly(butylene
terephthalate) to 300°C and 200 MPa (experimental data by P. Zoller), J. Polym. Sci.: Part
B: Polym. Phys., 29, 1141, 1991,
1993JAN Janssen, S., Schwahn, D., Mortensen, K., and Springer, T., Pressure dependence of the
Flory-Huggins interaction parameter in polymer blends. A SANS study and a comparison to
the Flory-Orwoll-Vrij equation of state (experimental data by S. Janssen), Macromolecules,
26, 5587, 1993.
1992KIM Kim, C.K. and Paul, D.R., Interaction parameters for blends containing polycarbonates. 1.
Tetramethyl bisphenol-A polycarbonate/polystyrene, Polymer, 33, 1630, 1992.
1992WIN Wind, R.W., Untersuchungen zum Phasenverhalten von Mischungen aus Ethylen, Acrylsäu-
re und Ethylen-Acrylsäure-Copolymeren unter hohem Druck, Ph.D. Thesis, TH Darmstadt,
1992.
1993ROG Rodgers, P.A., Pressure-volume-temperature relationships for polymeric liquids. A review
of equations of state and their characteristic parameters for 56 polymers, J. Appl. Polym.
Sci., 48, 1061, 1993.
1994COM Compostizo, A., Cancho, S.M., Colin, A.C., and Rubio, R.G., Polymer solutions with speci-
fic interactions: equation of state for poly(4-hydroxystyrene) + acetone, Macromolecules,
27, 3478, 1994.
1994MER Mertsch, R. and Wolf, B.A., Solutions of poly(dimethylsiloxane) in supercritical CO2:
viscometric and volumetric behavior, Macromolecules, 27, 3289, 1994.
1995COM Compostizo, A., Cancho, S.M., Rubio, R.G., and Colin, A.C., Equation of state of
hydrogen-bonded polymer solutions: poly(4-hydroxystyrene) + ethanol and + tetrahydro-
furan, J. Phys. Chem., 99, 10261, 1995.
1996MAI Maier, R.-D., Kressler, J., Rudolf, B., Reichert, P., Koopman, F., Frey, H., and Mühlhaupt,
R., Miscibility of poly(sila-α-methylstyrene) with polystyrene (experimental data by J.
Kressler), Macromolecules, 29, 1490, 1996.
1997COL Colin, A.C., Cancho, S.M., Rubio, R.G., and Compostizo, A., Equation of state of
hydrogen-bonded polymer solutions. Poly(propylene glycol) + n-hexane and poly(propylene
glycol) + ethanol, Macromolecules, 30, 3389, 1997.
1997SAT Sato, Y., Yamasaki, Y., Takishima, S., and Masuoka, H., Precise measurement of the PVT
of polypropylene and polycarbonate up to 330°C and 200 MPa, J. Appl. Polym. Sci., 66,
141, 1997.
6. PVT Data 603
____________________________________________________________________________________
1998AAL Aalto, M.M. and Liukkonen, S.S., Liquid densities of propane + linear low-density poly-
ethylene systems at (354-378) K and (4.00-7.00) MPa, J. Chem. Eng. Data, 43, 29, 1998.
1998LUN Luna-Barcenas, G., Mawson, S., Takishima, S., DeSimone, J.M., Sanchez, I.C., and
Johnston, K.P.: Phase behavior of poly(1,1-dihydroperfluorooctyl acrylate) in supercritical
carbon dioxide, Fluid Phase Equil., 146, 325, 1998.
1998SAC Sachdev, V.K., Yashi, U., and Jain, R.K., Equation of state of poly(dimethylsiloxane) melts,
J. Polym. Sci.: Part B: Polym. Phys., 36, 841, 1998.
1999CRE Crespo Colin, A., Cancho, S.M., Rubio, R.G., and Compostizo, A., Equation of state of
aqueous polymer systems: poly(propylene glycol) + water, Phys. Chem. Chem. Phys., 1,
319, 1999.
1999CHU Chu, J.H. and Paul, D.R., Interaction energies for blends of SAN with methyl methacrylate
copolymers with ethyl acrylate and n-butyl acrylate, Polymer, 40, 2687, 1999.
1999INO Inomata, H., Honma, Y., Imahori, M., and Arai, K., Fundamental study of desolventing
polymer solutions with supercritical CO2, Fluid Phase Equil., 158-160, 857, 1999.
1999LEE Lee, M.-J., Lo, C.-K., and Lin, H.-M., PVT measurements for mixtures of 1-octanol with
oligomeric poly(ethylene glycol) from 298 K to 338 K and pressures up to 30 MPa, J.
Chem. Eng. Data, 44, 1379, 1999.
1999MAI Maier, R.-D., Thermodynamik und Kristallisation von Metallocen-Polyolefinen
(experimental data by R.-D. Maier), Ph.D. Thesis, Albert-Ludwigs-Universität, Freiburg i.
Br., 1999.
2000BY1 Byun, H.-S., DiNoia, T.P., and McHugh, M.A., High-pressure densities of ethane, pentane,
pentane-d12, 25.5 wt% ethane in pentane-d12, 2.4 wt% deuterated poly(ethylene-co-butene)
(PEB) in ethane, 5.3 wt% hydrogenated PEB in pentane, 5.1 wt % hydrogenated PEB in
pentane-d12, and 4.9 wt % hydrogenated PEB in pentane-d12 + 23.1 wt % ethane, J. Chem.
Eng. Data, 45, 810, 2000.
2000BY2 Byun, H.-S., Kim, K., and Lee, H.-S., High-pressure phase behavior and mixture density of
binary poly(ethylene-co-butene)-dimethyl ether system, Hwahak Konghak, 38, 826, 2000.
2000LEE Lee, M.-J., Tuan, Y.-C., and Lin, H.-M., Pressure, volume, and temperature for mixtures of
poly(ethylene glycol methyl ether)-350 + anisole and poly(ethylene glycol)-200 + anisole
from 298 K to 338 K and pressures up to 50 MPa, J. Chem. Eng. Data, 45, 1100, 2000.
2000SAT Sato, Y., Inohara, K., Takishima, S., Masuoka, H., Imaizumi, M., Yamamoto, H., and
Takasugi, M., Pressure-volume-temperature behavior of polylactide, poly(butylene
succinate), and poly(butylene succinate-co-adipate), Polym. Eng. Sci., 40, 2602, 2000.
2001LI2 Li, D., Han, B., Liu, Z., Liu, J., Zhang, X., Wang, S., and Zhang, X., Effect of gas
antisolvent on conformation of polystyrene in toluene: Viscosity and small-angle X-ray
scattering study (experimental data by B. Han), Macromolecules, 34, 2195, 2001.
2001LIN Lin, H.-M., Hsu, T.-S., and Lee, M.-J., Pressure-volume-temperature properties for binary
polymer solutions of poly(propylene glycol) with 1-octanol and acetophenone,
2001MEK Mekhilef, N., Viscoelastic and pressure-volume-temperature properties of poly(vinylidene
fluoride) and poly(vinylidene fluoride)-hexafluoropropylene copolymers (experimental
PVT data by N. Mekhilef), J. Appl. Polym. Sci., 80, 230, 2001.
2002COM Comunas, M.J.P., Baylaucq, A., Boned, C., Canet, X., and Fernandez, J., High-pressure
volumetric behavior of x 1,1,1,2-tetrafluoroethane + (1-x) 2,5,8,11,14-pentaoxapentadecane
(TEGDME) mixtures, J. Chem. Eng. Data, 47, 233, 2002.
2002DIN Dindar, C. and Kiran, E., High-pressure viscosity and density of polymer solutions at the
critical polymer concentration in near-critical and supercritical fluids, Ind. Eng. Chem. Res.,
41, 6354, 2002.
____________________________________________________________________________________
2003ACE Acevedo, I.L., Lugo, L., Comunas, M.J.P., Arancibia, E.L., and Fernandez, J., Volumetric
properties of binary tetraethylene glycol dimethyl ether + heptane mixtures between (278.15
and 353.15) K and up to 25 MPa, J. Chem. Eng. Data, 48, 1271, 2003.
2003LEE Lee, M.-J., Tuan, Y.-C., and Lin, H.-M., Pressure-volume-temperature properties for binary
and ternary polymer solutions of poly(ethylene glycol), poly(propylene glycol), and
poly(ethylene glycol methyl ether) with anisole, Polymer, 44, 3891, 2003.
2003WOH Wohlfarth, C., Pressure-volume-temperature relationship for polymer melts, in CRC
Handbook of Chemistry and Physics, 84th ed., pp. 13-16 to 13-20, 2003.
2004BOL Bolotnikov, M.F., Verveyko, V.N., and Verveyko, M.V., Speeds of sound, densities, and
isentropic compressibilities of poly(propylene glycol)-425 at temperatures from (293.15 to
373.15) K and pressures up to 100 MPa, J. Chem. Eng. Data, 49, 631, 2004.
2004KIM Kim, J.H., Whang, M.S., and Kim, C.K., Novel miscible blends composed of poly(ether
sulfone) and poly(1-vinylpyrrolidone-co-styrene) copolymers and their interaction energies,
7. PRESSURE DEPENDENCE OF THE SECOND VIRIAL
COEFFICIENTS (A2) OF POLYMER SOLUTIONS
_____________________________________________________________________________
Polymer (B) Mn/ Mw/ Solvent (A) T/ P/ 104A2/ Ref.
kg/mol kg/mol K MPa cm3mol/g2
_____________________________________________________________________________
Dextran
1000 water 303.15 0.1 0.85 1991STA
1000 water 303.15 200.0 0.74 1991STA
1000 water 343.15 0.1 2.1 1991STA
1000 water 343.15 200.0 1.6 1991STA
1000 water 373.15 0.1 1.8 1991STA
1000 water 373.15 200.0 1.6 1991STA
7400 water 303.15 0.1 0.099 1991STA
7400 water 303.15 200.0 0.092 1991STA
7400 water 343.15 0.1 0.064 1991STA
7400 water 343.15 200.0 0.062 1991STA
7400 water 373.15 0.1 0.078 1991STA
7400 water 373.15 200.0 0.077 1991STA
17500 water 303.15 0.1 0.013 1991STA
17500 water 303.15 200.0 0.013 1991STA
17500 water 323.15 0.1 0.018 1991STA
17500 water 323.15 200.0 0.019 1991STA
17500 water 343.15 0.1 0.014 1991STA
17500 water 343.15 200.0 0.011 1991STA
17500 water 373.15 0.1 0.011 1991STA
17500 water 373.15 200.0 0.010 1991STA
21100 water 303.15 0.1 0.017 1991STA
21100 water 303.15 200.0 0.014 1991STA
21100 water 323.15 0.1 0.015 1991STA
21100 water 323.15 200.0 0.015 1991STA
21100 water 343.15 0.1 0.015 1991STA
21100 water 343.15 200.0 0.018 1991STA
21100 water 373.15 0.1 0.0045 1991STA
21100 water 373.15 200.0 0.0046 1991STA
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Polyacrylamide
1400 water 298.15 0.1 1.80 1981LEC
1400 water 298.15 50.0 1.60 1981LEC
1400 water 298.15 100.0 1.30 1981LEC
1400 water 298.15 150.0 1.90 1981LEC
1400 water 298.15 200.0 2.10 1981LEC
_____________________________________________________________________________
Poly(dimethyl siloxane)
578 benzene 300.15 0.1 2.95 1976KUB
578 benzene 300.15 9.8 3.02 1976KUB
578 benzene 300.15 19.6 3.02 1976KUB
578 benzene 300.15 29.4 3.03 1976KUB
578 benzene 300.15 39.2 3.00 1976KUB
578 bromocyclohexane 300.15 0.1 −0.0158 1976KUB
578 bromocyclohexane 300.15 9.8 0.0258 1976KUB
578 chlorobenzene 303.15 0.1 1.04 1976KUB
578 toluene 300.15 0.1 4.50 1976KUB
578 toluene 300.15 9.8 4.46 1976KUB
578 toluene 300.15 19.6 4.63 1976KUB
578 toluene 300.15 29.4 4.67 1976KUB
578 toluene 300.15 39.2 4.67 1976KUB
_____________________________________________________________________________
7. A2 Data 607
_____________________________________________________________________________

_____________________________________________________________________________
20 deuterium oxide 298.15 0.1 24.0 1987VEN
_____________________________________________________________________________
Polyisobutylene
703 1020 2-methylbutane 297.15 0.1 0.70 1972GAE
703 1020 2-methylbutane 330.15 0.1 −0.50 1972GAE
690 n-pentane 343.15 0.1 −0.55 1971WOL
690 n-pentane 343.15 5.2 −0.10 1971WOL
690 n-pentane 343.15 10.1 0.15 1971WOL
690 n-pentane 343.15 20.3 0.50 1971WOL
690 n-pentane 343.15 40.5 0.80 1971WOL
690 n-pentane 343.15 60.8 1.00 1971WOL
690 n-pentane 343.15 81.1 1.15 1971WOL
690 2,2,4-trimethylpentane 298.15 0.1 2.30 1971WOL
_____________________________________________________________________________
Polystyrene
975 2-butanone 295.15 0.1 1.10 1972GAE
975 2-butanone 295.15 5.0 1.20 1972GAE
975 2-butanone 295.15 12.0 1.70 1972GAE
100 cyclohexane 313.15 0.1 0.40 1970LEC
100 cyclohexane 313.15 20.3 0.39 1970LEC
100 cyclohexane 313.15 40.5 0.25 1970LEC
100 cyclohexane 318.15 0.1 0.79 1970LEC
100 cyclohexane 318.15 20.3 0.84 1970LEC
100 cyclohexane 318.15 40.5 0.87 1970LEC
100 cyclohexane 323.15 0.1 1.11 1970LEC
100 cyclohexane 323.15 20.3 1.18 1970LEC
100 cyclohexane 323.15 40.5 1.19 1970LEC
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
415 440 decalin 297.15 0.1 0.84 1976MCD
415 440 decalin 297.15 137.2 −0.50 1976MCD
739 850 decalin 297.15 0.1 0.55 1976MCD
739 850 decalin 297.15 137.2 −0.20 1976MCD
415 440 cis-decalin 297.15 0.1 1.12 1976MCD
415 440 cis-decalin 297.15 137.2 −0.30 1976MCD
100 trans-decalin 288.15 0.1 −0.25 1970LEC
100 trans-decalin 293.15 0.1 +0.20 1970LEC
100 trans-decalin 298.15 0.1 0.30 1970LEC
415 440 trans-decalin 297.15 0.1 0.29 1976MCD
415 440 trans-decalin 297.15 137.2 −0.30 1976MCD
_____________________________________________________________________________
7. A2 Data 609
_____________________________________________________________________________

_____________________________________________________________________________
1800 trans-decalin 298.15 0.1 0.19 1970SCH
1800 trans-decalin 298.15 57.0 −0.01 1970SCH
1563 2500 trans-decalin 299.15 0.1 0.26 1971LEC
1563 2500 trans-decalin 299.15 121.6 −0.26 1971LEC
1563 2500 trans-decalin 299.15 182.4 −0.50 1971LEC
160 170 ethyl acetate 297.15 0.1 2.01 1976MCD
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
1700 ethyl acetate 297.15 0.1 1.18 1976MCD
860 4-methyl-2-pentanone 297.15 0.1 0.50 1973MCD
100 toluene 303.15 0.1 4.60 1970LEC
100 toluene 303.15 20.3 4.60 1970LEC
100 toluene 303.15 40.5 4.60 1970LEC
100 toluene 303.15 60.8 4.60 1970LEC
100 toluene 303.15 81.1 4.60 1970LEC
100 toluene 303.15 0.1 4.60 1972SCH
100 toluene 303.15 20.3 4.60 1972SCH
100 toluene 303.15 40.5 4.60 1972SCH
100 toluene 303.15 60.8 4.60 1972SCH
100 toluene 303.15 81.1 4.60 1972SCH
415 440 toluene 297.15 0.1 5.65 1976MCD
415 440 toluene 297.15 392.2 6.50 1976MCD
1700 toluene 297.15 0.1 4.43 1976MCD
1700 toluene 297.15 392.2 5.70 1976MCD
1800 toluene 288.15 0.1 2.24 1970LEC
1800 toluene 288.15 19.0 2.40 1970LEC
1800 toluene 288.15 38.0 2.35 1970LEC
1800 toluene 288.15 57.0 2.42 1970LEC
1800 toluene 288.15 76.0 2.39 1970LEC
1800 toluene 298.15 0.1 2.27 1970LEC
1800 toluene 298.15 19.0 2.38 1970LEC
1800 toluene 298.15 38.0 2.40 1970LEC
1800 toluene 298.15 57.0 2.46 1970LEC
1800 toluene 298.15 76.0 2.41 1970LEC
100 trichloromethane 303.15 0.1 5.40 1970LEC
100 trichloromethane 303.15 0.1 5.40 1972SCH
_____________________________________________________________________________
7. A2 Data 611
_____________________________________________________________________________

_____________________________________________________________________________
415 440 trichloromethane 297.15 0.1 8.75 1976MCD
_____________________________________________________________________________
_____________________________________________________________________________
∂A2/∂
7.2. Pressure coefficient of the second virial coefficient (∂ ∂P)T at
zero pressure
_____________________________________________________________________________
Polymer (B) Mn/ Mw/ Solvent (A) T/ 104A2/ 106(∂
∂A2/∂
∂P)T/ Ref.
kg/mol kg/mol K cm3mol/g2 cm3mol/g2MPa
_____________________________________________________________________________
20 deuterium oxide 298.15 24.0 −8.0 1987VEN
_____________________________________________________________________________
Polyisobutylene
703 1020 2-methylbutane 330.15 −0.50 15.5 1972GAE
703 1020 2-methylbutane 337.15 −0.90 16.5 1972GAE
690 n-pentane 343.15 −0.55 8.3 1971WOL
_____________________________________________________________________________
Polystyrene
975 2-butanone 295.15 1.10 5.0 1972GAE
24.6 25 cyclohexane 295.15 −2.10 −3.3 2003MOS
24.6 25 cyclohexane 314.15 0.90 −1.7 2003MOS
100 cyclohexane 313.15 0.40 −0.4 1970LEC
100 cyclohexane 318.15 0.79 0.3 1970LEC
100 cyclohexane 323.15 1.11 0.2 1970LEC
377 400 cyclohexane 300.15 −2.90 1.3 2003MOS
849 900 cyclohexane 302.15 −4.20 2.8 2003MOS
86.5 90 decalin 298.15 2.00 −2.6 2003MOS
415 440 decalin 297.15 0.84 −1.0 1976MCD
739 850 decalin 297.15 0.55 −0.6 1976MCD
415 440 cis-decalin 297.15 1.12 −1.0 1976MCD
100 trans -decalin 288.15 −0.25 −0.7 1970LEC
100 trans -decalin 293.15 0.00 −0.5 1970LEC
100 trans -decalin 313.15 1.11 0.1 1970LEC
415 440 trans -decalin 297.15 0.29 −0.4 1976MCD
_____________________________________________________________________________
7. A2 Data 613
_____________________________________________________________________________
Polymer (B) Mn/ Mw/ Solvent (A) T/ 104A2/ 106(∂

∂A2/∂
∂P)T/ Ref.
kg/mol kg/mol K cm3mol/g2 cm3mol/g2MPa
_____________________________________________________________________________
1563 2500 trans -decalin 299.15 0.26 −0.4 1971LEC
1563 2500 trans -decalin 332.65 1.06 0.1 1971LEC
24.6 25 methylcyclohexane 295.15 −6.00 5.5 2003MOS
86.5 90 toluene 298.15 3.00 3.4 2003MOS
100 toluene 303.15 4.60 0.0 1970LEC
415 440 toluene 297.15 5.65 0.4 1976MCD
1700 toluene 297.15 4.43 0.4 1976MCD
1800 toluene 288.15 2.24 0.4 1970LEC
1800 toluene 298.15 2.27 0.4 1970LEC
86.5 90 trichloromethane 298.15 4.60 3.0 2003MOS
100 trichloromethane 303.15 4.60 −3.8 1970LEC
415 440 trichloromethane 297.15 8.75 −0.2 1976MCD
_____________________________________________________________________________
_____________________________________________________________________________
7.3. References
1970LEC Lechner, M.D. and Schulz, G.V., Lichtstreuung von hochmolekularen Lösungen in
Abhängigkeit von Temperature und Druck, Eur. Polym. J., 6, 945, 1970.
1970SCH Schulz, G.V. and Lechner, M.D., A light-scattering photometer for use at elevated
pressures, J. Polym. Sci.: Part A-2, 8, 1885, 1970.
1971LEC Lechner, M.D. and Schulz, G.V., Über die Beziehung zwischen der Winkelabhängigkeit
und der Wellenlängenabhängigkeit bei Streulichtmessungen, Makromol. Chem., 148, 325,
1971.
1971WOL Wolf, Streulichtmessungen an exotherm-pseudoidealen Lösungen in Abhängigkeit von
Druck und Temperatur, Ber. Bunsenges. Phys. Chem., 75, 924, 1971.
1972LEC Lechner, M.D., Schulz, G.V., and Wolf, B.A., Thermodynamics of polymer solutions as
functions of pressure and temperature, J. Coll. Interface Sci., 39, 462, 1972.
1972GAE Gaeckle, D. and Patterson, D., Effect of pressure on the second virial coefficient and chain
dimensions in polymer solutions, Macromolecules, 5, 136, 1972.
1972SCH Schulz, G.V. and Lechner, M.D., Influence of pressure and temperature, in Light Scattering
from Polymer Solutions, Huglin, M.B., Ed., Academic Press, New York, 1972, 503.
1973MCD McDonald, C.J. and Claesson, S., Light scattering measurements under high pressure. I.
Pure solvents and polystyrene in methyl isobutyl ketone, Chem. Scripta, 4, 155, 1973.
1976KUB Kubota, K., Kubo, K., and Ogino, K., The pressure and temperature dependence of the
second virial coefficients and the chain dimensions of polydimethylsiloxane solutions, Bull.
Chem. Soc. Japan, 49, 2410, 1976.
1976MCD McDonald, C.J. and Claesson, S., Light scattering measurements under high pressure. II.
Dilute solution properties of polystyrene, Chem. Scripta, 9, 36, 1976.
1979HAM Hammel, G.L., Schulz, G.V., and Lechner, M.D., Die Knäueldimensionen von Polystyrol in
verschiedenen Lösungsmitteln unter hohen Drucken, Eur. Polym. J., 15, 209, 1979.
1981LEC Lechner, M.D. and Steinmeier, D.G., Das Verhalten von Polyacrylamidlösungen unter
hohen Drücken, Macromol. Chem., Rapid Commun., 2, 421, 1981.
1987VEN Vennemann, N., Lechner, M.D., and Oberthür, R.C., Thermodynamics and conformation of
1991STA Stankovic, R.I., Jovanovic, S., Ilic, L., Nordmeier, E., and Lechner, M.D., Study of aqueous
dextran solutions under high pressures and different temperatures by dynamic light
scattering, Polymer, 32, 235, 1991.
2003MOS Moses, C.L. and van Hook, W.A., Pressure dependence of the second virial coefficient of
dilute polystyrene solutions, J. Polym. Sci.: Polym. Phys., 41, 3070, 2003.
APPENDICES
Appendix 1 List of systems and properties in order of the polymers
_____________________________________________________________________________
_____________________________________________________________________________
Butylene succinate/butylene adipate copolymer
carbon dioxide gas solubility 17
____________________________________________________________________________________
Butyl methacrylate/N,N-dimethylaminoethyl
methacrylate block copolymer
____________________________________________________________________________________
Butyl methacrylate/perfluoroalkylethyl
acrylate block copolymer
____________________________________________________________________________________
Dextran
water A2 605
____________________________________________________________________________________
− PVT 551
ethene HPPE 227-232
ethene + acrylic acid HPPE 407-408
ethene + n-decane HPPE 409
ethene + ethanol HPPE 409-410
ethene + ethyl acetate HPPE 410-411
ethene + n-heptane HPPE 411
ethene + octanoic acid HPPE 411-412
ethene + 2,2,4-trimethyl-
pentane HPPE 412
____________________________________________________________________________________
− PVT 551-552
1-butene HPPE 232-234
dimethyl ether density 567
dimethyl ether-d6 density 567-568
ethane density 568
ethane + n-pentane-d12 density 592
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Ethylene/1-butene copolymer (continued)
ethene HPPE 234-235
ethene + 1-butene HPPE 412
n-pentane density 568-569
n-pentane-d12 density 569
propane HPPE 235-237
____________________________________________________________________________________
ethene HPPE 237-241
ethene + butyl acrylate HPPE 413-414
ethene + methyl acrylate HPPE 414-415
____________________________________________________________________________________
Ethylene/butyl methacrylate copolymer
ethene HPPE 241
____________________________________________________________________________________
ethene HPPE 242
____________________________________________________________________________________
ethene HPPE 243
ethene + 2-ethylhexyl acrylate HPPE 415
____________________________________________________________________________________
ethene HPPE 243-244
ethene + n-butane HPPE 415
ethene + carbon dioxide HPPE 415-416
ethene + ethane HPPE 416
ethene + helium HPPE 416
ethene + 1-hexene HPPE 417-418
ethene + 1-hexene + n-butane HPPE 418-419
ethene + 1-hexene + helium HPPE 419-420
ethene + 1-hexene + methane HPPE 420-421
ethene + 1-hexene + nitrogen HPPE 421
ethene + methane HPPE 422
ethene + nitrogen HPPE 422
ethene + propane HPPE 422-423
2-methylpropane HPPE 244-246
2-methylpropane + 1-hexene HPPE 423
____________________________________________________________________________________
ethene HPPE 249-251
____________________________________________________________________________________
Appendices 617
_____________________________________________________________________________

_____________________________________________________________________________
ethene HPPE 251-254
____________________________________________________________________________________
Ethylene/methyl methacrylate copolymer
ethene HPPE 254-255
ethene + butyl acrylate HPPE 423
ethene + 2-ethylhexyl acrylate HPPE 424
ethene + n-heptane HPPE 424
ethene + methyl acrylate HPPE 424-425
____________________________________________________________________________________
Ethylene/norbornene copolymer
ethene + toluene
+ bicyclo[2,2,1]-2-heptene VLE 84-86
____________________________________________________________________________________
− PVT 552
ethene HPPE 255-256
propane HPPE 257
____________________________________________________________________________________
Ethylene/propyl acrylate copolymer
ethene HPPE 258-259
____________________________________________________________________________________
− PVT 553
1-butene VLE 19
ethene gas solubility 19-20
ethene HPPE 260-262
ethene + 1-butene HPPE 425
ethene + carbon dioxide HPPE 425-426
ethene + 1-hexene HPPE 426-427
1-hexene HPPE 262-263
propane HPPE 263
propene HPPE 264-266
propene + ethylene/propylene
copolymer HPPE 427-428
propene + ethylene/propylene
copolymer + n-dodecane HPPE 428
____________________________________________________________________________________
Ethylene/propylene block copolymer
ethene + n-hexane VLE, K∞ 86
propene gas solubility 20
propene + n-hexane VLE, K∞ 87
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Ethylene/propylene/isoprene terpolymer
dimethyl ether HPPE 267
ethane HPPE 267
ethene HPPE 267-268
propane HPPE 268
propene HPPE 268
____________________________________________________________________________________
− PVT 553-554
ethene HPPE 268-280
ethene + carbon dioxide HPPE 428
ethene + ethane HPPE 429
ethene + helium HPPE 429
ethene + nitrogen HPPE 430
ethene + propane HPPE 430
ethene + vinyl acetate HPPE 430-440
ethene + vinyl acetate
+ carbon dioxide HPPE 441
+ helium HPPE 442
+ 2-methyl-2-propanol HPPE 443-444
+ nitrogen HPPE 444-445
cyclopentane LLE 111
cyclopentene LLE 111
____________________________________________________________________________________
N-Isopropylacrylamide/1-deoxy-1-
methacryl-amido-D-glucitol copolymer
water LLE 111-112
____________________________________________________________________________________
DL-Lactide/glycolide copolymer
carbon dioxide HPPE 281-282
chlorodifluoromethane HPPE 282-283
dimethyl ether HPPE 283-284
trifluoromethane HPPE 284
____________________________________________________________________________________
Nylon 6
carbon dioxide
+ 2,2,2-trifluoroethanol HPPE 445-446
styrene VLE 22
____________________________________________________________________________________
Appendices 619
_____________________________________________________________________________

_____________________________________________________________________________
n-dodecane LLE 112-113
water LLE 113-114
____________________________________________________________________________________
Poly(acrylamide)
water A2 606
____________________________________________________________________________________
Polybutadiene
carbon dioxide + cyclohexane VLE 87-88
carbon dioxide + cyclohexane HPPE 446
carbon dioxide + n-hexane VLE, K∞ 88
carbon dioxide
+ tetrahydrofuran HPPE 446-448
carbon dioxide + toluene VLE 88-89
carbon dioxide + toluene HPPE 448-450
cyclohexane VLE 22
1,2-dichlorobenzene +
polystyrene LLE 205-206
ethene HPPE 285-286
n-hexane density 570
____________________________________________________________________________________
Poly(1-butene)
− PVT 554
____________________________________________________________________________________
− PVT 556
carbon dioxide HPPE 288
____________________________________________________________________________________
Poly(butylene glycol)
____________________________________________________________________________________
Poly(butylene oxide)-b-poly(ethylene oxide)
diblock copolymer
____________________________________________________________________________________
carbon dioxide gas solubility 23-24
carbon dioxide + butyl
methacrylate VLE 87
carbon dioxide + butyl
methacrylate HPPE 450-451
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Poly(butylene succinate)
− PVT 554-555
____________________________________________________________________________________
Poly(butylene terephthalate)
− PVT 555
____________________________________________________________________________________
ethanol LLE 114
ethene HPPE 289
____________________________________________________________________________________
− PVT 556-557
____________________________________________________________________________________
− PVT 557
____________________________________________________________________________________
Polycarbonate tetramethyl bisphenol-A
− PVT 557-558
____________________________________________________________________________________
Poly(chlorotrifluoroethylene)
____________________________________________________________________________________
Poly(1,1-dihydroxyperfluorooctyl acrylate)
− PVT 558
____________________________________________________________________________________
Poly(2,6-dimethyl-1,4-phenylene ether)
carbon dioxide + polystyrene gas solubility 89
____________________________________________________________________________________
− PVT 559
benzene A2 606
bromocyclohexane A2 606
n-butane LLE 114
carbon dioxide swelling 25-26
carbon dioxide + 1,1,1,3,3,3-
hexadeutero-2-propanone Kc 90
____________________________________________________________________________________
Appendices 621
_____________________________________________________________________________

_____________________________________________________________________________
Poly(dimethylsiloxane) (continued)
carbon dioxide
+ methanol swelling 90-91
carbon dioxide
+ 2-propanol swelling 92-93
carbon dioxide
+ 2-propanone swelling 93
carbon dioxide + toluene VLE 93-94
carbon dioxide density 570-571
chlorobenzene A2 606
chlorodifluoromethane gas solubility 26-27
cyclohexane PVT 571
ethane LLE 114-115
hexamethyldisiloxane PVT 571
propane LLE 115
toluene A2 606
____________________________________________________________________________________
Poly(dimethylsiloxane) monomethacrylate
____________________________________________________________________________________
Poly(dimethylsiloxane)-g-poly(ethylene oxide)
graft copolymer
____________________________________________________________________________________
Poly(dimethylsiloxane)-g-poly(ethylene oxide)-
g-poly(propylene oxide) graft copolymer
____________________________________________________________________________________
Poly(di-1H,1H,2H,2H-perfluorodecyl
diitaconate)
____________________________________________________________________________________
Poly(di-1H,1H,2H,2H-perfluorodecyl
monoitaconate)
____________________________________________________________________________________
Poly(di-1H,1H,2H,2H-perfluorododecyl
diitaconate)
____________________________________________________________________________________
Poly(di-1H,1H,2H,2H-perfluorododecyl
monoitaconate)
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Poly(di-1H,1H,2H,2H-perfluorohexyl
diitaconate)
____________________________________________________________________________________
Poly(di-1H,1H,2H,2H-perfluorohexyl
monoitaconate)
____________________________________________________________________________________
Poly(di-1H,1H,2H,2H-perfluorooctyl
diitaconate)
____________________________________________________________________________________
Poly(di-1H,1H,2H,2H-perfluorooctyl
monoitaconate)
____________________________________________________________________________________
Polyester (hyperbranched, aliphatic)
carbon dioxide + ethanol HPPE 451-452
carbon dioxide + water HPPE 452-453
ethanol VLE 27
water VLE 27-28
____________________________________________________________________________________
Poly(ether sulfone)
− PVT 559
____________________________________________________________________________________
Poly(ethyl acrylate)
ethene HPPE 296
____________________________________________________________________________________
Polyethylene
− PVT 560
1-butene VLE 28-30
1-butene HPPE 297
carbon dioxide + cyclohexane HPPE 453-454
carbon dioxide + n-heptane HPPE 454
cyclohexane VLE 31-32
cyclohexane LLE 115-116
cyclohexane + nitrogen HPPE 454
cyclohexane + polystyrene LLE 204-205
ethane HPPE 298-299
ethane + cyclohexane HPPE 455
ethene HPPE 299-349
____________________________________________________________________________________
Appendices 623
_____________________________________________________________________________

_____________________________________________________________________________
ethene density 32-33,
572-573
ethene + butyl acrylate HPPE 455
ethene + n-hexane HPPE 456-460
ethene + n-hexane + 1-octene HPPE 458-459
ethene + 1-hexene HPPE 460
ethene + 4-methyl-1-pentene HPPE 460-461
ethene + polyethylene HPPE 461-472
ethene + vinyl acetate HPPE 472-473
n-heptane VLE 37
n-heptane LLE 116
n-hexane VLE 37-38
n-hexane LLE 117-123
n-hexane + nitrogen VLE 94-95
n-hexane + nitrogen HPPE 474-476
n-hexane + 1-octene VLE 95
n-hexane + 1-octene LLE 202
1-hexene VLE 39-40
methane gas solubility 40
2-methylpropane gas solubility 40-41
nitrogen gas solubility 42-43
1-octene VLE 43
1-octene LLE 123-124
n-pentane VLE 43
n-pentane LLE 124-125
n-pentane density 573
3-pentanol VLE 43-44
3-pentanone VLE 44
1-pentene VLE 44
propane VLE 44-45
propane + cyclohexane HPPE 476-477
propane density 574
propyl acetate VLE 45
2-propylamine VLE 45
____________________________________________________________________________________
anisole density 575
anisole + poly(propylene
glycol) density 592-594
carbon dioxide + methanol HPPE 477-478
1-octanol density 576-577
propane gas solubility 49-50
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
carbon dioxide VLE 50-51
carbon dioxide + water +
diisopropanolamine gas solubility 95-96
hydrogen gas solubility 52
hydrogen + water +
diisopropanolamine gas solubility 96
methanol ∆ MH 549
methanol VLE 52-53
nitrogen gas solubility 54
nitrogen + water +
diisopropanolamine gas solubility 96-97
____________________________________________________________________________________
Poly(ethylene glycol) monododecyl ether-
b-poly(propylene glycol) diblock copolymer
____________________________________________________________________________________
anisole density 578
anisole + poly(propylene
____________________________________________________________________________________
− PVT 560
deuterium oxide A2 607, 612
water LLE 125
water PVT 578-579
____________________________________________________________________________________
Poly(ethylene oxide)-b-poly(dimethyl-
siloxane) diblock copolymer
toluene +
poly(ethylene oxide) LLE 203
____________________________________________________________________________________
diblock copolymer
____________________________________________________________________________________
____________________________________________________________________________________
Appendices 625
_____________________________________________________________________________

_____________________________________________________________________________
carbon dioxide + ethyl
methacrylate VLE 97
carbon dioxide + ethyl
methacrylate HPPE 478
____________________________________________________________________________________
Poly(fluoroalkoxyphosphazene)
____________________________________________________________________________________
Poly(hexyl acrylate)
carbon dioxide + hexyl
acrylate HPPE 479
____________________________________________________________________________________
Poly(hexyl methacrylate)
carbon dioxide + hexyl
methacrylate HPPE 479-480
____________________________________________________________________________________
Poly(β-hydroxybutyrate)
carbon dioxide density 363
____________________________________________________________________________________
Poly(4-hydroxystyrene)
ethanol PVT 579
2-propanone PVT 579-580
tetrahydrofuran PVT 580
____________________________________________________________________________________
Polyisobutylene
benzene PVT 581
n-butane LLE 126
carbon dioxide + n-heptane VLE 97
carbon dioxide + n-heptane HPPE 480
cyclohexane PVT 581
ethane HPPE 368-370
ethene HPPE 370
n-heptane VLE 55
n-heptane LLE 126
n-hexane LLE 126
2-methylbutane LLE 127
2-methylbutane A2 607, 612
n-pentane LLE 127
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Polyisobutylene (continued)
n-pentane A2 607, 612
propane LLE 128
2,2,4-trimethylpentane A2 607, 612
____________________________________________________________________________________
Polyisoprene
carbon dioxide swelling 55
ethane HPPE 373
ethene HPPE 373
propane HPPE 373
propene HPPE 374
____________________________________________________________________________________
deuterium oxide LLE 128
water LLE 128-129
____________________________________________________________________________________
Poly(DL-lactide)
− PVT 561
carbon dioxide
+ dimethyl ether HPPE 486-487
carbon dioxide
+ trichloromethane HPPE 488
difluoromethane HPPE 378
1,1,1,2-tetrafluoroethane HPPE 379-380
trifluoromethane HPPE 380
____________________________________________________________________________________
Poly(L-lactide)
carbon dioxide
+ chlorodifluoromethane HPPE 480-484
carbon dioxide
+ dichloromethane HPPE 484-486
carbon dioxide
+ 2-propanone HPPE 487
carbon dioxide
+ trichloromethane HPPE 487
____________________________________________________________________________________
Appendices 627
_____________________________________________________________________________

_____________________________________________________________________________
propene HPPE 381
____________________________________________________________________________________
carbon dioxide Tg 56
carbon dioxide + 2-butanone HPPE 488-490
carbon dioxide
+ dichloromethane HPPE 490
carbon dioxide + ethanol HPPE 490
carbon dioxide
+ methyl methacrylate HPPE 490-491
carbon dioxide + 2-propanone HPPE 491-497
carbon dioxide
carbon dioxide
+ trichloromethane HPPE 505-506
chlorodifluoromethane HPPE 381
ethene Tg 58
methane Tg 58
propene HPPE 381
____________________________________________________________________________________
Poly(α-methylstyrene)
− PVT 561
____________________________________________________________________________________
Poly(octadecyl acrylate)
ethene HPPE 382
ethene + octadecyl acrylate HPPE 506-507
____________________________________________________________________________________
Poly(octadecyl methacrylate)
ethene + octadecyl
methacrylate HPPE 508
____________________________________________________________________________________
Poly(1-octene)
− PVT 562
____________________________________________________________________________________
Poly(phenylmethylsiloxane)
− PVT 562-563
____________________________________________________________________________________
Poly(propyl acrylate)
ethene HPPE 382
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Polypropylene
− PVT 563-564
n-butane HPPE 382-383
n-butane + toluene VLE 98
n-butane + toluene LLE 203
1-butene + toluene VLE 98
1-butene + toluene LLE 204
nitrogen gas solubility 59
propane HPPE 386
propene gas solubility 60
propene HPPE 387
____________________________________________________________________________________
− PVT 564
acetophenone density 581-582
anisole density 583
anisole + poly(ethylene
anisole + poly(ethylene
glycol) monomethyl ether density 595-596
ethanol PVT 584
n-hexane PVT 584
1-octanol PVT 585
water PVT 586
____________________________________________________________________________________
____________________________________________________________________________________
____________________________________________________________________________________
Polystyrene
− PVT 564-565
acetaldehyde LLE 130-138
tert-butyl acetate LCST/UCST 217
2-butanone A2 607, 612
carbon dioxide Tg 62
carbon dioxide
+ 2-butanone HPPE 508-509
carbon dioxide +
cyclohexane HPPE 509-514
____________________________________________________________________________________
Appendices 629
_____________________________________________________________________________

_____________________________________________________________________________
carbon dioxide
+ methylcyclohexane HPPE 514-516
carbon dioxide
carbon dioxide + toluene swelling 597
carbon dioxide
+ trichloromethane HPPE 524-525
1-chloro-1,1-difluoroethane gas solubility 62-63
chlorodifluoromethane VLE 63
cyclohexane UCST 217-218
cyclohexane A2 607, 612
cyclohexane + ethane HPPE 525-526
cyclohexane + nitrogen HPPE 526-527
cyclohexane + polyethylene LLE 204-205
cyclohexane + propane HPPE 527
cyclopentane UCST 218-219
decalin A2 608, 612
cis-decalin A2 608, 612
trans-decalin LLE 139-140
trans-decalin A2 608-609,
612-613
1,2-dichlorobenzene +
polybutadiene LLE 205-206
1,2-dichloro-1,1,2,2-
tetrafluoroethane VLE 64
diethyl ether LCST/UCST 219
diethyl oxalate LLE 140
1,1-difluoroethane gas solubility 64
ethane + toluene HPPE 528
ethene gas solubility 64
ethyl acetate A2 609-610,
612
ethyl formate LCST/UCST 219
1,1,1,3,3,3-hexadeutero-2-
propanone LLE 141-145
hydrogen gas solubility 64
methane gas solubility 64-65
methyl acetate LLE 145-146
methylcyclohexane VLE 65
methylcyclohexane LLE 146-157
methylcyclohexane UCST 219-220
methylcyclohexane A2 612
methylcyclopentane LLE 158-159
methylcyclopentane + dodeca-
deuteromethylcyclopentane LLE 206-207
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
4-methyl-2-pentanone A2 610, 612
nitroethane LLE 159-170
nitrogen swelling 66-67
2-propanone LLE 170-176
2-propanone LCST/UCST 220
2-propanone + 1,1,1,3,3,3-
hexadeutero-2-propanone LLE 207-211
propionitrile LLE 176-194
propionitrile + polystyrene LLE 211-213
sulfur dioxide VLE 68
sulfur dioxide HPPE 392-393
1,1,2,2-tetrafluoroethane gas solubility 68
toluene A2 610, 612
trichlorofluoromethane VLE 68
trichloromethane A2 610-612
____________________________________________________________________________________
Polystyrene-b-polybutadiene-b-polystyrene
triblock copolymer
____________________________________________________________________________________
Polystyrene-b-polyisoprene
diblock copolymer
____________________________________________________________________________________
Polystyrene-b-poly(methyl methacrylate)
diblock copolymer
____________________________________________________________________________________
Polystyrene-b-poly(vinyl pyridine)
diblock copolymer
____________________________________________________________________________________
Polysulfone
carbon dioxide
carbon dioxide
+ tetrahydrofuran density 598-601
____________________________________________________________________________________
Appendices 631
_____________________________________________________________________________

_____________________________________________________________________________
Poly(1,1,2,2-tetrahydroperfluorodecyl
acrylate)
____________________________________________________________________________________
Poly[P-tris(trifluoroethoxy)-N-trimethylsilyl]
phosphazene
____________________________________________________________________________________
Poly(vinyl acetate)
carbon dioxide + benzene VLE, K∞ 98-99
carbon dioxide + toluene VLE, K∞ 99
____________________________________________________________________________________
− PVT 565-566
1,2-dimethylbenzene LLE 195
phenetole LLE 195
tetrahydrofuran + water LLE 213-214
____________________________________________________________________________________
____________________________________________________________________________________
− PVT 566
____________________________________________________________________________________
− PVT 566
____________________________________________________________________________________
Poly(vinyl pyridine)
____________________________________________________________________________________
Starch
carbon dioxide + water gas solubility 99
____________________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Tetra(ethylene glycol) dimethyl ether
n-heptane density 586-588
methanol ∆ MH 550
1,1,1,2-tetrafluoroethane density 589-591
____________________________________________________________________________________
____________________________________________________________________________________
Appendices 633
_____________________________________________________________________________
Appendix 2 List of solvents in alphabetical order
_____________________________________________________________________________
_____________________________________________________________________________
acetaldehyde C2H4O 75-07-0 130-138
acetophenone C8H8O 98-86-2 581-582
acrylic acid C3H4O2 79-10-7 407-408
anisole C7H8O 100-66-3 575, 578, 583, 592-596
benzene C6H6 71-43-2 98-99, 581, 606
bicyclo[2,2,1]-2-heptene C7H10 498-66-8 84-86
bromocyclohexane C6H11Br 108-85-0 606
n-butane C4H10 106-97-8 98, 114, 126, 203, 382-383,
415, 418-419
2-butanone C4H8O 78-93-3 488-490, 509, 607, 612
1-butene C4H8 106-98-9 19, 28-30, 98, 204, 232-233,
259-260, 287-288, 297, 384-
385, 412, 425
tert-butyl acetate C6H12O2 540-88-5 217
butyl acrylate C7H12O2 141-32-2 413-414, 423, 455
butyl methacrylate C8H14O2 97-88-1 87, 450-451
carbon dioxide CO2 124-38-9 17-19, 21-26, 30-31, 45-47,
50-52, 54-62, 69-73, 87-94,
96-99, 281-282, 288-296,
351-357, 359-364, 374-375,
388-394, 415-416, 425-426,
428, 441, 445-454, 477-506,
508-525, 528-530, 570-571,
597-601
chlorobenzene C6H5Cl 108-90-7 606
1-chloro-1,1-difluoroethane C2H3ClF2 75-68-3 62-63
chlorodifluoromethane CHClF2 75-45-6 26-27, 63, 282-283, 289-290,
365-366, 375-377, 381, 480-
484
cyclohexane C6H12 110-82-7 22, 87-88, 115-116, 138-139,
204-205, 217-218, 446, 453-
454-455, 476-477, 509-514,
525-527, 571, 581, 607, 612
cyclopentane C5H10 287-92-3 31-32, 111, 116, 194, 218-219
cyclopentene C5H8 142-29-0 111, 116, 194
decalin C10H18 91-17-8 608, 612
cis-decalin C10H18 493-01-6 608, 612
trans-decalin C10H18 493-02-7 139-140, 608-609, 612-613
n-decane C10H22 124-18-5 409
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
deuterium oxide D2O 7789-20-0 128, 607, 612
1,2-dichlorobenzene C6H4Cl2 95-50-1 205-206
dichloromethane CH2Cl2 75-09-2 484-486, 490
1,2-dichloro-1,1,2,2-tetrafluoroethane C2Cl2F4 76-14-2 63
diethyl ether C4H10O 60-29-7 219
diethyl oxalate C6H10O4 95-92-1 140
1,1-difluoroethane C2H4F2 75-37-6 64
difluoromethane CH2F2 75-10-5 378
diisopropanolamine C6H15NO2 110-97-4 96-97
1,2-dimethylbenzene C8H10 95-47-6 195
dimethyl ether C2H6O 115-10-6 267, 283-284, 366-368, 372-
373, 378-379, 486-487, 567
dimethyl ether-d6 C2D6O 17222-37-6 567-568
n-dodecane C12H26 112-40-3 112-113, 428
dodecadeuteromethylcyclopentane C6D12 144120-51-4 206-207
ethane C2H6 74-84-0 114-115, 267, 298-299, 368-
370, 373, 416, 429, 455, 525-
526, 528, 568, 592
ethanol C2H6O 64-17-5 27, 114, 409-410, 451-452,
490, 578, 584
ethene C2H4 74-85-1 19-21, 32-37, 58, 64, 84-86,
227-232, 234-235, 237-244,
249-256, 258-262, 267-280,
285-286, 289, 296, 299-349,
370, 373, 382, 407-445, 455-
473, 507-508, 572-573
ethyl acetate C4H8O2 141-78-6 410-411, 609-610, 613
ethyl formate C3H6O2 109-94-4 219
ethyl methacrylate C6H10O2 97-63-2 97, 478
2-ethylhexyl acrylate C11H20O2 103-11-7 415, 424
ethyl phenyl ether C8H10O 103-73-1 195
helium He 7440-59-7 416, 419-420, 429, 442
n-heptane C7H16 142-82-5 37, 55, 97, 116, 126, 411, 424,
454, 480, 586-588
1,1,1,3,3,3-hexadeutero-2-propanone C3D6O 666-52-4 90, 141-145, 207-211
hexamethyldisiloxane C6H18OSi2 107-46-0 571
n-hexane C6H14 110-54-3 37-38, 86-88, 94-95, 117-123,
126, 202, 456-460, 474-476,
570, 584
1-hexene C6H12 592-41-6 39-40, 262-263, 417-421, 423,
426-427, 460
hexyl acrylate C9H16O2 2499-95-8 479
hexyl methacrylate C10H18O2 142-09-6 479-480
hydrogen H2 1333-74-0 52, 64, 94-96
isobutyl methyl ketone C6H12O 108-10-1 610, 613
methane CH4 74-82-8 40, 59, 64-65, 420-422
_____________________________________________________________________________
Appendices 635
_____________________________________________________________________________

_____________________________________________________________________________
methanol CH4O 67-56-1 52-53. 90-91, 477-478,
549-550
methanol-d4 CD4O 811-98-3 91
methoxybenzene C7H8O 100-66-3 575, 578, 583, 592-596
methyl acetate C3H6O2 79-20-9 145-146
methyl acrylate C4H6O2 96-33-3 414-415, 424-425
2-methylbutane C6H12 78-78-4 127, 607, 612
methylcyclohexane C7H14 108-87-2 65, 146-157, 219-220, 514-
516, 613
methylcyclopentane C6H12 96-37-7 158-159, 206-207
methyl methacrylate C5H8O2 82-62-6 490-491
4-methyl-2-pentanone C6H12O 108-10-1 610, 613
4-methyl-1-pentene C6H12 691-37-2 460-461
methyl phenyl ketone C8H8O 98-86-2 581-582
2-methylpropane C4H10 75-28-5 40-41, 244-246
2-methyl-2-propanol C4H10O 75-65-0 443-444
nitroethane C2H5NO2 79-24-3 159-169
nitroethane-d5 C2D5NO2 57817-88-6 165-166, 169-170
nitrogen N2 7727-37-9 42-43, 47-48, 54, 59, 66-67,
96-97, 421-422, 430, 444-445,
454, 474-476, 526-527
norbornene C7H10 498-66-8 84-86
octadecyl acrylate C21H40O2 4813-57-4 507
octadecyl methacrylate C22H42O2 32360-05-7 508
octanoic acid C8H16O2 124-07-2 411-412
1-octanol C8H18O 111-87-5 576-577, 585
1-octene C8H16 111-66-0 43, 95, 123-124, 202, 458-459
n-pentane C5H12 109-66-0 43, 124-125, 127, 568-569,
573, 607, 612
n-pentane-d12 C5D12 2031-90-5 569, 592
3-pentanol C5H12O 584-02-1 43-44
3-pentanone C5H10O 96-22-0 44
1-pentene C5H10 109-67-1 44
phenetole C8H10O 103-73-1 195
propane C3H8 74-98-6 44-45, 48-50, 115, 128, 235-
237, 246-249, 257, 263, 268,
349-351, 357-359, 371-373,
386, 422-423, 430, 476-477,
527, 574
2-propanol C3H8O 67-63-0 92
2-propanol-d8 C3D8O 22739-76-0 92-93
2-propanone C3H6O 67-64-1 93, 170-176, 207-211, 220,
487, 491-497, 579-580
propene C3H6 115-07-1 20, 60, 264-266, 268, 374, 381,
387, 427-428
propionitrile C3H5N 107-12-0 176-194, 211-213
propyl acetate C5H10O2 109-60-4 45
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
2-propylamine C3H9N 75-31-0 45
styrene C8H8 100-42-5 22
sulfur dioxide SO2 7446-09-5 68, 391-392
1,1,1,2-tetrafluoroethane C2H2F4 811-97-2 68, 379-380, 589-591
tetrahydrofuran C4H8O 109-99-9 213-214, 446-448, 498-500,
516-519, 528-529, 580, 598-
601
toluene C7H8 108-88-3 84, 88-89, 93-94, 98-99, 203-
204, 448-450, 500-505, 520-
523, 528-530, 597, 606, 610,
613
trichlorofluoromethane CCl3F 75-69-4 68
trichloromethane CHCl3 67-66-3 487-488, 505-506, 524-525,
610-611, 613
2,2,2-trifluoroethanol C2H3F3O 75-89-8 445-446
trifluoromethane CHF3 75-46-7 284, 380
2,2,4-trimethylpentane C8H18 540-84-1 412, 607, 612
vinyl acetate C4H6O2 108-05-4 21, 430-445, 472-473
water H2O 7732-18-5 27-28, 96-97, 99, 111-114,
125, 128-129, 213-214, 452-
453, 578-579, 586, 605-606
_____________________________________________________________________________
Appendices 637
_____________________________________________________________________________
Appendix 3 List of solvents in order of their molecular formulas
_____________________________________________________________________________
_____________________________________________________________________________
CCl3F trichlorofluoromethane 75-69-4 68
CD4O methanol-d4 811-98-3 91
CHClF2 chlorodifluoromethane 75-45-6 26-27, 63, 282-283, 289-290,
365-366, 375-377, 381, 480-
484
CHCl3 trichloromethane 67-66-3 487-488, 505-506, 524-525,
610-611, 613
CHF3 trifluoromethane 75-46-7 284, 380
CH2Cl2 dichloromethane 75-09-2 484-486, 490
CH2F2 difluoromethane 75-10-5 378
CH4 methane 74-82-8 40, 59, 64-65, 420-422
CH4O methanol 67-56-1 52-53. 90-91, 477-478,
549-550
CO2 carbon dioxide 124-38-9 17-19, 21-26, 30-31, 45-47,
50-52, 54-62, 69-73, 87-94,
96-99, 281-282, 288-296,
351-357, 359-364, 374-375,
388-394, 415-416, 425-426,
428, 441, 445-454, 477-506,
508-525, 528-530, 570-571,
597-601
C2Cl2F4 1,2-dichloro-1,1,2,2-tetrafluoroethane 76-14-2 63
C2D5NO2 nitroethane-d5 57817-88-6 165-166, 169-170
C2D6O dimethyl ether-d6 17222-37-6 567-568
C2H2F4 1,1,1,2-tetrafluoroethane 811-97-2 68, 379-380, 589-591
C2H3ClF2 1-chloro-1,1-difluoroethane 75-68-3 62-63
C2H3F3O 2,2,2-trifluoroethanol 75-89-8 445-446
C2H4 ethene 74-85-1 19-21, 32-37, 58, 64, 84-86,
227-232, 234-235, 237-244,
249-256, 258-262, 267-280,
285-286, 289, 296, 299-349,
370, 373, 382, 407-445, 455-
473, 507-508, 572-573
C2H4F2 1,1-difluoroethane 75-37-6 64
C2H4O acetaldehyde 75-07-0 130-138
C2H5NO2 nitroethane 79-24-3 159-169
C2H6 ethane 74-84-0 114-115, 267, 298-299, 368-
370, 373, 416, 429, 455, 525-
526, 528, 568, 592
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
C2H6O dimethyl ether 115-10-6 267, 283-284, 366-368, 372-
373, 378-379, 486-487, 567
C2H6O ethanol 64-17-5 27, 114, 409-410, 451-452,
490, 578, 584
C3D6O 1,1,1,3,3,3-hexadeutero-2-propanone 666-52-4 90, 141-145, 207-211
C3D8O 2-propanol-d8 22739-76-0 92-93
C3H4O2 acrylic acid 79-10-7 407-408
C3H5N propionitrile 107-12-0 176-194, 211-213
C3H6 propene 115-07-1 20, 60, 264-266, 268, 374, 381,
387, 427-428
C3H6O 2-propanone 67-64-1 93, 170-176, 207-211, 220,
487, 491-497, 579-580
C3H6O2 ethyl formate 109-94-4 219
C3H6O2 methyl acetate 79-20-9 145-146
C3H8 propane 74-98-6 44-45, 48-50, 115, 128, 235-
237, 246-249, 257, 263, 268,
349-351, 357-359, 371-373,
386, 422-423, 430, 476-477,
527, 574
C3H8O 2-propanol 67-63-0 92
C3H9N 2-propylamine 75-31-0 45
C4H6O2 methyl acrylate 96-33-3 414-415, 424-425
C4H6O2 vinyl acetate 108-05-4 21, 430-445, 472-473
C4H8 1-butene 106-98-9 19, 28-30, 98, 204, 232-233,
259-260, 287-288, 297, 384-
385, 412, 425
C4H8O 2-butanone 78-93-3 488-490, 509, 607, 612
C4H8O tetrahydrofuran 109-99-9 213-214, 446-448, 498-500,
516-519, 528-529, 580, 598-
601
C4H8O2 ethyl acetate 141-78-6 410-411, 609-610, 613
C4H10 n-butane 106-97-8 98, 114, 126, 203, 382-383,
415, 418-419
C4H10 2-methylpropane 75-28-5 40-41, 244-246
C4H10O diethyl ether 60-29-7 219
C4H10O 2-methyl-2-propanol 75-65-0 443-444
C5D12 n-pentane-d12 2031-90-5 569, 592
C5H8 cyclopentene 142-29-0 111, 116, 194
C5H8O2 methyl methacrylate 82-62-6 490-491
C5H10 cyclopentane 287-92-3 31-32, 111, 116, 194, 218-219
C5H10 1-pentene 109-67-1 44
C5H10O 3-pentanone 96-22-0 44
C5H10O2 propyl acetate 109-60-4 45
C5H12 n-pentane 109-66-0 43, 124-125, 127, 568-569,
573, 607, 612
C5H12O 3-pentanol 584-02-1 43-44
C6D12 dodecadeuteromethylcyclopentane 144120-51-4 206-207
_____________________________________________________________________________
Appendices 639
_____________________________________________________________________________

_____________________________________________________________________________
C6H4Cl2 1,2-dichlorobenzene 95-50-1 205-206
C6H5Cl chlorobenzene 108-90-7 606
C6H6 benzene 71-43-2 98-99, 581, 606
C6H10O2 ethyl methacrylate 97-63-2 97, 478
C6H10O4 diethyl oxalate 95-92-1 140
C6H11Br bromocyclohexane 108-85-0 606
C6H12 cyclohexane 110-82-7 22, 87-88, 115-116, 138-139,
204-205, 217-218, 446, 453-
454-455, 476-477, 509-514,
525-527, 571, 581, 607, 612
C6H12 1-hexene 592-41-6 39-40, 262-263, 417-421, 423,
426-427, 460
C6H12 2-methylbutane 78-78-4 127, 607, 612
C6H12 methylcyclopentane 96-37-7 158-159, 206-207
C6H12 4-methyl-1-pentene 691-37-2 460-461
C6H12O isobutyl methyl ketone 108-10-1 610, 613
C6H12O 4-methyl-2-pentanone 108-10-1 610, 613
C6H12O2 tert-butyl acetate 540-88-5 217
C6H14 n-hexane 110-54-3 37-38, 86-88, 94-95, 117-123,
126, 202, 456-460, 474-476,
570, 584
C6H15NO2 diisopropanolamine 110-97-4 96-97
C6H18OSi2 hexamethyldisiloxane 107-46-0 571
C7H8 toluene 108-88-3 84, 88-89, 93-94, 98-99, 203-
204, 448-450, 500-505, 520-
523, 528-530, 597, 606, 610,
613
C7H8O anisole 100-66-3 575, 578, 583, 592-596
C7H8O methoxybenzene 100-66-3 575, 578, 583, 592-596
C7H10 bicyclo[2,2,1]-2-heptene 498-66-8 84-86
C7H10 norbornene 498-66-8 84-86
C7H12O2 butyl acrylate 141-32-2 413-414, 423, 455
C7H14 methylcyclohexane 108-87-2 65, 146-157, 219-220, 514-
516, 613
C7H16 n-heptane 142-82-5 37, 55, 97, 116, 126, 411, 424,
454, 480, 586-588
C8H8 styrene 100-42-5 22
C8H8O acetophenone 98-86-2 581-582
C8H8O methyl phenyl ketone 98-86-2 581-582
C8H10 1,2-dimethylbenzene 95-47-6 195
C8H10O ethyl phenyl ether 103-73-1 195
C8H10O phenetole 103-73-1 195
C8H14O2 butyl methacrylate 97-88-1 87, 450-451
C8H16 1-octene 111-66-0 43, 95, 123-124, 202, 458-459
C8H16O2 octanoic acid 124-07-2 411-412
C8H18 2,2,4-trimethylpentane 540-84-1 412, 607, 612
C8H18O 1-octanol 111-87-5 576-577, 585
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
C9H16O2 hexyl acrylate 2499-95-8 479
C10H18 decalin 91-17-8 608, 612
C10H18 cis-decalin 493-01-6 608, 612
C10H18 trans-decalin 493-02-7 139-140, 608-609, 612-613
C10H18O2 hexyl methacrylate 142-09-6 479-480
C10H22 n-decane 124-18-5 409
C11H20O2 2-ethylhexyl acrylate 103-11-7 415, 424
C12H26 n-dodecane 112-40-3 112-113, 428
C21H40O2 octadecyl acrylate 4813-57-4 507
C22H42O2 octadecyl methacrylate 32360-05-7 508
D 2O deuterium oxide 7789-20-0 128, 607, 612
H2 hydrogen 1333-74-0 52, 64, 94-96
H 2O water 7732-18-5 27-28, 96-97, 99, 111-114,
125, 128-129, 213-214, 452-
453, 578-579, 586, 605-606
He helium 7440-59-7 416, 419-420, 429, 442
N2 nitrogen 7727-37-9 42-43, 47-48, 54, 59, 66-67,
96-97, 421-422, 430, 444-445,
454, 474-476, 526-527
SO2 sulfur dioxide 7446-09-5 68, 391-392
____________________________________________________________________________
641
INDEX
A F R
Activity Fractionation, 3, 5 Rectilinear diameter, 5

coefficient, 14
experimental data, 26 G S
Analytical method, 2-3
Glass transition, 7 Scattering methods, 8
B Second virial coefficient
H experimental data, 605-613
Binodal, 5 experimental methods, 8
Heat, see: Enthalpy Segment number, 10
C High-pressure phase equilibrium Sorption, 4, 17-110
experimental data, 227-548 Synthetic method, 3-4
Cloud point, 5 experimental methods, 2-4
Concentration T
critical, 5 L Temperature
feed, 5 critical, 5
measures, 10-11 Liquid-liquid equilibrium (LLE) glass transition, 7
Continuous thermodynamics, 5 experimental data, 111-216 LCST, 5, 217-218
Critical exponent, 5 experimental methods, 2-4 UCST, 5, 217-218
Critical point
explanation, 5 M U
Molar mass U-tube vibrating densimeter, 7
D averages, 9
distribution function, 2, 5 V
Density in equations, 7-8
experimental data, 551-602 Vapor-liquid equilibrium (VLE)
experimental methods, 6-7 N experimental data, 17-101
in volume fraction, 10 experimental methods, 2-4
of mixtures, 7 Nomenclature, 11 Viscosity, 3-4
Diffusion, 3 Volume
Distribution, see: molar mass O excess, 7, 567-591
molar, 7, 10
E Osmotic pressure, 8 specific, 7, 551-601
Enthalpy P
definition, 6
excess, 6 Piston-die technique, 6
experimental data, 549-550 PVT behavior
experimental methods, 6 experimental data, 551-566
mixing, 6 experimental methods, 6-7
partial, 6
CRC HANDBOOK OF
THERMODYNAMIC
DATA of
COPOLYMER
SOLUTIONS
CRC HANDBOOK OF
THERMODYNAMIC
DATA of
COPOLYMER
SOLUTIONS
Christian Wohlfarth
CRC Press
Boca Raton London New York Washington, D.C.
1074/Disclaimer Page 1 Tuesday, March 13, 2001 12:33 PM
Library of Congress Cataloging-in-Publication Data
Catalog record is available from the Library of Congress
This book contains information obtained from authentic and highly regarded sources. Reprinted material is quoted with
permission, and sources are indicated. A wide variety of references are listed. Reasonable efforts have been made to publish
reliable data and information, but the author and the publisher cannot assume responsibility for the validity of all materials
or for the consequences of their use.
Neither this book nor any part may be reproduced or transmitted in any form or by any means, electronic or mechanical,
including photocopying, microfilming, and recording, or by any information storage or retrieval system, without prior
permission in writing from the publisher.
The consent of CRC Press LLC does not extend to copying for general distribution, for promotion, for creating new works,
or for resale. Specific permission must be obtained in writing from CRC Press LLC for such copying.
Direct all inquiries to CRC Press LLC, 2000 N.W. Corporate Blvd., Boca Raton, Florida 33431.
identification and explanation, without intent to infringe.
Visit the CRC Press Web site at www.crcpress.com
© 2001 by CRC Press LLC

International Standard Book Number 0-8493-1074-1
Printed in the United States of America 1 2 3 4 5 6 7 8 9 0
Printed on acid-free paper
Foreword
Practical applications of thermodynamics as well as theoretical calculations of thermodynamic

properties generally require data of real systems. In most cases these data rest on laboratory measurements
of various physical properties. The study of phase behavior and thermodynamic properties of polymers
and mixtures containing polymers has been subject of interest during the last 50 years. Investigations on
such properties for copolymer systems were emphasized during the last decade when copolymers gained
an increasing commercial interest because of their unique physical properties.
Much effort has been devoted over the years to compiling thermodynamic data for types of
systems from literature and preparing compilations and databases for both scientific and industrial use.
However, scarcely anything is found when one looks for compilations or databases that provide
thermodynamic properties of polymer, or even more specially, copolymer solutions. Experimental
information is spread over many articles and journals. There are only a small number of data books that
cover this field. The author of this handbook wrote one of them on vapor-liquid equilibria of binary
polymer solutions in 1994. He is known for his experience and his own experimental investigations on
polymer and copolymer solutions for more than 20 years. With his new Handbook of Thermodynamic
Data of Copolymer Solutions for the first time a compilation of thermodynamic data for copolymer
solutions from the original literature is available.
Taking into account vapor-liquid equilibrium (VLE) data, liquid-liquid equilibrium (LLE) data,
high-pressure phase equilibrium (HPPE) data of copolymer solutions in supercritical fluids, volumetric
property (PVT) data of copolymer melts, enthalpy data, and second osmotic virial coefficients of
copolymer solutions, the book covers all the necessary areas for researchers and engineers who work in
this field.
When dealing with copolymer systems, one encounters the special problem of copolymer
characterization since a copolymer is far from well-defined only by its chemical formula. Copolymers
vary by a number of characterization variables. Molar mass, chemical composition, and distribution
functions, tacticity, sequence distribution, branching, and end groups determine their thermodynamic
behavior in solution. It is far from clear how these parameters influence the thermodynamic properties in
detail. Unfortunately, there usually is not much information in the original papers; the available ones are
added to each system in this book.
In comparison to low-molecular systems, the amount of data for copolymer solutions is still
rather small. About 300 literature sources were perused for the purpose of this handbook, including some
dissertations and diploma papers. Several hundred vapor-pressure isotherms, Henry’s constants, LLE and
HPPE data sets, a number of PVT data and some second osmotic virial coefficients are reported.
I am sure that readers interested in the field of thermodynamic properties of polymer solutions
will benefit from this handbook and will identify the work that has to be done in the future.
Henry V. Kehiaian
Chairman
IUPAC-CODATA Task Group on Standard Physico-Chemical Data Formats
PREFACE
Knowledge of thermodynamic data of copolymer solutions is a necessity for industrial and

copolymer solutions, for studying intermolecular interactions, and for gaining insights into the molecular
Copolymer Solutions provides a reliable collection of such data for copolymer solutions from the original
literature.
The Handbook is divided into seven chapters: (1) Introduction, (2) Vapor-Liquid Equilibrium
(VLE) Data of Binary Copolymer Solutions, (3) Liquid-Liquid Equilibrium (LLE) Data of Quasibinary or
Quasiternary Copolymer Solutions, (4) High-Pressure Phase Equilibrium (HPPE) Data of Quasibinary or
Quasiternary Copolymer Solutions in Supercritical Fluids, (5) Enthalpy Changes for Binary Copolymer
Solutions, (6) PVT Data of Molten Copolymers, and (7) Second Virial Coefficients (A2) of Copolymer
Solutions. Finally, four appendices quickly route the user to the desired data sets.
Original data have been gathered from approximately 300 literature sources, including also a
number of dissertations and diploma papers. The Handbook provides about 250 vapor-pressure isotherms,
75 tables of Henry’s constants, 50 LLE data sets, 175 HPPE data sets, and 70 PVT data tables for more
than 165 copolymers and 165 solvents. Data are included only if numerical values were published or
authors provided their numerical results by personal communication (and I wish to thank all those who did
so). No digitized data have been included in this data collection, but some tables include systems data
published in graphical form. The Handbook is the first complete overview about this subject in the
world’s literature. The closing day for the data collection was October 1, 2000. The Handbook results
from parts of a more general database, Thermodynamic Properties of Polymer Systems, which is
continuously updated by the author. Thus, the user who is in need for new additional data sets is kindly
invited to ask for new information beyond this book via e-mail at wohlfarth@chemie.uni-halle.de.
Additionally, the author will be grateful to users who call his attention to mistakes and make suggestions
for improvements.
The Handbook also highlights the work still to be done − obvious, when one compares the
relatively small number of copolymer solutions for which data exist with the number of copolymers in use
today. Additionally, only a small minority of possible solutions of the copolymers covered by this book
were properly investigated (in relation to the combinatorial number of copolymer/solvent pairs, although it
is appreciated that not all make thermodynamic sense or are of practical use).
The CRC Handbook of Thermodynamic Data of Copolymer Solutions will be useful to

researchers, specialists, and engineers working in the fields of polymer science, physical chemistry,
chemical engineering, material science, and those developing computerized predictive packages. The
Handbook should also be of use as a data source to Ph.D. students and faculty in Chemistry, Physics,
Chemical Engineering, and Materials Science Departments at universities.
Merseburg, January 2001 Christian Wohlfarth

About the Author
Halle-Wittenberg, Germany. He earned his degree in Chemistry in 1974 and wrote his Ph.D. thesis on
Since then, his main research is related to polymer systems. Currently, his research topics are
molecular thermodynamics, continuous thermodynamics, phase equilibria in (co)polymer mixtures and
solutions, (co)polymers in supercritical fluids, PVT-behavior and equations of state, sorption properties of
(co)polymers, about which he has published approximately 90 original papers. He has also built a
database, Thermodynamic Properties of Polymer Systems, and has written the book Vapor-Liquid
Equilibria of Binary Polymer Solutions.

compounds and mixtures resulting in 6 volumes of Landolt-Börnstein New Series. He is a member of the
Editorial Board of ELDATA: The International Electronic Journal of Physico-Chemical Data.
CONTENTS
1. INTRODUCTION
1.1. Objectives of the handbook......................................................................................................1
1.2. Experimental methods involved...............................................................................................2
1.3. Guide to the data tables..........................................................................................................21
1.4. List of symbols.......................................................................................................................25
1.5. References..............................................................................................................................27

OF BINARY COPOLYMER SOLUTIONS
2.1. Partial solvent vapor pressures or solvent activities for copolymer solutions........................29
2.2. Classical mass-fraction Henry's constants of solvent vapors in molten
copolymers.............................................................................................................................88
2.3. References............................................................................................................................142

OF QUASIBINARY OR QUASITERNARY COPOLYMER SOLUTIONS
3.1. Cloud-point and/or coexistence curves of quasibinary solutions.........................................145
graphical form as phase diagrams or related figures............................................................160
containing at least one copolymer........................................................................................163
3.4. Table of systems where ternary LLE data were published only in
3.5. Lower critical (LCST) and/or upper (UCST) critical solution temperatures
of copolymer solutions.........................................................................................................175
3.6. References............................................................................................................................183

OF COPOLYMER SOLUTIONS IN SUPERCRITICAL FLUIDS
4.1. Experimental data of quasibinary copolymer solutions........................................................187
4.2. Table of systems where binary HPPE data were published only in
4.3. Experimental data of quasiternary solutions containing at least
one copolymer......................................................................................................................229
4.4. Table of systems where ternary HPPE data were published only in
4.5. References............................................................................................................................266
5. ENTHALPY CHANGES FOR BINARY COPOLYMER SOLUTIONS
and copolymer partial enthalpies of mixing (at infinite dilution),
or copolymer (first) integral enthalpies of solution .............................................................269
5.2. Partial molar enthalpies of mixing at infinite dilution of solvents
and enthalpies of solution of gases/vapors of solvents in molten
copolymers from inverse gas-liquid chromatography (IGC)................................................307
5.3. Table of systems where additional information on enthalpy effects
in copolymer solutions can be found....................................................................................333
5.4. References............................................................................................................................337
6. PVT DATA OF MOLTEN COPOLYMERS

6.1. Experimental data and/or Tait equation parameters.............................................................341
6.2. References............................................................................................................................430
7. SECOND VIRIAL COEFFICIENTS (A2) OF COPOLYMER SOLUTIONS

7.1. Experimental A2 data............................................................................................................431
7.2. References............................................................................................................................445
8. APPENDICES
8.1. List of copolymer acronyms.................................................................................................447
8.2. List of systems and properties in order of the copolymers...................................................451
8.3. List of solvents in alphabetical order...................................................................................494
8.4. List of solvents in order of their molecular formulas...........................................................499
1. INTRODUCTION

Knowledge of thermodynamic data of copolymer solutions is a necessity for industrial and
behavior of copolymer solutions, for studying intermolecular interactions, and for gaining insights into the
database for copolymer solutions is even smaller. On the other hand, copolymers are gaining increasing
commercial interest because of their unique physical properties, and thermodynamic data are needed for
optimizing their synthesis, production, and application.
Basic information on polymers as well as copolymers can be found in the Polymer Handbook
(99BRA). Some data books on polymer solutions appeared in the early 1990s (90BAR, 92WEN, 93DAN,
and 94WOH), but most data for copolymer solutions have been compiled during the last decade. No
books or databases dedicated to copolymer solutions presently exist. Thus, the intention of the Handbook
is to fill this gap and to provide scientists and engineers with an up-to-date compilation from the literature
of the available thermodynamic data on copolymer solutions. The Handbook does not present theories and
models for (co)polymer solution thermodynamics. Other publications (71YAM, 90FUJ, 90KAM, and
99PRA) can serve as starting points for investigating those issues.
• Vapor-liquid equilibrium (VLE) data of binary copolymer solutions

• Liquid-liquid equilibrium (LLE) data of quasibinary or quasiternary copolymer
solutions
• High-pressure phase equilibrium (HPPE) data of copolymer solutions in supercritical
fluids
• Enthalpy changes for binary copolymer solutions
• PVT data of molten copolymers
• Second virial coefficients (A2) of copolymer solutions
chapters. Data are included only if numerical values were published or authors provided their numerical
results by personal communication (and I wish to thank all those who did so). No digitized data have been
included in this data collection, but some tables include systems data published in graphical form.
This volume also highlights the work still to be done − obvious, when one compares the
relatively small number of copolymer solutions for which data exist with the number of copolymers in use
today. Additionally, only a small minority of possible solutions of the copolymers covered by this book
were properly investigated (in relation to the combinatorial number of copolymer/solvent pairs, although it
is appreciated that not all make thermodynamic sense or are of practical use).
Very few investigations involved thermodynamic data for particular copolymer solutions, and the
temperature (and/or pressure) ranges usually investigated are rather limited. The Handbook provides the
results of recent research, and clearly identifies areas that require further exploration in the future.
2 CRC Handbook of Thermodynamic Data of Copolymer Solutions
____________________________________________________________________________________

Vapor-liquid equilibrium (VLE) measurements
Investigations on vapor-liquid equilibrium of polymer solutions can be made by various methods:

3. Isopiestic sorption/desorption methods, i.e., gravimetric sorption, piezoelectric sorption,
or isothermal distillation
4. Inverse gas-liquid chromatography (IGC) at infinite dilution, IGC at finite concentrations,
and headspace gas chromatography (HSGC)
5. Steady-state vapor-pressure osmometry (VPO)
Experimental techniques for vapor pressure measurements were reviewed in 75BON and
2000WOH. Methods and results of the application of IGC to polymers and polymer solutions were more
often reviewed (76NES, 88NES, 89LLO, 89VIL, and 91MU1). Reviews on ebulliometry and/or vapor-
pressure osmometry can be found in 74TOM, 75GLO, 87COO, 91MAY, and 99PET.
The measurement of vapor pressures for polymer solutions is generally more difficult and more
time-consuming than that of low-molecular mixtures. The main difficulties can be summarized as follows:
Polymer solutions exhibit strong negative deviations from Raoult’s law. These are mainly due to the large
entropic contributions caused by the difference between the molar volumes of solvents and polymers as
was explained by the classical Flory-Huggins theory about 60 years ago. However, because of this large
difference in molar mass, vapor pressures of dilute solutions do not differ markedly from the vapor
pressure of the pure solvent at the same temperature, even at polymer concentrations of 10-20 wt%. This
requires special techniques to measure very small differences in solvent activities. Concentrated polymer
solutions are characterized by rapidly increasing viscosities with increasing polymer concentration. This
leads to a strong increase in time required to obtain real thermodynamic equilibrium caused by slow
solvent diffusion effects (in or out of a non-equilibrium-state polymer solution). Furthermore, only the
solvent coexists in both phases because polymers do not evaporate. The experimental techniques used for
the measurement of vapor pressures of polymer solutions have to take into account all these effects.
Vapor pressures of polymer solutions are usually measured in the isothermal mode by static
methods. Dynamic methods are seldom applied, e.g., ebulliometry (75GLO and 87COO). At least, one
can consider measurements by VPO to be dynamic ones, where a dynamic (steady-state) balance is
obtained. Limits for the applicable ranges of polymer concentration and polymer molar mass, limits for
the solvent vapor pressure and the measuring temperature and some technical restrictions prevent its
broader application, however. Static techniques usually work at constant temperature. The three different
methods (1 through 3 above) were used to determine most of the vapor pressures of polymer solutions in
the literature. All three methods have to solve the problems of establishing real thermodynamic
equilibrium between liquid polymer solution and solvent vapor phase, long-time temperature constancy
during the experiment, determination of the final polymer concentration, and determination of pressure
and/or activity. Absolute vapor pressure measurement and differential vapor pressure methods were
mostly used by early workers. Most recent measurements were done with the isopiestic sorption methods.
Gas-liquid chromatography as IGC closes the gap at high polymer concentrations where vapor pressures
cannot be measured with sufficient accuracy. HSGC can be considered as some combination of absolute
vapor pressure measurement with GLC.
The following text (a short summary from the author’s own review, 2000WOH) explains briefly
the usual experimental equipment and the measuring procedures.
1. Introduction 3
____________________________________________________________________________________
Absolute vapor pressure measurement may be considered the classical technique for our purpose,
because one measures directly the vapor pressure above a solution of known polymer concentration. The
literature gives a variety of absolute vapor pressure apparatuses developed and used by different authors.
Vapor pressure measurement and solution equilibration were often made separately. A polymer sample is
prepared by weighing, the sample flask is evacuated, degassed solvent is introduced into a sample flask
that is sealed thereafter. Samples are equilibrated at elevated temperature in a thermostatted bath for some
weeks. The flask with the equilibrated polymer solution is then connected with the pressure-measuring
device at the measuring temperature. The vapor pressure is measured after reaching equilibrium and the
final polymer concentration is obtained after correcting for the amount of evaporated solvent. Modern
equipment applies electronic pressure sensors and digital technique to measure the vapor pressure. Data
processing can then be made online by computers. A number of problems have to be solved during the
experiment. The solution is usually of an amount of some cm3 and may contain about 1g of polymer or
even more. Degassing is absolutely necessary. All impurities in the pure solvent have to be eliminated.
Equilibration of all prepared solutions is very time consuming (liquid oligomers need not so much time, of
course). Increasing viscosity makes the preparation of concentrated solutions more and more difficult with
further increasing amount of polymer. Solutions above 50-60 wt% can hardly be prepared (depending on
the solvent/polymer pair under investigation).
The determination of the volume of solvent vaporized in the unoccupied space of the apparatus is
difficult and can cause serious errors in the determination of the final solvent concentration. To
circumvent the vapor phase correction, one can measure the concentration directly by means, for example,
of a differential refractometer. The contact of solvent vapor with the Hg surface in older equipment may
cause further errors. Complete thermostatting of the whole apparatus is necessary to avoid condensation of
solvent vapor at colder spots. Since it is disadvantageous to thermostat Hg manometers at higher
temperatures, null measurement instruments with pressure compensation were sometimes used. Modern
electronic pressure sensors can be thermostatted within certain temperature ranges. If pressure
measurement is made outside the thermostatted equilibrium cell, the connecting tubes must be heated
slightly above the equilibrium temperature to avoid condensation.
The measurement of polymer solutions with lower polymer concentrations requires very precise
pressure instruments, because the difference to the pure solvent vapor pressure becomes very small with
decreasing amount of polymer. No one can really answer the question if real thermodynamic equilibrium
is obtained or only a frozen non-equilibrium state is achieved. Non-equilibrium data can be detected from
unusual shifts of the χ-function with some experience. Also some kind of hysteresis appearing in
experimental data seems to point to non-equilibrium results. A common consistency test on the basis of
the integrated Gibbs-Duhem equation does not work for vapor pressure data of binary polymer solutions
because the vapor phase is pure solvent vapor. Thus, absolute vapor pressure measurements need very
careful handling, plenty of time and an experienced experimentator. They are not the methods of choice
for highly viscous polymer solutions.
The differential method can be compared under some aspects with the absolute method, but it has
some advantages. The measuring principle is to obtain the vapor pressure difference between the pure
solvent and the polymer solution at the measuring temperature. Again, the polymer sample is filled, after
weighing, into a sample flask, the apparatus is evacuated, a desired amount of degassed solvent is distilled
into the sample flask to build the solution and the samples have to be equilibrated for a necessary duration
of time. The complete apparatus is kept at constant measuring temperature and, after reaching equilibrium,
____________________________________________________________________________________
the pressure difference is read from the manometer difference and the concentration is calculated after
correcting the amount of vaporized solvent in the unoccupied space of the equipment. The pure solvent
vapor pressure is usually precisely known from independent experiments.
Difference/differential manometers have some advantages from their construction: they are
comparatively smaller and their resolution is much higher (modern pressure transducers can resolve
differences of 0.1 Pa and less). However, there are the same disadvantages with sample/solution
preparation (solutions of grams of polymer in some cm3 volume, degassing, viscosity), long-time
thermostatting of the complete apparatus because of long equilibrium times (increasing with polymer
molar mass and concentration/viscosity of the solution), correction of unoccupied vapor space, impurities
of the solvent, connection to the Hg surface in older equipment, and the problem of obtaining real
thermodynamic equilibrium (or not) as explained above. Modern equipment uses electronic pressure
sensors instead of Hg manometers and digital technique to measure the vapor pressure. Also,
thermostatting is more precise in recent apparatuses. Problems caused by the determination of the
unoccupied vapor space could be avoided by measuring the absolute vapor pressure as well.
Again, the concentration can be determined independently by using a differential refractometer

and a normalized relation between concentration and refractive index. Degassing of the liquids remains a
necessity. Time for establishing thermodynamic equilibrium could somewhat be shortened by intensive
stirring. In comparison to absolute vapor pressure measurements, differential vapor pressure
measurements with a high resolution for the pressure difference can be applied even for dilute polymer
solutions where the solvent activity is very near to 1. They need more time than VPO measurements,
however.
3. Isopiestic sorption/desorption methods
Isopiestic measurements allow a direct determination of solvent activity or vapor pressure in

polymer solutions by using a reference system (a manometer may not have to be applied). There are two
general principles for lowering the solvent activity in the reference system: concentration lowering or
temperature lowering. Isopiestic measurements have to obey the condition that no polymer can vaporize
(as might be the case for lower-molecular oligomers at higher temperatures).
Concentration lowering under isothermal conditions is the classical isopiestic technique,

sometimes also called isothermal distillation. A number of solutions (two as the minimum) are in contact
with each other via their common solvent vapor phase and solvent evaporates and condenses (this is the
isothermal distillation process) between them as long as the chemical potential of the solvent is equal in
all solutions. At least one solution serves as reference system, i.e., its solvent activity vs. solvent
concentration dependence is precisely known. After an exact determination of the solvent concentration in
all equilibrated solutions (usually by weighing), the solvent activity in all measured solutions is known
from and equal to the activity of the reference solution. This method is almost exclusively used for
aqueous polymer solutions, where salt solutions can be applied as reference systems. It is a standard
method for inorganic salt systems.
Temperature lowering at specified isobaric or isochoric conditions is the most often used
technique for the determination of solvent vapor pressures or activities in polymer solutions. The majority
of all measurements are made using this kind of an isopiestic procedure where the pure solvent is used as
the reference system. The equilibrium condition of equal chemical potential of the solvent in the polymer
solution as well as in the reference system is realized by keeping the pure solvent at a lower temperature
(T1) than the measuring temperature (T2) of the solution. In equilibrium, the vapor pressure of the pure
solvent at the lower temperature is then equal to the partial pressure of the solvent in the polymer solution,
i.e., P1s(T1) = P1(T2). Equilibrium is again established via the common vapor phase for both subsystems.
1. Introduction 5
____________________________________________________________________________________
The vapor pressure of the pure solvent is either known from independent data or measured
additionally in connection with the apparatus. The composition of the polymer solution can be altered by
changing T1 and a wide range of compositions can be studied (between 30-40 and 85-90 wt% polymer,
depending on the solvent). Measurements above 85-90 wt% polymer are subject to increasing errors
because of surface adsorption effects.
A broad variety of experimental equipment is based on this procedure. This isopiestic technique
is the recommended one for most polymer solutions since it is advantageous in nearly all aspects of
measurement. It covers the broadest concentration range. Only very small amounts of polymer are needed
(about 30-50 mg with the classical quartz spring balance, about 100 µg with piezoelectric sorption
detector or microbalance techniques, see below). It is much more rapid than all other methods explained
above, because equilibrium time decreases drastically for such small amounts of polymer and polymer
solution (about 12-24 hours for the quartz spring balance, about 3-4 hours for piezoelectric or
microbalance techniques). The complete isotherm can be measured using a single loading of the
apparatus. Equilibrium is easier to obtain since comparatively small amounts of solvent have to diffuse
into the bulk sample solution. Equilibrium can be tested better by measuring sorption and desorption runs
which must lead to equal results for thermodynamic absorption equilibrium.
Supercritical solvents can be investigated if the piezoelectric detector is used (otherwise

buoyancy in dense fluids may cause serious problems). Much broader pressure and temperature ranges
can be covered with relatively simple equipment, which may again be limited by the weighing system.
Isopiestic sorption measurements can be automated and will also allow kinetic experiments. They have
two disadvantages. First, isopiestic sorption measurements below about 30 wt% polymer are subject to
increasing errors because very small temperature differences (vapor pressure changes) are connected with
large changes in concentration. Second, problems may arise with precise thermostatting of both the
solvent and the solution at different constant temperatures over a longer period of time.
The classical concept is the sorption method using a quartz spring balance that measures the
extension of the quartz spring according to Hook’s law (linear relationship, no hysteresis). In this method
a weighed quantity of the (non-volatile) polymer is placed on the pan of the quartz spring balance within a
measuring cell. The determination of spring extension vs. mass has to be made in advance as a calibration
procedure. Reading of the spring extension is usually made by means of a cathetometer. The cell is sealed,
evacuated and thermostatted to the measuring temperature (T2) and the solvent is then introduced into the
measuring cell as solvent vapor. The solvent vapor is absorbed by the polymer sample to form the
polymer solution until thermodynamic equilibrium is reached. The solvent vapor is provided from a
reservoir of either pure liquid solvent thermostatted at a lower temperature (T1) or a reference liquid
solution of known concentration/solvent partial pressure as in the case of the isothermal distillation
procedure as described above. Such an apparatus was used widely in the author’s work.
The following problems have to be solved during the experiment. The equilibrium cell has to be
sealed carefully to avoid any air leakage over the complete duration of the measurements (to measure one
isotherm takes about 14 days). Specially developed thin Teflon sealing rings are preferred to grease. The
polymer sample has to stand the temperature. Changes by thermal aging during the experiment must be
avoided. The temperatures provided by the thermostats must not fluctuate more than ± 0.1 K.
Condensation of solvent vapor at points that become colder than T2 has to be avoided. As was stated by
different experimentalists, additional measurement of the vapor pressure inside the isopiestic sorption
apparatus seems to be necessary if there is some doubt about the real pressure or if no reliable pure
solvent vapor pressure data exist for the investigated temperature range. This direct pressure measurement
has the advantage that absolute pressures can be obtained and pressure fluctuations can be observed. More
modern equipment applies electronic pressure sensors instead of Hg manometers to avoid the problems
____________________________________________________________________________________
caused by the contact of solvent vapor with the mercury surface and to get a better resolution of the
measuring pressure.
Isopiestic vapor sorption can be made using an electronic microbalance instead of the quartz
spring balance. Electronic microbalances are commercially available from a number of producers. Their
main advantages are their high resolution and their ability to allow kinetic measurements. Additionally,
experiments using electronic microbalances can be automated easily and provide computing facilities.
The major disadvantage with some kinds of microbalances is that they cannot be used at high
solvent vapor pressures and so are limited to a relatively small concentration range. However, since thin
polymer films can be applied, this reduces both the time necessary to attain equilibrium (some hours) and
the amount of polymer required, and equilibrium solvent absorption can be obtained also at polymer mass
fractions approaching 1 (i.e., for small solvent concentrations). Depending on their construction, the
balance head is situated inside or outside the measuring apparatus. Problems may arise when it is inside
where the solvent vapor may come into contact with some electronic parts. Furthermore, all parts of the
balance that are inside the apparatus have to be thermostatted to the measuring temperature to enable the
correct equilibration of the polymer solution or even slightly above measuring temperature to avoid
condensation of solvent vapor in parts of the balance. The allowed temperature range of the balance and
its sensitivity to solvent corrosion determine the accessible measuring range of the complete apparatus. A
magnetic suspension balance can be applied instead of an electronic microbalance. The magnetic
suspension technique has the advantage that all sensitive parts of the balance are located outside the
measuring cell because the balance and the polymer solution measuring cell are in separate chambers and
connected by magnetic coupling only. This allows magnetic suspension balances to be used at
temperatures up to about 500 K as well as at pressures up to about 200 MPa.
The most sensitive solvent vapor sorption method is the piezoelectric sorption detector. The
amount of solvent vapor absorbed by a polymer is detected by a corresponding change in frequency of a
piezoelectric quartz crystal coated with a thin film of the polymer because a frequency change is the
response of a mass change at the surface of such a crystal. The frequency of the crystal decreases as mass
increases when the crystal is placed in a gas or vapor medium. The frequency decrease is fairly linear. The
polymer must be coated onto the crystal from a solution with some care to obtain a fairly uniform film.
Measurements can be made at dynamic (vapor flow) or static conditions. With reasonable assumptions for
the stability of the crystal’s base frequency and the precision of the frequency counter employed, the
piezoelectric method allows the detection of as few as 10 nanograms of solvent using a 10 MHz crystal.
This greatly reduces both the time necessary to attain equilibrium (3-4 hours) and the amount of polymer
required. Because very thin films are applied, equilibrium solvent absorption can be obtained also at
polymer mass fractions approaching 1 (i.e., for small solvent concentrations). Sorption-desorption
hysteresis has never been observed when using piezoelectric detectors. This demonstrates the effect of
reducing the amount of polymer from about 50 mg for the quartz spring sorption technique by an order of
103 for the piezoelectric detector. However, measurements are limited to solvent concentrations well
below the region where solution drops would be formed. On the other hand, measurements can be made
also at higher temperatures and pressures. Limits are set by the stability of the electrical equipment and the
construction of the measuring cell.
4. Gas-liquid chromatography (GLC)
GLC can be used to determine the activity coefficient of a solute in a (molten) polymer at
essentially zero solute concentration. This type of activity coefficient is known as an infinite-dilution
activity coefficient. Because the liquid polymer in the stationary phase acts as a solvent for the very small
amount of an injected solute sample, this technique is often called inverse gas-liquid chromatography
(IGC).
1. Introduction 7
____________________________________________________________________________________
The equipment does not differ in principle very much from that used in analytical GLC. For
operating at infinite dilution, the carrier gas flows directly to the column which is inserted into a
thermostatted oil bath (to get a more precise temperature control than in a conventional GLC oven). The
output of the column is measured with a flame ionization detector or alternately with a thermal
conductivity detector. Helium is used today as the carrier gas (nitrogen was used in earlier work). From
the difference between the retention time of the injected solvent sample and the retention time of a non-
interacting gas (marker gas), thermodynamic equilibrium data can be obtained. Most experiments were
done up to now with packed columns, but capillary columns were used too.
The experimental conditions must be chosen so that real thermodynamic data can be obtained,
i.e., equilibrium bulk absorption conditions. Errors caused by unsuitable gas flow rates, unsuitable
polymer loading percentages on the solid support material and support surface effects as well as any
interactions between the injected sample and the solid support in packed columns, unsuitable sample size
of the injected probes, carrier gas effects, and imprecise knowledge of the real amount of polymer in the
column, can be sources of problems, whether data are nominally measured under real thermodynamic
equilibrium conditions or not, and have to be eliminated. The sizeable pressure drop through the column
must be measured and accounted for. Column preparation is the most difficult and time-consuming task
within the IGC experiment. Two, three or even more columns must be prepared to test the reproducibility
of the experimental results and to check any dependence on polymer loading and sometimes to filter out
effects caused by the solid support. In addition, various tests regarding solvent sample size and carrier gas
flow rate have to be done to find out correct experimental conditions. There is an additional condition for
obtaining real thermodynamic equilibrium data that is caused by the nature of the polymer sample.
Synthetic polymers are usually amorphous or semicrystalline products. Thermodynamic equilibrium data
require the polymer to be in a molten state, however. This means that IGC measurements have to be
performed for our purpose well above the glass transition temperature of the amorphous polymer or even
above the melting temperature of the crystalline parts of a polymer sample. On the other hand, IGC can be
applied to determine these temperatures. Only data at temperatures well above the glass transition
temperature lead to real thermodynamic vapor-liquid equilibrium data. As a rule, the experimental
temperature must exceed the glass transition temperature by about 50 K.
GLC can also be used to determine the partial pressure of a solute in a polymer solution at
concentrations as great as 50 wt% solute. In this case of finite concentration IGC, a uniform background
concentration of the solute is established in the carrier gas. The carrier gas is diverted to a saturator
through a metering valve. In the saturator it passes through a diffuser in a well-stirred, temperature-
controlled liquid bath. It leaves the separator with the solute equilibrium vapor pressure in the carrier gas.
The solute concentration is varied by changing the saturator temperature. Precise control of the
temperature bath is needed in order to obtain a constant plateau concentration. Upon leaving the saturator
the gas flows to the injector block and then to the column. As in the infinite dilute case a small pulse of the
solvent is then injected. This technique is known as elution on a plateau. Because finite concentration IGC
is technically more complicated, few workers have applied it. Whereas the vapor sorption results are more
accurate at higher concentrations, the reverse is true for finite concentration IGC since larger injection
volumes have to be used, which strains the theory on which the calculations are based. Also, at large vapor
concentrations the chromatographic peaks become more spread out, making the measurement of retention
times less precise. Additionally, the concentration range is limited by the requirement that the saturator
temperature must be below that of the column. Clearly, at higher measuring temperatures, higher solvent
concentrations may be used. Finite concentration IGC can be extended to multicomponent systems. Data
reduction is somewhat complicated, however.
VLE measurements for polymer solutions can be done by so-called headspace gas chroma-
tography (HSGC), which is practically a combination of static vapor pressure measurement with gas
chromatographic detection (97KOL). Again, polymer solutions have to be prepared in advance and have
to be equilibrated at the measuring temperature for some weeks before measurement. HSGC experiments
____________________________________________________________________________________
were carried out with an apparatus consisting of a headspace sampler and a normal gas chromatograph.
The thermostatted headspace sampler samples a constant amount of gas phase and injects this mixture into
the gas chromatograph. After separation of the components of the gaseous mixture in a capillary column,
they are detected individually by a thermal conductivity detector. The signals are sent to an integrator
which calculates the peak areas proportional to the amount of gas in the sample volume and consequently
to the vapor pressure. Calibration can be done by measuring the signal of the pure solvent in dependence
on temperature and comparing the data with the corresponding vapor pressure vs. temperature data.
Measurements can be done between about 25 and 85 wt% polymer in the solution (again depending on
temperature, solvent and polymer investigated). In order to guarantee thermodynamic equilibrium in the
sampler, solutions have to be conditioned for at least 24 h at constant temperature in the headspace
sampler before measurement. Additional degassing is not necessary and solvents have to be purified only
to the extent that is necessary to prevent unfavorable interactions in the solution. The experimental error in
the vapor pressures is typically of the order of 1-3%. One great advantage of HSGC is its capability to
measure VLE data not only for binary polymer solutions but also for polymer solutions in mixed solvents
since it provides a complete analysis of the vapor phase in equilibrium.
The data reduction for infinite dilution IGC starts with the usually obtained parameters of
retention volume or net retention volume which have to be calculated from the measured retention times
and the flow rate of the carrier gas at column conditions.
Vnet = Vr − Vdead (1)
where:
Vnet net retention volume
Vr retention volume
Vdead retention volume of the inert marker gas, dead retention, gas holdup
These net retention volumes are reduced to specific retention volumes, Vg0, by division of
equation (1) with the mass of the liquid (here the liquid is the molten copolymer). They are corrected for
the pressure difference between column inlet and outlet pressure, and reduced to a temperature T0 =
273.15 K.
V   T0  3( Pin / Pout ) 2 − 1
Vg =  net
0
  (2)
  T  2 ( Pin / Pout ) − 1
3
 mB
where:
Vg0 specific retention volume corrected to 0oC = 273.15 K
mB mass of the copolymer in the liquid phase within the column
Pin column inlet pressure
Pout column outlet pressure
T measuring temperature
T0 reference temperature = 273.15 K
Theory of GLC provides the relation between Vg0 and thermodynamic data for the low-molecular
component (solvent A) at infinite dilution:
∞ ∞
 PA  RT0  PA  RT0
 L = 0 or  L = 0 (3)
 xA  Vg M B  wA  Vg M A
1. Introduction 9
____________________________________________________________________________________
where:
MB molar mass of the liquid (molten) polymer B
R gas constant
xAL mole fraction of solvent A in the liquid solution
wAL mass fraction of solvent A in the liquid solution
The activity coefficients at infinite dilution read, if we neglect interactions to and between carrier
gas molecules (which are normally helium):
 RT   ( B − V L )( P − PAs ) 
γ A∞ =  0 0 s  exp  AA A  (4)
V M P  RT
 g B A   
∞
 RT   ( B − VA L )( P − PA s ) 
Ω A =  0 0 s  exp  AA  (5)
V M P  RT
 g A A   
where:
activity aA = wAΩA
The standard state pressure P has to be specified. It is common practice by many authors to
define zero pressure as standard pressure since pressures are usually very low during GLC measurements.
Then, equations (4 and 5) change to:
∞
 RT0   P s A (VA L − BAA ) 
γA = 0
 V M P s 
exp   (6)
 g B A   RT 
∞
 RT   P s (V L − BAA ) 
Ω A =  0 0 s  exp  A A  (7)
V M P  RT
 g A A   
One should keep in mind that mole fraction-based activity coefficients γA become very small
values for common polymer solutions and reach a value of zero for MB →∞, which means a limited
applicability at least to oligomer solutions. Therefore, the common literature provides only mass fraction-
based activity coefficients for (high-molecular) polymer/(low-molecular) solvent pairs. The molar mass
MB of the polymeric liquid is an average value (Mn) according to the usual molar-mass distribution of
polymers. Additionally, it is a second average if mixed stationary liquid phases are applied.
____________________________________________________________________________________
Furthermore, thermodynamic VLE data from GLC measurements are provided in the literature as
values for (PA/wA)∞, see equation (3), i.e., classical mass fraction based Henry’s constants (if assuming
ideal gas phase behavior):
∞
 P  RT
H A, B =  AL  = 0 0 (8)
 wA  Vg M A
Since Vnet = Vr − Vdead, the marker gas is assumed to not be retained by the copolymer
stationary phase and will elute at a retention time that is usually very small in comparison with those of the
samples investigated. However, for small retention volumes, values for the mass fraction-based Henry’s
constants should be corrected for the solubility of the marker gas (76LIU). The apparent Henry’s constant
is obtained from equation (8) above.
−1
 M A H Aapp 
H A, B = H app
A, B  1 + ,B
 (9)
 M ref H A,ref 
Mref is the molar mass of the marker gas. The Henry’s constant of the marker gas itself,
determined by an independent experiment, need not be known very accurately, as it is usually much larger
than the apparent Henry’s constant of the sample.
5. Vapor-pressure osmometry (VPO)
Vapor-pressure osmometry is from its name comparable to membrane osmometry by allowing the
vapor phase to act like a semipermeable membrane, but it is based on vapor pressure lowering or boiling
temperature elevation. Since the direct measure of vapor pressure lowering of dilute polymer solutions is
impractical because of the extreme sensitivity that is required, VPO is in widespread use for low-
molecular and oligomer solutions (i.e., Mn less than 20,000 g/mol) by employing the thermoelectric
method where two matched temperature-sensitive thermistors are placed in a chamber that is
thermostatted to the measuring temperature and where the atmosphere is saturated with solvent vapor. If
drops of pure solvent are placed on both thermistors, the thermistors will be at the same temperature (zero
point calibration). If a solution drop is placed on one thermistor, a temperature difference ∆T which is
caused by condensation of solvent vapor onto the solution drop occurs. From equilibrium thermodynamics
it follows that this temperature increase has its theoretical limit when the vapor pressure of the solution is
equal to that of the pure solvent, i.e., at infinite dilution. The obtained temperature difference is very
small, about 10−5 K.
Because solvent transfer effects are measured, VPO is a dynamic method. This leads to a time-
dependent measurement of ∆T. Depending on technical details of the equipment, sensitivity of the
temperature detector, measuring temperature, solvent vapor pressure and polymer concentration in the
solution drop, a steady state for ∆T can be obtained after some minutes. The value of ∆Tst is the basis for
thermodynamic data reduction; see below. If measuring conditions do not allow a steady state, an
extrapolation method to ∆T at zero measuring time can be employed for data reduction. Sometimes a
value is used that is obtained after a predetermined time. However, this may lead to some problems with
knowing the exact polymer concentration in the solution. The extrapolation method is somewhat more
complicated and needs experience of the experimentator but gives an exact value of polymer
concentration. Both methods are used within solvent activity measurements where polymer concentrations
are higher and condensation is faster than in common polymer characterization experiments.
1. Introduction 11
____________________________________________________________________________________
Experience has shown that careful selection of solvent and temperature is critical to the success
of the VPO experiment. Nearly all common solvents, including water (usually, there are different
thermistor sensors for organic solvents and for water), can be used with VPO. The measuring temperature
should be chosen so that the vapor pressure of the solvent will be greater than 6,000 Pa, but not so high as
to lead to problems with evaporation from the chamber. Solvent purity is critical, and volatile impurities
and water must be avoided. Greater sensitivity can be achieved by using solvents with low enthalpies of
vaporization. This means that not all desirable polymer/solvent pairs and not all temperature (pressure)
ranges can be investigated by VPO. Additionally, VPO has some inherent sources of error. These can be
attributed to the possible existence of surface films, to differences in diffusion coefficients in solutions, to
appreciably different solution concentrations, to differences in heat conductivity, to problems with drop
size and shape, to the occurrence of reactions in the solution, and to the presence of volatile solutes. Of
course, most errors can be avoided to a good measure by careful laboratory practice and/or technical
improvements, but they must be taken into account when measuring solvent activities.
The data reduction of vapor-pressure osmometry (VPO) uses the stationary temperature
difference as the starting point for determining solvent activities. There is an analogy to the boiling point
elevation in thermodynamic equilibrium. Therefore, in the steady-state period of the experiment, the
following relation can be applied if one assumes that the steady state is sufficiently near the vapor-liquid
equilibrium and linear non-equilibrium thermodynamics is valid:
RT 2
∆T st = − kVPO ln a A (10)
∆ LV H 0 A
where:
R gas constant
T measuring temperature (= temperature of the pure solvent drop)
∆Tst temperature difference between solution and solvent drops in the steady state
Liquid-liquid equilibrium (LLE) measurements
There are two different situations for the liquid-liquid equilibrium in copolymer/solvent systems:
(i) the equilibrium between a dilute copolymer solution (sol) and a copolymer-rich solution (gel) and (ii)
the equilibrium between the pure solvent and a swollen copolymer network (gel). Only case (i) is
considered here. To understand the results of LLE experiments in copolymer/solvent systems, one has to
take into account the strong influence of distribution functions on LLE, because fractionation occurs
during demixing, both with respect to chemical distribution and to molar mass distribution. Fractionation
during demixing leads to some effects by which the LLE phase behavior differs from that of an ordinary,
strictly binary mixture, because a common copolymer solution is a multicomponent system. Cloud-point
curves are measured instead of binodals; and per each individual feed concentration of the mixture, two
parts of a coexistence curve occur below or above (UCST or LCST behavior) the cloud-point curve, i.e.,
to produce an infinite number of coexistence data.
Distribution functions of the feed copolymer belong only to cloud-point data. On the other hand,
____________________________________________________________________________________
copolymer distribution function. The threshold (maximum or minimum corresponding to UCST or LCST
behavior) temperature (or pressure) is not equal to the critical point, since the critical point is to be found
at a shoulder of the cloud-point curve. Details were discussed by Koningsveld (68KON, 72KON). Thus,
LLE data have to be specified in the tables as cloud-point or coexistence data, and coexistence data make
sense only if the feed concentration is given.
Experimental methods can be divided into measurements of cloud-point curves, of real

coexistence data, and of critical points.
Due to distinct changes in a number of physical properties at the phase transition border, a
number of methods can be used to determine cloud-points. In many cases, the refractive index change is
determined because refractive indices depend on concentration (with the rare exception of isorefractive
phases) and the sample becomes cloudy when the highly dispersed droplets of the second phase appear at
the beginning of phase separation. Simple experiments observe cloud-points visually. More sophisticated
equipment applies laser techniques and light scattering, where changes in scattering pattern or intensity are
recorded as a function of decreasing/increasing temperature or pressure. The point where first deviations
from a basic line are detected is the cloud-point. Since demixing or phase homogenization requires some
time (especially for highly viscous solutions), special care is to be applied to obtain good data. Around the
critical point, large fluctuations occur (critical opalescence) and scattering data have to be measured at a
90o scattering angle. The determination of the critical point is to be made by independent methods; see
below. Various other physical properties have been applied for detecting liquid-liquid phase separation,
i.e., viscosity, ultrasonic absorption, thermal expansion, dielectric constant, differential thermal analysis
(DTA) or differential scanning calorimetry (DSC), UV- or IR-spectroscopy, and size exclusion
chromatography/gel permeation chromatography (SEC, GPC).
Real coexistence data were measured only in a small number of investigations. This is mainly due
to very long equilibrium times (usually weeks) which are necessary for obtaining thermodynamically
correct data. A common method is to cool homogeneous solutions in ampullas very slowly to the desired
temperature in the LLE region, and equilibrium is reached after both phases are sharply separated and
clear. After separating both phases, concentrations and distribution functions are measured. Acceptable
results can be obtained for low copolymer concentrations (up to 20 wt%). Highly viscous copolymer
solutions at higher concentrations can be investigated by a modified ultracentrifuge where the equilibrium
is quickly established during cooling by action of gravitational forces. After some hours, concentrations,
phase volume ratios and concentration differences can be determined.
copolymers, the critical point is the maximum (or minimum) of the binodal. Binodals of copolymer
solutions can be rather broad and flat. Then, the exact position of the critical point can be obtained by the
method of the rectilinear diameter:
(ϕ B − ϕ B )
I II
T
− ϕ B ∝ (1 − crit )1−α
crit
(11)
2 T
where:
ϕBI volume fraction of the copolymer in coexisting phase I
ϕBII volume fraction of the copolymer in coexisting phase II
ϕBcrit volume fraction of the copolymer at the critical point
1. Introduction 13
____________________________________________________________________________________
For solutions of polydisperse copolymers, such a procedure cannot be used because the critical
methods were developed to solve this problem: the phase-volume-ratio method (68KON) where one uses
the fact that this ratio is exactly equal to one only at the critical point, and the coexistence concentration
plot (69WOL) where an isoplethal diagram of values of ϕBI and ϕBII vs. ϕ0B gives the critical point as the
intersection of cloud-point and shadow curves. Details will not be discussed here. Treating copolymer
solutions with divariate distribution functions by continuous thermodynamics is reviewed in 90RAE.
High-pressure phase equilibrium (HPPE) measurements
The experimental investigation of high-pressure fluid phase equilibria in copolymer solutions is

confronted with the same problems discussed above insofar as the investigated phase equilibria
correspond with a VLE-, LLE-, or VLLE-type behavior, which are the only cases considered here. The
experimental equipment follows on the same techniques, however, extended to high pressure conditions,
using high-pressure cells and autoclaves for turbidimetry, light scattering, viscometry, and others.
The solvents are in many cases supercritical fluids, i.e., gases/vapors above their critical
temperature and pressure. Data were measured mainly for two kinds of solutions: solutions in supercritical
CO2 (and some other fluids) or solutions in supercritical monomers. There are recent reviews on phase
behavior of polymers and copolymers in supercritical fluids (94MCH, 97KIR, and 99KIR) that summarize
today’s state of investigation.
Measurement of enthalpy changes in copolymer solutions
Experiments on enthalpy changes in binary copolymer solutions can be made within common
microcalorimeters by applying one of the following three methods:
1. Measurement of the enthalpy change caused by solving a given amount of the solute
copolymer in an (increasing) amount of solvent, i.e., the solution experiment
2. Measurement of the enthalpy change caused by mixing a given amount of a concentrated
copolymer solution with an amount of pure solvent, i.e., the dilution experiment
3. Measurement of the enthalpy change caused by mixing a given amount of a
liquid/molten copolymer with an amount of pure solvent, i.e., the mixing experiment
Care must be taken for polymer solutions with respect to the resolution of the instruments, which
has to be higher than for common mixtures or solutions with larger enthalpic effects, and for all effects
and necessary corrections when working with highly viscous media with long equilibration times. Thus,
the usually employed calorimeters for such purposes are the Calvet-type calorimeters based on the heat
flux principle, which need not be discussed further. Details can be found in 84HEM and 94MAR.
In particular, one has to distinguish between the following effects for polymer solutions. The
(integral) enthalpy of mixing or the (integral) enthalpy of solution of a binary system is the amount of heat
which must be supplied when nA mole of pure solvent A and nB mole of pure copolymer B are combined
to form a homogeneous mixture/solution in order to keep the total system at constant temperature and
pressure.

