Sec: XII C/F IIT WTM – 04 Ex.

Date: 16-05-2022

KEY SHEET
PHYSICS

1 2 3 4 5 6 7 8 9 10
C A D A D B D B D D
11 12 13 14 15 16 17 18 19 20
D D C D B D D D B A
21 22 23 24 25 26 27 28 29 30
1 5 2 99 1500 8 45 2 7 6

CHEMISTRY
31 32 33 34 35 36 37 38 39 40
D D A B C D C B B A
41 42 43 44 45 46 47 48 49 50
B D B A C D C A B B
51 52 53 54 55 56 57 58 59 60
6 3 6 2 1 5 4 2 0 6

MATHEMATICS
61 62 63 64 65 66 67 68 69 70
B B B C D C B C C D
71 72 73 74 75 76 77 78 79 80
D B C D A A D B B B
81 82 83 84 85 86 87 88 89 90
1 0 25 1 24 0 0 0 1 1
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022

Hints & Solution

PHYSICS
1. 1 2 3 4 5
+ − +
If 1 is positively charged, then 2 should be negatively charged, then 4 should be positively
charged. Now, 1 and 4 cannot attract. It means ball 1 should be neutral (2 and 4 cannot be
neutral because they are showing repulsion with 3 and 5, respectively)
2. Torque about 𝑄 of charge −𝑞 is zero, so angular momentum charge −𝑞 is constant, but
distance between charges is changing, so force is changing, so speed and velocity are changing
3. Frequency or time period of SHM depends on variable forces. It does not depend on constant
external force. Constant external force can only change the mean position. For example, in the
given question mean position is at natural length of spring in the absence of electric field.
Whereas in the presence of electric field mean position will be obtained after a compression
of𝑥0 . Where 𝑥0 is given by
𝑘𝑥0 = 𝒬𝐸
𝒬𝐸
𝑥0 =
𝑘
4. To keep the system in equilibrium, net force experienced by charges at ‘𝐴’, ‘B’ and ‘𝐶’ should be
zero. For this, another charge of oppositesign should be placed at the centroidof the triangle.
Let this charge be ‘−𝒬’

𝑙√3 2 1
𝐴𝐷 = 𝑙 cos 30° = , 𝐴𝑂 = 𝐴𝐷 =
2 3 √3
⃗ ⃗
2 = |𝐹𝐶𝐴 | cos 30° = |𝐹𝑐𝑜 |
1 𝑞 2 √3 1 𝒬𝑞 𝑞
2× × 2× = 2 ⇒𝒬=−
4𝜋𝜀0 𝑙 2 4𝜋𝜀𝑜 (𝑙√3) √3
5. 𝐴𝐶 = √2𝑙 = 𝐵𝐷
1
⇒ 𝐵𝑂 =
√2

𝐹𝐵𝑂 = 𝐹𝐵𝐷 + (𝐹𝐵𝐴 + 𝐹𝐵𝐶 ) cos 45°

Solving, we get
𝑞
𝒬 = 4 (1 + 2√2), 𝒬should be negative of 𝑞
6. When spheres are touched and separated, charge is
4𝑞 −2𝑞 2𝑞
𝑞′ = 2 = 2 = 𝑞
From Coulomb’s law
1 (4𝑞)(−2𝑞)
𝐹 = 4𝜋𝜀 … (i)
0 𝑟
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022
When made to touch
1 𝑞2
𝐹 ′ = 4𝜋𝜀 𝑟 … . . (ii)
0
From Eqs. (i) and (ii), we get
𝐹
𝐹′ = 8
7. By symmetry of problem the components of force on 𝑄 due to charges at 𝐴 and 𝐵 along 𝑦-axis
will cancel each other while along 𝑥-axis will add up and will be along 𝐶𝑂. Under the action of
this force charge 𝑄 will move towards 𝑂. If at any time charge 𝑄 is at a distance 𝑥 from 𝑂. Net
force on charge 𝑄

