WTA–01-2015-P1-ADV MODEL

XII-IC(CF) BATCHES (Date: 16.05.2022)

Tim e: 3 ho u r s Ma x im um m a rk s: 2 6 4
JEE ADV Model
PHYSICS

Section Question type +Ve – Ve No. of Total

Qs. marks
Marks Marks

Sec – I (Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32

Questions with Multiple Choice Correct
Sec – II (Q.N : 9 – 18) 4 -2 10 40
Matrix Match (+2/-1 for every match)
Sec – III (Q.N : 19 – 8 -4 2 16
20)

Total 20 88

CHEMISTRY

Section Question type +Ve – Ve No. of Total

Qs. marks
Marks Marks

Sec – I (Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32

Questions with Multiple Choice Correct
Sec – II (Q.N : 9 – 18) 4 -2 10 40
Matrix Match (+2/-1 for every match)
Sec – III (Q.N : 19 – 8 -4 2 16
20)

Total 20 88

MATHEMATICS

Section Question type +Ve – Ve No. of Total

Qs. marks
Marks Marks

Sec – I (Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32

Questions with Multiple Choice Correct
Sec – II (Q.N : 9 – 18) 4 -2 10 40
Matrix Match (+2/-1 for every match)
Sec – III (Q.N : 19 – 8 -4 2 16
20)

Total 20 88
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PHYSICS
SECTION – I
(INTEGER ANSWER TYPE)
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both
inclusive).
Marking scheme: +4 for correct answer,0 if not attempted and 0 in all other cases.

1. Three equal charges each having value q are placed at the corners of an equilateral triangle.
The force between two charges is F. The net force on each charge is xF, then x is:
2. Two charges placed at a certain distance r in air exert a force F on each other. Now the charges
are immersed in a liquid of dielectric constant K and separation between them is changed to
r / K. New force between charges is xF, then x is:
3. A charged oil drop in Millikan’s experiment remains suspended in a uniform electric field of
2 104 Vm1. If mass of oil drop is 1.6 1015 kg, the excess number of electrons on the drop
are:
4. Two particles A and B having charges 8.0 106 C and 2.0 106 C respectively are held
fixed with a separation of 20 cm. Where should a third charged particle be placed so that it
does not experience a net electric force? (as shown in figure). Value of x is equal to 4 n (in
cm), value of ‘n’ is

5. A charge of 2  C is placed at x = 0 and a charge of 32C at x = 60 cm. A third charge –Q

be placed on the x-axis such that it experiences no force. The distance of the point from 2  C
is (in cm) is ( x  4  n ). Value of ‘n’ is

6. Two charges of 50C and 100C are separated by a distance of 0.6m. The intensity of
electric field at a point midway between them is x 10 N / C. Value of x is
7. The excess (equal in number) number of electrons that must be placed on each of two small
spheres spaced 3 cm apart with force of repulsion between the spheres to be 1019 N is. Excess
number of electron is 125 n . Value of ‘n’ is
8. Electrical force between two point charges is 200N. If we increase 10% charge on one of the
charges and decrease 10% charge on the other, then electrical force between them for the same
distance becomes 99 n . Value of ‘n’ is

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SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and
(D) for its answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer,0 if not attempted and -2 in all other cases.

9. Five balls numbered 1 to 5 are suspended using separate threads. Pairs (1, 2), (2, 4) and (4, 1)
show electrostatic attraction while pairs (2, 3) and (4, 5) show repulsion. Therefore ball 1 must
be
(A) Positively charged (B) Negatively charged
(C) Neutral (D) Made of metal
10. A point charge ‘Q’ is placed at origin ‘O’. Let E A , E B and E C represent electric fields at A, B
and C respectively. If coordinates of A, B and C are respectively (1, 2, 3)m, (1, 1, -1)m and (2,
2, 2)m then
(A) E A  E B (B) E A || E C
(C) | EB |  4 | EC | (D) | E B |  8 | E C |
11. A negative point charge placed at the point A is

(A) in stable equilibiurm alogn x-axis

(B) in unstable equilibrium along y-axis
(C) in stable equilibiurm along y-axis
(D) in unstable equilibrium along x-axis.
12. Mark out the correct options.
(A) The total charge of the universe is constant
(B) The total positive charge of the universe is constant
(C) The total negative charge of the universe is constant.
(D) The total number of charged particles in the universe is constant.
13. Two fixed charges 4Q (positive) and Q (negative) are located at A and B, the distance AB
being 3m.