∆solh = nAHA + nBHB − (nAH0A + nBH0B) (12b)
____________________________________________________________________________________
where:
∆ Mh (integral) enthalpy of mixing
∆solh (integral) enthalpy of solution
HB partial molar enthalpy of copolymer B
H0B molar enthalpy of pure copolymer B
nB amount of substance of copolymer B
The enthalpy effect might be positive (endothermic solution/mixture) or negative (exothermic

solution/mixture) depending on the ratio nA/nB, i.e., the concentration of the total system. Unfortunately, in
some of the older literature, the definition of the sign of the so-called (integral) heat of solution is
reversed, compared to the enthalpy, occasionally causing some confusion. In principle, the enthalpy effect
depends also on pressure, However, in the case of condensed systems this pressure dependence is
relatively small. All values in this handbook usually refer to normal pressure. H0A and H0B are the molar
enthalpies of pure solvent A and pure copolymer B and HA and HB the partial molar enthalpies of solvent
and copolymer in the solution/mixture.
The value of the (integral) enthalpy of solution is dependent on the degree of crystallinity for
semicrystalline copolymers and, usually to a lesser extent, on the thermal history of glassy copolymers.
The (integral) enthalpy of mixing is independent of any crystalline or glassy aspects of the copolymer.
Thus, the (integral) enthalpy of mixing can be obtained without difficulties only for liquid/molten
copolymers mixed with a solvent. Otherwise, the melting enthalpy of the crystallites and/or the glass
enthalpy have to be determined additionally by independent measurements. As such a procedure is rather
difficult and might cause substantial errors, it is common to measure the (integral) intermediary enthalpy
of dilution, i.e., the enthalpy effect obtained if solvent A is added to an existing homogeneous copolymer
solution. The intermediary enthalpy of dilution is the difference between two values of the enthalpy of
mixing/solution corresponding to the concentrations of the copolymer solution at the beginning and at the
end of the dilution process. The term integral is often added to these enthalpy changes to describe changes
where finite amounts of substances are mixed. Especially, the integral enthalpy of solution/mixing for a
copolymer B is given in a number of literature sources by applying not the partial (molar or specific)
quantities but the following two definitions:
• per mole copolymer B:
∆solHB = ∆solh/nB = ∆solH/xB

int
(13a)
∆MHB = ∆Mh/nB = ∆MH/xB
int
(13b)
• per gram copolymer B (where the intensive ∆Hs are the specific ones):
∆solHB = ∆solh/mB = ∆solH/wB

int
(13c)
∆MHB = ∆Mh/mB = ∆MH/wB
int
(13d)
where:
int
∆solHB integral enthalpy of solution of copolymer B
int
∆ MH B integral enthalpy of mixing of copolymer B
mB mass of copolymer B
wB mass fraction of copolymer B
xB mole fraction of copolymer B
1. Introduction 15
____________________________________________________________________________________
As stated above, the difference between int∆solHB and int∆MHB is determined by any enthalpic
effects caused from solid-liquid phase transition of the crystallites and/or from glass transition and is zero
for liquid/molten copolymers.
The term differential is sometimes added to enthalpy changes where infinitesimal (i.e., very
small) amounts were added to a very large amount of either solution or pure component. These enthalpy
changes are usually called partial (molar or specific) enthalpies of solution/mixing. The mathematical
definition of partial molar enthalpies of solution/mixing is given for the copolymer B by:
∆solHB = (∂∆ sol h / ∂nB ) P ,T ,n j = HB − H0B (14a)

∆MHB = (∂∆ M h / ∂nB ) P ,T ,n j = HB − H0B (14b)
with a unit of J/mol. However, for copolymer solutions, ∆solHB or ∆MHB is often expressed as the enthalpy
change per unit mass of copolymer added which can be obtained from the following derivative:
∆solHB = (∂∆ sol h / ∂mB ) P ,T ,m j (14c)

∆MHB = (∂∆ M h / ∂mB ) P ,T ,m j (14d)
where:
∆solHB partial molar (or specific) enthalpy of solution of the copolymer B
∆ MH B partial molar (or specific) enthalpy of mixing of the copolymer B
with a unit of J/g. Similar to these definitions one can find results related to one mole of monomers (or
base units). The derivative is then made by applying the base mole fraction of the copolymer. The partial
(molar or specific) enthalpy of solution of the copolymer B is equal to the so-called differential enthalpy
of solution at finite concentrations which is, for finite concentrations, different from the int∆solHB or
int
∆MHB data as defined above. For example, in the case of a binary mixture, one obtains the relation:
∆MHB = ∆MH + (1 − xB)(∂∆MH/∂xB) (15)
which results in different values to int∆MHB. In the case of adding an infinitesimal amount of copolymer to
the pure solvent, the partial (molar or specific) enthalpy of solution of the copolymer B is properly
identified as the partial enthalpy of solution of the copolymer at infinite dilution, ∆solHB∞, or the partial
enthalpy of mixing of the copolymer at infinite dilution, ∆MHB∞. Its value at infinite dilution of the
copolymer is equal to the so-called first integral enthalpy of solution (unfortunately, sometimes referred to
more simply as the enthalpy of solution of the copolymer, but, as discussed above, identical values can
only be obtained for infinite dilution). In practice, the partial (molar or specific) enthalpy of solution of
the copolymer B is measured by mixing isothermally a large excess of pure solvent and a certain amount
of the copolymer to form a homogeneous solution.
The state of the copolymer before dissolution can significantly affect the enthalpy of solution. An
amorphous copolymer below its glass transition temperature Tg often dissolves with the release of heat.
The enthalpy of solution of a glassy copolymer is usually dependent on temperature and, to some extent,
on the thermal history of the glass-forming process. An amorphous copolymer above Tg can show
endothermic or exothermic dissolution behavior depending on the nature of the solvent and the interaction
energies involved as is the case for any enthalpy of mixing. The dissolving of a semicrystalline copolymer
requires an additional amount of heat associated with the disordering of crystalline regions. Consequently,
____________________________________________________________________________________
its enthalpy of solution is usually positive and depends on the degree of crystallinity of the given
copolymer sample.
The mathematical definition for the partial molar enthalpies of solution/mixing is given for the
solvent A by
∆solHA = (∂∆ sol h / ∂nA ) P ,T ,n j = HA − H0A (16a)

∆MHA = (∂∆ M h / ∂nA ) P ,T ,n j = HA − H0A (16b)
where:
again with a unit of J/mol. It is equal to the so-called differential enthalpy of dilution as a consequence of
adding an infinitesimal amount of solvent to the solution/mixture. The integral enthalpy of dilution for the
solvent is equivalent to the integral molar enthalpy of mixing for the solvent A as defined by:
∆MHA = ∆Mh/nA
int
(17)
and, in the case of adding a very small amount of solvent to the pure copolymer, the partial molar enthalpy
of solution at infinite dilution of the solvent is obtained. Partial molar enthalpies of mixing (or dilution) of
the solvent are included in this data collection only for cases where they were obtained from calorimetric
experiments.
Generally, it is known that such partial molar enthalpies of mixing (or dilution) of the solvent can
also be determined from the temperature dependence of the activity of the solvent:
∆MHA = R [∂ ln a A / ∂ (1/ T )]P (18)
where:
P pressure
R gas constant
T temperature
Any thermodynamic equilibrium experiments that measure vapor-liquid equilibrium, osmotic

equilibrium, swelling equilibrium, sedimentation equilibrium or static light scattering can serve as
potential sources for such data. Even from measurements of the intrinsic viscosity, enthalpy data were
derived applying some theoretical background. However, agreement between enthalpy changes measured
by calorimetry and results determined from the temperature dependence of solvent activity data is often of
limited quality. Therefore, such data are not included here, except for one instance. From engineering and
also from scientific aspects, the partial molar enthalpy of mixing at infinite dilution of the solvent in the
liquid/molten copolymer ∆MHA∞ is of special importance. Therefore, data for ∆MHA∞ determined by
inverse gas-liquid chromatography (IGC) have been included here.
∞
∆MHA∞ = R [∂ ln Ω A / ∂ (1/ T )]P (19)
1. Introduction 17
____________________________________________________________________________________
where:
∆ M H A∞ partial molar enthalpy of mixing at infinite dilution of the solvent A
P pressure
R gas constant
T temperature
Additionally, the enthalpies of solution at infinite dilution ∆solHA(vap)∞ of gases or vapors in

molten copolymers determined by IGC have been included since IGC is the best recommended method for
such data.
∆solHA(vap)∞ = − R [∂ ln Vg / ∂ (1/ T )]P

0
(20)
where:
Vg0 specific retention volume corrected to 0oC
PVT measurement for the copolymer melt
There are two widely practiced methods for the PVT measurement of polymers and copolymers:
which were described in detail by Zoller in papers and books (e.g., 86ZOL, 95ZOL). Thus, a short
____________________________________________________________________________________
Commercial machines are available. Thus, most of the literature data from the last decade were
measured with this technique.
used.
The tables in Chapter 6 provide specific volumes neither at or below the melting transition of
semicrystalline materials nor at or below the glass transition of amorphous samples, since PVT data of
solid polymer samples are non-equilibrium data and depend on sample history and experimental
procedure (which will not be discussed here). Therefore, only equilibrium data for the liquid/molten state
are tabulated. Their common accuracy (standard deviation) is about 0.001 cm3/g in specific volume, 0.1 K
in temperature and 0.005*P in pressure (95ZOL).
There are a couple of methods for the experimental determination of the second virial coefficient:
colligative properties (vapor pressure depression, freezing point depression, boiling point increase,
membrane osmometry), scattering methods (classical light scattering, X-ray scattering, neutron scattering),
sedimentation velocity and sedimentation equilibrium. Details of the special experiments can be found in
many textbooks and will not be repeated here. See, for example, 72HUG, 74TOM, 75CAS, 75FUJ,
75GLO, 87ADA, 87BER, 87COO, 87KRA, 87WIG, 91CHU, 91MAY, 91MU2, 92HAR, and 99PET.
The vapor pressure depression of the solvent in a binary copolymer solution, i.e., the difference
between the saturation vapor pressure of the pure solvent and the corresponding partial pressure in the
solution, ∆PA = PAs − PA, is expressed as:
∆PA  1 
= VAL cB  + A2 cB + A3cB + ...
2
(21)
PA  Mn 
where:
A2, A3, ... second, third, ... osmotic virial coefficients at temperature T
cB (mass/volume) concentration at temperature T
Mn number-average relative molar mass of the copolymer
The freezing point depression, ∆SLTA, is:
 1 
∆ SLTA = ESL cB  + A2 cB + A3cB + ...
2
(22)
 Mn 
1. Introduction 19
____________________________________________________________________________________
and the boiling point increase, ∆LVTA, is:
 1 
∆ LV TA = ELV cB  + A2 cB + A3cB + ...
2
(23)
 Mn 
where:
The osmotic pressure, π , can be described as:
π  1 
= RT  + A2 cB + A3cB + ...
2
(24)
cB  Mn 
where:
R gas constant
π osmotic pressure
In the dilute concentration region, the virial equation is usually truncated after the second virial
coefficient which leads to a linear relationship. A linearized relation over a wider concentration range can
be constructed if the Stockmayer-Casassa relation between A2 and A3 is applied:
2
AM 
A3 M n =  2 n  (25)
 2 
0.5 0.5
π  RT   A2 M n 
  =  1 + 2 c2  (26)
 c2   Mn 
KcB 1
= + 2 A2Q ( q )cB + ... (27)
R( q) M w Pz ( q)
with
4π θ
q= sin (28)
λ 2
____________________________________________________________________________________
where:
Mw mass-average relative molar mass of the copolymer
q scattering vector
λ wavelength
θ scattering angle
calculated from different relations. For details see the corresponding textbooks (72HUG, 75CAS, 82GLA,
86HIG, 87BER, 87KRA, 87WIG, and 91CHU).
Thermodynamic data from the ultracentrifuge experiment can be obtained either from the
sedimentation velocity (sedimentation coefficient) or from the sedimentation-diffusion equilibrium since
the centrifugal forces are balanced by the activity gradient. The determination of sedimentation and
diffusion coefficients yields the virial coefficients by:
D  1 
 s
( )
  1 − υ B ,spez ρ A = RT  + 2 A2cB + 3 A3cB + ... 
2
(29)
 MB 
where:
D diffusion coefficient
MB molar mass of the polymer
υ B , spez partial specific volume of the polymer
ρA density of the solvent
Sedimentation-diffusion equilibrium in an ultracentrifuge also gives a virial series:
(
ω 2 hD 1 − υB , spez ρ A )  ∂∂ lnhc B
  1
 = RT 

+ 2 A2 cB + 3 A3cB + ... 
2
(30)
 D   MB 
where:
ω angular velocity
Both equations are valid for monodisperse copolymers only, i.e., for one definite single
component B. For all polydisperse copolymers, different averages were obtained for the sedimentation
and the diffusion coefficients which depend on the applied measuring modes and the subsequent
calculations. The averages of MB correspond with averages of D and s and are mixed ones that have to
be transformed into the desired common averages. For details, please see reviews 75FUJ, 91MU2, and
92HAR.
1. Introduction 21
____________________________________________________________________________________

Characterization of the copolymers
Copolymers vary by a number of characterization variables. Molar mass, chemical

composition, and their distribution functions are the most important variables. However, tacticity,
sequence distribution, branching, and end groups determine their thermodynamic behavior in solution too.
Unfortunately, much less information is provided with respect to the copolymers that were applied in most
of the thermodynamic investigations in the original literature. In many cases, the copolymer is
characterized by its average chemical composition, some molar mass averages and some additional
information (e.g., where it was synthesized) only. Sometimes even such an information is missed.
number average Mn
Mn = i
= i
(31)
∑n i
Bi ∑w
i
Bi / M Bi
mass average Mw
Mw = i
= i
(32)
∑ni
Bi M Bi ∑w i
Bi
z-average Mz
Mz = i
= i
(33)
∑n
i
2
Bi M Bi ∑w i
Bi M Bi
 ∑ wBi M Bai
1/ a

M η =  i 
 (34)
 ∑ wBi 
 i 
where:
a exponent in the viscosity - molar mass relationship
MBi molar mass of the copolymer species Bi
nBi amount of substance of copolymer species Bi
wBi mass fraction of copolymer species Bi
____________________________________________________________________________________
The data tables of each chapter are provided below in order of the copolymers. The tables in all
the following chapters always begin with a summary of the available characterization data for the
corresponding samples of a given kind of copolymer. An acronym is defined for each copolymer sample
corresponding to the comonomers. The average chemical composition of the copolymer is then added
after a slash. For example, AN-B/51w describes an acrylonitrile/butadiene copolymer with an average
chemical composition of 51 wt% acrylonitrile, and E-P/33x describes an ethylene/propylene copolymer
with an average chemical composition of 33 mol% ethylene. Sometimes, a figure in parenthesis is added
to distinguish between different samples characterized by equal average chemical composition. The
acronyms are used in the subsequent presentation of the data tables to denote the copolymer samples.
Appendix 8.1. provides a complete list of all copolymer acronyms used in this handbook together with the
pages where data with corresponding copolymers are given.
Example (from Henry’s constants data tables)
_____________________________________________________________________________
Copolymers from acrylonitrile and butadiene
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B) Acronym Ref.
_____________________________________________________________________________
Acrylonitrile/butadiene copolymer
18.0 wt% acrylonitrile AN-B/18w 95TRI
34.0 wt% acrylonitrile AN-B/34w(1) 93ISS
34.0 wt% acrylonitrile AN-B/34w(1) 97SCH
34.0 wt% acrylonitrile AN-B/34w(2) 95TRI
34.0 wt% acrylonitrile AN-B/34w(3) 82LIP
41.0 wt% acrylonitrile AN-B/41w 86IT2
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
Copolymer (B) Mn/ Mw/ M η/ Further information
g/mol g/mol g/mol
_____________________________________________________________________________
AN-B/18w 100000 Bayer India
AN-B/34w(1) 60000 Perbunan 3307, Bayer AG, Ger.
AN-B/34w(2) 111000 Bayer India
AN-B/34w(3) Krynac, Polysar
AN-B/41w no data
_____________________________________________________________________________
Further information indicates no data if nothing more than the type of the copolymer was stated in the
corresponding literature source.
1. Introduction 23
____________________________________________________________________________________
Measures for the copolymer concentration
denotes the copolymer, A denotes the solvent, and in ternary systems C denotes the third component):
mass/volume concentration:
mass fraction:
mole fraction:
volume fraction:
segment fraction:
base mole fraction:
where:
cB (mass/volume) concentration of copolymer B
MB molar mass of the copolymer B
M0 molar mass of a basic unit of the copolymer B
rB segment number of the copolymer B
zB base mole fraction of copolymer B
____________________________________________________________________________________

ϕB volume fraction of copolymer B
ρB density of copolymer B
ψB segment fraction of copolymer B
For high-molecular copolymers, a mole fraction is not an appropriate unit to characterize

on the chosen equation of state (or simply some group contribution schemes, e.g., 68BON, 90KRE) and
have to be specified.
neglect excess volumes of mixing and, very often, the densities of the copolymer in the state of the
solution are not known correctly. However, volume fractions can be calculated without the exact
knowledge of the copolymer molar mass (or its averages). Base mole fractions are seldom applied for
copolymer systems. The value for M0, the molar mass of a basic unit of the copolymer, has to be
determined according to the corresponding average chemical composition. Sometimes it is chosen
Experimental data tables
The data tables are sorted with respect to the copolymers. Within types of copolymers the
individual samples are ordered by increasing average chemical composition as given in the head table with
the copolymer acronyms. Subsequently, systems are ordered by their solvents. Solvents are listed
alphabetically. When necessary, systems are ordered by increasing temperature. Each data set begins with
two lines for the solution components, e.g.,
copolymer (B): AN-B/21w 95GUP

solvent (A): acetonitrile C2H3N 75-05-8
where the copolymer sample is given in the first line together with the reference. The second line provides
the solvent’s chemical name, molecular formula and CAS-registry number. There are some exceptions
from this type of presentation within the tables for Henry’s constants, A2 values, UCST/LCST data, and
PVT data.
The originally measured data for each single system are then listed together with some comment
lines if necessary. The data are usually given as published, but temperatures are always given in K.
Pressures are sometimes recalculated into kPa or MPa. Enthalpy data are always recalculated into J or kJ,
if necessary. Mass fraction-based Henry’s constants are calculated from published specific retention
volumes, if such data are not provided in the original source. They are always tabulated in MPa.
1. Introduction 25
____________________________________________________________________________________

B parameter of the Tait equation
cB (mass/volume) concentration of copolymer B
C parameter of the Tait equation
HE excess enthalpy = ∆MH = enthalpy of mixing
HB partial molar (or specific) enthalpy of copolymer B
H0B molar (or specific) enthalpy of pure copolymer B
HA,B classical mass fraction Henry’s constant of solvent vapor A in molten copolymer B
∆dilH12 (integral) intermediary enthalpy of dilution ( = ∆MH(2) − ∆MH(1))
∆solH (integral) enthalpy of solution
int
∆ MH A integral enthalpy of mixing of solvent A ( = integral enthalpy of dilution)
∆MHA∞ partial molar enthalpy of mixing at infinite dilution of the solvent A
int
∆solHA integral enthalpy of solution of solvent A
∆solHA∞ first integral enthalpy of solution of solvent A (= ∆MHA∞ in the case of liquid/molten
copolymers and a liquid solvent, i.e., it is different from the values for solutions of
solvent vapors or gases in a liquid/molten copolymer ∆solHA(vap)∞ )
int
∆ MH B integral enthalpy of mixing of copolymer B
∆ MH B partial molar (or specific) enthalpy of mixing of copolymer B
∆MHB∞ partial molar (or specific) enthalpy of mixing at infinite dilution of copolymer B
int
∆solHB integral enthalpy of solution of copolymer B
∆solHB partial molar (or specific) enthalpy of solution of copolymer B
∆solHB∞ first integral enthalpy of solution of copolymer B (∆MHB∞ in the case of liquid/molten B)
MB molar mass of the copolymer B
M0 molar mass of a basic unit of the copolymer B
MI melting index
____________________________________________________________________________________

P pressure
Pin column inlet pressure in IGC
Pout column outlet pressure in IGC
q scattering vector
R gas constant
rB segment number of the copolymer B
T0 reference temperature (= 273.15 K)
∆Tst temperature difference between solution and solvent drops in VPO
Vnet net retention volume in IGC
Vr retention volume in IGC
Vdead retention volume of the (inert) marker gas, dead retention, gas holdup in IGC
Vg0 specific retention volume corrected to 0oC in IGC
Vspez specific volume
zB base mole fraction of copolymer B
λ wavelength
ϕB volume fraction of copolymer B
ρB density of copolymer B
ψB segment fraction of copolymer B
π osmotic pressure
θ scattering angle
ω angular velocity
activity aA = xAΩA
1. Introduction 27
____________________________________________________________________________________
1.5. References
Makromol. Chem., 128, 284, 1969.
1972.
72KON Koningsveld, R., Polymer Solutions and Fractionation, in Polymer Science, Jenkins, E.D.,
75FUJ Fujita, H., Foundations of Ultracentrifugal Analysis, J. Wiley & Sons, New York, 1975.
75GLO Glover, C.A., Absolute colligative property methods, in Polymer Molecular Weights,
Marcel Dekker, New York, 1975, Pt. 1, 79.
76LIU Liu, D.D. and Prausnitz, J.M, Solubilities of gases and volatile liquids in polyethylene and
15, 330, 1976.
76NES Nesterov, A.E. and Lipatov, J.S., Obrashchennaya Gasovaya Khromatografiya v Termodi-
namike Polimerov, Naukova Dumka, Kiev, 1976.
1982.
84HEM Hemminger, W. and Höhne, G., Calorimetry: Fundamentals and Practice, Verlag Chemie,
Weinheim, 1984.
87ADA Adams, E.T., Osmometry, in Encyclopedia of Polymer Science and Engineering, Vol. 10,
1987.
88NES Nesterov, A.E., Obrashchennaya Gasovaya Khromatografiya Polimerov, Naukova Dumka,
Kiev, 1988.
89LLO Lloyd, D.R., Ward, T.C., Schreiber, H.P., and Pizana, C.C., Eds., Inverse Gas Chromato-
graphy, ACS Symposium Series 391, American Chemical Society, Washington, 1989.
89VIL Vilcu, R. and Leca, M., Polymer Thermodynamics by Gas Chromatography, Elsevier,
Amsterdam, 1989.
____________________________________________________________________________________
90RAE Raetzsch, M.D. and Wohlfarth, Ch., Continuous thermodynamics of copolymer systems,
Adv. Polym. Sci., 98, 49, 1990.
91MAY Mays, J.W. and Hadjichristidis, N., Measurement of molecular weight of polymers by
osmometry, in Modern Methods of Polymer Characterization, Barth, H.G. and Mays, J.W.,
Eds., J. Wiley & Sons, New York, 1991, 201.
91MU1 Munk, P., Polymer characterization using inverse gas chromatography, in Modern Methods
of Polymer Characterization, Barth, H.G. and Mays, J.W., Eds., J. Wiley & Sons, New
York, 1991, 151.
91MU2 Munk, P., Polymer characterization using the ultracentrifuge, in Modern Methods of
Polymer Characterization, Barth, H.G. and Mays, J.W., Eds., J. Wiley & Sons, New York,
1991, 271.
92HAR Harding, S.E., Rowe, A.J., and Horton, J.C., Analytical Ultracentrifugation in Biochemistry
and Polymer Science, Royal Society of Chemistry, Cambridge, 1992.
94MAR Marsh, K.N., Ed., Experimental Thermodynamics, Volume 4, Solution Calorimetry,
Blackwell Science, Oxford, 1994.
94WOH Wohlfarth, Ch., Vapour-Liquid Equilibrium Data of Binary Polymer Solutions: Physical
95GUP Gupta, R.B., and Prausnitz, J.M., Vapor-liquid equilibria of copolymer + solvent and
homopolymer + solvent binaries: new experimental data and their correlation, J. Chem.
Eng. Data, 40, 784, 1995.
97KOL Kolb, B. and Ettre, L.S., Static Headspace Gas Chromatography: Theory and Practice,
Wiley-VCH, Weinheim, 1997.
Chem. Rev., 99, 565, 1999.
2000WOH Wohlfarth, Ch., Methods for the measurement of solvent activity of polymer solutions, in
OF BINARY COPOLYMER SOLUTIONS
2.1. Partial solvent vapor pressures or solvent activities for copolymer

solutions
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
21.0 wt% acrylonitrile AN-B/21w 95GUP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
Copolymer (B) Mn/ M w/ M η/ Further information
g/mol g/mol g/mol
_____________________________________________________________________________
AN-B/21w Sci. Polym. Products, catalog #523
_____________________________________________________________________________
Experimental VLE data:

_____________________________________________________________________________

T/K = 333.15
wB 0.989 0.974 0.935 0.915 0.888 0.813
PA/kPa 6.8 13.7 26.1 30.1 34.1 39.3
____________________________________________________________________________________

solvent (A): cyclohexane C6H12 110-82-7
T/K = 333.15
wB 0.823 0.824 0.790 0.784 0.717
PA/kPa 35.6 35.7 38.1 39.7 43.1

solvent (A): n-hexane C6H14 110-54-3
T/K = 333.15
wB 0.975 0.956 0.918 0.896 0.866 0.830 0.764 0.749
PA/kPa 12.9 25.6 38.8 44.5 50.8 57.5 63.7 64.9

solvent (A): n-octane C8H18 111-65-9
T/K = 333.15
wB 0.964 0.948 0.936 0.921 0.889 0.842
PA/kPa 2.90 4.19 5.08 5.91 6.91 8.41

solvent (A): n-pentane C5H12 109-66-0
T/K = 333.15
wB 0.984 0.979 0.967 0.954 0.945 0.930 0.922 0.911
PA/kPa 36.0 46.8 65.5 84.0 97.3 113.3 124.8 137.6

T/K = 333.15
wB 0.977 0.957 0.935 0.909 0.852 0.794
PA/kPa 6.7 13.3 18.3 23.2 32.5 37.9

T/K = 333.15
wB 0.998 0.983 0.974 0.963
PA/kPa 12.4 25.1 36.0 43.3
____________________________________________________________________________________

T/K = 333.15
wB 0.986 0.975 0.973 0.968 0.964 0.956 0.950 0.945
PA/kPa 26.9 53.5 64.7 77.5 89.7 101.7 115.7 130.1

solvent (A): trichloromethane CHCl3 67-66-3
T/K = 333.15
wB 0.920 0.830 0.828 0.738 0.628 0.576 0.515 0.437
PA/kPa 13.6 26.8 26.9 39.6 52.8 59.9 66.3 73.3

T/K = 333.15
wB 0.979 0.953 0.889 0.856 0.818 0.707
PA/kPa 6.8 13.7 26.1 30.1 34.1 39.3

T/K = 333.15
wB 0.993 0.989 0.985 0.976 0.968 0.953 0.940 0.909
PA/kPa 13.7 19.1 19.6 26.4 32.0 35.6 39.7 43.1

T/K = 333.15
wB 0.982 0.980 0.971 0.967 0.959 0.956 0.938 0.938
PA/kPa 12.9 25.6 38.8 44.5 50.8 57.5 63.7 64.9

T/K = 333.15
wB 0.993 0.990 0.987 0.985 0.979 0.974
PA/kPa 2.85 4.19 5.08 5.91 6.91 8.41
____________________________________________________________________________________

T/K = 333.15
wB 0.991 0.987 0.981 0.978 0.978 0.974 0.973 0.966
PA/kPa 36.0 46.8 65.5 84.0 97.3 113.3 124.8 137.6
_____________________________________________________________________________
Copolymers from acrylonitrile and styrene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
25.0 wt% acrylonitrile S-AN/25w 98SCH
28.0 wt% acrylonitrile S-AN/28w 96WO2
30.0 wt% acrylonitrile S-AN/30w 95GUP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-AN/25w 90000 147000 Bayer AG Leverkusen, Ger.
S-AN/28w 46000 100000 synthesized in the laboratory
S-AN/30w 185000 Sci. Polym. Products, catalog #495
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-AN/25w 98SCH

solvent (A): toluene C7H8 108-88-3
T/K = 313.15
wB 0.399 0.447 0.497 0.522 0.601 0.638 0.699 0.747 0.799
PA/PAs 0.999 0.991 0.954 0.952 0.902 0.869 0.796 0.745 0.644
wB 0.848 0.894 0.952
PA/PAs 0.544 0.476 0.331
____________________________________________________________________________________

T/K = 323.15
wB 0.352 0.448 0.499 0.524 0.603 0.643 0.702 0.750 0.802
PA/PAs 0.996 0.986 0.934 0.918 0.877 0.848 0.779 0.717 0.628
wB 0.852 0.897 0.955
PA/PAs 0.529 0.454 0.337

T/K = 333.15
wB 0.353 0.449 0.500 0.525 0.604 0.644 0.704 0.751 0.803
PA/PAs 0.989 0.979 0.924 0.909 0.872 0.843 0.776 0.711 0.625
wB 0.853 0.899 0.956
PA/PAs 0.523 0.446 0.332
copolymer (B): S-AN/28w 96WO2, 97WO1

solvent (A): benzene C6H6 71-43-2
T/K = 343.15
wB 0.8339 0.8053 0.7876 0.7501 0.7207 0.6967 0.6587 0.6384 0.6198
PA/PAs 0.6433 0.7080 0.7415 0.8036 0.8454 0.8752 0.9097 0.9251 0.9369
wB 0.5892 0.5564
PA/PAs 0.9598 0.9724

solvent (A): propylbenzene C9H12 103-65-1
T/K = 398.15
wB 0.8270 0.8132 0.8018 0.7781 0.7649 0.7346 0.7179 0.6834
PA/PAs 0.7559 0.7834 0.8033 0.8423 0.8618 0.8991 0.9127 0.9372

T/K = 343.15
wB 0.7962 0.7433 0.7192 0.6960 0.6607 0.6482 0.6199 0.5856
PA/PAs 0.7257 0.8126 0.8458 0.8735 0.9090 0.9172 0.9377 0.5856
____________________________________________________________________________________

T/K = 373.15
wB 0.8003 0.7632 0.7375 0.7157 0.7093 0.6831 0.6686 0.6388 0.6056
PA/PAs 0.7071 0.7752 0.8147 0.8410 0.8523 0.8817 0.8951 0.9208 0.9427
wB 0.5883 0.5654
PA/PAs 0.9567 0.9690

solvent (A): o-xylene C8H10 95-47-6
T/K = 398.15
wB 0.7606 0.7371 0.7107 0.6838 0.6593 0.6276 0.5960 0.5586
PA/PAs 0.8048 0.8389 0.8722 0.9008 0.9228 0.9459 0.9642 0.9800

solvent (A): m-xylene C8H10 108-38-3
T/K = 398.15
wB 0.7977 0.7611 0.7428 0.7167 0.6884 0.6460 0.6198 0.5894
PA/PAs 0.7462 0.8162 0.8387 0.8690 0.9010 0.9405 0.9510 0.9701

solvent (A): p-xylene C8H10 106-42-3
T/K = 373.15
wB 0.7632 0.7416 0.7204 0.6997 0.6566 0.6223 0.5917
PA/PAs 0.8081 0.8378 0.8736 0.8883 0.9347 0.9547 0.9714

T/K = 398.15
wB 0.8082 0.7896 0.7534 0.7263 0.7006 0.6731 0.6519 0.6292 0.6028
PA/PAs 0.7188 0.7537 0.8142 0.8528 0.8828 0.9101 0.9286 0.9439 0.9609

T/K = 423.15
wB 0.7738 0.7547 0.7259 0.6931 0.6674 0.6492 0.6211
PA/PAs 0.7769 0.8077 0.8483 0.8846 0.9106 0.9253 0.9444
____________________________________________________________________________________
copolymer (B): S-AN/30w 95GUP

solvent (A): 1,2-dichloroethane C2H4Cl2 107-06-2
T/K = 343.15
wB 0.861 0.804 0.757 0.719 0.704 0.661
PA/kPa 30.8 36.5 40.7 43.9 46.0 49.1
copolymer (B): S-AN/30w 95GUP

T/K = 353.15
wB 0.749 0.721 0.652 0.624 0.611
PA/kPa 45.7 50.1 57.6 59.5 60.7
_____________________________________________________________________________
Copolymers from p-bromostyrene and p-methylstyrene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
p-Bromostyrene/p-methylstyrene copolymer
16.7 mol% p-bromostyrene pBS-pMS/17x 63COR
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
pBS-pMS/17x 5000-10000 synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): pBS-pMS/17x 63COR

T/K = 293.20
ϕB 0.1643 0.2633 0.3444 0.4641 0.5449 0.6416
aA 0.9952 0.9865 0.9650 0.9259 0.8696 0.7859

T/K = 293.20
ϕB 0.1970 0.2792 0.3648 0.4799 0.5932 0.6473
aA 0.9952 0.9860 0.9649 0.9255 0.8708 0.7858

T/K = 293.20
ϕB 0.1857 0.2672 0.3696 0.4870 0.5755 0.6629
aA 0.9952 0.9865 0.9652 0.9250 0.8690 0.7855

T/K = 293.20
ϕB 0.1803 0.3066 0.3931 0.5074 0.5844 0.6742
aA 0.9952 0.9865 0.9650 0.9250 0.8680 0.7852

T/K = 293.20
ϕB 0.2088 0.3489 0.4095 0.5417 0.6147 0.7028
aA 0.9952 0.9868 0.9658 0.9256 0.8698 0.7859
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from butadiene and styrene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Butadiene/styrene copolymer
5.0 wt% styrene S-BR/05w 95GUP
23.0 wt% styrene S-BR/23w 95GUP
41.0 wt% styrene S-BR/41w 96WO1
45.0 wt% styrene S-BR/45w(1) 90IWA
45.0 wt% styrene S-BR/45w(1) 91IWA
45.0 wt% styrene S-BR/45w(2) 95GUP
(block copolymer without specification)
30.0 wt% styrene S-?-B/30w 90IWA
triblock copolymer
31.0 wt% styrene S-B-S/31w 99FRE
Polystyrene-b-polybutadiene(hydrogenated)-
b-polystyrene triblock copolymer
13.0 wt% styrene S-B(h)-S/13w 99FRE
31.0 wt% styrene S-B(h)-S/31w 99FRE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BR/05w Sci. Polym. Products, catalog #199
S-BR/23w Sci. Polym. Products, catalog #200
S-BR/41w 86300 181200 synthesized in the laboratory
S-BR/45w(1) 130430 600000 Sci. Polym. Products
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BR/45w(2) Sci. Polym. Products, catalog #201
S-?-B/30w 108000 140000 Sci. Polym. Products
S-?-B/77w 117650 200000 Denki Kagaku Industry
S-B-S/31w 111000
S-B(h)-S/13w 90000 synthesized in the laboratory
S-B(h)-S/31w 48000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-BR/05w 95GUP

T/K = 333.15
wB 0.848 0.811 0.767 0.724 0.677
PA/kPa 24.8 29.5 33.7 37.6 40.7

solvent (A): 2-propanone C3H6O 67-64-1
T/K = 323.15
wB 0.944 0.933 0.928 0.933 0.934 0.922 0.921 0.920 0.909
PA/kPa 41.5 45.3 46.5 47.2 47.3 51.1 52.3 53.3 55.2
wB 0.885 0.890 0.880
PA/kPa 59.6 59.7 61.3

T/K = 308.15
wB 0.957 0.901 0.816 0.681 0.584 0.487
PA/kPa 0.93 2.08 3.04 4.36 4.83 5.45
____________________________________________________________________________________

T/K = 323.15
wB 0.960 0.894 0.796 0.728 0.659 0.543 0.511 0.463 0.420
PA/kPa 8.5 16.3 25.5 31.6 38.3 45.5 47.6 50.0 53.7
wB 0.362
PA/kPa 56.4

T/K = 296.65
wB 0.803 0.724 0.672
PA/kPa 7.64 9.03 10.03

T/K = 333.15
wB 0.864 0.832 0.792 0.756 0.713
PA/kPa 24.8 29.5 33.7 37.6 40.7

T/K = 343.15
wB 0.890 0.838 0.738
PA/kPa 48.8 61.5 75.2

T/K = 333.15
wB 0.954 0.945 0.930 0.922 0.911
PA/kPa 84.0 97.3 113.3 124.8 137.6

T/K = 333.15
wB 0.979 0.963 0.938 0.908 0.872 0.853 0.817 0.769
PA/kPa 26.4 40.7 54.8 68.5 81.3 84.8 91.5 97.9
____________________________________________________________________________________

T/K = 323.15
wB 0.951 0.939 0.929 0.925 0.915 0.912 0.909 0.900 0.875
PA/kPa 36.3 41.5 45.3 46.5 51.1 52.3 53.3 55.2 59.6
wB 0.880 0.870
PA/kPa 59.7 61.3

T/K = 308.15
wB 0.971 0.969 0.968 0.963 0.963 0.962
PA/kPa 0.93 2.08 3.04 4.36 4.83 5.45

T/K = 323.15
wB 0.954 0.889 0.794 0.730 0.662 0.551 0.518 0.486 0.434
PA/kPa 8.5 16.3 25.5 31.6 38.3 45.5 47.6 50.0 53.7
wB 0.379
PA/kPa 56.4
copolymer (B): S-BR/41w 96WO1, 97WO1

T/K = 343.15
wB 0.7998 0.7553 0.7207 0.6864 0.6485 0.6039 0.5517 0.4916 0.4326
PA/PAs 0.5091 0.5897 0.6418 0.6910 0.7388 0.7876 0.8357 0.8798 0.9143

T/K = 343.15
wB 0.7831 0.7564 0.7197 0.6712 0.6394 0.6008 0.5586 0.5234
PA/PAs 0.6522 0.6966 0.7491 0.8083 0.8385 0.8693 0.8985 0.9176
____________________________________________________________________________________

solvent (A): ethylbenzene C8H10 100-41-4
T/K = 373.15
wB 0.7917 0.7604 0.7285 0.6799 0.6412 0.5996 0.5616 0.5173 0.4845
PA/PAs 0.5829 0.6358 0.6841 0.7471 0.7897 0.8271 0.8562 0.8854 0.9037

T/K = 398.15
wB 0.6887 0.6528 0.6293 0.5818 0.5495 0.5106 0.4698
PA/PAs 0.7292 0.7736 0.7973 0.8390 0.8629 0.8876 0.9108

solvent (A): mesitylene C9H12 108-67-8
T/K = 398.15
wB 0.7694 0.7389 0.6908 0.6576 0.6232 0.5856 0.5407 0.5009
PA/PAs 0.6520 0.6982 0.7617 0.7987 0.8311 0.8610 0.8911 0.9107

T/K = 343.15
wB 0.7619 0.7198 0.6721 0.6276 0.5800 0.5317 0.4961 0.4533
PA/PAs 0.5825 0.6476 0.7125 0.7634 0.8103 0.8497 0.8753 0.9011

T/K = 373.15
wB 0.8168 0.7701 0.7387 0.6970 0.6319 0.5726 0.5063 0.4308
PA/PAs 0.4844 0.5704 0.6214 0.6833 0.7612 0.8178 0.8691 0.9143

T/K = 398.15
wB 0.8071 0.7593 0.7162 0.6784 0.6499 0.6075 0.5698 0.5201 0.4899
PA/PAs 0.5536 0.6388 0.7027 0.7503 0.7803 0.8216 0.8520 0.8884 0.9050
____________________________________________________________________________________
copolymer (B): S-BR/45w(2) 95GUP

T/K = 296.65
wB 0.824 0.747 0.699
PA/kPa 7.64 9.03 10.03

T/K = 333.15
wB 0.870 0.837 0.800 0.760 0.718
PA/kPa 24.8 29.5 33.7 37.6 40.7
copolymer (B): S-BR/45w(1) 90IWA

T/K = 373.15
wB 0.9717 0.9589 0.9452 0.9448 0.9248 0.9112 0.9022 0.8830 0.8390
PA/kPa 4.00 5.42 6.92 6.89 9.10 10.00 11.10 12.60 16.10
wB 0.8380 0.0000
PA/kPa 16.10 34.25

T/K = 403.15
wB 0.9791 0.9738 0.9723 0.9639 0.9587 0.9559 0.9539 0.9494 0.9407
PA/kPa 7.14 8.79 9.45 11.40 12.60 13.80 14.30 15.70 18.10
wB 0.9333 0.9332 0.9308 0.9241 0.9229 0.9110 0.9081 0.9036 0.8920
PA/kPa 19.70 20.50 20.40 22.00 22.20 25.60 26.50 27.10 29.60
wB 0.8850 0.8790 0.8450 0.0000
PA/kPa 31.30 32.00 38.70 85.55

T/K = 343.15
wB 0.897 0.845 0.751
PA/kPa 48.8 61.5 75.2
____________________________________________________________________________________

solvent (A): n-nonane C9H20 111-84-2
T/K = 373.15
wB 0.9832 0.9516 0.9428 0.9308 0.9093 0.9082 0.8820 0.8700 0.8460
PA/kPa 2.87 6.45 7.36 8.51 10.20 10.20 12.00 12.70 14.00
wB 0.8270 0.8260 0.0000
PA/kPa 14.90 14.90 20.72

T/K = 403.15
wB 0.9819 0.9647 0.9589 0.9468 0.9286 0.9171 0.9098 0.8960 0.8820
PA/kPa 6.86 12.10 13.80 17.40 21.40 24.10 25.40 28.00 30.50
wB 0.8520 0.8290 0.0000
PA/kPa 35.00 37.40 55.85

T/K = 333.15
wB 0.978 0.978 0.974 0.973 0.966
PA/kPa 84.0 97.3 113.3 124.8 137.6

T/K = 323.15
wB 0.954 0.939 0.926 0.922 0.926 0.929 0.912 0.908 0.905
PA/kPa 36.3 41.5 45.3 46.5 47.2 47.3 51.1 52.3 53.3
wB 0.895 0.863 0.870 0.859
PA/kPa 55.2 59.6 59.7 61.3

T/K = 333.15
wB 0.956 0.931 0.899 0.860 0.837 0.803 0.742
PA/kPa 40.7 54.8 68.5 81.3 84.8 91.5 97.9
____________________________________________________________________________________

T/K = 323.15
wB 0.957 0.893 0.795 0.728 0.657 0.537 0.500 0.466 0.408
PA/kPa 8.5 16.3 25.5 31.6 38.3 45.5 47.6 50.0 53.7
wB 0.350
PA/kPa 56.4
copolymer (B): S-?-B/30w 90IWA

T/K = 373.15
wB 0.9704 0.9528 0.9240 0.9098 0.9022 0.8760 0.8550 0.8360 0.8130
PA/kPa 3.87 5.83 8.79 10.00 10.70 13.00 14.80 16.10 17.80
wB 0.0000
PA/kPa 34.25

T/K = 403.15
wB 0.9752 0.9692 0.9643 0.9582 0.9533 0.9509 0.9409 0.9368 0.9270
PA/kPa 7.93 9.73 11.10 12.30 13.80 14.70 17.10 18.20 20.40
wB 0.9196 0.9145 0.9055 0.9042 0.8950 0.8860 0.8700 0.8600 0.8510
PA/kPa 22.20 23.50 25.60 25.70 27.90 29.60 33.00 34.80 37.10
wB 0.8340 0.0000
PA/kPa 39.70 85.55

T/K = 373.15
wB 0.9801 0.9673 0.9506 0.9489 0.9291 0.9229 0.9076 0.8970 0.8830
PA/kPa 2.81 4.28 5.95 6.17 7.85 8.44 9.57 10.20 11.30
wB 0.8690 0.8470 0.8360 0.0000
PA/kPa 12.00 13.20 13.60 20.72
____________________________________________________________________________________

T/K = 403.15
wB 0.9867 0.9750 0.9584 0.9459 0.9294 0.9248 0.9224 0.9032 0.8950
PA/kPa 4.62 8.12 12.70 15.90 20.20 20.80 21.40 25.30 26.80
wB 0.8720 0.8700 0.8600 0.8400 0.0000
PA/kPa 30.60 30.70 32.40 34.90 55.85

T/K = 373.15
wB 0.9780 0.9693 0.9614 0.9520 0.9319 0.9266 0.9140 0.8980 0.8810
PA/kPa 3.85 4.85 5.81 7.17 9.10 9.69 11.10 12.60 14.70
wB 0.8690 0.8460 0.8400 0.0000
PA/kPa 15.20 17.10 17.60 34.25

T/K = 403.15
wB 0.9744 0.9685 0.9572 0.9461 0.9402 0.9358 0.9354 0.9232 0.9213
PA/kPa 10.00 11.80 14.70 18.20 20.00 21.00 21.60 24.30 25.00
wB 0.9026 0.9004 0.8940 0.8780 0.8560 0.0000
PA/kPa 29.60 30.40 32.10 35.00 40.80 85.55

T/K = 373.15
wB 0.9847 0.9581 0.9514 0.9344 0.9275 0.9195 0.9037 0.8820 0.8490
PA/kPa 3.41 7.32 7.88 10.20 10.90 11.30 12.80 14.40 16.40
wB 0.8480 0.0000
PA/kPa 16.40 20.72

T/K = 403.15
wB 0.9842 0.9765 0.9579 0.9578 0.9442 0.9429 0.9330 0.9120 0.9082
PA/kPa 7.10 10.90 17.40 17.90 22.00 22.70 25.40 30.60 31.50
continue
____________________________________________________________________________________
continue
wB 0.8780 0.8620 0.8300 0.0000
PA/kPa 36.90 39.90 44.20 55.85
copolymer (B): S-B-S/31w 99FRE

T/K = 323.85
wB 0.9877 0.9866 0.9674 0.9627 0.9618 0.9614 0.9607 0.9539 0.9485
aA 0.0533 0.0543 0.1324 0.1488 0.1536 0.1529 0.1568 0.1766 0.1988
wB 0.9393 0.9373 0.9296 0.9131 0.9097 0.8989 0.8955 0.8857 0.8753
aA 0.2288 0.2358 0.2612 0.3128 0.3314 0.3539 0.3563 0.3886 0.4153
wB 0.8655 0.8625 0.8581 0.8508 0.8459 0.8414 0.8381 0.8352 0.8242
aA 0.4398 0.4606 0.4569 0.4745 0.4854 0.4948 0.5035 0.5092 0.5327
wB 0.8198 0.8198 0.8196
aA 0.5424 0.5424 0.5430

T/K = 348.15
wB 0.9820 0.9678 0.9530 0.9542 0.9246 0.9256 0.9260 0.8773 0.8810
aA 0.0790 0.1282 0.1861 0.1832 0.2880 0.2805 0.2805 0.4209 0.4129
wB 0.8815 0.7972
aA 0.4112 0.5942

T/K = 373.15
wB 0.9779 0.9481 0.9197 0.9167 0.8804
aA 0.0915 0.1993 0.2907 0.2899 0.4042

T/K = 393.15
wB 0.9845 0.9851 0.9850 0.9767 0.9765 0.9768 0.9628 0.9643 0.9489
aA 0.0513 0.0513 0.0512 0.0778 0.0778 0.0780 0.1198 0.1192 0.1666
wB 0.9492 0.9487 0.9486 0.9488 0.9255 0.9266 0.9264 0.8973 0.8972
aA 0.1661 0.1657 0.1660 0.1664 0.2324 0.2327 0.2326 0.3173 0.3166
wB 0.8920 0.8952 0.8954 0.8973
aA 0.3046 0.3186 0.3159 0.3166
____________________________________________________________________________________
copolymer (B): S-B(h)-S/13w 99FRE

T/K = 324.35
wB 0.9963 0.9943 0.9929 0.9910 0.9888 0.9869 0.9868 0.9855 0.9839
aA 0.0127 0.0204 0.0247 0.0312 0.0388 0.0474 0.0455 0.0484 0.0543
wB 0.9807 0.9800 0.9710 0.9662 0.9555 0.9462 0.9460 0.9460 0.9452
aA 0.0639 0.0666 0.0951 0.1102 0.1433 0.1732 0.1733 0.1712 0.1710
wB 0.9404 0.9332 0.9129 0.9123 0.9118 0.9086 0.9078 0.9076 0.8396
aA 0.1901 0.2098 0.2735 0.2841 0.2761 0.2833 0.2849 0.2874 0.5550
wB 0.8381
aA 0.5602
copolymer (B): S-B(h)-S/31w 99FRE

T/K = 393.15
wB 0.9935 0.9934 0.9906 0.9893 0.9891 0.9875 0.9867 0.9846 0.9810
aA 0.0241 0.0247 0.0347 0.0400 0.0390 0.0441 0.0472 0.0556 0.0716
wB 0.9771 0.9702 0.9670 0.9666 0.9635 0.9521 0.9499 0.9479 0.9472
aA 0.0854 0.1088 0.1139 0.1156 0.1307 0.1748 0.1748 0.1782 0.1774
wB 0.9409 0.9406 0.9294 0.9289 0.9139 0.9135 0.9084 0.9052 0.8832
aA 0.1938 0.1966 0.2323 0.2339 0.2772 0.2785 0.2885 0.2967 0.3551
wB 0.8830 0.8818 0.8808 0.8429 0.7884 0.7880 0.7410 0.7373 0.7368
aA 0.3557 0.3570 0.3600 0.4446 0.5502 0.5491 0.6734 0.6751 0.6738
_____________________________________________________________________________
Copolymers from dimethylsiloxane and methylphenylsiloxane
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Dimethylsiloxane/methylphenylsiloxane copolymer
15 wt% methylphenylsiloxane DMS-MPS/15w 98SCH
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
DMS-MPS/15w 9100 41200 Dow Corning Corp., Midland, USA
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): DMS-MPS/15w 98SCH

solvent (A): anisole C7H8O 100-66-3
T/K = 313.15
wB 0.309 0.408 0.451 0.506 0.562 0.606 0.640 0.633 0.754
PA/PAs 0.997 0.987 0.988 0.987 0.963 0.934 0.920 0.886 0.807
wB 0.798 0.850 0.896 0.949
PA/PAs 0.734 0.631 0.505 0.301

T/K = 323.15
wB 0.406 0.449 0.503 0.558 0.604 0.638 0.631 0.753 0.798
PA/PAs 0.992 0.997 0.987 0.968 0.950 0.918 0.926 0.813 0.733
wB 0.850 0.896 0.949
PA/PAs 0.625 0.499 0.298

T/K = 333.15
wB 0.306 0.404 0.447 0.501 0.556 0.602 0.636 0.629 0.752
PA/PAs 0.991 0.980 0.981 0.976 0.957 0.944 0.918 0.919 0.804
wB 0.797 0.849 0.896 0.948
PA/PAs 0.724 0.610 0.486 0.289
____________________________________________________________________________________

T/K = 343.15
wB 0.306 0.404 0.447 0.501 0.556 0.602 0.636 0.629 0.752
PA/PAs 0.988 0.977 0.971 0.966 0.942 0.925 0.896 0.903 0.793
wB 0.797 0.849 0.896 0.948
PA/PAs 0.714 0.606 0.479 0.284

T/K = 305.15
wB 0.400 0.452 0.499 0.549 0.595 0.649 0.699 0.752 0.799
PA/PAs 0.971 0.966 0.956 0.948 0.935 0.920 0.915 0.891 0.858
wB 0.849 0.899 0.948
PA/PAs 0.785 0.683 0.489

T/K = 309.15
wB 0.401 0.453 0.500 0.551 0.596 0.651 0.701 0.753 0.801
PA/PAs 0.980 0.973 0.976 0.961 0.947 0.932 0.880 0.846 0.823
wB 0.850 0.900 0.949
PA/PAs 0.731 0.622 0.436

T/K = 314.15
wB 0.402 0.454 0.501 0.552 0.597 0.652 0.702 0.754 0.802
PA/PAs 0.976 0.970 0.968 0.949 0.927 0.916 0.884 0.844 0.797
wB 0.851 0.901 0.950
PA/PAs 0.718 0.599 0.411

T/K = 318.15
wB 0.404 0.456 0.502 0.553 0.599 0.653 0.703 0.756 0.804
PA/PAs 0.975 0.975 0.963 0.947 0.923 0.886 0.862 0.823 0.776
continue
____________________________________________________________________________________
continue
wB 0.853 0.902 0.951
PA/PAs 0.693 0.575 0.374

T/K = 322.15
wB 0.407 0.458 0.504 0.555 0.601 0.655 0.705 0.758 0.805
PA/PAs 0.958 0.960 0.957 0.947 0.915 0.887 0.859 0.807 0.765
wB 0.854 0.903 0.952
PA/PAs 0.687 0.565 0.372
_____________________________________________________________________________
Copolymers from ethylene and vinyl acetate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
9.0 wt% vinyl acetate E-VA/09w 95GUP
15.6 wt% vinyl acetate E-VA/16w(1) 73BEL
39.4 wt% vinyl acetate E-VA/39w 75BOB
41.4 wt% vinyl acetate E-VA/41w 76KIE
42.6 wt% vinyl acetate E-VA/43w 76KIE
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-VA/09w Sci. Polym. Products, catalog #506
E-VA/16w(1) 2774 fractionated in the laboratory
E-VA/25w 20000 88000 Sci. Polym. Products, catalog #245
E-VA/39w 3650 fractionated in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-VA/16w(1) 73BEL

T/K = 373.15
ϕB 0.0000 0.0982 0.1729 0.1895 0.2573 0.2839 0.3228 0.3641
PA/Torr 1335.0 1327.9 1315.8 1313.0 1294.9 1287.9 1273.6 1254.1

T/K = 373.15
ϕB 0.0000 0.0675 0.1307 0.1907 0.2503 0.3082 0.3310 0.3791 0.4668
PA/Torr 1335.0 1331.6 1324.9 1315.1 1300.7 1284.4 1276.5 1255.0 1206.0

T/K = 373.15
ϕB 0.0000 0.0775 0.1465 0.1884 0.2624 0.3308 0.3817
PA/Torr 1335.0 1331.0 1323.3 1316.8 1300.3 1278.4 1257.8
____________________________________________________________________________________

T/K = 373.15
ϕB 0.0000 0.0976 0.1647 0.2072 0.2609 0.3142 0.3670 0.3971
PA/Torr 1335.0 1330.8 1323.6 1317.0 1307.9 1295.0 1286.7 1260.0
copolymer (B): E-VA/39w 75BOB

T/K = 303.15
wB 0.000 0.244 0.292 0.333 0.498 0.516 0.536 0.590 0.622
PA/Torr 118.5 118.3 118.2 116.4 110.1 106.5 105.0 101.6 95.5
wB 0.739 0.760 0.835 0.872
PA/Torr 82.0 79.2 69.7 59.7

T/K = 323.15
wB 0.000 0.157 0.224 0.259 0.279 0.306 0.336 0.392 0.485
PA/Torr 269.20 268.90 267.20 265.90 266.25 261.95 259.45 254.00 233.80
wB 0.489 0.646 0.719 0.848 0.870
PA/Torr 215.40 210.10 189.80 167.70 155.15

T/K = 303.15
wB 0.000 0.247 0.299 0.318 0.349 0.396 0.415 0.478 0.497
PA/Torr 118.50 118.20 117.40 117.70 116.90 115.95 114.10 110.75 109.55
wB 0.518 0.622 0.672 0.712 0.779
PA/Torr 107.50 96.20 89.00 85.65 77.15

T/K = 323.15
wB 0.000 0.149 0.224 0.336 0.427 0.513 0.559 0.618 0.665
PA/Torr 269.20 269.15 261.90 257.05 242.15 220.85 207.05 193.25 181.80
wB 0.758 0.801 0.802 0.888 0.907
PA/Torr 150.90 121.35 124.35 106.00 70.20
____________________________________________________________________________________

T/K = 323.15
wB 0.000 0.307 0.325 0.348 0.435 0.495 0.527 0.557 0.621
PA/Torr 269.20 265.80 258.25 256.10 243.20 234.60 227.00 217.90 203.35
wB 0.692 0.730 0.749
PA/Torr 176.40 161.40 151.70

T/K = 343.15
wB 0.000 0.360 0.457 0.506 0.516 0.563 0.584 0.593 0.615
PA/Torr 548.16 519.90 494.40 476.90 496.90 445.50 433.50 423.60 414.40
wB 0.647 0.674 0.679
PA/Torr 388.10 372.10 366.60
copolymer (B): E-VA/09w 95GUP

solvent (A): 1-butanol C4H10O 71-36-3
T/K = 353.15
wB 0.994 0.988 0.983 0.973 0.969 0.966 0.964
PA/kPa 2.7 5.2 8.0 10.8 12.3 13.9 15.2
copolymer (B): E-VA/41w 76KIE

solvent (A): butyl acetate C6H12O2 123-86-4
T/K = 323.15
wB 0.1771 0.2141 0.2897 0.3163 0.3655 0.4005 0.4623 0.5462
PA/Torr 41.80 40.30 38.00 36.80 34.80 33.80 31.30 28.00

T/K = 343.15
wB 0.1802 0.2374 0.2580 0.3315 0.3655 0.4387 0.4892 0.5773
PA/Torr 101.40 98.10 96.40 89.70 87.40 79.90 75.40 64.90
____________________________________________________________________________________

T/K = 363.15
wB 0.1866 0.2591 0.3132 0.3767 0.4165 0.4571 0.5355 0.6488
PA/Torr 219.80 209.60 201.10 190.00 181.50 175.20 158.30 134.80

T/K = 353.15
wB 0.860 0.772 0.762 0.723 0.700 0.631
PA/kPa 39.7 54.9 55.5 60.7 64.1 70.4

T/K = 353.15
wB 0.896 0.841 0.830 0.795 0.775 0.713
PA/kPa 39.7 54.9 55.5 60.7 64.1 70.4

T/K = 353.15
wB 0.974 0.919 0.877 0.867 0.844 0.809 0.758
PA/kPa 14.4 39.7 54.9 55.5 60.7 64.1 70.4

solvent (A): ethyl acetate C4H8O2 141-78-6
T/K = 303.15
wB 0.2430 0.2805 0.3496 0.3565 0.3804 0.4400 0.5301
PA/Torr 118.70 118.30 117.85 115.60 114.10 111.75 100.90

T/K = 323.15
wB 0.2554 0.2959 0.3241 0.3707 0.3817 0.4400 0.5704
PA/Torr 281.20 279.10 274.90 272.80 263.10 257.20 230.20
____________________________________________________________________________________

T/K = 343.15
wB 0.2302 0.2885 0.3372 0.3651 0.4539 0.5754 0.7667
PA/Torr 588.20 584.00 570.40 566.70 547.55 489.10 386.30

T/K = 303.15
wB 0.2143 0.2476 0.3038 0.3490 0.3654 0.4005 0.4487 0.4851
PA/Torr 118.00 117.20 116.20 115.20 111.50 109.90 108.00 104.20

T/K = 323.15
wB 0.2208 0.2558 0.3170 0.3655 0.3849 0.4224 0.4764 0.5195
PA/Torr 277.20 276.40 270.50 269.70 259.00 252.00 244.00 235.70

T/K = 343.15
wB 0.2475 0.2894 0.3003 0.3750 0.4399 0.5250 0.6110 0.6960
PA/Torr 575.80 569.50 568.10 547.00 529.30 488.50 499.30 392.10

solvent (A): methyl acetate C3H6O2 79-20-9
T/K = 303.15
wB 0.2654 0.3257 0.3549 0.3651 0.4123 0.5102 0.5610 0.6130
PA/Torr 265.75 261.75 260.05 258.75 255.25 240.75 232.15 215.75

T/K = 323.15
wB 0.2561 0.3030 0.3762 0.3879 0.4387 0.4829 0.6341 0.7189
PA/Torr 586.15 584.15 565.15 561.65 550.65 535.15 473.15 424.65
____________________________________________________________________________________

T/K = 303.15
wB 0.1951 0.2632 0.3190 0.3725 0.3951 0.4839 0.5363 0.5744
PA/Torr 265.75 263.95 262.75 258.25 257.05 244.75 234.15 220.75

T/K = 323.15
wB 0.2154 0.2744 0.3706 0.4313 0.4775 0.5564 0.6653 0.7667
PA/Torr 586.15 579.15 565.05 542.15 526.35 490.15 439.45 378.15

solvent (A): propyl acetate C5H10O2 109-60-4
T/K = 303.15
wB 0.1978 0.2330 0.2662 0.2815 0.3335 0.3865 0.4445 0.5075
PA/Torr 42.70 42.10 41.50 40.70 39.50 38.20 36.20 34.00

T/K = 323.15
wB 0.2048 0.2428 0.2671 0.2959 0.3249 0.3701 0.4180 0.4815
PA/Torr 111.70 108.60 106.80 104.50 101.90 96.20 91.20 84.50

T/K = 343.15
wB 0.2200 0.2644 0.2931 0.3387 0.3658 0.4052 0.4434 0.5749
PA/Torr 250.60 243.00 237.50 227.90 220.90 211.00 202.70 168.00

T/K = 363.15
wB 0.2523 0.3126 0.3569 0.4066 0.4427 0.5364 0.6073 0.8102
PA/Torr 501.60 481.40 463.30 443.40 427.30 381.80 344.80 245.80
____________________________________________________________________________________

T/K = 373.15
ϕB 0.0000 0.1459 0.2589 0.3228 0.3869 0.4668 0.4760 0.5356
PA/Torr 558.60 542.50 533.10 518.50 499.90 472.60 470.80 444.60

T/K = 373.15
ϕB 0.0000 0.0496 0.1272 0.2658 0.3599 0.3843 0.4432 0.5039
PA/Torr 558.60 557.20 552.10 543.60 515.60 510.50 491.60 475.70

T/K = 373.15
ϕB 0.0000 0.1209 0.2005 0.2113 0.3186 0.3711 0.4590 0.5357
PA/Torr 558.60 553.00 545.60 544.40 527.90 513.60 493.60 473.80

T/K = 373.15
ϕB 0.0000 0.1116 0.2037 0.2245 0.3482 0.3725 0.4318 0.4803 0.5302
PA/Torr 558.60 555.60 547.20 544.40 528.20 522.90 509.00 497.10 485.10

T/K = 303.15
wB 0.000 0.364 0.413 0.463 0.469 0.488 0.524 0.588 0.666
PA/Torr 41.65 41.00 41.10 40.00 39.05 40.20 38.50 36.65 28.15
wB 0.687
PA/Torr 30.05

T/K = 323.15
wB 0.000 0.389 0.437 0.501 0.520 0.571 0.642 0.661 0.668
PA/Torr 97.25 96.30 93.25 90.35 89.30 87.35 81.50 78.00 74.20
continue
____________________________________________________________________________________
continue
wB 0.718 0.730
PA/Torr 62.25 63.75

T/K = 303.15
wB 0.000 0.201 0.276 0.339 0.414 0.436 0.465 0.523 0.546
PA/Torr 41.65 40.20 40.00 38.85 39.50 38.20 37.50 36.90 36.00
wB 0.555 0.578 0.598 0.621
PA/Torr 37.40 35.50 33.90 32.30

T/K = 323.15
wB 0.000 0.237 0.311 0.328 0.438 0.495 0.515 0.568 0.604
PA/Torr 97.25 96.15 95.00 95.95 94.60 94.00 91.00 89.35 80.60
wB 0.630 0.673 0.694
PA/Torr 81.35 72.90 65.35

T/K = 323.15
wB 0.000 0.403 0.473 0.519 0.537 0.567 0.571 0.600 0.673
PA/Torr 92.00 85.38 80.78 77.83 77.30 74.50 72.13 71.00 62.00
wB 0.736 0.749 0.785
PA/Torr 52.60 51.50 44.90

T/K = 343.15
wB 0.000 0.375 0.448 0.504 0.543 0.619 0.649 0.652 0.672
PA/Torr 204.05 191.80 182.60 176.70 169.80 154.30 149.80 147.30 139.20
wB 0.694 0.728 0.765 0.795
PA/Torr 132.80 124.10 109.40 101.20
____________________________________________________________________________________

T/K = 363.15
wB 0.000 0.431 0.506 0.524 0.549 0.570 0.600 0.680 0.715
PA/Torr 407.00 370.70 348.70 346.00 339.00 323.80 315.30 277.40 251.00
wB 0.771
PA/Torr 220.00

T/K = 333.15
wB 0.969 0.933 0.896 0.853 0.832 0.804 0.784 0.747
PA/kPa 14.0 28.1 40.1 53.2 58.4 66.1 72.3 87.1

T/K = 333.15
wB 0.938 0.860 0.772 0.680 0.642 0.599 0.559 0.519
PA/kPa 13.9 26.7 39.9 53.2 59.9 66.5 73.1 79.3

T/K = 333.15
wB 0.902 0.798 0.697 0.602 0.561 0.523 0.488 0.448
PA/kPa 13.9 26.7 39.9 53.2 59.9 66.5 73.1 79.3

T/K = 333.15
wB 0.941 0.839 0.713 0.597 0.550 0.511 0.474 0.427
PA/kPa 13.9 26.7 39.9 53.2 59.9 66.5 73.1 79.3

T/K = 323.15
wB 0.000 0.157 0.298 0.363 0.376 0.381 0.457 0.503 0.628
PA/Torr 25.76 25.30 25.25 25.10 25.30 25.30 24.20 23.20 17.80
continue
____________________________________________________________________________________
continue
wB 0.630 0.643 0.730 0.817 0.852 0.867
PA/Torr 17.50 18.35 14.80 11.90 10.40 8.45

T/K = 343.15
wB 0.000 0.307 0.336 0.386 0.437 0.442 0.504 0.577 0.588
PA/Torr 60.82 60.60 59.60 58.10 56.30 55.50 51.00 48.20 46.50
wB 0.616 0.640 0.676 0.716 0.780
PA/Torr 45.25 43.30 42.00 39.80 35.55

T/K = 363.15
wB 0.000 0.380 0.479 0.487 0.581 0.676 0.724 0.790 0.800
PA/Torr 139.00 129.10 120.90 120.65 108.85 93.10 85.10 71.15 63.10

T/K = 373.15
ϕB 0.0000 0.1593 0.3009 0.3797 0.4441 0.4629 0.5091 0.5602
PA/Torr 242.1 237.5 226.9 218.4 209.0 206.1 196.6 186.1

T/K = 373.15
ϕB 0.0000 0.1767 0.2788 0.3282 0.3886 0.4585 0.5094 0.5728
PA/Torr 242.1 237.0 229.4 225.0 217.7 206.9 199.0 181.3

T/K = 373.15
ϕB 0.0000 0.1256 0.1878 0.2892 0.3569 0.4169 0.4525 0.5668
PA/Torr 242.1 239.4 236.5 228.9 223.7 214.9 201.6 189.2
____________________________________________________________________________________

T/K = 373.15
ϕB 0.0000 0.1573 0.2319 0.3007 0.3691 0.4466 0.5104 0.5857
PA/Torr 242.1 238.0 234.3 229.5 222.3 212.1 201.3 189.0

T/K = 323.15
wB 0.000 0.157 0.180 0.325 0.416 0.441 0.530 0.545 0.576
PA/Torr 32.25 31.95 32.20 32.00 31.00 29.85 27.05 26.76 25.00
wB 0.578 0.632
PA/Torr 25.80 23.20

T/K = 343.15
wB 0.000 0.241 0.297 0.317 0.420 0.464 0.542 0.578 0.640
PA/Torr 75.70 75.50 73.50 72.90 70.05 67.05 61.40 59.35 56.60
wB 0.660 0.745 0.762
PA/Torr 51.90 46.65 43.60

T/K = 343.15
wB 0.000 0.440 0.524 0.599 0.605 0.615 0.643 0.748 0.802
PA/Torr 75.70 67.85 62.40 57.60 56.70 55.50 54.30 42.70 36.20

T/K = 363.15
wB 0.000 0.450 0.489 0.549 0.577 0.630 0.690 0.737 0.760
PA/Torr 167.80 149.70 145.20 136.90 131.90 121.80 110.70 103.35 91.95
wB 0.812
PA/Torr 77.20
____________________________________________________________________________________

T/K = 323.15
wB 0.000 0.451 0.512 0.597 0.634 0.649 0.732 0.737 0.800
PA/Torr 32.25 28.60 26.85 24.45 23.05 22.75 19.30 18.30 14.95

T/K = 343.15
wB 0.000 0.390 0.477 0.575 0.597 0.637 0.655 0.764 0.814
PA/Torr 75.70 69.15 65.15 59.20 56.80 53.50 52.10 40.75 37.80

T/K = 363.15
wB 0.000 0.450 0.509 0.558 0.600 0.641 0.681 0.717 0.732
PA/Torr 167.80 149.70 142.95 135.90 127.50 120.80 114.80 104.00 109.70
wB 0.773 0.827
PA/Torr 89.40 70.00
_____________________________________________________________________________
Copolymers from ethylene oxide and tert-butyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(tert-butyl methacrylate)
diblock copolymer
49 mol% ethylene oxide EO-b-tBMA/49x 94WOH
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
Copolymer (B) Mn/ Further information
g/mol
_____________________________________________________________________________
EO-b-tBMA/49x 8200 (= 4000 + 4200) synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): EO-b-tBMA/49x 94WOH

T/K = 323.15
ψB 0.0000 0.4505 0.4669 0.4983 0.5444 0.5827 0.6132 0.6352 0.6469

PA/Torr 92.12 86.46 85.81 83.88 81.36 78.58 76.25 74.12 72.88
ψB 0.6715 0.7086 0.7461 0.7622 0.7877

PA/Torr 69.51 65.20 60.40 57.28 53.11
Comments: segment fraction is based on Bondi's volumina with rB = 80
copolymer (B): EO-b-tBMA/49x 94WOH

T/K = 343.75
ψB 0.0000 0.5091 0.5128 0.5663 0.5976 0.6185 0.6439 0.6590 0.6879

PA/Torr 208.40 184.38 182.95 175.99 170.90 167.55 162.12 158.66 151.55
ψB 0.6879 0.7232 0.7501 0.7501
PA/Torr 152.29 143.51 134.77 135.21

____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene oxide and methyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(methyl methacrylate)
diblock copolymer
51.7 mol% ethylene oxide EO-b-MMA/52x 86KRC
Poly(ethylene oxide)-b-poly(methyl methacrylate)-
61.0 mol% ethylene oxide EO-MMA-EO/61x 86KRC
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol
_____________________________________________________________________________
EO-b-MMA/52x 8900 (= 4600 + 4300) synthesized in the laboratory
EO-MMA-EO/61x 7860 (= 2400 + 3060 + 2400) synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): EO-b-MMA/52x 86KRC

T/K = 323.41
ψB 0.536 0.562 0.648 0.747 0.766
PA/kPa 10.626 10.226 9.613 7.933 7.773

continue
____________________________________________________________________________________
continue
T/K = 343.27
ψB 0.522 0.562 0.567 0.615 0.641 0.644
PA/kPa 23.878 22.638 22.691 21.878 21.252 20.132

T/K = 373.27
ψB 0.432 0.499 0.559 0.609 0.668 0.744 0.789 0.829 0.839
PA/kPa 69.671 67.697 64.822 62.333 59.430 54.473 50.826 47.979 46.333
ψB 0.867
PA/kPa 44.703
copolymer (B): EO-MMA-EO/61x 86KRC

T/K = 323.08
ψB 0.461 0.547 0.599 0.667 0.736 0.762
PA/kPa 11.457 10.626 10.226 9.613 8.706 8.399
Comments: segment fraction is based on Bondi's volumina with rB = 73.2

T/K = 343.17
ψB 0.535 0.573 0.583 0.629 0.654 0.697
PA/kPa 23.878 22.638 22.691 21.878 21.252 19.772

T/K = 373.26
ψB 0.554 0.612 0.628 0.665 0.685 0.729 0.785 0.876
PA/kPa 69.010 66.786 65.349 63.299 61.341 57.274 56.992 54.174

____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene oxide and propylene oxide
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
diblock copolymer
40.0 mol% propylene oxide EO-b-PO/40x 94WOH
58.0 wt% propylene oxide EO-b-PO/58w 89MOE

50.0 mol% propylene oxide EO-PO-EO/50x 94WOH
67.0 wt% propylene oxide EO-PO-EO/67w 89MOE

50.0 mol% propylene oxide PO-EO-PO/50x 94WOH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
EO-b-PO/40x 4240 4700 synthesized in the laboratory
EO-b-PO/58w 1700
EO-PO-EO/50x 10800 synthesized in the laboratory
EO-PO-EO/67w 1900
EO-PO-EO/87w 950
EO-PO-EO/93w 1800
PO-EO-PO/50x 10800 synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): EO-b-PO/40x 94WOH

T/K = 343.75
wB 0.1075 0.1277 0.1496 0.1859 0.2135 0.2315 0.2626 0.3182 0.5333
PA/PAs 0.9961 0.9959 0.9922 0.9892 0.9851 0.9839 0.9795 0.9637 0.9057
wB 0.6201 0.6639 0.6987 0.7048 0.7339 0.7655 0.7805 0.8040 0.8290
PA/PAs 0.8528 0.8135 0.7823 0.7750 0.7431 0.7072 0.6805 0.6532 0.6036
copolymer (B): EO-b-PO/58w 89MOE

solvent (A): tetrachloromethane CCl4 56-23-5
T/K = 303.15
wB 0.1004 0.2011 0.3019 0.4026 0.5038 0.6038 0.7032 0.8031 0.8971
aA 0.9830 0.9466 0.8884 0.8088 0.7088 0.5925 0.4620 0.3163 0.1704
copolymer (B): EO-PO-EO/50x 94WOH

T/K = 323.35
ψB 0.0000 0.4191 0.4480 0.4565 0.4877 0.5584 0.5834 0.6325 0.6906
PA/Torr 92.90 84.97 83.29 82.84 80.76 75.51 73.03 68.18 60.69
ψB 0.7184 0.7604 0.7856 0.8077
PA/Torr 57.08 50.74 46.62 42.56
copolymer (B): EO-PO-EO/50x 94WOH

T/K = 343.75
ψB 0.0000 0.4471 0.4635 0.4811 0.5474 0.5629 0.5818 0.6436 0.6717
PA/Torr 208.40 178.31 176.28 173.77 163.06 160.68 157.33 144.30 138.30
ψB 0.6986 0.7356 0.7556
PA/Torr 130.92 121.29 114.87

____________________________________________________________________________________
copolymer (B): EO-PO-EO/67w 89MOE

T/K = 303.15
wB 0.0995 0.1993 0.2994 0.3992 0.5004 0.6004 0.7021 0.8014 0.9032
aA 0.9919 0.9620 0.9114 0.8383 0.7416 0.6264 0.4910 0.3423 0.1755

T/K = 303.15
wB 0.0991 0.1987 0.2988 0.3986 0.4991 0.5998 0.7004 0.8007 0.9025
aA 0.9810 0.9453 0.8912 0.8162 0.7204 0.6054 0.4746 0.3281 0.1677

T/K = 303.15
wB 0.0991 0.1988 0.2986 0.3994 0.4998 0.6002 0.7009 0.8017 0.8981
aA 0.9861 0.9518 0.8964 0.8173 0.7179 0.6010 0.4674 0.3219 0.1712
copolymer (B): PO-EO-PO/50x 94WOH

T/K = 323.05
ψB 0.0000 0.3885 0.4300 0.4341 0.4682 0.5138 0.5604 0.5761 0.6269
PA/Torr 91.72 84.97 83.29 82.84 80.76 77.99 74.37 73.03 68.18
ψB 0.7369 0.7580 0.7838
PA/Torr 54.35 50.74 46.62
copolymer (B): PO-EO-PO/50x 94WOH

T/K = 342.65
ψB 0.0000 0.3794 0.4077 0.4516 0.5346 0.5629 0.6045 0.6148 0.6320
PA/Torr 200.10 181.02 178.31 173.77 163.06 158.86 152.05 150.12 147.40
ψB 0.6646 0.7063 0.7262 0.7695 0.7898
PA/Torr 140.64 130.92 125.98 114.87 108.41

____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene oxide and styrene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Polystyrene-b-poly(ethylene oxide) diblockcopolymer
blocks are not further specified S-b-EO/? 94WOH
Poly(ethylene oxide)-b-polystyrene-b-poly(ethylene oxide)

triblock copolymer
blocks are not further specified EO-S-EO/? 94WOH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-b-EO/? 45000 synthesized in the laboratory
EO-S-EO/? 45000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-b-EO/? 94WOH

T/K = 322.95
wB 0.0000 0.5773 0.6233 0.6728 0.6772 0.6981 0.7255 0.7387 0.7551

PA/Torr 91.33 82.40 79.77 76.10 75.51 73.38 70.90 69.71 67.48
wB 0.7842 0.7903 0.8222
PA/Torr 65.05 62.82 58.71
____________________________________________________________________________________
copolymer (B): S-b-EO/? 94WOH

T/K = 342.65
wB 0.0000 0.5628 0.5805 0.6064 0.6212 0.6532 0.6839 0.7077 0.7280
PA/Torr 200.10 182.80 179.74 178.06 175.64 170.71 165.13 160.98 156.29
wB 0.7385 0.7439 0.7467 0.7841 0.8155
PA/Torr 154.61 152.14 153.18 144.15 135.01
copolymer (B): EO-S-EO/? 94WOH

T/K = 323.35
wB 0.0000 0.5825 0.6191 0.6634 0.6865 0.7081 0.7210 0.7379 0.7592
PA/Torr 92.90 82.40 79.77 75.51 73.38 70.90 69.71 67.48 65.05
wB 0.7666 0.7704 0.8017 0.8269
PA/Torr 64.11 62.82 58.71 54.00
copolymer (B): EO-S-EO/? 94WOH

T/K = 343.75
wB 0.0000 0.5576 0.5759 0.5978 0.6141 0.6165 0.6390 0.6717 0.6863
PA/Torr 208.40 182.80 179.74 178.06 175.64 174.51 170.71 165.13 160.98
wB 0.7144 0.7144 0.7209 0.7343 0.7591 0.7856 0.8057
PA/Torr 154.61 156.29 153.18 152.14 144.15 135.01 127.11
_____________________________________________________________________________
Copolymers from 3-hydroxybutanoic acid and 3-hydroxypentanoic acid
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
3-Hydroxybutanoic acid/3-hydroxypentanoic acid copolymer
14 wt% 3-hydroxypentanoic acid HBA-HPA/14w 99WOH
22 wt% 3-hydroxypentanoic acid HBA-HPA/22w 99WOH
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
HBA-HPA/14w 153000 454000 Aldrich Chem.Co., catalog #34739-6
HBA-HPA/22w 188000 529000 Aldrich Chem.Co., catalog #34741-8
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): HBA-HPA/14w 99WOH

solvent (A): chlorobenzene C6H5Cl 108-90-7
T/K = 373.15
wB 0.7854 0.7495 0.7028 0.6566 0.6205 0.5746 0.5311 0.0000

PA/Pa 23780.0 26315.0 28811.7 30649.7 32403.5 33602.1 34540.3 38293.0

T/K = 388.15
wB 0.7312 0.6970 0.6627 0.6245 0.5989 0.5581 0.5128 0.4885 0.0000

PA/Pa 43492.0 46497.2 49109.0 51272.2 52716.4 54775.2 56514.4 57104.4 61455.4

T/K = 403.15
wB 0.8103 0.7537 0.7093 0.6687 0.6329 0.5908 0.5617 0.5113 0.0000

PA/Pa 53051.4 62960.1 68848.4 74082.4 77856.2 81961.9 83886.7 86475.3 94819.4
copolymer (B): HBA-HPA/w 99WOH

T/K = 373.15
wB 0.7663 0.7015 0.6779 0.6482 0.6289 0.5963 0.5340 0.4813 0.4220

PA/Pa 23538.7 27283.8 28260.2 29592.8 30354.9 31698.9 33418.3 34578.6 35777.2
____________________________________________________________________________________

T/K = 388.15
wB 0.0000 0.4112 0.5127 0.5600 0.6122 0.6354 0.6708 0.7046 0.7352

PA/Pa 61455.4 57983.2 54984.1 52833.2 50178.3 48605.1 45882.6 43246.2 40658.9
wB 0.7740 0.7970
PA/Pa 37039.2 34556.4

T/K = 403.15
wB 0.0000 0.5091 0.5586 0.5997 0.6354 0.6731 0.7182 0.7501 0.7877

PA/Pa 94819.4 85015.1 81582.6 78690.6 74376.3 71199.9 64941.8 60722.3 54435.8
_____________________________________________________________________________
Copolymers from styrene and butyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/butyl methacrylate copolymer
50.0 wt% styrene S-BMA/50w 95GUP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BMA/50w 105300 200000 Sci. Polym. Products, catalog #595
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-BMA/50w 95GUP

T/K = 333.15
wB 0.978 0.956 0.947 0.929 0.910 0.867 0.856 0.836 0.799
PA/kPa 23.5 43.3 51.6 60.3 67.6 81.7 85.3 90.4 95.9
wB 0.776 0.746
PA/kPa 98.7 100.4
copolymer (B): S-BMA/50w 95GUP

T/K = 343.15
wB 0.922 0.852 0.778 0.708 0.631 0.545 0.488
PA/kPa 13.3 26.4 40.1 53.6 65.5 78.8 86.0
_____________________________________________________________________________
Copolymers from styrene and docosyl maleate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/docosyl maleate copolymer
50.0 mol% styrene S-DCM/50x 97MIO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-DCM/50x 244500 293400 synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-DCM/50x 97MIO

T/K = 333.15
wB 0.976 0.967 0.943 0.929 0.906 0.881 0.846 0.809 0.765

PA/Torr 50.5 76.5 106.0 131.5 157.5 188.5 218.0 251.5 279.0
wB 0.710 0.630 0.000
PA/Torr 300.5 362.5 390.0

solvent (A): methanol CH4O 67-56-1
T/K = 333.15
wB 0.982 0.975 0.965 0.954 0.940 0.920 0.895 0.879 0.000

PA/Torr 128.0 190.0 247.5 296.0 354.5 400.5 457.5 489.5 635.0

T/K = 323.15
wB 0.974 0.965 0.957 0.945 0.927 0.904 0.874 0.846 0.799

PA/Torr 106.0 156.0 196.0 243.0 295.5 346.5 406.0 448.0 492.0
wB 0.769 0.000
PA/Torr 513.0 612.0

T/K = 343.15
wB 0.976 0.964 0.950 0.937 0.915 0.890 0.858 0.827 0.806

PA/Torr 230.0 317.5 408.5 494.5 587.0 679.5 786.0 857.5 896.0
wB 0.000
PA/Torr 1196.0
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and dodecyl maleate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/dodecyl maleate copolymer
50.0 mol% styrene S-DDM/50x 97MIO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-DDM/50x 177500 213000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-DDM/50x 97MIO

T/K = 333.15
wB 0.990 0.978 0.963 0.941 0.935 0.914 0.887 0.856 0.821

PA/Torr 50.5 76.5 106.0 131.5 157.5 188.5 218.0 251.5 279.0
wB 0.769 0.692 0.000
PA/Torr 300.5 362.5 390.0

T/K = 333.15
wB 0.976 0.966 0.950 0.931 0.907 0.835 0.808 0.000

PA/Torr 128.0 190.0 247.5 296.0 354.5 457.5 489.5 635.0
____________________________________________________________________________________