1 −𝑞𝑄 𝑥
𝐹𝑛𝑒𝑡 ⇒ 2𝐹 cos 𝜃 = 2 ×
4𝜋𝜀0 (𝑎2 + 𝑥 2 ) (𝑎2 + 𝑥 2 )1/2
1 2𝑞𝑄𝑥
𝑖. 𝑒. , 𝐹𝑛𝑒𝑡 = − . 2
4𝜋𝜀0 (𝑎 + 𝑥 2 )3/2
As the restoring force 𝐹𝑛𝑒𝑡 is not linear, motion will be oscillatory (with amplitude 2𝑎) but not
simple harmonic
8. 𝐹net = 2|𝐹31 | cos 𝛼
1 2 × 4 × 10−12 4
=2× × × = 0.46 N
4𝜋𝜀0 (0.5)2 5

9. If there had been a sixth charge +𝑞 at the remaining vertex of hexagon, force due to all the six
charges on – 𝑞 at 𝑂 will be zero

Now if 𝑓is the force due to the sixth charge and 𝐹due to the remaining five charges, then
𝐹⃗ + 𝑓⃗ = 0, i.e.,F
⃗⃗ = −𝑓⃗
1 𝑞×𝑞 1 𝑞 2
|𝐹⃗ | = |𝑓⃗| = = ( )
4𝜋𝜀0 𝐿2 4𝜋𝜀0 𝐿
10. Each charge will produce the same magnitude of intensity, say 𝐸 , at the centroid. These are
directed at angles of 120°with each other. So, their vector sum will be zero
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022

11. Mass of disc ∝ area, 𝑀𝐴 = 4𝑀𝐵 (as 𝑅𝐴 = 2𝑅𝐵 )

1 2
𝐼𝐴 2 𝑀𝐴 𝑅𝐴
=
𝐼𝐵 1 𝑀𝐵 𝑅𝐵2
2
12. Given 𝛼𝐴 = 2𝛼 = 5 m/s 2 ⇒ 𝛼 = 5 m/s2
2
5
Hence, acceleration of 𝐵, 𝑎𝐵 = 1(𝑎) = 2 m/s2
13. Torque exerted on the disc

Now 𝜏 = 𝐼𝛼
𝜏 𝑇𝑅 2𝑇𝑅 2𝑇
𝛼= =1 = 2
=
𝐼 𝑀𝑅 2 𝑀𝑅 𝑀𝑅
2
14. 1 1 𝑣 2 3𝑣 2
𝑚𝑣 2 = 2 𝐼 (𝑅) = 𝑚g ( 4g )
2
1
∴ 𝐼 = 𝑚𝑅 2
2
∴ Body is disc.
15. 𝑀𝐿2 6 × 4 × 4
𝐼= = = 8 kg m2
12 12
From 𝜏⃗ = 𝑟⃗ × 𝐹⃗ = [2𝑖̂ × (3𝑖̂ + 2𝑗̂ + 6𝑘̂)] = 4𝑘̂ − 12𝑗̂
3
𝜏𝑦 = 𝐼𝛼 ⇒ −12 𝑗 = 8𝛼 ⇒ 𝑎 = − 𝑗 rad/s2
2
16. In case of rolling in the inclined plane, friction is static and acts in the upward direction and is
given by
𝑚g sin θ
𝑓= 𝑅2
…(i)
1+ 2
𝑘
2
For sphere, 𝑘 2 = 𝑅 2 …(ii)
5
2
From Eqs.(i) and (ii), 𝑓 = 7 𝑚g sin θ(upwards)
17. Since linear acceleration is same for all (𝑎 = 𝑀g sin θ − 𝜇 𝑀g cos θ) as they have same mass ‘𝑀′
and same ‘𝜇’
Hence, all will reach the bottom simultaneously
18. 𝐼 = 𝐼1 + 𝐼2 + 𝐼3
3
𝐼1 = 𝐼2 = 𝑚𝑟 2
2
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022
3
𝐼1 = 𝐼2 = 𝑚𝑟 2
2
7
𝐼 = 𝐼1 + 𝐼2 + 𝐼3 = 𝑚𝑟 2
2
19.