(A) The point P where the resultant field due to both is zero is on AB outside AB.
(B) The point P where the resultant field due to both is zero is on AB inside AB.
(C) If a positive charge is placed at P and displaced slightly along AB it will execute
oscillations.

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(D) IF a negative charge is placed at P and displaced slightly along AB it will execute
oscillations.
14. Select the correct statement: (Only force on a particle is due to electric field)
(A) A charged particle always moves along the electric line of force.
(B) A charged particle may move along the line of force
(C) A charge particle never moves along the line of force
(D) A charged particle moves along the line of force only if released from rest.
15. A point charge is brought in an electric field. The electric field at a nearby point
(A) will increase if the charge is positive
(B) Will decrease if the charge is negative
(C) May increase if the charge is positive
(D) May decrease if the charge is negative.
16. A proton and an electron are placed in a uniform electric field.
(A) The electric forces acting on them will be equal.
(B) The magnitudes of the forces will be equal.
(C) Their accelerations will be equal.
(D) The magnitudes of their accelerations will be equal.
17. Two identical charges +Q are kept fixed some distance apart. A small particle P with charge q
is placed midway between them. If P is given a small displacement D, it will undergo simple
harmonic motion if
(A) q is positive and D is along the line joining the charges.
(B) q is positive and D is perpendicular to the line joining the charges
(C) q is negative and D is perpendicular to the line joining the charges
(D) q is negative and D is along the line joining the charges.
18. A particle of mass m and charge q is thrown in a region where uniform gravitational field and
electric field are present. The path of particle
(A) may be a straight line (B) may be a circle
(C) may be a parabola (D) may be a hyperbola

SECTION – III
(MATRIX MATCHING ANSWER TYPE)
This section contains 2 questions. Each question has four statements (A,B,C and D)given in column I and
four statements (P,Q,Rand S) in column II. Any given statement in column I can have correct matching with
ONE or MORE statement(s) given in column II. For example, if for a given question, statement B matches
with the statements given in Q and R, then for the particular question darken the bubbles corresponding to Q
and R in the OMR sheet.
For each correct matching will be awarded +2 marks ONLY and 0 if not attempted and -1 in all other
cases.

19. 4 kg block has charge of 2 coulomb and 5kg block is neutral. (bodies are non-conducting in
nature)
An electric field of magnitudes 9 N/C is switched on along +x direction.
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Column-I Column-II
(a) Acceleration of 4 kg block (P) 0
(b) Acceleration of 5 kg block (Q) 2
(c) Friction between 4 and 5 kg block (R) ½
(d) Friction between 5 kg block and ground (S) 3.2
(T) 10

20. 10 kg block, carrying charge 1C is placed on Rough horizontal surface of friction coefficient
(   0.4 ) electric field is switch on. (Block and the surface are non-conducting in nature)

Column-I Column-II
(A) E  30iˆ  40 ˆj (P) 0
(B) E  40iˆ  30 ˆj (Q) 0.6
(C) E  30iˆ  40 ˆj (R) 1.2
(D) E  40iˆ  30 ˆj (S) 1.6

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CHEMISTRY
SECTION – I
(INTEGER ANSWER TYPE)
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both
inclusive).
Marking scheme: +4 for correct answer,0 if not attempted and 0 in all other cases.