T/K = 323.15
wB 0.965 0.950 0.941 0.921 0.893 0.861 0.826 0.786 0.712

PA/Torr 106.0 156.0 196.0 243.0 295.5 346.5 406.0 448.0 492.0
wB 0.665 0.000
PA/Torr 513.0 612.0

T/K = 343.15
wB 0.978 0.961 0.947 0.927 0.898 0.863 0.817 0.778 0.746

PA/Torr 230.0 317.5 408.5 494.5 587.0 679.5 786.0 857.5 896.0
wB 0.000
PA/Torr 1196.0
_____________________________________________________________________________
Copolymers from styrene and isoprene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Polystyrene-b-polyisoprene-b-polystyrene triblock copolymer
15.0 wt% styrene S-I-S/15w 99FRE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-I-S/15w 159000 synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-I-S/15w 99FRE

T/K = 323.45
wB 0.9941 0.9922 0.9921 0.9883 0.9833 0.9826 0.9791 0.9709 0.9649

aA 0.0242 0.0298 0.0291 0.0449 0.0646 0.0661 0.0798 0.1097 0.1306
wB 0.9531 0.9209 0.8960 0.8959 0.8680 0.8679 0.8447 0.8376 0.8364
aA 0.1712 0.2792 0.3526 0.3529 0.4409 0.4412 0.5140 0.5505 0.5546
wB 0.8359 0.8195 0.8183
aA 0.5547 0.6841 0.6941

T/K = 323.55
wB 0.9916 0.9839 0.9806 0.9724 0.9581 0.9579 0.9445 0.9421 0.8907

aA 0.0325 0.0602 0.0700 0.1007 0.1496 0.1503 0.1948 0.2032 0.3552
wB 0.8894 0.8570 0.8158
aA 0.3606 0.4376 0.5434

T/K = 323.95
wB 0.9922 0.9921 0.9892 0.9891 0.9814 0.9785 0.9768 0.9723 0.9670

aA 0.0327 0.0321 0.0440 0.0439 0.0737 0.0854 0.0912 0.1086 0.1294
wB 0.9574 0.9492 0.9305 0.9231 0.9226 0.8606 0.7565
aA 0.1644 0.1925 0.2565 0.2791 0.2817 0.4405 0.6721
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and maleic anhydride
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/maleic anhydride copolymer
50.0 mol% styrene S-MAH/50x 97MIO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-MAH/50x 96700 116000
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-MAH/50x 97MIO

T/K = 333.15
wB 0.932 0.906 0.878 0.830 0.794 0.761 0.737 0.700 0.657

PA/Torr 127.5 175.5 229.5 286.5 339.0 393.0 434.5 484.5 505.0
wB 0.000
PA/Torr 635.0
copolymer (B): S-MAH/50x 97MIO

T/K = 323.15
wB 0.902 0.856 0.819 0.783 0.771 0.714 0.621 0.000

PA/Torr 215.5 278.0 336.5 389.0 400.0 454.0 489.0 612.0
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and methyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
44.0 wt% styrene S-MMA/44w 97WO2
50.0 wt% styrene S-MMA/50w 97TAN
Polystyrene-b-poly(methyl methacrylate) diblock copolymer

47.8 wt% polystyrene S-b-MMA/48w 98WOH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
Copolymer (B) Mn/ M w/ Further information
g/mol g/mol
_____________________________________________________________________________
S-MMA/44w 50600 85000 synthesized in the laboratory
S-MMA/50w 91000 100000 Polysciences Inc.
S-b-MMA/48w 18000 20500 ( = 9800-b-10700) Polysciences Inc.
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-MMA/44w 97WO2

T/K = 343.15
wB 0.0000 0.4664 0.5157 0.5797 0.6218 0.6566 0.7079 0.7615 0.8101

PA/Pa 73128.3 67029.4 65054.9 61786.1 59190.0 56652.5 52147.8 46421.8 40015.8

continue
____________________________________________________________________________________
continue
T/K = 373.15
wB 0.0000 0.5735 0.5905 0.6201 0.6489 0.6717 0.7056 0.7339 0.7653

PA/Pa 34300.5 31378.1 31172.3 30668.1 29937.5 29296.1 28253.3 27196.9 25704.8
wB 0.8097
PA/Pa 23190.6

T/K = 398.15
wB 0.0000 0.5496 0.6039 0.6328 0.6600 0.7014 0.7221 0.7575 0.7930

PA/Pa 74321.2 68866.0 67022.9 65618.2 64243.2 61493.4 59895.5 56603.0 52693.7
wB 0.8143
PA/Pa 49661.4

T/K = 398.15
wB 0.0000 0.6365 0.6783 0.7010 0.7321 0.7598 0.7834 0.8066 0.8293

PA/Pa 32215.7 29635.2 28936.1 28614.0 27708.7 26822.8 25982.0 24703.0 23085.8

T/K = 343.15
wB 0.0000 0.4775 0.5203 0.5674 0.6186 0.6607 0.7091 0.7520 0.7997

PA/Pa 27250.3 24991.3 24459.9 23707.8 22857.6 21868.4 20484.1 19042.5 17017.8

T/K = 373.15
wB 0.0000 0.5029 0.5586 0.6111 0.6508 0.6930 0.7366 0.7823

PA/Pa 74464.2 67256.1 65118.9 62594.6 59765.0 57464.0 53673.8 48736.8
____________________________________________________________________________________

T/K = 398.15
wB 0.0000 0.6109 0.6393 0.6708 0.6954 0.7112 0.7467 0.7799 0.8083

PA/Pa 69803.4 64896.2 63967.8 63179.1 61985.4 60987.2 58209.1 54893.4 51598.7
wB 0.8363
PA/Pa 47368.6
copolymer (B): S-MMA/50w 97TAN

T/K = 323.15
wB 0.919 0.879 0.826 0.754 0.679 0.000

PA/kPa 43.10 52.81 61.39 68.83 74.73 78.69

T/K = 323.15
wB 0.926 0.874 0.769 0.555 0.000

PA/kPa 51.98 64.30 76.06 81.66 81.67

T/K = 323.15
wB 0.884 0.749 0.626 0.492 0.376 0.000

PA/kPa 14.36 27.96 40.43 51.86 60.79 70.17
copolymer (B): S-b-MMA/48w 98WOH

T/K = 343.15
wB 0.0000 0.4524 0.5067 0.5491 0.5889 0.6291 0.6674 0.7127 0.7567

PA/Pa 73128.3 67614.5 65530.0 63512.0 61303.5 58751.0 55877.5 51840.5 46977.5

continue
____________________________________________________________________________________
continue
T/K = 373.15
wB 0.0000 0.5801 0.6199 0.6512 0.6990 0.7293 0.7617 0.8014
PA/Pa 34300.5 31591.0 30891.0 30243.0 28843.5 27807.5 26384.0 24151.0

T/K = 398.15
wB 0.0000 0.5794 0.6262 0.6508 0.6833 0.7158 0.7485 0.7771 0.8144
PA/Pa74321.2 68279.0 66465.5 65410.0 63500.0 61137.0 58201.0 54886.0 50211.5

T/K = 398.15
wB 0.0000 0.6714 0.6997 0.7223 0.7591 0.7982 0.8245
PA/Pa 32215.7 29603.0 28965.0 28430.5 26984.0 25295.5 23646.5

T/K = 343.15
wB 0.0000 0.5017 0.5340 0.5611 0.5960 0.6326 0.6723 0.7138 0.7469
PA/Pa 27250.3 24751.5 24362.0 23947.5 23372.5 22699.5 21511.5 20585.0 19418.5
wB 0.7782
PA/Pa 18277.0

T/K = 373.15
wB 0.0000 0.4832 0.5364 0.5796 0.6298 0.6663 0.6997 0.7462 0.7897
PA/Pa 74464.2 68224.0 66668.0 64694.5 61939.0 59750.0 57404.5 53197.0 48424.0

T/K = 398.15
wB 0.0000 0.5998 0.6476 0.6895 0.7192 0.7465 0.7839 0.8124
PA/Pa 69803.4 64910.0 63870.0 62292.5 60268.0 58328.0 54314.0 51424.0
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and pentyl maleate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/pentyl maleate copolymer
50.0 mol% styrene S-PM/50x 97MIO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-PM/50x 130000 156000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-PM/50x 97MIO

T/K = 333.15
wB 0.996 0.994 0.982 0.981 0.975 0.953 0.946 0.934 0.892

PA/Torr 76.5 106.0 131.5 157.5 188.5 218.0 251.5 279.0 300.5
wB 0.874 0.000
PA/Torr 362.5 390.0

T/K = 333.15
wB 0.970 0.956 0.940 0.915 0.882 0.847 0.783 0.734 0.000

PA/Torr 128.0 190.0 247.5 296.0 354.5 400.5 457.5 489.5 635.0
____________________________________________________________________________________

T/K = 323.15
wB 0.967 0.942 0.932 0.914 0.888 0.848 0.806 0.759 0.675
PA/Torr 106.0 156.0 196.0 243.0 295.5 346.5 406.0 448.0 492.0
wB 0.631 0.000
PA/Torr 513.0 612.0

T/K = 343.15
wB 0.985 0.968 0.950 0.924 0.891 0.849 0.794 0.745 0.706
PA/Torr 230.0 317.5 408.5 494.5 587.0 679.5 786.0 857.5 896.0
wB 0.000
PA/Torr 1196.0
_____________________________________________________________________________
Copolymers from vinyl acetate and vinyl chloride
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Vinyl acetate/vinyl chloride copolymer
10.0 wt% vinyl acetate VA-VC/10w 95GUP
12.0 wt% vinyl acetate VA-VC/12w(1) 98KIM
12.0 wt% vinyl acetate VA-VC/12w(2) 95GUP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
VA-VC/10w 115000 Sci. Polym. Products, catalog #068
VA-VC/12w(1) 7800 22000 Sci. Polym. Products
VA-VC/12w(2) 14300 30000 Sci. Polym. Products, catalog #063
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): VA-VC/12w(1) 98KIM

T/K = 398.15
wB 0.9747 0.9689 0.9610 0.9503 0.9421 0.9309 0.9190
aA 0.1084 0.1384 0.1648 0.1991 0.2099 0.2593 0.2911

T/K = 418.15
wB 0.9690 0.9630 0.9561 0.9482 0.9400 0.9318 0.9289
aA 0.1120 0.1371 0.1614 0.1846 0.2166 0.2774 0.2869
copolymer (B): VA-VC/12w(2) 95GUP

solvent (A): 1-butanol C4H10O 71-36-3
T/K = 353.15
wB 0.993 0.984 0.978 0.967 0.960 0.956 0.954
PA/kPa 2.7 5.2 8.0 10.8 12.3 13.9 15.2

T/K = 398.15
wB 0.9880 0.9841 0.9794 0.9738 0.9674 0.9600 0.9516
aA 0.0828 0.0927 0.1159 0.1517 0.1990 0.2268 0.2642

T/K = 398.15
wB 0.9703 0.9611 0.9510 0.9384 0.9225 0.9010 0.8716
aA 0.2431 0.3024 0.3670 0.4353 0.5054 0.5755 0.6955

T/K = 418.15
wB 0.9794 0.9748 0.9691 0.9622 0.9547 0.9460 0.9364
aA 0.1793 0.2100 0.2508 0.2973 0.3446 0.3957 0.4476
____________________________________________________________________________________

T/K = 428.15
wB 0.9814 0.9773 0.9727 0.9676 0.9613 0.9538 0.9446
aA 0.1406 0.1709 0.2030 0.2360 0.2690 0.3260 0.3890
copolymer (B): VA-VC/12w(2) 95GUP

T/K = 353.15
wB 0.971 0.970 0.968 0.963 0.963 0.962
PA/kPa 13.6 28.4 39.9 52.5 65.7 79.1

T/K = 398.15
wB 0.9846 0.9828 0.9809 0.9789 0.9766 0.9742 0.9718
aA 0.1859 0.2023 0.2188 0.2355 0.2521 0.2686 0.2849

T/K = 418.15
wB 0.9823 0.9804 0.9786 0.9766 0.9744 0.9722 0.9701
aA 0.2006 0.2268 0.2496 0.2606 0.2738 0.3038 0.3296

T/K = 398.15
wB 0.9884 0.9843 0.9791 0.9729 0.9649 0.9549 0.9432
aA 0.0927 0.1472 0.1970 0.2368 0.2890 0.3436 0.4189

T/K = 418.15
wB 0.9864 0.9815 0.9752 0.9675 0.9583 0.9476 0.9355
aA 0.1262 0.1677 0.2148 0.2765 0.3420 0.4001 0.4566
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from vinyl acetate and vinyl alcohol
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
8.0 mol% vinyl acetate VA-VAL/08x 2000NAG
17.5 mol% vinyl acetate VA-VAL/18x 2000NAG
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
VA-VAL/08x 70000 ρB (298 K) = 1.241 g/cm3
VA-VAL/18x 85000 ρB (298 K) = 1.234 g/cm3
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): VA-VAL/08x 2000NAG

solvent (A): water H2O 7732-18-5
T/K = 298.15
ϕB 0.0039 0.0075 0.0083 0.0113 0.0125 0.0151 0.0164 0.0206

aA 0.999968 0.999963 0.999959 0.999945 0.999917 0.999896 0.999867 0.999839
ϕB 0.0302 0.0330 0.0360 0.0409 0.0505 0.0575 0.0635 0.0727
aA 0.999998 0.999996 0.999995 0.999992 0.999991 0.999990 0.999987 0.999980
ϕB 0.0747 0.0883 0.0910 0.1065
aA 0.999819 0.999746 0.999738 0.999627
Comments: ϕB = (wB/1.241) (0.99705 + 0.245 wB)

____________________________________________________________________________________
copolymer (B): VA-VAL/18x 2000NAG

T/K = 298.15
ϕB 0.0039 0.0076 0.0114 0.0150 0.0222 0.0305 0.0363 0.0494

aA 0.999999 0.999997 0.999994 0.999991 0.999983 0.999971 0.999961 0.999928
ϕB 0.0626 0.0756 0.0878
aA 0.999883 0.999832 0.999767
Comments: ϕB = (wB/1.234) (0.99705 + 0.237 wB)
2.2. Classical mass-fraction Henry's constants of solvent vapors in

molten copolymers
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
18.0 wt% acrylonitrile AN-B/18w 95TRI
34.0 wt% acrylonitrile AN-B/34w(1) 93ISS, 97SCH
34.0 wt% acrylonitrile AN-B/34w(2) 95TRI
34.0 wt% acrylonitrile AN-B/34w(3) 82LIP
41.0 wt% acrylonitrile AN-B/41w 86IT2
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-B/18w 100000 Bayer India
AN-B/34w(1) 60000 Perbunan 3307, Bayer AG, Ger.
AN-B/34w(2) 111000 Bayer India
AN-B/34w(3) Krynac, Polysar
AN-B/41w no data
_____________________________________________________________________________
____________________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): AN-B/18w 95TRI
Comments: Henry’s constants were not corrected for solubility of the marker gas
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 353.15 0.2525 n-nonane 353.15 0.06916
n-decane 353.15 0.02913 n-octane 353.15 0.1708
1,4-dioxane 353.15 0.1291 2-propanone 353.15 1.124
ethyl acetate 353.15 0.4129 tetrahydrofuran 353.15 0.3937
n-heptane 353.15 0.4353 toluene 353.15 0.09431
n-hexane 353.15 1.110 trichloromethane 353.15 0.1960
_____________________________________________________________________________
copolymer (B): AN-B/34w(1) 93ISS
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 333.15 0.2622 n-nonane 373.15 0.8153
benzene 353.15 0.4657 n-nonane 393.15 1.414
benzene 373.15 0.8845 n-octane 333.15 0.5001
benzene 393.15 1.388 n-octane 353.15 0.8916
n-heptane 333.15 1.308 n-octane 373.15 1.638
n-nonane 333.15 0.2007 toluene 373.15 0.3969
n-nonane 353.15 0.4117 toluene 393.15 0.6886
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): AN-B/34w(1) 97SCH
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 330.15 0.1954 n-hexane 330.15 0.4091
cyclohexane 330.15 0.1920 toluene 330.15 0.06506
n-heptane 330.15 0.1420
_____________________________________________________________________________
copolymer (B): AN-B/34w(2) 95TRI
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 353.15 0.3038 n-nonane 353.15 0.1434
n-decane 353.15 0.06299 n-octane 353.15 0.3348
1,4-dioxane 353.15 0.09262 2-propanone 353.15 0.7357
_____________________________________________________________________________
copolymer (B): AN-B/34w(3) 82LIP
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 348.15 0.2346 1-octene 348.15 0.2997
butylcyclohexane 348.15 0.02746 2-pentanone 348.15 0.1336
1-chlorobutane 348.15 0.3311 tetrachloromethane 348.15 0.2014
n-decane 348.15 0.0385 toluene 348.15 0.0921
n-octane 348.15 0.2395 trichloromethane 348.15 0.1714
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): AN-B/41w 86IT2
Comments: Henry’s constants were corrected for solubility of the marker gas N2
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 398.15 1.24 ethylbenzene 398.15 0.333
1,3-butadiene 398.15 17.1 n-hexane 398.15 6.70
n-butane 398.15 30.3 mesitylene 398.15 0.155
cyclohexane 398.15 3.08 2-methylpropane 398.15 38.1
n-decane 398.15 0.498 n-octane 398.15 1.78
n-decane 423.15 0.995 n-octane 423.15 3.13
n-decane 448.15 1.83 n-octane 448.15 5.08
n-decane 473.15 2.97 n-octane 473.15 7.47
2,2-dimethylbutane 398.15 9.84 toluene 398.15 0.599
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from acrylonitrile and 2-(3-methyl-3-phenylcyclobutyl)-
2-hydroxyethyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Acrylonitrile/2-(3-methyl-3-phenylcyclobutyl)-
2-hydroxyethyl methacrylate copolymer
45.0 mol% acrylonitrile AN-MPCHEMA/45x 2000KAY
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-MPCHEMA/45x ρB = 1.075 g/cm3,
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): AN-MPCHEMA/45x 2000KAY
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 423.15 3.603 methyl acetate 423.15 4.813
2-butanone 423.15 4.074 n-nonane 423.15 1.970
n-decane 423.15 1.319 n-octane 423.15 2.661
n-decane 433.15 1.559 n-octane 433.15 2.945
n-decane 443.15 1.772 n-octane 443.15 3.151
n-decane 453.15 1.988 n-octane 453.15 3.488
n-decane 463.15 2.323 n-octane 463.15 3.602
n-dodecane 423.15 0.567 2-propanone 423.15 5.784
ethanol 423.15 7.938 toluene 423.15 2.565
ethanol 433.15 8.649 toluene 433.15 2.931
ethanol 443.15 9.354 toluene 443.15 3.124
ethanol 453.15 9.666 toluene 453.15 3.349
ethanol 463.15 10.38 toluene 463.15 3.975
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
ethyl acetate 423.15 3.646 n-undecane 423.15 0.8903
methanol 423.15 12.18 o-xylene 423.15 1.493
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
62.0 mol% acrylonitrile S-AN/62x 84MAT
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-AN/28w 46000 100000 synthesized in the laboratory
S-AN/62x 86000 synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): S-AN/28w 97WO1
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 423.15 3.50 o-xylene 423.15 0.80
benzene 448.15 5.42 o-xylene 448.15 1.40
benzene 473.15 8.10 o-xylene 473.15 2.40
propylbenzene 423.15 0.55 m-xylene 423.15 0.85
toluene 423.15 1.65 p-xylene 423.15 0.90
toluene 448.15 2.75 p-xylene 448.15 1.55
toluene 473.15 4.30 p-xylene 473.15 2.60
_____________________________________________________________________________
copolymer (B): S-AN/62x 84MAT
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 393.15 2.47 toluene 393.15 1.14
benzene 423.15 4.96 toluene 423.15 2.57
benzene 453.15 7.63 toluene 453.15 4.99
ethyl acetate 393.15 2.62 trichloromethane 393.15 1.94
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from acrylonitrile and vinylidene chloride
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Acrylonitrile/vinylidene chloride copolymer
20 wt% acrylonitrile AN-VdC/20w 86DEM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-VdC/20w Polysciences Inc.
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): AN-VdC/20w 86DEM
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1,1-dichloroethene 291.0 1.498 1,1-dichloroethene 314.0 2.984
1,1-dichloroethene 306.0 2.437
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
20.0 mol% styrene S-BR/20x 84MAT
25.0 mol% styrene S-BR/25x 87OEN
15.0 wt% styrene S-BR/15w(1) 95PET
15.0 wt% styrene S-BR/15w(2) 93ISS, 97SCH
23.0 wt% styrene S-BR/23x 93ISS
23.0 wt% styrene S-BR/23x 97SCH
23.5 wt% styrene S-BR/24w 95PET
25.0 wt% styrene S-BR/25w 95PET
30.0 wt% styrene S-BR/30w 86IT1
40.0 wt% styrene S-BR/40w(1) 95PET
40.0 wt% styrene S-BR/40w(2) 93ISS, 97SCH
triblock copolymer
17.0 wt% styrene S-B-S/17w 92ROM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BR/20x 60000
S-BR/25x 170000 Petkim Petrokimya A.S. Yarimca, Turkey
S-BR/15w(1) 170000 18 wt% 1,2-vinyl, 58 wt% trans
S-BR/15w(2) 240000 Buna EM BT98, Buna Werke Huels/Marl
S-BR/23w 210000 400000 Buna EM 1500, Buna Werke Huels/Marl
S-BR/24w 170000 15 wt% 1,2-vinyl, 53.5 wt% trans
S-BR/25w 200000 73 wt% 1,2-vinyl
S-BR/30w 107700 140000
S-BR/40w(1) 155000 12 wt% 1,2-vinyl, 42 wt% trans
S-BR/40w(2) 190000 Buna EM 1516, Buna Werke Huels/Marl
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BR/41w 86300 181200 synthesized in the laboratory
S-BR/45w 130000 600000
S-BR/77w 117600 200000
S-B-S/17w 114800 188300 Kraton D-1301X
S-B-S/31w 110800 139600 Kraton D-1101
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): S-BR/20x 84MAT
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 393.15 1.77 toluene 393.15 0.77
benzene 423.15 3.71 toluene 423.15 1.72
benzene 453.15 6.68 toluene 453.15 3.33
cyclohexane 393.15 2.19 trichloromethane 393.15 1.54
_____________________________________________________________________________
copolymer (B): S-BR/25x 87OEN
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 343.3 0.3031 cyclohexane 358.3 0.7113
benzene 353.3 0.3906 cyclohexane 363.2 0.8285
benzene 358.3 0.4549 n-hexane 343.3 0.9960
benzene 363.2 0.5285 n-hexane 353.1 1.3191
cyclohexane 343.3 0.4648 n-hexane 358.3 1.6120
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): S-BR/15w(1) 95PET
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 323.15 0.1145 n-heptane 393.15 0.9323
benzene 353.15 0.3358 n-hexane 323.15 0.3059
benzene 373.15 0.6294 n-hexane 353.15 0.7950
benzene 393.15 0.9492 n-hexane 373.15 1.342
cyclohexane 353.15 0.3790 n-nonane 323.15 0.01156
n-decane 353.15 0.01920 n-nonane 393.15 0.2020
n-decane 373.15 0.04503 n-octane 323.15 0.03392
n-decane 393.15 0.09523 n-octane 353.15 0.1177
n-heptane 373.15 0.5884
_____________________________________________________________________________
copolymer (B): S-BR/15w(2) 93ISS
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 333.15 0.1707 n-nonane 333.15 0.01888
benzene 353.15 0.3303 n-nonane 353.15 0.04760
benzene 373.15 0.5873 n-nonane 373.15 0.1051
benzene 393.15 0.9477 n-nonane 393.15 0.2045
n-hexane 333.15 0.4348 toluene 333.15 0.05511
n-hexane 353.15 0.7965 toluene 353.15 0.1199
n-hexane 373.15 1.363 toluene 373.15 0.2310
n-hexane 393.15 2.182 toluene 393.15 0.3993
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): S-BR/15w(2) 97SCH
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 330.15 0.1707 n-hexane 330.15 0.4348
n-heptane 330.15 0.1523
_____________________________________________________________________________
copolymer (B): S-BR/23w 93ISS
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 333.15 0.1749 n-nonane 333.15 0.02070
benzene 353.15 0.3401 n-nonane 353.15 0.05108
benzene 373.15 0.6074 n-nonane 373.15 0.1102
benzene 393.15 1.006 n-nonane 393.15 0.2146
n-hexane 333.15 0.4596 toluene 333.15 0.05687
n-hexane 353.15 0.8464 toluene 353.15 0.1225
n-hexane 373.15 1.455 toluene 373.15 0.2362
n-hexane 393.15 2.359 toluene 393.15 0.4241
_____________________________________________________________________________
copolymer (B): S-BR/23w 97SCH
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 330.15 0.1748 n-hexane 330.15 0.4595
n-heptane 330.15 0.1601
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): S-BR/24w 95PET
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 353.15 0.3266 n-hexane 323.15 0.3247
benzene 373.15 0.5766 n-hexane 353.15 0.8192
benzene 393.15 0.9507 n-hexane 373.15 1.399
n-decane 353.15 0.02042 n-nonane 393.15 0.2111
n-decane 373.15 0.04752 n-octane 323.15 0.03580
n-decane 393.15 0.09996 n-octane 353.15 0.1245
n-heptane 373.15 0.5861
_____________________________________________________________________________
copolymer (B): S-BR/25w 95PET
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 353.15 0.3537 n-hexane 323.15 0.3333
benzene 373.15 0.6222 n-hexane 353.15 0.8652
benzene 393.15 1.048 n-hexane 373.15 1.443
n-decane 353.15 0.02067 n-nonane 393.15 0.2130
n-decane 373.15 0.04801 n-octane 323.15 0.03630
n-decane 393.15 0.1009 n-octane 353.15 0.1270
n-heptane 373.15 0.6031
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): S-BR/30w 86IT1

_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 423.15 2.07 2,2-dimethylbutane 498.15 16.7
benzene 498.15 7.14 n-hexane 423.15 4.44
1,3-butadiene 498.15 41.2 mesitylene 423.15 0.241
n-butane 498.15 43.4 2-methylpropane 423.15 24.5
cyclohexane 498.15 7.84 n-octane 423.15 1.14
n-decane 423.15 0.311 n-octane 448.15 2.00
n-decane 448.15 0.619 n-octane 473.15 3.23
n-decane 473.15 1.12 n-octane 498.15 5.22
n-decane 498.15 1.98 toluene 423.15 0.981
_____________________________________________________________________________
copolymer (B): S-BR/40w(1) 95PET

_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 353.15 0.3537 n-hexane 323.15 0.3333
benzene 373.15 0.6222 n-hexane 353.15 0.8652
benzene 393.15 1.048 n-hexane 373.15 1.443
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
n-decane 353.15 0.02067 n-nonane 393.15 0.2130
n-decane 373.15 0.04801 n-octane 323.15 0.03630
n-decane 393.15 0.1009 n-octane 353.15 0.1270
n-heptane 373.15 0.6031
_____________________________________________________________________________
copolymer (B): S-BR/40w(2) 93ISS

_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 333.15 0.1838 n-nonane 333.15 0.02543
benzene 353.15 0.3518 n-nonane 353.15 0.06000
benzene 373.15 0.6209 n-nonane 373.15 0.1282
benzene 393.15 1.052 n-nonane 393.15 0.2562
n-hexane 333.15 0.5441 toluene 333.15 0.06121
n-hexane 353.15 0.9938 toluene 353.15 0.1269
n-hexane 373.15 1.660 toluene 373.15 0.2433
n-hexane 393.15 2.698 toluene 393.15 0.4344
_____________________________________________________________________________
copolymer (B): S-BR/40w(2) 97SCH

_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 330.15 0.1838 n-hexane 330.15 0.5440
n-heptane 330.15 0.1947
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): S-BR/41w 97WO1

_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 373.15 0.670 mesitylene 398.15 0.150
benzene 473.15 4.85 styrene 373.15 0.115
1,3-butadiene 373.15 11.0 styrene 398.15 0.240
cyclohexane 373.15 0.853 styrene 473.15 1.35
ethylbenzene 373.15 0.138 toluene 473.15 2.50
ethylbenzene 398.15 0.303 p-xylene 373.15 0.140
mesitylene 373.15 0.065 p-xylene 473.15 1.60
_____________________________________________________________________________

_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
n-decane 423.15 0.319 n-octane 423.15 1.18
n-decane 448.15 0.675 n-octane 448.15 2.18
n-decane 473.15 1.20 n-octane 473.15 3.43
n-decane 498.15 2.07 n-octane 498.15 5.45
________________________________________________________________________________________________________________________________________________________________________

_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
n-decane 423.15 0.469 n-octane 423.15 1.67
n-decane 448.15 0.899 n-octane 448.15 2.84
n-decane 473.15 1.63 n-octane 473.15 4.58
n-decane 498.15 2.68 n-octane 498.15 6.81
________________________________________________________________________________________________________________________________________________________________________
____________________________________________________________________________________
copolymer (B): S-B-S/17w 92ROM
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 328.15 0.1499 n-hexane 308.15 0.2012
benzene 348.15 0.2823 n-hexane 328.15 0.3881
2-butanone 308.15 0.1731 n-hexane 348.15 0.6846
2-butanone 328.15 0.3592 toluene 308.15 0.02207
ethylbenzene 308.15 0.00796 trichloromethane 348.15 0.2694
n-heptane 308.15 0.06244 p-xylene 348.15 0.04245
n-heptane 328.15 0.1349
_____________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 328.15 0.1589 n-hexane 308.15 0.2292
benzene 348.15 0.3038 n-hexane 328.15 0.4552
2-butanone 308.15 0.1740 n-hexane 348.15 0.7962
n-heptane 308.15 0.07359 p-xylene 348.15 0.04591
n-heptane 328.15 0.1574
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from dimethyl siloxane and bisphenol-A carbonate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Dimethylsiloxane/bisphenol-A carbonate random copolymer
49.0 wt% dimethylsiloxane DMS-BAC/49w 81WAR
Dimethylsiloxane/bisphenol-A carbonate alternating
block copolymer
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
Copolymer (B) Mn/
g/mol
_____________________________________________________________________________
DMS-BAC/32w 50000-100000 (Mn - PDMS-blocks = 10000, Mn - BAC-blocks = 19000)
DMS-BAC/49w 50000-100000 (statist. react. with PDMS-2000-oligomers)
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): DMS-BAC/32w 81WAR

_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
chlorobenzene 433.15 0.7975 o-dichlorobenzene 433.15 0.2116
n-decane 433.15 0.7824 toluene 433.15 1.813
n-decane 453.15 1.228
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
chlorobenzene 453.15 1.187 toluene 433.15 1.724
o-dichlorobenzene 433.15 0.2088
_____________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
chlorobenzene 433.15 0.8269 n-decane 468.15 1.438
n-decane 433.15 0.6542 o-dichlorobenzene 468.15 0.5082
n-decane 453.15 1.308 toluene 433.15 1.786
_____________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
chlorobenzene 468.15 1.529 toluene 433.15 1.611
o-dichlorobenzene 433.15 0.2232
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
n-decane 433.15 0.4256 toluene 433.15 1.541
n-decane 453.15 0.6596
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and carbon monoxide
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Ethylene/carbon monoxide copolymer
10.5 wt% carbon monoxide E-CO/11w 78DIP
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-CO/11w no data
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): E-CO/11w 78DIP
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
n-octane 381.23 0.3391 n-octane 397.23 0.5281
n-octane 383.21 0.3589 n-octane 399.24 0.5518
n-octane 385.20 0.3811 n-octane 401.24 0.5914
n-octane 387.20 0.4028 n-octane 403.23 0.6135
n-octane 389.21 0.4236 n-octane 405.23 0.6538
n-octane 391.22 0.4508 n-octane 407.23 0.6717
n-octane 393.23 0.4767 n-octane 409.23 0.7204
n-octane 395.24 0.4961 n-octane 411.23 0.7422
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and propylene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
unspecified contents of propylene E-P/? 86PRI
unspecified contents of propylene E-P/? 87PRI
50 mol% propylene E-P-D/50x 93ISS
50 mol% propylene E-P-D/50x 97SCH
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-P/? 24500 low molecular weight EPR from Aldrich
E-P-D/50x 90000 200000 Buna AP341, Buna-Werke Huels/Marl
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): E-P/? 86PRI, 87PRI
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 298.15 0.06423 n-octane 298.15 0.01007
cyclohexane 298.15 0.05695 n-pentane 298.15 0.4342
dichloromethane 298.15 0.1833 tetrachloromethane 298.15 0.03278
_____________________________________________________________________________
copolymer (B): E-P-D/50x 86PRI, 87PRI
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 333.15 0.2204 n-nonane 333.15 0.01394
benzene 353.15 0.4018 n-nonane 353.15 0.03662
benzene 373.15 0.6913 n-nonane 373.15 0.08031
benzene 393.15 1.111 n-nonane 393.15 0.1592
n-hexane 333.15 0.3467 toluene 333.15 0.06840
n-hexane 353.15 0.6417 toluene 353.15 0.1425
n-hexane 373.15 1.082 toluene 373.15 0.2675
n-hexane 393.15 1.723 toluene 393.15 0.4577
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
3.95 wt% vinyl acetate E-VA/04w 76LIU
15.4 wt% vinyl acetate E-VA/15w 99GUO
29.0 wt% vinyl acetate E-VA/29w 78DIN
40.0 wt% vinyl acetate E-VA/40w 82LI1
40.0 wt% vinyl acetate E-VA/40w 82LI2
45.0 wt% vinyl acetate E-VA/45w 83WAL
48.5 wt% vinyl acetate E-VA/49w 99GUO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
Copolymer (B) Mn/ M w/ M η/ M z/ Further information
g/mol g/mol g/mol g/mol
_____________________________________________________________________________
E-VA/04w 36600 147900 392700 Union Carbide, DXM-228,
MI = 0.91
MI = 2.9
E-VA/15w 11000
E-VA/29w 43200 Union Carbide, DX-31034,
MI = 15.0
MI = 14.0
E-VA/40w Aldrich Chem. Co.
E-VA/45w 37700 194500 Levapren 45N, Bayer AG, Ger.
E-VA/49w 81500 220000
_____________________________________________________________________________
____________________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): E-VA/04w 76LIU
Comments: Henry’s constants were corrected for solubility of the marker gas
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
2-butanone 398.15 3.192 methyl chloride 473.15 37.1
2-butanone 448.15 6.991 2-propanol 398.15 7.60
carbon dioxide 398.15 126.6 2-propanol 473.15 17.73
carbon dioxide 448.15 150.0 2-propanone 398.15 8.511
ethane 398.15 102.0 2-propanone 473.15 20.26
ethane 448.15 137.8 sulfur dioxide 398.15 22.49
ethene 398.15 142.0 sulfur dioxide 473.15 40.9
ethene 448.15 172.0 vinyl acetate 398.15 3.242
methyl chloride 398.15 20.26 vinyl acetate 473.15 9.524
methyl chloride 448.15 31.6
_____________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B): E-VA/15w 99GUO
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 393.15 0.8667 n-octane 393.15 0.3434
cyclohexane 393.15 0.9070 tetrachloromethane 393.15 0.4701
1,4-dioxane 393.15 0.7078 tetrahydrofuran 393.15 1.384
ethyl acetate 393.15 1.759 toluene 393.15 0.3710
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): E-VA/29w 78DIN

_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
acetaldehyde 423.61 18.48 n-heptane 433.68 2.327
acetaldehyde 433.68 12.61 n-hexane 423.61 3.9045
acetic acid 423.61 2.157 n-hexane 433.68 4.600
acetic acid 433.68 2.543 methanol 423.61 24.03
acetonitrile 423.61 9.298 methanol 433.68 26.45
acetonitrile 433.68 11.18 methylcyclohexane 423.61 1.271
acrylonitrile 423.61 6.285 methylcyclohexane 433.68 1.554
acrylonitrile 433.68 7.698 nitroethane 423.61 1.943
benzene 423.61 1.859 nitroethane 433.68 2.424
benzene 433.68 2.286 nitromethane 423.61 3.695
1-bromobutane 423.61 0.788 nitromethane 433.68 4.543
1-bromobutane 433.68 1.008 1-nitropropane 423.61 1.376
1-butanol 423.61 1.960 2-nitropropane 433.68 1.756
1-butanol 433.68 2.493 n-octane 423.61 0.9287
2-butanol 423.61 2.995 n-octane 433.68 1.198
2-butanol 433.68 3.584 1-octene 423.61 0.9643
2-butanone 423.61 3.688 1-octene 433.68 1.230
2-butanone 433.68 4.412 n-pentane 423.61 8.197
chlorobenzene 423.61 0.3937 n-pentane 433.68 9.177
chlorobenzene 433.68 0.5156 3-pentanone 423.61 1.765
cyclohexane 423.61 2.052 3-pentanone 433.68 2.238
cyclohexane 433.68 2.489 2-propanol 423.61 7.411
1,2-dichloroethane 423.61 1.372 2-propanol 433.68 8.325
1,2-dichloroethane 433.68 1.808 2-propanone 423.61 8.670
dichloromethane 423.61 3.633 2-propanone 433.68 10.29
dichloromethane 433.68 4.210 propionitrile 423.61 4.581
diethyl ether 423.61 7.076 propionitrile 433.68 5.579
diethyl ether 433.68 8.881 propyl acetate 423.61 1.666
1,4-dioxane 423.61 1.399 propyl acetate 433.68 2.094
1,4-dioxane 433.68 1.732 tetrachloromethane 423.61 1.045
dipropyl ether 423.61 2.010 tetrachloromethane 433.68 1.274
dipropyl ether 433.68 2.526 tetrahydrofuran 423.61 2.963
ethanol 423.61 11.38 tetrahydrofuran 433.68 3.629
ethanol 433.68 13.14 trichloromethane 423.61 1.434
ethyl acetate 433.68 4.192 2,2,2-trifluoroethanol 423.61 3.598
formic acid 423.61 2.911 2,2,2-trifluoroethanol 433.68 4.514
formic acid 433.68 3.562 water 423.61 37.00
furan 423.61 6.404 water 433.68 53.01
furan 433.68 7.414 m-xylene 423.61 0.4208
n-heptane 423.61 1.892 m-xylene 433.68 0.5640
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B): E-VA/40w 82LI1
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 348.15 0.2830 n-octane 348.15 0.1263
1-butanol 348.15 0.1335 1-octene 348.15 0.1255
1-chlorobutane 348.15 0.3290 2-pentanone 348.15 0.1987
n-decane 348.15 0.02067 toluene 348.15 0.1042
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): E-VA/40w 82LI1
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 338.15 0.2006 n-octane 338.15 0.0859
benzene 348.15 0.2827 n-octane 348.15 0.1267
benzene 358.15 0.3830 n-octane 358.15 0.1793
1-butanol 338.15 0.0851 1-octene 338.15 0.0843
1-butanol 348.15 0.1337 1-octene 348.15 0.1256
1-butanol 358.15 0.2037 1-octene 358.15 0.1773
n-decane 338.15 0.01277 toluene 338.15 0.0697
n-decane 348.15 0.02067 toluene 348.15 0.1044
n-decane 358.15 0.0317 toluene 358.15 0.1459
_____________________________________________________________________________
copolymer (B): E-VA/45w 83WAL
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
2-butanone 343.15 0.7612 methanol 373.15 18.36
2-butanone 373.15 2.647 n-pentane 343.15 3.9346
dichloromethane 343.15 0.8012 n-pentane 373.15 10.49
dichloromethane 373.15 2.785 2-propanone 343.15 2.444
diethyl ether 343.15 2.980 2-propanone 373.15 4.888
diethyl ether 373.15 8.418 tetrahydrofuran 343.15 0.7283
methanol 343.15 7.081 trichloromethane 373.15 0.8889
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): E-VA/49w 99GUO
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 393.15 0.8176 n-octane 393.15 0.5209
1,4-dioxane 393.15 0.5046 tetrahydrofuran 393.15 1.160
ethyl acetate 393.15 1.253 toluene 393.15 0.3619
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethyl methacrylate and methacrylic acid
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Ethyl methacrylate/methacrylic acid copolymer
36.6 mol% methacrylic acid EMA-MA/37x 92CHE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
EMA-MA/37x synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): EMA-MA/37x 92CHE
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 413.15 4.838 n-decane 413.15 1.497
benzene 423.15 6.045 n-decane 423.15 1.689
benzene 433.15 7.966 n-decane 433.15 2.245
benzene 443.15 9.757 n-decane 443.15 2.705
benzene 453.15 11.68 n-decane 453.15 3.653
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from isobutyl methacrylate and acrylic acid
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Isobutyl methacrylate/acrylic acid copolymer
10.5 mol% acrylic acid IBMA-AA/11x 96DJA
22.0 mol% acrylic acid IBMA-AA/22x 96DJA
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
IBMA-AA/11x synthesized in the laboratory
IBMA-AA/22x synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): IBMA-AA/11x 96DJA
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 423.15 3.917 n-decane 423.15 0.6869
benzene 433.15 4.705 n-decane 433.15 0.9445
benzene 443.15 5.752 n-decane 443.15 1.210
benzene 453.15 7.537 n-decane 453.15 1.558
_____________________________________________________________________________
copolymer (B): IBMA-AA/22x 96DJA
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 423.15 4.290 n-decane 423.15 0.8616
benzene 433.15 5.239 n-decane 433.15 1.105
benzene 443.15 6.937 n-decane 443.15 1.455
benzene 453.15 8.613 n-decane 453.15 2.006
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and acrylic acid
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/acrylic acid copolymer
20.0 mol% acrylic acid S-AA/20x 91CHE
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-AA/20x synthesized in the laboratory
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): S-AA/20x 91CHE
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 423.15 4.095 n-decane 423.15 1.125
benzene 433.15 4.743 n-decane 433.15 1.355
benzene 443.15 5.850 n-decane 443.15 1.900
benzene 453.15 7.287 n-decane 453.15 2.258
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
58.0 wt% styrene S-BMA/58w 81DIP
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BMA/58w 32500 72500 Xerox Corp., Can.
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): S-BMA/58w 81DIP
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 413.15 1.900 n-octane 413.15 1.442
1-chlorobutane 413.15 2.282 tetrachloromethane 413.15 1.202
n-decane 413.15 0.3873 2,2,4-trimethylpentane 413.15 2.727
dichloromethane 413.15 3.481 3,4,5-trimethylheptane 413.15 0.5778
tert-butyl-benzene 413.15 0.1987
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and isobutyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/isobutyl methacrylate copolymer
80.0 wt% styrene S-IBMA/80w 81DIP
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-IBMA/80w 70000 Xerox Corp., Can.
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): S-IBMA/80w 81DIP
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 413.15 2.030 n-octane 413.15 1.669
n-decane 413.15 0.4494 trichloromethane 413.15 1.677
1-chlorobutane 413.15 2.553 2,2,4-trimethylpentane 413.15 3.458
dichloromethane 413.15 3.869 3,4,5-trimethylheptane 413.15 0.6947
tert-butyl-benzene 413.15 0.2257
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and N,N-dimethyl aminoethyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/N,N-dimethyl aminoethyl methacrylate
copolymer
6.0 mol% methacrylate S-DMAM/06x 96DJA
12.0 mol% methacrylate S-DMAM/12x 96DJA
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-DMAM/06x synthesized in the laboratory
S-DMAM/12x synthesized in the laboratory
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): S-DMAM/06x 96DJA
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 423.15 8.189 n-decane 423.15 2.150
benzene 433.15 9.040 n-decane 433.15 2.693
benzene 443.15 10.25 n-decane 443.15 3.320
benzene 453.15 12.37 n-decane 453.15 4.138
_____________________________________________________________________________
copolymer (B): S-DMAM/12x 96DJA
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 423.15 4.022 n-decane 423.15 1.089
benzene 433.15 5.239 n-decane 433.15 1.376
benzene 443.15 6.551 n-decane 443.15 1.811
benzene 453.15 8.316 n-decane 453.15 2.283
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and 2-(3-methyl-3-phenylcyclobutyl)-2-hydroxyethyl
methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/2-(3-methyl-3-phenylcyclobutyl)-2-hydroxyethyl
methacrylate copolymer
40.0 mol% styrene S-MPCHEMA/40x 2000KAY
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-MPCHEMA/40x ρB = 1.045 g/cm3,
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): S-MPCHEMA/40x 2000KAY
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
n-decane 423.15 0.8922 n-octane 423.15 2.436
n-decane 433.15 1.015 n-octane 433.15 2.808
n-decane 443.15 1.188 n-octane 443.15 3.078
n-decane 453.15 1.342 n-octane 453.15 3.319
ethanol 423.15 10.27 toluene 423.15 2.676
ethanol 433.15 12.17 toluene 433.15 2.896
ethanol 443.15 13.32 toluene 443.15 3.506
ethanol 453.15 13.40 toluene 453.15 3.349
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and nonyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/nonyl methacrylate copolymer
80 mol% styrene S-NMA/80x 95BOG
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-NMA/80x 29000 synthesized in the laboratory
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): S-NMA/80x 95BOG
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1-butanol 526.6 20.43 n-heptane 526.6 7.083
dibutyl ether 526.6 10.90 n-octane 526.6 4.418
1,4-dioxane 526.6 13.57
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from tetrafluoroethylene and
2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
13 mol% tetrafluoroethylene TFE-PFD/13x 99BON
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
TFE-PFD/13x AF2400, DuPont, Wilmington
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): TFE-PFD/13x 99BON
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
n-hexane 373.15 0.7530 n-pentane 423.15 5.246
n-hexane 423.15 2.635
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
43.4 mol% vinyl acetate VA-VAL/43x 86CAS
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
VA-VAL/43x synthesized in the laboratory
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): VA-VAL/43x 86CAS
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 393.15 4.263 1-hexanol 415.15 0.6594
benzene 400.15 4.953 1-hexanol 423.15 0.8636
benzene 408.15 5.646 tert-butanol 393.15 1.463
1-butanol 393.15 1.019 tert-butanol 415.15 2.750
1-butanol 408.15 1.651 n-nonane 393.15 5.731
1-butanol 415.15 2.039 n-nonane 400.15 6.534
1-butanol 423.15 2.560 n-nonane 408.15 7.767
2-butanol 393.15 1.926 n-nonane 415.15 8.898
2-butanol 400.15 2.309 n-nonane 423.15 10.67
2-butanol 408.15 2.972 1-octanol 393.15 0.1033
2-butanol 415.15 3.575 1-octanol 400.15 0.1335
2-butanol 423.15 4.365 1-octanol 408.15 0.1793
cyclohexanol 393.15 0.1780 1-octanol 415.15 0.2359
cyclohexanol 408.15 0.3115 1-pentanol 393.15 0.5446
n-decane 393.15 3.136 1-pentanol 415.15 1.134
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1-decanol 393.15 0.03609 2-pentanol 415.15 2.108
1-decanol 408.15 0.06846 1-propanol 393.15 2.073
n-dodecane 393.15 0.9768 1-propanol 415.15 3.825
ethylbenzene 393.15 1.370 2-propanol 415.15 6.472
ethylbenzene 408.15 2.003 n-tetradecane 393.15 0.3877
1-heptanol 393.15 0.1767 n-tetradecane 415.15 0.8248
1-heptanol 408.15 0.3127 toluene 393.15 2.293
n-hexadecane 393.15 0.1361 toluene 415.15 3.781
n-hexadecane 408.15 0.2588 n-undecane 393.15 1.755
1-hexanol 393.15 0.2946 n-undecane 415.15 3.340
1-hexanol 408.15 0.5211
_____________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 393.15 3.153 1-hexanol 415.15 0.5736
benzene 400.15 3.516 1-hexanol 423.15 0.7324
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1-butanol 408.15 1.517 n-nonane 393.15 3.768
1-butanol 415.15 1.839 n-nonane 400.15 4.319
1-butanol 423.15 2.258 n-nonane 408.15 5.045
2-butanol 393.15 1.720 n-nonane 415.15 5.864
2-butanol 400.15 2.103 n-nonane 423.15 6.864
2-butanol 408.15 2.603 1-octanol 393.15 0.0891
2-butanol 415.15 3.123 1-octanol 400.15 0.1182
2-butanol 423.15 3.806 1-octanol 408.15 0.1609
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1-hexanol 408.15 0.4588
_____________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 393.15 2.159 1-hexanol 415.15 0.4725
benzene 400.15 2.578 1-hexanol 423.15 0.6012
1-butanol 408.15 1.297 1-octanol 393.15 0.0705
1-butanol 415.15 1.568 1-octanol 400.15 0.0927
1-butanol 423.15 1.926 1-octanol 408.15 0.1248
2-butanol 393.15 1.468 1-octanol 415.15 0.1538
2-butanol 400.15 1.771 1-octanol 423.15 0.2019
2-butanol 408.15 2.185 n-nonane 393.15 2.374
2-butanol 415.15 2.599 n-nonane 400.15 2.784
2-butanol 423.15 3.146 n-nonane 408.15 3.291
cyclohexanol 393.15 0.1526 n-nonane 415.15 3.752
cyclohexanol 400.15 0.1935 n-nonane 423.15 4.427
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1-hexanol 408.15 0.3788
_____________________________________________________________________________
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 393.15 1.565 1-hexanol 415.15 0.4028
benzene 400.15 1.959 1-hexanol 423.15 0.5095
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1-butanol 408.15 1.147 n-nonane 393.15 1.511
1-butanol 415.15 1.383 n-nonane 400.15 1.800
1-butanol 423.15 1.700 n-nonane 408.15 2.208
2-butanol 393.15 1.384 n-nonane 415.15 2.623
2-butanol 400.15 1.646 n-nonane 423.15 3.208
2-butanol 408.15 2.021 1-octanol 393.15 0.0560
2-butanol 415.15 2.384 1-octanol 400.15 0.0730
2-butanol 423.15 2.872 1-octanol 408.15 0.0979
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1-hexanol 408.15 0.3273
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
3 wt% vinyl acetate VA-VC/03w 79HEI
3 wt% vinyl acetate VA-VC/03w 80MER
10 wt% vinyl acetate VA-VC/10w(1) 79HEI
10 wt% vinyl acetate VA-VC/10w(2) 88SAT
15 wt% vinyl acetate VA-VC/15w 78OIS
17 wt% vinyl acetate VA-VC/17w 79HEI
17 wt% vinyl acetate VA-VC/17w 80MER
Vinyl acetate/vinyl chloride/glycidyl methacrylate

terpolymer
10.5 wt% VA, 80 wt% VC, 9.5 wt% GMA VA-VC-GMA/10w 78OIS
Vinyl acetate/vinyl chloride/hydroxypropyl acrylate

terpolymer
5 wt% VA, 80 wt% VC, 15 wt% HPA VA-VC-HPA/05w 78OIS
34 wt% VA, 58 wt% VC, 8 wt% HPA VA-VC-HPA/34w 78OIS
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
VA-VC/03w Polysciences, Inc.
VA-VC/10w(1) Polysciences, Inc.
VA-VC/10w(2) no data
VA-VC/15w 26000 Union Carbide Corp.
VA-VC/17w Polysciences, Inc.
VA-VC-GMA/10w 8400 Union Carbide Corp.
VA-VC-HPA/05w 10000 Union Carbide Corp.
VA-VC-HPA/34w 12000 Union Carbide Corp.
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): VA-VC/03w 79HEI
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
cyclohexane 398.15 5.09 n-heptane 398.15 6.02
1,4-dioxane 398.15 0.85 toluene 398.15 1.03
1,4-dioxane 413.15 1.26 toluene 413.15 1.46
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): VA-VC/03w 80MER
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
acetaldehyde 398.15 15.16 1,4-dioxane 413.15 1.245
acetic acid 398.15 3.232 n-heptane 413.15 7.555
acetonitrile 413.15 5.371 nitroethane 398.15 0.9919
benzene 413.15 2.997 2-propanol 398.15 6.516
2-butanone 413.15 3.387 2-propanone 398.15 5.356
cyclohexane 398.15 5.140 2-propanone 413.15 6.517
cyclohexane 413.15 6.425 tetrahydrofuran 398.15 3.088
1,2-dichloroethane 398.15 1.550 tetrahydrofuran 413.15 3.351
1,2-dichloroethane 413.15 2.105 toluene 398.15 1.058
1,4-dioxane 398.15 0.8536 toluene 413.15 1.425
_____________________________________________________________________________
copolymer (B): VA-VC/10w(1) 80MER
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1,4-dioxane 398.15 0.7695 toluene 413.15 1.369
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): VA-VC/10w(1) 79HEI
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1,4-dioxane 398.15 0.78 toluene 398.15 0.98
1,4-dioxane 413.15 1.21 toluene 413.15 1.38
_____________________________________________________________________________
copolymer (B): VA-VC/10w(2) 88SAT
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
acrylonitrile 388.15 2.64 n-nonane 388.15 1.32
benzene 388.15 1.67 2-propanone 388.15 3.82
2-butanone 388.15 1.90 styrene 388.15 0.224
chlorobenzene 388.15 0.293 tetrachloromethane 388.15 1.81
n-decane 388.15 0.679 toluene 388.15 0.854
n-decane 398.15 0.849 toluene 398.15 0.962
n-decane 408.15 1.03 toluene 408.15 1.20
n-decane 423.15 1.49 toluene 423.15 1.60
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
fluorobenzene 388.15 1.36 vinyl acetate 388.15 2.68
fluorobenzene 398.15 1.67 vinyl acetate 398.15 3.24
fluorobenzene 408.15 2.08 p-xylene 388.15 0.350
_____________________________________________________________________________
copolymer (B): VA-VC/15w 78OIS
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
2-propanone 383.15 4.276 propyl acetate 423.15 3.668
2-propanone 403.15 6.647 vinyl chloride 383.15 21.68
propyl acetate 383.15 1.216 vinyl chloride 423.15 41.14
propyl acetate 403.15 2.178
_____________________________________________________________________________
copolymer (B): VA-VC/17w 80MER
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1,4-dioxane 398.15 0.7582 toluene 413.15 1.354
_____________________________________________________________________________
copolymer (B): VA-VC/17w 79HEI
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
cyclohexane 398.15 4.70 nitroethane 398.15 0.79
cyclohexane 413.15 6.03 nitroethane 413.15 1.27
1,4-dioxane 398.15 0.76 toluene 398.15 0.93
1,4-dioxane 413.15 1.18 toluene 413.15 1.38
_____________________________________________________________________________
copolymer (B): VA-VC-GMA/10w 78OIS
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
2-propanone 383.15 4.327 vinyl acetate 383.15 3.131
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): VA-VC-HPA/05w 78OIS
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
2-propanone 383.15 3.992 propyl acetate 423.15 3.698
propyl acetate 403.15 2.138
_____________________________________________________________________________
copolymer (B): VA-VC-HPA/34w 78OIS
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from vinyl chloride and vinylidene chloride
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Vinyl chloride/vinylidene chloride copolymer
20 wt% vinyl chloride VC-VdC/20w(1) 86DEM
20 wt% vinyl chloride VC-VdC/20w(2) 91DEM
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
VC-VdC/20w(1) 90000 Polysciences Inc.
VC-VdC/20w(2) Borden Chem. Corp., USA
_____________________________________________________________________________
Experimental data:
_____________________________________________________________________________
copolymer (B): VC-VdC/20w(1) 86DEM
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
1,1-dichloroethene 306.15 2.766
_____________________________________________________________________________
copolymer (B): VC-VdC/20w(2) 91DEM
_____________________________________________________________________________
K MPa K MPa
_____________________________________________________________________________
benzene 363.15 2.823 n-octane 363.15 0.06041
n-decane 363.15 0.5149 tetrahydrofuran 363.15 2.739
n-nonane 363.15 1.157 trichloromethane 363.15 3.523
_____________________________________________________________________________
____________________________________________________________________________________
2.3. References
63COR Corneliussen, R., Rice, S.A., and Yamakawa, H., On the thermodynamic properties of
solutions of polar polymers. A comparison of experiment and theory, J. Chem. Phys., 38,
1768, 1963.
72PEI Peinze, K., Dampfdruckmessungen in binären Lösungen aus Aromaten und Copolymeren,
Diploma paper, TH Leuna-Merseburg, 1972.
73BEL Belorussow, J., Freie Exzessenthalpie binärer Lösungen aus Aromaten und Ethylen-
Vinylacetat-Copolymeren, Diploma paper, TH Leuna-Merseburg, 1973.
75BOB Boblenz, M. and Glindemann, D., Abhängigkeit der freien Exzessenthalpie vom
Lösungsmittel in binären Mischungen mit Ethylen-Vinylacetat-Copolymerisat, Diploma
paper, TH Leuna-Merseburg, 1975.
76KIE Kiessling, D., Untersuchungen des Flüssig-Dampf-Gleichgewichts von Polyethylenvinyl-
acetat-Essigester-Systemen, Diploma paper, TH Leuna-Merseburg, 1976.
76LIU Liu, D.D. and Prausnitz, J.M., Solubilities of gases and volatile liquids in polyethylene and
15, 330, 1976.
78DIN Dincer, S. and Bonner, D.C., Thermodynamic analysis of ethylene and vinylacetate
78DIP DiPaola-Baranyi, G., Braun, J.-M., and Guillet, J.E., Partial molar heats of mixing of small
molecules with polymers by gas chromatography, Macromolecules, 11, 224, 1978.
78OIS Oishi, T. and Prausnitz, J.M., Solubilities of some volatile polar fluids in copolymers
containing vinyl chloride, vinyl acetate, glycidyl methacrylate, and hydroxypropyl acrylate,
Ind. Eng. Chem. Fundam., 17, 109, 1978.
79HEI Heintz, A., Lichtenthaler, R.N., and Prausnitz, J.M., Solubilities of volatile solvents in
polyvinylacetate, polyvinylchloride, and their random copolymers, Ber. Bunsenges. Phys.
Chem. 83, 926, 1979.
80MER Merk, W., Lichtenthaler, R.N., and Prausnitz, J.M., Solubilities of fifteen solvents in
copolymers of poly(vinyl acetate) and poly(vinyl chloride) from gas-liquid chromatography.
Estimation of polymer solubility parameters, J. Phys. Chem., 84, 1694, 1980.
81DIP DiPaola-Baranyi, G., Thermodynamic miscibility of various solutes with styrene-butyl
methacrylate polymers and copolymers, Macromolecules, 14, 683, 1981.
81WAR Ward, T.C., Sheeny, D.P., Riffle, J.S., and McGrath, J.E., Inverse gas chromatography
studies of poly(dimethylsiloxane)-polycarbonate copolymers and blends, Macromolecules,
14, 1791, 1981.
82LI1 Lipson, J.E.G. and Guillet, J.E., Solubilities and solubility parameters of polymers from
inverse gas chromatography, in Macromolecular Solutions, Solvent Prop. Relat. Polym.
Pap. Symp., 1982, 14.
82LI2 Lipson, J.E.G. and Guillet, J.E., Measurement of solubility and solubility parameters for
small organic solutes in polymer films by gas chromatography, J. Coat. Technol., 54, 89,
1982.
83WAL Walsh, D.J., Higgins, J.S., Rostami, S., and Weerape-Ruma, K., Compatibility of ethylene-
vinylacetate copolymers with chlorinated polyethylenes. 2. Investigation of the
thermodynamic parameters, Macromolecules, 16, 391, 1983.
84MAT Matsumara, K., Measurement of infinite dilution activity coefficient of solvent in polymer
by gas-liquid chromatography, Kagaku Kogaku Ronbunshu, 10, 516, 1984.
86CAS Castells, R.S. and Massa, G.D., Study of polymer-solvent interactions by gas
chromatography. Copolymers of vinyl acetate and vinyl alcohol with hydrocarbons and
alcohols, J. Appl. Polym. Sci., 32, 5917, 1986.
____________________________________________________________________________________
86DEM Demertzis, P.G. and Kontominas, M.G., Interaction between vinylidene chloride and
copolymers of vinylidene chloride by inverse gas chromatography, Lebensm.-Wiss.
Technol., 19, 249, 1986.
86IT1 Itsuno, S., Iwai, Y., and Arai, Y., Measurement and correlation of solubilities of hydrocar-
bon gases in styrene-butadiene copolymers, Kagaku Kogaku Ronbunshu, 12, 349, 1986.
86IT2 Itsuno, S., Ohyama, K., Iwai, Y., and Arai, Y., Measurement and correlation of solubilities
for hydrocarbon gases in acrylonitrile-butadiene copolymer, Kagaku Kogaku Ronbunshu,
12, 734, 1986.
86KRC Krcek, M., Diploma paper, Verdampfungsgleichgewicht in Systemen aus Polymermischun-
gen oder Blockcopolymeren und einem Lösungsmittel, TH Leuna-Merseburg, 1986.
86PRI Price, G.J., Guillet, J.E., and Purnell, J.H., Measurement of solubility parameters by gas-
liquid chromatography, J. Chromatogr., 369, 273, 1986.
87OEN Oener, M. and Dincer, S., Thermodynamical properties of polymer-probe pairs by gas
chromatography, Polymer, 28, 279, 1987.
87PRI Price, G.J. and Guillet, J.E., The use of gas chromatography to study solubility in polymeric
systems, J. Solution Chem., 16, 605, 1987.
88SAT Sato, Y., Inomata, H., and Arai, K., Solubilities of fifteen organic substances in poly(vinyl
chloride), poly(vinyl acetate), and vinyl chloride-vinyl acetate copolymer, Kobunshi
Ronbunshu, 45, 287, 1988.
89MOE Moeller, F., Energetik der Wechselwirkungen von Oligomeren des Ethylen- und Propylen-
oxids und deren Cooligomeren in Mischung mit CCl4, PhD-Thesis, TU München, 1989.
90IWA Iwai, Y., Miyamoto, S., Nakano, K., and Arai, Y., Measurement and prediction of
solubilities of ethylbenzene vapor in styrene-butadiene rubbers, J. Chem. Eng. Japan, 23,
508, 1990.
91CHE Cherrak, D.-E. and Djadoun, S., A study of mixtures of poly(ethylene oxide) with
polystyrene or poly(styrene-co-acrylic acid) by inverse gas chromatography and
viscosimetry, Polym. Bull., 27, 289, 1991.
91DEM Demertzis, P.G., Riganakos, A., and Akrida-Demertzi, K., An inverse gas chromatographic
study of compatibility of food grade PVdC copolymer and low volatility plasticizers,
Polym. Internat., 25, 229, 1991.
91IWA Iwai, Y., Ishidao, T., Miyamoto, S., Ikeda, H., and Arai, Y., Solubilities of nonane vapor in
styrene-butadiene copolymers at 100 and 130 oC, Fluid Phase Equil., 68, 197, 1991.
92CHE Cherrak, D.-E. and Djadoun, S., Inverse gas chromatography of poly(ethylene oxide) with
poly(ethyl methacrylate) or poly(ethyl methacrylate-co-methacrylic acid), J. Appl. Polym.
Sci., Appl. Polym. Symp., 51, 209, 1992.
92ROM Romdhane, I.H., Plana, A., Hwang, S., and Danner, R.P., Thermodynamic interactions of
solvents with styrene-butadiene-styrene triblock copolymers, J. Appl. Polym. Sci., 45, 2049,
1992.
93ISS Issel, H.-M., Thermodynamische und rheologische Steuerung der Materialeigenschaften von
Elastomeren durch trans-Poly(octenylen), PhD-Thesis, Univ. Hannover, 1993.
94WOH Wohlfarth, Ch., Vapour-Liquid Equilibrium Data of Binary Polymer Solutions: Physical
95BOG Bogillo, V.I. and Voelkel, A., Solution properties of amorphous co- and terpolymers of
styrene as examined by inverse gas chromatography, J. Chromatogr. A, 715, 127, 1995.
95GUP Gupta, R.B. and Prausnitz, J.M., Vapor-liquid equilibria of copolymer + solvent and
homopolymer + solvent binaries: new experimental data and their correlation, J. Chem.
Eng. Data, 40, 784, 1995.
95PET Peterseim, V., Quantitative Betrachtung der Verträglichkeit von Kautschuken und Unter-
suchungen zur Rußdistribution und Rußdispersion, PhD-Thesis, Univ. Hannover, 1995.
95TRI Tripathi, V.S., Lal, D., and Sen, A.K., Studies on thermodynamic compatibility of nitrile
rubber and polybutadiene by inverse gas chromatography, J. Appl. Polym. Sci., 58, 1681,
1995.
____________________________________________________________________________________
96DJA Djadoun, S., Karasz, F.E., and Hamou, A.S.H., Blends of poly(isobutyl methacrylate) with
poly(styrene-co-acrylic acid) and of poly(isobutyl methacrylate-co-acrylic acid) with
poly(styrene-co-N,N-dimethyl-aminoethyl methacrylate), Thermochim. Acta, 282/283, 399,
1996.
96WO1 Wohlfarth, Ch., Isopiestic vapor sorption measurements for solutions of butadiene/styrene
random copolymer in cyclohexane, benzene, toluene, ethylbenzene, 1,4-dimethylbenzene,
or 1,3,5-trimethylbenzene at (343.15 - 398.15) K, ELDATA: Int. Electron. J. Phys.-Chem.
Data, 2, 13, 1996.
96WO2 Wohlfarth, Ch., Isopiestic vapor sorption measurements for solutions of acrylonitrile/
styrene random copolymer in benzene, toluene, 1,2-dimethylbenzene, 1,3-dimethylbenzene,
1,4-dimethylbenzene, or propylbenzene at (343.15 - 423.15) K, ELDATA: Int. Electron. J.
Phys.-Chem. Data, 2, 163, 1996.
97MIO Mio, C., Jayachandran, K.N., and Prausnitz, J.M., Vapor-liquid equilibria for binary
solutions of some comb polymers based on poly(styrene-co-maleic anhydride) in acetone,
methanol and cyclohexane, Fluid Phase Equil., 141, 165, 1997.
97SCH Schuster, R.H., Issel, H.M., and Peterseim, V., Charakterisierung der Kautschuk - Lösungs-
mittel Wechselwirkung mittels inverser Gaschromatographie, Kautschuk Gummi Kunst-
stoffe, 50, 890, 1997.
97TAN Tanbonliong, J.O. and Prausnitz, J.M., Vapor-liquid equilibria for some binary and ternary
polymer solutions, Polymer, 38, 5775, 1997.
97WO1 Wohlfarth, Ch., Vapour-liquid equilibria of concentrated poly(styrene-co-butadiene) and
poly(styrene-co-acrylonitrile) solutions, Macromol. Chem. Phys., 198, 2689, 1997.
97WO2 Wohlfarth, Ch., Isopiestic vapor sorption measurements for solutions of poly(methyl
methacrylate-co-styrene) in benzene, toluene, ethylbenzene, 1,4-dimethylbenzene, or 1,3,5-
trimethylbenzene at (343.15 - 398.15) K, ELDATA: Int. Electron. J. Phys.-Chem. Data, 3,
47, 1997.
98KIM Kim, N.H., Kim, S.J., Won, Y.S., and Choi, J.S., Prediction of activities of solvents in
concentrated copolymer solutions, Korean J. Chem. Eng., 15, 141, 1998.
98SCH Schneider, A., Homopolymer- und Copolymerlösungen im Vergleich: Wechselwirkungs-
parameter und Grenzflächenspannung, PhD-Thesis, Univ. Mainz, 1998.
98WOH Wohlfarth, Ch., Isopiestic vapor sorption measurements for solutions of a polystyrene-
block-poly(methyl methacrylate) diblock copolymer in benzene, toluene, ethylbenzene,
1,4-dimethylbenzene, or 1,3,5-trimethylbenzene at (343.15 - 398.15) K, ELDATA: Int.
Electron. J. Phys.-Chem. Data, 4, 83, 1998.
amorphous glassy perfluorodioxol copolymer, Macromolecules, 32, 6163, 1999.
99FRE French, R.N. and Koplos, G.J., Activity coefficients of solvents in elastomers measured
with a quartz crystal microbalance, Fluid Phase Equil., 158-160, 879, 1999.
99GUO Guo, Y., Gu, B., Lu, Z., and Du, Q., Study on segmental interaction parameter between
ethylene and vinyl acetate monomer units of EVA by inverse gas chromatography, J. Appl.
Polym. Sci., 71, 693, 1999.
99WOH Wohlfarth, Ch., Isopiestic vapor sorption measurements for solutions of poly(3-hydroxybu-
tanoic acid-co-3-hydroxypentanoic acid) in chlorobenzene at 373.15, 388.15 and 403.15 K,
ELDATA: Int. Electron. J. Phys.-Chem. Data, 5, 5, 1999.
2000KAY Kaya, I. and Demirelli, K., Determination of thermodynamic properties of poly[2-(3-
methyl-3-phenyl-cyclobutyl)-2-hydroxyethylmethacrylate] and its copolymers at infinite
dilution using inverse gas chromatography, Polymer, 41, 2855, 2000.
2000NAG Nagy, M., A comparative and systematic thermodynamic study of aqueous solutions and
hydrogels of homo- and copolymers of poly(vinyl alcohol), Phys. Chem. Chem. Phys., 2,
2613, 2000.
OF QUASIBINARY OR QUASITERNARY COPOLYMER
SOLUTIONS
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-AN/25w 90000 147000 Bayer AG Leverkusen, Germany
_____________________________________________________________________________
Experimental LLE data:

_____________________________________________________________________________
copolymer (B): S-AN/25w 98SCH, 2000SCH

Type of data: cloud-points (UCST-behavior)
wB 0.006 0.010 0.020 0.042 0.061 0.080 0.081 0.101 0.141

T/K 324.35 326.85 326.15 321.35 316.85 313.15 313.15 309.35 300.25
____________________________________________________________________________________

Type of data: critical point (UCST)
wB 0.080
T/K 313.15

The total feed concentration of the copolymer in the homogeneous system is: wB = 0.080
This is the critical concentration, i.e., sol phase and gel phase are identical phases at the critical point,
see the first line in the table below.
_____________________________________________________________________________
temperature sol phase gel phase sol phase gel phase
_____________________________________________________________________________
T/ Mn/ M w/ Mn/ M w/
K g/mol g/mol g/mol g/mol
_____________________________________________________________________________
313.15 0.080 0.080 90000 147000 90000 147000
311.65 0.055 0.125 62000 124000 80000 170000
309.35 0.043 0.151 48500 105000 74500 163000
307.05 0.029 0.156 56500 187000 84000 167000
305.15 0.046 0.147 54000 110000 91000 174000
302.95 0.035 0.168 47000 89000 90000 171000
300.95 0.042 0.181 48000 90000 90000 175000
299.15 0.033 0.178 80000 170000 79000 169000
_____________________________________________________________________________
Comments: apparent Mw and Mn values were determined via polystyrene standard

____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from N-cyclopropylacrylamide and vinylferrocene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
N-Cyclopropylacrylamide/vinylferrocene copolymer
0.0 mol% vinylferrocene NCPAM-VFe/00x 98KUR
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
NCPAM-VFe/00x synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): NCPAM-VFe/00x 98KUR

Type of data: cloud-point (LCST-behavior)

cB/(g/l) 1.0 T/K 320.25


cB/(g/l) 1.0 T/K 314.85


cB/(g/l) 1.0 T/K 296.95
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from N,N-diethylacrylamide and vinylferrocene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
N,N-Diethylacrylamide/vinylferrocene copolymer
0.0 mol% vinylferrocene DEA-VFe/00x 97KUR
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
DEA-VFe/00x synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): DEA-VFe/00x 97KUR


cB/(g/l) 1.0 T/K 304.65


cB/(g/l) 1.0 T/K 300.35


cB/(g/l) 1.0 T/K 293.55
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from dimethylsiloxane and methylphenylsiloxane
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
DMS-MPS/15w 9100 41200 Dow Corning Corp., Midland, USA
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): DMS-MPS/15w 98SCH, 2000SCH

wB 0.010 0.030 0.050 0.100 0.150 0.200 0.226 0.239 0.240

T/K 309.85 309.75 308.65 304.05 299.35 291.55 293.15 291.75 291.45
wB 0.250 0.300 0.351
T/K 291.15 287.85 284.35

wB 0.240
T/K 291.45
____________________________________________________________________________________

This is a concentration above the critical concentration where the feed phase is a gel phase.
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
290.65 0.195 0.298 8300 25200 9400 42600
290.29 0.204 0.282 9000 27200 10900 41200
289.38 0.165 0.327 7800 16600 5200 40100
288.27 0.165 0.328 4700 21800 5500 35000
287.00 0.189 0.345 8300 19600 12100 43000
285.96 0.137 0.357 4400 18600 5700 39000
284.83 0.115 0.391 4100 13700 5500 39500
283.36 0.128 0.399 7300 15600 11800 40600
_____________________________________________________________________________

wB 0.010 0.044 0.064 0.080 0.098 0.152 0.198 0.248 0.298

T/K 296.75 298.15 297.25 296.35 295.15 291.55 288.45 285.25 282.65
wB 0.310
T/K 282.45

wB 0.310
T/K 282.45
____________________________________________________________________________________

This is a concentration above the critical concentration where the feed phase is a gel phase.
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
281.00 0.229 0.413 8700 22400 13600 52400
280.05 0.186 0.453 8100 18100 13600 51100
279.35 0.191 0.409 9000 22600 13200 53600
278.05 0.183 0.473
277.25 0.179 0.460 7800 18600 14200 52600
276.05 0.167 0.465 7700 16000 13100 50900
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from N-ethylacrylamide and vinylferrocene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
0.0 mol% vinylferrocene NEAM-VFe/00x 97KUR
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
NEAM-VFe/00x synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): NEAM-VFe/00x 97KUR

cB/(g/l) 1.0
T/K 317.85

cB/(g/l) 1.0
T/K 335.65

cB/(g/l) 1.0
T/K 317.85
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
42.6 mol% vinyl acetate E-VA/43x 86RAE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
Copolymer (B) Mn/ M w/ M z/ Further information
g/mol g/mol g/mol
_____________________________________________________________________________
E-VA/43x 14800 41500 79200 ρB (293.15 K) = 1.241 g/cm3
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-VA/43x 86RAE


ϕB 0.0051 0.0117 0.0152 0.0300 0.0453 0.0579 0.0740 0.0817 0.0843
T/K 311.1 314.9 315.9 314.9 313.9 312.4 310.3 309.3 309.0
ϕB 0.0875 0.0934 0.0992 0.1019 0.1031 0.1052 0.1225 0.1278 0.1303
T/K 308.7 308.0 307.5 307.2 307.0 306.8 305.7 305.3 305.7
ϕB 0.1500 0.1650 0.1947 0.2570
T/K 304.4 303.7 302.2 296.3
copolymer (B): E-VA/43x 86RAE


ϕB 0.1031
T/K 307.0
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
20.0 wt% propylene oxide EO-PO-EO/20w 95KIM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
EO-PO-EO/20w 2500
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): EO-PO-EO/20w 95KIM

wB 0.005 0.010 0.025 0.050 0.075 0.100

T/K 308.15 305.15 301.15 299.15 297.15 296.15
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from N-isopropylacrylamide and itaconic acid
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
N-Isopropylacrylamide/itaconic acid copolymer
9.8 mol% itaconic acid NIPAM-IA/10x 99ERB
23.0 mol% itaconic acid NIPAM-IA/23x 99ERB
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
NIPAM-IA/10x synthesized in the laboratory
NIPAM-IA/23x synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): NIPAM-IA/10x 99ERB

wB 0.005 0.005 0.005 0.005 0.005 0.005

pH 2.01 2.30 3.09 3.32 4.08 5.03
T/K 307.55 308.15 309.25 310.15 312.65 332.55
copolymer (B): NIPAM-IA/23x 99ERB

wB 0.005 0.005 0.005

pH 1.00 2.02 3.14
T/K 310.35 310.65 315.55
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from N-isopropylacrylamide and vinylferrocene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
N-Isopropylacrylamide/vinylferrocene copolymer
0.0 mol% vinylferrocene NIPAM-VFe/00x 98KUR
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
NIPAM-VFe/00x synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): NIPAM-VFe/00x 98KUR


cB/(g/l) 1.0 T/K 306.45


cB/(g/l) 1.0 T/K 304.45


cB/(g/l) 1.0 T/K 299.15
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and α-methylstyrene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/α-methylstyrene copolymer
20.0 mol% styrene S-αMS/20x 95PFO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-αMS/20x 100000 114000 Sci. Polym. Products
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): αMS/20x

S-α 95PFO

wB 0.0050 0.0100 0.0202 0.0298 0.0403 0.0501 0.0705 0.0893 0.1187
T/K 274.85 283.65 288.35 288.75 288.65 288.85 288.55 286.75 281.95
wB 0.1405
T/K 279.95

S-α 95PFO

wB 0.0050 0.0100 0.0202 0.0298 0.0403 0.0501 0.0705 0.0893 0.1187
T/K 468.45 463.55 458.15 456.85 453.05 454.45 453.95 454.45 455.05
wB 0.1405
T/K 456.55
____________________________________________________________________________________

S-α 95PFO
wB 0.0050 0.0101 0.0196 0.0297 0.0398 0.0505 0.0532 0.0703 0.1008

T/K 279.35 282.15 284.55 284.55 285.05 285.65 285.85 285.55 285.35
wB 0.1521
T/K 283.55

S-α 95PFO
wB 0.0050 0.0101 0.0196 0.0297 0.0398 0.0505 0.0532 0.0703 0.1008

T/K 494.65 490.55 486.45 484.85 486.55 485.15 487.05 486.35 485.95
wB 0.1521
T/K 489.25

S-α 95PFO
solvent (A): cyclopentane C5H10 287-92-3
wB 0.0053 0.0104 0.0241 0.0364 0.0482 0.0526 0.0913 0.1437 0.1876

T/K 281.65 284.65 288.95 290.15 290.95 290.85 290.65 289.65 288.45

S-α 95PFO
wB 0.0053 0.0104 0.0241 0.0364 0.0482 0.0526 0.0913 0.1437 0.1876

T/K 431.35 427.55 422.65 422.45 421.55 421.05 421.25 422.25 423.35

S-α 95PFO
solvent (A): trans-decahydronaphthalene C10H18 493-02-7
wB 0.0050 0.0099 0.0197 0.0301 0.0402 0.0473 0.0687 0.0845 0.1177

T/K 254.45 259.55 262.05 263.05 263.75 263.75 264.05 264.15 263.95
wB 0.1385 0.1893
T/K 263.55 263.65
____________________________________________________________________________________

S-α 95PFO
solvent (A): hexyl acetate C8H16O2 142-92-7
wB 0.0050 0.0100 0.0202 0.0301 0.0393 0.0496 0.0703 0.0899 0.1192

T/K 277.05 284.25 287.35 288.25 287.35 288.55 287.15 286.75 282.95
wB 0.1486
T/K 280.95

S-α 95PFO
solvent (A): hexyl acetate C8H16O2 142-92-7
wB 0.0050 0.0100 0.0202 0.0301 0.0393 0.0496 0.0703 0.0899 0.1192

T/K 526.55 524.15 515.85 515.05 514.55 514.45 514.65 514.25 514.45
wB 0.1486
T/K 514.05

S-α 95PFO
solvent (A): pentyl acetate C7H14O2 628-63-7
wB 0.0010 0.0050 0.0107 0.0201 0.0301 0.0401 0.0505 0.0689 0.0840

T/K 274.55 289.75 296.25 298.25 304.25 302.25 300.45 300.65 299.95
wB 0.1093 0.1527
T/K 297.15 294.05

S-α 95PFO
solvent (A): pentyl acetate C7H14O2 628-63-7
wB 0.0010 0.0050 0.0107 0.0201 0.0301 0.0401 0.0505 0.0689 0.0840

T/K 502.75 493.55 489.55 482.95 481.55 482.45 480.65 481.35 481.55
wB 0.1093 0.1527
T/K 483.05 485.95
____________________________________________________________________________________
graphical form as phase diagrams or related figures
_____________________________________________________________________________
Copolymer (B) Solvent (A) Ref.
_____________________________________________________________________________
Acrylamide/N,N-dimethylaminoethyl methacrylate
copolymer water 97CHO
_____________________________________________________________________________
Acrylic acid/N-isopropylacrylamide copolymer water 2000BOK
_____________________________________________________________________________
Acrylic acid/methyl acrylate copolymer water 93TAG
_____________________________________________________________________________
Acrylic acid/2-methyl-5-vinylpyridine copolymer water 85VED
_____________________________________________________________________________
Acrylic acid/nonyl acrylate copolymer bisphenol-A-
diglycidyl ether 99MIK
_____________________________________________________________________________
N-Acryloylpyrrolidine/vinylferrocene copolymer water 94KUR
_____________________________________________________________________________
tert-Butylstyrene/dimethylsiloxane triblock copolymer 2-butanone 86KUE
1-nitropropane 86KUE
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-methoxyethyl acrylate
copolymer water 96ELE
water 97ELE
_____________________________________________________________________________
N,N-Dimethylacrylamide/N-phenylacrylamide copolymer water 96MIY
_____________________________________________________________________________
Dimethylsiloxane/methylphenylsiloxane copolymer anisole 2000SCH
2-propanone 2000SCH
_____________________________________________________________________________
Dimethylsiloxane/1,1,3,3-tetramethyldisiloxanyl-ethylene
diblock copolymer ethoxybenzene 2000AZU
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Ethylene/propylene copolymer n-hexane 86IRA
2-methylbutane 86IRA
methylcyclopentane 86IRA
3-methylpentane 86IRA
n-pentane 86IRA
_____________________________________________________________________________
Ethylene/vinyl acetate copolymer diphenyl ether 90VAN
_____________________________________________________________________________
Ethylene/vinyl alcohol copolymer 2-propanol 90CHE
water 71SHI
_____________________________________________________________________________
Ethylene glycol/N-isopropylacrylamide copolymer water 97TOP
_____________________________________________________________________________
Ethylene oxide/1,2-butylene oxide copolymer water 2000SAH
_____________________________________________________________________________
Ethylene oxide/dimethylsiloxane triblock copolymer water 92YAN
_____________________________________________________________________________
Ethylene oxide/propylene oxide copolymer acetic acid 93JOH
butanoic acid 93JOH
propionic acid 93JOH
water 81MED
water 87ANA
water 91LOU
water 93JOH
water 94ZHA
_____________________________________________________________________________
2-Ethyl-2-oxazoline/ε-caprolactone diblock copolymer water 2000KIM
water 2000KIM
_____________________________________________________________________________
N-Isopropylacrylamide/butyl methacrylate copolymer water 93FEI
_____________________________________________________________________________
Maleic anhydride/diethylene glycol copolymer styrene 92LEC
_____________________________________________________________________________
diblock copolymer formamide 90SAM
water 90SAM
water 90SIM
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Polystyrene-b-poly(butyl methacrylate)
diblock copolymer 2-propanol 94SIQ
_____________________________________________________________________________
Styrene/acrylonitrile copolymer 2-butanone 68TER
cyclohexane 68TER
ethyl acetate 82MAN
toluene 72TE1
toluene 72TE2
toluene 2000SCH
_____________________________________________________________________________
Styrene/butyl methacrylate copolymer 2-butanone 90KYO
_____________________________________________________________________________
Styrene/cellulose diacetate graft copolymer 2-propanone 82GOL
N,N-dimethylformamide 82GOL
tetrahydrofuran 82GOL
_____________________________________________________________________________
N-Vinylacetamide/N-vinylisobutyramide copolymer water 97SUW
_____________________________________________________________________________
Vinyl acetate /vinyl alcohol copolymer water 97PAE
_____________________________________________________________________________
Vinyl acetate/vinyl caprolactam copolymer water 93PAS
_____________________________________________________________________________
Vinyl acetate/1-vinyl-2-pyrrolidinone copolymer water 74TAN
_____________________________________________________________________________
Vinyl alcohol/vinyl butyrate copolymer water 74TAN
water 84SHI
_____________________________________________________________________________
Vinyl amine/vinyl caprolactam copolymer water 91TAG
water 94TAG
_____________________________________________________________________________
Vinyl caprolactam/N-vinyl-N-methylacetamide copolymer water 93PAS
_____________________________________________________________________________
N-Vinylisobutyramide/N-vinylvaleramide copolymer water 97SUW
_____________________________________________________________________________
____________________________________________________________________________________

containing at least one copolymer
_____________________________________________________________________________
Copolymers from dimethylsiloxane and styrene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Poly(dimethylsiloxane)-b-polystyrene diblock copolymer
50.0 wt% styrene DMS-b-S/50w 97SCH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
DMS-b-S/50w 55000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): DMS-b-S/50w 97SCH

polymer (C): polystyrene Mw/g.mol-1 = 96000 (Mw/Mn = 1.04)
Type of data: cloud-points

Comments: the weight ratio of polystyrene : DMS-b-S/50w was kept constant at 7.5 : 1
wB + wC 0.011 0.040 0.070 0.100 0.126 0.150 0.179

T/K 290.32 293.57 295.07 296.99 301.85 310.82 340.68
Comments: experimental data by personal communication with A. Schneider

____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
33.3 mol% ethylene oxide EO-PO/33x 98LI1
50.0 mol% ethylene oxide EO-PO/50x(1) 99LIW
50.0 mol% ethylene oxide EO-PO/50x(3) 98LI1
50.0 mol% ethylene oxide EO-PO/50x(5) 98LI2
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
EO-PO/33x 3000 3330 Zhejiang Univ. Chem. Factory, PR China
EO-PO/50x(1) 780 865 Zhejiang Univ. Chem. Factory, PR China
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): EO-PO/33x 98LI1

polymer (C): hydroxypropyl starch Mn = 10000 (Reppe Glykos AB, Sweden)
T/K = 298.15
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
_____________________________________________________________________________
0.8500 0.1000 0.0500 0.7729 0.0250 0.2021 0.8571 0.1080 0.0349
0.8399 0.0999 0.0602 0.7618 0.0222 0.2160 0.8533 0.1139 0.0328
0.8300 0.1000 0.0700 0.7494 0.0204 0.2302 0.8498 0.1200 0.0302
0.8208 0.0995 0.0797 0.7405 0.0190 0.2405 0.8460 0.1260 0.0280
0.8099 0.0999 0.0902 0.7276 0.0172 0.2552 0.8420 0.1321 0.0259
0.8002 0.0999 0.0999 0.7169 0.0159 0.2672 0.8370 0.1380 0.0250
0.7901 0.1000 0.1099 0.7077 0.0152 0.2771 0.8320 0.1441 0.0239
0.7801 0.1000 0.1199 0.6950 0.0140 0.2909 0.8280 0.1489 0.0231
_____________________________________________________________________________
copolymer (B): EO-PO/33x 98LI1

T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.8503 0.0999 0.0498 0.7872 0.0220 0.1908 0.8597 0.1118 0.0285
0.8401 0.1000 0.0599 0.7699 0.0171 0.2130 0.8561 0.1200 0.0239
0.8299 0.1001 0.0700 0.7567 0.0122 0.2311 0.8519 0.1271 0.0210
0.8201 0.1000 0.0799 0.7480 0.0100 0.2420 0.8469 0.1340 0.0190
0.8099 0.1000 0.0901 0.7336 0.0062 0.2602 0.8431 0.1390 0.0179
0.7998 0.1000 0.1002 0.7235 0.0050 0.2715 0.8361 0.1481 0.0158
0.7902 0.1000 0.1098 0.7145 0.0050 0.2805 0.8323 0.1529 0.0148
0.7796 0.1002 0.1202 0.7068 0.0050 0.2882 0.8260 0.1600 0.0140
_____________________________________________________________________________

____________________________________________________________________________________
copolymer (B): EO-PO/50x(3) 98LI1

T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.8498 0.1000 0.0502 0.7895 0.0303 0.1802 0.8549 0.1070 0.0381
0.8399 0.0999 0.0602 0.7767 0.0282 0.1951 0.8517 0.1141 0.0342
0.8296 0.1000 0.0704 0.7679 0.0251 0.2070 0.8476 0.1202 0.0322
0.8199 0.1001 0.0800 0.7516 0.0222 0.2262 0.8419 0.1281 0.0300
0.8099 0.1002 0.0899 0.7447 0.0212 0.2341 0.8378 0.1342 0.0280
0.8000 0.1000 0.1000 0.7326 0.0201 0.2473 0.8335 0.1403 0.0262
0.7901 0.1000 0.1099 0.7207 0.0201 0.2592 0.8299 0.1451 0.0250
0.7801 0.1000 0.1199 0.7090 0.0200 0.2710 0.8248 0.1511 0.0241
_____________________________________________________________________________

T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.8403 0.0999 0.0598 0.7753 0.0241 0.2006 0.8627 0.1022 0.0351
0.8499 0.1001 0.0500 0.7620 0.0198 0.2182 0.8605 0.1090 0.0305
0.8403 0.0999 0.0704 0.7448 0.0142 0.2410 0.8570 0.1160 0.0270
0.8302 0.0999 0.0598 0.7290 0.0110 0.2600 0.8534 0.1230 0.0236
0.8201 0.1001 0.0699 0.7203 0.0092 0.2705 0.8495 0.1275 0.0230
0.8099 0.1001 0.0798 0.7089 0.0063 0.2848 0.8448 0.1322 0.0230
0.7996 0.1001 0.0899 0.6973 0.0052 0.2975 0.8410 0.1370 0.0220
0.7900 0.1001 0.1099 0.6892 0.0050 0.3058 0.8357 0.1423 0.0220
0.7802 0.0999 0.1199 0.6750 0.0050 0.3200 0.8320 0.1462 0.0218
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
copolymer (B): EO-PO/50x(1) 99LIW

component (C): ammonium sulfate (NH4)2SO4 7783-20-2
T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.6996 0.2005 0.0999 0.8007 0.0290 0.1703 0.5869 0.3839 0.0292
0.6894 0.2001 0.1105 0.7939 0.0193 0.1868 0.5553 0.4221 0.0226
0.6775 0.2017 0.1208 0.7847 0.0176 0.1977 0.5254 0.4576 0.0170
0.6587 0.2006 0.1407 0.7669 0.0103 0.2228 0.4774 0.5086 0.0140
0.6406 0.2003 0.1591 0.7479 0.0143 0.2378 0.4355 0.5570 0.0075
_____________________________________________________________________________

T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.7670 0.1512 0.0818 0.8624 0.0221 0.1155 0.6510 0.3224 0.0266
0.7594 0.1505 0.0901 0.8566 0.0151 0.1283 0.6160 0.3630 0.0210
0.7502 0.1498 0.1000 0.8440 0.0119 0.1441 0.5832 0.4008 0.0160
0.7308 0.1495 0.1197 0.8264 0.0086 0.1650 0.5152 0.4749 0.0099
0.7095 0.1503 0.1402 0.8045 0.0049 0.1906 0.4590 0.5362 0.0048
_____________________________________________________________________________

____________________________________________________________________________________

T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.8090 0.1205 0.0705 0.8750 0.0247 0.1003 0.6631 0.3147 0.0222
0.8003 0.1196 0.0801 0.8667 0.0115 0.1218 0.6179 0.3642 0.0179
0.7743 0.1206 0.1051 0.8453 0.0077 0.1470 0.5386 0.4513 0.0101
0.7502 0.1197 0.1301 0.8251 0.0039 0.1710 0.4751 0.5190 0.0059
0.7319 0.1200 0.1481 0.8067 0.0041 0.1892 0.4213 0.5752 0.0036
_____________________________________________________________________________

component (C): dipotassium phosphate K2HPO4 7758-11-4
T/K = 275.15
_____________________________________________________________________________
_____________________________________________________________________________
0.7147 0.1801 0.1052 0.8168 0.0010 0.1822 0.5958 0.3916 0.0141
0.7449 0.1652 0.0899 0.8408 0.0052 0.1540 0.6497 0.3298 0.0205
0.7653 0.1548 0.0799 0.8568 0.0096 0.1336 0.6744 0.3014 0.0242
0.7847 0.1453 0.0700 0.8631 0.0231 0.1138 0.7275 0.2395 0.0330
_____________________________________________________________________________

____________________________________________________________________________________

component (C): dipotassium phosphate K2HPO4 7758-11-4
T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.7148 0.1800 0.1052 0.8350 0.0021 0.1629 0.5137 0.4793 0.0070
0.7252 0.1749 0.0999 0.8381 0.0031 0.1588 0.5420 0.4501 0.0079
0.7450 0.1651 0.0899 0.8534 0.0021 0.1445 0.5573 0.4341 0.0086
0.7652 0.1549 0.0799 0.8719 0.0028 0.1253 0.5855 0.4037 0.0108
0.7848 0.1452 0.0700 0.8835 0.0053 0.1112 0.6552 0.3300 0.0148
0.8050 0.1350 0.0600 0.8986 0.0103 0.0911 0.6773 0.3056 0.0171
_____________________________________________________________________________

component (C): potassium dihydrogen phosphate KH2PO4 7778-77-0
T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.7100 0.1950 0.0950 0.8382 0.0100 0.1518 0.5003 0.4850 0.0147
0.7250 0.1850 0.0900 0.8424 0.0097 0.1479 0.5818 0.3960 0.0222
0.7399 0.1751 0.0850 0.8477 0.0109 0.1414 0.6273 0.3435 0.0292
0.7700 0.1550 0.0750 0.8630 0.0216 0.1154 0.6721 0.2933 0.0346
0.7851 0.1450 0.0699 0.8610 0.0394 0.0996 0.6980 0.2653 0.0367
_____________________________________________________________________________

____________________________________________________________________________________

component (C): sodium sulfate Na2SO4 7757-82-6
T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________
0.7750 0.1550 0.0700 0.8827 0.0041 0.1132 0.5800 0.4183 0.0017
0.7900 0.1450 0.0650 0.8973 0.0062 0.0965 0.6163 0.3770 0.0067
0.8049 0.1350 0.0601 0.9058 0.0094 0.0848 0.6309 0.3634 0.0057
0.8200 0.1252 0.0550 0.9082 0.0128 0.0790 0.6724 0.3165 0.0111
0.8350 0.1150 0.0500 0.9089 0.0223 0.0688 0.7160 0.2714 0.0126
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene terephthalate and p-hydroxybenzoic acid
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Ethylene terephthalate/p-hydroxybenzoic acid
copolymer
27.0 mol% p-hydroxybenzoic acid ET-pHBA/27x 88SCH
35.0 mol% p-hydroxybenzoic acid ET-pHBA/35x 88SCH
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
ET-pHBA/27x 6000 synthesized in the laboratory
ET-pHBA/35x 6000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): ET-pHBA/27x 88SCH

polymer (C): polycarbonate-bisphenol-A Mn = 19300, Mw = 32800 g/mol
T/K = 295.15
ϕA 0.8588 0.8554 0.8777 0.8931 0.9095 0.9096 0.9208 0.9218 0.9234

ϕB 0.1412 0.1367 0.1021 0.0782 0.0537 0.0444 0.0371 0.0308 0.0282
ϕC 0.0000 0.0079 0.0202 0.0287 0.0368 0.0459 0.0421 0.0474 0.0484
ϕA 0.9172 0.9161 0.9037 0.8628
ϕB 0.0265 0.0227 0.0186 0.0129
ϕC 0.0563 0.0612 0.0777 0.1243
copolymer (B): ET-pHBA/35x 88SCH

polymer (C): polycarbonate-bisphenol-A Mn = 19300, Mw = 32800 g/mol
T/K = 295.15
ϕA 0.9021 0.9005 0.9021 0.9052 0.9386 0.9493 0.9583 0.9673 0.9692

ϕB 0.0979 0.0973 0.0932 0.0844 0.0442 0.0333 0.0225 0.0126 0.0083
ϕC 0.0000 0.0025 0.0047 0.0104 0.0172 0.0174 0.0192 0.0201 0.0225
ϕA 0.9473 0.9292 0.9234
ϕB 0.0091 0.0094 0.0623
ϕC 0.0435 0.0614 0.0143
Comments: experimental data by personal communication with M. Hess