The velocities of the ends 𝐴 and 𝐵 along the length of rod should be the same
Hence, 𝑣𝐴 cos 30° = 𝑣𝐵 cos 30° ⇒ 𝑣𝐴 = 𝑣𝐵 = 𝑣
Hence, the angular velocity of the rod is
(𝑣𝐴𝐵 )⊥ 2𝑣 sin 30° 𝑣
𝜔= = ⇒𝜔=
𝑙 𝑙 ℓ
20. In case of pure rolling bottommost point is the instantaneous centre of zero velocity.

Velocity of any point on the disc, 𝑣 = 𝑟𝜔,

where 𝑟 is distance of point from 𝑂.
𝑟𝑄 > 𝑟𝐶 > 𝑟𝑃
∴ 𝑣𝑄 > 𝑣𝐶 > 𝑣𝑃
21. After turning through 90°, the rod comes at rest momentarily. So there is no change in KE. Net
work done by all the forces should be zero

𝐿 𝐿 𝑀g
𝒬𝐸 − 𝑀g = 0 ⇒ 𝐸 =
2 2 𝒬
22. 𝑊 = 𝑞𝐸 × 𝑠 cos 𝜃 ⇒ 1 = 0.2 𝐸 × 2 cos 60°
⇒ 𝐸 = 5NC−1
23. 𝑞𝐸 𝑞𝐸
𝑎1 = and 𝑎2 = ⇒ 𝑎1 = 2𝑎2
𝑚 2𝑚
1 1 1 1
𝐾1 = 𝑚1 𝑣12 = 𝑚1 (𝑎, 𝑡)2 , 𝐾2 = 𝑚2 𝑣22 = 𝑚2 (𝑎2 𝑡)2
2 2 2 2
𝐾1 𝑚1 𝑎12 𝑚 4 2
= = × =
𝐾2 𝑚2 𝑎22 2𝑚 1 1
24. 100 = 𝑘𝑞1 𝑞2 /𝑟 2 and 𝐹 = 𝑘(1.1𝑞1 )(0.9𝑞2 )/𝑟 2
𝐹
⇒ = 0.99 ⇒ 𝐹 = 99 N
100
25. Taking torque about the attachment point for 𝑊, we get
−𝑇1 (0.4𝐿) + 𝑇2 (0.3𝐿) + 500(0.2𝐿) = 0
𝑇 = 1000 N, where 𝑇1 = 𝑇2 = 𝑇
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022
Σ𝐹𝑦 = 0 ⇒ 2𝑇 − 𝑊 − 500 = 0
⇒ 𝑊 = 1500 N
26. Balancing the torque:
For the first case: 16𝑙1 = 𝑚𝑙2
For the second case: 𝑚𝑙1 = 4𝑙2
Divide them to get 𝑚 = 8 kg
27. The cube will not topple until the line of action of CM passes through the cube

𝐴𝑋 𝑎/2
That is, tan θ = 𝑂𝑋 = 𝑎/2 or θ = 45°
28. 𝐹 = 𝑞1𝑞2 2 =𝑞1(𝑞1−𝑞22 )
4πε 𝑟 0 4πε 𝑟 0
∴ 𝐹 will be maximum, if
𝑑𝐹
𝑑𝑞
=0
1
q
∴ 𝑞 − 2𝑞1 = 0 or 𝑞1 = 𝑞/2 or 𝑞1 /𝑞 = 0.5 or =2
q1
29. Electric force 𝑞𝐸 = 𝑚𝑎 ⇒ 𝑎 = 𝑞𝐸
𝑚
1.6 × 10−19 × 1 × 103 1.6
∴𝑎= = × 1015
9 × 10−31 9
𝑢 = 5 × 106 and 𝑣 = 0
𝑢2
∴ From 𝑣 2 = 𝑢2 − 2𝑎𝑠 ⇒ 𝑠 =
2
2𝑎
(5×106 ) ×9
∴ Distance 𝑠 = = 7 𝑐𝑚. (approx)
2×1.6×1015