21. If the number of square and hexagonal faces formed in a truncated octahedron are x and y
3y
respectively, then the value of is
x
22. For ABCABCABC…… packing distance between two successive tetrahedral voids is x and
y 2
distance between two successive octahedral void is y in a unit cell, then value of   is
 x 
23. Marbles of diametre 2cm are to be placed either inside or upon an equilateral triangle of edge
length 4 cm drawn on a floor. Find the maximum effective number of marbles that can be
accommodated in this triangle
24. A crystalline solid is made of X, Y and Z elements. Atoms of X form FCC packing, atoms of Y
occupy octahedral voids while atoms of Z occupy tetrahedral voids. If atoms along one body
diagonal are removed. The simplest formula of solids becomes Xa , Yb , Zc , then the value of
a + b – c is
25. A crystal is made of particles A and B. A forms F.C.C. packing and B occupies all the
octahedral voids. If all the particles along the plane as shown in figure are removed, then, the
number of particle A removed upon number of particle B removed from a unit cell is

26. In NaCl crystal, if number of nearest neighbour of Na  be x and second nearest neighbour be
y then y-x is _________.
27. The net change in coordination number of the salt CsCl when subjected under high
temperature (above 500°C) is ________

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28. The edge length of a B.C.C. lattice of an element is 300 pm, then the molar volume of the
element is cm3 (approximated to nearest integer) is _________.

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and
(D) for its answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer,0 if not attempted and -2 in all other cases.

29. Select the correct statement among the following:

(A) Nearest neighbor distance in NaCl = a/2
a 3
(B) Nearest neighbor distance in CaF2 
4
a
(C) Nearest neighbor distance in CsCl 
2
a 3
(D) Nearest neighbor distance in Na 2 O 
4
30. In an F.C.C unit cell shown, which of the following statements is/are correct-

(A) sphere 11 & 14 touch each other

(B) sphere 10 & 14 touch each other
(C) sphere 10 & 12 are at a distance of 2 2r

(D) There are six planes in the fcc unit cell having such arrangement of atoms.

0
31. The height of a HCP unit cell is 5.715 A . Then
3
0 0
(A) radius of atom is 1.75 A (B) volume of unit cell 182 A

(C) each atom is in contact with 8 atoms (D) It is an ABAB type of packing

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32. In which of the following solids, cations occupy tetrahedral voids?

(A) Diamond (B) CaF2 (C) ZnS (D) Na 2O
0
33. The radius ratio of Cs  to Cl is 0.90. If the radius of Cl ion is 1.80 A , the correct statements
regarding the CsCl structure is/are
0
(A) The distance between the centres of Cl ions is greater than 3.60 A
0
(B) The distance between the centres of two Cl1 ions is 3.60 A
0
(C) The distance between Cs  ion and Cl1 is 3.42 A
0
(D) The distance between two Cs  ions is greater than 3.24 A
34. If maximum spherical space in a tetrahedral and octahedral void be ‘a’ and ‘b’ respectively,
then a spherical ion of volume ‘c’ which is to occupy a void space created in a F.C.C lattice
prefers:
(A) Octahedral void if a  c  b (B) Octahedral void if a> c > b
(C) tetrahedral void if a  c  b (D) b < c < a tetrahedral void
35. In a hypothetical solid, C atoms are found to form cubical close packed lattice. A atoms occupy
all tetrahedral voids. B atoms occupy all octahedral voids. A and B atoms are of appropriate
size, so that there is no distortion in CCP lattice of C atoms. Now if a plane as shown in the
following figure is cut. Then the cross section of this plane will look like.