____________________________________________________________________________________
3.4. Table of systems where ternary LLE data were published only
_____________________________________________________________________________
Copolymer (B) Second and third component Ref.
_____________________________________________________________________________
Arylene sulfonoxide/butadiene
polyblock copolymer
polybutadiene and trichloromethane 88ROG
polybutadiene and 1,1,2,2-tetrachloroethane 88ROG
_____________________________________________________________________________
Ethyl acrylate/4-vinylpyridine copolymer
polystyrene and tetrahydrofuran 92WAN
_____________________________________________________________________________
2-propanol and water 98YOU
_____________________________________________________________________________
hydroxypropyl starch and water 94MOD
poly(ethylene oxide) and water 94ZH1
poly(propylene oxide) and water 94ZH1
_____________________________________________________________________________
Ethylene terephthalate/p-hydroxybenzoic
acid copolymer
polycarbonate-bisphenol-A
and trichloromethane 88SCH
_____________________________________________________________________________
-b-poly(ethylene oxide) triblock copolymer
1-butanol and water 97HOL
____________________________________________________________________________
Poly(ethylene oxide)-b-poly(tetrahydrofuran)
-b-poly(ethylene oxide) triblock copolymer
1-butanol and water 97HOL
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Methyl methacrylate/4-vinylpyridine
copolymer
styrene/4-vinylpyridine copolymer
and 1,4-dioxane 77DJA
and 2-butanone 77DJA
and trichloromethane 77DJA
_____________________________________________________________________________
triblock copolymer
polybutadiene and 4-methyl-2-pentanone 97HWA
_____________________________________________________________________________
Polystyrene-b-poly(dimethylsiloxane)
diblock copolymer
polystyrene and cyclohexane 97SCH
_____________________________________________________________________________
Polystyrene-b-polyisoprene diblock
copolymer (hydrogenated PIP)
N,N-dimethylformamide and methylcyclohexane 93PO1
_____________________________________________________________________________
Styrene/acrylamide copolymer
vinyl acetate/vinyl alcohol copolymer
and tetrahydrofuran 82LE1
_____________________________________________________________________________
_____________________________________________________________________________
Styrene/acrylonitrile copolymer
poly(methyl methacrylate)
and dimethyl phthalate 77BER
_____________________________________________________________________________
Styrene/butadiene copolymer
polybutadiene and toluene 89INO
polystyrene and tetrahydrofuran 72WHI
polystyrene and styrene 75WHI
_____________________________________________________________________________
Styrene/methacrylic acid copolymer
poly(ethylene oxide) and benzene 92LE2
poly(ethylene oxide) and tetrahydrofuran 92LE2
poly(ethylene oxide) and trichloromethane 92LE2
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Styrene/2-methoxyethyl methacrylate
copolymer
1,1,2,2-tetrachloroethene and dimethyl sulfoxide 93PO2
_____________________________________________________________________________
nitroethane and decahydronaphthalene 94KAW
_____________________________________________________________________________
Styrene/4-vinylpyridine copolymer
methyl methacrylate/4-vinylpyridine copolymer
and 2-butanone 77DJA
and 1,4-dioxane 77DJA
and trichloromethane 77DJA
vinyl acetate/methacrylic acid copolymer
_____________________________________________________________________________
Styrene/1-vinyl-2-pyrrolidinone copolymer
_____________________________________________________________________________
Vinyl acetate/methacrylic acid copolymer
_____________________________________________________________________________
poly(vinyl alcohol) and water 97PAE
styrene/acrylamide copolymer
styrene/acrylic acid copolymer
styrene/1-vinyl-2-pyrrolidinone copolymer
_____________________________________________________________________________
_____________________________________________________________________________

temperatures of copolymer solutions

_____________________________________________________________________________
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-butoxyethyl acrylate copolymer
50 wt% 2-butoxyethyl acrylate DMA-BOEA/50w 92MUE
_____________________________________________________________________________
15 wt% butyl acrylate DMA-BA/15w 92MUE
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-ethoxyethyl acrylate copolymer
50 wt% 2-ethoxyethyl acrylate DMA-EOEA/50w 92MUE
75 wt% 2-ethoxyethyl acrylate DMA-EOEA/75w 92MUE
_____________________________________________________________________________
N,N-Dimethylacrylamide/ethyl acrylate copolymer
25 wt% ethyl acrylate DMA-EA/25w 92MUE
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-methoxyethyl acrylate copolymer
38 mol% 2-methoxyethyl acrylate DMA-MOEA/38x 96ELE
50 wt% 2-methoxyethyl acrylate DMA-MOEA/50w 92MUE
_____________________________________________________________________________
20 wt% propyl acrylate DMA-PA/20w 92MUE
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
N,N-Dimethylacrylamide/methyl acrylate copolymer
30 wt% methyl acrylate DMA-MA/30w 92MUE
_____________________________________________________________________________
_____________________________________________________________________________
33 mol% ethylene E-P/33x 81CHA
43 mol% ethylene E-P/43x 86IRA
_____________________________________________________________________________
2.3 wt% vinyl acetate E-VA/02w 90VAN
42.6 mol% vinyl acetate E-VA/43x 86RAE
_____________________________________________________________________________
87.2 mol% vinyl alcohol E-VAL/87x 71SHI
_____________________________________________________________________________
72.4 mol% ethylene oxide EO-PO/72x 91LOU
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
15 mol% acrylamide NIPAM-AM/15x 94MUM
_____________________________________________________________________________
Maleic anhydride/diethylene glycol copolymer
1:1, 50 mol% maleic anhydride MAH-DEG/50x 92LEC
_____________________________________________________________________________
21.1 wt% acrylonitrile S-AN/21w 72TE2
23.2 wt% acrylonitrile S-AN/23w 72TE2
51.0 mol% acrylonitrile S-AN/51x 82MAN
_____________________________________________________________________________
52.0 mol% styrene S-MMA/52x 70KOT
_____________________________________________________________________________
Styrene/α-methylstyrene copolymer
20 mol% styrene S-αMS/20x 95PFO
_____________________________________________________________________________
Styrene/cellulose diacetate graft copolymer
77.4 wt% grafted polystyrene gS-CDA/77w 82GOL
_____________________________________________________________________________
Tetrafluoroethylene/trifluoronitrosomethane copolymer
1:1, alternating TFE-TFNM/50x 61MOR
_____________________________________________________________________________
7.5 mol% butyralized PVA VAL-VBU/08x 84SHI
_____________________________________________________________________________
Vinyl amine/vinyl caprolactam copolymer
3 mol% vinyl amine VAMN-VCPL/03x 91TAG
3.8 mol% vinyl amine VAMN-VCPL/04x 94TAG
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer-solvent systems and corresponding UCST and/or LCST values
_____________________________________________________________________________
Copolymer (B) Mn/ Mw/ Mη / Solvent UCST/ LCST/
_____________________________________________________________________________
DMA-BA/15w water 346.2
_____________________________________________________________________________
DMA-BOEA/50w water < 273.2
_____________________________________________________________________________
DMA-EOEA/50w water 319.2
DMA-EOEA/75w water 285.2
_____________________________________________________________________________
DMA-EA/30w water 347.2
DMA-EA/55w water < 273.2
_____________________________________________________________________________
DMA-MOEA/38x water 353.2
DMA-MOEA/50w water 343.2
_____________________________________________________________________________
DMA-MA/30w water 371.2
DMA-MA/70w water < 273.2
_____________________________________________________________________________
DMA-PA/20w water 353.2
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
DMS-MPS/15w 9100 41200 2-propanone 282.45
DMS-MPS/15w 9100 41200 anisole 291.45
_____________________________________________________________________________
E-P/33x 145000 cyclohexane 534.
E-P/33x 145000 cyclopentane 490.
E-P/33x 145000 2,2-dimethylbutane 428.
E-P/33x 145000 3,4-dimethylhexane 541.
E-P/33x 145000 2,2-dimethylpentane 472.
E-P/33x 145000 3-ethylpentane 511.
E-P/33x 145000 n-heptane 502.
E-P/33x 145000 n-hexane 455.
E-P/33x 145000 2-methylbutane 396.
E-P/33x 145000 methylcyclohexane 558.
E-P/33x 145000 methylcyclopentane 512.
E-P/33x 145000 2-methylhexane 486.
E-P/33x 145000 n-nonane 558.
E-P/33x 145000 n-octane 528.
E-P/33x 145000 n-pentane 409.
E-P/33x 145000 2,2,4,4-tetramethylpentane 539.
E-P/33x 145000 2,2,3-trimethylbutane 500.
E-P/33x 145000 2,2,4-trimethylpentane 503.
_____________________________________________________________________________
E-P/43x 70000 140000 n-hexane 436.
E-P/43x 70000 140000 2-methylpentane 474.
E-P/43x 70000 140000 n-pentane 441.
_____________________________________________________________________________
E-P/53x 154000 n-heptane 493.
E-P/53x 154000 n-hexane 443.
E-P/53x 154000 n-pentane 395.
E-P/53x 154000 2,3,4-trimethylhexane 565.
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
E-P/63x 236000 n-heptane 485.
E-P/63x 236000 n-hexane 436.
E-P/63x 236000 n-nonane 547.
E-P/63x 236000 n-octane 512.
E-P/63x 236000 n-pentane 387.
_____________________________________________________________________________
E-P/75x 109000 n-heptane 475.
E-P/75x 109000 n-hexane 427.
E-P/75x 109000 n-nonane 542.
E-P/75x 109000 n-octane 509.
E-P/75x 109000 n-pentane 378.
_____________________________________________________________________________
E-P/81x 195000 n-heptane 468.
E-P/81x 195000 n-hexane 425.
E-P/81x 195000 methylcyclohexane 541.
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
E-P/81x 195000 n-nonane 540.
E-P/81x 195000 n-octane 506.
E-P/81x 195000 n-pentane 370.
_____________________________________________________________________________
E-VA/02w 52000 465000 diphenyl ether 404.2
E-VA/43x 14800 41500 methyl acetate 307.0
_____________________________________________________________________________
E-VAL/87x ∞ ∞ water 463.55 285.65
E-VAL/89x ∞ ∞ water 449.15 290.75
E-VAL/91x ∞ ∞ water 428.45 302.95
E-VAL/94x ∞ ∞ water 389.25 324.45
_____________________________________________________________________________
EO-PO/72x 36000 water 333.
EO-PO/80x 30800 water 345.
EO-PO/80x 32500 water 345.
EO-PO/87x 30100 water 355.5
_____________________________________________________________________________
NIPAM-AM/15x 3100000 water 315.15
NIPAM-AM/30x 4500000 water 326.15
NIPAM-AM/45x 3900000 water 347.15
_____________________________________________________________________________
MAH-DEG/50x 2200 4200 styrene 352.15
MAH-DEG/50x 2380 4590 styrene 339.15
_____________________________________________________________________________
S-AN/21w ∞ ∞ toluene 325.4
S-AN/23w ∞ ∞ toluene 355.1
S-AN/25w 90000 147000 toluene 313.15
S-AN/51x 347000 ethyl acetate 344.15
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
S-MMA/52x ∞ ∞ cyclohexanol 334.65
_____________________________________________________________________________
S-αMS/20x 100000 114000 butyl acetate 288.85 453.05
S-αMS/20x 100000 114000 cyclohexane 285.85 484.85
S-αMS/20x 100000 114000 cyclopentane 290.95 421.05
S-αMS/20x 100000 114000 trans-decahydro- 264.15
naphthalene
S-αMS/20x 100000 114000 hexyl acetate 288.55 514.15
S-αMS/20x 100000 114000 pentyl acetate 303.15 480.65
_____________________________________________________________________________
gS-CDA/77w 480000 N,N-dimethyl- 257. 402.
formamide
formamide
formamide
formamide
gS-CDA/77w 480000 tetrahydrofuran 367.
_____________________________________________________________________________
TFE-TFNM/50x ∞ ∞ 1,1,2-trichloro- 301.6
trifluoroethane
_____________________________________________________________________________
VAL-VBU/08x ∞ ∞ water 408.0 298.25
VAL-VBU/10x ∞ ∞ water 296.45
VAL-VBU/13x ∞ ∞ water 287.55
_____________________________________________________________________________
VCPL-VAMN/03x ∞ ∞ water 308.8
VCPL-VAMN/04x 160000 water 308.8
_____________________________________________________________________________
____________________________________________________________________________________
3.6. References
61MOR Morneau, G.A., Roth, P.I., and Shultz, A.R., Trifluoronitrosomethane/tetrafluoroethylene
elastomers dilute solution properties and molecular weight, J. Polym. Sci., 55, 609, 1961.
68TER Teramachi, S. and Nagasawa, M., The fractionation of copolymers by chemical compo-
sition, J. Macromol. Sci.-Chem. A, 2, 1169, 1968.
70KOT Kotaka, T., Tanaka, T., Ohnuma, H., Murakami, Y., and Inagaki, H., Dilute solution
properties of styrene-methyl methacrylate copolymers with different architecture, Polym. J.,
1, 245, 1970.
71SHI Shibatani, K. and Oyanagi, Y., Solution properties of vinyl alcohol-ethylene copolymers in
water, Kobunshi Kagaku, 28, 361, 1971.
72TE1 Teramachi, S., Tomioka, H., and Mamoru, S., Phase-separation phenomena of copolymer
solutions and fractionation of copolymers by chemical composition, J. Macromol. Sci.-
Chem. A, 6, 97, 1972.
72TE2 Teramachi, S. and Fujikawa, T., Phase-separation phenomena of random copolymer solu-
tion: SAN random copolymer-toluene systems, J. Macromol. Sci.-Chem. A, 6, 1393, 1972.
72WHI White, J.L., Salladay, D.G., Quisenberry, D.O., and Mac Lean, D.L., Gel permeation and
thin-layer chromatographic characterization and solution properties of butadiene and
styrene homopolymers and copolymers, J. Appl. Polym. Sci., 16, 2811, 1972.
aqueous polymer solutions, J. Coll. Interface Sci., 46, 511, 1974.
75WHI White, J.L. and Patel, R.D., Phase separation conditions in polystyrene-styrene-(butadiene-
styrene) copolymer solutions, J. Appl. Polym. Sci., 19, 1775, 1975.
77BER Bernstein, R.E., Cruz, C.A., Paul, D.R., and Barlow, J.W., LCST behavior in polymer
blends, Macromolecules, 10, 681, 1977.
77DJA Djadoun, S., Goldberg, R.N., and Morawetz, H., Ternary systems containing an acidic
copolymer, a basic copolymer, and a solvent 1, Macromolecules, 10, 1015, 1977.
81CHA Charlet, G. and Delmas, G., Thermodynamic properties of polyolefine solutions at high
temperature, Polymer, 22, 1181, 1981.
81MED Medved, Z.N., Penzel, U., Denosiva, T.A., and Lebedev, V.S., Study of phase equilibrium
in mixtures of water and ethylene oxide-propylene oxide cooligomers (Russ.), Vysokomol.
Soedin., Ser. B, 23, 276, 1981.
82GOL Goloborod'ko, V.I., Valatin, S.M., and Tashmukhamedov, I.P., Vliyanie sostava i
molekulyarnoi massy privitykh sopolimerov na fasovoe ravnovesie ikh rastvorov, Uzb.
Khim. Zh., (3), 33, 1982.
82LE1 Lecourtier, J., Lafuma, F., and Quivoron, C., Compatibilization of copolymers in solution
through interchain hydrogen bonding, Eur. Polym. J., 18, 241, 1982.
82LE2 Lecourtier, J., Lafuma, F., and Quivoron, C., Study of polymer compatibilization in solution
through polymer/polymer interactions: Ternary systems poly(ethylene oxide)/styrene-
methacrylic acid copolymers/solvent, Makromol. Chem., 183, 2021, 1982.
82MAN Mangalam, P. V. and Kalpagam, V., Styrene-acrylonitrile random copolymer in ethyl
acetate, J. Polym. Sci., Polym. Phys. Ed., 20, 773, 1982.
84HEF Hefford, R.J., Polymer mixing in aqueous solution, Polymer, 25, 979, 1984.
84SHI Shiomi, T., Imai, K., Watanabe, C., and Miya, M., Thermodynamic and conformational
properties of partially butyralized poly(vinyl alcohol) in aqueous solution, J. Polym. Sci.,
Polym. Phys. Ed., 22, 1305, 1984.
85VED Vedikhina, L.I., Kurmaeva, A.I., and Barabanov, V.P., Phase separation in solutions of
polyampholytes of acrylic acid-2-methyl-5-vinylpyridine copolymers (Russ.), Vysokomol.
Soedin., Ser. A, 27, 2131, 1985.
New York, 1986.
____________________________________________________________________________________
86IRA Irani, C.A. and Cozewith, C., Lower critical solution temperature behavior of ethylene-
86KUE Kuecuekyavruz, Z. and Kuecuekyavruz, S., Theta-behaviour of poly(p-tert-butylstyrene)-b-
poly(dimethylsiloxane)-b-poly(p-tert-butylstyrene), Makromol. Chem., 187, 2469, 1986.
86RAE Raetzsch, M.T., Kehlen, H., Browarzik, D., and Schirutschke, M., Cloud-point curve for the
system copoly(ethylene-vinyl acetate) + methyl acetate. Measurement and prediction by
continuous thermodynamics, J. Macromol. Sci.-Chem. A, 23, 1349, 1986.
87ANA Ananthapadmanabhan, K.P. and Goddard, E.D., The relationship between clouding and
aqueous biphase formation in polymer solutions, Coll. Surfaces, 25, 393, 1987.
88ROG Rogovina, L.Z., Nikiforova, G.G., Martirosov, V.A., Shilov, V.V., Gomza, Yu.P., and
Slonimskii, G.L., Parametry termodinamicheskoi nesovmestimosti v sisteme poliarilensul'f-
oksid-polibutadien i ikh svyaz' so svoistvami poliblochnykh sopolimerov na ikh osnove,
88SCH Schubert, F., Friedrich, K., Hess, M., and Kosfeld, R., Investigations on phase diagrams of a
coil-polymer (PC) and a semiflexible thermotropic mainchain polymer (PET-co-PHB) in
solution, Mol. Cryst. Liq. Cryst., 155, 477, 1988.
89INO Inoue, T. and Ougizawa, T., Characterization of phase behavior in polymer blends by light
scattering, J. Macromol. Sci.-Chem. A, 26, 147, 1989.
90CHE Chen, L.-W. and Young, T.H., EVAL membranes for blood dialysis, Makromol. Chem.,
Macromol. Symp., 33, 183, 1990.
90KYO Kyoumen, M., Baba, Y., Kagemoto, A., and Beatty, C.L., Determination of the consolute
temperature of poly[styrene-co-(butyl methacrylate)] solutions by simultaneous
measurement of differential thermal analysis and laser transmittance, Macromolecules, 23,
1085, 1990.
90SAM Samii, A.A., Lindman, B., and Karstrom, G., Phase behavior of some nonionic polymers in
non-aqueous solvents, Prog. Coll. Polym. Sci., 82, 280, 1990.
90SIM Simek, L., Petrik, S., Hadobas, F., and Bohdanecky, M., Solubility in water of triblock
(PEP) copolymers of ethylene and propylene oxides, Eur. Polym. J., 26, 375, 1990.
90VAN Van der Haegen, R. and Van Opstal, L., Thermodynamic investigation of the phase
separation behaviour of ethylene-vinyl acetate copolymers in diphenyl ether, Makromol.
Chem., 191, 1871, 1990.
91TAG Tager, A.A., Safronov, A.P., Berezyuk, E.A., and Galaev, I.Yu., Hydrophobic interactions
Soedin., Ser. B, 33, 572, 1991.
92LEC Lecointe, J.P., Pascault, J.P., Suspene, L., and Yang, Y.S., Cloud-point curves and
interaction parameters of unsaturated polyester-styrene solutions, Polymer, 33, 3226, 1992.
92MUE Mueller, K.F, Thermotropic aqueous gels and solutions of N,N-dimethylacrylamide-acrylate
copolymers, Polymer, 33, 3470, 1992.
92WAN Wang, J., Khokhlov, A., Peiffer, D.G., and Chu, B., Phase equilibria in the ternary system
zinc sulfonated polystyrene/poly(ethyl acrylate-4-vinylpyridine)/tetrahydrofuran, Macro-
molecules, 25, 2566, 1992.
92YAN Yang, J., Wegner, G., and Koningsveld, R., Phase behavior of ethylene oxide-dimethyl-
siloxane PEO-PDMS-PEO triblock copolymers with water, Colloid Polym. Sci., 270, 1080,
1992.
93FEI Feil, H., Bae, Y.H., Feifen, J., and Kim, S.W., Effect of comonomer hydrophobicity and
ionization on the lower critical solution temperature of N-isopropylacrylamide copolymers,
93JOH Johansson, H.O., Karlstroem, G., and Tjerneld, F., Experimental and theoretical study of
phase separation in aqueous solutions of clouding polymers and carboxylic acids,
____________________________________________________________________________________
93PAS Pashkin, I.I., Kirsh, Yu.E., Zubov, V.P., Anisimova, T.V., Kuz'kina, I.F., Voloshina, Ya.P.,
and Krylov, A.V., Synthesis of water-soluble N-vinylcaprolactam-based copolymers and
physicochemical properties of their aqueous solutions (Russ.), Vysokomol. Soedin., Ser. A,
35, 481, 1993.
93PO1 Podesva, J., Stejskal, J., and Kratochvil, P., Fractionation of a diblock copolymer in a
demixing-solvent system, J. Appl. Polym. Sci., 49, 1265, 1993.
93PO2 Podesva, J., Stejskal, J., Prochazka, O., Spacek, P., and Enders, S., Fractionation of a
statistical copolymer in a demixing-solvent system: Theory and experiment, J. Appl. Polym.
Sci., 48, 1127, 1993.
93TAG Tager, A.A., Klyuzhin, E.S., Adamova, L.V., and Safronov, A.P., Thermodynamics of
Ser. B, 35, 1357, 1993.
94KAW Kawai, T., Terajima, T., Ogaswara, T., Baba, H., and Teramachi, S., Phase separation phen-
omena in quasi-ternary systems of demixing solvents and poly(styrene-stat-methyl meth-
acrylate) and composition fractionation, Kogakuin Daigaku Kenkyu Hokoku, 76, 23, 1994.
94KUR Kuramoto, N., Shishida, Y., and Nagai, K., Preparation of thermally responsive electroactive
poly(N-acryloylpyrrolidine-co-vinylferrocene), Macromol. Rapid Commun., 15, 441, 1994.
94MOD Modlin, R.F., Alred, P.A., and Tjerneld, F., Utilization of temperature-induced phase
separation for the purification of ecdysone and 20-hydroxyecdysone from spinach, J.
Chromatogr. A, 668, 229, 1994.
94MUM Mumick, P.S. and McCormick, C.L., Water soluble copolymers. 54: N-isopropylacrylamide-
co-acrylamide copolymers in drag reduction: synthesis, characterization, and dilute solution
behavior, Polym. Eng. Sci., 34, 1419, 1994.
94SIQ Siqueira, D.F., Nunes, S.P., and Wolf, B.A., Solution properties of a diblock copolymer in a
selective solvent of marginal quality 1, Macromolecules, 27, 234, 1994.
temperature and hydrophobic hydration in aqueous polymer solutions, Coll. Polym. Sci.,
272, 1234, 1994.
94ZH1 Zhang, K., Carlsson, M., Linse, P., and Lindman, B., Phase behavior of copolymer-
homopolymer mixtures in aqueous solution, J. Phys. Chem., 98, 2452, 1994.
94ZH2 Zhang, K., Karlstroem, G., and Lindman, B., Ternary aqueous mixtures of a nonionic
polymer with a surfactant or a second polymer, J. Phys. Chem., 98, 4411, 1994.
95KIM Kim, Y.-H., Kwon, C., Bae, Y.H., and Kim, S.W., Saccharide effect on the lower critical
solution temperature of thermosensitive polymers, Macromolecules, 28, 939, 1995.
95PFO Pfohl, O., Hino, T., and Prausnitz, J.M., Solubilities of styrene-based polymers and
copolymers in common solvents, Polymer, 36, 2065, 1995.
95SVE Svensson, M., Linse, P., and Tjerneld, F., Phase behavior in aqueous two-phase systems
containing micelle-forming block copolymers, Macromolecules, 28, 3597, 1995.
96ELE El-Ejmi, A.A.S. and Huglin, M.B., Characterization of N,N-dimethylacrylamide/2-methoxy-
ethylacrylate copolymers and phase behaviour of their thermotropic aqueous solutions,
Polym. Internat., 39, 113, 1996.
96MIY Miyazaki, H. and Kataoka, K., Preparation of polyacrylamide derivatives showing thermo-
reversible coacervate formation and their potential application to two-phase separation
processes, Polymer, 37, 681, 1996.
97CHO Cho, S.H., Jhon, M.S., Yuk, S.H., and Lee, H.B., Temperature-induced phase transition of
poly(N,N-dimethylaminoethyl methacrylate-co-acrylamide), J. Polym. Sci., Part B: Polym.
Phys., 35, 595, 1997.
97ELE El-Ejmi, A.A.S. and Huglin, M.B., Behaviour of poly(N,N-dimethylacrylamide-co-2-
methoxyethylacrylate) in non-aqueous solution and LCST behaviour in water, Eur. Polym.
J., 33, 1281, 1997.
97HOL Holmqvist, P., Alexandridis, P., and Lindman, B., Phase behavior and structure of ternary
amphiphilic block copolymer-alkanol-water systems: Comparison of poly(ethylene oxide)/
____________________________________________________________________________________
poly(propylene oxide) to poly(ethylene xide)/poly(tetrahydro-furan) copolymers, Langmuir,

13, 2471, 1997.
97HWA Hwang, J.H., Lee, K.H., and Lee, D.C., Study of phase behavior in SBS triblock copolymer/
polybutadiene/methyl isobutyl ketone ternary system, Pollimo, 21, 745, 1997.
97KUR Kuramoto, N., Shishido, Y., and Nagai, K., Thermosensitive and redox-active polymers:
preparation and properties of poly(N-ethylacrylamide-co-vinylferrocene) and poly(N,N-
diethylacrylamide-co-vinylferrocene), J. Polym. Sci., Part A: Polym. Chem., 35, 1967, 1997.
97PAE Pae, B.J., Moon, T.J., Lee, C.H., Ko, M.B., Park, M., Lim S., Kim, J., and Choe, C.R.,
Phase behavior in PVA/water solution, Korea Polym. J., 5, 126, 1997.
97SCH Schneider, A. and Wolf, B.A., Interfacial tension of demixed polymer solutions:
Augmentation by polymer additives, Macromol. Rapid Commun., 19, 561, 1997.
97SUW Suwa, K., Morishita, K., Kishida, A., and Akashi, M., Synthesis and functionalities of
poly(N-vinylalkylamide), J. Polym. Sci., Part A: Polym. Chem., 35, 3087, 1997.
97TOP Topp, M.D.C., Dijkstra, P.J., Talsma, H., and Feijen, J., Thermosensitive micelle-forming
block copolymers of poly(ethylene glycol) and poly(N-isopropylacrylamide),
97YOU Young, T.-H., Lai, J.-Y., You, W.-M., and Cheng, L.-P., Equilibrium phase behavior of the
membrane forming water-DMSO-EVAL copolymer system, J. Membr. Sci., 128, 55, 1997.
98KUR Kuramoto, N. and Shishido, Y., Property of thermo-sensitive and redox-active poly(N-
cyclopropylacrylamide-co-vinylferrocene) and poly(N-isopropylacrylamide-co-vinylferro-
cene), Polymer, 39, 669, 1998.
98LI1 Li, M., Zhu, Z.-Q., Wu, Y.-T., and Lin, D.-Q., Measurement of phase diagrams for new
aqueous two-phase systems and prediction by a generalized multicomponent osmotic virial
equation, Chem. Eng. Sci., 53, 2577, 1998.
98LI2 Li, M., Wang, Y.-X., and Zhu, Z.-Q., Liquid-liquid equilibria for random copolymer of
ethylene oxide + propylene oxide + salt + water, J. Chem. Eng. Data, 43, 93, 1998.
98YOU Young, T.-H., Cheng, L.-P., Hsieh, C.-C., and Chen, L.-W., Phase behavior of EVAL
polymers in water-2-propanol cosolvent, Macromolecules, 31, 1229, 1998.
99ERB Erbil, C., Akpinar, F.D., and Uyanik, N., Investigation of the thermal aggregations in
aqueous poly(N-isopropylacrylamide-co-itaconic acid) solutions, Macromol. Chem. Phys.,
200, 2448, 1999.
99LIW Li, W., Zhu, Z.-Q., and Lin, D.-Q., Liquid-liquid equilibria of aqueous two-phase systems
containing ethylene oxide-propylene oxide random copolymer and ammonium sulfate, J.
Chem. Eng. Data, 44, 921, 1999.
99MIK Mikhailov, Yu.M., Ganina, L.V., Makhonina, L.I., Smirnov, V.S., and Shapayeva, N.V.,
Mutual diffusion and phase equilibrium in copolymers of nonyl acrylate and acrylic acid -
diglycidyl ether of bisphenol-A systems, J. Appl. Polym. Sci., 74, 2353, 1999.
2000AZU Azuma, T., Tyagi, O.S., and Nose, T., Static and dynamic properties of block-copolymer
solution in poor solvent I, Polym. J., 32, 151, 2000.
2000BOK Bokias, G., Staikos, G., and Iliopoulos, I., Solution properties and phase behaviour of
copolymers of acrylic acid with N-isopropylacrylamide, Polymer, 41, 7399, 2000.
2000KIM Kim, C., Lee, S.C., Kang, S.W., Kwon, I.C., and Jeong, S.Y., Phase-transition charac-
teristics of amphiphilic poly(2-ethyl-2-oxazoline)/poly(ε-caprolactone) block copolymers in
aqueous solutions J. Polym. Sci., Part B: Polym. Phys., 38, 2400, 2000.
2000SAH Sahakaro, K., Chaibundit, C., Kaligradaki, Z., Mai, S.-M., Heatley, F., Booth, C., Padget,
J.C., and Shirley, I.M., Clouding of aqueous solutions of difunctional tapered statistical
copolymers of ethylene oxide and 1,2-butylene oxide, Eur. Polym. J., 36, 1835, 2000.
2000SCH Schneider, A. and Wolf, B.A., Specific features of the interfacial tension in the case of
phase separated solutions of random copolymers, Polymer, 41, 4089, 2000.
OF COPOLYMER SOLUTIONS
IN SUPERCRITICAL FLUIDS
4.1. Experimental data of quasibinary copolymer solutions
_____________________________________________________________________________
Copolymers from butylene oxide and ethylene oxide
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
poly(butylene oxide)-b-poly(ethylene oxide)
diblock copolymer
44.4 mol% ethylene oxide BO-EO/44x 98ONE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol
_____________________________________________________________________________
BO-EO/44x 1620 ( = 960 + 660) SAM 185, hydroxyl terminated
_____________________________________________________________________________
Experimental HPPE data:

_____________________________________________________________________________
copolymer (B): BO-EO/44x 98ONE

solvent (A): carbon dioxide CO2 124-38-9
wB 0.001
T/K 308.15
P/MPa 27.58
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and acrylic acid
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
3.0 wt% acrylic acid E-AA/03w 92WIN
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-AA/03w 37500 183000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-AA/03w 92WIN

solvent (A): ethene C2H4 74-85-1
wB 0.019 0.019 0.019 0.019 0.019 0.082 0.082 0.082 0.082

T/K 413.15 433.15 453.15 473.15 493.15 413.15 433.15 453.15 473.15
P/MPa 196.8 178.4 163.1 152.2 141.7 186.7 166.6 153.1 143.3
wB 0.082 0.128 0.128 0.128 0.128 0.128 0.186 0.186 0.186
T/K 493.15 413.15 433.15 453.15 473.15 493.15 413.15 433.15 453.15
P/MPa 135.4 181.2 162.8 150.1 140.3 132.2 172.1 154.3 142.5
continue
____________________________________________________________________________________
continue
wB 0.186 0.186 0.231 0.231 0.231 0.231 0.231 0.295 0.295

T/K 473.15 493.15 413.15 433.15 453.15 473.15 493.15 413.15 433.15
P/MPa 134.0 128.5 165.6 148.9 137.7 129.8 124.2 153.1 139.8
wB 0.295 0.295 0.295 0.318 0.318 0.318 0.318 0.318 0.338
T/K 453.15 473.15 493.15 413.15 433.15 453.15 473.15 493.15 413.15
P/MPa 130.2 123.1 118.0 150.4 136.6 127.9 121.3 115.8 146.0
wB 0.338 0.338 0.338 0.338 0.428 0.428 0.428 0.428 0.428
T/K 433.15 453.15 473.15 493.15 413.15 433.15 453.15 473.15 493.15
P/MPa 134.1 125.3 118.9 113.4 127.5 119.4 113.4 108.7 105.1
wB 0.510 0.510 0.510 0.510 0.510
T/K 413.15 433.15 453.15 473.15 493.15
P/MPa 109.8 105.5 102.0 99.0 96.0

T/K = 403.15
Total feed concentration of the copolymer in the homogeneous system: wB = 0.155
_____________________________________________________________________________
_____________________________________________________________________________
MPa g/mol g/mol g/mol g/mol g/mol g/mol
_____________________________________________________________________________
116.0 0.508 0.982 2818 8803 18920
161.0 0.711 0.951 9188 31060 73720
178.5 0.789 0.918 42880 176300 510700 13170 52620 156100
188.0 0.845 (cloud-point) 37500 183000 601000 (feed sample)
_____________________________________________________________________________

T/K = 433.15
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
94.0 0.438 0.993 1520 6745 13920
113.0 0.536 0.982 2500 8300 17620
129.0 0.633 0.966 8200 29070 69600
147.7 0.766 0.939 41500 173700 472800 11600 47030 146200
157.5 0.836 (cloud-point) 37500 183000 601000 (feed sample)
_____________________________________________________________________________

wB 0.038 0.038 0.038 0.038 0.057 0.057 0.057 0.057 0.076

T/K 433.15 453.15 473.15 493.15 433.15 453.15 473.15 493.15 433.15
P/MPa 203.4 176.8 157.3 142.0 195.7 170.5 152.3 138.9 191.2
wB 0.076 0.076 0.076 0.116 0.116 0.116 0.116 0.150 0.150
T/K 453.15 473.15 493.15 433.15 453.15 473.15 493.15 433.15 453.15
P/MPa 167.2 148.9 134.0 189.5 164.2 146.2 132.5 183.9 161.1
wB 0.150 0.150 0.215 0.215 0.215 0.215 0.260 0.260 0.260
T/K 473.15 493.15 433.15 453.15 473.15 493.15 433.15 453.15 473.15
P/MPa 145.2 130.5 172.4 152.2 135.4 125.4 165.3 146.3 132.6
wB 0.260 0.295 0.295 0.295 0.295 0.335 0.335 0.335 0.335
T/K 493.15 433.15 453.15 473.15 493.15 433.15 453.15 473.15 493.15
P/MPa 121.8 158.3 142.0 129.8 119.0 147.5 135.9 125.6 115.5
wB 0.383 0.383 0.383 0.383 0.430 0.430 0.430 0.430 0.505
T/K 433.15 453.15 473.15 493.15 433.15 453.15 473.15 493.15 433.15
P/MPa 137.5 126.9 118.5 112.2 130.1 120.2 112.0 106.3 114.4
wB 0.505 0.505 0.505
T/K 453.15 473.15 493.15
P/MPa 108.0 103.1 99.2
____________________________________________________________________________________

T/K = 433.15
_____________________________________________________________________________
P/ wA
_____________________________________________________________________________
124.9 0.5550 0.9870
138.1 0.6130 0.9735
158.6 0.7130 0.9540
172.0 0.7855 0.9300
182.0 0.8435 (cloud-point)
_____________________________________________________________________________

wB 0.043 0.043 0.043 0.102 0.102 0.102 0.102 0.160 0.160

T/K 453.15 473.15 493.15 443.15 453.15 473.15 493.15 443.15 453.15
P/MPa 192.4 165.6 143.9 196.2 181.4 157.7 140.2 186.0 171.4
wB 0.160 0.160 0.203 0.203 0.203 0.203 0.272 0.272 0.272
T/K 473.15 493.15 443.15 453.15 473.15 493.15 443.15 453.15 473.15
P/MPa 150.8 135.3 178.2 165.3 146.3 132.5 166.0 156.4 140.6
wB 0.272 0.330 0.330 0.330 0.330 0.410 0.410 0.410 0.410
T/K 493.15 443.15 453.15 473.15 493.15 443.15 453.15 473.15 493.15
P/MPa 126.8 155.5 147.0 134.0 122.5 141.0 134.3 123.6 114.9
wB 0.500 0.500 0.500 0.500
T/K 443.15 453.15 473.15 493.15
P/MPa 121.4 117.0 110.8 104.8
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and butyl acrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
15.0 wt% butyl acrylate E-BA/15w 96MUE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-BA/15w 6980 34900 sample from BASF AG, Ger.
E-BA/67w 11500 37000 synthesized in the laboratory
E-BA/75w 13900 35200 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-BA/15w 96MUE

wB 0.025 0.025 0.025 0.025 0.025 0.050 0.050 0.050 0.050

T/K 522.85 498.05 473.05 448.55 423.85 524.05 498.35 473.85 449.15
P/MPa 117.7 121.5 126.3 132.3 139.6 116.9 120.8 125.5 131.3
continue
____________________________________________________________________________________
continue
wB 0.050 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150
T/K 423.75 522.85 498.05 473.15 448.95 424.15 524.15 498.25 473.55
P/MPa 138.8 121.2 124.1 127.5 132.1 139.4 120.8 122.5 125.1
wB 0.150 0.150 0.200 0.200 0.200 0.200 0.200
T/K 448.95 424.35 523.35 498.05 473.35 449.15 423.35
P/MPa 128.5 133.6 117.3 118.8 121.5 124.8 128.7

wB 0.034 0.034 0.034 0.034 0.034 0.050 0.050 0.050 0.050

T/K 523.05 498.55 472.65 448.15 423.15 523.95 497.85 473.05 449.25
P/MPa 116.8 120.6 125.4 131.6 138.4 118.4 121.3 125.3 130.8
wB 0.050 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150
T/K 423.95 523.55 498.85 473.45 449.05 424.25 524.85 498.15 472.65
P/MPa 139.0 121.7 123.6 128.2 131.6 139.4 120.3 122.1 128.4
wB 0.150 0.150 0.199 0.199 0.199 0.199
T/K 448.95 424.25 523.25 498.55 473.35 448.95
P/MPa 130.6 134.7 120.7 123.0 126.1 129.8

wB 0.025 0.025 0.025 0.025 0.025 0.050 0.050 0.050 0.050

T/K 523.65 498.55 473.05 448.55 423.45 523.75 498.05 472.95 448.05
P/MPa 111.5 115.9 120.4 127.2 134.4 109.4 113.1 117.2 122.3
wB 0.050 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150
T/K 423.25 523.45 498.05 473.15 448.45 423.45 523.85 498.35 472.95
P/MPa 129.7 107.1 109.8 113.1 116.9 121.9 105.9 108.1 111.5
wB 0.150 0.150 0.199 0.199 0.199 0.199 0.199
T/K 448.05 423.85 523.75 498.05 473.25 449.15 424.05
P/MPa 115.1 119.8 104.9 106.7 109.5 115.4 120.5

wB 0.168 0.168 0.168 0.168 0.168

T/K 522.35 498.15 473.65 448.35 424.65
P/MPa 96.6 98.4 100.1 102.3 104.0
____________________________________________________________________________________

wB 0.069 0.069 0.069 0.069 0.069 0.069

T/K 524.05 499.05 474.45 448.65 423.75 398.75
P/MPa 89.4 90.3 92.9 96.5 99.8 102.1
_____________________________________________________________________________
Copolymers from ethylene and 1-hexene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
10.6 wt% 1-hexene E-H/11w 2000CH3
16.1 wt% 1-hexene E-H/16w 99KIN
20.6 wt% 1-hexene E-H/21w 2000CH2
35.0 wt% 1-hexene E-H/35w(1) 2000CH3
35.0 wt% 1-hexene E-H/35w(2) 2000CH3
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-H/11w 52600 80000
E-H/16w 60000 129000
E-H/21w 51300 126000
E-H/35w(1) 48100 103000
E-H/35w(2) 112100 139000
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-H/11w 2000CH3

wB 0.148 0.148 0.148 0.148

T/K 393.25 413.15 433.25 453.15
P/MPa 168.0 154.5 146.0 138.9
copolymer (B): E-H/16w 99KIN

wB 0.150 0.150 0.150 0.150 0.150 0.150

T/K 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 156.0 144.3 137.3 129.1 123.1 118.6
copolymer (B): E-H/35w(1) 2000CH3

wB 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100

T/K 393.15 403.15 413.15 423.15 433.15 443.15 453.15 393.15 403.15
P/MPa 136.3 132.6 129.6 127.0 124.9 122.9 121.0 134.8 131.4
wB 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150 0.150
T/K 413.15 423.15 433.15 443.15 453.15 393.15 403.15 413.15 423.15
P/MPa 128.3 125.8 123.7 121.8 120.8 129.4 126.1 123.6 121.5
wB 0.150 0.150 0.150
T/K 433.15 443.15 453.15
P/MPa 119.8 118.7 119.4

solvent (A): propane C3H8 74-98-6
wB 0.010 0.010 0.010 0.010 0.051 0.051 0.051 0.051 0.148

T/K 363.15 373.25 413.15 453.15 363.15 373.15 413.15 453.15 373.25
P/MPa 50.3 50.0 49.9 50.7 51.0 50.4 50.4 50.4 50.6
wB 0.148 0.148
T/K 413.15 453.15
P/MPa 50.4 51.1
____________________________________________________________________________________


T/K = 453.15
wB 0.018 0.031 0.055 0.066 0.075 0.079 0.089 0.098 0.100
P/bar 446.0 454.0 456.0 459.0 468.0 475.0 478.0 470.0 474.0
wB 0.108 0.114 0.148
P/bar 471.0 466.0 459.0


wB 0.150 0.150 0.150 0.150 0.150 0.150
T/K 313.15 343.15 363.05 373.05 413.15 453.15
P/MPa 37.3 38.1 39.1 39.7 42.3 44.6


wB 0.009 0.009 0.009 0.009 0.009 0.009 0.152 0.152 0.152
T/K 313.25 353.25 368.25 373.15 413.15 453.15 353.25 373.15 413.15
P/MPa 39.0 36.8 37.6 37.9 40.6 42.9 37.8 39.2 41.5
wB 0.152
T/K 453.15
P/MPa 43.7
_____________________________________________________________________________
Copolymers from ethylene and methyl acrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
25.0 wt% methyl acrylate E-MA/25w 96MUE
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-MA/25w 17000 75400 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-MA/25w 96MUE

wB 0.010 0.010 0.010 0.010 0.010 0.050 0.050 0.050 0.050

T/K 522.65 498.15 473.85 448.55 424.05 523.95 498.85 472.75 449.15
P/MPa 113.7 119.8 123.6 128.8 133.0 115.9 119.4 123.2 127.5
wB 0.050 0.050 0.100 0.100 0.100 0.100 0.100 0.113 0.113
T/K 423.95 404.15 525.05 498.35 474.35 448.65 424.95 523.15 498.35
P/MPa 134.2 140.0 117.3 117.4 120.2 124.6 129.2 117.2 119.0
wB 0.113 0.113 0.113 0.149 0.149 0.149 0.149 0.149 0.207
T/K 473.55 448.85 423.45 522.85 498.55 473.25 448.45 423.05 523.95
P/MPa 122.7 125.5 131.2 116.7 118.8 121.2 125.0 130.2 109.4
wB 0.207 0.207 0.207 0.207
T/K 497.85 473.05 448.85 424.15
P/MPa 112.2 115.5 119.5 124.1

wB 0.010 0.010 0.010 0.010 0.010 0.050 0.050 0.050 0.050

T/K 523.75 498.35 473.75 448.05 423.55 522.95 498.65 473.95 449.05
P/MPa 125.8 133.7 140.6 149.7 161.3 124.9 130.8 138.2 148.5
wB 0.050 0.050 0.101 0.101 0.101 0.101 0.101 0.150 0.150
T/K 423.95 404.05 524.65 499.15 473.25 448.45 424.05 524.05 498.95
P/MPa 163.1 178.8 123.0 128.4 135.6 145.0 162.0 122.7 127.8
wB 0.150 0.150 0.150 0.200 0.200 0.200 0.200
T/K 473.45 448.95 423.55 523.75 498.45 473.85 448.45
P/MPa 132.3 140.6 150.6 117.3 122.1 128.2 136.2
____________________________________________________________________________________

wB 0.011 0.011 0.011 0.011 0.011 0.050 0.050 0.050 0.050

T/K 523.85 498.95 473.55 448.45 423.75 523.25 498.35 473.15 448.85
P/MPa 136.5 145.5 157.8 165.2 206.4 136.1 145.2 157.7 174.4
wB 0.050 0.050 0.101 0.101 0.101 0.101 0.101 0.150 0.150
T/K 423.85 403.65 523.65 498.25 473.25 448.25 423.15 523.35 498.15
P/MPa 201.3 234.3 133.6 142.0 153.0 167.4 189.3 133.9 141.0
wB 0.150 0.150 0.150 0.192 0.192 0.192 0.192 0.192
T/K 473.05 448.95 424.35 523.45 497.95 472.65 448.85 423.45
P/MPa 151.8 164.9 184.1 132.0 139.9 150.0 163.2 181.9
_____________________________________________________________________________
Copolymers from ethylene and 1-octene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
13.9 wt% 1-octene E-O/14w 2000CH1
25.8 wt% 1-octene E-O/26w 2000CH1
38.7 wt% 1-octene E-O/39w 2000CH1
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-O/14w 51200 83000 4 hexyl branches/100 ethyl units
E-O/26w 54800 115000 8 hexyl branches/100 ethyl units
E-O/39w 83300 120000 13.6 hexyl branches/100 ethyl units
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-O/14w 2000CH1

wB 0.050 0.050 0.050 0.050 0.050 0.050

T/K 453.15 413.15 393.15 373.15 368.15 363.15
P/MPa 53.4 52.8 52.8 53.2 53.5 53.7

wB 0.049 0.049 0.049

T/K 453.15 413.15 373.15
P/MPa 48.5 47.1 46.3

wB 0.010 0.010 0.010 0.010 0.010 0.049 0.049 0.049 0.049

T/K 453.15 413.15 373.15 343.15 333.15 453.15 413.15 373.15 343.15
P/MPa 38.6 36.0 33.2 34.8 37.8 40.8 38.4 35.6 33.7
wB 0.049 0.100 0.100 0.100

T/K 333.15 453.15 413.15 373.15
P/MPa 33.6 40.4 37.9 35.5
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
50.0 mol% propene E-P/50x(1) 92CH1
50.0 mol% propene E-P/50x(1) 93GRE
50.0 mol% propene E-P/50x(1) 94GR1
Ethylene/propylene/isoprene terpolymer
28.2 mol% propene, 43.6 mol% isoprene E-P-IP/28x 96ALB
36.7 mol% propene, 26.6 mol% isoprene E-P-IP/37x 96ALB
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-P/50x(1) 782 790 alternating ethylene/propylene units from
E-P-IP/28x 7650 13620 alternating ethylene/propylene units from
E-P-IP/37x 7690 13690 alternating ethylene/propylene units from
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-P/50x(1) 92CH1

solvent (A): 1-butene C4H8 106-98-9
wB = 0.151
T/K 355.05 373.15 398.15 421.65 424.05 426.35 428.15 432.95 444.45
P/bar 11.5 16.4 27.1 39.8 42.5 44.8 46.5 51.7 63.4
T/K 473.15
P/bar 90.8

wB = 0.157
T/K 376.15 378.85 382.65 397.95 423.15 447.95 473.15

P/bar 21.3 27.2 35.5 66.7 110.0 146.0 172.5
Comments: a lower critical endpoint is found at 373.15 K

wB = 0.160
T/K 346.35 348.35 350.35 355.15 361.35 361.85 367.45 373.15 398.15
P/bar 12.3 15.2 20.5 29.0 40.2 38.2 50.3 61.2 108.0
T/K 416.35 423.15 448.35 473.35
P/bar 137.3 149.0 183.0 213.4

____________________________________________________________________________________

wB = 0.152
T/K 334.45 336.05 339.55 343.75 355.15 373.15 398.15 423.75 448.15
P/bar 8.4 13.1 19.5 28.4 54.0 90.8 137.3 177.3 210.1
T/K 473.15
P/bar 240.5
copolymer (B): E-P/50x(1) 93GRE, 94GR1

wB 0.156 0.156 0.156 0.152 0.152

T/K 293.15 323.15 363.15 423.15 475.15
P/bar 571.5 555.0 550.0 600.9 689.6

wB 0.156 0.156 0.156 0.158 0.158 0.157 0.158 0.158 0.158

T/K 308.15 323.15 325.65 348.15 373.15 398.15 448.15 468.15 473.15
P/bar 1080.1 1018.6 1001.1 941.9 897.9 899.9 899.1 892.8 900.0

wB 0.038 0.038 0.038 0.038 0.038

T/K 353.15 373.15 398.15 423.15 473.15
P/bar 1722.5 1569.0 1389.0 1235.5 1132.7
copolymer (B): E-P/50x(3) 92CH1, 92CH2

solvent (A): 1-hexene C6H12 592-41-6

continue
____________________________________________________________________________________
continue
wB = 0.160
T/K 427.15 447.95 467.85 473.15 477.95 478.65 473.15 477.95 478.55
P/bar 7.2 12.7 17.2 23.5 29.4 31.6 19.3 20.0 20.4
(VLE VLE VLE LLE LLE LLE VLLE VLLE VLLE)

solvent (A): 1-hexene C6H12 592-41-6
wB = 0.150
T/K 416.95 453.15 459.35 454.95 474.45 463.95
P/bar 8.3 14.0 18.3 28.5 43.3 17.3
(VLE VLE LLE LLE LLE VLLE)

solvent (A): propene C3H6 115-07-1
wB = 0.172
T/K 319.45 343.35 350.55 352.15 355.05 373.35 397.95 423.15 447.95
P/bar 19.0 30.2 34.4 37.7 43.0 73.0 113.0 144.0 170.0
(VLE VLE VLE LLE LLE LLE LLE LLE LLE)
T/K 473.35 352.15 353.75 355.05
P/bar 180.0 35.9 36.9 38.3
(LLE VLLE VLLE VLLE)

wB = 0.155
T/K 272.65 298.15 325.15 356.15 373.15 398.95 423.35 447.95 472.75
P/bar 5.5 64.0 126.0 190.5 224.4 267.0 296.0 325.0 344.0
____________________________________________________________________________________
copolymer (B): E-P/50x(2) 93GRE, 94GR1, 94GR2

wB 0.018 0.073 0.150 0.216 0.281 0.392 0.018 0.073 0.150

T/K 373.15 373.75 373.15 373.35 373.45 373.15 423.15 423.15 423.15
P/bar 179.5 202.8 212.5 209.8 200.2 189.1 248.6 273.7 295.0
wB 0.216 0.329
T/K 423.15 423.15
P/bar 293.0 267.1

wB = 0.151
T/K 323.55 355.55 373.55 398.05 423.55 448.15
P/bar 273.0 312.0 332.0 361.2 388.0 412.0

wB = 0.158
T/K 264.15 265.85 271.15 274.15 277.95 280.35 285.25 287.05 293.55
P/bar 354.0 347.0 337.0 331.0 325.5 322.5 316.7 315.0 311.0
T/K 303.05 317.15 322.55 331.15 354.65 373.05 397.75 423.35 447.95
P/bar 310.6 319.5 322.3 330.0 352.0 371.0 396.4 423.0 442.3
T/K 473.55
P/bar 461.0
copolymer (B): E-P/50x(4) 93GRE, 94GR1, 94GR2

wB 0.008 0.045 0.088 0.158 0.231 0.008 0.045 0.088 0.158

T/K 373.15 373.15 373.15 373.15 373.15 423.15 423.15 423.15 423.15
P/bar 393.1 363.0 371.3 371.2 343.0 402.1 413.8 423.0 423.1
wB 0.231
T/K 423.15
P/bar 393.0
____________________________________________________________________________________
copolymer (B): E-P-IP/28x 96ALB

solvent (A): dimethyl ether C2H6O 115-10-6
wB = 0.0536
T/K 424.75 383.25 347.55 329.95

P/bar 216.6 133.0 46.2 12.2

solvent (A): dimethyl ether C2H6O 115-10-6
wB = 0.0524
T/K 423.45 411.95 410.65 384.35 362.35 348.65 328.15

P/bar 208.9 186.1 184.4 132.9 85.5 53.5 11.9

solvent (A): ethane C2H6 74-84-0
wB = 0.0722
T/K 423.65 414.15 393.75 392.85 383.05 382.25 373.75 364.85 362.25
P/bar 818.1 824.2 869.4 874.3 918.7 923.0 964.9 1005.4 1038.7

wB = 0.0843
T/K 423.75 423.15 421.65 409.15 394.35

P/bar 1249.1 1250.5 1256.2 1293.2 1352.9
____________________________________________________________________________________

wB = 0.0528
T/K 422.75 422.05 390.05 389.85 388.75 388.45 363.95 347.75 333.65
P/bar 377.8 378.3 370.2 370.2 366.6 369.5 398.0 423.0 453.0
T/K 327.25
P/bar 472.3

wB = 0.0478
T/K 424.25 390.45 363.65 339.05 335.85 310.95

P/bar 357.5 320.7 301.1 304.5 305.0 337.5
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
7.5 wt% vinyl acetate E-VA/08w 82RAE
7.5 wt% vinyl acetate E-VA/08w 84WAG
10.9 wt% vinyl acetate E-VA/11w 91NIE
27.5 wt% vinyl acetate E-VA/28w(1) 91NIE
27.5 wt% vinyl acetate E-VA/28w(2) 99KIN
29.0 wt% vinyl acetate E-VA/29w 91FIN
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
_____________________________________________________________________________
31.8 wt% vinyl acetate E-VA/32w(1) 82RAE
31.8 wt% vinyl acetate E-VA/32w(1) 84WAG
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-VA/08w 20400 145000 Leuna-Werke, Germany
E-VA/11w 29300 161600 Exxon Chemical Company
E-VA/28w(1) 35000 126500 Exxon Chemical Company
E-VA/28w(2) 61900 167000
E-VA/32w(1) 16200 45800 Leuna-Werke, Germany
E-VA/58w 35000 Exxon Chemical Company
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-VA/08w 82RAE

T/K = 433.15
wB 0.05 0.10 0.15 0.20 0.30

P/MPa 140.3 139.3 137.3 131.2 121.0
copolymer (B): E-VA/08w 84WAG

wB 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15 0.20

T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 155.0 154.5 149.5 144.9 133.2 146.4 144.9 141.9 136.8
wB 0.30 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15
T/K 413.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 126.1 140.7 139.3 137.9 131.2 121.0 135.3 134.8 133.2
wB 0.20 0.30 0.05 0.10 0.15 0.20 0.30
T/K 453.15 453.15 473.15 473.15 473.15 473.15 473.15
P/MPa 127.2 116.0 130.7 129.7 126.7 122.6 113.0
copolymer (B): E-VA/11w 91NIE

T/K = 403.15
_____________________________________________________________________________
P/ wA
_____________________________________________________________________________
88.6 0.449 0.991
108.8 0.567 0.983
125.5 0.674 0.968
136.2 0.768 0.949
_____________________________________________________________________________
____________________________________________________________________________________

T/K = 433.15
_____________________________________________________________________________
P/ wA
_____________________________________________________________________________
94.8 0.501 0.992
104.9 0.568 0.985
115.2 0.652 0.975
128.2 0.782 0.952
_____________________________________________________________________________

T/K = 433.15
wB 0.05 0.10 0.15 0.20 0.30

P/MPa 132.4 128.5 125.0 121.6 114.7

wB 0.05 0.075 0.10 0.15 0.20 0.30 0.05 0.075 0.10

T/K 393.15 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15
P/MPa 146.6 145.1 143.3 138.9 133.9 125.5 137.8 137.3 134.8
wB 0.15 0.20 0.30 0.05 0.075 0.10 0.15 0.20 0.30
T/K 413.15 413.15 413.15 433.15 433.15 433.15 433.15 433.15 433.15
P/MPa 130.4 127.0 119.6 132.4 130.4 128.5 125.0 121.6 114.7
wB 0.05 0.075 0.10 0.15 0.20 0.30 0.05 0.075 0.10
T/K 453.15 453.15 453.15 453.15 453.15 453.15 473.15 473.15 473.15
P/MPa 127.5 125.5 124.0 120.6 117.7 109.8 122.6 121.1 119.6
wB 0.15 0.20 0.30
T/K 473.15 473.15 473.15
P/MPa 116.7 113.8 105.5
____________________________________________________________________________________

wB 0.030 0.030 0.030 0.081 0.081 0.081 0.081 0.211 0.211

T/K 373.65 403.15 433.15 363.15 393.15 423.15 453.15 388.15 403.15
P/MPa 158.6 143.5 133.0 156.2 141.4 131.8 124.5 136.5 130.5
wB 0.211 0.211 0.344 0.344 0.344 0.344 0.462 0.462 0.462
T/K 433.15 448.15 398.65 403.15 433.15 453.15 373.15 433.15 463.15
P/MPa 122.8 119.6 125.5 117.5 111.4 108.2 104.2 95.0 93.5
wB 0.585 0.585 0.585
T/K 393.15 433.15 453.15
P/MPa 78.2 77.2 76.8

T/K = 403.15
_____________________________________________________________________________
_____________________________________________________________________________
P/ Mn/ M w/ Mn/ M w/ M z/
MPa g/mol g/mol g/mol g/mol g/mol
_____________________________________________________________________________
48.7 0.276 0.9992
100.1 0.543 0.989 7833 15338 30553
118.7 0.680 0.980 11676 23830 42441
134.1 0.855 (cloud point) 33400 137700 (feed sample)
_____________________________________________________________________________

T/K = 433.15
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/ wA
_____________________________________________________________________________
43.1 0.280
47.8 0.999
75.5 0.410
77.5 0.995
89.7 0.497 0.993
103.5 0.584 0.984
107.9 0.623 0.985
113.8 0.679 0.972
121.0 0.757 0.948
123.8 0.792 0.940
_____________________________________________________________________________

T/K = 463.15
_____________________________________________________________________________
P/ wA
_____________________________________________________________________________
48.1 0.252 0.9994
97.4 0.542 0.9905
108.7 0.650 0.9792
_____________________________________________________________________________

wB 0.040 0.040 0.040 0.067 0.067 0.101 0.101 0.101 0.157

T/K 373.15 403.15 463.15 393.15 433.15 393.15 433.15 453.15 373.15
P/MPa 146.6 139.8 125.5 139.7 129.0 138.5 128.0 123.8 143.5
continue
____________________________________________________________________________________
continue
wB 0.157 0.157 0.157 0.262 0.262 0.262 0.262 0.360 0.360

T/K 393.15 433.15 453.15 393.15 413.15 433.15 453.15 403.15 418.15
P/MPa 136.5 126.2 122.5 130.2 125.4 121.2 117.0 115.5 113.0
wB 0.360 0.408 0.408 0.408 0.408 0.480 0.480 0.480 0.480
T/K 453.15 393.15 413.15 433.15 453.15 373.15 393.15 433.15 449.15
P/MPa 108.2 110.6 107.5 105.2 102.8 99.2 96.5 94.0 93.8

T/K = 433.15
wB 0.05 0.10 0.15 0.20 0.30

P/MPa 121.0 120.0 118.0 115.5 109.0

wB 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15 0.20

T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 128.5 127.5 125.5 123.0 116.5 125.5 124.0 122.0 119.0
wB 0.30 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15
T/K 413.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 112.0 121.0 120.0 118.0 115.5 109.0 118.5 117.0 115.0
wB 0.20 0.30 0.05 0.10 0.15 0.20 0.30
T/K 453.15 453.15 473.15 473.15 473.15 473.15 473.15
P/MPa 112.0 105.0 115.5 113.5 111.5 109.0 102.5
copolymer (B): E-VA/28w(1) 91NIE

T/K = 433.15
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/ wA
_____________________________________________________________________________
70.8 0.998
80.0 0.996
80.8 0.450
92.8 0.551 0.987
104.0 0.981
104.2 0.600
113.8 0.693
114.2 0.964
119.0 0.745 0.945
120.5 0.936
123.8 0.792
_____________________________________________________________________________
copolymer (B): E-VA/28w(2) 99KIN

wB 0.030 0.060 0.100 0.150 0.200 0.230 0.240 0.250 0.270

T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15
P/MPa 121.6 128.7 128.3 125.9 121.4 118.0 116.9 115.7 113.4
wB 0.300 0.350 0.030 0.060 0.100 0.150 0.200 0.230 0.240
T/K 393.15 393.15 413.15 413.15 413.15 413.15 413.15 413.15 413.15
P/MPa 111.4 110.4 117.5 124.0 123.6 121.5 117.4 114.5 113.4
wB 0.250 0.270 0.300 0.350 0.030 0.060 0.100 0.150 0.200
T/K 413.15 413.15 413.15 413.15 433.15 433.15 433.15 433.15 433.15
P/MPa 112.3 110.2 108.0 107.0 113.7 119.5 119.2 117.4 113.6
wB 0.230 0.240 0.250 0.270 0.300 0.350 0.030 0.060 0.100
T/K 433.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 110.7 109.8 109.2 107.3 105.4 104.4 110.5 116.3 116.0
wB 0.150 0.200 0.230 0.240 0.250 0.270 0.300 0.350 0.030
T/K 453.15 453.15 453.15 453.15 453.15 453.15 453.15 453.15 473.15
P/MPa 113.9 110.5 108.1 107.1 106.4 104.7 102.9 101.9 108.1
wB 0.060 0.100 0.150 0.200 0.230 0.240 0.250 0.270 0.300
T/K 473.15 473.15 473.15 473.15 473.15 473.15 473.15 473.15 473.15
P/MPa 113.0 112.9 111.2 108.0 105.9 104.9 104.2 102.1 100.8
continue
____________________________________________________________________________________
continue
wB 0.350 0.030 0.060 0.100 0.150 0.200 0.230 0.240 0.250

T/K 473.15 493.15 493.15 493.15 493.15 493.15 493.15 493.15 493.15
P/MPa 99.8 105.7 110.4 110.3 108.5 105.7 103.7 102.8 101.9
wB 0.270 0.300 0.350
T/K 493.15 493.15 493.15
P/MPa 100.0 98.8 97.8
copolymer (B): E-VA/29w 91FIN

T/K = 443.15
wA 0.0116 0.0184 0.0657 0.0538 0.0777 0.0884 0.1005 0.1207 0.1430

P/MPa 1.991 3.041 5.882 8.972 12.864 14.415 16.768 20.788 24.318
wA 0.1619
P/MPa 28.143

T/K = 443.15
_____________________________________________________________________________
P/ wA
_____________________________________________________________________________
48.06 0.2719
52.08 0.9710
55.12 0.3199
67.77 0.4045 0.9364
80.71 0.5468 0.8985
81.49 0.5211 0.8930
90.12 0.7401 0.7584
_____________________________________________________________________________
____________________________________________________________________________________

solvent (A): vinyl acetate C4H6O2 108-05-4
T/K = 413.15
wA 0.042 0.077 0.079 0.114 0.115 0.205 0.245 0.237 0.318

P/MPa 0.152 0.169 0.186 0.273 0.288 0.371 0.405 0.435 0.444
wA 0.299
P/MPa 0.464

T/K = 443.15
wA 0.028 0.030 0.047 0.050 0.065 0.071 0.116 0.127 0.129

P/MPa 0.125 0.144 0.165 0.166 0.185 0.265 0.494 0.557 0.567
wA 0.322 0.456 0.684
P/MPa 0.886 1.02 1.14

T/K = 473.15
wA 0.024 0.037 0.039 0.055 0.056 0.086 0.122 0.155

P/MPa 0.179 0.211 0.234 0.425 0.495 0.543 0.788 0.935

wB 0.014 0.04 0.07 0.10 0.20 0.25 0.30 0.05 0.10

T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 433.15 433.15
P/MPa 122.6 124.0 123.1 121.6 118.7 115.2 114.2 117.9 115.1
wB 0.20 0.30 0.014 0.04 0.07 0.10 0.20 0.25 0.30
T/K 433.15 433.15 473.15 473.15 473.15 473.15 473.15 473.15 473.15
P/MPa 112.0 108.3 111.3 113.3 110.3 107.4 106.4 103.9 102.5
____________________________________________________________________________________

wB 0.014 0.04 0.07 0.10 0.15 0.20 0.25 0.30 0.014

T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15 413.15
P/MPa 122.6 124.0 123.1 121.6 122.1 119.7 115.2 114.2 119.2
wB 0.04 0.07 0.10 0.15 0.20 0.25 0.30 0.014 0.04
T/K 413.15 413.15 413.15 413.15 413.15 413.15 413.15 433.15 433.15
P/MPa 121.6 118.7 118.1 118.7 115.2 112.8 110.3 116.2 118.2
wB 0.07 0.10 0.15 0.20 0.25 0.30 0.014 0.04 0.07
T/K 433.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 115.7 114.5 114.5 110.8 110.3 108.4 114.2 115.2 112.8
wB 0.10 0.15 0.20 0.25 0.30 0.014 0.04 0.07 0.10
T/K 453.15 453.15 453.15 453.15 453.15 473.15 473.15 473.15 473.15
P/MPa 111.8 111.8 108.8 108.8 106.4 111.3 113.3 110.3 107.4
wB 0.15 0.20 0.25 0.30
T/K 473.15 473.15 473.15 473.15
P/MPa 108.4 106.4 105.9 102.5
copolymer (B): E-VA/32w(1) 82RAE

T/K = 433.15
wB 0.05 0.10 0.15 0.20 0.30

P/MPa 119.7 119.5 117.5 115.5 111.5
copolymer (B): E-VA/32w(1) 84WAG

wB 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15 0.20

T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 126.8 126.0 125.8 124.5 119.5 123.0 122.2 121.0 120.0
wB 0.30 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15
T/K 413.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 115.5 119.7 119.5 117.5 115.5 111.5 116.0 115.7 114.0
wB 0.20 0.30 0.05 0.10 0.15 0.20 0.30
T/K 453.15 453.15 473.15 473.15 473.15 473.15 473.15
P/MPa 112.0 108.0 113.5 112.5 111.0 109.2 105.5
____________________________________________________________________________________


wB 0.12 0.16 0.20 0.25 0.30 0.0075 0.12 0.16 0.20
T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 121.1 120.6 118.7 116.2 112.3 114.2 117.2 117.2 114.7
wB 0.25 0.30 0.0075 0.04 0.08 0.12 0.16 0.20 0.25
T/K 413.15 413.15 433.15 433.15 433.15 433.15 433.15 433.15 433.15
P/MPa 113.7 108.8 111.3 114.2 113.7 114.7 113.7 111.8 110.3
wB 0.30 0.0075 0.04 0.08 0.12 0.16 0.20 0.25 0.30
T/K 433.15 453.15 453.15 453.15 453.15 453.15 453.15 453.15 453.15
P/MPa 106.9 110.9 112.3 110.8 111.8 110.8 109.8 107.4 103.9
wB 0.0075 0.04 0.08 0.12 0.16 0.20 0.25 0.30
T/K 473.15 473.15 473.15 473.15 473.15 473.15 473.15 473.15
P/MPa 108.4 109.8 108.4 108.8 107.9 105.9 104.9 102.0


wB 0.009 0.04 0.08 0.12 0.20 0.25 0.30 0.009 0.04
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 473.15 473.15
P/MPa 118.7 120.1 118.2 117.4 114.9 111.8 105.9 107.9 109.8
wB 0.08 0.12 0.20 0.25 0.30
T/K 473.15 473.15 473.15 473.15 473.15
P/MPa 107.9 106.9 105.9 102.7 99.1


wB 0.009 0.04 0.08 0.12 0.20 0.25 0.304 0.009 0.04
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 413.15 413.15
P/MPa 118.7 120.1 118.2 117.4 114.9 111.8 105.9 116.2 118.2
wB 0.08 0.12 0.20 0.25 0.304 0.009 0.04 0.08 0.12
T/K 413.15 413.15 413.15 413.15 413.15 433.15 433.15 433.15 433.15
P/MPa 115.2 114.9 112.3 108.4 104.5 112.3 115.2 112.8 112.5
wB 0.20 0.25 0.304 0.009 0.04 0.08 0.12 0.20 0.25
T/K 433.15 433.15 433.15 453.15 453.15 453.15 453.15 453.15 453.15
P/MPa 110.3 106.4 103.2 110.8 112.8 110.3 108.9 107.9 104.5
wB 0.304 0.009 0.04 0.08 0.12 0.20 0.25 0.30
T/K 453.15 473.15 473.15 473.15 473.15 473.15 473.15 473.15
P/MPa 100.2 107.9 109.8 107.9 106.9 105.9 102.7 99.1
____________________________________________________________________________________


wB 0.068 0.068 0.068 0.068 0.157 0.157 0.178 0.178 0.178
T/K 383.15 393.15 433.15 453.15 383.15 433.15 373.15 403.15 453.15
P/MPa 118.2 115.8 108.5 105.7 116.5 107.0 116.0 110.0 103.2
wB 0.300 0.300 0.300 0.393 0.393 0.393 0.393 0.393 0.439
T/K 393.15 403.15 433.15 353.15 373.15 403.15 433.15 453.15 373.15
P/MPa 107.5 106.0 102.3 107.4 103.5 99.2 96.4 95.0 98.0
wB 0.439
T/K 433.15
P/MPa 92.2


wB 0.014 0.04 0.08 0.12 0.20 0.25 0.32 0.014 0.04
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 473.15 473.15
P/MPa 92.7 98.6 100.0 99.0 98.6 96.6 94.3 86.8 93.6
wB 0.08 0.12 0.20 0.25 0.32
T/K 473.15 473.15 473.15 473.15 473.15
P/MPa 93.2 91.2 90.7 88.7 86.8


wB 0.014 0.04 0.08 0.12 0.16 0.20 0.25 0.32 0.014
T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15 413.15
P/MPa 92.7 98.6 100.0 99.0 98.6 99.0 96.6 94.2 90.2
wB 0.04 0.08 0.12 0.16 0.20 0.25 0.32 0.014 0.04
T/K 413.15 413.15 413.15 413.15 413.15 413.15 413.15 433.15 433.15
P/MPa 97.1 98.1 96.8 97.1 96.9 95.1 93.2 88.7 96.1
wB 0.08 0.12 0.16 0.20 0.25 0.32 0.014 0.04 0.08
T/K 433.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 96.1 94.6 95.1 94.3 92.7 90.2 87.8 95.1 94.6
wB 0.12 0.16 0.20 0.25 0.32 0.014 0.04 0.08 0.12
T/K 453.15 453.15 453.15 453.15 453.15 473.15 473.15 473.15 473.15
P/MPa 92.7 93.2 92.7 90.4 88.7 86.8 93.6 93.2 91.2
wB 0.16 0.20 0.25 0.32
T/K 473.15 473.15 473.15 473.15
P/MPa 91.2 90.7 88.7 80.8
____________________________________________________________________________________

wB 0.05 0.10 0.20 0.30

T/K 433.15 433.15 433.15 433.15
P/MPa 111.2 111.0 108.4 104.4

wB 0.007 0.03 0.08 0.12 0.16 0.20 0.25 0.30 0.007

T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15 413.15
P/MPa 114.2 116.2 118.2 116.7 116.7 115.2 113.3 110.8 110.8
wB 0.03 0.08 0.12 0.16 0.20 0.25 0.30 0.007 0.03
T/K 413.15 413.15 413.15 413.15 413.15 413.15 413.15 433.15 433.15
P/MPa 113.3 114.9 112.8 112.8 112.3 109.8 106.7 108.4 110.8
wB 0.08 0.12 0.16 0.20 0.25 0.30 0.007 0.03 0.08
T/K 433.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 111.8 109.3 108.8 108.4 107.4 104.1 105.9 108.4 108.4
wB 0.12 0.16 0.20 0.25 0.30 0.007 0.03 0.08 0.12
T/K 453.15 453.15 453.15 453.15 453.15 473.15 473.15 473.15 473.15
P/MPa 106.9 106.9 105.9 103.9 100.8 104.4 105.9 106.4 104.4
wB 0.16 0.20 0.25 0.30
T/K 473.15 473.15 473.15 473.15
P/MPa 104.4 103.0 101.0 98.6

wB 0.0105 0.04 0.08 0.12 0.16 0.20 0.25 0.30 0.0105

T/K 393.15 393.15 393.15 393.15 393.15 393.15 393.15 393.15 413.15
P/MPa 114.2 114.7 110.8 110.3 110.3 107.8 107.8 106.4 111.0
wB 0.04 0.08 0.12 0.16 0.20 0.25 0.30 0.0105 0.04
T/K 413.15 413.15 413.15 413.15 413.15 413.15 413.15 433.15 433.15
P/MPa 111.8 108.4 107.4 105.9 103.9 104.2 103.5 108.4 108.8
wB 0.08 0.12 0.16 0.20 0.25 0.30 0.0105 0.04 0.08
T/K 433.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 105.4 104.4 102.5 102.0 102.0 100.5 106.9 106.4 103.0
continue
____________________________________________________________________________________
continue
wB 0.12 0.16 0.20 0.25 0.30 0.0105 0.04 0.08 0.12

T/K 453.15 453.15 453.15 453.15 453.15 473.15 473.15 473.15 473.15
P/MPa 101.5 100.5 100.1 100.1 98.5 104.4 104.4 101.0 99.5
wB 0.16 0.20 0.25 0.30
T/K 473.15 473.15 473.15 473.15
P/MPa 98.5 98.0 97.6 96.6

T/K = 473.15
wA 0.0135 0.0264 0.0336 0.0337 0.0373 0.0462 0.0577 0.0652 0.0752

P/MPa 2.695 4.683 6.464 6.551 6.779 8.847 11.356 14.006 16.135
wA 0.1091 0.1323
P/MPa 22.361 29.520

wB 0.05 0.10 0.15 0.20 0.30

T/K 433.15 433.15 433.15 433.15 433.15
P/MPa 114.5 112.0 109.3 107.5 106.2

wB 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15 0.20

T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 121.3 118.6 116.5 114.1 112.4 117.2 115.5 112.7 110.3
wB 0.30 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15
T/K 413.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 109.6 114.5 112.0 109.8 107.5 106.2 111.3 108.9 106.9
wB 0.20 0.30 0.05 0.10 0.15 0.20 0.30
T/K 453.15 453.15 473.15 473.15 473.15 473.15 473.15
P/MPa 105.5 103.4 108.6 106.8 103.4 102.7 101.0
____________________________________________________________________________________

T/K = 463.15
_____________________________________________________________________________
P/ wA
_____________________________________________________________________________
93.5 0.376
133.0 0.980
139.5 0.560
151.6 0.602
156.2 0.972
160.2 0.630
164.5 0.964
170.0 0.942
171.5 0.718
174.5 0.920
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
diblock copolymer
8.6 mol% ethylene oxide EO-b-PO/09x 98ONE
10.0 mol% ethylene oxide EO-b-PO/10x 98ONE
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
_____________________________________________________________________________
11.8 mol% ethylene oxide EO-PO-EO/11x 98ONE
24.8 mol% ethylene oxide EO-PO-EO/25x(1) 98ONE
24.8 mol% ethylene oxide EO-PO-EO/25x(2) 98ONE

24.7 mol% ethylene oxide PO-EO-PO/25x(1) 98ONE
24.8 mol% ethylene oxide PO-EO-PO/25x(2) 98ONE
46.7 mol% ethylene oxide PO-EO-PO/47x 98ONE
56.9 mol% ethylene oxide PO-EO-PO/57x 98ONE
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol
_____________________________________________________________________________
EO-b-PO/09x 1988 (= 132 + 1856) Jeffamine M2000, hydroxyl terminated EO,
NH2 terminated PO
EO-b-PO/10x 566 (= 44 + 522) Jeffamine M600, hydroxyl terminated EO,
NH2 terminated PO
EO-PO-EO/11x 1050 (= 50 + 950 + 50) Pluronic L31, hydroxyl terminated
EO-PO-EO/25x(1) 2460 (= 245 + 1970 + 245) Pluronic L62, hydroxyl terminated
EO-PO-EO/25x(2) 3738 (= 374 + 2990 + 374) Pluronic L92, hydroxyl terminated
PO-EO-PO/25x(1) 3125 (= 1250 + 625 + 1250) Pluronic 25R2, hydroxyl terminated
PO-EO-PO/25x(2) 2125 (= 850 + 425 + 850) Pluronic 17R2, hydroxyl terminated
PO-EO-PO/47x 2833 (= 850 + 1133 + 850) Pluronic 17R4, hydroxyl terminated
PO-EO-PO/57x 2000 (= 500 + 1000 + 500) Pluronic 10R5, hydroxyl terminated
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): EO-b-PO/09x 98ONE

wB 0.001
T/K 308.15
P/MPa 27.58
copolymer (B): EO-b-PO/10x 98ONE

wB 0.007
T/K 308.15
P/MPa 27.58
copolymer (B): EO-PO-EO/11x 98ONE

wB 0.030
T/K 308.15
P/MPa 27.58

wB 0.002
T/K 308.15
P/MPa 27.58

wB 0.008
T/K 308.15
P/MPa 27.58
____________________________________________________________________________________
copolymer (B): EO-PO-EO/25x(1) 98ONE

wB 0.002
T/K 308.15
P/MPa 27.58
copolymer (B): EO-PO-EO/25x(2) 98ONE

wB 0.001
T/K 308.15
P/MPa 27.58

wB 0.003
T/K 308.15
P/MPa 27.58
copolymer (B): PO-EO-PO/25x(1) 98ONE

wB 0.001
T/K 308.15
P/MPa 27.58
copolymer (B): PO-EO-PO/25x(2) 98ONE

wB 0.007
T/K 308.15
P/MPa 27.58
____________________________________________________________________________________
copolymer (B): PO-EO-PO/47x 98ONE

wB 0.001
T/K 308.15
P/MPa 27.58
copolymer (B): PO-EO-PO/57x 98ONE

wB 0.003
T/K 308.15
P/MPa 27.58
_____________________________________________________________________________
Copolymer (B) Solvent/gas (A) Ref.
_____________________________________________________________________________
n-butane 94LE1
n-butane 96LE3
1-butene 94LE1
1-butene 93HA2
1-butene 94LE2
1-butene 96LE3
ethene 92LUF
ethene 93HA2
ethene 97LEE
propane 94LE1
propane 96LE1
propene 93HA2
propene 94LE1
propene 96LE1
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
n-heptane 96DEL
propane 95CHE
propane 98HAN
_____________________________________________________________________________
ethene 96BYU
_____________________________________________________________________________
n-heptane 96DEL
2-methylpropane 99PAN
propane 98HAN
propane 99PAN
_____________________________________________________________________________
n-butane 97LEE
1-butene 97LEE
dimethyl ether 97LEE
ethene 97LEE
propane 97LEE
_____________________________________________________________________________
n-butane 93PRA
n-butane 94LOS
n-butane 94LE2
n-butane 96LE1
n-butane 96LE3
1-butene 93PRA
1-butene 96LE1
carbon dioxide 99LOR
chlorodifluoromethane 93HA1
chlorodifluoromethane 93PRA
ethane 92HAS
ethane 93HA2
ethane 94LOS
ethane 96LE3
ethene 92HAS
ethene 93HA2
ethene 96BYU
ethene 96LE3
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
n-hexane 94LOS
methanol 96LE3
propane 91MEI
propane 92HAS
propane 93HA1
propane 93HA2
propane 94LOS
propene 92HAS
propene 93HA2
propene 96LE3
_____________________________________________________________________________
n-heptane 96DEL
_____________________________________________________________________________
cyclohexane 96DEL
n-heptane 96DEL
n-hexane 96DEL
2-methylpentane 96DEL
propane 97WHA
propane 98HAN
_____________________________________________________________________________
1-butene 93CHE
ethene 97HAN
n-heptane 96DEL
propane 97WHA
propane 98HAN
propene 93CHE
propene 97HAN
_____________________________________________________________________________
ethene 82WOH
ethene 96FOL
ethene 2000KIN
_____________________________________________________________________________
Methyl methacrylate/2-hydroxyethyl methacrylate
copolymer
carbon dioxide 97LEP
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
carbon dioxide 98ONE
_____________________________________________________________________________
carbon dioxide 98MCH
hexafluoroethane 96MER
octafluoropropane 96MER
sulfur hexafluoride 98MCH
tetrafluoromethane 96MER
tetrafluoromethane 98MCH
_____________________________________________________________________________
_____________________________________________________________________________
Vinylidene fluoride/hexafluoropropylene copolymer
1-chloro-1,1-difluoroethane 2000DIN
chlorotrifluoromethane 2000DIN
1,1-difluoroethane 2000DIN
pentafluoroethane 2000DIN
_____________________________________________________________________________
____________________________________________________________________________________
4.3. Experimental data of quasiternary solutions containing at least

one copolymer
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________

solvent (A): acrylic acid C3H4O2 79-10-7
solvent (C): ethene C2H4 74-85-1
T/K = 413.15
wA 0.007 0.014 0.026 0.043 0.068 0.095
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.858 0.851 0.839 0.822 0.797 0.770
P/MPa 164.4 157.1 152.9 148.0 142.7 138.2
____________________________________________________________________________________

T/K = 433.15
wA 0.007 0.014 0.026 0.043 0.068 0.095

wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.858 0.851 0.839 0.822 0.797 0.770
P/MPa 150.6 146.2 143.2 139.4 134.1 130.5

T/K = 453.15
wA 0.007 0.014 0.026 0.043 0.068 0.095

wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.858 0.851 0.839 0.822 0.797 0.770
P/MPa 141.3 138.2 135.8 132.7 128.4 124.7

T/K = 473.15
wA 0.007 0.014 0.026 0.043 0.068 0.095

wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.858 0.851 0.839 0.822 0.797 0.770
P/MPa 133.8 131.7 129.7 127.5 123.7 120.5

T/K = 413.15
continue
____________________________________________________________________________________
continue
wA 0.005 0.017 0.026 0.043 0.068 0.104

wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.860 0.848 0.839 0.822 0.797 0.761
P/MPa 195.1 175.5 166.0 157.5 150.4 144.0

T/K = 433.15
wA 0.005 0.014 0.017 0.026 0.043 0.068 0.104

wB 0.135 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.860 0.851 0.848 0.839 0.822 0.797 0.761
P/MPa 173.4 163.2 169.4 154.5 147.2 141.2 135.1

T/K = 453.15
wA 0.005 0.014 0.017 0.026 0.043 0.068 0.104

wB 0.135 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.860 0.851 0.848 0.839 0.822 0.797 0.761
P/MPa 155.2 149.1 147.5 144.5 139.1 134.1 130.0

T/K = 473.15
wA 0.005 0.014 0.017 0.026 0.043 0.068 0.104

wB 0.135 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.860 0.851 0.848 0.839 0.822 0.797 0.761
P/MPa 143.1 140.5 139.2 137.5 133.3 128.5 124.6
____________________________________________________________________________________

T/K = 413.15
wA 0.007 0.014 0.023 0.051 0.074 0.113

wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.858 0.851 0.842 0.814 0.791 0.752
P/MPa 210.3 189.5 174.4 157.6 152.8 150.3

T/K = 433.15
wA 0.007 0.014 0.023 0.051 0.074 0.113

wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.858 0.851 0.842 0.814 0.791 0.752
P/MPa 180.1 169.3 160.2 147.3 144.0 142.4

T/K = 453.15
wA 0.007 0.014 0.023 0.051 0.074 0.113
wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.858 0.851 0.842 0.814 0.791 0.752
P/MPa 162.4 155.3 149.0 139.5 137.3 136.5

T/K = 473.15
continue
____________________________________________________________________________________
continue
wA 0.007 0.014 0.023 0.051 0.074 0.113

wB 0.135 0.135 0.135 0.135 0.135 0.135
wC 0.858 0.851 0.842 0.814 0.791 0.752
P/MPa 148.5 144.7 140.5 134.1 131.9 130.5
_____________________________________________________________________________
Copolymers from ethylene and 1-hexene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
10.6 wt% 1-hexene E-H/11w 2000CH3
16.1 wt% 1-hexene E-H/16w 99KIN
35.0 wt% 1-hexene E-H/35w 2000CH3
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-H/11w 52600 80000
E-H/16w 60000 129000
E-H/35w 48100 103000
_____________________________________________________________________________

_____________________________________________________________________________

solvent (C): n-butane C4H10 106-97-8

continue
____________________________________________________________________________________
continue
wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 145.0 135.3 127.3 121.2 116.6 113.0 134.0 125.9 119.1
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 113.6 109.6 106.2 125.4 117.8 111.7 107.1 103.7 101.0

solvent (C): ethane C2H6 74-84-0
wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 151.7 140.7 133.4 126.3 120.8 116.5 147.1 136.8 129.1
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 123.0 118.1 114.3 143.2 133.5 125.5 120.0 116.0 112.0

solvent (C): helium He 7440-59-7
wA 0.840 0.840 0.840 0.840 0.840 0.840 0.830 0.830 0.830

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.010 0.010 0.010 0.010 0.010 0.010 0.020 0.020 0.020
T/K 393.15 413.15 433.15 453.15 473.15 493.15 433.15 453.15 473.15
P/MPa 195.0 178.6 165.8 155.4 148.2 143.0 214.6 200.7 188.3
wA 0.830
wB 0.150
wC 0.020
T/K 493.15
P/MPa 176.8
____________________________________________________________________________________

solvent (C): 1-hexene C6H12 592-41-6
wA 0.4255 0.4255 0.4255 0.2755 0.2755 0.2755

wB 0.1490 0.1490 0.1490 0.1390 0.1390 0.1390
wC 0.4255 0.4255 0.4255 0.5855 0.5855 0.5855
T/K 393.15 423.15 453.35 393.25 423.15 453.25
P/MPa 65.4 66.5 65.1 44.2 45.1 44.6

wA 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.4250 0.4250 0.4250

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.4250 0.4250 0.4250
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 118.2 103.2 99.2 95.7 93.3 91.4 59.0 59.0 59.1
wA 0.4250 0.4250 0.4250 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4250 0.4250 0.4250 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 59.0 59.1 59.1 25.6 27.0 28.3 30.3 32.3 34.6

wA 0.4558 0.4558 0.4558 0.4558

wB 0.1400 0.1400 0.1400 0.1400
wC 0.4042 0.4042 0.4042 0.4042
T/K 393.15 413.15 433.15 453.15
P/MPa 55.7 55.7 56.2 57.7

solvent (C): methane CH4 74-82-8

continue
____________________________________________________________________________________
continue
wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 169.0 156.7 147.1 139.4 132.4 126.4 186.5 170.5 157.8
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 149.0 142.0 137.5 202.0 186.9 174.0 162.8 153.7 149.1

solvent (C): propane C3H8 74-98-6
wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 148.5 136.0 128.1 122.1 117.4 113.6 138.3 129.3 123.3
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 117.1 113.3 110.0 130.3 122.1 116.0 111.8 108.9 106.6

solvent (D): n-butane C4H10 106-97-8
wA 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 99.9 95.8 91.6 89.7 87.7 86.0 90.5 87.2 84.6
wA 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
continue
____________________________________________________________________________________
continue
wC 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750

wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 82.6 81.1 79.9 85.5 83.1 81.1 79.5 78.2 77.2

wA 0.4000 0.4000 0.4000 0.4000 0.4000 0.4000 0.3750 0.3750 0.3750

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4000 0.4000 0.4000 0.4000 0.4000 0.4000 0.3750 0.3750 0.3750
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 57.0 57.1 57.2 57.3 57.3 57.4 55.6 55.6 55.7
wA 0.3750 0.3750 0.3750 0.3500 0.3500 0.3500 0.3500 0.3500 0.3500
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.3750 0.3750 0.3750 0.3500 0.3500 0.3500 0.3500 0.3500 0.3500
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 55.8 55.9 56.1 54.9 54.9 55.1 55.4 55.6 55.6

wA 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1785

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 25.1 26.6 27.7 29.7 32.0 34.0 23.7 25.1 26.6
wA 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 28.6 30.8 33.1 23.4 24.9 26.5 28.4 30.6 32.8
____________________________________________________________________________________

solvent (D): helium He 7440-59-7
wA 0.6300 0.6300 0.6300 0.6300 0.6300 0.6300 0.6225 0.6225 0.6225

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2100 0.2100 0.2100 0.2100 0.2100 0.2100 0.2075 0.2075 0.2075
wD 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 0.0200 0.0200
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 150.3 139.9 131.5 125.1 119.9 115.5 200.5 185.5 172.6
wA 0.6225 0.6225 0.6225
wB 0.1500 0.1500 0.1500
wC 0.2075 0.2075 0.2075
wD 0.0200 0.0200 0.0200
T/K 453.15 473.15 493.15
P/MPa 161.4 152.5 147.7

wA 0.4200 0.4200 0.4200 0.4200 0.4200 0.4200 0.4150 0.4150 0.4150

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4200 0.4200 0.4200 0.4200 0.4200 0.4200 0.4150 0.4150 0.4150
wD 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 0.0200 0.0200
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 100.0 95.1 91.2 88.2 86.1 84.4 149.7 139.0 130.5
wA 0.4150 0.4150 0.4150 0.4100 0.4100 0.4100 0.4100 0.4100 0.4100
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4150 0.4150 0.4150 0.4100 0.4100 0.4100 0.4100 0.4100 0.4100
wD 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300 0.0300 0.0300 0.0300
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 123.6 118.2 113.6 209.9 189.9 172.9 161.6 153.8 148.4


continue
____________________________________________________________________________________
continue
wA 0.2100 0.2100 0.2100 0.2100 0.2100 0.2100 0.2075 0.2075 0.2075
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6300 0.6300 0.6300 0.6300 0.6300 0.6300 0.6225 0.6225 0.6225
wD 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 0.0200 0.0200
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 54.4 54.6 54.5 54.3 54.0 54.0 93.3 88.8 85.1
wA 0.2075 0.2075 0.2075 0.2050 0.2050 0.2050 0.2050 0.2050 0.2050
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6225 0.6225 0.6225 0.6150 0.6150 0.6150 0.6150 0.6150 0.6150
wD 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300 0.0300 0.0300 0.0300
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 82.1 79.8 78.0 134.5 127.1 121.7 117.1 113.3 110.2

solvent (D): methane CH4 74-82-8
wA 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 123.0 117.5 112.4 108.1 104.7 102.0 137.2 129.7 124.2
wA 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 119.6 115.8 112.8 151.9 144.0 137.1 131.4 127.0 123.4

wA 0.4000 0.4000 0.4000 0.4000 0.4000 0.4000 0.3750 0.3750 0.3750

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4000 0.4000 0.4000 0.4000 0.4000 0.4000 0.3750 0.3750 0.3750
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 83.0 80.9 79.0 77.4 76.0 74.8 100.5 97.1 94.0
continue
____________________________________________________________________________________
continue
wA 0.3750 0.3750 0.3750 0.3500 0.3500 0.3500 0.3500 0.3500 0.3500

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.3750 0.3750 0.3750 0.3500 0.3500 0.3500 0.3500 0.3500 0.3500
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 91.3 89.1 87.2 121.6 115.2 109.6 105.4 101.9 99.0

wA 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1785

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 40.9 42.5 44.0 45.5 46.9 48.3 58.6 58.8 59.1
wA 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 59.2 59.4 59.5 82.5 81.0 79.6 78.5 77.4 76.6
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
50.0 mol% ethylene E-P/50x 92CH2
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-P/50x 25200 26000 alternating ethylene/propylene units from
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-P/50x 92CH2

solvent (C): 1-butene C4H8 106-98-9
wA 0.074 0.074 0.074 0.074 0.074 0.074 0.117 0.117 0.117

wB 0.187 0.187 0.187 0.187 0.187 0.187 0.162 0.162 0.162
wC 0.739 0.739 0.739 0.739 0.739 0.739 0.721 0.721 0.721
T/K 355.35 373.45 398.15 423.15 448.15 473.55 355.35 373.35 398.25
P/bar 144.0 177.0 215.3 250.3 278.0 303.0 200.4 232.0 266.4
wA 0.117 0.117 0.117 0.234 0.234 0.234 0.234
wB 0.162 0.162 0.162 0.154 0.154 0.154 0.154
wC 0.721 0.721 0.721 0.612 0.612 0.612 0.612
T/K 423.15 447.95 473.45 355.35 373.55 398.15 423.25
P/bar 296.8 322.0 344.5 318.5 340.2 365.0 389.0

wA = 0.122 wB = 0.158 wC = 0.820
T/K 299.65 323.15 353.45 373.65 384.05 397.15 405.75 413.15 422.15
P/bar 16.9 23.0 32.1 38.5 41.2 44.0 58.0 68.0 85.0
(VLE VLE VLE VLE VLE VLE LLE LLE LLE)
T/K 424.75 433.45 447.65 463.65 468.55 473.35 424.75 433.45 447.65
P/bar 89.2 100.0 124.0 138.0 144.0 148.0 53.1 54.1 59.8
(LLE LLE LLE LLE LLE LLE VLLE VLLE VLLE)
continue
____________________________________________________________________________________
continue
T/K 468.15
P/bar 63.2
(VLLE)

wA = 0.243 wB = 0.150 wC = 0.607
T/K 300.65 306.15 314.15 321.85 353.75 371.95 395.85 425.55 447.85
P/bar 28.0 31.7 43.0 56.5 114.0 144.0 179.0 222.0 246.0
(VLE VLE LLE LLE LLE LLE LLE LLE LLE)
T/K 472.55 315.95 323.35 341.15 353.75 371.95 395.85 424.15
P/bar 266.0 35.0 39.2 47.0 55.6 63.4 73.0 81.2
(LLE VLLE VLLE VLLE VLLE VLLE VLLE VLLE)

wA = 0.355 wB = 0.153 wC = 0.492
T/K 251.15 264.65 271.15 282.75 295.45 311.65 324.65 355.45 373.45
P/bar 187.0 176.0 175.0 182.5 194.7 216.5 233.0 269.0 290.0
T/K 398.15 423.95 449.15 473.45 258.85 282.75 295.45 311.65 324.65
P/bar 320.5 348.0 370.0 384.0 17.2 30.0 36.5 45.8 55.0
(LLE LLE LLE LLE VLLE VLLE VLLE VLLE VLLE)
T/K 355.45 373.45 398.15
P/bar 75.5 85.0 91.8
(VLLE VLLE VLLE)

continue
____________________________________________________________________________________
continue
wA = 0.504 wB = 0.149 wC = 0.347
T/K 296.05 310.85 325.75 343.25 358.85 374.85 397.25 424.15 446.55
P/bar 488.0 464.0 456.0 452.0 459.0 468.0 479.0 492.0 502.0
T/K 469.65 295.65 311.15 325.95 343.25 358.85 374.85
P/bar 511.0 48.6 59.4 70.0 79.0 88.6 92.0
(LLE VLLE VLLE VLLE VLLE VLLE VLLE)
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
27.5 wt% vinyl acetate E-VA/28w(2) 99KIN
32.3 wt% vinyl acetate E-VA/32w 84WOH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-VA/28w(2) 61900 167000
E-VA/58w 35000 Exxon Chemical Company
_____________________________________________________________________________

_____________________________________________________________________________

solvent (C): vinyl acetate C4H6O2 108-05-4
T/K = 403.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.590; wB = 0.153; wC = 0.257
_____________________________________________________________________________
_____________________________________________________________________________
56.5 0.311 0.542 0.147
75.5 0.683 0.016 0.301
87.8 0.450 0.352 0.198 0.678 0.023 0.299
100.2 0.546 0.212 0.242 0.660 0.048 0.292
104.1 0.590 0.153 0.257 (cloud point)
_____________________________________________________________________________

T/K = 403.15
continue
____________________________________________________________________________________
continue
wA = 0.347; wB = 0.157; wC = 0.496
_____________________________________________________________________________
_____________________________________________________________________________
58.5 0.387 0.037 0.576
68.0 0.322 0.215 0.463 0.380 0.056 0.564
72.7 0.347 0.157 0.496 (cloud point)
_____________________________________________________________________________

T/K = 433.15
wA = 0.254; wB = 0.155; wC = 0.591
_____________________________________________________________________________
_____________________________________________________________________________
48.7 0.231 0.230 0.539 0.277 0.050 0.673
53.4 0.254 0.155 0.591 (cloud point)
_____________________________________________________________________________

wA 0.422 0.422 0.422 0.217 0.217 0.217 0.120 0.120 0.120

wB 0.159 0.159 0.159 0.156 0.156 0.156 0.298 0.298 0.298
wC 0.419 0.419 0.419 0.627 0.627 0.627 0.582 0.582 0.582
T/K 373.15 403.15 433.15 373.15 403.15 433.15 378.15 388.15 403.15
P/MPa 75.3 69.8 68.0 45.8 38.3 39.0 21.4 19.5 18.0
continue
____________________________________________________________________________________
continue
wA 0.120 0.120 0.120
wB 0298 0.298 0.298
wC 0.582 0.582 0.582
T/K 423.15 433.15 443.15
P/MPa 19.4 20.5 22.2

T/K = 433.15
wA = 0.217; wB = 0.156; wC = 0.627
_____________________________________________________________________________
_____________________________________________________________________________
27.5 0.160 0.360 0.480 0.251 0.041 0.708
33.5 0.188 0.276 0.536 0.242 0.061 0.697
39.0 0.217 0.156 0.627 (cloud point)
_____________________________________________________________________________

T/K = 433.15
wA = 0.343; wB = 0.136; wC = 0.521
_____________________________________________________________________________
_____________________________________________________________________________
19.9 0.4042 0.0004 0.5954
43.0 0.256 0.361 0.383 0.3936 0.0127 0.5937
57.3 0.343 0.136 0.521 (cloud point)
_____________________________________________________________________________
____________________________________________________________________________________

T/K = 433.15
wA = 0.442; wB = 0.159; wC = 0.419
_____________________________________________________________________________
_____________________________________________________________________________
37.7 0.221 0.532 0.247 0.498 0.025 0.477
50.0 0.288 0.404 0.308 0.487 0.038 0.475
61.9 0.365 0.272 0.363 0.476 0.062 0.462
68.0 0.422 0.159 0.419 (cloud point)
_____________________________________________________________________________

