Ksp AgCl 1.

80E-10
V NaCl (mL) 25.00
M NaCl (mmol/mL) 0.5000
M AgNO3 (mmol/mL) 0.2500

Volume AgNO3 added (mL) [Ag+] [Cl-] pAg pCl

0.00 0 5.00E-01 N/A 0.30
20.00 1.08E-09 1.67E-01 8.97 0.78
49.00 5.33E-08 3.38E-03 7.27 2.47
50.00 1.34E-05 1.34E-05 4.87 4.87
51.00 3.29E-03 5.47E-08 2.48 7.26
80.00 7.14E-02 2.52E-09 1.15 8.60
 Figure 1. Titration curve of 25.00 mL of 0.5000 M
NaCl with 0.2500 M AgNO3
10.00
9.00
8.00
7.00
6.00
5.00
4.00
3.00
2.00
1.00
0.00
10.00 20.00 30.00 40.00 50.00 60.00 70.00 80.00 90.00

Answer 1. 50 mL of AgNO3 is required to reach the equivalent point.

Ksp AgCl 1.80E-10
Volume NaCl (mL) 25.00
Molarity of NaCl 0.5000
Molarity of AgNO3 0.2500

Volume AgNO3 added (mL) [Ag+] [Cl-] pAg pCl

0.00 0 5.00E-01 N/A 0.30
5.00 4.80E-10 3.75E-01 9.32 0.43
25.00 1.44E-09 1.25E-01 8.84 0.90
40.00 4.68E-09 3.85E-02 8.33 1.41
45.00 1.01E-08 1.79E-02 8.00 1.75
49.00 5.33E-08 3.38E-03 7.27 2.47
50.00 1.34E-05 1.34E-05 4.87 4.87
51.00 3.29E-03 5.47E-08 2.48 7.26
55.00 1.56E-02 1.15E-08 1.81 7.94
60.00 2.94E-02 6.12E-09 1.53 8.21
75.00 6.25E-02 2.88E-09 1.20 8.54
95.00 9.38E-02 1.92E-09 1.03 8.72
100.00 1.00E-01 1.80E-09 1.00 8.74

Figure 2. Titration curve of 25.00 mL of 0.5000 M

NaCl with 0.2500 M AgNO3
10.00
9.00
8.00
7.00
6.00
5.00
4.00
3.00
2.00
1.00
0.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00

Answer 2. Based on the titration curve, indicators with pH ranges of 4.0-5.5 should provide a sharp endpoint in this titration.
sharp endpoint in this titration.
Ksp AgCl 1.80E-10
Volume NaCl (mL) 25.00
Molarity of NaCl 0.05000
Molarity of AgNO3 0.02500

Volume AgNO3 added (mL) [Ag+] [Cl-] pAg pCl

0.00 0 5.00E-01 N/A 0.30
5.00 4.80E-09 3.75E-02 8.32 1.43
25.00 1.44E-08 1.25E-02 7.84 1.90
40.00 4.68E-08 3.85E-03 7.33 2.41
45.00 1.01E-07 1.79E-03 7.00 2.75
49.00 5.33E-07 3.38E-04 6.27 3.47
50.00 1.34E-05 1.34E-05 4.87 4.87
51.00 3.29E-04 5.47E-07 3.48 6.26
55.00 1.56E-03 1.15E-07 2.81 6.94
60.00 2.94E-03 6.12E-08 2.53 7.21
75.00 6.25E-03 2.88E-08 2.20 7.54
95.00 9.38E-03 1.92E-08 2.03 7.72
100.00 1.00E-02 1.80E-08 2.00 7.74
 Figure 3. Titration curve for A. 25.00 mL of 0.5000 M NaCl
with 0.2500 M AgNO3 and B. 25.00 mL of 0.05000 M NaCl
with 0.02500 M AgNO3
10.00
9.00
8.00
7.00
6.00
5.00
4.00
3.00
2.00
1.00
0.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00

Answer 3. The change in the pAg at the equivalence-point region of curve B is

relatively less than that of curve A. Based on this, we can conclude that the wideness
of the curve, vertically, is affected by the concentration of the solutions. The higher
the concentration, the wider the curve is, vertically.
Ksp AgBr 5.0E-13
Volume NaBr (mL) 25.00
Molarity of NaBr 0.5000
Molarity of AgNO3 0.2500

Volume AgNO3 added (mL) [Ag+] [Cl-] pAg pCl

0.00 0 5.00E-01 N/A 0.30
5.00 1.33E-12 3.75E-01 11.88 0.43
25.00 4.00E-12 1.25E-01 11.40 0.90
40.00 1.30E-11 3.85E-02 10.89 1.41
45.00 2.80E-11 1.79E-02 10.55 1.75
49.00 1.48E-10 3.38E-03 9.83 2.47
50.00 7.07E-07 7.07E-07 6.15 6.15
51.00 3.29E-03 1.52E-10 2.48 9.82
55.00 1.56E-02 3.20E-11 1.81 10.49
60.00 2.94E-02 1.70E-11 1.53 10.77
75.00 6.25E-02 8.00E-12 1.20 11.10
95.00 9.38E-02 5.33E-12 1.03 11.27
100.00 1.00E-01 5.00E-12 1.00 11.30

Ksp AgI 8.3E-17

Volume NaI (mL) 25.00
Molarity of NaI 0.5000
Molarity of AgNO3 0.2500

Volume AgNO3 added (mL) [Ag+] [Cl-] pAg pCl

0.00 0 5.00E-01 N/A 0.30
5.00 2.2E-16 3.75E-01 15.65 0.43
25.00 6.6E-16 1.25E-01 15.18 0.90
40.00 2.2E-15 3.85E-02 14.67 1.41
45.00 4.6E-15 1.79E-02 14.33 1.75
49.00 2.5E-14 3.38E-03 13.61 2.47
50.00 9.1E-09 9.11E-09 8.04 8.04
51.00 3.3E-03 2.52E-14 2.48 13.60
55.00 1.6E-02 5.31E-15 1.81 14.27
60.00 2.9E-02 2.82E-15 1.53 14.55
75.00 6.3E-02 1.33E-15 1.20 14.88
95.00 9.4E-02 8.85E-16 1.03 15.05
100.00 1.0E-01 8.30E-16 1.00 15.08

18.00

16.00
18.00

16.00

14.00

12.00

10.00

8.00

6.00

4.00

2.00

0.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00
 Figure 4. Titration curve for A. 25.00 mL of 0.5000
M NaCl with 0.2500 M AgNO3, B. 25.00 mL of
0.5000 M NaBr with 0.2500 M AgNO3, and C. 25.00
mL of 0.5000 M NaI with 0.2500 M AgNO3
18.00

16.00

14.00
Ksp AgI - 8.3E-17
12.00

10.00
Ksp AgBr - 5.0E-13
8.00

6.00
Ksp AgCl - 1.8E-10
4.00

2.00

0.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00

Answer 4. The range of the change in the pAg at the equivalence-point region of the
three curves varied greatly: curve A appears to be relatively narrower than the other
two, while curve C appears to be the widest. Based on this, we can conclude that the
Ksp (solubility) of the products had an effect on the trend of the curves. The
supposed "length" of the equivalence-point region becomes greater as the solubility
products becomes smaller.