(A) (B)

(C) (D)

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36. The HCP and CCP structure for a given element would be expected to
(A) The same co-ordination number
(B) The same volume of unit cell
(C) The same packing fraction
(D) The same effective number of atoms per unit cell
37. A mineral having the formula AB2 cystallises in the cubic close packed lattice, with A-atoms
occupying the lattice points. Now, Select the correct statement(s) of the following :
(A) Co-ordination number of A-atoms is 8
(B) Co-ordination number of B-atoms is 4
(C) Fraction of octahedral sites occupied by B-atoms is 50%
(D) Fraction of the tetrahedral sites occupied by B-atoms is 100%
38. KF crystallizes in the rock-salt type structure. If the radius of K  is x pm and that of F is y
pm, the shortest distance between the given ions in the structure is
(A) K  and F ions is  x  y  pm (B) K  and K  ions is 2 x  y
2

(C) F and F ions is 2y pm (D) Two corner ions is 2  x 2  y 2  pm

SECTION – III
(MATRIX MATCHING ANSWER TYPE)
This section contains 2 questions. Each question has four statements (A,B,C and D)given in column I and
four statements (P,Q,Rand S) in column II. Any given statement in column I can have correct matching with
ONE or MORE statement(s) given in column II. For example, if for a given question, statement B matches
with the statements given in Q and R, then for the particular question darken the bubbles corresponding to Q
and R in the OMR sheet.
For each correct matching will be awarded +2 marks ONLY and 0 if not attempted and -1 in all other
cases.

39. An element ‘A’ of atomic radius ‘r’ crystallizes in FCC unit cell of edge length ‘a’
Column-I Column-II
(A) Distance between the successive tetrahedral (P) a
voids 2
(B) Distance between two successive octahedral (Q) a
voids 2
(C) Distance between two nearest atom (R) 2r
(D) Shortest distance between an octahedral (S) 2r
and a tetrahedral void.
(T) <a

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40.

Column-I Column-II
(Arrangement in unit cell, (Coordination number of cation:
radius ratio in higher limit) Anion)
(A) Cations in CCP and anions in (P) Ration of number of cation to anion in one
alternate unit tetrahedral voids cell is 1 : 1
(B) Cations in simple cubic and (Q) Ratio of coordination number of cation to
anions in the body centre anion is 1 : 1
(C) Anions in CCP and cations in (R) Ratio of number of cation to anion just
all tetrahedral voids touching each other is not 1
(D) Cations in CCP and anions in (S) Number of next neighbors of ion is greater
all octahedral voids than 10

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MATHEMATICS
SECTION – I
(INTEGER ANSWER TYPE)
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both
inclusive).
Marking scheme: +4 for correct answer,0 if not attempted and 0 in all other cases.

41. If system of equations

 tan   x   cot   y  8cos 2  z  0
 cot   x   8cos 2  y   tan   z  0
 8cos 2  x   tan   y   cot   z  0
have non-trivial solution, then | 2sin  4  | is equal to
42. Number of positive integral value of p for which the system of equations
x  2y  z  px
3x  py  2z
2x  2y  z  pz
has a non-trivial solutions, is
43. If system of linear equations
 a  1 x  z  
x   b  1 y  
y   c  1 z  
where a, b, c  I does not have a unique solution, then maximum possible value of |a + b + c|
is:
44. The number of real values of a for which the system of equations:
a 3 x   a  1 y   a  2  z  0,
3 3

ax   a  1 y   a  2  z  0
xyz 0
has a non-zero solution is
28 25 38
45. Let N  42 38 65 , then the number of ways in which N can be resolved as a product of
56 47 83
two divisors which are relatively prime is

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ap 2 2ap 1 apq a  p  q  1
1
46. Let 1  aq 2
2aq 1 and  2  aqr a  q  r  1 then is equal to
2
ar 2 2ar 1 arp a r  p 1
1 1  sin x 1  sin x  cos x
 
47. Let F  x   2 3  2sin x 4  3sin x  2 cos x , x  R then F '   is equal to
2
3 6  3sin x 10  6sin x  3cos x
1  n  2n
48. If 1, ,  2 are the cube root of unity, then    n  2n 1 ( n  N, n  2 ) is equal to
 2n 1 n

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and
(D) for its answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer,0 if not attempted and -2 in all other cases.