T/K = 433.15
wA = 0.645; wB = 0.158; wC = 0.197
_____________________________________________________________________________
_____________________________________________________________________________
30.4 0.176 0.760 0.064 0.779 0.0008 0.221
43.7 0.244 0.670 0.086 0.766 0.0009 0.233
66.6 0.370 0.506 0.124 0.754 0.0130 0.233
86.0 0.513 0.325 0.162 0.736 0.0290 0.235
97.2 0.645 0.158 0.197 (cloud point)
_____________________________________________________________________________
____________________________________________________________________________________

T/K = 463.15
wA = 0.460; wB = 0.135; wC = 0.405
_____________________________________________________________________________
_____________________________________________________________________________
47.3 0.273 0.506 0.221 0.582 0.012 0.406
58.8 0.346 0.363 0.291 0.546 0.051 0.403
70.7 0.460 0.135 0.405 (cloud point)
_____________________________________________________________________________
Fractionation during demixing

_____________________________________________________________________________
Demixing molar mass averages
pressure bottom phase top phase
_____________________________________________________________________________
_____________________________________________________________________________
47.3 5611 13634 27447
58.8 11958 26057 44198
70.7 33400 137700 (feed sample)
_____________________________________________________________________________

wA 0.317 0.317 0.317 0.317 0.317 0.317 0.340 0.340 0.413

wB 0.360 0.360 0.360 0.360 0.360 0.360 0.322 0.322 0.207
wC 0.323 0.323 0.323 0.323 0.323 0.323 0.338 0.338 0.380
T/K 363.15 373.15 393.15 413.15 438.15 453.15 383.15 433.15 403.15
P/MPa 52.3 53.1 54.0 55.2 57.2 58.5 62.4 64.5 75.4
continue
____________________________________________________________________________________
continue
wA 0.413 0.505 0.505 0.505 0.505 0.505 0.631 0.631 0.631

wB 0.207 0.257 0.257 0.257 0.257 0.257 0.187 0.187 0.187
wC 0.380 0.238 0.238 0.238 0.238 0.238 0.182 0.182 0.182
T/K 433.15 363.15 383.15 403.15 438.15 453.15 363.15 383.15 403.15
P/MPa 75.1 88.3 86.1 83.7 82.0 81.8 106.8 102.8 100.0
wA 0.631 0.795 0.795 0.795
wB 0.187 0.105 0.105 0.105
wC 0.182 0.100 0.100 0.100
T/K 443.15 383.15 403.15 433.15
P/MPa 96.5 122.0 118.5 113.0

wA 0.594 0.594 0.594 0.200 0.200 0.200

wB 0.148 0.148 0.148 0.152 0.152 0.152
wC 0.258 0.258 0.258 0.648 0.648 0.648
T/K 398.15 403.15 433.15 401.15 413.15 433.15
P/MPa 90.2 86.4 84.6 26.1 27.2 29.0

T/K = 403.15
wA = 0.353; wB = 0.159; wC = 0.488
_____________________________________________________________________________
_____________________________________________________________________________
30.7 0.415 0.016 0.569
31.2 0.220 0.446 0.334
39.1 0.409 0.025 0.563
39.7 0.255 0.349 0.396
46.7 0.319 0.224 0.457 0.403 0.044 0.553
49.5 0.353 0.159 0.488 (cloud point)
_____________________________________________________________________________
____________________________________________________________________________________

T/K = 433.15
wA = 0.594; wB = 0.148; wC = 0.258
_____________________________________________________________________________
_____________________________________________________________________________
35.5 0.204 0.702 0.094
48.2 0.273 0.613 0.114 0.709 0.008 0.283
56.6 0.322 0.551 0.127 0.705 0.013 0.282
67.0 0.392 0.447 0.161 0.692 0.020 0.288
78.6 0.500 0.290 0.210 0.677 0.040 0.283
84.6 0.594 0.148 0.258 (cloud point)
_____________________________________________________________________________

T/K = 433.15
wA = 0.349; wB = 0.152; wC = 0.499
_____________________________________________________________________________
_____________________________________________________________________________
27.8 0.176 0.529 0.295 0.419 0.012 0.567
35.8 0.221 0.439 0.340 0.413 0.021 0.566
46.2 0.289 0.308 0.403 0.402 0.051 0.547
51.0 0.349 0.152 0.499 (cloud point)
_____________________________________________________________________________
____________________________________________________________________________________

T/K = 433.15
wA = 0.200; wB = 0.152; wC = 0.648
_____________________________________________________________________________
_____________________________________________________________________________
14.5 0.140 0.400 0.460 0.238 0.014 0.748
19.5 0.154 0.356 0.490 0.231 0.031 0.738
26.0 0.181 0.233 0.586 0.228 0.051 0.721
29.0 0.200 0.152 0.648 (cloud point)
_____________________________________________________________________________

solvent (C): carbon dioxide CO2 124-38-9

wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 127.7 123.0 119.2 115.9 113.0 110.2 128.5 123.8 120.1
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 117.0 113.9 111.2 130.3 125.7 121.8 118.9 115.8 113.1

solvent (C): ethane C2H6 74-84-0

wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 125.6 121.2 117.2 113.9 110.8 108.0 126.0 121.5 117.3
continue
____________________________________________________________________________________
continue
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 114.0 111.3 108.4 124.8 120.0 115.8 112.4 109.7 107.5

solvent (C): helium He 7440-59-7
wA 0.955 0.955 0.955 0.955 0.955 0.955 0.920 0.920 0.920

wB 0.035 0.035 0.035 0.035 0.035 0.035 0.070 0.070 0.070
wC 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 163.6 156.1 149.2 142.8 137.5 132.7 168.1 159.3 151.5
wA 0.920 0.920 0.920 0.870 0.870 0.870 0.870 0.870 0.870
wB 0.070 0.070 0.070 0.120 0.120 0.120 0.120 0.120 0.120
wC 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 145.4 139.9 135.3 165.2 157.6 150.7 144.6 139.2 134.5
wA 0.840 0.840 0.840 0.840 0.840 0.840 0.790 0.790 0.790
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.200 0.200 0.200
wC 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 163.8 156.2 149.4 143.3 137.9 133.3 163.2 155.7 148.8
wA 0.790 0.790 0.790 0.640 0.640 0.640 0.640 0.640 0.640
wB 0.200 0.200 0.200 0.350 0.350 0.350 0.350 0.350 0.350
wC 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 142.5 137.5 132.6 158.7 150.1 142.7 137.4 132.5 128.4

solvent (C): nitrogen N2 7727-37-9
wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 146.5 140.5 135.8 130.5 125.4 120.5 172.5 164.7 155.6
continue
____________________________________________________________________________________
continue
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 148.8 142.5 137.5 193.0 184.8 176.8 168.9 161.4 154.4

solvent (C): propane C3H8 74-98-6
wA 0.800 0.800 0.800 0.800 0.800 0.800 0.750 0.750 0.750

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 122.0 117.7 113.6 110.5 107.6 104.9 116.3 112.4 109.0
wA 0.750 0.750 0.750 0.700 0.700 0.700 0.700 0.700 0.700
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 105.8 103.4 100.8 112.9 109.2 105.9 103.0 100.4 98.0

wA 0.6715 0.6715 0.6715 0.6715 0.6715 0.6715 0.6375 0.6375 0.6375

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1785 0.1785 0.1785 0.1785 0.1785 0.1785 0.2125 0.2125 0.2125
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 99.5 97.5 95.5 94.1 92.7 91.5 94.3 92.6 91.1
wA 0.6375 0.6375 0.6375 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2125 0.2125 0.2125 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 89.8 88.6 87.5 60.7 61.1 61.6 62.0 62.4 62.7
wA 0.2125 0.2125 0.2125 0.2125 0.2125 0.2125 0.0850 0.0850 0.0850
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6375 0.6375 0.6375 0.6375 0.6375 0.6375 0.7650 0.7650 0.7650
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 26.7 28.9 30.9 33.1 34.8 37.6 4.8 7.1 9.8
continue
____________________________________________________________________________________
continue
wA 0.0850 0.0850 0.0850

wB 0.1500 0.1500 0.1500
wC 0.7650 0.7650 0.7650
T/K 453.15 473.15 493.15
P/MPa 13.2 17.5 19.5

wA 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250 0.3060 0.3060

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250 0.5440 0.5440
T/K 348.15 353.15 358.15 368.15 383.15 393.15 423.15 348.15 353.15
P/MPa 48.7 47.5 46.8 46.7 47.5 48.0 50.8 42.2 41.4
wA 0.3060 0.3060 0.3060 0.3060 0.3060 0.3060 0.3060 0.3060 0.3060
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.5440 0.5440 0.5440 0.5440 0.5440 0.5440 0.5440 0.5440 0.5440
T/K 358.15 368.15 373.15 383.15 393.15 403.15 423.15 443.15 463.15
P/MPa 41.0 40.9 41.0 41.1 41.5 42.0 43.9 45.3 46.9
wA 0.0850 0.0850 0.0850 0.0850 0.0850 0.0850 0.0850 0.0850 0.0850
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.7650 0.7650 0.7650 0.7650 0.7650 0.7650 0.7650 0.7650 0.7650
T/K 341.15 343.15 348.15 353.15 358.15 368.15 373.15 383.15 403.15
P/MPa 4.8 3.5 2.9 2.8 2.7 3.0 3.4 4.0 5.7
wA 0.0850 0.0850 0.0850
wB 0.1500 0.1500 0.1500
wC 0.7650 0.7650 0.7650
T/K 423.15 443.15 463.15
P/MPa 8.6 11.0 15.5

wA 0.4825 0.4825 0.4825 0.4825 0.4825 0.4825 0.4600 0.4600 0.4600

wB 0.0350 0.0350 0.0350 0.0350 0.0350 0.0350 0.0800 0.0800 0.0800
wC 0.4825 0.4825 0.4825 0.4825 0.4825 0.4825 0.4600 0.4600 0.4600
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 59.0 59.9 60.6 61.2 61.6 61.9 61.9 62.3 62.9
continue
____________________________________________________________________________________
continue
wA 0.4600 0.4600 0.4600 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250
wB 0.0800 0.0800 0.0800 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.4600 0.4600 0.4600 0.4250 0.4250 0.4250 0.4250 0.4250 0.4250
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 63.3 63.8 64.1 60.7 61.1 61.6 62.0 62.4 62.7
wA 0.3750 0.3750 0.3750 0.3750 0.3750 0.3750
wB 0.2500 0.2500 0.2500 0.2500 0.2500 0.2500
wC 0.3750 0.3750 0.3750 0.3750 0.3750 0.3750
T/K 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 53.8 54.9 56.0 56.9 58.0 58.9


wA 0.3450 0.3450 0.3450 0.3450 0.3450 0.3450 0.3400 0.3400 0.3400
wB 0.3100 0.3100 0.3100 0.3100 0.3100 0.3100 0.3200 0.3200 0.3200
wC 0.3450 0.3450 0.3450 0.3450 0.3450 0.3450 0.3400 0.3400 0.3400
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 47.5 49.2 50.7 52.1 53.5 54.7 49.0 50.4 51.8
wA 0.3400 0.3400 0.3400 0.3250 0.3250 0.3250 0.3250 0.3250 0.3250
wB 0.3200 0.3200 0.3200 0.3500 0.3500 0.3500 0.3500 0.3500 0.3500
wC 0.3400 0.3400 0.3400 0.3250 0.3250 0.3250 0.3250 0.3250 0.3250
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 53.2 54.5 55.7 48.6 50.1 51.6 53.0 54.3 55.5
wA 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750
wB 0.4500 0.4500 0.4500 0.4500 0.4500 0.4500
wC 0.2750 0.2750 0.2750 0.2750 0.2750 0.2750
T/K 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 42.8 44.6 46.2 47.7 49.1 50.3

solvent (D): carbon dioxide CO2 124-38-9

wA 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 97.9 96.0 94.3 92.6 91.1 90.0 101.5 99.4 97.3
continue
____________________________________________________________________________________
continue
wA 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 95.7 94.2 92.9 105.1 102.4 100.1 97.7 95.9 94.3

wA 0.400 0.400 0.400 0.400 0.400 0.400 0.375 0.375 0.375

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.400 0.400 0.400 0.400 0.400 0.400 0.375 0.375 0.375
wD 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 64.9 65.1 65.3 65.5 65.7 65.8 69.6 69.6 69.5
wA 0.375 0.375 0.375 0.350 0.350 0.350 0.350 0.350 0.350
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.375 0.375 0.375 0.350 0.350 0.350 0.350 0.350 0.350
wD 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 69.5 69.4 69.3 74.9 74.6 74.3 74.1 73.7 73.5

wA 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875

wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 32.5 34.4 36.1 38.0 39.4 40.9 38.9 40.3 41.8
wA 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 43.1 44.2 45.2 45.2 46.1 47.2 48.3 48.9 49.6
____________________________________________________________________________________


wA 0.8300 0.8300 0.8300 0.8300 0.8300 0.8300 0.6300 0.6300 0.6300
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.2100 0.2100 0.2100
wD 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200 0.0100 0.0100 0.0100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 209.4 197.5 185.4 174.8 165.9 158.5 139.1 133.4 127.4
wA 0.6300 0.6300 0.6300 0.6225 0.6225 0.6225 0.6225 0.6225 0.6225
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2100 0.2100 0.2100 0.2075 0.2075 0.2075 0.2075 0.2075 0.0750
wD 0.0100 0.0100 0.0100 0.0200 0.0200 0.0200 0.0200 0.0200 0.0200
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 122.6 118.7 116.3 186.5 176.6 166.4 157.7 151.3 147.1


wA 0.420 0.420 0.420 0.420 0.420 0.420 0.415 0.415 0.415
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.420 0.420 0.420 0.420 0.420 0.420 0.415 0.415 0.415
wD 0.010 0.010 0.010 0.010 0.010 0.010 0.020 0.020 0.020
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 99.2 96.8 95.0 93.0 91.3 89.9 148.0 139.6 132.0
wA 0.415 0.415 0.415 0.410 0.410 0.410 0.410 0.410 0.410
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.415 0.415 0.415 0.410 0.410 0.410 0.410 0.410 0.410
wD 0.020 0.020 0.020 0.030 0.030 0.030 0.030 0.030 0.030
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 126.8 121.7 117.3 215.6 201.1 185.4 173.2 163.1 153.5

continue
____________________________________________________________________________________
continue
wA 0.2100 0.2100 0.2100 0.2100 0.2100 0.2100 0.2075 0.2075 0.2075
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6300 0.6300 0.6300 0.6300 0.6300 0.6300 0.6225 0.6225 0.6225
wD 0.0100 0.0100 0.0100 0.0100 0.0100 0.0100 0.0200 0.0200 0.0200
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 69.4 67.1 65.1 63.7 62.9 62.8 117.3 109.4 102.8
wA 0.2075 0.2075 0.2075 0.2050 0.2050 0.2050 0.2050 0.2050 0.2050
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6225 0.6225 0.6225 0.6150 0.6150 0.6150 0.6150 0.6150 0.6150
wD 0.0200 0.0200 0.0200 0.0300 0.0300 0.0300 0.0300 0.0300 0.0300
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 97.6 94.0 91.8 165.0 151.9 140.6 131.5 124.9 120.6


wA 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 115.4 112.5 110.0 108.0 105.4 103.0 142.2 136.6 131.1
wA 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 125.5 120.6 116.1 170.0 160.9 153.2 146.2 139.8 133.9


wA 0.400 0.400 0.400 0.400 0.400 0.400 0.375 0.375 0.375
wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.400 0.400 0.400 0.400 0.400 0.400 0.375 0.375 0.375
wD 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 0.100
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 84.1 82.5 81.3 79.7 78.5 77.3 107.0 104.0 101.1
continue
____________________________________________________________________________________
continue
wA 0.375 0.375 0.375 0.350 0.350 0.350 0.350 0.350 0.350

wB 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150 0.150
wC 0.375 0.375 0.375 0.350 0.350 0.350 0.350 0.350 0.350
wD 0.100 0.100 0.100 0.150 0.150 0.150 0.150 0.150 0.150
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 98.4 96.1 93.9 130.8 126.1 122.0 118.6 115.5 112.5


wA 0.2000 0.2000 0.2000 0.2000 0.2000 0.2000 0.1875 0.1875 0.1875
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.6000 0.6000 0.6000 0.6000 0.6000 0.6000 0.5625 0.5625 0.5625
wD 0.0500 0.0500 0.0500 0.0500 0.0500 0.0500 0.1000 0.1000 0.1000
T/K 393.15 413.15 433.15 453.15 473.15 493.15 393.15 413.15 433.15
P/MPa 48.4 49.0 49.4 49.6 50.2 50.7 73.6 72.2 70.9
wA 0.1875 0.1875 0.1875 0.1750 0.1750 0.1750 0.1750 0.1750 0.1750
wB 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
wC 0.5625 0.5625 0.5625 0.5250 0.5250 0.5250 0.5250 0.5250 0.5250
wD 0.1000 0.1000 0.1000 0.1500 0.1500 0.1500 0.1500 0.1500 0.1500
T/K 453.15 473.15 493.15 393.15 413.15 433.15 453.15 473.15 493.15
P/MPa 70.0 69.3 68.7 99.8 97.7 95.8 94.1 92.6 91.3
copolymer (B): E-VA/32w 84WOH

Comments: the feed (total) monomer weight fraction ratio wA/wC = 64/36 was kept constant
wB 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15 0.20

T/K 393.15 393.15 393.15 393.15 393.15 413.15 413.15 413.15 413.15
P/MPa 80.4 77.8 75.8 73.3 71.3 78.3 76.8 75.0 72.3
wB 0.30 0.05 0.10 0.15 0.20 0.30 0.05 0.10 0.15
T/K 413.15 433.15 433.15 433.15 433.15 433.15 453.15 453.15 453.15
P/MPa 70.3 76.8 76.0 74.0 70.3 68.8 76.3 74.8 73.3
wB 0.20 0.30
T/K 453.15 453.15
P/MPa 68.8 67.8
____________________________________________________________________________________

wA 0.761 0.761 0.761 0.761 0.761 0.657 0.657 0.657 0.657

wB 0.073 0.073 0.073 0.073 0.073 0.136 0.136 0.136 0.136
wC 0.166 0.166 0.166 0.166 0.166 0.207 0.207 0.207 0.207
T/K 348.15 373.15 403.15 433.15 453.15 373.15 403.15 433.15 453.15
P/MPa 65.8 65.4 65.8 66.8 67.8 84.9 82.9 81.4 80.6
wA 0.505 0.505 0.505 0.361 0.361 0.361 0.430 0.430 0.521
wB 0.184 0.184 0.184 0.246 0.246 0.246 0.273 0.273 0.084
wC 0.311 0.311 0.311 0.393 0.393 0.393 0.297 0.297 0.395
T/K 358.15 383.15 438.15 373.15 403.15 433.15 373.15 433.15 373.15
P/MPa 98.1 94.6 90.2 53.4 55.6 58.5 63.1 64.3 61.7
wA 0.521
wB 0.084
wC 0.395
T/K 433.15
P/MPa 64.1

T/K = 473.15
wA = 0.4395; wB = 0.2500; wC = 0.2565
_____________________________________________________________________________
_____________________________________________________________________________
28.15 0.1554 0.7016 0.1489
29.32 0.1640 0.6923 0.1515 0.6095 0.0700 0.3299
31.28 0.1720 0.7010 0.1498 0.6801 0.0090 0.3305
32.54 0.1863 0.6719 0.1600 0.6573 0.0307 0.3314
36.19 0.1968 0.6550 0.1507
38.05 0.2118 0.6400 0.1557 0.6211 0.0314 0.3279
50.12 0.2594 0.6017 0.1591 0.6653 0.0381 0.3331
51.40 0.2736 0.5415 0.1870 0.6590 0.0266 0.3318
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
_____________________________________________________________________________
52.54 0.3404 0.4725 0.2066 0.6541 0.0300 0.3441
59.01 0.3348 0.4848 0.2051 0.6361 0.0552 0.3302
64.90 0.3782 0.4188 0.2262 0.6550 0.0692 0.3210
66.94 0.4114 0.3811 0.2295 0.6427 0.0483 0.3296
71.00 0.4675 0.3011 0.2425 0.6232 0.0734 0.3230
_____________________________________________________________________________

T/K = 473.15
wA = 0.4125; wB = 0.2500; wC = 0.3375
_____________________________________________________________________________
_____________________________________________________________________________
20.11 0.1116 0.7008 0.1876 0.5426 0.0392 0.4182
20.70 0.1193 0.6861 0.1947 0.5672 0.0000 0.4328
20.99 0.1171 0.6957 0.1872 0.5395 0.0169 0.4436
21.09 0.1166 0.6876 0.1959 0.5397 0.0303 0.4299
21.68 0.1191 0.6864 0.1944 0.5416 0.0299 0.4284
21.68 0.1204 0.6815 0.1981 0.5366 0.0214 0.4420
29.32 0.1650 0.6410 0.2009 0.5621 0.0232 0.4292
30.70 0.1742 0.6255 0.2047 0.5571 0.0330 0.4217
36.58 0.2132 0.5672 0.2132 0.5274 0.0362 0.4432
38.35 0.2273 0.5445 0.2405 0.5283 0.0414 0.4431
42.77 0.2487 0.6113 0.2400 0.5705 0.0215 0.4070
44.63 0.2630 0.4983 0.2387 0.5659 0.0281 0.4060
48.16 0.2846 0.4441 0.2714 0.5340 0.0547 0.4112
49.15 0.3009 0.4163 0.2828 0.5317 0.0330 0.4350
50.81 0.3188 0.3966 0.2846 0.5334 0.0512 0.4154
51.60 0.3308 0.3757 0.2935 0.4975 0.0870 0.4155
56.99 0.3618 0.3357 0.3025 0.5201 0.0696 0.4102
60.43 0.3881 0.2553 0.3567 0.5047 0.0974 0.3979
_____________________________________________________________________________
____________________________________________________________________________________

T/K = 393.15
wA = 0.167; wB = 0.219; wC = 0.614
_____________________________________________________________________________
_____________________________________________________________________________
8.3 0.231 0.013 0.756
8.65 0.128 0.350 0.522
9.6 0.130 0.337 0.533 0.227 0.021 0.752
11.0 0.151 0.286 0.563
11.65 0.217 0.050 0.733
12.1 0.167 0.219 0.614 (cloud point)
_____________________________________________________________________________
Comments: some three-phase demixing data below 8 MPa can be found in the original source 91NIE

T/K = 393.15
wA = 0.251; wB = 0.200; wC = 0.549
_____________________________________________________________________________
_____________________________________________________________________________
9.85 0.112 0.489 0.399 0.330 0.004 0.666
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
_____________________________________________________________________________
13.9 0.132 0.487 0.381 0.346 0.004 0.645
17.4 0.150 0.441 0.409 0.343 0.007 0.650
20.0 0.164 0.415 0.421 0.336 0.009 0.650
24.9 0.200 0.328 0.472
25.2 0.319 0.037 0.644
27.1 0.224 0.272 0.504
27.7 0.311 0.061 0.628
28.1 0.251 0.200 0.549 (cloud point)
_____________________________________________________________________________
Comments: some three-phase demixing data below 10 MPa can be found in the original source 91NIE

wA 0.096 0.096 0.096 0.148 0.152 0.152 0.160 0.196 0.196

wB 0.200 0.200 0.200 0.214 0.214 0.214 0.205 0.198 0.198
wC 0.704 0.704 0.704 0.638 0.642 0.642 0.635 0.606 0.606
T/K 363.15 393.15 423.15 393.15 363.15 393.15 393.15 363.15 393.15
P/MPa 4.2 5.3 6.8 7.9 6.3 8.4 9.8 12.0 18.0
wA 0.196 0.299 0.401 0.401 0.401

wB 0.198 0.203 0.204 0.204 0.204
wC 0.606 0.498 0.405 0.405 0.405
T/K 423.15 363.15 363.15 393.15 423.15
P/MPa 23.3 36.0 65.0 64.5 64.2
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
n-butane and dimethyl ether 96LE2
_____________________________________________________________________________
1-butene and polyethylene 98LEE
_____________________________________________________________________________
ethene and 2-ethylhexyl acrylate 96BUB
_____________________________________________________________________________
ethene and 1-hexene 2000KIN
2-methylpropane and 1-hexene 99PAN
_____________________________________________________________________________
n-butane and dimethyl ether 97LEE
n-butane and ethanol 97LEE
_____________________________________________________________________________
n-butane and ethylene/ 98LEE
methyl acrylate copolymer
n-butane and ethylene/ 98LEE
vinyl alcohol copolymer
1-butene and ethylene/ 98LEE
methyl acrylate copolymer
chlorodifluoromethane and ethanol 92MEI
chlorodifluoromethane and 2-propanone 92MEI
ethene and methyl acrylate 87LUF
propane and 1-butanol 94LOS
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
propane and ethanol 92MEI
propane and ethanol 94LOS
propane and n-hexane 94LOS
propane and 1-hexene 94LOS
propane and methanol 94LOS
propane and 1-propanol 94LOS
propane and 2-propanone 92MEI
_____________________________________________________________________________
carbon dioxide and C6-fraction solvent 85MCH
ethene and C6-fraction solvent 85MCH
ethene and 1-butene 93CHE
ethene and n-hexane 85MCC
ethene and 1-hexene 93CHE
methane and C6-fraction solvent 85MCH
propene and C6-fraction solvent 85MCH
propene and C6-fraction solvent 86IRA
propene and 2-methylbutane 86IRA
_____________________________________________________________________________
ethene and vinyl acetate 80RAE
ethene and vinyl acetate 83WOH
ethene and vinyl acetate 92FIN
ethene and vinyl acetate 96FOL
ethene and vinyl acetate 2000KIN
_____________________________________________________________________________
n-butane and ethylene/
methyl acrylate copolymer 98LEE
_____________________________________________________________________________
carbon dioxide and sulfur hexafluoride 99MER
carbon dioxide and trifluoromethane 99MER
trifluoromethane and sulfur hexafluoride 99MER
_____________________________________________________________________________
____________________________________________________________________________________
4.5. References
80RAE Raetzsch, M., Findeisen, R., and Sernov, V.S., Untersuchungen zum Phasenverhalten von
Monomer-Polymer-Systemen unter hohem Druck, Z. Phys. Chemie, Leipzig, 261, 995, 1980.
82RAE Raetzsch, M.T., Wagner, P., Wohlfarth, C., and Heise, D., High-pressure phase equilibrium
studies in mixtures of ethylene and (ethylene-vinyl acetate) copolymers. Part I. Dependence
on vinyl acetate content of copolymers (Ger.), Acta Polym., 33, 463, 1982.
82WOH Wohlfarth, C., Wagner, P., Raetzsch, M.T., and Westmeier, S., High-pressure phase
equilibrium studies in mixtures of ethylene and (ethylene-vinyl acetate) copolymers. Part II.
Temperature effect (Ger.), Acta Polym., 33, 468, 1982.
83RAE Raetzsch, M.T., Wagner, P., Wohlfarth, C., and Gleditzsch, S., Studies of phase equilib-
riums in mixtures of ethylene and ethylene-vinyl acetate copolymers at high pressures. Part
III. Dependence on the molar weight distribution (Ger.), Acta Polym., 34, 340, 1983.
83WOH Wohlfarth, C. and Rätzsch, M.T., Calculation of high-pressure phase equilibria in mixtures
of ethylene, vinyl acetate, and ethylene-vinyl acetate copolymers, Acta Polym., 34, 255, 1983.
84WAG Wagner, P., Zum Phasengleichgewicht im System Ethylen + Ethylen-Vinylacetat-
Copolymer unter hohem Druck, PhD-Thesis, TH Leuna-Merseburg, 1984.
84WOH Wohlfarth, Ch., Wagner, P., Glindemann, D., Voelkner, M., and Rätzsch, M.T., High-
pressure phase equilibrium in the system ethylene + vinyl acetate + (ethylene-vinyl acetate)
copolymers (Ger.), Acta Polym., 35, 498, 1984.
85MCC McClellan, A.K. and McHugh, M.A., Separating polymer solutions using high pressure
lower critical solution temperature (LCST) phenomena, Polym. Eng. Sci., 25, 1088, 1985.
85MCH McHugh, M.A. and Guckes, T.L., Separating polymer solutions with supercritical fluids,
86IRA Irani, C.A. and Cozewith, C., Lower critical solution temperature behavior of ethylene
87LUF Luft, G. and Subramanian, N.S., Phase behavior of mixtures of ethylene, methyl acrylate,
and copolymers under high pressures, Ind. Eng. Chem. Res., 26, 750, 1987.
91FIN Finck, U., Phasengleichgewichte in Monomer + Copolymer - Systemen, Diploma paper,
91MEI Meilchen, M.A., Hasch, B.M., and McHugh, M.A., Effect of copolymer composition on the
phase behavior of mixtures of poly(ethylene-co-methyl acrylate) with propane and chloro-
difluoromethane, Macromolecules, 24, 4874, 1991.
91NIE Nieszporek, B., Untersuchungen zum Phasenverhalten quasibinärer und quasiternärer
Mischungen aus Polyethylen, Ethylen-Vinylacetat-Copolymeren, Ethylen und Vinylacetat
unter Druck, PhD-Thesis, TH Darmstadt, 1991.
92CH1 Chen, S.-J. and Radosz, M., Density-tuned polyolefin phase equilibria 1, Macromolecules,
25, 3089, 1992.
92CH2 Chen, S.-J., Economou, I.G., Radosz, M., Density-tuned polyolefin phase equilibria 2,
92FIN Finck, U., Wohlfarth, Ch., and Heuer, T., Calculation of high pressure phase equilibria of
mixtures of ethylene, vinyl acetate and an (ethylene-vinyl acetate) copolymer, Ber.
92HAS Hasch, B.A., Meilchen, M.A., Lee, S.-H., and McHugh, M.A., High-pressure phase
behavior of mixtures of poly(ethylene-co-methyl acrylate) with low-molecular weight
hydrocarbons, J. Polym. Sci., Part B: Polym. Phys., 30, 1365, 1992.
92LUF Luft, G. and Wind, R.W., Phasenverhalten von Mischungen aus Ethylen und Ethylen-
Acrylsäure-Copolymeren unter hohem Druck, Chem.-Ing.-Techn., 64, 1114, 1992.
92MEI Meilchen, M.A., Hasch, B.M., Lee, S.-H., and McHugh, M.A., Poly(ethylene-co-methyl
acrylate)-solvent-cosolvent phase behaviour at high pressures, Polymer, 33, 1922, 1992.
92WIN Wind, R.W., Untersuchungen zum Phasenverhalten von Mischungen aus Ethylen, Acrylsäure
und Ethylen-Acrylsäure-Copolymer unter hohem Druck, PhD-Thesis, TH Darmstadt, 1992.
____________________________________________________________________________________
93CHE Chen, S.-J., Economou, I.G., and Radosz, M., Phase behavior of LCST and UCST solutions
of branchy copolymers. Experiment and SAFT modelling, Fluid Phase Equil., 83, 391, 1993
93GRE Gregg, C.J., Chen, S.-J., Stein, F.P., and Radosz, M., Phase behavior of binary ethylene-
propylene copolymer solutions in sub- and supercritical ethylene and propylene, Fluid
Phase Equil., 83, 375, 1993.
93HA1 Hasch, B.M., Meilchen, M.A., Lee, S.-H., and McHugh, M.A., Cosolvency effects on
copolymer solutions at high pressure, J. Polym. Sci., Part B: Polym. Phys., 31, 429, 1993.
93HA2 Hasch, B.M., Lee, S.-H., and McHugh, M.A., The effect of copolymer architecture on
solution behavior, Fluid Phase Equil., 83, 341, 1993.
93PRA Pratt, J.A., Lee, S.-H., and McHugh, M.A., Supercritical fluid fractionation of copolymers
based on chemical composition and molecular weight, J. Appl. Polym. Sci., 49, 953, 1993.
94GR1 Gregg, C.J., Phase equilibria of supercritical fluid solutions of associating polymers in
nonpolar and polar fluids, PhD-Thesis, Lehigh University, Bethlehem, 1994.
94GR2 Gregg, C.J., Stein, F.P., Morgan, C.K., and Radosz, M., A variable-volume optical pressure-
volume-temperature cell for high-pressure cloud points, densities, and IR-spectra, applicable
to supercritical fluid solutions of polymers up to 2 kbar, J. Chem. Eng. Data, 39, 219, 1994.
94LE1 Lee, S.-H., LoStracco, M.A., Hasch, B.M., and McHugh, M.A., Solubility of poly(ethylene-
co-acrylic acid) in low molecular weight hydrocarbons, J. Phys. Chem., 98, 4055, 1994.
94LE2 Lee, S.-H., LoStracco, A., and McHugh, M.A., High pressure, molecular weight-dependent
behavior of (co)polymer-solvent mixtures, Macromolecules, 27, 4652, 1994.
95CHE Chen, S., Banaszak, M., and Radosz, M., Phase behavior of poly(ethylene-1-butene) in
subcritical and supercritical propane, Macromolecules, 28, 1812, 1995.
96ALB Albrecht, K.L., Stein, F.P., Han, S.J., Gregg, C.J., and Radosz, M., Phase equilibria of
saturated and unsaturated polyisoprene in sub- and supercritical ethane, ethylene, propane,
propylene, and dimethyl ether, Fluid Phase Equil., 117, 84, 1996.
96BUB Buback, M., Busch, M., Dietzsch, H., Droege, T., and Lovis, K., Cloud-point curves in
ethylene-acrylate-poly(ethylene-co-acrylate) systems, in High Pressure Chemical Enginee-
ring, von Rohr, Ph.R., Trepp, Ch., Eds., Elsevier Sci. B.V., 1996, 175.
96BYU Byun, H.-S., Hasch, B.M., McHugh, M.A., Maehling, F.-O., Busch, M., and Buback, M.,
Poly(ethylene-co-butyl acrylate). Phase behavior in ethylene compared to the poly(ethylene-
co-methyl acrylate)-ethylene system and aspects of copolymerization kinetics at high
pressures, Macromolecules, 29, 1625, 1996.
96DEL DeLoos, Th.W., de Graaf, L.J., and de Swaan Arons, J., Liquid-liquid phase separation in
linear low density polyethylene - solvent systems, Fluid Phase Equil., 117, 40, 1996.
96FOL Folie, B., Gregg, C., Luft, G., and Radosz, M., Phase equilibria of poly(ethylene-co-vinyl
acetate) copolymers in subcritical and supercritical ethylene and ethylene - vinyl acetate
mixtures, Fluid Phase Equil., 120, 11, 1996.
96LE1 Lee, S.-H., Hasch, B.M., and McHugh, M.A., Calculating copolymer solution behavior with
statistical associating fluid theory, Fluid Phase Equil., 117, 61, 1996.
96LE2 Lee, S.-H., LoStracco, M.A., and McHugh, M.A., Cosolvent effect on the phase behavior of
poly(ethylene-co-acrylic acid) - butane mixtures, Macromolecules, 29, 1349, 1996.
96LE3 Lee, S.-H. and McHugh, M.A., Influence of chain architecture on high-pressure co-polymer
solution behavior: Experiments and modeling, in High Pressure Chemical Engineering, von
Rohr, Ph.R., Trepp, Ch., Eds., Elsevier Sci. B.V., 1996, 11.
96MER Mertdogan, C.A., Byun, H.-S., McHugh, M.A., and Tuminello, W.H., Solubility of poly
(tetrafluoroethylene-co-19 mol% hexafluoropropylene) in supercritical CO2 and halogenated
supercritical solvents, Macromolecules, 29, 6548, 1996.
96MUE Mueller, C., Untersuchungen zum Phasenverhalten von quasibinären Gemischen aus
Ethylen und Ethylen-Copolymeren, PhD-Thesis, Univ. Karlsruhe (TH), 1996.
____________________________________________________________________________________
96RIN Rindfleisch, F., DiNoia, T.P., and McHugh, M.A., Solubility of polymers and copolymers
in supercritical CO2, J. Phys. Chem., 100, 15581, 1996.
97HAN Han, S.J., Gregg, C.J., and Radosz, M., How the solute polydispersity affects the cloud-
point and coexistence pressures in propylene and ethylene solutions of alternating
poly(ethylene-co-propylene), Ind. Eng. Chem. Res., 36, 5520, 1997.
97LEE Lee, S.-H. and McHugh, M.A., Phase behaviour studies with poly(ethylene-co-methacrylic
acid) at high pressures, Polymer, 38, 1317, 1997.
97LEP Lepilleur, C., Beckman, E.J., Schonemann, H., and Krukonis, V.J., Effect of molecular
architecture on the phase behavior of fluoroether-functional graft copolymers in
supercritical CO2, Fluid Phase Equil., 134, 285, 1997.
97MER Mertdogan, C.A., DiNoia, T.P., and McHugh, M.A., Impact of backbone architecture on the
solubility of fluoropolymers in supercritical CO2 and halogenated supercritical solvents,
97WHA Whaley, P.D., Winter, H.H., and Ehrlich, P., Phase equilibria of polypropylene with
compressed propane and related systems. 2, Macromolecules, 30, 4887, 1997.
98HAN Han, S.J., Lohse, D.J., Radosz, M., and Sperling, L.H., Short chain branching effect on the
cloud-point pressures of ethylene copolymers in subcritical and supercritical propane,
98LEE Lee, S.-H. and McHugh, M.A., Phase behavior of copolymer-copolymer-solvent mixtures at
98MCH McHugh, M.A., Mertdogan, C.A., DiNoia, T.P., Anolick, C., Tuminello, W.H., and
Wheland, R., Impact of melting temperature on poly(tetrafluoroethylene-co-hexafluoro-
propylene) solubility in supercritical fluid solvents, Macromolecules, 31, 2252, 1998.
98ONE O'Neill, M.L., Cao, Q., Fang, C.M., Johnston, K.P., Wilkinson, S.P., Smith, C.D.,
Kerschner, J.L., and Jureller, S.H., Solubility of homopolymers and copolymers in carbon
dioxide, Ind. Eng. Chem. Res., 37, 3067, 1998.
99KIN Kinzl, M., Einfluss der Zugabe von Inertkomponenten auf die Phasengleichgewichte von
Copolymerlösungen in überkritischem Ethen, PhD-Thesis, TH Darmstadt, 1999.
99LOR Lora, M., Rindfleisch, F., and McHugh, M.A., Influence of the alkyl tail on the solubility of
poly(alkyl acrylates) in ethylene and CO2 at high pressures: Experiments and modeling, J.
Appl. Polym. Sci., 73, 1979, 1999.
99MER Mertdogan, C.A., McHugh, M.A., and Tuminello, W.H., Cosolvency effect of SF6 on the
solubility of poly(tetrafluoroethylene-co-19 mol% hexafluoropropylene) in supercritical CO2
and CHF3, J. Appl. Polym. Sci., 74, 2039, 1999.
99PAN Pan, C. and Radosz, M., Phase behavior of poly(ethylene-co-hexene-1) solutions in
isobutane and propane, Ind. Eng. Chem. Res., 38, 2842, 1999.
2000CH1 Chan, K.C., Adidharma, H., and Radosz, M., Fluid-liquid and fluid-solid transitions of
poly(ethylene-co-octene-1) in sub- and supercritical propane solutions, Ind. Eng. Chem.
Res., 39, 3069, 2000.
2000CH2 Chan, A.K.C., Russo, P.S., and Radosz, M., Fluid-liquid equilibria in poly(ethylene-co-
hexene-1) + propane: a light-scattering probe of cloud-point pressure and critical polymer
concentration, Fluid Phase Equil., 173, 149, 2000.
2000CH3 Chan, A.K.C. and Radosz, M., Fluid-liquid and fluid-solid phase behavior of poly(ethylene-
co-hexene-1) solutions in sub- and supercritical propane, ethylene, and ethylene + hexene-1,
2000DIN DiNoia, T.P., Conway, S.E., Lim, J.S., McHugh, M.A., Solubility of vinylidene fluoride
polymers in supercritical CO2 and halogenated solvents, J. Polym. Sci., Part B: Polym.
Phys., 38, 2832, 2000
2000KIN Kinzl, M., Luft, G., Adidharma, H., and Radosz, M., SAFT modeling of inert-gas effects on
the cloud-point pressures in ethylene copolymerization systems: Poly(ethylene-co-vinyl
acetate) + vinyl acetate + ethylene and poly(ethylene-co-hex-1-ene) + 1-hexene + ethylene
with carbon dioxide, nitrogen, or butane, Ind. Eng. Chem. Res., 39, 541, 2000.
5. ENTHALPY CHANGES FOR BINARY COPOLYMER
SOLUTIONS

and copolymer partial enthalpies of mixing (at infinite dilution),
or copolymer (first) integral enthalpies of solution
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
18.0 wt% acrylonitrile AN-B/18w 55TA1
26.0 wt% acrylonitrile AN-B/26w(1) 50TAG
26.0 wt% acrylonitrile AN-B/26w(2) 55TA1
40.0 wt% acrylonitrile AN-B/40w(2) 55TA1
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-B/18w no data
AN-B/26w(1) Buna No. 26
AN-B/26w(2) no data
AN-B/40w(1) Buna No. 40
AN-B/40w(2) no data
_____________________________________________________________________________
____________________________________________________________________________________
Experimental enthalpy data:

_____________________________________________________________________________
copolymer (B): AN-B/18w 55TA1

T/K = 298.15
∆solHB∞ = 0.0 J/(g copolymer)
Comments: the final concentration is about 2 g copolymer/132 g solvent
copolymer (B): AN-B/26w(1) 50TAG, 51TAG

T/K = 298.15
Comments: the final concentration is about 0.55 g copolymer/100 g solution
copolymer (B): AN-B/26w(2) 55TA1

T/K = 298.15
∆solHB∞ = −1.88 J/(g copolymer)
copolymer (B): AN-B/40w(1) 50TAG, 51TAG

T/K = 298.15
Comments: the final concentration is about 0.85 g copolymer/100 g solution
copolymer (B): AN-B/40w(2) 55TA1

T/K = 298.15

____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from acrylonitrile and isoprene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Acrylonitrile/isoprene copolymer
85.0 mol% acrylonitrile AN-IP/85x 76PET
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-IP/85x no data
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): AN-IP/85x 76PET

solvent (A): N,N-dimethylformamide C3H7NO 68-12-2
T/K = 323.15
Comments: additional information is given for varying isoprene contents between 2 and 22 mol% in the
copolymer in Fig. 1 of the original source 76PET
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from acrylonitrile and vinyl chloride
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
13.0 wt% acrylonitrile AN-VC/13w 59ZEL
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-VC/13w no data
AN-VC/29w no data
AN-VC/40w no data
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): AN-VC/13w 59ZEL

T/K 295.15 308.15 308.15 323.15 323.15 338.15 338.15

∆solHB∞/(g copolymer) −37.95 −22.18 −21.34 −19.25 −16.95 −15.48 −14.64
T/K 353.15 353.15
∆solHB∞/(g copolymer) −12.97 −11.30

____________________________________________________________________________________

T/K 295.15 295.15 308.15 308.15 323.15 323.15 338.15

T/K 338.15 353.15 353.15
∆solHB∞/(g copolymer) −17.99 −16.32 −15.90

T/K 295.15 295.15 308.15 323.15 323.15 338.15 338.15

T/K 353.15
∆solHB∞/(g copolymer) −17.15
_____________________________________________________________________________
Copolymers from acrylonitrile and vinylidene chloride
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
unspecified contents of acrylonitrile AN-VdC/? 55ZAZ
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-VdC/? fibre "Saniv", USSR
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): AN-VdC/? 55ZAZ

T/K = 298.15 ∆solHB∞ = −28.03 J/g copolymer

T/K = 298.15 ∆solHB∞ = −19.25 J/g copolymer (fibre drawn 156%)
_____________________________________________________________________________
Copolymers from bisphenol A-isophthaloyl chloride and terephthaloyl chloride
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Bisphenol A-isophthaloyl chloride/terephthaloyl
chloride copolymer
50 mol% terephthaloyl chloride BAIPC-TPC/50x 78SOK
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
BAIPC-TPC/50x synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): BAIPC-TPC/50x 78SOK

solvent (A): N,N-dimethylacetamide C4H9NO 127-19-5
T/K = 298.15
Comments: amorphous sample

solvent (A): 1,1,2,2-tetrachloroethane C2H2Cl4 79-34-5
T/K = 298.15
Comments: amorphous sample

solvent (A): 1,1,2,2-tetrachloroethane C2H2Cl4 79-34-5
T/K = 298.15
Comments: partially crystalline sample
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
10.0 wt% styrene S-BR/10w 55TA2
30.0 wt% styrene S-BR/30w(1) 55TA2
30.0 wt% styrene S-BR/30w(1) 58TA2
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
_____________________________________________________________________________
30.0 wt% styrene S-BR/30w(2) 56STR
30.0 wt% styrene S-BR/30w(2) 58SLO
75.0 wt% styrene S-BR/75w 50TAG
75.0 wt% styrene S-BR/75w 51TAG
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BR/10w synthesized in the laboratory
S-BR/30w(1) synthesized in the laboratory
S-BR/30w(2) intrinsic viscosity = 1.50
S-BR/75w Buna-S
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-BR/10w 55TA2

T/K = 293.65
wB 0.1 0.2 0.3 0.4 0.5 0.7 0.8 0.99
∆MH/(J/g) 0.33 0.63 0.92 1.26 1.59 2.43 2.55 0.42
____________________________________________________________________________________

T/K = 293.65
Comments: the final concentration is about 2.7 g copolymer/100 ml solvent

solvent (C): 2,2,4-trimethylpentane C8H18 540-84-1
T/K = 298.15
Comments: solvent mixture concentration 10 wt% C8H10 / 90 wt% C8H18
copolymer (B): S-BR/30w(1) 55TA2

T/K = 293.65
wB 0.1 0.2 0.3 0.4 0.5 0.685 0.943 0.96

∆MH/(J/g) 0.17 0.38 0.54 0.71 0.88 1.21 0.92 0.67

T/K = 293.65
copolymer (B): S-BR/30w(2) 56STR, 58SLO

T/K = 298.15
Comments: final concentration 1 g copolymer/100 g solvent

____________________________________________________________________________________

T/K = 298.15

T/K = 293.65
Comments: the final concentration is about 4 g copolymer/100 ml solvent

T/K = 298.15

T/K = 293.65
wB 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

∆MH/(J/g) 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0

T/K = 293.65

____________________________________________________________________________________

T/K = 298.15

T/K = 293.65

T/K = 298.15
copolymer (B): S-BR/75w 50TAG, 51TAG

T/K = 298.15

T/K = 293.65

____________________________________________________________________________________

T/K = 298.15

T/K = 293.65
wB 0.10 0.20 0.30 0.44 0.55 0.65 0.79 0.81 0.86 0.93
∆MH/(J/g) −0.50 −1.00 −1.46 −2.13 −2.72 −3.18 −3.89 −4.02 −4.22 −3.39
wB 0.95 0.95 0.96
∆MH/(J/g) −2.80 −2.59 −1.88

T/K = 293.65

T/K = 298.15

____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from butyl methacrylate and isobutyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Butyl methacrylate/isobutyl methacrylate copolymer
50 wt% isobutyl methacrylate BMA-IBMA/50w 96SAT
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
BMA-IBMA/50w 150000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): BMA-IBMA/50w 96SAT

solvent (A): cyclohexanone C6H10O 108-94-1
T/K = 298.15
and
T/K = 298.15
∆MHB∞ = 14.0 J/(g copolymer)
Comments: ∆MHB∞ is corrected for the enthalpy from the glass transition
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from butyl methacrylate and methyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Butyl methacrylate/methyl methacrylate copolymer
55 wt% methyl methacrylate BMA-MMA/55w 96SHI
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
BMA-MMA/55w 109000 250000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): BMA-MMA/55w 96SHI

T/K = 298.15
and
T/K = 298.15
∆MHB∞ = +9.1 J/(g copolymer)
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from ε-carbobenzoxy-L-lysine and L-phenylalanine
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
ε-Carbobenzoxy-L-lysine/L-phenylalanine copolymer
25 mol% L-phenylalanine CBL-PHA/25x 70GIA
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
CBL-PHA/25x no data
CBL-PHA/50x no data
CBL-PHA/75x no data
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): CBL-PHA/25x 70GIA

T/K = 303.15
∆solHB∞ = −6900 J/(base mol copolymer)
Comments: the final concentration is about 0.1 wt%
A graph is given in the original source for ∆solHB∞ for the binary mixture of 1,2-dichloroethane with
dichloroacetic acid
____________________________________________________________________________________

T/K = 303.15
dichloroacetic acid

T/K = 303.15
dichloroacetic acid
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
33 mol% ethylene E-P/33x 79PH1
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-P/33x 145000
E-P/63x 236000
E-P/75x 109000
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-P/33x 79PH1, 79PH2

T/K = 298.15

T/K = 298.15

T/K = 298.15

solvent (A): cyclooctane C8H16 292-64-8
T/K = 298.15

T/K = 298.15
____________________________________________________________________________________

T/K = 298.15

T/K = 298.15
∆MHB∞ = −3.5 J/(g copolymer)

T/K = 298.15

solvent (A): cis-decahydronaphthalene C10H18 493-01-6
T/K = 298.15

T/K = 298.15

T/K = 298.15

T/K = 298.15
____________________________________________________________________________________

T/K = 298.15

T/K = 298.15

solvent (A): 3,3-diethylpentane C9H20 4032-86-4
T/K = 298.15

solvent (A): 3,3-diethylpentane C9H20 4032-86-4
T/K = 298.15
∆MHB∞ = < 0.1 J/(g copolymer)

solvent (A): 2,2-dimethylpentane C7H16 590-35-2
T/K = 298.15

T/K = 298.15

T/K = 298.15
____________________________________________________________________________________

T/K = 298.15

T/K = 298.15

T/K = 298.15

T/K = 298.15

T/K = 298.15

T/K = 298.15

solvent (A): n-dodecane C12H26 112-40-3
T/K = 298.15
____________________________________________________________________________________

T/K = 298.15

T/K = 298.15

solvent (A): 3-ethylpentane C7H16 617-78-7
T/K = 298.15

solvent (A): 3-ethylpentane C7H16 617-78-7
T/K = 298.15

solvent (A): 2,2,4,4,6,8,8-heptamethylnonane C16H34 4390-04-9
T/K = 298.15

T/K = 298.15

T/K = 298.15
____________________________________________________________________________________

solvent (A): n-hexadecane C16H34 544-76-3
T/K = 298.15

T/K = 298.15

T/K = 298.15
Comments: after subtracting the small heat of fusion of this copolymer

solvent (A): 3-methylhexane C7H16 589-34-4
T/K = 298.15

solvent (A): 3-methylhexane C7H16 589-34-4
T/K = 298.15

T/K = 298.15

____________________________________________________________________________________

T/K = 298.15

T/K = 298.15

solvent (A): 2,2,4,6,6-pentamethylheptane C12H26 13475-82-6
T/K = 298.15

T/K = 298.15

T/K = 298.15

solvent (A): 2,2,4,4-tetramethylpentane C9H20 1070-87-7
T/K = 298.15

____________________________________________________________________________________

T/K = 298.15

T/K = 298.15

solvent (A): 2,2,4-trimethylpentane C8H18 540-84-1
T/K = 298.15

T/K = 298.15

T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
70.0 wt% vinyl acetate E-VA/70w 90SHI
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-VA/70w 220000 Bayer, Japan
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-VA/70w 90SHI

solvent (A): tetrahydrofuran C4H8O 109-99-9
T/K = 304.65
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
diblock copolymer
58.0 wt% propylene oxide EO-b-PO/58w 89MOE
58.0 wt% propylene oxide EO-b-PO/58w 90KIL

60.6 mol% propylene oxide EO-PO-EO/61x 85COR
60.6 mol% propylene oxide EO-PO-EO/61x 95KIL
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
EO-b-PO/58w 1700
EO-PO-EO/61x 1900 PE 4300, BASF, Germany
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): EO-b-PO/58w 89MOE, 90KIL

T/K = 303.15
wB 0.0180 0.0408 0.0628 0.0838 0.1235 0.1602 0.1942 0.2370 0.2402

∆MH/(J/g) −0.285 −0.618 −0.925 −1.205 −1.685 −2.096 −2.437 −2.856 −2.897
wB 0.2763 0.2936 0.3121 0.3449 0.3804 0.4241 0.4792 0.5306 0.5942
∆MH/(J/g) −3.178 −3.287 −3.436 −3.578 −3.728 −3.844 −3.902 −3.860 −3.690
wB 0.6751 0.7246 0.7818 0.8487 0.9283 0.9739 0.9935
∆MH/(J/g) −3.324 −3.010 −2.564 −1.917 −0.950 −0.298 −0.078
copolymer (B): EO-PO-EO/61x 85COR, 95KIL

T/K = 303.15
wB 0.0076 0.0147 0.0251 0.0353 0.0453 0.0551 0.0658 0.0763 0.0866

∆MH/(J/g) −0.067 −0.134 −0.236 −0.340 −0.443 −0.546 −0.663 −0.776 −0.889
wB 0.0966 0.1064 0.1160 0.1265 0.1368 0.1564 0.1687 0.1806 0.1935
∆MH/(J/g) −0.998 −1.104 −1.209 −1.321 −1.429 −1.612 −1.718 −1.822 −1.932
wB 0.2059 0.2180 0.2297 0.2411 0.2567 0.2852 0.3131 0.3506 0.3587
∆MH/(J/g) −2.037 −2.139 −2.235 −2.327 −2.425 −2.653 −2.818 −2.990 −3.021
wB 0.3750 0.3865 0.3912 0.4101 0.4215 0.4524 0.4923 0.5305 0.5581
∆MH/(J/g) −3.092 −3.153 −3.162 −3.226 −3.245 −3.329 −3.352 −3.331 −3.296
wB 0.5930 0.6263 0.6578 0.7062 0.8022 0.8708 0.9475 0.9821
∆MH/(J/g) −3.194 −3.043 −2.871 −2.592 −1.982 −1.381 −0.584 −0.198
____________________________________________________________________________________

T/K = 303.15
wB 0.0040 0.0110 0.0215 0.0316 0.0449 0.0577 0.0850 0.1107 0.1339

∆MH/(J/g) −0.021 −0.065 −0.136 −0.209 −0.309 −0.407 −0.624 −0.837 −0.967
wB 0.1573 0.1936 0.2284 0.2729 0.3432 0.4134 0.4892 0.5528 0.6162
∆MH/(J/g) −1.123 −1.331 −1.503 −1.694 −1.924 −2.094 −2.138 −2.158 −2.045
wB 0.7140 0.8178 0.9076 0.9389 0.9723
∆MH/(J/g) −1.817 −1.455 −0.829 −0.566 −0.254

T/K = 303.15
wB 0.0027 0.0043 0.0389 0.0613 0.0896 0.1207 0.1498 0.1770 0.2272

∆MH/(J/g) −0.024 −0.038 −0.361 −0.564 −0.834 −1.130 −1.394 −1.617 −2.048
wB 0.2726 0.3285 0.3974 0.4479 0.5449 0.6677 0.7389 0.8270 0.9053
∆MH/(J/g) −2.367 −2.668 −2.907 −2.999 −2.945 −2.535 −2.130 −1.496 −0.837
_____________________________________________________________________________
Copolymers from isobutyl methacrylate and methyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Isobutyl methacrylate/methyl methacrylate copolymer
49 wt% methyl methacrylate IBMA-MMA/49w 96SAT
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
IBMA-MMA/49w 240000 synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): IBMA-MMA/49w 96SAT

T/K = 298.15
and
T/K = 298.15
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
20.6 wt% styrene S-BMA/21w 87KYO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BMA/21w 185000 311000 Scientific Polymer Products
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-BMA/21w 87KYO

solvent (A): 2-butanone C4H8O 78-93-3
T/K = 298.15
ϕB(1) 0.0908 0.0908 0.0908 0.0908 0.0908 0.0908

ϕB(2) 0.0272 0.0454 0.0545 0.0636 0.0724 0.0814
∆dilH12/(J/mol) 0.564 0.778 0.860 1.056 1.390 1.748
Comments: the table provides the ratio of ∆dilH12/∆nA, i.e., the enthalpy change caused by diluting the
primary solution by 1 mol solvent, where ϕB(1) denotes the volume fraction of the copolymer
in the starting solution and ϕB(2) denotes the volume fraction after the dilution process.

T/K = 298.15
ϕB(1) 0.0788 0.0788 0.0788 0.0788 0.0788 0.0788 0.0788

ϕB(2) 0.0221 0.0323 0.0355 0.0497 0.0551 0.0654 0.0607
∆dilH12/(J/mol) 0.170 0.282 0.261 0.351 0.393 0.399 0.569

T/K = 298.15
ϕB(1) 0.0465 0.0465 0.0465 0.0465 0.0465 0.0776 0.0776 0.0766

ϕB(2) 0.0189 0.0279 0.0326 0.0372 0.0419 0.0380 0.0388 0.0465
∆dilH12/(J/mol) 0.104 0.164 0.121 0.228 0.232 0.304 0.326 0.432
ϕB(1) 0.0766 0.0766 0.0766
ϕB(2) 0.0543 0.0621 0.0698
∆dilH12/(J/mol) 0.555 0.706 0.867
____________________________________________________________________________________

T/K = 298.15
ϕB(1) 0.0777 0.0777 0.0777 0.0777 0.0777 0.0777

ϕB(2) 0.0583 0.0505 0.0428 0.0350 0.0272 0.0192
∆dilH12/(J/mol) −0.453 −0.328 −0.255 −0.195 −0.169 −0.105
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
0.4 mol% vinyl acetate VA-VAL/01x 56AMA
4.2 mol% vinyl acetate VA-VAL/04x(1) 55OYA
9.0 mol% vinyl acetate VA-VAL/09x 55OYA
9.0 wt% vinyl acetate VA-VAL/09w 58TA1
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
VA-VAL/01x 53000 Mitsubishi Rayon Co., Japan
VA-VAL/04x(1) 7560
VA-VAL/04x(2) 64300
VA-VAL/09x 66900
VA-VAL/10x 7970
VA-VAL/15x(1) 8300
VA-VAL/15x(2) 70700
VA-VAL/20x 73100
VA-VAL/22x 8800
VA-VAL/26x 77000
VA-VAL/31x 9370
VA-VAL/34x 81600
VA-VAL/35x 9670
VA-VAL/09w synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): VA-VAL/01x 56AMA

T/K = 343.15
V (1)/cm3 9.00 9.51

ϕB(1) 0.099 0.109
V (2)/cm3 19.00 19.51
ϕB(2) 0.047 0.053
∆dilh12/J −0.607 −0.741
where ϕB(1) denotes the volume fraction of the copolymer in the starting solution and ϕB(2) in
denotes the volume fraction after the dilution process.
____________________________________________________________________________________
copolymer (B): VA-VAL/04x(1) 55OYA

T/K = 303.15
Comments: the final concentration is < 2 g copolymer/200 cm3 solvent

T/K = 303.15
copolymer (B): VA-VAL/09x 55OYA

T/K = 303.15

T/K = 303.15

T/K = 343.15
V (1)/cm3 9.57 8.57
ϕB(1) 0.077 0.077
V (2)/cm3 19.57 18.57
ϕB(2) 0.038 0.0355
∆dilh12/J −0.699 −0.632
____________________________________________________________________________________

T/K = 303.15

T/K = 303.15

T/K = 343.15
V (1)/cm3 9.91 9.94
ϕB(1) 0.052 0.052
V (2)/cm3 19.91 19.94
ϕB(2) 0.026 0.026
∆dilh12/J −0.167 −0.172

T/K = 343.15
V (1)/cm3 9.86 9.94
ϕB(1) 0.038 0.038
V (2)/cm3 19.86 19.94
ϕB(2) 0.019 0.019
∆dilh12/J −0.071 −0.063
____________________________________________________________________________________

T/K = 303.15

T/K = 303.15

T/K = 303.15

T/K = 303.15

T/K = 303.15

____________________________________________________________________________________

T/K = 303.15
copolymer (B): VA-VAL/09w 58TA2

solvent (C): ethanol C2H6O 64-17-5
T/K = 298.15
Comments: the solvent mixture concentration is equal to the comonomer contents,

i.e., 9.0 wt% ethyl acetate/91.0 wt% ethanol

T/K = 298.15

T/K = 298.15


T/K = 298.15

____________________________________________________________________________________

T/K = 298.15


T/K = 298.15

T/K = 298.15


T/K = 298.15

T/K = 298.15

____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
10.0 wt% vinyl acetate VA-VC/10w 97SAT
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
VA-VC/10w 12400 26000 Scientific Polymer Products
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): VA-VC/10w 97SAT

T/K = 304.15
and
T/K = 304.15
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
unspecified contents of vinyl chloride VC-VdC/? 56LIP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
VC-VdC/? no data
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): VC-VdC/? 56LIP

T/K = 297.15
Comments: non-oriented sample
and
T/K = 297.15
Comments: oriented sample, drawn 100%

____________________________________________________________________________________
5.2. Partial molar enthalpies of mixing at infinite dilution of solvents

and enthalpies of solution of gases/vapors of solvents in molten
copolymers from inverse gas-liquid chromatography (IGC)
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
34.0 wt% acrylonitrile AN-B/34w 93ISS
34.0 wt% acrylonitrile AN-B/34w 97SCH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-B/34w 60000 Perbunan 3307, Bayer AG, Ger.
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): AN-B/34w 93ISS
_____________________________________________________________________________
solvent (A) T-range/ ∆solHA(vap)∞/ solvent (A) T-range/ ∆solHA(vap)∞/
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 333.15-393.15 −31.80 n-octane 333.15-393.15 −30.23
n-heptane 333.15-393.15 −25.94 toluene 333.15-393.15 −35.30
n-nonane 333.15-393.15 −35.62
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): AN-B/34w 97SCH
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 323.15-393.15 −31.82 n-hexane 323.15-393.15 −30.50
cyclohexane 323.15-393.15 −31.65 toluene 323.15-393.15 −35.60
n-heptane 323.15-393.15 −35.41
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from acrylonitrile and methyl acrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Acrylonitrile/methyl acrylate copolymer
91.9 wt% acrylonitrile AN-MA/92w 94COS
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-MA/92w Yalova Fibre Co., Turkey
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): AN-MA/92w 94COS
_____________________________________________________________________________
solvent (A) T-range/ ∆MHA∞/ solvent (A) T-range/ ∆MHA∞/
K kJ/mol K kJ/mol
_____________________________________________________________________________
1-butanol 383.15-413.15 31.74 1-pentanol 383.15-413.15 31.11
ethanol 383.15-413.15 33.24 1-propanol 383.15-413.15 32.41
1-hexanol 383.15-413.15 45.05
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from acrylonitrile and 2-(3-methyl-3-phenylcyclobutyl)-
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
45.0 mol% acrylonitrile AN-MPCHEMA/45x 2000KAY
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-MPCHEMA/45x ρB = 1.075 g/cm3,
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): AN-MPCHEMA/45x 2000KAY
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 443.15-453.15 24.95 methyl acetate 443.15-453.15 16.62
2-butanone 443.15-453.15 8.33 n-nonane 443.15-453.15 23.28
n-decane 443.15-453.15 23.28 n-octane 443.15-453.15 16.62
n-dodecane 443.15-453.15 26.63 2-propanone 443.15-453.15 18.30
ethanol 443.15-453.15 38.27 toluene 443.15-453.15 24.95
ethyl acetate 443.15-453.15 14.99 n-undecane 443.15-453.15 19.97
methanol 443.15-453.15 24.95 o-xylene 443.15-453.15 23.28
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from acrylonitrile and α-methylstyrene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Acrylonitrile/α-methylstyrene copolymer
30.0 wt% acrylonitrile AN-αMS/30w 84SIO
30.0 wt% acrylonitrile AN-αMS/30w 86SIO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-αMS/30w 160000 synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): αMS/30w

AN-α 84SIO, 86SIO
_____________________________________________________________________________
solvent (A) T-range/ ∆MHA∞/ ∆solHA(vap)∞/
K kJ/mol kJ/mol
_____________________________________________________________________________
benzene 438.15-468.15 8.46 −18.46
1-butanol 438.15-468.15 14.57 −24.12
2-butanone 438.15-468.15 6.95 −20.10
butyl acetate 438.15-468.15 11.35 −21.94
butylbenzene 438.15-468.15 10.59 −30.60
chlorobenzene 438.15-468.15 4.31 −29.14
cyclohexanol 438.15-468.15 15.78 −25.79
dichloromethane 438.15-468.15 −2.51 −24.91
1,4-dioxane 438.15-468.15 4.48 −25.87
n-dodecane 438.15-468.15 31.36 −16.66
n-tetradecane 438.15-468.15 26.08 −29.98
tetrahydrofuran 438.15-468.15 11.68 −13.19
toluene 438.15-468.15 6.82 −23.57
trichloromethane 438.15-468.15 7.41 −17.08
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
15.0 wt% styrene S-BR/15w 97SCH
triblock copolymer
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BR/15w 240000 Buna EM BT98, Buna Werke Huels/Marl
S-BR/23w 210000 400000 Buna EM 1500, Buna Werke Huels/Marl
S-BR/40w 190000 Buna EM 1516, Buna Werke Huels/Marl
S-B-S/17w 114800 188300 Kraton D-1301X
S-B-S/31w 110800 139600 Kraton D-1101
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 323.15-393.15 −32.25 n-hexane 323.15-393.15 −29.44
n-heptane 323.15-393.15 −33.67
_____________________________________________________________________________
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 323.15-393.15 −31.84 n-hexane 323.15-393.15 −29.00
n-heptane 323.15-393.15 −34.93
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 323.15-393.15 −32.47 n-hexane 323.15-393.15 −29.22
n-heptane 323.15-393.15 −33.48
_____________________________________________________________________________
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
benzene 308.15-348.15 −0.252 −32.7
2-butanone 308.15-348.15 0.302 −32.8
cyclohexane 308.15-348.15 0.727 −30.8
ethylbenzene 308.15-348.15 0.397 −40.2
n-heptane 308.15-348.15 0.464 −34.4
n-hexane 308.15-348.15 −0.228 −30.0
toluene 308.15-348.15 −0.106 −36.7
trichloromethane 308.15-348.15 −2.467 −32.4
p-xylene 308.15-348.15 0.270 −40.4
_____________________________________________________________________________
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
benzene 308.15-348.15 −0.745 −33.2
2-butanone 308.15-348.15 −1.11 −34.2
cyclohexane 308.15-348.15 1.09 −30.4
ethylbenzene 308.15-348.15 −0.130 −40.7
n-heptane 308.15-348.15 0.459 −34.4
n-hexane 308.15-348.15 −0.765 −30.6
toluene 308.15-348.15 −0.134 −36.7
p-xylene 308.15-348.15 0.158 −40.5
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from chloroprene and methyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Chloroprene/methyl methacrylate copolymer
15.0 mol% methyl methacrylate CP-MMA/15x 98YAM
Chloroprene/methyl methacrylate/methacrylic acid terpolymer

13.8 mol% methyl methacrylate and
78.2 mol% chloroprene CP-MMA-MA/14x 98YAM
14.8 mol% methyl methacrylate and
83.7 mol% chloroprene CP-MMA-MA/15x 98YAM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
CP-MMA/15x synthesized in the laboratory
CP-MMA-MA/14x synthesized in the laboratory
CP-MMA-MA/15x synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): CP-MMA/15x 98YAM
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
tetrachloromethane 298.15-383.15 −4.64 −20.1
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): CP-MMA-MA/14x 98YAM
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B): CP-MMA-MA/15x 98YAM
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from diethylmaleate and vinyl acetate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Diethylmaleate/vinyl acetate copolymer
50 mol% vinyl acetate DEM-VA/50x 95NEM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
DEM-VA/50x 51200 synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): DEM-VA/50x 95NEM
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
n-heptane 359.96-378.36 12.748 −19.147
n-hexane 359.96-378.36 3.949 −24.071
n-nonane 359.96-378.36 29.693 −11.010
n-octane 359.96-378.36 21.209 −14.892
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and carbon monoxide
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
10.5 wt% carbon monoxide E-CO/11w 78DIP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-CO/11w no data
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-CO/11w 78DIP
_____________________________________________________________________________
solvent (A) T-range/ ∆MHA∞/
K kJ/mol
_____________________________________________________________________________
n-octane 381.23-411.23 1.08
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
40 wt% propylene E-P/40w 79ITO
50 mol% propylene E-P-D/50x 93ISS
50 mol% propylene E-P-D/50x 97SCH
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-P/40w no data
E-P-D/50x 90000 200000 Buna AP341, Buna-Werke Huels/Marl
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-P/40w 79ITO
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 303.15-346.15 2.39 n-decane 303.15-346.15 1.00
cyclohexane 303.15-346.15 0.92 n-hexane 303.15-346.15 1.05
ethylbenzene 303.15-346.15 2.13 n-octane 303.15-346.15 1.37
tert-butyl- 303.15-346.15 1.93 2,2,4-trimethyl- 303.15-346.15 1.30
benzene pentane
_____________________________________________________________________________
copolymer (B): E-P-D/50x 93ISS
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 333.15-393.15 −29.38 n-nonane 333.15-393.15 −43.25
n-heptane 333.15-393.15 −33.91 n-octane 333.15-393.15 −38.71
n-hexane 333.15-393.15 −29.05 toluene 333.15-393.15 −34.51
_____________________________________________________________________________
copolymer (B): E-P-D/50x 97SCH
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 323.15-393.15 −29.35 n-hexane 323.15-393.15 −29.41
n-heptane 323.15-393.15 −33.89 toluene 323.15-393.15 −34.50
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
18.0 wt% vinyl acetate E-VA/18w 80DIP
20.0 wt% vinyl acetate E-VA/20w 98KIM
29.0 wt% vinyl acetate E-VA/29w 78DIN
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-VA/18w DuPont Elvax460, MI = 2.5
E-VA/20w 37000 49000 Polymer Laboratories
E-VA/29w 43200 Union Carbide, DX-31034, MI = 15.0
_____________________________________________________________________________
_____________________________________________________________________________
copolymer (B): E-VA/18w 80DIP
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
benzene 388.15-408.15 0.08 −28.93
1-butanol 398.15-418.15 10.47 −32.07
chlorobenzene 388.15-408.15 0.88 −35.13
1-chlorobutane 388.15-408.15 2.01 −26.08
chlorocyclohexane 388.15-408.15 −36.13
cyclohexane 388.15-408.15 1.72 −26.59
cyclohexanol 388.15-408.15 9.59 −39.94
cyclohexanone 388.15-408.15 −37.30
n-hexane 388.15-408.15 1.09 −25.67
2-pentanone 388.15-408.15 3.01 −30.02
phenol 398.15-418.15 −1.42 −51.16
tetrachloromethane 388.15-408.15 2.60 −25.50
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): E-VA/20w 98KIM
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
benzene 423.15-463.15 −14.07 −41.88
1-butanol 423.15-463.15 −11.56 −48.85
2-butanone 423.15-463.15 −11.79 −26.23
butyl acetate 423.15-463.15 −11.55 −45.30
cyclohexane 423.15-463.15 −12.97 −38.91
n-decane 423.15-463.15 −12.61 −51.39
ethanol 423.15-463.15 − 9.72 −41.50
ethyl acetate 423.15-463.15 −10.42 −37.10
methanol 423.15-463.15 −12.01 −41.78
n-octane 423.15-463.15 −12.29 −44.55
2-propanone 423.15-463.15 −12.19 −36.52
toluene 423.15-463.15 −11.02 −38.79
p-xylene 423.15-463.15 −13.14 −47.60
_____________________________________________________________________________
copolymer (B): E-VA/29w 78DIN
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
acetaldehyde 423.61-433.68 −23.08 n-hexane 423.61-433.68 −24.63
acetic acid 423.61-433.68 −24.91 methanol 423.61-433.68 −14.48
acetonitrile 423.61-433.68 −28.21 methylcyclohexane 423.61-433.68 −30.94
acrylonitrile 423.61-433.68 −30.46 nitroethane 423.61-433.68 −32.98
benzene 423.61-433.68 −31.12 nitromethane 423.61-433.68 −31.78
1-bromobutane 423.61-433.68 −37.10 1-nitropropane 423.61-433.68 −33.52
2-bromobutane 423.61-433.68 −33.76 2-nitropropane 423.61-433.68 −35.36
1-butanol 423.61-433.68 −36.23 n-octane 423.61-433.68 −38.49
2-butanol 423.61-433.68 −26.99 1-octene 423.61-433.68 −37.04
2-butanone 423.61-433.68 −27.27 n-pentane 423.61-433.68 −16.92
chlorobenzene 423.61-433.68 −41.02 3-pentanone 423.61-433.68 −36.17
cyclohexane 423.61-433.68 −26.03 2-propanol 423.61-433.68 −17.65
1,2-dichloro- 423.61-433.68 −41.30 2-propanone 423.61-433.68 −25.48
ethane propionitrile 423.61-433.68 −30.06
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
dichloromethane 423.61-433.68 −22.64 propyl acetate 423.61-433.68 −35.46
diethyl ether 423.61-433.68 −34.21 tetrachloro- 423.61-433.68 −29.65
1,4-dioxane 423.61-433.68 −33.08 methane
dipropyl ether 423.61-433.68 −34.44 tetrahydrofuran 423.61-433.68 −29.94
ethanol 423.61-433.68 −21.32 trichloromethane 423.61-433.68 −29.83
ethyl acetate 423.61-433.68 −35.34 2,2,2-trifluoro- 423.61-433.68 −35.11
formic acid 423.61-433.68 −30.09 ethanol
furan 423.61-433.68 −21.97 water 423.61-433.68 −28.00
n-heptane 423.61-433.68 −31.79 m-xylene 423.61-433.68 −44.36
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and vinyl alcohol
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
71.0 wt% vinyl alcohol E-VAL/71w 96GAV
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-VAL/71w CERDATO, Elf Atochem, France
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-VAL/71w 96GAV
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
1-butanol 333.15-363.15 −71.18 methanol 333.15-363.15 −15.49
2-butanol 333.15-363.15 −19.26 1-propanol 333.15-363.15 −81.22
ethanol 333.15-363.15 −74.52 2-propanol 333.15-363.15 −67.41
2-methyl- 333.15-363.15 −17.58 2-methyl- 333.15-363.15 −25.12
1-propanol 2-propanol
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
58.0 wt% styrene S-BMA/58w 81DIP
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BMA/58w 32500 72500 Xerox Corp., Can.
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-BMA/58w 81DIP
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 393.15-423.15 −0.25 ethylbenzene 393.15-423.15 0.13
1-butanol 393.15-423.15 5.11 methylcyclohexane 393.15-423.15 3.22
butyl acetate 393.15-423.15 −0.46 tert-butyl-benzene 393.15-423.15 0.84
butylbenzene 393.15-423.15 0.25 n-octane 393.15-423.15 3.81
butylcyclohexane 393.15-423.15 3.85 2-pentanone 393.15-423.15 −1.17
chlorobenzene 393.15-423.15 −0.75 tetrachloromethane 393.15-423.15 0.08
1-chlorobutane 393.15-423.15 −1.38 trichloromethane 393.15-423.15 −3.94
cyclohexane 393.15-423.15 2.39 2,2,4-trimethyl- 393.15-423.15 5.73
cyclohexanol 393.15-423.15 5.74 pentane
n-decane 393.15-423.15 4.73 3,4,5-trimethyl- 393.15-423.15 5.31
dichloromethane 393.15-423.15 −2.22 heptane
n-dodecane 393.15-423.15 5.15
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and divinylbenzene
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/divinylbenzene copolymer
5 wt% divinylbenzene S-DVB/05w 87SAN, 89SAN
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-DVB/05w network, synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-DVB/05w 87SAN, 89SAN
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
1-butanol 445.-465. 22.0 − 5.7
ethanol 445.-465. 17.0 −16.0
methanol 445.-465. 11.9 −12.7
1-propanol 445.-465. 22.6 − 8.8
_____________________________________________________________________________
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
1-butanol 455.-480. 17.0 −16.0
methanol 455.-480. 10.3 −17.9
1-pentanol 455.-480. 16.0 −15.1
1-propanol 455.-480. 10.2 −16.9
_____________________________________________________________________________
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
1-butanol 460.-480. 25.9 −11.7
ethanol 460.-480. 13.8 −16.8
methanol 460.-480. 14.6 −13.4
1-pentanol 460.-480. 22.2 − 8.5
1-propanol 460.-480. 17.2 −11.9
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and ethyl acrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/ethyl acrylate copolymer
18.5 mol% ethyl acrylate S-EA/19x 92COS
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-EA/19x synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-EA/19x 92COS
_____________________________________________________________________________
solvent (A) T-range/ ∆solHA(vap)∞/
K kJ/mol
_____________________________________________________________________________
n-decane 373.15-423.15 −21.20
n-hexane 373.15-423.15 − 2.66
n-nonane 373.15-423.15 −21.28
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
K kJ/mol
_____________________________________________________________________________
n-decane 373.15-423.15 −23.82
n-hexane 373.15-423.15 − 6.47
n-nonane 373.15-423.15 −15.49
_____________________________________________________________________________
_____________________________________________________________________________
K kJ/mol
_____________________________________________________________________________
n-decane 373.15-423.15 −13.63
n-hexane 373.15-423.15 −14.21
n-nonane 373.15-423.15 −28.50
_____________________________________________________________________________
_____________________________________________________________________________
K kJ/mol
_____________________________________________________________________________
n-decane 373.15-423.15 −26.15
n-hexane 373.15-423.15 −19.05
n-nonane 373.15-423.15 −10.91
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and maleic anhydride
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/maleic anhydride/methacrylic acid terpolymer (1:1:1)
33 mol% styrene S-MAH-MA/33x 95BOG
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-MAH-MA/33x 28000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-MAH-MA/33x 95BOG
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
1-butanol 526.6-556.6 −23.0 −11.0
n-decane 526.6-556.6 −13.0 −18.0
dibutyl ether 526.6-556.6 −16.0 −15.0
1,4-dioxane 526.6-556.6 −13.0 −15.0
n-heptane 526.6-556.6 −16.0 −15.0
n-nonane 526.6-556.6 −15.0 −15.0
n-octane 526.6-556.6 −13.0 −17.0
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
42 mol% styrene S-MMA/42x 95NEM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-MMA/42x 57800 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-MMA/42x 95NEM
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
n-heptane 443.2-471.7 8.147 −19.147
n-hexane 443.2-471.7 10.096 −12.674
n-nonane 443.2-471.7 6.651 −25.529
n-octane 443.2-471.7 8.314 −28.720
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and 2-(3-methyl-3-phenylcyclobutyl)-
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/2-(3-methyl-3-phenylcyclobutyl)-
40.0 mol% styrene S-MPCHEMA/40x 2000KAY
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-MPCHEMA/40x ρB = 1.045 g/cm3,
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-MPCHEMA/40x 2000KAY
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 443.15-453.15 11.64 methyl acetate 443.15-453.15 21.65
2-butanone 443.15-453.15 23.28 n-nonane 443.15-453.15 19.97
n-decane 443.15-453.15 21.65 n-octane 443.15-453.15 21.65
n-dodecane 443.15-453.15 16.62 2-propanone 443.15-453.15 16.62
ethanol 443.15-453.15 41.62 toluene 443.15-453.15 43.25
ethyl acetate 443.15-453.15 29.94 n-undecane 443.15-453.15 4.98
methanol 443.15-453.15 21.65 o-xylene 443.15-453.15 9.96
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from styrene and nonyl methacrylate
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
Styrene/nonyl methacrylate copolymer
80 mol% styrene S-NMA/80x 95BOG
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-NMA/80x 29000 synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): S-NMA/80x 95BOG
_____________________________________________________________________________
K kJ/mol kJ/mol
_____________________________________________________________________________
1-butanol 358.15-383.15 − 5.0 −38.0
n-decane 358.15-383.15 − 4.0 −41.0
dibutyl ether 358.15-383.15 8.0 −46.0
1,4-dioxane 358.15-383.15 0.0 −34.0
n-heptane 358.15-383.15 −14.0 −16.0
n-nonane 358.15-383.15 0.0 −40.0
n-octane 358.15-383.15 − 9.0 −25.0
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from tetrafluoroethylene and
2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
13 mol% tetrafluoroethylene TFE-PFD/13x 99BON
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
TFE-PFD/13x AF2400, DuPont, Wilmington
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): TFE-PFD/13x 99BON
_____________________________________________________________________________
K kJ/mol K kJ/mol
_____________________________________________________________________________
benzene 423.15 −29.98 n-hexane 423.15 −31.74
n-butane 423.15 −21.14 2-methylpropane 423.15 −24.95
n-heptane 423.15 −36.34 octafluorotoluene 423.15 −44.38
hexafluorobenzene 423.15 −37.68 n-pentane 423.15 −27.13
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
20 wt% vinyl chloride VC-VdC/20w 92KAL
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
VC-VdC/20w 90000 Polysciences Inc.
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): VC-VdC/20w 92KAL
_____________________________________________________________________________
K kJ/mol
_____________________________________________________________________________
water 298.15-323.15 −42.70
_____________________________________________________________________________
____________________________________________________________________________________
5.3. Table of systems where additional information on enthalpy

effects in copolymer solutions can be found
_____________________________________________________________________________
Copolymer (B) Solvent (A) Enthalpy T-range Ref.
_____________________________________________________________________________
_____________________________________________________________________________
Acrylic acid/methyl methacrylate
copolymer
_____________________________________________________________________________
2-butanone ∆MHA 311 K 69POD
benzene ∆MHA∞ 298 K 55TA1
benzene ∆MH 298 K 55TA1
cyclohexane ∆MHA 311 K 69POD
hydrogen ∆solHA(vap)∞ 293-343 K 39BAR
nitrogen ∆solHA(vap)∞ 293-343 K 39BAR
_____________________________________________________________________________
carbon dioxide ∆solHA(vap)∞ 50AME
helium ∆solHA(vap)∞ 50AME
hydrogen ∆solHA(vap)∞ 50AME
nitrogen ∆solHA(vap)∞ 50AME
oxygen ∆solHA(vap)∞ 50AME
_____________________________________________________________________________
Acrylonitrile/2-methylfuran copolymer
N,N-dimethyl- ∆solHB∞ 64USM
formamide
_____________________________________________________________________________
acrylonitrile ∆solHB∞ 298 K 89EGO
N,N-dimethyl- ∆solHB∞ 298 K 91ZVE
formamide
styrene ∆solHB∞ 298 K 89EGO
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
formamide
_____________________________________________________________________________
formamide
_____________________________________________________________________________
Butadiene/methyl methacrylate copolymer
argon ∆solHA(vap)∞ 293-343 K 39BAR
oxygen ∆solHA(vap)∞ 293-343 K 39BAR
_____________________________________________________________________________
argon ∆solHA(vap)∞ 293-343 K 39BAR
argon ∆solHA(vap)∞ 298 K 60TIK
benzene ∆MHA 293 K 55TA2
_____________________________________________________________________________
_____________________________________________________________________________
Ethyl acrylate/tetraethylene glycol
dimethacrylate copolymer
argon ∆solHA(vap)∞ 333 K 68BAR
carbon dioxide ∆solHA(vap)∞ 333 K 68BAR
hydrogen ∆solHA(vap)∞ 333 K 68BAR
krypton ∆solHA(vap)∞ 333 K 68BAR
methane ∆solHA(vap)∞ 333 K 68BAR
neon ∆solHA(vap)∞ 333 K 68BAR
nitrogen ∆solHA(vap)∞ 333 K 68BAR
oxygen ∆solHA(vap)∞ 333 K 68BAR
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
benzene ∆solHA(vap)∞ 283-313 K 64FRE
benzene ∆MHA 298-373 K 64HOL
chlorobenzene ∆MHA 298-373 K 64HOL
cyclohexane ∆solHA(vap)∞ 283-313 K 64FRE
cyclohexane ∆MHA 298-373 K 64HOL
dichloromethane ∆solHA(vap)∞ 283-313 K 64FRE
n-heptane ∆MHA 298-373 K 64HOL
n-hexane ∆solHA(vap)∞ 283-313 K 64FRE
n-pentane ∆solHA(vap)∞ 283-313 K 64FRE
tetrachloro- ∆solHA(vap)∞ 283-313 K 64FRE
methane
tetrachloro- ∆MHA 298-373 K 64HOL
methane
1,1,2-trichloro- ∆solHA(vap)∞ 283-313 K 64FRE
trifluoroethane
_____________________________________________________________________________
n-dodecane ∆MH 383-433 K 81DRU
n-octadecane ∆MH 383-433 K 81DRU
_____________________________________________________________________________
9,9-bis(4-Hydroxyphenyl)fluorene/
terephthaloyl chloride copolymer
1,1,2,2-tetra- ∆MH 298K 77TA2
chloroethane
trichloro- ∆MH 298K 77TA2
methane
_____________________________________________________________________________
Isobutylene/maleic acid copolymer
_____________________________________________________________________________
N-Isopropylacrylamide/N-octadecyl-
water ∆dilH12 303 K 96FAE
_____________________________________________________________________________
N-Methacryloyl-L-alanine/N-phenyl-
methacrylamide copolymer
_____________________________________________________________________________
4-Methyl-1-pentene/maleic acid copolymer
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Phenolphthalein/terephthaloyl chloride
copolymer
1,1,2,2-tetra- ∆MH 298K 77TA2
chloroethane
trichloro- ∆MH 298K 77TA1
methane
_____________________________________________________________________________
Polyisoprene-b-polystyrene diblock
copolymer
cyclohexane ∆MHA 293-333 K 72GIR
4-methyl- ∆MHA 293-333 K 72GIR
2-pentanone
toluene ∆MHA 293-333 K 72GIR
_____________________________________________________________________________
Propylene/maleic acid copolymer
_____________________________________________________________________________
trichloro- ∆solHB∞ 303-323 K 93FRE
methane
trichloro- ∆solHB∞ 303-323 K 94FRE
methane
_____________________________________________________________________________
Trimethyl-1-pentene/maleic acid copolymer
_____________________________________________________________________________
Vinyl acetate/1-vinyl-2-pyrrolidinone
copolymer
vinyl acetate ∆solHB∞ 298 K 89EGO
1-vinyl-2-pyr- ∆solHB∞ 298 K 89EGO
rolidinone
_____________________________________________________________________________
Vinyl amine/vinyl caprolactam copolymer
_____________________________________________________________________________
5-Vinyltetrazole/2-methyl-5-vinyltetrazole
copolymer
N,N-dimethyl- ∆solHB∞ 298 K 95KIZ
formamide
water ∆solHB∞, ∆dilH12 298 K 97KIZ
water ∆MH 298 K 97KIZ
_____________________________________________________________________________
____________________________________________________________________________________
5.4. References
39BAR Barrer, R.M., Permeation, diffusion and solution of gases in organic polymers, Trans.
Faraday Soc., 35, 628, 1939.
50AME Amerongen, G.J. van, Influence of structure of elastomers on their permeability to gases, J.
Polym. Sci., 5, 307, 1950.
50TAG Tager, A. and Sanatina, V., Heats of solution and swelling of some synthetic high-molecular
compounds (Russ.), Kolloidn. Zh., 12, 474, 1950.
51TAG Tager, A. and Sanatina, V., Heats of solution and swelling of some synthetic high-molecular
compounds, Rubber Chem. Technol., 24, 773, 1951.
55OYA Oya, S., Heat of solution of synthetic high polymers. III. Heat of solution of partially
acetylated poly(vinyl alcohol), Chem. High Polym. Japan, 12, 122, 1955.
55TA1 Tager, A.A. and Kosova, L.K., Thermodynamic studies of copolymer solutions 2.
Thermodynamic study of butadiene-acrylonitrile copolymer solutions (Russ.), Kolloidn. Zh.,
17, 391, 1955.
55TA2 Tager, A.A., Kosova, L.K., Karlinskaya, D.Yu., and Yurina, I.A., Thermodynamic studies
of copolymer solutions 1. Thermodynamic study of butadiene-styrene copolymer solutions
(Russ.), Kolloidn. Zh., 17, 315, 1955.
55ZAZ Zazulina, Z.A. and Rogovin, Z.A., Studies on properties of synthetic carbochain fibres. 2.
Mechanism of the thermorelaxation behavior of carbochain fibres (Russ.), Kolloidn. Zh.,
17, 343, 1955.
56AMA Amaya, K. and Fujishiro, R., Heats of dilution of polyvinylalcohol solutions II, Bull. Chem.
Soc. Japan, 29, 830, 1956.
56LIP Lipatov, Yu.S., Kargin, V.A., and Slonimskii, G.L., Study on orientation in high polymers
II. Crystalline polymers (Russ.), Zh. Fiz. Khim., 30, 1207, 1956.
56STR Struminskii, G.V. and Slonimskii, G.L., Mutual solubility of polymers III. Heats of mixing
(Russ.), Zh. Fiz. Khim., 30, 1941, 1956.
58SLO Slonimskii, G.L., Mutual solubility of polymers and properties of their mixtures, J. Polym.
Sci., 30, 625, 1958.
58TA1 Tager, A.A. and Iovleva, M., Thermodynamic studies of copolymer solutions III.
Saponified poly(vinyl acetate)s (Russ.), Zh. Fiz. Khim., 32, 1774, 1958.
58TA2 Tager, A.A. and Kargin, V.A., Thermodynamic studies of polymer-hydrogenated monomer
systems II. Enthalpies of solution of copolymers in mixtures of hydrogenated monomers
(Russ.), Zh. Fiz. Khim., 32, 1362, 1958.
59ZEL Zelikman, S.G. and Mikhailov, N.V., Studies on the structure and properties of carbochain
polymers in dilute solutions. IV. The integral and differential heats of solution and densities
of the polymers (Russ.), Vysokomol. Soedin., 1, 1077, 1959.
60TIK Tikhomirova, N.S., Malinksii, Yu.M., and Karpov, V.L., Studies on diffusion processes in
polymers. I. Diffusion of monoatomic gases through polymer films of different structures
(Russ.), Vysokomol. Soedin., 2, 221, 1960.
64FRE Frensdorff, H.K., Diffusion and sorption of vapors in ethylene-propylene copolymers. I.
Equilibrium sorption, J. Polym. Sci., Pt. A, 2, 333, 1964.
64HOL Holly, E.D., Interaction parameters and heats of dilution for ethylene-propylene rubber in
various solvents, J. Polym. Sci., Pt. A, 2, 5267, 1964.
64USM Usmanov, Kh.U., Tillaev, R.S., and Musaev, Y.N., Radiation copolymerization of acrylo-
nitrile with sylvane (Russ.), Nauchn. Tr. Tashkent. Gos. Univ., 257, 3, 1964.
68BAR Barrer, R.M., Barrie, J.A., and Wong, P.S.-L., The diffusion and solution of gases in highly
crosslinked copolymers, Polymer, 9, 609, 1968.
____________________________________________________________________________________
69POD Poddubnyi, I.Ya. and Podalinskii, A.V., Possible production of thermodynamically ideal
polymer-solvent systems (Russ.), Dokl. Akad. Nauk SSSR, 185, 401, 1969.
70GIA Giacommeti, G., Turolla, A., and Boni, R., Enthalpy of helix-coil transitions from heats of
solution. II. Poly-eps-carbobenzoxy-L-lysine and copolymers with L-phenylalanine,
Biopolymers, 9, 979, 1970.
72GIR Girolamo, M. and Urwin, J.R., Thermodynamic parameters from osmotic studies on
solutions of block copolymers of polyisoprene and polystyrene, Eur. Polym. J., 8, 299,
1972.
76PET Petrosyan, V.A., Gabrielyan, G.A., and Rogovin, Z.A., Investigation of some properties of
fiber-forming copolymers of acrylonitrile and isoprene, Arm. Khim. Zh., 29, 516, 1976.
77TA1 Tager, A.A., Kolmakova, L.K., Bessonov, Yu.S., Salazkin, S.N., and Trofimova, N.M.,
Effect of the molecular mass and porous structure of cardo polyarylate on the thermody-
namic parameters of dissolution (Russ.), Vysokomol. Soedin., Ser. A, 19, 1475, 1977.
77TA2 Tager, A.A., Kolmakova, L.K., Anufriev, V.A., Bessonov, Yu.S., Zhigunova, O.A.,
Vinogradova, S.V., Salazkin, S.N., and Tsilipotkina, M.V., Thermodynamics of the
dissolution of cardo polyarylates in chloroform and tetrachloroethane (Russ.), Vysokomol.
Soedin., Ser. A, 19, 2367, 1977.
78DIN Dincer, S. and Bonner, D.C., Thermodynamic analysis of ethylene and vinyl acetate
78DIP Dipaola-Baranyi, G., Braun, J.-M., and Guillet, J.E., Partial molar heats of mixing of small
molecules with polymers by gas chromatography, Macromolecules, 11, 224, 1978.
78SOK Sokolova, D.F., Kudim, T.V., Sokolov, L.B., Zhegalova, N.I., and Zhuravlev, N.D.,
Thermochemical evaluation of the orderliness of copolymer polyarylates (Russ.),
79ITO Ito, K. and Guillet, J.E., Estimation of solubility parameters for some olefin polymers and
copolymers by inverse gas chromatography, Macromolecules, 12, 1163, 1979.
79PH1 Phuong-Nguyen, H. and Delmas, G., Heats of mixing at infinite dilution of atactic polymers.
1. Effect of correlations of orientations in the solvents or in the polymers, Macromolecules,
12, 740, 1979.
79PH2 Phuong-Nguyen, H. and Delmas, G., Heats of mixing at infinite dilution of atactic polymers.
2. Effect of steric hindrance and of the shape of the solvent, Macromolecules, 12, 746,
1979.
80DIP DiPaola-Baranyi, G., Guillet, J.E., Jeberien, H.-E., and Klein, J., Thermodynamics of
hydrogen bonding polymer-solute interactions by inverse gas chromatography, Makromol.
Chem., 181, 215, 1980.
81DIP DiPaola-Baranyi, G., Thermodynamic miscibility of various solutes with styrene-butyl
methacrylate polymers and copolymers, Macromolecules, 14, 683, 1981.
81DRU Druz, N.I., Kreitus, A., and Chalykh, A.E., Thermodynamic parameters of mixing in the
systems ethylene-vinyl acetate copolymers - hydrocarbons (Russ.), Latv. PSR Zinat. Akad.
Vestis. Kim. Ser., (3), 199, 1981.
81PAO Paoletti, S., Delben, F., and Crescenzi, V., Enthalpies of dilution of partially neutralized
maleic acid copolymers in water. Correlation of experiments with theories, J. Phys. Chem.,
85, 1413, 1981.
82MOR Morcellet, M., Loucheux, C., and Daoust, H., Poly(methacrylic acid) derivatives 5.
Microcalorimetric study of poly(N-methacryloyl-L-alanine) and poly(N-methacryloyl-L-
alanine-co-N-phenylmethacrylamide) in aqueous solutions, Macromolecules, 15, 890, 1982.
84SIO Siow, K.S., Goh, S.H., and Yap, K.S., Solubility parameters of poly(α-methylstyrene-co-
acrylnitrile) from gas-liquid chromatography, Polym. Mater. Sci. Eng., 51, 532, 1984.
85COR Cordt, F., Die Energetik der Wechselwirkungen von Oligomeren des Ethylenoxids und
dessen Copolymeren mit Propylenoxid in CCl4-Lösung, PhD-Thesis, TU München, 1985.
____________________________________________________________________________________
86SIO Siow, K.S., Goh, S.H., and Yap, K.S., Solubility parameters of poly(α-methylstyrene-co-
acrylonitrile) from gas-liquid chromatography, J. Chromatogr., 354, 75, 1986.
87KYO Kyohmen, M., Inoue, K., Baba, Y., Kagemoto, A., and Beatty, Ch.L., Heats of dilution of
poly[styrene-ran-(butyl methacrylate)] solutions measured with an automatic flow
microcalorimeter, Makromol. Chem., 188, 2721, 1987.
87SAN Sanetra, R., Kolarz, B., and Wlochowicz, A., Determination of thermodynamic data for the
interaction of aliphatic alcohols with poly(styrene-co-divinylbenzene) using inverse gas
chromatography, Polymer, 28, 1753, 1987.
89EGO Egorochkin, G.A., Semchikov, Yu.D., Smirnova, L.A., Knyazeva, T.E., Tokhonova, Z.A.,
Karyakin, N.V., and Sveshnikova, T.G., Thermodynamic analysis of the copolymerization
of styrene with acrylonitrile and N-vinylpyrrolidone with vinyl acetate (Russ.), Vysokomol.
Soedin., Ser. B, 31, 46, 1989.
89MOE Moeller, F., Energetik der Wechselwirkungen von Oligomeren des Ethylen- und Propylen-
oxids und deren Cooligomeren in Mischung mit CCl4, PhD-Thesis, TU München, 1989.
89SAN Sanetra, R., Kolarz, B.N., and Wlochowicz, A., Badanie metoda inwesyjnej chromatografii
gazowej struktury usieciowanych kopolimerow na przykladzie kopolimerow styren/
diwinylobenzen, Polimery, 34, 490, 1989.
90KIL Killmann, E., Cordt, F., and Moeller, F., Thermodynamics of mixing ethylene oxide
oligomers with different end groups in tetrachloromethane, Makromol. Chem., 191, 2929,
1990.
90SHI Shiomi, T., Ishimatsu, H., Eguchi, T., and Imai, K., Application of equation-of-state theory
to random copolymer systems. 1, Macromolecules, 23, 4970, 1990.
91ZVE Zverev, M.P., Zenkov, I.D., Zakharova, N.N., Zashchenkina, E.S., and Bondarenko, O.A.,
Properties of polyacrylonitrile and its fibers containing chemically active groups (Russ.),
Khim. Volokna, (5), 32, 1991.
92COS Coskun, M., Oezdemir, E., Benzen, R., and Pulat, E., Stiren-etilakrilat kopolimerlerinin
termodinamik oezellikerinin invers gaz kromatografisi ile incelenmesi, Doga - Turk Kimya
Dergisi, 16, 76, 1992.
92KAL Kalaouzis, P.J. and Demertzis, P.G., Water sorption and water vapour diffusion in food-
grade plastics packaging materials: Effect of a polymeric plasticizer, Packag. Technol. Sci.,
5, 133, 1992.
92ROM Romdhane, I.H., Plana, A., Hwang, S., and Danner, R.P., Thermodynamic interactions of
solvents with styrene-butadiene-styrene triblock copolymers, J. Appl. Polym. Sci., 45, 2049,
1992.
93ADA Adamova, L.V., Klyuzhin, E.S., Safronov, A.P., Nerush, N.T., and Tager, A.A.,
Thermodynamics of interactions between water and copolymers of acrylate and acrylic acid
(Russ.), Vysokomol. Soedin., Ser. B, 35, 893, 1993.
93FRE Frezzotti, D. and Ravanetti, G.P., Evaluation of the Flory-Huggins interaction parameter for
poly(styrene-co-acrylonitrile) and poly(methyl methacrylate) blend from enthalpy of mixing
measurements, J. Calorim. Anal. Therm., 24, 135, 1993.
93ISS Issel, H.-M., Thermodynamische und rheologische Steuerung der Materialeigenschaften von
Elastomeren durch trans-Poly(octenylen), PhD-Thesis, Univ. Hannover, 1993.
93TAG Tager, A.A., Klyuzhin, E.S., Adamova, L.V., and Safronov, A.P., Thermodynamics of
Ser. B, 35, 1357, 1993.
94COS Coskun, M., Oezdemir, E., Celik, S., and Cansiz, A., Inverse gas chromatography of n-
alcohols - poly(acrylonitrile-co-methyl acrylate) systems, J. Macromol. Sci., Macromol.
Rep. A, (Suppl.1&2), 31, 63, 1994.
____________________________________________________________________________________
94FRE Frezzotti, D. and Ravanetti, G.P., Evaluation of the Flory-Huggins interaction parameter for
poly(styrene-co-acrylonitrile) and poly(methyl methacrylate) blend from enthalpy of mixing
measurements, J. Therm. Anal., 41, 1237, 1994.
272, 1234, 1994.
95BOG Bogillo, V.I. and Voelkel, A., Solution properties of amorphous co- and terpolymers of
styrene as examined by inverse gas chromatography, J. Chromatogr. A, 715, 127, 1995.
95KIL Killmann, E., Cordt, F., Moeller, F., and Zellner, H., Thermodynamics of mixing propylene
oxide oligomers with different end groups of statistical and block cooligomers of ethylene
oxide and propylene oxide in tetrachloromethane, Macromol. Chem. Phys., 196, 47, 1995.
95KIZ Kizhnyaev, V.N., Gorkovenko, O.P., Bazhenov, D.N., and Smirnov, A.I., Interrelation
between hydrodynamic and thermodynamic characteristics of solutions of poly(vinyl
tetrazoles) in mixed solvents (Russ.), Vysokomol. Soedin., Ser. B, 37, 1948, 1995.
95NEM Nemtoi, G. and Beldie, C., Thermodynamic characterization of some copolymers by gas-
chromatographic measurements, Rev. Roum. Chim., 40, 335, 1995.
96FAE Faes, H., De Schryver, F.C., Sein, A., Bijma, K., Kevelam, J., and Engberts, J.B.F., Study
of self-associating amphiphilic copolymers and their interaction with surfactants,
96GAV Gavara, R., Catala, R., Aucejo, S., Cabedo, D., and Hernandez, R., Solubility of alcohols in
ethylene-vinyl alcohol copolymers by inverse gas chromatography, J. Polym. Sci., Part B:
Polym. Phys., 34, 1907, 1966.
96SAT Sato, T., Tohyama, M., Suzuki, M., Shiomi, T., and Imai, K., Application of equation-of-
state theory to random copolymer blends with upper critical solution temperature type
miscibility, Macromolecules, 29, 8231, 1996.
96SHI Shiomi, T., Tohyama, M., Endo, M., Sato, T., and Imai, K., Dependence of Flory-Huggins
χ-parameters on the copolymer composition for solutions of poly(methyl methacrylate-ran-
n-butyl methacrylate) in cyclohexanone, J. Polym. Sci., Part B: Polym. Phys., 34, 2599,
1996.
97KIZ Kizhnyaev, V.N., Gorkovenko, O.P., Safronov, A.P., and Adamova, L.V., Thermodynamics
of the interaction between tetrazole-containing polyelectrolytes and water (Russ.),
97SAT Sato, T., Suzuki, M., Tohyama, M., Endo, M., Shiomi, T., and Imai, K., Behavior of
temperature dependence of χ-parameter in random copolymer blends showing an
immiscibility window, Polym. J., 29, 417, 1997.
97SCH Schuster, R.H., Issel, H.M., and Peterseim, V., Charakterisierung der Kautschuk-
Lösungsmittel Wechselwirkung mittels inverser Gaschromatographie, Kautschuk Gummi
Kunststoffe, 50, 890, 1997.
98KIM Kim, N.H., Won, Y.S., and Choi, J.S., Partial molar heat of mixing at infinite dilution in
solvent/polymer (PEG, PMMA, EVA) solutions, Fluid Phase Equil., 146, 223, 1998.
98YAM Yampolskii, Yu.P. and Bondarenko, G.N., Evidence of hydrogen bonding during sorption
of chloromethanes in copolymers of chloroprene with methyl methacrylate and methacrylic
acid, Polymer, 39, 2241, 1998.
amorphous glassy perfluorodioxol copolymer, Macromolecules, 32, 6163, 1999.
2000KAY Kaya, I. and Demirelli, K., Determination of thermodynamic properties of poly[2-(3-
methyl-3-phenyl-cyclobutyl)-2-hydroxyethylmethacrylate] and its copolymers at infinite
dilution using inverse gas chromatography, Polymer, 41, 2855, 2000.
6. PVT DATA OF MOLTEN COPOLYMERS
6.1. Experimental data and/or Tait equation parameters
_____________________________________________________________________________
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms, range of data, and references:
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
2.7 wt% acrylonitrile S-AN/03w 438-539 0.1-200 92KIM
25.0 wt% acrylonitrile S-AN/25w 433-573 0.1-200 95ZOL
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-AN/03w 93500 211000 Asahi Chemical
S-AN/06w 270000 Asahi Chemical
S-AN/18w 197000 Asahi Chemical
S-AN/25w 81900 506000 Polysciences Inc.
S-AN/70w Monsanto Co.
_____________________________________________________________________________
____________________________________________________________________________________
Experimental PVT data:

