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11 Equilibrium Study Notes
11 Equilibrium Study Notes
Kc = and Kp =
cC + dD
aA + bB K =
1
naA + nbB
ncC + ndD K = Kn
2
1 1 1 1
aA + bB
cC + dD
n n n n K3 = K1/n
Equilibrium 105
Predicting the direction of reaction :
If Qc = Kc ⇒ The reaction is in a state of equilibrium.
Qc > Kc ⇒ The reaction proceeds in reverse direction.
Qc < Kc ⇒ The reaction proceeds in forward direction.
α=
3. Salt of strong acids and weak bases (e.g., NH4Cl) hydrolyse, pH < 7.
(The cation acts as an acid).
M+ + H2O
MOH + H+
pH = (pKb + logC)
4. Salt of weak acids and weak base (e.g., CH3COONH4) hydrolyse. The
cation acts as an acid and anion as a base but whether the solution
is acidic or basic depends upon the relative values of Ka and Kb for
these ions.
M+ + X– + H2O
MOH + HX
pH = (pKa – pKb)
Basic buffer : Solution of weak base and its salt with strong acid, For e.g.,
NH4OH + NH4Cl
Acidic buffer : Solution of weak acid and its salt with strong base, For
e.g., CH3COOH + CH3COONa.
pOH
= pKa + log (for basic buffer)
Equilibrium 107
Solubility Product (Ksp) : The equilibrium constant that represent the
equilibrium between undissolved salt (solute) and its ions in a saturated
solution is called solubility product constant (Ksp).
For
AxBy xAy+ + yBx–
K p = Kc(R5) and
ng = (c + d) + (a + b)
Effect of Concentration
Gaseous component A, B, C & D
Le-Chatlier If reactant concentration increases or
Principle product decreases then forward reaction
forward and vice-versa
Reaction Quotent
c d
[C] [D]
Qc = a b Effect of Volume (Opposite ‘P’ Effect)
[A] [B]
n = 0 No effect
Q c = Kc Reaction is at equilbrium n > 0 On increasing pressure
Q c < Kc Forward reaction favoured backward reaction favoured
Q c > Kc Backward reaction fovoured till and vice-versa
new equilibrium is re-establish n < 0 On increasing pressure
backward reaction favoured
and vice-versa
Equilibrium
Effect of Temperature Effect of Inert Gas (N2, Xe, Kr, etc.)
K2
H 1 1 If inter gas is added at constant condition then
log = = R ( –) no effect is observed
K1 2.303 T 1 T1
If inter gas is added at constant pressure then
For endothermic reaction H is + at ng = 0 No effect
If T increases, forward reaction favoure
ng > 0 Forward reaction fovoured
and otherwise backward reaction
109
If T decreases, For Exothermic opposite effect ng < 0 Forward reaction fovoured
110 Chemistry Class XI
MULTIPLE CHOICE QUESTION (MCQ)
1.
For the hypothetical reactions, the equilibrium constant (k) values are
given
A B : k1 = 2
B C: K2 = 4
C D : K3 = 8
(a)
H2(g) + Cl2(g) 2HCl(g) (b) N2(g) + 3H2(g) 2NH3(g)
(c)
PCl5(g) PCl3(g) + C12(g) (d) H2(l) + CO2(g) H2CO3(l)
5. For the reaction CO(g) + Cl2 (g) COCl2(g), the value of Kc/Kp is
equal to
(a) RT (b) RT (c) 1/RT (d) 1.0
6. At 90°C pure water has Kw = 10–12. The solution with pH value 6.5 is
(a) Acidic (b) Basic (c) Amphoteric (d) Data insufficient
Equilibrium 111
7. 40 ml of 0.1 M NH4OH is mixed with 20 mL of 0.1 M HCl. What is the
pH of the mixture? (pKb of ammonia solution = 4.74)
(a) 4.74 (b) 2.26 (c) 9.26 (d) 5
8. Identify Bronsted Lowry Acids in the reaction
[Al(H2Ol6]3– + HCO3 [Al(H2O)5(OH)]2+ + H2CO3
(X) (Y) (P) (Q)
Equilibrium 113
2.
Coloumn-I Column-II
A) Salt of weak acid and weak base P) pH = ½ (pKw + pKa + logc)
B) Salt of weak Acid and strong Base Q) pH = ½ (pKw + pKa – pkb)
C) Salt of strong acid and strong base R) pH = ½ (pKw – pKb – logc)
D) Salt of strong acid and weak base S) pH = ½ (pKw)
Equilibrium 117
33. Arrange the following in increasing Lewis base strange
NH3, BiH3, PH3, AsH3, SbH3
[Ans. BiH3< SbH3 < ASH3< PH3 < NH3]
34. Arrange following in increasing pH value
0.1M CH3COOH, 0.1 M NaCl, 0.1MHCl, 0.1MNaOH, 0.1MNH4OH
[Ans. 0.1MHCl < 0.1M CH3COOH < 0.1M NaCl <
0.1 NH4OH < 0.1M NaOH]
35. Arrange following in increasing order of degree of hydrolysis.
0.1M NH4OH, 0.01 M NH4OH, 10-5 M NH4OH, 10-3 M NH4OH, 10-6 M
NH4OH
[Ans. 0.1M NH4OH < 10-2 M NH4OH, 10-3M NH4OH<
10-5MNH4OH < 10-6 M NH4OH]
36. Arrange following in increasing order of acidic strengh
CH3COOH, HCOOH, CH3CH2COOH, C6H5COOH, CH2COOH
[Ans. CH3COOH < C6H5COOH < HCOOH < CH2FCOOH]
37. Arrange following in increasing order of basic strength in gas phase
NH3, (CH3)2NH, (CH3)3N, CH3NH2
[Ans. NH3 < NH3NH2 < (CH3)2NH < (CH3)3N]
38. Arrange the following pkb in increasing order
[Ans. pK2 < pK1 < pK4 < pK3]
39. Arrange the basic strength of following
F–, Br–, Cl–, I–
[Ans. I– < Br– < Cl– < F–]
40. Arrange the following in increasing base strength
CH3–, NH2–, OH–, F–
[Ans. F– < OH– < NH2 < CH3]
10. How many grams of NaOH must be dissolved in IL of the solution to give
it a pH value of L2? [Ans. 0.4g]
Equilibrium 119
3-MARKS QUESTIONS
Equilibrium 121
6. The % yield of Ammonia as a function of time in the reaction N2(g) +
3H2(g) 2NH3(g), DH < O at (P, T) is given below:
If this reaction is conducted at T2 > T1, then plot the % yield of NH3 as a
function of time on same graph
Ans. Initially on increasing temperature the T1
T2
rate of reaction increases, however since the %
reaction is exothermic therefore % yield of NH3 (yield)
Equilibrium 123