30. 𝐿total 𝑚1 𝑟12

= +1
𝐿𝐵 𝑚2 𝑟22

CHEMISTRY

31. Greater the electron density in Benzene Ring faster is the rate of Nitration Rxn.
32. Right Ring is more activated because Ione pair is donating the electronic cloud.
33. +H effect of C-H bond is compare to C-D & C-T bond that’s why first is more
reactive.
34. Greater the electron density in Benzene Ring faster is the rate of Nitration Rxn.
35. Conceptual
36. Conceptual (Electrophile will go to that ring where electron density is more).
37. Conceptual
38.
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022

39. Conceptual (Huckle’s Rule of Aromaticity).

40. Rate of Nitration will be same in all the cases because the remove of H+ is not
happening in RDs of Rxn.
41. D = 0.533 g/ml
M.M = ?
a  0.351107 cm
Z=2
Z  M .M
D
a3  NA
8
42. No. of moles of X   0.1 Moles.
80
4 atoms  1 unit cell
1
0.1 NA atom   0.1 N.A unit cell.
4
43. For CCP packing
2a  4r.
a  2 2r  2  2  215 Pm.
44. Theoretical
45. Theoretical
46. Theoretical
47. Theoretical
48. 1st , 2nd & 3rd nearest neighbor in SCC is - a, 2a, 3a
49. Answer is B. (Because packing fraction lies between SC & FCC unit cell.
1
50. ZA  8  1
8
1
ZB  8  2
4
1
ZC  4   1  3
2
AB2C3
O
||
51.  NH 2 ,  N  O, ome, O  C  CH 3 ,  ET ,  N  NH 2 are the O/P directing groups.
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022
52.

53.

54. 2nd position (Due to greater electron density & para position)
55. 1st position due to greater e- density in 2nd ring &  NH   is O/P directing.
||
O

56. Theoretical
57. Theoretical
1 1
58. ZX  8  2  2
8 2
59. Z  12
60. Theoretical

MATHEMATICS
61. Since the roots of the given equation are real.
 Disc. > 0  16 + 4 log3a  0
 log3 a  – 4  a 3–4  a  1/81
Hence, the least value of a is 1/81.
62. If roots are in same ratio then
32 (1).(2) ( 2) 2
= 9=  =
( 1) 2
(1). () ( ) 9

63. 3x2 + 2x + p (p – 1) = 0;   < 0

p ( p – 1)
< 0; p (p – 1) < 0;  0  p  1
3

64. One root of ax2 + bx + c = 0 is square of other root if

ac2 + a2c + b3 = 3abc
Here 3x2 + px + 3 = 0
 27 + 27 + p3 = 27 p
 p3 – 27 p + 54 = 0
Clearly p = 3 is a root
 (p – 3) (p2 + 3p – 18) = 0
 p = 3& from p2 + 3p – 18 = 0
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022

– 3  9  72
p=
2
p = – 6 or 3

65. f(x) = (x – a) (x – b) – 1 (a < b)

 f(a) = f(b) = – 1

a b
 
–1

Clearly – <  < a

& b <  < + 

66. D<0
4a2 – 4 (10 – 3a) < 0
(a2 + 3a – 10) < 0
(a + 5) (a – 2) < 0
–5<a<2
67. x + bx – 1 = 0 …(i)
-2

x2 + x + b = 0 …(ii)
b 1
(i) – (ii) we get x 
b 1
2
 b 1  b 1
   b  –1=0
 b 1   b 1 
b2 + 3b = 0
b(b2 + 3) = 0
b = 0 or b   i 3

68. Applying C1 + C2 + C3, we get

1 a b
Det. = 2(a + b + c) 1 b  c  2a b
1 a c  a  2b
1 a b
= 2(a + b + c) 0 a  b  c 0
0 0 cab
[by R2 – R1, R3 – R1]
= 2(a + b + c)3
69. Applying R1–(R2 + R3), we get
0  2c 2  2b 2
Det. = b 2 c2  a 2 b2
c2 c2 a 2  b2
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022
0  c2  b2
= 2 b2 c2  a 2 b2
c2 c2 a 2  b2

0  c2  b2
= 2 b2 a2 0
2
c 0 a2

(by R2 + R1, R3 + R1)