_____________________________________________________________________________
copolymer (B): S-AN/03w 92KIM
_____________________________________________________________________________
P/MPa T/K
438.25 450.65 456.65 469.75 494.45 505.85 516.55 529.55 539.25
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.0042 1.0105 1.0154 1.0218 1.0379 1.0465 1.0519 1.0620 1.0716
10 0.9963 1.0024 1.0068 1.0131 1.0279 1.0353 1.0406 1.0496 1.0585
20 0.9883 0.9945 0.9977 1.0045 1.0176 1.0237 1.0293 1.0370 1.0448
30 0.9820 0.9881 0.9913 0.9975 1.0102 1.0156 1.0211 1.0284 1.0359
40 0.9762 0.9820 0.9853 0.9914 1.0033 1.0085 1.0135 1.0204 1.0279
50 0.9710 0.9765 0.9797 0.9854 0.9970 1.0018 1.0070 1.0132 1.0204
60 0.9660 0.9713 0.9744 0.9800 0.9911 0.9958 1.0004 1.0067 1.0133
70 0.9611 0.9663 0.9695 0.9747 0.9855 0.9900 0.9947 1.0005 1.0071
80 0.9566 0.9616 0.9647 0.9698 0.9803 0.9846 0.9890 0.9948 1.0008
90 0.9524 0.9573 0.9603 0.9651 0.9753 0.9796 0.9839 0.9890 0.9953
100 0.9483 0.9533 0.9559 0.9608 0.9706 0.9750 0.9789 0.9840 0.9899
110 0.9446 0.9493 0.9520 0.9568 0.9662 0.9701 0.9741 0.9790 0.9849
120 0.9408 0.9455 0.9481 0.9527 0.9619 0.9658 0.9696 0.9746 0.9803
130 0.9444 0.9489 0.9578 0.9617 0.9654 0.9703 0.9755
140 0.9409 0.9452 0.9538 0.9577 0.9610 0.9656 0.9709
150 0.9373 0.9417 0.9501 0.9537 0.9571 0.9616 0.9666
160 0.9339 0.9380 0.9462 0.9497 0.9532 0.9574 0.9625
170 0.9306 0.9347 0.9425 0.9461 0.9495 0.9536 0.9585
180 0.9274 0.9314 0.9389 0.9425 0.9457 0.9498 0.9545
190 0.9241 0.9281 0.9356 0.9389 0.9418 0.9458 0.9506
200 0.9209 0.9248 0.9321 0.9354 0.9383 0.9421 0.9466
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
436.75 449.85 463.15 475.75 495.65 506.45 517.25 527.55 540.35
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.0086 1.0169 1.0259 1.0336 1.0467 1.0535 1.0619 1.0701 1.0809
10 1.0009 1.0088 1.0171 1.0244 1.0364 1.0428 1.0507 1.0583 1.0678
20 0.9934 1.0009 1.0084 1.0153 1.0264 1.0325 1.0399 1.0467 1.0546
30 0.9871 0.9945 1.0015 1.0082 1.0186 1.0243 1.0315 1.0382 1.0455
40 0.9812 0.9884 0.9951 1.0019 1.0111 1.0170 1.0238 1.0302 1.0370
50 0.9758 0.9829 0.9891 0.9956 1.0046 1.0100 1.0168 1.0229 1.0292
_____________________________________________________________________________
continue
6. PVT Data 343
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
436.75 449.85 463.15 475.75 495.65 506.45 517.25 527.55 540.35
3 −1
Vspez/cm g
_____________________________________________________________________________
60 0.9707 0.9777 0.9838 0.9895 0.9982 1.0037 1.0101 1.0158 1.0218
70 0.9660 0.9722 0.9782 0.9842 0.9925 0.9977 1.0040 1.0093 1.0150
80 0.9616 0.9676 0.9735 0.9791 0.9872 0.9922 0.9983 1.0036 1.0088
90 0.9573 0.9634 0.9690 0.9745 0.9821 0.9872 0.9928 0.9980 1.0034
100 0.9532 0.9591 0.9646 0.9701 0.9776 0.9820 0.9879 0.9927 0.9977
110 0.9492 0.9552 0.9605 0.9659 0.9728 0.9775 0.9831 0.9877 0.9926
120 0.9456 0.9514 0.9566 0.9616 0.9684 0.9730 0.9785 0.9831 0.9878
130 0.9474 0.9526 0.9576 0.9641 0.9686 0.9741 0.9786 0.9826
140 0.9439 0.9487 0.9538 0.9602 0.9644 0.9700 0.9740 0.9781
150 0.9403 0.9448 0.9499 0.9562 0.9606 0.9656 0.9696 0.9738
160 0.9370 0.9411 0.9462 0.9523 0.9565 0.9613 0.9653 0.9694
170 0.9376 0.9428 0.9486 0.9528 0.9573 0.9613 0.9651
180 0.9342 0.9393 0.9450 0.9489 0.9534 0.9572 0.9613
190 0.9307 0.9358 0.9412 0.9453 0.9494 0.9533 0.9569
200 0.9271 0.9324 0.9377 0.9416 0.9458 0.9494 0.9534
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
423.25 436.55 450.05 463.05 475.95 488.55 501.55 515.05 528.05
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 0.9714 0.9788 0.9862 0.9936 1.0006 1.0080 1.0155 1.0240 1.0317
10 0.9650 0.9721 0.9791 0.9861 0.9928 0.9997 1.0067 1.0145 1.0217
20 0.9586 0.9654 0.9720 0.9786 0.9850 0.9916 0.9979 1.0049 1.0119
30 0.9533 0.9598 0.9662 0.9725 0.9786 0.9848 0.9910 0.9976 1.0041
40 0.9483 0.9547 0.9608 0.9667 0.9727 0.9786 0.9845 0.9908 0.9970
50 0.9436 0.9498 0.9557 0.9615 0.9673 0.9727 0.9784 0.9844 0.9905
60 0.9393 0.9452 0.9510 0.9565 0.9620 0.9676 0.9728 0.9789 0.9842
70 0.9349 0.9407 0.9463 0.9516 0.9569 0.9623 0.9675 0.9731 0.9783
80 0.9366 0.9421 0.9470 0.9522 0.9575 0.9624 0.9678 0.9729
90 0.9327 0.9382 0.9429 0.9479 0.9529 0.9577 0.9629 0.9680
100 0.9290 0.9340 0.9389 0.9437 0.9487 0.9534 0.9582 0.9631
110 0.9254 0.9301 0.9349 0.9397 0.9444 0.9492 0.9538 0.9586
120 0.9218 0.9265 0.9314 0.9358 0.9404 0.9453 0.9498 0.9542
130 0.9232 0.9279 0.9320 0.9364 0.9412 0.9454 0.9499
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
423.25 436.55 450.05 463.05 475.95 488.55 501.55 515.05 528.05
Vspez/cm3g−1
_____________________________________________________________________________
140 0.9197 0.9244 0.9286 0.9325 0.9373 0.9414 0.9458
150 0.9164 0.9207 0.9248 0.9292 0.9333 0.9377 0.9420
160 0.9132 0.9174 0.9215 0.9254 0.9298 0.9339 0.9378
170 0.9140 0.9181 0.9220 0.9260 0.9300 0.9341
180 0.9108 0.9146 0.9185 0.9228 0.9266 0.9301
190 0.9077 0.9113 0.9153 0.9191 0.9230 0.9265
200 0.9047 0.9082 0.9117 0.9159 0.9193 0.9229
_____________________________________________________________________________
copolymer (B): S-AN/25w 95ZOL
_____________________________________________________________________________
P/MPa T/K
433.05 442.95 452.75 462.55 472.75 482.25 493.65 503.85 514.45
Vspez/cm3g−1
_____________________________________________________________________________
0.1 0.9856 0.9912 0.9968 1.0026 1.0085 1.0142 1.0213 1.0274 1.0343
20 0.9742 0.9795 0.9847 0.9898 0.9953 1.0004 1.0065 1.0121 1.0181
40 0.9643 0.9694 0.9741 0.9789 0.9839 0.9887 0.9942 0.9992 1.0047
60 0.9556 0.9603 0.9648 0.9692 0.9737 0.9784 0.9835 0.9882 0.9929
80 0.9479 0.9525 0.9566 0.9607 0.9650 0.9693 0.9741 0.9784 0.9829
100 0.9406 0.9451 0.9489 0.9528 0.9569 0.9610 0.9655 0.9697 0.9738
120 0.9339 0.9382 0.9419 0.9457 0.9495 0.9535 0.9577 0.9616 0.9655
140 0.9278 0.9319 0.9354 0.9390 0.9428 0.9464 0.9506 0.9543 0.9579
160 0.9220 0.9259 0.9293 0.9328 0.9364 0.9400 0.9438 0.9474 0.9509
180 0.9166 0.9204 0.9235 0.9269 0.9303 0.9338 0.9375 0.9409 0.9443
200 0.9115 0.9151 0.9181 0.9214 0.9246 0.9280 0.9316 0.9348 0.9382
_____________________________________________________________________________
continue S-AN/25w
_____________________________________________________________________________
P/MPa T/K
524.05 533.15 543.95 553.05 563.25 573.75
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.0403 1.0455 1.0522 1.0578 1.0642 1.0711
20 1.0231 1.0280 1.0337 1.0385 1.0442 1.0501
_____________________________________________________________________________
continue
6. PVT Data 345
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
524.05 533.15 543.95 553.05 563.25 573.75
Vspez/cm3g−1
_____________________________________________________________________________
40 1.0092 1.0136 1.0187 1.0230 1.0281 1.0333
60 0.9971 1.0012 1.0060 1.0100 1.0146 1.0199
80 0.9868 0.9905 0.9949 0.9986 1.0030 1.0074
100 0.9774 0.9810 0.9850 0.9885 0.9927 0.9967
120 0.9689 0.9723 0.9761 0.9795 0.9832 0.9871
140 0.9613 0.9644 0.9680 0.9712 0.9747 0.9785
160 0.9540 0.9571 0.9605 0.9635 0.9669 0.9703
180 0.9472 0.9503 0.9536 0.9562 0.9595 0.9627
200 0.9410 0.9437 0.9468 0.9497 0.9526 0.9558
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
423.25 440.65 455.65 475.45 492.95 509.85 522.75 535.55 544.35
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 0.9488 0.9578 0.9683 0.9755 0.9866 0.9954 1.0020 1.0098 1.0168
10 0.9431 0.9517 0.9612 0.9684 0.9783 0.9867 0.9931 1.0003 1.0062
20 0.9375 0.9455 0.9538 0.9614 0.9695 0.9777 0.9843 0.9909 0.9952
30 0.9328 0.9406 0.9483 0.9558 0.9635 0.9713 0.9774 0.9838 0.9877
40 0.9283 0.9359 0.9434 0.9504 0.9579 0.9654 0.9713 0.9772 0.9810
50 0.9241 0.9314 0.9386 0.9458 0.9527 0.9600 0.9656 0.9712 0.9748
60 0.9200 0.9271 0.9339 0.9409 0.9474 0.9545 0.9600 0.9653 0.9687
70 0.9161 0.9232 0.9298 0.9366 0.9428 0.9496 0.9546 0.9599 0.9632
80 0.9193 0.9261 0.9321 0.9384 0.9448 0.9499 0.9549 0.9580
90 0.9158 0.9221 0.9280 0.9342 0.9405 0.9453 0.9502 0.9532
100 0.9122 0.9183 0.9244 0.9304 0.9364 0.9410 0.9458 0.9487
110 0.9089 0.9147 0.9209 0.9265 0.9326 0.9370 0.9417 0.9446
120 0.9057 0.9114 0.9174 0.9229 0.9287 0.9331 0.9377 0.9406
130 0.9080 0.9139 0.9193 0.9250 0.9292 0.9335 0.9365
140 0.9048 0.9106 0.9159 0.9216 0.9257 0.9297 0.9325
150 0.9018 0.9075 0.9124 0.9180 0.9218 0.9261 0.9284
160 0.8987 0.9041 0.9091 0.9144 0.9185 0.9225 0.9249
170 0.9011 0.9060 0.9111 0.9152 0.9190 0.9214
180 0.8981 0.9027 0.9076 0.9116 0.9152 0.9177
190 0.8949 0.8996 0.9042 0.9080 0.9117 0.9140
200 0.8917 0.8963 0.9011 0.9045 0.9083 0.9105
_____________________________________________________________________________
____________________________________________________________________________________
Tait equation parameter functions:
_____________________________________________________________________________
Copolymer V(P/MPa, T/K) = V(0, T/K){1 − C*ln[1 + (P/MPa)/B(T/K)]}
with C = 0.0894 and θ = T/K − 273.15
_____________________________________________________________________________
V(0,T/K)/cm3 g−1 B(T/K)/MPa
_____________________________________________________________________________
S-AN/03w 0.9233 + 3.9355 10−4θ + 5.6848 10−7θ 2 239.8 exp(−4.3763 10−3θ )
S-AN/15w 0.9044 + 4.2068 10−4θ + 4.0772 10−7θ 2 238.4 exp(−3.9434 10−3θ )
S-AN/18w 0.9016 + 4.0365 10−4θ + 4.2061 10−7θ 2 240.4 exp(−3.8578 10−3θ )
S-AN/40w 0.8871 + 3.4057 10−4θ + 4.9378 10−7θ 2 289.3 exp(−4.4313 10−3θ )
S-AN/70w 0.8528 + 3.6159 10−4θ + 2.6336 10−7θ 2 335.4 exp(−3.9230 10−3θ )
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
33.0 wt% acrylonitrile AN-B/33w 303-513 0.1-200 95ZOL
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
AN-B/33w Polysciences Inc.
_____________________________________________________________________________
6. PVT Data 347
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): AN-B/33w 95ZOL
_____________________________________________________________________________
P/kg cm−2 T/K
303.05 312.25 322.25 333.55 343.75 354.25 363.75 374.15 383.85
Vspez/cm3g−1
_____________________________________________________________________________
1 0.9985 1.0055 1.0166 1.0184 1.0246 1.0319 1.0380 1.0442 1.0499
200 0.9907 0.9969 1.0027 1.0090 1.0148 1.0213 1.0269 1.0329 1.0384
400 0.9834 0.9890 0.9946 1.0006 1.0062 1.0122 1.0174 1.0229 1.0281
600 0.9764 0.9818 0.9871 0.9927 0.9980 1.0038 1.0085 1.0138 1.0185
800 0.9702 0.9754 0.9802 0.9857 0.9906 0.9961 1.0006 1.0056 1.0102
1000 0.9641 0.9691 0.9739 0.9791 0.9838 0.9891 0.9932 0.9980 1.0023
1200 0.9586 0.9634 0.9680 0.9730 0.9774 0.9823 0.9864 0.9910 0.9953
1400 0.9535 0.9580 0.9624 0.9673 0.9716 0.9763 0.9801 0.9847 0.9885
1600 0.9486 0.9529 0.9570 0.9619 0.9660 0.9705 0.9743 0.9785 0.9824
1800 0.9441 0.9481 0.9523 0.9567 0.9607 0.9651 0.9688 0.9729 0.9765
2000 0.9393 0.9432 0.9474 0.9518 0.9556 0.9599 0.9634 0.9675 0.9710
_____________________________________________________________________________
continue AN-B/33w
_____________________________________________________________________________
P/kg cm−2 T/K
394.05 404.55 413.35 423.55 432.55 442.65 453.05 462.75 472.75
Vspez/cm3g−1
_____________________________________________________________________________
1 1.0569 1.0634 1.0694 1.0768 1.0825 1.0892 1.0961 1.1023 1.1098
200 1.0445 1.0507 1.0560 1.0626 1.0679 1.0738 1.0801 1.0858 1.0919
400 1.0337 1.0394 1.0446 1.0504 1.0554 1.0606 1.0665 1.0716 1.0774
600 1.0238 1.0291 1.0341 1.0395 1.0441 1.0488 1.0542 1.0589 1.0643
800 1.0149 1.0202 1.0247 1.0297 1.0341 1.0386 1.0435 1.0479 1.0530
1000 1.0070 1.0118 1.0162 1.0208 1.0250 1.0291 1.0339 1.0379 1.0428
1200 0.9994 1.0041 1.0082 1.0128 1.0166 1.0206 1.0250 1.0289 1.0335
1400 0.9928 0.9972 1.0011 1.0054 1.0092 1.0129 1.0172 1.0209 1.0253
1600 0.9866 0.9906 0.9943 0.9987 1.0021 1.0057 1.0099 1.0134 1.0175
1800 0.9806 0.9845 0.9881 0.9927 0.9995 0.9991 1.0029 1.0063 1.0101
2000 0.9749 0.9786 0.9821 0.9861 0.9893 0.9928 0.9962 0.9996 1.0035
_____________________________________________________________________________
____________________________________________________________________________________
continue AN-B/33w
_____________________________________________________________________________
P/kg cm−2 T/K
482.55 493.65 502.45 513.35
Vspez/cm3g−1
_____________________________________________________________________________
1 1.1167 1.1245 1.1309 1.1384
200 1.0983 1.1052 1.1106 1.1171
400 1.0830 1.0892 1.0938 1.0996
600 1.0694 1.0752 1.0793 1.0849
800 1.0577 1.0632 1.0670 1.0721
1000 1.0471 1.0521 1.0559 1.0603
1200 1.0378 1.0426 1.0459 1.0502
1400 1.0293 1.0337 1.0370 1.0409
1600 1.0213 1.0256 1.0287 1.0323
1800 1.0140 1.0178 1.0209 1.0245
2000 1.0071 1.0109 1.0135 1.0173
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
10.0 wt% styrene S-BR/10w 393-533 0.1-196 94WAN
25.0 % styrene S-BR/25 348-373 0.1-10 77REN
Butadiene/styrene copolymer (block copolymer
without specification)
48.0 % styrene S-?-B/48 348-373 0.1-10 77REN
70.0 % styrene S-?-B/70 348-373 0.1-10 77REN
triblock copolymer
25.4 % styrene S-B-S/25 348-373 0.1-10 77REN
30.0 % styrene S-B-S/30 348-373 0.1-10 77REN
_____________________________________________________________________________
6. PVT Data 349
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-BR/10w 112000 650000 35% 1,4-cis, 52% 1,4-trans, 13% 1,2-vinyl
S-BR/25 239000 481000 Europrene R130, ANIC Mailand
S-?-B/48 61800 76100 Europrene S141, ANIC Mailand
(32% styrene in blocks)
S-?-B/70 97600 126400 Europrene S142, ANIC Mailand
(45% styrene in blocks)
S-B-S/25 3800 (7Styr-43Buta-7Styr), 40% 1,4-cis,
50% 1,4-trans, 10% 1,2-vinyl
S-B-S/30 130500 229600
_____________________________________________________________________________

_____________________________________________________________________________
with C = 0.0894
_____________________________________________________________________________
V(0,T/K)/cm3g−1 B(T/K)/MPa
_____________________________________________________________________________
S-BR/10w 0.9053 exp(2.437 10−5 T 1.5) 530.3 exp[-3.99 10−3 (T-273.15)]
S-BR/23w 0.8986 exp(2.317 10−5 T 1.5) 551.6 exp[-4.17 10−3 (T-273.15)]
S-BR/60w 0.8812 exp(2.031 10−5 T 1.5) 486.0 exp[-4.34 10−3 (T-273.15)]
S-BR/85w 0.8704 exp(1.846 10−5 T 1.5) 356.7 exp[-4.24 10−3 (T-273.15)]
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer V(P/MPa, T/K) = V(0, T/K){1 − C(T/K) ln[1 + (P/MPa)/B(T/K)]}
_____________________________________________________________________________
S-BR/25 T/K = 348.15; V/cm3g−1 = 1.1074 [1 − 0.10290 ln(1 + P/130.1)]
T/K = 373.15; V/cm3g−1 = 1.1260 [1 − 0.11820 ln(1 + P/137.1)]
S-?-B/48 T/K = 348.15; V/cm3g−1 = 1.0607 [1 − 0.10780 ln(1 + P/168.1)]
T/K = 373.15; V/cm3g−1 = 1.0770 [1 − 0.08794 ln(1 + P/121.1)]
S-?-B/70 T/K = 348.15; V/cm3g−1 = 1.0298 [1 − 0.08723 ln(1 + P/177.2)]
T/K = 373.15; V/cm3g−1 = 1.0148 [1 − 0.07611 ln(1 + P/126.2)]
S-B-S/25 T/K = 348.15; V/cm3g−1 = 1.0989 [1 − 0.07866 ln(1 + P/117.1)]
T/K = 373.15; V/cm3g−1 = 1.1177 [1 − 0.08936 ln(1 + P/118.8)]
S-B-S/30 T/K = 348.15; V/cm3g−1 = 1.0972 [1 − 0.13030 ln(1 + P/222.5)]
T/K = 373.15; V/cm3g−1 = 1.1158 [1 − 0.11420 ln(1 + P/165.0)]
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
3.0 wt% acrylic acid E-AA/03w 393-473 0.1-200 92WIN
9.0 wt% acrylic acid E-AA/09w 410-515 0.1-200 95ZOL
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-AA/09w unspecified commercial product
E-AA/10w Du Pont, Nucrel, MI = 1.3
E-AA/20w Sci. Polym. Prod., No. 10
_____________________________________________________________________________
6. PVT Data 351
____________________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
T/K 393.2 413.2 433.2 453.2 473.2
_____________________________________________________________________________
_____________________________________________________________________________
0.1 1.2366 0.1 1.2516 0.1 1.2686 0.1 1.2856 0.1 1.3035
0.9 1.2360 5.3 1.2455 1.2 1.2675 1.0 1.2861 4.3 1.2969
2.1 1.2343 10.2 1.2400 2.9 1.2649 3.1 1.2814 10.2 1.2878
5.0 1.2312 20.4 1.2295 6.9 1.2598 7.6 1.2751 18.4 1.2766
7.3 1.2290 29.4 1.2211 11.6 1.2541 13.4 1.2675 30.2 1.2617
10.7 1.2257 39.0 1.2127 21.2 1.2433 24.7 1.2540 43.9 1.2470
14.4 1.2221 46.7 1.2066 31.0 1.2335 44.9 1.2334 63.3 1.2292
17.8 1.2189 59.5 1.1970 44.7 1.2209 64.2 1.2166 83.4 1.2131
21.5 1.2156 73.4 1.1875 64.3 1.2051 85.2 1.2009 102.7 1.1996
32.6 1.2058 87.5 1.1786 83.7 1.1911 102.4 1.1894 122.2 1.1869
101.2 1.1709 102.5 1.1792 121.6 1.1778 142.0 1.1759
123.7 1.1587 121.6 1.1682 142.2 1.1665 160.0 1.1665
141.7 1.1579 159.8 1.1578 179.8 1.1573
160.4 1.1491 179.5 1.1488 200.9 1.1479
179.0 1.1411 200.4 1.1401
_____________________________________________________________________________
_____________________________________________________________________________
T/K 393.2 413.2 433.2 453.2 473.2
_____________________________________________________________________________
_____________________________________________________________________________
0.1 1.2256 2.9 1.2364 2.7 1.2531 11.7 1.2574 23.3 1.2564
1.4 1.2243 6.5 1.2321 6.5 1.2483 18.6 1.2487 34.0 1.2442
3.7 1.2218 11.0 1.2271 11.4 1.2423 29.1 1.2370 47.6 1.2303
7.6 1.2179 18.5 1.2193 17.9 1.2349 44.5 1.2214 64.3 1.2151
14.3 1.2113 31.2 1.2073 32.9 1.2195 63.9 1.2046 83.0 1.2001
22.7 1.2038 44.4 1.1960 45.1 1.2082 83.4 1.1899 102.8 1.1863
32.7 1.1956 63.1 1.1819 64.2 1.1929 102.2 1.1775 121.8 1.1743
36.3 1.1918 82.2 1.1689 83.4 1.1791 121.0 1.1655 141.0 1.1634
41.9 1.1885 101.7 1.1571 102.7 1.1670 141.6 1.1551 160.3 1.1534
121.2 1.1465 121.6 1.1563 160.3 1.1457 180.1 1.1440
144.9 1.1335 141.1 1.1463 178.7 1.1374 201.8 1.1345
160.2 1.1372 197.0 1.1295
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
T/K 393.2 413.2 433.2 453.2 473.2
_____________________________________________________________________________
_____________________________________________________________________________
18.4 1.1989 3.4 1.2271 3.6 1.2436 4.0 1.2593 3.7 1.2755
37.2 1.1832 6.6 1.2234 7.6 1.2384 8.5 1.2532 7.5 1.2699
56.4 1.1691 11.8 1.2179 15.6 1.2293 16.8 1.2128 12.2 1.2632
77.5 1.1557 20.4 1.2092 27.6 1.2169 27.7 1.2306 20.9 1.2515
30.6 1.1998 43.7 1.2018 43.7 1.2145 31.5 1.2391
44.1 1.1884 63.1 1.1866 63.3 1.1980 43.6 1.2263
64.3 1.1736 82.2 1.1730 82.6 1.1837 62.8 1.2089
83.1 1.1613 101.9 1.1607 102.4 1.1707 82.7 1.1931
102.8 1.1500 121.3 1.1495 121.3 1.1595 102.5 1.1794
121.6 1.1399 140.7 1.1395 140.9 1.1487 120.8 1.1679
142.0 1.1292 159.8 1.1306 159.8 1.1393 140.6 1.1565
177.5 1.1228 178.4 1.1308 160.2 1.1464
193.4 1.1164 197.9 1.1225 179.2 1.1375
199.4 1.1288
_____________________________________________________________________________
copolymer (B): E-AA/09w 95ZOL
_____________________________________________________________________________
P/MPa T/K
410.15 418.55 426.45 434.75 442.05 450.45 458.75 466.95 475.15
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2221 1.2301 1.2365 1.2443 1.2506 1.2588 1.2655 1.2736 1.2819
20 1.2017 1.2081 1.2142 1.2205 1.2265 1.2330 1.2393 1.2458 1.2522
40 1.1855 1.1911 1.1967 1.2023 1.2078 1.2139 1.2192 1.2252 1.2306
60 1.1714 1.1766 1.1818 1.1869 1.1922 1.1973 1.2025 1.2077 1.2128
80 1.1591 1.1640 1.1688 1.1735 1.1785 1.1833 1.1879 1.1927 1.1974
100 1.1481 1.1526 1.1572 1.1615 1.1663 1.1707 1.1751 1.1795 1.1841
120 1.1381 1.1421 1.1464 1.1509 1.1553 1.1595 1.1635 1.1676 1.1719
140 1.1289 1.1327 1.1367 1.1407 1.1451 1.1492 1.1530 1.1569 1.1610
160 1.1202 1.1238 1.1277 1.1315 1.1358 1.1397 1.1433 1.1471 1.1507
180 1.1124 1.1157 1.1193 1.1230 1.1270 1.1308 1.1343 1.1377 1.1414
200 1.1046 1.1078 1.1116 1.1151 1.1193 1.1225 1.1259 1.1291 1.1327
_____________________________________________________________________________
6. PVT Data 353
____________________________________________________________________________________
continue E-AA/09w
_____________________________________________________________________________
P/MPa T/K
483.05 490.85 499.15 507.35 515.55
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2887 1.2963 1.3046 1.3129 1.3213
20 1.2588 1.2652 1.2719 1.2787 1.2858
40 1.2366 1.2424 1.2480 1.2541 1.2602
60 1.2181 1.2233 1.2287 1.2340 1.2395
80 1.2024 1.2073 1.2122 1.2171 1.2221
100 1.1888 1.1931 1.1977 1.2025 1.2070
120 1.1763 1.1805 1.1847 1.1892 1.1937
140 1.1650 1.1690 1.1730 1.1772 1.1814
160 1.1549 1.1586 1.1623 1.1664 1.1702
180 1.1452 1.1488 1.1525 1.1561 1.1601
200 1.1364 1.1400 1.1433 1.1469 1.1506
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
409.45 417.85 426.35 434.65 442.65 450.75 458.95 467.25 475.45
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2214 1.2286 1.2363 1.2436 1.2506 1.2581 1.2657 1.2732 1.2806
20 1.2027 1.2089 1.2156 1.2220 1.2282 1.2346 1.2409 1.2478 1.2541
40 1.1867 1.1926 1.1986 1.2044 1.2101 1.2158 1.2214 1.2275 1.2332
60 1.1729 1.1783 1.1839 1.1892 1.1945 1.1997 1.2053 1.2102 1.2157
80 1.1609 1.1658 1.1710 1.1759 1.1808 1.1856 1.1906 1.1956 1.2005
100 1.1498 1.1545 1.1595 1.1640 1.1686 1.1732 1.1777 1.1822 1.1870
120 1.1399 1.1442 1.1489 1.1532 1.1576 1.1621 1.1663 1.1704 1.1749
140 1.1306 1.1347 1.1393 1.1434 1.1476 1.1515 1.1556 1.1596 1.1640
160 1.1220 1.1260 1.1306 1.1341 1.1381 1.1422 1.1459 1.1498 1.1539
180 1.1142 1.1180 1.1221 1.1257 1.1297 1.1333 1.1372 1.1406 1.1446
200 1.1070 1.1105 1.1147 1.1179 1.1215 1.1252 1.1288 1.1323 1.1360
_____________________________________________________________________________
____________________________________________________________________________________
continue E-AA/10w
_____________________________________________________________________________
P/MPa T/K
484.15 492.05 500.55 508.85 516.95 525.75
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2889 1.2966 1.3049 1.3134 1.3215 1.3306
20 1.2613 1.2677 1.2747 1.2814 1.2883 1.2955
40 1.2392 1.2450 1.2512 1.2575 1.2634 1.2698
60 1.2210 1.2265 1.2319 1.2374 1.2429 1.2486
80 1.2055 1.2104 1.2154 1.2204 1.2256 1.2304
100 1.1917 1.1965 1.2009 1.2056 1.2103 1.2149
120 1.1792 1.1837 1.1880 1.1924 1.1969 1.2011
140 1.1679 1.1722 1.1763 1.1804 1.1847 1.1886
160 1.1577 1.1617 1.1657 1.1695 1.1737 1.1774
180 1.1482 1.1523 1.1558 1.1596 1.1634 1.1672
200 1.1397 1.1433 1.1469 1.1504 1.1540 1.1574
_____________________________________________________________________________
_____________________________________________________________________________
T/K 393.2 413.2 433.2 453.2 473.2
_____________________________________________________________________________
_____________________________________________________________________________
8.6 1.1749 3.4 1.1930 6.1 1.2047 5.6 1.2208 5.3 1.2355
19.6 1.1653 7.6 1.1884 10.7 1.1994 9.8 1.2157 10.2 1.2288
30.4 1.1568 14.7 1.1814 19.2 1.1905 17.9 1.2056 18.2 1.2187
39.7 1.1498 27.9 1.1698 31.6 1.1788 31.1 1.1923 32.2 1.2035
49.6 1.1430 43.1 1.1575 44.2 1.1683 45.5 1.1792 44.4 1.1916
62.8 1.1348 62.8 1.1434 63.4 1.1538 63.5 1.1652 64.1 1.1748
78.9 1.1249 82.0 1.1316 83.3 1.1409 82.8 1.1518 83.1 1.1607
94.1 1.1167 99.0 1.1227 103.1 1.1296 102.7 1.1397 102.8 1.1481
99.3 1.1128 102.2 1.1205 122.3 1.1196 122.1 1.1287 121.4 1.1369
112.3 1.1076 121.0 1.1114 141.5 1.1105 141.2 1.1189 141.9 1.1263
129.6 1.0995 141.7 1.1020 160.4 1.1022 159.8 1.1101 161.0 1.1169
159.9 1.0942 179.3 1.0946 178.6 1.1021 180.0 1.1085
178.3 1.0863 198.3 1.0873 197.5 1.0944 200.1 1.1005
_____________________________________________________________________________
6. PVT Data 355
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
401.75 409.75 418.45 426.15 434.75 443.55 451.95 459.75 468.25
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.1543 1.1605 1.1673 1.1740 1.1807 1.1878 1.1952 1.2017 1.2090
20 1.1384 1.1441 1.1501 1.1562 1.1620 1.1680 1.1742 1.1804 1.1866
40 1.1248 1.1300 1.1354 1.1410 1.1465 1.1518 1.1571 1.1629 1.1686
60 1.1128 1.1176 1.1226 1.1279 1.1327 1.1377 1.1424 1.1479 1.1530
80 1.1018 1.1064 1.1111 1.1159 1.1206 1.1250 1.1295 1.1347 1.1393
100 1.0923 1.0967 1.1011 1.1056 1.1099 1.1143 1.1183 1.1232 1.1275
120 1.0833 1.0880 1.0919 1.0962 1.1002 1.1041 1.1080 1.1129 1.1166
140 1.0751 1.0791 1.0831 1.0871 1.0909 1.0947 1.0985 1.1029 1.1068
160 1.0675 1.0713 1.0751 1.0789 1.0826 1.0862 1.0898 1.0940 1.0978
180 1.0603 1.0641 1.0679 1.0713 1.0749 1.0749 1.0817 1.0858 1.0894
200 1.0536 1.0572 1.0607 1.0641 1.0677 1.0677 1.0742 1.0782 1.0815
_____________________________________________________________________________
continue E-AA/20w
_____________________________________________________________________________
P/MPa T/K
476.55 485.15 493.25 501.95 510.25 518.65 526.75 535.35
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2163 1.2237 1.2309 1.2387 1.2467 1.2543 1.2622 1.2707
20 1.1927 1.1993 1.2057 1.2121 1.2189 1.2254 1.2319 1.2388
40 1.1741 1.1798 1.1856 1.1914 1.1971 1.2031 1.2088 1.2146
60 1.1581 1.1634 1.1686 1.1736 1.1790 1.1844 1.1896 1.1949
80 1.1441 1.1490 1.1539 1.1585 1.1635 1.1683 1.1732 1.1781
100 1.1321 1.1367 1.1412 1.1454 1.1500 1.1546 1.1591 1.1637
120 1.1210 1.1254 1.1296 1.1336 1.1380 1.1423 1.1465 1.1507
140 1.1108 1.1149 1.1190 1.1227 1.1270 1.1309 1.1350 1.1389
160 1.1017 1.1054 1.1094 1.1130 1.1169 1.1207 1.1247 1.1283
180 1.0931 1.0967 1.1006 1.1039 1.1077 1.1114 1.1150 1.1186
200 1.0851 1.0886 1.0922 1.0955 1.0991 1.1026 1.1061 1.1095
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and 1-butene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
20.2 wt% 1-butene E-B/20w 425-545 0.1-200 99MAI
52.2 wt% 1-butene E-B/52w 425-545 0.1-200 99MAI
69.6 wt% 1-butene E-B/70w 425-545 0.1-200 99MAI
81.6 wt% 1-butene E-B/82w 425-545 0.1-200 99MAI
87.5 wt% 1-butene E-B/88w 425-545 0.1-200 99MAI
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-B/20w 121900 305000 synthesized in the laboratory,
ρB = 0.8817 g/cm3
ρB = 0.8662 g/cm3
ρB = 0.8683 g/cm3
ρB = 0.8701 g/cm3
ρB = 0.8830 g/cm3
_____________________________________________________________________________
6. PVT Data 357
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-B/20w 99MAI
_____________________________________________________________________________
P/MPa T/K
425.24 434.75 444.75 455.35 465.22 475.34 485.06 495.15 505.89
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2752 1.2841 1.2936 1.3046 1.3135 1.3221 1.3320 1.3418 1.3523
10 1.2636 1.2718 1.2806 1.2904 1.2988 1.3067 1.3157 1.3244 1.3339
20 1.2531 1.2605 1.2688 1.2773 1.2855 1.2929 1.3012 1.3090 1.3176
30 1.2437 1.2507 1.2585 1.2666 1.2738 1.2812 1.2888 1.2962 1.3041
40 1.2351 1.2417 1.2490 1.2568 1.2637 1.2702 1.2777 1.2846 1.2921
50 1.2272 1.2335 1.2403 1.2478 1.2543 1.2605 1.2672 1.2742 1.2813
60 1.2198 1.2258 1.2324 1.2395 1.2457 1.2517 1.2580 1.2648 1.2714
70 1.2129 1.2186 1.2250 1.2317 1.2378 1.2435 1.2497 1.2557 1.2624
80 1.2064 1.2119 1.2181 1.2245 1.2304 1.2359 1.2419 1.2477 1.2536
90 1.2003 1.2056 1.2116 1.2178 1.2233 1.2287 1.2344 1.2400 1.2458
100 1.1945 1.1996 1.2055 1.2114 1.2167 1.2220 1.2275 1.2330 1.2386
110 1.1890 1.1939 1.1996 1.2053 1.2106 1.2156 1.2209 1.2264 1.2317
120 1.1837 1.1884 1.1939 1.1996 1.2046 1.2094 1.2148 1.2199 1.2252
130 1.1787 1.1832 1.1887 1.1941 1.1989 1.2038 1.2088 1.2140 1.2190
140 1.1738 1.1782 1.1835 1.1888 1.1935 1.1982 1.2033 1.2081 1.2131
150 1.1692 1.1734 1.1786 1.1838 1.1882 1.1928 1.1978 1.2026 1.2075
160 1.1647 1.1687 1.1739 1.1789 1.1833 1.1877 1.1927 1.1974 1.2021
170 1.1604 1.1643 1.1693 1.1742 1.1785 1.1830 1.1877 1.1922 1.1968
180 1.1562 1.1599 1.1650 1.1697 1.1740 1.1782 1.1828 1.1875 1.1919
190 1.1522 1.1559 1.1608 1.1654 1.1695 1.1737 1.1782 1.1827 1.1870
200 1.1484 1.1518 1.1568 1.1613 1.1654 1.1694 1.1738 1.1783 1.1824
_____________________________________________________________________________
continue E-B/20w
_____________________________________________________________________________
P/MPa T/K
515.09 524.94 535.01 545.00
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3623 1.3729 1.3841 1.3950
10 1.3429 1.3524 1.3623 1.3719
20 1.3258 1.3346 1.3434 1.3521
30 1.3118 1.3200 1.3281 1.3360
40 1.2993 1.3069 1.3146 1.3219
50 1.2882 1.2953 1.3026 1.3096
60 1.2781 1.2849 1.2918 1.2983
70 1.2689 1.2753 1.2819 1.2881
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
515.09 524.94 535.01 545.00
Vspez/cm3g−1
_____________________________________________________________________________
80 1.2602 1.2665 1.2728 1.2789
90 1.2519 1.2583 1.2643 1.2700
100 1.2444 1.2501 1.2563 1.2619
110 1.2373 1.2429 1.2485 1.2543
120 1.2306 1.2361 1.2415 1.2467
130 1.2243 1.2295 1.2349 1.2399
140 1.2181 1.2234 1.2284 1.2335
150 1.2123 1.2174 1.2224 1.2273
160 1.2069 1.2118 1.2167 1.2214
170 1.2015 1.2063 1.2110 1.2157
180 1.1965 1.2012 1.2058 1.2103
190 1.1915 1.1962 1.2007 1.2051
200 1.1869 1.1914 1.1958 1.2001
_____________________________________________________________________________

_____________________________________________________________________________
P/MPa T/K
424.48 433.74 443.82 454.18 464.52 474.15 484.04 493.79 504.43
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2558 1.2645 1.2734 1.2828 1.2924 1.3025 1.3119 1.3210 1.3314
10 1.2443 1.2522 1.2604 1.2692 1.2778 1.2868 1.2953 1.3038 1.3133
20 1.2337 1.2410 1.2487 1.2569 1.2647 1.2728 1.2804 1.2887 1.2974
30 1.2243 1.2313 1.2384 1.2462 1.2534 1.2610 1.2681 1.2756 1.2839
40 1.2158 1.2224 1.2290 1.2365 1.2433 1.2504 1.2571 1.2642 1.2716
50 1.2080 1.2142 1.2205 1.2276 1.2342 1.2409 1.2472 1.2539 1.2611
60 1.2007 1.2066 1.2127 1.2193 1.2257 1.2322 1.2382 1.2446 1.2514
70 1.1939 1.1995 1.2053 1.2118 1.2179 1.2240 1.2300 1.2360 1.2425
80 1.1874 1.1929 1.1985 1.2046 1.2107 1.2166 1.2222 1.2281 1.2342
90 1.1815 1.1867 1.1922 1.1980 1.2039 1.2096 1.2150 1.2207 1.2265
100 1.1757 1.1807 1.1861 1.1917 1.1974 1.2029 1.2081 1.2137 1.2193
110 1.1703 1.1752 1.1803 1.1857 1.1913 1.1966 1.2018 1.2072 1.2125
120 1.1651 1.1698 1.1748 1.1802 1.1856 1.1906 1.1957 1.2009 1.2061
130 1.1602 1.1646 1.1696 1.1748 1.1800 1.1850 1.1899 1.1949 1.2000
140 1.1554 1.1597 1.1646 1.1697 1.1747 1.1796 1.1844 1.1893 1.1942
150 1.1508 1.1551 1.1598 1.1647 1.1697 1.1745 1.1791 1.1839 1.1887
160 1.1464 1.1505 1.1550 1.1600 1.1648 1.1695 1.1740 1.1787 1.1834
170 1.1422 1.1462 1.1507 1.1554 1.1601 1.1648 1.1691 1.1738 1.1782
180 1.1382 1.1419 1.1463 1.1510 1.1556 1.1601 1.1645 1.1690 1.1733
190 1.1343 1.1379 1.1422 1.1468 1.1514 1.1558 1.1601 1.1645 1.1686
200 1.1304 1.1340 1.1383 1.1428 1.1472 1.1516 1.1558 1.1601 1.1642
_____________________________________________________________________________
6. PVT Data 359
____________________________________________________________________________________
continue E-B/52w
_____________________________________________________________________________
P/MPa T/K
513.63 523.99 533.96 544.35
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3413 1.3521 1.3626 1.3734
10 1.3221 1.3316 1.3409 1.3503
20 1.3052 1.3138 1.3221 1.3307
30 1.2913 1.2991 1.3068 1.3145
40 1.2788 1.2862 1.2934 1.3006
50 1.2673 1.2748 1.2815 1.2882
60 1.2574 1.2641 1.2708 1.2771
70 1.2482 1.2546 1.2607 1.2670
80 1.2398 1.2459 1.2517 1.2573
90 1.2319 1.2378 1.2434 1.2487
100 1.2246 1.2302 1.2356 1.2407
110 1.2176 1.2230 1.2283 1.2332
120 1.2111 1.2164 1.2213 1.2261
130 1.2048 1.2100 1.2148 1.2194
140 1.1989 1.2040 1.2087 1.2131
150 1.1933 1.1981 1.2027 1.2070
160 1.1879 1.1926 1.1970 1.2012
170 1.1827 1.1873 1.1917 1.1957
180 1.1779 1.1823 1.1864 1.1905
190 1.1731 1.1774 1.1815 1.1854
200 1.1685 1.1728 1.1767 1.1805
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
424.88 435.03 445.15 455.26 465.29 475.12 484.94 494.74 504.78
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2548 1.2640 1.2729 1.2822 1.2914 1.3016 1.3110 1.3203 1.3300
10 1.2423 1.2507 1.2589 1.2674 1.2758 1.2848 1.2933 1.3019 1.3106
20 1.2308 1.2385 1.2463 1.2539 1.2618 1.2697 1.2778 1.2856 1.2934
30 1.2211 1.2283 1.2358 1.2428 1.2501 1.2574 1.2648 1.2720 1.2797
40 1.2123 1.2191 1.2261 1.2327 1.2398 1.2467 1.2534 1.2602 1.2672
50 1.2044 1.2106 1.2174 1.2237 1.2304 1.2369 1.2433 1.2498 1.2562
60 1.1969 1.2028 1.2094 1.2154 1.2217 1.2281 1.2342 1.2403 1.2464
70 1.1900 1.1956 1.2019 1.2078 1.2137 1.2199 1.2257 1.2316 1.2374
80 1.1836 1.1888 1.1950 1.2006 1.2063 1.2123 1.2179 1.2235 1.2291
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
424.88 435.03 445.15 455.26 465.29 475.12 484.94 494.74 504.78
3 −1
Vspez/cm g
_____________________________________________________________________________
90 1.1776 1.1826 1.1884 1.1939 1.1994 1.2052 1.2106 1.2161 1.2214
100 1.1718 1.1766 1.1823 1.1876 1.1929 1.1985 1.2038 1.2090 1.2143
110 1.1664 1.1709 1.1764 1.1816 1.1866 1.1922 1.1973 1.2024 1.2072
120 1.1611 1.1656 1.1709 1.1760 1.1809 1.1862 1.1912 1.1961 1.2008
130 1.1562 1.1604 1.1655 1.1705 1.1752 1.1804 1.1854 1.1903 1.1948
140 1.1513 1.1555 1.1604 1.1654 1.1700 1.1750 1.1799 1.1846 1.1889
150 1.1468 1.1508 1.1555 1.1603 1.1648 1.1699 1.1746 1.1791 1.1835
160 1.1424 1.1461 1.1508 1.1557 1.1598 1.1649 1.1696 1.1740 1.1781
170 1.1381 1.1417 1.1464 1.1510 1.1552 1.1601 1.1647 1.1690 1.1731
180 1.1340 1.1376 1.1421 1.1467 1.1508 1.1555 1.1601 1.1642 1.1682
190 1.1301 1.1335 1.1379 1.1424 1.1463 1.1511 1.1555 1.1596 1.1636
200 1.1263 1.1297 1.1339 1.1383 1.1422 1.1468 1.1512 1.1553 1.1590
_____________________________________________________________________________
continue E-B/70w
_____________________________________________________________________________
P/MPa T/K
514.68 525.18 535.17 545.27
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3405 1.3515 1.3616 1.3724
10 1.3198 1.3293 1.3382 1.3475
20 1.3016 1.3100 1.3182 1.3262
30 1.2873 1.2949 1.3024 1.3097
40 1.2746 1.2818 1.2887 1.2954
50 1.2629 1.2700 1.2765 1.2829
60 1.2527 1.2591 1.2657 1.2716
70 1.2435 1.2495 1.2554 1.2616
80 1.2350 1.2407 1.2463 1.2518
90 1.2270 1.2325 1.2380 1.2430
100 1.2196 1.2249 1.2302 1.2350
110 1.2126 1.2177 1.2227 1.2274
120 1.2060 1.2109 1.2157 1.2204
130 1.1996 1.2046 1.2092 1.2137
140 1.1937 1.1984 1.2030 1.2074
150 1.1881 1.1926 1.1971 1.2013
160 1.1826 1.1871 1.1914 1.1956
170 1.1774 1.1818 1.1860 1.1900
180 1.1726 1.1767 1.1809 1.1847
190 1.1677 1.1719 1.1758 1.1797
200 1.1632 1.1673 1.1711 1.1748
_____________________________________________________________________________
6. PVT Data 361
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
424.74 434.29 444.47 454.98 465.22 474.85 485.01 494.29 504.54
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2589 1.2673 1.2763 1.2858 1.2952 1.3042 1.3134 1.3220 1.3322
10 1.2466 1.2545 1.2627 1.2714 1.2798 1.2878 1.2961 1.3042 1.3132
20 1.2355 1.2429 1.2505 1.2583 1.2661 1.2730 1.2809 1.2884 1.2966
30 1.2257 1.2327 1.2400 1.2472 1.2544 1.2609 1.2678 1.2752 1.2828
40 1.2169 1.2235 1.2302 1.2371 1.2438 1.2499 1.2564 1.2630 1.2705
50 1.2087 1.2149 1.2214 1.2281 1.2344 1.2401 1.2462 1.2525 1.2591
60 1.2012 1.2070 1.2133 1.2197 1.2255 1.2312 1.2370 1.2429 1.2491
70 1.1942 1.1999 1.2057 1.2119 1.2175 1.2228 1.2284 1.2340 1.2400
80 1.1877 1.1930 1.1988 1.2046 1.2100 1.2152 1.2206 1.2260 1.2317
90 1.1815 1.1866 1.1922 1.1978 1.2030 1.2080 1.2131 1.2183 1.2240
100 1.1758 1.1806 1.1861 1.1914 1.1964 1.2013 1.2064 1.2112 1.2166
110 1.1703 1.1748 1.1802 1.1853 1.1901 1.1949 1.1998 1.2046 1.2097
120 1.1650 1.1694 1.1746 1.1796 1.1843 1.1889 1.1937 1.1983 1.2033
130 1.1599 1.1642 1.1692 1.1741 1.1787 1.1832 1.1876 1.1924 1.1972
140 1.1552 1.1592 1.1641 1.1687 1.1734 1.1777 1.1820 1.1867 1.1913
150 1.1504 1.1545 1.1593 1.1639 1.1681 1.1725 1.1767 1.1813 1.1858
160 1.1461 1.1499 1.1545 1.1590 1.1633 1.1675 1.1716 1.1760 1.1805
170 1.1417 1.1456 1.1500 1.1544 1.1586 1.1627 1.1667 1.1711 1.1754
180 1.1376 1.1412 1.1458 1.1499 1.1541 1.1581 1.1619 1.1664 1.1706
190 1.1336 1.1372 1.1416 1.1458 1.1497 1.1538 1.1574 1.1618 1.1659
200 1.1298 1.1334 1.1376 1.1417 1.1456 1.1495 1.1530 1.1574 1.1614
_____________________________________________________________________________
continue E-B/82w
_____________________________________________________________________________
P/MPa T/K
514.64 524.44 534.44 544.66
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3416 1.3520 1.3622 1.3731
10 1.3214 1.3307 1.3396 1.3490
20 1.3038 1.3123 1.3203 1.3285
30 1.2893 1.2972 1.3046 1.3121
40 1.2765 1.2839 1.2908 1.2978
50 1.2652 1.2721 1.2786 1.2852
60 1.2546 1.2616 1.2678 1.2739
70 1.2453 1.2515 1.2580 1.2638
80 1.2368 1.2427 1.2485 1.2545
90 1.2287 1.2344 1.2400 1.2453
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
514.64 524.44 534.44 544.66
Vspez/cm3g−1
_____________________________________________________________________________
100 1.2213 1.2268 1.2322 1.2374
110 1.2144 1.2196 1.2248 1.2298
120 1.2078 1.2128 1.2178 1.2227
130 1.2015 1.2064 1.2114 1.2160
140 1.1956 1.2003 1.2050 1.2096
150 1.1899 1.1945 1.1992 1.2036
160 1.1847 1.1889 1.1935 1.1979
170 1.1795 1.1837 1.1881 1.1924
180 1.1745 1.1785 1.1829 1.1870
190 1.1698 1.1738 1.1780 1.1820
200 1.1652 1.1691 1.1733 1.1771
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
424.88 434.88 445.04 455.03 465.05 475.25 485.00 495.09 505.18
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2609 1.2695 1.2784 1.2874 1.2977 1.3069 1.3160 1.3254 1.3342
10 1.2483 1.2563 1.2645 1.2727 1.2816 1.2901 1.2986 1.3068 1.3146
20 1.2368 1.2443 1.2519 1.2595 1.2672 1.2753 1.2833 1.2906 1.2976
30 1.2268 1.2341 1.2412 1.2482 1.2554 1.2625 1.2704 1.2771 1.2836
40 1.2179 1.2246 1.2314 1.2381 1.2448 1.2516 1.2584 1.2651 1.2712
50 1.2096 1.2159 1.2225 1.2289 1.2352 1.2416 1.2481 1.2539 1.2602
60 1.2021 1.2080 1.2143 1.2204 1.2264 1.2327 1.2389 1.2442 1.2499
70 1.1950 1.2007 1.2066 1.2126 1.2183 1.2243 1.2303 1.2354 1.2407
80 1.1885 1.1938 1.1997 1.2053 1.2108 1.2166 1.2223 1.2272 1.2324
90 1.1823 1.1874 1.1930 1.1985 1.2038 1.2094 1.2149 1.2194 1.2245
100 1.1764 1.1813 1.1867 1.1922 1.1972 1.2028 1.2080 1.2124 1.2172
110 1.1709 1.1756 1.1808 1.1861 1.1911 1.1965 1.2016 1.2056 1.2104
120 1.1656 1.1701 1.1752 1.1804 1.1852 1.1904 1.1954 1.1993 1.2039
130 1.1605 1.1649 1.1698 1.1748 1.1795 1.1846 1.1896 1.1933 1.1977
140 1.1556 1.1599 1.1646 1.1696 1.1742 1.1792 1.1840 1.1876 1.1919
150 1.1511 1.1552 1.1597 1.1647 1.1691 1.1739 1.1787 1.1822 1.1862
160 1.1465 1.1505 1.1551 1.1599 1.1642 1.1689 1.1736 1.1769 1.1809
170 1.1422 1.1461 1.1505 1.1552 1.1595 1.1641 1.1687 1.1719 1.1758
180 1.1381 1.1418 1.1462 1.1508 1.1550 1.1596 1.1641 1.1672 1.1709
190 1.1342 1.1379 1.1420 1.1465 1.1507 1.1550 1.1594 1.1627 1.1662
200 1.1303 1.1340 1.1379 1.1424 1.1464 1.1508 1.1551 1.1582 1.1616
_____________________________________________________________________________
6. PVT Data 363
____________________________________________________________________________________
continue E-B/88w
_____________________________________________________________________________
P/MPa T/K
514.84 525.16 535.15 545.25
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3439 1.3538 1.3642 1.3743
10 1.3232 1.3320 1.3411 1.3498
20 1.3054 1.3132 1.3214 1.3291
30 1.2906 1.2979 1.3054 1.3126
40 1.2778 1.2845 1.2915 1.2981
50 1.2664 1.2727 1.2791 1.2855
60 1.2562 1.2621 1.2682 1.2742
70 1.2463 1.2524 1.2583 1.2639
80 1.2378 1.2430 1.2490 1.2546
90 1.2297 1.2348 1.2402 1.2460
100 1.2223 1.2271 1.2323 1.2375
110 1.2151 1.2200 1.2250 1.2299
120 1.2085 1.2132 1.2179 1.2229
130 1.2023 1.2068 1.2113 1.2161
140 1.1963 1.2006 1.2052 1.2097
150 1.1906 1.1948 1.1991 1.2037
160 1.1852 1.1892 1.1935 1.1979
170 1.1800 1.1840 1.1880 1.1924
180 1.1750 1.1789 1.1828 1.1872
190 1.1702 1.1740 1.1778 1.1822
200 1.1657 1.1694 1.1731 1.1773
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and methacrylic acid
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
4.0 wt% methacrylic acid E-MAA/04w 418-524 0.1-200 95ZOL
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-MAA/04w DuPont, Nucrel, MI = 11
E-MAA/11w DuPont, Nucrel, MI = 1.5
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-MAA/04w 95ZOL
_____________________________________________________________________________
P/MPa T/K
418.05 426.05 434.35 442.45 450.55 458.55 466.65 474.45 482.65
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2600 1.2677 1.2754 1.2827 1.2904 1.2982 1.3060 1.3136 1.3217
20 1.2392 1.2459 1.2525 1.2590 1.2655 1.2722 1.2788 1.2854 1.2924
40 1.2218 1.2283 1.2338 1.2397 1.2456 1.2518 1.2574 1.2634 1.2695
60 1.2069 1.2126 1.2179 1.2233 1.2288 1.2341 1.2396 1.2451 1.2508
80 1.1943 1.1992 1.2040 1.2090 1.2140 1.2190 1.2241 1.2292 1.2343
100 1.1822 1.1871 1.1916 1.1964 1.2010 1.2058 1.2104 1.2155 1.2199
120 1.1717 1.1762 1.1804 1.1849 1.1895 1.1939 1.1982 1.2028 1.2072
140 1.1619 1.1661 1.1701 1.1744 1.1789 1.1828 1.1870 1.1914 1.1955
160 1.1527 1.1570 1.1608 1.1648 1.1688 1.1729 1.1769 1.1810 1.1849
180 1.1444 1.1482 1.1519 1.1561 1.1597 1.1635 1.1673 1.1716 1.1751
200 1.1364 1.1403 1.1439 1.1474 1.1512 1.1549 1.1585 1.1624 1.1660
_____________________________________________________________________________
6. PVT Data 365
____________________________________________________________________________________
continue E-MAA/04w
_____________________________________________________________________________
P/MPa T/K
490.95 498.15 507.75 516.05 523.95
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.3301 1.3380 1.3475 1.3563 1.3648
20 1.2993 1.3058 1.3136 1.3205 1.3278
40 1.2755 1.2815 1.2881 1.2940 1.3002
60 1.2563 1.2617 1.2671 1.2727 1.2784
80 1.2391 1.2449 1.2494 1.2545 1.2596
100 1.2248 1.2297 1.2340 1.2385 1.2435
120 1.2116 1.2164 1.2204 1.2246 1.2292
140 1.1995 1.2042 1.2081 1.2120 1.2164
160 1.1887 1.1932 1.1967 1.2003 1.2046
180 1.1788 1.1831 1.1863 1.1899 1.1939
200 1.1695 1.1736 1.1767 1.1801 1.1838
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
410.55 418.85 426.95 435.25 443.05 451.35 459.45 467.35 475.45
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2303 1.2373 1.2446 1.2518 1.2588 1.2667 1.2748 1.2818 1.2894
20 1.2108 1.2172 1.2234 1.2297 1.2361 1.2427 1.2493 1.2555 1.2622
40 1.1945 1.2003 1.2060 1.2118 1.2175 1.2234 1.2291 1.2349 1.2408
60 1.1805 1.1858 1.1911 1.1963 1.2016 1.2071 1.2122 1.2175 1.2229
80 1.1683 1.1730 1.1779 1.1828 1.1877 1.1925 1.1976 1.2024 1.2076
100 1.1569 1.1616 1.1662 1.1707 1.1754 1.1799 1.1846 1.1891 1.1938
120 1.1468 1.1511 1.1555 1.1598 1.1642 1.1684 1.1729 1.1773 1.1817
140 1.1375 1.1415 1.1458 1.1499 1.1540 1.1580 1.1622 1.1665 1.1707
160 1.1290 1.1328 1.1369 1.1407 1.1446 1.1485 1.1524 1.1566 1.1604
180 1.1208 1.1245 1.1284 1.1322 1.1360 1.1396 1.1434 1.1472 1.1513
200 1.1135 1.1170 1.1206 1.1241 1.1279 1.1314 1.1351 1.1388 1.1426
_____________________________________________________________________________
____________________________________________________________________________________
continue E-MAA/09w
_____________________________________________________________________________
P/MPa T/K
484.05 491.55 500.35 508.35 516.15 524.45
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2974 1.3050 1.3137 1.3221 1.3294 1.3389
20 1.2690 1.2755 1.2827 1.2890 1.2959 1.3031
40 1.2466 1.2528 1.2586 1.2644 1.2708 1.2767
60 1.2284 1.2337 1.2390 1.2441 1.2501 1.2556
80 1.2123 1.2175 1.2220 1.2269 1.2323 1.2371
100 1.1982 1.2031 1.2074 1.2119 1.2170 1.2213
120 1.1858 1.1905 1.1943 1.1987 1.2031 1.2075
140 1.1745 1.1788 1.1826 1.1866 1.1909 1.1949
160 1.1643 1.1683 1.1718 1.1756 1.1797 1.1835
180 1.1549 1.1588 1.1620 1.1656 1.1694 1.1731
200 1.1459 1.1496 1.1528 1.1564 1.1601 1.1636
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
409.25 417.95 425.75 433.85 441.95 449.95 458.35 465.95 474.85
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2149 1.2220 1.2291 1.2362 1.2434 1.2506 1.2581 1.2657 1.2737
20 1.1967 1.2030 1.2093 1.2158 1.2222 1.2282 1.2348 1.2410 1.2479
40 1.1812 1.1870 1.1927 1.1983 1.2042 1.2101 1.2157 1.2214 1.2274
60 1.1679 1.1730 1.1786 1.1837 1.1890 1.1942 1.1996 1.2048 1.2102
80 1.1559 1.1610 1.1658 1.1706 1.1756 1.1806 1.1854 1.1905 1.1953
100 1.1452 1.1498 1.1545 1.1590 1.1637 1.1684 1.1729 1.1776 1.1823
120 1.1354 1.1398 1.1442 1.1485 1.1530 1.1573 1.1617 1.1661 1.1703
140 1.1265 1.1305 1.1347 1.1389 1.1430 1.1472 1.1514 1.1555 1.1595
160 1.1181 1.1219 1.1262 1.1300 1.1341 1.1380 1.1419 1.1460 1.1497
180 1.1104 1.1141 1.1180 1.1218 1.1256 1.1295 1.1332 1.1372 1.1407
200 1.1033 1.1068 1.1107 1.1145 1.1180 1.1217 1.1252 1.1289 1.1324
_____________________________________________________________________________
6. PVT Data 367
____________________________________________________________________________________
continue E-MAA/11w
_____________________________________________________________________________
P/MPa T/K
483.15 491.45 499.95 507.95 516.75 524.65
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2812 1.2892 1.2974 1.3059 1.3140 1.3226
20 1.2546 1.2612 1.2683 1.2748 1.2818 1.2888
40 1.2335 1.2392 1.2453 1.2513 1.2573 1.2635
60 1.2157 1.2209 1.2266 1.2317 1.2373 1.2430
80 1.2004 1.2052 1.2101 1.2152 1.2202 1.2254
100 1.1868 1.1914 1.1963 1.2006 1.2053 1.2101
120 1.1748 1.1790 1.1832 1.1877 1.1921 1.1966
140 1.1638 1.1678 1.1718 1.1760 1.1802 1.1844
160 1.1538 1.1575 1.1614 1.1653 1.1692 1.1733
180 1.1445 1.1481 1.1518 1.1558 1.1593 1.1632
200 1.1363 1.1396 1.1431 1.1468 1.1502 1.1542
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
409.75 418.45 426.05 434.55 442.75 450.55 458.45 466.45 474.65
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2161 1.2234 1.2298 1.2369 1.2442 1.2513 1.2589 1.2664 1.2746
20 1.1973 1.2035 1.2096 1.2159 1.2222 1.2284 1.2350 1.2412 1.2478
40 1.1817 1.1874 1.1928 1.1984 1.2040 1.2098 1.2154 1.2212 1.2270
60 1.1679 1.1731 1.1783 1.1835 1.1885 1.1937 1.1990 1.2042 1.2095
80 1.1560 1.1606 1.1655 1.1701 1.1750 1.1800 1.1847 1.1896 1.1946
100 1.1450 1.1495 1.1540 1.1584 1.1629 1.1675 1.1720 1.1767 1.1812
120 1.1351 1.1391 1.1436 1.1476 1.1519 1.1563 1.1606 1.1650 1.1692
140 1.1260 1.1298 1.1340 1.1380 1.1419 1.1463 1.1502 1.1543 1.1584
160 1.1175 1.1211 1.1252 1.1289 1.1327 1.1368 1.1408 1.1446 1.1484
180 1.1098 1.1131 1.1170 1.1205 1.1242 1.1281 1.1318 1.1355 1.1395
200 1.1024 1.1055 1.1095 1.1127 1.1162 1.1201 1.1237 1.1272 1.1307
_____________________________________________________________________________
____________________________________________________________________________________
continue E-MAA/12w
_____________________________________________________________________________
P/MPa T/K
482.95 491.05 498.85 507.35 515.75 524.15
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2823 1.2900 1.2975 1.3060 1.3142 1.3240
20 1.2546 1.2613 1.2677 1.2746 1.2814 1.2889
40 1.2330 1.2389 1.2447 1.2507 1.2567 1.2633
60 1.2149 1.2202 1.2255 1.2309 1.2363 1.2421
80 1.1994 1.2044 1.2093 1.2143 1.2191 1.2245
100 1.1858 1.1904 1.1951 1.1996 1.2041 1.2091
120 1.1735 1.1779 1.1824 1.1870 1.1909 1.1954
140 1.1625 1.1666 1.1707 1.1748 1.1788 1.1833
160 1.1523 1.1567 1.1603 1.1642 1.1678 1.1720
180 1.1430 1.1467 1.1505 1.1542 1.1577 1.1617
200 1.1345 1.1381 1.1416 1.1453 1.1488 1.1522
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
401.55 409.75 418.15 426.35 434.25 442.25 450.05 458.95 467.35
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.1917 1.1980 1.2049 1.2119 1.2193 1.2263 1.2333 1.2414 1.2484
20 1.1742 1.1801 1.1861 1.1925 1.1988 1.2052 1.2113 1.2179 1.2242
40 1.1600 1.1652 1.1706 1.1762 1.1820 1.1879 1.1935 1.1991 1.2048
60 1.1469 1.1522 1.1571 1.1622 1.1676 1.1730 1.1782 1.1834 1.1884
80 1.1356 1.1402 1.1451 1.1498 1.1551 1.1599 1.1649 1.1696 1.1743
100 1.1253 1.1296 1.1344 1.1387 1.1436 1.1483 1.1531 1.1574 1.1616
120 1.1158 1.1200 1.1243 1.1287 1.1334 1.1378 1.1421 1.1462 1.1502
140 1.1072 1.1111 1.1152 1.1193 1.1237 1.1282 1.1322 1.1360 1.1398
160 1.0991 1.1029 1.1068 1.1108 1.1150 1.1190 1.1231 1.1266 1.1303
180 1.0917 1.0953 1.0990 1.1029 1.1071 1.1108 1.1147 1.1181 1.1218
200 1.0848 1.0844 1.0919 1.0955 1.0996 1.1031 1.1072 1.1101 1.1135
_____________________________________________________________________________
6. PVT Data 369
____________________________________________________________________________________
continue E-MAA/15w
_____________________________________________________________________________
P/MPa T/K
475.65 484.05 492.15 500.85 509.25 517.25 525.75
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2563 1.2642 1.2715 1.2800 1.2886 1.2969 1.3048
20 1.2309 1.2376 1.2439 1.2508 1.2575 1.2644 1.2713
40 1.2109 1.2166 1.2224 1.2285 1.2343 1.2402 1.2463
60 1.1939 1.1995 1.2046 1.2099 1.2152 1.2207 1.2261
80 1.1792 1.1842 1.1891 1.1940 1.1989 1.2039 1.2089
100 1.1663 1.1710 1.1754 1.1799 1.1846 1.1892 1.1938
120 1.1548 1.1590 1.1634 1.1676 1.1718 1.1762 1.1804
140 1.1441 1.1484 1.1522 1.1562 1.1603 1.1644 1.1684
160 1.1345 1.1383 1.1422 1.1460 1.1498 1.1538 1.1578
180 1.1255 1.1292 1.1329 1.1365 1.1402 1.1440 1.1477
200 1.1172 1.1208 1.1245 1.1279 1.1314 1.1350 1.1385
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
401.95 410.15 417.95 426.25 434.25 442.25 450.55 458.35 466.55
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.1685 1.1742 1.1809 1.1879 1.1943 1.2015 1.2082 1.2150 1.2224
20 1.1501 1.1556 1.1616 1.1674 1.1733 1.1792 1.1853 1.1913 1.1978
40 1.1357 1.1409 1.1465 1.1514 1.1577 1.1621 1.1675 1.1730 1.1787
60 1.1233 1.1279 1.1330 1.1378 1.1426 1.1477 1.1526 1.1579 1.1630
80 1.1122 1.1166 1.1212 1.1257 1.1304 1.1349 1.1395 1.1443 1.1492
100 1.1023 1.1063 1.1108 1.1149 1.1193 1.1237 1.1279 1.1325 1.1369
120 1.0931 1.0970 1.1011 1.1052 1.1093 1.1133 1.1174 1.1218 1.1261
140 1.0847 1.0884 1.0924 1.0961 1.1001 1.1040 1.1081 1.1119 1.1158
160 1.0768 1.0804 1.0841 1.0877 1.0915 1.0952 1.0991 1.1029 1.1067
180 1.0695 1.0729 1.0765 1.0800 1.0836 1.0871 1.0906 1.0944 1.0980
200 1.0627 1.0658 1.0693 1.0726 1.0762 1.0794 1.0830 1.0866 1.0899
_____________________________________________________________________________
____________________________________________________________________________________
continue E-MAA/20w
_____________________________________________________________________________
P/MPa T/K
474.85 482.95 490.95 499.45 507.45 515.55 523.95
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2302 1.2375 1.2454 1.2531 1.2616 1.2684 1.2770
20 1.2040 1.2104 1.2170 1.2233 1.2295 1.2360 1.2429
40 1.1843 1.1901 1.1955 1.2014 1.2068 1.2126 1.2186
60 1.1680 1.1732 1.1782 1.1834 1.1885 1.1938 1.1989
80 1.1539 1.1586 1.1633 1.1679 1.1725 1.1776 1.1824
100 1.1413 1.1458 1.1501 1.1545 1.1590 1.1632 1.1678
120 1.1301 1.1343 1.1382 1.1426 1.1464 1.1506 1.1551
140 1.1197 1.1236 1.1276 1.1314 1.1354 1.1393 1.1436
160 1.1102 1.1143 1.1177 1.1215 1.1252 1.1289 1.1327
180 1.1015 1.1054 1.1087 1.1122 1.1156 1.1193 1.1231
200 1.0934 1.0970 1.1003 1.1037 1.1069 1.1104 1.1138
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and 1-octene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
2.0 wt% 1-octene E-O/02w 423-543 0.1-200 98SUH, 99MAI
_____________________________________________________________________________
6. PVT Data 371
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-O/02w 35200 73900 Dow Chemical, ρB = 0.935 g/cm3
E-O/11w 230000 598000 synthesized in the laboratory,
ρB = 0.8975 g/cm3
ρB = 0.8626 g/cm3
ρB = 0.8485 g/cm3
ρB = 0.8503 g/cm3
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-O/02w 98SUH, 99MAI
_____________________________________________________________________________
P/MPa T/K
423.97 433.40 443.51 453.42 463.64 473.72 483.63 493.11 502.84
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2703 1.2793 1.2885 1.2982 1.3085 1.3183 1.3286 1.3381 1.3486
10 1.2590 1.2673 1.2759 1.2848 1.2943 1.3031 1.3124 1.3214 1.3308
20 1.2486 1.2564 1.2645 1.2727 1.2816 1.2896 1.2981 1.3068 1.3152
30 1.2394 1.2467 1.2543 1.2620 1.2704 1.2778 1.2857 1.2937 1.3019
40 1.2303 1.2377 1.2448 1.2521 1.2602 1.2672 1.2747 1.2824 1.2898
50 1.2224 1.2290 1.2361 1.2431 1.2508 1.2576 1.2645 1.2719 1.2789
60 1.2151 1.2214 1.2279 1.2350 1.2422 1.2487 1.2553 1.2624 1.2691
70 1.2082 1.2143 1.2205 1.2273 1.2343 1.2405 1.2467 1.2536 1.2601
80 1.2017 1.2076 1.2135 1.2198 1.2270 1.2329 1.2390 1.2455 1.2517
90 1.1957 1.2012 1.2070 1.2131 1.2197 1.2258 1.2316 1.2379 1.2438
100 1.1898 1.1952 1.2008 1.2067 1.2131 1.2187 1.2247 1.2307 1.2365
110 1.1842 1.1895 1.1949 1.2006 1.2068 1.2122 1.2181 1.2239 1.2296
120 1.1790 1.1841 1.1894 1.1949 1.2009 1.2061 1.2114 1.2175 1.2230
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
423.97 433.40 443.51 453.42 463.64 473.72 483.63 493.11 502.84
Vspez/cm3g−1
_____________________________________________________________________________
130 1.1789 1.1840 1.1894 1.1951 1.2003 1.2056 1.2109 1.2167
140 1.1738 1.1788 1.1841 1.1897 1.1947 1.1999 1.2050 1.2102
150 1.1689 1.1738 1.1789 1.1844 1.1894 1.1944 1.1994 1.2045
160 1.1642 1.1691 1.1741 1.1793 1.1842 1.1891 1.1940 1.1989
170 1.1645 1.1694 1.1745 1.1792 1.1841 1.1888 1.1938
180 1.1600 1.1649 1.1699 1.1745 1.1793 1.1840 1.1887
190 1.1558 1.1606 1.1654 1.1700 1.1747 1.1793 1.1838
200 1.1518 1.1565 1.1612 1.1656 1.1703 1.1748 1.1791
_____________________________________________________________________________
continue E-O/02w
_____________________________________________________________________________
P/MPa T/K
513.17 522.94 533.06 542.96
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3597 1.3703 1.3816 1.3926
10 1.3407 1.3503 1.3601 1.3698
20 1.3242 1.3330 1.3417 1.3505
30 1.3102 1.3181 1.3263 1.3344
40 1.2976 1.3051 1.3127 1.3201
50 1.2864 1.2934 1.3005 1.3076
60 1.2762 1.2830 1.2896 1.2964
70 1.2669 1.2733 1.2798 1.2861
80 1.2582 1.2644 1.2704 1.2765
90 1.2502 1.2561 1.2618 1.2677
100 1.2426 1.2483 1.2538 1.2594
110 1.2354 1.2410 1.2463 1.2518
120 1.2286 1.2340 1.2392 1.2444
130 1.2222 1.2274 1.2324 1.2375
140 1.2160 1.2210 1.2260 1.2309
150 1.2100 1.2151 1.2197 1.2246
160 1.2040 1.2093 1.2139 1.2186
170 1.1987 1.2034 1.2082 1.2128
180 1.1935 1.1981 1.2025 1.2074
190 1.1884 1.1931 1.1973 1.2018
200 1.1837 1.1882 1.1925 1.1968
_____________________________________________________________________________
6. PVT Data 373
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
423.39 433.78 443.83 453.70 464.04 474.46 484.38 494.28 504.08
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2736 1.2829 1.2925 1.3017 1.3114 1.3218 1.3317 1.3421 1.3523
10 1.2615 1.2704 1.2792 1.2878 1.2966 1.3059 1.3151 1.3243 1.3335
20 1.2503 1.2590 1.2671 1.2751 1.2833 1.2917 1.3004 1.3086 1.3169
30 1.2408 1.2490 1.2568 1.2642 1.2719 1.2797 1.2878 1.2955 1.3033
40 1.2321 1.2394 1.2473 1.2543 1.2616 1.2689 1.2767 1.2839 1.2912
50 1.2242 1.2311 1.2381 1.2453 1.2522 1.2592 1.2666 1.2734 1.2804
60 1.2168 1.2233 1.2302 1.2366 1.2436 1.2503 1.2574 1.2639 1.2705
70 1.2099 1.2161 1.2227 1.2289 1.2353 1.2421 1.2487 1.2551 1.2615
80 1.2034 1.2094 1.2157 1.2217 1.2278 1.2341 1.2408 1.2470 1.2530
90 1.1974 1.2030 1.2092 1.2149 1.2208 1.2269 1.2334 1.2393 1.2452
100 1.1915 1.1970 1.2029 1.2085 1.2142 1.2201 1.2259 1.2322 1.2379
110 1.1860 1.1912 1.1970 1.2024 1.2079 1.2137 1.2193 1.2249 1.2308
120 1.1808 1.1857 1.1913 1.1966 1.2021 1.2076 1.2130 1.2184 1.2239
130 1.1756 1.1804 1.1858 1.1910 1.1963 1.2018 1.2070 1.2123 1.2177
140 1.1708 1.1754 1.1807 1.1857 1.1908 1.1962 1.2011 1.2064 1.2117
150 1.1660 1.1704 1.1757 1.1805 1.1855 1.1909 1.1957 1.2009 1.2058
160 1.1614 1.1658 1.1708 1.1756 1.1805 1.1857 1.1904 1.1955 1.2004
170 1.1571 1.1613 1.1661 1.1708 1.1756 1.1807 1.1853 1.1902 1.1950
180 1.1528 1.1570 1.1617 1.1663 1.1710 1.1761 1.1805 1.1854 1.1900
190 1.1487 1.1528 1.1575 1.1620 1.1665 1.1715 1.1758 1.1806 1.1851
200 1.1448 1.1489 1.1533 1.1577 1.1623 1.1671 1.1713 1.1761 1.1806
_____________________________________________________________________________
continue E-O/08w
_____________________________________________________________________________
P/MPa T/K
514.22 524.46 534.71 543.97
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3628 1.3738 1.3853 1.3957
10 1.3429 1.3526 1.3627 1.3718
20 1.3254 1.3342 1.3433 1.3513
30 1.3111 1.3192 1.3275 1.3350
40 1.2985 1.3060 1.3137 1.3207
50 1.2871 1.2943 1.3016 1.3080
60 1.2769 1.2837 1.2905 1.2966
70 1.2674 1.2740 1.2805 1.2863
80 1.2588 1.2651 1.2713 1.2769
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
514.22 524.46 534.71 543.97
Vspez/cm3g−1
_____________________________________________________________________________
90 1.2506 1.2569 1.2627 1.2680
100 1.2430 1.2492 1.2546 1.2599
110 1.2358 1.2418 1.2470 1.2520
120 1.2290 1.2348 1.2397 1.2448
130 1.2222 1.2281 1.2330 1.2378
140 1.2160 1.2219 1.2264 1.2312
150 1.2102 1.2153 1.2203 1.2250
160 1.2046 1.2096 1.2139 1.2190
170 1.1991 1.2042 1.2081 1.2127
180 1.1940 1.1988 1.2027 1.2073
190 1.1890 1.1937 1.1976 1.2021
200 1.1844 1.1890 1.1927 1.1970
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
422.14 431.98 441.99 451.98 462.44 472.53 482.35 492.16 502.32
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2819 1.2925 1.3017 1.3110 1.3210 1.3308 1.3408 1.3506 1.3611
10 1.2702 1.2797 1.2884 1.2971 1.3063 1.3153 1.3243 1.3332 1.3424
20 1.2594 1.2679 1.2763 1.2846 1.2929 1.3013 1.3096 1.3178 1.3260
30 1.2499 1.2579 1.2655 1.2738 1.2817 1.2894 1.2971 1.3047 1.3122
40 1.2411 1.2487 1.2560 1.2638 1.2712 1.2788 1.2858 1.2929 1.3000
50 1.2330 1.2404 1.2473 1.2544 1.2618 1.2688 1.2756 1.2824 1.2890
60 1.2256 1.2327 1.2393 1.2459 1.2527 1.2597 1.2664 1.2728 1.2790
70 1.2186 1.2255 1.2319 1.2383 1.2447 1.2511 1.2578 1.2640 1.2700
80 1.2121 1.2188 1.2250 1.2310 1.2373 1.2434 1.2494 1.2559 1.2617
90 1.2059 1.2124 1.2183 1.2244 1.2301 1.2361 1.2420 1.2477 1.2538
100 1.2001 1.2064 1.2121 1.2179 1.2235 1.2292 1.2350 1.2406 1.2460
110 1.1945 1.2006 1.2062 1.2118 1.2174 1.2227 1.2283 1.2337 1.2391
120 1.1893 1.1950 1.2005 1.2060 1.2113 1.2166 1.2220 1.2271 1.2325
130 1.1842 1.1898 1.1950 1.2005 1.2057 1.2107 1.2160 1.2210 1.2261
140 1.1792 1.1847 1.1899 1.1951 1.2002 1.2051 1.2102 1.2150 1.2202
150 1.1745 1.1798 1.1849 1.1900 1.1948 1.1999 1.2047 1.2095 1.2144
160 1.1701 1.1751 1.1800 1.1852 1.1898 1.1947 1.1995 1.2041 1.2090
170 1.1657 1.1707 1.1754 1.1805 1.1849 1.1898 1.1943 1.1990 1.2038
180 1.1615 1.1663 1.1710 1.1759 1.1803 1.1850 1.1895 1.1940 1.1988
190 1.1574 1.1623 1.1667 1.1716 1.1758 1.1805 1.1850 1.1893 1.1939
200 1.1536 1.1584 1.1626 1.1673 1.1715 1.1763 1.1805 1.1849 1.1894
_____________________________________________________________________________
6. PVT Data 375
____________________________________________________________________________________
continue E-O/11w
_____________________________________________________________________________
P/MPa T/K
512.35 522.40 532.43 542.16
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3715 1.3826 1.3935 1.4045
10 1.3518 1.3621 1.3717 1.3810
20 1.3344 1.3443 1.3530 1.3610
30 1.3202 1.3293 1.3373 1.3444
40 1.3076 1.3158 1.3234 1.3303
50 1.2962 1.3039 1.3109 1.3176
60 1.2858 1.2932 1.2999 1.3061
70 1.2765 1.2836 1.2898 1.2958
80 1.2678 1.2745 1.2806 1.2862
90 1.2595 1.2662 1.2720 1.2774
100 1.2519 1.2583 1.2638 1.2691
110 1.2448 1.2509 1.2563 1.2614
120 1.2376 1.2439 1.2491 1.2541
130 1.2313 1.2369 1.2423 1.2472
140 1.2250 1.2305 1.2354 1.2407
150 1.2193 1.2244 1.2293 1.2339
160 1.2137 1.2186 1.2234 1.2280
170 1.2083 1.2131 1.2177 1.2224
180 1.2032 1.2078 1.2122 1.2169
190 1.1983 1.2028 1.2071 1.2117
200 1.1936 1.1981 1.2022 1.2068
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
424.40 433.97 444.27 454.30 464.81 475.00 484.88 494.98 505.43
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2798 1.2887 1.2983 1.3081 1.3184 1.3283 1.3387 1.3487 1.3594
10 1.2674 1.2758 1.2848 1.2939 1.3032 1.3122 1.3217 1.3307 1.3402
20 1.2560 1.2642 1.2726 1.2810 1.2895 1.2978 1.3066 1.3148 1.3232
30 1.2464 1.2538 1.2620 1.2700 1.2779 1.2857 1.2939 1.3014 1.3095
40 1.2377 1.2444 1.2520 1.2599 1.2675 1.2748 1.2824 1.2896 1.2971
50 1.2295 1.2360 1.2431 1.2503 1.2577 1.2649 1.2721 1.2790 1.2859
60 1.2221 1.2281 1.2350 1.2419 1.2486 1.2559 1.2627 1.2692 1.2760
70 1.2150 1.2207 1.2274 1.2340 1.2404 1.2474 1.2540 1.2604 1.2668
80 1.2084 1.2140 1.2203 1.2267 1.2329 1.2392 1.2460 1.2520 1.2582
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
424.40 433.97 444.27 454.30 464.81 475.00 484.88 494.98 505.43
Vspez/cm3g−1
_____________________________________________________________________________
90 1.2022 1.2075 1.2137 1.2199 1.2258 1.2318 1.2381 1.2443 1.2502
100 1.1963 1.2014 1.2073 1.2133 1.2192 1.2249 1.2309 1.2367 1.2427
110 1.1905 1.1956 1.2013 1.2072 1.2129 1.2184 1.2243 1.2297 1.2352
120 1.1852 1.1900 1.1955 1.2012 1.2068 1.2122 1.2178 1.2232 1.2284
130 1.1800 1.1847 1.1900 1.1956 1.2010 1.2063 1.2118 1.2171 1.2221
140 1.1750 1.1796 1.1847 1.1902 1.1956 1.2006 1.2060 1.2111 1.2160
150 1.1701 1.1746 1.1796 1.1851 1.1902 1.1951 1.2005 1.2054 1.2101
160 1.1656 1.1699 1.1747 1.1800 1.1851 1.1899 1.1951 1.2000 1.2044
170 1.1610 1.1653 1.1700 1.1752 1.1802 1.1849 1.1899 1.1948 1.1990
180 1.1568 1.1609 1.1655 1.1706 1.1755 1.1801 1.1850 1.1897 1.1939
190 1.1525 1.1566 1.1612 1.1662 1.1710 1.1755 1.1802 1.1849 1.1889
200 1.1486 1.1526 1.1571 1.1620 1.1668 1.1710 1.1758 1.1803 1.1842
_____________________________________________________________________________
continue E-O/12w
_____________________________________________________________________________
P/MPa T/K
515.58 525.44 535.59 545.01
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3705 1.3814 1.3928 1.4032
10 1.3501 1.3597 1.3696 1.3788
20 1.3324 1.3411 1.3498 1.3580
30 1.3176 1.3257 1.3337 1.3414
40 1.3047 1.3123 1.3196 1.3269
50 1.2933 1.3004 1.3074 1.3141
60 1.2828 1.2896 1.2962 1.3025
70 1.2733 1.2797 1.2861 1.2920
80 1.2644 1.2707 1.2768 1.2824
90 1.2562 1.2622 1.2680 1.2734
100 1.2484 1.2543 1.2599 1.2651
110 1.2411 1.2468 1.2522 1.2574
120 1.2337 1.2397 1.2450 1.2497
130 1.2271 1.2329 1.2380 1.2428
140 1.2210 1.2261 1.2314 1.2361
150 1.2149 1.2200 1.2248 1.2297
160 1.2092 1.2141 1.2187 1.2233
170 1.2038 1.2084 1.2131 1.2174
180 1.1986 1.2031 1.2076 1.2118
190 1.1935 1.1980 1.2024 1.2065
200 1.1888 1.1931 1.1974 1.2013
_____________________________________________________________________________
6. PVT Data 377
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
423.68 433.84 443.84 453.96 463.69 474.13 483.96 493.93 503.56
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2820 1.2913 1.3007 1.3104 1.3201 1.3303 1.3401 1.3502 1.3608
10 1.2696 1.2784 1.2872 1.2961 1.3050 1.3142 1.3232 1.3323 1.3419
20 1.2582 1.2668 1.2750 1.2833 1.2915 1.2999 1.3083 1.3165 1.3253
30 1.2485 1.2563 1.2644 1.2721 1.2798 1.2877 1.2954 1.3031 1.3113
40 1.2397 1.2469 1.2543 1.2620 1.2691 1.2767 1.2840 1.2911 1.2988
50 1.2315 1.2383 1.2454 1.2523 1.2596 1.2666 1.2736 1.2804 1.2877
60 1.2240 1.2305 1.2372 1.2438 1.2504 1.2575 1.2642 1.2706 1.2776
70 1.2169 1.2230 1.2296 1.2360 1.2423 1.2488 1.2555 1.2617 1.2682
80 1.2103 1.2161 1.2225 1.2287 1.2347 1.2411 1.2472 1.2534 1.2596
90 1.2041 1.2097 1.2158 1.2218 1.2276 1.2337 1.2396 1.2453 1.2516
100 1.1981 1.2035 1.2094 1.2152 1.2208 1.2268 1.2326 1.2380 1.2442
110 1.1925 1.1976 1.2034 1.2091 1.2144 1.2203 1.2258 1.2310 1.2367
120 1.1871 1.1919 1.1976 1.2031 1.2085 1.2140 1.2194 1.2245 1.2300
130 1.1819 1.1866 1.1921 1.1975 1.2027 1.2080 1.2133 1.2184 1.2235
140 1.1769 1.1814 1.1868 1.1920 1.1971 1.2024 1.2074 1.2123 1.2174
150 1.1720 1.1764 1.1816 1.1869 1.1918 1.1968 1.2019 1.2067 1.2116
160 1.1674 1.1718 1.1768 1.1819 1.1866 1.1916 1.1965 1.2012 1.2060
170 1.1629 1.1672 1.1720 1.1771 1.1817 1.1867 1.1914 1.1959 1.2007
180 1.1587 1.1627 1.1675 1.1725 1.1771 1.1818 1.1865 1.1909 1.1955
190 1.1545 1.1585 1.1632 1.1681 1.1725 1.1771 1.1817 1.1862 1.1906
200 1.1506 1.1545 1.1590 1.1639 1.1682 1.1727 1.1772 1.1816 1.1859
_____________________________________________________________________________
continue E-O/14w
_____________________________________________________________________________
P/MPa T/K
513.94 524.07 533.83 544.30
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3721 1.3831 1.3938 1.4051
10 1.3519 1.3617 1.3711 1.3808
20 1.3343 1.3433 1.3517 1.3602
30 1.3196 1.3279 1.3356 1.3433
40 1.3066 1.3144 1.3216 1.3288
50 1.2950 1.3024 1.3092 1.3157
60 1.2845 1.2915 1.2979 1.3041
70 1.2750 1.2815 1.2877 1.2936
80 1.2660 1.2725 1.2783 1.2839
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
513.94 524.07 533.83 544.30
Vspez/cm3g−1
_____________________________________________________________________________
90 1.2577 1.2639 1.2695 1.2750
100 1.2500 1.2560 1.2614 1.2665
110 1.2427 1.2484 1.2536 1.2586
120 1.2354 1.2413 1.2463 1.2512
130 1.2288 1.2342 1.2394 1.2441
140 1.2224 1.2277 1.2325 1.2375
150 1.2165 1.2216 1.2262 1.2307
160 1.2107 1.2157 1.2202 1.2245
170 1.2052 1.2100 1.2144 1.2187
180 1.2000 1.2047 1.2090 1.2132
190 1.1950 1.1996 1.2037 1.2078
200 1.1902 1.1947 1.1987 1.2026
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
423.10 433.01 443.28 453.42 463.80 473.36 483.63 493.64 503.31
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2825 1.2930 1.3026 1.3122 1.3227 1.3324 1.3431 1.3533 1.3639
10 1.2704 1.2798 1.2887 1.2977 1.3072 1.3163 1.3256 1.3349 1.3444
20 1.2592 1.2677 1.2763 1.2845 1.2933 1.3019 1.3101 1.3188 1.3275
30 1.2494 1.2574 1.2650 1.2733 1.2814 1.2895 1.2971 1.3050 1.3133
40 1.2403 1.2479 1.2550 1.2625 1.2706 1.2781 1.2853 1.2926 1.3004
50 1.2320 1.2392 1.2459 1.2531 1.2603 1.2679 1.2745 1.2815 1.2888
60 1.2242 1.2311 1.2375 1.2443 1.2514 1.2582 1.2648 1.2714 1.2783
70 1.2169 1.2236 1.2296 1.2363 1.2430 1.2496 1.2556 1.2623 1.2687
80 1.2101 1.2166 1.2224 1.2286 1.2352 1.2416 1.2474 1.2533 1.2600
90 1.2038 1.2099 1.2155 1.2216 1.2279 1.2341 1.2397 1.2454 1.2515
100 1.1977 1.2038 1.2091 1.2150 1.2209 1.2270 1.2324 1.2380 1.2439
110 1.1919 1.1978 1.2030 1.2086 1.2145 1.2203 1.2256 1.2310 1.2366
120 1.1863 1.1922 1.1971 1.2025 1.2083 1.2138 1.2190 1.2243 1.2298
130 1.1811 1.1866 1.1915 1.1968 1.2023 1.2078 1.2127 1.2179 1.2233
140 1.1759 1.1814 1.1861 1.1913 1.1966 1.2019 1.2069 1.2118 1.2172
150 1.1710 1.1765 1.1809 1.1860 1.1912 1.1964 1.2012 1.2061 1.2112
160 1.1662 1.1716 1.1760 1.1808 1.1859 1.1911 1.1958 1.2005 1.2055
170 1.1617 1.1670 1.1712 1.1759 1.1809 1.1860 1.1907 1.1951 1.2001
180 1.1575 1.1624 1.1666 1.1713 1.1761 1.1811 1.1857 1.1902 1.1949
190 1.1533 1.1583 1.1623 1.1669 1.1715 1.1764 1.1809 1.1853 1.1900
200 1.1492 1.1541 1.1581 1.1624 1.1672 1.1719 1.1764 1.1806 1.1853
_____________________________________________________________________________
6. PVT Data 379
____________________________________________________________________________________
continue E-O/25w
_____________________________________________________________________________
P/MPa T/K
514.02 524.03 533.91 543.88
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3754 1.3865 1.3977 1.4094
10 1.3546 1.3644 1.3745 1.3846
20 1.3368 1.3455 1.3546 1.3637
30 1.3216 1.3296 1.3384 1.3465
40 1.3082 1.3156 1.3239 1.3314
50 1.2963 1.3033 1.3108 1.3181
60 1.2854 1.2924 1.2995 1.3063
70 1.2755 1.2821 1.2890 1.2953
80 1.2665 1.2729 1.2791 1.2852
90 1.2580 1.2641 1.2704 1.2761
100 1.2496 1.2558 1.2620 1.2675
110 1.2422 1.2481 1.2542 1.2596
120 1.2352 1.2406 1.2467 1.2520
130 1.2285 1.2337 1.2392 1.2448
140 1.2221 1.2273 1.2328 1.2377
150 1.2161 1.2211 1.2263 1.2311
160 1.2102 1.2152 1.2202 1.2249
170 1.2045 1.2095 1.2145 1.2189
180 1.1992 1.2041 1.2091 1.2134
190 1.1941 1.1989 1.2038 1.2080
200 1.1894 1.1940 1.1987 1.2028
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
423.60 433.65 443.42 453.53 464.23 474.19 483.79 493.75 503.81
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2785 1.2879 1.2973 1.3070 1.3177 1.3273 1.3366 1.3458 1.3558
10 1.2664 1.2752 1.2838 1.2926 1.3023 1.3113 1.3197 1.3279 1.3368
20 1.2554 1.2636 1.2715 1.2796 1.2883 1.2970 1.3046 1.3121 1.3201
30 1.2458 1.2535 1.2611 1.2686 1.2767 1.2846 1.2920 1.2989 1.3061
40 1.2369 1.2442 1.2513 1.2585 1.2662 1.2735 1.2801 1.2870 1.2936
50 1.2288 1.2356 1.2426 1.2492 1.2566 1.2635 1.2697 1.2758 1.2826
60 1.2212 1.2278 1.2344 1.2407 1.2478 1.2544 1.2602 1.2661 1.2722
70 1.2142 1.2206 1.2269 1.2330 1.2396 1.2461 1.2516 1.2570 1.2628
80 1.2077 1.2136 1.2198 1.2256 1.2320 1.2382 1.2433 1.2487 1.2542
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
423.60 433.65 443.42 453.53 464.23 474.19 483.79 493.75 503.81
Vspez/cm3g−1
_____________________________________________________________________________
90 1.2015 1.2072 1.2132 1.2188 1.2249 1.2309 1.2358 1.2409 1.2463
100 1.1956 1.2011 1.2068 1.2124 1.2183 1.2240 1.2288 1.2338 1.2389
110 1.1899 1.1953 1.2008 1.2063 1.2119 1.2175 1.2220 1.2269 1.2318
120 1.1845 1.1898 1.1952 1.2004 1.2058 1.2113 1.2156 1.2202 1.2250
130 1.1794 1.1844 1.1898 1.1949 1.2001 1.2055 1.2096 1.2141 1.2187
140 1.1744 1.1793 1.1845 1.1895 1.1945 1.1997 1.2038 1.2082 1.2127
150 1.1698 1.1744 1.1794 1.1844 1.1893 1.1944 1.1983 1.2026 1.2069
160 1.1651 1.1697 1.1747 1.1794 1.1843 1.1891 1.1930 1.1972 1.2015
170 1.1607 1.1651 1.1700 1.1746 1.1794 1.1843 1.1879 1.1921 1.1962
180 1.1565 1.1608 1.1655 1.1701 1.1747 1.1795 1.1831 1.1871 1.1911
190 1.1524 1.1568 1.1613 1.1657 1.1702 1.1750 1.1784 1.1825 1.1863
200 1.1485 1.1528 1.1572 1.1617 1.1659 1.1706 1.1741 1.1780 1.1818
_____________________________________________________________________________
continue E-O/39w
_____________________________________________________________________________
P/MPa T/K
514.05 523.82 533.95 543.80
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3664 1.3770 1.3878 1.3993
10 1.3463 1.3558 1.3653 1.3754
20 1.3287 1.3374 1.3460 1.3551
30 1.3142 1.3222 1.3303 1.3385
40 1.3012 1.3086 1.3162 1.3236
50 1.2896 1.2965 1.3034 1.3106
60 1.2791 1.2859 1.2921 1.2991
70 1.2692 1.2760 1.2820 1.2888
80 1.2604 1.2669 1.2727 1.2790
90 1.2522 1.2581 1.2641 1.2699
100 1.2444 1.2501 1.2557 1.2617
110 1.2372 1.2428 1.2481 1.2535
120 1.2305 1.2358 1.2408 1.2461
130 1.2241 1.2292 1.2339 1.2390
140 1.2178 1.2227 1.2276 1.2324
150 1.2119 1.2167 1.2214 1.2262
160 1.2063 1.2110 1.2155 1.2200
170 1.2008 1.2057 1.2099 1.2142
180 1.1957 1.2005 1.2046 1.2088
190 1.1909 1.1954 1.1995 1.2037
200 1.1862 1.1906 1.1947 1.1988
_____________________________________________________________________________
6. PVT Data 381
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
423.15 433.05 443.06 453.05 463.51 473.26 483.30 493.10 503.26
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2860 1.2957 1.3054 1.3151 1.3262 1.3357 1.3443 1.3543 1.3650
10 1.2738 1.2827 1.2918 1.3006 1.3105 1.3190 1.3268 1.3359 1.3456
20 1.2626 1.2709 1.2793 1.2874 1.2964 1.3040 1.3113 1.3198 1.3287
30 1.2527 1.2606 1.2686 1.2762 1.2844 1.2914 1.2978 1.3061 1.3145
40 1.2436 1.2510 1.2586 1.2658 1.2735 1.2803 1.2862 1.2934 1.3016
50 1.2352 1.2424 1.2496 1.2562 1.2637 1.2699 1.2756 1.2822 1.2898
60 1.2275 1.2343 1.2413 1.2476 1.2547 1.2605 1.2659 1.2724 1.2796
70 1.2202 1.2270 1.2334 1.2397 1.2464 1.2519 1.2571 1.2633 1.2701
80 1.2134 1.2199 1.2263 1.2322 1.2387 1.2440 1.2490 1.2549 1.2613
90 1.2071 1.2132 1.2194 1.2252 1.2315 1.2365 1.2413 1.2470 1.2532
100 1.2010 1.2071 1.2130 1.2186 1.2247 1.2295 1.2341 1.2396 1.2455
110 1.1953 1.2012 1.2069 1.2123 1.2183 1.2229 1.2274 1.2327 1.2385
120 1.1898 1.1956 1.2011 1.2063 1.2121 1.2166 1.2209 1.2261 1.2315
130 1.1845 1.1901 1.1955 1.2007 1.2064 1.2106 1.2149 1.2198 1.2251
140 1.1795 1.1849 1.1901 1.1952 1.2007 1.2047 1.2090 1.2137 1.2189
150 1.1747 1.1799 1.1851 1.1899 1.1953 1.1993 1.2034 1.2080 1.2131
160 1.1700 1.1754 1.1801 1.1848 1.1902 1.1940 1.1981 1.2024 1.2075
170 1.1656 1.1706 1.1754 1.1801 1.1852 1.1888 1.1928 1.1973 1.2020
180 1.1612 1.1662 1.1708 1.1755 1.1805 1.1841 1.1880 1.1922 1.1969
190 1.1572 1.1621 1.1665 1.1710 1.1758 1.1795 1.1832 1.1875 1.1921
200 1.1532 1.1581 1.1623 1.1668 1.1716 1.1750 1.1787 1.1829 1.1873
_____________________________________________________________________________
continue E-O/55w
_____________________________________________________________________________
P/MPa T/K
513.39 523.14 532.76 542.82
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3760 1.3866 1.3970 1.4090
10 1.3556 1.3646 1.3741 1.3845
20 1.3380 1.3457 1.3547 1.3638
30 1.3229 1.3300 1.3383 1.3468
40 1.3095 1.3161 1.3237 1.3317
50 1.2973 1.3037 1.3110 1.3183
60 1.2864 1.2929 1.2997 1.3064
70 1.2765 1.2825 1.2895 1.2959
80 1.2675 1.2731 1.2796 1.2859
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
513.39 523.14 532.76 542.82
Vspez/cm3g−1
_____________________________________________________________________________
90 1.2591 1.2646 1.2709 1.2765
100 1.2512 1.2566 1.2627 1.2682
110 1.2438 1.2490 1.2549 1.2601
120 1.2369 1.2418 1.2475 1.2527
130 1.2301 1.2351 1.2407 1.2456
140 1.2238 1.2286 1.2341 1.2388
150 1.2180 1.2226 1.2278 1.2324
160 1.2123 1.2167 1.2217 1.2262
170 1.2067 1.2112 1.2160 1.2204
180 1.2015 1.2059 1.2106 1.2148
190 1.1965 1.2007 1.2053 1.2095
200 1.1917 1.1959 1.2005 1.2045
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
423.50 433.48 443.33 453.37 463.49 474.04 483.94 493.91 503.70
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2741 1.2839 1.2936 1.3034 1.3145 1.3255 1.3355 1.3464 1.3572
10 1.2728 1.2825 1.2921 1.3019 1.3128 1.3237 1.3336 1.3443 1.3550
20 1.2716 1.2811 1.2906 1.3003 1.3111 1.3219 1.3317 1.3423 1.3528
30 1.2703 1.2798 1.2892 1.2988 1.3094 1.3201 1.3298 1.3403 1.3507
40 1.2690 1.2784 1.2878 1.2973 1.3078 1.3183 1.3280 1.3383 1.3486
50 1.2678 1.2771 1.2864 1.2958 1.3061 1.3165 1.3261 1.3364 1.3466
60 1.2665 1.2758 1.2850 1.2944 1.3045 1.3148 1.3244 1.3345 1.3446
70 1.2653 1.2745 1.2836 1.2929 1.3030 1.3131 1.3226 1.3326 1.3426
80 1.2641 1.2732 1.2822 1.2915 1.3014 1.3115 1.3209 1.3308 1.3406
90 1.2629 1.2719 1.2809 1.2901 1.2998 1.3098 1.3191 1.3290 1.3387
100 1.2617 1.2707 1.2796 1.2887 1.2983 1.3082 1.3175 1.3272 1.3368
110 1.2605 1.2693 1.2782 1.2873 1.2968 1.3064 1.3158 1.3253 1.3349
120 1.2593 1.2681 1.2769 1.2858 1.2953 1.3048 1.3140 1.3235 1.3329
130 1.2581 1.2669 1.2756 1.2845 1.2938 1.3033 1.3123 1.3218 1.3310
140 1.2570 1.2657 1.2742 1.2830 1.2920 1.3016 1.3108 1.3199 1.3292
150 1.2558 1.2645 1.2729 1.2817 1.2906 1.3002 1.3091 1.3182 1.3274
160 1.2547 1.2633 1.2717 1.2804 1.2891 1.2987 1.3076 1.3167 1.3257
170 1.2536 1.2621 1.2705 1.2791 1.2877 1.2972 1.3060 1.3150 1.3240
180 1.2525 1.2609 1.2692 1.2780 1.2864 1.2958 1.3045 1.3135 1.3224
190 1.2515 1.2598 1.2681 1.2767 1.2851 1.2944 1.3031 1.3119 1.3207
200 1.2504 1.2586 1.2669 1.2755 1.2838 1.2930 1.3016 1.3104 1.3191
_____________________________________________________________________________
6. PVT Data 383
____________________________________________________________________________________
continue E-O/64w
_____________________________________________________________________________
P/MPa T/K
513.61 523.74 533.61 543.85
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3687 1.3806 1.3925 1.4044
10 1.3663 1.3781 1.3898 1.4014
20 1.3640 1.3756 1.3871 1.3986
30 1.3617 1.3732 1.3846 1.3958
40 1.3595 1.3708 1.3820 1.3931
50 1.3573 1.3684 1.3795 1.3904
60 1.3551 1.3661 1.3771 1.3878
70 1.3530 1.3639 1.3747 1.3852
80 1.3509 1.3617 1.3724 1.3827
90 1.3489 1.3595 1.3701 1.3802
100 1.3469 1.3574 1.3678 1.3778
110 1.3447 1.3551 1.3653 1.3753
120 1.3427 1.3529 1.3630 1.3729
130 1.3407 1.3508 1.3609 1.3704
140 1.3388 1.3488 1.3587 1.3682
150 1.3369 1.3467 1.3566 1.3660
160 1.3351 1.3448 1.3546 1.3637
170 1.3333 1.3429 1.3526 1.3617
180 1.3315 1.3411 1.3507 1.3595
190 1.3298 1.3393 1.3489 1.3575
200 1.3282 1.3376 1.3470 1.3557
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
10.8 wt% propylene E-P/11w 422-542 0.1-200 99MAI
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
Copolymer Acronym Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
23.0 wt% propylene E-P/23w 398-570 0.1-200 95ZOL
50.0 wt% propylene E-P/50w 413-523 0.1-63 93ROD
57.0 wt% propylene E-P/57w 377-581 0.1-200 95ZOL
76.0 wt% propylene E-P/76w(1) 388-575 0.1-200 95ZOL
76.2 wt% propylene E-P/76w(2) 422-542 0.1-200 99MAI
83.5 wt% propylene E-P/84w(1) 422-542 0.1-200 99MAI
84.0 wt% propylene E-P/84w(2) 388-570 0.1-200 95ZOL
unknown propylene content E-P/? 413-523 0.1-62 73RAO
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-P/11w 143600 273000 synthesized in the laboratory,
ρB = 0.9007 g/cm3
ρB = 0.9008 g/cm3
E-P/23w 53300 160000 random, most probable distribution
ρB = 0.8871 g/cm3
E-P/57w 51500 134000 random, most probable distribution
ρB = 0.8582 g/cm3
E-P/76w(1) 40200 84400 random, most probable distribution
E-P/76w(2) 77800 117000 synthesized in the laboratory,
ρB = 0.8600 g/cm3
E-P/84w(1) 49600 94200 synthesized in the laboratory,
ρB = 0.8783 g/cm3
E-P/84w(2) 35700 75000 random, most probable distribution
ρB = 0.8889 g/cm3
E-P/? no data
_____________________________________________________________________________
6. PVT Data 385
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-P/11w 99MAI
_____________________________________________________________________________
P/MPa T/K
421.89 431.91 441.92 452.05 462.47 472.46 482.53 492.22 501.54
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2776 1.2871 1.2975 1.3068 1.3164 1.3266 1.3362 1.3462 1.3559
10 1.2662 1.2750 1.2844 1.2929 1.3020 1.3113 1.3200 1.3291 1.3380
20 1.2557 1.2638 1.2723 1.2806 1.2889 1.2976 1.3056 1.3138 1.3220
30 1.2465 1.2542 1.2622 1.2695 1.2779 1.2858 1.2934 1.3012 1.3089
40 1.2381 1.2452 1.2530 1.2599 1.2674 1.2755 1.2826 1.2899 1.2971
50 1.2303 1.2370 1.2444 1.2511 1.2582 1.2653 1.2727 1.2798 1.2866
60 1.2230 1.2295 1.2364 1.2429 1.2498 1.2566 1.2636 1.2704 1.2769
70 1.2164 1.2224 1.2291 1.2353 1.2420 1.2486 1.2549 1.2617 1.2680
80 1.2101 1.2158 1.2222 1.2283 1.2347 1.2410 1.2471 1.2532 1.2597
90 1.2040 1.2097 1.2157 1.2216 1.2277 1.2339 1.2398 1.2459 1.2516
100 1.1983 1.2037 1.2097 1.2153 1.2213 1.2272 1.2329 1.2387 1.2444
110 1.1929 1.1981 1.2038 1.2094 1.2152 1.2208 1.2264 1.2322 1.2375
120 1.1877 1.1928 1.1983 1.2037 1.2093 1.2149 1.2202 1.2258 1.2310
130 1.1826 1.1876 1.1930 1.1983 1.2037 1.2092 1.2144 1.2198 1.2247
140 1.1779 1.1826 1.1878 1.1930 1.1985 1.2036 1.2087 1.2139 1.2190
150 1.1732 1.1779 1.1829 1.1882 1.1932 1.1985 1.2034 1.2085 1.2132
160 1.1688 1.1733 1.1783 1.1834 1.1884 1.1935 1.1983 1.2032 1.2078
170 1.1645 1.1688 1.1737 1.1787 1.1836 1.1885 1.1934 1.1982 1.2026
180 1.1602 1.1646 1.1695 1.1742 1.1792 1.1841 1.1885 1.1932 1.1978
190 1.1563 1.1605 1.1652 1.1700 1.1747 1.1796 1.1841 1.1886 1.1929
200 1.1524 1.1566 1.1612 1.1659 1.1705 1.1753 1.1798 1.1842 1.1884
_____________________________________________________________________________
continue E-P/11w
_____________________________________________________________________________
P/MPa T/K
512.33 521.91 531.78 541.21
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3669 1.3778 1.3882 1.3999
10 1.3475 1.3573 1.3662 1.3764
20 1.3305 1.3394 1.3471 1.3561
30 1.3166 1.3248 1.3318 1.3402
40 1.3040 1.3118 1.3185 1.3263
50 1.2930 1.3004 1.3067 1.3140
60 1.2832 1.2901 1.2959 1.3029
70 1.2739 1.2807 1.2861 1.2928
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
512.33 521.91 531.78 541.21
Vspez/cm3g−1
_____________________________________________________________________________
80 1.2654 1.2719 1.2773 1.2836
90 1.2576 1.2638 1.2689 1.2751
100 1.2496 1.2562 1.2611 1.2670
110 1.2427 1.2485 1.2537 1.2594
120 1.2360 1.2417 1.2467 1.2523
130 1.2296 1.2352 1.2397 1.2456
140 1.2236 1.2291 1.2333 1.2387
150 1.2179 1.2232 1.2275 1.2326
160 1.2124 1.2176 1.2216 1.2267
170 1.2070 1.2121 1.2162 1.2211
180 1.2020 1.2070 1.2109 1.2158
190 1.1972 1.2021 1.2058 1.2106
200 1.1925 1.1973 1.2011 1.2057
_____________________________________________________________________________