49. Which of the following values of  satisfy the equation

1    1  2  1  3 
2 2 2

 2     2  2   2  3   648 ?
2 2 2

 3     3  2   3  3 
2 2 2

(A) -4 (B) 9 (C) -9 (D) 4

50. The value of  for which the system of equations
1    x  3y  4z  0
x   3    y  5z  0
3x  y   z  0
possesses non-trivial solution is(are)
(A) -1 (B) 0 (C) 1 (D) 2
 y  z
2 2
x yz
 z  x zx , ( x  y  z  0, x  y  z  0 ) Which of the following are true?
2
51. Let y 2
 x  y
2
z2 xy
(A)  is divisible by x 2  y 2  z 2
(B)   0
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(C)  is divisible by x  y  z
(D)  is divisible by both  x  y  and  y  z 
52. If A11 , A12 , A13 are the cofactors of the elements of the first row of the determinant A   a ij 
and  is the value of the determinant then
(A) a 21A11  a 22 A12  a 23A13  0 (B) a11A11  a12 A12  a13A13  
(C) a11A11  a12 A12  a13A13   (D) a 31A11  a 32 A12  a 33A13  0

2r x n  n  1 n
53. If  r  6r  1 2
y n  2n  3 , then the value of
2
 r is independent of
n  n  1
r 1
4r 3  2nr z 3

(A) x (B) y (C) z (D) x,y,z,n

x a
2 2
x  b2 x 2  c2
2

If    x  a   x  b  x  c  0 (where a  b  c ) then value of x is/are

3 3 3
54.
x  a  x  b  x  c
3 3 3

1
(A) 0 (B)  bc  ca  ab 
3
1
(C)   bc  ca  ab  (D) a
3
55. The determinant
a2  x2 ab ac
  ab b x
2 2
bc is divisible by
ac bc c2  x 2
(A) x (B) x 2 (C) x 3 (D) x 4
a1  b1x a1x  b1 c1
56.   a 2  b2 x a 2 x  b2 c 2  0 , then
a 3  b3 x a 3 x  b3 c3
a1 b1 c1
(A) x  1 (B) x  1 (C) x  4
2
(D) a 2 b2 c2  0
a3 b3 c3
1 x x x2
57. If   x 1 x x2  ax5  bx4  cx3  dx2  ex  f
x2 x 1 x

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(A) f  1 (B) e  3 (C) a  c  1 (D) b  d  1

58. If f  x  and g  x  are functions such that f  x  y   f  x  g  y   g  x  f  y  then
f    g   f    
f    g    f      is independent of
f   g   f    
(A)  (B)  (C)  (D) 

SECTION – III
(MATRIX MATCHING ANSWER TYPE)
This section contains 2 questions. Each question has four statements (A,B,C and D)given in column I and
four statements (P,Q,Rand S) in column II. Any given statement in column I can have correct matching with
ONE or MORE statement(s) given in column II. For example, if for a given question, statement B matches
with the statements given in Q and R, then for the particular question darken the bubbles corresponding to Q
and R in the OMR sheet.
For each correct matching will be awarded +2 marks ONLY and 0 if not attempted and -1 in all other
cases.

59. Match the following for system of linear equations.

2x  3y  5z  12
3x  y   z  
x  7y  8z  17
Column-I Column-II
(A) Unique solution (P)   2,   7
(B) Infinite solutions (Q)   2,   R
(C) No solutions (R)   R,   7
(D) Consistent system of equation (S)   2,   7

60.
Column-I Column-II
(A)
1  sin x  (P) 10
3
x cos x
Coefficient of x in f  x   1 log 1  x  2 is
x 2
1 x 2
0
(B) 1 3cos  1 (Q) 0
Maximum value of sin  1 3cos  is   R 
1 sin  1

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(C) xa x2 1 1 (R) -12

If a, b, c are in A.P. and f  x   x  b 2x 2  1 1 , then
x  c 3x 2  2 1
f '0
(D) x 2 x (S) -2

If 1 x 6  a 4 x  a 3 x  a 2 x  a 2 x  a 0 , then a 0
3 2

x x x 1
is

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Space for rough work 15