=2 (a2b2c2 + a2b2c2) = 4a2b2c2
70. Expanding along R1, we get
 6i (0) + 3i (4i + 20) +1 (12 – 60i) = x + iy
 –12 + 60i + 12 – 60i = 0 + 0i = x + iy
x=y=0

71. Non-zero solution

 = 0
1 k 1
 k 1 1 = 0
1 1 1

Let R3 = R3 – R2 ; R2 = R2 – R1
1 k 1
 k 1 k 1 0 = 0
1 k 2 0

Expanding along C3 , we get

k – 1 k 1
(–1) =0
1 k 2

1 1
(k–1) =0
1 k 2

(k–1) (k+1) = 0
k = ± 1

72. 1 1 1 1 1 1
= 1  1  2 2 = 1  2
1 2 4 1 2 

Let R1 = R1 + R2 + R3
3 0 0
 = 1  2
1 2 

 = 3 (2 – 4) = 3 (2 – ) = 3( –1)

73. =0
1 a 0
 0 1 a = 0
a 0 1
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022
 1 + a3 = 0
a3 = –1
 a = –1
74. Here
2 1  2
 = 1 2 1 =0
1 1 

 = –3
2 1  2
Also x =  4  2 1 = –8 –14  0
4 1 

When  = –3
 = –3 is solution

75.

76.
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022

77.

78.  k  2  x 2  8x  k  4  0
If real roots then,
82  4  k  2  k  4   0

 k 2  2k  8  16
 k 2  6k  4k  24  0
  k  6  k  4   0
 6  k  4
If both roots are negative then  is +ve and     0
 2k 4
 k 3

79. A relation on a set A is said to be symmetric if  a, b   A   b, a   A,  a, b  A

Here A  3, 4, 6,8,9

Number of order pairs of A  A  5  5

Divide 25 order pairs of A  A in 3 parts as follows:
Part - A :  3,3 ,  4, 4  ,  6, 6  , 8,8  ,  9,9 

Part- B :  3, 4  ,  3, 6  ,  3,8  ,  3,9  ,  4, 6  , (4,8), (4,9), (6,8), (6,9), (8,9)

Part - C :  4,3 ,  6,3 , 8,3 ,  9,3  ,  6, 4  , (8, 4), (9, 4), (8, 6), (9, 6), (9,8)
In part-A both components of each other pair are same. In part-B, both components are different but not two
such order pairs are present in which first component of one order pair is the second component of another order
pair and vice-versa.
In part-C, only reverse of the order pairs of part-B are present i.e., if (a, b) is present in part-B, then (b,a) will be
present in part-C
For example (3, 4) is present in part-B and (4, 3) present in part-C
Number of order pair in A, B and C are 5, 10 and 10 respectively.
In any symmetric relation on set A, if any order pair of part – B is present then its reverse order pair of part-C
will must be also present.
Hence number of symmetric relation on set A is equal to the number of all relations on a set D, which contains
all the order pairs of part-A and part-B.
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022
Now n  D   n  A  n  B   5  10  15

Hence number of all relations on set D   2 

15

80. Given that roots of the equation

bx2  cx  a  0 are imaginary
 c 2  4ab  0 ...  i 

Let y  3b2 x 2  6bcx  2c 2

D
 y  y  c 2  y  4ab from  i 
4A

81. Here the equation is x2 – p(x + 1) – c = 0

  = p,  = – (p + c) 
  ( + 1) ( + 1) = 1 – c
Now given expression
(  1) 2 (  1) 2
= + ,
(  1) 2  (1  c) (  1) 2  (1  c)

Putting value of 1 – c = ( + 1) ( +1)

 1  1
= +
  
  1   1
= = 1
 

82. Let be the common root of the given equations. Then
a2 + 2c + b = 0
and a2 + 2b+ c = 0
2 (c – b) + (b – c) = 0
1
 = [ b  c]
2
Putting  = 1/2 in a2 + 2c+ b = 0,
we get a + 4b + 4c = 0.
83. 3a 3b c 3a x p
x 2 y z = 3b 2 y 5
p 5 5 c z 5
(changing rows into columns)
3a x p
1
= 3b 2 y 5
3
3c 3z 15
a 5x p
3 1 1
= × b 10 y 5 = (125) = 25.
3 5 5
c 15z 15