_____________________________________________________________________________
P/MPa T/K
422.29 432.39 442.28 452.35 462.56 472.70 482.67 492.24 501.91
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2665 1.2756 1.2849 1.2951 1.3050 1.3143 1.3237 1.3336 1.3435
10 1.2551 1.2634 1.2720 1.2811 1.2901 1.2990 1.3076 1.3166 1.3255
20 1.2447 1.2524 1.2603 1.2682 1.2770 1.2854 1.2931 1.3015 1.3097
30 1.2353 1.2426 1.2502 1.2576 1.2654 1.2736 1.2811 1.2888 1.2964
40 1.2269 1.2337 1.2408 1.2478 1.2553 1.2625 1.2702 1.2773 1.2846
50 1.2191 1.2254 1.2323 1.2391 1.2459 1.2530 1.2598 1.2672 1.2740
60 1.2118 1.2178 1.2243 1.2308 1.2376 1.2442 1.2506 1.2573 1.2642
70 1.2050 1.2107 1.2171 1.2232 1.2298 1.2361 1.2423 1.2486 1.2549
80 1.1987 1.2040 1.2102 1.2161 1.2224 1.2285 1.2346 1.2406 1.2466
90 1.1926 1.1977 1.2038 1.2095 1.2156 1.2214 1.2273 1.2332 1.2389
100 1.1869 1.1919 1.1977 1.2031 1.2090 1.2148 1.2204 1.2262 1.2316
110 1.1814 1.1861 1.1920 1.1972 1.2028 1.2084 1.2139 1.2195 1.2248
120 1.1762 1.1809 1.1865 1.1915 1.1971 1.2024 1.2076 1.2131 1.2183
130 1.1712 1.1756 1.1812 1.1860 1.1914 1.1967 1.2018 1.2072 1.2122
140 1.1665 1.1706 1.1760 1.1809 1.1860 1.1912 1.1962 1.2014 1.2063
150 1.1618 1.1660 1.1713 1.1759 1.1809 1.1860 1.1908 1.1958 1.2006
160 1.1574 1.1613 1.1666 1.1712 1.1761 1.1809 1.1856 1.1906 1.1952
170 1.1531 1.1569 1.1621 1.1666 1.1713 1.1761 1.1807 1.1856 1.1900
180 1.1491 1.1526 1.1578 1.1622 1.1666 1.1714 1.1759 1.1807 1.1851
190 1.1450 1.1486 1.1535 1.1579 1.1623 1.1669 1.1714 1.1760 1.1802
200 1.1413 1.1447 1.1496 1.1539 1.1581 1.1627 1.1669 1.1714 1.1757
_____________________________________________________________________________
6. PVT Data 387
____________________________________________________________________________________
continue E-P/17w
_____________________________________________________________________________
P/MPa T/K
512.38 522.39 532.94 542.69
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3540 1.3643 1.3757 1.3869
10 1.3348 1.3440 1.3539 1.3637
20 1.3180 1.3262 1.3351 1.3440
30 1.3041 1.3117 1.3199 1.3279
40 1.2916 1.2989 1.3063 1.3139
50 1.2805 1.2874 1.2943 1.3015
60 1.2705 1.2769 1.2836 1.2902
70 1.2614 1.2675 1.2737 1.2801
80 1.2522 1.2586 1.2647 1.2709
90 1.2443 1.2500 1.2562 1.2622
100 1.2369 1.2422 1.2485 1.2541
110 1.2298 1.2352 1.2405 1.2465
120 1.2231 1.2284 1.2336 1.2389
130 1.2168 1.2219 1.2270 1.2320
140 1.2109 1.2157 1.2206 1.2257
150 1.2050 1.2098 1.2147 1.2196
160 1.1995 1.2042 1.2088 1.2137
170 1.1942 1.1988 1.2033 1.2081
180 1.1894 1.1937 1.1981 1.2028
190 1.1844 1.1886 1.1930 1.1975
200 1.1797 1.1838 1.1883 1.1926
_____________________________________________________________________________
copolymer (B): E-P/23w 95ZOL
_____________________________________________________________________________
P/MPa T/K
398.45 408.65 418.85 428.65 438.95 449.25 458.95 469.05 479.15
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2632 1.2730 1.2825 1.2914 1.3010 1.3109 1.3195 1.3296 1.3392
20 1.2433 1.2524 1.2607 1.2688 1.2768 1.2852 1.2932 1.3017 1.3097
40 1.2266 1.2350 1.2427 1.2500 1.2571 1.2649 1.2716 1.2791 1.2863
60 1.2121 1.2199 1.2271 1.2338 1.2407 1.2473 1.2537 1.2605 1.2670
80 1.1993 1.2065 1.2136 1.2200 1.2262 1.2322 1.2383 1.2445 1.2505
100 1.1878 1.1948 1.2014 1.2075 1.2133 1.2191 1.2246 1.2304 1.2360
120 1.1773 1.1839 1.1901 1.1962 1.2014 1.2071 1.2173 1.2179 1.2230
140 1.1677 1.1740 1.1799 1.1861 1.1908 1.1963 1.2012 1.2065 1.2113
160 1.1588 1.1650 1.1708 1.1762 1.1812 1.1862 1.1912 1.1963 1.2007
180 1.1505 1.1567 1.1620 1.1671 1.1720 1.1770 1.1818 1.1864 1.1909
200 1.1427 1.1488 1.1537 1.1587 1.1637 1.1685 1.1730 1.1777 1.1817
_____________________________________________________________________________
____________________________________________________________________________________
continue E-P/23w
_____________________________________________________________________________
P/MPa T/K
489.55 499.35 509.45 519.95 529.75 539.75 550.35 559.65 570.45
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3496 1.3599 1.3698 1.3808 1.3913 1.4023 1.4137 1.4242 1.4632
20 1.3180 1.3265 1.3350 1.3435 1.3524 1.3608 1.3699 1.3786 1.3878
40 1.2937 1.3010 1.3085 1.3160 1.3232 1.3307 1.3384 1.3459 1.3538
60 1.2738 1.2805 1.2869 1.2933 1.3004 1.3067 1.3135 1.3206 1.3271
80 1.2566 1.2629 1.2687 1.2746 1.2807 1.2867 1.2928 1.2990 1.3054
100 1.2415 1.2475 1.2529 1.2583 1.2640 1.2696 1.2752 1.2808 1.2865
120 1.2283 1.2337 1.2389 1.2442 1.2493 1.2545 1.2597 1.2650 1.2701
140 1.2163 1.2214 1.2264 1.2309 1.2361 1.2409 1.2457 1.2508 1.2557
160 1.2055 1.2102 1.2148 1.2192 1.2242 1.2286 1.2332 1.2381 1.2426
180 1.1955 1.2000 1.2044 1.2085 1.2131 1.2175 1.2218 1.2264 1.2307
200 1.1863 1.1904 1.1948 1.1985 1.2032 1.2072 1.2112 1.2158 1.2198
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
422.35 432.50 442.35 452.05 462.27 472.37 482.18 492.51 502.28
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2740 1.2836 1.2938 1.3028 1.3122 1.3220 1.3317 1.3422 1.3523
10 1.2624 1.2711 1.2804 1.2886 1.2975 1.3066 1.3155 1.3249 1.3339
20 1.2517 1.2598 1.2681 1.2761 1.2843 1.2929 1.3010 1.3095 1.3178
30 1.2423 1.2498 1.2578 1.2648 1.2731 1.2810 1.2886 1.2966 1.3042
40 1.2337 1.2408 1.2484 1.2550 1.2624 1.2702 1.2776 1.2851 1.2922
50 1.2259 1.2324 1.2399 1.2460 1.2531 1.2601 1.2675 1.2746 1.2814
60 1.2186 1.2247 1.2319 1.2377 1.2445 1.2512 1.2578 1.2651 1.2716
70 1.2118 1.2177 1.2245 1.2301 1.2366 1.2431 1.2494 1.2558 1.2626
80 1.2053 1.2110 1.2176 1.2229 1.2292 1.2354 1.2415 1.2477 1.2536
90 1.1993 1.2047 1.2110 1.2163 1.2222 1.2282 1.2342 1.2400 1.2458
100 1.1935 1.1987 1.2048 1.2100 1.2157 1.2214 1.2272 1.2329 1.2385
110 1.1881 1.1930 1.1990 1.2040 1.2095 1.2151 1.2206 1.2262 1.2315
120 1.1828 1.1876 1.1932 1.1984 1.2036 1.2090 1.2144 1.2197 1.2250
130 1.1777 1.1825 1.1880 1.1930 1.1980 1.2033 1.2086 1.2136 1.2187
140 1.1729 1.1775 1.1828 1.1877 1.1926 1.1978 1.2028 1.2079 1.2128
150 1.1683 1.1726 1.1777 1.1827 1.1875 1.1925 1.1976 1.2023 1.2071
160 1.1639 1.1680 1.1730 1.1778 1.1826 1.1876 1.1923 1.1972 1.2016
170 1.1595 1.1635 1.1684 1.1733 1.1779 1.1828 1.1873 1.1921 1.1966
180 1.1553 1.1593 1.1640 1.1687 1.1733 1.1781 1.1826 1.1872 1.1916
190 1.1513 1.1553 1.1597 1.1645 1.1689 1.1737 1.1780 1.1826 1.1868
200 1.1475 1.1513 1.1557 1.1604 1.1647 1.1694 1.1736 1.1783 1.1822
_____________________________________________________________________________
6. PVT Data 389
____________________________________________________________________________________
continue E-P/32w
_____________________________________________________________________________
P/MPa T/K
512.33 522.19 532.19 542.01
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3631 1.3732 1.3843 1.3959
10 1.3434 1.3523 1.3619 1.3720
20 1.3262 1.3340 1.3426 1.3515
30 1.3119 1.3193 1.3271 1.3353
40 1.2993 1.3062 1.3135 1.3211
50 1.2880 1.2947 1.3015 1.3085
60 1.2779 1.2843 1.2906 1.2973
70 1.2685 1.2747 1.2808 1.2871
80 1.2599 1.2659 1.2717 1.2777
90 1.2513 1.2576 1.2633 1.2691
100 1.2438 1.2500 1.2553 1.2609
110 1.2367 1.2421 1.2479 1.2533
120 1.2300 1.2353 1.2403 1.2461
130 1.2237 1.2288 1.2336 1.2386
140 1.2175 1.2226 1.2273 1.2322
150 1.2118 1.2167 1.2213 1.2259
160 1.2064 1.2109 1.2155 1.2201
170 1.2010 1.2055 1.2100 1.2143
180 1.1960 1.2003 1.2047 1.2090
190 1.1912 1.1954 1.1997 1.2039
200 1.1866 1.1907 1.1949 1.1989
_____________________________________________________________________________
copolymer (B): E-P/57w 95ZOL
_____________________________________________________________________________
P/MPa T/K
377.65 385.55 394.05 401.95 410.05 418.45 426.45 434.85 442.45
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2411 1.2479 1.2558 1.2629 1.2703 1.2782 1.2856 1.2933 1.3006
20 1.2222 1.2284 1.2353 1.2420 1.2481 1.2548 1.2612 1.2678 1.2724
40 1.2067 1.2124 1.2185 1.2244 1.2301 1.2361 1.2421 1.2478 1.2535
60 1.1931 1.1984 1.2040 1.2095 1.2147 1.2201 1.2257 1.2307 1.2362
80 1.1810 1.1860 1.1911 1.1962 1.2012 1.2061 1.2111 1.2161 1.2211
100 1.1702 1.1749 1.1797 1.1844 1.1892 1.1937 1.1984 1.2031 1.2079
120 1.1604 1.1647 1.1693 1.1739 1.1780 1.1824 1.1869 1.1912 1.1958
140 1.1511 1.1555 1.1596 1.1639 1.1681 1.1721 1.1766 1.1806 1.1850
160 1.1427 1.1469 1.1510 1.1549 1.1587 1.1625 1.1666 1.1707 1.1748
180 1.1347 1.1386 1.1427 1.1463 1.1502 1.1537 1.1575 1.1616 1.1655
200 1.1274 1.1311 1.1348 1.1385 1.1422 1.1454 1.1491 1.1528 1.1569
_____________________________________________________________________________
____________________________________________________________________________________
continue E-P/57w
_____________________________________________________________________________
P/MPa T/K
451.05 459.35 467.15 475.35 483.65 491.65 499.85 508.25 516.65
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.3088 1.3169 1.3250 1.3331 1.3414 1.3497 1.3580 1.3678 1.3756
20 1.2810 1.2878 1.2945 1.3014 1.3084 1.3153 1.3220 1.3292 1.3362
40 1.2595 1.2654 1.2713 1.2775 1.2835 1.2899 1.2956 1.3016 1.3078
60 1.2417 1.2473 1.2523 1.2578 1.2632 1.2687 1.2742 1.2795 1.2852
80 1.2262 1.2311 1.2362 1.2415 1.2461 1.2510 1.2561 1.2609 1.2659
100 1.2128 1.2171 1.2218 1.2265 1.2310 1.2360 1.2407 1.2448 1.2494
120 1.2003 1.2045 1.2087 1.2133 1.2176 1.2220 1.2264 1.2308 1.2349
140 1.1891 1.1933 1.1972 1.2015 1.2056 1.2097 1.2138 1.2178 1.2221
160 1.1790 1.1826 1.1868 1.9088 1.9945 1.9986 1.2026 1.2060 1.2099
180 1.1695 1.1729 1.1768 1.1806 1.1843 1.1880 1.1920 1.1953 1.1988
200 1.1607 1.1639 1.1676 1.1714 1.1748 1.1787 1.1821 1.1853 1.1888
_____________________________________________________________________________
continue E-P/57w
_____________________________________________________________________________
P/MPa T/K
524.85 533.25 541.15 549.05 557.05 565.25 573.35 581.55
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.3850 1.3938 1.4029 1.4118 1.4209 1.4307 1.4405 1.4512
20 1.3434 1.3506 1.3575 1.3647 1.3716 1.3790 1.3865 1.3939
40 1.3137 1.3201 1.3259 1.3318 1.3380 1.3441 1.3503 1.3566
60 1.2904 1.2956 1.3010 1.3063 1.3118 1.3171 1.3227 1.3283
80 1.2709 1.2757 1.2808 1.2854 1.2902 1.2951 1.3002 1.3051
100 1.2539 1.2587 1.2632 1.2674 1.2719 1.2764 1.2811 1.2855
120 1.2391 1.2432 1.2476 1.2519 1.2557 1.2599 1.2642 1.2684
140 1.2258 1.2300 1.2336 1.2376 1.2414 1.2453 1.2493 1.2532
160 1.2137 1.2174 1.2210 1.2248 1.2287 1.2322 1.2358 1.2397
180 1.2027 1.2064 1.2098 1.2132 1.2165 1.2201 1.2237 1.2272
200 1.1922 1.1958 1.1990 1.2024 1.2057 1.2092 1.2124 1.2158
_____________________________________________________________________________
6. PVT Data 391
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
422.35 432.82 442.90 452.71 462.75 473.22 483.07 492.81 502.36
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2670 1.2766 1.2859 1.2954 1.3046 1.3159 1.3255 1.3352 1.3450
10 1.2550 1.2638 1.2724 1.2810 1.2895 1.2993 1.3081 1.3170 1.3259
20 1.2441 1.2521 1.2601 1.2680 1.2760 1.2844 1.2929 1.3010 1.3093
30 1.2344 1.2419 1.2495 1.2567 1.2643 1.2722 1.2795 1.2875 1.2953
40 1.2257 1.2325 1.2397 1.2466 1.2537 1.2612 1.2682 1.2751 1.2829
50 1.2176 1.2240 1.2309 1.2375 1.2441 1.2511 1.2578 1.2645 1.2713
60 1.2100 1.2161 1.2226 1.2289 1.2354 1.2420 1.2484 1.2547 1.2613
70 1.2030 1.2087 1.2150 1.2211 1.2274 1.2337 1.2398 1.2458 1.2521
80 1.1965 1.2019 1.2078 1.2137 1.2198 1.2259 1.2317 1.2376 1.2435
90 1.1903 1.1954 1.2011 1.2069 1.2128 1.2186 1.2243 1.2298 1.2357
100 1.1843 1.1893 1.1948 1.2004 1.2061 1.2119 1.2172 1.2227 1.2282
110 1.1787 1.1836 1.1889 1.1942 1.1999 1.2052 1.2106 1.2159 1.2213
120 1.1734 1.1781 1.1831 1.1885 1.1939 1.1991 1.2042 1.2094 1.2147
130 1.1683 1.1727 1.1776 1.1829 1.1882 1.1933 1.1982 1.2032 1.2084
140 1.1635 1.1677 1.1726 1.1775 1.1827 1.1877 1.1925 1.1975 1.2025
150 1.1588 1.1629 1.1675 1.1725 1.1775 1.1823 1.1870 1.1918 1.1967
160 1.1543 1.1582 1.1627 1.1675 1.1725 1.1772 1.1818 1.1866 1.1913
170 1.1501 1.1537 1.1581 1.1628 1.1677 1.1722 1.1768 1.1814 1.1860
180 1.1458 1.1493 1.1537 1.1583 1.1631 1.1675 1.1719 1.1765 1.1810
190 1.1418 1.1452 1.1495 1.1539 1.1586 1.1630 1.1672 1.1718 1.1763
200 1.1380 1.1411 1.1455 1.1499 1.1543 1.1586 1.1629 1.1672 1.1717
_____________________________________________________________________________
continue E-P/61w
_____________________________________________________________________________
P/MPa T/K
512.82 522.52 532.78 542.86
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3560 1.3663 1.3773 1.3890
10 1.3356 1.3448 1.3543 1.3643
20 1.3179 1.3263 1.3347 1.3435
30 1.3032 1.3110 1.3186 1.3267
40 1.2903 1.2974 1.3046 1.3122
50 1.2787 1.2855 1.2922 1.2993
60 1.2679 1.2747 1.2811 1.2878
70 1.2583 1.2645 1.2709 1.2773
80 1.2494 1.2555 1.2613 1.2677
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
512.82 522.52 532.78 542.86
Vspez/cm3g−1
_____________________________________________________________________________
90 1.2414 1.2471 1.2527 1.2584
100 1.2337 1.2392 1.2446 1.2501
110 1.2265 1.2319 1.2369 1.2424
120 1.2197 1.2249 1.2299 1.2349
130 1.2133 1.2183 1.2231 1.2280
140 1.2072 1.2121 1.2167 1.2215
150 1.2013 1.2061 1.2106 1.2153
160 1.1958 1.2005 1.2047 1.2092
170 1.1905 1.1950 1.1992 1.2035
180 1.1852 1.1898 1.1938 1.1982
190 1.1804 1.1847 1.1886 1.1930
200 1.1757 1.1800 1.1838 1.1879
_____________________________________________________________________________
copolymer (B): E-P/76w(1) 95ZOL
_____________________________________________________________________________
P/MPa T/K
387.65 397.85 408.05 418.45 428.75 438.75 448.65 458.95 469.35
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2496 1.2588 1.2678 1.2772 1.2868 1.2962 1.3058 1.3158 1.3260
20 1.2300 1.2380 1.2459 1.2540 1.2622 1.2702 1.2785 1.2868 1.2956
40 1.2136 1.2207 1.2278 1.2351 1.2422 1.2496 1.2569 1.2643 1.2717
60 1.1993 1.2059 1.2126 1.2192 1.2255 1.2322 1.2389 1.2455 1.2522
80 1.1686 1.1928 1.1989 1.2050 1.2110 1.2175 1.2234 1.2298 1.2357
100 1.1755 1.1812 1.1868 1.1924 1.1980 1.2040 1.2097 1.2155 1.2212
120 1.1655 1.1707 1.1758 1.1812 1.1864 1.1922 1.1975 1.2028 1.2082
140 1.1557 1.1607 1.1659 1.1708 1.1760 1.1811 1.1865 1.1915 1.1965
160 1.1470 1.1519 1.1566 1.1614 1.1661 1.1711 1.1760 1.1810 1.1858
180 1.1389 1.1433 1.1481 1.1524 1.1571 1.1619 1.1666 1.1712 1.1758
200 1.1311 1.1355 1.1401 1.1442 1.1486 1.1534 1.1579 1.1623 1.1668
_____________________________________________________________________________
6. PVT Data 393
____________________________________________________________________________________
continue E-P/76w(1)
_____________________________________________________________________________
P/MPa T/K
479.65 489.55 499.75 509.75 519.85 530.15 550.35 560.25 569.75
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3363 1.3467 1.3570 1.3672 1.3780 1.3899 1.4115 1.4230 1.4342
20 1.3037 1.3121 1.3207 1.3292 1.3380 1.3470 1.3640 1.3731 1.3815
40 1.2791 1.2863 1.2938 1.3012 1.3087 1.3164 1.3307 1.3381 1.3458
60 1.2588 1.2654 1.2721 1.2788 1.2855 1.2920 1.3050 1.3114 1.3181
80 1.2417 1.2477 1.2539 1.2602 1.2660 1.2724 1.2837 1.2895 1.2957
100 1.2267 1.2323 1.2381 1.2439 1.2494 1.2548 1.2656 1.2711 1.2767
120 1.2132 1.2186 1.2240 1.2296 1.2346 1.2399 1.2498 1.2546 1.2600
140 1.2013 1.2064 1.2115 1.2165 1.2214 1.2265 1.2359 1.2401 1.2452
160 1.1904 1.1952 1.1999 1.2048 1.2094 1.2141 1.2227 1.2270 1.2321
180 1.1800 1.1851 1.1895 1.1941 1.1985 1.2028 1.2111 1.2152 1.2198
200 1.1706 1.1752 1.1797 1.1841 1.1882 1.1926 1.2006 1.2042 1.2086
_____________________________________________________________________________
copolymer (B): E-P/76w(2) 99MAI
_____________________________________________________________________________
P/MPa T/K
422.46 432.42 442.40 452.55 462.61 472.81 482.66 492.45 502.25
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2641 1.2736 1.2827 1.2923 1.3015 1.3115 1.3224 1.3322 1.3417
10 1.2519 1.2604 1.2689 1.2776 1.2861 1.2950 1.3044 1.3133 1.3221
20 1.2407 1.2484 1.2564 1.2644 1.2723 1.2803 1.2884 1.2971 1.3050
30 1.2308 1.2381 1.2457 1.2531 1.2604 1.2681 1.2756 1.2830 1.2905
40 1.2219 1.2286 1.2356 1.2429 1.2497 1.2570 1.2640 1.2711 1.2780
50 1.2136 1.2200 1.2267 1.2336 1.2401 1.2471 1.2537 1.2605 1.2669
60 1.2062 1.2120 1.2186 1.2251 1.2313 1.2379 1.2442 1.2507 1.2569
70 1.1992 1.2047 1.2109 1.2172 1.2233 1.2295 1.2356 1.2417 1.2476
80 1.1925 1.1978 1.2039 1.2099 1.2158 1.2219 1.2276 1.2335 1.2392
90 1.1863 1.1915 1.1973 1.2029 1.2087 1.2145 1.2203 1.2258 1.2313
100 1.1805 1.1854 1.1910 1.1965 1.2022 1.2077 1.2132 1.2186 1.2239
110 1.1749 1.1796 1.1850 1.1903 1.1959 1.2014 1.2066 1.2119 1.2170
120 1.1695 1.1742 1.1795 1.1846 1.1899 1.1953 1.2004 1.2054 1.2104
130 1.1644 1.1690 1.1741 1.1791 1.1841 1.1895 1.1944 1.1995 1.2043
140 1.1595 1.1639 1.1690 1.1737 1.1790 1.1840 1.1888 1.1937 1.1984
150 1.1549 1.1591 1.1642 1.1686 1.1736 1.1786 1.1834 1.1882 1.1928
160 1.1506 1.1545 1.1595 1.1638 1.1688 1.1735 1.1782 1.1829 1.1873
170 1.1463 1.1501 1.1548 1.1593 1.1640 1.1688 1.1732 1.1778 1.1821
180 1.1420 1.1458 1.1504 1.1547 1.1595 1.1640 1.1685 1.1730 1.1773
190 1.1381 1.1416 1.1464 1.1506 1.1552 1.1595 1.1639 1.1683 1.1725
200 1.1342 1.1376 1.1423 1.1464 1.1509 1.1553 1.1596 1.1639 1.1680
_____________________________________________________________________________
____________________________________________________________________________________
continue E-P/76w(2)
_____________________________________________________________________________
P/MPa T/K
512.63 522.53 532.52 542.51
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3523 1.3631 1.3735 1.3849
10 1.3315 1.3409 1.3499 1.3597
20 1.3134 1.3217 1.3297 1.3385
30 1.2986 1.3062 1.3134 1.3216
40 1.2851 1.2928 1.2995 1.3069
50 1.2735 1.2802 1.2871 1.2940
60 1.2631 1.2695 1.2756 1.2825
70 1.2537 1.2597 1.2655 1.2721
80 1.2450 1.2508 1.2564 1.2621
90 1.2368 1.2425 1.2478 1.2532
100 1.2293 1.2348 1.2399 1.2452
110 1.2222 1.2274 1.2326 1.2374
120 1.2156 1.2205 1.2255 1.2302
130 1.2092 1.2140 1.2189 1.2235
140 1.2030 1.2078 1.2125 1.2171
150 1.1974 1.2019 1.2065 1.2109
160 1.1918 1.1963 1.2006 1.2052
170 1.1864 1.1909 1.1951 1.1996
180 1.1814 1.1856 1.1899 1.1941
190 1.1767 1.1808 1.1849 1.1889
200 1.1720 1.1760 1.1800 1.1841
_____________________________________________________________________________
copolymer (B): E-P/84w(1) 99MAI
_____________________________________________________________________________
P/MPa T/K
422.88 433.00 443.00 453.12 463.34 473.59 483.52 493.17 503.21
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2720 1.2816 1.2909 1.3007 1.3113 1.3209 1.3304 1.3409 1.3509
10 1.2593 1.2681 1.2766 1.2855 1.2950 1.3037 1.3124 1.3217 1.3307
20 1.2479 1.2558 1.2636 1.2719 1.2803 1.2885 1.2966 1.3049 1.3133
30 1.2377 1.2452 1.2525 1.2602 1.2681 1.2753 1.2833 1.2911 1.2987
40 1.2285 1.2355 1.2424 1.2497 1.2571 1.2639 1.2710 1.2785 1.2860
50 1.2200 1.2267 1.2332 1.2401 1.2472 1.2536 1.2603 1.2670 1.2744
60 1.2121 1.2185 1.2247 1.2313 1.2382 1.2444 1.2507 1.2571 1.2636
70 1.2050 1.2109 1.2170 1.2233 1.2298 1.2357 1.2418 1.2480 1.2542
80 1.1982 1.2039 1.2097 1.2158 1.2221 1.2278 1.2337 1.2396 1.2455
_____________________________________________________________________________
continue
6. PVT Data 395
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
422.88 433.00 443.00 453.12 463.34 473.59 483.52 493.17 503.21
Vspez/cm3g−1
_____________________________________________________________________________
90 1.1918 1.1972 1.2029 1.2088 1.2150 1.2204 1.2260 1.2318 1.2375
100 1.1858 1.1910 1.1965 1.2022 1.2081 1.2134 1.2189 1.2245 1.2299
110 1.1801 1.1850 1.1906 1.1959 1.2017 1.2068 1.2121 1.2175 1.2228
120 1.1747 1.1793 1.1847 1.1900 1.1956 1.2005 1.2058 1.2111 1.2161
130 1.1695 1.1740 1.1792 1.1843 1.1898 1.1947 1.1996 1.2048 1.2097
140 1.1645 1.1688 1.1739 1.1790 1.1842 1.1890 1.1939 1.1991 1.2037
150 1.1598 1.1639 1.1689 1.1738 1.1790 1.1837 1.1885 1.1934 1.1978
160 1.1552 1.1591 1.1641 1.1689 1.1739 1.1785 1.1832 1.1881 1.1923
170 1.1508 1.1546 1.1595 1.1642 1.1690 1.1736 1.1782 1.1830 1.1871
180 1.1467 1.1503 1.1549 1.1597 1.1645 1.1687 1.1734 1.1781 1.1820
190 1.1426 1.1461 1.1507 1.1553 1.1601 1.1642 1.1688 1.1734 1.1773
200 1.1387 1.1420 1.1467 1.1511 1.1559 1.1598 1.1644 1.1687 1.1727
_____________________________________________________________________________
continue E-P/84w(1)
_____________________________________________________________________________
P/MPa T/K
513.39 523.53 533.36 543.24
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3618 1.3721 1.3830 1.3939
10 1.3404 1.3494 1.3588 1.3683
20 1.3218 1.3299 1.3384 1.3468
30 1.3067 1.3140 1.3218 1.3293
40 1.2934 1.3002 1.3074 1.3144
50 1.2816 1.2879 1.2947 1.3013
60 1.2708 1.2771 1.2833 1.2897
70 1.2607 1.2670 1.2731 1.2790
80 1.2517 1.2574 1.2636 1.2693
90 1.2435 1.2489 1.2543 1.2603
100 1.2357 1.2410 1.2462 1.2520
110 1.2285 1.2335 1.2385 1.2437
120 1.2216 1.2265 1.2314 1.2364
130 1.2150 1.2198 1.2246 1.2294
140 1.2089 1.2136 1.2181 1.2229
150 1.2031 1.2076 1.2119 1.2167
160 1.1974 1.2019 1.2062 1.2106
170 1.1920 1.1964 1.2006 1.2051
180 1.1868 1.1912 1.1952 1.1996
190 1.1818 1.1862 1.1902 1.1944
200 1.1771 1.1814 1.1853 1.1894
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): E-P/84w(2) 95ZOL
_____________________________________________________________________________
P/MPa T/K
387.65 398.15 408.55 418.65 429.45 440.05 450.75 461.15 471.65
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2480 1.2572 1.2666 1.2757 1.2857 1.2961 1.3063 1.3162 1.3267
20 1.2286 1.2365 1.2448 1.2528 1.2613 1.2704 1.2785 1.2875 1.2961
40 1.2123 1.2193 1.2264 1.2338 1.2414 1.2493 1.2567 1.2644 1.2718
60 1.1980 1.2042 1.2108 1.2179 1.2459 1.2316 1.2383 1.2451 1.2521
80 1.1849 1.1911 1.1972 1.2035 1.2099 1.2165 1.2226 1.2291 1.2353
100 1.1738 1.1795 1.1852 1.1911 1.1971 1.2032 1.2089 1.2148 1.2207
120 1.1634 1.1688 1.1743 1.1799 1.1855 1.1912 1.1965 1.2021 1.2078
140 1.1539 1.1591 1.1643 1.1695 1.1748 1.1803 1.1853 1.1905 1.1958
160 1.1452 1.1501 1.1550 1.1600 1.1654 1.1704 1.1750 1.1801 1.1851
180 1.1371 1.1418 1.1464 1.1515 1.1562 1.1610 1.1655 1.1705 1.1752
200 1.1295 1.1341 1.1387 1.1433 1.1480 1.1524 1.1569 1.1613 1.1659
_____________________________________________________________________________
continue E-P/84w(2)
_____________________________________________________________________________
P/MPa T/K
481.45 492.35 502.45 513.25 523.85 534.45 554.55 565.05 575.15
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3365 1.3474 1.3578 1.3700 1.3813 1.3917 1.4149 1.4266 1.4388
20 1.3041 1.3129 1.3216 1.3305 1.3396 1.3486 1.3663 1.3754 1.3847
40 1.2790 1.2868 1.2944 1.3020 1.3097 1.3173 1.3325 1.3399 1.3480
60 1.2586 1.2654 1.2722 1.2790 1.2862 1.2926 1.3060 1.3123 1.3195
80 1.2412 1.2475 1.2538 1.2600 1.2659 1.2723 1.2847 1.2903 1.2964
100 1.2262 1.2321 1.2380 1.2436 1.2491 1.2550 1.2660 1.2715 1.2769
120 1.2129 1.2182 1.2238 1.2290 1.2341 1.2397 1.2499 1.2546 1.2601
140 1.2006 1.2057 1.2112 1.2159 1.2207 1.2258 1.2354 1.2400 1.2449
160 1.1896 1.1945 1.1994 1.2040 1.2088 1.2134 1.2229 1.2268 1.2315
180 1.1795 1.1841 1.1889 1.1934 1.1976 1.2021 1.2108 1.2147 1.2193
200 1.1704 1.1748 1.1792 1.1833 1.1874 1.1918 1.2001 1.2038 1.2081
_____________________________________________________________________________
6. PVT Data 397
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
422.53 432.68 442.81 452.84 463.23 472.84 482.90 492.87 502.57
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2759 1.2855 1.2946 1.3042 1.3154 1.3243 1.3341 1.3441 1.3543
10 1.2619 1.2706 1.2790 1.2877 1.2975 1.3056 1.3147 1.3235 1.3325
20 1.2493 1.2569 1.2647 1.2728 1.2812 1.2893 1.2975 1.3055 1.3135
30 1.2387 1.2461 1.2534 1.2607 1.2688 1.2758 1.2838 1.2912 1.2985
40 1.2292 1.2361 1.2430 1.2500 1.2576 1.2641 1.2714 1.2785 1.2854
50 1.2207 1.2270 1.2339 1.2404 1.2476 1.2538 1.2607 1.2669 1.2741
60 1.2129 1.2189 1.2253 1.2317 1.2383 1.2443 1.2509 1.2568 1.2631
70 1.2056 1.2113 1.2176 1.2237 1.2299 1.2358 1.2421 1.2478 1.2538
80 1.1989 1.2043 1.2104 1.2162 1.2222 1.2279 1.2339 1.2393 1.2452
90 1.1927 1.1977 1.2036 1.2091 1.2149 1.2206 1.2263 1.2317 1.2373
100 1.1866 1.1915 1.1972 1.2027 1.2083 1.2137 1.2193 1.2244 1.2297
110 1.1808 1.1856 1.1911 1.1965 1.2017 1.2072 1.2125 1.2176 1.2227
120 1.1754 1.1800 1.1852 1.1907 1.1957 1.2009 1.2063 1.2111 1.2162
130 1.1702 1.1749 1.1799 1.1852 1.1899 1.1952 1.2003 1.2050 1.2099
140 1.1653 1.1696 1.1747 1.1799 1.1845 1.1896 1.1945 1.1991 1.2040
150 1.1606 1.1647 1.1697 1.1747 1.1791 1.1843 1.1891 1.1936 1.1982
160 1.1561 1.1601 1.1649 1.1698 1.1742 1.1792 1.1838 1.1883 1.1928
170 1.1517 1.1555 1.1601 1.1651 1.1692 1.1743 1.1787 1.1832 1.1877
180 1.1475 1.1513 1.1557 1.1607 1.1647 1.1696 1.1739 1.1783 1.1826
190 1.1435 1.1472 1.1515 1.1564 1.1601 1.1651 1.1693 1.1736 1.1779
200 1.1395 1.1431 1.1474 1.1522 1.1559 1.1609 1.1650 1.1691 1.1733
_____________________________________________________________________________
continue E-P/96w
_____________________________________________________________________________
P/MPa T/K
512.93 522.96 532.67
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.3651 1.3756 1.3864
10 1.3419 1.3510 1.3604
20 1.3219 1.3300 1.3384
30 1.3064 1.3137 1.3213
40 1.2927 1.2996 1.3067
50 1.2808 1.2873 1.2940
60 1.2701 1.2762 1.2827
70 1.2599 1.2662 1.2722
80 1.2510 1.2564 1.2628
_____________________________________________________________________________
continue
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
512.93 522.96 532.67
Vspez/cm3g−1
_____________________________________________________________________________
90 1.2429 1.2481 1.2536
100 1.2352 1.2402 1.2457
110 1.2280 1.2328 1.2380
120 1.2213 1.2259 1.2309
130 1.2148 1.2193 1.2241
140 1.2088 1.2133 1.2178
150 1.2031 1.2073 1.2119
160 1.1975 1.2017 1.2061
170 1.1922 1.1962 1.2006
180 1.1870 1.1910 1.1952
190 1.1823 1.1860 1.1903
200 1.1775 1.1813 1.1854
_____________________________________________________________________________
copolymer (B): E-P/? 73RAO
_____________________________________________________________________________
P/atm T/K
413.15 448.15 483.15 523.15
Vspez/cm3g−1
_____________________________________________________________________________
1 1.2758 1.2992 1.3281 1.3663
79 1.2722 1.2936 1.3197 1.3512
159 1.2655 1.2855 1.3099 1.3389
232 1.2594 1.2775 1.3008 1.3279
316 1.2506 1.2677 1.2902 1.3153
474 1.2353 1.2531 1.2737 1.2953
618 1.2258 1.2433 1.2632 1.2847
_____________________________________________________________________________

_____________________________________________________________________________
with C = 0.0894 and θ = T/K − 273.15
_____________________________________________________________________________
_____________________________________________________________________________
E-P/50w 1.2291 + 5.799 10−5θ + 1.964 10−6θ 2 487.0 exp(−8.103 10−3θ )
_____________________________________________________________________________
6. PVT Data 399
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and styrene
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
Ethylene/styrene copolymer
1.7 mol% styrene E-S/02x 403-473 0.1-170 96XUY
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-S/02x 175000 455000 synthesized in the laboratory
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-S/02x 96XUY

_____________________________________________________________________________
P/MPa T/K
403.15 413.15 423.15 433.15 443.15 453.15 463.15 473.15
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2103 1.2188 1.2272 1.2363 1.2451 1.2546 1.2653 1.2752
10 1.2012 1.2092 1.2171 1.2256 1.2336 1.2423 1.2514 1.2604
20 1.2001 1.2075 1.2153 1.2228 1.2307 1.2383 1.2471
30 1.1919 1.1989 1.2065 1.2133 1.2207 1.2280 1.2353
40 1.1844 1.1912 1.1983 1.2048 1.2118 1.2188 1.2251
50 1.1776 1.1840 1.1908 1.1970 1.2036 1.2102 1.2160
60 1.1712 1.1772 1.1837 1.1898 1.1961 1.2023 1.2076
70 1.1708 1.1771 1.1830 1.1887 1.1949 1.1999
80 1.1649 1.1709 1.1766 1.1821 1.1879 1.1927
90 1.1590 1.1648 1.1705 1.1756 1.1813 1.1859
100 1.1534 1.1591 1.1646 1.1695 1.1751 1.1794
110 1.1535 1.1591 1.1638 1.1691 1.1734
120 1.1482 1.1536 1.1583 1.1635 1.1675
130 1.1433 1.1486 1.1531 1.1582 1.1619
140 1.1385 1.1436 1.1480 1.1528 1.1566
150 1.1390 1.1432 1.1479 1.1516
160 1.1348 1.1387 1.1432 1.1467
170 1.1305 1.1343 1.1388 1.1422
_____________________________________________________________________________

_____________________________________________________________________________
P/MPa T/K
403.15 413.15 423.15 433.15 443.15 453.15 463.15 473.15
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.1956 1.2041 1.2122 1.2216 1.2298 1.2394 1.2489 1.2628
10 1.1864 1.1941 1.2021 1.2106 1.2183 1.2268 1.2355 1.2473
20 1.1775 1.1847 1.1923 1.2001 1.2076 1.2151 1.2232 1.2335
30 1.1697 1.1765 1.1837 1.1911 1.1981 1.2052 1.2125 1.2210
40 1.1625 1.1690 1.1760 1.1831 1.1896 1.1961 1.2033 1.2107
50 1.1560 1.1620 1.1688 1.1755 1.1817 1.1880 1.1946 1.2011
60 1.1498 1.1557 1.1619 1.1685 1.1744 1.1804 1.1866 1.1925
70 1.1437 1.1495 1.1556 1.1620 1.1676 1.1732 1.1795 1.1844
80 1.1437 1.1494 1.1557 1.1609 1.1666 1.1723 1.1770
_____________________________________________________________________________
continue
6. PVT Data 401
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
403.15 413.15 423.15 433.15 443.15 453.15 463.15 473.15
3 −1
Vspez/cm g
_____________________________________________________________________________
90 1.1382 1.1436 1.1498 1.1547 1.1600 1.1658 1.1700
100 1.1329 1.1383 1.1443 1.1488 1.1540 1.1594 1.1633
110 1.1278 1.1328 1.1389 1.1431 1.1483 1.1534 1.1570
120 1.1229 1.1277 1.1336 1.1377 1.1427 1.1477 1.1512
130 1.1228 1.1286 1.1326 1.1375 1.1423 1.1457
140 1.1180 1.1239 1.1278 1.1325 1.1372 1.1403
150 1.1136 1.1192 1.1229 1.1277 1.1323 1.1351
160 1.1151 1.1184 1.1231 1.1276 1.1303
170 1.1108 1.1141 1.1186 1.1230 1.1256
180 1.1070 1.1102 1.1146 1.1187 1.1211
190 1.1063 1.1105 1.1146 1.1170
200 1.1027 1.1068 1.1108 1.1131
_____________________________________________________________________________

_____________________________________________________________________________
P/MPa T/K
403.15 413.15 423.15 433.15 443.15 453.15 463.15 473.15
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.1696 1.1771 1.1849 1.1929 1.2008 1.2088 1.2173 1.2272
10 1.1611 1.1682 1.1756 1.1829 1.1901 1.1974 1.2052 1.2139
20 1.1529 1.1596 1.1664 1.1734 1.1801 1.1866 1.1938 1.2021
30 1.1456 1.1522 1.1587 1.1654 1.1715 1.1776 1.1847 1.1918
40 1.1393 1.1457 1.1517 1.1581 1.1638 1.1696 1.1761 1.1827
50 1.1334 1.1393 1.1453 1.1515 1.1568 1.1623 1.1683 1.1743
60 1.1276 1.1335 1.1393 1.1452 1.1503 1.1556 1.1613 1.1667
70 1.1224 1.1281 1.1334 1.1391 1.1443 1.1492 1.1545 1.1596
80 1.1173 1.1229 1.1281 1.1334 1.1382 1.1431 1.1484 1.1530
90 1.1124 1.1178 1.1227 1.1281 1.1326 1.1373 1.1424 1.1466
100 1.1076 1.1131 1.1176 1.1230 1.1274 1.1318 1.1367 1.1410
110 1.1082 1.1129 1.1179 1.1221 1.1266 1.1315 1.1353
120 1.1039 1.1082 1.1132 1.1174 1.1214 1.1263 1.1300
130 1.0997 1.1037 1.1087 1.1128 1.1166 1.1214 1.1249
140 1.0955 1.0996 1.1045 1.1083 1.1120 1.1166 1.1201
150 1.0915 1.0955 1.1003 1.1040 1.1076 1.1122 1.1155
160 1.0914 1.0963 1.0998 1.1034 1.1078 1.1111
170 1.0878 1.0923 1.0959 1.0994 1.1036 1.1069
180 1.0841 1.0888 1.0921 1.0955 1.0997 1.1028
190 1.0808 1.0853 1.0888 1.0920 1.0960 1.0992
200 1.0778 1.0821 1.0852 1.0887 1.0926 1.0956
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
403.15 413.15 423.15 433.15 443.15 453.15 463.15 473.15
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.1220 1.1294 1.1368 1.1449 1.1526 1.1606 1.1690 1.1787
10 1.1139 1.1208 1.1279 1.1353 1.1427 1.1501 1.1576 1.1661
20 1.1062 1.1126 1.1192 1.1261 1.1331 1.1401 1.1470 1.1543
30 1.0992 1.1053 1.1117 1.1183 1.1251 1.1316 1.1380 1.1449
40 1.0931 1.0991 1.1051 1.1112 1.1178 1.1239 1.1301 1.1364
50 1.0874 1.0931 1.0988 1.1047 1.1111 1.1169 1.1227 1.1287
60 1.0820 1.0875 1.0931 1.0986 1.1047 1.1103 1.1159 1.1215
70 1.0769 1.0821 1.0874 1.0931 1.0988 1.1041 1.1096 1.1148
80 1.0720 1.0771 1.0822 1.0876 1.0932 1.0983 1.1035 1.1086
90 1.0673 1.0723 1.0773 1.0824 1.0878 1.0927 1.0978 1.1026
100 1.0628 1.0676 1.0725 1.0773 1.0826 1.0873 1.0923 1.0969
110 1.0584 1.0631 1.0679 1.0725 1.0777 1.0823 1.0872 1.0916
120 1.0543 1.0589 1.0635 1.0680 1.0730 1.0774 1.0823 1.0865
130 1.0503 1.0548 1.0593 1.0636 1.0685 1.0728 1.0775 1.0816
140 1.0464 1.0507 1.0551 1.0595 1.0642 1.0684 1.0730 1.0769
150 1.0428 1.0471 1.0513 1.0554 1.0601 1.0641 1.0686 1.0725
160 1.0391 1.0433 1.0475 1.0516 1.0560 1.0601 1.0644 1.0681
170 1.0356 1.0398 1.0439 1.0479 1.0523 1.0561 1.0604 1.0641
180 1.0324 1.0364 1.0405 1.0444 1.0486 1.0525 1.0566 1.0602
190 1.0293 1.0333 1.0372 1.0410 1.0451 1.0489 1.0530 1.0565
200 1.0262 1.0302 1.0341 1.0379 1.0418 1.0456 1.0496 1.0531
_____________________________________________________________________________

_____________________________________________________________________________
P/MPa T/K
353.15 363.15 373.15 383.15 393.15 403.15 413.15 423.15 433.15
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.0512 1.0573 1.0636 1.0700 1.0766 1.0832 1.0903 1.0973 1.1051
10 1.0458 1.0516 1.0576 1.0637 1.0699 1.0761 1.0828 1.0573 1.0626
20 1.0404 1.0459 1.0515 1.0574 1.0633 1.0692 1.0756 1.0895 1.0966
30 1.0353 1.0406 1.0461 1.0517 1.0574 1.0630 1.0690 1.0817 1.0883
40 1.0306 1.0358 1.0409 1.0464 1.0519 1.0572 1.0629 1.0749 1.0812
50 1.0261 1.0312 1.0362 1.0415 1.0466 1.0517 1.0574 1.0685 1.0746
60 1.0219 1.0267 1.0316 1.0367 1.0418 1.0467 1.0521 1.0627 1.0684
70 1.0178 1.0226 1.0271 1.0322 1.0371 1.0418 1.0471 1.0520 1.0571
80 1.0139 1.0184 1.0230 1.0279 1.0326 1.0372 1.0423 1.0471 1.0521
_____________________________________________________________________________
continue
6. PVT Data 403
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
353.15 363.15 373.15 383.15 393.15 403.15 413.15 423.15 433.15
Vspez/cm3g−1
_____________________________________________________________________________
90 1.0102 1.0145 1.0190 1.0238 1.0283 1.0329 1.0377 1.0424 1.0471
100 1.0066 1.0109 1.0151 1.0198 1.0241 1.0287 1.0332 1.0378 1.0423
110 1.0031 1.0072 1.0114 1.0159 1.0200 1.0245 1.0290 1.0335 1.0380
120 0.9997 1.0036 1.0077 1.0122 1.0162 1.0205 1.0249 1.0293 1.0335
130 0.9964 1.0003 1.0042 1.0086 1.0125 1.0167 1.0209 1.0254 1.0293
140 0.9932 0.9970 1.0009 1.0051 1.0089 1.0130 1.0171 1.0214 1.0253
150 0.9901 0.9939 0.9976 1.0018 1.0055 1.0096 1.0136 1.0177 1.0215
160 0.9870 0.9909 0.9944 0.9987 1.0023 1.0063 1.0101 1.0141 1.0178
170 0.9841 0.9879 0.9914 0.9956 0.9991 1.0030 1.0066 1.0107 1.0144
180 0.9812 0.9851 0.9885 0.9927 0.9961 0.9999 1.0036 1.0074 1.0110
190 0.9784 0.9824 0.9857 0.9898 0.9932 0.9969 1.0005 1.0043 1.0078
200 0.9759 0.9798 0.9831 0.9871 0.9904 0.9940 0.9976 1.0014 1.0047
_____________________________________________________________________________
continue E-S/22x
_____________________________________________________________________________
P/MPa T/K
443.15 453.15 463.15 473.15
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.1126 1.1201 1.1274 1.1348
10 1.1037 1.1106 1.1175 1.1243
20 1.0951 1.1015 1.1082 1.1144
30 1.0876 1.0936 1.0999 1.1058
40 1.0808 1.0864 1.0923 1.0981
50 1.0744 1.0797 1.0854 1.0909
60 1.0684 1.0736 1.0790 1.0843
70 1.0627 1.0677 1.0730 1.0782
80 1.0574 1.0622 1.0672 1.0721
90 1.0522 1.0569 1.0618 1.0666
100 1.0473 1.0518 1.0566 1.0613
110 1.0427 1.0470 1.0517 1.0563
120 1.0382 1.0425 1.0470 1.0514
130 1.0338 1.0380 1.0426 1.0468
140 1.0298 1.0339 1.0383 1.0424
150 1.0258 1.0298 1.0341 1.0381
160 1.0221 1.0259 1.0302 1.0340
170 1.0184 1.0221 1.0262 1.0301
180 1.0149 1.0185 1.0226 1.0264
190 1.0117 1.0151 1.0191 1.0229
200 1.0086 1.0119 1.0159 1.0196
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
343.15 353.15 363.15 373.15 383.15 393.15 403.15 413.15 423.15
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.0319 1.0378 1.0437 1.0499 1.0559 1.0624 1.0691 1.0760 1.0829
10 1.0268 1.0324 1.0382 1.0440 1.0498 1.0559 1.0623 1.0687 1.0753
20 1.0218 1.0270 1.0327 1.0381 1.0435 1.0493 1.0556 1.0616 1.0677
30 1.0172 1.0221 1.0277 1.0328 1.0382 1.0436 1.0497 1.0554 1.0614
40 1.0128 1.0176 1.0229 1.0277 1.0332 1.0382 1.0441 1.0496 1.0551
50 1.0087 1.0132 1.0184 1.0231 1.0283 1.0333 1.0387 1.0442 1.0497
60 1.0047 1.0092 1.0142 1.0187 1.0238 1.0284 1.0338 1.0391 1.0443
70 1.0007 1.0052 1.0099 1.0145 1.0193 1.0238 1.0290 1.0341 1.0391
80 0.9969 1.0015 1.0060 1.0103 1.0151 1.0193 1.0245 1.0294 1.0343
90 0.9934 0.9977 1.0022 1.0063 1.0110 1.0151 1.0201 1.0250 1.0297
100 0.9898 0.9940 0.9984 1.0024 1.0068 1.0110 1.0157 1.0206 1.0251
110 0.9864 0.9904 0.9950 0.9987 1.0032 1.0069 1.0117 1.0164 1.0208
120 0.9830 0.9871 0.9915 0.9950 0.9993 1.0031 1.0076 1.0123 1.0168
130 0.9798 0.9837 0.9881 0.9916 0.9958 0.9995 1.0039 1.0084 1.0127
140 0.9767 0.9806 0.9847 0.9881 0.9923 0.9958 1.0002 1.0047 1.0090
150 0.9737 0.9774 0.9816 0.9850 0.9889 0.9923 0.9965 1.0011 1.0051
160 0.9708 0.9745 0.9785 0.9818 0.9858 0.9889 0.9933 0.9977 1.0015
170 0.9680 0.9717 0.9757 0.9787 0.9827 0.9858 0.9899 0.9944 0.9981
180 0.9654 0.9689 0.9730 0.9759 0.9797 0.9829 0.9869 0.9911 0.9949
190 0.9628 0.9663 0.9702 0.9731 0.9769 0.9799 0.9839 0.9881 0.9918
200 0.9604 0.9638 0.9676 0.9705 0.9742 0.9772 0.9812 0.9853 0.9888
_____________________________________________________________________________
continue E-S/29x
_____________________________________________________________________________
P/MPa T/K
433.15 443.15 453.15 463.15 473.15
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.0899 1.0972 1.1041 1.1126 1.1225
10 1.0819 1.0885 1.0952 1.1026 1.1104
20 1.0740 1.0802 1.0866 1.0930 1.0995
30 1.0672 1.0729 1.0792 1.0851 1.0898
40 1.0609 1.0665 1.0722 1.0779 1.0811
50 1.0551 1.0604 1.0658 1.0714 1.0732
60 1.0497 1.0547 1.0599 1.0652 1.0663
70 1.0443 1.0492 1.0542 1.0593 1.0598
80 1.0392 1.0441 1.0487 1.0537 1.0540
_____________________________________________________________________________
continue
6. PVT Data 405
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/MPa T/K
433.15 443.15 453.15 463.15 473.15
3 −1
Vspez/cm g
_____________________________________________________________________________
90 1.0345 1.0392 1.0435 1.0484 1.0485
100 1.0298 1.0345 1.0385 1.0431 1.0434
110 1.0253 1.0299 1.0338 1.0383 1.0385
120 1.0210 1.0254 1.0293 1.0329 1.0366
130 1.0168 1.0212 1.0250 1.0285 1.0320
140 1.0128 1.0171 1.0208 1.0248 1.0251
150 1.0092 1.0131 1.0169 1.0205 1.0241
160 1.0053 1.0095 1.0130 1.0160 1.0191
170 1.0019 1.0058 1.0094 1.0126 1.0158
180 0.9986 1.0025 1.0058 1.0086 1.0113
190 0.9954 0.9992 1.0025 1.0055 1.0084
200 0.9923 0.9962 0.9994 1.0021 1.0049
_____________________________________________________________________________

_____________________________________________________________________________
with C = 0.0894 and θ = T/K − 273.15
_____________________________________________________________________________
_____________________________________________________________________________
E-S/02x 1.17640 − 6.3389 10−4T + 1.7815 10−6T2 278.02 exp(−6.449 10−3θ )
E-S/04x 1.36913 − 1.5928 10−3T + 2.8859 10−6T2 281.50 exp(−6.694 10−3θ )
E-S/06x 1.00930 + 4.2123 10−5T + 8.8038 10−7T2 258.51 exp(−5.502 10−3θ )
E-S/14x 0.98570 − 5.9468 10−5T + 9.8460 10−7T2 240.72 exp(−5.059 10−3θ )
E-S/22x 0.93220 + 6.4243 10−5T + 7.7144 10−7T2 241.50 exp(−4.732 10−3θ )
E-S/22x 0.96947 − 1.8184 10−4T + 1.0626 10−6T2 250.23 exp(−4.948 10−3θ )
_____________________________________________________________________________
Comments: Tait equation parameters - this work

____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
9 wt% vinyl acetate E-VA/09w 393-473 10-80 90BU1
14 wt% vinyl acetate E-VA/14w 393-535 0.1-200 95ZOL
18 wt% vinyl acetate E-VA/18w(1) 385-517 0.1-177 86ZOL
20 wt% vinyl acetate E-VA/20w 353-422 5-40 90BU1
28 wt% vinyl acetate E-VA/28w(B) 373-473 10-80 90BU1
28 wt% vinyl acetate E-VA/28w(B) 373-473 10-80 90BU2
28 wt% vinyl acetate E-VA/28w(Z1) 367-517 0.1-177 86ZOL
28 wt% vinyl acetate E-VA/28w(Z2) 377-519 0.1-200 95ZOL
87.1 wt% vinyl acetate E-VA/87w 303-443 0.1 90CIM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-VA/09w 6500 EVA-1-wax, BASF, Ger.
E-VA/14w Sci. Polym. Products
E-VA/18w(1) Sci. Polym. Products, catalog #244
E-VA/18w(2) Sci. Polym. Products
E-VA/20w C-Elvax 210, DSM, Netherlands
E-VA/28w(B) 6000 Dodiflow 2846-1, Hoechst, Ger.
E-VA/28w(Z1) Sci. Polym. Products, catalog #316
E-VA/28w(Z2) Sci. Polym. Products
E-VA/33w Sci. Polym. Products
_____________________________________________________________________________
continue
6. PVT Data 407
____________________________________________________________________________________
continue
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-VA/65w no data
E-VA/87w 67000 200000 Kuraray Co. (Japan)
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-VA/09w 90BU1
_____________________________________________________________________________
P/MPa T/K
393.15 403.15 413.15 423.15 433.15 443.15 453.15 463.15 473.15
Vspez/cm3g−1
_____________________________________________________________________________
10 1.2201 1.2283 1.2374 1.2474 1.2592 1.2691 1.2785 1.2896 1.2984
20 1.2100 1.2175 1.2255 1.2354 1.2462 1.2560 1.2654 1.2751 1.2824
30 1.2014 1.2080 1.2155 1.2250 1.2354 1.2447 1.2534 1.2627 1.2688
40 1.1935 1.2002 1.2061 1.2151 1.2257 1.2347 1.2426 1.2518 1.2565
50 1.1853 1.1923 1.1979 1.2069 1.2165 1.2253 1.2341 1.2409 1.2467
60 1.1782 1.1849 1.1905 1.1995 1.2078 1.2164 1.2248 1.2310 1.2368
70 1.1722 1.1784 1.1844 1.1925 1.2007 1.2094 1.2166 1.2225 1.2289
80 1.1667 1.1729 1.1781 1.1864 1.1943 1.2028 1.2105 1.2155 1.2218
_____________________________________________________________________________
copolymer (B): E-VA/20w 90BU1

_____________________________________________________________________________
P/MPa T/K
353.9 363.5 373.8 383.3 393.0 402.7 412.3 421.9
Vspez/cm3g−1
_____________________________________________________________________________
5 1.1273 1.1338 1.1408 1.1472 1.1538 1.1604 1.1669 1.1734
10 1.1229 1.1292 1.1359 1.1422 1.1485 1.1549 1.1612 1.1675
15 1.1184 1.1245 1.1311 1.1371 1.1433 1.1494 1.1555 1.1616
20 1.1140 1.1199 1.1262 1.1320 1.1380 1.1439 1.1498 1.1557
25 1.1096 1.1153 1.1214 1.1270 1.1327 1.1385 1.1441 1.1498
30 1.1051 1.1106 1.1165 1.1229 1.1275 1.1330 1.1385 1.1439
35 1.1007 1.1059 1.1116 − 1.1222 1.1275 1.1328 1.1381
40 1.0963 1.1013 1.1068 1.1118 1.1169 1.1220 1.1271 1.1322
_____________________________________________________________________________
____________________________________________________________________________________
copolymer (B): E-VA/14w 95ZOL
_____________________________________________________________________________
P/MPa T/K
393.75 401.75 410.05 418.65 426.35 435.15 442.95 451.95 459.15
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2055 1.2128 1.2199 1.2278 1.2351 1.2436 1.2507 1.2589 1.2664
20 1.1877 1.1939 1.2003 1.2071 1.2138 1.2208 1.2270 1.2339 1.2403
40 1.1724 1.1779 1.1837 1.1899 1.1959 1.2021 1.2079 1.2140 1.2199
60 1.1586 1.1640 1.1693 1.1749 1.1807 1.1861 1.1915 1.1968 1.2026
80 1.1466 1.1516 1.1565 1.1617 1.1671 1.1721 1.1773 1.1821 1.1875
100 1.1360 1.1407 1.1452 1.1501 1.1552 1.1599 1.1647 1.1694 1.1744
120 1.1261 1.1305 1.1350 1.1395 1.1446 1.1488 1.1533 1.1575 1.1625
140 1.1169 1.1214 1.1257 1.1300 1.1344 1.1384 1.1430 1.1467 1.1516
160 1.1086 1.1126 1.1166 1.1209 1.1252 1.1290 1.1332 1.1368 1.1416
180 1.1007 1.1045 1.1084 1.1124 1.1167 1.1203 1.1242 1.1277 1.1323
200 1.0931 1.0972 1.1008 1.1046 1.1089 1.1121 1.1159 1.1193 1.1238
_____________________________________________________________________________
continue E-VA/14w
_____________________________________________________________________________
P/MPa T/K
468.65 477.05 484.95 492.65 501.85 510.25 518.75 527.15 535.25
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2749 1.2833 1.2913 1.2999 1.3089 1.3175 1.3272 1.3361 1.3461
20 1.2476 1.2548 1.2615 1.2682 1.2761 1.2831 1.2906 1.2984 1.3067
40 1.2260 1.2323 1.2386 1.2444 1.2507 1.2570 1.2636 1.2703 1.2775
60 1.2078 1.2135 1.2192 1.2247 1.2302 1.2362 1.2417 1.2477 1.2546
80 1.1924 1.1975 1.2029 1.2079 1.2129 1.2182 1.2235 1.2291 1.2349
100 1.1786 1.1835 1.1886 1.1935 1.1979 1.2027 1.2077 1.2127 1.2184
120 1.1665 1.1709 1.1756 1.1803 1.1845 1.1890 1.1936 1.1983 1.2036
140 1.1552 1.1596 1.1638 1.1683 1.1723 1.1764 1.1808 1.1853 1.1902
160 1.1449 1.1490 1.1533 1.1575 1.1611 1.1652 1.1693 1.1735 1.1782
180 1.1356 1.1394 1.1435 1.1475 1.1511 1.1548 1.1589 1.1628 1.1673
200 1.1266 1.1306 1.1345 1.1385 1.1415 1.1453 1.1490 1.1528 1.1575
_____________________________________________________________________________
6. PVT Data 409
____________________________________________________________________________________
copolymer (B): E-VA/18w(2) 95ZOL
_____________________________________________________________________________
P/MPa T/K
393.75 402.05 409.45 417.35 426.15 434.15 441.65 449.95 457.65
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2023 1.2091 1.2163 1.2232 1.2313 1.2394 1.2459 1.2538 1.2618
20 1.1844 1.1906 1.1968 1.2033 1.2104 1.2174 1.2233 1.2300 1.2368
40 1.1691 1.1748 1.1806 1.1868 1.1928 1.1993 1.2046 1.2106 1.2166
60 1.1556 1.1611 1.1664 1.1720 1.1776 1.1835 1.1885 1.1942 1.1994
80 1.1436 1.1484 1.1537 1.1589 1.1641 1.1693 1.1744 1.1793 1.1844
100 1.1331 1.1376 1.1427 1.1478 1.1525 1.1575 1.1620 1.1667 1.1714
120 1.1233 1.1276 1.1325 1.1371 1.1417 1.1464 1.1510 1.1551 1.1596
140 1.1142 1.1183 1.1232 1.1275 1.1317 1.1361 1.1403 1.1446 1.1488
160 1.1058 1.1098 1.1142 1.1187 1.1226 1.1269 1.1308 1.1347 1.1389
180 1.0980 1.1018 1.1061 1.1103 1.1142 1.1181 1.1220 1.1257 1.1296
200 1.0905 1.0943 1.0985 1.1025 1.1062 1.1099 1.1137 1.1173 1.1210
_____________________________________________________________________________
continue E-VA/18w(2)
_____________________________________________________________________________
P/MPa T/K
466.45 474.15 483.85 491.25 499.85 507.95 515.45 523.85
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2699 1.2782 1.2882 1.2943 1.3035 1.3120 1.3196 1.3288
20 1.2437 1.2503 1.2579 1.2641 1.2715 1.2786 1.2851 1.2926
40 1.2225 1.2285 1.2349 1.2406 1.2470 1.2531 1.2587 1.2651
60 1.2047 1.2101 1.2158 1.2211 1.2267 1.2325 1.2372 1.2431
80 1.1893 1.1944 1.1993 1.2043 1.2094 1.2145 1.2192 1.2243
100 1.1758 1.1808 1.1853 1.1900 1.1946 1.1993 1.2036 1.2087
120 1.1638 1.1684 1.1724 1.1771 1.1814 1.1857 1.1897 1.1942
140 1.1526 1.1570 1.1609 1.1651 1.1691 1.1732 1.1771 1.1815
160 1.1425 1.1467 1.1504 1.1543 1.1581 1.1623 1.1657 1.1696
180 1.1331 1.1372 1.1404 1.1446 1.1480 1.1521 1.1552 1.1590
200 1.1246 1.1283 1.1313 1.1351 1.1386 1.1422 1.1458 1.1494
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
P/kg cm−2 T/K
385.55 393.85 403.15 412.55 421.45 430.75 439.15 447.85 457.65
Vspez/cm3g−1
_____________________________________________________________________________
1 1.2063 1.2142 1.2204 1.2286 1.2372 1.2440 1.2519 1.2578 1.2674
100 1.1977 1.2045 1.2114 1.2189 1.2263 1.2329 1.2398 1.2464 1.2548
200 1.1898 1.1953 1.2024 1.2094 1.2160 1.2224 1.2293 1.2354 1.2429
300 1.1818 1.1870 1.1939 1.2006 1.2071 1.2131 1.2194 1.2253 1.2328
400 1.1746 1.1797 1.1863 1.1926 1.1985 1.2046 1.2105 1.2163 1.2231
500 1.1676 1.1727 1.1786 1.1848 1.1907 1.1965 1.2023 1.2075 1.2142
600 1.1611 1.1662 1.1719 1.1778 1.1833 1.1889 1.1944 1.1996 1.2058
700 1.1554 1.1599 1.1655 1.1716 1.1767 1.1820 1.1872 1.1924 1.1984
800 1.1494 1.1540 1.1592 1.1653 1.1702 1.1751 1.1803 1.1848 1.1913
900 1.1441 1.1485 1.1536 1.1592 1.1638 1.1689 1.1740 1.1783 1.1845
1000 1.1388 1.1432 1.1481 1.1535 1.1580 1.1630 1.1679 1.1722 1.1783
1100 1.1340 1.1380 1.1431 1.1482 1.1526 1.1573 1.1618 1.1666 1.1721
1200 1.1292 1.1332 1.1379 1.1432 1.1474 1.1520 1.1562 1.1609 1.1665
1300 1.1246 1.1285 1.1332 1.1381 1.1425 1.1469 1.1512 1.1557 1.1611
1400 1.1202 1.1242 1.1285 1.1336 1.1375 1.1419 1.1464 1.1505 1.1557
1500 1.1161 1.1196 1.1242 1.1290 1.1329 1.1372 1.1416 1.1457 1.1506
1600 1.1122 1.1155 1.1201 1.1243 1.1287 1.1326 1.1369 1.1410 1.1456
1700 1.1082 1.1119 1.1159 1.1207 1.1243 1.1286 1.1325 1.1362 1.1414
1800 1.1042 1.1078 1.1120 1.1165 1.1203 1.1240 1.1285 1.1322 1.1370
_____________________________________________________________________________
_____________________________________________________________________________
P/kg cm−2 T/K
466.25 475.35 483.35 492.45 500.75 508.85 517.15
3 −1
Vspez/cm g
_____________________________________________________________________________
1 1.2748 1.2819 1.2893 1.2977 1.3083 1.3132 1.3208
100 1.2617 1.2684 1.2761 1.2831 1.2905 1.2972 1.3048
200 1.2496 1.2558 1.2624 1.2698 1.2759 1.2824 1.2900
300 1.2383 1.2447 1.2510 1.2580 1.2634 1.2694 1.2762
400 1.2290 1.2345 1.2405 1.2471 1.2519 1.2581 1.2646
500 1.2198 1.2250 1.2302 1.2371 1.2420 1.2474 1.2533
600 1.2115 1.2163 1.2218 1.2275 1.2326 1.2378 1.2436
700 1.2035 1.2082 1.2136 1.2191 1.2238 1.2287 1.2345
800 1.1962 1.2004 1.2057 1.2109 1.2158 1.2203 1.2260
_____________________________________________________________________________
continue
6. PVT Data 411
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/kg cm−2 T/K
466.25 475.35 483.35 492.45 500.75 508.85 517.15
3 −1
Vspez/cm g
_____________________________________________________________________________
900 1.1892 1.1931 1.1983 1.2033 1.2076 1.2126 1.2182
1000 1.1828 1.1866 1.1918 1.1966 1.2005 1.2053 1.2106
1100 1.1767 1.1800 1.1853 1.1899 1.1938 1.1984 1.2036
1200 1.1705 1.1743 1.1790 1.1839 1.1876 1.1918 1.1969
1300 1.1651 1.1682 1.1732 1.1776 1.1816 1.1859 1.1907
1400 1.1597 1.1636 1.1678 1.1719 1.1759 1.1801 1.1845
1500 1.1542 1.1576 1.1628 1.1663 1.1703 1.1746 1.1791
1600 1.1493 1.1531 1.1573 1.1609 1.1648 1.1689 1.1741
1700 1.1445 1.1482 1.1525 1.1567 1.1599 1.1638 1.1682
1800 1.1402 1.1437 1.1480 1.1517 1.1551 1.1589 1.1630
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
393.85 401.35 409.25 417.75 425.85 432.75 441.65 449.95 457.15
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.1796 1.1866 1.1938 1.2014 1.2089 1.2158 1.2238 1.2314 1.2385
20 1.1622 1.1687 1.1752 1.1816 1.1883 1.1947 1.2015 1.2080 1.2140
40 1.1474 1.1532 1.1590 1.1648 1.1711 1.1764 1.1827 1.1885 1.1939
60 1.1341 1.1395 1.1449 1.1503 1.1557 1.1609 1.1666 1.1719 1.1768
80 1.1220 1.1274 1.1324 1.1373 1.1423 1.1472 1.1524 1.1574 1.1619
100 1.1119 1.1170 1.1216 1.1262 1.1309 1.1356 1.1404 1.1451 1.1493
120 1.1023 1.1070 1.1114 1.1158 1.1203 1.1247 1.1293 1.1338 1.1377
140 1.0935 1.0980 1.1022 1.1064 1.1108 1.1150 1.1191 1.1233 1.1270
160 1.0855 1.0898 1.0937 1.0976 1.1019 1.1058 1.1099 1.1137 1.1174
180 1.0778 1.0819 1.0858 1.0895 1.0934 1.0976 1.1014 1.1052 1.1085
200 1.0707 1.0747 1.0785 1.0821 1.0857 1.0896 1.0933 1.0970 1.1002
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
465.75 474.15 482.55 490.75 499.05 507.25 515.65 523.45 531.75
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2461 1.2547 1.2628 1.2713 1.2802 1.2899 1.2985 1.3075 1.3188
20 1.2206 1.2279 1.2345 1.2415 1.2489 1.2563 1.2638 1.2715 1.2805
40 1.1996 1.2059 1.2120 1.2181 1.2250 1.2309 1.2377 1.2446 1.2524
60 1.1824 1.1877 1.1931 1.1987 1.2046 1.2102 1.2162 1.2222 1.2293
80 1.1667 1.1718 1.1770 1.1821 1.1876 1.1926 1.1980 1.2036 1.2102
100 1.1540 1.1589 1.1634 1.1681 1.1730 1.1779 1.1829 1.1881 1.1941
120 1.1419 1.1464 1.1508 1.1553 1.1598 1.1645 1.1692 1.1741 1.1797
140 1.1310 1.1352 1.1393 1.1436 1.1479 1.1522 1.1567 1.1613 1.1668
160 1.1211 1.1251 1.1291 1.1332 1.1372 1.1413 1.1455 1.1498 1.1551
180 1.1121 1.1162 1.1197 1.1235 1.1274 1.1315 1.1353 1.1395 1.1445
200 1.1037 1.1073 1.1110 1.1148 1.1185 1.1221 1.1259 1.1301 1.1347
_____________________________________________________________________________
_____________________________________________________________________________
P/kg cm−2 T/K
367.45 376.35 385.45 393.85 403.05 412.85 421.45 430.55 439.65
Vspez/cm3g−1
_____________________________________________________________________________
1 1.1648 1.1720 1.1785 1.1872 1.1950 1.2029 1.2097 1.2186 1.2254
100 1.1564 1.1637 1.1701 1.1775 1.1847 1.1926 1.1990 1.2062 1.2136
200 1.1486 1.1555 1.1624 1.1687 1.1754 1.1829 1.1891 1.1956 1.2021
300 1.1414 1.1480 1.1544 1.1608 1.1669 1.1734 1.1801 1.1864 1.1923
400 1.1347 1.1411 1.1475 1.1530 1.1591 1.1657 1.1717 1.1773 1.1834
500 1.1284 1.1344 1.1405 1.1460 1.1519 1.1578 1.1639 1.1695 1.1749
600 1.1224 1.1280 1.1341 1.1396 1.1451 1.1506 1.1564 1.1624 1.1671
700 1.1169 1.1227 1.1280 1.1333 1.1388 1.1442 1.1495 1.1550 1.1598
800 1.1115 1.1170 1.1224 1.1275 1.1325 1.1378 1.1436 1.1484 1.1529
900 1.1063 1.1116 1.1169 1.1217 1.1267 1.1320 1.1369 1.1419 1.1465
1000 1.1015 1.1068 1.1120 1.1165 1.1217 1.1266 1.1315 1.1359 1.1403
1100 1.0970 1.1017 1.1069 1.1113 1.1163 1.1214 1.1261 1.1304 1.1344
1200 1.0924 1.0975 1.1020 1.1067 1.1113 1.1164 1.1208 1.1251 1.1284
1300 1.0884 1.0930 1.0977 1.1023 1.1067 1.1115 1.1157 1.1198 1.1234
1400 1.0841 1.0885 1.0932 1.0974 1.1023 1.1070 1.1110 1.1151 1.1184
1500 1.0799 1.0847 1.0896 1.0933 1.0977 1.1023 1.1063 1.1104 1.1138
1600 1.0763 1.0807 1.0852 1.0889 1.0935 1.0982 1.1017 1.1057 1.1092
1700 1.0724 1.0771 1.0812 1.0851 1.0897 1.0941 1.0977 1.1012 1.1050
1800 1.0689 1.0732 1.0775 1.0814 1.0856 1.0897 1.0936 1.0971 1.1008
_____________________________________________________________________________
6. PVT Data 413
____________________________________________________________________________________
_____________________________________________________________________________
P/kg cm−2 T/K
448.15 457.85 466.45 473.05 482.25 490.65 499.05 507.05 515.55
3 −1
Vspez/cm g
_____________________________________________________________________________
1 1.2325 1.2408 1.2497 1.2568 1.2646 1.2702 1.2773 1.2859 1.2926
100 1.2204 1.2282 1.2356 1.2408 1.2482 1.2547 1.2624 1.2692 1.2754
200 1.2090 1.2163 1.2230 1.2275 1.2345 1.2405 1.2474 1.2543 1.2604
300 1.1988 1.2058 1.2121 1.2161 1.2218 1.2286 1.2348 1.2414 1.2471
400 1.1895 1.1961 1.2019 1.2055 1.2117 1.2175 1.2237 1.2296 1.2350
500 1.1807 1.1870 1.1928 1.1964 1.2022 1.2075 1.2129 1.2189 1.2240
600 1.1727 1.1787 1.1843 1.1873 1.1933 1.1982 1.2036 1.2092 1.2140
700 1.1653 1.1713 1.1764 1.1797 1.1847 1.1898 1.1949 1.2004 1.2048
800 1.1581 1.1638 1.1689 1.1723 1.1769 1.1817 1.1867 1.1918 1.1966
900 1.1514 1.1569 1.1618 1.1651 1.1696 1.1746 1.1791 1.1840 1.1886
1000 1.1451 1.1504 1.1552 1.1583 1.1632 1.1676 1.1722 1.1766 1.1811
1100 1.1392 1.1444 1.1489 1.1523 1.1565 1.1609 1.1653 1.1700 1.1740
1200 1.1335 1.1386 1.1430 1.1462 1.1505 1.1545 1.1591 1.1633 1.1673
1300 1.1283 1.1332 1.1375 1.1405 1.1444 1.1489 1.1531 1.1572 1.1612
1400 1.1229 1.1278 1.1322 1.1349 1.1390 1.1434 1.1472 1.1514 1.1552
1500 1.1181 1.1228 1.1269 1.1294 1.1339 1.1378 1.1417 1.1456 1.1496
1600 1.1135 1.1181 1.1220 1.1245 1.1286 1.1326 1.1364 1.1406 1.1438
1700 1.1088 1.1134 1.1174 1.1199 1.1237 1.1274 1.1315 1.1354 1.1389
1800 1.1046 1.1089 1.1127 1.1156 1.1191 1.1232 1.1265 1.1301 1.1340
_____________________________________________________________________________
copolymer (B): E-VA/28w(Z2) 95ZOL
_____________________________________________________________________________
P/MPa T/K
376.85 385.05 393.65 401.85 410.05 418.55 427.05 434.85 443.65
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.1509 1.1576 1.1647 1.1712 1.1786 1.1895 1.1931 1.2010 1.2089
20 1.1352 1.1413 1.1476 1.1535 1.1599 1.1664 1.1727 1.1796 1.1862
40 1.1215 1.1271 1.1328 1.1382 1.1440 1.1499 1.1555 1.1619 1.1675
60 1.1094 1.1146 1.1197 1.1248 1.1303 1.1355 1.1408 1.1463 1.1516
80 1.0982 1.1031 1.1080 1.1127 1.1177 1.1227 1.1276 1.1328 1.1377
100 1.0888 1.0933 1.0978 1.1024 1.1069 1.1116 1.1163 1.1213 1.1258
120 1.0798 1.0841 1.0884 1.0926 1.0971 1.1015 1.1058 1.1106 1.1147
140 1.0715 1.0757 1.0797 1.0838 1.0878 1.0922 1.0962 1.1007 1.1046
160 1.0637 1.0676 1.0715 1.0755 1.0795 1.0834 1.0874 1.0917 1.0954
180 1.0564 1.0602 1.0641 1.0681 1.0717 1.0756 1.0792 1.0834 1.0868
200 1.0499 1.0534 1.0569 1.0607 1.0644 1.0678 1.0717 1.0757 1.0791
_____________________________________________________________________________
____________________________________________________________________________________
continue E-VA/28w(Z2)
_____________________________________________________________________________
P/MPa T/K
451.85 459.95 468.25 476.35 485.25 493.45 502.05 510.45 518.95
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.2162 1.2244 1.2315 1.2392 1.2486 1.2562 1.2644 1.2733 1.2827
20 1.1926 1.1989 1.2056 1.2123 1.2193 1.2264 1.2331 1.2406 1.2478
40 1.1732 1.1791 1.1849 1.1909 1.1970 1.2029 1.2092 1.2154 1.2221
60 1.1569 1.1621 1.1675 1.1729 1.1784 1.1838 1.1895 1.1953 1.2008
80 1.1427 1.1475 1.1524 1.1575 1.1624 1.1674 1.1725 1.1776 1.1831
100 1.1303 1.1350 1.1395 1.1444 1.1489 1.1535 1.1583 1.1632 1.1680
120 1.1190 1.1233 1.1279 1.1322 1.1365 1.1409 1.1451 1.1499 1.1544
140 1.1087 1.1128 1.1169 1.1211 1.1251 1.1294 1.1336 1.1376 1.1421
160 1.0992 1.1032 1.1071 1.1112 1.1151 1.1190 1.1227 1.1269 1.1312
180 1.0905 1.0945 1.0982 1.1018 1.1056 1.1095 1.1130 1.1169 1.1209
200 1.0824 1.0860 1.0897 1.0933 1.0969 1.1006 1.1039 1.1078 1.1116
_____________________________________________________________________________
copolymer (B): E-VA/28w(Z1) 86ZOL
_____________________________________________________________________________
P/kg cm−2 T/K
367.25 376.75 385.65 393.95 403.25 412.75 421.65 430.45 439.35
Vspez/cm3g−1
_____________________________________________________________________________
1 1.1600 1.1661 1.1744 1.1818 1.1901 1.1973 1.2054 1.2123 1.2201
100 1.1516 1.1580 1.1658 1.1728 1.1797 1.1872 1.1942 1.2013 1.2086
200 1.1440 1.1501 1.1572 1.1642 1.1704 1.1774 1.1845 1.1910 1.1977
300 1.1370 1.1432 1.1498 1.1563 1.1623 1.1689 1.1758 1.1815 1.1883
400 1.1305 1.1363 1.1429 1.1490 1.1547 1.1612 1.1673 1.1733 1.1795
500 1.1245 1.1300 1.1363 1.1421 1.1478 1.1538 1.1598 1.1654 1.1714
600 1.1186 1.1242 1.1300 1.1358 1.1411 1.1469 1.1527 1.1582 1.1638
700 1.1133 1.1180 1.1241 1.1295 1.1349 1.1406 1.1458 1.1515 1.1571
800 1.1077 1.1131 1.1185 1.1241 1.1289 1.1342 1.1394 1.1446 1.1502
900 1.1026 1.1077 1.1133 1.1186 1.1232 1.1287 1.1336 1.1387 1.1442
1000 1.0980 1.1029 1.1083 1.1134 1.1179 1.1233 1.1278 1.1329 1.1382
1100 1.0935 1.0980 1.1036 1.1083 1.1130 1.1179 1.1225 1.1271 1.1325
1200 1.0890 1.0937 1.0988 1.1039 1.1081 1.1131 1.1175 1.1221 1.1272
1300 1.0849 1.0895 1.0946 1.0995 1.1035 1.1080 1.1127 1.1173 1.1222
1400 1.0808 1.0854 1.0904 1.0948 1.0993 1.1038 1.1081 1.1121 1.1173
1500 1.0769 1.0815 1.0863 1.0906 1.0947 1.0994 1.1035 1.1078 1.1126
1600 1.0733 1.0775 1.0823 1.0870 1.0907 1.0952 1.0993 1.1036 1.1082
1700 1.0697 1.0740 1.0786 1.0825 1.0866 1.0911 1.0951 1.0991 1.1036
1800 1.0663 1.0701 1.0752 1.0793 1.0832 1.0875 1.0910 1.0951 1.0999
_____________________________________________________________________________
6. PVT Data 415
____________________________________________________________________________________
continue E-VA/28w(Z1)
_____________________________________________________________________________
P/kg cm−2 T/K
447.55 457.25 465.85 474.75 483.35 492.15 500.75 508.55 517.05
3 −1
Vspez/cm g
_____________________________________________________________________________
1 1.2279 1.2365 1.2426 1.2500 1.2585 1.2663 1.2743 1.2809 1.2900
100 1.2157 1.2237 1.2302 1.2371 1.2442 1.2520 1.2595 1.2671 1.2739
200 1.2047 1.2120 1.2180 1.2240 1.2317 1.2386 1.2447 1.2521 1.2584
300 1.1946 1.2018 1.2072 1.2133 1.2198 1.2263 1.2328 1.2395 1.2454
400 1.1857 1.1924 1.1979 1.2034 1.2098 1.2158 1.2218 1.2283 1.2337
500 1.1774 1.1837 1.1886 1.1940 1.2003 1.2056 1.2114 1.2168 1.2226
600 1.1695 1.1757 1.1802 1.1854 1.1915 1.1968 1.2020 1.2079 1.2132
700 1.1623 1.1683 1.1729 1.1774 1.1837 1.1886 1.1936 1.1993 1.2041
800 1.1551 1.1611 1.1655 1.1701 1.1757 1.1807 1.1856 1.1907 1.1953
900 1.1491 1.1547 1.1585 1.1631 1.1688 1.1736 1.1785 1.1832 1.1873
1000 1.1432 1.1485 1.1521 1.1564 1.1622 1.1667 1.1712 1.1757 1.1799
1100 1.1374 1.1426 1.1462 1.1505 1.1559 1.1602 1.1646 1.1692 1.1733
1200 1.1317 1.1368 1.1406 1.1447 1.1499 1.1540 1.1583 1.1629 1.1671
1300 1.1269 1.1317 1.1346 1.1392 1.1440 1.1486 1.1526 1.1571 1.1612
1400 1.1217 1.1265 1.1301 1.1339 1.1390 1.1426 1.1472 1.1511 1.1553
1500 1.1171 1.1217 1.1245 1.1290 1.1336 1.1378 1.1421 1.1455 1.1497
1600 1.1128 1.1174 1.1201 1.1237 1.1284 1.1324 1.1371 1.1403 1.1443
1700 1.1083 1.1129 1.1154 1.1193 1.1239 1.1277 1.1320 1.1356 1.1397
1800 1.1042 1.1086 1.1110 1.1148 1.1194 1.1231 1.1270 1.1306 1.1351
_____________________________________________________________________________
copolymer (B): E-VA/28w(B) 90BU1
_____________________________________________________________________________
P/MPa T/K
373.15 383.15 393.15 403.15 413.15 423.15 433.15 443.15 453.15
Vspez/cm3g−1
_____________________________________________________________________________
10 1.1378 1.1443 1.1563 1.1636 1.1749 1.1822 1.1884 1.1978 1.2057
20 1.1288 1.1356 1.1462 1.1529 1.1631 1.1696 1.1755 1.1848 1.1922
30 1.1208 1.1277 1.1372 1.1439 1.1529 1.1589 1.1644 1.1736 1.1805
40 1.1131 1.1200 1.1288 1.1355 1.1433 1.1488 1.1542 1.1635 1.1698
50 1.1061 1.1128 1.1210 1.1277 1.1348 1.1400 1.1462 1.1547 1.1612
60 1.0997 1.1069 1.1139 1.1203 1.1275 1.1321 1.1383 1.1472 1.1526
70 1.0940 1.1008 1.1079 1.1145 1.1205 1.1249 1.1311 1.1399 1.1454
80 1.0888 1.0956 1.1022 1.1086 1.1148 1.1189 1.1244 1.1338 1.1395
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
385.25 393.75 402.05 409.95 418.45 427.15 435.15 443.55 451.95
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.1403 1.1473 1.1544 1.1610 1.1686 1.1765 1.1836 1.1909 1.1983
20 1.1238 1.1301 1.1362 1.1421 1.1487 1.1554 1.1617 1.1680 1.1746
40 1.1100 1.1155 1.1211 1.1265 1.1324 1.1383 1.1441 1.1498 1.1555
60 1.0975 1.1026 1.1080 1.1130 1.1185 1.1237 1.1290 1.1342 1.1394
80 1.0863 1.0911 1.0959 1.1008 1.1057 1.1106 1.1156 1.1206 1.1251
100 1.0766 1.0811 1.0857 1.0902 1.0949 1.0995 1.1042 1.1088 1.1131
120 1.0676 1.0718 1.0760 1.0805 1.0848 1.0892 1.0935 1.0979 1.1019
140 1.0591 1.0632 1.0672 1.0718 1.0756 1.0796 1.0839 1.0878 1.0916
160 1.0513 1.0555 1.0590 1.0630 1.0669 1.0710 1.0748 1.0787 1.0826
180 1.0441 1.0478 1.0514 1.0554 1.0591 1.0628 1.0665 1.0703 1.0737
200 1.0371 1.0409 1.0443 1.0481 1.0515 1.0551 1.0586 1.0623 1.0656
_____________________________________________________________________________
continue E-VA/33w
_____________________________________________________________________________
P/MPa T/K
459.65 468.05 476.75 484.85 492.85 501.65 510.35 518.35 526.55
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.2057 1.2136 1.2216 1.2296 1.2377 1.2466 1.2551 1.2646 1.2738
20 1.1810 1.1874 1.1942 1.2010 1.2080 1.2149 1.2222 1.2294 1.2373
40 1.1611 1.1670 1.1732 1.1789 1.1849 1.1910 1.1975 1.2039 1.2106
60 1.1445 1.1500 1.1550 1.1607 1.1661 1.1715 1.1776 1.1829 1.1892
80 1.1301 1.1349 1.1399 1.1450 1.1499 1.1551 1.1604 1.1654 1.1712
100 1.1177 1.1221 1.1266 1.1315 1.1361 1.1408 1.1456 1.1505 1.1559
120 1.1063 1.1105 1.1150 1.1194 1.1238 1.1279 1.1327 1.1369 1.1422
140 1.0958 1.0999 1.1038 1.1082 1.1124 1.1163 1.1207 1.1249 1.1298
160 1.0863 1.0902 1.0939 1.0981 1.1019 1.1058 1.1099 1.1138 1.1186
180 1.0776 1.0811 1.0849 1.0887 1.0925 1.0961 1.1000 1.1038 1.1082
200 1.0694 1.0728 1.0762 1.0800 1.0836 1.0871 1.0909 1.0946 1.0988
_____________________________________________________________________________
6. PVT Data 417
____________________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
367.75 375.95 383.05 391.55 399.45 408.35 415.95 424.35 431.95
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.1010 1.1072 1.1135 1.1205 1.1275 1.1349 1.1415 1.1491 1.1555
20 1.0872 1.0927 1.0986 1.1048 1.1108 1.1170 1.1233 1.1299 1.1359
40 1.0746 1.0798 1.0854 1.0910 1.0967 1.1019 1.1078 1.1139 1.1191
60 1.0634 1.0683 1.0736 1.0788 1.0839 1.0887 1.0943 1.0998 1.1047
80 1.0532 1.0578 1.0630 1.0678 1.0726 1.0771 1.0822 1.0871 1.0921
100 1.0444 1.0488 1.0536 1.0583 1.0629 1.0670 1.0718 1.0764 1.0810
120 1.0361 1.0402 1.0450 1.0493 1.0536 1.0575 1.0621 1.0665 1.0709
140 1.0284 1.0324 1.0368 1.0409 1.0451 1.0486 1.0534 1.0574 1.0616
160 1.0213 1.0250 1.0296 1.0334 1.0373 1.0406 1.0450 1.0488 1.0532
180 1.0148 1.0183 1.0226 1.0263 1.0301 1.0332 1.0375 1.0412 1.0451
200 1.0084 1.0118 1.0161 1.0198 1.0233 1.0264 1.0305 1.0338 1.0378
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
441.05 448.75 455.65 464.85 473.75 481.65 489.15 496.85
Vspez/cm3g−1
_____________________________________________________________________________
0.1 1.1635 1.1708 1.1772 1.1855 1.1938 1.2012 1.2087 1.2164
20 1.1424 1.1485 1.1545 1.1613 1.1682 1.1747 1.1811 1.1878
40 1.1248 1.1304 1.1360 1.1419 1.1479 1.1536 1.1595 1.1655
60 1.1097 1.1151 1.1203 1.1255 1.1307 1.1360 1.1415 1.1469
80 1.0966 1.1016 1.1067 1.1112 1.1161 1.1209 1.1262 1.1313
100 1.0851 1.0899 1.0948 1.0989 1.1032 1.1080 1.1128 1.1177
120 1.0748 1.0792 1.0838 1.0876 1.0918 1.0962 1.1007 1.1052
140 1.0651 1.0694 1.0739 1.0774 1.0815 1.0857 1.0899 1.0941
160 1.0564 1.0607 1.0649 1.0681 1.0719 1.0757 1.0800 1.0841
180 1.0484 1.0524 1.0565 1.0596 1.0632 1.0670 1.0709 1.0750
200 1.0407 1.0447 1.0487 1.0517 1.0550 1.0587 1.0625 1.0663
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
P/kg cm−2 T/K
348.25 357.05 366.75 376.05 385.15 393.55 402.65 412.15 421.05
Vspez/cm3g−1
_____________________________________________________________________________
1 1.0901 1.0964 1.1041 1.1112 1.1174 1.1267 1.1339 1.1407 1.1474
100 1.0837 1.0901 1.0973 1.1040 1.1107 1.1180 1.1240 1.1315 1.1377
200 1.0773 1.0835 1.0902 1.0965 1.1030 1.1101 1.1156 1.1229 1.1285
300 1.0713 1.0774 1.0837 1.0901 1.0962 1.1027 1.1082 1.1148 1.1202
400 1.0658 1.0717 1.0778 1.0838 1.0898 1.0959 1.1009 1.1076 1.1127
500 1.0603 1.0658 1.0718 1.0778 1.0831 1.0895 1.0947 1.1006 1.1056
600 1.0553 1.0608 1.0661 1.0720 1.0777 1.0833 1.0881 1.0941 1.0985
700 1.0505 1.0556 1.0612 1.0669 1.0724 1.0777 1.0826 1.0883 1.0924
800 1.0460 1.0510 1.0562 1.0617 1.0670 1.0722 1.0771 1.0823 1.0864
900 1.0415 1.0466 1.0513 1.0568 1.0623 1.0668 1.0719 1.0769 1.0809
1000 1.0373 1.0419 1.0470 1.0521 1.0575 1.0622 1.0668 1.0714 1.0755
1100 1.0335 1.0380 1.0426 1.0475 1.0530 1.0575 1.0620 1.0664 1.0704
1200 1.0296 1.0339 1.0386 1.0434 1.0486 1.0532 1.0575 1.0620 1.0657
1300 1.0259 1.0300 1.0345 1.0394 1.0443 1.0489 1.0532 1.0576 1.0609
1400 1.0223 1.0264 1.0308 1.0357 1.0405 1.0449 1.0489 1.0532 1.0567
1500 1.0187 1.0230 1.0273 1.0317 1.0366 1.0408 1.0449 1.0490 1.0522
1600 1.0154 1.0197 1.0234 1.0282 1.0329 1.0375 1.0410 1.0450 1.0484
1700 1.0123 1.0164 1.0206 1.0249 1.0295 1.0333 1.0375 1.0414 1.0446
1800 1.0092 1.0133 1.0172 1.0216 1.0262 1.0301 1.0338 1.0373 1.0408
_____________________________________________________________________________
_____________________________________________________________________________
P/kg cm−2 T/K
430.25 439.45 447.85 457.45 466.15 474.95 484.05 500.55 516.75
3 −1
Vspez/cm g
_____________________________________________________________________________
1 1.1544 1.1598 1.1694 1.1769 1.1863 1.1917 1.1987 1.2138 1.2288
100 1.1446 1.1508 1.1576 1.1654 1.1724 1.1789 1.1857 1.1998 1.2138
200 1.1348 1.1410 1.1472 1.1549 1.1610 1.1671 1.1734 1.1867 1.1999
300 1.1264 1.1324 1.1374 1.1451 1.1509 1.1566 1.1629 1.1752 1.1876
400 1.1186 1.1245 1.1297 1.1364 1.1413 1.1472 1.1531 1.1648 1.1766
500 1.1111 1.1165 1.1221 1.1281 1.1332 1.1385 1.1440 1.1550 1.1663
600 1.1045 1.1096 1.1148 1.1204 1.1252 1.1302 1.1357 1.1465 1.1568
700 1.0978 1.1029 1.1081 1.1136 1.1179 1.1231 1.1280 1.1382 1.1489
800 1.0917 1.0966 1.1016 1.1071 1.1108 1.1159 1.1208 1.1304 1.1407
_____________________________________________________________________________
continue
6. PVT Data 419
____________________________________________________________________________________
continue
_____________________________________________________________________________
P/kg cm−2 T/K
430.25 439.45 447.85 457.45 466.15 474.95 484.05 500.55 516.75
3 −1
Vspez/cm g
_____________________________________________________________________________
900 1.0861 1.0905 1.0952 1.1008 1.1046 1.1094 1.1141 1.1229 1.1330
1000 1.0805 1.0851 1.0898 1.0950 1.0984 1.1032 1.1078 1.1170 1.1263
1100 1.0755 1.0796 1.0847 1.0891 1.0928 1.0971 1.1019 1.1106 1.1196
1200 1.0707 1.0748 1.0792 1.0839 1.0871 1.0914 1.0960 1.1045 1.1132
1300 1.0661 1.0699 1.0741 1.0790 1.0821 1.0861 1.0906 1.0989 1.1076
1400 1.0618 1.0654 1.0695 1.0742 1.0770 1.0811 1.0856 1.0940 1.1023
1500 1.0574 1.0608 1.0651 1.0693 1.0724 1.0761 1.0806 1.0885 1.0967
1600 1.0528 1.0568 1.0609 1.0648 1.0678 1.0715 1.0757 1.0838 1.0908
1700 1.0488 1.0526 1.0564 1.0612 1.0636 1.0668 1.0713 1.0793 1.0864
1800 1.0455 1.0486 1.0525 1.0570 1.0591 1.0624 1.0671 1.0746 1.0823
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
343.65 351.65 360.35 368.55 376.75 385.15 393.55 401.85 409.35
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.0072 1.0132 1.0195 1.0256 1.0314 1.0378 1.0437 1.0503 1.0563
20 0.9962 1.0018 1.0076 1.0131 1.0184 1.0240 1.0295 1.0353 1.0408
40 0.9860 0.9914 0.9967 1.0018 1.0067 1.0117 1.0171 1.0222 1.0276
60 0.9769 0.9819 0.9870 0.9917 0.9962 1.0009 1.0058 1.0108 1.0154
80 0.9683 0.9733 0.9780 0.9826 0.9867 0.9911 0.9958 1.0004 1.0049
100 0.9609 0.9656 0.9701 0.9744 0.9784 0.9826 0.9870 0.9912 0.9956
120 0.9538 0.9584 0.9627 0.9669 0.9706 0.9746 0.9788 0.9829 0.9870
140 0.9471 0.9515 0.9556 0.9598 0.9643 0.9672 0.9712 0.9752 0.9790
160 0.9409 0.9453 0.9492 0.9533 0.9567 0.9603 0.9641 0.9678 0.9717
180 0.9352 0.9393 0.9432 0.9471 0.9505 0.9541 0.9577 0.9615 0.9649
200 0.9297 0.9338 0.9375 0.9414 0.9447 0.9480 0.9516 0.9550 0.9585
_____________________________________________________________________________
____________________________________________________________________________________
continue E-VA/65w
_____________________________________________________________________________
P/MPa T/K
418.45 426.65 434.75 442.85 451.25 459.65 476.35 493.25 501.75
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 1.0631 1.0702 1.0763 1.0834 1.0908 1.0982 1.1144 1.1336 1.1455
20 1.0468 1.0529 1.0587 1.0647 1.0711 1.0777 1.0916 1.1082 1.1180
40 1.0327 1.0383 1.0436 1.0491 1.0548 1.0604 1.0729 1.0878 1.0969
60 1.0205 1.0256 1.0304 1.0355 1.0406 1.0459 1.0574 1.0711 1.0790
80 1.0096 1.0143 1.0190 1.0236 1.0284 1.0333 1.0439 1.0564 1.0640
100 0.9999 1.0046 1.0088 1.0133 1.0176 1.0222 1.0321 1.0440 1.0510
120 0.9911 0.9953 0.9994 1.0036 1.0079 1.0123 1.0216 1.0329 1.0394
140 0.9829 0.9869 0.9909 0.9949 0.9988 1.0029 1.0120 1.0225 1.0289
160 0.9754 0.9793 0.9830 0.9868 0.9906 0.9945 1.0030 1.0133 1.0193
180 0.9685 0.9721 0.9759 0.9793 0.9830 0.9867 0.9949 1.0049 1.0107
200 0.9619 0.9654 0.9689 0.9726 0.9759 0.9796 0.9875 0.9969 1.0027
_____________________________________________________________________________
copolymer (B): E-VA/87w 90CIM
_____________________________________________________________________________
P/MPa T/K
303.15 313.15 323.15 333.15 343.15 353.15 363.15 373.15 383.15
Vspez/cm3g−1
_____________________________________________________________________________
0.1 0.879 0.885 0.891 0.897 0.903 0.909 0.916 0.922 0.929
_____________________________________________________________________________
continue E-VA/87w
_____________________________________________________________________________
P/MPa T/K
393.15 403.15 413.15 423.15 433.15 443.15
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 0.936 0.943 0.950 0.958 0.965 0.973
_____________________________________________________________________________
6. PVT Data 421
____________________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
C = 0.0894 and θ = T/K − 273.15
_____________________________________________________________________________
E-VA/18w(1) 1.02391 exp(2.173 10−5T 1.5) 188.2 exp(−4.537 10−3θ )
E-VA/25w(1) 1.00416 exp(2.244 10−5T 1.5) 184.4 exp(−4.734 10−3θ )
E-VA/28w(Z1) 1.00832 exp(2.241 10−5T 1.5) 183.5 exp(−4.457 10−3θ )
E-VA/40w(1) 1.06332 exp(2.288 10−5T 1.5) 205.1 exp(−4.989 10−3θ )
_____________________________________________________________________________
C = 0.065504
_____________________________________________________________________________
E-VA/09w 0.96060 + 0.35674 10−3T + 8.4287 10−7T 2 667.89 exp(−5.9742 10−3T)
_____________________________________________________________________________
C = 0.064626
_____________________________________________________________________________
E-VA/28w(B) 0.75181 + 1.20228 10−3T − 3.6156 10−7T 2 386.92 exp(−4.9032 10−3T)
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from ethylene and vinyl alcohol
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
56 wt% vinyl alcohol E-VAL/56w 468-535 0.1-200 95ZOL
_____________________________________________________________________________
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
E-VAL/56w no data
E-VAL/62w no data
E-VAL/70w no data
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): E-VAL/56w 95ZOL
_____________________________________________________________________________
P/MPa T/K
468.35 476.85 485.35 493.45 501.95 510.25 518.75 527.25 535.55
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 0.9808 0.9860 0.9911 0.9960 1.0017 1.0067 1.0122 1.0178 1.0241
20 0.9711 0.9759 0.9806 0.9853 0.9902 0.9949 1.0000 1.0051 1.0107
40 0.9629 0.9673 0.9718 0.9762 0.9806 0.9852 0.9897 0.9944 0.9997
60 0.9553 0.9595 0.9636 0.9678 0.9721 0.9764 0.9807 0.9850 0.9898
80 0.9483 0.9523 0.9562 0.9602 0.9643 0.9684 0.9723 0.9765 0.9811
100 0.9421 0.9458 0.9496 0.9534 0.9573 0.9611 0.9648 0.9689 0.9731
120 0.9360 0.9396 0.9432 0.9468 0.9507 0.9542 0.9578 0.9615 0.9659
140 0.9302 0.9338 0.9373 0.9409 0.9443 0.9478 0.9513 0.9549 0.9589
160 0.9249 0.9283 0.9316 0.9351 0.9385 0.9419 0.9452 0.9486 0.9525
180 0.9199 0.9232 0.9265 0.9297 0.9330 0.9363 0.9394 0.9428 0.9465
200 0.9151 0.9182 0.9214 0.9246 0.9278 0.9309 0.9340 0.9374 0.9409
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
466.45 475.05 483.35 491.55 499.05 507.75 516.05 524.15 531.75
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 0.9527 0.9576 0.9621 0.9671 0.9713 0.9767 0.9818 0.9889 0.9982
_____________________________________________________________________________
continue
6. PVT Data 423
____________________________________________________________________________________
continue E-VAL/62w
_____________________________________________________________________________
P/MPa T/K
466.45 475.05 483.35 491.55 499.05 507.75 516.05 524.15 531.75
3 −1
Vspez/cm g
_____________________________________________________________________________
20 0.9445 0.9489 0.9531 0.9575 0.9617 0.9663 0.9712 0.9779 0.9865
40 0.9372 0.9413 0.9453 0.9493 0.9535 0.9575 0.9621 0.9686 0.9768
60 0.9306 0.9344 0.9382 0.9420 0.9460 0.9497 0.9541 0.9603 0.9680
80 0.9243 0.9280 0.9315 0.9351 0.9390 0.9426 0.9467 0.9528 0.9600
100 0.9186 0.9221 0.9256 0.9289 0.9326 0.9359 0.9400 0.9458 0.9528
120 0.9132 0.9164 0.9197 0.9230 0.9266 0.9298 0.9336 0.9394 0.9462
140 0.9081 0.9114 0.9144 0.9176 0.9210 0.9240 0.9279 0.9334 0.9397
160 0.9032 0.9063 0.9093 0.9125 0.9158 0.9186 0.9224 0.9277 0.9338
180 0.8986 0.9016 0.9046 0.9075 0.9108 0.9136 0.9171 0.9224 0.9283
200 0.8943 0.8973 0.9000 0.9029 0.9060 0.9087 0.9122 0.9174 0.9231
_____________________________________________________________________________
_____________________________________________________________________________
P/MPa T/K
469.25 477.75 486.15 494.35 502.65 511.35 519.55 527.85 536.15
3 −1
Vspez/cm g
_____________________________________________________________________________
0.1 0.9386 0.9431 0.9479 0.9514 0.9561 0.9610 0.9658 0.9711 0.9765
20 0.9299 0.9342 0.9385 0.9419 0.9462 0.9506 0.9551 0.9597 0.9648
40 0.9228 0.9269 0.9308 0.9340 0.9381 0.9422 0.9464 0.9508 0.9555
60 0.9163 0.9201 0.9238 0.9268 0.9307 0.9346 0.9386 0.9429 0.9472
80 0.9102 0.9139 0.9174 0.9203 0.9240 0.9276 0.9314 0.9354 0.9397
100 0.9047 0.9082 0.9115 0.9142 0.9178 0.9214 0.9251 0.9288 0.9328
120 0.8994 0.9028 0.9059 0.9086 0.9120 0.9154 0.9188 0.9224 0.9263
140 0.8944 0.8976 0.9007 0.9032 0.9065 0.9097 0.9130 0.9165 0.9202
160 0.8896 0.8928 0.8957 0.8981 0.9013 0.9043 0.9076 0.9110 0.9146
180 0.8851 0.8882 0.8909 0.8933 0.8964 0.8994 0.9025 0.9058 0.9092
200 0.8807 0.8838 0.8864 0.8887 0.8918 0.8946 0.8976 0.9008 0.9042
_____________________________________________________________________________
____________________________________________________________________________________
_____________________________________________________________________________
Copolymers from perfluoroethylene oxide and perfluoromethylene oxide
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
Perfluoro(oxyethylene/oxymethylene)
copolymer
43 mol% perfluorooxymethylene PF(OE-OM)/43x 253-333 0.1 95DAN
49 mol% perfluorooxymethylene PF(OE-OM)/49x(1) 253-333 0.1 95DAN
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
PF(OE-OM)/43x 465 500 endgroup −CH2-OH on each side of the
chain, i.e., = 12.4 wt% in this sample
PF(OE-OM)/49x(1) 2550 3290 endgroup −CH2-OH on each side of the
_____________________________________________________________________________
continue
6. PVT Data 425
____________________________________________________________________________________
continue
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
copolymer (B): PF(OE-OM)/43x 95DAN
P/MPa = 0.1 = constant
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15

Vspez/cm3g−1 0.5585 0.5636 0.5687 0.5738 0.5789 0.5843 0.5895 0.5949
T/K 333.15
Vspez/cm3g−1 0.6003
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15

Vspez/cm3g−1 0.5457 0.5512 0.5566 0.5621 0.5674 0.5729 0.5785 0.5840
T/K 333.15
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15

Vspez/cm3g−1 0.5625 0.5674 0.5723 0.5773 0.5823 0.5874 0.5924 0.5973
T/K 333.15
____________________________________________________________________________________
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15

Vspez/cm3g−1 0.5476 0.5529 0.5583 0.5638 0.5691 0.5748 0.5803 0.5858
T/K 333.15
copolymer (B): PF(OE-OM)/49x(1) 95DAN
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15

Vspez/cm3g−1 0.5311 0.5367 0.5423 0.5479 0.5534 0.5592 0.5646 0.5705
T/K 333.15
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15

Vspez/cm3g−1 0.5280 0.5336 0.5393 0.5450 0.5506 0.5566 0.5624 0.5681
T/K 333.15
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15

Vspez/cm3g−1 0.5255 0.5312 0.5369 0.5427 0.5483 0.5543 0.5599 0.5656
T/K 333.15
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15

Vspez/cm3g−1 0.5246 0.5302 0.5359 0.5416 0.5471 0.5529 0.5588 0.5644
T/K 333.15
6. PVT Data 427
____________________________________________________________________________________
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15

Vspez/cm3g−1 0.5223 0.5280 0.5337 0.5395 0.5452 0.5512 0.5570 0.5626
T/K 333.15
T/K 253.15 263.15 273.15 283.15 293.15 303.15 313.15 323.15

Vspez/cm3g−1 0.5405 0.5461 0.5518 0.5575 0.5631 0.5692 0.5747 0.5806
T/K 333.15
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
20.5 wt% methyl methacrylate S-MMA/21w 383-543 0.1-200 92KIM
58.5 wt% methyl methacrylate S-MMA/59w 383-543 0.1-200 92KIM
_____________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
S-MMA/21w 110000 268000 Richardson Polymer Noan 81
S-MMA/59w Richardson Polymer RPC 100
_____________________________________________________________________________
____________________________________________________________________________________

_____________________________________________________________________________

_____________________________________________________________________________
with C = 0.0894 and θ = T/K − 273.15
_____________________________________________________________________________
_____________________________________________________________________________
S-MMA/21w 0.9063 + 3.5702 10−4θ + 6.5323 10−7θ 2 232.0 exp(−4.1430 10−3θ )
S-MMA/59w 0.8610 + 3.3500 10−4θ + 6.9801 10−7θ 2 261.0 exp(−4.6112 10−3θ )
_____________________________________________________________________________
_____________________________________________________________________________
Copolymers from N-vinylcarbazole and 4-alkylstyrenes
_____________________________________________________________________________
_____________________________________________________________________________
Copolymer Acronym
Range of data Ref.
T/K P/MPa
_____________________________________________________________________________
N-Vinylcarbazole/4-ethylstyrene copolymer
50 mol% 4-ethylstyrene VCZ-ES/50x 393-443 30-100 94PRI
N-Vinylcarbazole/4-hexylstyrene copolymer
20 mol% 4-hexylstyrene VCZ-HS/20x 473-523 30-100 94PRI
N-Vinylcarbazole/4-octylstyrene copolymer
50 mol% 4-octylstyrene VCZ-OS/50x 403-453 30-100 94PRI
N-Vinylcarbazole/4-pentylstyrene copolymer
50 mol% 4-pentylstyrene VCZ-PS/50x 383-443 30-100 94PRI
_____________________________________________________________________________
6. PVT Data 429
____________________________________________________________________________________
Characterization:
_____________________________________________________________________________
g/mol g/mol g/mol
_____________________________________________________________________________
VCZ-ES/50x synthesized in the laboratory
VCZ-HS/20x synthesized in the laboratory
VCZ-OS/50x synthesized in the laboratory
VCZ-PS/50x synthesized in the laboratory
_____________________________________________________________________________

_____________________________________________________________________________

_____________________________________________________________________________
with C = 0.0894 and θ = T/K − 273.15
_____________________________________________________________________________
_____________________________________________________________________________
VCZ-ES/50x 0.6676 + 6.63 10−4T 5281.7 exp(−9.264 10−3θ )
VCZ-HS/20x 0.6416 + 5.42 10−4T 489.8 exp(−3.193 10−3θ )
VCZ-HS/33x 0.7710 + 4.86 10−4T 460.4 exp(−3.453 10−3θ )
VCZ-HS/40x 0.7805 + 4.92 10−4T 155.0 exp(−1.605 10−3θ )
VCZ-HS/50x 0.7827 + 5.05 10−4T 136.0 exp(−1.083 10−3θ )
VCZ-HS/60x 0.8213 + 6.23 10−4T 229.1 exp(−2.133 10−3θ )
VCZ-HS/67x 0.8028 + 6.50 10−4T 581.7 exp(−4.553 10−3θ )
VCZ-HS/80x 0.7753 + 6.17 10−4T 247.6 exp(−2.604 10−3θ )
VCZ-OS/50x 0.7081 + 7.40 10−4T 666.5 exp(−4.503 10−3θ )
VCZ-PS/50x 0.7814 + 4.36 10−4T 880.1 exp(−4.393 10−3θ )
_____________________________________________________________________________
____________________________________________________________________________________
6.2. References
73RAO Rao, K. and Griskey, R.G., An equation of state for molten polymers, J. Appl. Polym. Sci.,
17, 3293, 1973.
77REN Renuncio, J.A.R. and Prausnitz, J.M., Volumetric properties of block and random copoly-
mers of butadiene and styrene at pressures to 1 kilobar, J. Appl. Polym. Sci., 21, 2867,
1977.
86ZOL Zoller, P., Jain, R. K., and Simha, R., Equation of state of copolymer melts: The poly(vinyl
acetate)-polyethylene pair, J. Polym. Sci., Part B: Polym. Phys., 24, 687, 1986.
(experimental data by private communication with P. Zoller)
90BU1 Busch, B., Das spezifische Volumen geschmolzener Polymere und Copolymere in
Abhängigkeit von Druck und Temperatur, PhD-Thesis, Univ. Osnabrück, 1990.
90BU2 Busch, B., Lechner, M.D., and Kleintjens, L.A., The specific volume of polymer melts as a
function of temperature and pressure, Thermochim. Acta, 160, 131, 1990.
90CIM Cimmino, S., Martuscelli, E., Saviano, M., and Silvestre, C., A comparison of theoretical
predictions and experimental evidences of miscibility for poly(ethylene oxide)-based
blends, Makromol. Chem., Macromol. Symp., 38, 61,1990.
92KIM Kim, C.K. and Paul, D.R., Interaction parameters for blends containing polycarbonates. 2.
Tetramethyl bisphenol-A polycarbonate - styrene copolymers, Polymer, 33, 2089, 1992.
(experimental data by private communication with D. R. Paul)
92WIN Wind, R.W., Untersuchungen zum Phasenverhalten von Mischungen aus Ethylen, Acrylsäu-
re und Ethylen-Acrylsäure-Copolymeren unter hohem Druck, PhD-Thesis, TH Darmstadt,
1992.
93ROD Rodgers, P.A., Pressure-volume-temperature relationships for polymeric liquids: A review
of equations of state and their characteristic parameters for 56 polymers, J. Appl. Polym.
Sci., 48, 1061, 1993.
94PRI Privalko, V.P., Arbuzova, A.P., Korskanov, V.V., and Zagdanskaya, N.E., Thermodyna-
mics of random copolymers of N-vinylcarbazole and 4-alkylstyrenes, Polym. Intern., 35,
161, 1994.
94WAN Wang, Y.Z., Hsieh, K.H., Chen, L.W., and Tseng, H.C., Effect of compatibility on specific
volume of molten polyblends, J. Appl. Polym. Sci., 53, 1191, 1994.
95DAN Danusso, F., Levi, M., Gianotti, G., and Turri, S., Thermovolumetric properties versus glass
transition temperature of diolic perfluoro-poly(oxyethylene-ran-oxymethylene) oligomers,
96XUY Xu, Y., Charakterisierung von Styrol-Ethylen-Copolymeren und deren Mischungen mit
Poly(2,6-dimethyl-1,4-phenylen ether), Diploma paper, Albert-Ludwigs-Univ., Freiburg i.
Br., 1996.
(experimental data by personal communication with Y. Thomann)
98SUH Suhm, J., Maier, R.-D., Kressler, J., and Mühlhaupt, R., Microstructure and pressure-
volume-temperature properties of ethene/1-octene random copolymers, Acta Polym., 49, 80,
1998.
(experimental data by personal communication with R.-D. Maier)
99MAI Maier, R.-D., Thermodynamik und Kristallisation von Metallocen-Polyolefinen, PhD-
Thesis, Albert-Ludwigs-Univ., Freiburg i. Br., 1999.
(experimental data by personal communication with R.-D. Maier)
7. SECOND VIRIAL COEFFICIENTS (A2) OF COPOLYMER
SOLUTIONS
_____________________________________________________________________________

_____________________________________________________________________________
46.0 mol% acrylonitrile AN-αMS/46x 79GL2
_____________________________________________________________________________
59.0 wt% acrylonitrile AN-VdC/59w 86KAM
_____________________________________________________________________________
14.6 mol% styrene B-S/15x(1) 79STA
23.9 mol% styrene B-S/24x 79STA
25.0 mol% styrene B-S/25x(9/51) 61COO
(9 mol% 1,4-cis, 51 mol% 1,4-trans)
(9 mol% 1,4-cis, 54 mol% 1,4-trans)
(7.8 mol% 1,4-cis, 50.4 mol% 1,4-trans)
(12.6 mol% 1,4-cis, 44.8 mol% 1,4-trans)
_____________________________________________________________________________
Butyl acrylate/methyl methacrylate copolymer
29.5 wt% methyl methacrylate BA-MMA/30w 70WU1
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Butyl methacrylate/methyl methacrylate copolymer
50.0 wt% methyl methacrylate BMA-MMA/50w 70WU2
_____________________________________________________________________________
Butylene/ethylethylene copolymer
1:1, alternating B-EE/50x 84MAY
_____________________________________________________________________________
Ethyl acrylate/methyl methacrylate copolymer
50.0 wt% methyl methacrylate EA-MMA/50w 70WU2
_____________________________________________________________________________
1:1, alternating E-P/50x 84MAY
_____________________________________________________________________________
Ethylene/tetrafluoroethylene copolymer
1:1, alternating E-TFE/50x 89CHU
_____________________________________________________________________________
_____________________________________________________________________________
9,9-bis(4-Hydroxyphenyl)fluorene/terephthaloyl
chloride copolymer
1:1, alternating HPF-TPC/50x 77TA1
_____________________________________________________________________________
_____________________________________________________________________________
Isopropylethylene/1-methylbutylene copolymer
1:1, alternating IPE-MB/50x 84MAY
_____________________________________________________________________________
Isopropylethylene/1-methyl-1-ethylethylene
copolymer
1:1, alternating IPE-MEE/50x 84MAY
_____________________________________________________________________________
7. A2 Data 433
_____________________________________________________________________________

_____________________________________________________________________________
Methyl acrylate/methyl methacrylate copolymer
50.0 wt% methyl methacrylate MA-MMA/50w 70WU2
_____________________________________________________________________________
Methyl methacrylate/acrylonitrile copolymer
23.6 mol% acrylonitrile MMA-AN/24x 82MA2
_____________________________________________________________________________
1-Octadecene/maleic anhydride copolymer
1:1, alternating ODC-MAH/50x 85MAT
_____________________________________________________________________________
Oxyethylene/oxymethylene copolymer
<5 wt% oxyethylene OE-OM/05w 65WAG
_____________________________________________________________________________
Pyromellitic acid/4-amino-1,4-phenyleneoxy-
1,4-phenyleneamine copolymer
1:1, alternating P-AA1/50x 77BIR
_____________________________________________________________________________
Pyromellitic acid/4-amino-1,4-phenyleneoxy-1,
4-phenylenoxy-1,4-phenyleneamine copolymer
1:1, alternating P-AA2/50x 77BIR
_____________________________________________________________________________
38.5 mol% acrylonitrile S-AN/38x 77GL1
40.0 mol% acrylonitrile S-AN/40x 89EGO
41.0 mol% acrylonitrile S-AN/41x 89EGO
51.0 mol% acrylonitrile S-AN/51x 82MA1
_____________________________________________________________________________
Styrene/p-methoxystyrene copolymer
26.0 mol% p-methoxystyrene S-pMOS/26x(1) 72PIZ
53.0 mol% p-methoxystyrene S-pMOS/53x 72PIZ
53.8 mol% p-methoxystyrene S-pMOS/54x 72PIZ
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
29.8 mol% methyl methacrylate S-MMA/30x 66KOT
46.4 wt% methyl methacrylate S-MMA/46w 55STO
_____________________________________________________________________________
Tetrafluoroethylene/trifluoronitrosomethane
copolymer
1:1, alternating TFE-TFNM/50x 61MOR
_____________________________________________________________________________
11.4 mol% vinyl acetate VA-VC/11x 85MIN
_____________________________________________________________________________
Vinyl acetate/1-vinyl-2-pyrrolidinone copolymer
65.0 mol% 1-vinyl-2-pyrrolidinone VA-NVP/65x 89EGO
_____________________________________________________________________________
Vinyl chloride/butyl acrylate copolymer
16.6 mol% butyl acrylate VC-BA/17x 85MIN
40.0 mol% butyl acrylate VC-BA/40x 85MIN
_____________________________________________________________________________
Vinyl chloride/butyl ether copolymer
9.2 mol% butyl ether VC-BE/09x 85MIN
_____________________________________________________________________________
Vinyl chloride/methyl acrylate copolymer
25.5 mol% methyl acrylate VC-MA/25x 85MIN
_____________________________________________________________________________
15.0 mol% vinylidene chloride VC-VdC/15x 85MIN
42.0 mol% vinylidene chloride VC-VdC/42x 85MIN
_____________________________________________________________________________
7. A2 Data 435
_____________________________________________________________________________
Copolymer-solvent systems, measuring temperatures and A2-values:
_____________________________________________________________________________
Copolymer (B) Mn/ M w/ Solvent (A) T/ A2 104/
_____________________________________________________________________________
AN-αMS/46x 45000 tetrahydrofuran 298.15 7.19
_____________________________________________________________________________
AN-VdC/59w 204000 γ-butyrolactone 298.15 0.119
AN-VdC/59w 42000 N,N-dimethylacetamide 298.15 0.132
AN-VdC/59w 204000 N,N-dimethylformamide 298.15 0.137
_____________________________________________________________________________
B-S/15x(1) 30300 54800 tetrahydrofuran 296.15 14.4
B-S/24x 122000 132000 tetrahydrofuran 296.15 10.9
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
B-S/25x(9/51) 112000 800000 benzene 301.75 14.2
B-S/25x(9/51) 112000 800000 cyclohexane 301.75 0.46
B-S/25x(9/54) 84100 740000 benzene 301.75 12.0
B-S/25x(9/54) 84100 740000 cyclohexane 301.75 1.39
B-S/29x(8/50) 116000 1700000 benzene 301.75 12.8
B-S/29x(8/50) 116000 1700000 cyclohexane 301.75 1.62
B-S/30x(13/45) 58400 2670000 benzene 301.75 14.9
B-S/30x(13/45) 58400 2670000 cyclohexane 301.75 0.14
_____________________________________________________________________________
_____________________________________________________________________________
BA-MMA/30x 27000 2-propanone 293.15 9.5
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
BMA-MMA/50x 70000 2-propanone 293.15 3.2
_____________________________________________________________________________
7. A2 Data 437
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
B-EE/50x 19500 19600 toluene 310.15 9.5
B-EE/50x 54500 56700 toluene 310.15 8.4
B-EE/50x 95500 103000 toluene 310.15 7.8
B-EE/50x 129000 137000 toluene 310.15 7.55
B-EE/50x 209000 228000 toluene 310.15 7.1
_____________________________________________________________________________
EA-MMA/50w 95000 2-propanone 293.15 5.0
_____________________________________________________________________________
E-P/50x 8200 8400 toluene 310.15 22.3
E-P/50x 14500 14900 toluene 310.15 18.4
E-P/50x 22500 24500 toluene 310.15 15.8
E-P/50x 34600 36300 toluene 310.15 13.7
E-P/50x 41600 46400 toluene 310.15 12.85
E-P/50x 91400 96000 toluene 310.15 9.8
E-P/50x 267000 301000 toluene 310.15 6.8
E-P/50x 293000 316000 toluene 310.15 6.6
E-P/50x 545000 600000 toluene 310.15 5.35
_____________________________________________________________________________
E-TFE/50x 540000 diisobutyl adipate 513.15 1.97
E-TFE/50x 1160000 diisobutyl adipate 513.15 1.02
E-TFE/50x 1605000 3210000 diisobutyl adipate 513.15 0.511
_____________________________________________________________________________
EO-PO/72x 36000 water 298.15 6.0
EO-PO/80x 30800 water 298.15 10.5
EO-PO/80x 32500 water 298.15 12.5
EO-PO/87x 30100 water 298.15 21.5
_____________________________________________________________________________
HPF-TPC/50x 90000 trichloromethane 298.15 5.0
HPF-TPC/50x 90000 1,1,2,2-tetrachloroethane 298.15 7.8
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
NIPAM-AM/15x 3100000 water 298.15 3.01
NIPAM-AM/30x 4500000 water 298.15 3.31
NIPAM-AM/45x 3900000 water 298.15 3.46
NIPAM-AM/60x 2200000 water 298.15 3.62
_____________________________________________________________________________
IPE-MB/50x 11000 11300 toluene 310.15 13.2
IPE-MB/50x 17400 17600 toluene 310.15 11.5
IPE-MB/50x 37100 37800 toluene 310.15 9.2
IPE-MB/50x 97500 101000 toluene 310.15 6.9
IPE-MB/50x 115000 119000 toluene 310.15 6.55
IPE-MB/50x 216000 227000 toluene 310.15 5.4
IPE-MB/50x 275000 286000 toluene 310.15 5.0
IPE-MB/50x 393000 425000 toluene 310.15 4.5
_____________________________________________________________________________
IPE-MEE/50x 14600 15000 toluene 310.15 5.9
IPE-MEE/50x 27000 29200 toluene 310.15 5.6
IPE-MEE/50x 68300 72900 toluene 310.15 5.1
IPE-MEE/50x 90300 107000 toluene 310.15 5.0
IPE-MEE/50x 127000 133000 toluene 310.15 4.9
IPE-MEE/50x 157000 170000 toluene 310.15 4.8
IPE-MEE/50x 258000 278000 toluene 310.15 4.6
_____________________________________________________________________________
MA-MMA/50w 80000 2-propanone 293.15 5.5
_____________________________________________________________________________
MMA-AN/24x 400000 acetonitrile 303.15 1.522
_____________________________________________________________________________
7. A2 Data 439
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
ODC-MAH/50x 28000 ethyl acetate 298.15 3.0
_____________________________________________________________________________
OE-OM/05w 34000 62000 1H,1H,5H-octafluoro- 383.15 22.0
1-pentanol
1-pentanol
1-pentanol
1-pentanol
_____________________________________________________________________________
P-AA1/50x 90000 N,N-dimethylacetamide 298.15 11.0
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
S-AN/25w 90000 147000 tetrahydrofuran 298.15 11.5
_____________________________________________________________________________
S-AN/38x 96000 2-butanone 298.15 4.72
S-AN/38x 197000 2-butanone 298.15 7.70
S-AN/38x 197000 2-butanone 298.15 7.72
S-AN/38x 238000 2-butanone 298.15 4.15
S-AN/38x 264000 2-butanone 298.15 5.45
S-AN/38x 265000 2-butanone 298.15 5.43
S-AN/38x 323000 2-butanone 298.15 4.04
S-AN/38x 543000 2-butanone 298.15 3.67
S-AN/38x 601000 2-butanone 298.15 5.25
S-AN/38x 602000 2-butanone 298.15 5.23
S-AN/38x 647000 2-butanone 298.15 4.62
S-AN/38x 648000 2-butanone 298.15 4.62
S-AN/38x 756000 2-butanone 298.15 4.80
S-AN/38x 761000 2-butanone 298.15 4.77
S-AN/38x 832000 2-butanone 298.15 5.03
S-AN/38x 836000 2-butanone 298.15 5.01
S-AN/38x 1130000 2-butanone 298.15 4.89
S-AN/38x 1390000 2-butanone 298.15 3.59
_____________________________________________________________________________
S-AN/38x 144000 tetrahydrofuran 298.15 8.47
_____________________________________________________________________________
S-AN/40x 77000 50 mol% acrylonitrile + 298.15 12.0
50 mol% styrene
_____________________________________________________________________________
7. A2 Data 441
_____________________________________________________________________________

_____________________________________________________________________________
50 mol% styrene
50 mol% styrene
50 mol% styrene
_____________________________________________________________________________
S-AN/51x 269000 ethyl acetate 303.15 4.275
_____________________________________________________________________________
S-pMOS/26x(1) 61000 toluene 298.15 5.34
S-pMOS/26x(2) 71000 toluene 298.15 5.0
S-pMOS/26x(2) 86000 toluene 298.15 5.6
S-pMOS/26x(1) 93000 toluene 298.15 5.62
S-pMOS/26x(2) 105000 toluene 298.15 4.6
S-pMOS/26x(1) 131000 toluene 298.15 5.54
S-pMOS/26x(2) 137000 toluene 298.15 4.3
S-pMOS/26x(2) 171000 toluene 298.15 4.3
S-pMOS/26x(1) 200000 toluene 298.15 4.99
S-pMOS/26x(1) 245000 toluene 298.15 4.64
S-pMOS/26x(1) 285000 toluene 298.15 4.69
S-pMOS/26x(2) 308000 toluene 298.15 3.8
S-pMOS/26x(1) 348000 toluene 298.15 4.67
S-pMOS/26x(2) 350000 toluene 298.15 3.0
S-pMOS/26x(1) 420000 toluene 298.15 4.49
S-pMOS/26x(1) 665000 toluene 298.15 4.29
_____________________________________________________________________________
S-pMOS/53x 66000 toluene 298.15 5.46
S-pMOS/53x 104000 toluene 298.15 5.33
S-pMOS/53x 168000 toluene 298.15 4.68
S-pMOS/53x 269000 toluene 298.15 4.26
S-pMOS/53x 292000 toluene 298.15 4.22
S-pMOS/53x 446000 toluene 298.15 3.97
S-pMOS/53x 564000 toluene 298.15 3.98
S-pMOS/53x 642000 toluene 298.15 3.86
S-pMOS/53x 920000 toluene 298.15 3.82
S-pMOS/53x 1346000 toluene 298.15 3.81
S-pMOS/53x 1783000 toluene 298.15 3.41
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
S-pMOS/54x 35500 toluene 298.15 4.1
S-pMOS/54x 50500 toluene 298.15 5.2
S-pMOS/54x 60000 toluene 298.15 4.2
S-pMOS/54x 72000 toluene 298.15 3.6
S-pMOS/54x 94000 toluene 298.15 4.0
S-pMOS/54x 100000 toluene 298.15 3.6
S-pMOS/54x 121000 toluene 298.15 3.5
S-pMOS/54x 154000 toluene 298.15 3.2
S-pMOS/54x 234000 toluene 298.15 4.2
S-pMOS/54x 400000 toluene 298.15 3.8
S-pMOS/54x 660000 toluene 298.15 3.9
S-pMOS/54x 701000 toluene 298.15 3.2
_____________________________________________________________________________
S-pMOS/76x(2) 44000 toluene 298.15 5.9
S-pMOS/76x(2) 61000 toluene 298.15 5.4
S-pMOS/76x(1) 79000 toluene 298.15 4.54
S-pMOS/76x(1) 118000 toluene 298.15 4.50
S-pMOS/76x(2) 119000 toluene 298.15 4.1
S-pMOS/76x(2) 169000 toluene 298.15 3.9
S-pMOS/76x(1) 184000 toluene 298.15 3.92
S-pMOS/76x(2) 187000 toluene 298.15 4.2
S-pMOS/76x(2) 232000 toluene 298.15 3.2
S-pMOS/76x(1) 279000 toluene 298.15 3.72
S-pMOS/76x(2) 294000 toluene 298.15 3.0
S-pMOS/76x(2) 421000 toluene 298.15 3.5
S-pMOS/76x(1) 431000 toluene 298.15 3.55
S-pMOS/76x(1) 730000 toluene 298.15 3.30
S-pMOS/76x(1) 1149000 toluene 298.15 3.05
S-pMOS/76x(1) 1717000 toluene 298.15 3.00
_____________________________________________________________________________
S-MMA/30x 342000 cyclohexanol 339.15 0.0
S-MMA/30x 342000 2-ethoxyethanol 345.95 0.0
_____________________________________________________________________________
S-MMA/46w 1330000 2-butanone 298.15 1.8
S-MMA/46w 1330000 1,4-dioxane 298.15 3.3
S-MMA/46w 1330000 nitroethane 298.15 1.5
S-MMA/46w 1330000 tetrachloromethane 298.15 2.3
S-MMA/46w 1900000 2-butanone 298.15 1.5
S-MMA/46w 1900000 1,4-dioxane 298.15 3.6
S-MMA/46w 1900000 nitroethane 298.15 1.2
S-MMA/46w 1900000 tetrachloromethane 298.15 2.4
_____________________________________________________________________________
7. A2 Data 443
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
TFE-TFNM/50x 283000 1,1,2-trichloro- 308.15 0.745
1,2,2-trifluoroethane
_____________________________________________________________________________
VA-NVP65x 61000 30 mol% vinylacetate/70 mol% 298.15 −11.1
1-vinyl-2-pyrrolidinone
VA-NVP65x 126000 30 mol% vinylacetate/70 mol% 298.15 − 4.3
VA-NVP65x 148000 30 mol% vinylacetate/70 mol% 298.15 − 0.6
VA-NVP65x 631000 30 mol% vinylacetate/70 mol% 298.15 + 1.1
_____________________________________________________________________________
VA-VC/11x 29500 tetrahydrofuran 298.15 0.119
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
_____________________________________________________________________________
VC-BA/17x 173000 tetrahydrofuran 298.15 0.052
_____________________________________________________________________________
_____________________________________________________________________________
VC-BE/09x 30000 tetrahydrofuran 298.15 0.115
_____________________________________________________________________________
VC-MA/25x 221000 tetrahydrofuran 298.15 0.057
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
VC-VdC/15x 50000 tetrahydrofuran 298.15 0.091
_____________________________________________________________________________
7. A2 Data 445
_____________________________________________________________________________
7.2. References
55STO Stockmayer, W.H., Moore, L.D., Fixman, M., and Epstein, B.N., Copolymers in dilute
solution. I. Preliminary results for styrene-methyl methacrylate, J. Polym. Sci., 16, 517,
1955.
61COO Cooper, W., Vaughan, G., Eaves, D.E., and Madden, R.W., Molecular weight distribution
and branching in butadiene polymers and copolymers, J. Polym. Sci., 50, 159, 1961.
61MOR Morneau, G.A., Roth, P.I., and Shultz, A.R., Trifluoronitrosomethane/tetrafluoroethylene
elastomers dilute solution properties and molecular weight, J. Polym. Sci., 55, 609, 1961.
65WAG Wagner, H.L. and Wissbrun, K.F, Molecular weight and rheology of acetal copolymers,
Makromol. Chem., 81, 14, 1965.
66KOT Kotaka, T., Ohnuma, H., and Murakami, S., The theta-condition for random and block
copolymers of styrene and methyl methacrylate, Y, J. Phys. Chem., 70, 4099, 1966.
70WU1 Wunderlich, W., Lösungseigenschaften von statistischen Copolymeren aus Methyl-
methacrylat und n-Butylacrylat, Angew. Makromol. Chem., 11, 73, 1970.
70WU2 Wunderlich, W., Flexibilität und thermodynamische Eigenschaften von Polyacrylaten,
Polymethacrylaten und statistischen Acrylat/Methacrylat-Copolymeren, Angew. Makromol.
Chem., 11, 189, 1970.
72PIZ Pizzoli, M. and Ceccorulli, G., Solution properties of styrene-p-methoxystyrene random
copolymers II, Eur. Polym. J., 8, 769, 1972.
77BIR Birshtein, T.M., Zubkov, V.A., Milevskaya, I.S., Eskin, V.E., and Baranovskaya, I.A.,
Flexibility of aromatic polyimides and polyamidoacids, Eur. Polym. J., 13, 375, 1977.
77GL1 Gloeckner, G. and Mauksch, D., Streulichtmessungen an azeotropen Styrol-Acrylnitril-
Copolymeren in Butanon, Z. Phys. Chem., Leipzig, 258, 1142, 1977.
77GL2 Gloeckner, G., Über das Verhalten von Styrol-Acrylnitril-Copolymeren in Lösung III,
Faserforsch. Textiltechn., 28, 111, 1977.
77TA1 Tager, A.A., Kolmakova, L.K., Anufriev, V.A., Bessonov, Yu.S., Zhigunova, O.A.,
Vinogradova, S.V., Salazkin, S.N., and Tsilipotkina, M.V., Thermodynamics of the
dissolution of cardo polyarylates in chloroform and tetrachloroethane (Russ.), Vysokomol.
Soedin., Ser. A, 19, 2367, 1977.
79GL1 Gloeckner, G., Francuskiewicz, F., and Reichardt, H.-U., On the behaviour of styrene-
acrylonitrile copolymers in solution IV. Light scattering investigation of azeotropic
copolymers in tetrahydrofuran, Acta Polym., 30, 551, 1979.
79GL2 Gloeckner, G., Francuskiewicz, F., and Reichardt, H.-U., On the behaviour of styrene-
acrylonitrile copolymers in solution V. Light scattering investigation of α-methylstyrene
copolymers with about 46 mol% acrylonitrile in tetrahydrofuran as a solvent, Acta Polym.,
30, 628, 1979.
79STA Stacy, C.J. and Kraus, G., Second virial coefficients of homopolymers and copolymers of
butadiene and styrene in tetrahydrofuran, J. Polym. Sci., Polym. Phys. Ed., 17, 2007, 1979.
82MA1 Mangalam, P.V. and Kalpagam, V., Styrene-acrylonitrile random copolymer in ethyl
acetate, J. Polym. Sci., Polym. Phys. Ed., 20, 773, 1982.
82MA2 Mangalam, P.V. and Kalpagam, V., Behaviour of methylmethacrylate-acrylonitrile random
copolymers in dilute solution, Polymer, 23, 991, 1982.
84MAY Mays, J., Hadjichristidis, N., and Fetters, L.J., Characteristic ratios of model polydienes and
polyolefins, Macromolecules, 17, 2723, 1984.
85MAT Matsuo, K., Stockmayer, W.H., and Bangerter, F., Conformational properties of poly(1-
octadecene/maleic anhydride) in solution, Macromolecules, 18, 1346, 1985.
_____________________________________________________________________________
85MIN Minsker, K.S., Panchesnikova, R.B., Monakov, Yu.B., and Zaikov, G.E., Thermodynamic
and hydrodynamic properties of chlorine-containing carbochain polymers in solutions, Eur.
Polym. J., 21, 981, 1985.
86KAM Kamide, K., Miyazaki, Y., and Yamazaki, H., Dilute solution properties of acrylonitrile/
vinylidene chloride copolymer, Polym. J., 18, 645, 1986.
89EGO Egorochkin, G.A., Semchikov, Yu.D., Smirnova, L.A., Knyazeva, T.E., Tokhonova, Z.A.,
Karyakin, N.V., and Sveshnikova, T.G., Thermodynamic analysis of the copolymerization
of styrene with acrylonitrile and N-vinylpyrrolidone with vinyl acetate (Russ.), Vysokomol.
Soedin., Ser. B, 31, 46, 1989.
89CHU Chu, B., Wu, C., and Buek, W., Light scattering characterization of an alternating
copolymer of ethylene and tetrafluoroethylene. 3. Temperature dependence of polymer size,
94MUM Mumick, P.S., and McCormick, C.L., Water soluble copolymers. 54: N-isopropyl-
8. APPENDICES
8.1. List of copolymer acronyms
_____________________________________________________________________________
Acronym Copolymer Page(s)
_____________________________________________________________________________
AN-B Acrylonitrile/butadiene copolymer 22, 24, 29-32, 88-91, 269
270, 307-308, 346-348
AN-IP Acrylonitrile/isoprene copolymer 271
AN-MA Acrylonitrile/methyl acrylate copolymer 308-309
AN-MPCHEMA Acrylonitrile/2-(3-methyl-3-phenylcyclobutyl)- 91-93, 309-310
AN-αMS Acrylonitrile/α-methylstyrene copolymer 310-311, 431, 435
AN-VC Acrylonitrile/vinyl chloride copolymer 272-273
AN-VdC Acrylonitrile/vinylidene chloride copolymer 95, 273-274, 431, 435
B-EE Butylene/ethylethylene copolymer 432, 436-437
BA-MMA Butyl acrylate/methyl methacrylate copolymer 431, 436
BAIPC-TPC Bisphenol A-isophthaloyl chloride/terephthaloyl 274-275
chloride copolymer
BMA-IBMA Butyl methacrylate/isobutyl methacrylate copolymer 281
BMA-MMA Butyl methacrylate/methyl methacrylate copolymer 282, 431, 436-437
BO-EO Poly(butylene oxide)-b-poly(ethylene oxide) 187
diblock copolymer
pBS-pMS p-Bromostyrene/p-methylstyrene copolymer 35-36
CBL-PHA ε-Carbobenzoxy-L-lysine/L-phenylalanine copolymer 283-284
CP-MMA Chloroprene/methyl methacrylate copolymer 314
CP-MMA-MA Chloroprene/methyl methacrylate/methacrylic acid 314-315
terpolymer
DEA-VFe N,N-Diethylacrylamide/vinylferrocene copolymer 148
DEM-VA Diethylmaleate/vinyl acetate copolymer 315-316
DMA-BA N,N-Dimethylacrylamide/butyl acrylate copolymer 175, 178
DMA-BOEA N,N-Dimethylacrylamide/2-butoxyethyl acrylate 175, 178
copolymer
DMA-EA N,N-Dimethylacrylamide/ethyl acrylate copolymer 175, 178
DMA-EOEA N,N-Dimethylacrylamide/2-ethoxyethyl acrylate 175, 178
copolymer
DMA-MA N,N-Dimethylacrylamide/methyl acrylate copolymer 176, 178
DMA-MOEA N,N-Dimethylacrylamide/2-methoxyethyl acrylate 175, 178
copolymer
DMA-PA N,N-Dimethylacrylamide/propyl acrylate copolymer 175, 178
DMS-BAC Dimethylsiloxane/bisphenol-A carbonate copolymer 106-108
DMS-b-S Poly(dimethylsiloxane)-b-polystyrene diblock 163
copolymer
DMS-MPS Dimethylsiloxane/methylphenylsiloxane copolymer 47-50, 149-151, 176, 179
E-AA Ethylene/acrylic acid copolymer 188-191, 229-233, 350-355
E-B Ethylene/1-butene copolymer 356-363
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
E-BA Ethylene/butyl acrylate copolymer 192-194
E-CO Ethylene/carbon monoxide copolymer 108-109, 316-317
E-H Ethylene/1-hexene copolymer 194-196, 233-240
E-MA Ethylene/methyl acrylate copolymer 196-198
E-MAA Ethylene/methacrylic acid copolymer 363-370
E-O Ethylene/1-octene copolymer 198-199, 370-383
E-P Ethylene/propylene copolymer 22, 109-110, 176, 179-181,
200-204, 241-243, 284-292,
317-318, 383-398, 432, 437
E-P-D Ethylene/propylene/diene terpolymer 109-110, 317-318
E-P-IP Ethylene/propylene/isoprene terpolymer 200, 205-206
E-S Ethylene/styrene copolymer 399-405
E-TFE Ethylene/tetrafluoroethylene copolymer 432, 437
E-VA Ethylene/vinyl acetate copolymer 50-62, 111-117, 153, 176,
181, 206-221, 243-263,
292-293, 319-321, 406-421
E-VAL Ethylene/vinyl alcohol copolymer 176, 181, 321-322, 421-423
EA-MMA Ethyl acrylate/methyl methacrylate copolymer 432, 437
EMA-MA Ethyl methacrylate/methacrylic acid copolymer 117-118
EO-b-MMA Poly(ethylene oxide)-b-poly(methyl methacrylate) 64-65
diblock copolymer
EO-b-tBMA Poly(ethylene oxide)-b-poly(tert-butyl methacrylate) 62-63
diblock copolymer
EO-MMA-EO Poly(ethylene oxide)-b-poly(methyl methacrylate)- 64-65
EO-PO Ethylene oxide/propylene oxide copolymer 66-67, 164-170, 176, 181,
432, 437
EO-b-PO Poly(ethylene oxide)-b-poly(propylene oxide) diblock 66-67, 221-223, 293-294
copolymer
EO-PO-EO Poly(ethylene oxide)-b-poly(propylene oxide)- 66-68, 154, 222-224, 293-
b-poly(ethylene oxide) triblock copolymer 295
EO-S-EO Poly(ethylene oxide)-b-polystyrene-b-poly(ethylene 69-70
oxide) triblock copolymer
ET-pHBA Ethylene terephthalate/p-hydroxybenzoic acid 170-171
copolymer
HBA-HPA 3-Hydroxybutanoic acid/3-hydroxypentanoic acid 70-72
copolymer
HPF-TPC 9,9-bis(4-Hydroxyphenyl)fluorene/terephthaloyl 432, 437
chloride copolymer
IBMA-AA Isobutyl methacrylate/acrylic acid copolymer 118-119
IBMA-MMA Isobutyl methacrylate/methyl methacrylate copolymer 295-296
IPE-MB 1-Methylbutylene/isopropylethylene copolymer 432
IPE-MEE Isopropylethylene/1-methyl-1-ethylethylene copolymer 432, 438
MA-MMA Methyl acrylate/methyl methacrylate copolymer 432, 438
MAH-DEG Maleic anhydride/diethylene glycol copolymer 177, 181
MMA-AN Methyl methacrylate/acrylonitrile copolymer 433, 438-439
NCPAM-VFe N-Cyclopropylacrylamide/vinylferrocene copolymer 147
_____________________________________________________________________________
8. Appendices 449
_____________________________________________________________________________

_____________________________________________________________________________
NEAM-VFe N-Ethylacrylamide/vinylferrocene copolymer 151-152
NIPAM-AM N-Isopropylacrylamide/acrylamide copolymer 177, 181, 432, 438
NIPAM-IA N-Isopropylacrylamide/itaconic acid copolymer 155
NIPAM-VFe N-Isopropylacrylamide/vinylferrocene copolymer 156
ODC-MAH 1-Octadecene/maleic anhydride copolymer 433, 439
OE-OM Oxyethylene/oxymethylene copolymer 433, 439
P-AA1 Pyromellitic acid/4-amino-1,4-phenyleneoxy- 433, 439
1,4-phenyleneamine copolymer
P-AA2 Pyromellitic acid/4-amino-1,4-phenyleneoxy- 433, 440
1,4-phenylenoxy-1,4-phenyleneamine copolymer
PF(OE-OM) Perfluoro(oxyethylene/oxymethylene) copolymer 424-427
PHTH-TC Phenolphthalein/terephthaloyl chloride copolymer 336
PO-EO-PO Poly(propylene oxide)-b-poly(ethylene oxide)- 66, 68, 222-225
S-αMS Styrene/α-methylstyrene copolymer 157-159, 177, 182
S-AA Styrene/acrylic acid copolymer 119-120
S-AM Styrene/acrylamide copolymer 173
S-AN Acrylonitrile/styrene copolymer 32-35, 93-94, 145-146, 177,
181-182, 341-346, 433,
439-441
S-BR Butadiene/styrene copolymer 37-44, 96-104, 275-280,
311-313, 348-349
S-B-S Polystyrene-b-polybutadiene-b-polystyrene triblock 37-38, 46, 96-97, 105, 173,
copolymer 311-313, 348-349
S-B(h)-S Polystyrene-b-polybutadiene(hydrogenated)- 37-38, 47
b-polystyrene triblock copolymer
S-?-B Butadiene/styrene copolymer (block copolymer 37-38, 44-46, 348-349
without specification)
S-BMA Styrene/butyl methacrylate copolymer 72-73, 120-121, 296-298,
322-323
gS-CDA Styrene/cellulose diacetate graft copolymer 177, 182
S-DCM Styrene/docosyl maleate copolymer 73-74
S-DDM Styrene/dodecyl maleate copolymer 75-76
S-DMAM Styrene/N,N-dimethyl aminoethyl methacrylate 122-123
copolymer
S-DVB Styrene/divinylbenzene copolymer 323-324
S-EA Styrene/ethyl acrylate copolymer 325-326
S-b-EO Polystyrene-b-poly(ethylene oxide) diblock copolymer 69-70
S-I-S Polystyrene-b-polyisoprene-b-polystyrene 76-77
triblock copolymer
S-IBMA Styrene/isobutyl methacrylate copolymer 121-122
S-MAA Styrene/methacrylic acid copolymer 173
S-MAH Styrene/maleic anhydride copolymer 78
S-MAH-MA Styrene/maleic anhydride/methacrylic acid terpolymer 327
S-MEMA Styrene/2-methoxyethyl methacrylate copolymer 174
S-b-MMA Polystyrene-b-poly(methyl methacrylate) diblock 79, 81-82
copolymer
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
S-MMA Styrene/methyl methacrylate copolymer 79-81, 177, 182, 328,
427-428, 434, 442-443
S-pMOS Styrene/p-methoxystyrene copolymer 433, 441-442
S-MPCHEMA Styrene/2-(3-methyl-3-phenylcyclobutyl)- 124-125, 329
S-NMA Styrene/nonyl methacrylate copolymer 125-126, 330
S-NVP Styrene/1-vinyl-2-pyrrolidinone copolymer 174
S-PM Styrene/pentyl maleate copolymer 83-84
S-4VP Styrene/4-vinylpyridine copolymer 174
TFE-HFP Tetrafluoroethylene/hexafluoropropylene copolymer 228, 265
TFE-PFD Tetrafluoroethylene/2,2-bis(trifluoromethyl)- 126-127, 228, 331
TFE-TFNM Tetrafluoroethylene/trifluoronitrosomethane 177, 182, 434, 443
copolymer
VA-MAA Vinyl acetate/methacrylic acid copolymer 174
VA-NVP Vinyl acetate/1-vinyl-2-pyrrolidinone copolymer 162, 434, 443
VA-VAL Vinyl acetate/vinyl alcohol copolymer 87-88, 127-134, 298-304,
VA-VC Vinyl acetate/vinyl chloride copolymer 84-86, 134-139, 305, 434,
443-444
VA-VC-GMA Vinyl acetate/vinyl chloride/glycidyl methacrylate 134-135, 139
terpolymer
VA-VC-HPA Vinyl acetate/vinyl chloride/hydroxypropyl acrylate 134-135, 140
terpolymer
VA-VCPL Vinyl acetate/vinyl caprolactam copolymer 162
VAA-VIBA N-Vinylacetamide/N-vinylisobutyramide copolymer 162
VAL-VBU Vinyl alcohol/vinyl butyrate copolymer 162, 177, 182
VAMN-VCPL Vinyl amine/vinyl caprolactam copolymer 177, 182
VC-BA Vinyl chloride/butyl acrylate copolymer 434, 444
VC-BE Vinyl chloride/butyl ether copolymer 434, 444
VC-MA Vinyl chloride/methyl acrylate copolymer 434, 444
VC-VdC Vinyl chloride/vinylidene chloride copolymer 140-141, 306, 332, 434,
444
VCPL-VMA Vinyl caprolactam/N-vinyl-N-methylacetamide 162
copolymer
VCZ-ES N-Vinylcarbazole/4-ethylstyrene copolymer 428-429
VCZ-HS N-Vinylcarbazole/4-hexylstyrene copolymer 428-429
VCZ-OS N-Vinylcarbazole/4-octylstyrene copolymer 428-429
VCZ-PS N-Vinylcarbazole/4-pentylstyrene copolymer 428-429
VdF-HFP Vinylidene fluoride/hexafluoropropylene copolymer 228
VIBA-VVA N-Vinylisobutyramide/N-vinylvaleramide copolymer 162
VTZ-MVTZ 5-Vinyltetrazole/2-methyl-5-vinyltetrazole copolymer 336
_____________________________________________________________________________
8. Appendices 451
_____________________________________________________________________________
8.2. List of systems and properties in order of the copolymers
_____________________________________________________________________________
Copolymer (B) Solvent (A) Property Page(s)
_____________________________________________________________________________
Acrylamide/N,N-dimethylaminoethyl
water LLE 160
_____________________________________________________________________________
Acrylamide/N-isopropylacrylamide copolymer
see
_____________________________________________________________________________
Acrylamide/styrene copolymer
see
Styrene/acrylamide copolymer
_____________________________________________________________________________
Acrylic acid/ethylene copolymer
see
_____________________________________________________________________________
Acrylic acid/isobutyl methacrylate copolymer
see
Isobutyl methacrylate/acrylic acid copolymer
_____________________________________________________________________________
Acrylic acid/N-isopropylacrylamide copolymer
water LLE 160
_____________________________________________________________________________
water LLE 160
water Enthalpy 333
_____________________________________________________________________________
Acrylic acid/methyl methacrylate copolymer
water Enthalpy 333
_____________________________________________________________________________
Acrylic acid/2-methyl-5-vinylpyridine copolymer
water LLE 160
_____________________________________________________________________________
Acrylic acid/nonyl acrylate copolymer
bisphenol-A-diglycidyl ether LLE 160
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Acrylic acid/styrene copolymer
see
_____________________________________________________________________________
acetonitrile VLE 29-31
benzene Henry 89-91
benzene Enthalpy 270, 307
benzene Enthalpy 308
1,3-butadiene Henry 91
n-butane Henry 91
butylcyclohexane Henry 90
1-chlorobutane Henry 90
cyclohexane Henry 90-91
cyclohexane Enthalpy 308
n-decane Henry 89-91
2,2-dimethylbutane Henry 91
1,4-dioxane Henry 89-90
ethyl acetate Henry 89-90
ethylbenzene Henry 91
n-heptane Henry 89-90
n-heptane Enthalpy 307-308
n-hexane VLE 30-31
n-hexane Henry 89-90
n-hexane Enthalpy 308
hydrogen Enthalpy 333
mesitylene Henry 91
2-methylpropane Henry 91
nitrogen Enthalpy 333
n-nonane Henry 89-90
n-nonane Enthalpy 307
n-octane VLE 30-31
n-octane Henry 89-91
n-octane Enthalpy 307
1-octene Henry 90
n-pentane VLE 30-32
2-pentanone Henry 90
2-propanone Henry 89-90
tetrachloromethane Henry 90
tetrahydrofuran Henry 89-90
toluene Henry 89-91
toluene Enthalpy 307-308
trichloromethane VLE 30
trichloromethane Henry 89-90
without PVT 346-348
_____________________________________________________________________________
8. Appendices 453
_____________________________________________________________________________

_____________________________________________________________________________
carbon dioxide Enthalpy 333
N,N-dimethylformamide Enthalpy 271
helium Enthalpy 333
oxygen Enthalpy 333
_____________________________________________________________________________
Acrylonitrile/methyl acrylate copolymer
1-butanol Enthalpy 309
ethanol Enthalpy 309
1-hexanol Enthalpy 309
1-pentanol Enthalpy 309
1-propanol Enthalpy 309
_____________________________________________________________________________
Acrylonitrile/2-methylfuran copolymer
_____________________________________________________________________________
Acrylonitrile/methyl methacrylate copolymer
see
Methyl methacrylate/acrylonitrile copolymer
_____________________________________________________________________________
benzene Henry 92
2-butanone Henry 92
2-butanone Enthalpy 310
n-decane Henry 92
n-decane Enthalpy 310
n-dodecane Henry 92
n-dodecane Enthalpy 310
ethanol Henry 92
ethanol Enthalpy 310
ethyl acetate Henry 93
ethyl acetate Enthalpy 310
methanol Henry 93
methanol Enthalpy 310
methyl acetate Henry 92
methyl acetate Enthalpy 310
n-nonane Henry 92
n-octane Henry 92
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
2-propanone Henry 92
2-propanone Enthalpy 310
toluene Henry 92
toluene Enthalpy 310
n-undecane Henry 93
n-undecane Enthalpy 310
o-xylene Henry 93
o-xylene Enthalpy 310
_____________________________________________________________________________
1-butanol Enthalpy 311
2-butanone Enthalpy 311
butyl acetate Enthalpy 311
butylbenzene Enthalpy 311
chlorobenzene Enthalpy 311
cyclohexanol Enthalpy 311
dichloromethane Enthalpy 311
1,4-dioxane Enthalpy 311
n-dodecane Enthalpy 311
n-tetradecane Enthalpy 311
tetrahydrofuran Enthalpy 311
tetrahydrofuran A2 435
toluene Enthalpy 311
trichloromethane Enthalpy 311
_____________________________________________________________________________
acrylonitrile Enthalpy 333
acrylonitrile A2 440-441
benzene VLE 33
benzene Henry 94
2-butanone LLE 161
2-butanone A2 439-440
cyclohexane LLE 161
1,2-dichloroethane VLE 35
dimethyl phthalate LLE 173
ethyl acetate Henry 94
ethyl acetate LLE 161, 181
ethyl acetate LLE 182
ethyl acetate A2 440-441
propylbenzene VLE 33
propylbenzene Henry 94
styrene Enthalpy 333
styrene A2 440-441
_____________________________________________________________________________
8. Appendices 455
_____________________________________________________________________________

_____________________________________________________________________________
tetrahydrofuran A2 439-440
toluene VLE 32-34
toluene Henry 94
toluene LLE 145-146
toluene LLE 162, 181
trichloromethane Henry 94
water Enthalpy 333
o-xylene VLE 34
o-xylene Henry 94
m-xylene VLE 34
m-xylene Henry 94
p-xylene VLE 34
p-xylene Henry 94
without PVT 341-346
_____________________________________________________________________________
water Enthalpy 334
_____________________________________________________________________________
N,N-dimethylformamide Enthalpy 272-273
water Enthalpy 334
_____________________________________________________________________________
γ-butyrolactone A2 435
1,1-dichloroethene Henry 95
N,N-dimethylacetamide A2 435
N,N-dimethylformamide A2 435
2-propanone Enthalpy 274
_____________________________________________________________________________
N-Acryloylpyrrolidine/vinylferrocene copolymer
water LLE 160
_____________________________________________________________________________
Arylene sulfoxide/butadiene polyblock copolymer
trichloromethane LLE 172
1,1,2,2-tetrachloroethane LLE 172
_____________________________________________________________________________
Bisphenol-A carbonate/dimethylsiloxane
copolymer
see
Dimethylsiloxane/bisphenol-A carbonate
copolymer
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Bisphenol A-isophthaloyl chloride/terephthaloyl
chloride copolymer
N,N-dimethylacetamide Enthalpy 275
1,1,2,2-tetrachloroethane Enthalpy 275
_____________________________________________________________________________
p-Bromostyrene/p-methylstyrene copolymer
toluene VLE 36
_____________________________________________________________________________
Butadiene/acrylonitrile copolymer
see
_____________________________________________________________________________
Butadiene/methyl methacrylate copolymer
argon Enthalpy 334
_____________________________________________________________________________
argon Enthalpy 334
benzene VLE 40
benzene Henry 97-105
benzene Enthalpy 276-280
benzene A2 435-436
1,3-butadiene Henry 101-104
n-butane Henry 101-104
2-butanone Henry 105
cyclohexane Henry 97-105
cyclohexane Enthalpy 312-313
cyclohexane A2 435-436
2,2-dimethylbutane Henry 101, 104
ethylbenzene VLE 41-42
ethylbenzene Henry 101-105
ethylbenzene Enthalpy 277-280
n-heptane Henry 98-105
n-heptane Enthalpy 312-313
n-hexane VLE 39, 42
n-hexane Henry 97-105
n-hexane Enthalpy 312-313
mesitylene VLE 41
mesitylene Henry 101-104
2-methylpropane Henry 101, 104
_____________________________________________________________________________
8. Appendices 457
_____________________________________________________________________________

_____________________________________________________________________________
n-nonane VLE 43
n-nonane Henry 98-102
n-octane Henry 98-104
n-pentane VLE 39, 43
2-propanone VLE 38-40, 43
styrene Henry 103
styrene LLE 173
tetrahydrofuran LLE 173
tetrahydrofuran A2 435-436
toluene VLE 38-41
toluene Henry 97-105
toluene LLE 173
toluene Enthalpy 312-313
trichloromethane VLE 39-40, 44
trichloromethane Henry 97, 105
2,2,4-trimethylpentane Enthalpy 277-280
p-xylene VLE 41
p-xylene Henry 103-105
without PVT 348-349
_____________________________________________________________________________
Butadiene/styrene block copolymer (unspecified)
ethylbenzene VLE 44-45
n-nonane VLE 44-46
without PVT 348-349
_____________________________________________________________________________
1-Butene/ethylene copolymer
see
_____________________________________________________________________________
2-Butoxyethyl acrylate/N,N-dimethylacrylamide
copolymer
see
N,N-Dimethylacrylamide/2-butoxyethyl acrylate
copolymer
_____________________________________________________________________________
Butyl acrylate/N,N-dimethylacrylamide copolymer
see
_____________________________________________________________________________
Butyl acrylate/ethylene copolymer
see
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Butyl acrylate/methyl methacrylate copolymer
2-propanone A2 436
_____________________________________________________________________________
Butyl acrylate/vinyl chloride copolymer
see
Vinyl chloride/butyl acrylate copolymer
_____________________________________________________________________________
Butylene/ethylethylene copolymer
toluene A2 436-437
_____________________________________________________________________________
1,2-Butylene oxide/ethylene oxide copolymer
see
Ethylene oxide/1,2-butylene oxide copolymer
_____________________________________________________________________________
Butyl ether/vinyl chloride copolymer
see
Vinyl chloride/butyl ether copolymer
_____________________________________________________________________________
Butyl methacrylate/isobutyl methacrylate
copolymer
cyclohexanone Enthalpy 281
_____________________________________________________________________________
Butyl methacrylate/N-isopropylacrylamide
copolymer
see
N-Isopropylacrylamide/butyl methacrylate
copolymer
_____________________________________________________________________________
Butyl methacrylate/methyl methacrylate
copolymer
cyclohexanone Enthalpy 282
2-propanone A2 436-437
_____________________________________________________________________________
Butyl methacrylate/styrene copolymer
see
_____________________________________________________________________________
tert-Butylstyrene/dimethylsiloxane triblock
copolymer
2-butanone LLE 160
1-nitropropane LLE 160
_____________________________________________________________________________
8. Appendices 459
_____________________________________________________________________________

_____________________________________________________________________________
Carbon monoxide/ethylene copolymer
see
_____________________________________________________________________________
ε-Carbobenzoxy-L-lysine/L-phenylalanine
copolymer
1,2-dichloroethane Enthalpy 283-284
_____________________________________________________________________________
Chloroprene/methyl methacrylate copolymer
tetrachloromethane Enthalpy 314
_____________________________________________________________________________
Chloroprene/methyl methacrylate/methacrylic
acid terpolymer
_____________________________________________________________________________
water Enthalpy 334
_____________________________________________________________________________
N-Cyclopropylacrylamide/vinylferrocene
copolymer
water LLE 147
_____________________________________________________________________________
N,N-Diethylacrylamide/vinylferrocene copolymer
water LLE 148
_____________________________________________________________________________
Diethylene glycol/maleic anhydride copolymer
see
Maleic anhydride/diethylene glycol copolymer
_____________________________________________________________________________
Diethylmaleate/vinyl acetate copolymer
n-heptane Enthalpy 316
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-butoxyethyl acrylate
copolymer
water LLE 178
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
N,N-Dimethylacrylamide/butyl acrylate
copolymer
water LLE 178
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-ethoxyethyl acrylate
copolymer
water LLE 178
_____________________________________________________________________________
N,N-Dimethylacrylamide/ethyl acrylate
copolymer
water LLE 178
_____________________________________________________________________________
N,N-Dimethylacrylamide/2-methoxyethyl
acrylate copolymer
water LLE 160, 178
_____________________________________________________________________________
N,N-Dimethylacrylamide/methyl acrylate
copolymer
water LLE 178
_____________________________________________________________________________
N,N-Dimethylacrylamide/N-phenylacrylamide
copolymer
water LLE 160
_____________________________________________________________________________
N,N-Dimethylacrylamide/propyl acrylate
copolymer
water LLE 178
_____________________________________________________________________________
N,N-Dimethylaminoethyl methacrylate/
see
Acrylamide/N,N-dimethylaminoethyl
_____________________________________________________________________________
N,N-Dimethylaminoethyl methacrylate/styrene
copolymer
see
Styrene/N,N-dimethylaminoethyl methacrylate
copolymer
_____________________________________________________________________________
copolymer
_____________________________________________________________________________
8. Appendices 461
_____________________________________________________________________________

_____________________________________________________________________________
copolymer
chlorobenzene Henry 106-108
o-dichlorobenzene Henry 106-108
toluene Henry 106-108
_____________________________________________________________________________
Dimethylsiloxane/methylphenylsiloxane
copolymer
anisole VLE 48-49
anisole LLE 149-150
anisole LLE 160, 179
2-propanone VLE 49-50
2-propanone LLE 150-151
2-propanone LLE 160, 179
_____________________________________________________________________________
Dimethylsiloxane/1,1,3,3-tetramethyldisiloxanyl-
ethylene diblock copolymer
ethoxybenzene LLE 160
_____________________________________________________________________________
Docosyl maleate/styrene copolymer
see
Styrene/docosyl maleate copolymer
_____________________________________________________________________________
Dodecyl maleate/styrene copolymer
see
Styrene/dodecyl maleate copolymer
_____________________________________________________________________________
2-Ethoxyethyl acrylate/N,N-dimethylacrylamide
copolymer
see
N,N-Dimethylacrylamide/2-ethoxyethyl acrylate
copolymer
_____________________________________________________________________________
water LLE 152
_____________________________________________________________________________
Ethyl acrylate/N,N-dimethylacrylamide
copolymer
see
N,N-Dimethylacrylamide/ethyl acrylate
copolymer
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
Ethyl acrylate/ethylene copolymer
see
_____________________________________________________________________________
Ethyl acrylate/methyl methacrylate copolymer
2-propanone A2 437
_____________________________________________________________________________
Ethyl acrylate/styrene copolymer
see
Styrene/ethyl acrylate copolymer
_____________________________________________________________________________
Ethyl acrylate/tetraethylene glycol
dimethacrylate copolymer
argon Enthalpy 334
carbon dioxide Enthalpy 334
krypton Enthalpy 334
methane Enthalpy 334
neon Enthalpy 334
oxygen Enthalpy 334
_____________________________________________________________________________
Ethyl acrylate/4-vinylpyridine copolymer
tetrahydrofuran LLE 172
_____________________________________________________________________________
acrylic acid HPPE 229-233
n-butane HPPE 225, 264
1-butene HPPE 225
dimethyl ether HPPE 225, 264
ethanol HPPE 264
ethene HPPE 188-191
ethene HPPE 225, 229
ethene HPPE 230-233
propane HPPE 225
propene HPPE 225
without PVT 350-355
_____________________________________________________________________________
n-heptane HPPE 226
propane HPPE 226
without PVT 355-363
_____________________________________________________________________________
8. Appendices 463
_____________________________________________________________________________

_____________________________________________________________________________
ethene HPPE 192-194
ethene HPPE 226
_____________________________________________________________________________
n-octane Henry 109
_____________________________________________________________________________
1-butene HPPE 264
_____________________________________________________________________________
ethene HPPE 264
2-ethylhexyl acrylate HPPE 264
_____________________________________________________________________________
n-butane HPPE 233-237
n-butane HPPE 264
ethane HPPE 234
ethene HPPE 234-240
ethene HPPE 264
helium HPPE 234-239
n-heptane HPPE 226
1-hexene HPPE 264
methane HPPE 235-240
2-methylpropane HPPE 226, 264
nitrogen HPPE 264
propane HPPE 226, 236
_____________________________________________________________________________
water Enthalpy 334
_____________________________________________________________________________
1-butene HPPE 226
dimethyl ether HPPE 226, 264
ethanol HPPE 264
ethene HPPE 226
propane HPPE 226
without PVT 363-370
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
1-butanol HPPE 264
1-butene HPPE 226, 264
chlorodifluoromethane HPPE 226, 264
dimethyl ether HPPE 226
ethane HPPE 226
ethanol HPPE 264-265
ethene HPPE 197-198
ethene HPPE 226-227
n-hexane HPPE 227, 265
1-hexene HPPE 265
methanol HPPE 227, 265
methyl acrylate HPPE 264
propane HPPE 227, 264
propane HPPE 265
1-propanol HPPE 265
2-propanone HPPE 264-265
propene HPPE 227
_____________________________________________________________________________
n-heptane HPPE 227
_____________________________________________________________________________
cyclohexane HPPE 227
ethene HPPE 199
n-heptane HPPE 227
n-hexane HPPE 227
2-methylpentane HPPE 227
propane HPPE 227
propene HPPE 227
without PVT 370-383
_____________________________________________________________________________
benzene Henry 110
1-butene HPPE 227, 241
1-butene HPPE 265
tert-butylbenzene Enthalpy 318
chlorobenzene Enthalpy 335
cyclohexane Henry 110
cyclohexane Enthalpy 285, 318
_____________________________________________________________________________
8. Appendices 465
_____________________________________________________________________________

_____________________________________________________________________________
cyclohexane Enthalpy 335
cyclooctane Enthalpy 285-286
cyclopentane LLE 179-180
cyclopentane Enthalpy 286
cis-decahydronaphthalene Enthalpy 286
trans-decahydronaphthalene Enthalpy 286-287
n-decane Enthalpy 318
dichloromethane Henry 110
3,3-diethylpentane Enthalpy 287
2,2-dimethylbutane LLE 179-180
2,3-dimethylbutane LLE 179-180
2,4-dimethylhexane LLE 180
2,5-dimethylhexane LLE 180
3,4-dimethylhexane LLE 179-180
2,2-dimethylpentane LLE 179-180
2,2-dimethylpentane Enthalpy 287
2,3-dimethylpentane Enthalpy 287-288
n-dodecane Enthalpy 288-289
ethene HPPE 241-243
ethene HPPE 265
ethylbenzene Enthalpy 318
3-ethylpentane LLE 179-180
3-ethylpentane Enthalpy 289
n-heptane Henry 110
n-heptane LLE 179-180
n-heptane HPPE 227
2,2,4,4,6,8,8-heptamethylnonane Enthalpy 289
n-hexadecane Enthalpy 290
n-hexane Henry 110
n-hexane LLE 160, 179
n-hexane LLE 180
n-hexane HPPE 265
n-hexane Enthalpy 318, 335
1-hexene HPPE 265
methane HPPE 265
2-methylbutane LLE 160, 179
2-methylbutane LLE 180
2-methylbutane HPPE 265
_____________________________________________________________________________
_____________________________________________________________________________

_____________________________________________________________________________
methylcyclohexane LLE 179-180
methylcyclopentane LLE 160, 179
methylcyclopentane LLE 180
2-methylhexane LLE 179-180
3-methylhexane LLE 181
3-methylhexane Enthalpy 290
2-methylpentane LLE 179
3-methylpentane LLE 161
n-nonane LLE 179-181
n-octane Henry 110
n-octane LLE 179-181
n-octane Enthalpy 290-291
2,2,4,6,6-pentamethylheptane Enthalpy 291
n-pentane Henry 110
n-pentane LLE 161, 179
n-pentane LLE 181
n-pentane Enthalpy 335
propane HPPE 227
propene HPPE 203-204
propene HPPE 227, 265
tetrachloromethane Henry 110
2,2,4,4-tetramethylpentane LLE 179-181
2,2,4,4-tetramethylpentane Enthalpy 291-292
toluene Henry 110
toluene A2 437
trichloromethane Henry 110
1,1,2-trichlorotrifluoroethane Enthalpy 335
2,2,3-trimethylbutane LLE 179-181
2,3,4-trimethylhexane LLE 179
2,2,4-trimethylpentane LLE 179-181
2,2,4-trimethylpentane Enthalpy 292, 318
without PVT 383-398
_____________________________________________________________________________
benzene Henry 110
n-heptane Henry 110
n-hexane Henry 110
n-nonane Henry

(2018, CRC Press) CRC Handbook of Thermodynamic Data of Polymer Solutions, Three Volume Set

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

(2018, CRC Press) CRC Handbook of Thermodynamic Data of Polymer Solutions, Three Volume Set

Uploaded by

Copyright:

Available Formats

CRC HANDBOOK OF

No claim to original U.S. Government works

International Standard Book Number-13: 978-0-203-99820-5 (eBook - PDF)

Dr. Henry V. Kehiaian

IUPAC Representative on ICSU Committee on

Knowledge of thermodynamic data of polymer solutions is a necessity for industrial and

He is working on the evaluation, correlation, and calculation of thermophysical properties of pure

2. VAPOR-LIQUID EQUILIBRIUM (VLE) DATA

3. LIQUID-LIQUID EQUILIBRIUM (LLE) DATA

5. ENTHALPY CHANGES FOR AQUEOUS POLYMER SOLUTIONS

6. PVT DATA OF POLYMERS AND SOLUTIONS

7. SECOND VIRIAL COEFFICIENTS (A2)

1.1. Objectives of the handbook

• Vapor-liquid equilibrium (VLE) data of binary or ternary aqueous polymer solutions

1.2. Experimental methods involved

Investigations on vapor-liquid equilibrium of polymer solutions can be made by various methods:

1. Absolute vapor pressure measurement

1. Absolute vapor pressure measurement

2. Differential vapor pressure measurement

Difference/differential manometers have some advantages in their construction: they are

Again, the concentration can be determined independently by using a differential refractometer

3. Isopiestic sorption/desorption methods

Isopiestic measurements allow a direct determination of solvent activity or vapor pressure in

Concentration lowering under isothermal conditions is the classical isopiestic technique,

4. Gas-liquid chromatography (GLC)

Vnet = Vr − Vdead (1)

5. Vapor-pressure osmometry (VPO)

Liquid-liquid equilibrium (LLE) measurements

Experimental methods can be divided into measurements of cloud-point curves, of real

High-pressure phase equilibrium (HPPE) measurements

The experimental investigation of high-pressure fluid phase equilibria in polymer solutions is

Measurement of enthalpy changes in polymer solutions

∆Mh = nAHA + nBHB − (nAH0A + nBH0B) (12a)

The enthalpy effect might be positive (endothermic solution/mixture) or negative (exothermic

• per mole polymer B:

∆solHB = (∂∆ sol h / ∂nB ) P ,T ,n j = HB − H0B (14a)

∆solHB = (∂∆ sol h / ∂mB ) P ,T ,m j (14c)

∆MHB = ∆MH + (1 − xB)(∂∆MH/∂xB) (15)

∆solHA = (∂∆ sol h / ∂nA ) P ,T ,n j = HA − H0A (16a)

∆MHA = R [∂ ln a A / ∂ (1/ T )]P (18)

PVT/density measurement for polymer melt and solution

VEspez = Vspez − (wAV0A, spez + wBV0B, spez) (21a)

Determination of second virial coefficients A2

The freezing point depression, ∆SLTA, is:

and the boiling point increase, ∆LVTA, is:

The osmotic pressure, π , can be described as:

Scattering methods enable the determination of A2 via the common relation:

Sedimentation-diffusion equilibrium in an ultracentrifuge also gives a virial series:

1.3. Guide to the data tables

The molar mass averages are defined as follows:

Measures for the polymer concentration

cA = mA/V cB = mB/V (36)

wA = mA/Σ mi wB = mB/Σ mi (37)

xA = nA/Σ ni xB = nB/Σ ni with ni = mi/Mi and MB = Mn (38)

ϕA = (mA/ρA)/Σ (mi/ρi) ϕB = (mB/ρB)/Σ (mi/ρi) (39)

ψA = xArA/Σ xiri ψB = xBrB/Σ xiri usually with rA = 1 (40)

base mole fraction:

zA = xArA/Σ xiri zB = xBrB/Σ xiri with rB = MB/M0 and rA = 1 (41)

ϕA volume fraction of solvent A

For high-molecular polymers, a mole fraction is not an appropriate unit to characterize

Experimental data tables

Polymer (B): methylcellulose 1972KAG

Polymer (B): poly(N,N-diethylacrylamide) 2002MA2

or, e.g., in ternary systems with a second polymer