84. Breaking the given determinant into two determinants, we get

32  k 42 32  k 32  k 42 3
4 k 5
2 2
4  k + 42  k 52 4 = 0
2

52  k 62 52  k 52  k 62 5
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022
9  k 16 3
0 + 7 9 1 =0
9 11 1
[Applying R3 – R2 and R2 – R1 in second det.]
9  k 16 3
 7 9 1 = 0 [Applying R3 – R2]
2 2 0
9k 7k 3
 7 2 1  = 0 [Applying C2 – C1]
2 0 0

2(7 – k – 6) = 0
k = 1.
85. Applying - R2  R2 – (R1 + R3)
x2  x x 1 x2
Determinant 4 0 0
x  2x  3 2x  1 2x  1
2

1 2
Applying = R1 R1 + x R2
4
1 2
and R3  R3 + x R2
4
x x 1 x2
Determinant =  4 0 0
2x  3 2x  1 2x  1
Applying = R3  R3 – 2R1
x  0 x 1 x  2
Determinant =  4 0 0
3 3 3
x x x 0 1 2
= 4 0 0 + 4 0 0
3 3 3 3 3 3
1 1 1 0 1 2
= x 4 0 0 + 4 0 0
3 3 3 3 3 3
= (24x – 12) P = 24.
n
86.   (r  1) = 1 + 2 +…..+ (n – 1)
r 1

n (n  1)
=
2
n
 (r  1) 2 =12 + 22+...+(n –1)2 = n (n  1) ( 2n  1)
6
r 1
n
 (r  1)3 = 13 + 23 +...+ (n – 1)3
r 1

n 2 (n  1) 2
=
4
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022
n (n  1)
n 6
2
n
1
  r n (n  1)(2n  1) 2n 2 2(2n  1)
r 1 6
1 2
n (n  1) 2 3n 3 3n (n  1)
4
6 n 6
n ( n  1)
= 2 (2n  1) 2n 2 2( 2n  1) = 0
12
3n (n  1) 3n 3 3n (n  1)

87. 3x 2 cos x  sin x

f '(x) = 6 1 0
2
p p p3

6 x  sin x  cos x
f "(x) = 6 1 0
2
p p p3
6  cos x sin x
f "(x) = 6 1 0
p p2 p3
put x = 0
6 1 0
f "'(0) = 6  1 0 = 0
p p2 p3

88. 1 x ( x  1)
f ( x)  2x x( x –1) x( x  1) x
3x( x –1) x( x –1)( x – 2) ( x  1) x( x  1)  x( x  1)
1 x ( x  1)
f(x) = x (x–1) 2 ( x – 1) ( x  1)
2

3 ( x – 2) ( x  1)

Let R3 = R3 – R2, R2 = R2 – R1
1 x x 1
f(x) = x (x–1) 2
1 1 0 =0
1 1 0

 f(100) = 0

89. (K + 1) x + 8y = 4K
Kx + (K+3) y = (3K–1)
For  solutions
K 1 8 4K
 
K K  3 3K – 1
K 1 8
   K = 1, 3 
K K 3
8 4K
    K = 1, 2
K  3 3K – 1
Narayana IIT Academy XII C/F IIT- CTM-01: EX. DT. 02-05-2022
K 1 4k
   K=1
K 3K  1

K = 1 is only solution

90.  = cos
2
+ i sin
2
=–
1
i
3
3 3 2 2
 is one of cube root of unity
z 1  2
 z 2
1 0
2 1 z

R1  R1 + R2 + R3
z z z
 z 2
1 0
 2
1 z

C1  C1 – C2 , C2  C2 – C3
0 0 z
z  2
z   1 2
1 0
 1 2
1 z   z
z [( – z – 2) (1 – z – ) – (2 – 1) (z + 2 – 1)] = 0
z (z 2) = 0
z3 = 0 ; z = 0
No. of distinct z is 1.